WQ0005910_Monitoring - 11-2022_20221222 (3)

Monitoring Report Submittal
Permit Number #*
Name of Facility:*
Month: * November
Report Information
Type *
GW-59
WQ0005910
Avoca LLC
Confirmation Email Address:*
Name of Submitter: *
Signature:
Date of submittal:
Initial Review
Year:* 2022
Upload Document*
Avoca LLC Nov. 2022 GW-59 2.72MB
Forms.pdf
PDF Only
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59).
[e-mail]
Brian M. Conner
t
Reviewer: Gerald, Wanda
12/22/2022
This will be filled in automatically

Is the project number correct?* WQ0005910
Is the monitoring report accepted?* Yes No
Regional Office* Washington
Reviewer: _anonymous
Review Date: 1/11/2023

GW-59A COMPLIANCE REPORT FORM verrrtit ## Wac)00Ga10
(Suhinit ofte each nromforing period ivith GIV S9 fornir.)
Enter date monitoring results were due. -�1��7t Will this monitoring report (GW-59 and GW-59A)
YES
NQ
be submitted after the established due date?
Was any regnired Informatlon missing on the GW-59 report forms?
YES
NO
IF the answer to question 1 or 2 is 'YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information,
`
V
3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, m3sstng YES
NO
Identification Plate, area overgrown, etc,)? l the aimvei is "kcs", contact llieRegionalO�ce for guidance,
4 Are any monitored constituents equal to or above the established standards? YES
�
NO
if the answer to question 4 is "NO", skip to section 8.
If the answer fo question 4 is "YES" list the affected wells individually with conslituent(s) and conceniration(s)
exceeding standards in the space provided below, f
I W\% . 13O
Forthe constituents identified in question 4 abovq, have standards been exceeded previously for the YES
NO
same constituent(s) In the same well(s) In the last two years?
11 [ire answer to question 5 is "NU skip to section d
If the answer to question 5 is "YES'; list In the space provided below, each well with constituent(s) exceeding
standards, concentrations) reported, and sample collection data for each occurrence (for the last two years).
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t►)1te111 9.810 "jSao it%l-J,o Slog
6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO
7
P
If the answer Is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE If the answer is "NO'; monitoring welts maybe improperly
located, contact the Regional Office. V
Is the permittee implementing previously approved actions required by the Division involving this YES i NO
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below
If the answer to questlon 7 is "NO'; contact the Regional Office within 90 daysLan
a
The person completing this portion (GW 59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top ofthe current CW-59 form.
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y
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Ni - Nick -ell mc A
Pb - Lead MA
Zn - Zinc m •
_-
Ammonia Nitrogen M
FACILITY INFQRMATION
Please Print Clearly or Type
Facility Name, Awc2CrA LLC_
Permit Name (if different):
F acility, Address:.SL-k I PvQQCa 5A�v�aad
Zilis-7
*
County
P4Y) Vip)
Contact Person.- ZiI CQ�On&
Telephone #: _2l�Z-14%z-a IS3
Well Location/ Site Name:
No® of Wells to be Sampled: 6
(Irom Pemll)
Well identification Nu er (from Permit): WAI G
For Groundwater Tr'eatment Systems
Well Depth: ft, Well Diameter: —2t--
-2'2-
in, CheckOne; 0 Influent (98)
Screened interval: i ft. to ft_
El Effluent (99)
Depth to Water Leve,: ft. below measuring point.
Measuring Point (M-P_) is:--2— ft- above land surface-
Relative M.P. Elevation in ft,:
Gallons of water pumpecL/bailed beffore sampling: S
Date sample collected
Field analysis: pH L4 , Specific Conductance
uMhos;
Temp- f> -C, Odor NGIV15-
Appearance Cle-Ar
COD mall
Colifonm- MF Fecal 11 00m]
Coliform: MF Total /1 00ml
(Note: Use MPN method for highly turbLd
Dissolved Solids: Total mg/l
pH (when analyzed) units
TOC
Chloride mq/1
Arsenic mg/l
Grease and Oils mg/I
Phenol mg1l
Sulfate mg/l
Specific Conductance _uMhos
Total Ammonia•mg/I
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALMY DIVISION, GROUNDWATER SECTION
1636 MAIL SERVICE CENTER
- X0 1 11
PERMIT4k, - EXPIRATION DATE: 10� 3-07 q
Non-Discharcie LQ 000`5
[APID ES
TYPE OF PERN41TTED OPERATION BEING MONITORE
Lagoon —,Remediation- Infillaation Gall I
Spray Field — Remediation:
Rotary Distributor — Land Application of Sludge
Other
ROAC=1 MU-es—s ff5-`­uT1Tr`fI ­15-73-s UfVTeW7M'
colloidal concentrations.
Date sample analyzed: t1IS01az- \:)-h 121
Laboratory Name: _EYI�Onme*lk
Certification No... 10
ere TES —NO and field acidifi
Nitrite (NO2) as N mg/1
Nitrate (NO3) as N mg/1
Phosphorus: Total as P 0.10 mg/I
Orthophosphate mg/1
A] - Aluminum mg/I
Ba - Barium mq/1
Ca - Calcium a I 5 mg/l
Cd - Cadmium mq/1
Chromium: Total mg/1
Cu - Copper— mgA
Fe - Iron mg/I
Hg - Mercury mg/l
K - Potassium mg/1
Mg - Magnesium III
M
anganese method#= Lu a ENVAMN
method#=
type

