NC0000175_Regional Office Physical File Scan Up To 12/13/2022

NAME OF FACILITY:
COUNTY:
RALEIGH
Parameters
Arsenic
Unimin Corporation
Mitchell
----------------------
Metals
Barium
Chromium
Lead
----------------------
Fluoride
ASHEVILLE
Parameters
TDS
pH
Bottles
Disposable (Filtered) add preservative
HNO BEFORE taking sample ("P") on lid
of Aottle FILTER LAST
Disposable (Filtered) add preservative
HNO BEFORE taking sample ("P") on lid
of Bottle FILTER LAST
1 liter (Filtered)
Bottles
2 1/2 liters
TOTAL NO. OF WELLS: 2
TOTAL NO. OF BOTTLES: 4 disposables + extra
2 liters _
4 1/2 liters
ADDITIONAL SANPLING REQUESTED (other than Permit requirements):

State of North Cc,,, ,na �
Department of, Environment,
Health and Natural Resources `+ •
Division of Environmental Management
James B. Hunt, Jr., Governor c
Jonathan B. Howes, Secretory O C �
Nann B. Guthrie, Regional Manager
Asheville Regional Office
GROUNDWATER SECTION
July 13, 1994
Mr. Roy Riddle
Unimin Corporation Quartz Operations
Post Office Box 588
Spruce Pine, North Carolina 28777
Dear Mr. Riddle:
Subject: Groundwater Monitor Well Analytical Results
Unimin Corporation
NPDES Permit No. NC0000175
Mitchell County, North Carolina
Attached for your information are copies of the analytical results for
samples collected by this office from the groundwater monitor wells on
June 13, 1994.
If you have any questions, please contact me at [phone].
Sincerely,
C' • o�'`-c �Yc �r-�-c c
Ann C. Rumbough
Environmental Technician
/acr
Attachments
Interchange Building, 59 Woodfin Place, Asheville, N.C. 28801 Telephone [phone] FAX [phone]
An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post -consumer paper

Facility
County
Contact:
MONITOR WELL SAMPLING FIELD LOG
Date: June 13, 1994
Unimin Corporation
Mitchell
Roy Riddle
Vell #
ucNUii
(ft)
I OYVLJ
I (ft)
I rsu"11. .,uiicui
I Pumped
I
I Time
, Remarks
I81t1
115.0
112.5
I Bailed 1 1/2 gal.
i 10:45 AM
I Water contained
(MW-1)
I
I
I
!I fine silt.
181t2
25.0
15.0
+ Bailed 5 gal.
I
111:10 AM
I
I Water clear.
(MW-2)
I
I
I
I
S
S
I
I
I
I
I
I
I
I
I
I

State of North C(- Iina
Department of Environment,
Health and Natural Resources
Division of Environmental Management
James B. Hunt, Jr., Governor
Jonathan B. Howes, Secretary
A. Preston Howard, Jr., P.F., Director -
d
�EHNF1
DIVISION OF ENVIRONMENTAL MANAGEMENT
GROUNDWATER SECTION
August 18, 1993
Mr. Roy Riddle
Unimin Corporation Quartz Operations
Post Office Box 588
Spruce Pine, North Carolina 28777
Dear Mr. Riddle:
Subject: Groundwater Monitor Well Analytical Results
Unimin Corporation
NPDES Permit No. NC0000175
Mitchell County, North Carolina
Attached for your information are copies of the analytical results for
samples collected by this office from the groundwater monitor wells on
June 22, 1993.
If you have any questions, please contact me at (704) 25176208.
Sincerely,
Ann C. Rumbough
,Environmental Technician
ACR/gc
Attachments
Itttr•rchanttc 1lnilding, S') W"-diill r'larc, I'. ). Ilnx ;70, Adirvillc, N.C. 288020370 • Tdcphnnr 704-251-620R
An Prltml Opr wmpity A(Hrnntivr Action fntplr,Ncr

MONITOR WELL SAMPLING FIELD LOG
Date: June 22. 1993
Facility: Unimin Corporation
County: Mitchell
Contact: Roy Riddle
Depth SWL
Well 0 (ft) (ft)
I81t1 15.0 5.3
(MW-1)
I81t2 25.0 I
13.2
(MW-2)
Amt. Bailed/
Pumped
lBailed 5 gal.
Bailed 6 gal
Time
10:25 AM
10:45 AM
Remarks
Water contained fine
silt.
Water clear.

MONITOR WELL SAMPLING FIELD LOG
Date: May 12, 1992
Facility: Unimin Corporation
County: Mitchell
Contact: Tony Crowder
Depth STkL
Well (ft) (ft)
I81t1 15.0 12.1
MW-1
I81t2 25.0 113.5
MW-2
Amt. Bailed/
Pumped
Bailed 2 gal.
Bailed 6 gal
Time
10:40 AM
11:05 AM
Remarks
Water contained fine
silt
Water clear

State of North Carolina
Department of Environment, Health, and Natural Resources
Asheville Regional Office
James G. Martin, Governor
William W. Cobey, Jr., Secretary DIVISION OF ENVIRONMENTAL MANAGEMENT
GROUNDWATER SECTION
July 15, 1992
Mr. Roy Riddle
Unimin Corporation.Quartz Operations
Post Office Box 588
Spruce Pine, North Carolina 26777
Dear Mr. Riddle:
Subject: Groundwater.Monitor Well Analytical Results
Unimin Corporation
NPDES Permit No. NC0000175
Mitchell County, North Carolina
Ann B. Orr
Regional Manager
Attached for your information are copies of the analytical results for
samples collected by this office from the groundwater monitor wells on May 12,
1992.
If you have any questions, please contact me at [phone].
ACR/gC
Attachments
Sincerely,
Ann C. Rumbough
Environmental Technician
Interchange Building, 59 Woodfin Place, Asheville, N.C. 28801 • Telephone [phone]
An Equal Opportunity Affirmative Action Employer

State of North Carolina
Department of Environment, Health, and Natural Resources
Asheville Regional Office
James G. Martin, Governor Ann B. Orr
William W. Cobey, Jr., Secretary Regional Manager
DIVISION OF ENVIRONMENTAL MANAGEMENT
GROUNDWATER SECTION
,Tune 9, 1992
Mr. Roy Riddle
Unimin Corporation Quartz Operations
Post Office Box 588
Spruce Pine, North Carolina 28777
Dear Mr. Riddle:
Subject: Compliance Monitoring Data Review
Unimin Corporation
NPDES Permit No. NC0000175
Mitchell County, North Carolina
This office is in receipt of the compliance monitoring data for the March
16, 1992, sample date. In reviewing this data, we find that the Compliance
Monitoring Report Forms are incomplete. Enclosed for future reference are
copies of Compliance Monitoring Report Forms containing information that is to
be provided in compliance monitoring reports submitted to the Groundwater
Section. Also, information requested in the highlighted areas is to be
provided.
Note that well identification numbers have been assigned to each well. It
is necessary to use the numbers provided as they relate to our data entry
records. The previous well identification number, in parenthesis, is given for
reference. If there is any discrepancy between this information and your
records, please notify me so that any future confusion may be eliminated.
I have also enclosed blank copies of the compliance monitoring report
form (GW-59 revised 4/91) to be used in reporting the compliance monitoring
data.
Interchange Building, 59 Woodfin Place, Asheville, N.C. 28801 • Telephone [phone]
An Equal Opportunity Affirmative Action Employer

Mr. Roy Riddle
June 9, 1992
Page 2
If you have any questions or comments regarding compliance monitoring,
please contact me at [phone].
Sincerely,
Ann C. Rumbough
Environmental Technician
ACR/gc
Enclosures
cc: Pace, Incorporated
Betty Wilcox

_:.... ;
YfBQf�MED[.l?A NAGEM � � ROUt1I?,WA,TEI�SE
GROUNDWATER QUALrrY MONITORING [moo ox��g
For addi nd ism cfVR&gGRW& W
COMPLIANCE REPORT FORM or . .Iva
IN
..7i
-_ il' ' Name UIV/MIIV CORPORATION QUARTZ OPERA-rI o.y.5
Box S8B
-5"UCE "O/ACE-, /VC- Z 5777C0U: M17'cl�EcO
1Neli gam• t0,p pUWNaRAoi--MT of LAGoonj
eI tMw- /�fiuroFt.
I Dim r : ° ;) lifetval -S Ft To IS' Ft.
1dla�r s ffl°w measun,�ngt(be ne)saris
aasut a � palm 27ty.Wve lar�M surface
REM��3 EQUIR
Non -Discharge
PjL1D- NG vvooi7
T�YPE.�DISP_t{�A� Y - , � _ BE(N�' ItAC�117Ui�ED
�R�QUIREU
✓ Lagoon Septic TanWDrain Field
Spray Field Subsurface Low -Pressure
Piping (u'P)
Land Application of Sludge
-iel nalysis: RR� Specific Conductance uMhos Temp. °C Odor Appearance
+ate o Collected
cL ra o ; IVartt - lLCecfifira6on ;N000-
COD mg/I
Coliform: MF Fecal /100ml
Coliform: MF Total /100ml
(Note: Use WN fnethod for highly turbid samples)
iss •• ve a s' oli:ds: o
mg/I
6p en an[yzed
units
TOC
mgA
Chloride
mgA
4 Ar-eMIe
mg/I
,'Grease and Oils
mgA
Hardness: Total
mgA
Phenol
mgA
Sulfate
mgA
Specific Conductance
uMhos
Total Ammonia
mg/l
TKN as N
mgA
Nitrite (NO 2) as N
mgA
Nitrate (NO as N
mg/I
g)
Phosphorus: Total as P
mgA
Al - Aluminum
mgA
(BU-- anTM
m9A
Ca - Calcium
mgA
Cd - Cadmium
mg/I
bro r =' • _ Tr tall
mgA
Cu - Copper
mgA
Fe - Iron
mg/I
Hg - Mercury
mgA
K - Potassium
mgA
Mg - Magnesium
mgA
Mn - Manganese
mgA
Na - Sodium
mgA
I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE.
Wvate.
Other
Distributor
Ni - Nickel
mgA
jp,Lead
.mgA
Zn - Zlnc
mgA,-
Pesticides/Herbicides
(Speafy Compounds)
ugA
ugA
ugA
Other (Specify Compounds and
Concentration units)
Note: Values should reflect dissolved and
colloidal concentrations. (see #2 on back)
` See back for instructions.
" Submit blue, green, and yellow copies only to address above.
REV. 4/91

' I -0v
60 WT Lj D
OWEW -G WAMERE M
0 29
GROUNDWATER. :QUALITY MONITORING:'.
COMPLIANCE :FORM::
fm For additional �fomas R�
UA11A11.#V —oR
P, O. 16ox
,rARucC- Pl.,va, NC 29777 Coon
zo 0owV6,RA40tCoV-r of 44Goo,,�J
-- b � 31
V, V, V�e I 10 lca' bnk Mum'
-2 -5' Ft.
:,—^
r -.2 Ft
W%L2 q r �-- � b�
T o -2 -6' Ft.
_e
MI-N-V whp--u 05"
x'ifiUr-aff= -
COD —
Coliform:
Coliform:
MF Fecal
MF Total
Non D' h ogy ��r � E
LM I
tl­EQ I USED
Septic TanWDrain Field
Conductance — uMhos Temp. G odor
ma a �,'LabwSam,6L6�iAnafvz _�
(Note: Use MPN method for highly turbid samples)
— mgA
/1 00ml
/1 00ml
mg/l
--
units
TOC
mgA
Chloride
mgA
LAI �rj: s �en i p
mgA
Grease and Oils
mgA
Hardness: Total
mgA
Phenol
mg/l
Sulfate
mgA
Specific Conductance
uMhos
Total Ammonia
mgA
TKN as N
mgA
Nitrite (NO 2) as N
mgA
Nitrate (NO 3) as N
mgA
Phosphorus: Total as P
mg/l
A] - Aluminum
mgA
mgA
Ca - Calcium
mgA
Cd - Cadmium
mgA
C 5 M-0 t- Tum, - I E I �1711 0—
mgA
Cu - Copper
mg/l
Fe - Iron
mg/l
Hg _ Mercury
mgA
K - Potassium
mg/l
Mg - Magnesium
mgA
Mn - Manganese
mgA
Na - Sodium
mgA
I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE.
,: V �7— � 1 �(d --0r-iZ-e--d�A-g"—n"
Spray Field Subsurface Low -Pressure
Piping (LPP)
Land Application of Sludge
Other
kppearance
Ni Nickel mg/l
mg/l
Zn - Zinc mgA
Pesticides/Herbicides
(Specify Comp . ounds) ugA
ugA
ugA
Other (Specify Compounds and
Concentration units)
Note: Values should reflect dissolved and
colloidal concentrations. (see #2 on back)
• See back for instructions.
submit blue, green, and yellow copies only to address above.
V-59 REV. 4/91

a� a a„M Na••
State of North Carolina
Department of Natural Resources and Community Development
Asheville Regional Office
James G. Martin, Governor I S. Thomas Rhodes, Secretary
DIVISION OF ENVIRONMENTAL MANAGEMENT
GROUNDWATER SECTION
June 8, 1987
Mr. Roy Riddle
Unimin Corporation Quartz Operations
P. 0. Box 588
Spruce Pine, North Carolina 28777
Subject: Monitor Well Analysis
Unimin Corporation
NPDES Permit No. NC0000175
Mitchell County, North Carolina
Dear Mr, Riddle:
Attached are copies of analytical results of monitor well samples that
I collected on March 4, 1987.
I look forward to receiving the analytical results of the resample of
your March 12, 1987, compliance monitoring collection.
Sincerely,
�� 40&4-'�
Kay Dechant
Hydrogeological Technician
KD/ar
cc: Bob Cheek
Attachment
Interchange Building, 59 Woodfin Place, P.O. Box 370, Asheville, N.C. 28802-0370 • Telephone [phone]
An Equal Opportunity Affirmative Action Employer

n SW o
v
State of North Carolina
Department of Natural Resources and Community Development
Asheville Regional Office
James G. Martin, Governor
DIVISION OF ENVIRONMENTAL MANAGEMENT
GROUNDWATER SECTION
June 8, 1987
Mr. Roy Riddle
Unimin Corporation Quartz Operations
P. 0. Box 588
Spruce Pine, North Carolina 28777
Dear Mr. Riddle:
S. Thomas Rhodes, Secretary
l
gv
f RE
JU N 1 1 1987
GROUNU VvHlrn oL'I,TI()N
RALEIGH, N. G,
Subject: Monitor Well Analysis
Unimin Corporation
NPDES Permit No. NC0000175
Mitchell County, North Carolina
Attached are copies of analytical results of monitor well samples that
I collected on March 4, 1987.
I look forward to receiving the analytical results of the resample of
your March 12, 1987, compliance monitoring collection.
KD/ar
cc: ob Cheek
Sincerely,
Kay Dechant
Hydrogeological Technician
>5
J''U� �I - 1987
Groundwater Section
a Asheville Regional Office i
Interchange Building, 59 Woodfin Place, P.O. Box 370, Asheville, N.C. 28802-0370 Telephone [phone]
An Equal Opportunity Affirmative Action Employer

COUNTY
QUAD NO. 7-
SERI AL -NO--,4.
LAT.
Report t6:�� FRO
W S R 0;. %Kinston FO ',,O'thae"-'.
Shipped by: ,Bus, ourier Other
'
COLLECTOR(S): k E­
7
FIELD ANALYSES
0
C fi
PH409 pep. C 94,
d at -25 �Zdda
T 10
0
9 rn P.C.: . q
Ap peiiravlqar'
T, S airip.0
Field AnalystBy"-'.*
ORY,'AL 'N Y­ S
ti
0
IqOD �gh-`3� 114
COD Low 335
-Fecal"
-poliform:MF . 316116—: , fni
"Coliform- I MF Total 31504
0
2.
403
fy� to PH 4.� 410
5 11�01iy to PH 8
its. 44 mg/
Mg 16 onpi3O`44'0`­�'
1002. -tig/v
on, dioxide 405
71�'
'Iqhl6rldo 940,.
Me 0
rqMlbM. 31
-co
Jri� 'Pt
ar,72 �­rng/
1`---`;R'E1S0U R C E S
LAB NUMBER 8
WENT�.­
DATE RECEIVED-.�,,.�\21 Time
�7
n—C,
From: Bus
Rec'd by: -Courier
A L A )QJ R
Other
4'.
1,00TINIE_,�,,
DATA ENTRY, BY: CK:
DATE REPORTED:
MPLIANC LUST, OTHER
�O
(circle
o
0
0 ;A
Mew
4
Flljor
. 06,�N
77T
7
R
N R
N.�
ALI
-W, K A
pt
e.,
u
Revised , 7 8 5
SampleAlnterval — 2d- 2-S
4
Ay ug/l
1,077
_MtiMlnurn 1105 Ug/l
Be, ariurn.;1007 UQ/l
Ca c 1-6 M 916 mg/l
1� M 1027 ug/l
;c ;tI-,-,1034 Ug/l
10412 ug/l
45 Ug/l
9­r�', 9100,11, Ug/l
PUrn :93
e,siurn* 927 mg./I
Mari 99nese 10.55 ug/l
w a mg/l
34 _.,;�Sqdllurn 929r
ug/l
r
Pb U .0 5 1 g/l
I-qf.Mi ' P 1. 147 'Ug . /I
ug/j.
z
y 3jgq
�1. - - e d write
ite "OIS* in block
a n. i Yellow I
A Ow copy Lab
ng time, air temp, etc.)
Organochlorine Pesticides
Organophosphorus Pesticides
Acid Herdicides
Base / Neutral Extractable Organics
Acid Extractable Organics
Purgeable Organics (VOA bottle)
1,2 - Dibrornoethan a (EDB)

It a
< COUNTY aAV t4 Al;
QUAD NO. SERIAL NO h
W.
LAT W•L'ONG,".2
ReportEO,',MRO RRO;'WaRO YV�Rp R
WSRO, .Kinston FO Other; r7 `` x
Shipped by: Bus, Jr.ier f �ihY
160
COLLECTOR(S): ,���OATE
.FIELD 'ANALYSES � w`"i
�?
,pN400� Spec Cond gq.^,_;at250C�����.roc>:
Temp..:I °C Odor �,s10
yr Appearance ` Taste `(
✓ < Sami
FLeId Arlal:y§is By:.'f#eri3
1
LASORAIbRY ANAL' YSESr
plss`'Sol
COW
f ' Fluliddo`9
Hardpess 7
51 ° Hertlnti5s "I
Phenol's; 3'
ti Spoc(Qc C
^' ri f}. aSl1{ti♦te.-:9;�
` Seittdw f1
t •,r
1-4
.�.rpIV
r tJ02 t'3,bc
Pe
" 7 iliiie
sX.10n..0 itw
h ,
720.
� r s ✓ iiJ
L'ab Comments
BOb5i.3.i0`
��/t'.
oli(ofm:MF �Fecat 31816 fir') c' '/1100mi
v
Cotlform;MF 7o1a1.31504
tx `
'1'u{bldity 76
.r•
pF1�'403�}Yx'' x^ units
�,Alkalln(tYto PH 4.5 .410
.
'AIkallnilY to PH B.3 115 ;�ih9/L
r
fb Onale"445. mg/I
p1 �
48l�ettoloet® 440
/►rr3en(c.Total 100Z
Corbon dtaaide. aos.,. °,mglt'
Chrbmiprfl,:He32 ?
Color:Tn� 80
1RAL RSOU
LAB NUMBER 8
:G MENT,
DATE RECEIVED Time
�11 � l r_
Rec'd by: 0 From: Bus hurler
LAB �QRM
1-14
Other
tTY j
DATA ENTRY BY: CK:
1
gERGENY
-2 '7' —If
DATE REPORTED: >I r
A'
E7 �ASELINE
COMPLAINT,('�COMPLIANC LUST, OTHER
�.
t x
(circle Cne4-•--
r;' etc
Al Rumirurm 1105
Bq Bpf1Uln'`1007
Gtt Cn(a(Um..91s'
Od .=; Cadmium 1027
.bhromlumtTotal 1034
Cu CoDPer 1042
,F• tlydn1o45 ' ...
:Potasslum.93,7.
Mg Megnesfum 927.
Manganese 1055
"I" Sodl�um.929.
T Pb
�$a S9Jen(ur6 1-147
Ztnav 09F2
i
4
GW 54 Revised :7l86, �` / For. pissotVed li IySl S; subMitrti Flared sgmp)e ian
`s 11Vhite copy t(dadtbaret p►nk 'copy - Regain
Sample Interval 4_ f
(pumping time, air temp, etc
ug/I
ug/i
ug/I
mg/I
ug/I
ug/I
ug/I
ugh
ug/l
mg/i
mg/I
ug/i
mg/I
ug/i
ug/l
ug/l
ug/1-
write 'DIS' in block
Yellow copy -Lab
Organochlorine Pesticides
Organophosphorus Pesticides
Acid Herdicides
Base / Neutral Extractable Organics
Acid Extractable Organics
Purgeable Organics (VOA bottle)
1.2 - Dibromoethane .(EDB)
A Y
� _✓
Groundwater Section
Asheville Regional Office
i

Unimin
May 18, 1987
V
Kay Dechant
North Carolina Dept. of Natural
Resources and Community Development
Ground Water Section
P. 0. Box 370
Asheville, NC 28802-0370
Dear Ms. Dechant:
Attached are the results from our Monitoring Wells. As
discussed by phone it is believed that well- #1-was contaminated
wf.th-the 'New Bailer-. This well has been re -sampled and as soon
as the results are back from the lab, I will send a copy to
your office.
cc: Andy Regis
Steve Booth
John Thompson
Robert McKenzie
RR/pe
Sinc ely,
oy Riddle
RE s s E H V E_
1 it jCp7
GFOIIndwntl r Svtion
i;,hevi(le 12e inna1 f f r
t
x
0

/ "k 70
MEMO.
� E d; r
},
7CJ °
IIAT 'E.:
SU BAIE C Tj-.
IT
Ou
L) 7)
n of
n Noturall,
North Carolinic Depailme, t of
. ! m m,,, unty, Deg Resources, &CO elopmend

NORTH CAROLINA IRTMENT OF NATURAL RESOURCES & COMM 'Y DEVELOPMENT
WELL RECORD VISION OF ENVIRONMENTAL MANAGEMENT
P.• . Box 27687 — RALEIGH, N.C. 27611 919-733-2020
DRILLING CONTRACTOR �e A)��/7 WELL CONSTRUCTION PERMIT NO.�
1.
WELL LOCATION: (Show sketch of the ation below)'��
Nearest Town: :5-
A/I f, y "o
County: d ^
U . Crl�'V'ii bVa o
Quadrangle No. di ��'e�i`•=�EiO Office
(Roadmmunity or Subdivision and Lot No.)
2.
OWNER: kr10,4'�JONog� 1717me117. CC)rp
DRILLING LOG
3.
ADDRESS : , P14)e ' �� 2: 7 DEPTH
4.
TOPOGRAPHY: draw v�papl�ley,slope,hilltop,flat(circle one)
FROM TO FORMATION DESCRIPTION
S.
USE OF WELL: DATE: ® -
6.
DOES THIS WELL REPLACE AN EXISTING WELL? Ay
7.
TOTAL DEPTH RIG TYPE OR METHOD: J�
8.
FORMATION SAMPLES COLLECTED: YES NO
9.
CASING: Depth Inside .Wall thick. type
Dia. or weight/ft.
From to ft
VC
zo
10. GROUT: Depth Material Method
From to ft
I i Pei o j?ePIN
If additional -space is needed, use bacx or form
11. SCREEN: Depth Dia. Type & Opening
From to ft
5,40
12. GRAVEL: Depth Size Material
From to ft
5 Z5 &WW4 57o P e
13. WATER ZONES(depth):
14. STATIC WATER LEVEL: ft. above top of'casing
below
Casing is ft. above land surface ELEV:
15. YIELD(gpm): METHOD OF TESTING:
16. PUMPING WATER LEVEL: ft.
after hours at gpm.
17. CHLORINATION: Type Amount
18. WATER QUALITY: TEMPERATURE(OF)
19. PERMANENT PUMP: Date Installed
Type Capacity (gpm)HP
Make Intake Depth
Airline Depth
LOCATION SKETCH
(Show distance to numbered roads, or other map reference points)
p� 21 6�)t,
4 41A
� N C, Ca r ', ,�v'Av
20. HAS THE OWNER BEEN PROVIDED A COPY OF THIS RECORD AND INFORMED OF THE DEPARTMENTS REQUIREMENTS AND
RECOMMENDATIONS?
21. REMARKS
I do hereby certify that .t s well was onstructed in accordance with N.C. Well Construction
Regulations and Standards d ha�t�w ecordis true and exact.
J 0 ��
SIGNATURE OF tQQaZtLCTOR W AGENT D
GW-1 Revised 10/1/80 Submit original to Division of Environmental Management and copy to well owner

To
Date Time/V��
WHILE WERE
M
Pho
AREA CODE NUMBER EXTENSION
TELEPHONED
PLEASE CALL
CALLED TO SEE YOU
WILL CALL AGAIN
WANTS TO SEE YOU
URGENT
RETURNED YOUR CALL
Messa
L
�IMM
N. C. Dept. of Natural Resources and Community Development

To:
From:
i
NORTH CAROLINA, DEPA ENT OF NATURAL
RESOURCES AND COMMU1 tTY DEVELOPMENT
Date
19
ACTION
❑ Note and file
❑ Note, initial and forward
❑ Note and return to me
❑ Your comments, please
1-11Note end see me about this
❑ For your information
❑ For your approval
❑ Prepare reply for my signature
❑ Per our conversation
❑ Prepare information for me to reply
❑ Per your request
❑ Please answer, with copy to me

DIVISION OF
ENVIRONMENTAL
MANAGEMENT
Groundwater
Section
State of North Carolina
Department of Natural Resources and Community Development
Asheville Regional Office
James G. Martin, Governor
January 12, 1987
Mr. Roy Riddle
Unimin Corporation Quartz Operation
P. 0. Box 588
Spruce Pine, North Carolina 28777
S. Thomas Rhodes, Secretary
Subject: Compliance Monitoring Reports
Unimin Corporation, formerly International Minerals
& Chemical Corporation
NPDES Permit No. NC0000175
Mitchell County, North Carolina
Dear Mr. Riddle:
Enclosed are copies of the Compliance Monitoring Report Forms dated
January 5, 1987. When submitting the Reports, keep the white copies and
submit the blue and green copies to the Groundwater Section in Raleigh or
the Asheville Regional Office.
Note that the value for chromium for monitor well #2 was reported as
6.0 mg/l. I assume that the correct value is 6.0 ug/l, since chromium was
reported in ug's/1 from monitor well #1. Please contact me if my assumption
is incorrect.
In the future, care should be taken in transcribing analysis data onto
the report forms, so that the correct values will be reflected.
Sincerely,
Kay Dechant
Hydrogeological Technician
KD/ar
Enclosures
cc: Bob Cheek
Interchange Building, 59 Woodfin Place, P.O. Box 370, Asheville, N.C. 28802-0370 • Telephone [phone]
An Equal Opportunity Affirmative Action Employer

WELL DATA TABULATION
POLLUTION SOURCE MONITORING SITE
Facility Name: 64Dor 'r.o/1 County: / I-11CIe/l
Pollution Source (lagoon, landfill, etc.) Latitude: ZA S6 14,
Permit No: Longitude: $a 116,515-9
Non -Discharge:
NPDES:
Well Const.: DHS: Quad No: _T25/t
Sampled By: A; I
Well No.
Date
Installed
Total
Depth
(ft)
Diam.
(in)
Screen(S)/
Open hole
(OH)
(ft-ft)
Grout
Interval
(ft-ft)
Gravel/Sand
Pack
Interval
(ft-ft)
Remarks
s-
A ,
..
,
�o
..
D-
J.
G
12,0 -As
,
Draw a diagram on the reverse side of this form showing map location of the site and the
location (direction and distance) of each well with respect to the pollution source and to
each other. Indicate sampling schedule, parameters and any changes to schedule.
GW-51
Revised 8/20/84

TWIG /17.T�1re0� noun
t-
J
AD
4 4ers
N
�56� acre
c

NORTH CAROLINA
DEPARTMENT OF NATURAL RESOURCES AND COMMUNITY DEVELOPMENT
DIVISION OF ENVIRONMENTAL MANAGEMENT
QUALITY OF WATER DATA (Office)
Location: Town /[& /:he_ County, _ �'f��o
Map . S!1/'eGe rn� TDD
Quad No. ex6l ;
Serial No. A, /3le
% y
Owner = D/®D/Q/i0/1 Depth /,S ft. Diam. in. Yield gpm
An,,; fPr Ad r,,O# Screen
Date
Hour
Discharg6
Temp.
°F
pH
Specific
Conductance
(micromhos)
Chloride
mg/1
Iron
g/1
Hardness
mg/l
Remarks
(taste, odor, appearance,
etc.)
period
g_m
GW-6 Revised 10/1/80

u°a 'cl'i K•",�::7!'+;.4r'..:. .-. ;'(.•:.i;-�wz��cv:; •,�rrta,.L;r+•�3a �:o- +i'
Fax: [phone]
November 6, 1995
Kay Dechant, Hydrogeologist
NC Department of Environment,
Health and Natural Resources
Ground Water Section
59 Woodfin Place
Asheville, NC 28801
Subject: Well abandonment, UNIMIN Corporation Quartz/Feldspar Mitchell County, NC
Dear Ms. Dechant:
As discussed, enclosed please find the Well Abandonment Records for our three (3)
wells located in Mitchell County, NC off -`Highway 226 3 miles Notth of Spruce Pine,NC..
1); Mo_n�to.r�ie_LL(:2�'_'x1.5! )�--.-01-2—yds�cement_g.r_out
2) Monitor well (21lx251) .020 yds. cement grout
3) Drinking water (6110861) 2.8 yds. cement grout
Each well was completely filled with cement after being disinfected.
Should you have any questions please feel free to call me at [phone].
Since
r
.0'
R Riddle
Envi onmental Supervisor
cc: J. Taylor
c. Klimper
T. Haskell
B. Shalter

Q.� 4X4 l
North Carolina
Department of Environment, Health, & Naturat Resources p
Division of Environmental Management Olt j
Groundwater Section
P.O. Box 295-35"- Raleigh, N.C. 27626-'08'35-,
WELL ABANDONMENT RECORD
CONTRACTOR
1. WELL LOCATION: (S w a mil
Nearest Town•
(Road,
2. OWNER: dW IYYC%
omm�u ,
3. ADDRESS: _U
REG. NO.
[-of the I ation back of form.) ,
III) f e' (L Crnm1v �� /1
ivision, Lot No
4. TO
POG�Z/1I'Fi :draw, slope, hilltop, valley, flat
��v-Taw j t w
5. SE OF W .LL: e'( I DATE:
TOTAL 417H: DIAMFrER:
7. CASING REMOVED:
feet diameter
!J Old ee oZ v
8. SEALING MATERIAL:
Neat cement
bags of cement
gals. of water
Sand cement
bags of cement
yds. of sand
Igals. of water
th 1 m eA+
Type ateria
Amount • �� / S
. EXP HOD ZKCEMENT Og MATE
Jq_k � lf�e. Kr W I - eMeVQ)t GI-oLLt
N
t
a
WELL DIAGRAM: Draw a detailed sketch of
the well showing total depth, depth and dia-
p)eter of screens remaining in the well, gravel
interval, intervals of casing perforations, and
depths and types of fill matt�rtls se
Qa+n��ll_ y �erytiek
!� tom- q4
;L)/C,aVJ5
tr7
I do hereby c t. y that this waban o e rec i, rue and exact.
!D a
Signature of Contractor or*Agent Date
WELL LOCATION: Draw a location sketch on the reverse of this sheet, showing the direc-
tion and dlstance of the well to at least two (2) nearby reference points
such as roads, intersections and streams. Identify roads with State High
way road identification members.
Submit original to the Division of Environmental Management, one copy to
and one copy to the owner.
GW-30 Revised 3/8/90
NOY 8 1995
Groundwater Section
A eville Re ' al Ifice

