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HomeMy WebLinkAboutNC0021491_Fact Sheet_20230118Fact Sheet NPDES Permit No. NCOO21491 Permit Writer / Email Contact Diana Yitbarek / diana.yitbarekkncdenr.gov Date: 1/18/2023 Division/Unit: NC DEQ Division of Water Resources / NPDES Municipal Permitting Unit Fact Sheet Template: Version 1/9/2017 Permitting Action: ❑X Renewal ❑ Renewal with Expansion ❑ New Discharge ❑ Modification (Fact Sheet should be tailored to mod request) 1. Basic Facility Information Table 1. Facility Information Facility Information Applicant/Facility Name: Town of Mocksville/Dutchman Creek Wastewater Treatment Plant (WWTP) Applicant Address: 171 Clement Street, Mocksville, NC 27028 Facility Address: 295 Garwood Road, Mocksville, NC 27028 Permitted Flow: 0.98 million gallons per day (MGD) Facility Type/% Waste: MINOR Municipal; 75% domestic and 25% industrial' Facility Class: Class III, Biological Water Pollution Control System Treatment Units: Aeration basins, clarifiers, chlorination and dechlorination units, and sludge digester (See the full list of treatment components in the draft NPDES permit) Pretreatment Program (Y/N/Inactive) Y County: Davie Region Winston-Salem 'Based on current permitted industrial flow: 0.25 MGD Permitting Action: This Facility is owned by the Town of Mocksville operated and maintained by Envirolink Inc. The Town applied for NPDES permit renewal and submitted a renewal application dated December 21, 2018, received on January 2, 2019. The Dutchman Creek WWTP has a design capacity of 0.98 MGD and is currently authorized to discharge 0.98 MGD into Dutchman Creek. The Facility serves about 5,100 customers within the Town limits of Mocksville. The Facility's Pretreatment Program is active and has one Significant Industrial User (SIU), a chicken processing plant, authorized to discharge 0.25 MGD [See attached Pollutants of Concern (POC) review form and Allocation Table (AT) sheet for details]. Page 1 of 16 For the calendar year 2021 the total effluent flow averaged 0.47 MGD, 48% of the permitted flow. This Fact Sheet assessment is based on a WWTP flow of 0.98 MGD. Facility Background: The Facility was initially permitted in 1982. In 2005 the Facility transitioned from 0.68 MGD to 0.98 MGD. The Facility does not have current plans to expand but had significant upgrades since the last NPDES permit renewal; therefore, the facility's components list has been updated. Inflow and infiltration (I/I) were reported as 40.000 gpd in the NPDES renewal application. Sludge disposal: The Facility land applies biosolids under Division permit WQ0003351. Currently, sludge and solids produced at this facility are also pumped on an as -needed basis by EMA Resources. This typically occurs every two to three months, depending on the accumulation of solids in the digester and weather conditions that would prohibit solids from being disposed via land application. 2. Receiving Waterbody Information: Table 2. Receiving Waterbodv Information Receiving Waterbody Information Outfalls/Receiving Stream(s): Outfall 001 at 35053'33"N 80030'07"W /Dutchman Creek Stream Segment: 12-102-(2) Stream Classification: C Drainage Area (m12): 108' Summer 7Q10 (cfs) 2.5' Winter 7Q10 (cfs): 11.9' 30Q2 (cfs): - Average Flow (cfs): 106' IWC (% effluent): 37 2022 303(d) listed/parameter: None Subject to TMDL/parameter: Statewide Mercury TMDL Basin/Subbasin/HUC: Yadkin -Pee Dee River Basin/03-07-05 / 03040101 USGS Topo Quad: D16NE ' Stream flows taken from previous Fact Sheet (2014) per Division's guidelines The WWTP is currently authorized to discharge via Outfall 001 into Dutchman Creek, at stream segment 12- 102-(2), classified as C water. The class denotes use as waters protected for uses such as aquatic life propagation, survival and maintenance of biological integrity (including fishing and fish), wildlife, secondary contact recreation, and agriculture. Yadkin River upstream of Dutchman Creek — at station Q2810000 is impaired for turbidity. Basin Planning Division requests to apply this impairment to this stream segment and therefore include effluent and instream monitoring for turbidity on the basis that the watershed is impaired for turbidity. The Outfall 001 is located about 100 feet from the Facility and about 5.5 miles upstream from the boundary of the Yadkin River Water Supply Watershed. Page 2of16 This permit may be reopened and modified to implement nutrient requirements in accordance with any future TMDL and/or Nutrient Management Strategy (NMS) for the downstream water body, High Rock Lake. The NMS development will commence upon the completion of North Carolina's nutrient -related water quality criteria and in consultation with stakeholders in the watershed. 3. Effluent Data Summary Effluent data for Outfall 001 is summarized below from July 2017 through June 2022. Table 3. Effluent Data Summary with permit limits for Outfall 001. Parameters are listed as in the last NPDES permit. Parameter Units Average Max Min Limit' Flow MGD 0.5 2.4 0.0 0.98 BOD5 summer mg/l 6.2 38.0 1.8 MA: 5.0 mg/I WA: 7.5 mg/I BOD5 winter mg/1 10.6 420.02 < 1.0 MA: 10.0 mg/I WA: 15.0 mg/I BOD5 removal % 97.5 99.6 89.8 > 85 TSS mg/1 7.5 535.02 2.6 MA: 30.0 mg/I WA: 45.0 mg/I TSS removal % 94.5 99.1 53.3 > 85 Temperature °C 16.4 26.4 2.2 - DO mg/1 8.4 13.8 5.0 DA > 6.0 mg/I (S) DA > 5.0 mg/I (W) Fecal Coliform #/100 ml 2.94 (GeoMean) 981.0 < 1.0 MA: 200/100 ml WA: 400/100 ml NH3N summer mg/1 1.5 15.0 0.1 MA: 2.0 mg/I WA: 6.0 mg/I NH3N winter mg/1 2.1 14.1 0.1 MA: 4.0 mg/I WA: 12.0 mg/I TN mg/1 22.1 42.3 < 0.5 - TP mg/1 6.0 15.0 0.3 - pH SU 6.9 8.7 5.8 6.0 - 9.0 S.U. Total Residual Chlorine ug/l 19.2 49.0 15.0 DA: 28 ug/I Cadmium ug/1 0.73 2.4 < 0.5 MA: 5.3 ug/I DA: 36.0 ug/I Copper ug/l 11.07 41.0 < 2.0 - Silver ug/1 1.24 5.6 -0.5 - Zinc ug/1 1 67.6 230 2.6 - 'MA -Monthly Average, WA -Weekly Average, DM -Daily Maximum, DA-Daily Average. 2From the Comments section of the March 2020 eDMR: "Returns stopped working, causing solids to back up in clarifier causing high BOD and TSS on 3/11, raising the monthly levels. Solids could not be removed right away due to construction traffic." Table 4. Effluent Data Summary from expanded effluent pollutant scan Outfall 001 Code - Parameter Units Average Max Chloroform ug/1 8.4 27.2 Page 3of16 Code - Parameter Units Average Max Chromium ug/1 3.6 6.0 Dichlorobromomethane ug/1 1.6 3.1 Methyl Bromide ug/1 10.1 17 Mercury ng/1 2.1 4.4 Nickel ug/1 8.6 16 Total Phenolic Compounds ug/1 12.3 14 The data above was provided in the signed effluent pollutant scans/priority pollutant analysis (PPAs), Electronic Discharge Monitoring Report (eDMR). Sample results for the sampled constituents not included above such as arsenic, beryllium, cyanide, lead, and selenium (among others sampled by the effluent pollutant scan/priority pollutant analysis (PPA)), were less than the method detection level. The compounds in the above table were analyzed in the reasonable potential analysis (RPA) and discussed below in the RPA section (Section 6.4) of this Fact Sheet. As required by Session Law 2018-5, Senate Bill 99, Section 13.1(r), every applicant shall submit documentation of any additional pollutants for which there are certified methods with the permit application if their discharge is anticipated. If there are additional pollutants with certified methods to be reported, the permittee shall submit the Chemical Addendum to NPDES Application table with their application and, if applicable, list the selected certified analytical method used. If there are no additional pollutants to report, this form is not required to be included with their application. This requirement applies to all NPDES facilities. Envirolink Inc., informed the Division via email that no monitoring for additional pollutants has been conducted (see email exchange in attachments) and no additional pollutants of concern have been identified; therefore, with this permit renewal, the Division is adding PFAS and 1,4 Dioxane monitoring requirements. 4. Instream Data Summary Instream monitoring may be required in certain situations, for example, 1) to verify model predictions when model results for instream DO are within 1 mg/1 of instream standard at full permitted flow; 2) to verify model predictions for outfall diffuser; 3) to provide data for future total maximum daily load (TMDL); 4) based on other instream concerns. Instream monitoring may be conducted by the Permittee, and there are also Monitoring Coalitions established in several basins that conduct instream sampling for the Permittee (in which case instream monitoring is waived in the permit as long as coalition membership is maintained). Is this Facility a member of a Monitoring Coalition with waived instream monitoring (YIN): Y Name of Monitoring Coalition: Yadkin Pee -Dee River Basin Association Instream data summary and instream monitoring proposed for this permit action: The current permit requires instream [upstream (U) and downstream (D)] monitoring for two parameters: DO, and Temperature. This permit renewal proposes to include conductivity, and pH monitoring per 15A NCAC 02B .0508 and hardness per the hardness -dependent dissolved metals water quality standards approved in 2016, instream hardness data is needed for calculations of permit limitations. This permit is also including Nitrate, Nitrate, TKN, NH3, TN, TP, and TSS. Since the downstream waters are Nutrient Sensitive Waters (NSW) and the Basin Planning Team will need additional data to develop the TMDL. Turbidity is also added due to turbidity impairment in the watershed. Page 4 of 16 The upstream location in the current permit is set to be about 100 ft of the outfall, and the downstream location is set to be about 0.5 miles of the outfall. However, since the Permittee is a member of the Yadkin Pee -Dee River Basin Association, the downstream data is collected from station Q3105000, 0.9 miles downstream of the discharge point. There is no near upstream station. The available instream data was obtained from the DWR Water Sciences Section's Monitoring Coalition database for review. The available data was reviewed from June 2017 through June 2022 and was compared with concurrent effluent data, and against state water quality standards where applicable. Instream data review findings for each parameter are summarized in the figures below. Figure 1. Downstream and Effluent Data Summary Dissolved oxygen (DO), mg/L Temperature, °C 16.00 30.00 14.00 25.00 12.00 - 10.00 20.00 8.00 15.00 6.00 10.00 4.00 2.00 5.00 0.00 0.00 Average Max Min Average Max Min ■ Downstream 7.92 12.00 5.60 ■ Downstream 17.87 26.10 4.30 ■ Effluent 8.37 13.80 5.00 ■ Effluent 16.36 26.40 2.20 pH, Standard Units Total Phosphorous, mg/I 10.00 16.00 9.00 14.00 8.00 - 7.00 12.00 - 6.00 - 10.00 5.00 - 8.00 4.00 6.00 .00 .00 2.00 12 .00 2.00 0.00 0.00 Average Max Min Average Max Min ■ Downstream 6.95 7.50 5.90 ■ Downstream 0.15 0.44 0.03 ■ Effluent 6.89 8.71 5.82 ■ Effluent 5.98 15.00 0.28 Ammonia, mg/L Total Nitrogen, mg/L 16.00 45.00 14.00 40.00 12.00 35.00 10.00 30.00 25.00 - 8.00 20.00 6.00 15.00 4.00 10.00 2.00 5.00 0.00 0.00 Average Max Min Average i Max Min ■ Downstream 0.12 0.49 0.02 ■ Downstream 1.41 5.72 0.52 ■ Effluent i 0.8 15.0 0.0 , i ■ Effluent 21.3 42.3 0.5 Page 5 of 16 Turbidity, NTU 120.00 250.00 100.00 200.00 80.00 150.00 60.00 100.00 40.00 20.00 50.00 0.00 0.00 Average Max Min ■ Effluent 26.68 110.00 6.90 ■ Effluent 9000.00 8000.00 7000.00 6000.00 5000.00 4000.00 3000.00 2000.00 1000.00 0.00 ■ Downstream ■ Effluent Specific Conductance, uS/cm Fecal Coliform, cfu/100ml Average 651.30 72.2 Max 8400.00 2419.6 Average 137.37 Min 44.00 1.0 Max 231.00 ■ Min 57.00 Dissolved Oxygen (DO) -The downstream DO data is meeting the criteria for DO (per 15A NCAC 02B .0211 (6)), remaining not less than a daily average of 5.0 mg/l with an instantaneous value of not less than 4.0 mg/l. Temperature - Reviewed instream temperature data showed seasonal patterns of summer highs and winter lows. Summer temperature maxima at the station was at or below the water quality standard of 29°C for mountain and upper piedmont waters (15A NCAC 02B .0211 (18)). pH - Reviewed downstream and effluent pH data were between 5.8 and 8.7. The water quality standard shall be between 6.0 and 9.0 standard units (15A NCAC 02B .0211 (14)) Total Phosphorous (TP), Total Nitrogen (TN), and ammonia - The permit does not currently require instream monitoring for nutrients. The maximum TP effluent values within this permit cycle were detected in October 2017 and April 2018. Fecal Coliform - Fecal Coliform is a parameter of concern for aquatic life and human health. The permit has not required instream monitoring for Fecal Coliform, since the receiving stream is neither impaired for coliform nor a Class B waterbody, per the 2002 guidance. Per review of the effluent monitoring report violations data revealed that effluent fecal coliform exceeded 400 cfu/100 mL in 3% of the samples. Since the Facility drains to the Yadkin River just upstream of High Rock Lake, which has had reported spikes of fecal coliform (up to 8400 cfu/100 ml in 2019 and 4400 cfu/ml in 2021), with this permit renewal, the Division is recommending the Facility to study the upstream, effluent, and downstream fecal concentrations to demonstrate impacts to the Lake. No fecal monitor requirement has been added at this time. The NPDES Permit requires upstream and downstream monitoring for this Facility. As stated above, the Permittee has a membership with the Yadkin Pee -Dee River Basin Association (monitoring coalition). This monitoring coalition currently only has a downstream monitoring station, and there is no upstream monitoring station. To comply with the NPDES permit requirements, the Facility may coordinate with the monitoring coalition the addition of an upstream monitoring station. Page 6of16 5. Compliance Summary Summary of the compliance record with permit effluent limits (past S years): The Facility has reported 69 limit violations over the past five years (since July 2017), involving BOD, fecal, NH3-N, DO, pH, and TSS exceedances or not reaching the daily minimum. The report on limit violations by type of violations is on Table 5, and the report on limit violations that proceeded to Enforcement Case, notice of deficiency (NOD), or notice of violation (NOV) is as follows: BOD — 26 violations proceeded to Enforcement Case, 5 proceeded to NOD, and 25 proceeded to NOV. Fecal Coliform — 1 violation proceeded to Enforcement case. Ammonia — 4 violations proceeded to Enforcement Case. DO — 1 violation proceeded to NOD. pH — 1 violation proceeded to NOD. TSS — 5 violations proceeded to enforcement case and 1 proceeded to NOV. Table 5. Limit violations by Type of Violation Parameter Daily Minimum Not Reached Monthly Average Exceeded Weekly Average Exceeded Weekly Geometric Mean Exceeded BOD, 5-Day 18 38 Coliform, Fecal Ammonia 1 3 Oxygen, dissolved (DO) 1 pH 1 Solids, Total Suspended - Concentration 2 4 Summary of the compliance record with aquatic toxicity test limits and any second species test results (past S years): The facility passed 20 of 21 quarterly chronic toxicity tests from June 2017—July 2022. Failed the 2018 January test and collected and passed the two consecutive samples. The Facility failed to provide the 4 second species chronic toxicity tests with the NPDES permit application submittal. An extension for this submittal was made and the results were submitted to the Aquatic Toxicology Branch on 10/2021, 1/2022, 4/2022, and 7/2022. All the 4 second species tests passed. Summary of the results from the most recent compliance inspection: The most recent inspection (compliance evaluation), conducted 05/12/2022, found the facility without compliance issues. The inspection report noted that the new secondary clarifiers were clean and operating properly, and the facility appeared to be well operated and maintained. No discrepancies were noted during the inspections. A pretreatment inspection was conducted on 8/1/2022 and similarly reported that records were well organized, and the program is considered satisfactory. A note was made regarding their only SIU, a chicken cooking and packaging facility, it has had repeated flow and BOD violations, for which the POTW had issued Notices of Violation. Page 7 of 16 6. Water Quality -Based Effluent Limitations (WQBELs) 6.1 Dilution and MixingZones ones In accordance with 15A NCAC 213.0206, the following stream flows are used for dilution considerations for development of WQBELs: 1Q10 streamflow (acute Aquatic Life); 7Q10 streamflow (chronic Aquatic Life; non -carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). If applicable, describe any other dilution factors considered (e.g., based on CORMIX model results): NA If applicable, describe any mixing zones established in accordance with I5A NCAC 2B. 0204(b): NA 6.2 Oxygen -Consuming Waste Limitations Limitations for oxygen -consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits (e.g., BOD= 30 mg/l for Municipals) may be appropriate if deemed more stringent based on dilution and model results. Ifpermit limits are more stringent than TBELs, describe how limits were developed: The current BOD limits were set from a level B model in 2005. The model predicted that the expanded waste flow would require tertiary limits (BOD5= 5 mg/l, NH3=2 mg/l, DO = 6 mg/1) for the protection of the dissolved oxygen standard in Dutchman Creek. No changes are proposed. 6.3 Ammonia and Total Residual Chlorine Limitations Limitations for ammonia are based on protection of aquatic life utilizing an ammonia chronic criterion of 1.0 mg/1 (summer) and 1.8 mg/l (winter). Acute ammonia limits are derived from chronic criteria, utilizing a multiplication factor of 3 for Municipals and a multiplication factor of 5 for Non -Municipals. Limitations for Total Residual Chlorine (TRC) are based on the NC water quality standard for protection of aquatic life (17 ug/1) and capped at 28 ug/l (acute impacts). Due to analytical issues, all TRC values reported below 50 ug/1 are considered compliant with their permit limit. Describe any proposed changes to ammonia and/or TRC limits for this permit renewal: The current ammonia limits were set from a level B model in 2005. The model predicted that the expanded waste flow would require tertiary limits (BOD5= 5 mg/l, NH3=2 mg/l, DO = 6 mg/1) for the protection of the dissolved oxygen standard in Dutchman Creek. The current TRC limit was first placed in the 2004 permit, capped at 28 µg/L to protect the water quality standard of 17 µg/L. Ammonia and TRC have been reviewed in the attached Wasteload Allocation (WLA) sheet. Current limits for ammonia were found to be more stringent than the IWC-based calculated results in the WLA sheet. The resulting TRC limit is capped at 28 µg/L and will be maintained in the permit. 