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WQ0028693_Monitoring - 11-2022_20221229
Monitoring Report Submittal Permit Number #* WQ0028693 Name of Facility:* Mountain Top Golf & Lake Club Month: * November Year: * 2022 Report Information Type* Upload Document* GW-59 Mountain Top (WQ0028693) 2.15MB GW-59 with lab results 12-29- 22.pdf PDF Only Please upload one PDF containing all applicable monitoring reports (i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59). Confirmation Email Address:* kreese@rpbsystems.com Name of Submitter: * Kimber Reese Signature: Date of submittal: 12/29/2022 This will be filled in automatically Initial Review Reviewer: Gerald, Wanda Is the project number correct?* WQ0028693 Is the monitoring report accepted?* Yes NO Regional Office* Asheville Reviewer: _anonymous Review Date: 1/18/2023 CA,V-51),N WQ0028693 (S'ut,�,Ivfir 02P�e eue,A olremilfn in"', petiodl widl 0f, -59jm als) I Enter date monitoring results were due, (12)31)2022 ) Will this monitoring report (GW-59 and GW-59A) YES NO be submitted after the established due date? X 2 Was any required information missing on the GW-59 report forms? YES IF the answer to question I or2is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information, 3 Are any of the monitor wells in need of repair or maintenance(dawaged casing, unlocked or missing cap, missing Identification plate, area overgrown, etc.)? 1j'1he auviveris 'Tey", contact the RegioiicilOfficefot,gteicicitice. YE5 NO 4 Are any monitored constituents equal to or above the established standards? YES — --MO If the answer to question 4 is "NO", skip to section 8, If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration (sj exceeding -standards in the space provided below., 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? If the answer to question 5 is "NO", skip to section B. If the answer to question Sis "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). MW-01R: PH 5.57 MW-1 pF1 5,96 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO If the answer is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL OFFICE IMMEDIA TEL Y FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this —'VE—S NO groundwater quality problem? ifthe answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is 'WO", contact (he Rgglonal Office within 90 d a evaluation may b am a Li reguired to determine the imgact the waste gisoogat system is having at the reXJ:evv and, Hance boundaries surrounding this facility, Failure to do so a?av subbed the ggrmittee to a Nad of Violation, lines, and/or penalties. 8 The person completing this portion (GW-59A) of the monitoring report should sign below and submit this form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form, I hereby acknowledge that the above Information was evaluated and the Information submitted in this report (Compliance Report GW-59A) Is true and complete to the best of my knowledge. Signature of Perrmittee (or Authorized Agent) Date (;W-59 k 12/8/2003 9L0Z-L0-90'na6 69-ME) lefl) {Iua6V^ pazuogjnyjo) !!pwJed jo aJneu6!g adfLjo Tuud asea i Id DR! 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Units 1 11/26/22 11:42 Temperature 14.5 deg C 1 11/26/22 11:42 Static Water Level 12.7 feet 1 11/26/22 11:42 Specific Conductance 87.9 umhos/cm 1 11/26/22 11:42 Oxygen, Dissolved 7.90 mg/L 1 11/26/22 11:42 7782-44-7 Total Well Depth 25.6 feet 1 11/26/22 11:42 REDOX -140.1 mV 1 11/26/22 11:42 Turbidity 319.5 NTU 1 11/26/22 11:42 Odor None 1 11/26/22 11:42 Appearance Cloudy 1 11/26/22 11:42 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11/21/22 19:54 71-43-2 Bromobenzene ND ug/L 0.50 1 11/21/22 19:54 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/21/22 19:54 74-97-5 Bromod ichloromethane ND ug/L 0.50 1 11/21/22 19:54 75-27-4 Bromoform ND ug/L 0.50 1 11/21/22 19:54 75-25-2 Bromomethane ND ug/L 5.0 1 11/21/22 19:54 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/21/22 19:54 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/21/22 19:54 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/21/22 19:54 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/21/22 19:54 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/21/22 19:54 108-90-7 Chloroethane ND ug/L 1.0 1 11/21/22 19:54 75-00-3 Chloroform ND ug/L 0.50 1 11/21/22 19:54 67-66-3 Chloromethane ND ug/L 1.0 1 11/21/22 19:54 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/21/22 19:54 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/21/22 19:54 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/21/22 19:54 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/21/22 19:54 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/21/22 19:54 106-93-4 Dibromomethane ND ug/L 0.50 1 11/21/22 19:54 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/21/22 19:54 