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HomeMy WebLinkAboutWQ0032016_Monitoring - 11-2022_20221229Monitoring Report Submittal Permit Number #* Name of Facility:* WQ0032016 Rose Hill Plantation Month: * November Year: * 2022 Report Information Type* Upload Document* GW-59 Rose Hill (WQ0032016) GW- 2.18MB 59 with lab results 12-29- 22.pdf PDF Only Please upload one PDF containing all applicable monitoring reports (i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59). Confirmation Email Address:* kreese@rpbsystems.com Name of Submitter: * Kimber Reese Signature: Date of submittal: 12/29/2022 This will be filled in automatically Initial Review Reviewer: Gerald, Wanda Is the project number correct?* WQ0032016 Is the monitoring report accepted?* Yes NO Regional Office* Asheville Reviewer: _anonymous Review Date: 1/18/2023 ("NV (`0NJ19LLkN(`E REA101014)lukl llei'mil fi nQ0-320116 ("SdOppal raa oach Pqopdlorha,pet h A " I with G Oi-39 P wory. � Enter date monitoring results were due. (12J31/2022) Will this monitoring report (GW-59 and GW-59A) be submitted after the established due date? YES NO X 2 Was any reqtjjred information missing on the GW-59 report forms? --V7ES— NO IF the answer to question t or 2 is "YES': list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO -K identification plate, area overgrown, etc.)'.' It answer is" Yes ", van tact the Heyional tJ1 el ) IfidancL 4 Are any monitored constituents equal to or above the established standards? --TVE—S NO If the answer to question 4 is 'WO", skip to section 8 It the answer to question 4 is "YES" list the affected wells individually with constituents) and concentration(s) exceeding standards in the space provided below: 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES— NO same constituents) t(s) in the same wells) in the last two years? if the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). N4W- 1: PH &5; Fe 0.38 MW-2: PH 5.0 MW-3: PH 6.26; Fe 25.4; Mn 544 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO If the answer is "YES", a groundwater quality problem may be occurring. CONTAcr rHE REGIORAL OFFICE IMMEDIA TEL Y FOR GUIDANCE. If the answer is "NO", monitoring wells maybe improperly located; contact the Regional Office. 7 is the permittee livioJementing previously approved actions required by the Division involving this NO groundwater quality problem? If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 Is "NO", contact the Regional Office within 90 days, an evaluation may be required to determine the Imoact the waste dispogal system -is hm �Jng at the review and complianc boundaries LurrogLnding this facility. E011ure to do so may sub ect the germittee to a Notice of Vialedo fines, aadl2r r�ena ties. 8 The person completing this portion (GW-59A) of the monitoring report should sign below and submit this form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form, I hereby acknowledge that the above Information was evaluated and the information submitted in this report (Compliance Report GW-59A) is true and complete to the best of my knowledge. Signature of Pormittee (or Authorized Agent) Date (; M, -54) A I ZM204'0 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: e DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES COMPLIANCE REPORT FORM a. INFORMAT1ONPROCESSING UNIT 1617MAIL SERVICE CENTER, RALEIGH,NC 7699-1617 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Gate, 5/3012028 Facility Marne: Rose Hill Plantation Development, LLC Non -Discharge UIC NPDES Other W00032016 Permit Name (if different): Facility Address: 3041 New Leicester Highway TYPE OF PERMITTED OPERATION BEING MONITORED Leicester NC 2874$ Count Buncombe y ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ 1Remediation: Contact Person: Bob Barr Telephone#: (828) 251-1900 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Fell # 1(MW A can GW-1 b) No. of wells to be sampled: 3 ❑ Water Source Heat Pump X Other: Surface Irrigation (from Permit) SAMPLING INFORMATION If WELL WELL 10 NUMBER (from Permit): Well # 1 Upgradient Date sample collected; 1112212022 FIELD ANALYSES: WAS Well Depth: 69 ft. Well Diameter: 2 in. pH 00400: 6.05 units Temp. 00010: 14.8 °C DRY at Depth to Water Level 82546: 37.85 ft. below measuring point Screened Interval: 49 ft.. to 69 ft. Spec. Cond. 00094 52.1 µMhos time of MeasuringPoint is 2.5 ft. above land surface Relative M.P. Elevation: ft. Odor o00�5: None sampling, check Volume of water pumped/bai[ed before sampling: gallons Appearance Clear here. Samples for metals were collected unfiltered: 0 YES ❑ NO and field acidified: 10 YES ❑ NO LABORATORY INFORMATION Date sample analyzed:12112r2022 Laboratory Name: Pace Analytical Certification No. 