6.4 Reasonable Potential Analvsis (RPA) for Toxicants The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall. The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of '/2 detection limit for "less than" values; and 4) stream flows used for dilution consideration based on 15A NCAC 213.0206. Effective April 6, 2016, NC began implementation of dissolved metals criteria in the RPA Page 8of16 process in accordance with guidance titled NPDES Implementation of Instream Dissolved Metals Standards, dated June 10, 2016. A reasonable potential analysis (RPA) was conducted on effluent toxicant data collected from the Permittee's 2021 effluent pollutant scans, DMRs from July 2017 to June 2022, and default upstream hardness. Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. The data set was limited for arsenic, beryllium, total phenolic compound, chromium, cyanide, lead, nickel, selenium, dichlorobromomethane, methyl bromide, and chloroform. Based on this analysis, the following permitting actions are proposed for this permit: • Effluent Limit with Monitoring. The following parameters will receive a water quality -based effluent limit (WQBEL) since they demonstrated a reasonable potential to exceed applicable water quality standards/criteria: copper and cadmium. Copper was under quarterly monitoring in previous cycle. Cadmium was limited in previous cycle. Cadmium limits were updated. • Monitoring Only. The following parameters will receive a monitor -only requirement since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria, but the maximum predicted concentration was >50% of the allowable concentration: silver and zinc. • No Limit or Monitoring: The following parameters will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria, and the maximum predicted concentration was <50% of the allowable concentration: arsenic, chromium, cyanide, lead, and selenium. • These compounds will be monitored in the pretreatment program during this permit cycle: • POTW Effluent Pollutant Scan Review: Three effluent pollutant scans sampled in 2021 were evaluated for additional pollutants of concern. o The following parameter(s) will receive a water quality -based effluent limit (WQBEL) with monitoring since as part of a limited data set, two samples exceeded the allowable discharge concentration: NA o The following parameter(s) will receive a monitor -only requirement, since as part of a limited data set, one sample exceeded the allowable discharge concentration: Nickel o The following parameters that showed detection will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria: dichlorobromomethane, methyl bromide, chloroform, and chromium total. RPA results, as well as a copy of the Dissolved Metals Implementation Fact Sheet for freshwater, are included as attachments of this Fact Sheet. 6.5 Toxicity Testina Limitations Permit limits and monitoring requirements for Whole Effluent Toxicity (WET) have been established in accordance with Division guidance (per WET Memo, 8/2/1999). Per WET guidance, all NPDES permits issued to Major facilities or any facility discharging "complex" wastewater (contains anything other than domestic waste) will contain appropriate WET limits and monitoring requirements, with several exceptions. The State has received prior EPA approval to use an Alternative WET Test Procedure in NPDES permits, using single concentration screening tests, with multiple dilution follow-up upon a test failure. Describe proposed toxicity test requirement: Dutchman WWTP is a Minor Publicly Owned Treatment Work (POTW), discharging domestic and industrial wastewater with chronic WET limits of 37% effluent, monitored quarterly using Ceriodaphnia dubia. Per 40 CFR 122.210)(5)(v), four -second species will continue to be required as well. Page 9of16 6.6 Mercury Statewide Total Maximum Daily Load (TMDL) Evaluation There is a statewide TMDL for mercury approved by EPA in 2012. The TMDL target was to comply with EPA's mercury fish tissue criteria (0.3 mg/kg) for human health protection. The TMDL established a wasteload allocation for point sources of 37 kg/year (81 lb/year) and is applicable to municipals and industrial facilities with known mercury discharges. Given the small contribution of mercury from point sources (-2% of total load), the TMDL emphasizes mercury minimization plans (MMPs) for point source control. Municipal facilities > 2 MGD and discharging multiple quantifiable levels of mercury (>1 ng/1) received an MMP requirement. Industrials are evaluated on a case -by -case basis, depending if mercury is a pollutant of concern. Effluent limits may also be added if annual average effluent concentrations exceed the WQBEL value (based on the NC WQS of 12 ng/1) and/or if any individual value exceeds a TBEL value of 47 ng/1 A mercury evaluation was conducted in accordance with the Permitting Guidance developed for the implementation of the statewide Mercury TMDL to determine the need for a limit. Below find summaries of compliance mercury data from 2017 to 2019. Based on the dataset, the water quality - based effluent limitation (WQBEL) for mercury is 31.7 ng/l, and the technology -based effluent limit (TBEL) is 47 ng/l. Table 6. Mercury Effluent Data Summary and Evaluation 2017 2018 2019 4 of Samples 3 1 Mercury Annual Average (ng/1) 1.8 0.5 3.4 Mercury Annual Max (ng/1) 4.4 0.5 3.3 TBEL, ng/L 47 WQBEL, ng/L 31.7 Describe proposed permit actions based on mercury evaluation: Mercury evaluation results used Method 1631E. Since no annual average mercury concentration exceeded the WQBEL, and no individual mercury sample exceeded the TBEL, no mercury limit is required, and no mercury minimization plan (MMP) is required since the facility is < 2 MGD. 6.7 Other TMDL/Nutrient Management Strategy Considerations If applicable, describe any other TNDDLs/Nutrient Management Strategies and their implementation within this permit: High Rock Lake is presently impaired for several water quality parameters including chlorophyll a, turbidity, and pH. DWR concluded its modeling efforts with support from a technical advisory committee in 2016. High Rock Lake is also presently the focus of a plan to revisit North Carolina's nutrient -related water quality criteria. Nutrient strategy development will commence upon the completion of that effort and in consultation with stakeholders in the watershed. 1. The NPDES permit had quarterly effluent monitoring for TN and TP, and also has a nutrient reopener special condition, for the implementation of any nutrient requirements in accordance with any TMDL or nutrient management strategy for High Rock Lake. The Basin Planning Division reviewed the draft NPDES permit package in this permit cycle renewal and requested to increase the frequency for Page 10 of 16 effluent nutrient (TN and TP) monitoring from quarterly to monthly. This plant discharges upstream of High Rock Lake. There will likely be a need to better understand their load contribution of nitrogen and phosphorus to the system; therefore, the increase in effluent monitoring frequencies and the addition of Nutrient Sensitive Waters (NSW) instream monitoring requirements. With this NPDES permit renewal DWR is adding instream Nitrate and Nitrate (NO2 + NO3), Total Kjeldahl Nitrogen (TKN), Ammonia (NH3 as N), Total Nitrogen, Total Phosphorous and pH. 6.8 Other WOBEL Considerations If applicable, describe any other parameters of concern evaluated for WQBELs: NA If applicable, describe any special actions (HQW or ORW) this receiving stream and classification shall comply with in order to protect the designated waterbody: NA If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 15A NCAC 2H 0 10 7(c) (2) (B), 40CFR 122.47, and EPA May 2007 Memo: A 3-year schedule of compliance for copper was added to the permit with option for a WER study. If applicable, describe any water quality standards variances proposed in accordance with NCGS 143- 215.3(e) and 15A NCAC 2B. 0226 for this permit renewal: Dutchman WWTP discharges into a Class C waterbody with a water supply watershed located —5.5 miles downstream. Because 1,4-Dioxane and PFAS have not been evaluated, quarterly monitoring for these parameters will be added to the permit. In addition, a permit reopener special condition regarding 1,4-Dioxane based on changes toward limits, monitoring or treatment will be added to the permit. Since an EPA method for sampling and analyzing PFAS in wastewater is not currently available, the PFAS sampling requirement in the Permit includes a compliance schedule which delays the effective date of this requirement until the first full calendar quarter beginning 6 months after EPA has a final wastewater method in 40 CFR 136 published in the Federal Register. This date may be extended upon request and if there are no NC - certified labs. 7. Technology -Based Effluent Limitations (TBELs) Municipals (if not applicable, delete and skip to Industrials) Are concentration limits in the permit at least as stringent as secondary treatment requirements (30 mg/l BOD5/TSS for Monthly Average, and 45 mg/l for BOD5/TSS for Weekly Average). If NO, provide a justification for alternative limitations (e.g., waste stabilization pond). Are 85% removal requirements for BOD5/TSS included in the permit? Y If NO, provide a justification (e.g., waste stabilization pond). NA 8. Antidegradation Review (New/Expanding Discharge) The objective of an antidegradation review is to ensure that a new or increased pollutant loading will not degrade water quality. Permitting actions for new or expanding discharges require an antidegradation review in accordance with 15A NCAC 213.0201. Each applicant for a new/expanding NPDES permit must document an effort to consider non -discharge alternatives per 15A NCAC 2H.0105( c)(2). In all cases, existing instream water uses and the level of water quality necessary to protect the existing use is maintained and protected. If applicable, describe the results of the antidegradation review, including the Engineering Alternatives Analysis (EAA) and any water quality modeling results: NA Page 11 of 16 9. Antibacksliding Review Sections 402(o)(2) and 303(d)(4) of the CWA and federal regulations at 40 CFR 122.44(1) prohibit backsliding of effluent limitations in NPDES permits. These provisions require effluent limitations in a reissued permit to be as stringent as those in the previous permit, with some exceptions where limitations may be relaxed (e.g., based on new information, increases in production may warrant less stringent TBEL limits, or WQBELs may be less stringent based on updated RPA or dilution). Are any effluent limitations less stringent than previous permit (YESINO): NO If YES, confirm that antibacksliding provisions are not violated.- NA 10. Monitoring Frequency Requirements Monitoring frequencies for NPDES permitting are established in accordance with the following regulations and guidance: 1) State Regulation for Surface Water Monitoring, 15A NCAC 213.0500; 2) NPDES Guidance, Monitoring Frequency for Toxic Substances (7/15/2010 Memo); 3) NPDES Guidance, Reduced Monitoring Frequencies for Facilities with Superior Compliance (10/22/2012 Memo); 4) Best Professional Judgement (BPJ). Per US EPA (Interim Guidance, 1996), monitoring requirements are not considered effluent limitations under Section 402(o) of the Clean Water Act, and therefore anti -backsliding prohibitions would not be triggered by reductions in monitoring frequencies. The permit proposes monitoring frequencies in compliance with the frequency criteria for class III facilities. For instream monitoring, refer to Section 4. 11. Electronic Reporting Requirements The US EPA NPDES Electronic Reporting Rule was finalized on December 21, 2015. Effective December 21, 2016, NPDES regulated facilities are required to submit Discharge Monitoring Reports (DMRs) electronically. While NPDES regulated facilities would initially be required to submit additional NPDES reports electronically effective December 21, 2020, EPA extended this deadline from December 21, 2020, to December 21, 2025. The current compliance date, effective January 4, 2021, was extended as a final regulation change published in the November 2, 2020, Federal Register. This permit contains the requirements for electronic reporting, consistent with Federal requirements. 12.Summary of Proposed Permitting Actions Table 7. Current Permit Conditions and Proposed Changes for 0.98 MGD Current Permit Limits Parameter and Monitoring Proposed Change' Basis for Condition/Change Frequency' Flow MA: 0.98 MGD No changes 15A NCAC 2B .0505 Monitoring continuously BODs Summer No changes WQBEL. Based on the protection of MA: 5.0 mg/1 DO standard via level B model WA: 7.5 mg/1 calculated in 2005. Winter Monitoring Frequency criteria (MFC) MA: 10.0 mg/1 for class III facilities WA: 15.0 mg/1 Monitoring 3/week Total Suspended MA: 30.0 mg/1 Added monthly TBEL. Secondary treatment Solids (TSS) WA: 45.0 mg/1 instream monitoring standards/40 CFR 133 / 15A NCAC 2B requirements .0406 Monitoring 3/week Page 12 of 16 MFC for class III facilities. Instream TSS is needed to develop TMDLs Ammonia, NH3 as N Summer Added monthly WQBEL. Based on the protection of MA: 2.0 mg/1 instream monitoring DO standard via level B model WA: 6.0 mg/1 requirements calculated in 2005. Winter MFC for class III facilities MA: 4.0 mg/1 WA: 12.0 mg/1 Nutrient sensitive waters (NSW)/nutrient enriched watershed Monitoring 3/week minimum instream monitoring requirements are added to protect High Rock Lake and develop nutrient strategy DO Effluent: No changes WQBEL. State WQ standard, 15A NCAC 2B .0200., .0500. Summer DA>6.Omg/1 MFC for class III facilities Winter DA>5.Omg/l Monitoring 3/week Instream monitoring Fecal coliform MA: 200/100 ml Added instream WQBEL. State WQ standard, 15A WA: 400/100 ml monitoring requirement NCAC 2B .0200. at a variable frequency Monitoring 3/week MFC for class III facilities Instream monitoring added for facility to study fecal impacts to High Rock Lake Temperature Monitoring daily effluent Monitoring daily State WQ reporting requirements 15A effluent NCAC 2B .0500. Instream monitoring daily MFC for class III facilities. Instream monitoring at a variable frequency Conductivity No requirement Added effluent report State WQ reporting requirements 15A and monitoring NCAC 2B .0500; facility treats requirement. Monitor industrial waste. 3/week MFC for class III facilities Instream monitoring at variable frequency pH 6.0 — 9.0 standard units Added Instream WQBEL. State WQ standard, 15A Monitoring 3/week monitoring 3/week NCAC 2B .0200 MFC for class III facilities NSW instream monitoring requirements to study nutrients and protect High Rock Lake Turbidity No requirement Added effluent and Turbidity impairment in the watershed instream monitoring requirement 3/Week Page 13 of 16 Total Residual DM: 28.0 mg/1 DM: 28.0 mg/1 WQBEL. State WQ standard, 15A Chloride (TRC) Monitoring 2/week Monitor 3/week NCAC 2B .0200 MFC for class III facilities Total Hardness No requirement Add effluent and Hardness -dependent dissolved metals upstream hardness water quality standards, approved in quarterly monitoring 2016, need effluent and instream requirement hardness data for calculations of permit limitations. Total Nitrogen (TN) Monitoring quarterly Updated to monthly State WQ reporting requirements 15A monitoring for effluent NCAC 2B .0500 This plant discharges upstream of High Added instream Rock Lake. There will likely be a need monthly monitoring to better understand their load contribution of nitrogen and phosphorus to the system and due to the effluent data Nutrient sensitive waters (NSW)/nutrient enriched watershed minimum instream monitoring requirements to protect High Rock Lake and develop nutrient strategy Total Phosphorus Monitoring quarterly Updated to monthly State WQ reporting requirements 15A (TP) monitoring for effluent NCAC 2B .0500 Added monthly NSW instream monitoring requirements instream monitoring to protect High Rock Lake and develop nutrient strategy Nitrite and Nitrate Added effluent and NSW instream monitoring requirements (NOz+W) No requirement instream monitoring at a to protect High Rock Lake and develop monthly frequency nutrient strategy Total Kjeldahl Added effluent and NSW instream monitoring requirements Nitrogen (TKN) No requirement instream monitoring at a to protect High Rock Lake and develop monthly frequency nutrient strategy Cadmium MA: 5.3 ug/1 MA: 1.8 ug/1 Based on Reasonable Potential Analysis WA: 36 ug/1 WA: 9.4 ug/1 (RPA), RP exists. Predicted Max > Allowable Cw Monitoring monthly Monitoring monthly Copper Monitoring quarterly Added limits Based on RPA, RP exists. Predicted Max > Allowable Cw MA: 25.04 ug/1 WA: 31.07 ug/1 Monitor monthly Added 3-year Schedule of Compliance for Copper Zinc Monitoring quarterly No changes Based on RPA, predicted Max > 50% of Allowable Cw — Maintain quarterly monitoring Silver Monitoring quarterly Added monthly Based on RPA; Predicted Max > monitoring requirement Allowable Cw - apply monthly Monitoring per Division's guideline. Continue using lowest PQL Page 14 of 16 Added quarterly 1,4-Dioxane No requirement monitoring; added Based on downstream water supply. reopener special Data is needed to evaluate. condition Added quarterly Based on downstream water supply. monitoring with Data is needed to PFAS No requirement delayed evaluate. Implementation delayed until implementation after EPA certified method becomes available. Toxicity Test Monitoring 37% on No changes WQBEL. No toxics in toxic amounts. January, April, July, and 15A NCAC 213.0200 and 15A NCAC October 213.0500. Effluent Pollutant Three Effluent Pollutant Three annual Effluent 40 CFR parts 423 and 122 Scan Scans during the term of Pollutant Scans during this permit permit cycle, sampling on the following years: 2024, 2025, 2026 Mercury No requirement No changes Consistent with EPA approved 2012 Minimization Plan Statewide Mercury TMDL (MMP) Electronic Reporting Updated Special Condition to add In accordance with EPA Electronic Special Condition new electronic Reporting Rule 2015 and Rule -Phase 2 reporting deadline Extension December 21, 2025 Footnotes: 1. MGD — Million gallons per day, A.A. — Annual Average, M.A. - Monthly Average, WA — Weekly Average, D.M. — Daily Max, QA — Quarterly Average 2. Variable frequency: Monitor instream 3/Week during June —September and 1/Week during the remaining months of the year. 13. Public Notice Schedule Permit to Public Notice: 10/27/2022 Per 15A NCAC 2H .0109 & .0111, The Division will receive comments for a period of 30 days following the publication date of the public notice. Any request for a public hearing shall be submitted to the Director within the 30 days comment period indicating the interest of the party filing such request and the reasons why a hearing is warranted. If you have questions concerning this permit, please contact Diana Yitbarek at (919) 707-9130 or by email at diana.yitbarek&ncdenr. gov. 14. Fact Sheet Addendum (if applicable) Were there any changes made since the Draft Permit was public noticed (Yes/No): Yes. The NPDES permit draft package was reviewed by the Basin Planning Division Nutrient Manager, who provided comments to protect High Rock Lake If Yes, list changes and their basis below: • Increased frequency of nutrient (Total Nitrogen and Total Phosphorous) effluent monitoring from quarterly to monthly. Better monitoring is needed to develop the nutrient strategy to protect High Rock Lake. Page 15 of 16 • Added instream monitoring for turbidity due to turbidity impairment in the watershed. • Added instream monitoring for Total suspended solids (TSS). This parameter is used when developing total maximum daily loads (TMDLs). • Corrected the instream Temperature requirement: from daily to 3/week subject to variable frequency per State WQ reporting requirements 15A NCAC 2B .0500 and Monitoring Frequency criteria (MF'C) for class III facilities. • Added monthly instream monitoring requirements for facilities that impact nutrient sensitive waters (NSW)/Nutrient sensitive watershed such as: Nitrate and Nitrate (NO2 +NO3), Total Kjeldahl Nitrogen (TKN), Ammonia (NH3 as N), Total Nitrogen, Total Phosphorous, and pH. This monitoring is needed to develop the nutrient strategy to protect High Rock Lake. However, as a participant in the Yadkin Pee -Dee River Basin Association (YPDRBA), instream monitoring is provisionally waived, except for hardness. Instream monitoring will be immediately reinstated, and the Division shall be notified immediately should the permittee end its participation in the Association. • Corrected the effluent table to add monitoring for Zinc. Zinc quarterly monitoring requirement is maintained per reasonable potential analysis (RPA). Since the predicted Max > 50% of Allowable Cw. 15. Fact Sheet Attachments: RPA Sheets Summary for 0.98 MGD: input information, data analyzed, hardness -dependent metals table, and RPA results summary Renewal Application Addendums o Addendum Form 2A o Signed Effluent Pollutant Scans, 2021 BOD and TSS Removal Rate calculations 4. Correspondence 5. eDMR notes 6. NPDES Implementation of Instream Dissolved Metals Standards — Freshwater Standards 7. Mercury TMDL Calculations for 0.98 MGD 8. Monitoring Report Violations Summary, Compliance Evaluations, and Inspections 9. Toxicity Summary/WET testing 10. NH3/TRC/Fecal Waste Load Allocation (WLA) Spreadsheet for 0.98 MGD 11. PT Summary 12. POC Review Form 13. Affidavit, 10/17/2022 Page 16 of 16 N J Cf a w Q i L i O � U � w 0 1 L i+ E L � a N d H d E z FA J J J J J J J J J J_ J J J J J O Ln O r r M O Q W O) O Q 00 r- N LO O) N Q O V Ln M Z O O r Z O N M z LO M M 00 M 00 O O LO Q Q _ j 2 LO O p W O r o O LQ O O o O Q O V N O N O LO O o0 00 0 C09 N 0 Z V W r p N CO O 0 c� o 0 O V 0 M N Ln U U U U U U U U U U U U U U U U U U U U U U U U z z z z z z z z z z z z z z z z z z z z z Q ? 4 Q _ n U U U n U U U U U U U U U= U U) U U U U U U (6 Q E N . Q . Q . 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O .G _ O a N O a vt M .6 O a h a O O a a O a h 7 O a M M O a O a O a O a m v N M m o O N h O O h a\ N c O 00 00 O N U z u z u z u u z z u z u z u z u u z u z `w w E c A s w o o y a_ o `o n E w > c o o m o O u U J z z N u)N O o T s y L U s u � H1 Date 1 4/28/2021 2 8/25/2021 3 12/7/2021 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 REASONABLE POTENTIAL ANALYSIS H2 Use"PASTE SPECIAL Effluent Hardness Values" then "COPY". Upstream Hardness Maximum data points = 58 Data BDL=1/2DL Results 46.4 46.4 Std Dev. 44 44 Mean 32 32 C.V. (default) n 10th Per value Average Value Max. Value 7.7149 1 40.8000 2 0.6000 3 3 4 34.40 mg/L 5 40.80 mg/L 6 46.40 mg/L 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Date Data BDL=1/2DL Results 25 25 Std Dev. Mean C.V. n 10th Per value Average Value Max. Value Use"PASTE SPECIAL Values" then "COPY" Maximum data points = 58 25.0000 0.0000 1 25.00 mg/L 25.00 mg/L 25.00 mg/L -4- 21491 RPA, data 10/27/2022 REASONABLE POTENTIAL ANALYSIS Par01 & Par02 Arsenic Use"PASTE SPECIAL Values" then "COPY" . Par03 Maximum data points = 58 Date Data BDL=1/2DL Results Date Data 1 4/28/2021 < 10 5 Std Dev. 0.0000 1 4/28/2021 < 2 8/25/2021 < 10 5 Mean 5.0000 2 8/25/2021 < 3 12/7/2021 < 10 5 C.V. (default) 0.6000 3 12/7/2021 < 4 n 3 4 5 5 6 Mult Factor = 3.00 6 7 Max. Value 5.0 ug/L 7 8 Max. Pred Cw 15.0 ug/L 8 9 9 10 10 11 11 12 12 13 13 14 14 15 15 16 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 Beryllium BDL=1/2DL Results 5 2.5 Std Dev. 5 2.5 Mean 5 2.5 C.V. (default) n Mult Factor = Max. Value Max. Pred Cw Use"PASTE SPECIAL Values" then "COPY" Maximum data points = 58 2.5000 0.6000 3 3.00 2.50 ug/L 7.50 ug/L 21491 RPA, data -5- 10/27/2022 REASONABLE POTENTIAL ANALYSIS Par04 Cadmium Date Data BDL=1/2DL Results 1 10/18/2017 1.1 1.1 Std Dev. 2 10/19/2017 12 12 Mean 3 10/25/2017 1.3 1.3 C.V. 4 10/26/2017 1.3 1.3 n 5 11 /28/2017 1 1 6 12/5/2017 12 12 Mult Factor = 7 1/16/2018 1 1 Max. Value 8 2/13/2018 1.5 1.5 Max. Pred Cw 9 3/6/2018 12 12 10 4/3/2018 12 1-2 11 5/1/2018 1 0.5 12 6/5/2018 12 12 13 7/3/2018 2 2 14 8/7/2018 12 1-2 15 9/6/2018 < 1 0-5 16 10/4/2018 1.5 1.5 17 12/12/2018 < 1 0-5 18 1 /8/2019 1.8 1-8 19 2/5/2019 < 1 0.5 20 3/7/2019 < 1 0-5 21 4/2/2019 < 1 0-5 22 5/1 /2019 < 1 0.5 23 6/4/2019 < 1 0-5 24 7/9/2019 < 1 0-5 25 8/6/2019 < 1 0.5 26 9/10/2019 1 1 27 9/19/2019 < 1 0-5 28 10/1/2019 < 1 0-5 29 11/6/2019 < 1 0-5 30 12/3/2019 < 1 0.5 31 1 /8/2020 < 1 0.5 32 2/5/2020 < 1 0.5 33 3/4/2020 < 0.5 025 34 4/7/2020 < 0.5 025 35 5/6/2020 < 0.5 025 36 6/2/2020 < 0.5 025 37 7/1/2020 < 0.5 025 38 8/4/2020 < 0.5 025 39 9/2/2020 < 0.5 025 40 10/6/2020 2 2 41 11/3/2020 2.4 2.4 42 12/2/2020 < 1 0.5 43 1 /5/2021 < 1 0.5 44 2/4/2021 < 0.5 025 45 3/2/2021 < 0.5 025 46 4/7/2021 < 0.5 025 47 7/13/2021 < 0.5 025 48 8/3/2021 < 0.4 02 49 9/8/2021 < 0.5 025 50 10/6/2021 2.1 2.1 51 11/3/2021 < 0.5 025 52 12/2/2021 0.5 0.5 53 1/11/2022 < 1 0.5 54 2/2/2022 < 1 0.5 55 3/2/2022 < 0.5 025 56 4/6/2022 1 1 57 5/3/2022 < 0.15 0.075 58 6/1 /2022 < 0.15 0.075 Use "PASTE SPECIAL Use r07 Values" then "COPY". Total Phenolic Compounds Maximum data points = 58 0.7336 0.7681 58 1.00 2.400 ug/L 2.400 ug/L Date Data 1 4/28/2021 2 8/25/2021 3 12/7/2021 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 BDL=1/2DL Results 12 12 Std Dev. 14 14 Mean 11 11 C.V. (default) n Mult Factor = Max. Value Max. Pred Cw Use"PASTE SPECIAL Values" then "COPY" Maximum data points = 58 12.3333 0.6000 3 3.00 14.0 ug/L 42.0 ug/L 21491 RPA, data -6- 10/27/2022 REASONABLE POTENTIAL ANALYSIS Par10 Date Data 1 4/28/2021 2 8/25/2021 < 3 12/7/2021 < 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Chromium, Total BDL=1/2DL Results 6 6 Std Dev- 5 2-5 Mean 5 2-5 C-V- (default) n Mult Factor = Max- Value Max- Pred Cw Use "PASTE SPECIAL Use 1 Values" then "COPY". Maximum data points = 58 3-6667 0-6000 3 3-00 6-0 Ng/L 18-0 Ng/L Date Data 1 7/11/2017 2 10/18/2017 3 10/19/2017 4 10/25/2017 5 10/26/2017 6 1/16/2018 7 4/3/2018 8 7/3/2018 9 10/4/2018 10 1/8/2019 11 4/2/2019 12 6/4/2019 13 7/9/2019 14 8/6/2019 15 10/1/2019 16 1 /8/2020 17 4/7/2020 18 7/1 /2020 19 10/6/2020 20 1 /5/2021 21 4/8/2021 22 8/3/2021 23 10/12/2021 24 1 /11 /2022 25 4/6/2022 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Copper BDL=1/2DL Results 14 14 Std Dev- 9-9 9-9 Mean 7-5 7-5 C-V- 14 14 n 11 11 324 324 Mult Factor = 22 22 Max- Value 13 13 Max- Pred Cw 41 41 7 7 7 7 9 9 11 11 2 1 24 24 7 7 9-5 9-5 4-7 4-7 8-6 8-6 7 7 4-2 4-2 10 10 8-5 8-5 7-6 7-6 7-3 7-3 'RP has Use"PASTE SPECIAL Values" then "COPY" Maximum data points = 58 23-5920 2-6742 25 1-87 324-00 ug/L 605-88 ug/L 21491 RPA, data -7- 10/27/2022 REASONABLE POTENTIAL ANALYSIS Par12 Par14 Use"PASTE SPECIAL. Cyanide Values" then "COPY". Maximum data points = 58 Date Data BDL=1/2DL Results Date 1 4/28/2021 < 5 5 Std Dev. 0.0000 1 4/28/2021 < 2 8/25/2021 < 5 5 Mean 5.00 2 8/25/2021 < 3 12/7/2021 < 6 5 C.V. (default) 0.6000 3 12/7/2021 < 4 n 3 4 5 5 6 Mult Factor = 3.00 6 7 Max. Value 5.0 ug/L 7 8 Max. Pred Cw 15.0 ug/L 8 9 9 10 10 11 11 12 12 13 13 14 14 15 15 16 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 Lead BDL=1/2DL Results 10 5 Std Dev. 10 5 Mean 10 5 C.V.(default) n Mult Factor = Max. Value Max. Pred Cw Use"PASTE SPECIAL Values" then "COPY" Maximum data points = 58 5.0000 0.6000 3 3.00 5.000 ug/L 15.000 ug/L 21491 RPA, data -8- 10/27/2022 REASONABLE POTENTIAL ANALYSIS 21491 RPA, data - 9 - 10/27/2022 REASONABLE POTENTIAL ANALYSIS Par17 & Par18 Nickel Date Data BDL=1/2DL Results 1 4/28/2021 16 16 Std Dev. 2 8/25/2021 < 10 5 Mean 3 12/7/2021 < 10 5 C.V. (default) 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Par19 Use"PASTE SPECIAL Use"PASTE SPECIAL Values" then "COPY". Selenium Values" then "COPY" Maximum data points Maximum data points = 58 = 58 1 Date 4/28/2021 Data BDL=1/2DL < 10 5 Results Std Dev. 0.0000 6.3509 8.6667 2 8/25/2021 < 10 5 Mean 5.0000 0.6000 3 12/7/2021 < 10 5 C.V. (default) 0.6000 3 4 n 3 5 3.00 6 Mult Factor = 3.00 16.0 Ng/L 7 Max. Value 5.0 ug/L 48.0 Ng/L 8 Max. Pred Cw 15.0 ug/L 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 21491 RPA, data -10- 10/27/2022 REASONABLE POTENTIAL ANALYSIS PaL20 Date Data 1 7/11/2017 < 2 10/18/2017 < 3 10/19/2017 < 4 10/25/2017 < 5 10/26/2017 < 6 1 /16/2018 < 7 4/3/2018 < 8 7/3/2018 < 9 10/4/2018 < 10 1 /8/2019 < 11 4/2/2019 < 12 6/4/2019 < 13 7/9/2019 < 14 8/6/2019 < 15 10/1/2019 16 1 /8/2020 < 17 4/7/2020 < 18 7/1 /2020 < 19 10/6/2020 < 20 1 /5/2021 < 21 4/8/2021 < 22 8/3/2021 < 23 10/12/2021 < 24 1/11/2022 < 25 4/6/2022 < 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Silver BDL=1/2DL Results 5 2.5 Std Dev. 2.5 125 Mean 2.5 125 C.V. 2.5 125 n 2.5 125 2.5 125 Mult Factor = 2.5 125 Max. Value 2.5 125 Max. Pred Cw 5 2.5 2 1 5 2.5 2.5 125 2.5 125 2.5 125 5.6 5.6 2 1 1 0.5 1 0.5 1 0.5 1 0.5 1 0.5 0.5 025 0.5 025 0.5 025 0.5 025 Use "PASTE SPECIALr- Use r21 Values" then "COPY" . Maximum data points = 58 12440 0.9069 25 1.40 5.600 ug/L 7.840 ug/L Date Data 1 7/11/2017 2 10/18/2017 3 10/19/2017 4 10/25/2017 5 10/26/2017 6 1/16/2018 7 4/3/2018 8 7/3/2018 9 10/4/2018 10 1/8/2019 11 4/2/2019 12 6/4/2019 13 7/9/2019 14 8/6/2019 15 10/1/2019 16 1 /8/2020 17 4/7/2020 18 7/1 /2020 19 10/6/2020 20 1 /5/2021 21 4/8/2021 22 8/3/2021 23 10/12/2021 24 1 /11 /2022 25 4/6/2022 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Zinc BDL=1/2DL Results 54 54 Std Dev. 73 73 Mean 50 50 C.V. 50 50 n 50 50 110 110 Mult Factor = 100 100 Max. Value 39 39 Max. Pred Cw 42 42 40 40 54 54 36 36 44 44 2.6 2.6 116 116 56 56 75 75 61 61 51 51 230 230 71 71 100 100 54 54 70 70 63 63 Use"PASTE SPECIAL Values" then "COPY" Maximum data points = 58 67.6640 0.6233 25 128 230.0 ug/L 294.4 ug/L -11- 21491 RPA, data 10/27/2022 REASONABLE POTENTIAL ANALYSIS Par22 Par23 Use "PASTE SPECIAL. Use "PASTE SPECIAL- Dichlorobromomethane Values" then "COPY" . Methyl Bromide Values" then "COPY". Maximum data points Maximum data points = 58 = 58 Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 1 8/25/2021 3.17 3.17 Std Dev. 1.3829 1 8/25/2021 17 17 Std Dev. 72803 2 12/7/2021 1.21 121 Mean 1.6267 2 12/7/2021 < 5 2.5 Mean 10.1333 3 5/13/2021 < 1 0.5 C.V. (default) 0.6000 3 5/13/2021 10.9 10.9 C.V. (default) 0.6000 4 n 3 4 n 3 5 5 6 Mult Factor = 3.00 6 Mult Factor = 3.00 7 Max. Value 3.170000 Ng/L 7 Max. Value 17.000000 Ng/L 8 Max. Pred Cw 9.510000 Ng/L 8 Max. Pred Cw 51.000000 Ng/L 9 9 10 10 11 11 12 12 13 13 14 14 15 15 16 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 21491 RPA, data -12- 10/27/2022 REASONABLE POTENTIAL ANALYSIS Par24 Use "PASTE SPECIAL - Chloroform Values" then "COPY". Maximum data points = 58 Date Data BDL=1/2DL Results 1 8/25/2021 272 272 Std Dev. 12.5404 2 12/7/2021 9.79 9.79 Mean 132833 3 5/13/2021 2.86 2.86 C.V. (default) 0.6000 4 n 3 5 6 Mult Factor = 3.00 7 Max. Value 27200000 Ng/L 8 Max. Pred Cw 81.600000 Ng/L 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 21491 RPA, data - 13 - 10/27/2022 I w S a Na Er > > >'°La ¢ a'E 'E 'E a a u o 0 0 y 3 Attachment A —Request for Missing Information Table 2. EPA Application Form 2A Missing Information 1 Email address of facility contact: cwhite@envirolinkinc.com Applicant email address: cwhite@envirolinkinc.com 1'.3 , Email address of the organization transporting the discharge for treatment prior to discharge: smixon@brakebush.com 1.4 Email address of the organization receiving the discharge for treatment prior to discharge: Itrivette@mocksvillenc.gov ',t5, Do you intend to request or renew one or more of the variances authorized at 40 CFR 122.21(n)? (Check all that apply. Consult with your NPDES permitting authority to determine what information needs to be submitted and when,) Discharges into marine waters (CWA Section Water quality related effluent limitation (CWA 301(h)) Section 302(b)(2)) ❑X Not applicable 1:6 +Email address of contractor responsible for operational or maintenance aspects of the treatment works: cwhite envirolinkinc.com i 1',7 ' Indicate the number of SIUs and NSCIUs that discharge to the POTW. Number of SIUs Number of CIUs 1 0 8 Certification Statement I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. Name: Robert White Official title: Dutchman Creek WWTP ORC Signature �--- Date signed 3 -a 3 -� 1 r� Analytical Results Town of Mocksville-Envirolink 771 Sanford Ave Mocksville, NC 27028 Receive Date: 04/28/2021 Reported: 05/17/2021 For: Dutchman Comments: STATESVILLE ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 210428-17-01 Ammonia Nitrogen Effluent 2.69 mg/L SM4500NH3C-2011 05/04/2021 CE 210428-17-01 Hardness Effluent 46.4 mg/L CaCO3 Calculation 04/29/2021 MD 210428-17-01 Nitrate/Nitrite Effluent 6.0 mg/L SM450OF-2011 05/04/2021 CL 210428-17-01 Oil and Grease Effluent <5.05 mg/L EPA1664RevB 05/06/2021 CE 210428-17-01 PPA Effluent See Attached As Noted 05/05/2021 MT 210428-17-01 T. Phosphorous Effluent 6.7 mg/L SM450OPE-2011 04/29/2021 CL 210428-17-01 TKN Effluent <0.5 mg/L SM4500NorgB-2011 04/29/2021 CL 210428-17-01 Total Dissolved Effluent 462 mg/L SM 2540 C 18th Edition 05/03/2021 MD Solids Respectfully submitted, X�- � � " �-' J, ;'� Melissa Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 7 N N is _.i q m Cb�i Zn ! Uw 3 E V N 3 C U A d E U O F m N p Q7 f0 O CD- M G d U g O O O m �0 © g, CL a W c _ � c � w E E cE0 a E E E E E E 1= 1= 1= L) a � � m C o m E T �O a cr 0 mO D ro o a o 0 n I I As 4 E E c c6 [C I o lA Q N i m v� 13 rm t N m N O Q) 61 C Q7 C d to `m_ n pcp E_ > ar C -� m E E E E CJ ¢ C7 d U C)I H F- 1= PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 7 =1 A l =1 A m c�D m O oCD 39 0 0 a m N N 9 CD CD CAD CD � m w �• � CD O = CD O CD CL CQ CA C7 fC to C. m C_ Vi CD 7 C CD Cap OL Q- N 3 3 m 12 Q 3 3 a � 3 3 3 3 �� \ CD CD CD CD 1 I I I P o3 m -D CD C CL CD C 3 y ` tab Camp. 3 3 l 3 x � s'r O Q 0 0 \ CD CD CD CD I j a � y n o m m n 3 N Vm N w 3 3 LA a o+. _ _a o ci g v ' 3 O CC p CD mCL 3 Q a SD (DD CD a It - N c Q cp p 3 �cy.::; q �- r''<A 7 10 a 2. m r N N as PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 7 Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 Contact: C. Little Report Date: 5/13/2021 Client: Statesville Analytical 122 Court St Statesville, NC 28677 Date Sample Rcvd: 4/29/2021 Meritech Work Order # 042921115 Sample: PPA 4/28/21 Parameters Results Analysis Date Reporting Limit Method Antimony, total <0.025 mg/L 5/10/21 0.0005 mg/L EPA 200.8 Arsenic, total <0.010 mg/L 5/10/21 0.002 mg/L EPA 200.8 Beryllium, total <0.005 mg/L 5/10/21 0.0005 mg/L EPA 200.8 Cadmium, total <0.002 mg/L 5/10/21 0.00015 mg/L EPA 200.8 Chromium, total 0.006 mg/L 5/10/21 0.002 mg/L EPA 200.8 Copper, total 0.015 mg/L 5/10/21 0.002 mg/L EPA 200.8 Lead, total <0.010 mg/L 5/10/21 0.0005 mg/L EPA 200.8 Nickel, total 0,016 mg/L 5/10/21 0.002 mg/L EPA 200.8 Phosphorus, total 6.49 mg/L 5/7/21 0.020 mg/L EPA 200.7 Selenium, total <0.010 mg/L 5/10/21 0.001 mg/L EPA 200.8 Silver, total <0.005 mg/L 5/10/21 0.0005 mg/L EPA 200.8 Thallium, total <0.020 mg/L 5/10/21 0.0005 mg/L EPA 200.8 Zinc, total 0.077 mg/L 5/10/21 0.010 mg/L EPA 200.8 Cyanide, total <0.005 mg/L 4/30/21 0.005 mg/L EPA 335.4 Phenols, total 0.012 mg/L 5/6/21 0.010 mg/L EPA 420.1 EPA 625.1 Attached 5/10/21 - 625.1 I hereby certify that i have reviewed and approve these data 'I /t� Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 4 of 7 MERITECH, INC. - Environmental Laboratories if Laboratory Certificate #165 e"'I. r Client: Statesville Analytical Meritech ID#: 042921115 Project: PPA Analysis: 05/10/21 Client Sample ID: PPA Extraction: 05/05/21 Sample Collection: 04/28/21 Analyst: PM Report Date: 05/11/21 Dilution Factor: 1 EPA 625.1 SEMIVOLATILE ORGANICS Parameter Result Parameter Result Acenaphthene <10 ug/L Fluoranthene <10 ug/L Acenaphthylene <10 ug/L Fluorene <10 ug/L Anthracene <10 ug/L Hexachlorobenzene <10 ug/L Benzidine <50 ug/L Hexachlorobutadiene <10 ug/L Benzo(a)anthracene <10 ug/L Hexachlorocyclopentadiene <50 ug/L Benzo(a)pyrene <10 ug/L Hexachloroethane <10 ug/L Benzo(b)fluoranthene <10 ug/L Indeno(1,2,3-cd)pyrene <10 ug/L Benzo(k)fluoranthene <10 ug/L Isophorone <10 ug/L Benzo(g,h,i)perylene <10 ug/L 2-Methylnaphthalene <10 ug/L. Benzyl butyl phthalate <10 ug/L Naphthalene <10 ug/L Bis(2-chloroethoxy)methane <10 ug/L Nitrobenzene <10 ug/L Bis(2-chloroethyl)ether <10 ug/L N-Nitrosodimethylamine <10 ug/L Bis(2-chloroisopropyl)ether <10 ug/L N-Nitrosodi-n-propylamine <10 ug/L Bis(2-ethylhexyl)phthalate <10 ug/L N-Nitrosodiphenylamine <10 ug/L 4-Bromophenyl phenyl ether <10 ug/L Phenanthrene <10 ug/L 2-Chloronaphthalene <10 ug/L Pyrene <10 ug/L 4-Chlorophenyl phenyl ether <10 ug/L 1,2,4-Trichlorobenzene <10 ug/L Chrysene <10 ug/L Dibenzo(a,h)anthracene <10 ug/L 4-Chloro-3-methylphenol <10 ug/L 1,2-Dichlorobenzene <10 ug/L, 2-Chlorophenol <10 ug/L 1,3-Dichlorobenzene <10 ug/L 2,4-Dichlorophenol <10 ug/L 1,4-Dichlorobenzene <10 ug/L 2,4-Dimethylphenol <10 ug/L 3,3'-Dichlorobenzidine <50 ug/L 2,4-Dinitrophenol <50 ug/L Diethyl phthalate <10 ug/L, 4,6-Dinitro-2-methylphenol <50 ug/L Dimethyl phthalate <10 ug/L 2-Nitrophenol <10 ug/L Di-n-butyl phthalate <10 ug/L. 4-Nitrophenol <50 ug/L 2,4-Dinitrotoluene <10 ug/L Pentachlorophenol <50 ug/L 2,6-Dinitrotoluene <10 ug/L Phenol <10 ug/L Di-n-octyl phthalate <10 ug/L 2,4,6-Trichlorophenol <10 ug/L 1,2-Diphenylhydrazine <10 ug/L I hereby certify that I have reviewed and approve these data. �, 4-'! 