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/21/22 19:54 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/21/22 19:54 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/21/22 19:54 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/21/22 19:54 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/21/22 19:54 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/21/22 19:54 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/21/22 19:54 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/05/2022 05:51 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 30 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Mtn Top MW 11/17 Pace Project No.: 92637438 Sample: MW-01R Lab ID: 92637438001 Collected: 11/17/22 13:30 Received: 11/17/22 16:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte trans-1,2-Dichloroethene ND ug/L 0.50 1 11/21/22 19:54 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/21/22 19:54 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/21/22 19:54 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/21/22 19:54 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/21/22 19:54 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/21/22 19:54 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/21/22 19:54 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/21/22 19:54 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/21/22 19:54 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/21/22 19:54 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/21/22 19:54 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/21/22 19:54 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/21/22 19:54 1634-04-4 Naphthalene ND ug/L 2.0 1 11/21/22 19:54 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/21/22 19:54 103-65-1 Styrene ND ug/L 0.50 1 11/21/22 19:54 100-42-5 1, 1, 1,2-Tetrachloroethane ND ug/L 0.50 1 11/21/22 19:54 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/21/22 19:54 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/21/22 19:54 127-18-4 Toluene ND ug/L 0.50 1 11/21/22 19:54 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/21/22 19:54 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/21/22 19:54 120-82-1 1, 1, 1 -Trichloroethane ND ug/L 0.50 1 11/21/22 19:54 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/21/22 19:54 79-00-5 Trichloroethene ND ug/L 0.50 1 11/21/22 19:54 79-01-6 Trich lo rofluoro methane ND ug/L 1.0 1 11/21/22 19:54 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/21/22 19:54 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/21/22 19:54 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/21/22 19:54 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/21/22 19:54 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/21/22 19:54 179601-23-1 o-Xylene ND ug/L 0.50 1 11/21/22 19:54 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 11/21/22 19:54 17060-07-0 4-Bromofluorobenzene (S) 96 % 70-130 1 11/21/22 19:54 460-00-4 Toluene-d8 (S) 100 % 70-130 1 11/21/22 19:54 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services - Asheville Total Dissolved Solids 53.0 mg/L 25.0 1 11/21/22 11:13 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Asheville Fecal Coliforms ND CFU/100 mL 2.0 2 11/17/22 16:57 11/18/22 15:38 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/05/2022 05:51 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 30 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Mtn Top MW 11/17 Pace Project No.: 92637438 Sample: MW-01R Lab ID: 92637438001 Collected: 11/17/22 13:30 Received: 11/17/22 16:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Ammonia ND mg/L 0.10 1 11/30/22 13:48 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Nitrate 0.11 mg/L 0.040 1 11/18/22 01:53 14797-55-8 Nitrogen, Nitrite 0.065 mg/L 0.040 1 11/18/22 01:53 14797-65-0 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services - Asheville Phosphorus 0.69 mg/L 0.050 1 11/29/22 21:48 11/30/22 17:37 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services - Asheville Chloride 18.5 mg/L 1.0 1 11/17/22 22:54 16887-00-6 5310E TOC Analytical Method: SM 531OB-2014 Pace Analytical Services - Asheville Total Organic Carbon 2.7 mg/L 1.0 1 11/22/22 02:05 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/05/2022 05:51 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 30 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Mtn Top MW 11/17 Pace Project No.: 92637438 Sample: MW-2 Lab ID: 92637438002 Collected: 11/17/22 13:00 Received: 11/17/22 16:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 11/26/22 11:53 Collected By Mark 1 11/26/22 11:53 Swann Collected Date 11/17/22 1 11/26/22 11:53 Collected Time 1300 1 11/26/22 11:53 pH 5.96 Std. Units 1 11/26/22 11:53 Temperature 13.5 deg C 1 11/26/22 11:53 Static Water Level 12.9 feet 1 11/26/22 11:53 Specific