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N oo615 <0.040 mg/L Pb -Lead 01051 <5.0 ug/L Coliform: MF Fecal 31616 <1 11OOmL Nitrate (NO3) as N 00620 0.082 mg/L Zn - Zinc 01092 <10.0 mg/L Col iform: MF Total 31504 11OOmL Phosphorus: Total as P 00665 0.085 mg/L (Note: Use MPN method for highly turgid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): Dissolved Solids:Total 70300 55.0 mgiL Al F Aluminum or io5 m 1L pH (Lab) 00403 units Ba - Barium 01007 21.6 ug/L TOC o0680 <1.0 mgiL Ca - Calcium o0916 mg/L Chloride 00940 1.0 mglL Cd - Cadmium 01027 ug/L Arsenic 01002 <10.0 ugfL Chrornium: Total 01034 <5.0 ug1L Grease and Oils 00552 ri Cu -Copper 01042 <5.0 mgiL ORGANICS: (by GC, GCIMS, HPLC) Phenol 32730 ugfL Fe - iron 01045 380 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mgiL Hg - Mercury 71900 ug/L Lab Report Attached? 9Yes (1) ElNo (0) Specific Conductance o0095 µMhos K - Potassium 00937 mg/L VOC 7873 method # SM 6200E Total Ammonia aoslo <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrager, NH, as r,: Ammonia Ni}roam, Total) Mn - Manganese 01055 18.8 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ugfL method # ror Kemedlauon systems Unty (Attach Lab Reports): Influent Total VOCs: Robert P. Barr I Authorized Agent Permittee (or Authorized Agent) Name and Title - Please print or type ------ mg1L Effluent Total VOCs: Signature of mg1L VOC Removal% GW-59 Rev, 06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY . . c+ern mmm t ur vlrevremcn'tlt 4irJFiLi 1 T - jAv. ut- XYR.I�K ml:,souKcFs GROUNDWATER QUALITY MONITORING: . v INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date. 6t30/2028 Facility Name: Rose Hill Plantation Development, LLC Non -Discharge UIC Permit Name (if different): NPDES Other W00032016 Facility Address: 3041 New Leicester Highway TYPE OF PERMITTED OPERATION BEING MONITORED Leicester NC 28748 County Buncombe ❑ Lagoon ❑ Remediation: Infiltration Gallery Spray Field ❑ Remediation: Contact Person: Bob Barr Telephone#: (828) 251-1900 ® Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Well # 2(MW B on GW-1b) No. of wells to be sampled: 3 ❑ Water Source Heat Pump Q Other: Surface Irrigation .LL ID NUMBER (from Permit): Well # 2 downgradient Date sample collected: 11/22/2022 II Depth: 30 ft. Well Diameter: 2 in. 3th to Water Level 82546: 14,09 ft. below measuring point Screened Interval: 10 ft. to 30 ft. asuring Point is 2.5 ft. above land surface Relative M.P. Elevation: ft. ume of water pumped/bailed before sampling: gallons nples for metals were collected unfiltered: (K YES ❑ NO and field acidified. ❑■ YES ❑ NO FIELD ANALYSES: pH 00400: 5.0 units Spec. Cond. 00094: 20.3 Odor 00085: None Appearance Clear Date sample analyzed: 1211212022 Laboratory Name: Pace Analytical PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 1 Nitrite (NO2) as N 00615 <0.040 mg/L Pb -Lead o1o51 <5.0 Coliform: MF Fecal 31616 <1.0 /100mL Nitrate (NO3) as N 00620 0.37 mg/L Zn -Zinc 01092 <10.o Coliform: MF Total 31504 /10®mL Phosphorus_ Total as P 00665 <0.050 mg/L tNote Use VPN method for highly turbid samples) - Temp. oc01o: 13.7 aC µMhos Certification No. 40 ug/L mgfL Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): )issolved Solids:Total 70300 <25.0 mg/L Al - Aluminum o11o5 mgfL pH (Lab) 00403 units Ba - Barium 01007 26.1 ug1L TfOC 00680 <1.0 mgiL Ca - Calcium costs mgfL Chloride 00940 1.6 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 <10.0 ug/L Chromium: Total 01034 <5.0 ug/L Grease and (ails 00552 mg/L Cu -Copper 01042 <5.0 mgfL ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ugiL Fe - Iron 01045 48.2 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? X Yes (1) ❑ No (0) Specific Conductance 00495 µMhos K - Potassium 00937 mg/L VOC 7873 method # SM 6200B Total Ammonia ot1610 <0,10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia nitrogen NH, as N Ammonia Nitrogen, Total) Mn - Manganese c1D55 <10.0 g ugiL ,method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L For Remediation Systems Only (Attach Lab Reports): Influent Total VtOCs: Robert P. Barr / Authorized Agent Permittee (or Authorized Agent) Name and Title - Please print or type GW-59 Rev.06-07-2018 mgfL Effluent Total VOCs: method # mgfL VOC Removal% WAS DRY at time of sampling, check here: SUBMIT FORM nN YF-i I ntA1 PLPF:pa nNi u GROUNDWATER QUALITY MONITORING: • . DEPARTMENT DEPARTMENT OF ENVIRONMENTAL QUALITY - DIVE OF WATER RESOURCES COMPLIANCE REPORT FORM PROCESSING UNIT 1E17 MAIL SERVICE CENTER, RALEIG, N6 276913=1647 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date 6130Q028 Facility Name: Pose Hill Plantation Development, LLC Non -Discharge UIC Permit Name (if different): NPDES Other W00032016 Facility Address: 3041 New Leicester Highway 1TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon El Remediation: Infiltration Gallery Leicester NC 28748 County Buncombe El Spray Field D Remediation: Contact Person, Bob Barr Telephone#: (828) 251=1900 ® Notary Distributor ❑ Land Application of Sludge Well Location/Site Name: Well # 3 No. of wells to be sampled: 3 ❑ Water Source Neat Pump X Other: Surface Irrigation (cram Permit) _ SAMPLING INFORMATION WELL ID NUMBER (from Permit): Veil # 3 Date sample collected: 11/2212022 FIELD ANALYSES: If WELL WAS Well Depth: 14 ft. Well Diameter: 2 in. H 00400: 6.26 11.9 p units Temp. C DRY at Depth to Water Level 82546:4.87 ft. below measuringpoint p Screened Interval: 4 ft. to 14 Spec. Cond. 0oos4. 1Q4.3 f1Mllos time of Measuring Point is 0 ft. above land surface Relative M.P.0 .P. Elevation: _ft. ft. Odor o85: None sampling. Volume of water pumped/bailed before sampling: gallons Appearance Clear check here: Samples for metals were collected unfiltered: A YES ED NO and field acidified: ® YES NO LABORATORY INFORMATION Date sample analyzed: 12/12112022 Laboratory Name Pace Analytical Certification No. 40 PARAMETERS NOTE: values should reflect dissolved and colloidal concentrations. COD oasis mg/L Nitrite (NO2) as N Da515 <0.040 mg/L Pb - Lead o1c51 <5.0 ug/L Coliforml MF Fecal 31616 <1.0 f100mL Nitrate (NO3) as N 00620 <0.040 g/L Zn - Zinc 01092 <10.0 mg/L Gollform: MF Total 31504 1100ml- Phosphorus: Total as P co665 0-95 mglL (Note- Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 7o3oo 69.0 mg/L Al -Aluminum o11c5 mg/L pH (Lab) 00403 units Ba - Barium 01007 29.7 ug/L TOG oo68o <1.0 mg1L Ca - Calcium 00916 mg/L Chloride 0094o 2.7 mg/L Cd - Cadmium 01027 a lL 9 Arsenic 01002 <10.0 ug/L Chromium: Total 01034 <5-0 uglL Grease and Oils 00552 mg/L Cu -Copper 01042 <5.0 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 uglL Fe - Iron 01045 25400 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71000 ug/L Lab Report Attached? A Yes (1) L1 No (0) Specific Conductance oco95 ltMhos K - Potassium 00937 mg/L VOC 7873 method # 5M 6200B Total Ammonia o©6io <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nil .ragen; NH, as N. Ammonia Nitrogen, Total) Mn - Manganese ?doss 544 uglL method # TKN as N 00625 mg/L Ni - Nickel 01067 uglL method # FUI rse1r1ea1dE10F1 Oys[ems unry tAitacn LaD Keports): Influent Iota] VUGs: Robert P. Barr 1 Authorized Agent Permlttee (or Authorized Agent) ?Jame and Title - Please print or type mglL Effluent Total• - fplete, and that ttte labomciry analytical data was produced using ap ?pithy of fines and.€mp sonmeral for knowing vioWons. Signature of Permittee (or Authorized Agent) mg/L VOC Removal% (mate) GW-59 Rev.06-07-2018 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: ROSE HILL MW 11/22 Pace Project No.: 92638143 Sample: MW-1 Lab ID: 92638143001 Collected: 11/22/22 15:20 Received: 11/22/22 16:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 11/26/22 11:25 Collected By Mark 1 11/26/22 11:25 Swann Collected Date 11/22/22 1 11/26/22 11:25 Collected Time 1520 1 11/26/22 11:25 pH 6.05 Std. Units 1 11/26/22 11:25 Temperature 14.8 deg C 1 11/26/22 11:25 Static Water Level 37.85 feet 1 11/26/22 11:25 Specific Conductance 52.1 umhos/cm 1 11/26/22 11:25 Oxygen, Dissolved 4.49 mg/L 1 11/26/22 11:25 7782-44-7 Total Well Depth 69 feet 1 11/26/22 11:25 REDOX -24.8 mV 1 11/26/22 11:25 Turbidity 9.80 NTU 1 11/26/22 11:25 Odor None 1 11/26/22 11:25 Appearance Clear 1 11/26/22 11:25 200.8ATL ICPMS, NC Analytical Method: EPA200.8 Preparation Method: EPA200.8 Pace Analytical Services - Peachtree Corners, GA Arsenic ND ug/L 5.0 1 12/05/2212:47 12/08/2216:14 7440-38-2 Barium 21.6 ug/L 5.0 1 12/05/2212:47 12/08/2216:14 7440-39-3 Chromium ND ug/L 5.0 1 12/05/2212:47 