1.4d' Laboratory Representative 642 Tamco Road * Reidsville, NC 27320 (336) 342-4748 * info@meritechlabs.com PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 5 of 7 C C C C c 3 z c �. 3 a om N Q r x rt 0 O D - a 3 2 n \ a a D K C G L p. w Z. Z (D m ro n <\i Z 3 z z rn ri' �• N Q 0 r+ Q 3 0 (D M 0 o m o o rn � aET 3 rn o r D ^ s Q _ Ln x o l W = O n v W 0 ` n 'O 2 s w to W D w N O iL A N N 0 rD } n m N A rn Y) Q f9 a ru SD 3 fD y • r3o � 'o m � � 3 O ci a `.. o � (j- n. 'a CI)C. � 'p z � v 7 n K � 'y -0 � P 0 O E a a o (� CD - E < O OX < D n n vJ m m i {o v N- CD m D � z�qD = w fD 0 o v i'SJ N T — coo = l}�� @ �. P� ' r$ t q � O v LA N a ..a S O � X \ J l r=-r -ID z 75- �- \ LI Q 3 c z m S — UQ 0 m roc <-. N O F w' 3 D m 3 3 oo 7m -a •• a - s G> a ro m p " C 0 v O O �^ a PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 6 of 7 Permit NCO021491 constitute an invalid test and will require immediate follow-up besting to be completed no later than the last day of the month following the month of the initial monitoring. A. (3) EFFLUENT POLLUTANT SCAN The Permittee shall perform a total of three (3) Effluent Pollutant Scans for all parameters listed below. One scan must be performed in each of the following years: 2015, 2016, and 2017. Analytical methods shall be in accordance with 40 CFR Part 136 and shall be sufficiently sensitive to determine whether parameters are present in concentrations greater than applicable standards and criteria. Samples should be collected with one quarterly toxicity test each year, and must represent seasonal variation [i.e., do not sample in the same quarter every year]. Unless otherwise indicated, metals shall be analyzed as "total recoverable." v,44�etal residual, TRC) en ate men 13 Akeesric, G==ni$rn Gopp— ethod 1631E) -=iviczECi- -qe4w4um �Cy+�ide- ds Volatile organic coinpoacnds: Acrolein 6 Acrylonitrile Benzene Bromoform Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane 2-chloroethylvinyl ether Chloroform Dichlorobromomethane 1,1-dichloroethane 1,2-dichloroethane Trans-1,2-dichloroethylene 1,1-dichloroethylene 1,2-dicbloropropane 1,3-dichloropropylene Ethylbenzene Methyl bromide Methyl chloride Methylene chloride 1,1,2,2-tetradloroethane Tetrachloroethylene Toluene 1,1,1-trichloroethane 1,1,2-trichloroethane Trichloroethylene Vinyl chloride Acid -extractable compounds: P-chloro-m-cresol 2-chlorophenol 2,4-dichlorophenol 2,4-dimethylphenol 4,6-dinitro-o-cresol 2,4-dinitrophenol 2-nitrophenol 4-nitrophenol Pentachlorophenol Phenol 2,4,6-trichlorophenol Base -neutral compoumds: Acenaphthene b Z 5• Acenaphthylene Anthracene Benzidine Benzo(a)anthracene Benzo(a)pyrene 3,4 benzofluoranthene Benzo(ghi)perylene Benzo(k)fluoranthene Bis (2-chloroethoxy) methane Page 5 of 8 Bis (2-chloroethyl) ether Bis (2-chloroisopropyl) ether Bis (2-ethylhexyl) phthalate 1,2-diphenylhydrazine Fluoranthene Fluorene Hexachiorobenzene Hexachlorobutadiene Hexachlorocyclo-pentadiene Hexachloroethane Indeno(1,2,3-cd)pyrene Isophorone Naphthalene Nitrobenzene N-nitrosodi n-propylamine N-nitrosodimethylam.ine N-nitrosodiphenylamine Phenanthrene Pyrene 1,2,4-trichlorobenzene PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 7 of 7 Meritech, Inc. Environmental Laboratory �A Laboratory Certification No. 165 Contact: C. Little Report Date: 5/25/2021 Client: Statesville Analytical 122 Court St Project: Mocksville Statesville, NC 28677 Date Sample Rcvd: 5/14/2021 Meritech Work Order # 05142135 Sample: Grab 5/13/21 Parameters Results Analysis Date Reporting Limit Method EPA 624.1 Attached 5/20/21 - EPA 624.1 I hereby certify that I have reviewed and approve these data, JMn:Lo--& OLL Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 Client: SAH Meritech ID#: 05142135 Project: Mocksville Analysis: 05/20/21 Client Sample ID: Mocksville Analyst: VWV Sample Collection: 05/13/21 Dilution Factor: 1 Report Date: 05/24/21 EPA 624.1 VOLATILE ORGANICS Parameter Benzene Dichlorobromomethane Bromoform Methyl Bromide Carbon Tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Methyl Chloride Chlorodibromomethane 1,2-Dibromoethane 1,1-Dichloroethane 1,2-Dichloroethane 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,1-Dichloroethylene trans-1,2-Dichloroethylene 1,2-Dichloropropane cis-1,3-Dichloropropylene trans-1,3 -Dichloropropylene Ethylbenzene Methylene chloride 1,1,2,2-Tetrachloroethane Tetrachloroethylene Toluene 1, 1, 1 -Trichloroethane 1,1,2-Trichloroethane Trichloroethylene Trichlorofluoromethane Vinyl chloride Additional Compounds Acrolein Acrylonitrile I hereby certify that I have reviewed and approve these data. Result < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L 10.9 ug/L < 1.00 ug/L < 1.00 ug/L < 5.00 ug/L < 5.00 ug/L 2.86 ug/L < 5.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L 7.67 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 5.00 ug/L < 5.00 ug/L <50.0 ug/L <10.0 ug/L Laborat ry Reprtsa6tative 642 Tamco Road * Reidsville, NC 27320 (336) 342-4748 * info@meritechlabs.com r ❑ ❑ Cn ❑rD cn 3 O CL T m -p �+ C a r; p m m � f(D O m < r�o x O p • �� —hrD v � o o S C C � 3-S n non S J y (p 7 \ O rD r m L * p m < o, O Y C- Z D — 3 z° rn V rD° °_ v n Q z L O Q N p L y, Q --• a rD h o o rn (D A 3 Mo =i �• cn o n rD® C- rD W J v v W o V� l -a = > s Wrn O O 0 o �MMFn- N N ® Z a m Nn ,< m W J rD (A Q D y 3 3 3 El 3 r ro rD (D D NrD El z n O 77 Q n N i- (�� m aj 4� - m m m J CD N 3 r a-Q ZiP (D ` aq 7 C •'< 0 [ti O [� CD M I \'` O l N r (D M Ln Q (D (n O TI {� O (D � X 7 rt __ � lD a -a T m TI v 'O z O 9 _ O O rD v_ x O :3 i m El * * ^.. ]..L Ln y ❑ n ° On m rD m 3 3 \ p " -ai' �O . a O DCD Q- �n _ r c OZ •.r C a C O. ❑ O -1C fD n m O O p < Analytical Results Town of Mocksville-Envirolink 771 Sanford Ave Mocksville, NC 27028 Receive Date: 08/25/2021 Reported: 09/22/2021 For: Dutchman Comments: Sample Number Parameter Sample ID Result 210825-22-01 Mercury ILL 210825-22-01 PPA Respectfully submitted, Melissa Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 Effluent 1.61 Effluent See Attached 4 STATESVILLE ANALYTICAL Unit Method Analyzed Analyst ng/L SM1631E 09/17/2021 SL As Noted 08/30/2021 MT PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 9 Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 Contact: C. Little Client: Statesville Analytical 122 Court St Statesville, NC 28677 Report Date: Project: Date Sample Rcvd: 9/15/2021 PPA 8/26/2021 Meritech Work Order # 08262159 Sample: Effluent Composite 8/24-25/21 Parameters Results Analysis Date Reporting Limit Method Total Dissolved Solids 608 mg/L 8/30/21 10.0 mg/L SM 2540C Ammonia, Nitrogen <0.1 mg/L 8/31/21 0.1 mg/L EPA 350.1 TKN <0.20 mg/L 9/1/21 0.20 mg/L EPA 351.1 Nitrate/Nitrite, Nitrogen 39.5 mg/L 8/31/21 0.10 mg/L EPA 353.2 Nitrogen, total 39.5 mg/L 9/1/21 0.20 mg/L EPA 353.2 Antimony, total <0.025 mg/L 9/9/21 0.025 mg/L EPA 200.7 Arsenic, total <0.010 mg/L 9/9/21 0.010 mg/L EPA 200.7 Beryllium, total <0.005 mg/L 9/9/21 0.005 mg/L EPA 200.7 Cadmium, total <0.002 mg/L 9/9/21 0.002 mg/L EPA 200.7 Chromium, total <0.005 mg/L 9/9/21 0.005 mg/L EPA 200.7 Copper, total 0.013 mg/L 9/9/21 0.002 mg/L EPA 200.7 Lead, total <0.010 mg/L 9/9/21 0.010 mg/L EPA 200.7 Nickel, total <0.010 mg/L 9/9/21 0.010 mg/L EPA 200.7 Phosphorus, total 12.6 mg/L 9/8/21 0.020 mg/L EPA 200.7 Selenium, total <0.010 mg/L 9/9/21 0.010 mg/L EPA 200.7 Silver, total <0.005 mg/L 9/9/21 0.005 mg/L EPA 200.7 Thallium, total <0.020 mg/L 9/9/21 0.020 mg/L EPA 200.7 Zinc, total 0.070 mg/L 9/9/21 0.010 mg/L EPA 200.7 Hardness (titration) 44 mg/L 9/2/21 1 mg/L SM 2340C EPA 625.1 Attached 9/1/21 - 625.1 Meritech Work Order # 08262160 Sample: Effluent Grab 8/25/2021 Parameters Results Analysis Date Reporting Limit Method Cyanide, total <0.005 mg/L 8/31/21 0.005 mg/L EPA 335.4 Oil & Grease (HEM) <5.0 mg/L 8/30/21 5.0 mg/L EPA 1664B Phenols, total 0.014 mg/L 9/3/21 0.010 mg/L EPA 420.1 EPA 624.1 Attached 8/31/21 EPA 624.1 1 hereby certify that I have reviewed and approve these data. �K`n Q CI`X_1fra k-) Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 9 MERITECH, INC. Environmental Laboratories Laboratory Certificate #165 Client: Statesville Analytical Meritech ID#: 08262159 Project: Dutchman Creek PPA Analysis: 09/01/21 Client Sample ID: Effluent Extraction: 08/30/21 Sample Collection: 08/25/21 Analyst: PM Report Date: 09/02/21 Dilution Factor: 1 EPA 625.1 SEMIVOLATILE ORGANICS Parameter Result Parameter Result Acenaphthene <10 ug/L Fluoranthene <10 ug/L Acenaphthylene <10 ug/L Fluorene <10 ug/L Anthracene <10 ug/L, Hexachlorobenzene <10 ug/L Benzidine <50 ug/L Hexachlorobutadiene <10 ug/L Benzo(a)anthracene <10 ug/L Hexachlorocyclopentadiene <50 ug/L Benzo(a)pyrene <10 ug/L Hexachloroethane <10 ug/L Benzo(b)fluoranthene <10 ug/L Indeno(1,2,3-cd)pyrene <10 ug/L Benzo(k)fluoranthene <10 ug/L Isophorone <10 ug/L Benzo(g,h,i)perylene <10 ug/L 2-Methylnaphthalene <10 ug/L Benzyl butyl phthalate <10 ug/L Naphthalene <10 ug/L Bis(2-chloroethoxy)methane <10 ug/L Nitrobenzene <10 ug/L Bis(2-chloroethyl)ether <10 ug/L N-Nitrosodimethylamine <10 ug/L Bis(2-chloroisopropyl)ether <10 ug/L N-Nitrosodi-n-propylamine <10 ug/L Bis(2-ethylhexyl)phthalate <10 ug/L N-Nitrosodiphenylamine <10 ug/L 4-Bromophenyl phenyl ether <10 ug/L Phenanthrene <10 ug/L 2-Chloronaphthalene <10 ug/L Pyrene <10 ug/L 4-Chlorophenyl phenyl ether <10 ug/L 1,2,4-Trichlorobenzene <10 ug/L Chrysene <10 ug/L Dibenzo(a,h)anthracene <10 ug/L 4-Chloro-3-methylphenol <10 ug/L 1,2-Dichlorobenzene <10 ug/L 2-Chlorophenol <10 ug/L 1,3-Dichlorobenzene <10 ug/L 2,4-Dichlorophenol <10 ug/L 1,4-Dichlorobenzene <10 ug/L, 2,4-Dimethylphenol <10 ug/L 3,3'-Dichlorobenzidine <50 ug/L 2,4-Dinitrophenol <50 ug/L Diethyl phthalate <10 ug/L 4,6-Dinitro-2-methylphenol <50 ug/L Dimethyl phthalate <10 ug/L 2-Nitrophenol <I0 ug/L Di-n-butyl phthalate <10 ug/L 4-Nitrophenol <50 ug/L 2,4-Dinitrotoluene <10 ug/L Pentachlorophenol <50 ug/L 2,6-Dinitrotoluene <10 ug/L Phenol <10 ug/L Di-n-octyl phthalate <10 ug/L 2,4,6-Trichlorophenol <10 ug/L 1,2-Diphenylhydrazine <10 ug/L I hereby certify that 1 have reviewed and approve these data. t4� . a/, Laboratory Representative 642 Tamco Road * Reidsville, NC 27320 (336) 342-4748 * info@meritechlabs.com PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 9 MERI TECH, INC. •1�' Environmental Laboratories Laboratory Certification #165 Client: SAH Meritech ID#: 08262160 Project: Dutchman Creek PPA Analysis: 08/31/21 Client Sample ID: Effluent Analyst: VWV Sample Collection: 08/25/21 Dilution Factor: 1 Report Date: 09/02/21 EPA 624.1 VOLATILE ORGANICS Parameter Result Benzene < 1.00 ug/L Dichlorobromomethane 3.17 ug/L Bromoform < 1.00 ug/L Methyl Bromide 17.0 ug/L Carbon Tetrachloride < 1.00 ug/L Chlorobenzene < 1.00 ug/L Chloroethane < 5.00 ug/L 2-Chloroethyl vinyl ether <5.00 ug/L Chloroform 27.2 ug/L Methyl Chloride < 5.00 ug/L Chlorodibromomethane < 1.00 ug/L 1,2-Dibromoethane < 1.00 ug/L 1,1-Dichloroethane < 1.00 ug/L 1,2-Dichloroethane < 1.00 ug/L 1,4-Dichlorobenzene < 1.00 ug/L 1,2-Dichlorobenzene < 1.00 ug/L 1,3-Dichlorobenzene < 1.00 ug/L 1,1-Dichloroethylene < 1.00 ug/L trans-1,2-Dichloroethylene < 1.00 ug/L 1,2-Dichloropropane < 1.00 ug/L cis-1,3-Dichloropropylene < 1.00 ug/L trans- l,3-Di chloropropylene < 1.00 ug/L Ethyl benzene < 1.00 ug/L Methylene chloride < 1.00 ug/L. 1,1,2,2-Tetrachloroethane < 1.00 ug/L Tetrachloroethylene < 1.00 ug/L Toluene < 1.00 ug/L 1,1,1-Trichloroethane < 1.00 ug/L 1,1,2-Trichloroethane < 1.00 ug/L Trichloroethylene < 1.00 ug/L Trichlorofluoromethane < 5.00 ug/L Vinyl chloride < 5.00 ug/L Additional Compounds Acrolein <50.0 ug/L Acrylonitrile <10.0 ug/L I hereby certify that I have reviewed and approve these data. Laboratory Rspra4entative 642 Tamco Road * Reidsville, NC 27320 (336) 342-4748 * info@meritechlabs.com PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 4 of 9 El �� ❑ E ` m m o m � c a = c c r �� a ° (1) X fl. 3 .. 3 n � Q.Iv N X p r � N`=_�2 m Q 'D - Q- 0 3 0 z rT m m -00 n x o 0 m. mm G m !' _� M y M rr °c O Q .� N : W W M�� 0 o 6 ti C W W y`° n C CL 4CD n y cn a= N Cli M G.D o m °� o y �1 „ m QD . a+ O o Y 3 p O p Z J�ft 0fD p `� o eT � �p -Y p� �f m m = o CD y a O y ~ K y ..a m N •� v 6 m y 7 G) G) G) n n n n c, 3 o D Q ✓ �D Q y 3 .'�. C) cD CL ' R RC W N i pa CI)�_ 0CD N (l \ of 3 z � Q y w f/) m m Q C iA O p CD n y Z N fn CA ,v w O Cf1 •� O a z 2 N —� O ° W O N N j _ 0 (�cn N V y o 0 CD 0 CD .Q Ca ,, c a Q 0 CD CD v m m m m z ° o0 y x cn _ O O y a m iJ� i 3 to G 3 D m .� 0 `co a. Q w D C fu PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 5 of 9 Client: Attention NPDES # MERITECH, INC. ENVIRONMENTAL LABORATORIES Laboratory Certification No. 165 Statesville Analytical 122 Court St. Statesville, NC 28677 Crystal Little Date Sampled 08/25/21 Digested 08/26/21 Analysis 09/17/21 Analyst: Summit EPA 1631 Low Level Mercury Analysis Meritech ID # Sample ID Result Reporting Limit MBLK0917 Method Blank < 0.5 ng/L 0.5 ng/L M08262101 Field Blank < 1.0 ng/L 1.0 ng/L M08262102 Dutchman Creek 1.61 ng/L 1.0 ng/L Effluent I hereby certify that I have reviewed and approve these data. 'Laboratory Representative 642 Tamco Rd - PO Box 27 - Reidsville, NC 27320 (336) 342-4748 Ph - (336) 342-1522 Fax E-Mail: info@meritechlabs.com PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 6 of 9 U' Summit Environmental Technologies. In WO#: 21090782 3310 Win St. ENVIPIONrneraTAL TEC4ryOLO-.Jr.s, •rvC Cuyahoga Falls, Ohio 44223 Date Reported: 9/17/2021 ra yrc`cat .[ r�rorrer TEL: (330) 253-8211 FAX.. (330) 253-4489 Company: Meritech Environmental Laboratories Websire: htmWwww.serrekcom Address: 642 Tarrtco Rd. Reidsville NC 27320 Received: 9/13/2021 Project#: Client ID# Lab 1D# Collected Analyte Result Units Matrix Method DF MDL Run Analyst 082601 SAH F8 018 8/25/2021 Mercury ND ng/L Non- EPA 1631 1 0.247 9/17/2021 KMW Potable Water Page 21 of 35 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 7 of 9 SUMMIT Summit Environmental Technologies. Inc. WO*: 21090782 3310 Win St. ENVIPONMENTAL TECIINCLOGMS, Cuyahoga Falls. Ohio 44223 Date Reported: 9/17/2021 Amrtyt/cof Laborarerieu TEL: (330) 253.8211 FAX.- (330) 253— 489 Company: Meritech Environmental Laboratories Websire: hrm://www.settekcom Address: 642 Tamco Rd. Reidsville NC 27320 Received: 9/13/2021 Project#: Client ID# Lab ID# Collected Analyte Result Units Matrix Method DF MDL Run Analyst 082602 SAH DEff 019 8/25/2021 Mercury 1.61 ng/L Non- EPA 1631 1 0.247 9/172021 KMW Potable Water Page 22 of 35 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 8 of 9 G p -n Cl) 7IDm �CD fD v r 3 0 0. A:. 0 CD Q. T. �_ m �� O 0CD a '. n -> m m N o CD m m CD CD CD _. 0 r N cn 0 Z chi OCD 0 ai Q 3 CDC- m zcc c rn �p -I -v D �X=�no CD�N T v o D cr D w O .. y �� NW> 1 3 W N N X v fTl �..� N co c,s m vis N _D n 0 c'1 y Cn ti CD ' �m CL co 3 cn N n d 0) 'aN o -� s L CO Al % a it P0 cr O o °7 0 z 2 3 va c� _ 0 _ x o o m S CD CD .. fD # N G l CD 0 m O C T m P-+ N2_ 3 d � a 0 CD v x m •J .. PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 9 of 9 Analytical Results Town of Mocksville-Envirolink 771 Sanford Ave Mocksville, NC 27028 Receive Date: 12/07/2021 Reported: 12/30/2021 For: Dutchman Comments: Sample Number Parameter Sample ID Result 211207-46-01 PPA Respectfully submitted, Melissa Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 Eff See Attached 4 STATESVILLE ANALYTICAL Unit Method Analyzed Analyst As Noted 12/09/2021 MT PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 6 Condition of Receipt Sample Number 211207-46-01 Temp on Arrival: 2.5 Parameter Schedule: Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 6 Meritech, Inc. Environmental Laboratory Laboratory Certification No. 165 Contact: C. Little Client: Statesville Analytical 122 Court St Statesville, NC 28677 Report Date: Project: Date Sample Rcvd: 12/30/2021 PPA 12/8/2021 Meritech Work Order # 12082154 Sample: Effluent Composite 12/6-7/21 Parameters Results Analysts Date Reporting Limit Method Total Dissolved Solids 542 mg/L 12/9/21 10.0 mg/L SM 2540C Ammonia, Nitrogen <0.1 mg/L 12/9/21 0.1 mg/L EPA 350.1 TKN 0.97 mg/L 12/14/21 0.20 mg/L EPA 351.1 Nitrate/Nitrite, Nitrogen 16.4 mg/L 12/15/21 0.10 mg/L EPA 353.2 Nitrogen, total 17.4 mg/L 12/15/21 0.20 mg/L EPA 353.2 Antimony, total <0.025 mg/L 12/23/21 0.025 mg/L EPA 200.7 Arsenic, total <0.010 mg/L 12/23/21 0.010 mg/L EPA 200.7 Beryllium, total <0.005 mg/L 12/23/21 0.005 mg/L EPA 200.7 Cadmium, total <0.002 mg/L 12/23/21 0.002 mg/L EPA 200.7 Chromium, total <0.005 mg/L 12/23/21 0.005 mg/L EPA 200.7 Copper, total 0.009 mg/L 12/23/21 0.002 mg/L EPA 200.7 Lead, total <0.010 mg/L 12/23/21 0.010 mg/L EPA 200.7 Nickel, total <0.010 mg/L 12/23/21 0.010 mg/L EPA 200.7 Phosphorus, total 9.47 mg/L 12/23/21 0.020 mg/L EPA 200.7 Selenium, total <0.010 mg/L 12/23/21 0.010 mg/L EPA 200.7 Silver, total <0.005 mg/L 12/23/21 0.005 mg/L EPA 200.7 Thallium, total <0.020 mg/L 12/23/21 0.020 mg/L EPA 200.7 Zinc, total 0.099 mg/L 12/23/21 0.010 mg/L EPA 200.7 Hardness (titration) 32 mg/L 12/9/21 1 mg/L SM 2340C EPA 625.1 Attached 12/22/21 - 625.1 Meritech Work Order # 12082155 Sample: Effluent Grab 12/7/2021 Parameters Results Analysis Date Reporting Limi Method Cyanide, total 0.006 mg/L 12/9/21 0.005 mg/L EPA 335.4 Oil & Grease (HEM) <5.0 mg/L 12/13/21 5.0 mg/L EPA 1664B Phenols, total 0.011 mg/L 12/10/21 0.010 mg/L EPA 420.1 EPA 624.1 Attached 12/13/21 - EPA 624.1 I hereby certify thatl have reviewed and approve these data. 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 6 1. MERI TECH, INC. Environmental Laboratories Laboratory Certificate #165 Client: Statesville Analytical Meritech ID#: 12082154 Project: PPA Analysis: 12/22/21 Client Sample ID: Effluent Extraction: 12/13/21 Sample Collection: 12/07/21 Analyst: PM Report Date: 12/30/21 Dilution Factor: 1 EPA 625.1 SEMIVOLATILE ORGANICS Parameter Result Parameter Result Acenaphthene <10 ug/L Fluoranthene <10 ug/L Acenaphthylene <10 ug/L Fluorene <10 ug/L Anthracene <10 ug/L Hexachlorobenzene <10 ug/L Benzidine <50 ug/L Hexachlorobutadiene <10 ug/L Benzo(a)anthracene <10 ug/L Hexachlorocyclopentadiene <50 ug/L Benzo(a)pyrene <10 ug/L Hexachloroethane <10 ug/L Benzo(b)fluoranthene <10 ug/L Indeno(1,2,3-cd)pyrene <10 ug/L Benzo(k)fluoranthene <10 ug/L lsophorone <10 ug/L Benzo(g,h,i)perylene <10 ug/L 2-Methylnaphthalene <10 ug/L Benzyl butyl phthalate <10 ug/L Naphthalene <10 ug/L Bis(2-chloroethoxy)methane <10 ug/L Nitrobenzene <10 ug/L Bis(2-chloroethyl)ether <10 ug/L N-Nitrosodimethylamine <10 ug/L Bis(2-chloroisopropyl)ether <10 ug/L N-Nitrosodi-n-propylamine <10 ug/L Bis(2-ethylhexyl)phthalate <10 ug/L N-Nitrosodiphenylamine <10 ug/L 4-Bromophenyl phenyl ether <10 ug/L Phenanthrene <10 ug/L 2-Chloronaphthalene <10 ug/L Pyrene <10 ug/L 4-Chlorophenyl phenyl ether <10 ug/L 1,2,4-Trichlorobenzene <10 ug/L Chrysene <10 ug/L Dibenzo(a,h)anthracene <10 ug/1. 