WELL NO. O fi
COUNTY / % C /-I C L L
DATE SAMPLED
/J - 9
ALKALINITY, TO pH 4.5
ALKALINITY, TO pH 8.3
ALUMINUM
ARSENIC
G O.OD
y• U (
4 O. ODy
L !i_ COS
D• ac
BARIUM
G O •
0. v y&,
Q: / l
t D • / O
O
BERYLLIUM
BICARBONATE
CADMIUM
CALCIUM
CARBONATE
CHLORIDE
CFIROMIUM, TOTAL
L O
v 5
J• ODD
1 d d.?D
z d.
COBALT
COD
COLIFORM, FECAL
COLIFORM, TOTAL
COPPER
c. 0• D/
0, 0 /s-
G D• O l
` Q• O i
CYANIDE
DISSOLVED SOLIDS
397
G
/
FLUORIDE
O • i ARo
t7 , i P/iL
HARDNESS CaCo,
HARDNESS, NON -CARBONATE
IRON
LEAD
G• ©. OS
D •y /
G D• O S
d. 0. O
LITHIUM
Red Ink = Sample taken by facility

WELL NO. —T 9 I -t
COUNTY /'% i % e /-f L- L L
DATE SAMPLED
3 ——.9'�
G -/-� y
%— /9- 9�
�i-i5 -9
3-,70-9-5
MBAS
MAGNESIUM
MANGANESE
MERCURY
NICKEL
NITROGEN, AMMONIA
NITROGEN, KJELDAHL
NITRATE & NITRITE
ORGANIC SCAN
PH
PHENOLS
PHOSPHORUS, TOTAL
POTASSIUM
SELENIUM
SILVER
SODIUM
SPECIFIC CONDUCTANCE
SULFATE
TOC (UNFILTERED)
TOY
TSS
VOC
ZINC
STATIC WATER LEVEL.
Ic3o 2
4

WELL
NO. I gltl
Ali
COUNTY i 7G HE L
DATE SAMPLED
%" % - 9.7_
//- / `/ - %.,L
3 - 93
//- r yj
ALKALINITY, TO pH 4.5
ALKALINITY, TO pH 8.3
ALUMINUM
ARSENIC
C,• 00/
C O. OO(
G 0, O0 I
Z / G
z o • oo I
,1
C7 oc7
BARIUM
O. 30
O.IO
Q, io
D• /0
/, p, /o
oe AI
BERYLLIUM
BICARBONATE
CADMIUM
CALCIUM
CARBONATE
CHLORIDE
CHROMIUM, TOTAL
O. 0,2
O. C? ,,-k
L OK 0 ,�
L o, 0 3�
O. 0.2
i 0. 0;4
COBALT
COD
COLIFORM, FECAL
COLIFORM, TOTAL
COPPER
o . 0,2 'r
c (i , of
c. o. o /
� 0 . o /
G
CYANIDE
DISSOLVED SOLIDS
go
3
36
.Sr
FLUORIDE
t o, AR0
HARDNESS CaCo,
HARDNESS, NON -CARBONATE
IRON
LEAD
z. O. D 5�
O , f7
0 .
0- 0 /
0.
LITHIUM
Red Ink = Sample taken by facility

ELL NO.
COUNTY "/ -TC H L- L L.
DATE SAMPLED
MBAS
MAGNESIUM
MANGANESE
MERCURY
NICKEL
NITROGEN, AMMONIA
NITROGEN, KJELDAHL
NITRATE & NITRITE
ORGANIC SCAN
pH�
i
PHENOLS
PHOSPHORUS, TOTAL
POTASSIUM
SELENIUM
SILVER
SODIUM
SPECIFIC CONDUCTANCE
/
SULFATE
TOC (UNFILTERED)
TOX
TSS
VOC
ZINC
STATIC [CATER LEVEL
/ �• �
/ ,�, ()
/� . ��
�• �
/ �; �
f �, ��

ELL
NO. d l ./4/
COUNTY N/ i C H, L
DATE SAMPLED
//- S = %
�'S- i l
7- - `% /
//- %- i !
ALKALINITY, TO pH, 4.5
ALKALINITY, TO pH 8.3
ALUMINUM
ARSENIC
h(D
At p
4 0, OO 1
,0 , o 10
.G 4. v.l
BARIUM
N D
D• 3G
C)• 31
Q
o./y
BERYLLIUM
BICARBONATE
CADMIUM
CALCIUM
CARBONATE
CHLORIDE
CHROMIUM, TOTAL
No
eV 0
< ©° d2
O. 0,2
G 4• Da S
c�• pa
COBALT
COD
COLIFORM, FECAL
COLIFORM, TOTAL
COPPER
0•
O• ®
0• 0A 3
G�
CYANIDE
DISSOLVED SOLIDS®(�
.5
a��o
3o
36
FLUORIDE
/° o' /
HARDNESS CaCo3
..
HARDNESS, NON -CARBONATE
IRON
LEAD
AID
NO
b• 0,5
•G O</
4010/0
. d, d
LITHIUM
Aeo INK = SA/-lpLE %4/GEnr /9y J::7AaiL/-Ty

ALL
NO , -T S /"� /
COUNTY M 17C /-(Z L L
DATE SAMPLED
MBAS
MAGNESIUM
MANGANESE
MERCURY
NICKEL
NITROGEN, AMMONIA
NITROGEN, KJELDAHL
NITRATE & NITRITE
ORGANIC SCAN
PHENOLS
PHOSPHORUS, TOTAL
POTASSIUM
SELENIUM
SILVER
SODIUM
SPECIFIC CONDUCTANCE
2; p
SULFATE
TOC (UNFILTERED)
.i
ZINC
STATIC WATER LEVEL
I a. 3 3
61 56
/ -3. 0 D
/_,7 ,

/ T ,
/SAMPLE►)
-
/
3GZ
11 -- 97
II
3A% =fv i
_59a
9- 9-90
%
LINIT4.5f
� Y TO H
I
,KALINITY, TO pH 8.3
UMI NUM -
I
d U
,RSENIC
`D,D/Z�
�D.oG�S'
,m !
�D,DD s
L ®• adS"I.G®•
ODS'
1 . v /®
4 O. v d.s
ARIUM
140
- 05-6
-e 0. oyo 1.4
- ofa
ICARBONATE
/
ADMI UM
G . O o g
ALCIUM
TiRBONATE
"
�1
MORIDE
iROMIUM, TOTAL
CO.O/!�
�D.DIo
D.I>7�
G D.Q�
L0 - [��1?'
y C7. G�oLD
L . 0�25
L O• D A
)D
I
)LIFORM, FECAL
4
I
I
L
DLIFORM, TOTAL
UPPER
IrJ"q
��.14 716
.
146,010,
,c (,. D/O
t .U®�
0• D�d
(ANIDE
!
I
I-
ISSOLVED SOLIDS
70,
(� ,,. S
I U I
la •
��
•2 0
.JUORIDE
s
Y
d ®' 1
kRDNESS, CaCO
kRDNESS NON -CARBONATE
.L
0/0
< D, 0,.5-
3AS
iGNESI M
—
�N E
;RCURY
,
� bf©

(Continued)
SAMPLET)
dmo
zf L
/ 17 -
1.0
-1 f To I
Y'ROGEN. AMMONIA
/ITROGEN,KJELDAHL
jNITRATE & NITRITE-
ORGANIC SCAN
pH
2-6
PHENOLS
1
PHOSPHORUS, TOTAL
0 ir
POTASSIUM
SELENIUM
v o 6-
3ILVER.
30DIUM
i.
SPECIFIC CONDUCTANCE
3 ULFAT E
10C (UNFILTERED)
'INC
I
V�3
ta G Lt
14127
T-2,
/3, 9 3
1

/it. SAIPLEn
KALINITY CaCO3 To pH--8.3
To pH4.5
b
-
�luminum _
o
�rseni c
4D, 01
Q ®037
.4D. aL
4,01
�.d.oro
�A l>
11Bi carbonate
'7
Cadmi um
O�
�G�DD
Calcium
ICarbonate
--
Chloride
Chlorinated Hydrocarbon
'
Chromium, rlexavalent
Chromium, Total
D 4l
Ol;�"
Q D 2S
COD
Col iform, Fecal
Col i form, Total
Cyanide
Dissolved Solids
.30
Fluoride
Hardness as CaCO
Hardness, Non -carbonate
f
�,
Iron
Lead
40.05
Ue ,l
Li thi um
WAS
Magnesium
Manganese
4trcury
�De6dD�
t_ffi rkP1 __

,�TF SA'lPLEn 3 -
'� 7 49 7
tvogen,. Artmonia ✓� ' S
/itrogen, Kjel dahl "
,Nitrate & Nitrite_ -
Organi c Scan
Phenols
Phosphorus.'Tota1
Potassi um _
_
"
0:3D
Silica
Si fiver
J
Sodium ,.
Specific Conducta�oe
Su'fate}y
Zi nc
D
Barium:D.D%,�3
l�.D6
GD
©07/
Copper:

~. ±''i?TY (CaCC,3)
j
To nN; 8.3
To pN .a.,
# j
E I
t
s eni c
# � . D/ �Q, D.S�
.F
I t
�D D ! ; , Q,5'
7
D-d 140,01
�.0�� 44 D 00
icarbonate
t
D
ad -iii i um
I
E
4
�alcium-
r
,
Carbonate-
h! on as
?
{
I
i
nlorinaLed mydrocaon
E
I1
:hr omium,Nexavalent ►
�.
f
i,
hromium, Total
<D. USi
Ale.
OD
oliform, Fecal
I
-
oliform, Total
i
s
I
anide
l.ssol Ved So i i us
/
✓
I/�. v - .
l.uoride
t
ardness as CaCO3
+
`
rdness, Non Carbonate
-
t.
10.
a.,
Fd /
,Ds,
GD.I
fie.
,4
D.OS
`4,0050 D.D D,3,
th i um
s
f
.
S
i -
nesium
6nese
I �.
Z--,O. ),Odl
1
d. �S
I4a
i
1
�
-
cur
cel
�45 -V.IVI& cdlettW � 0..'- 'gcjdA�f-

t' A-1 L C'
i•:(l� (ConiinUedj
iTE. SA"IPLE�
Itrogen, Ammonia
f
{
0103 `
Itrogen, Ki,eldahi
_
orate Yt Nitrite
i
c
, i
I
panic Scan
.4
I
lhenols
phosphorus. Total
aotassium
+
t
D
.D
I
v
Selenium
}
i
Silica
!
}
f
�il•ver
odium
a
peciric Conductance
3
Iu,l f at e
< J
Iulfite
•nc
C,i
}
d
Z D
� !
4 D..�~
4 D S
ZD
i
G
1
!
I

Type or Use a ball-point pen and press firmly.
PERMIT NUMBER: (REQUIRED)
Facility Name Unimin Corporation
Non-Dischar e
,-Address P. 0. Box 588, 226 Bakersville Hwy.
NPDES ,'— QlJd f7��
Spruce Pine, NC 28777 County
TYPE OF DISPOSAL OPERATION BEING MONITORED
Well Location Iota
(REQUIRED) , j
Ll goon
Septic Tank/Drain Field
Well Identification Number MW#1 Well Depth
'Ft.
Well Diameter Sample (Screened) Interval _/_D Ft. To ��—Ft.
Spray Field
Subsurface Low -Pressure
Depth to Water Level 11.8.4 ft. below measuring point (before sampling)
Land Application of sludge
Piping (LPP)
Cj
Measuring point isabove land surface
Other
_ft.
�Ilons of water pump/bailed before sampling l
Rotary Distributor
p/ Field Analysis: pH • 1 Specific Conductance 15 uMhos Temp. 12 °C
Odor Appearance"=�
Date Sample Collected 3/20/95 Date Lab Sample Analyzed 3/20/95
c--<
Laboratory Name PACE, TncnrnnrnfAd
Certification No. 40
SAMPLES FOR METALS WERE COLLECTED UNFILTERED AND FIELD ACIDIFIED
YES NO
-�
m�
COD mg/I
Coliform: MF Fecal A 00ml
Coliform: MF Total /100ml
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total 21
mg/I
pH (when analyzed)
units
TOC
mg/I
Chloride
mg/I
Arsenic L 0.005
mg/I
irease and Oils
mg/I
hardness: Total
mg/I
Phenol
mg/I
Sulfate
mg/I
Specific Conductance
uMhos
Total Ammonia
mg/I
TKN as N
mg/I
CERTIFY T T THIS REPORT IS TRUE AN[
t
Signature Permittee (or Authorized A )
GW-59 REV. 6/93 ��w
/'/v
Nitrite (NO2) as N
mg/I
Nitrate (NO3) as N
rri�g/I
Phosphorus: Total as P
I"ng/I
Al - Aluminum
mg/I
Ba - Barium L p _ 1 0
mg/I
Ca - Calcium
mg/I
Cd - Cadmium
mg/I
Chromium: Total L 0.020
mg/I
Cu - Copper L 0.01
,mg/I
Fe - Iron
mg/I
Hg - Mercury
mg/I
K - Potassium
mg/I
Mg - Magnesium
mg/I
Mn - Manganese
mg/I
Na - Sodium
mg/I
cn
Ni - Nickel o mg/I
Pb - Lead L 0.05 mg/I
Zn - Zinc mg/I
Pesticides/Herbicides
(Specify Compounds)
ug/I
ug/I
ug/I
Other (Specify Compounds and
Concentration units)
JRATE. Values should reflect dissolved and
Note:JUN 1 9 1995 colloidal concentrations. (see #3 on back) / 'IT L
het A See back for instructions.
Submit blue, green, and yellow copies only to address above.

COLLECTION AND ANALYSIS OF GROUNDWATER SAMPLES ..1
1 . Samples s , hould.be analyzed as soon as possible after collection. SAMPLES WHICH ARE NOT ANALYSED WITHIN THE HOLDING TIME SPECI-
FIED FOR THEII-ETHOD USED (SEE #4. BELOW) MUST BE DISCARDED AND NEW -SAMPLES COLLECTED.
2
3.
4,
Metals Analyses. Use Standard Method-303OC- for sample preparation (mercury excluded). DO NOT FILTER METALS SAMPLES IN THE FIELD
Unfiltered samples must bk,'dlofleilted for'me'A'als, then field acidified with 5 ml concentrated nitric acid per liter of sample, and should be submitted to the
tab within 24 hours.
Sample preparation in the laboratory (extraction and filtration) must be completed within 72 hours of collection.
ANALYSES ARE TO BE MADE OF THE MOBILE CONSTITUENTS (DISSOLVED -AS WELL AS dbLLOIDAL) IN THE
GROU.NDWATER, NOT THOSE THAT ARE A PART OF SEDIMENT ASSOCIATED WITH WELL CONSTRUCTION OR SAMPLING PROCEDURES.
CHICXWITH YOUR LABORATORY ON PROPER PROCEDURES FORS AMPLE COLLECTION- AND, PRESERVATION.
As per TiE�'l 5, North Carolina Administrative Code, Subchapter 2L, analytical 6rocedures shall be in accordance with the methods Cescribed in one of
ffe folloMing publications, or by other methods approved beforehand by the Director, Division of Environmental
Man_agere,ent:
(a) Standard Methods for thb'Examination of Water and Wastewater, 16th Edition, 1985 and I 7th Edition, 1989, published jointly by
American Public Health Association, American Water Works Association and Water, Pollution Control Federation,
(b) Methods for Chemical Analysis of Water and Waste, 1979, U.S. Environmental Protection Agency publication number
EPA-600/4-79-020, as revised March 1983;
(c) Test Methods for 'Evaluating Solid Wastes: Physical/Chemical Methods, 3rd Edition!, 1986, U.S. Environmental Protection Agency
publication number SW-846:
(d) Test Procedures for the Analysis of Polluants Under the Clean Water Act, Federal Register Vol. 49, No. 209, 40 CFR Part 136,
October 26, 1984;
5. Measure and record the depth of water in the well prior to pumping or bailing anywaterfrom the well.
6. At least 3 volumes of water in the well should be pumped or bailed prior to cc - llecting a sample for analysis, If the well is pumped/bailed dry before 3 well
volumes are removed, samples can be collected as soon as the well recovers to the point where enough water is available to collect your sample.
7. Determination for pH, Specific Conductance, temperature, odor and appearance must be made in the field on unfiltered samples when the sample is
collected.
8. Field equipment must be calibrated in accordance with recommendations by the manufacturer.
9. Samples must be filtered through a 0.45 micron filter immediately after collection when a dissolved analysis is required. (See #4. above)
10. The sample container should be labeled at the time of collection with the facility' name", well identification number and date and time collected.
11 "Authorized agent" is any corporate officer or public official authorized by theco npany, corporation, or 'governmental body to sign official docurents.

JUN .80• Q I
ER
unmim'10
Quarlx Operation
P. O. Sax 588
ukerwille Hwy.
Spruce Pine, N. C. 28777
(704) 765-42.83
Fax: [phone]
DELIVER TO:
FROX:
DATE :
AAT'ERIAL BEING TRANSMITTED:
P. I
4
NUMBER OF PAGES: THIS COVER PAG8 PLUS ! � -PAGE(S)
FOR VOICE CONTACT, CALL [phone] Ext.
SUN
- 8 i995 :
Groundvtater Section
A,hevi(ie P.er;Q,ai Office

A
PERMIT NUMBE W(REQUIRED)
NorrDisgh'age
NPDES- ;(-,-
TYPE OF D1SP= OPE4M�BEIN MOG NITQRED
Wen Location 10ta - (REQUIRED)
�- Cf Laacon SepticTanWrait Field
Well Identification Number Its#1 = Well Depth -�,—_Ft
Weil Diameter LSa g le (Smeened) Inteni�. /1: Ft To Z�_FL t� �y �d SuMu � low -Pressure
y
Depth to water Level fL below measuring point (before sampling) t WdApoiiNdm of siuck
Measuring point is —7--fL above land surktoe." a outer
gallons of water pum fled before sampli
Field Analysis: pH • 1 Specrfic Conducwce 15 uMhos Temp. • 12 `oC Odor Apoearance
Date Sample Cotlecled 3/20I95 pite Lab Sample Analyzed 2/20 95
Laboratory Name PACK8 Certification No. 60
SAMPLES FOR METALS WM COLLECTED UNRLTERED AND FIELD ACIDIFIED YES �
Facility Name
Type or use a ball-point pen and press
COD
:cngA
Coliform: MF Feel
000ml
Coliform: MF Total
1100m1
(Not.. Use MPtt method h r highly turbid samples)
Dissolved Solids: Total 21
MgA
T� en analyzed)
units
mgA
Chloride
mgA
Arsenic L 0.005
rrtgA
Grease and Oils
Hardness: Total
m'gA
3henol
mgA
Sulfate
."A
Speodic Conductance
uMhos
Total Ammonia •
MgA
TIN as N
m9A
County
Nitrite (NO2) as N - *
mgA
Nitrate (NO3) as N
Phosphorus: Totai
Zr� ,,
as P
Ift9A .;,
Al -Aluminum
mgA `
Ba-Barium L 0-to
mgA
Ca - Calcium
mgA
Cd - Cadmium
mgA
Chromium: Total L 0.020
Cu -Copper L 0.fii
mg .:.
Fe - Iron
MgA
Hg - Mercury
mgA ;.
K - Potassium
mgA
Mg - Magnesitim
rnw..
Mn-
mgn..
Na-Sodium
mgA-•..
CERTIFY THAT THIS REPORT IS TRUEAND ACCURATE.
Signature Permittee (or Authorized A ate
Ni - Nickel
mgA
Pb - Lead L 0.05
m
Zn - Zinc
_ M9A
Pes9ddes/Herbicides
(Specify Compounds) "
ugA
ugA
ug11
Other (Specify Compounds and
Concentration traits) ._
Note: Values should
and
.colloidal concentrations. (see •111`3 on back)
See beds for instructions:
•` submit blue, green, and yellow copies only to address above.
GW-59 RE . 9193
f..... f ..C.1..,7

Type or Use a ball-point pen and press firmly. PERMIT NUMBER: (REQUIRED)
Facility Name Unimin Corp. Non -Discharge
Address P. 0. Box 588, Spruce Pine, NC 28777 NPDES
County Spruce Pine TYPE OF DISPOSAL OPERATION BEING MONITORED
Well Location Iota (REQUIRED)
Well Identification Number MW#1n SepticTanWDrain Field
Well Depth Ft.Vary�
Well Diameter Sam (Screened) Interval Ft. To FL o - , Field Subsurface Low -Pressure
13. 5 Piping (�P)
Depth to Water Level fL below measuring point (before sampling) , Land Application of sludge
Measuring point is fL above land surface r ^( -j odw
lions of water pumped/bailed before sampling " Rotary Distributor .
_Id Analysis: pH 5.4 Specific Conductance 19 uMhos Temp. 17 °C Odor Appearance
11/15/94 PPe
Date Sample Collected Date Lab Sample Analyzed 11�/15/94
Laboratory Name PACE- Tnn - Certification No. 40
SAMPLES FOR METALS WERE COLLECTED UNFILTERED AND FIELD ACIDIFIED YES NO
COD
Coliform: MF Fecal
Coliform: MF Total
(Note: Use MPH raeeQhod for highly turbid aamples)
_ mgA
/100ml
/100ml
Dissolved Solids: Total t R
mgA
pH (when analyzed) 5.4
units
TOC
mgA
Chloride
mgA
Arsenic L 0.005
mgn
"-ease and Oils
mgA
irdness: Total
mgA
Phenol
mgA
Sulfate
mgA
Specific Conductance 19
uMhos
Total Ammonia
mgA
TKN as N
mgA
I CERTIFY THAT THIS REPORT IS TRUE AND
Signature of Permittee (or Authorized Agent')
Nitrite (NO2) as N
mgA
Nitrate (NO3) as N
rftgA
ZgA
Phosphorus: Total as P
Al - Aluminum
mgA
Ba - Barium L 0.10
mgA
Ca - Calcium
mgA
Cd - Cadmium
mgA
Chromium: Total L 0.020
mgA
Cu - Copper L 0.01
mgn
Fe - Iron
mgA
Hg - Mercury
mgA
K - Potassium
mgA
Mg - Magnesium
mgA
Mn - Manganese
mgA
Na - Sodium
mgA
Ni - Nickel
mgA
Pb - Lead L 0.05
mgA
Zn - Zinc
mgA
Pesticides/Herbicides
(Specify Compounds)
ug/I
ug/I
ug/I
Other (Specify Compounds and
Concentration units)
Note: Values should reflect dissolved and
colloidal concentrations. (see #3 on back)
• See back for instructions.
•• Submit blue, green, and yellow copies only to address above.
GW-59 REV. 6/93

Quartz Operation
P. O. Box 588
Bakersville Hwy.
Spruce Pine, NC 28777
[phone]
Fax: [phone]
.DELIVER TO:
FROM:
DATE:
MATERIAL BE
RrCEIVED/E,i=NR
OEM. Cj-)'0U"Nl) Vv',,TER SE G.
95FEB It$ RIAI1*44
.NUMBER OF PAGES: THIS COVER PAGE PLUS a PAGE(S)
U
FOR VOICE CO TACT, CALL (704) 765- 233 EXT. S
a
x't
EFFEB:211995
GP,OiJ DNJATEI SECTfON
1 AHEVILLE REGIONAL OFFICE

or Use a ball-point pen and press
Facility Name Unimin Corp.
Address P: 0. Box 588, Spruce Pine, NC 28777
County Spruce Pine
Well Location Iota
Well Identification Number MWff1 Well DepthFt
Well Diameter 2"r Sample (Screened) Interval_ Ft. To _L�Ft
Depth to Water Level 13.55 ft. below measuring point (before sampling)
Measuring point is • D ft. above land surface 1
allons of water pumpedthailed before sampling � C/,, Q sS
PERMIT NUMBER: (REQUIRED)
Non -Discharge
NPDES N •6 -D
TYPE OF DISPOSAL OPERATION REfIN-6 MONITORED
(REQUIRED) � �
Lagoon Septic Tank/Drain Field
Spray Field
Land Application of Sludge
Rotary Distributor
,.eld Analysis: pH 5.4 Specific Conductance 19 uMhos Temp. 17 °C Odor Appearance
Date Sample Collected 11 / 15/ 94 Date Lab Sample Analyzed 11 / 15 / 94
Laboratory Name PACE, Inc. Certification No. 40
SAMPLES FOR METALS WERE COLLECTED UNFILTERED AND FIELD ACIDIFIED YES NO
COD
Coliform: MF Fecal
Coliform: MF Total
(Note: Use MPN method for highly turbid samples)
mg/l
A 00ml
/100ml
Dissolved Solids: Total 18
mg/l
pH (when analyzed) 5.4
units
TOC
mg/l
Chloride
mg/I
Arsenic L 0.005
mg/I
rease and Oils
mg/l
..ardness: Total
mg/l
Phenol
mg/l
Sulfate
mg/l
Specific Conductance 19
uMhos
Total Ammonia
mg/l
TKN as N
mg/l
Nitrite (NO2) as N
mg/l
Nitrate (NO3) as N
gA
Phosphorus: Total as P
g/I
Al - Aluminum
mg/I
Ba - Barium
mg/I
Ca - Calcium
mg/I
Cd - Cadmium
mg/l
Chromium: Total L 0.020
mg/I
Cu - Copper L 0.01
mg/l
Fe - Iron
mg/l
Hg - Mercury
mg/l
K - Potassium
mg/l
Mg - Magnesium
mg/l
Mn - Manganese
mg/l
Na - Sodium
mg/l
I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE.
Signatur4 of Permittee (or Authorized Agent*) Date
Subsurface Low -Pressure
Piping (LPP)
Other
-t1 �
n
c
Z71 = r±7
Y25 P
Ni - Nickel �0
55 mg/l
Pb - Lead L 0.05 mg/1
Zn - Zincmg/1
Pesticides/Herbicides
(Specify Compounds)
ug/1
ug/1
ug/1
Other (Specify Compounds and
Concentration units)
1 1
CD r
Note: Values should reflect dissolved and
colloidal concentrations. (see #3 on back)
* See back for instructions.
** Submit blue, green, and yellow copies only to address above.
GW-59 REV. 6/93

1 . Samples should be analvzod,as soon as possible after collection. SAMPLES WHICH ARE NOT ANALYSED WITHIN THOL
DING LDING TIME Sp
I
FIED FOR THE METHOD USED (SEE #4. BELOW) MUST BE DISCARDED AND NEW SAtUIPLES COLLECTED,
2. Metals Analyses: Use Standard ' Method 303.0C for sample preparation (mercury excluded). DO NOT FILTER METALS SAMPLES IN THE: FIELD HI!
Unfiltered samples, must be, collected� or"rri6tais, then field acidified with 5 ml concentrated nitric acid per liter of sample, and should be submitted to the
lab within 24 hours. I -
Sample preparation in the laboratory (extraction and filtration) must be completed within 72 hours of collection.
3. ANALYSES ARE TO BE [,4ADE OF THE MOBILE CONSTITUENTS (DISSOLVED AS WELL AS ol-L.01DAL) jq THE
GROUNDWATER, N P )CE� ES. _QT —.10SE IL AIARE A PART OF SEDIMENT ASSOCIATED WITH WELL!�N 0 R 5 2A. b E ki _NG LL_ j_
CIE Wj J4 YOUR LA60RATORY ON PPOPER PROCEDURES FOR SAMPLE COLLECTmN AND PRESERVATION.
4. As itle;1-5, North Caroiina Administrative Code, Subchapter 2L, analytical procedures shall be in accordance with the methods described in one of
thE'ri5ilbwIM, publications, or by other methods approved beforehand by the Director, Division of Environmental
(a) Standard Methods for the Examination of Water and Wastewater, 16th Edition, 1985 and 17th Edition, 39, published Jointly by
- ' American Public Health Association, American Water Works Association and Wate., Pollution Control Federation;
(b) Methods for Chemical Analysis of Water and Waste, 1979, U.S. Environmental ProtOction Agency publication number
EPA-600/4-79-020, as revised March 1983;
(c) Test Methods for Evaluating Solid Wastes: Physical/Chemical Methods, 3rd Edition, 1986, U.S. Environmental Protection Agency
publication number SW-846;
(d) Test Procedures for the Analysis of Polluants Under the Clean Water Act, Federal Register Vol. 49, No. 209, 40 CFR Part 136,
October 26, 1984;
5. Measure and record the depth of water in the well prior to pumping or bailing any water from the well.
6. At least 3'volumes of water in the well should be pumped or bailed prior to collecting a sample for analysis. If the well is pumped/bailed dry before 3 wel'
volumes are removed, sarriples can be collected as soon as the well recovers to the point where enough water is available to collect your sample_
7. Determination for pH, Specific Conductance, temperature, odor and appearance must be made in the field on unfiltered samples when the sample is
collected. .,-.1 1 -1
� 63
S. Field equipment must be calibrated in accordance with recorrimenclations by the manufacturer.
9. Samples must be filtered through a 0.45 micron filter immediately after collection when a dissolved analysis is required. (See #4. above)
1 O.The sample container should be labeled at the time of collection with the facility name, well identification number and date and time collected.
11. "Authorized agent" is any corporate officer orpublicofficial authorized by ilib.,00tn-piny, corporation, or governmental body to

North Carolina
GROUNDWATER FIELD/LAB FORM DIVISION
of Environment, Health, and Natural Resources
DIVISION OF ENVIRONMENTAL MANAGEMENT- GROUNDWATER SECTION
County /" 11 T C H E LL-
Quad No I. 9-f' t Serial No. ALT 3 6-4
Lat. 3-5' -5-6 / J�- Long. f-9 U 5 S i
Report To: RO FRO, MRO, RRO, WaRO, WiRO,
SAMPLE PRIORITY
�OU{TINE EMERGENCY
CHAIN OF CUSTODY
WSRO, Kinston FO, Fed. Trust, Central Off., Other:
Shipped by: Bus, Courier, and Del Other-
'
M1, ^/N f C K i Purpose:
Collector(s): R u n-i ✓3 v<< G t1Date r ' `j Time /D= ` .6- 11 M Baseline, Complaint, om lian LUST, Pesticide Study, Federal Trust, Other:
IEI Q ANALYSES ,Owner L.Cn/1 /N! 1 rV C OR,00R.4 Tict7 ! Q"A2T Z
pH400 Spec. Cond.94 at 250 C Location or site 0o w ^) G 2A o / cN i D F L A G a nal
Temp.10 oC Odor Description of sampling point
Appearance Sampling Method A i L 15R Sample Interval
Field Analysis By: Remarks �Pu"�' bailer, a"
LABORATORY ANALYSES 5`rAT/c W14TG-� L� �%�IDL.ping ume;iyp.et
BOD 31(
COD High
COD Low
Coliform: P
Coliform: t
TOC 6so
Turbidity 7
Residue.,:
pH 403
Alkalinity tc
Alkalinity tc
Carbonate
Bicarbonat
Carbon dic
Chloride 91
Chromium:
Color: TruE
Cyanide 72
Lab Comments:
Lab Number i'-� & 3
Date Received G -13-`7 Y Time 42 •' o 0
EDRec'd by: From: Bus, Courier, and Del ,
M W - / Other:
Data Entry By: S Ck: I&AP
Date Reported: -qv -G N
GW-54 REV. 6/93 For Dissolved Analysis - submit filtered sample and write "DIS" in block.