Conductance 142.2 umhos/cm 1 11/26/22 11:53 Oxygen, Dissolved 9.50 mg/L 1 11/26/22 11:53 7782-44-7 Total Well Depth 33.73 feet 1 11/26/22 11:53 REDOX -146.0 mV 1 11/26/22 11:53 Turbidity 0.45 NTU 1 11/26/22 11:53 Odor None 1 11/26/22 11:53 Appearance Clear 1 11/26/22 11:53 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11/21/22 20:12 71-43-2 Bromobenzene ND ug/L 0.50 1 11/21/22 20:12 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/21/22 20:12 74-97-5 Bromod ichloromethane ND ug/L 0.50 1 11/21/22 20:12 75-27-4 Bromoform ND ug/L 0.50 1 11/21/22 20:12 75-25-2 Bromomethane ND ug/L 5.0 1 11/21/22 20:12 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/21/22 20:12 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/21/22 20:12 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/21/22 20:12 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/21/22 20:12 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/21/22 20:12 108-90-7 Chloroethane ND ug/L 1.0 1 11/21/22 20:12 75-00-3 Chloroform ND ug/L 0.50 1 11/21/22 20:12 67-66-3 Chloromethane ND ug/L 1.0 1 11/21/22 20:12 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/21/22 20:12 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/21/22 20:12 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/21/22 20:12 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/21/22 20:12 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/21/22 20:12 106-93-4 Dibromomethane ND ug/L 0.50 1 11/21/22 20:12 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/21/22 20:12 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/21/22 20:12 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/21/22 20:12 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/21/22 20:12 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/21/22 20:12 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/21/22 20:12 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/21/22 20:12 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/21/22 20:12 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/05/2022 05:51 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 30 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Mtn Top MW 11/17 Pace Project No.: 92637438 Sample: MW-2 Lab ID: 92637438002 Collected: 11/17/22 13:00 Received: 11/17/22 16:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte trans-1,2-Dichloroethene ND ug/L 0.50 1 11/21/22 20:12 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/21/22 20:12 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/21/22 20:12 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/21/22 20:12 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/21/22 20:12 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/21/22 20:12 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/21/22 20:12 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/21/22 20:12 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/21/22 20:12 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/21/22 20:12 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/21/22 20:12 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/21/22 20:12 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/21/22 20:12 1634-04-4 Naphthalene ND ug/L 2.0 1 11/21/22 20:12 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/21/22 20:12 103-65-1 Styrene ND ug/L 0.50 1 11/21/22 20:12 100-42-5 1, 1, 1,2-Tetrachloroethane ND ug/L 0.50 1 11/21/22 20:12 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/21/22 20:12 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/21/22 20:12 127-18-4 Toluene ND ug/L 0.50 1 11/21/22 20:12 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/21/22 20:12 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/21/22 20:12 120-82-1 1, 1, 1 -Trichloroethane ND ug/L 0.50 1 11/21/22 20:12 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/21/22 20:12 79-00-5 Trichloroethene ND ug/L 0.50 1 11/21/22 20:12 79-01-6 Trich lo rofluoro methane ND ug/L 1.0 1 11/21/22 20:12 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/21/22 20:12 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/21/22 20:12 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/21/22 20:12 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/21/22 20:12 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/21/22 20:12 179601-23-1 o-Xylene ND ug/L 0.50 1 11/21/22 20:12 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 11/21/22 20:12 17060-07-0 4-Bromofluorobenzene (S) 99 % 70-130 1 11/21/22 20:12 460-00-4 Toluene-d8 (S) 100 % 70-130 1 11/21/22 20:12 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services - Asheville Total Dissolved Solids 95.0 mg/L 25.0 1 11/21/22 11:13 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 11/17/22 16:57 11/18/22 15:38 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/05/2022 