4-Chloro-3-methylphenol <10 ug/l. 1,2-Dichlorobenzene <10 ug/L 2-Chlorophenol <10 ug/L 1,3-Dichlorobenzene <10 ug/L 2,4-Dichlorophenol <10 ug/L 1,4-Dichlorobenzene <10 ug/L 2,4-Dimethylphenol <10 ug/L 3,3'-Dichlorobenzidine <50 ug/L 2,4-Dinitrophenol <50 ug/L Diethyl phthalate <10 ug/L 4,6-Dinitro-2-methylphenol <50 ug/L Dimethyl phthalate <10 ug/L 2-Nitrophenol <10 ug/L Di-n-butyl phthalate <10 ug/L 4-Nitrophenol <50 ug/L 2,4-Dinitrotoluene <10 ug/L Pentachlorophenol <50 ug/L 2,6-Dinitrotoluene <10 ug/L Phenol <10 ug/L Di-n-octylphthalate <10 ug/L 2,4,6-Trichlorophenol <10 ug/L 1,2-Diphenylhydrazine <10 ug/L I hereby certify that I have reviewed and approve these data. Laboratory Repres&tative 642 Tamco Road * Reidsville, NC 27320 (336) 342-4748 * info@meritechlabs.com PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 4 of 6 MERITECH, INC. Environmental Laboratories Laboratory Certification #165 Client: Statesville Analytical, Inc. Meritech ID#: 12082155 Project: PPA Analysis: 12/13/21 Client Sample ID: Effluent Analyst: VWV Sample Collection: 12/07/21 Dilution Factor: I Report Date: 12/16/21 EPA 624.1 VOLATILE ORGANICS Parameter Benzene Dich lorob romomethane Bromoform Methyl Bromide Carbon Tetrachloride Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform Methyl Chloride Chlorodibromomethane 1,2-Dibromoethane 1,1-Dichloroethane 1,2-Dichloroethane 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,1-Dichloroethylene trans-1,2-Dichloroethylene 1,2-Dichloropropane cis-1,3-Dichloropropylene trans-1,3-Dichloropropylene Ethyl benzene Methylene chloride 1,1,2,2-Tetrachloroethane Tetrachloroethylene Toluene 1, 1, 1 -Trichloroethane 1,1,2-Trichloroethane Trichloroethylene Trichlorofluoromethane Vinyl chloride Additional Compounds Acrolein Acrylonitrile I hereby certify that I have reviewed and approve these data. Result < 1.00 ug/L 1.21 ug/L < 1.00 ug/L, < 5.00 ug/L < 1.00 ug/L < 1.00 ug/L < 5.00 ug/L < 5.00 ug/L 9.79 ug/L < 5.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L. < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 1.00 ug/L < 5.00 ug/L < 5.00 ug/L <50.0 ug/L <10.0 ug/L Laboratory ntative 642 Tamco Road * Reidsville, NC 27320 (336) 342-4748 * info@meritechlabs.com PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 5 of 6 C j ❑ ❑ ❑ (m m m m T a m co CL 3 ca QN p x 0CD IV N -I cn w 0-3 CD S o '—. o 0 0 fli 3 X m-n -u -h R• n �_ N v svx� � �0 �� d o tjy cn a .c CDy V L. N X 0 r. `M T 0'0 0 Q y CD3 ,,Qn ✓O� L1 a T T n e. 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Ul zo u � rl LLn 16n1 � O 00 N O r- 6ml m r- 00 m 00-1 r, Q0 � N N Ln m � M LNr1 -1 CN r, m Q WOO n r-I oon n oo ooof ��(-o n 0000 n lo oon of of moo of ri of of ooof of ri O OO -1 -1 _I p C O N O N N rl rI N r1 N N N N s N N C 0 0 0 N i N i i N N N rl rl rl rI N i N i i N N N N N N ra N N N N N-0 i s N N N N N i s N N N co ao v o Q tip v o m Q co c 0 <„ z o <„ z o L ++ o r1 m 00 lD m Ln Ln Ln m Ln m 00 00 00 00 -1 r1 r1 N 1, Ln O 1, 00 m -1 O 61 r1 C� C� (0l 1- C� C� C� C� N rl 1:1: O m In lD O� rl� O rl� Gl O O N 1:1: N 1- cl� G OC 00 n n 00 00 00 00 00 00 lD 00 n n lD :I- Lr) In 1, Lr) c-I Ol 00 n lD n n n n 00 Ol 61 Ol Ol Ol Ol Ol Ol Ol Ol Ol Ol a) a) a) a) a) a) a) a) a) Ol Ol Ol Ol Ol Ol Ol Ol Ol 00 0 m n n n 00 00 00 al Ol Ol I� rl rl 00 � 00 00 00r1 r1 61 CY) r1 Ol r1 r1 00 00 00 00 r1 i i Ol Ol Ol 61 r1 N i S rl rl _0 N i S rl rl r1 N E -0 m ao v o v v a0 v° v v ra M a0 v° v v Q u > u Q Q u> u Q Q u> u Q Q) p o v— U Q Q) p o v—� Q� p o v <n z 0 Ul z 0 Ul z 0 To:NPDES Permitting Branch From: Nora Deamer, Basin Planning Branch Date: November 30, 2021 Re: Standardized instream monitoring of NSW/nutrient enriched watersheds. The Basin Planning, Modeling and Assessment, Nonpoint Source and the Classification, Standards and Rules Review branches in the Planning Section of DWR request standardization of instream (upstream and downstream) surface water monitoring requirements to be reported as part of the monthly eDMRs for all major dischargers in NSW watersheds and those identified as nutrient enriched waters across the state. Table 1. Minimum set of instream surface water monitoring requirements requested for NPDES permits in all NSW and nutrient enriched watersheds. Additional parameters, frequency, sample types and locations could be needed based on site specific monitoring needs. These represent the minimum set of data needed to assess instream impacts from a wastewater discharger to surface waters of NC. Instream Characteristics Monitoring Requirements Measurement Frequency^ Sample Type Sample Location Dissolved Oxygen Monthly (year-round) Grab Upstream, Downstream pH Monthly (year-round) Grab Upstream, Downstream Specific Conductance Monthly (year-round) Grab Upstream, Downstream Temperature Monthly (year-round) Grab Upstream, Downstream Fecal Coliform Monthly (year-round) Grab Upstream, Downstream Total Phosphorus Monthly (year-round) Grab Upstream, Downstream PO4 Monthly (year-round) Grab Upstream, Downstream Total Nitrogen Monthly (year-round) Grab Upstream, Downstream NO2 + NO3 Monthly (year-round) Grab Upstream, Downstream NH3 as N Monthly (year-round) Grab Upstream, Downstream TKN Monthly (year-round) Grab Upstream, Downstream ^ Minimum monitoring frequency. More frequent summer monitoring when conditions are more variable would be preferred. Standardized instream surface water monitoring requirements in each NPDES permit would ensure the availability of a minimum set of data for all streams receiving nutrient laden wastewater effluent. This information would allow DWR staff (permit writers, basin planners, modelers, etc.) to have a reliable set of information to evaluate the water quality and the impact of a discharger to the aquatic ecosystem. This action would ensure instream water quality information is collected equitably by all dischargers. There are several monitoring coalition programs in place that allow for the collection of instream surface water data using a collaborative monitoring approach. We continue to support standardized language for dischargers to forgo their specific instream monitoring requirements by participating in a DWR approved monitoring coalition. However, over the years monitoring coalitions have come and gone, have added, and dropped stations which has resulted in changes in available instream data. Having a minimum set of instream monitoring requirements will eliminate the loss of essential water quality data if a discharger withdraws from a coalition. An example of this specific situation occurred when Durham County (Triangle WWTP, NC0026051) pulled out of the Upper Cape Fear River Basin Association (UCFRBA) in 2012. The coalition dropped one of the monitoring stations resulting in no instream nutrient monitoring data at that location in a critical nutrient sensitive watershed with an EPA approved TMDL and a nutrient reduction strategy in place. The request includes a year-round frequency component for all parameters collected. Year-round data is necessary to assess water quality models, loading, trends and impact analysis, since standards apply year-round. Current coalition monitoring frequencies includes year-round monthly monitoring for nutrients, physical and bacteriological parameters. They increase the frequency of the physical parameters to twice monthly in the summer. We request that this be the minimum instream monitoring frequency included in NPDES permits. More frequent summer monitoring when conditions are more variable would be preferred as the upstream and downstream stations are specifically used to understand the impacts of a discharge to surface waters of the state, especial during the most critical periods. Our efforts to protect and enhance state waters are only possible when we have the data we need to make a comprehensive assessment. We appreciate your consideration of our requests. CC: Jim Hawhee — Basin Planning Branch Pam Behm — Modeling and Assessment Branch Rich Gannon- Nonpoint Source Branch Jeff Manning — Classification and Standards Branch Karen Higgins — Planning Section Chief [External] Automatic reply: Dutchman Creek WWTP, Town of Mocksville - Draft NPDES Permit NCO021491 - Public Notice - SIC 4952 R4NPDESPermits <R4NPDESPermits@epa.gov> Thu 10/27/2022 09:50 To: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. This is to acknowledge receipt by the EPA Region 4. R4NPDESPermits@epa.gov is a shared mailbox for states to submit NPDES permit packages to EPA Region 4 and should only be used for that purpose. We may provide written comments and recommendations or objections to a draft or proposed final permit. If we do not respond within the timeframes below, as per the current State/EPA Memorandum of Agreement (MOA) (Section IV), then the State may issue the final permit. However, if other parties raised significant concerns objecting to the draft or if the final permit is significantly different than the draft the State needs to send a proposed permit to us for review. Timeframes for EPA review: • Draft Individual Permit: the EPA has 30 calendar days to review it and may request 90 days for review • Draft General Permit: the EPA has 90 calendar days to review it • Proposed Permit: the EPA has 15 business days to review it and may request 90 calendar days to review it If you have any questions about this please don't hesitate to contact me. Sincerely, Craig Hesterlee, Chief NPDES Permitting Section 404-562-9749 Hesterlee.Craig@gpa.gov Re: [External] - Re: [External] - Dutchman.21491 - NPDES permit renewal process Madelyn Mills <mmills@envirolinkinc.com> Wed 8/31/2022 11:40 To: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> 1 2 attachments (961 KB) Dutchman NCO021491 Additional Info Req.pdf, 210428-17_624 PPA - VOC.pdf, CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Hi Diana, Thank you for your patience. My answers to your questions are highlighted in red below. Updates to the cadmium data for the 2018-2022 reports are still underway, however, I wanted to submit what I have available so far in the interest of providing you with a timely response. -Please complete and submit this form to meet the latest application requirements for the updated application EPA form 2A enclosed -If there are additional pollutants with certified methods to be reported, please submit this Chemical Addendum none -If there are additional pollutants without certified methods to be reported, please submit the Supplemental Chemical Datasheet (attached) none -Please let me know if there are any changes in the Facility components or plans for expansion The facility has undergone several upgrades since this application was initially sent. If there is any supporting documentation you require, please let me know. -If the Facility has upstream hardness sampling results, please submit them. If not, please collect 5 samples at the upstream of the discharge over the course of a week. We will need those to calculate accurate allowable concentrations for the hardness dependent metals No upstream hardness sampling has been conducted. We will proceed with collecting the 5 samples and will share the results as soon as possible. Please clarify and update the following entry values in the eDMR as needed: -Revise the magnitude or units of measurement for the cadmium results reported in the eDMR from 2018-2022. in progress Copper, silver, and zinc results reported on 4/3/2018 and 7/3/2018. The magnitude reported appears to be mg/I, but was reported in ug/I 04-2018 and 07-2018 reports revised -Revise the priority pollutant analysis (PPA) sampled on 04/28/2021. There were no results for volatile organics in the package submitted associated VOC results enclosed Thank you. Sincerely, Madelyn Mills Mountains/Piedmont Compliance Coordinator Mocksville Office: (984) 365-9160 773 Sanford Ave Mocksville, NC 27028 hftp_://www.envirolinkinc.com From: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Sent: Monday, August 8, 2022 1:45 PM To: Madelyn Mills <mmills@envirolinkinc.com> Cc: Josh Powers <jpowers@envirolinkinc.com>; Todd Robinson <trobinson@envirolinkinc.com> Subject: [External] - Re: [External] - Dutchman.21491- NPDES permit renewal process EXTERNAL EMAIL: Do not click any links or open any attachments unless you trust the sender and know the content is safe. August 31st works. Thank you, Diana Yitbarek (she/her) Engineer T: 919-707-9130 diana.yitbarek@ncdenr.gov From: Madelyn Mills <mmills@envirolinkinc.com> Sent: Monday, August 8, 2022 11:57 To: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Cc: Josh Powers <jpowers@envirolinkinc.com>; Todd Robinson <trobinson@envirolinkinc.com> Subject: Re: [External] - Dutchman.21491- NPDES permit renewal process CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Thank you, Diana. I will be in touch and have this information ready for you as soon as possible. I will be on vacation from August 10th - August 19th, and will be returning on August 22nd. With this being the case, could we aim for a deadline of August 31st? Please let me know whether this works for you. Thank you, Madelyn Mills Mountains/Piedmont Compliance Coordinator Mocksville Office: (984) 365-9160 773 Sanford Ave Mocksville, NC 27028 hftp_://www.envirolinkinc.com 0 EN IROLIN From: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Sent: Monday, August 8, 2022 8:45 AM To: Madelyn Mills <mmills@envirolinkinc.com> Cc: cbitterman@enironlinkinc.com <cbitterman@enironlinkinc.com>; Chip White <cwhite@envirolinkinc.com>; Josh Powers <jpowers@envirolinkinc.com> Subject: [External] - Dutchman.21491 - NPDES permit renewal process EXTERNAL EMAIL: Do not click any links or open any attachments unless you trust the sender and know the content is safe. Good morning, Madelyn Thank you for submitting the December 20, 2018, NPDES permit renewal application. I look forward to working with you to complete this NPDES permit renewal. I will appreciate your support with the following additional/revised information: -Please complete and submit this form to meet the latest application requirements for the updated application EPA form 2A -If there are additional pollutants with certified methods to be reported, please submit this Chemical Addendum -If there are additional pollutants without certified methods to be reported, please submit the Supplemental Chemical Datasheet (attached) -Please let me know if there are any changes in the Facility components or plans for expansion -If the Facility has upstream hardness sampling results, please submit them. If not, please collect 5 samples at the upstream of the discharge over the course of a week. We will need those to calculate accurate allowable concentrations for the hardness dependent metals Please clarify and update the following entry values in the eDMR as needed: -Revise the magnitude or units of measurement for the cadmium results reported in the eDMR from 2018-2022. Copper, silver, and zinc results reported on 4/3/2018 and 7/3/2018. The magnitude reported appears to be mg/I, but was reported in ug/I -Revise the priority pollutant analysis (PPA) sampled on 04/28/2021. There were no results for volatile organics in the package submitted I will set a due date of August 22, 2022. If you need more time, please let me know. Please let me know if you have any questions along the way. Thank you, Diana Yitbarek (she/her) Engineer T: 919-707-9130 diana.yitbarek@ncdenr.gov NPDES Municipal Permitting Unit NC Department of Environmental Quality Division of Water Resources Mailing: 1617 Mail Service Center, Raleigh, NC 27699-1617 Physical: 512 North Salisbury Street, Raleigh, NC 27604 D,�E -,- 1� R *M PI FnwrmmWJ+I CNAft *Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email. We can also be available via Microsoft Teams or other web -based calling services if requested. Thanks for your patience and stay safe. Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. NPDES PERMIT NO.: NCO021491 FACILITY NAME: Dutchman Creek WWTP OWNER NAME: Town of Mocksville GRADE: WW-3 eDMR PERIOD: 03-2020 (March 2020) PERMIT VERSION: 4.0 CLASS: WW-3 ORC: Robert Charles White ORC HAS CHANGED: No VERSION: 1.0 PERMIT STATUS: Expired COUNTY: Davie ORC CERT NUMBER: 1008731 STATUS: Submitted SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 001 NO DISCHARGE*: NO d q E o U A F E d O d O o z O a z Z 50050 00010 00400 50060 C0310 C0610 C0530 31616 00300 Continuous 5 X week 3 X week 2 X week 3 X week 3 X week 3 X week 3 X week 3 X week Recorder Gmb Gmb Gmb Composite Composite Composite Gmb Gmb FLOW TEMP-C pH CHLORINE HOD Cone NH3-N-Cone TSS - Cone FCOLI HR DO 2400 clock Hrs 2400 clock Hrs Y/R/N mgd deg c su ug/I mg/I mg/I mg/1 #/100mt mg/1 1 0715 2.0 Y 0.359 6.2 6.11 38 13.8 2 0645 3.5 Y 0.388 8.5 6.2 < 15 13.2 3 0800 24 0615 2.25 Y 0.437 12.2 7.1 < 15 6.89 < 0.5 < 6.098- 1 11.42 4 0800 24 0715 1.25 Y 0.46 13.9 11.4 < 0.5 8.064 < 1 - 0800 24 0730 1.25 Y 0.429 12.1 8.27 <0.5 18.27 < 1 6 0700 2.0 Y 0.412 10.4 7 0645 1.5 Y 0.355 8 0.345 9 0600 12.5 Y 1 0.382 18.2 1 12.31 10 0600 4.5 Y 0.34 11.5 6.9 8.96 11 0800 24 0630 2.5 Y 0.457 14.1 420 1.79 535 < I 12 0800 24 0700 2.5 Y 0.416 14.7 6.65 < 15 13.8 1.12 20.67 1 9.78 13 0800 24 0630 2.25 Y 0.424 16.6 8.87 <0.5 4.737 19.4 14 0.367 15 0.353 16 10800 24 10700 3.25 1 Y 1 0.394 11.7 6.99 26 9.62 17 0800 24 0615 2.5 Y 0.398 12.2 7.37 18 2.87 < 0.5 5.4 < 1 8.27 18 0800 24 0615 3.0 Y 0.407 12.8 7.42 26 2.37 <0.5 <3.125 <1 11.25 19 0545 6.75 Y 0.396 15 2.13 < 0.5 5.4 < 1 20 0515 6 Y 0.398 17.5 21 0.39 22 0.337 23 0545 2.5 B 0.421 13.7 7.4 20 9.35 24 0800 24 0645 3.25 B 0.477 14.2 7.44 23 6.36 < 0.5 4.545 < 1 9.68 25 0800 24 0720 1.0 Y 1.231 13.1 '.21 18 11.9 < 0.5 17.65 > 2419.6 11.6 26 0800 25 0648 1.0 Y 1.171 13.5 27 0645 13.0 Y 1 0.582 113.9 130.8 <0.5 57.33 1 >2419.6 eft 0.468 29 0.395 30 0645 1.5 Y 0.433 14.4 7.33 19 9.71 31 0800 24 0730 2.5 Y 0.464 15.2 6.81 2 6.07 0.56 4.333 < 1 9.83 Monthly Average Limit: 0.98 10 4 30 200 Monthly Average: 0.460839 12.852174 15.769231 40.902308 0.266923 52.415308 4.048334 10.627143 Daily Maximum: 1.231 17.5 7.44 38 420 1.79 535 2419.6 13.8 Daily Minimum: 0.337 6.2 6.11 0 2.13 0 0 0 8.27 **** No Reporting Reason: ENFRUSE - No Flow-Reuse/Recycle; ENV WTHR - No Visitation - Adverse Weather; NOFLOW - No Flow; HOLIDAY - No Visitation - Holiday NPDES PERMIT NO.: NCO021491 FACILITY NAME: Dutchman Creek WWTP OWNER NAME: Town of Mocksville GRADE: WW-3 eDMR PERIOD: 03-2020 (March 2020) PERMIT VERSION: 4.0 CLASS: WW-3 ORC: Robert Charles White ORC HAS CHANGED: No VERSION: 1.0 PERMIT STATUS: Expired COUNTY: Davie ORC CERT NUMBER: 1008731 STATUS: Submitted SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 001 NO DISCHARGE*: NO (Continue) d q E - o U � A F E d O d O e O U O a z Z C0600 C0665 01027 THP313 01042 01077 01092 Quarterly Quarterly Monthly Monthly Quarterly Quarterly Quarterly Composite Composite Composite Composite Composite Composite Composite TOTAL N - Cone TOTAL P - Cone CADMIUM CER7DCHV COPPER SILVER ZINC 2400 eloek Hrs 2400 eloek Hrs Y/B/N mg/I mg/1 ug/I percent mg/I mg/I mg/I 1 0715 2.0 Y 2 0645 3.5 Y 3 0800 24 0615 2.25 Y 4 0800 24 0715 1.25 Y <0.000, - 0800 24 0730 1.25 Y 6 0700 2.0 Y 7 0645 1.5 Y a 9 0600 2.5 Y 10 0600 4.5 Y 11 0800 24 0630 2.5 Y 12 0800 24 0700 2.5 Y 13 0800 24 0630 2.25 Y 14 15 16 0800 24 0700 3.25 Y 17 0800 24 0615 2.5 Y 18 0800 24 0615 3.0 Y 19 0545 6.75 Y 20 0515 6 Y 21 22 23 0545 2.5 B 24 0800 24 0645 3.25 B 25 0800 24 0720 1.0 Y 26 0800 25 0648 1.0 Y 27 0645 13.0 Y 28 29 30 0645 1.5 Y 31 0800 24 0730 2.5 Y Monthly Average Limit: 5.3 Monthly Average: 0 Daily Maximum: 0 Daily Minimum: 0 **** No Reporting Reason: ENFRUSE — No Flow-Reuse/Recycle; ENV WTHR — No Visitation — Adverse Weather; NOFLOW — No Flow; HOLIDAY — No Visitation — Holiday NPDES PERMIT NO.: NCO021491 FACILITY NAME: Dutchman Creek WWTP OWNER NAME: Town of Mocksville GRADE: WW-3 eDMR PERIOD: 03-2020 (March 2020) PERMIT VERSION: 4.0 CLASS: WW-3 ORC: Robert Charles White ORC HAS CHANGED: No VERSION: 1.0 PERMIT STATUS: Expired COUNTY: Davie ORC CERT NUMBER: 1008731 STATUS: Submitted SAMPLING LOCATION: INFLUENT DISCHARGE NO.: 001 E F E E E F E c_'i - a � C0310 C0530 3 X week 3 X week Composite Composite BOD-Cone TSS - Cone 2400 Hrs mg/I mg11 1 3 0800 24 497 1 T a 10800 24 658 1683 - 0800 24 619 100 6 7 a y 10 11 0800 24 686 182.5 12 0800 24 485 70 13 0800 24 224 23.2 14 15 16 17 0800 24 394 137.8 18 0800 24 340 110.8 19 0800 24 341 63.64 20 21 22 23 24 0800 24 642 164 25 0800 24 305 115.7 26 27 0800 24 170 82.67 2s 29 30 31 0800 24 940 81.18 Monthly Average Limit: Monthly Average: 484 692308 113.214615 Daily Maximum: 940 182.5 Daily Minimum: 170 123.2 **** No Reporting Reason: ENFRUSE — No Flow-Reuse/Recycle; ENV WTHR — No Visitation — Adverse Weather; NOFLOW — No Flow; HOLIDAY — No Visitation — Holiday NPDES PERMIT NO.: NCO021491 FACILITY NAME: Dutchman Creek WWTP OWNER NAME: Town of Mocksville GRADE: WW-3 eDMR PERIOD: 03-2020 (March 2020) COMPLIANCE STATUS: Non -Compliant PERMIT VERSION: 4.0 CLASS: WW-3 ORC: Robert Charles White ORC HAS CHANGED: No VERSION: 1.0 CONTACT PHONE #: 3365498990 PERMIT STATUS: Expired COUNTY: Davie ORC CERT NUMBER: 1008731 STATUS: Submitted SUBMISSION DATE: 04/22/2020 04/22/2020 ORC/Certifier Signature: Chris Bitterman E-Mail:cbitterman@envirolinkinc.com Phone #:252-235-7933 Date By this signature, I certify that this report is accurate and complete to the best of my knowledge. The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment. Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the permittee becomes aware of the circumstances. If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by part II.E.6 of the NPDES permit. 04/22/2020 Permittee/Submitter Signature:*** Chris Bitterman E-Mail:cbitterman@envirolinkinc.com Phone #:252-235-7933 Date Permittee Address: 295 Garwood Rd Mocksville NC 27028 Permit Expiration Date: 06/30/2019 I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of Imes and imprisonment for knowing violations. LAB NAME: Statesville Analytical CERTIFIED LAB #: 440 PERSON(s) COLLECTING SAMPLES: Operators CERTIFIED LABORATORIES PARAMETER CODES Parameter Code assistance may be obtained by calling the NPDES Unit (919) 807-6300 or by visiting http://portal.ncdenr.org/web/wq/swp/ps/npdes/forms. FOOTNOTES Use only units of measurement designated in the reporting facility's NPDES permit for reporting data. * No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR for entire monitoring period. ** ORC on Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204. *** Signature of Permittee: If signed by other than the permittee, then delegation of the signatory authority must be on file with the state per 15A NCAC 2B .0506(b)(2)(D). NPDES PERMIT NO.: NCO021491 FACILITY NAME: Dutchman Creek WWTP OWNER NAME: Town of Mocksville GRADE: WW-3 eDMR PERIOD: 03-2020 (March 2020) Report Comments: PERMIT VERSION: 4.0 CLASS: WW-3 ORC: Robert Charles White ORC HAS CHANGED: No VERSION: 1.0 PERMIT STATUS: Expired COUNTY: Davie ORC CERT NUMBER: 1008731 STATUS: Submitted Returns stopped working causing solids to back up in clarifier causing high BOD and TSS on 3/11, raising the monthly levels. Solids could not be removed right away due to construction traffic. Permit No. NC0021491 NPDES Implementation of Instream Dissolved Metals Standards - Freshwater Standards The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. Therefore, metal limits in draft permits out to public notice after April 6, 2016 must be calculated to protect the new standards - as approved. Table 1. NC Dissolved Metals Water Quality Standards/Aquatic Life Protection Parameter Acute FW, µg/l (Dissolved) Chronic FW, µg/1 (Dissolved) Acute SW, µg/1 (Dissolved) Chronic SW, µg/l (Dissolved) Arsenic 340 150 69 36 Beryllium 65 6.5 --- --- Cadmium Calculation Calculation 40 8.8 Chromium III Calculation Calculation --- --- Chromium VI 16 11 1100 50 Copper Calculation Calculation 4.8 3.1 Lead Calculation Calculation 210 8.1 Nickel Calculation Calculation 74 8.2 Silver Calculation 0.06 1.9 0.1 Zinc Calculation Calculation 90 81 Table 1 Notes: 1. FW= Freshwater, SW= Saltwater 2. Calculation = Hardness dependent standard 3. Only the aquatic life standards listed above are expressed in dissolved form. Aquatic life standards for Mercury and selenium are still expressed as Total Recoverable Metals due to bioaccumulative concerns (as are all human health standards for all metals). It is still necessary to evaluate total recoverable aquatic life and human health standards listed in 15A NCAC 213.0200 (e.g., arsenic at 10 µg/l for human health protection; cyanide at 5 µg/L and fluoride at 1.8 mg/L for aquatic life protection). Table 2. Dissolved Freshwater Standards for Hardness -Dependent Metals The Water Effects Ratio (WER) is equal to one unless determined otherwise under 15A NCAC 02B .0211 Subparagraph (11)(d) Metal NC Dissolved Standard, µg/I Cadmium, Acute WER*{1.136672-[ln hardness](0.041838)} - e^ f0.9151 [In hardness]-3.14851 Cadmium, Acute Trout waters WER*{1.136672-[ln hardness](0.041838)} - e^{0.915I[In hardness]-3.6236} Cadmium, Chronic WER* { 1.101672-[ln hardness](0.041838)} - of 0.7998[ln hardness]-4.4451 } Chromium III, Acute WER*0.316 eA fO.8190[ln hardness]+3.7256} Chromium III, Chronic WER*0.860 e^{0.8190[ln hardness]+0.6848} Copper, Acute WER*0.960 eA fO.9422[ln hardness] - 1. 7001 Copper, Chronic WER*0.960 eA fO.8545[ln hardness] - 1.7021 Lead, Acute WER*{1.46203-[ln hardness] (0. 145712)1 • e 11.273[In hardness]-1.4601 Lead, Chronic WER*{1.46203-[ln hardness](0.145712)1 • of 1.273[ln hardness]-4.705} Nickel, Acute WER*0.998 eA fO.8460[ln hardness]+2.255} Nickel, Chronic WER*0.997 eA10.8460[ln hardness]+0.0584} Page 1 of 4 Permit No. NCO021491 Silver, Acute WER*0.85 • e^{1.72[ln hardness]-6.59} Silver, Chronic Not applicable Zinc, Acute WER*0.978 eA fO.8473[ln hardness]+0.8841 Zinc, Chronic WER*0.986 eA10.8473[ln hardness]+0.8841 General Information on the Reasonable Potential Analysis (RPA) The RPA process itself did not change as the result of the new metals standards. However, application of the dissolved and hardness -dependent standards requires additional consideration in order to establish the numeric standard for each metal of concern of each individual discharge. The hardness -based standards require some knowledge of the effluent and instream (upstream) hardness and so must be calculated case -by -case for each discharge. Metals limits must be expressed as `total recoverable' metals in accordance with 40 CFR 122.45(c). The discharge -specific standards must be converted to the equivalent total values for use in the RPA calculations. We will generally rely on default translator values developed for each metal (more on that below), but it is also possible to consider case -specific translators developed in accordance with established methodology. RPA Permitting Guidance/WOBELs for Hardness -Dependent Metals - Freshwater The RPA is designed to predict the maximum likely effluent concentrations for each metal of concern, based on recent effluent data, and calculate the allowable effluent concentrations, based on applicable standards and the critical low -flow values for the receiving stream. If the maximum predicted value is greater than the maximum allowed value (chronic or acute), the discharge has reasonable potential to exceed the standard, which warrants a permit limit in most cases. If monitoring for a particular pollutant indicates that the pollutant is not present (i.e. consistently below detection level), then the Division may remove the monitoring requirement in the reissued permit. 1. To perform a RPA on the Freshwater hardness -dependent metals the Permit Writer compiles the following information: • Critical low flow of the receiving stream, 7Q10 (the spreadsheet automatically calculates the 1 Q 10 using the formula 1 Q 10 = 0.843 (s7Q 10, cfs) 0.993 • Effluent hardness and upstream hardness, site -specific data is preferred • Permitted flow • Receiving stream classification In order to establish the numeric standard for each hardness -dependent metal of concern and for each individual discharge, the Permit Writer must first determine what effluent and instream (upstream) hardness values to use in the equations. The permit writer reviews DMR's, Effluent Pollutant Scans, and Toxicity Test results for any hardness data and contacts the Permittee to see if any additional data is available for instream hardness values, upstream of the discharge. If no hardness data is available, the permit writer may choose to do an initial evaluation using a default hardness of 25 mg/L (CaCO3 or (Ca + Mg)). Minimum and maximum limits on the hardness value used for water quality calculations are 25 mg/L and 400 mg/L, respectively. If the use of a default hardness value results in a hardness -dependent metal showing reasonable potential, the permit writer contacts the Permittee and requests 5 site -specific effluent and upstream hardness samples over a period of one week. The RPA is rerun using the new data. Page 2 of 4 Permit No. NCO021491 The overall hardness value used in the water quality calculations is calculated as follows: Combined Hardness (chronic) _ (Permitted Flow, cfs *Avg. Effluent Hardness, mg/L) + (s7Q10, cfs *Avg. Upstream Hardness, mg/L) (Permitted Flow, cfs + s7Q10, cfs) The Combined Hardness for acute is the same but the calculation uses the 1Q10 flow. 3. The permit writer converts the numeric standard for each metal of concern to a total recoverable metal, using the EPA Default Partition Coefficients (DPCs) or site -specific translators, if any have been developed using federally approved methodology. EPA default partition coefficients or the "Fraction Dissolved" converts the value for dissolved metal at laboratory conditions to total recoverable metal at in -stream ambient conditions. This factor is calculated using the linear partition coefficients found in The Metals Translator: Guidance for Calculating a Total Recoverable Permit Limit from a Dissolved Criterion (EPA 823-B-96-007, June 1996) and the equation: Cdiss - I Ctow I + { [KPO] [SS(l+a)] [10-6] } Where: ss = in -stream suspended solids concentration [mg/1], minimum of 10 mg/L used, and Kpo and a = constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A list of constants used for each hardness -dependent metal can also be found in the RPA program under a sheet labeled DPCs. 4. The numeric standard for each metal of concern is divided by the default partition coefficient (or site -specific translator) to obtain a Total Recoverable Metal at ambient conditions. In some cases, where an EPA default partition coefficient translator does not exist (le. silver), the dissolved numeric standard for each metal of concern is divided by the EPA conversion factor to obtain a Total Recoverable Metal at ambient conditions. This method presumes that the metal is dissolved to the same extent as it was during EPA's criteria development for metals. For more information on conversion factors see the June, 1996 EPA Translator Guidance Document. 5. The RPA spreadsheet uses a mass balance equation to determine the total allowable concentration (permit limits) for each pollutant using the following equation: Ca = (s7Q10 + Qw) Cwgs) — (s7Q10) (Cb) Qw Where: Ca = allowable effluent concentration (µg/L or mg/L) Cwqs = NC Water Quality Standard or federal criteria (µg/L or mg/L) Cb = background concentration: assume zero for all toxicants except NH3* (µg/L or mg/L) Qw = permitted effluent flow (cfs, match s7Q10) s7Q10 = summer low flow used to protect aquatic life from chronic toxicity and human health through the consumption of water, fish, and shellfish from noncarcinogens (cfs) * Discussions are on -going with EPA on how best to address background concentrations Flows other than s7Q10 may be incorporated as applicable: 1Q10 = used in the equation to protect aquatic life from acute toxicity Page 3 of 4 Permit No. NC0021491 QA = used in the equation to protect human health through the consumption of water, fish, and shellfish from carcinogens 30Q2 = used in the equation to protect aesthetic quality The permit writer enters the most recent 2-3 years of effluent data for each pollutant of concern. Data entered must have been taken within four and one-half years prior to the date of the permit application (40 CFR 122.21). The RPA spreadsheet estimates the 95th percentile upper concentration of each pollutant. The Predicted Max concentrations are compared to the Total allowable concentrations to determine if a permit limit is necessary. If the predicted max exceeds the acute or chronic Total allowable concentrations, the discharge is considered to show reasonable potential to violate the water quality standard, and a permit limit (Total allowable concentration) is included in the permit in accordance with the U.S. EPA Technical Support Document for Water Quality -Based Toxics Control published in 1991. 7. When appropriate, permit writers develop facility specific compliance schedules in accordance with the EPA Headquarters Memo dated May 10, 2007 from James Hanlon to Alexis Strauss on 40 CFR 122.47 Compliance Schedule Requirements. The Total Chromium NC WQS was removed and replaced with trivalent chromium and hexavalent chromium Water Quality Standards. As a cost savings measure, total chromium data results may be used as a conservative surrogate in cases where there are no analytical results based on chromium III or VI. In these cases, the projected maximum concentration (95th %) for total chromium will be compared against water quality standards for chromium III and chromium VI. 9. Effluent hardness sampling and instream hardness sampling, upstream of the discharge, are inserted into all permits with facilities monitoring for hardness -dependent metals to ensure the accuracy of the permit limits and to build a more robust hardness dataset. 10. Hardness and flow values used in the Reasonable Potential Analysis for this permit included: Parameter Value Comments (Data Source) Average Effluent Hardness (mg/L) [Total as, CaCO3 or (Ca+Mg)] 40.8 Data provided in PPAs Average Upstream Hardness (mg/L) [Total as, CaCO3 or (Ca+Mg)] 25 Default value 7Q10 summer(cfs) 2.5 NPDES Files 1Q10 (cfs) 2.09 Calculated in RPA Permitted Flow (MGD) 0.98 NPDES permit application Date: 8/05/2022 Permit Writer: Diana Yitbarek Page 4 of 4 �.D r, 00 rn rn ri ri ri O N \ \ OA dA i i i O O O N N N OA dA dA Ln co co co I� N N N r-I m Q Q Q =3 = J Q Q Q LU co cr \ \ \ i 00 Ln 4zll O m z J U Q O O D z z O O J CDLO a o i LU N O J LU m H II II \ ) LUO co Li Cf D i U cr- a N Ln Ln Ln m J \00 ; � c N N r-I r-I r-I l0 v m z c ryi N \ LU r I d J CO OA co > c � Ln II O i N C� 11 s u Cf-0 v v v d 0 Lu c � c-I � r, 00 rn E O r-I r-I r-I m z O N O N O N O N O N z a- \ \ \ \ \ Ol Ln Ln r-I O ate, i 4� r-I N N r-I m N m d L - \ O co O 00 H 1C5LO M 0 rn co N V� � uo � CL db dL Q C 7 dA J scn COc LU c u Q N O1 (B � o 0 O .o � U (6 o U o Cl) E 0000 O C) O d N (B 0 O Q N oO o C � O C 7 O m U N N O N 00 C L co o Z N O I� o Q E J z O > m E N � L� n r _ O d CV LU O O 0 z o 0 Z_ 0' E E c 0 Z Z — O L LaL W a z O Q O F. 