161011TI I name 11141=3:11
FACILITY INFQRMATION Please Print Clearly or Type
Facility Name; Awn(a LLC
Permit Name (if different):
P cility Address- !!i I PNOCA
Well Identification Number (from Permit): IIllill -_1 For Groundwater Treatment Systems
Well Depth: — It ft. Well Diameter: 2. in. Check0ne:E] Influent (98)
Screened Interval: ft. to —1-IL- - ft11 Effluent (99)
Depth to Water Level: ft. below measuring point.
Measuring Point (M.P.) is:_I�_ ft. above land surface. Relative M.P. Elevation in ft.:
Gallons of water pumped/bailed before sampling: Date sample collected: A
Feld analysis: p Specific Conductance uMhos
Temp. cC, Odor Q Q^?- Appearance C-leA--
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 MAIL SERVICE CENTER
PERMIT#: - EXPIRATIOND :kOWM
Non-Discharge_LQQ_Q)o051 I UIC
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon —Ramediation: Infiltration Gallery
V Spray Field — Remedialion:
— Rotary Distributor —Land Application of Sludge
Other
Date sample analyzed:
Ln.b slame:
Certificafjon No.
PARAIVIETEIR�j (Samples for metals were collected unfiltered "� YES —NO and field acidified
COD
mg/I
00ml
Nitrite (NO2) as N
Nitrate (NO3) as N 51E
mg1j
mg1l
Coliform: MF Fecal
Coliform: MF T otal
/1 00ml
PhclsphorusTotal as P 0 - 14b
mg/l
(Note: Use MPN method for highly turbid Samples)
Dissolved Solids: Total mg/I
Orthophosphate
Al - Aluminum
mq/l
mg/l
pH (when analyzed)
units
Ba - Barium
mg/I
TOC LA .2.S
moll
Ca - Calcium,
mgA
Chloride
mg/1
Cd - Cadmium
mg/I
Arsenic
ril
Chromium: Total
mg/I
Grease and Oils
mg/I
Cut - Copper
mg/I
Phenoi
mg/I
Fe - Iron
mg/l
Sulfate
mq/I
Hg - Mercury
mgA
Specific Conductance
uMh�s
K - Potassiu
mg/I
I otal Ammonia .0 4
mg/l
Mg - Magnesium
mg/I
TKN as N
mg/I
Mn - Manganese
mg/I
YES — NO)
Ni - Nickel
mg/1
Pb - Lead
mg/l
mgA
Ammonia Nitrogen
mg/I
ORGANICS- (GC.GC/MS,HPLC)
(Specify test and method #. Attach tab report.)
ReportAttached? Yes_V(1) No_(0)
voc method #
method # =
method ill

FACILITY INFQRMATION Please Print Clearly or Type
Facility3 o-
Perm -it Name (if diflerent
Facility Address:— A\ILQF.Q ­1
. __
Cor-- ._Telephone
Well Location/ Site Name: No. of Wells to be Sampled:
r. a r • �. - . i f. --
COD
mg/I
00ml
(Note. Use IM t
' method
Dissolved
pH (when analyzed)
units
Chloride
Arsenic
mg/I
Grease d Oils
mg/I
Phenol
ma/I
SpecificSulfate
#
uMh8s
Total * e
Check One: 0 Influent t
t
DEPARTMENT GP ENVIRONMENT & NATURAL RESOURCE
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 MAIL SERVICE CENTER
RALEIGH. NC 7699-1636 Phone. [phone]
PERMIT DATt
Non-DischarqeWQ0o0S91Q
TYE5_QE PEaMrrTED OPERATIONMONITORED
.tit e t Infiltration Gallery
Spray- r - mot..... t
RotaryDistributor Application of Sludge
t
Date sample ai
Laboratory Name: Ey-iwl�rOV'%Vn�
Certification No. ko
ered
--
tfieldacidified
#
Nitrite #
Nitrate
#
:f x s mg/1
Phosphorus: Ti E
Orthophosphate
:
2 Aluminum
:a Barium
mgA
Chro• _
Copper
mg/1
•
g
Magnesium!
Manganese
INER0751M
Ni - Nickel mgA
b _ F` a r mQA
Ammonia Nitroge
- o..e
Other (Specify Compounds and Concentration Units)
ORGANICS:
(Specify methodachtab report.)
_
ReportAttached?
VOC ••
t <
type