12/08/2216:14 7440-47-3 Copper ND ug/L 5.0 1 12/05/2212:47 12/08/2216:14 7440-50-8 Iron 380 ug/L 40.0 1 12/05/2212:47 12/08/2216:14 7439-89-6 Lead ND ug/L 1.0 1 12/05/2212:47 12/08/2216:14 7439-92-1 Manganese 18.8 ug/L 10.0 1 12/05/2212:47 12/08/2216:14 7439-96-5 Zinc ND ug/L 10.0 1 12/05/2212:47 12/08/2216:14 7440-66-6 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11/28/22 22:30 71-43-2 Bromobenzene ND ug/L 0.50 1 11/28/22 22:30 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/28/22 22:30 74-97-5 Bromod ichloromethane ND ug/L 0.50 1 11/28/22 22:30 75-27-4 Bromoform ND ug/L 0.50 1 11/28/22 22:30 75-25-2 Bromomethane ND ug/L 5.0 1 11/28/22 22:30 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/28/22 22:30 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/28/22 22:30 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/28/22 22:30 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/28/22 22:30 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/28/22 22:30 108-90-7 Chloroethane ND ug/L 1.0 1 11/28/22 22:30 75-00-3 Chloroform ND ug/L 0.50 1 11/28/22 22:30 67-66-3 Chloromethane ND ug/L 1.0 1 11/28/22 22:30 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/28/22 22:30 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/28/22 22:30 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/28/22 22:30 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2022 01:46 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 37 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: ROSE HILL MW 11/22 Pace Project No.: 92638143 Sample: MW-1 Lab ID: 92638143001 Collected: 11/22/22 15:20 Received: 11/22/22 16:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Dibromochloromethane ND ug/L 0.50 1 11/28/22 22:30 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/28/22 22:30 106-93-4 Dibromomethane ND ug/L 0.50 1 11/28/22 22:30 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/28/22 22:30 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/28/22 22:30 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/28/22 22:30 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/28/22 22:30 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/28/22 22:30 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/28/22 22:30 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/28/22 22:30 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/28/22 22:30 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/28/22 22:30 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/28/22 22:30 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/28/22 22:30 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/28/22 22:30 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/28/22 22:30 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/28/22 22:30 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/28/22 22:30 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/28/22 22:30 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/28/22 22:30 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/28/22 22:30 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/28/22 22:30 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/28/22 22:30 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/28/22 22:30 1634-04-4 Naphthalene ND ug/L 2.0 1 11/28/22 22:30 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/28/22 22:30 103-65-1 Styrene ND ug/L 0.50 1 11/28/22 22:30 100-42-5 1, 1, 1,2-Tetrachloroethane ND ug/L 0.50 1 11/28/22 22:30 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/28/22 22:30 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/28/22 22:30 127-18-4 Toluene ND ug/L 0.50 1 11/28/22 22:30 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/28/22 22:30 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/28/22 22:30 120-82-1 1, 1, 1 -Trichloroethane ND ug/L 0.50 1 11/28/22 22:30 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/28/22 22:30 79-00-5 Trichloroethene ND ug/L 0.50 1 11/28/22 22:30 79-01-6 Trich lo rofluoro methane ND ug/L 1.0 1 11/28/22 22:30 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/28/22 22:30 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/28/22 22:30 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/28/22 22:30 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/28/22 22:30 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/28/22 22:30 179601-23-1 o-Xylene ND ug/L 0.50 1 