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E C C � C � C � � �p U U (D (D (D (D (D 0C)p Cp Cp C O O OO O O O O O O D U U U U U U}U} z U QU QU QU N U N U N U Q Q Q Q Q Q ° z s° s° s° 0 0 0 aEi aEi aEi aEi aEi aEi c c c c c c c c c c c c c c c c a� a� a� a� D D D D D D D D D D EE - EE 4-- w W W W W W W W W -S� W W W W W W O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O 0) 0) 0) 0) 0) 0) 0) 00 0) 0) 0) O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N N N N N N N N N N N N N N N N I- M 0) M 0) 00 I- 1` 1` Lco:) O O O O O O O O O I i ❑ O .O � U N o U o M E 0000 O O O d N N 0 L, .r- o in U CD c O M O_ 0 0 C � O C 7 O fy m U CV CV O CV 00 C L O U) o Z N O ti o Q E J O z i m N N � d O d CV LU C] C] 0 z o 0 Z_ 2 E E c o a)z Z o LL J U LaL o > O w Q w J D D J U j Q U H J LL w O j H Q z w } U z W D a W w LL z O w Q ~ J Q O❑ w W w W a N O z LL rn N > O w Q w J D D J U j Q U H J LL w O j H Q z w } U Y z W N D 3 W x w LO LL z O N H F Q O 0 ❑ C 0 6 N j -0 W > W N 23) 5 m U a a� Q E r z c O D Q W O J Q LL H O O c o O z 0 0 af af N > OF d o t ZOW O � O z O a� N U O d E 00 N N 0 0 0 N 0 United States Environmental Protection Agency Form Approved. EPA Washington, D.C. 20460 OMB No. 2040-0057 Water Compliance Inspection Report Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCS) Transaction Code NPDES yr/mo/day Inspection Type Inspector Fac Type 1 IN 1 2 15 I 3 I NC0021491 I11 121 22/05/12 I17 18 n 19 L G j 201 21111111111111111111111111111111111111111111 f6 Inspection Work Days Facility Self -Monitoring Evaluation Rating B1 CA ---------------------- Reserved ------------------- 67 I 71 I I 72 L n, � 73 LLI74 71 I I I I I I I80 70 Iu ty LJ Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include Entry Time/Date Permit Effective Date POTW name and NPDES permit Number) 10:OOAM 22/05/12 14/11/01 Dutchman Creek WWTP 295 Garwood Rd Exit Time/Date Permit Expiration Date Mocksville NC 27028 11:30AM 22/05/12 19/06/30 Name(s) of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) Other Facility Data Dennis W Murdock/ORC/828-238-4659/ Name, Address of Responsible Official/Title/Phone and Fax Number Contacted Kenneth W Gamble,171 S Clement St Mocksville NC 27028/Town of Manager/336-751-9187/ No Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Permit 0 Flow Measurement Operations & Maintenar 0 Records/Reports Facility Site Review Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) of Inspector(s) Agency/Office/Phone and Fax Numbers Date Gary Hudson DWR/Division of Water Quality/336-776-9694/ Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete. Page# NPDES yr/mo/day Inspection Type 31 NCO021491 I11 12I 22/05/12 117 18 ICI Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) *The current permit expired on 06/30/2019. A permit renewal application was submitted in 2018 but was put on hold by Raleigh. *Mr. Murdock does a very good job with regards to keeping records. *The flow meter was calibrated on March 10, 2022. *The new secondary clarifiers were clean and operating properly. *The WWTP appeared to be well operated and maintained. No discrepancies were noted during the inspection. Page# Permit: NCO021491 Owner - Facility: Dutchman Creek WWTP Inspection Date: 05/12/2022 Inspection Type: Compliance Evaluation Permit Yes No NA NE (If the present permit expires in 6 months or less). Has the permittee submitted a new 0 ❑ ❑ ❑ application? Is the facility as described in the permit? ❑ ❑ 0 ❑ # Are there any special conditions for the permit? ❑ ❑ ❑ Is access to the plant site restricted to the general public? 0 ❑ ❑ ❑ Is the inspector granted access to all areas for inspection? 0 ❑ ❑ ❑ Comment: The current permit expired on 06/30/2019. A permit renewal application was submitted in 2018 but was out on hold by Raleiah. Record Keeping Yes No NA NE Are records kept and maintained as required by the permit? 0 ❑ ❑ ❑ Is all required information readily available, complete and current? 0 ❑ ❑ ❑ Are all records maintained for 3 years (lab. reg. required 5 years)? 0 ❑ ❑ ❑ Are analytical results consistent with data reported on DMRs? 0 ❑ ❑ ❑ Is the chain -of -custody complete? 0 ❑ ❑ ❑ Dates, times and location of sampling Name of individual performing the sampling Results of analysis and calibration Dates of analysis Name of person performing analyses Transported COCs Are DMRs complete: do they include all permit parameters? ❑ ❑ ❑ Has the facility submitted its annual compliance report to users and DWQ? ❑ ❑ ❑ (If the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified ❑ ❑ ❑ operator on each shift? Is the ORC visitation log available and current? ❑ ❑ ❑ Is the ORC certified at grade equal to or higher than the facility classification? ❑ ❑ ❑ Is the backup operator certified at one grade less or greater than the facility ❑ ❑ ❑ classification? Is a copy of the current NPDES permit available on site? 0 ❑ ❑ ❑ Facility has copy of previous year's Annual Report on file for review? 0 ❑ ❑ ❑ Comment: Mr. Murdock does a very good iob with regards to keeping records. Flow Measurement - Effluent Yes No NA NE Page# 3 Permit: NCO021491 Owner - Facility: Inspection Date: 05/12/2022 Inspection Type: Dutchman Creek WWTP Compliance Evaluation Flow Measurement - Effluent Yes No NA NE # Is flow meter used for reporting? 0 ❑ ❑ ❑ Is flow meter calibrated annually? 0 ❑ ❑ ❑ Is the flow meter operational? 0 ❑ ❑ ❑ (If units are separated) Does the chart recorder match the flow meter? ❑ ❑ ❑ Comment: The flow meter was calibrated on March 10, 2022 Aeration Basins Yes No NA NE Mode of operation Ext. Air Type of aeration system Surface Is the basin free of dead spots? 0 ❑ ❑ ❑ Are surface aerators and mixers operational? 0 ❑ ❑ ❑ Are the diffusers operational? ❑ ❑ 0 ❑ Is the foam the proper color for the treatment process? 0 ❑ ❑ ❑ Does the foam cover less than 25% of the basin's surface? 0 ❑ ❑ ❑ Is the DO level acceptable? ❑ ❑ ❑ Is the DO level acceptable?(1.0 to 3.0 mg/1) ❑ ❑ ❑ Comment: The aeration basin appeared to be operating properly. Secondary Clarifier Yes No NA NE Is the clarifier free of black and odorous wastewater? 0 ❑ ❑ ❑ Is the site free of excessive buildup of solids in center well of circular clarifier? 0 ❑ ❑ ❑ Are weirs level? 0 ❑ ❑ ❑ Is the site free of weir blockage? 0 ❑ ❑ ❑ Is the site free of evidence of short-circuiting? 0 ❑ ❑ ❑ Is scum removal adequate? 0 ❑ ❑ ❑ Is the site free of excessive floating sludge? 0 ❑ ❑ ❑ Is the drive unit operational? 0 ❑ ❑ ❑ Is the return rate acceptable (low turbulence)? 0 ❑ ❑ ❑ Is the overflow clear of excessive solids/pin floc? 0 ❑ ❑ ❑ Is the sludge blanket level acceptable? (Approximately'/4 of the sidewall depth) ❑ ❑ ❑ Comment: The new secondary clarifiers were clean and operating properly. Operations & Maintenance Yes No NA NE Page# 4 Permit: NCO021491 Owner - Facility: Dutchman Creek WWTP Inspection Date: 05/12/2022 Inspection Type: Compliance Evaluation Operations & Maintenance Yes No NA NE Is the plant generally clean with acceptable housekeeping? 0 ❑ ❑ ❑ Does the facility analyze process control parameters, for ex: MLSS, MCRT, Settleable ❑ ❑ ❑ Solids, pH, DO, Sludge Judge, and other that are applicable? Comment: The WWTP appeared to be well operated and maintained. No discrepancies were noted during the inspection. Page# 5 United States Environmental Protection Agency Form Approved. EPA Washington, D.C. 20460 OMB No. 2040-0057 Water Compliance Inspection Report Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCS) Transaction Code NPDES yr/mo/day Inspection Type Inspector Fac Type 1 IN 1 2 15 I 3 I NC0021491 I11 121 22/08/01 I17 18 I D I 19 L G j 201 21111111111111111111111111111111111111111111 f6 Inspection Work Days Facility Self -Monitoring Evaluation Rating B1 CA ---------------------- Reserved ------------------- 67 70 �� LJ � 71 I tyI 72 L Ln, � 73LLI74 71 J 1 1 1 1 L L j80 Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include Entry Time/Date Permit Effective Date POTW name and NPDES permit Number) 09:55AM 22/08/01 14/11/01 Dutchman Creek WWTP 295 Garwood Rd Exit Time/Date Permit Expiration Date Mocksville NC 27028 11:16AM 22/08/01 19/06/30 Name(s) of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) Other Facility Data Name, Address of Responsible Official/Title/Phone and Fax Number Contacted Kenneth W Gamble,171 S Clement St Mocksville NC 27028/Town of Manager/336-751-9187/ No Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Pretreatment Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) of Inspector(s) Agency/Office/Phone and Fax Numbers Date Alex Lowe DWR/WSRO WQ/336-776-9689/ Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete. Page# NPDES yr/mo/day Inspection Type (Cont.) 31 NCO021491 I11 12I 22/08/01 117 18 I p Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) On August 1, 2022, Alex Lowe of the DWR Winston-Salem Regional Office conducted a routine pretreatment compliance inspection of the Town of Mocksville's pretreatment program, as run by Envirolink, Inc. Piedmont -Metro Area Manager Josh Powers was present throughout the inspection to assist Mr. Lowe. Mocksville's pretreatment program elements were all up to date and available for review. The headworks analiysis submitted to the State in January 2022 is still under review. The next assigned update for any pretreatment program element is the industrial waste survey, which is due on June 30, 2024. This program consists of only one SIU, Brakebush Bros. Inc, which is a chicken cooking and packaging facility. A review of the SIU files indicates that Brakebush has had some compliance concerns in the past 12 months, with repeated violations of both flow and BOD. Monthly monitoring reports are submitted by the SIU to Envirolink in an effort to ensure compliance, and all of these records were available for review upon inspection. The most recent six month period showed three violations, two in March and one in April 2022. A Notice of Violation was assigned for each of these exceedences. Records for this program were properly maintained and well organized. No instances of permit non-compliance were uncovered during this inspection. This program is considered satisfactory. Page# Permit: NC0021491 Inspection Date: 08/01/2022 Owner - Facility: Dutchman Creek WWTP Inspection Type: Pretreatment Compliance Yes No NA NE Page# Analytical Results Town of Mocksville-Envirolink 771 Sanford Ave Mocksville, NC 27028 Receive Date: 10/05/2021 Reported: 10/28/2021 For: Dutchman FATHEAD TOX Comments: Sample Number Parameter Sample ID Result 211005-39-01 Chronic Toxicity Respectfully submitted, X�- � � " �-' J, 1�1� Melissa Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 Eff-TOX-FH >100 4 STATESVILLE ANALYTICAL Unit Method Analyzed Analyst ca day 10/05/2021 MT PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 20 Effluent Toxicity Report Form -Chronic Fathead Minnow Multi -Concentration Test Date:10/18/2021 Facility: Dutchman NPDES # NC00 21491 Pipe* 001 County: Davie Laboratory: Meritech, Inc. (Lab #NCO27) Comments x Signature of Operator in Responsib e,Charge/Email Address/Phone Number X J-�z- Signature of Laboratory Supervisor MAIL ORIGINAL TO: Water Sciences Section Aquatic Toxicology Branch Division of Water Resources 1621 Mail Service Center Raleigh, N.C. 27699-1621 Test Initiation Daterrime 10/5/2021 3:27 PM % Eff. Repl. 1 2 3 Control Surviving # Original # WUoriginal (mg) F-F2-5-1 Surviving # Original # Wt/original (mg) 8.5 1Surviving # Original # Wt/original (mg) F-77--1 Surviving # Original # Wt/original (mg) F__7_4_1 Surviving # Original # WUoriginal (mg) Avg WUSurv. Control 0.748 4 10 10 9 9 10 10 10 10 0.751 0.675 0.762 0.648 8 9 10 10 10 10 10 10 0.628 0.645 0.710 0.637 9 9 10 10 10 10 10 10 0.522 0.641 0.648 0.653 8 10 10 10 10 10 T0.635 Wo 0.681 0.735 10 10 10 9 10 10 10 10 0.886 0.578 1 0,755 0.678 F-TO07 Surviving # Original # WUoriginal (mg) Water Quality Data Control 0 1 2 pH (SU) [nit/Fin DO (mg/L) IniUFin Temp (C) Init/Fin High Concentration 0 1 2 pH (SU) Init/Fin DO (mg/L) Init/Fin Temp (C) IniUFln Sample 1 2 3 Collection Start Date Grab Composite (Duration) Hardness (mg/L) Alkalinity (mg/L) Conductivity (umhos/cm) Chlorine(mg/L) Temp. at Receipt (°C) Day % Survival 95.0 Avg Wt (mg) 0.709 % Survival 92.5 Avg Wt (mg) 0.655 % Survival 95.0 Avg Wt (mg) 0.616 % Survival 92.5 Avg Wt (mg) 0.702 % Survival 97.5 Avg Wt (mg) 0.724 % Survival 97.5 Avg Wt (mg) 0.696 3 4 5 6 Test Organisms i- Cultured In -House i_ Outside Supplier Hatch Date: 10/4/21 Hatch Time: 4:00-5:00pm 7.83 17.52 7.91 / 7.64 7.77 1 7.57 7.73 1 7.81 7,85 / 7.86 7.95 1 7.68 7.83 / 7.38 7.53 1 7.30 8.00 1 7.39 7.28 16.86 7.51 17.57 7.87 17.85 8.16 1 7.34 8.01 16.26 24.3 / 25.0 24.0 / 24.4 24.2 / 24.7 24.0 / 24.5 24.2 I 24.1 24.2 / 24.3 24.1 / 24.3 3 4 5 6 6.99 17.51 7.06 1 7.57 7.24 1 7.61 7.34 17.85 7.49 1 7.89 T61 1 7.63 7.55 / 7.62 7.37 1 7.59 7.60 / 7.01 7.51 16.61 7.62 17.44 7.74 1 7.90 8.04 / 6.99 8.15 1 6.65 25.1 124.8 25.0 124.7 25.2 ! 24.4 24.1 124.5 25.0 1 24.6 24.1 124.0 24.7 124.7 10/4/2021 10/6/2021 10/7/2021 24.0 24.0 24.0 42 46 46 56 61 59 856 899 947 <0.1 <0.1 <0.1 1.6 1.6 1.1 Dilution H2O Batch # 1602 1603 1604 E42 Hardness (mg/L) 44 44 44 Alkalinity (mg/L) 33 32 31 Conductivity (umhos/cm) 157 155 160 Survival Growth Overall Result Normal F,I rl ChV >100 Hom. Var. j+l 1711 NOEC 100 100 LOEC >100 >100 ChV >100 >100 Method Dunnett's Dunnell's Stats Survival Growth Cone. Critical Calculated Critical Calculated 9.25 2,41 0.5 2.41 1.0581 18.5 2.41 0 2.41 1.8223 37 2.41 0.5 2.41 0.1323 74 2.41 -0.5 2.41-0.2988 100 2.41 -0.5 2.41 0.2645 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 20 10 10 9 10 10 10 10 10 0.764 0.711 0.650 0.657 2 / / Dj a k R 7 0 k § / ( i PO Bo 228e Statesville, Nc 28687. 70 / 72 4 97 Page aym A ER/ TEC"r /NC'_ ENVIRONMENTAL LABORATORIES A Oivlsion of Wotan tech —logy and C—t,01S, InC. Chemical and Physical Determinations Client: Dutchman NPDES#: 0021491 Start Date: 10/5/21 End Date: 10/12/21 Concentration: control 0-1 1-2 1 2-3 3-4 4-5 5-6 6-7 Remarks Soft Synthetic FBelch : Batch N : 0a 71� ( V v L J n s - I l/ pH: Initial 7, i 7 7� 7, 7 �7 �iti `(. Cl 7, 3 Final ?, J 2 `l. Q LA 7,77 7 1. Ac ; D.O.: 7, S -7 % `il . l Final 7 :C 2.3CI Tem .: Initial Final ,-L1. 'f Conductivity: Initial is 15-7 j61 Final i I%. 1-7 Residual Chlorine: LU ,i ' u I %' 0. I . l ! v 2 C: q t Hardness: Alkalinity: ) Concentration: 9.25% 0-1 1-2 2-3 3-4 4-5 5-6 6-7 Remarks pH: Initial -7, �rGd ) 7.F1 Final 7,57 — '; 7dd 7d D.O.: Initial % 7, %, a 78 Final 7, q L -7. J 7•20 C, fu 6.F�q I ct h Temp.: Initial Final dj. rT�• aH,I �i- 1'-).1 i �H Zy.3 �Q-)G 1''� Conductivity: Initial Final Residual Chlorine: �3 L 0, I c`�I Z- 0• I �4 0, t Z 0, t Z 0. 6 2� t U: f. `� �=U ; Concentration: 18.5% 0-1 1-2 2-3 3-4 4-5 5-6 6-7 Remarks pH: Initial _7.�3 7. � 5 7rU 77 : 2 .TI , 1,'7 Final 7. i,Q �. �, rj 9 `�. ./�y� r i `i D.O.: Initial -7i �{ li 7, 2 7, Y6 -7 h 2 . �:?; H•� E Final 7 2 5 `7, G Ld rh34� 6.V 7sV i � 3 2 �C' t Temp.: Initial L�. 4 '� L. 0 Do Final �•) �'ti;'1 �� ,v 1. 24,Y ,� Conductivity: Initial ? 5 3 ��..�j A 3 12 Final � Q 3 i I' 31 3 3 3�-- Residual Chlorine: ! 0 . i. 1_. 0 . <-t, . t r „ I. `- (; • 1 U . t t 1 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 4 of 20 MER/TECH /NC_ —J q ENVIRONMeNTAL LA BORA70RIE5. Chemical and Physical Determinations Client: Dutchman NPDES#: 0021491 Start Date: 10/5/21 End Date: 10/12/21 r.Mr Page 2 of 2 Concentration: 37% 0-1 1-2 2-3 3-4 4-5 5-6 6-7 Remarks pH: Initial Final ,at 7,66 7,'2 5 � • 5 7 7, y '7, (;0 7, S2 c 6 r 'd �' -T �� �) 7,69 `? 45' D.o.: Initial -7, 7. 0 7+L <� 7. 5- 7, 7 " .. c, 1 C 6 Final 7, �], I `i 6,67 7L '�_6 -1, R O 7 T � (, � 1 Temp.:Initial Final )L4. � 1`{, te, � i , a � �ii 2-1(,j :2 'D Conductivity: Initial I 40 3S (AC,3 4SU y 39 Final ' 1 9 yH7 `f.57 4 TA 1 y Residual Chlorine: x-O:1 /_& , q '` t' .p 1 Concentration: 74% 0-1 1-2 2-3 3-4 4-5 5-6 6-7 Remarks pH: Initial () 7 r 7� 7? �, 3 ' 1r a 7' Final 7,, -7 1.5 7, 5-7 %, 4 `1 ';i 7, "!f 7. ?� D.O.: Initial -7, ��� 7, ? ' i';_, 7, S.5 `� ^' s ! i U Final , cf (,� .�j �+ { . 7C % %. Temp.: Initial { ] U t t 5 ri `i . U .� '� `• 5 Final } ,'� ' qji 4-46(' Conductivity: Initial (g 31,, (o o '�'� '1 I 7 Final Qel (P -7 Residual Chlorine: i G,{ 4-0. 1 �� 1 0 .1 V t U •1 ILL k Concentration: 100% 0-1 1-2 2-3 3-4 4-5 5-6 6.7 Remarks pH: Initial %- 72 -'3 1( - v7 ii { 7, $ Final 7, 5 "7 7, b l - -TV 7, 63 1 W D.O.: Initial �j 160 -7'51 7r(,2 �, ," ?, 01 8.1S Final 7,Jrq -7.Gt 6,6( (' 6.�,f I � (.'� Tem .: Initial �,, 0 , 5 2 �{ . � 0 2 �' L Final �' 1, 1.� l .'} . "' 2 6 J t1 t 1 Conductivity: Initial g(o y � ((l 2 q � �,� °1 '> U Final O 1 -/1lL4 9l (GU q 5' Residual Chlorine: Hardness: Alkalinity: 5 �) PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 5 of 20 MERITECH, INC. Mortality Data: Chronic Fathead Test Client: Dutchman NPDES#: 0021491 Start Date: 10/5/21 End Date: 10/12/21 Concentration Control Tuesday Wednesday Thursday Friday Saturday Sunday Monday Rep A 0 Rep B 0 Rep 0 U s- Rep D 0 Concentration 9.25% Tuesday Wednesday Thursday Friday Saturday Sunday Monday Rep A 0 Rep B 0 4'_ Rep C 0 L Rep D 0 V , l 0 Concentration 18.5% Tuesday Wednesday Thursday Friday Rep A 0 Rep B 0 Rep C 0 O Rep D 0 Saturday Sunday Monday v Tuesday 6 Tuesday Tuesday -- ) - a PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 6 of 20 MERITECH, INC. Mortality Data: Chronic Fathead Test Client: Dutchman NPDES#: 0021491 Start Date: 1015/21 End Date: 10/12/21 Concentration 37% Tuesday Wednesday Thursday Friday Saturday Sunday Monday Tuesday Rep A 0 ll0 Rep B 0 V Rep C 0 Rep D 0_-- Concentration 74% Tuesday Wednesday Thursday Friday Saturday Sunday Monday Tuesday Rep A 0 c_ `r Rep B 0_ Rep C 0 Rep D 0 Concentration 100% Tuesday Wednesday Thursday Rep A 0 Rep B 0 k Rep C 0_ Rep D 0 V Friday Saturday Sunday Monday —T�— Tuesday PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 7 of 20 MER/TECH, //VC_ ^ ENVRONMENTAL LABORATORIES Iwo A OiYWj—In cJ W. r- TechnnloJy —a C.—IS, mc- FISH LARVAL SURVIVALIGROWTH DATA SHEET CHRONIC FATHEAD MINNOW Facility: Dutchman Page: 1 of 2 NPDES #: 0021491 Outfall: Date of Test: 10/5/21 Initial weights taken on: by: Ln/ Organism: Pime hales promelys Final weights taken on: -- by: Blank Pan: Initial Weight: Final Weight: 2 -7. - Difference: Qi CONC REP PAN WT. (mg) PAN + ORG. WT. (mg) WT. OF ORG. (mg) # ORG. MEAN WTJORG. (mg) SURV % A 7 "7'; I �I�j 7, D E613, A 1,766,q 9.25% o Ba. r, ��� c�,615 �. G �37, �� , 7 /0 C> o. '20 0 2 D ' o �.3 10 o, 3`7 13 D PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 8 of 20 MERI TECH, INC. ENVIRONMENTAL LABORATORIES A Dil sion of water Tech-119y and Controls, /n FISH LARVAL SURVIVALIGROWTH DATA SHEET CHRONIC FATHEAD MINNOW Facility: Dutchman NPDES #: 0021491 Date of Test: 10/5/21 Page: 2 of 2 Outfall: Initial weights taken on: 'o�-, by: L✓ Organism: Pimephales promelas Final weights taken on: —/L� L by: CONC REP PAN WT. (mg) PAN + ORG. WT. (mg) WT. OF ORG. (mg) # ORG. MEAN WTJORG. (mg) SURV % e 37% '� 7C;� —7, �� is � 0 7_.. D A r( ?5q qq , l 1 c> aI g F'� Z q q, Z2g, G., I r 5� 7 Zoo 74% D 9-3q, q6, 9 &-77 oI A �'3 I , I �� , D '-T 16 L. 10 C>, 7, 00% C 6, OQ Ell, �, _ i 6, ),5o D I , 0I6 ! U 61 6 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 9 of 20 MERITECH, INC. (Lab #027) Meritech Sample ID M Bloassay Sample Chain of Custody 642 Tamco Rd, Reidsville NC 27320 Phone: 1.336-342.4748 Fax:1-336-342-1522 Toxicity Supervisor email: mike.reed0meritechtabs.com Web Site: www.maritechiabs.com CLIENT INFORMATION Client: POP Contact Person: NPDES#: NC falya 1 T Address: Phone: City: Pipe #: DO 1 County: State: Zip: SAMPLE INFORMATION Sample Site: Sample Type: ❑ Grab Composite # of containers: Sampling Time: Start Date: Li Start Time: ry� n FAM PM End Date: End Time: Olt, PM —Triple rinse sample container with sample before filling completely with NO AIRSPACE. Pack the sample cooler completely with ice. The sample must be <0.6°C upone receipt at Meritech— Collector's Name: Print: �SSWL O� Signa re: TOXICITY TEST INFORMATION Test Required: ❑ Chronic (7 days) Test Organism: ❑ Ceriodaphnla dubla (water flea) ❑ Acute (24-48 hours) 'Pimephates prometas (fathead minnow) ❑ Mysidopsis bahia (mysid shrimp) IWC: % —Friday Samples for Chronic Fathead test must be collected after 9:00 a.m. on Friday — Comments: Comments: OQCl QS—' IPPING INFORMATION jjq 1 Relinquished by. Date: Time: JIVJ����1111�I c A PM Received by: Date: O / Time: 1/AM P Relinquished by: Date: Time: cam. K AM PM Received by: Date: Time: AM 16f Relinquished by: Date: Time: AM PM Received by: Date: Time: AM PM Relinquished by: Date: Time: AM PM Received by: Date: Time: AM PM Sample Temperature CC): Method of Shipment: ❑ UPS ❑ Fed EX ❑ Meritech Pick-up ❑ Delivered ❑ Other " Samples shipped on Friday must be FedEx and must be clearly labeled for Saturday delivery, NO SIGNATURE REQUIRED " SAMPLE RECEIVING (Laboratory Use Only /finl Relinquished by: ! 