Please Print Clearly or Type
Facility Name:-j
Permit Name (if
F F aCifltv Address:
On- mor-R&IMMIMM
Well Identification Number (from Permit): WW__q For Groundwater Treatment Systems
i f
Wait Deoth: 272­0c.)
—ft, Well Diarneter!�in. CheckOne-E] Influent (98)
Screened ln*Lerval:--LQ— It. to 1�� ft. 0 Effluent (99)
Depth to Water Level: ft. below measuring point.
Measuring Point (M.P-) ft. above land surface. Relative M.P. Elevation in ft.:
Gallons of water pumped/bafled before sampling: 5 Date sample collected: kX-jXS-2A
Field analysis, pH (A- %9 . Specific Conductance uMhos
Temp_ 2�1113_00 'C, 0 d o r -0-0-A—C, Appearance Cagi-_-
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 MAIL SERVICE CENTER
PERMIT EXPIRATION DATE 10 1 -St I q
Non -Discharge QQ U Ic
NPDES
TYPE QE PEBMI=Q OPERATION BEING MONITORED
Lagoon —Remediation: Infiltration Gallery
Spray Field Remediation:
Rotary Distributor Land Application of Sludge
Other,
NOTE,�-, Values should reflect dissolved and
coiloidal concentrations.
Date sample analyzed:
Certification No.
PABAMETERS (Samples for metals were collected unfiltered V YES -NO
and field acidifi
CC. 0 D
ma/l
Nitrite (NO2) as N
mg/I
ColiformMF Fecal
11 00ml
Nitrate (NO,3) as N
rng/l
Colifform: M4F Total
11 00ml
Phosphorus: Total as P_
Q-NI m_q11
(Note, Use MPN melhod for highly turbid samples)
Orthophosphate
mg/l
Dissolved Solids: Total ISO
— mg/I
A[ - Aluminum
mgA
pH (when analyzed)
units
Ba - Barium
mg/l
yoc I .1R)
mg/l
Ca - Calcium LAS
L71 I mq/l
Ghloriiide
mg/I
Cd - Cadmium
mg/1
Arsenic
mQA
Chromium: Total
mg/I
Grease and Oils
mg/I
Cu � Copper
mq/1
Phenol
mq/1
Fe - Iron
mg/I
Sulfate
mg/I
Hg - Mercury
mg/I
Specific Conductance _uMhos
K - Potassiu
Mg/I
Total Ammonia v2_
mg/l
Mg - Magnesium
mg/I
TKN as N
ma/l
Mn - Manganese
mg/I
method "r =
method ft
Ni - Nickel
M-M
Pb
Zn - Zinc
m-
Ammonia Nitrogen
m 0jj
ORGANICS: (GC,GCIMSHPLC)
(specify test and method #. Altach tab report.)
Report Attached? Yes 8 ',
voc method # =
r type

KOM=
Facility Name: io r, el
Permit Name if different):
MR
'SAW
Please Print Clearly or Type
Well Identification Number (from Permit): For Groundwater Treatment Systems
Well Depth- ft. Well
!'CheckOne0 Influent (98)
Screened interval- ft� to - 2JQ ft.
ffluent (99)
E
Depth to Water 'Level: IM ft. below measuring point.
Measuring Point (M.P-) is:-2-- ft. above land surface. Relative M.P. Elevation in ft.:
Gallons of water pu d/balled before sampling: -5 Date sample collected:
Fieldanalysis: pnFMV%0 Specific Conductance uMhos
-Temp. ?t�110C, Odor 9051`0- Appearance Cleav-
TePWAYT; 4111FZ1611wetj
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 MAIL SERVICE CENTER
PERMIT 4- EXPIRATION DATE- Xcf'ik 1292q
Non-Discharqe 00531Q--Ulc
NPIDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon —Remediation: Infiltration Gallery
Spray Field — Remediarion:
Rotary Distributor - Land Application of Sludge
Other
N_QTE. Values should reflect dissolved and
colloidal concentrations.
late sample analyzed: kX-SO-aa-
Laboratory Name: Er%\J'kkCany-%
Certification
PARAMETERS (Samples for metals were collected unfiltered Nf YES —NO and field acidified
COD
mg/l
Nitrite (NO2) as N
mg/l
Coliform: MF Fecal
/1 00ml
Nitrate (NO3) as N 1 .9 L0
mg/l
Coliform- MF Total _/100ml
Phosphorus: Total as P 0.0b —mg/l
(Note- Use MPN method for highly turbid samples)
Orthophosphate
m_q1l
Dissolved Solids: Total mg/l
A] - Aluminum
mg/l
pH (when analyzed)
units
Ba - Barium
ma/l
TOC 1,.tz
mg/1
Ca - Calciun
mg/I
Chloride
mg/l
Cd - Cadmium
mg/I
Arsenic
mg/I
Chromium: Total
mq/1
Grease and Oils
mg/l
Cu - Copper
mg/I
Phenol
mg/l
Fe - Iron
mg/l
Sulfate
mo/l
Hg - Mercury
mg/1
Specific Conductance
uMh6s
K - Potassiu
mg/l
Total Ammonia 4004
mg/l
Mg - Magnesium
mg/l
TKN as N
mg/l
Mn - Manganese
mg/I
method # =
method # =
NI - Nickel mgA
Pb - Lead mg/l
Zn - Zinc MV
Ammonia Nitrogen mg/I
ORGANICS- (GC,GCIMS,HPLC)
(Specify test and method It. Ptach lab report.)
Report Attached? Yes� V (1) No — (0)
VOC : method#=
Tr 7ni or type
0