GROUNDWATER FIELD/LAD FORM
County /"� �" C, /I C `. L.
Quad No f Serial No. M� 3G �f
Lat. 3S- S i Long. Y.2 0 SI
Report To: 40 FRO, MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO, Fed. Trust, Central Off., Other:
Shipped by: Bus, Hand Del., Other:
North Carolina
Department of Environment, Health, and Natural Resources
DIVISION OF ENVIRONMENTAL MANAGEMENT- GROUNDWATER SECTION
Lab Number �V o -r"
SAMPLE PRIORITY Date Received11 Time --Vb
-
�ROUTINE EMERGENCY Rec'd by:` 5 From: Bus our , Hand Del.,
CHAIN OF CUSTODY MW_ I Other:
Data Entry By: Ck:
Date Reported:
Pur se:
Collector(s): RuMee K �� Date 6- —13- `j`I-Time l V --6-AMBaseline, Complaint, om lianc LUST, Pesticide Study, Federal Trust, Other:
^IELD ANALYSES
NH400 Spec. Cond.94
Temp.to oC Odor
Appearance
Field Analysis By:
LABORATORY ANALYSES
Lab Comments:
at 250 C
circle one,
Owner aly /Mini G a/Z PaR 4 -r1 v.y q `t. ,4 R T Z 0A R.q Ti oys-
Location or site o P L A G c>o Q
Description of samplingpoint v / E L L /a E14 D
Sampling Method A i L ER _ Sample Interval
(Pump, baler etc i
Remarks S 1Ai"/ c W,4-7"J5.E' L t �c _
METAL S�jMP�Es �E Pumputgume,aeto/,0/.) 14AO // `7'"'LW nV 14RO
Urganochlonne Hestiaoes
Organophosphorus Pesticides
Nitroqen Pesticides
I Acid Herbicides I
I Semivolatile Organics I
I I Volatile Organics (VOA bottle) I
TPH - Gasoline Range
r TPH - BTEX Gasoline Range
GW-54 REV. 6/93 For Dissolved Analysis - submit filtered sample and write "DIS" in block.
Ground per y4 r,

Type or Use a ball-point pen and press firmly. PERMIT NUMBER: (REQUIRED)
Facility Name Unimin Corporation Non-Dischar e
Address P. 0. Box 588 NPDES
Spruce Pine, NC 28777 County Mitchel-1 TYPE OF DISPOSAL OPERATION BEING MONITORED
Monitor Well (REQUIRED)
Well Location Lagoon Septic Tank/Drain Field
Well Identification Numbe#1 1 ytZ Well Depth AS_Ft.
Well Diameter 19 ' / Sample (Screened) Interval A2 Ft. To _4Ft.
Depth to Water Level 13.25 ft. below measuring point (before sampling)
Measuring point is 4_ft. above land surface
"allons of water pumped/balled before sampling
eld Analysis: pH 4.7 Specific Conductance 20 uMhos Temp. 16 °C Odor
Date Sample Collected 7/19/94 Date Lab Sample Analyzed 7/19/94
Laboratory Name PACE, Tncor=p=tPA Certification No.
Spray Field Subsurface Low -Pressure
Piping (LPP)
Land Application of Sludge
Other
Rotary Distributor
Appearance
40
SAMPLES FOR METALS WERE COLLECTED UNFILTERED AND FIELD ACIDIFIED __AYES NO
COD
Coliform
Coliform
MF Fecal
M F Total
(Note: Use MPN method for highly turbid samples)
_ mg/I
/100ml
A 00ml
Dissolved Solids: Total
L 1 mg/I
pH (when analyzed)
4.7 units
TOC
mg/I
Chloride
mg/I
Arsenic
L 0.005 mg/I
grease and Oils
mg/1
ardness: Total
mg/I
Phenol
mg/I
Sulfate
mg/I
Specific Conductance
20 uMhos
Total Ammonia
mg/I
TKN as N
mg/I
CERTIFY TTHIS
Q '
gnp6re of Permittee (or Autho
Nitrite (NO2) as N
mg/I
Nitrate (NO3) as N
rri�g/I
Phosphorus: Total as PIg/I
Al - Aluminum
mg/I
Ba - Barium 0.171
mg/I
Ca - Calcium
mg/I
Cd - Cadmium
mg/I
Chromium: Total T. 0.090
mg/I
Cu - Copper 0,015
mg/l
Fe - Iron
mg/I
Hg - Mercury
mg/I
K - Potassium
mg/1
Mg - Magnesium
mg/I
Mn - Manganese
mg/I
Na - Sodium
mg/I
4 Q0t
ter se ,:;,-;� at
Ni - Nickel
mg/I
Pb - Lead L 0.05
mg/I
Zn - Zinc
mg/I
Pesticides/Herbicides
(Specify Compounds)
*
My"
ug/I
ug/I
-r_
ug/I
Other (Specify Compounds -and
Concentration units)s
Note: Values should reflect dissolved and
colloidal concentrations. (see #3 on back)
* See back for instructions.
** Submit blue, green, and yellow copies only to address above.
GW-59 REV. 6/93

1. Samples should be analyzed as soon as possible after collection. SAMPLES WHICH ARE NOT ANALYSED WITHIN THE HOLDING TIME SPECI-
FiED FOR THE METHOD USED (SEE #4. BELOW) MUST BE DISCARDED AND NEW SAMPLES COLLECTED.
2. Metals Analyses: Use Standard. Method 3,030C for sample preparation (mercury excluded). DO NOT FILTER METALS SAMPLES IN THE FIELD!!!
Unfiltered samples must bd cd1lected forrnetals, then field acidified with 5 mi concentrated nitric acid per liter of sample, and should be submitted to the
lab within 24 hours.
Sample preparation in the laboratory (extrectian and filtration) must be completedwithin 72 hours of collection.
3. ANALYSES ARE TO BE MADE OF THE MOBILE CONSTITUENTS (DISSOLVlEbAS WELL AS"COLLOIDAL) IN THE '
GROUNDWATER, NOT THOSE THAT ARE A PART OF SEDIMENT ASSOCIATED WITH WELL CONSTRUCTION OR SAMPLING PROCEDURES.
CHECK WITH YOUR LABORATORY ON PROPER PROCEDURES FOR SAMPLE COLLECTION AND PRESERVATION.
4. As per Title 15, North Carolina Administrative Code; Sabohapter 2i_, analytical procedures shall be in accordance with the methods described in one of
the following publications, or by other methods approved beforehand by the Director, Division of Environmental
Management:
(a) Standard Methods for the Examination of Water and Wastewater, 16th Edition, 1985 and 17th Edition, 1989, published jointly by
American Public Health Association, American Water Works Association and dater Pollution Control Federation;
(b) Methods for Chemical Analysis of Water and Waste, 1979, U.S. Environmental Protection Agency publication number
EPA-600/4-79-020, as revised March 1983;
(c) Test Methods for Evaluating Solid Wastes: Physical/Chemical Methods, 3rd Edition, 1986, U.S. Environmental Protection Agency
publication number SW-846;
(d) Test Procedures for the Analysis of Polluants Under the Clean Water Act, Federal. Register Vol. 49. No. 209, 40 CFR Part 136,
October 26, 1984;
5. iVIG tst r i d record the depth of water in the well prior to pumping or bailing any water from the well.
-.
6. At-ldst,�fumes of water in the well should be pumped or bailed prior to collecting a sample for analysis. If the well is pumped/bailed dry before 3 well
volumes iare removed, samples can be collected as soon as the well recovers to the point where enough water is available to collect your sample.
7. Detdeihindtibn for pH, Specific Conductance, temperature, odor and appearance must be made in the field on unfiltered samples when the sample is
collected. -
Y ,
8. Field equipment must be calibrated in accordance with recommendations by the manufacturer.
9. Samples must be filtered through a 0.45 micron filter immediately after collection when a dissolved analysis is required. (See #4. above)
10.The sample container should be labeled at the time of collection with the facilityn(ame, well identification number and date and -time (30611`ecied.
11."Authorized agent" is any corporate officer or public official authorized Q tth�,'-ccimipan'y. corporation, or governmental body t4�-Qn�fficial dod0rhi ts.

Unimin
Quartz Operation
P. O. Box 588
Bakersville Hwy.
Spruce Pine, NC 28777
[phone]
Fax: [phone]
September 22, 1994
Ground Water Section
Division of Environmental Management
P. 0. Box 29535
Raleigh, NC 27626-0535
Dear Sirs:
Enclosed are the test results of our monitoring wells.
#1-18lt2 and #2-18-lt'l located in Mitchell County, North
Carolina (Spruce Pine).
If you have any questions, please call me at 7o4-765-4283.
cc: D. Voelker
C. Klimper
G. Hughes
File
0
Sinc ely
Roy E. Riddle
Environmental Supervisor
9Z=ilF1V LZOS�6
'03S UNA 011flOJJ 1430
W13iO3A13338

Facility Name
Address
Well Location /'
Please use ink pen and press firmly.
UA1j1y1V 0 eORPOPWI-tOA/
P.Alze NL <2 8777
/ W sJ/IvBz tAj,;
County
Well Identification Number %7%'# / I SOt/ Well Depth Is Ft.
Well Diameter Vv Sample (Screened) Interval ✓0 Ft To 1.5_7 Ft.
Depth to Water Level A" ft. below measuring point (before sampling)
Measuring point is / O ft. above land surface
PERMrr NUMBER: (REQUIRED)
Non -Discharge
NPDES Ali 000017r
TYPE OF DISPOSAL OPERA110N BEING MONrrORED
(REQUIRED)
Lagoon Septic TanWDrain Field
lions of water pumped/bailed before sampling / 0 I
. 'Id Analysis: pH 'y 8 Specific Conductance AF uMhos Temp. /V °C Odor
Date Sample Collected 02- 08-A Date Lab Sample Analyzed a.;r- Off- 9V
Laboratory Name P17ei', ZAICORP0,011'2ri) Certification No.
COD
Coliform:
Coliform:
ma/I
MF Fecal A 00ml
MF Total A 00ml
(Note: Use WN method for highly turbid samples)
Dissolved Solids: Totals
mg/I
pH (when analyzed) !
units
TOC
mg/I
Chloride
mg/I
Arsenic L O• 001
mg/I
crease and Oils
mg/I
hardness: Total
mg/I
Phenol
mg/I
Sulfate
mg/I
Specific Conductance A? uMhos
Total Ammonia
mg/I
TKN as N
mg/I
Spray Field
Land Application
Rotary Distribut
Appearance
Nitrite (NO 2) as N
mg/I
Nitrate (NO 3) as N
mg/I
Phosphorus: Total as P
mg/I
AI - Aluminum
mg/I
Ba - Barium L o• /®
mg/I
Ca - Calcium
mg/I
Cd - Cadmium
mg/I
Chromium: Total L O. 02
mg/I
Cu - Copper L 0. Ql
mg/I
Fe - Iron
mg/I
Hg - Mercury
mg/I
K - Potassium
mg/I
Mg - Magnesium
mg/I
Mn - Manganese
mg/I
Na - Sodium
mg/I
Subsurface Low -Pressure
Piping (LPP)
Ni - Nickel
mg/I
Pb - Lead L 0. or
to
mg/I
Zn - Zinc
4 "
mg/I
Pesticides/Herbicides
'
(Specify Compounds)a.
r
_-°mug/I
�.�
d
;Ug/I
v,—TTF
jug/I
Other (Specify Compound and
-; ,"
Concentration units)
c ri
V�°'`
I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE. Note: Values should reflect dissolved and
colloidal concentrations. (see #2 on back)
�a 3-RY 1 * See back for instructions.
Signaturef of Permittee (or Authorized Agent*) Date " suborn blue, gam, and yell copies only to address above.
GW-59 REV. 9/92

1. Samples should be analyzed as soon as possible after collection. SAMPLES WHICH ARE NOT ANALYSED WITHIN THE HOLDIfft
TIME SPECIFIED FOR THE METHOD USED (SEE #3. BELOW) MUST BE DISCARDED'AND NEW SAMPLES COLLECTED.
2. ANALYSES ARE TO BE MADE'OF THE_ -MOBILE CONS11TUENTS (DISSOLVED AS WELL AS COLLOIDAL) IN THE
GROUNDWATER, NOT THOSE THAT ARE, A PART OF SEDIMENT. CHECK WITH"YOUR LABORATORY ON PROPER
PROCEDURES FOR SAMPLE COLLECTION AND PRESERVATION.
3. As per Title 15, North Carolina Administrative Code, Subchapter 2L, analytical" procedures shall be in accordance with --the, methods
described in one of the following publications, or by other methods approved beforehand by the Director, Division of Environmental
Management:
(a) Standard Methods for the Examination of Water and Wastewater, 1 6th Edition, 1985 and, 17th Edition, - 1989, publishe
jointl� by American Public Health Association, American Water Works Association and Water' Pollution Control Federatio
(b) Methods for Chemical Analysis of Water and Waste, 1979,Environmental Protection Agency publication number
EPA-600/4-79-020, as revised March 1983;
(c) Test Methods for Evaluating Solid Wastes: Physical/Chemical Methods, 3rd Edition, 1986, U.S. Environmental
Protection 'gency publication number SW-846;
(d) Test Procedures for the Analysis of Polluants Under the Clean Water Act, Federal Register Vol. 49, No. 209, 40 CFR
Part 136, October 26, 1984;
4. Measute and record the depth of water in the well prior to pumping or bang any water from the well.
5. At least 3 volumes of water in the well should be pumped or bailed prior to collecting a sample for analysis. If the well is pumped/bailed dr
before.3 -well'volumes are removed, samples can be collected as soon: -as the well recovers to the point where enough water is -available tj
collect, your sample.
6. Determination for pH, Specific Conductance, temperature, odor and appearance must be made in the field on unfiltered samples when the
sample is collected.
7. Field equipment must be calibrated in accordance with recommendations by the manufacturer.
8. Samples must be filtered through a 0.45 micron filter immediately after collection when a dissolved analysis is required. (See #3. above)
9. The sample container should be labeled at the time of collection with the facility name, well identification number and date and time col-
lected.
10."Authorized agenf' is any corporate officer or public official authorized by the company, corporation, or governmental body to sign official
documents.

Please use ink pen and press firmly.
Facility Name 11nimin Corporation
Address
Spruce Pine, NC 28777 County °
Well Location Nov. MW Sampling
Well Identification Number MW#1 18ti Well Depth 1,57 Ft.
Well Diameter,-? / I • Sample (Screened) Interval 10 Ft To —/ �;_ Ft.
Depth to Water Level /y .r ft. below measuring point (before sampling)
Measuring point is / 0 ft. above land surface
illons of water pumped/bailed before sampling I
,ld Analysis: pH 4.5 Specific Conductance 19 uMhos Temp °C
PERMIT NUMBER: (REQUIRED)
Non -Discharge
NPDES W, C, ^::�l
TYPE OF DISPOSAL OPERATION
(REQUIRED)
Lagoon
Spray Field
Septic TanWDrain Field
Subsurface Low -Pressure
Piping (LPP)
Land Application of Sludge
Other
Rotary Distributor
Odor Appearance
Date Sample Collected 11 / 0 9 / 9 3 Date Lab Sample Analyzed 11 / 0 9
/ 9 3
Laboratory Name PACE, Inc.
Certification No.
40
COD
mgA
Nitrite (NO 2) as N
mg/I
Ni - Nickel
y ` ifig/I
Cofrform: MF Fecal
/100ml
Nitrate (NO 3) as N
mg/I
Pb - Lead L 0.1
mg/I
Coliform: MF Total
/100ml
Phosphorus: Total as P
mgA
Zn - Zinc
.mgA
(Note: Use WiPN method for highly turbid samples)
AI - Aluminum
mgA
Pesticides/Herbicides
Dissolved Solids: Total 54
mg/I
Ba - Barium 0.11
mg/I
(Specify Compounds)
A
pH (when analyzed) 4.5
units
Ca - Calcium
mgA
ug/I
TOC
mgA
Cd - Cadmium
mgA
ug/I
Chloride
mgA
Chromium: Total L 0.02
mgA
ug/I
Arsenic 0.004
mgA
Grease and Oils
mgA
lardness: Total
mgA
Phenol
mgA
Sulfate
mgA,
Specific Conductance 19.
uMhos
Total Ammonia
mgA
TKN as N
mg/I
Cu - Copper L 0.01
mgA
Fe - Iron
mgA
Hg - Mercury
mg/I
K - Potassium
mgA
Mg - Magnesium
mg/I
Mn - Manganese
mgA
Na - Sodium
mgA
Other (Specify Compounds and
Concentration units)
I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE. Note: Values should reflect dissolved and
a colloidal concentrations. (see 42 on back)
.AO /Az" /� ' 93 see back for irtslrucdons.
Signature of Per ittee (or Authorized Agent*) Date submit blue, green, and yellow copies only to address above.
GW 59 REV. 9/92

1 . Samples_sl�pulq. HIN THE HO
analyzed as soon as possible after collection. SAMPLES WHICH ARE NOT ANALYSED M LDIN&
TIME SPECIFIED ;FOR THE METHOD USED (SEE a BELOW) MUST BE DISCARDED AND NEW SAMPLES -COLLECTED.
2. ANALYSES ARE TO BE 'MADE OP TH8_ MOBILE CONSTITUENTS (DISSOLVED -_ AS WELL AS COLLOIDAL) IN THE
GROUNDWATER, NOT THOSE THAT ARE A PART OF SEDIMENT.- CHECK WITH YOUR LABORATORY ON PROPE,1�1
PROCEDURES FOR SAMPLE COLLECTION AND PRESERVATION.
3. As per Title 15, North Carolina Administrative Code, Subchapter 2L, analytical procedures skull be in accordance with the methods
described in one of the following publications, or by other methods approved beforehand by the Director, Division of Environmental
Management:
(a) Standard Methods for the Examination of Water and Wastewater, 16th Edition, 1985 and 17th Edition, 1989, published
jointly by American Public Health Association, American Water Works Association and Water Pollution Control Federation;
(b) Methods for Chemical Analysis of Water and Waste, 1979, U.S. Environmental Protection Agency publication number
EPA-600/4-79-020i-,as revised March 1983;
(c) Test Methods for Evaluating Solid Wastes: Physical/Chemical Methods,.3rd Edition, 1986, U.S. Environmental
Protection Agency publication number SW-846;
(d) Test Procedures for the Analysis of Polluants Under the Clean Water Act, Federal Register Vol. 49, No. 209, 40 CFR
Part 136, October 26, 1984;
4. Measure and record the depth of water in the well prior to pumping or bailing any water from the well.
5. At least 3 volumes of water in the well should be pumped or bailed prior to collecting a sample for analysis. If the well is, pumped/bailed dry
before 3 well volumes are removed, samples can be collected as soon as the well recovers to the point Mere enough water is available t,o
collect your sample.
6. Determination for pH, Specific Conductance, temperature, odor and appearance must be made in the field on unfiltered samples when the
sample is collected.
7. Field equipment must be calibrated in accordance with recommendations by the manufacturer.
8. Samples must be filtered through a 0.45 micron filter immediately after collecton when a dissolved analysis is required. (See #3. aboVO7
6. The sample container should be labeled at the time of collection with the facility name, well identification number and date and time col-
lected.
10."Authorized agent" is any corporate officer or public official authorized by the company, corporation, or governmental body to sign officia
documents.

e_r
Facility Name
Unimin
Corporation
PERMIT NUMBER: (REQUIRED)
Non -Discharge
Address
P. 0. Box 588 F. 0NPDES
Spruce
Pine, -NC 28777 County
ON BE
TYPE OF DISP=Lagoon
Well Location
MW, Triannual
(REQUIRED)
Well Identification Number
MW��1 181tl Well. Depth %— Ft.
Well Diameter
Z Sample
(Screened) Interval � Ft. To S"� Ft.
spray Field
Depth to Water Level 13.0 ft. below measuring point (before sampling)
Measuring point is • D ft. above land surface
allons of water pumped/bailed before sampling
rleld Analysis: pH 5~ 4 Specific Conductance 20 uMhos Temp. � C Odor
Date Sample Collected7 / 13/ 93 Date Lab Sample Analyzed- 7 / 13 / 93 -
Laboratory Name PACE, Incorpot:ated Certification
Septic Tank/Drain Feld
Subsurface Low -Pressure
Piping PP)
Land Application of Sludge
Other
Rotary Distributor
CAppearance - Lt , Ll'
No. 40
COD
mg/I
Nitrite (NO 2) as N
mg/I
Ni - Nickel FAIN
II;, NG- mg/f
Coliform: MF Fecal
/100ml
Nitrate (NO 3) as N
mg/I
Pb -"Lead L 0.05
mg/I
Coliform: MF Total
A 00ml
Phosphorus: Total as P
mg/I
Zn - Zinc
mg/I
(Note: Use MPN method for highly turbid samples)
All - Aluminum
mg/I
Pesticides/Herbicides
Dissolved Solids: Total 36
mg/I
Ba -,Barium L 0.10
mg/I
(Specify Compounds)
pH (when analyzed) 5.4
units
TOC
mg/I
Chloride
mg/I
Arsenic T. 0- 001
mg/I
rease and Oils
mg/I
. .ardness: Total
mg/I
Phenol
mg/l
Sulfate
mg/I
Specific Conductance
uMhos
Total Ammonia
mg/I
TKN as N
mg/I
Ca - Calcium
mg/I
Cd - Cadmium
mg/l
Chromium: Total - L n _
n9 mg/I
Cu - Copper L 0.01
mg/I
Fe - Iron
mg/I
Hg .- Mercury
mg/I
K - Potassium
mg/I
Mg - Magnesium
mg/I
Mn - Manganese
mg/I
Na - Sodium
mg/I
u g/I
ug/I
Ug/I
Other (Specify Compounds and
Concentration units)
I CERTIFY THAT HIS REP T IS TRUE AND ACCURATE. Note: Values should reflect dissolved and
j colloidal concentrations. (see #2 on back)
See back for instructions.
Signature of Vrermittee (or Authorized Agent*) Date Submit blue, green, and yellow copies only to address above.
G\-59 REV. 4/91

COLLECTION. -ANALYSIS TSAMPLES
1 Sarnples should be anal ed�: soon'as possible after collection., SAMPLES IC ARE T ANALYSEDI E'• H L I , ..
TIME SPECIFIED FOR E l3 (SEA ELF - E _ SAMPLES LLE^ ED.
2. ANALYSESARE T _._ - 3F THE MOBILE CONSTITUENTS(DISSOLVED WELL AS COLLOIDAL) Ili! E
�. U _ - ATE, NOT T I E THAT P E I @.. C_ _� ' H YOUR DRAT PROPER
4. ,_0 -' EI l� ES- ...8A PLE--COLLECTION P ES ATI
. As per Title 1 , - north Carolina Administrative Code, Subchapter 2L, an*ical procedures shall be, in'accordance with ,the -methods -
described in one of,, the following publications, or by other methods approved beforehand by. the Director, Division of Environmental
Management:
-(a) Standard Methods for -the, _ Examination of Water and Wastewater, 1 th Edition, 19 5. "and 17th Edition; '-'1,989, -publishes
jointly by American- Public Health Association, American Water Works Association and Water Pollution Control Federation;
(b) Methods for Chemical Analysis of iafier and Waste, ` 1979, U.S. Environmental Protection- Agency publication number
- EPA-60014-79-020, as revised - �rrch 1983;
(c) Test Methods-- for. Evaluating -.,Solid -.Wastes: Physicavchemical Methods, 3rd- Edition, 1986, U.S..Environmental
Protection Agency publication number SW-846;
(d) Test- Procedures for the Analysis- of Polluants Under 'the Clean Water Acts Federal Register- Vol.--49-, -No. 209, 40 CFR ,
Part 136, October 26, 1984;
4. Measure and record the depth .cif water in the well prior _to pumping or bailing any water from the well.
5: At least _volumes of water in . the well should be pumped or bailed . prior- to- collecting a sample .for analysis. If the _d ell ispumped/bailed dry,_
before- well volumes are removed, samples can be collected as- soon as� the well;,,recovers to the, point ere_ enough water is avaiiable to .
collect your sample.
6. Determination for pH, Specific Conductance, temperature, -odor and appear mu t be; ,made. iny'the field on unfiltered samples when the,
sample is collected:
7. Field equipment must be calibrated in accorc ance With recommendations by the manufacturer. -
8. Samples., must be filtered -through a A5---micron- filter immediately after- collection when a dissolved analysis - is required. (See #3. above)
9. The sample ntaiher should be labeled at the time of collection with the facility nar,6eg well identification number and date .and time col-
lected.
1 W,ALAhorized, agent" is, any -corporate officer or.,,public official authorized by the company; corporation, or--,gover m ntai � tc sign b iciai }
documents. .

GROUNDWATER FIELD/LAB FORM
North Carolina
Department of Environment, Health, and Natural Resources
DIVISION OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER SECTION
County T a MCI L
Quad No Z 8 t I Serial No. MI 3 G 9-SAMPLE PRIORITY
Lat..3 S S6 Long. 8,2 o b' S 9 ROUTINE EMERGENCY
Report To RO FRO, MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO, Other
Shipped by: Bus, ou Other
as 93 T•)/D: a.5r' 14M Purpose• Baseline Complaini
Lab Number 8
Date Received ��
Rec'd by:
Other
Date Entry By: Ck.
Date Reported- �3
Collector(s): iQuMi.30e- U / Date me f LUST, Other
(biiLR6a
�"� vn� s
LD ANALYSES owner
H Spec. Cond. 94 at 250 C Location or site o �✓M G R.� !J / E 7 0 F is G vc �J
P 400 oC Odor Description of samplin point �/E 4 HEAD
Temp.10 NA I c ER Sample Interval
Appearance Taste Sampling Method pump baI r a�
Remarks S 7 /4 0 C W A -rC r� G 'J l_ L S. 3
Field Analysis By: umpingtime, irtemp.etc.)
LABORATORY ANALYSES MC-T/-I/_ 5/lM/'4C- Sr HAvE /10EmI .�C1a�F�K� /a"�D F��TE�� o d y ,�1�o
(lrnannrhlnnne Pesticides
COD High 340 mgn
COD Low 335
Coliform: MF Fecal 31616
mg/I
/100ml
Coliform: MF Total 31504
/100ml
TOC 680
MO
Turbidity 76
NTU
pH 403
units
Alkalinity to pH 4.5 410
mg/I
Alkalinity to pH 8.3 415
mg/I
Carbonate 445
mg/I
Bicarbonate 440
mg/I
Arsenic' Total 1002 G/Cl
uq/I
Carbon dioxide 405
Chloride 940
m94
mg/I
Chromium: Hex 1032
ug/I
Color: True 80
Pt -Co
Cyanide 720
mg/1
Lab Comments:
Diss. Solids 70300 m /I
A /I - Silver 1077 u
p,5
Flouride 951 z v - m /I
Al -Aluminum 1105 u /I
Hardness: Total 900 m /I
DiS
Ba - Barium 1007 u /l
Hardness non-carb 902 m n
Ca - Calcium 916 m /I
Phenols 32730 u /1
Cd - Cadmium 1027 u /I
Specific Cond. 95 uMhos/cm2
cis
Chromium: Total 1034 -1-25 u n
Sulfate 945 m /I
Cu - Copper 1042 u /I
Sulfide 745 m /I
Fe - Iron 1045 u /I
H - Mercu 71900 u /I
K - Potassium 937 mg/l
Mg - Magnesium 927 mg/I
Mn - Manganese 1055 u /1
Na - Sodium 929 m /1
NH3 as N 610 m /I
Ni - Nickel 1067 u /1
TKN as N 625 m /I
D 1-5
Pb - Lead 1051 u n
NO + NOq as N 630 m /I
Se - Selenium 1147 u /l
P: Total as P 665 m /I
Zn - Zinc 1092 2 u /I
Organophosphorus Pesticides
Nitrogen Pesticides
Acid Herbicides
Base/Neutral Extractable Organics
Acid Extractable Organics
Purgeable Organics (VOA bottle)
1,2 - Dibromoethane (EDB)
GW-54 REV.3/92
For Dissolved Analysis - submit filtered sample and write "DIS" in block
White Copy - Groundwater Central Office Yellow Copy, - Regi-11 Office Pink Copy - Central Files
Goldenrod Copy - Lab

North Carolina
Department of Environment, Health, and Natural Resources
GROUNDWATER FIELD/LAB FORM DIVISION OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER SECTION
County
Quad No Serial No. SAMPLE PRIORITY
Lat. ­2 Long. J []ROUTINE I [—]EMERGENCY
Report To:%,R(?) FRO, MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO, Other
Lab Number 8
Date Received -2 Time
Rec'd by: From: Bus -Courier
eVt V'v' Other
,Date Entry By: Ck.
Date Reported:
Shipped by: Bus, Courier, Other—
Collector(s): 61 k Date '-r Time Purpose: Baseline, Complaint, �LUST, Other
FIELD ANALYSES (circle one)
Owner Ll"LJ'i - - " � - �'­� - t -) i e, '�; t'
*6;H 400 Spec. Cond. 94 at 250 C
Temp.10 oc Odor
Appearance Taste
Field Analysis By:
LABORATORY ANALYSES
0
Location or site
Description of sampling point _VVI L'
Sampling Method -4 j Sample Interval
Remarks (Pump, bailer, etc.)
BOD'5 310 mgA
i -,: 5
Diss. Solids 70300
COD High 340 mgA
!D4 s
Flouride 951
COD Low 335 mg/I
Hardness: Total 90C
Coliform: MF Fecal 31616 A 00ml
Hardness (nonmcarb
Coliform: MF Total 31504 /1 00m I
Phenols 32730
TOC 680 mgA
Specific Cond. 95
Turbidity 76 NTU
Sulfate 945
Sulfide 745
pH 403 units
to pH 4.5 410 mg/l
--Alkalinity
Alkalinity to pH 8.3 415 mg/I
Carbonate 445 mgA
Bicarbonate 440
NH3 as N 610
Arsenic: Total 1002
TKN'as N 625
Carbon dioxide 405 mgA
NO + NO as N 6
Chloride 940 mg/I
P, Total as P 665
Chromium: Hex 1032 ugA
Color: True 80 __Pt -Co
Cyanide 720 mg/I
L
Lab Comments:
GW-54 REV. 3/92 For Dissolved Analysis - submit filtered sample and write "DIS" in block
White Copy - Groundwater Central Office Yellow Copy - Regional Office Pink Copy - Central Files Goldenrod Copy - Lab