11/28/22 22:30 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 92 % 70-130 1 11/28/22 22:30 17060-07-0 4-Bromofluorobenzene (S) 96 % 70-130 1 11/28/22 22:30 460-00-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2022 01:46 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 37 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: ROSE HILL MW 11/22 Pace Project No.: 92638143 Sample: MW-1 Lab ID: 92638143001 Collected: 11/22/22 15:20 Received: 11/22/22 16:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Surrogates Toluene-d8 (S) 99 % 70-130 1 11/28/22 22:30 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services - Asheville Total Dissolved Solids 55.0 mg/L 25.0 1 11/27/22 11:10 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 11/22/22 16:56 11/23/22 15:05 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Ammonia ND mg/L 0.10 1 12/02/22 12:41 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Nitrate 0.082 mg/L 0.040 1 11/22/22 23:43 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 1 11/22/22 23:43 14797-65-0 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services - Asheville Phosphorus 0.085 mg/L 0.050 1 12/05/22 20:27 12/06/22 16:00 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services - Asheville Chloride 1.0 mg/L 1.0 1 12/02/2218:48 16887-00-6 5310E TOC Analytical Method: SM 531OB-2014 Pace Analytical Services - Asheville Total Organic Carbon ND mg/L 1.0 1 11/29/22 07:15 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2022 01:46 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 37 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: ROSE HILL MW 11/22 Pace Project No.: 92638143 Sample: MW-2 Lab ID: 92638143002 Collected: 11/22/22 15:55 Received: 11/22/22 16:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 11/26/22 11:32 Collected By Sarah 1 11/26/22 11:32 Kline Collected Date 11/22/22 1 11/26/22 11:32 Collected Time 1555 1 11/26/22 11:32 pH 5.0 Std. Units 1 11/26/22 11:32 Temperature 13.7 deg C 1 11/26/22 11:32 Static Water Level 14.09 feet 1 11/26/22 11:32 Specific Conductance 20.3 umhos/cm 1 11/26/22 11:32 Oxygen, Dissolved 6.0 mg/L 1 11/26/22 11:32 7782-44-7 Total Well Depth 30 feet 1 11/26/22 11:32 REDOX 224.0 mV 1 11/26/22 11:32 Turbidity 3.76 NTU 1 11/26/22 11:32 Odor None 1 11/26/22 11:32 Appearance Clear 1 11/26/22 11:32 200.8ATL ICPMS, NC Analytical Method: EPA200.8 Preparation Method: EPA200.8 Pace Analytical Services - Peachtree Corners, GA Arsenic ND ug/L 5.0 1 12/05/2212:47 12/08/2216:32 7440-38-2 Barium 26.1 ug/L 5.0 1 12/05/2212:47 12/08/2216:32 7440-39-3 Chromium ND ug/L 5.0 1 12/05/2212:47 12/08/2216:32 7440-47-3 Copper ND ug/L 5.0 1 12/05/2212:47 12/08/2216:32 7440-50-8 Iron 48.2 ug/L 40.0 1 12/05/2212:47 12/08/2216:32 7439-89-6 Lead ND ug/L 1.0 1 12/05/2212:47 12/08/2216:32 7439-92-1 Manganese ND ug/L 10.0 1 12/05/2212:47 12/08/2216:32 7439-96-5 Zinc ND ug/L 10.0 1 12/05/2212:47 12/08/2216:32 7440-66-6 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11/28/22 22:48 71-43-2 Bromobenzene ND ug/L 0.50 1 11/28/22 22:48 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/28/22 22:48 74-97-5 Bromod ichloromethane ND ug/L 0.50 1 11/28/22 22:48 75-27-4 Bromoform ND ug/L 0.50 1 11/28/22 22:48 75-25-2 Bromomethane ND ug/L 5.0 1 11/28/22 22:48 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/28/22 22:48 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/28/22 22:48 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/28/22 22:48 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/28/22 22:48 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/28/22 22:48 108-90-7 Chloroethane ND ug/L 1.0 1 11/28/22 22:48 75-00-3 M1 Chloroform ND ug/L 0.50 1 11/28/22 22:48 67-66-3 Chloromethane ND ug/L 1.0 1 11/28/22 22:48 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/28/22 22:48 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/28/22 22:48 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/28/22 22:48 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2022 01:46 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 37 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: ROSE HILL MW 11/22 Pace Project No.: 92638143 Sample: MW-2 Lab ID: 92638143002 Collected: 11/22/22 15:55 Received: 11/22/22 16:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Dibromochloromethane ND ug/L 0.50 1 11/28/22 22:48 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/28/22 