GROUNDWATER QUALITY MONITORINI
COMPLIANCE REPORT FORM
FACILITY LNFQRMATION Please Print Clearly or Type
Facility Name: Awncrj LL(_
Permit Name (if different}
Well Location! Site Name:
No. of Wells to be Sampled:
Wel'Ildentification Number (from Permit): � —I !-- 1� For Groundwater Treatment Systems
Well Depth: 2.0 ft. Well Diameter-, 2- in. Influent (98)
Screened interval:-- ft.to_10__ft'�
I El Effluent (99)
Depth to Water Level: ft. below measuring point.
Measuring Point (M.P.) is:- ft. above land surface. Relative M.P. Elevation in ft.:
Gallons of water pumped/bailed before sampling: -5 Date sample coliected.
Field analysis: pH (0-S-5 . Specific Conductance uMhos
Temp. IM-'A OC, Odor Appearance
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 MAIL SERVICE CENTER
PERMIT EXPIRATION DATE: 1619UP2
Non -Discharge WQ00051 t uic
NPOES
TYPE QF PERMITTED OPERATION BEING MONITORED
Lagoon Remedlation: Infiltration Gallery
7� S_ppray Field Remediation:
— Rotary DistributoT Land Application of Sludge
111011
Values should reflect dissolved and
colloidal concentrations.
Date sample analyzed:
Certification No.
PARAMETERS (Samples for metals were collecte.cl unfiltered V YES —NO
and field acidified
COD
mg/I
Nitrite (NO2) as
Coliform: MF FecalNitrate
(NO3) as N 0 - 0_1
— mg/l
Coliform, MF Total
/1 00m]
Phosphorus: Total as P 40-klio
ma/l
(Note: Use MPN method for highly turbid mples)
Orthophosphate
mg/l
Dissolved Solids: Total—
_mg/I
A] - Aluminum
DH (when analyz!�d_)
units
Ba - Barium
mg/l
toc
ma/I
Ca - Calcium
mall
Chloride
mg/I
Cd - Cadmium
mg/I
Arsenic
mg/I
Chromium: Total
rng/1
Grease and Oils
ma/I
Cu - Coppe
MQ/1
Phenol
mg/l
Fe - Iron
mo/I
Sulfate
mg/l
Hg - Mercury
mg/I
Specific Conductance
uMhos
K - Potassiu
mg/I
I otal Ammonia _kO 'b A
rng/1
Mg - Magnesium
mg/l
TKN as N
mg/l
Mn - Manganese
mg/l
method It=
YES — NO)
Ni - Nickel mg/I
Pb - Lead mgIl
Zn - Zinc mgA
mmoni Nitro en— mall
i il, 11
*RGANICS: (GC,GC/.MS,HPLC)
(Specify test and method #. Altach lab report.)
ReportAttached? Yes=_Z(1) No_(0)
VOC method#=
method#=
— !? 9'-<s:,Af'VA
print Or tyr,,C

"-�✓-
".:.'�rm%�,.'..�-'r.
f,. r�
waabawater In: 10 ,.
114 OAKMONT DRIVE
GREENVILI.,E, N.C, 27858
AVOCA, LLC (WASTEWATER)
MR. BRIAN CONNER
P.O. BOX 129
MERRY HILL, NC 27957
Effluent
PARAMETERS
BOD, mg/1
3015
Total Suspended Residue, mg/1
333
Ammonia Nitrogen as N, mgll
<0.04
Total Kjeldahl Nitrogen as N,mg/1
60.20
Nitrate+Nitrite as N, mg/1 (talc)
0.52
Nitrate Nitrogen as N, mg/1
<0.04
Nitrite Nitrogen as N, mg/l
0.52
Total Phosphorus as P, mg/l
8.80
Total Organic Carbon, mg/1
Chloride, mg/l
135
Total Dissolved Residue, mg/i
2400
Calcium, ng/l
14879
Magnesium, 11g/1
2361
Sodium, ug/l
193350
Sodium Adsorption Ratio (talc)
12.3
Total Nitrogen, :ng/1 (talc)
60.72
PHONE [phone]
FAX [phone]
SD#: 132
DATE COLLECTED: 11/28/22
DATE REPORTED : 12/21/22
REVIEWED BY:
Well #5 Well #7 Well #8 Well #9 Analysis Method
Date Analyst Code
11/29122
ADR 521OB-16
11/30/22
11MV 254OD-15
0.08
<0.04
0.46
0.12
11/30/22
I ES 350.1 112-93
12/01/22
BMD 351.2 R2-93
353,2 R2-93
<0.04
1.08
0.63
2.57
11/30/22
TRJ 353.2 R2-93
11/30/22
BMD 353.2 R2-93
0.10
0.18
2.23
0.11
12/01/22
TRJ 365.4-74
3.08
4.23
14.14
1.18
11/30/22
HAIM 531OC-14
31
35
16
21
11/30/22
JDJ 4500CLB-11
560
320
380
250
12/01/22
BNC D5907-13
31348
10316
11008
45671
12/01/22
MTM EPA200.7
12/01/22
MTM EPA200.7
12/01/22
MTM EPA200.7

hwqow ddco do
�Y •+i?�-t^;..�%��ia'�aYM x. ;. =✓�;' t ..,='. �� _ �y _ _ s^�^.,.,,w.
::mow
�wneteveber xn, i'o
114 OAKMONT DRIVE
GREi=NVELLE, N Cr 27858
AVOCA, LLC (WASTEWATER)
MR. BRIAN CONNER
P.Q. BOX 129
MERRY HILL, 1dC 27957
Weil #10 Well #11
PARAMETERS
PHONE [phone]
FAX [phone]
ID## : 1.32
DATE COLLECTED: 11./28/22
DATE REPORTED : 12/21/22
REVIEWED BY:
Analysis Method
Date Analyst Code
Ammonia Nitrogen as N, mg/l
<0.04
10.84
11/30122
KITS
350.1 R2-93
Nitrate Nitrogen as N, mg/1
3.96
0.07
11/30/22
TRJ
353.2 R2-93
Total Phosphorus as P, mg/l
0.08
0.16
12/01/22
TRJ
365.4-74
Total Organic Carbon, mg/l
1.12
9.16
11/30/22
UMM
5310E-14
Chloride, mg/1
82
24
11/30/22
JDJ
4500CLB-11
Total Dissolved Residue, mg/1
440
730
12/01/22
BNC
D5907-13
Calcium, ug/l
22198
13853
12/01/22
MTM
EPA200.7