4r �(/� ! (" / C /1' 4 Received by: l�A�1rl n(`rIIJ Date: 10r - 2> T�t Time: AM i Sample Temperatures CC): 6 1 1,6 ! ! Sample Condition: WHITE = Laboratory coov YELLOW = Client cony PO Box 228 a Statesville, NC 28687 a 704/872/4697 Page 10 of 20 MERITECH, INC. (Lab #027) Meritech Sample Sloassay Sample Chain of Custody 642 Tamco Rd, Reidsville NC 27320 Phone: 1-336-342-4748 Fax:1-336-342-1522 Toxicity Supervisor email: m-ike.reed@meritecch-I-abs.com Web Site: www.morit-echiabs.com CLIENT INFORMATION Client: l�stli 1 �t �( PO#: Contact Person: T NPDES#: NC Address: Phone: City: Pipe #: County: State: Zip: Sample Site: L,, Sample Type: ❑Grab Composite SAMPLE INFORMATION # of containers: Sampling Time: Start Date: v b all Start Time: na'iaO A PM End Date: Ali r71 End Time:Klac AM PM Triple rinse sample container with sample before filling completely with NO AIR SPACE, Pack the sample cooler completely with ice. The sample must be <0.6°C upone receipt at Meritech"* Collector's Name: Print: �haoSignatur -cam TOXICITY TEST INFORMATION Test Required: ❑ Chronic (7 days) Test Organism: ❑ Cer' aphnia dubia (water flea) El Acute (24-48 hours) imephales promelas (Fathead minnow) ❑ Mysidopsis bahia (mysid shrimp) IWC: % —Friday Samples for Chronic Fathead test must be collected after 9:00 a.m. on Friday — Comments: ��� G� �( k -- T SHIPPING INFORMATION Relinquished by4� Dale: Time: PM Received by: Date: Time: PM Relinquished by: Date: /,9 Time: `AA�M/�PIOf� Received by: or Date: Time: AM PM Relinquished by: Date: Time: AM PM Received by: Date: Time: AM PM Relinquished by: Date: Time: AM PM Received by: Date: Time: AM PM Sample Temperature (°C): Method of Shipment:❑ UPS ❑ Fed EX [71 Meritech Pick-up []Delivered ❑ Other " Samples shipped on Friday must be FedEx and must be clearly labeled for Saturday delivery, NO SIGNATURE REQUIRED " SAMPLE RECEIVING (Laboratory Use Only) Relinquished by: /' /` ( Time: 7 Received by:���v Date: 1 t� ` � / � AM PM Sample Temperatures (°C): L,— /-•J-I-hI—/ / Sample Condition: WHITF o I rn VFI 1 r1W a raia f rnnv PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 11 of 20 MERITECH, INC. (Lab #027) Meritech Sample I Il J 0 C Bloassa) Sam le Chain of Custody 642 Tamco Rd, Reidsville NC 27320 Phone: 1-336-342-4748 Fax:1-336-342-1522 Toxicity Supervisor email: mike.reedOmerltechiabs.com Web Site: www.meritechiabs.com \ CLIENT INFORMATION Client: i�t'+n PO#: Contact Person: NPDES#: NC Address: Phone: 0j -I-X35 V-I City: _ Pipe A County: State: Zip: SAMPLE INFORMATION Sample Site: (e Sample Type: ❑ Grab n4composile # of containers: L i� ovu Sampling Time: Start Date: Start Time: PM End Date: End Time:12ity AM PM i DO Triple rinse sample container with sample before filling completely with NO AIR SPACE. Pack the sample cooler completely with ice. The sample must be <0.6°C upone receipt at Meritech— Collector's Name: Print: / d�C� lr�y f�,iySo N Signature: TOXICITY TEST INFORMATION Test Required: ❑ Chronic (7 days) Test Organism: ❑ Ce ' aphnla dubia (water flea) ❑ Acute (24 48 hours) Plmephales promotes (fathead minnow) ❑ Mysialopsis bahia (mysid shrimp) IWC: % —Friday Samples for Chronic Fathead test must be collected after 9:00 a.m. on Friday— Comments: SHIPPING INFORMATION Relinquished by: V ram^ Date: t> Time: (A PM Received by: J Date: / y Time: 7 AM PM Relinquished b�' Date: / CJ Time: _7/�� AM 1-6 Received by: Date: Time: AM PM Relinquished by: Date: Time: AM PM Received by: Date: Time: AM PM Relinquished by: Date: Time: AM PM Received by: Date: Time: AM PM Sample Temperature (°C): Method of Shipment:❑ UPS ❑ Fed EX ❑ Meritech Pick-up ❑Delivered ❑ Other Samples shipped on Friday mull be FedEx and must be clearly labeled for Saturday delivery, NO SIGNATURE REQUIRED " A I� SAMPLE RECEIVING (Laboratory Use Only► Relinquished by: Alf, C ('/�i„�� t t� Received by: b u qy, - Date: Time: c AM �M Sample Temperatures (°C): f e 1 L 1 }'ti 1 Sample Condition: F 1 UruITG - I �M—r,,.., rnrw VFI 1 rlW = Clinnt rnnv PO Box 228 e Statesville, NC 28687 e 704/872/4697 Page 12 of 20 Title: Dutchman File: DutchGrowth Transform: NO TRANSFORMATION Shapiro - Wilk's Test for Normality ----------------------------------------------------------------------------- D = 0.0938 W = 0.9676 Critical W = 0.8840 (alpha = 0.01 , N = 24) W = 0.9160 (alpha = 0.05 , N = 24) Data PASS normality test (alpha = 0.01). Continue analysis. PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 13 of 20 Title: Dutchman File: DutchGrowth Transform: NO TRANSFORMATION Bartlett's Test for Homogeneity of Variance ---------------------------------------------------------------------------- Calculated B1 statistic = 5.4921 (p-value = 0.3588) Data PASS B1 homogeneity test at 0.01 level. Continue analysis. ---------------------------------------------------------------------------- Critical B = 15.0863 (alpha = 0.01, df = 5) = 11.0705 (alpha = 0.05, df = 5) PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 14 of 20 Title: Dutchman File: DutchGrowth Transform: NO TRANSFORMATION ANOVA Table ---------------------------------------------------------------------------- SOURCE DF SS MS F ---------------------------------------------------------------------------- Between 5 0.0327 0.0065 1.2555 Within (Error) 18 0.0938 0.0052 ---------------------------------------------------------------------------- Total 23 0.1265 ----------------------------------------------------------------------------- (p-value = 0.3252) Critical F = 4.2479 (alpha = 0.01, df = 5,18) = 2.7729 (alpha = 0.05, df = 5,18) Since F < Critical F FAIL TO REJECT Ho: All equal (alpha = 0.05) PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 15 of 20 Title: Dutchman File: DutchGrowth Transform: NO TRANSFORMATION Dunnett's Test - TABLE 1 OF 2 Ho:Control<Treatment ---------------------------------------------------------------------------- TRANSFORMED MEAN CALCULATED IN SIG GROUP IDENTIFICATION MEAN ORIGINAL UNITS ------------------ T STAT 0.05 ------ --- ------------------------- 1 Control ----------- 0.7090 0.7090 2 9.25 0.6550 0.6550 1.0581 3 18.5 0.6160 0.6160 1.8223 4 37 0.7023 0.7023 0.1323 5 74 0.7243 0.7243 -0.2988 6 100 0.6955 0.6955 0.2645 ---------------------------------------------------------------------------- Dunnett critical value = 2.4100 (1 Tailed, alpha = 0.05, df = 5,18) Title: Dutchman File: DutchGrowth Transform: NO TRANSFORMATION Dunnett's Test - TABLE 2 OF 2 Ho:Control<Treatment ---------------------------------------------------------------------------- NUM OF MIN SIG DIFF °s OF DIFFERENCE GROUP IDENTIFICATION REPS ------- (IN ORIG. UNITS) ---------------- CONTROL ------- FROM CONTROL ------------ ----- 1 -------------------- Control 4 2 9.25 4 0.1230 17.3 0.0540 3 18.5 4 0.1230 17.3 0.0930 4 37 4 0.1230 17.3 0.0068 5 74 4 0.1230 17.3 -0.0152 6 ---------------------------------------------------------------------------- 100 4 0.1230 17.3 0.0135 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 16 of 20 Title: Dutchman File: DutchSury Transform: NO TRANSFORMATION Shapiro - Wilk"s Test for Normality ---------------------------------------------------------------------------- D = 0.0900 W = 0.8989 Critical W = 0.8840 (alpha = 0.01 , N = 24) W = 0.9160 (alpha = 0.05 , N = 24) ---------------------------------------------------------------------------- Data PASS normality test (alpha = 0.01). Continue analysis. f 1 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 17 of 20 Title: Dutchman File: DutchSury Transform: NO TRANSFORMATION Bartlett's Test for Homogeneity of Variance ---------------------------------------------------------------------------- Calculated B1 statistic = 2.6158 (p-value = 0.7590) Data PASS B1 homogeneity test at 0.01 level. Continue analysis. ---------------------------------------------------------------------------- Critical B = 15.0863 (alpha = 0.01, df = 5) = 11.0705 (alpha = 0.05, df = 5) PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 18 of 20 Title: Dutchman File: DutchSury Transform: NO TRANSFORMATION ANOVA Table ---------------------------------------------------------------------------- SOURCE DF SS MS F ---------------------------------------------------------------------------- Between 5 0.0100 0.0020 0.4000 Within (Error) 18 0.0900 0.0050 ---------------------------------------------------------------------------- Total 23 0.1000 ---------------------------------------------------------------------------- (p-value = 0.8424) Critical F = 4.2479 (alpha = 0.01, df = 5,18) = 2.7729 (alpha = 0.05, df = 5,18) Since F < Critical F FAIL TO REJECT Ho: All equal (alpha = 0.05) PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 19 of 20 Title: Dutchman File: DutchSury Transform: NO TRANSFORMATION Dunnett's Test - TABLE 1 OF 2 Ho:Control<Treatment ---------------------------------------------------------------------------- TRANSFORMED MEAN CALCULATED IN SIG GROUP IDENTIFICATION MEAN ORIGINAL UNITS ------------------ T STAT 0.05 ------ --- ----- 1 --------------------- Control ----------- 0.9500 0.9500 2 9.25 0.9250 0.9250 0.5000 3 18.5 0.9500 0.9500 0.0000 4 37 0.9250 0.9250 0.5000 5 74 0.9750 0.9750 -0.5000 6 100 0.9750 0.9750 -0.5000 ----------------------------------------------------------------------------- Dunnett critical value = 2.4100 (1 Tailed, alpha = 0.05, df = 5,18) Title: Dutchman File: DutchSury Transform: NO TRANSFORMATION Dunnett's Test - TABLE 2 OF 2 Ho:Control<Treatment ---------------------------------------------------------------------------- NUM OF MIN SIG DIFF o OF DIFFERENCE GROUP IDENTIFICATION REPS ------- (IN ORIG. UNITS) ---------------- CONTROL ------- FROM CONTROL ------------ ----- 1 -------------------- Control 4 2 9.25 4 0.1205 12.7 0.0250 3 18.5 4 0.1205 12.7 0.0000 4 37 4 0.1205 12.7 0.0250 5 74 4 0.1205 12.7 -0.0250 6 ------------------------------------------------------------ 100 4 0.1205 12.7 — -------------- -0.0250 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 20 of 20 Qa a a a Q Qa a a LL Q Q ,7 ate, C! 0 a vtn a � LL G Q Z M j z Q, C m Li: d Q Z O C o ti C O bD N C O �I U O cu 0 a v a � LL G V m LL Q d d d d C .N f0 m Li: d O E O N C O U1 O- E O OJ 2 c Z Q c 7 O V L LL rn E O Lf C � U 00 Q O VLL Z d a d a w ti O a\-1 V m M bA 1 O m V U Z LL n a m o o 0 0 0 0 LL > > d N c G L LL z z z V O �I V O �I V O �I V V V O V) O V) O Ln O Oa a a a Oa a a a cu C! C! 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Z ^ Z O N c N \ O N \ c-I V m h0 1 = LL V ^ J h0 1 L m d d d m d d d d d U 7 U1 O C � O o 0 0 0 0 cu = LL N LL CL 7 CL U ^ c 2 V 2 V o � n V V V O �I O �I O �I O O O Ln Ln Ln Q Q 0 LL LL a a N Q cu C! C! 0 u O cu o' cu v N tocu Q . . . . d d d d Ln. Q Z Ol d Q Q Q V n c Z C O C O co LL CL m LL CL m LL CL . . . . . . . . 1 a d d d . M O V O O o o 0 O c c cr 1 d 1 a d d d d 1 c c c O O O bb b tlo U1 w U1 ai O c bA �, LnQC) C C G 0 0 L Q Q Q E O E E m O •- O p O L V V c c M V c o 2 c Z Q a Z 0 Q n Z Q a a a a a T T T C C C 7 7 7 V V V O V J O = LL c-1 O o � e O N N c-1 O n a cy O J O a) O '� O Q O O p \ 0) Z \ M \ N 00 Z M M O Q N V 00 V O O O u LL OV LL u LL . Z Z Z N c O 0 C N N N C ~ c-1 c-I r-1 n Q1 n V c c c J b0 1Z2 b0 1 b0 1 � J N Co 2 N m . . . . . m d d d d d c U1 b0 7 V O > 2 N LL d N d O d 7 V O p b0 O U N 2 LL 2 V 2 V n w O N 0 m d NH3JTRC WLA Calculations Facility: Town of Mocksville/Dutchman's Creek Wastewater Treatment Plant (WWTP) PermitNo. NC0021491 Prepared By: Diana Yitbarek Enter Design Flow (MGD): 0.98 Enter s7Q10 (cfs): 2.5 Enter w7Q10 cfs : 11.9 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/1) Ammonia (Summer) Monthly Average Limit (mg NH3-N/1) s7Q10 (CFS) 2.5 s7Q10 (CFS) 2.5 DESIGN FLOW (MGD) 0.98 DESIGN FLOW (MGD) 0.98 DESIGN FLOW (CFS) 1.519 DESIGN FLOW (CFS) 1.519 STREAM STD (UG/L) 17.0 STREAM STD (MG/L) 1.0 Upstream Bkgd (ug/1) 0 Upstream Bkgd (mg/1) 0.22 IWC (%) 37.80 IWC (%) 37.80 Allowable Conc. (ug/I) 45 Allowable Conc. (mg/1) 2.3 Maintain limit at 28 ug/I Maintain limit at 2.0 mg/I, as set by model Ammonia (VVInter) Monthly Average Limit (mg NH3-N/1) Fecal Coliform w7Q10 (CFS) 11.9 Monthly Average Limit: 200/100mi DESIGN FLOW (MGD) 0.98 (If DF >331; Monitor) DESIGN FLOW (CFS) 1.519 (If DF<331; Limit) STREAM STD (MG/L) 1.8 Dilution Factor (DF) 2.65 Upstream Bkgd (mg/1) 0.22 IWC (%) 11.32 Allowable Conc. (mg/1) 14.2 Maintain 200/100 ml MA limit Maintain limit at 4.0 mg/I, as set by model Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/I to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/l, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals) 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis) If the allowable ammonia concentration is > 35 mg/L, no limit shall be imposed Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) Pretreatment Program Info Database printed on: 9/8/2022 for Program Name MOcksville WWTP Name Dutchman Program Approval Date 01/14/1985 Pretreatment Status Modified Region WSRO County Davie Stream Information IWC % at 7Q10 37.39 7Q10 Flow cfs / mgd 2.54 / 1.64 1 Q10 Flow cfs / mgd 2.13 / 1.37 Stream Classification C Basin Number YAD05 Receiving Stream Name DUTCHMAN CREEK NPDES Number NC0021491 Last PAR Rec 03/01/2022 PAR Due Date 03/01/2023 mercury NPDES Effective Date 11 /01 /2014 1631 NPDES Expire Date p� 06/30/2019 Current Fiscal 04/10/2019 required Year PCI Done POTW is Primary WWTP TRUE Last Audit on 06/23/2021 Audit Year Next25/26 yes Design Flow mgd 0.9800 % Design mgd is SIU permitted 25.51 Permitted SIU flow (mgd) [Pt. SIU) 25 WWTP SIU's 1 Program SIUs 1 WWTP CIU's 10 Program CIUsF6 I HWA LTMP IWS SUo ERP date Inactive Date Next Due 06/30/2024 Date Received by DWR 01/11/2022 08/28/2018 05/04/2020 06/11/2014 03/04/2020 Date Approved 12/03/2018 07/28/2020 06/11/2014 03/17/2020 Adopt Date Required Date Adopted 07/01/2014 Info in this Box from Pt Contacts Date Date Date PT —Pro Attended Attended Attended Formal Name g.Prime Phone1 ext Fax HWA Wksp IUP Wksp PAR Wksp Ms. Madelyn Mills Prim 984-365-9160 mmills(cDenvirolinkinc.com jEnvirolink, Inc. Compliance 1773 Sanford Ave. 27028 Mr. Kenneth Gamble 1 (336) 753-6701 yl1 kgamble@mocksvillenc.gov I Town Manager S. Clement Street 27028 Mr. Joshua Powers Prim (704) 775-6128 jpowers@envirolinkinc.com Envirolink, Inc. Piedmont Area 1773 Sanford Ave. 27028 Pretreatment Related NO Vs from DWQ L 6/24/1993 Itmp, hwa, erp, iws 9/23/1993 late SAR 3/9/1994 NCP 94-01 9/29/1994 program inadequate, late SAR 10/7/1996 late SAR 3/29/2001 IUPs, comp judge/enforce, pub not; 9/00 PCI 9/21/2001 enforce, imple stmp (from respon to 3/29 nov) 3/5/2003 failure to issue IUPs 4/9/2010 NOV-NOI for failure to submit PAR 2009 4/19/2010 NOV-NOI For PT elements (HWA, ERP, STMP) DWR Central Office Contact JMcGee & Miller DWR Regional Contact lex Lowe �0000©o®©o0©0©©0 e.. POC Review Form e � ■ e e � v■ e moo■ e • moo■ m_ m m mo m m m m m m m m .; W in n n n n n ■ _ m m -- m I IPOC, Chi m v�■�o_soe_����_ m v�■�o_soe_����_ m 0�■�ooaoe_����� m 0�■�00000_����� m v®■�00000_����� m m mL-PITMPm m m m m - � ®[ m � � DAVIM COUNTY CNTCRPRIIE RECORD Publisher's Affidavit Of Publication No.1533850 STATE OF NORTH CAROLINA Public Notice DAVIE COUNTY North Carolina Environmental Management Commission/NP- DES Unit Before the undersigned, a Notary Public of said county 1617 Mail Service Center and state, duly commissioned, qualified, and authorized Raleigh, NC 27699-1617 Notice of Intent to Issue a by law to administer oaths, personally appeared MARK A. NPDES Wastewater Permit BEE, who being first duly sworn, deposes and says that he NC0021491 Dutchman Creek WWTP is GENERAL MANAGER of a newspaper known as DAVIE The North Carolina Environmental COUNTY ENTERPRISE -RECORD, published, issued and ement esanato g sue a NPDESsion wasttewater entered as second class mail in the City of Mocksville, in discharge permit to the person(s) listed below. Written comments Davie County, North Carolina, that he is authorized to make reggarding the proposed permit wfl be accepted until 30 days af- this affidavit and sworn statement, that the notice or other ter the publish date of this notice. legal advertisement is a true co of which was attached g PY The Director of the W Division of Water Resources (DWR) may hold hereto, was published in the DAVIE COUNTY ENTERPRISE- a public hearing should there be a significant degree of public inter - RECORD, on the following dates: est. Please mail comments and/ or information requests to DWR at the above address. Interested pNersons may visit the DWR at 512 u Stre10/27/22 27 041i to rev view theR nleighforrmat on on file. Additional information on NPDES permits and this notice may be found on our website: http://deq.nc.gov/about/divisions/ water-resources/water-resourc- and that the said newspaper in which such notice, paper es-permits/wastewater-branch/np- des-wastewater/public-notices,or document or legal advertisement was published at the time b calling (919) 707-3601. The Clement of each and every such publication, a newspaper meeting Town of Mocksville 1171 Street, Mocksville, NC 27028j in all the requirements and qualifications of Section 1-597 of Q Q Davie County requested renewal of permit NC0021491 for Dutch - the General Statutes of North Carolina, and was a qualified man Creek WWTP discharging newspaper within the meaning of Section 1-597 of the Gen- treated municipal wastewater to Dutchman creek, a class C water, eral Statutes of North Carolina, in the Yadkin -Pee Dee River Ba- sin. Ammonia, cadmium, copper, dissolved oxygen, biochemical oxygen demand, fecal coliform, pH, total residual chlorine, and at a cost of $57.50 total suspended solids are water qquality limited parameters. This Account #: 23483 discharge may affect future allo- cations in this portion of the Yad- Re: kin -Pee Dee River Basin. Publish 10/27/22 Purchase Order #: (signature of person making affidavit) Sworn and subscribed before me this 27th Day of October, 2022 9x - 4 5 , Notary Public - My comr9ission expires D5/02/2026 f! T A , &&tic