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NC0085928_Permit Modification_20030801
State of North Carolina Department of Environment AWWipA and Natural Resources Division of Water Quality Michael F. Easley, Governor 11CDEl.iR William G. Ross, Jr., Secretary NORTH CAROLINA DEPARTMENT OF Alan W. Klimek, P.E., Director ENVIRONMENT AND NATURAL RESOURCES August 1, 2003 Mr. Dirk Jaekel American Truetzschler Inc. P.O. Box 669228 Charlotte, North Carolina 28266 Subject: NPDES Permit Modification Permit NC0085928 American Truetzschler Inc. Mecklenburg County Dear Mr. Jaekel: The Division has reviewed and approved your request to change the monitoring requirement for Toxicity from composite to grab for the subject permit. Please find enclosed the revised permit page. The revised page should be inserted into your permit. The old page may then be discarded. All other terms and conditions contained in the original permit remain unchanged and in full effect. This permit modification is issued under the requirements of North Carolina General Statutes 143-215.1 and the Memorandum of Agreement between North Carolina and the U. S. Environmental Protection Agency. If any parts, measurement frequencies or sampling requirements contained in this permit modification are unacceptable to you, you have the right to an adjudicatory hearing upon written request within thirty (30) days following receipt of this letter. This request must be a written petition conforming to Chapter 150B of the North Carolina General Statutes, filed with the Office of Administrative Hearings (6714 Mail Service Center, Raleigh, North Carolina 27699-6714). Unless such demand is made, this decision shall be final and binding. If you have any questions concerning this permit modification, please contact Valery Stephens at telephone number (919) 733-5083, extension 520. Sincerely, ianFr` A an W. Klimek, P.E. cc: Central Files Mooresville Regional Office, Water Quality Section Point Source Compliance Enforcement Unit NPDES Unit 1617 Mail Service Center,Raleigh,North Carolina 27699-1617 Telephone(919)733-5083 FAX(919)733-0719 An Equal Opportunity Affirmative Action Employer VISIT US ON THE INTERNET @ http://h2o.enr.state.nc.us/NPDES A. (1.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS Beginning on the effective date of the permit and lasting until expiration,the Permittee is authorized to discharge from Outfall 001. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Type Sample Location Average _Maximum Frequency Flow 0.05MGD Weekly Pump or Meter Effluent 1,1-DichloroetheneI 0.057µg/L Monthly Grab Effluent 1,2-Dichloroethanel 0.38.tg/L Monthly Grab Effluent Trichloroethylene(TCE) 2.7µg/L Monthly Grab Effluent 1,1-Dichloroethane 2/Month Grab Effluent 1,1,1-Trichloroethane Monthly Grab Effluent Tetrachloroethylene(PCE) Monthly Grab Effluent pH2 Monthly Grab Effluent Chronic Toxicity3 Quarterly Grab Effluent Footnotes: 1. The detection limit for 1,1-Dichloroethene and for 1,2-Dichloroethane is 1.0 µg/L. If the measured level of 1,1-Dichloroethene or 1,2-Dichloroethane is below the detection limit,then the measurement is considered to be zero for compliance purposes and should be reported on the Discharge Monitoring Report(DMR)as<1.0 p.g/L. 2. pH shall not fall below 6.0 nor exceed 9.0 standard units. 1. Chronic Toxicity(Ceriodaphnia P/F at 90%),monitor quarterly in February, May, August and November[see Special Condition A.(2.)]. There shall be no discharge of floating solids or foam visible in other than trace amounts. r • , A&W Professional Services, PLLC JUL 16 July 14,2003 David Goodrich Director NCDENR-Permits&Engineering 1617 Mail Service Center Raleigh,NC 27699-1617 RE: Request Approval for Minor Modification to Ground Water Treatment System American Truetzschler,Inc. NPDES Permit No.NC0085928 A&W Project No. 30304X Dear Mr. Goodrich: On behalf of American Truetzschler, Inc. (ATI), Aaron & Wright Technical Services, Inc. (Aaron & Wright) and its professional subsidiary company A&W Professional Services, PLLC (A&W) is requesting permission to implement minor ground water remediation system modification. The original National Pollutant Discharge Elimination System (NPDES) Permit for this system was issued on December 3, 1996 and became effective on January 1, 1997. The current permit was issued on October 1,2001 and