114 OAKMONT DRIVE
GRUNVILLC, N C 27858
CLIENT: AVOCA, LLC (WASTEWATER)
MR. 13RIAN CONNER
P.O. BOX 129
MERRY HILL, NC 27957
REVIEWED BY:
VOLATILE ORGANICS
STD. METHODS 620OC-11
�Wastewater IAi 10�
PHONE [phone]
FAX [phone]
CLIENT ID: 132
ANALYST: JAP
DATE COLLECTED: 11/28/22 Page: 1
DATE ANALYZED: 12/02/22
DATE REPORTED: 12/21/22
PARAME4 TE, RS, ugll
Well #5
Well #7
Well #8
Well #9
Well #10
1. Benzene
<0.50
<0.50
<0.50
<0.50
<0.50
2. Broniobenzene
<0.50
<0.50
<0.50
<0.50
<0.50
3. Bromochloromethane
<0.50
<0.50
<0.50
<0.50
<0.50
4. Broniodichloromethane
<0.50
<0.50
<0.50
<0.50
<0.50
5. Bromoforin
<0.50
<0.50
<0.50
<0150
<0.50
6. Bromomethane
<0.50
<0.50
<0.50
<0.50
<0.50
7. N-Butylbenzene
<0150
<0.50
<0.50
<0.50
<0.50
8. Sec-Butylbenzene
<0.50
<0.50
<0.50
<0.50
<0.50
9. Tert-Butylbenzene
<0.50
<0.50
<0.50
<0.50
<0.50
10. Carbon Tetrachloride
<0.50
<0.50
<0.50
<0.50
<0.50
11. Chlorobenzene
<0.50
<0.50
<0.50
<0.50
<0.50
12. Chloroethane
<0,50
<0.50
<0.50
<0.50
<0.50
13. Chloroform
<0.50
<0.50
<0.50
<0.50
<0,50
14. Chloromethane
<0.50
<0.50
<0.50
<0.50
<0.50
15. 2-Chlorotoluene
<0.50
<0.50
<0,50
<0.50
<0,50
16. 4-Chlorotoluene
<0.50
<0.50
<0.50
<0.50
<0.50
17. Dibromochlorometbane
<0,50
<0.50
<0.50
<0.50
<0.50
18. 1,2-Dibromo-3-Chloropropune
<Mo
<0.50
<0.50
<0.50
<0,50
19. 1,2-Dibroinoethane
<0150
<0.50
<0.50
<0.50
<0.50
20. Dibromomethane
<0.50
<0.50
<0.50
<0.50
<0.50
21. 1,2-Dichlorobenzene
<0150
<0.50
<0.50
<0.50
<0.50
22. 1,3-Dichlorobenzene
<0.50
<0.50
<0.50
<0.50
<0.50
23. 1,4-Dichlorobenzene
<0,50
<0,50
<0.50
<0.50
<0.50
24. Dichlorodi(luoromethane
<0.50
<0.50
<0.50
<0.50
<0.50
25. 1,1-Dichloroethane
<0.50
<0.50
<0.50
<0.50
<0.50
26. 1,2-Dichloroethane
<0.50
<0.50
<0.50
<0.50
<0.50
27, 1,1-Dicliloroethene
<0.50
<0.50
<0.50
<0.50
<0.50
28. Cis-1,2-Dicliloroethene
<0,50
<0.50
<0.50
<0.50
<0.50
29. trans-1,2-Dichloroethane
<0150
<0.50
<0.50
<0.50
<0.50
30. 1,2-Dichloropropane
<0.50
<0.50
<0.50
<0.50
<0.50
31. 1,3-Dichloropropane
<0,50
<0.50
<0.50
<0.50
<0.50
32. 2,2-Dichloropropatle
<0,50
<0.50
<0.50
<0.50
<0.50
33. 1,1-Dichloropropene
<0.50
<0.50
<0.50
<0.50
<0.50
34. Cis-1,3-Dlchloropropene
<0.50
<0.50
<0.50
<0.50
<0.50
35. trans-1,3-Dichloropropene
<0.50
<0.50
<0.50
<0.50
<0.50
36. Ethylbenzene
<0.50
<0.50
<0.50
<0.50
<0.50
37. Rexachlorobutadiene
<0.50
<0.50
<0.50
<0,50
<0,50
38. lsopropylbenzene
<0.50
<0.50
<0.50
<0.50
<0.50
39, 4-1sopropyltoluene
<0.50
<0.50
<0.50
<0.50
<0.50
40. Methylene Chloride
<0.50
<0.50
<0.50
<0.50
<0.50
41. Naphthalene
<0,50
<0.50
<0.50
<0.50
<0.50
42. Propylbenzene
<0.50
<0.50
<0.50
<0.50
<0.50
43. Styrene
<0.50
<0.50
<0.50
<0.50
<0.50
44. 1,1,1,2-Tetrachloroethane
<0.50
<0.50
<0.50
<0.50
<0,50
45. 1,1,2,2-Telruchloroethane
<0.50
<0.50
<0.50
<0.50
<0.50
46, Tetrachloroethene
<0.50
<0.50
<0.50
<0.50
<0.50
47. Toluene
<0,50
<0.50
<0.50
<0.50
<0.50
48. 1,2,3-Trichlotobenzene
<0,50
<0.50
<0,50
<0.50
<0.50