22:48 106-93-4 Dibromomethane ND ug/L 0.50 1 11/28/22 22:48 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/28/22 22:48 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/28/22 22:48 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/28/22 22:48 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/28/22 22:48 75-71-8 M1 1,1-Dichloroethane ND ug/L 0.50 1 11/28/22 22:48 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/28/22 22:48 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/28/22 22:48 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/28/22 22:48 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/28/22 22:48 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/28/22 22:48 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/28/22 22:48 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/28/22 22:48 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/28/22 22:48 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/28/22 22:48 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/28/22 22:48 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/28/22 22:48 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/28/22 22:48 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/28/22 22:48 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/28/22 22:48 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/28/22 22:48 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/28/22 22:48 1634-04-4 Naphthalene ND ug/L 2.0 1 11/28/22 22:48 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/28/22 22:48 103-65-1 Styrene ND ug/L 0.50 1 11/28/22 22:48 100-42-5 1, 1, 1,2-Tetrachloroethane ND ug/L 0.50 1 11/28/22 22:48 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/28/22 22:48 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/28/22 22:48 127-18-4 Toluene ND ug/L 0.50 1 11/28/22 22:48 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/28/22 22:48 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/28/22 22:48 120-82-1 1, 1, 1 -Trichloroethane ND ug/L 0.50 1 11/28/22 22:48 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/28/22 22:48 79-00-5 Trichloroethene ND ug/L 0.50 1 11/28/22 22:48 79-01-6 Trich lo rofluoro methane ND ug/L 1.0 1 11/28/22 22:48 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/28/22 22:48 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/28/22 22:48 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/28/22 22:48 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/28/22 22:48 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/28/22 22:48 179601-23-1 o-Xylene ND ug/L 0.50 1 11/28/22 22:48 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 92 % 70-130 1 11/28/22 22:48 17060-07-0 4-Bromofluorobenzene (S) 97 % 70-130 1 11/28/22 22:48 460-00-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2022 01:46 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 37 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: ROSE HILL MW 11/22 Pace Project No.: 92638143 Sample: MW-2 Lab ID: 92638143002 Collected: 11/22/22 15:55 Received: 11/22/22 16:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Surrogates Toluene-d8 (S) 97 % 70-130 1 11/28/22 22:48 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services - Asheville Total Dissolved Solids ND mg/L 25.0 1 11/27/22 11:10 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 11/22/22 16:56 11/23/22 15:05 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Ammonia ND mg/L 0.10 1 12/02/22 12:42 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Nitrate 0.37 mg/L 0.040 1 11/23/22 23:59 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 1 11/23/22 23:59 14797-65-0 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services - Asheville Phosphorus ND mg/L 0.050 1 12/05/22 20:27 12/06/22 16:04 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services - Asheville Chloride 1.6 mg/L 1.0 1 12/02/2218:49 16887-00-6 5310E TOC Analytical Method: SM 531OB-2014 Pace Analytical Services - Asheville Total Organic Carbon ND mg/L 1.0 1 11/29/22 07:31 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2022 01:46 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 37 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: ROSE HILL MW 11/22 Pace Project No.: 92638143 Sample: MW-3113 Lab ID: 92638143003 Collected: 11/22/22 12:45 Received: 11/22/22 16:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 11/26/22 