expires on midnight September 30,2006. Reason for System Modification Due to failed chronic toxicity testing in 1999 and 2000, ATI requested a modification to the ground water remediation system in August 2000.The modification at that time included the addition of two strongly acidic sodium cation exchange units to remove dissolved and total zinc from the treated ground water followed by the addition of two small limestone filtration filters to add cations back into the treated ground water prior to discharging to an open ditch. The request was granted and the modifications completed in August 2001. On August 28, 2001, ATI's consultant prepared the system for start-up and ran a batch sample through the system. ATI's consultant collected a sample of the effluent water and had it analyzed for total and dissolved zinc as well as for VOCs. The system was turned off immediately after the batch sample was collected. The sample results indicated that the total zinc levels were still too high to have a successful chronic toxicity analysis. ATI reduced the bypass water to approximately four gallons per minute (gpm) and increased the amount of discharge that runs through the resin at approximately twelve gpm. This made the discharge ratio of one-third-bypass water and two-thirds resin treated water. A&W Professional Services, PLLC 7523 A Little Avenue, Suite 213,Charlotte,NC 28226 704/543-4221 Fax 704/543-4295 e • Mr.David Goodrich July 14,2003 Page 2 On September 19, 2001, All's consultant turned on the system long enough to sample the effluent water for VOCs in accordance with EPA Method 601 plus cis-1,2 dichloroethene and for both total and dissolved zinc. Upon completion of the sampling activities, All's consultant turned the system off. The analytical results did not indicate detectable VOC concentrations with the exception of methylene chloride, which was flagged as a common laboratory contaminant. The analytical report also indicated zinc concentrations were within a range that ATI's consultant believed would pass the chronic toxicity sampling parameters. ATI's consultant collected effluent water samples for chronic toxicity testing on September 25 and 29, 2001. All's consultant also collected a grab sample for analysis of total and dissolved zinc on September 25, 2001. The September 25, 2001 laboratory report indicated acceptable concentrations of zinc. The laboratory report also indicated a passing chronic toxicity sample. ATI started the treatment system operations on October 8,2001. On November 6 and 9, 2001, ATI's consultant collected a sample of the effluent water and had it analyzed for pass/fail chronic toxicity utilizing Ceriodaphnia dubia at the 90 percentile. The laboratory analysis indicated that the results failed the chronic toxicity test at 90 percent. As a result of this failed test, All's consultant conducted two separate full range chronic toxicity test utilizing Ceriodaphnia dubia. The first test sample was collected on December 4 and 7,2001. The results of this chronic test showed a chronic value of 76.5 percent, which is below the required 90 percent. This test result was similar to the May 2, 2000 bench test results, which showed that the Ceriodaphnia dubia would live but not reproduce as well as the control. The test conducted in May 2000 was conducted utilizing the sodium cation exchange resin, however no limestone filter was used. The similarity in the results suggest that the limestone filter residence time was not adequate for the current flow or that the limestone has ceased providing enough cations to produce an environment suitable for the Ceriodaphnia dubia to live and reproduce. All's consultant reduced the flow rate from 16 gpm to 6 gpm to increase the limestone filter residence time and maintained the mixture rate of two parts effluent run through the sodium cation exchange resin to one part bypass water. All's consultant re-sampled the system effluent with the reduced flow rate on December 18 and 21, 2001. The results of this full range chronic toxicity test revealed a second failed chronic value of 76.5 percent. Since no change in chronic value was observed, ATI's consultant determined that the limestone was no longer dissolving cations and anions in the effluent water. ATI's consultant also sampled the effluent for water quality parameters to help