grw quo
h (%mpumagd
�'.;.���^ w�^� "�'��'"' ='
'✓'P.
"yea'.. � 3 "-;,' c'..'
.":+°✓;>,���\`� %� �"Y=
..�::%,�,. � G w
� � r
_ ., .,.ter% ., , ,. - „
114 OAKMONT DRIVE
GREENVILLE, N C 2785€3
CLIENT: AVOCA, LLC (WASTEWATER)
MR. BRIAN CONNER
P.O. BOX 129
MERRY HILL, NC 27957
ti
REVIEWED BY: ,��
VOLATILE ORGANICS
STD. METHODS 620OC-11
PHONE [phone]
FAX [phone]
CLIENT ID: 132
ANALYST: UAP
DATE COLLECTED: 11/28/22 Page: 2
DATE ANALYZED: 12/02/22
DATE REPORTED: 12/21/22
PARAMETERS, ug/1
Well #f5
well #f7
Well #J8
Well <#9
Well #10
49. 1,2,4-Trichlorobenzeue
<0.50
<0.50
<0.50
<0.50
<0.50
50. 1,1,1-Trichloroethane
<0.50
<0.50
<0.50
<0.50
<0.50
51. 1,1,2-Trichloroethane
<0.50
<0.50
<0.50
<0.50
<0,50
52. Trichloroethene
<0.50
<0.50
<0.50
<0.50
<0.50
53. Triclilorofluoromethane
<0.50
<0.50
<0.50
<0.50
<0.50
54. 1,2,3-Trichloropropane
<0.50
<0.50
<0.50
<0.50
<0.50
55. 1,2,4-Trlmethylbenzene
<0.50
<0.50
<0.50
<0.50
<0.50
56. 1,3,5-Trimethylbenzene
<0.50
<0.50
<0.50
<0.50
<0,50
57. Vinyl Chloride
<0.50
<0.50
<0,50
<0.50
<0.50
58, Total Xylenes
< 1.00
< 1.00
< 1.00
<1.00
< 1.00
59. Methyl Tert Butyl Ether
<1,00
<1.00
<1.00
<1.00
<1.00

Eww'mf(mmid hm)ff pow6 t�(W
114 OAKMON"I' DRIVE
GREENVILLE, N G, 27858
CLIENT: A'V'OCA, LLC (WASTEWATER)
Mil. BRIAN CONNER
P.O. BOX 129
MERRY HILL, NC 27957
REVIEWED BY: � /L--'-
VOLATILE ORGANICS
STD. METHODS 620OC-11
Naekewater ID:10
PHONE [phone]
FAX [phone]
CLIENT ID: 132
ANALYST: .7AP
DATE COLLECTED: 11/28/22 Page; 3
DATE ANALYZED: 12/02/22
DATE REPORTED: 12/21/22
PARAM1✓T1:RS, ugll
Well #11
1.
13enzene
<0.50
2.
Bromobenzene
<0.50
3.
Brontachloromethane
<0,50
4.
Bromodichloromethane
<0.50
5.
Bromoform
<0.50
6.
Brmnamethane
<0.50
7,
N-Butylbenzene
<0.50
8.
Sec-Butylhenzene
<0.50
9.
Tert Butylbenzene
<0.50
10.
Carbon Tetrachloride
<0.50
11,
Chlorobenzene
<0.50
12,
Chloroelhane
<0.50
13.
Chloroform
0.55
14,
Chloromnethane
<0.50
15.
2-Chlorotoluene
<0.50
16.
4-Chlorotoluene
< 0.50
17.
Dibromochloromethane
<0.50
18.
1,2-Dibromo-3-Chloropropane.
<0.50
19.
1,2-Dibromoethane
<0.50
20.
Dibromomethane
<0.50
21.
1,2-Dichlorobenzene
<0.50
22.
1,3-Dichlorobenzene
< 0.50
23,
1,4-Dichlorobenzene
<0.50
24.
DichloroditInoromethane
<0.50
25.
1,1-Dichloroethane
<0.50
26.
1,2-Dichloroethane
<0.50
27.
1,1-Dichloroethene
< 0.50
28,
Cis-1,2-Dichloroethene
<0.50
29.
trans-1,2-Dichloroethene
<0.50
30.
1,2-Dichloropropane
<0.50
31.
1,3-Dichloropropane
<0.50
32.
2,2-Dichloropropane
< 0.50
33.
1,1-Dichloropropene
< 0.50
34.
Cis-1,3-Dichloropropene
<0.50
35.
trans-1,3-Dichloropropene
<0.50
36.
Rthylbenzene
<0.50
37.
Hexaehlorobutadiene
<0.50
38.
lsopropylbenzene
< 0.50
39.
4-Isopropyltoluene
<0.50
40.
Methylene Chloride
<0.50
41.
Naphthalene
<0.50
42.
Propylbenzene
< 0.50
43.
Styrene
<0.50
44,
1,1,1,2-Tetrachloroethane
<0.50
45.
1,1,2,2-Tetrachloroethane
<0.50
46.
Tetrachloroethane
<0.50
47.
ToIuene
<0.50
48.
1,2,3-Trick lorobenzene
<0.50