PERMIT NUMBER: (REQUIRED)
Facility Name Unimin
Corporation
Non -Discharge
Address P. 0. -Box 588
NPDES 4ye- ODVUI7s
Spruce
Pine, NC 28777
County= G aL%
TYPE OF DISPOSAL OPERATION BEING MONITORED
Well Location 31� Ma*titoring
We" 1S
�%?,i/?o U ��Lagoon
(REQUIRED)
Septic TanWDrain Feld
Well Identification Number
MW it, T- Y/- f
WeISDepth /S Ft.
Well Diameter P Sample
(Screened) Interval
!S
Ft. To Ft.
spray Field Subsurface Low Pressure
Depth to Water Level 12.5
ft. below measuring point (before sampling)
Land Applicator of sludge Piping (LPP)
Measuring point is /• O
ft. above land surface
r,
{ t r
allons of water pumped/bailed
before sampling
Z•S
Rotary Distributor w
—
r-,eld Analysis: pH 5.2
Specific Conductance
uMhos Temp. 11 °C
Odor Appearance
Date Sample Collected 1/9.193
Date
Lab Sample Analyzed 3.1 -41 A R
2 2 ��
Laboratory Name PACE,
Incor-porrued
Certification No. 40
COD
mg/I
Nitrite (NO 2) as N
mg/I
Ni - Nickel
mg/I
Coliform: MF Fecal
/100ml
Nitrate (NO 3) as N
mg/I
Pb - Lead L 0.1
mg/I
Coliform: MF Total
/100ml
Phosphorus: Total as P
mg/I
Zn - Zinc
mg/I
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total 46 (1)
mg/I
Al - Aluminum
Ba - Barium L 0.10
mg/I
mg/l
Pesticides/Herbicides
(Specify Compounds)
pH (when analyzed) 5.2
units
Ca - Calcium
mg/I
ug/I
TOC
mg/I
Cd - Cadmium
mg/I
ug/I
Chloride
mg/I
Chromium: Total L 0-09
mg/I
ug/I
Arsenic L 0.001
mg/I
Cu - Copper L 0.01
mg/I
Other (Specify Compounds and
,ease and Oils
ardness: Total
Phenol
Sulfate
Specific Conductance
mg/I
mg/I
mg/I
mg/I
--uMhos
Fe - Iron
Hg - Mercury
K - Potassium
Mg - Magnesium
Mn - Manganese
mg/I
mg/I
mg/I
mg/I
mg/I
Concentration units)
rwR
Total Ammonia
TKN as N
mg/I
mg/Ia�14�J'`7::`L-�
Na - Sodium mg/I
(1) -Sample analyzed one day out of hold time due
toee " w . ­S nA l F_:ta I, 17
I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE. Note: Values should reflect dissolved and
�j colloidal concentrations. (see #2 on back)
d See back for instructions.
Signature of Permittee (or Authorized Agent*) Date ** submit blue, green,' and yellow copies only to address above.
GW-59 REV. 4/91

COLLECTION AND ANALYSIS OF GROUNDWATER SAMPLES
1. Samples should be analyzed, as soon as possible after collection. SAMPLES WHICH ARE NOT ANALYSED WITHIN THE HOLDING
11ME SPECIFIED FOR THE METHOD USED _ (SEE 43. BELOW) MUST BE. ®ISCARDED AND NEW SAMPLER COLLE ED. .
2. ANALYSES ARE TO, BE MADE -OF THE MOBILE CONSTITUENTS (DISSOLVED AS WELL AS COLLOIDAL) IN THE
GROUNDWATER,- NOT. THOSE -THAT ARE -A PART. OF SEDIMENT. CHECK WITH YOUR LABORATORY -PROPER
PROCEDURES FOR SAMPLE COLLECTION AND PRESERVATION.
3. As per Title 1.5, North Carolina -Administrative Code, Subchapter 2L, analytical procedures shall be, in accordance with the' methods
described in one of -the following publications, or by other methods approved beforehand byAhe Director, Division of Environmental
Management: F:
(a) Standard Methods for the Examination of Water and Wastewater, 16th` Edition, 1985 and 17th Edition, - 1989, publishes
o'ntly by American Public Health Association, American Water Works Association- and Water Pollution Control Federation;
C%l c 3 Methods for Chemical Analysis of Water and Waste, 1979, U.S. Environmental Protection Agency publication number
EPA-600/4-79-020, as revised March 1983; -
(c) Test Methods for Evaluating. Solid Wastes: Physical/Chemical Methods, 3rd Edition, 1986, U.S. Environmental - -
Protection Agency publication number SW-846;
(d) Test Procedures for the Analysis of Polluants Under the Clean Water Act, 'Federal Register Vol. 49, No. 209, 40 -CFR
- Part 136, October 26, 1984;
4. Measure and record the depth of water in the -Well prior to pumping or bailing any water -from the well
5. At least 3 volumes of water in the well should,,be .pumped or bailed prior to collecting a sample for analysis. If the well is pumped/bailed ,dry
before 3. well volumes are removed, samplesi can be collected as soon as the well recovers to the, point where enough water is available tc3
collect your sample, - ' =
6. DeterrnihLion for PSI, Specific Conductance, temperature, odor and appearance must be made1n ,the field on unfiltered samples when the
sample- is collected.
7. Field equipment must be calibrated in accordance with recommendations by the manufacturer.
8. -Samples must :,be fiftered through a 0.45 micron filter immediately after collection when a dissolved analysis is required. (See 3. above).
9. The sample container_ should be' labeled at the time of collection with the facility name, well identification' number and date and time col-
lected.
10 "Authorized agent' is_, any corporate ,offic:er ..or "public official authorized`by 6D "company, 'corporation, or_govemmental body -- to to, official
documents.

Facility Name Unimin Corporation
Address P • 0 • Box 588
Spruce Pine, NC 28777 County Mitchell
Well Location Monitoring Well
Well Identification Number MW AEI X / Well th Ft.
Well Diameter '' r Sample (Screened) Interval'Ft. To Ft.
Depth to Water Level 13.0 ft. below measuring point (before sampling)
^^easuring point is D ft. above land surface ---
allons of water. pumped/bailed before sampling z'S
PERMIT NUMBER: (REQUIRED)
Non-Discha-rgg
NPDES
TYPE OF DISPOSAL OPERATION BEING MONITORED
(REQUIRED)
_k_��Lagoon Septic TanWDrain Feld
Spray Field
Land Application of Sludge
Rotary Distributor
Field Analysis: pH 5.3 Specific Conductance 17 uMhos Temp. 14 °C Odor - Appearance
Date Sample Collected 11 / 19 / 92 Date Lab Sample Analyzed 11 / 19 / 9 2 -
Laboratory Name . PACE, Incorporated Certification No. 40
COD
mg/I
Coliform: MF Fecal
/100ml
Coliform: MF Total
/100ml
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total 80
mg/I
pH (when analyzed) 5.3
units
TOC
mg/I
Chloride
mg/I
Arsenic T. n _ n(11
mg/I
rease and Oils
mg/I
nardness: Total
mg/I
Phenol
mg/I
Sulfate
mg/I
Specific Conductance 17
uMhos
Total Ammonia
mg/I
TKN as N
mg/I
Nitrite (NO 2) as N
mg/I
Nitrate (NO 3) as N
mg/I
Phosphorus: Total as P
mg/I
Al -.Aluminum
mg/I
Ba - Barium L 0.10
mg/I
Ca - Calcium
mg/I
Cd - Cadmium
mg/I
Chromium: Total L 0.02
mg/I
Cu - Copper L 0.01
mg/I
Fe - Iron
mg/I
Hg - Mercury
mg/I
K - Potassium
mg/I
Mg - Magnesium
mg/I
Mn - Manganese
mg/I
Na - Sodium
mg/I
I CERTIFY THAT THIS R T IS TRUE AN ACCURATE. °
(2 zYlz
Signature of PerAttee (or Authorized Agent*) Date
GW-59 REV. 4/91
I
Subsurface Low -Pressure
Piping (LPP)
3 ! 1992
Ni, - Nickel mg/I
Pb - Lead L 0. 05 mg/I
Zn - Zinc f mg/I
Pesticides/Herbicides
(Specify Compounds)
ug/I
ug/I
tis ug/I
Other (Specifyi"ds
Concentration r�,
b,. .,
Note: Values should reflect dissolved and
colloidal concentrations. (see #2 on back).
See back for instructions.
** Submit blue, green, and yellow copies only to address above.

COLLECTION -AND ANALYSIS OF'GROUNDWATER SAMPLES
1. Samples., should be analyzed as soon as possible after collection. SAMPLES WHICH ARE NOT ANALYSED WITHINJHE HOLDING
TIME, R CIl E[? -FOR THE METHOD -USED (SEE #Ki. BELOW) MUST BE DISCARDED AND NEW SAMPLES LLECTECi,
2. ANALYSES ARE. T . -BE MADE OF. THE MOBILE CONSTITUENTS (DISSOLVED AS WELL AS COLLOIDAL) IN THE
GROUNDWATER, NOT, , THOSE -THAT 'ARE A PART OF SEDIMENT. CHECK H YOUR LABORATORY ON PROPER
PROCEDURES FOR SAMPLE COLLECTION AND PRESERVATION.
3: As per Title 15, North Carolina .Administrative Code, Subch .ter 2L anal . a3_ 'roceduies;sAle in accordance with the methods . -
P _ P
described in one of the following publications, or by other methods approved' beforehand' by the Director, Division of Environmental..
Management:
(a) Standard Methods- for the Examination of Water anid Wastewat6r; ­16th Edition, 1985 and 17th Edition, 1989, publishes
jointly by American Public Health Association, American Water Works Associaiiori and Water Pollution Control -Federation;-'
(b) Methods for Chemical Analysis of Water and Waste, 1979, U.S. Environmental Protection Agency publication number
EPA-600/4-79-020, as revised March 1983;
(c) Test Methods for Evaluating- Solid Wastes: Physical/Chemical Methods, 3rd Edition, 1986, U.S. Environmental _
Protection Agency, publication number SW-846;
(d) Test Procedures for the Analysis of Polluants Under the Clean Water Act, Federal Register Vol. - 49, No. 209, 40 CFR
Part 136, October ' 26, 1984;
4. Measure and record the depth of water in the well prior to pumping or bailing any water, from the well.
5. At least'3' volumes of water in the well should be pumped or bailed prior to collecting a sample for analysis. If the well is pumped/bailed dry
before .3 well volumes are removed, samples can be collected as soon as, the well recovers to the point where enough water is available to
collect. your sample:
6. Determination :far pH, Specific Conductance, temperature, odor and appearance must be made in` the field on unfiltered samples when the
sample is,,;calCected.
7. Field equipmeh 'must:."be calibrated in accordance with recommendations by 'the.,,manufacturer.
- 8. Samples must be filtered through - A 0.45 micron filter immediately after collection when a dissolved analysis is required. (See #3._ above)
9. The sample 'container should be ' labeled at the ti' ie of collection with the facility name, well: identification number - and date and time col-
1 O."AtAhorized agent" is any corporate officer ,or'public official 'authorized. -';by- the company, corporation, sr govemmenta I dy. to,
,sign official
documents.

GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM
For additional forms please write or call:
Facility Name Unimin Corporation fB o
Address P. 0. Box 588 In
226 Bakersville Hwy.
Spruce Pine, NC 28777
Well Location Monitbri
1. .s 111V 0{4'+IVO Lt 14V
Well Identification Number MW #I E�i- Wdl llJ11GY�p ht t.
Well Diameter Sample (Screened) Interval S Ft. To %S Ft.
Depth to Water Level 10.5 ft below measurin oint (before s I' )
Division of Environmental Management
Groundwater Section, S�
P.O. Box ISM
Raleigh, NC 27611-7687
[phone]
County
PERMIT NUMBER: (REQUIRED)
Non -Discharge
NPDES Ay C. ODOO7
/e
)F bISPOSAL OPERATION BEING MONITORED
(RE IRE
��. Lagoon
Spray Field
— Septic Tank/Drain Field
Measuring
g point is 1.01
g p amp mg
feet above land surface
—
Land Application of sludge
— ODUJUIIdL;U LUW-rJutibure
Piping (LPP)
_
Gallons of water pumped/bailed
before sampling 2.5
Rotary Distributor
Other
-Field Analysis: pH
5.6 Specific Conductance 12 uMhos
Temp. 13 ° C Odor
Appearance
Date Sample Collected
7/7/92 Date Lab Sample
Analyzed 7/7/92
Laboratory Name -
PACE, Incorporated
Certification No. 40
COD
as
mg/I NO N
2
mg/I Ni -Nickel
mg/'I
Coliform: MF'Fecal
/100ml NO3 as N.
mg/I Pb -Lead
L 0.05 mg/'I
Coliform: MF Total
/100ml Phosphorus: Total as P
mg/I Zn - Zinc
mg/I
Dissolved Solids: Total
36 mg/I Al - Aluminum
mg/I Pesticides/Herbicides.
(Specify Compounds)
pH (when analyzed) 5.6 units
TOC mg/I
Chloride mg/I
Arsenic T. 0.001 mg/I
Grease and Oils
Hardness: Total
Phenol
Sulfate
Specific Conductance
mg/I
mg/I
mg/I
mg/I
12 uMhos
Ba - Barium 0.30 mg/I
Ca - Calcium mg/I
Cd - Cadmium mg/I
Chromium.: Total L 0.02 mg/I
Cu- Copper 0.027 mg/I
Fe - Iron
Hg - Mercury
mg/I
K - Potassium mg/I
Mg - Magnesium mg/I
Total Ammonia(NH3 + NH 4) mg/I Mn - Manganese
TKN as N m I Na - Sodium
I CERTIFY THel,
S REPORT RUE D ACCURATE.
ug/1"
ug/I
I
r
Other (Specify) ____ra
1I
-�n ug/I
Nu i 1•"
ug/I
.mg/I
NOT • "•
mg/I Values should reflect dissolved concentrations
(See #2. on reverse)
ug/1
* See back for Instructions.
** Submit blue, green, and yellow copies DDly to address above.
SIGNATURE OF PERMITTEE'(OR AUTHORIZED AGENT') DATE
r_1ni_r,o Rcv Oion

i A1,1V VSJ�D, wl T; �L
";f e V H a AI aiiv 4
SP�--OHEf,", -11H -PHE MFFTW�t,,-) #3. rv",1.;ST SE SpAN"UPLES COLtX-CTE"'�),
a T 4 01E, E T A R' P XTF
� %
h- U' U A 0 E r- H C CO N -1, 171, 1 , (4
i YOUR L Wi" PSOVEH PROCEDUR'C"'; FOR
�)JXITC-�, Sol j, 1SZ!j)4,1
A E
Aillry ;13ESIE�WAIPOK
A:; mordance vv-t-',�,e endhod's
),r otne�- b,�, 0'�e DXIT,+?ctv, Divlsi:or! Of Erm:uvnental
S&�.-rdlard for he Exam-n:-i?fin 0' %Iiiter EdRion, 1985, pubJshed 'iointi,v by American,
c , (snoki (;ontrol Fed -rat'
!th Assoc ��l 1,,- Amer;Arrier;C,ai I e r C, r A S;1; 0 C; K� o 'a n a ion,
for rht-i-n;[,a, Arlalys, V-ja-"ef -Yiv,r,)trr-nmt P"otection Agency publication number
EF7 --,!-'83as revisedM�,; ,
Mpthods, 3rd '198', ZY En,;ronmenta;
,,c? Mel`nods
11-p -
Federpj Rj:,.-g-ler Vcj�. 40-, "09, 41? "P:.R
f
t, e 1 9 Ei 4
4� It�y VI.P-1 1. om t! depth of 6,-N Z�, ,,:, Vvc;i P,-,Il"j "0
A; '3 o,' in the weii be ".)r plit""r �o car-llys if thp
1, , 1 0- P, NJ mi p -1; "d d r Y
` ,*1l -bta,:o 1�1)OW 0 �aip ca, C ,IS recovts0 'he oin'L et,�4mno�vj,31�r is a,vai,;a blt3 7C,
Fornpi,--,
e 1, 0 C. I C k., 0 Ct "c', a, e C� 24 Z —3 -3 u ma��C- :A,� �ield cr d samiples Otic
I r� L.: ,ii atd- by h. m-3 il iad, zrcw.
li', -3:j
Cto
n fd'a e (.0,

GROUNDWATER FIELD/LAB FORM
County /`I I -fC 14C- LL_
Quad No 1S 1 t 1 Serial No. 144-7 / 3 & S
Lat.. 3.5" 941 / `f Long. 9-2 OS SI?
Report To: FRO, MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO, Other
Shipped by: Bus, C u e ,Other
Collector(s): P"M1301-L C I't Date E R YA
FIELD ANALYSES
PH 400
Temp.10
Appearance
Field Analysis By:
Spec. Cond. 94
_ oC Odor
Taste
SAMPLE PRIORITY
�OUTINE EMERGENCY
North Carolina
Department of Environment, Health, and Natural Resources
DIVISION OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER SECTION
Lab Number 8
Date Received _��f t Time
Rec'd From: Bu ourier
e
Other
Date Entry By: Ck.
Date Reported: t! - 02 �, r7--
Time 10- 410 111"'1 Purpose: Baseline, Complai
Owner UIVJMiAJ CORI`'0RA 7'1
at 250 C
LUST, Other
"ARrz OPC-keI PIVA)s
Location or site L� ®t'`//+J G,�, f Q �,�17' Oft �q G oonl
Description of samplin point r1 EA a
Sampling Method �/I i Leg Sample Interval S^ ^ / 5 I
(Pump, bailer, etc.)
Remarks
1, _jpumping,Gme, air temp. etc.)
LABORATORY ANALYSES 57'-4Tj d W"-f_, 4:4 K i.wI
BOD5 310 m /I Diss. Solids 70300 mg/I A - Silver 1077 u /I Or anochlorine Pesticides
COD High 340 mg/I
pis
Flouride 951 44J m /I
Al - Aluminum 1105 u /I
Organophosphorus Pesticides
COD Low 335 m /I
Hardness: Total 900 m /I
D►s
Ba - Barium 1007 </D u /I
Nitrogen Pesticides
Coliform: MF Fecal 31616 A 00ml
Hardness non-carb 902 m /I
Ca - Calcium 916 m /I
Coliform: MF Total 31504 /100m1
Phenols 32730 u /1
Cd - Cadmium 1027 u /I
Acid Herbicides
TOC 680 m /I
Specific Cond. 95 uMhos/cm2
DISI
Chromium: Total 1034 L /I
Turbidity 76 NTU
Sulfate 945 m /I
Cu - Copper 1042 u /I
Base/Neutral Extractable Organics
Sulfide 745 m /I
Fe - Iron 1045 u /I
Acid Extractable Organics
H - Mercury 71900 u /I
pH 403 units
K - Potassium 937 mg/I
Purgeable Organics (VOA bottle)
Alkalinity to pH 4.5 410 mg/I
Mg - Magnesium 927 mg/I
Alkalinity to pH 8.3 415 mg/I
Mn :_Man anese 1055 u /I
11,2 - Dibromoethane (EDB)
Carbonate 445 mg/I
Na - Sodium 929 m /I
Bicarbonate 440 mg/I
NH3 as N 610 m /I
Ni - Nickel 1067 u /I
DiS
Arsenic: Total 1002 V u /I
TKN as N 625 m /I
DiS
Pb - Lead 1051 u /I
71
Carbon dioxide 405 mg/I
NO + NO3 as N 630 m /I
Se - Selenium 1147 u /I
Chloride 940 mg/I
P: Total as P 665 m /I
Zn - Zinc 1092 u /I
,... ,.
Chromium: Hex 1032 u /I
Color: True 80 Pt -Co
Cyanide 720 mg/I
Lab Comments:
GW-54 P' ' 3/92 For Dissolved Analysis - submit filtered sample and write "DIS" in bl
White Copy - Groundwater Central Office Yellow Copy - Reg- A Office Pink Copy - Central Files Goldenrod Copy - Lab

North Carolina
GROUNDWATER FIELD/LAB FORM Department of•Environment, Health, and Natural Resources
DIVISION OF ENVIRONMENTAL MANAGEMENT -GROUNDWATER SECTION
County Lab Number 8
Quad No. Serial No. SAMPLE PRIORITY Date Received _ Time -
Lat. - Long. F Reed by: From: Bus -Courier
ROUTINE EMERGENCY
. - r
Other - -
Report To:.ARO, FRO,, MRO, RRO, WaRO, WiRO; Date Entry, By: _ _ - Ck.
WSRO, Kinston FO, Other, __- -_ Date Reported:
Shipped by: Bus, Courier, Other
Collector(s) Date Time 4° Purpose:, Baseline, Complain Compliance;, LUST, Other
FIELD ANALYSES Owner
PH 400 Spec. Cond. 94 at, 250 C Location or site
Temp-1 0 oC Odor Description of sampling point r` °
Appearance _ _ -_ _ _ Taste Sampling Method - Sample Interval.
Field Analysis By: Remarks (aurnp, bailer, eco.):
- -. , mninnaimc sir tumn c}c 1
LABORATORY ANALYSES-
BO'D 310 m /I
..
Diss. Solids 70300 m ll'
A='Silver '1077 u /I
Or anochlorine Pesticides
COD High 340 mg/I
Flouride 951 m /I
Al - Aluminum 1105 u /I
Organophosphorus Pesticides
COD Low 335 m /I
Hardness: Total 900 m /I
Ba Barium 1007 u /I
Nitrogen Pesticides
Coliform: MF Fecal 31616 /100ml
Hardness non-carb 002 m /1
_=
Ca - Calcium 916 m 1l
Coliform: NIF Total 31504 A 00m1
Phenols 32730 u /I
Cd - Cadmium 1027 u /f
Acid Herbicides
TOC 680 m /I .
S ecific Cond. 95' 2
uMhos/cm
Chromium: Total 1034 u /I
Turbidity 76 NTU
Sulfate 945 m /I
Cu - Copper 1042 u /I
Base/Neutral Extractable Organics_
Sulfide 745 m /I
Fe - Iron 1045 u A
Acid Extractable Organics
- -
H - Mercury 71900 u /I'
pH 403 units
K -Potassium 937 mg/1'
Purgeabie Organics (VOA bottle)
'
Alkalinity to pH 4.5 410 mg/I
Mg - Magnesium 927 m /I
g
_
Alkalinity8.3 415 m /I
to P H _ 9 .
-
_ _ _
Mn - Manganese 1055 u /I _
1,2 - Dibromoethane. (EDB)
Carbonate 445 mg/I
-
Na - Sodium 929 m /I
Bicarbonate 440 mg/I
NH3 as N 610 m /I'
Ni - Nickel 1067 u /f
Arsenic, Total 1002, u =/I
TKN as N_625 m /I
Pb - Lead 1051 u /I
Carbon dioxide 405 mg/I
-
NO + NO3 as N 630 m /I'-
Se - Selenium 1147 u /I
Chloride 940 mg/I-
PTotal as P 665 m /I
Zn -Zinc 1092 u /I
Chromium: Hex 1032 u /I
Color: True 80 Pt -Co
Cyanide 720 mg/I
Lab Comments:
GW-54 REV. 3/92 For Dissolved Analysis -submit filtered sample and write "DIS" in block
'White Copy - Groundwater Central Office Yellow Copy - Regional Office Pink Copy - Central Files Goldenrod Copy - Lab

GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM
Facility Name
Address
Unimin Corpora
For additional forms please write or call:
Spruce Pine, NC 28777 !
Well Location Monitoring Well
Well Identification Number MW #1 Well Depth Ft.
Well Diameter Sample (Screened), Interval Ft. To Ft.
Division of Environmental Management
Groundwater Section
P.O. Box 27687
Raleigh, NC 27611-7687
[phone]
County
PERMIT NUMBER: (REQU
Non -Discharge —
TYPE OF DISPOSAL OPERIIATl0
(REQUIRED)
— Lagoon
�a l3
MAY 2 7 1992
— Septic Tank/Drain Field
Depth to Water Level
it."below measuring point. (before sampling)
— Spray Field
— Subsurface Low -Pressure
Measuring point is
feet above land surface
— Land Application of Sludge
Piping (LPP)
Gallons of water pumped/bailed before sampling
— Rotary Distributor
Other
Field Analysis: pH`
5.3 Specific Conductance 20 uMhos Temp.
oC Odor
Appearance
Date Sample Collected
3/16//02 Date Lab Sample Analyzed
3/16/92
Laboratory Name
PACE, Incorporated Certification No. 4n
COD
mg/I NO2 as N
mg/I Ni - Nickel
mg/I
Coliform: MF•Fecal
/100ml NO3 as N.
mg/I Pb -Lead
L 0.05 mg/1
Coliform: MF Total
/100ml Phosphorus: Total as P
mg/I Zn - Zinc
mg/I
Dissolved Solids: Total
36 mg/I Al - Aluminum
mg/I Pesticides/Herbicides. (Specify Compounds)
pH (when analyzed)
5.3 units Ba - Barium L 0.10
mg/I
'ug/I
TOC
mg/I Ca - Calcium
mg/I
ug/I
Chloride
rng/I
Cd - Cadmium
mg/I
Arsenic L 0.001
mg/I
Chromium: Total I n_n2
mg/I
Grease and Oils
mg/I
Cu - Copper L 0.01
mg/I
Hardness: Total
mg/l
Fe - Iron
mg/I
Phenol
mg/I
Hg - Mercury
mg/I
Sulfate
mg/I
K - Potassium
mg/I
Specific Conductance 20
uMhos
Mg - Magnesium
mg/I
Total Ammonia (NH H 4)
TKN as N
I CER Y THAPTI-
SIGNATURE OF PERMITTEE
mg/I Mn - Manganese mg/I
mg/I Na - Sodium mg/I
0"PORT IS TRUE AND ACCURAT
AUTHORIZED AGENT") DATE
ug/1
Other (Specify) ug/I
ug/I
ug/I
go 0ug/I.
ug/I
,. TER SE"'I'll' ug/I
I�LEIGO,
NOTE:
Values should reflect diss6lved concentrations
(See #2. on reverse)
* See back for Instructions.
"Submit blue, green, and yellow copies only to address above.
rrw_r%a Pr -xi Sion

2. ANALYSEP,�RE TO BE MADE OF THE CONSITITUENTS DISSOLVED IN THE GROUNDWATER, NOT THOSE THAT ARE A PART
OF, OR ADSbRBED ONTO, SOIL/SEDIMENT PARTICLES. CHECK WITH YOUR LABORATORY ON PROPER PROCEDURES FOR
SAMPLE COLLECTION AND PRESERVATION.
3. As per Title 15, North Carolina Administrative'Code, Subchapter 2L, analytical procedures shall be in accordance with the methods
described in one of the following publications, or by other methods approved beforehand by the Director, Division of Environmental
Management:
(a) Standard methods for the Examination of Water and Wastewater, 16tH Edition, 1985, published jointly by American
Pu' blic Health Association, American Water Works Association and Water Pollution Control Federation;
(b.) Methods for Chemical Analysis of Water and Waste, 1979, U.S.. Environmental Protection Agency publication number
EPA-600/4-79-020, as revised March 1983;
(c) Test Methods for Evaltiating Solid Wastes: Physi6al/Chemical Methods, 3rd Edition, 1986, U.S. Environmental
Protection Agency publication number SW-846;
(d) Test Procedures for the Analysis of Polluants Under the Clean Water Act, Federal Register Vol. 49, No. 209, 40 CFR
Part 136, October 26, 1984;
4. Measure and record the depth of water in the well prior to pumping or bailing any water from the well.
5. At least 3 volumes of water in the well should be pumped or bailed prior to collecting a sample for analysis. If the well is pumped/bailed dry
before 3 well volumes are removed, samples can" be collected as soon as the Well recovers to the point where enough water is available to
collect your sample.
6. Determi.nation-for pH, Specific Conductance, temperature, odor and appearance must be made in the field on unfiltered samples when the
sample is-- cdl'-1— -.16
7. Fie ld-equ ipmeritmust be lbrated in-accordance� with, recommendations by the manufacturer.'
S. Samoll&�m- U�tte Jiltered,torough a 0.45 micron filter immediately after collection when a dissolved analysis is required. (See #3. above)
6r should be labeled at the time of collection with the facility, name, well identification 9. -The sample-contaim number and date and time col-
lected.
1 O."Authorized agent" is any corporate officer or public official authorized by fhe,company, corporation, or governmental-b.ody-to sign official
documents.

GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Division of Environmental Management
Groundwater Section
P.O. Box 27687
Raleigh, NC 27611-7687
Ako For additional forms please write or call: [phone]
Facility Name
Unimin Corporatiori
County
PERMIT NUMBER: (REQUIRED+) a I��-----~^�
Non -Discharge �l
NPDES
i U ii
Il!=f I F
Address P.O. Box 588, 226 Bakersville Hwy.
Y•
- Spruce Pine, NC 28777
Well Location Monitoring Well
Well Identification Number. (`1W #1 Well Depth
Well Diameter Sample (Screened) Interval Ft. To
Ft.
'Ft.
TYPE OF bISPOSAL OPERATION RE1L1P, �MQ 11
(REQUIRED) �( Asheddle ��;fcd al Rr`;ieA _
Lagoon Septic Tank/Drain Field
Depth to Water Level
13.00 ft. below measuring point. (before sampling)
— Spray Field
— Subsurface Low -Pressure
Piping (LPP)
'Measuring point is
feet above land surface
— Land Application of Sludge
Other
Gallons of water pumped/bailed before sampling
— Rotary Distributor
Field Analysis: pH
5.5 Specific' Conductance 19 uMhos Temp. ' 13
o C Odor
Appearance
Date Sample Collected
11/7/91 Date Lab Sample Analyzed-
12/2/91
Laboratory Name
PACE, Incorporated Certification No'._
C_OD
mg/I NO2 as N
mg/I Ni -:Nickel
mg/I
Coliform: MF'Fegal
/100ml NO3 as N.
mg/I Pb - Lead
L 0.1 mg/'I
Coliform: MF Total
/100ml Phosphorus: Total as P
mg/I Zn - Zinc
mg/I
Dissolved Solids: Total
46 mg%I A['- Aluminum
mg/I Pesticides/Herbicides. (Specify Compounds)
pH (when analyzed)
units
TOC
mg/I
Chloride
mg/I
Arsenic L 0.001
mg/I
Grease and Oils
mg/I
Hardness: Total
mg/I
Phenol
mg/I
Ba - Barium L 0.10
mgll
Ca - Calcium
mg/I
Cd - Cadmium
mg/I
Chromium: Total LO.02 mg/I.
Cu - Copper 0.015 mg/I
Fe - Iron mg/1
Hg Mercury mg/I
Sulfate
mg/I
K - Potassium
mg/I
Specific Conductance
uMhos
Mg - Magn.esium
mg/I
Total Ammonia 3 * NH 4�)7
mg/I
Mn - Manganese
mg/I
TKN as / /
mg/I
Na - Sodium
mg/I
FY THIS BEPORT
IS RUE AND ACCURATE.
c �C_
SIGPfATIJWOF PEPMITTEE (OR AUTHORi E AG NT*) DATE
f-21nr_IZZo DGv lion
Other. (SpecI
NOTE:
Values should reflect dissolved concentrations
(See #2. on reverse)
ug/I
ug/I
ug/i
ug/I
ugjl
ug/I
ug/I
ug/I
ug/I
* See back for instructions.
** Submit blue, green, and yellow copies only to address above.