11:36 Collected By Mark 1 11/26/22 11:36 Swann Collected Date 11/22/22 1 11/26/22 11:36 Collected Time 1245 1 11/26/22 11:36 pH 6.29 Std. Units 1 11/26/22 11:36 Temperature 11.9 deg C 1 11/26/22 11:36 Static Water Level 4.87 feet 1 11/26/22 11:36 Specific Conductance 104.3 umhos/cm 1 11/26/22 11:36 Oxygen, Dissolved 0.61 mg/L 1 11/26/22 11:36 7782-44-7 Total Well Depth 14 feet 1 11/26/22 11:36 REDOX -138.0 mV 1 11/26/22 11:36 Turbidity 50.34 NTU 1 11/26/22 11:36 Odor None 1 11/26/22 11:36 Appearance Clear 1 11/26/22 11:36 200.8ATL ICPMS, NC Analytical Method: EPA200.8 Preparation Method: EPA200.8 Pace Analytical Services - Peachtree Corners, GA Arsenic ND ug/L 5.0 1 12/05/22 12:47 12/08/2217:17 7440-38-2 Barium 29.7 ug/L 5.0 1 12/05/22 12:47 12/08/2217:17 7440-39-3 Chromium ND ug/L 5.0 1 12/05/22 12:47 12/08/2217:17 7440-47-3 Copper ND ug/L 5.0 1 12/05/22 12:47 12/08/2217:17 7440-50-8 Iron 25400 ug/L 400 10 12/05/22 12:47 12/10/22 03:36 7439-89-6 Lead ND ug/L 1.0 1 12/05/22 12:47 12/08/2217:17 7439-92-1 Manganese 544 ug/L 100 10 12/05/22 12:47 12/10/22 03:36 7439-96-5 Zinc ND ug/L 10.0 1 12/05/22 12:47 12/08/2217:17 7440-66-6 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11/27/2217:33 71-43-2 Bromobenzene ND ug/L 0.50 1 11/27/2217:33 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/27/2217:33 74-97-5 Bromod ichloromethane ND ug/L 0.50 1 11/27/2217:33 75-27-4 Bromoform ND ug/L 0.50 1 11/27/2217:33 75-25-2 Bromomethane ND ug/L 5.0 1 11/27/2217:33 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/27/2217:33 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/27/2217:33 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/27/2217:33 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/27/22 17:33 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/27/2217:33 108-90-7 Chloroethane ND ug/L 1.0 1 11/27/2217:33 75-00-3 Chloroform ND ug/L 0.50 1 11/27/2217:33 67-66-3 Chloromethane ND ug/L 1.0 1 11/27/2217:33 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/27/2217:33 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/27/2217:33 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/27/2217:33 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2022 01:46 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 37 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: ROSE HILL MW 11/22 Pace Project No.: 92638143 Sample: MW-3B Lab ID: 92638143003 Collected: 11/22/22 12:45 Received: 11/22/22 16:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Dibromochloromethane ND ug/L 0.50 1 11/27/22 17:33 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/27/22 17:33 106-93-4 Dibromomethane ND ug/L 0.50 1 11/27/22 17:33 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/27/22 17:33 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/27/22 17:33 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/27/22 17:33 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/27/22 17:33 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/27/22 17:33 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/27/22 17:33 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/27/22 17:33 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/27/22 17:33 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/27/22 17:33 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/27/22 17:33 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/27/22 17:33 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/27/22 17:33 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/27/22 17:33 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/27/22 17:33 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/27/22 17:33 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/27/22 17:33 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/27/22 17:33 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/27/22 17:33 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/27/22 17:33 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/27/22 17:33 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/27/22 17:33 1634-04-4 Naphthalene ND ug/L 2.0 1 11/27/22 17:33 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/27/22 17:33 103-65-1 Styrene ND ug/L 0.50 1 11/27/22 17:33 100-42-5 1, 1, 1,2-Tetrachloroethane ND ug/L 0.50 1 11/27/22 17:33 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/27/22 17:33 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/27/22 