Enwuhhmo % wwpoo mbd
k�
�•=#'
v i Dv d a rA#375.
-r- ✓-tea T,�� �
WasteWater lot 10��
114 OAKMONT DRIVE
GREENVILLE, N,C 27858
CLIENT: AVOCA, LLC (WASTEWATER)
MR. BRIAN CONNER
P.O. BOX 129
MERRY HILL, NC 27957
REVIEWED BY: w
VOLATILE ORGANICS
STD. METHODS 620OC-11
PHONE [phone]
FAX [phone]
CLIENT ID: 132
ANALYST: aAP
DATE COLLECTED: 11/28/22 Page: 4
DATE ANALYZED: 12/02/22
DATE REPORTED: 12/21/22
PARAMETERS, ug/1
Well #11
49,
1,2,4-Trichlorobenzene
< 0.50
50,
1,1,1-Trichloroethaue
< 0.50
51,
1,1,2-Trichloroethane
<0.50
52,
Tricliloroethene
<0.50
53,
Trlchlorotlnoromethane
<0.50
54.
1,2,3-Trichloropropane
< 0.50
55.
1,2,4-Trimethylbenzene
< 0.50
56.
1,3,5-Tritnethylbenzene
< 0.50
57.
Vinyl Chloride
<0.50
58.
Total Xylenes
< 1.00
59.
Methy) Tert Bnty) Ether
<1100

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The results set forth Iterem we piovided by SGS Not €h Mm lctl I 1c, e-Hardcoj)v 2. d
Autonittted Report
Technical Report for
Environment 1, Inc
AVOCA LLC; Meriy Hill, NC
132
SGS Job Number: FC1003
Sampling Date: 11/29/22
Report to:
Environment 1, Inc
PO Box 7085
Greenville, NC 27835
[e-mail]
ATTN: Ann Brown
Total number of pages in report: 15
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Ariel Hartney 407-425.6700
Norm Farmer
Technical Directoi
Certifications: FL(E83510), LA(03051), KS(€?-10327), NC(573), NI(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAl3 L2229), AZ(AZ0806), CA(2937), TXJ104704404), PA(68-03573), VA(460177),
AL, AK, AR, CT, IA, KY, MA, MI MS, ND, Nil, NV, OK, OR, IL, UT, VT, WA, Wl, WV
This report shall not be reproduced, except in its entirety, witltout the written approval of SGS.
Test results relate only to samples analyzed
SGS North America Inc • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • lei 407-425-6700 • fax [phone]
St;S is the ticrle autlxirity fi» author#zing cclits or snaihficationti In this dticumciii Please, share your :dims about —
1 of 11
Uiiaulhorizej rrinditication of thss rel}ott is ',[Iictly piohil�itcd how WC cam uivc you better at

Sections:
'fable of Contents
Section1: Sample Summary...................................................................................................
3
Section2: Summary of Hits....................................................................................................
4
Section3: Sample Results........................................................................................................
5
3,1: FC1003-1: EFFLUENT.........................................................................
6
3.2: FC 1003-2: WELL 5......................................................................................................
7
3.3: FC 1003-3: WELL 7...... ............................. ........... ............... .......... I..............................
8
3.4: FC1003-4: WELL 8......................................................................................................
9
3.5: FC1003-5: WELL 9......................................................................................................
10
3.6: FC1003-6: WELL 10....................................................................................................
11
3.7: FC1003-7: WELL 11....................................................................................................
12
Section4: Misc. Forms............................................................................................................
13
4.1: Chain of Custody...........................................................................................................
14
-- 2 of 11

SOS North America Inc.
Sample Summary
Environment 1, Inc
AVOCA LLC; Merzy Hill, NC
Project No; 132
Job No: FC 1003
Sample
Collected
Matrix
Client
Number
Date Time By
Received Code Type
Sample ID
FC1003-1
11/28/22
12:15 RB
12/03/22
AQ
Water
EFFLUENT
FC1003-2
11/28/22
12:40 RB
12/03/22
AQ
Water
WELL 5
FC1003-3
11/28/22
14:15 RB
12/03/22
AQ
Water
WELL 7
FC1003-4
11/28/22
13:25 RB
I2/03/22
AQ
Water
WELL 8
FC1003-5
11/28/22
13:051tB
12/03/22
AQ
Water
WELL 4
FC1003-6 `
11/28/22
13:40 RB
12/03/22
AQ
Water
WELL 10
FC1003-7 ' 11/28/22 12:05 RB 12/03/22 AQ Water WELL I I
H
-
3 of 9 t
--

Summary of Hits
Job Number:
FC1003
Account:
Environment 1, Inc
Project:
AVOCA LLC; Merry Hill, NC
Collected:
11 /28/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
Page 1 of 1
FC1003-1 EFFLUENT
Bromide
95.3
5.0
Mgt]
EPA 300/SW846 9056A
FC1003-2 WELL 5
Bromide
4.6
2.5
mg/l
EPA 300/SW846 9056A
FC1003-3 WELL 7
Bromide
16.9
1.0
mg/1
EPA 300/SW846 9056A
FC1003-4 WELLS
Bromide
6.4
0.50
mg/I
EPA 300/SW846 9056A
FC1003-5 WELL 9
No hits reported in this sample,
FC1003-6 WELL 10
No hits reported in this sample
FC1003-7 WELL 11
Bromide
6.7
2 5
mg/I
EPA 300/SW846 9056A
--� 4 of 1

Sample Results
Report of Analysis
-- 5of1f

SOS North America Inc.
Report of Analysis
Client Sample ID: EFFLUENT
Lab Sample ID: F'C1003-1 Date Sampled: 11/28/22
Matrix: AQ - Water Date Received: 12/03/22
Percent Solids: n/a
Project: AVOCA LLQ Merry Hill, NC
General Chemistry
Analyte Result RL Units DID
Bromide 95.3 5.0 mg/1 10
RL = Reporting Limit
Page 1 of 1 P
Analyzed By Method
12/07/22 07:49 JB EPA 300/SW846 9056A
- sus, _ 6ot 9'.