05:51 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 30 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Mtn Top MW 11/17 Pace Project No.: 92637438 Sample: MW-2 Lab ID: 92637438002 Collected: 11/17/22 13:00 Received: 11/17/22 16:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Ammonia ND mg/L 0.10 1 11/30/22 13:50 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Nitrate 1.5 mg/L 0.040 1 11/18/22 02:07 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 1 11/18/22 02:07 14797-65-0 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services - Asheville Phosphorus ND mg/L 0.050 1 11/29/22 21:48 11/30/22 17:37 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services - Asheville Chloride 5.5 mg/L 1.0 1 11/17/22 22:47 16887-00-6 5310E TOC Analytical Method: SM 531OB-2014 Pace Analytical Services - Asheville Total Organic Carbon ND mg/L 1.0 1 11/22/22 02:23 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/05/2022 05:51 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 30 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Mtn Top MW 11/17 Pace Project No.: 92637438 Sample: MW-3 Lab ID: 92637438003 Collected: 11/17/22 12:35 Received: 11/17/22 16:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 11/26/22 11:53 Collected By Mark 1 11/26/22 11:53 Swann Collected Date 11/17/22 1 11/26/22 11:53 Collected Time 1235 1 11/26/22 11:53 pH 6.55 Std. Units 1 11/26/22 11:53 Temperature 3.3 deg C 1 11/26/22 11:53 Static Water Level 15.63 feet 1 11/26/22 11:53 Specific Conductance 98.7 umhos/cm 1 11/26/22 11:53 Oxygen, Dissolved 6.42 mg/L 1 11/26/22 11:53 7782-44-7 Total Well Depth 16 feet 1 11/26/22 11:53 REDOX -184.9 mV 1 11/26/22 11:53 Turbidity 5.56 NTU 1 11/26/22 11:53 Odor None 1 11/26/22 11:53 Appearance Clear 1 11/26/22 11:53 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11/21/22 20:30 71-43-2 Bromobenzene ND ug/L 0.50 1 11/21/22 20:30 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/21/22 20:30 74-97-5 Bromod ichloromethane ND ug/L 0.50 1 11/21/22 20:30 75-27-4 Bromoform ND ug/L 0.50 1 11/21/22 20:30 75-25-2 Bromomethane ND ug/L 5.0 1 11/21/22 20:30 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/21/22 20:30 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/21/22 20:30 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/21/22 20:30 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/21/22 20:30 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/21/22 20:30 108-90-7 Chloroethane ND ug/L 1.0 1 11/21/22 20:30 75-00-3 Chloroform ND ug/L 0.50 1 11/21/22 20:30 67-66-3 Chloromethane ND ug/L 1.0 1 11/21/22 20:30 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/21/22 20:30 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/21/22 20:30 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/21/22 20:30 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/21/22 20:30 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/21/22 20:30 106-93-4 Dibromomethane ND ug/L 0.50 1 11/21/22 20:30 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/21/22 20:30 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/21/22 20:30 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/21/22 20:30 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/21/22 20:30 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/21/22 20:30 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/21/22 20:30 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/21/22 20:30 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/21/22 20:30 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/05/2022 05:51 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 30 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Mtn Top MW 11/17 Pace Project No.: 92637438 Sample: MW-3 Lab ID: 92637438003 Collected: 11/17/22 12:35 Received: 11/17/22 16:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte trans-1,2-Dichloroethene ND ug/L 0.50 1 11/21/22 20:30 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/21/22 20:30 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/21/22 20:30 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/21/22 20:30 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/21/22 20:30 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/21/22 20:30 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/21/22 20:30 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/21/22 20:30 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/21/22 20:30 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/21/22 20:30 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/21/22 20:30 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/21/22 20:30 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/21/22 20:30 1634-04-4 Naphthalene ND ug/L 2.0 1 11/21/22 20:30 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/21/22 