establish a proper ratio of calcium and magnesium as well as other parameters such as total dissolved hardness, alkalinity, standard pH, and sulfate. ATI's consultant decided to turn the system off on December 27, 2001 until a solution could be achieved and to help reduce or avoid additional fines while a solution was found. On January 23 and 25, 2002, ATI's consultant turned the system on long enough to get a sample of effluent to test several new media and satisfy the NPDES requirement of a second Mr.David Goodrich July 14,2003 Page 3 chronic toxicitytest. Duringthis testingperiod, All's consultant conducted a month full range full chronic toxicity test utilizing crushed limestone. It should be noted that no water was allowed to bypass the resin filters during this sample collection to prevent an influence by low levels of zinc. All's consultant also collected and conducted a sample with 1/3 bypass water utilizing a neutralite filter media(i.e. 50 percent magnesium/carbonate media)and a soil compost filter. The neutralite and compost chronic test were conducted for pass/fail at 90 percent only. The results of the full chronic toxicity test utilizing the crushed limestone passed the test above 90 percent. The neutralite filter media test failed the pass/fail chronic toxicity at 90 percent. The compost media sample passed the chronic toxicity test above 90 percent. These chronic tests results also helped confirm that the problem with failed chronic toxicity is the result of the discharge water being absent of sufficient cations to support the test species. Based on this test All's consultant determined that the limestone would help add cations back into the system but that the rate at which limestone adds cations can be unpredictable. The compost filter was used to see if adding organic matter and naturally occurring nutrients might help buffer the discharge and provide a more predicable range of cations that would be conducive for sustaining the Ceriodaphnia dubia. On February 5 and 8, 2002, All's consultant collected an effluent sample and ran the sample through a crushed limestone bed and then through a compost filter prior to submittal to PACE for analysis of pass/fail chronic toxicity at 90 percent. The result of this test passed the 90 percent chronic toxicity. Based on this test it appeared that adding of nutrients by way of organic material may provide a more stable and reproducible chronic toxicity result. On April 4, 2002 All was issued civil penalties for failing the chronic toxicity test in November and December 2001. On May 6, 2002 All requested an administrative hearing, which was granted and originally set for November 2, 2002. On July 26, 2002, All met with representatives of the NCDENR, DWQ to discuss the problems with the remediation system. During that meeting it was agreed that ATI would submit an application requesting for a Special Order by Consent(SOC)to operate the remediation system for a period of one year to try several options to resolve the chronic toxicity problem. The three solutions for the system at that time included the adding of a compost filter, moving the discharge point to the Catawba River or changing the outfall location to allow the discharge to naturally move through some organic matter before sampling. In September 2002 ATI submitted an application requesting the SOC. On October 17, 2002 the NCDENR, DWQ sent a draft SOC for review and signature by All. All responded by signing the SOC and re-submitted it to the NCDENR. On January 13, 2003 the fmal SOC was received by All. In an effort to solve the chronic toxicity problem, All and it's new consultant A&W decided to run several full-scale pilot test while under the SOC. All and A&W revamped the remediation system by thoroughly cleaning the system, replacing the 3/.