1. Samples S�ould be 'analyzed as soo-n as po . ssibie after collection. SAMPLES WHICH, ARE'NOT ANALYSED WITHIN THE HOLDING
TIME SPECIFIED FOR THE METHOD USW (SEE 4:3. BELOW) MUSt BE DISCARDED ANONEW SAMPLES COLLECTED.
2. ANALYSES ARE TO BE -MADE OF THE CONSITITUENTS DISSOLVED IN THE GROUNDWATER, NOT THOSE THAT AR E. A PART
F8AYS0RBED ONTO,U-SEDIMENT PARTICLES. CHECK WITH YOUR LABORATORY ON PROPER PROCEDURES FOR
--SAMPLE COLLECTION AND -PRESERVATION.
3. As per Title 15, North Carolina Administrative'Cbde, 8ubehapter 2L, analytical procedures shall be in accordance with the methods
described in one of.the following publications, or by other m-elhods approved beforehand by the Director, Division of Environmental
Management: -
(a) Standard methods for the Examination of Water and Wastewater, 16th Editibn,' 1 985,'published jointly lb�, American
y
Public Health Association; American Water Works Association and Water Pollution Control Federation;
(b) Methods for Chemical Analysis of Water, and Waste, 1979, U.S. Environmental Protection Agency publication number
EPA-600/4-79-020, as revised March 1983;
(c) Test Methods foi' Evaluating Solid Wastes: Phydical/Chemical Methods, 3rd Edition, 1986, U.S. Environmental
Protection -Agency publication number SW-846;
(0� Test-.Proceduresfor the Analysis of Polluants Under the -Clean Water Act, Federal Register Vol. 49, No. 209, 40 CFR
Part 136, October 26, 1984;
4. Measure and record.the depth of water in the Well prior to'pumping or bailing any water from the well.
5. At least 3 volumes of water in,1he well --should be.p . Umped or bailed Oriorlo collecting a sample f6'r analysis. If the well is pumped/bailed dry
before-3 we'li'volumes are removed, samples can,be.- collected as soon -as th' e w6l.1 recovers to the point where enough water is available to
6., DetermifiaflopJbi pk_,-`§p-,�,,pific' 6.6niductance, temperature,. odor and 'appie�rande must be made in the field on unfiltered samples when the,
sarnpleis to ildetq
7.'Field equ ipT6nt`rn ust be call bfated,in, accordan cb.with,reco rmn e0dationg -by: themanufacturer.'.
medhit'ly afier.coller *hen'a*di'
BY .8amAles must. be filtered thrbugh a,,0:45--fricrbn.;filter iM ptiop 14, ssofvectanaly§is is required. (See,#3.above}
e b 0 t m0.-,W0J d
iner should b6 led-. at. ifip firh �qf.'c 11[��d h`_ I - .Q .4ql j. T ri 11� if ic tion-nu' and tima-601- -
9. The sample. contai I q.. mber and date'
lected.
lac tizod"15 �Ah* on-y? a. t�ap . . P., - , " f
..1 6.-,Aufh6ft"* ed'�genf -is any coM-or RG ,is 'fhb f, gVernment I:body to �jdn:of icia['
docurnonts..

GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Division of Environmental Management
Groundwater Section
P.O. Box 27687
Raleigh, NC 27611-7687
For additional forms please write or call: [phone]
,
Facility Name 11nimin Corpnrntion County
Address P. 0. Box 588 PERMIT
(REQUIRED)
Spruce Pine, NC 28777
Non -Discharge
Well Location MW
#1
NPDES
Well Identification Number. Well #1 Well Depth Ft.
TYPE OF DISPOSAL OPERATION BEING MONITORED
(REQUIRED)
Well Diameter
Sample (Screened), Interval Ft. To Ft.
Lagoon
Septic Tank/Drain Field
-)epth to Water Level
9.50 ft. below measuring point. (before sampling)
— Spray Field
— Subsurface Low -Pressure
Piping (LPP)
Measuring point is
feet above land surface
Land Application of Sludge
Gallons of water pumped/bailed
before sampling 3
Rotary Distributor
Other
Field Analysis: pH
5.10 Specific Conductance 21 uMhos Temp.
17.5 ° C Odor
Appearance
Date Sample Collected
7/9/91 Date Lab Sample Analyzed
7/17/91
Laboratory Name
PACE, Inc. Certification No.
COD
mg/I NO2 as N
mg/I Ni - Nickel
mg/I
Coliform: MF Fecal
/100ml NO 3 as N.
mg/I Pb -Lead
L 0.05 mg/'I
Coliform: MF Total
/100ml Phosphorus: Total as P
mg/I Zn - Zinc
mg/1
Dissolved Solids: Total
62 mg/I Al - Aluminum -
mg/1 Pesticides/Herbicides.
(Specify Compounds)
PH (when analyzed)
units
TOC mg/I
Chloride mg/I
Arsenic L 0.001 mg/l
Grease and Oils mg/I
Hardness: Total mg/I
Phenol mg/I
Sulfate mg/I
Specific Conducta_nL.Q uMhos
Ba - Barium 0.3.1 mg/I
Ca - Calcium mg/I
Cd - Cadmium mg/I
Chromium: Total L 0.02 mg/I
Cu Copper 0.023 mg/I
Fe Iron
Hg - Mercury _
K - Potassium_
Mg - Magn.esiu
Total Ammo ;a(NH + NH mg/I Mn - ManganeE
TKN as mg/1 Na - Sodium_
IS REPORT IS TRUE AND
Z
SICAATURIrOF
MITTEE_ (OR AUTHORIZED AGENT")
CCU
�G
DATE
s. .
t
mg
GROUNDWATER SECTION
i E REGIQw14 OFFICE mg
"ug/I
ug/I
ug/1
Other (Specify) ---o
e �v
P
ug/I
ug/I
ug/I
ti g t
ug/I
Plus
ug/L"
NOTE: RALEIGH. N
ug/I
Values should reflect dissolved concentrations
(See #2. on reverse)
* See back for instructions.
** Submit blue, green,, and yellow copies only to address above.
t-21ALCO ow Dion

zedo
, I I f , T ---
2. ANALYSES ARE TO BE MADE OFTHE CONSITITUENTS DISSOLVED IN THE GROUNDWATER, NOT THOSE THAT A RE A PART
OF, OR ADSORBED ONTO, SOIL/SEDIMENT PARTICLES. CHECK WITH YOUR LA130RATORY ON PROPER PROCEDURES FOR
'SAMPLE COLLECTION AND PRESERVATION.
3. As per Title 15, North Carolina Administrative Code, Subchapter 2L, analytical procedures shall be in accordance with the methoc
me
described in one of the following publications, or by other methods approved beforehand by the Director, Division of Environ _nt]
Management:
(a) Standard methods for the Examinhtion of Water and Wastewater, 16th'Edition, 1985, published jointly by American
Public Health Association, American Water Works Association and Water Pollution Control Federation;
(b) Methods ' for Chemical Analysis of Water and Waste, 1979, U.S. Environmental Protect -ion Agency publication number
EPA-600/4-79-020, as revised March 1983;
(c) Test Methods for EvalUating Solid Wastes: Physical/Che mical Methods, 3rd Edition, 1986, U.S. Environmental
Protection Agency publication number SW-846;
(d) Test Procedures. for the. Analysis of Polluants Under the, Clean Water Act, Federal Register Vol. 49, No. 209, 40 CFR
Part 136, October 26, 1984;
4. measure and record the depth of water in the Well prior to pumping or bailing any water from the well.
5. At least 3 volumes of water in the Well should bepumped or . bailed prior to col,lecti hg a sample -for analysis. If the well is pumped/bailed dry
before 3 well volumes'are removed, samples can be collected -as soon as the well• recovers, to the'point where enough water is available to
collect your sample..
6. Determinatio . h , Specifip.Co'j) d*uctance,. temperatur4,'odor 'and ap pearance must be_madein.thefield on unfiltered samples when the
sample is, doll6cted.
"I
f,. ig
7. Field equipmen� must be calibrat d. in &corda e A ffic the manufactbrer.
ktion alys
a sWi"us't'bi��filte�e-�,,throuoh"a"O.-4,15:mibi6�. Wl
8. S mpler y .%�iheh a -dissolved an is.Js re
ti
quired. {See #3. above
9... The sample contain6(-should be;.Iabeled-at-the ll;tme-6f:c.o.Ile-ctiort with. the faq­ility�-n4me, Well identification, nij m-berand*date and time- -col-
10;"Authorized agerit".is.any d0rp0:ratq*.qff1q`er- or p0lic.,'official a -co par t, d a
anti r al Ion,. or� qqyprnmental bo. y t-,o sign official
I.
documents.

GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM
Facility Name
Address
Unman Corporation
P.O. Box 588
For additional forms please write or call:
Spruce Pine, NC. 28777
Well Location Monitoring Well #1
Well Identification Number M-W. #1 Well Depth 15 Ft.
Well Diameter Sample (Screened) Interval Ft. To Ft.
Depth to Water Level 12.33 ft. below measuring point. (before sampling)
Division of Environmental Management
Groundwater Section
P.O. Box 27687
Raleigh, NC 27611-7687
County Ili -4 11
PERMIT NUMBER: (REQUIRED�)" I,V'y -8 1991
Non -Discharge u
Ground- ates vectiol
NPDES (I pomn-..,: gars
CREQUIRED)
— Lagoon Septic Tank/Drain 'Field
Spray Field Subsurface Low -Pressure
Piping (LPP)
Measuring point is f, r feet above land surface Land Application of Sludge
Gallons of water pumped/bailed before sampling 29 — Rotary Distributor Other
Field Analysis: pH 5 - 7 Specific Conductance 29 uMhos Temp. 12 ° C Odor Appearance
Date Sample Collected 03/05/91 Date Lab Sample Analyzed 03/05/91
Laboratory Name .Pace , Inc. Certification No•. 40
COD mg/I
Coliform: MF Fecal /100ml
Coliform: MF Total
100ml
Dissolved Solids: Total 52
mg/I
PH (when analyzed)
units
TOC
mg/I
Chloride
mg/I
Arsenic N 0
mg/I
Grease and Oils mg/I
Hardness: Total mg/I
Phenol mg/I
Sulfate mg/I
Specific Conduct nce u M h o s
Total Ammonia NH . N mg/I
TKN as N mg/I
SIGNATURI.1OI✓PF-PVITTI-E (OR
NO2 as N
mg/I
NO 3 as N.
mg/I
Phosphorus: Total as P
mg/I
Al - Aluminum
mg/I
Ba - Barium 0.36
mg/I
Ca - Calcium
mg/I
Cd - Cadmium
mg/I
Chromium: Total N0
mg/I
Cu - Copper 0.045
mg/I
Fe - Iron
mg/I
Hg - Mercury
mg/I
K - Potassium
mg/I
Mg - Magnesium
mg/I
Mn - Manganese
mg/I
Na - Sodium
mg/I
71 E AND ACC
D AGENT"). T
Ni - Nickel
mg/I
Pb - Lead N0 mg/'I
Zn - Zinc mg/I
Pesticides/Herbicides. (Specify Compounds)
.ug/I
ug/I
ug/I
Othe(: pea fj/l}` I `N//�� ug/I
Ei Qj
� ug/I
A ug/I
ug/I
—GROUNnWATER s crRQl ug
RAI FIGH, NG ug/I
NOTE:
Values should reflect dissolved concentrations
(See #2. on reverse)
* See back for Instructions.
** Submit blue, grwwn-
n1ni_IZZo QGv 1310n

W IL J'*JJ:ff*JjK0;U 0, 1 11M. I g *16 , T _Aj jM M a _J[JIQ4,
1. Samples should be analyzed as soon -as possible after collection. SAMPLES WHICH ARE NOT ANALYSED WITHIN THE HOLDING -
TIME SPECIFIED FOR THE METHOD USED (SEE #3. BELOW) MUST BE DISCARDED AND NEW SAMPLES COLLECTED.
99S ARE TO BE MADE OF THE CONSITITUENTS DISSOLVED IN THE GROUNDWA . TER, NOT THOSE THAT ARE A PART
2. AN�Ly
OF, OR ADSORBED ONTO, SOIL/SEDIMENT PARTICLES. CHECK WITH YOUR LABORATORY ON PROPER PROCEDURES FOR
SAMPLE COLLECTION AND PRESERVATION.
3. As per Title 15, North Carolina Administrative Code, Subchapter 2L, analytical procedures shall be in accordance with the methods
described in one of the following publications, or by other methods approved beforehand by the Director, Division of Environmental
Management:
(a) Standard methods for the Examination of Water and Wastewater, 16th Edition, 1985, published jointly by American
Public Health Association, American Water Works Association and Water Pollution Control Federation;
(b) Methods for Chemical Analysis of Water and Waste, 1979, U.S. Environmental Protection Agency publication number
EPA-600/4-79-020, as revised March 1983;
(c) Test Methods for Evaluating Solid Wastes: Physical/Chemical Methods, 3rd Edition, 1986, U.S. Environmental
Protection- Agency publication number SW-846;
(d) Test Procedures for the Analysis of Polluants Under the Clean Water Act, Federal Register Vol. 49, -No. 209, 40 &R
Part 136, October 26,1984;
4. Measure and record the depth of water in the well prior to pumping or bailing any water from the Well.
5. At least 3 volumes of water in the well should be pumped or bailed prior to collecting a sample for analysis. If the well is Oumped/baile"d dry
before 3 well volumes are removed, samples can be collected as soon as -the Well recovers to the point where enough water is available to
collect your sample.
6. ,Determination for pH, Specific Conductance, temperature, odor and appearance must be made in the field on unfiltered samples when the
sample is collected.
7. Field equipment must be calibrated in accordance with recommendations by the manufacturer.
8. Samples must be -filtered gh.a 0.45 micron filter immediately after collection when a dissolved analysis is required. (See #3. above)
9, The sample container should be labeled at the time of collection with the facility name, well identification number and date and time col-
lected.
t -
1 O."Authorized agent" is any corporate officer or public official authorized, by the company, corporation, or governmental body to sign official
mpnts.

MAY 02 '91 O-c_':FJIPM Ul'UMIM t UAP.T.'
Quartz Operation
P. 0. Box 588
Bakersville Hwy,
Spnice Pinar N, C. 28777
[phone]
Pax No: [phone]
FACSIMILE TRANSMISSION
DELIVER TO:
0
FROM. �` s .,t �
DATE:
MATERIAL BEING TRANSMITTED:
t--
NUMBER OF PAGES: THIS COVER PAGE PLUS — r� PAGE O S )
FOR VOICE CONTACT, CALL [phone] Ext. �4�
P.1

�njvlq!ori of r=nvkonmental mamgarnent
GROUNDWATER QUALITY MONITORING: COMPLIANCE -REPO RT FORM Graundwater S&cfiort
P-0- Sox 27687
i-alalqh, NC 27611-7697
,-or additional forms IA@ase write m call: (91 -9,)733-3n1
CF.l
Facility Name
County
IL
Address
PERMIT NUMBER: (REQUIRED)
4on-Discharge
114z-
Weff Location
NPDES
Well Idenlification Number
Well Depth
TYPE OF DISPOSAL OPM
-RATiON BEING L40NE ITORD
-Fi.
(REQUIRED)
W P, 1. 1 Diameter
Sample (Screened) Interval - Ft. To - Ft.
Lagoon w Septic. I ar�UDrajn Field
Depth to Water Level
It. below measiffing point. (before sampling)
Spray Feb Subsurface Low-Pre-ssare
Piping CLPFI)
IZIN
Measuring point is fcet above land surface
Land Apoicafion of S"e
ot"
r 3,a;lons of water purnped1bailed
before sampling
ROLary-Dis iributor
Field Arjafysis: PH -2
Specific Conductance uMhos Temp.
0
C Odor Appearance
'VI
Date Sample Colleciad
Date Lab Sample Analyzed
Laboratory Name
Certification Na.
COD
mg/1 NO2 as N
mg Ni Nickel
CoJiform: h4F Fecal
I 00ml NO3 as N
f-jl,- Pb Lead
mg/7
Coliform: MF Total
I 1100ml Phosphorus: Total as P
_11R; Zri Zinc,
mg/l
Dissolved Sofids: Total Mg1I Al - Aluminum
m p" Pesficideslrlebicides (Specify Compounds)
j-
pH (when analyzed)
units Sa - Barium
rng/I
Jr
�T;
D'
TOC
mg/I C'n. - Calcium
ring/I
Chloride
mg/I Cd - Cadmium
rng/I
Ug/I
Arsenic
mg/I Chromium: Total
MgA Other C'Specify;
ugil
7-
Grease and Oils
mg /I Cu - Copper r`SMg1l
-uq,!l
n
Hardness: Tolai
mg/I Fe - Iron
Mg/I
ugh
ILI
Phenol
MC III[ Hg -Mercury
Mg/I
Jg1l
r,71
rng/l K - Potassium--
f;g/i
ug / i
I17.,
Specific Conductance
--timhos Mg -Magnesium
-,ugjl
Total Ammonia(N7`-I3 + Nil 4
mg/i Mn - Manganese
TKN as N
Mg/I Na - Sodium
Mg/i -affect dissolve(( i-.oncentraticins
I CERTIFY THAT THIS IRSPORT IS TRUE AND ACCUBAh.
SIGNATURE Or PEPMITTEE (OR AUTHORIZED AGEZNT„) DATE
Pr-%r 9fw
Sep bark for instwffon:3.
Stibmil blue, green, and yedow copies 2akto address above_1

�4o0/ 7� ..yet ra)
COMPLIANCE MONITORING
REPORT FORM
Facility Name
Address
L- "Oyh��• �Gv C ��
Division of Environmental Management
Groundwater Section
P.O. Box 27687
761
For additional forms please write or call: R (9ale19)19). N.C. 2T33-3221 1
County
Permit Number:
AAID _ I (E- 1 Nil 0I- b r Non-Discharrg%
Well Location L���t't-1C1�, ` NPDES
1 1 .�I. ' 1 Well De Well Identification Number Depth Ft. Water Use
Well Diameter tt Sample (Screened) Interval Ft. To Ft. Injection Well
Depth to Water Level ft. below measuring point. (before sampling) Well Construction
Measuring point is feet above land surface Other
Gallons of water pumped/bailed before sampling 5 ��% / C
Field Analysis: pH 5. i-"Specific Conductance uMhos Temp. 110 J ° C Odor A ANPa9A69- AID'
Date Sample Collected Date Lab Sample Analyzed 7-9' 9n
Laboratory Name CxC.2 .j1C.. Certification No.
COD
Coliform: MF Fecal
Coliform: MF Total
- mg/I
/100ml
/100ml
Dissolved Solids: Total mg/I
pH (when analyzed) -� units
TOC mg/I
Chloride mg/I
Arsenic I_C 5.M'5 mg/1
Grease and Oils
Hardness: Total
Phenol
Sulfate
Specific Conductance
Total Ammonia(NH3 t NH 4)
TKN as N
I CERTI
SIGNAyI'1RE OF PERMITTEE
GW-59 Revised 6/88
mg/I
mg/I
mg/I
NO2 as N
NO 3 as N
Phosphorus: Total as P
mg/I
mg/I
mg/I
AI - Aluminum mg/I
Ba - Barium - 0.'D_n - mg/I
Ca - Calcium mg/I
Cd - Cadmium mg/I
Chromium: Total LJ• O�- mg/I
Cu - Copper l_1�J l umg/I
Fe - Iron mg/I
Hg - Mercury mg/I
Ni - Nickel mg/I
Pb - Lead L0. ^^ /5 mg/1
Zn - Zinc mg/I
Pesticides/Herbicides (Specify Compounds)
Other (Specify)
ug/I
ug/I
ug/1
ug/I
ug/I
ug/I
ug/I
mg/I
Ahos
K - Potassium
Mg - Magnesium
mg/I
mg/I
1101 I I II o N ug/I
JUUJ aEC I 9�110 ug/I
mg/I
� g / l
Mn - Manganese
Na - Sodium
mg/I
m g / I
Note: ., Groundwater Section
x' Asheville Re 'onal Office
IS TRUE AND ACCURATE.
Values show d re ect o a tions
k for instructions.
_AUTHORIZED AGENT*)
ff77
DAT*
'lue and green copies only to address above.

COUNTY M 1 TC-H LL
QUAD NO.-T/ SERIAL NO. MI 1 3l< S
LAT.3SSGa IY�_ LONG. a Of 5-
Report to:(ARO FRO; MRO, RRO, WaRO, WIrC,
WSRO, Kinston FO : Other
Shipped by: Bus, Courier, Other
N.C. DEPARTMENT OF NATURAL RESOURCES
& COMMUNITY DEVELOPMENT
DEM
GROUNDWATER FIELD/LAB FORM
SAMPLE PRIORITY
21"ROUTINE ❑ EMERGENCY
O
LAB NUMBER 8 0 C, y
DATE RECEIVED �� Time q 0
Rec'd by:. CA--) From: Bus- C wrier
Other
DATA ENTRY BY: CK:
DATE REPORTED:
COLLECTOR (S):G9yA/057AfF DATE 5-5'0 TIME S.GO 10 PURPOSE: BASELINE, COMPLAINT, COMPLIANCE LUS-: OTHER
I
I
FIELD ANALYSES
i
pf1400 Spec. Cond.94 at 250C
Temp.10 OC i Odor
Appearance Taste
Field Analysis By:
LABORATORY ANALYSES
BOD5 310 I mg/I
COD High 340 mg/I
COD Low 335 mg/I
Colllorm:MF Fecal 31616 /100ml
Colllorm:MF Total 315iO4 /100ml
TOC 680 mg/I
Turbidity 76 NTU
I
pH 403 units
Alkalinity to pH 4.5 41io mg/I
Alkalinity to pH 8.3 415 mg/I
Carbonate 445 mg/I
BicerLonate 440 mg/I
r
Arsenic:Total 1002 10 ug/I
Carbon dioxide 405 mg/I
Chloride 940 mg/I
Chromium:Hex 1032 ug/I
Color.True 80 i Pt -Co
Cyanide 720 ' mg/I
Lab Comments:
(circle
Owner /1J//-!//V CO �0D,eAT/OA/ &L,4_A/2T7_ OpCRAT/ONS
Location or site Q0WAI GeA01 T
Description of sampling point t/0AD
Sampling Method A/L_Qo Sample Interval S /S
(pump, bailer, etc.)
Remarks
,5 TA 7-/G 1'U,,4 j 6_A; L C V,IFL /„3, 9(?p rpping time, air temp, etc.)
Viss. Solids 70300
mg/1
Qr5
f Iuoride 951
mg/I
Ifardness:Total 900
mg/l
Haroness (non-carb) 902
mg/I
Prienols 32730
ug/I
S::ecilic Cond. 95
Sulfate 945
uMhos/cm2
mg/I
DIs
:sulfide 745
mg/I
Dr •
NH3 as N 610 .01
mg/I
Dry
TKN as N 625
mg/I
t71S
NO2 + NO3 as N 630 3
mg/I
p,S
P:Total as P 665
I mg/I
Ag - Silver 1077 3t
ug/I
p I
Al - Aluminum 1105
4 Sn
ug/I
QIS
Be - Barium 1007
4 (
ug/I
Ca - Calcium 916
.81
mg/I
0#51
Cd - Cadmium 1027
Ze,6
ug/I
i5
Chromium:Total 1034
[ Z5
ug/I
15
Cu - Copper 1042
Z 7,A
ug/I
Fe - Iron 1045
[
ug/I
DI •
Hg - Mercury 71900
L a tZ
ug/I
p,
K - Potassium 937
z
mp/I
ply
M9 - Magnesium 927
t 4
mg/I
D/
Mn - Manganese 1055
IU
ug/I
p/
Na - Sodium 929
1
mg/I
NI - Nickel 1067 -
Z'O
ug/I
Q/5
Pb - Lead 1051
-- 10
ug/I
Offs
Se - Selenium 1147
e
ug/I
D1
Zn - Zinc 1092
ug/I.
Organochlorine Pesticides
Organophosphorus Pesticides
Acid Hardicides
Base / Neutral Extractable Organics
Acid Extractable Organics
•
Purg�e-aab,lle Organics (VOA bottle) _
pi:b an6,( AI3)
t,:/ U \llltr-., SEeTI
LEIG , NG
On
NOV 19
GW-54 F 'tied 7/85 For Dissolved Analysis - submit tilt i sample and write 'DIS' in block
While copy - Headquarters Pink",,-,py - Region Yellow copy - Lab

COUNTY LA �' = ' N.C. DEPARTMENT OF NATURAL RESOURCES LAB NUMBER 8
QUAD NO.-<� 1 T i SERIAL NO.I f t ° &COMMUNITY DEVELOPMENT DATE RECEIVED%� �.y, Time
LAT.- ' ' LONG. " DEM Rec'd by:6 w From: Bus -Courier
Report to:1/AR0 FRO, MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO 0the?)
Shipped by: Bus, Courier, Other
COLLECTOR(S): ' ,7A !a' !'�"ir DATE
FIELD ANALYSES
P"400 Spec, C6nd.94
Temp.10 oC Odor _
Appearance Taste
Field Analysis By:
LABORATORY ANALYSES
BOD5 3-10
mg/I
COD High 340
mg/I
'
COD Low 335 97
mg/I'
��-
Coliform:MF Fecal 31616.<;00/tooml
tf!'
Colitcrm:MF Total 31504-4J00 /loom[
TOC 680
mg/I
Turbidity 76
NTU
,r•'
pH 403 50
units
./
• Alkalinity to pH 4.5 4I0 ' l
mg/I
Alkalinity to pH B.3 415
mg/I
Carbonate 44.5
mg/I
V
Bicaruonate 440
mg/I
Arsenic:Total 1002
ug/f
Carbon dioxide 405
mg/I
Chloride 940 A
mg/I
Chromium:Hex 1032
ug/I
Color:True 80
Pt -Co
Cyanide 720
mg/I
Lab Comments:
GROUNDWATER FIELD/LAB FORM Other
SAMPLE PRIORITY DATA ENTRY BY: t)Ir CK:
0 ROUTINE ❑ EMERGENCY DATE REPORTED: - 2 fq Q
TIME -t 'F �` / f'� PURPOSE: BASELINE, COMPLAINT, (C0MPLIANCE_'L.US7. OTHER
(circle one)—
Owner / r,'.1l/`i iAS ^��;/-�/.,tY-f; 1f--',�I /•:(/:§e- i s''--1 � I r' `..,'�.
at 250C Location or site
Description of sampling point
Sampling Method j` t ''� Sample Interval =t!
(pump, bailer, etc.)
Remarks
0.,5
Diss. Solids 70300
mg/1
Fluoride 951
mg/I
�n<,
Hardness:Total 900
mg/I
[td5
Hardness (non-carb) 902
G.
mg/I
Phenols 32730
ug/I
Specific Cord. 95
uMhos/cm2
Sulfate 946
mg/I
Sulfide 745
mg/1
NH3 as N 610
mg/I
TKN as N 625
mg/I
NO2 t NO3 as N 630
mg/I
P:Total as P 665
mg/I
z (pumping time, air temp, etc
Ag - Silver 1077 ug/1
Al - Aluminum 1105 ug/I
Be - Barium'1007 ug/I
Ca - Calcium 916 mg/I
Cd - Cadmium 1027 ug/I
Chromivm:Total 1034 ug/I
Cu - Copper 1042 ug/I
Fe - Iron 1045 ug/I
Hg - Mercury 71900 ug/I
K - Potassium 937 mg/I
Mg - Magnesium 927 mg/I
Mn - Manganese 1055 ug/I
Na - Sodium 929 mg/I
Ni - Nickel 1067 ug/I
Pb - Lead 1051 ug/I
Se - Selenium 1147 ug/I
Zn - Zinc 1092 ug/I•
II Organochlorine Pesticides
Organophosphorus Pesticides
I I Acid Herdicides I
Base / Neutral Extractable Orpenics
Acid Extractable Organics
Purgeable Organics (VOA bottle) I
1 1 1.2 - Dibromoethane (EDB) I
GW-54 Revised 7/85 For Dissolved Analysis - submit filtered sample and write 'DIS" in block
White copy - Headquarters Pink copy - Region Yellow copy - Lab

COMPLIANCE MONITORING
REPORT FORM
Facility Name
Address
Well Location
V
Division of Environmental Management
Groundwater Section
P.O. Box 27687
Raleigh, M.C. 27611
For additional forms please write or call: [phone]
County
Permit Number:
Non -Discharge
NPDES IBC- occo
Well Identification Number # Well Depth 16 Ft. Water Use ��--
4(eiT
Well Diameter �" Sample (Screened) Interval Ft. To IF) Ft. Injection WellJ')
Depth to Water Level ft. below measuring point. (before sampling) Well Construction ++` +y s 461
Measuring point is feet above land surface Other nnrn
1�-1
Gallons of water pumped/bailed before sampling t� 8r n -�
Field Analysis: pH �, G Specific Conductance uMhos Temp. °C Odor '}Aplpe�a ance
Date Sample Collected 3 2, 190 Date Lab Sample Analyzed 3 ZG -/ -
Laboratory Name PaCe 1—;nc, Certification No.
�c7 -Boy P,54S�
S�rIJCP��n� Vc- 283-1-4
i
COD
mg/I
NO2 as N
mg/I
Coliform: MF Fecal
/100ml
NO3 as N
mg/I
Coliform: MF Total
/100ml
Phosphorus: Total as P
mg/I
Dissolved Solids: Total 1N1.() mg/I
pH (when analyzed) 5 f oq units
TOC mg/I
Chloride mg/I
Arsenic < a non mg/I
Grease and Oils
Hardness: Total.
Phenol
Sulfate
Specific Conductance
Total Ammonia(NH3 t NH 4)
TKN as N
I CERTIFY
SIGNATURE
GW-59 Revised 6/88
mg/I
Al - Aluminum mg/I
Ba - Barium <mg/I
Ca - Calcium mg/I
Cd - Cadmium mg/I
Chromium: Total <�,(��('�. mg/I
Cu- Copper <C) ,Old mg/I
mg/I Fe - Iron mg/I
mg/I Hg - Mercury mg/I
- mg/I K - Potassium mg/I
uMhos Mg - Magnesium mg/I
Ni Nickel mg/I
Pb - Lead d'�� - mg/I
Zn - Zinc mg/1
Pesticides/Herbicides (Specify Compounds)
I _ Ug/I
ug/1
Other (Specify) Ah ug/I
U7rollridwatet Section ug/I
rte�;uie ucpin-tal Sffir-O
'ug/I
'Jug/1
ug/I
ug/I
mg/I Mn - Manganese mg/I
Note:
mg/I Na - Sodium mg/I
Values should reflect total concentrate
PORT I E AND ACCURATE.
See back for instructions.
MITTEE (OR AUTHORIZED AGENT*) DATE 1** Submit blue and green copies only to address above.