SGS Nortb America Inc.
Report of Analysis
Client Sample ID: WELL 5
Lab Sample ID: FC1003-2 date Sampled: 11/28/22
Matrix: AQ - Water Date Received: 12/03/22
Percent Solids. n/a
Project: AVOCA LLC; Merry Hill, NC
Page 1 of 1 n
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Bromide 4.6 2.5 mgll 5 12/07/22 10.24 in EPA 300/SW9469056A
RL = Deporting Limit
F-71�'eil
S-Gs"
7of1:

SGS North America lie.
Report of Analysis
Client Sample ID: WELL 7
Lab Sample ID: FC1003-3 Date Sampled: 11/28/22
Matrix: AQ - Water Date Received: 12/03/22
'Percent Solids: nla
Project: AVOCA LLC; Merry Hill, NC
General Chemistry
Analyte Result RL Units DF
Bromide 16.9 1.0 mg/I 2
RL = Repoi ting Limit
Page I of 1
Analyzed By Method
12/07/22 11 26 1B EPA 300/SW846 9056A
s8 of 9'.
us.

SGS North America Inc,
Report of Analysis
Client Sample ID: WELL 8
Lab Sample ID: FC1003-4 Date Sampled: 11/28/22
Matrix: AQ - Water Date Received: 12/03/22
Percent Solids: nla
Project: AVOCA LLC; Merry Hill, NC
General Chemistry
Analyte Result RL units DF
Bromide 6A 0.50 mg/I I
RL = Reporting Limit
Pate 1 of I
Analyzed By Method
12/07/22 11,05 JE EPA 3001SW846 9056A
_US'_ 9 of 1

SGS North America Inc.
Report of Analysis
Client Sample ID: WELL 9
Lab Sample 1D: FC1003-5 Date Sampled: 11/28/22
Matrix; AQ - Water Date Received: 12/03/22
Percent Solids: n/a
Project: AVOCA LLC; Merry Hill, NC
General Chemistry
Analyte Result RL Units DF
Bromide <0,50 0.50 mg/l 1
RL = Reporting Limit
Page 1 of I U
Analyzed By Method
12/07/22 11:46 iB E11A 3001SW846 9056A
su.__ 10 of 1

SGS North America Inc.
Report of Analysis
'llent Sample ID: WELL 10
gab Sample ID: FC1003-6 Date Sampled: L1/28/22
latrix: AQ - Water Date Received: 12/03/22
Percent Solids: n/a
roject: AVOCA LLC; Merry Hill, NC
General Chemistry
Analyte Result RL Units DF
Bromide a < 2.5 2.5 mg/l 5
(a) Dilution required based on initial conductivity reading.
RL = Reporting Limit
Page I of I
Analyzed By Method
12/07/22 12:07 n3 EPA 300/SW846 9056A
��
', 11 of 1:
---S.--

SGS North America Inc.
Report of Analysis
Client Sample ID: WELL 1 I
Lab Sample Ill: 1±C1003-7 Date Sampled: 11/28/22
Matrix: AQ - Water Date Received: 12/03/22
.Percent Solids: n/a
Project: AVOCA LLC; Merry Hill, NC
Page 1 of I
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Bromide 6.7 IS mg/l 5 12/07/22 12:27 JB EPA 300/SW846 9056A
RL = Repoiting Limit
I 12 of 9:

0
Orlando, FL
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
C
13of1!

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FC1003: Chain of Custody
Page l of 2
14of1!
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SGS Sample Receipt Summary
Job Number: FC1003 Client' ENVIRONMENT 1, INC Project AVOCA, LI.0 (WASTEWATER)
Date I Time Received: 12/312022 9'30 00 AM Delivery Method: FEDEX Alrbill Vs. 6051 6653 6525
Therm ID IR 1, Therm CF: 0 2, # of Coolers: 1
Cooler Temps (Raw Measured)'C: Cooler 1' (0 8),
Cooler Temps (Corrected) °C' Cooler 1 (10),
Cooler o a
1 Custody Seats Present
2 Custody Seals Intact
3 Temp cntana achieved
4 Cooler temp verifieallon
5 Cooler media
Tr la Bignk Information
1, Trip Blank present (cooler
2 Trip Blank listed on COC
Y„ .D► N
6d ❑
V ❑
91 ❑
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Ice (gaol
Y or, N _ULA.
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W or NIA .
3 Type OUB Received j
Misc Information
Number of Encores 25-Gram 5-Gram
Test Strip Lot ifs pH 0-3 230315
Residual Chlorine Test Strip Lot #
Comments
Saipplo information
1 Sample labels present on battles
2 Samples preserved properly
3, Suf9clent volumelcontalners recvd for analysis
4 Condition of sample
5, Sample recvd within HT
6, Doles(TimesllDs on COC match Sample Label
7 VOCs have headspace
8 Bottles received for unspecified tests
9 Composdma Instructions clear
IG Voa Soli Kits/Jars received past 48hrs?
11. % Solids Jar received?
12 Residual Chlorine Present?
Number of 5035 Field Kits
pH 10-12 219813A
or
N�Q
Intact
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Number of Lab Filtered Metals
Other, (Specify)
svduol Technician SAMUELM Date 121312022 S 30 00 AM Reviewer
7
Rev Bale ONVI -
i
Date
PC1003: Chaim of Custody
Page 2 of 2
15 of 1.