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State of North Carolina
Department of Environment,
Health and Natural Resources
Division of Water Quality
James B. Hunt, Jr., Governor
Jonathan B. Howes, Secretary
A. Preston Howard, Jr., P.E., Director
August 2, 1996
Mr. Scott Eaton
CITGO Petroleum Corporation
P.O. Box 58
Paw Creek, North Carolina 28130
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Subject: NPDES Permit Issuance
Permit No. NC0021962
Paw Creek Terminal
Mecklenburg County
Dear Mr. Eaton:
In accordance with the application for discharge permit received on March 1, 1996, the Division is
forwarding herewith the subject state - NPDES permit. This permit is issued pursuant to the requirements of North
Carolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the U.S.
Environmental Protection Agency dated December 6, 1983.
In response to oil terminals' comments pertaining to the chlorophenol monitoring requirements in the draft
permits, the Division held a teleconference with representatives from the oil terminals and their laboratories. The oil
terminals' representatives had the following concerns: (1) Why was there a requirement to monitor for eight
individual chlorophenols in addition to those specified in EPA Method 625; and (2) What is the proper laboratory
procedure to analyze for these eight chlorophenols?
After some additional data review, research, and discussion, two determinations were made. First, although
all chlorophenols have the potential to cause taste and odor problems in drinking water supplies and tainting of fish
tissue, the eight chlorophenols Bpi covered by EPA Method 625 are not considered to be carcinogens. Second,
certain chlorophenolic compounds are likely to form first. This is significant because certain parameters can be used
to "screen" the stormwater discharge for the presence of chlorophenols. Specifically, the five chlorophenols included
in EPA Method 625 can be used as indicators of all chlorophenols because these five compounds would be the first
to form when chlorine reacts with phenol.
Therefore, EPA Method 625 will be used as an initial screen. If no chlorophenols are detected, no additional
monitoring will be required. However, if one or more chlorophenols are detected at concentrations greater than 50
14/1, then the oil terminal would be required to monitor for the eight additional chlorophenols beginning with the
next scheduled monitoring event and continue to monitor until the permit expired. The additional chlorophenol
monitoring would include identifying and quantifying all chlorophenols present in the sample(s).
If any parts, measurement frequencies or sampling requirements contained in this permit are unacceptable to
you, you have the right to an adjudicatory hearing upon written request within thirty (30) days following redeipt of
this letter. This request must be in the form of a written petition, conforming to Chapter 150B of the North
Carolina General Statutes, and filed with the office of Administrative Hearings, Post Office Drawer 27447, Raleigh,
North Carolina 27611-7447. Unless such a demand is made, this permit shall be final and binding.
Please take notice that this permit is not transferable. Part II, E.4. addresses the requirements to be
followed in case of change in ownership or control of this discharge.
P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone 919-733-5083 FAX 919-733-0719
An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post -consumer paper
't .
This permit does not affect the legal requirements to obtain other permits which may be required by the
Division of Water Quality or permits required by the Division of Land Resources, Coastal Area Management Act, or
any other Federal or Local governmental permits may be required.
If you have any questions or need additional information, please contact Mr. Mark McIntire, telephone
number (919) 733-5083, extension 553.
Sincerely,
Original Signed
A. Preston Howard, Jr.
A. Preston Howard, Jr., P.E.
cc: Central Files
Mr. Roosevelt Childress, EPA
Mooresville Regional Office, Water Quality
Permits and Engineering Unit
Mecklenburg County Environmental Protection
Facility Assessment Unit
Aquatic Survey and Toxicology Unit
Permit No. NC0021962
STATE OF NORTH CAROLINA
DEPARTMENT OF ENVIRONMENT, HEALTH, AND NATURAL RESOURCES
DIVISION OF WATER QUALITY
PERMIT
TO DISCHARGE WASTEWATER UNDER THE
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM
In compliance with the provision of North Carolina General Statute 143-215.1,
other lawful standards and regulations promulgated and adopted by the North Carolina
Environmental Management Commission, and the Federal Water Pollution Control Act, as
amended,
CITGO Petroleum Corporation
is hereby authorized to discharge wastewater from a facility located at
Paw Creek Terminal
NCSR 1784
Paw Creek
Mecklenburg County
to receiving waters designated as an unnamed tributary to Gum Branch in the Catawba River
Basin
in accordance with effluent limitations, monitoring requirements, and other conditions set forth in
Parts I, II, III and IV hereof.
This permit shall become effective September 1, 1996
This permit and authorization to discharge shall expire at midnight on August 31, 2001
Signed this day August 2, 1996
Original Signed Ey
A. Preston Howard Jr
A. Preston Howard, Jr., P.E., Director
Division of Water Quality
By Authority of the Environmental Management Commission
Permit No. NC0021962
SUPPLEMENT TO PERMIT COVER SHEET
CITGO Petroleum Corporation
is hereby authorized to:
1. Continue to operate an existing stormwater treatment system consisting of an oil/water separator,
an equilization tank, a second oillwater separator, and a diffused aeration system located at Paw
Creek Terminal, NCSR 1784, Paw Creek, Mecklenburg County (See Part III of this Permit),
and
2. Discharge from said treatment works at the location specified on the attached map into an
unnamed tributary to Gum Branch which is classified Class WS-IV waters in the Catawba River
Basin.