COMPLIANCE MONITORING
REPORT FORM
Facility Name 1) ticm in Lrpoy-21_ �,,
Address 12(2 tau'
I`ve
Well Location
Division of Environmental Management
Groundwater Section
P.O. Box 27687
Raleig,h, N.C. 27611
For additional forms please write or call: [phone]
Well Identification Number -N� I Well Depth 115 _Ft.
Well Diameter ?" Sample (Screened) Interval J Ft. To 15 ft.
Depth to Water Level 12.41S ft. below measuring point. (before sampling)
Measuring point is © feet above land surface
Gallons of water pumped/bailed before sampling 10
County
iY11Tc?�ha�
Permit Number:
Non -Discharge - - -�
NPDES NIQ_
Water Use Vic?
Injection Well �1:: ' :N LO 19990
Well Construction
Other GR011n-y o IR SECT—
RALEM, NC.
Field Analysis: pH Specific Conductance uMhos Temp. o C Odor Appearance
Date Sample Collected 11 1 I q I1d9 Date Lab Sample Analyzed 1 (15 (aq
Laboratory Name En` irC'>v r},car�TcaI 1'�� ci-,Q L� �.- Certification No. -40
COD mg/I NO2 as N
Coliform: MF Fecal
Coliform: MF Total
/ 100ml NO 3 as N
1100ml Phosphorus: Total as P
Dissolved Solids: Total A;L0 mg/I
pH (when analyzed) E = 25 units
TOC mg/I
Chloride mg/I
Al - Aluminum
mg/I Ni - Nickel mg/I
mg/I Pb - Lead <a ,CQSc-) mg/I
mg/I Zn - Zinc mg/1
mg/I Pesticides/Herbicides (Specify Compounds)
Ba - Barium � () , oG mg/I
Ca - Calcium.
Cd - Cadmium
mg/I
I
Arsenic <O,00S
mg/I
Chromium: Total <0102-0
mg/I
Grease and Oils
mg/I
Cu - Copper a.otC)
mg/I
Hardness: Total
mg/I
Fe - Iron
mg/I
Phenol
mg/I
Hg - Mercury
mg/I
Sulfate
mg/I
K - Potassium
mg/I
Specific Conductance
uMhos
Mg - Magnesium
mg/I
Total Ammonia(NH3 t NH 4) mg/I Mn - Manganese-
TKN as N Na - Sodium
I CERTIFY T PO TRUE AND ACCURATE.
SIGNATUR OF PERMITTEE (OR AU HORIZED AGENT*)
mg/I
mg/I
ug /I
ug/I
ug/1
Other (Specify) Rug/I
c
iug/I
iic• it `+/ ug/I
vow
,I,liv 1 ;. ;.I ug/I
ug/I
Groundwater Section ug/I
Asheville Regional Office
Note: ±
k � `v
Q /
Values should reflect total concentrations � (�
7eeback for instructions.
DATE** Submit blue and green copies only to address above.
GW-59 Revised 6/88

• COMPLIANCE MONITORING
REPORT FORM
Environmental Management Division
Groundwater Section
P.O. Box 2768?
Raleigh,N.C. 27611
[phone]
Facility Name Unimin Corp. County Kitchell - - Groundwater Section
Address PO Box 545 Permit Number: 4shevilie Rp ,.gional Offir,.,
Snrur.a Pi nP , NF: 9R777 Non -Discharge k"
Well Location NPDES NC 000 �1A15=-_�� Y.-
Well Identification Number #1 Well Depth 15 Ft. Water Use
Well Diameter 211 Sample CScreened) Interval _F_ Ft. To 1.9 Ft.
Injection Well
Depth to Water Level 1 ri 77 ► ft. below measuring point. (before sampling) Well Construction -
y(y1114#I'� v'�Vlevu.
Measuring point is 0 feet above Land surface. Other 4JVU6-�^��n rpn
Gallons of water pumped/bailed before sampling To Dryness
BLS t?luuo
Field Analysis: pH 5.69 Specific Conductance uMhos Temp. °C Odor Appearance
Date Sample Collected 7/10/89 Date Lab Sample Analyzed 7/2❑/.R9'>
Laboratory Name Environmental Testing Inc. Certification No. 40
COD
mg/I
Coliform: MF Fecal
/100ml
Coliform: MF Total
/100ml
Dissolved Solids: Total
84 mg/I
pH (when analyzed)
5.69 units
TOC
mg/I
Chloride
mg/I
Arsenic <0.005
mg/I
Grease and Oils
mg/I
Hardness: Total
mg/I
Phenol
mg/I
Sulfate
mg/I
Specific Conductance
uMhos
NO2 as N
NO3 as N
Phosphorus: Total as P
Al - Aluminum
Ba - Barium <0.050
Ca - Calcium
Cd - Cadmium
mg/I
mg/I
mg/I
mg/I
mg/I
mg/I
mg/I
Chromium: Total <❑.❑2❑ mg/I
Cu - Copper 0.019 mg/I
Fe - Iron mg/I
Hg - Mercury
A
K - Potassium mg/I
Mg - Magnesium mg/I.
Ni - Nickel
mg/I
Pb - Lead <❑.005
—mg/1
Zn - Zinc
mg/I
Pesticides/Herbicides (Specify Compounds)
vg /1
ug/I
ug/t
Other (Specify)
ug/I
ug/I
ug/I
ug /I
ug/I
..ug/I
Total Arnmonia.(NH3.t NH 4) mg/t Mn - Manganese mg/I
Note:
TKN as N mg/I Na - Sodium- mg/I
- Values should reflect total concentrations
I CERTZT�pfTHIZREP T IS TRUE AND ACCURATE.
*See back. for .instructions.
SIGNA , E 4 PERMITTEE (OR _AUTHORIZED AGENT*) 9AJE'** Submit blue and green copies only to address above.
GW-59 Revised 3/88 -

COMPLIANCE MONITORING
REPORT FORM
Environmental Management Division
Groundwater Section
P.O. Box 27687
Raleigh,N.C. 27611
[phone]
Facility Name IINIMIN nnrpnrati nn
Address PO Box 588
Spruce Pine, NC 28777
Well Location
Well Identification Number #1 Well Depth 151 Ft.
Well Diameter 211 Sample (Screened) -Interval 5' Ft. To 15' Ft..
Depth to Water Level -14.871 ft. below measuring point. (before sampling)
Measuring point is 0 feet .above land surface..
Gallons of* water pumped/bailed before samp+ing To dryness
County Mitchell
Permit Number:
Non-Dischargeif t
NPDES NC 000017
Water Use
Injection Well RAA i IgRq
Well Construction Wlindwat t u,'_��
Other R, Asheville Regional Office
0
Field Analysis: pH 6.20 Specific Conductance uMhos Temp. ° C Odor Appearance
Date Sample Collected 3/6/89 Date Lab Sample Analyzed 3/12/89
Laboratory Name Environmental TPG+:i ng Inc.._ Certification No. 40
COD mg/1 NO2 as N mg/I Ni.- Nickel mg/1
Coliform: MF Fecal /100mi NO3 as N.
Coliform: MF Total
/100ml
Dissolved Solids: Total
<0.5
PH (when analyzed)
6.20 units
TOC
mg/I
Chloride
mg/I
Arsenic <0.005
mg/I
Grease and Oils
mg/I
Hardness: Total
mg/I
Phenol
m g /I
Sulfate
mg/1
Specific Conductance
uMhos
Total Ammonia.(NH3.t NH 4) mg/f
TKN as N ma/I
Phosphorus: Total as P
Al - Aluminum
mg/I Pb - Lead <n_nr;n mg/f
mg/I Zn - Zinc mg/I
mg/I Pesticides/Herbicides (Specify Compounds)
Ba - Barium <0.010
mg/l
Ca - Calcium
mg/I
Cd - Cadmium
mg/l
Chromium: Total <0.020
mg/I
Cu - Copperi<0.010 t_�
mg/I
Fe - Iron
mg/I
Hg - Mercury
mg/l
K - Potassium
mg/I
Mg - Magnesium
mg/I
Mn - Manganese mg/I
���� Na - Sodium' mg/I
I CERTIFY f] AT THIS REPORT IS TRUE AND ACCURATE.
7J
&GNAT4E OF RMITTEE (OR .AUTHORIZED AGE �'_) D TE
GW-59 Revised 3/88
Other (Specify)
•ug/1
ug/I
ug/1
ug/I
�IU /I
Mag ug/I
s.. ug/I
Note: Tconce
0AValues should refle t ibns
V
*..Sge back for:instructions.
** Submit blue and green copies only to address above.

COMPLIANCE MONITORING
REPORT FORM
Environmental Management Division
Groundwater Section
P.O. Box 27687
Raleigh,N.C. 27611
[phone] lE� ��Q`�
Facility Name l INT�ITN Cnrnnrai-.i nn
Address PO Box `588
Spruce Pine, NC 28777
Well Location
Well Identification Number #1 Well Depth 1.5 Ft.
Well Diameter 2" Sample (Screened) � Interval _ Ft. To _ 1.5— Ft.
Depth to Water Level 12_R it. below measuring point. (before sampling)
County _ S"
Permit Number: Poll,
Non -Discharge
R��-t
NPDES NC00001
Water Use 15 c E Q V iE
Injection Well
Well Construction
Measuring point is n feet above land surface:
Other
Groundwater Section
Gallons of water pumped/bailed before sampl+ng to drying
t,
Asheville eglona mice
.
Field Analysis: pH
.0
6.0Specific Conductance uMhos Temp.
° C
Odor
Appearance
Date Sample Collected
11/10/88 Date Lab Sample Analyzed
11118_JRR
Laboratory Name
Environmental TRsfJ ng Tnn.. Certification No'. 40
COD
mg/I NO2 as N
mg/I
Ni - Nickel
mg/I
Coliform: MF Fecal.
/100m1 NO3 as N.
mg/I
Pb -Lead fl.nS1
mg/1
Coliform: MF Total
/100ml Phosphorus: Total as P
mg/I
Zn - Zinc
mg/1
Dissolved Solids: Total
70'.7 _ mg/.l Al - Aluminum
mg/I
Pesticides/Herbicides (Specify Compounds)
pH (when analyzed)
ri_n0 units Ba - Barium 0.479
mg/I
ug/l
TOC
mg/I Ca - Calcium
mg/I
ug/I
Chloride
mg/I
Arsenic <0.005
mg/I
Grease and Oils
mg/I
Hardness: Total
mgA
Phenol
mg/I
Sulfate
mg /I
Specific Conductance
uMhos
Total Amrnc6a.(NH3.t NH 4)-
mg/1
TKN as N -
ma/I
Cd - Cadmium mg/l unIl
Chromium: -Total <0.010
mg/1
Cu - Copper 0.167
mg/I
Fe - Iron
mg/I
Hg - Mercury
mg/I
K - Potassium
mg/I
Mg - Magnesium
mg/I
Mn - Manganese
mg/I
Na - Sodium
mg/I
I CERTIFY�T THIS REPORT IS TRUE AND ACCURATE.
SIGNATUAOF
GW-59 Revised A188
PERMITTEE (OR AUTHORIZED AGENT*)
19/19/AR
DATE
Other (Specify)
ug /I
ug /I
ug /I
ug/I
ug/I
ug/I
Note:
values should reflect total` concentrations
*See back -fovinstructions.
** Submit blue and green copies only to address above.

COUNTY
N.0 '� EPARTMENT OF NATURAL RESOUF�S
LAB NUMBER B xc_.'2�
(761
A
QUAD NO. _r_/SERIAL NO.
A 13 & COMMUNITY DEVELOPMENT
DATE RECEIVED
Time 1�LL.J
LAT. 3S S 9 /i/ LONG. 52
DI` / DEM
Rec'd by:b� From: Bus-
ourier
GROUNDWATER FIELD/LAB FORM
Other
Report to: ARO FRO, MRO, RRO,
WaRO, WiRO,
SAMPLE PRIORITY
DATA ENTRY BY:
CK'
WSRO, Kinston FO Other
ROUTINE ❑ EMERGENCY
ATE REPORTED:
Shipped by: Bus, Courier Other
,
n
COLLECTOR(S):
DATE Z -'i TIME PURPOSE: BASELINE, COMPLAINT,
COMPLIANCE, UST, OTHER
(circle
FIELD ANALYSES
owner Ka/-,0.
Ifn/1 C
p11400 --Spec. Cond.94
Temp.10 oC Odor —
Appearance Taste
Field Analysis By:
LABORATORY ANALYSES
B005 310 mg/I
COD High 340 mg/I
COD Low 335 mg/I
Colitorm:MF Fecal 31616 /100ml
Collform:MF Total 31504 /100ml
TOC 680 mg/I
Turbidity 76 NTU
PH 403 units
Alkalinity to pH 4.5 410 mg/I
Alkalinity to pH 8.3 415 mg/I
Carbonate 445 mg/I
Bicarbonate 440 mg/I
Arsenic:Total 1002--de-- ug/I
Carbon dioxide 405 mg/I
Chloride 940 rng/I
Chromium:Hex 1032 ug/I
Color.True 80 Pt -Co
Cyanide 720 mg/I
a t 250C Location or site
Description of sampling point Sampling Method 41/ /110
(pump, bailer, etc
I
Sample Interval
Remarks
(pumping time, air temp, etc.)
Diss. Solids 70300 mg/1
Fluoride 951 LQr mg/I.
Hardness:Total 900 mg/I
Hardness (non-carb) 902 mg/I
Phenols 32730 ug/I
Specific Cond. 95 uMhos/cm2
IL
Sulfate 945 mg/I
Sulfide 745 mg/I
NH3 as N 610 mg/I
TKN as N 625 mg/I
NO2 + NO3 as N 630 mg/I
P:Total as P 665 mg/1'.
Ag - Silver 1077 ug/I
At - Aluminum 1105 ug/I
r
Be - Barium 1007 L ug/I
Ca - Calcium 916 mg/I
Cd - Cadmium 1027 U ug/I
PW
Chromium:Total 1034G ug/I
Cu Copper 1042 ug/I
Fe - Iron 1045 ug/1
Hg - Mercury 7190 . ug/I
K - Potassium 937 mg/I
Mg - Magnesium 927 mg/I
iS
Mn - Manganese 1055 G ug/I
Na - Sodium 929 mg/I
Ni - Nickel 1067 --<50 ug/I
Pb - Lead 1051 _,_" ug/I
/
Se - Selenium 1147 ug/I
Zn - Zinc 1092
Organochlorine Pesticides
Organophosphorus Pesticides
Acid Herdicides
Base / Neutral Extractable Organics
Acid Extractable Organics
Purgeable Organics (VOA bottle)
1,2 - Dibromoethane (EDB)
+'
trJ �Al
lk
qq log(
Lab Comments:
GROU NriWATLR SECTION
RALEIGH, ` 0 --
GW-54 Revised 7/85 For Dissolved Analysis - submit filtered sample and write 'DIS' in block
-� White copy - Headquarters Pink copy - Region Yellow ��

COUNTY N.C. DEPARTMENT OF NATURAL RESOURCES LAB NUMBER a ` '1
QUAD NO. j SERIAL NO. ��;' f 's- `,y & COMMUNITY DEVELOPMENT DATE RECEIVED �P f Time
LAT. 1-° LONG. / _ % DEM i; '1/t'
Rec'd by: From: Bus -Courier
— GROUNDWATER FIELD/LAB FORM Other
Repprt to: �ARO,�FRO, MRO, RRO, WaRO, WiRO,
SAMPLE PRIORITY DATA ENTRY BY: CK:
WSRO, Kinston FO Other }�
)" ROUTINE ❑ EMERGENCY DATE REPORTED:
Shipped by: Bus, Courier, Of 6ir
COLLECTOR(S): I'r1!'.!;-r,'� DATE"J: %C-' TIME PURPOSE: BASELINE, COMPLAINT, COM'PLIANCE;.LUST, OTHER
/Y (circle -one)
FIELDANALYSES Owner 3
pH400 Spec. Cond_94 at 250C Location or site
Temp.10 OC' Odor - Description of sampling point
Appearance Taste Sampling Method `1 r. f_ Sample Interval
(pump', bailer, 'etc.)
Field Analysis By: Remarks
t " �/ e (pumping time, air temp, etc.)
LABORATORY ANALYSES.
BOD5 310
mg/I
COD High 340
mg/I.
COD .Low 335
mg/I
Coliform:MF Fecal 31616
/100m1
Coliform:MF Total 31504
/100ml
TOC 680,
mg/I
Turbidity 76
NTU
pH. 403 1-^
units
t ,
• Alkalinity- to pH 4.5 410
k f
mg/I
= Alkalinity to pH 8.3 415
mg/I
,,",Carbonate
445
„� }
mg/I
,�.
Bicarbonate 440
+
mg/I
Arsenic:Total 1002
ug/1
Carbon dioxide: 405
mg/I:
Chloride 940
mg/I
Chromium:Hex 1032
ug/I
Color.True 80
Pt -co
Cyanide 720
mg/I
Lab Comments:
L.;''Diss.
Solids 70300-
mg/(
Fluoride 951
mg/I'
�.%Hardness:Total
900
11
mg/I
I to
ardness (non-carb) 902
I
mg/I
Phenols 32.730
ug/I
Specific Cond. 95
uMhos/cm2
Sulfate 945
mg/I
Sulfide 7.45
mg/I
NH3 as N 610
mg/I
TKN as N 625
mg/I
N0.2 + NO3 as N 630
mg/I
P:Total as P 66.5.
mg/I
Ag - Silver 1.077 ug/I
At - Aluminum 1105 ug/I
Ba - Barium'100.7 ug/I
Ca - Calcium 916 'mg/I
Cd - Cadmium 1027 ug/I
Chromlum:Total 1034 ug/I
Cu - Copper 1042 ug/I
Fe - Iron 1045 ug/l
Hg -Mercury 71900 ug/I
K - Potassium 937 mg/I
Mg - Magnesium 927 mg/I
Mn - Manganese. 1055 ug/I
Na - Sodium 929 mg/I
Ni - Nickel 1067 ug/I
Pb - Lead 1051 ug/I
Se - Selenium 1147 ug/I
Zn - Zinc 1092 ug/I
GW-54 Revised 7/85 For Dissolved Analysis - submit filtered sample and write 'DIS' in block
White Copy - Headquarters Pink copy - Region Yellow copy - Lab
Organochlorl,ne Pesticides
Organophosphoru s Pesticides
Acid Herdicides.
Base / Neutral Extractable Organics
Acid Extractable Organics
Purgeable Organics (VOA bottle)
1,2 - D,ibromoetha,ne (EDB)

COMPLIANCE MONITORING
REPORT FORM
Facility Name
Address
Environmental Management Division
Groundwater Section t
P.O. Box 27687 E ,I' V
Raleigh,N.C. 27611
[phone] O CT _ 1988
County Groundwater Section
Permit Number: 4Shcov -Regional.... .. o. w •mac
Non -Discharge �
Well Location
NPDES
Well Identification Number
Well Depth Ft.
Water Use
Well Diameter '
Sample (Screened) Interval Ft. To Ft.
Injection Well
Depth to Water Level '
` f.t. below measuring point. (before sampling)
Well Construction
Measuring point is feet above land surface
Other .
Gallons of water pumped bailed before sampling
Field Analysis: pH 5�7.;� Specific Conductance uMhos Temp.
_C Odor Appearance
Date Sample Collected
7/,r lI Date Lab Sample Analyzed
�I"04-9
Laboratory Name �'=�m�.� c�.t .1 T 1 t,7c� Certification No. +I?
COD
mg/I NO2 as N
mg/I Ni - Nickel
mg/I
Coliform: MF Fecal
/ 100ml NO 3 as N
^n
mg/I Pb - Lead `� " J'
mg/1
Coliform: MF Total
/100ml Phosphorus: Total as P
mg/I Zn - Zinc
mg/I
Dissolved Solids: Total
mg/I Al - Aluminum
mg/I Pesticides/Herbicides (Specify Compounds)
pH (when analyzed) , '
units Ba - Barium 167
mg/I
ug/1
TOC
mg/I Ca - Calcium
mg/I
ug/I
Chloride
mg/I _ Cd - Cadmium_
mg/I
ug/1
Arsenic ;l �F'i'
mg/I Chromium: Total=,`j`'1
mg/I Other [Specify)
ug/I
Grease and Oils
mg/I Cu - Copper '' "�
mg/I �e ' sue, , c. jai �''`
' = f' ug/I
Hardness: Total
mg/I Fe - Iron
mg/1
ug/I
Phenol
mg/1 Hg - Mercury
mg/I
ug/I
Sulfate
mg/I K - Potassium
mg/I
ug/I
Specific Conductance
uMhos Mg - Magn.esium
mg/I
.ug/I
Total Ammonia(NH3 t NH
mg/I Mn - Manganese
mg/I
4)
Note:
TKN as N
mg/I Na - Sodium
mg/I
r
_
Values should reflect total concentrations
I CERTIFY, -THAT THIS
REPORT IS TRUE AND ACCURATE.
See back for instructions
Submit blue and green copies to address
above.
SIGNATURE OF PERMITTEE (OR AUTHORIZED AGENT#) DATE
GW-59 Revised 7/85

Environmental Management Division
ewCOMPLIANCE
MONITORING
Groundwater Section0
REPORT FORM
P.O. Box 27687
G E N E
Raleigh,N.C. 27611
[phone]
i 9 8 8
Facility Name l lni mi n rnrporati
nn
County
Ml ^ho11
Address PO Box 588
Permit Number: (31roundwalar RPOinn
Asheville Regional Office
Spruce Pine, AC 28777
Non -Discharge
Well Location
NPDES nir nnnn1!7g ' -
Well Identification Number 1
Well Depth 15 Ft.
Water Use
Well Diameter 211 Sample
CScreened) Interval 5 Ft. To 15 Ft.
Injection Well
Depth to Water Level 7.70
ft. below
measuring point. (before sampling)
Well Construction
Measuring point is 0 feet above land surface
Other.
To dryness
Gallons of water pumped bailed
before sampling
Field Analysis: pH 5.70
Specific Conductance
uMhos Temp.
o C
Odor Appearance
Date Sample Collected 7-/g/.Rg
Date Lab Sample Analyzed
7/16/88
Laboratory Name Environmental
Testing
Inc Certification
No. 40
COD
mg/l
NO2 as N
mg/I
Ni - Nickel mg/1
Coliform: MF Fecal
/100ml
NO3 as N
mg/I
Pb -Lead <0.100 mg/I
Coliform: MF Total
/100ml
Phosphorus: Total as P
mg/I
Zn - Zinc mg/1
Dissolved Solids: Total
mg/I
Al - Aluminum
mg/1
Pesticides/Herbicides. CSpecify Compounds)
pH (when analyzed) 5.70
units
Ba - Barium 0.187
mg/I
ug/I
TOC
mg/I
Ca - Calcium
mg/I
ug/I
Chloride
mg/I
Cd - Cadmium _
mg/I
ug/I
Arsenic <0.010
mg/I
Chromium: Total <0.010
mg/I
Other (Specify) ug/I
Grease and Oils
mg/I
Cu - Copper 0.016
mg/I
Residue, Total Filterable-2.00 ug/I
Hardness: Total
mg/I
Fe - Iron
mg/1
ug/I
Phenol
mg/I
Hg - Mercury
mg/I
ug/I
Sulfate
mg/I
K - Potassium
mg/I
� ' ugA
1�
Specific Conductance
uMhos
Mg - Magnesium
mg/I
wr°= .ug/I
Total AmmoniaCNH3 4 t NH )
mg/I
Mn - Manganese
mg/I
'EPA
TKN as N
mg/I
Na - Sodium
mg/I
Values shouFd `ncentrations
I CERTIF HAT THIS REP T IS TRUE AND ACCURATE.
itte'so
p��r~ too t�
S IWPoQ�ri(I ntJG
Submit bl&V`and,gireen copies to address above.
SIGNAT RE OF PERMITTEE (OR AUTHORIZED
AGENT*) DATE
GW-59 Revise 7/85

Environmental Management Division �'•
COMPLIANCE MONITORING Groundwater Section C E I V E:
REPORT FORM P.O. Box 27687 PS
Raleigh,N.C. 27611 P�,;2 1988
[phone]
Facility Name UNTKAN Corporation County Kitchell Oro„pdiAvamr ggrfion
Address P..0. Box,,588 Permit Number: Asheville Regional Office
Spruce Pine, NC 28777 Non -Discharge
Well Location NPDES Nr nnnnl7.
Well Identification Number #1 Well Depth 15 Ft. Water Use
Well Diameter 211 Sample (Screened) Interval 5 Ft. To 15 Ft. Injection Well
Depth to Water Level 7•70 ft. below measuring point. (before sampling) Well Construction
Measuring point is 0 feet above land surface Other .
Gallons of water pumped bailed before sampling Tn Hr)/n ess
Field Analysis: pH 8-55 Specific Conductance uMhos Temp. 0C Odor Appearance
Date Sample Collected 3/10/88 Date Lab Sample Analyzed 3/18/88
Laboratory Name Enviromental Testing Inc. Certification No. 40
COD mg/I NO2 as N mg/I Ni - Nickel mg/I
Coliform: MF Fecal /100ml NO3 as N mg/I Pb -Lead - <n n50 mg/1
Coliform: MF Total /100ml Phosphorus: Total as P mg/I Zn - Zinc mg/I
Dissolved Solids: Total 35.3 mg/I Al - Aluminum mg/I Pesticides/Herbicides (Specify Compounds)
PH (when analyzed) units Ba - Barium 0.076 mg/I ug/I
TOC mg/I Ca - Calcium mg/I
ug/I
Chloride mg/I Cd - Cadmium— mg/I ug/1
Arsenic <0.010 mg/I Chromium: Total<0.010 mg/I Other (Specify) ug/I
Grease and Oils mg/I Cu - Copper <0.010 mg/I ug/I
Hardness: Total mg/I Fe - Iron mg/Ig/I
Phenol mg/I Hg - Mercury mg/I.j l:d '�• '-= 1`fla4,,"
ss gA
Sulfate mg/I K -Potassium mg/I � u9 /I
Specific Conductance _ uMhos Mg - Magnesium mg/I� APR �%� ug/I
Total Ammonia(NH3 t NH 4) mg/I Mn - Manganese mg/I Note: n� t trs/NA
1100
TKN as N mg/I Na -Sodium mg/I GRfff
tro
Values should rb twa���N ncentrations
I CERTIFY T S RE IS TRUE AND ACCURATE.
# See back for instructions
**Submit blue and green copies to address above.
SIG ATURE OF PERMITTEE (OR. AUTHORIZED AGENT*) DATE
GW-59 Revised 7/85

Environmental Management Division
COMPLIANCE MONITORING Groundwater Section E C F_ I M E'
REPORT FORM P.O. Box- 27687 P�
Raleigh,N.C. 27611
dwz�wz�,
[phone] Facility Name County z la 3 -�
uunu v � I
Address BQ V,
G % Permit Number: Asheville Regional Office
O / �� ,
� � � Non-Discha�r�e �.
Well Location L� NPDES ,l;�s-
Well IdentificationnnNurfpber44� Well Depth IS _Ft. Water Use
Well Diameter r�C ! Sample (Screened) Interval_ Ft. To/S Ft. Injection Well
Depth to Water Level ft. below measuring point. (before sampling) Well Construction 66—
Measuring point is feet above land surface Other .T .b21 1� it
Gallons of water pumped bailed before sampling /0— 1 yJwe s
r
Field Analysis: pH - Specific Conductance uMhos Temp. o C Odor Appearance
Date Sample Collected Z - 2S-4 Date Sample Analyzed Z—
Laboratory Name C_ I- �- Certification No.
COD mg/I NO2 as N mg/I Ni - Nickel mg/I
Coliform: MF Fecal /loom] NO3 as N mg/1 Pb - Lead mg/1
Coliform: MF Total /looml Phosphorus: Total as P mg/I Zn - Zinc mg/1
Dissolved Solids: Total '' mg/1 Al - Aluminum mg/I Pesticides/Herbicides (Specify Compounds)
��
pH (when analyzed) 40 units Ba - Barium mg/I ug/1
TOC mg/I Ca - Calcium mg/I ug/I
Chloride mg/I Cd - Cadmium mg/1 ug/1
Arsenic mg/I Chromium: Total mg/I Other (Specify) ug/I
Grease and Oils mg/I Cu- Copper mg/I ug/I
Hardness: Total mg/I Fe - Iron mg/I ug/I
Phenol mg/I Hg - Mercury mg/I ug/I
Sulfate mg/I K - Potassium mg/I ug/I
Specific Conductance uMhos Mg - Magnesium mg/I ug/I
Total Ammonia(NH3 t NH 4) mg/I Mn - Manganese mg/I
Notes
TKN as N . mg/I Na - Sodium mg/1
Values should reflect total concentrations
1 CERTIF AT TH.S RE T IS TRUE AND ACCURATE.
>« See back for instructions
OAE
Submit blue and green copies to address above.
SIGN RE OF PERMITTEE (OR AUTHORIZED AGENT*)
GW-59 Rev!ed 7/85

�j
.- - ." I - .. %, I - -'. I , I w2... . -, - .. ---, — -7;-- 14,— .-- ---l. - --1 ♦, .Y.. — IVIk.A, .. ,J

J OMPLIANCE MONITORING
REPORT FORM
Facility Name UNMIN Corporation
Address P. 0. Box 58B
Spruce Pine, N. C. 28777
Environmental Manageme
Groundwater Sec
P.O. Box 276E
Raleigh,N.C. 27e
(919)733-508
County mitcheii
Permit Number:
Non -Discharge
Well Location Mlf6hlc%l
NPDES NC0000175
Well Identification Number
#1
Well Depth 15' Ft.
Water Use
Well Diameter 211
Sample (Screened) Interval 5' Ft. To 15' Ft.
Injection Well
Depth to Water Level 11.5
ft. below
measuring point. Cbefore sampling)
Well Construction 60-01018-WIC-0004
Measuring point is feet above land surface
Other Z t l
Gallons of" water pumped bailed before sampling
Field Analysis: pH 4.35
Specific Conductance uMhos Temp.
o C Odor Appearance
Date Sample Collected 11-05-87
Date Lab Sample Analyzed
11-06-87 to 11-19-87
Laboratory Name Environmental Testing,
Inc. Certification No. 40
COD
mg/I
NO2 as N
mg/I Ni - Nickel
mg/I
Coliform: MF Fecal
/100ml
NO3 as N
mg/l Pb -Lead <.050
mg/1
Coliform: MF Total
/loom[
Phosphorus: Total as P
mg/I Zn - Zinc
mg/I
Dissolved Solids: Total 95.8 mg/I
AI - Aluminum
mg/I Pesticides/Herbicides. CSpecify Compounds)
pH (when analyzed) 4.35
units
Ba - Barium <.050
mg/I
ug/1
TOC
mg/I
Ca - Calcium
mg/I
ug/I
Chloride
mg/I
Cd - Cadmium
mg/I
ug/1
Arsenic <.010
mg/I
Chromium: Total <.010
mg/I Other (Specify)
ug/l
Grease and Oils
mg/I
Cu - Copper
mg/I -`�� - '�;a��� �,z-=�
ug/I
Hardness: Total
mg/I
Fe - Iron
(���' �'�� ���� �
mg/I n. i,-=�tr;�' i:�+ Ir', ';,i
`J
ug/I
Phenol
mg/I
H g -Mercury
mg/I Jll:t "�''��
ug/I
Sulfate
mg/I
K - Potassium
mg/I egR7
ug/I
Specific Conductance
uMhos
Mg - Magnesium
mg/I
rtUul'�^�V"A,
.ug/I
L ► �tl;jjWj'
Total AmmoniaCNH3 t NH 4)
mg/I
Mn - Manganese
mg/I Note: RALEIGH, %G
TKN as N
mg/I
Na - Sodium
mg/I
Values should reflect total concentrations
I CERTIF AT THIS
ORT IS TRUE
AND ACCURATE.
# See back for instructions
Submit blue and green copies to address above.
SIG URE OF PERMITTEE (OR AUTHORIZED AGENT#) A E
GW-59 Revised 7/85