17:33 127-18-4 Toluene ND ug/L 0.50 1 11/27/22 17:33 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/27/22 17:33 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/27/22 17:33 120-82-1 1, 1, 1 -Trichloroethane ND ug/L 0.50 1 11/27/22 17:33 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/27/22 17:33 79-00-5 Trichloroethene ND ug/L 0.50 1 11/27/22 17:33 79-01-6 Trich lo rofluoro methane ND ug/L 1.0 1 11/27/22 17:33 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/27/22 17:33 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/27/22 17:33 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/27/22 17:33 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/27/22 17:33 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/27/22 17:33 179601-23-1 o-Xylene ND ug/L 0.50 1 11/27/22 17:33 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 96 % 70-130 1 11/27/22 17:33 17060-07-0 4-Bromofluorobenzene (S) 98 % 70-130 1 11/27/22 17:33 460-00-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2022 01:46 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 37 aceAnalytical www.pacellabsxom Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: ROSE HILL MW 11/22 Pace Project No.: 92638143 Sample: MW-3B Lab ID: 92638143003 Collected: 11/22/22 12:45 Received: 11/22/22 16:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200E MSV Surrogates Toluene-d8 (S) 2540C Total Dissolved Solids Total Dissolved Solids MBIO 9222D Fecal Coliform AVL Fecal Coliforms 350.1 Ammonia Nitrogen, Ammonia 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate Nitrogen, Nitrite 365.1 Phosphorus, Total Phosphorus 4500 Chloride Chloride 5310E TOC Total Organic Carbon Date: 12/12/2022 01:46 PM Analytical Method: SM 6200B Pace Analytical Services - Charlotte 98 % 70-130 1 11/27/2217:33 2037-26-5 Analytical Method: SM 254OC-2015 Pace Analytical Services - Asheville 69.0 mg/L 25.0 1 11/27/2211:10 Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Asheville ND CFU/100 mL 1.0 1 11/22/22 16:56 11/23/22 15:05 Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville ND mg/L 0.10 1 12/02/2212:43 7664-41-7 Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville ND mg/L 0.040 1 11/22/22 23:38 14797-55-8 ND mg/L 0.040 1 11/22/22 23:38 14797-65-0 Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services - Asheville 0.95 mg/L 0.050 1 12/05/22 20:27 12/06/22 16:05 7723-14-0 Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services - Asheville 2.7 mg/L 1.0 1 12/02/2218:51 16887-00-6 Analytical Method: SM 531OB-2014 Pace Analytical Services - Asheville ND mg/L 1.0 1 11/29/22 08:20 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 37 I eAnalytical www.pacallabsxom Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALIFIERS Project: ROSE HILL MW 11/22 Pace Project No.: 92638143 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2022 01:46 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 37 1- 14- w jw I— i I mvi to ;j cc 0 M m :u M p .0 u) co ro > 0 3 9 0 C r I -j m rq cr 0 raR -4 a a v� z tl MATRIX CODE {see valid codes Io fell) ;t SAMPLE TYPE (G=GRAB CLLCWAP) cc m 07 m 0 z z > m -4 in m Z. En 1z 13 0 r m SAMPLE TEMP AT COLLECTION m 9 OF CONTAINERs 75"T m V -u 0 k.,1 Unprosewd IN Mc 1-12804 6o z HNO3 HU (D :2 1NaOH Au < Na2S203 m Melhanol o. other ti Analyses Test 'Y/N x ix Ter C car x x x Chloride Q x x x Fecal Cogi Ammonia I Total Phosphorus x x x Nitrate or Nitrite x x x TDS by 2540C x x x Malals 200,7 VOC 62(d0 -T7 TEMP in C in x Residual Chlorine (YIN) Received on lce z Q lym) o CustodV Scaled Cooler (YIN) 0 LN Samples Inlixt (Y1mN)O Dr CD ca > ll 10 m 1 5 0 C T-1 0 > iii > (D U) a 0 0 r- (D 3 Page 36 of 37 I eAnalytical wurmpacallaba.caim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 December 12, 2022 Kimber Reese RPB Systems Inc. P.O. Box 1325 Asheville, NC 28802 RE: Project: ROSE HILL MW 11/22 Pace Project No.: 92638143 Dear Kimber Reese: Enclosed are the analytical results for sample(s) received by the laboratory on November 22, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte • Pace Analytical Services - Peachtree Corners, GA If you have any questions concerning this report, please feel free to contact me. Sincerely, Taylor Dyson taylor.dyson@pacelabs.com (828)254-7176 Project Manager Enclosures cc: Mr. Robert Barr, RPB Systems Inc. Ms. Liz Barr, RPB Systems Inc. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 37