•
ROAD CLASSIFICATION
PRIMARY HIGHWAY
HARD SURFACE
LIGHT•DUTY ROAD, HARD OR
IMPROVED SURFACE
SECONDARY HIGHWAY
HARD SURFACE UNIMPROVED ROAD = =
Latitude 35°16'52" Longitude
Map # F15SW Sub -basin 03-08-34
Stream Class WS-IV
Discharge Class Industrial - Petroleum
Receiving Stream UT to Gum Branch
Design Q episodic Permit expires 8/31/01
80°56'02"
0
SCALE 1:24 000
0 1 MILE
7000 FEET
0
1 KILOMETER
CONTOUR INTERVAL 10 FEET
CITGO Petroleum
NC0021962
Mecklenburg County
Tank Farm
A. (). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS
Permit No. NC0021962
During the period beginning on the effective date of the permit and lasting until expiration, the Permittee is authorized to discharge stormwater
from outfall(s) serial number 001. Such discharges shall be limited and monitored by the Permittee as specified below:
Effluent Characteristics
Flow I
Total Suspended Solids
Oil and Grease2
Phenol
Benzene
Toluene
Xylene
EPA Methods 624/6253
Acute Toxicity4
Discharge Limitations
Monitoring Requirements
Measurement
Monthly Avg. Weekly Avg. Daily Max. Frequency
Monthly
45.0 mg/I Monthly
Monthly
Monthly
1.19 µg/I Monthly
11.0 µg/1 Monthly
Semi-annually
Semi-annually
Episodic
Sample
Type
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Sample
Location
Effluent
Effluent
Effluent
Effluent
Effluent
Effluent
Effluent
Effluent
Effluent
Footnotes:
I Where no measurable discharge occurs, "no discharge" should be clearly noted on the submitted monthly discharge monitoring report.
Flow may be monitored in one of four ways: a) Measure flow continuously, b) Calculate flow based on the area draining to the outfall, the built upon
area, and the total rainfall (this method of flow measurement should not be used at facilities that have large ponds to collect
surface water runoff), c) Estimate by flow measurement at 20 minute intervals during the entire discharge event, or d) Base flow on pump logs.
2 Where possible, the grab sample for oil and grease should be skimmed from the surface of a quiescent (calm water) zone.
3 EPA Method 625 includes five (5) chlorophenols. 1f one or more chlorophenol(s) is detected at concentrations greater than or equal to 50 µg/I, the
permittee will be required to analyze for the eight chlorophenols (listed below) in addition to EPA Method 625. This additional required monitoring
will begin with the pennittee's next scheduled monitoring event, occur on a semi-annual basis, and will last for the duration of the permit. Eight
chlorophenols include the following: 3-chlorophenol, 4-chlorophenol, 2,3-dichlorophenol, 2,5-dichlorophenol, 2,6--dichlorophenol, 3,4-
dichlorophenol, 2,3,4,6-Tetrachlorophenol, and 3-methyl-6-chlorophenol.
4 Acute Toxicity (Fathead Minnow, 24-hour) Monitoring, Episodic, See Part III, Condition E.
There shall be no discharge of floating solids or visible foam in other than trace amounts.
There shall be no direct discharge of tank solids, tank bottom water, or the rag layer.
There shall be no direct discharge of tank contents following hydrostatic testing unless the benzene concentration is less than 1.19 ug/1 and the toluene
concentration is less than 11 ug/1.
Part III. NC0021962
E. ACUTE TOXICITY MONITORING (EPISODIC)
The permittee shall conduct FIVE acute toxicity tests using protocols defined as definitive in
E.P.A. Document EPA/600/4-90/027 entitled "Methods for Measuring the Acute Toxicity of
Effluents to Freshwater and Marine Organisms." The monitoring shall be performed as a Fathead
Minnow (Pimephales promelas) 24 hour static test. Effluent samples for self -monitoring purposes
must be obtained below all waste treatment. Sampling and subsequent testing will occur during the
first five discrete discharge events after the effective date of this permit. After monitoring of the
fast five toxicity tests, the permittee will conduct one test annually, with the annual period
beginning in January of the next calendar year. The annual test requirement must be performed and
reported by June 30. If no discharge occurs by June 30, notification will be made to the Division
by this date. Toxicity testing will be performed on the next discharge event for the annual test
requirement.
The parameter code for this test is TAE6C. All toxicity testing results required as part of this permit
condition will be entered on the Effluent Discharge Form (MR-1) for the month in which it was
performed, using the appropriate parameter code. Additionally, DEM Form AT-1 (original) is to be
sent to the following address:
Attention: Environmental Sciences Branch
North Carolina Division of
Water Quality
4401 Reedy Creek Rd.
Raleigh, N.C. 27607
Test data shall be complete and accurate and include all supporting chemical/physical measurements
performed in association with the toxicity tests, as well as all dose/response data. Total residual
chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for
disinfection of the waste stream.
Should any test data from either these monitoring requirements or tests performed by the North
Carolina Division of Water Quality indicate potential impacts to the receiving stream, this permit
may be re -opened and modified to include alternate monitoring requirements or limits.
NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum
control organism survival and appropriate environmental controls, shall constitute an invalid test.
Failure to submit suitable test results will constitute noncompliance with monitoring requirements.