20:30 103-65-1 Styrene ND ug/L 0.50 1 11/21/22 20:30 100-42-5 1, 1, 1,2-Tetrachloroethane ND ug/L 0.50 1 11/21/22 20:30 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/21/22 20:30 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/21/22 20:30 127-18-4 Toluene ND ug/L 0.50 1 11/21/22 20:30 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/21/22 20:30 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/21/22 20:30 120-82-1 1, 1, 1 -Trichloroethane ND ug/L 0.50 1 11/21/22 20:30 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/21/22 20:30 79-00-5 Trichloroethene ND ug/L 0.50 1 11/21/22 20:30 79-01-6 Trich lo rofluoro methane ND ug/L 1.0 1 11/21/22 20:30 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/21/22 20:30 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/21/22 20:30 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/21/22 20:30 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/21/22 20:30 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/21/22 20:30 179601-23-1 o-Xylene ND ug/L 0.50 1 11/21/22 20:30 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 95 % 70-130 1 11/21/22 20:30 17060-07-0 4-Bromofluorobenzene (S) 98 % 70-130 1 11/21/22 20:30 460-00-4 Toluene-d8 (S) 102 % 70-130 1 11/21/22 20:30 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services - Asheville Total Dissolved Solids 62.0 mg/L 25.0 1 11/21/22 11:13 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Asheville Fecal Coliforms ND CFU/100 mL 2.0 2 11/17/22 16:57 11/18/22 15:38 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/05/2022 05:51 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 30 aceAnalytical www.pacallabsxom Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Mtn Top MW 11/17 Pace Project No.: 92637438 Sample: MW-3 Lab ID: 92637438003 Collected: 11/17/22 12:35 Received: 11/17/22 16:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Ammonia ND mg/L 0.10 1 11/30/22 13:51 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Nitrate 0.46 mg/L 0.040 1 11/18/22 02:05 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 1 11/18/22 02:05 14797-65-0 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services - Asheville Phosphorus ND mg/L 0.050 1 11/29/22 21:48 11/30/22 17:38 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services - Asheville Chloride 2.8 mg/L 1.0 1 11/17/22 22:48 16887-00-6 5310E TOC Analytical Method: SM 531OB-2014 Pace Analytical Services - Asheville Total Organic Carbon ND mg/L 1.0 1 11/22/22 02:43 7440-44-0 Date: 12/05/2022 05:51 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 30 I eAnalytical www.pacallabsxom Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALIFIERS Project: Mtn Top MW 11/17 Pace Project No.: 92637438 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/05/2022 05:51 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 30 CHAIN-OFCUSTODY I Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Submitting a sample via this chain of custody constitutes acknoMedgment and acceptance of the Pace Terms and Conditions found at hftps://info.pacelabs-com/hubfs/pas-standard-terrns.pdf. aeCu0n M Section C Required Client Information: Required Project Information: Invoice Information: Page I Of Company RPB Systems Inc. Report TO: Robert Barr Atiention: — Address, P.O Box 1325 Copy To Company Name, Asheville, NC 2M2 Address: EMulatpry AgenU Email: rbarr@rpbsystems.com Purchase Order# Face Ouote Phone: (828)251-1900 Fax Project Name. Min Top MW Pace Project Manager taylor.dyscn@apacelabs.com, State I Location Requested Due Date -Project #: Pace Profile M 2315 NC Requested Analysis Filtered fyIN) E7 Z z MATRIX CODE 0 3 COLLECTED z Preservatives Dmhnp Nate[ OW VV t, WT Li pr� .V. P 5.415.kd SL SAMPLE ID < 0 Q 01 0,; OL START END r 0 0 One Character per box. wipe Wp 0 (A-Z, 0-9 1, A, AR OT 0 < w 0 Sample Ids must be unique Z 0 , 0, as Lu < < 0 0 z LO L E E Or DATE TIME D1fl11E x 2: z :2 a u- <rs > 1 MW-01R WT 1 1 1 X 2 mw-2 WT 1! q X X X X X X X 1 3 MW-3 VVT q) X X X X X X X 4 J_L 6 7 8 9 10 11, 121 AWITRWALCONIMENTS RELINQUISHED BY I AFFLL4TtDN DATE TOJF ACCEPTED BY I AFFILIATION DATE TIME SAMPLE CONOMNS r? SAMPLER NAME AND SIGNATURE PRINT Name of SAMPLER: Ei SIGNATURE of SAMPLISR—,,( DATE Signed: T I eAnalytical wurmpacallaba.caim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 December 05, 2022 Kimber Reese RPB Systems Inc. P.O. Box 1325 Asheville, NC 28802 RE: Project: Mtn Top MW 11/17 Pace Project No.: 92637438 Dear Kimber Reese: Enclosed are the analytical results for sample(s) received by the laboratory on November 17, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Taylor Dyson taylor.dyson@pacelabs.com (828)254-7176 Project Manager Enclosures cc: Mr. Robert Barr, RPB Systems Inc. Ms. Liz Barr, RPB Systems Inc. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 30