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Roy Riddle, Environ. Manager
UNIMIN Quartz Corporation
P. 0. Box 588
Spruce Pine, NC 28777
Kay Dechant
Hydrogeological Technician
N. C. Dept. of Natural Resources &
Community Development
P. 0. Box 370
Asheville, NC 28802-0370
Subject: Monitor Well Analysis
NPDES Permit #NC0000175
Dear Ms. Dechant:
As discussed by phone, attached are the results of the resample
of Well #1 of March, 1987, Compliance Monitoring Collection.
cc: J. S. Booth
C. F. Stover
A. Regis
B. Shalters
Sincer
Roy
Environmental Manager
ECEIVE'
JUN 2 _ 1987
Groundwater Section
Asheville Regional Office
n

COMPLIANCE MONITORING
REPORT FORM
Facility Name
Address
Environmental Management Division
Groundwater Section
P.O. Box 27687
Raleigh,N.C. 27611
[phone]
Well Location
Well Identification. Number Well Depth Ft.
Well Diameter Sample (Screened) Interval Ft. To Ft.
Depth to Water Level
ft. below measuring point. (before sampling)
Measuring point is feet above land surface
Gallons of water pumped bailed before sampling
County
Permit Number:
Non -Discharge
NPDES . '����/S�
Water Use
Injection Well
Well Constructions--���°
Other
Field Analysis: pH
Specific Conductance - uMhos Temp.
o C
Odor Appearance
Date Sample Collected
'
D_ate Lab Sample Analyzed
Laboratory Name
Certification
No.
�
r
_
COD
mg/I
NO2 as N
mg/I,'
Ni - Nickel
mg/I
Coliform: MF Fecal
/100ml
NO3 as N
mg/I.
Pb - Lead
mg/I
Coliform: MF Total
/100ml
Phosphorus: Total as P
mg/1"
Zn - Zinc
mg/I
Dissolved Solids: Total
mg/I
Al - Aluminum
mg/I -
Pesticides/Herbicides (Specify Compounds)
PH (when analyzed)
units
Ba - Barium > !�'
mg/I
ug/1
TOC
mg/l
Ca - Calcium
mg/I,-
ug/I
Chloride mg/I
Arsenic mg/I
Grease and Oils mg/I
Hardness: Total
Phenol
mg/I
mg/I
Sulfate mg/I
Specific Conductance uMhos
Cd - Cadmium_
mg/I
Chromium: Total
�`'� mg/I,
Cu- Copper
mg/I,-
Fe - Iron
mg/I
Hg - Mercury
mg/I
K - Potassium_
Mg - Magnesium
Total Ammonia(NH3 t NH 4) mg/I Mn - Manganese_
TKN as N mg/I Na - Sodium
I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE.
.mg/I
mg/I
mg/I
mg/I
Other (Specify)
Note:
ug/1
ug/I
ug/I
ug/I
ug/I
ug/I
ug/I
Values should reflect total concentrations
# See back for instructions
>�* Submit blue and green copies to address above.
SIGNATURE OF PERMITTEE (OR AUTHORIZED AGENT*) DATE
GW-59 Revised 7/85

COUNTY F ! N.C. PARTMENT OF NATURAL RESOUR
QUAD NO. _TM ,' ': SERIAL NO. `" & COMMUNITY DEVELOPMENT
,F yd F
LAT. LONG. DEM
Report to: 'ARO,%FRO, MRO, FRO, WaRO, WiRO,
WSRO Kinston FO Other
Shipped by: Bus,, Courier, .Other
COLLECTOR,(S): ` - DATE
FIELD ANALYSES
pH400 - Spec. Cond.94 - at 250C
T'emp.10 - oC Odor
` Appearance Taste
Field Analysis By:
A
LABORATORY ANALYSES
BOD5 310 mg/I
COD High 340 mg/1.
COD Low 335 mg/I
Col;iform:MF Fecal, '31616 /loom[
Coliform;MF Total 31504 /100ml,
TOC 680 mg/I
Turbidity 76 NTU
pH 403 units
Alkalinity to pH 4.5 410 mg/l
Alkalinity to pH 8.3 415 mg/I
Carbonate 445 mg/I
Bicarbonate 4.40 mg/I
Arsenic:Total 1002 ff"2 ug/I
Carbon dioxide 405 mg/I
Chloride 940 mg/I
Chromium:Hex 1,032 ug/I
Color:True 80 Pt -co
Cyanide 720: mg/I
Lab Comments: ` X ; r
GROUNDWATER FIELD/LAB FORM
SAMPLE PRIORITY
❑' ROUTINE ❑ EMERGENCY
LAB NUMBER 8 <'---r0
DATE RECEIVED
t IV ,
i
Rec'd by rJrt- From: Bus CoGrler
Other
DATA ENTRY BY: CK; t-'• -
DATE REPORTED: �'- % __ ✓
TIME PURPOSE: BASELINE, COMPLAINT, EOMPLI`ANC'E; LUST, OTHER
(circle one)" -"
Owner r"
Location or site
Description of sampling point
Sampling Method ^-� Sample Interval
Cpump,"barlet, etc'.)
Remarks
(pumping time, air temp, etc.)
Diss. Solids 7.0300_ mg/I.
Fluoride 951 (� mg/I
-"
Hardness:Total 900. mg/l.
Hardness (non-carb). 902 mg/I
Phenols 32730 ug/I
Specific Cond. 95 uMhos/cm2
Sulfate 945. mg/i
Sulfide 745 mg/l
NH3 as N 610 mg/I
TK:N as N 625 mg/I
NO2 +-NO3 as N 630 mg/I -
P:Totai as P 665 mg/l
FT
Ag - Silver 1077
ug/I
Al - Aluminum 1105
ug/I
? , �
Be - Barium '1007
+ �±^/ �� ug/I
Ca - Calcium 916
mg/I
Cd - cadmium 1027'lf�
ug/l
Chromium:Total 1034
..0
ug/I
Cu - Copper 1042
--�,/
ug/l
Fe - Iron 1045
ug/.I,
Hg - Mercury 7190.0
ug/
K Potassium 937
mg/I
,Mg - Magnesium 927
mg/I
,Mn - Manganese 1055
ug/l
Na -,Sodium 929
mg/.l
Ni - Nickel 1067
u1C)
ug/l
Pb *- Lead 1.051
ug/I'.
Se - Selenium 1147
ug/I
Zn - Zinc 1092
ug/Is
GW-54 'Revised 7/85 For Dissolved Analysis submit filtered sample and write 'D,IS' in block
White copy - Headquarters Pink copy - Region Yellow copy - Lab
Organochlorine Pesticides
Organophosphorus Pestic..ide.s.
Acid Herdicldes
Base / Neutral Extractable Organics
Acid Extractable Organics
Purgeable Organics (VOA bottle)
1.2.. - :Dibrom'oe:thane (EDB).

COUNTY N.C. DEPARTMENT OF NATURAL RESOURCES LAB NUMBER 8
QUAD NO. __! .' SERIAL NO. & COMMUNITY DEVELOPMENT- DATE RECEIVED Time —
LAT. LONG. DEM Rec'd by: . _ _ From: Bus -Courier
GROUNDWATER FIELD/LAB FORM 0 Other
Report to: AR9, FRO, MRO, RRO, WaRO, WiRO,
SAMPLE PRIORITY DATA ENTRY BY: CK:
WSRO, Kinston FO Other
0 ROUTINE ❑ EMERGENCY DATE REPORTED:
Shipped by: Bus, CouTler; Other
COLLECTOR(S): DATE TIME PURPOSE: BASELINE, COMPLAINT,COMPLIANCE,,•LUST, OTHER
(circle' -one)- --
FIELD ANALYSES Owner
pH400 Spec. Cond.94 at 250C Location or site r7•.•
_
Temp.10 - oC Odor Description of sampling, point
Appearance Taste Sampling Method - r 'j4- Sample Interval
(pump, bailer, -etc.)
Field Analysis By: - Remarks
(pumping time, air temp, etc.)
LABORATORY ANALYSES
BOD5-310 mg/I
COD High 340 mg/l
COD 'Low 335 mg/I
Coliform:MF Fecal 31616 /100ml
Coliform:MF Total 31504 /100ml
TOC 680 mg/I
Turbidity 76 NTU
pH 403 - , n units
Alkalinity to pH 4.5 410 "• mg/I
,.
Alkalinity to pH 8.3 415 — mg/I
Carbonate 445 t. ` mg/t
Bicarbonate 440j , mg/I
Arsenic:Total 1002 ug/I
Carbon dioxide 405 mg/i
Chloride 940 . mg/l
Chromium:Hex 1,032 ug/i
Color:True 80 Pt -Co
Cyanide 720 mg/I
Lab Comments:
Diss. Solids 70300 "�. /-� mg/l,
Fluoride 951 w mg/I
Hardness:Total 900 mg/I.
Hardness (non-carb) 902 t mg/I
-Phenols
32730 ug/l
Specific Cond. 95 uMhos/cm2
Sulfate 945 mg/I
Sulfide 745 mg/I
NH3 as N 610 mg/I
TKN as N 625 mg/l
NO2+NO3 as N 630 mg/I
PTotal as P 665 mg/I
Ag - Silver 1077 ug/I
Al - Aluminum 1105 ug/I
Be - Barium'1007 ug/I
Ca - Calcium 916 mg/I
Cd - Cadmium 1027 ug/I
Chromium:Total 1034 ug/I
Cu - Copper 1042 ug/I
Fe - Iron 1045 ug/I
Hg - Mercury 71900 ug/I
K - Potassium 937 mg/I
Mg - Magnesium 927 mg/I
Mn - Manganese 1055 ug/I
Na - Sodium 92.9 mg/i
Ni - Nickel 1067 ug/I
Pb Lead 1051 ug/I
Se - Selenium 1147 ug/I
Zn - Zinc 1092 ug/I-
GW-54 Revised 7/85 For Dissolved Analysis - submit filtered sample and write 'DIS' in block
White copy - Headquarters Pink copy - Region Yellow copy - Lab
Organochlorine Pesticides
Organophosphorus Pesticides
I I Acid Herdicides I
Base / Neutral Extractable Organics
Acid Extractable Organics
I I 'Purgeable Organics (VOA bottle) I
I I 1,2 - Dibromoethane (EDB) I

COMPLIANCE MONITORING
REPORT FORM
Facility Name
Address
Environmental Management Division
Groundwater Section
P.O. Box 27687
Raleigh,N.C. 27611
[phone]
Unimin Corp. Quartz Operation
P. 0. Box 588
Spruce Pine, NC 28777
Well Location Off NC 226 Mitchell
Well Identification Number Well #1 Well Depth 15 Ft.
Well Diameter 211 Sample (Screened) Interval c Ft. To 15 Ft.
Depth to Water Level'' 13 ft. ft. below measuring point. (before sampling)
County Mi tchel 1
Permit Number:
Non -Discharge
NPDES NC 0000175
Water Use
Injection Well
Well Construction 60-00018-WM-0004
Measuring point is feet above land surface Other
Gallons of water pumped bailed before sampling 6
Field Analysis: pH 5.7 Specific Conductance uMhos Temp. o C Odor Appearance
Date Sample Collected Nov. 25, 1986 Date Lab Sample Analyzed 12/15, 12/05, and. 12/18/86
Laboratory Name Compuchem, Research Triangle Park Certification No. NC # 37723, EPA # NCO28
COD
Coliform: MF Fecal
Coliform: MF Total
_ mg/I
/100ml
/ 100m1
Dissolved Solids: Total • mg/I
PH (when analyzed) 47 units
TOC
mg/I
Chloride CD) mg/I
Arsenic CD) < U ug/I
Grease and Oils mg/I
Hardness: Total (D) mg/I
Phenol ug/I
Sulfate CD) mg/I
Specific Conductance uMhos
NO2 as N CD)
mg/
NO 3as N (D)
mg/I
Phosphorus: Total as P
mg/I
Al - Aluminum (D)
ug/I
�1d"- Barium (D) 40C IQ.
ug/I
Ca - Calcium (D)
mg/I
Cd - Cadmium (D)
ug/I
T2f"iromium: Total CD) 6,3ug/I
Cu - Copper CD)
ug/I
Fe - Iron (D)
ug/I
Hg - Mercury (D)
ug/I
K - Potassium CD)
ug/I
Mg - Magnesium (D)
Total Ammonia(NH3 t NH4 )(D)mg/I Mn - Manganese (D)
TKN as N CD) mg/I Na - Sodium CD)
I CERTI THAT THI EPORT IS TRUE AND ACCURATE.
GW-59 SIGNATU � OF PERMITTEE OR AUTHORIZED AGENT ID A
mg/I
ug/I
mg/I
Ni - Nickel CD) ug/I
Pb - Lead CD) S ug/I
Zn - Zino (D) ug/I
Pesticides/Herbicides (Specify Compounds)
Other (Specify)
ug/I
ug/I
ug/I
ug/I
ug/I
µ
ug/I
C E I fit' E: ug/I
u r,
1987 ug/I
ug/I
D = Dissolved''Anafj §i's —"Submit- Filtered
Sample 4
See back for instructions
�IE�IE Submit blue and green copies to address above.

i'
COUNTY '` N.C. PARTMENT OF NATURAL RESOUF LAB NUMBER 8
QUAD NO. SERIAL NO. 'A a `}' & COMMUNITY DEVELOPMENT DATE RECEIVED Time
LAT. - LONG. '` DEM Rec'd by: From: Bus -Courier•
-11�_ ` 1 GROUNDWATER FIELD/'LAB FORM 0 Other
Report to''ARO,,�FRO, MRO, RRO, WaRO, WiRO,
-- � SAMPLE PRIORITY DATA ENTRY BY: CK:
WSRO, Kinston FO' Other
[` 'ROUTINE ❑, EMERGENCY DATE REPORTED: -
Shipped by: 'Bus Co.urler—bther
COLLECTOR(S)�`u 2 E-SfSY DATE �r �' �('a TIME PURPOSE: BASELINE, COMPLAINT:L-CO:MRL1-AN.CE-,-LUST, OTHER
(circle one)
FIELD ANALYSES #
owner
-
pH400 rk- S-pec. Conde"94 at 25oC Location or site
f'Temp.-1 C Odor - Description of sampling point
Appearance Taste Sampling Method` !"(� Sample Interval
(pump, bailer, etc.)
Field Analysis By: Remarks _
pumping, time ai¢r temp, etc.)
LABORATORY ANALYSES
BOD5 310 mg/I
COD High 340 mg/I
COD Low 335 mg/I
Coliform,.MF Fecal 31616 /loom[
Coliform:MF Total 31504 /loom[
TOO 680 mg/I
Turbidity 76 NTU
pH 403 unl is
Alkalinity to pH 4.5 410 mg/I
Alkalinity to pH 8.3 415 mg/I
Carbonate 445 mg/I
Bicarbonate 440 mg/i
a
?'
Arsenic:Total 1002 � �.� ug/I
Carbon dioxide 405 m9/I
Chloride 940 mg/1
Chromium:Hex 1032 ug/I
Color.Tue 80 Pt -Co
Cyanide 720 mg/I
Lab Comments:
Diss. Solids 70300 mg/(
y,ee
Raves
Fluoride 951 �g mg/I
Hardness:Total 900 r mg/I
Hardness (non-carb) 902 mg/I
Phenols 32730 ug/I
Specific Cond. 95 uMhos/cm2
Sulfate 945 mg/I
Sulfide 745 mg/I
NH3 as N 610 - mg/I
TKN as N 625 mg/I
NO2 + NO3 as N 630 mg/I
P:Total as P 665 mg/I
Ag - Silver 1077
ug/I
Al - Aluminum 1105
ug/I
DD.
Ba - Barium'1007
g/I
Ca - Calcium 916
mg/I
Cd - Cadmium, 1027
ug/I
.fB
Chromium:Total 1034.aJ
ug/I
Cu - Copper 1042
ug/I
Fe - Iron 1045
ug/I
Hg - Mercury 71.900
ug/I
K - Potassium 937
mg/I
Mg - Magnesium 927
mg/I
Mn - Manganese. 1055
ug/I
Na - Sodium 929
mg/I
Ni - Nickel 1067
;%
ug/I
�r�g^
Pb - Lead 1051
�Fc-f
�ug/I
Se - Selenium 1'147
ug/I
Zn - Zinc 1092
ug/I•
GW-54 Revised 7/85 For Dissolved Analysis - submit filtered sample and write 'DIS' in block
White copy - Headquarters Pink copy - Region Yellow copy - Lab
Organochlorine Pesticides
Organophosphorus'Pesticides.
Acid Herdicides
Base / Neutral Extractable Organics
Acid Extractable Organics
Purgeable Organics (VOA bottle)
1,2.-_Dibromoethane (EDB)
LJ
LiNn
Q,uunawater Section
f7o iii_ n
;mom 'lcgluildf Lillie
'< a
A
•',Ji IJfV� C/�,o��
v`F'1v 1T

COUNTY �� < + t�,If y N.C. DEPARTMENT OF NATURAL RESOURCES
QUAD NO. E SERIAL NO. 4-� ` SI & COMMUNITY DEVELOPMENT
LAT. � � � 1 LONG. 7- DEM
GROUNDWATER FIELD/LAB FORM 0
Report toe `ARp! FRO, MRO, RRO, WaRO, WiRO, SAMPLE PRIORITY
WSRO, Kinston FO Other
M".,ROUTINE ❑ EMERGENCY
Shipped by: Bus' our�,rOther
COLLECTOR(S): MArow r>' I�i/ASUfATE OI'�IG�%' TIME PURPOSE: BASELINE, COMPLAINT
/ Cc1rcl
FIELD ANALYSES
pH400 ZSpec.. Cond?J4 at 250C
o'Tem "1�0 °C Odor
--
Appearance Taste
Field Analysis By:
LABORATORY ANALYSES
BODS 310 mg/I
COD High 340 mg/I
COD Low 335 mg/I
Coliform:MF Fecal 31616 /100ml
Coliform:MF Total 31504 /loom[
TOC. 680 mg/I
Turbidity 76 NTU
pH 403 L�_ Lf units
Alkalinity to pH 4.5 410 mg/I
Alkalinity to pH 8.3 415 mg/I
Carbonate 445 mg/I
Bicarbonate 440 mg/I
Arsenic:Total 1002 ug/1
Carbon dioxide 405 mg/I
Chloride 940 mg/I
Chromium:Hex 1032 ug/I
Color.True 80 Pt -Co
Cyanide 720 mg/I
Lab Comments:
GW-54 Revised 7/85
Owner y e—
Af'
Location or site
LAB NUMBER 8 `� l
DATE RECEIVED r �� `o Time
Rec'd by: From: Bus -Courier
Other
DATA ENTRY BY: u"r CK:
DATE REPORTED: ;e ry "r
!b
T, OTHER
Description of sampling point M)Ec (_ P ;4'J—)
Sampling Method A /L,; /) - Sample interval
(pump, bailer, etc.)
Remarks
r9 1 (pumping time, air temp, etc.)
Diss. Solids 70300 36 mg/1
Fluoride 951 mg/I
Hardness:Total 900 mg/1
Hardness (non -barb). 902 mg/I
Phenols 32730 ug/I
Specific Cond. 95 uMhos/cm2
Sulfate 945 mg/I
Sulfide. 745 mg/I
NH3 as N 610 mg/I
TKN as N 625 mg/I
NO2 1 NO3 as N 630 mg/l
P:Total as P 665 mg/I
Ag - Silver 1077 ugh
Al - Aluminum 1105 ug/I
Be - Barium'1007 ug/I
Ca - Calcium 916. mg/I
C'd -.Cadmium 1027 ug/I
Chromium:Total 1034 ug/I
Ou- Copper 1042 ug/I
Fe - Iron 1045 ug/1
Hg - Mercury, 71900 ug/I
K - Potassium 937 mg/I
Mg - Magnesium 927 MGM
Mn - Manganese 1055 ug/I
Na - Sodium 929 mg/I.
Ni - Nickel 10.67 ug/I
Pb - Lead 1061 ug/1
Se - Selenium 1147 ug/I
Zn - Zinc 1092 ug/I
For Dissolved Analysis - submit filtered sample and write 'DIS' in block
White copy - Headquarters Pink copy - Region Yellow copy - Lab
Organochlorine Pesticides
Organophosphorus Pesticides
I I. Acid Herdicides I
Base / Neutral Extractable Organics
Acid Extractable Organics
I I Purgeable Organics. (VOA bottle) I
1 1 1.2 - Dibromoethane (EDB)

'i
Environmental Management Division f'
COMPLIANCE MONITORING Groundwater Section V Z
P.O. Box 27687 Ri_
REPORT FORM
Raleigh,N.C. 27611
[phone]
Facility Name INTERNATIONAL MINERALS & CHEM. CORP.
County MITCHELL Gr un+w2terSect;?n
Address P. 0. Box 545
Permit Number: N.C. 0000/�1'7k o �«� c';"' C't,;ce
SPRUCE PINE,
N.C. 28777
Non -Discharge
E
Well Location Off NC #226,
Mitchell County
NPDES N.C. 0000175
Well Identification Number Well
#1 Well Depth 15 Ft.
Water Use � + - 1�R
Well Diameter2" Casing Sample
(Screened) Interval 5 Ft. To 15 Ft.
Injection Well
Depth to Water Level 1.1
ft. below measuring point. (before sampling)
Well Construction 60-00018-AMey¢QO,hgional Office
Measuring point is feet above land surface
Other
Gallons of water pumped bailed
before sampling '"6
Field Analysis: pH 5.6
Specific Conductance uMhos Temp.
o C Odor None Appearance
Date Sample Collected July 22, 1986 Date Lab Sample Analyzed
8-1-86, 8-6-86
Laboratory Name CompuChem, Research Triangle Park Certification No. NC #37723/EPA No. NC 028
COD
mg/I NO2 as N (D)
mg/I Ni - Nickel (D)
ug/I
Coliform: MF Fecal
/100ml NO 3 as N (D)
mg/I Pb - Lead CD) L 0.0050 mg/1
ug/I
Coliform: MF Total
/100ml Phosphorus: Total as P
mg/I Zn - Zinc (D)
ug/I
Dissolved Solids: Total 14
mg/I Al - Aluminum CD)
ug/I Pesticides/Herbicides (Specify Compounds)
pH (when analyzed) 5.4
units Ba - Barium (D) ` 0.20 mg/1
ug/I
ug/I
TOC
mg/I Ca - Calcium (D)
mg/I
ug/I
Chloride CD)
mg/I Cd - Cadmium (D)
ug/I
ug/1
Arsenic CD) 4 0.0050 mg/l
ug/I Chromium: Total CD) < 0.030 mg/1
ug/I Other (Specify)
ug/I
Grease and Oils
mg/I Cu - Copper (D)
ug/I "``' '
ug/I
Hardness: Total CD)
mg/I Fe - Iron (D)
ug/I �� �' {" ' G-��'
ug/I
Phenol
ug/I Hg - Mercury (D)
ug/I '°
g/I
; " dON
SEP(�
Sulfate CD)
mg/I K - Potassium (D)
ug/I F ,
ug/I
Specific Conductance
uMhos Mg -Magnesium (D)
mg/I C,F� ' .. r„�, 1':.
ug/I
Total Ammonia(NH3 t NH 4)(D)
mg/I Mn - Manganese (D)
ug/l
D -Dissolved Analysis— Submit Filtered
TKN as N (D)
mg/I Na -Sodium (D)
mg/I Sample
I CERTIFY AT TIS R
RT IS TRUE AND ACCURATE.

COMPLIANCE MONITORING Environmental Management Division
Groundwater Section
REPORT FORM P.O. Box 27687
Raleigh,N.C. 27611
[phone]
Facility Name County
Address Y Permit Number:
-`
-
Non -Discharge
Well Location
NPDES
Well Identification Number_-
l Well Depth / Ft.
Water Use
Well Diameter `
Sample (Screened) Interval - Ft. To Ft.
Injection Well
Depth to Water Level
-r"%% Jf. below measuring point. (before sampling)
Well Construction
Measuring point is
feet above land surface
Other
Gallons of water pumped
bailed before sampling
Field Analysis: pH
Specific Conductance uMhos Temp.
o C Odor
Appearance
Date Sample Collected
Date Lab Sample Analyzed
Laboratory Name
,
7„i�/� Wit. s' Ce
tiff ,•
r cation No.
r. ..,
COD
mg/I NO2 as N CD)
mg/I Ni Nickell CD)
ug/1 }
Coliform: MF Fecal
/100ml NO3 as N CD)
mg/I Pb - Lead (D)
eye c.' , <' 1+ '` Ug/I
Coliform: MF Total
/100m1 Phosphorus: Total .as P
mg/I Zn - Zinc CD)
ug/I
Dissolved Solids: Total mg/I AI - Aluminum (D)
ug/l Pesticides/Herbicides
(Specify Compounds)
pH (when analyzed)
units Ba - Barium CD) `- i. r-
ug/I
ug/I
TOC
mg/I Ca - Calcium CD)'
mg/I
ug/I
Chloride (D)
mg/I
Cd - Cadmium (D)
ug/I
Arsenic (D) „t�, `' r; 'r- «u,g/1
Chromium: Total (D) =f', , ;:
ug/l
Grease and Oils
mg/I
Cu - Copper, CD)
ug/I
Hardness: Total (D)
mg/i
Fe - Iron (D)
ug/l
Phenol
ug/I
Hg - Mercury (D)
ug/I
Sulfate CD)
mg/I
K - Potassium (D)
ug/I
Specific Conductance
uMhos
Mg - Magnesium (D)
mg/I
Total Ammonia(NH3 t NH 4)(D)
mg/I
Mn - Manganese (D)
ug/I
TKN as N CD) Ir
mg/I
Na - Sodium (D)
rng/I
I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE.
GW-59 SIGNATURE OF PERMITTEE OR AUTHORIZED AGENT DATE
ug/l
Other (Specify) ug/I
ug/I
ug/I
ug/I
ug/I
ua/I
D = Dissolved Analysis- Submit Filtered
Sample
CIF See back for instructions
CIE* Submit blue and green copies to address above.

Environmental Division
COMPLIANCE MONITORING
Groundwater Section
REPORT FORM
P.O. Box 27687
RmJeigh,N-0'Q7611
(0}10)730-508�
Facility Name ~ - �
-
County
Address
Penni'tNumbec
Non -Discharge
Well Location
NPOE8
Well Identification, Number ' `
-
Well Depth Ft.
'Water
Use
' Well Diameter Sample [Soroened]Interval _-r;---_Ft. To T -_Ft.
Injection Well
Depth, to Water Level � '
ft. below
measuring point.(befpro sampling)
Well Construction
. Measuring point intoot above land surface
Other
Gallons of water pumped bailed
before sampling
' .
Field Analysis: pH
Specific Conductance
uMhos Temp.
0
O
Odor Appearance
~~`, ,,,.~., ~~.~,^~^,
Date L"" "a...v'e "''"'xz""
Laboratory Name S, C T Certification No.
---
`''g^'
'`02 as '` ^~'
'"w/'
'``' Nickel' `-'
-"'' '
Oo|jforrn: K4F Fecal
/180m[
NO3au N[D]
mg/I
J»b - Lead [D] ' ' ^ '
ug/|
CV|ifonn: MFTota
/100nd
Phosphorus: Total as
mg/|
Zn -Zinc [U]
ug/|,
. .'�
~'�inao|v*d Solids: Total �
mg/|
Al -Aluminum (D)
ug/|
Poohoides/Herb ioides [SpooifyC>ompoundol
- (when analyzed) /
units
B'a -Barium CD)
ug/|
ug/|
TDC
mg/|
Da - Ca|olbnn [D]
mg/|
ug/|
Chloride [D]
mg/I
Cd - Cudmium(C)
/|
ug/|
� ./�{
�onioD] � - ~ ' '
ug/|
~Qhron�ium: Tofa|(0) z�
''� ` |
Othor[Specify}
ug/|
Grease and Oils
nng/|
Cu -Coppor (D]
ug/|
ug/|
Hardness: Total [D}
mg/|
Fe - Iron [O]
ug/|
�
��+
� ugH
Phenol
ug/i
Hg - Mercury CD)
ug/|
ug/|
Sulfate {D]
mg
K -potaouium(D)
ug/|
ug/|
Specific Conductance
uyWhou
Mg^Magnesium [D)
nng/|
ug//
Tubd AmrnoniuLNH3t mH4]{O)_---_-��
mg/|
Mn - Manganese(D)
ug/|
O ~ Di000|vedAna|ysio— Submit
Filtered
TKN as N [DJ
mg/|
Na ' Sodium CD)
rnO/|
Sump|e
\ CERTIFY THAT THIS REPORT
IS TRUEAND ACCURATE.
See b^ox for instructions
Submit mueanu green copies to uummsnuupvo.
-__-----'
GVV-58 SIGNATURE DFPERM|TTEEORAUTHORIZED AGENT DATE

COUNTY
QUAD NO. ' ' f 'SERIAL NO.:
LAT. J %W ' LONG.
Report to:�AROi FRO, MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO Other
Shipped by: Bus, Courier, Other
N.C. DEPARTMENT OF NATURAL. RESOURCES LAB NUMBER $
& COMMUNITY DEVELOPMENT
DEM
GROUNDWATER FIELD/LAB FORM
SAMPLE PRIORITY
❑' ROUTINE ❑ EMERGENCY
0 DATE RECEIVED 1—' 7' K*�fy' Time
Reed by: 1p.1 I From: Bus -Courier
Other
DATA ENTRY BY: r ,Y CK:
DATE REPORTED: �� 1
COLLECTOR(S): A<r!=�%'
"r,%y~
DATE l ,' TIME ALL()
PURPOSE: BASELINE,
COMPLAINT, `OMPLIANCE� LUST, OTHER
FIELD ANALYSES
Owner =f %', �. -�%� ; y.� i{' ." ,• r . ''; :r.
pH400 Spec.
Cond.94
at 250C Location or site
Temp. 10 °C
Odor
Description of sampling
point %� f�
oZ,
Appearance
Taste
Sampling Method
°'
Sample Interval
(pump, bailer, etc.)
Field Analysis By:
Remarks
_ (pumping time, air temp, etc.)
� }
LABORATORY ANALYSES
BOD5 310
mg/I
COD High 34.0
mg/I
COD Low 335
mg/I
Col].form:MF Fecal 31616
/loom]
Coliform:MF Total 31504
/loom]
TOC 660
mg/I
Turbidity 76
NTU
if
pH 403 1; _
units
{
Alkalinity to pH 4.5 410
mg/I
?�
Alkalinity to pH 8.3 415
mg/I
Carbonate 445
G, 7
mg/i
Bicarbonate 440
mg/I
Arseni c:Total 1002
ug/1
Carbon dioxide 405
mg/1
Chloride 940
w
mg/1
Chromium:Hex 1032
u8/I
Color:True 80
Pt -Co
Cyanide 720
mg/I
Lab Comments:
t
Diss. Solids 70300
.f7 n
mg/L
Fluoride 951
mg/I
Hardness:Total 900
mg/1
Hardness (non-carb) 902 4/
mg/I
Phenols 32730
u
ug/I'
Specific Cond. 95
uMhos/cm2
Sulfate 945
mg/I
Sulfide 745
mg/I
NH3 as N 610
mg/I
TKN as N 625
mg/I
NO2 + NO3 as N 630
mg/I
P:Total as P 665
mg/I
Ag - silver 1077 ug/I
Al - Aluminum 1105 ug/I
Be - Barium'1007 ug/1
Ca - Calcium 916 mg/1
Cd - Cadmium 1027 ug/I
Chromium:Total 1034 ug/I
Cu - Copper 1042 ug/I
Fe - Iron 1045 ug/I
Hg - Mercury 71900 ug/I
K - Potassium 937 mg/1
Mg - Magnesium 927 mg/I
Mn - Manganese 1055 ug/i
Na - Sodium 929 mg/I
Ni - Nickel 1067 ug/I
Pb - Lead 1051 ug/I
Se - Selenium 1147 ug/I
Zn - Zinc 1092 ug/I•
GW-54 Revised 7/85 For Dissolved Analysis - submit filtered sample and write 'DIS' in block
White copy - Headquarters Pink copy - Region Yellow copy - Lab
L-Organochlorine Pesticides
Organophosphorus Pesticides
I I Acid Herdicides I
Base / Neutral Extractable Organics
Acid Extractable Organics
I I Purgeable Organics (VOA bottle) I
1 1 1,2 - Dibromoethane (EDB) 1