-inch limestone filtration units with two 55-gallon crushed limestone filtration units, and replacing components that failed to work during trial test runs. On November 15, 2002, Aaron &Wright started the remediation Mr.David Goodrich July 14,2003 Page 4 system. As part of the start-up procedures, the sodium cation exchange resins filters were regenerated and the reject water contained for evaporation. The system was allowed to run for 4 days prior to sampling. On Tuesday,November 19, 2002, A&W collected an effluent sample at the original outfall (Outfall 001) for volatile organic compounds (VOCs) plus Cis 1,2- dichloroethene (DCE) in accordance with EPA Method 601. A sample was also collected for water quality parameters from Outfall 001. In addition, a grab sample of the effluent was collected for chronic toxicity 90%by Ceriodaphnia dubia. A second grab sample was collected for acute pass/fail Toxicity Test utilizing Pimphales promelas. A&W took a third grab sample at a second outfall created approximately 40 feet down stream of Outfall 001. This second sample was collected to determine if the migration of water through natural debris in the outfall ditch would affect the test results of chronic toxicity. The third sample was taken from the downstream location for both water quality parameters and chronic toxicity pass/fail 90%by test species Ceriodaphnia dubia. On November 22, 2002, A&W personnel returned to the site and collected a second grab sample from both outfall 001 and the downstream location to complete the chronic toxicity testing of the Ceriodaphnia dubia 90%pass fail tests. The laboratory analytical results for VOCs plus Cis 1,2-DCE sample collected on November 19, 2002, from outfall 001 did not detect VOC constituents above the laboratory quantitation limit. All three chronic toxicity tests) Outfall 001 Ceriodaphnia dubia, Pimhales promelas and the down stream Ceriodaphnia dubia)passed. Since all the tests passed, A&W has concluded that the change in limestone media from Y4 -inch limestone to crushed limestone sufficiently added cations into the discharge water to allow the test to be successful. Unfortunately, due to the successful passing all of the chronic tests, the results did not yield a clear path for ATI to pursue to effectively solve the periodic chronic failures. Attached for your review is a copy of the laboratory analytical results for the November 2002 testing period. From this point on ATI and A&W did not pursue the down stream sampling location since it was close to being off the subject property. The Outfall sample for Pimhales promelas was conducted only to determine a last alternative if a solution could not be determined. The system was inactive due to ice damage, which occurred on December 4, 2002, from December 4, 2002 through February 21, 2003. The system was re-started after repairs on February 21, 2003. The system ran for a total of 7 days during the month. The system was sampled for volatile organic compounds(VOC) in accordance with EPA Method 601 plus cis 1,2 dichloroethene per the NPDES requirements on February 25, 2003. In addition, the system was sampled on February 21 and 28, 2003 for chronic toxicity utilizing Ceriodaphnia dubia at 90% pass/fail along with other water quality parameters. The analytical results showed no VOCs present above the laboratory detection limit. However, the chronic toxicity test failed the 90% Cheriodaphnia dubia pass/fail test. The water quality parameters appeared to be within the normal range observed when the system passed the chronic rates. In addition, the VOC constituents were all below the laboratory detection limit. Based on the laboratory analysis, it appeared at the crushed limestone bed was again not producing enough cations to provide an optimum environment for the Ceriodaphnia dubia to survive and reproduce at the same rate as j Mr.David Goodrich July 14,2003 Page 5 the control. See attached laboratory analytical data sheets for a complete list of constituents and test results. Due to the failed chronic toxicity test in February 2003,A&W installed a stainless steel compost filter at the discharge point at outfall 001. The compost filter was constructed of Stainless Steel and had the dimensions of 3.79 feet square and 3 feet tall. The compost filter allows approximately 7 cubic feet of compost to be used as a filter media, which will add nutrients to the discharged water prior to it being discharged to the open ditch. The filter was installed on March 14, 2003. The compost was purchased form a local hardware store (Lowe's Home Improvement). On March 25 and 28, 2003 A&W collected a grab sample of the compost material and had it analyzed for total RCRA metals, Semi-volatile organic compounds,(SVOCs), VOCs, and Pesticides. In addition, A&W collected grab samples of the effluent from outfall 001 for chronic toxicity pass/fail testing utilizing Ceriodaphnia dubia along with the water quality parameters and volatile organic compounds (VOCs) plus cis 1,2 dichloroethene in accordance with EPA Method 601 per the NPDES requirements. The discharge water sample passed the chronic toxicity test. In addition, no VOCs were detected in the effluent water above the laboratory detection limits. Therefore, the system met the effluent limit requirements for the month of March 2003. The compost sample results did detect several metals and SVOCs present in.the compost but they did not cause problems with the chronic toxicity. See attached laboratory analytical results. On each Tuesday and Friday,ATI opens the compost filter and replaces approximately 1 cubic foot of compost material. The removed compost material is placed back with the other compost for re-use. On April 22 and 25, 2003, May 20 and 23, 2003, A&W collected grab samples of the effluent from Outfall 001 and delivered it to PACE Analytical Services, Inc. for chronic toxicity pass/fail testing utilizing Ceriodaphnia dubia along with the water quality parameters and volatile organic compounds (VOCs) plus cis 1,2 dichloroethene in accordance with EPA Method 601 per the NPDES requirements. The discharge water sample passed the chronic toxicity test. In addition, no VOCs were detected in the effluent water above the laboratory detection limits. See attached,laboratory analytical results. Based on the last four months of successfully passing the chronic toxicity sampling while utilizing the compost filter it appears that the solution to the chronic toxicity problem is the addition of nutrients through the compost filter. Based on these successes ATI and A&W are requesting the system modifications become permanent. System Modifications The ground water remediation system modifications include the changing out of the two 8-inch diameter by 4 feet tall limestone filtration units which originally used 3/4-inch limestone as . a buffering agent with two 55-gallon,gravity feed,crushed limestone filtration units. These units Mr.David Goodrich July 14,2003 Page 6 will each hold approximately 5 cubic feet of crushed limestone or a total of approximately 10 cubic feet. After the crushed limestone, A&W is adding a compost filtration unit constructed out of stainless steel. The unit holds approximately 7 cubic feet of compost material. The entire compost filter measures 3.79 feet wide by 3.79 feet long by 3 feet tall. See the attached flow diagram for the minor modification schematics. Based on the research and bench test conducted by A&W,the above minor modifications should resolve the toxic levels of zinc discovered in the effluent water. Attached for your review is a letter from All authorizing Aaron & Wright Technical Services, Inc. (Aaron & Wright) to submit this request for system modification. Aaron & Wright has subcontracted it's subsidiary A&W Professional Services,PLLC a North Carolina professional corporation submit this request on All's behalf. In addition, attached is the flow schematic and supporting laboratory analytical results. Please contact me with your approval to construct the minor system modifications. Per your guidelines A&W has included three copies of the request. If you have any questions or need additional information please contact me at(704)543-4221. Sincerely, ,.11'jf141�j �s�. X01 _ C A:;,`; }'1`'i A&W PROFESSION: c;' ' ' :." ; �.C. e� �\CE NSF. '' `%t SERI 1247h/ te,,itti. Robert S.Hird,P.G. �°;it'sleo !S\ © Ai` ,ro��C4G �_61, �. Principal���i�i►ua;>»,��� tST t•���` ```,• a'��!G A g, 1, �r111 tlllllt '�-f4=��E�`t .,:vilt., - ' s Brace t .Dai .E. Prn ci s %,';p( .leVi S.. . CY' Cc: atrit DENR,DWQ,Moorseville Regional Office SIMI Andrew Pitner,NCDENR,Mooresville Regional Office Kevin Bowden,NCDENR,DWQ Shannon Langley,Point Source Compliance/Enforcement Dirk Jaekel,All John Guglielmetti,All AIR EXHAUST FILTER y Z O TRANSFER TANK TRANSFER AERATION TRANSFER ION EXCHANGE LIMESTONE PUMP UNIT PUMP CYLINDERS FILTERS INFLOW FROM RECOVERY WELLS 1--0 D 4 TO DISCHARGE LOCATION PEAT FILTER ,`,��rrrrirlr►►►►►' � 0 OFES3 � �',. 1.-1;4)P 41t92.1,43W LEGEND CF H. 0Pl'..` 3 r:01 BALL VALVE TREATMENT SYSTEM SCHEMATIC FIGURE: 1 0 STRAINER A W DATE: 7/14/03 -0- FLOW METER AMERICAN TRUETZSCHLER VALVE MOORES CHAPEL ROAD SCALE: NONE CHECKCHARLOTTE, NORTH CAROLINA PROJECT NO. 030304X