COUNTY '--:",
'' '% /' `'
N.CJ APARTMENT OF NATURAL. RESOUO 1`
LAB NUMBER 8
QUAD NO. �1„r� �
SERIAL NO. ���' `'�� 1-
^& COMMUNITY DEVELOPMENT
DATE RECEIVED J ��sTime r /'
LAT. "' '�
LONG. ' �- /
DEM
Rec'd fiy — From: Bus�Ccurier----
'-
�_
GROUNDWATER FIELD/LAB FORM
Other
Report to:' ARO� FRO,
MRO, RRO, WaRO, WiRO,
)!-
SAMPLE PRIORITY
DATA ENTRY BY f/._ CK:-
WSRO, Kinston FO
Other
�'
0 ❑
ROUTINE EMERGENCY
DATE REPORTED:
Shipped by: Bus,+C�er, Other
COLLECTOR(S): 'J :i =1� 7�1,/DATE J�T�� ' : • TIME fir'- PURPOSE: BASELINE, COMPLAINT,
_
OMPLIANC LUST, OTHER
r
t (circle one)"-- --"
FIELD ANALYSES
OwnerrlrrJrr.'/)Y2 � 'it,"'r�.rr i�4
¢
!�.'rf"r.•sri,�.'�,
pH400 Spec.
Cond.94 at250C
Location or site "
Temp. 10 °C
Odor
Description of sampling point �• `� �Pj��'
Appearance
Taste
Sampling Method
—Sample Interval - 'ISM
(pump, bailer, etc'.)
Field Analysis By:
Remarks
�- / ; (pumping time, air temp, etc.)
"i;�
� r Af' kAe",, lJr�
LABORATORY ANALYSES
BOD5 310 mg/I
COD High 340 m9/I
COD Low 335 mg/I
Coliform:MF Fecal 31616 ✓100mi
Coliform:MF Total. 31504 /100ml
TOC 660 mg/I
Turbidity 76 NTU
pH 403 units
Alkalinity to pH 4.5 410 mg/I
Alkalinity to pH B.3 415 mg/I
Carbonate 445 mg/i
Bicarbonate 440 mg/I
G�.
Arsenic:Total 1002 ug/1
Carbon dioxide 405 mg/I
Chloride 940 mg/l
Chromium:Hex 1032 ug/I
Color:True 80 Pt -Co
Cyanide 720 mg/I
Diss. Solids 70300 mg/1
Fluoride 951 mg/I
Hardness:Total 900 mg/I
Hardness (non-carb) 902 mg/I
Phenols 32730 ug/I
Specific Cord. 95 uMhos/em2
Sulfate 945 mg/1
Sulfide 745 mg/1
NH3 as N 610 mg/I
TK14 as N 625 mg/I
NO2+NO3 as N 630 mg/I
P:Total as P 665 mg/I
Ag - Silver 1077
ug/I
Al - Aluminum 1105
ug/l
Be - Barium '1007
w Li
ug/I
Ca - Calcium 916
mg/I
Cd - Cadmium 1027
ug/I
a12i5
Chromium:Total 1034�
ug/I
Cu - Copper 1042
ug/I
Fe - Iron 1045
ug/I
Hg - Mercury 71900
ug/I
K - Potassium 937
mg/I
Mg - Magnesium 927
mg/I
Mn - Manganese 1055
ug/I
Na - Sodium 929
mg/I
Ni - Nickel 1067
ug/I
Pb - Lead 1061
r;)
ug/I
Se - Selenium 1147
ug/I
Zn - Zinc 1092
ug/I•
Organochlorine Pesticides
Organophosphorus Pesticides
Acid Herdicides
Base / Neutral Extractable Organics
Acid Extractable Organics
Purgeable Organics (VOA bottle)
1,2 - Dibromoethane (EDB)
y
u x), li
Lab Comments:
FED, 2 1986
Groundwater Section
n_�
tc: ue itegional Office
GW-54 Revised 7/85 For Dissolved Analysis - submit filtered sample and write 'DIS' in block
White copy - Headquarters Pink copy - Region Yellow copy - Lab
9

Environmental Management Division
COMPLIANCE MONITORING Groundwater Section
REPORT FORM P.O. Box 27687
Raleigh,fd.C. 276,1 1
[phone]
Facility Name .._nip,,-,.f1 1 County
Address ' `! 7 Permit Number:
Well Location -F
f
Well Identification Number ; / 4 f Well Depth i �,� Ft.
Well Diameter `�' ` Sample (Screened) Interval � Ft. To / �" Ft.
Depth to Water Level /2 ZLw ,ft. below measuring point. Cb,efore sampling)
Measuring point is feet above land surface
Gallons of water pumped bailed before sampling
Field Analysis: , pH Specific Conductance uMhos Temp. o C
Non -Discharge
Water. Use
Injection Well
Well Construction
Other
Date Sample Collected % ! ` Date Lab Sampie Analyzed
Laboratory Name'-`!�/,'rt}� /"fh_s% /7: w„, f 3� Certification N
! 1
COD mg/I NO2, as N (D) ' mg/I
Coliform: MF Fecal /100ml NO3 as N CD) mg/I
Coliform: MF Total /100ml
Dissolved Solids: Total ,:— mg/I
PH (when analyzed) �� 1 units
TOC mg/I
Chloride CD) mg/I
,1 t
Arsenic (D) — ,% Ls•J ii%+s/�9/I
t
Grease and Oils
Hardness: Total (D)
Phenol
mg/I
mg/I
ug/I
Sulfate CD) mg/I
Specific Conductance uMhos
Total AmmoniaCNH3 t NH4 )CD)mg/I
Phosphorus: Total as P mg/I
Al - Aluminum (D) ug/I
Ba - Barium (D) G f- U ri ry ; r-' ug/I
Ca - Calcium (D) mg/I
Cd - Cadmium (D) ug/I
Chromium: Total (D) 2 (0. /22`�'yti ug/I
Cu - Copper CD) ug/I
Fe - Iron CD) ug/I
Hg - Mercury (D) ug/I
K - Potassium CD) ug/I
Mg - Magnesium (D)
Mn - Manganese (D
TKN as N (D) mg/I Na - Sodium (D) _
I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE.
GW-59 SIGNATURE OF PERMITTEE OR AUTHORIZED AGENT
DATE
mg/I
ug/I
mg/I
Odor. 1G 1, Appearance
AC? 151
Ni -'Nickel CD) - ug/I +
Pb -Lead [D) �= Y`; c & ug/I
Zn - Zinc (D) ug/I
Pesticides/Herbicides (Specify Compounds)
Other CSpecify)
ug/I
ug/I
ug/1
ug/I
ug/I
ug/I
ug/I
ug/I
.uq/I
D = Dissolved Analysis — Submit Filtered
Sample
-1 See back for instructions
CIE* Submit blue and green copies to address above.

COLLECTION AND ANALYSIS OF GROUNDWATER SAMPLES
1. Samples should be analyzed as soon as possible after collection.
2. The Laboratory making the analysis should be consulted concerning proper procedures for sample
collection and preservation.
3. Measure and record the depth of water in the well prior to pumping or bailing any water from
the well.
4. At least six volumes of water in the well should be pumped or bailed prior to collecting a sample
for analysis.
5. Determination for pH, Specific Conductance, temperature, odor and apperance must be made in the
field on unfiltered samples when the sample is collected.
6. Field equipment must be calibrated in accordance with recommendations by the manufacturer.
7. Samples must be filtered through a 45 micron filter immediately after collection when a dissolved
analysis is required.
8. The sample container should be labeled with the facility name, well identification number and date
and time collected.

COUNTY N. C. DEPARTMENT OF NATURAL RESOURCES ' " '" LAB NUMBER
QUAD No. a SERIAL NO. & COMMUNITY DEMEVELOPMENT 8 DATE RECID
REPORT TO: (circle one) GROUNDWATER FIELD/LAB FORM JUL 15 1985 REcID BY
ARO, WSRO, MRO, FRO, WaRO, )
Groundwater Section DATA ENTRY BY CK
WiRO, RRO, Ahoske F0, - -�
OTHER Asheville Regional Office DATA REPORTED
PURPOSE: (circle one) baseline, pollution monitor, other _
DATE COLLECTED 4<- `7' Time i_i -?i ' By. :i , ,., . 7 Location or site fk a`.
Description of sampling point i .; ii i i�r;.^.dPY Sampled interval _
rW_ -
Remarks
'(pumping time, air temp, etc.)
e �a
Field Analysis By: Lat. Lon g. f s If
PH Spec. Cond. Temp, oC )dor Appearance Taste
Lab Analysis
Alkalinity to pH 4.5
P00410
m9/1
Alkalinity, hydroxide
P71830
mg/l
Carbonate
P00445
trig/1
Bitarbot[a*te
P00440
mg/1-
pH value (woen analyzed)
P00400
units
�:Arsenie (D)
Carbon dioxide
PO1000
P00405
ug/l
mg/l
Chloride (D)
P00940
mg/l
Color (True)
P00080
units
Cyanide
P00720
mg/l
Dissolved solids (D)
P70301
mg/l
,Fluoride (D)
P00951
mg/1
Hardness (as CaCO3)(D)
P00900
m9/1
Hardness (non-carbonate)(D)
P00902
mg/l
MBAs (D)
P38260
mg/l
Phenol (D)
P34466
ug/l
ti Silica (D)
P00955
`_% mg/l
._Sulfate (D)
P00946
G ;; mg/1
`*Specific Cond.
P00094
� Z,� UMHOS/cm
p
GW-54 Revised 1/12/82
4Ag-Silver (D) P61075 -<' 15b ug/1
e,Al-Aluminum (D)
P01106
I/;i';.ug/1
�-Ba-Barium (D)
P01005 ! .y/)0 ug/1
�Ca'-Calcium (D)
P00915
P, /^ mg/l
,,Cd-Cadmium (D)
P01025
f ug/l
j,Cr-Chromium (D)
P01030
g/l
�, Cu-Copper (D)
P01040
ug/l
`Fe -Iron (D)
P01046
u9/1
,; Hg-Mercury
P71900
'/�, �, ug/l
-Li=Lithium (D)
P01130
_ - �"f�ug/1
`.W Magnesium (D)
P00925
-. mg/l.
s
Mn-Manganese (D)
P01056,
✓ -",)u 1
- 7, g/
-N&Sodium (D)
P00929
2, / mg/1
,Pb-Lead (D)
P01049
_ :.;?' 'ug/l.
,,aZn-Zinc (D)
P01090;;
ug/1
K,7Potagsium (D)
P00935
BOD
P00310
MR/1
COD
P00341
12S/1
Coliform (Fecal MF)
P31616
/looms
Coliform (total MF)
P31505
/10oml
,TOQ
P00680
mg/l
Turbidity
P82079
NTU
.Ammonia (as Nitoogen) (D)
,�A
P00612
rr, �`_ mg/1
Kjeldahl (as Nitrogen)'(D)
P00623
vti + mg/l
'__Nitrate i- Nitrite (as Nitrogen)(D)
P00631
mg/1
Phosphorus, total as P (D)
P00666
mg/l
Dissolved Solids - cond. meter
P70304
mQ/l
Other Analyses:
MA {vi,
JUL 11 1985
D = Dissolved Analysis - submit filtered sample
White copy - Headquarters Pink copy - Region Yellow copy - Lab 7� PiU�I� t7ATER $ECTIC11
��ll �UIU RALEiGH. (let. Jr l� l

COUNTY
QUAD NO. _ SERIAL NO.
REPORT TO: (circle one)
ARO, WSRO, MRO, FRO, WaRO,
WiRO, RRO, Ahoskie FO,
OTHER
PURPOSE: (circle one) baseline; pollution monitor, other
N. C. DEPARTMENT OF NATURAL RESOURCES
& COMMUNITY DEVELOPMENT
DEM
GROUNDWATER FIELDAAB FORM
LAB NUMBER J
DATE RECID
REC'D BY
DATA ENTRY BY fi' `' t CK
=�
DATA REPORTED �--- -
DATE COLLECTED Time r; 'r' I By J! r`r '`✓f, e Location or site
Description of sampling point 'r f Sampled interval
Remarks
(pumping time, air temp, etc.)
Field Analysis By: Lat, p ;= Long. Z. _LIN,
pH Spec. Cond.- Temp, °C )dor Appearance Taste_;
i
Lab Analysis
Alkalinity to pH 4.5
P00410
m9/1
Alkalinity, Wdroxide
P71830
mg/l
Carbonate
P00445
mg/l
Bitarborra'te
P00440
m9/1
-pH value Cwoen analyzed)
/
P00400 (
units
Arsenic (D)
P01000 / 0
ug/1
_
Carbon dioxide
P00405
mg/l
Chloride (D)
P00940
mg/1
Color (True)
P00080
units
Cyanide
P00720
mg/l
Dissolved solids (D)
P70301
mg/l
---Fluoride (D)
P00951 = (7> ;
mg/1
Hardness (as CaCO-A)(D)
P00900
mg/l
Hardness (,non-carbonate)(D)
P00902
mg/l
MBAS (D)
P38260
mg/1
Phenol (D)
P34466
ug/l
..Silica (D)
P00955
m9/1
- Sulfate (D)
P00946 �
mg/1
-Specific Cond.
P00094 - 4 UMHOS/cm
GW-54 Revised 1/12/82
Ag-Silver (D) F01075 '-6 0_ug/l
"41-Aluminum (D) P01106 `"A)0 .ug/1
Ba-Barium (D) P01005 000 u 1
_Ca Calcium (D) .,'P00915 1e Y mg/1
­1�Cd-Cadmium (D) P01025 ?0 ug/l
O_=Chromium (D) P01030 ug/l
Cu-Copper (D) PO1040 0 ug/l
-"Fe-Iron (D) P01046 ��%(� (.� ug/l
--11g-Mercury P71900 -<10f 2 ug/1
—... Tt«1.1 /T\ Dni1In -Cf,< X —/'1
Mg -Magnesium (D) P00925 ut,71i mg/1
M-Mangane a (D) P01056 G+�r ug/l
Na,Sodium (D) P00929 �c mg/l
-Pb-Lead (D) P01049 C ` uQ/1
—Zn-Zinc
ium
BOD A
P00310
Gil
mg/1
E;
COD
P00341
/l
Coliform (Fecal NY)
P31616
/100ml
Coliform (total MF)
P31505
/100ml
TOC
P00680
mg/l
Turbidity
P82079 •
NTU
Ammonia (as Nitorgen) (D)
P00612
1mg/l
Kjeldahl (as Nitrogen)'(D)
P00623
mg/l
Nitrate + Nitrite (as Nitrogen)(D)
P00631
mg/l
Phosphorus, total as P (D)
P00666
mg/l
Dissolved Solids - cond. meter
P70304
mg/l
Other Analyses:
fit
D = Dissolved Analysis - submit filtered sample
White copy - Headquarters Pink copy - Region Yellow copy Lab
GROUND !LATER SECTICTI
"ALEIrH, 11. r

COUNTY ,° :". ;"; N , . y'.;`
N. C. DEPARTMENT OF NATURAL RESOURCES
LAB NUMBER
, SERIAL NO.
QUAD No.
.; °) - t``
$ COMMUNITY DEVELOPMENT
c`
,� °;
DEM
DATE REM'_
REPORT TO: (circle one)
GROUNDWATER FIELDAAB FORM
RECID BY
ARO;`WSRO, MRO, FRO, WaRO,
WiRO, RRO, Ahoskie FO,,
DATA ENTRY BY CR
OTHER
DATA REPORTED - J
PURPOSE: (circle one) baseline, tlluto ,,m-ionitor, other
DATE COLLECTED _ / 1 fc
Time i `
,,
By. fF. =e er � Location or site
,
°
r i t,..o• / J -
Description of sampling point
,� F>�r
'
,.
Sampled interval
Remarks
(pumping time, air temp, etc,)
t -
Field Analysis By: Lat. L e e'r Long.
PH_ Spec. Cond. Temp, oC )dor Appearance Taste
Lab Analysis
Alkalinity to pH 4.5
P00410
14
mg/1
NAlkalinity, Hydrexi,ds
P71830
mg/1
�sCarbonate
P00445
r e
mg/1
0 Bi ' rboxrate
P00440
I-1
mg/1
pH value (tvl9en analyzed)
P00400
C, C'
units
Arsenic CD)
P01000
ug/l
Carbon dioxide
P00405
m9/1
Chloride jD)
P00940
mg/l
Color (True)
P00080
units
Cyanide
P00720
mg/l
,,DiAsolved solids (D)
P70301
h
mg/l
Fluoride (D)
P00951
mg/l
,Hardness (as CaCO3)(D)
P00900
`41)
mg/1
.-Hardness (non-,carbonate)(D)
P00902
, \
mg/1
MBAS (D)
P3826o
mg/1
Phenol (D)
P34466
ug/l
Silica (D)
P00955
mg/l,
Sulfate (D)
P00946
mg/l
Specific Cond,
P00094
UMHOS/cm
GW-54 Revised 1/12/82
Ag=-Silver (D)
P01075
ug/l
Al -Aluminum (D)
P01106
ug/1
Ba-Barium (D)
P01005
ug/l
Ca -Calcium (D)
P00915
mg/1
Cd-Cadmium_(D)
P01025
ug/1
Cr-Chromium (D)
P01030
ug/l
Cu-Copper (D)
P01040
ug/1
Fe -Iron (D)
P01046
ug/l
Hg-Mercury
F71900
ug/l
Li -Lithium (D)
P01130
ug/1
Mg -Magnesium (D)
P00925
mg/l
Mn-Manganese (D)
P01056
ug/l
Na,Sodium (D)
P00929
mg/1
Pb-Lead (D)
P01049
ug/l
Zn-Zinc (D)
P01090
ug/l
K-Potassium (D)
P00935
mg/l
BOD
P00310
mg/1
COD
P00341
/1
Coliform (Fecal MF)
P31616
/100ml
Coli form (total MF)
P31505
/100m1
TOC
P00680
mg/l
Turbidity
P82079
NTU
Ammonia (as Nitorgen) (D)
P00612
mg/1
Kjeldahl (as Nitrogen)`(D)
P00623
mg/l
Nitrate + Nitrite (as Nitrogen)(D)
P00631
mg/l
Phosphorus, total as P (D)
P00666
mg/l
Dissolved Solids - cond. meter
P70304
mQ/l
Other Analyses:
D = Dissolved Analysis - submit filtered sample
White copy —Headquarters Pink copy - Region Yellow copy - Lab

NORTH CAROLINA kRTMENT OF NATURAL RESOURCES & COMNI _ FY DEVELOPMENT 131&1
WELL RECORD [VISION OF ENVIRONMENTAL MANAGEMENT
P 0. Box 27687 - RALEIGH, N.C. 27611 919-733-2020 t rW
DRILLING CONTRACTOR ,c � ��( REG. NO. WELL CONSTRUCTION PgAIT NO. (1 9
1. WELL LOCATION: (Show sketch of the loc n/b�elow) �
Nearest Town: L\ �c� //i County: �i4JA �/ i' CUildw?tel' Section
Office
(Road,Community or Subdivision and Lot No.) Quadrangle No.
2. OWNER: "% V - l do, /-a 1 / ///Y�i , C 0 rf_j DRILLING LOG
3. ADDRESS ��J ♦ P V -415 AIs 6 i X,7 ,r DEPTH
FROM TO FORMATION DESCRIPTION
4. TOPOGRAPHY: draw,valley,,slope,hilltop,flat(circle one)
5. USE OF WELL: CJl�%! V �� DATE: �_ % `a�
6. DOES THIS WELL REPLACE AN EXISTING WELL? /J;T/
7. TOTAL DEPTH RIG TYPE OR METHOD:
8. FORMATION SAMPLES COLLECTED: YES NO
9. CASING: Depth Inside Wall thick. type
Dia. or weight/ft.
From /►� to ft j
em
10. GROUT: Depth Material Method
From to ft
2 rl��
If add—it-1-0-n-a-E space is needed, use back o orm
11. SCREEN: Depth Dia. Type & Opening
From to ft LOCATION SKETCH
a j r♦ i G I (Show distance to numbered roads, or other map reference points)
12. GRAVEL: Depth Size Material
From to ft
13. WATER ZONES(depth):
14. STATIC WATER LEVEL: ft. above top of casing
below
Casing is ft. above land surface ELEV:
i
15. YIELD(gpm): METHOD OF TESTING:
16. PUMPING WATER LEVEL: ft.
after hours at gpm.
i
17. CHLORINATION: Type Amount
18. WATER QUALITY: TEMPERATURE(oF)
19. PERMANENT PUMP: Date Installed_
Type Capacity (gpm)HP I
Make Intake Depth
Airline Depth
20. HAS THE OWNER BEEN PROVIDED A COPY OF THIS RECORD AND INFORMED OF THE DEPARTMENTS REQUIREMENTS AND
RECOMMENDATIONS?
21. REMARKSAl
I
I do hereby certify that this ell was nstructed in accordance with N.C. Well Construction
Regulations and Standards an h th' wel rorpd is true and exact.
/ �i � �✓
SIGNA RE O _ AGENT DATE
GW-1 Revised 10/1/80 mit original to Division of Environmental Management and copy to well owner

NORTH CAROLINA
DEPARTMENT OF NATURAL RESOURCES AND COMMUNITY DEVELOPMENT
DIVISION OF ENVIRONMENTAL MANAGEMENT
QUALITY OF WATER DATA (Office)
Location: Town S,01,&ee 1;Ip _ ounty /%%!�t�&/z Quad No.
Map e /) / A-m Serial No. Ai
Owner .1 Depth ft. Diam. in. Yield gpm
Aquifer .ZP Screen
Date
Hour
Discharge
Temp.
°F
pH
Specific
Conductance
(micromhos)
Chloride
mg/1
Iron
g/1
Hardness
mg/1
Remarks
(taste, odor, appearance,
etc.)
period
g m
GW-6 Revised 10/1/80

NOV 07 '95 01:38PM
JIB Ilyr�;'-R•HIS-+giii,�Y>,aS�e�,.>*:.M::a:.u+X,.:+�m...:'M.et':�e^+.Yf�„+� P.
_� :g+ea3�ws h+... .s�ti.;.... u.�, f£ qi.,,a: � •, w��Sa n7•�ryy�_
UnImIri
Quartz Operation
P. O. Box 580
Bakenville Hwy,
Spruce Pine, NC 28777
[phone]
Fax [phone]
November 6, 1995
Kay Dechant, Hydrogeologist,
NC Department of Environment,
Health and Natural Resources
Ground Water Section
59 Woodfin Place
Asheville, NC 28801
Subject: Well abandonment, UNIMIN Corporation quartz/Feldspar Mitchell County, NC
Dear Ms. Dechant:
As discussed, enclosed please find the Well Abandonment Records for our three (3)
wells located in Mitchell County, NC off -Highway 226 3 miles North of Spruce Pine,NC.
1) Monitor we.l_h�(.2!'x1.5! )_.Q1r2_yd_s_. cement grout
2) Monitor wet-1--t2!'x25J) .020-ydsr._cement�gr_o.u.t
3) Drinking water (6"0861) 2.8 yds. cement grout
Each well was completely filled with cement after being disinfected.
Should you have any questions please feel free to call me at [phone].
Since
r
R Riddle
Envi onmental Supervisor
cc: J. Taylor
c. Klimper
T. Haskell
B. Shelter
NOV 71995
GROUNDWATER SECTION
ASHEVILLE REGIONAL OFFICE

North Carolina
Department of Environment, Health, & Natural Resources
Division of Environmental Management
Groundwater Section �-
P.O. Box 29535-- Raleigh, N.C. 27626-06-35-
WELL ABANDONMENT RECORD
CONTRACTOR
1. WELL LOCATION: (;
Nearest Town:,
'Bake H _% t/: I 1
a sketA pf the
2. OWNER: UN I M ;►k) Qp
tra.2. (0 A,' 3
, Subdivision, Lot
REG. NO.
on back of form.)
r1_11 f-
3. ADDRESS: r"® Iid-D �- J 1'S �hI ►' ce,c e I !N/p
4. TOPOG HY draw, slope, hilltop, valley, fiat
5. US . OF WE L: '4S� G(/2.I ( DATE:
6. TOTAL D 11: DIAMETER:
7. CASING REMOVED:
feet
8. SEALING MATERIAL:
Neat cement
bags of cement
gals. of water
diameter
Sand cement
bags of cement
yds. of sand
gals. of water
Other aephic).J4
Typematerial
AmonZ Jt
t o t �J • UA o
,9. CXPLAIN M71i % I7` EM,�' CEMENT OF MATERIAL.
(�
!,u I
Z,)01+ti TV-rtpQ _ A w 6.4IFVCi A A�ruaeca
i1Wf.�
Quadrangle No.
WELL DIAGRAM: Draw a detailed sketch of
he well showing total depth, depth and dia-
meter of screens remaining in the well, gravel
interval, intervals of casing perforations, and
:iepths and types of fill materials used.
V
w r -i w
M
I do hereby cer fy that this well abando ent rec rd is true and exact.
Signature of Contractor ot4Agent Date IdZ24T
WELL LOCATION: Draw a location sketch on the reverse of this sheet, showing the direc-
tion and distance of the well to at least two (2) nearby reference points
such as roads, intersections and streams. Identify roads with State High
way road identification numbers.
Submit original to the Division of Environmental Management, one copy to
and one copy to the owner.
GW-30 Revised 3/8/90

WELL NO. 7 91 t -2-
COUNTY / - / / 7G HE L L
DATE SAMPLED
ALKALINITY, TO pH 4.5
ALKALINITY, TO pH 8.3
ALUMINUM
ARSENIC
L Q o 00 /
i. O • ci f
- /J . 9.0
9. ©ps
4 O. 00-
BARIUM
L d • /y
t O• 0"2
< O. /O
4 O. i o
BERYLLIUM
BICARBONATE
CADMIUM
CALCIUM
CARBONATE
CHLORIDE
CHROMIUM, TOTAL
L ©�
0 0,6"
4 O' d
< 0• Oa 0
O • 0
COBALT
COD
COLIFORM, FECAL
COLIFORM, TOTAL
COPPER
D v /
C7 • O /
G O. O
CYANIDE
DISSOLVED SOLIDS
916
S
v
SJ
FLUORIDE
p, R,4 c-
HARDNESS CaCo,
HARDNESS, NON -CARBONATE
IRON
LEAD
L 0.
O. 0 -3
LITHIUM
Red Ink = Sample taken by facility

WELL NO.. T b 1 fi
COUNTY /N% l% C j-/ E L L
DATE SAMPLED
6_1-3-17f
%-/y_qf
//-/5
MBAS
MAGNESIUM
MANGANESE
MERCURY
NICKEL
NITROGEN, -AMMONIA
NITROGEN, KJELDAHL
NITRATE & NITRITE
ORGANIC SCAN
pH
.
'��•
4,9
IK s-
to .
PHENOLS
PHOSPHORUS, TOTAL
POTASSIUM
SELENIUM
SILVER
SODItn1
SPECIFIC CONDUCTANCE
SULFATE
TOC (UNFILTERED)
TOX
TSS
VOC
ZINC
STATIC WATER LEVEL
% ,
/��
/7 •D/
�h�• ��Z .
/-Y. O'

WELL NO. �:Z: S '
COUNTY M i T C H C L L
DATE SAMPLED
I - %' % �2
//-• / q - 7 �2
-9 - 9 - 9'3
6 2,213
`j- /3 - fg
11. 7- 5 3
ALKALINITY, TO pH 4.5
ALKALINITY, TO pH 8.3
ALUMINUM
ARSENIC
b• (GO I
` O . CUO j
O • G0 /
/
O. O 0 1
O,
BARIUM
o
o • sy
©. C� /S
O• /O .
4 0 . io
BERYLLIUM
BICARBONATE
CADMIUM
CALCIUM
CARBONATE
CHLORIDE
CHROMIUM, TOTAL
�- J
G D • 0 )L
z Q . G A
L Q.
0. O.X
02
COBALT
COD
COLIFORM, FECAL
COLIFORM, TOTAL
COPPER
�. U / (�
C�. C7 (
d • U /
. O /
O. �1
CYANIDE
DISSOLVED. SOLIDS
3 T
126
3
FLUORIDE
4 0 . / 14RO
HARDNESS CaCo3
HARDNESS, NON -CARBONATE
IRON
LEAD
.GC?.DS
L �,©3
•t ®� ®
LU.G1
L �.p��
O• j
LITHIUM
Red Ink = Sample taken by facility

WELL NO. T � f
COUNTY H/ T G /-/ r L L-
DATE SAMPLED
7 - %" 9
//- / y= y ],
3 - R - 9 ,3
6-,2a - 7 3
MBAS
MAGNESIUM
MANGANESE
MERCURY
NICKEL
NITROGEN, AMMONIA
NITROGEN, KJELDAHL
NITRATE & NITRITE.
ORGANIC SCAN
PH
7 -
PHENOLS
PHOSPHORUS, TOTAL
POTASSIUM
SELENIUM
SILVER
SODIUM
SPECIFIC CONDUCTANCE
CJ
SULFATE
TOC (UNFILTERED)
TOX
TSS
VOC
ZINC
STATIC WATER LEVEL
/ `
%'� •
/
�.3, O�
/'
�� - ,

WELL NO. = S /, -`i 2
COUNTY N1 %C 1/ELL
DATE SAMPLED
ALI:ALINITY, TO pH 4.5
ALIULINITY, TO pH 8.3
ALUMINUM
ARSENIC
No
AID
0. 0D1
L O- 00
0, 0/0
4 O,
BARIUM
No
ND
BERYLLIUM
BICARBONATE
CADMIUM
CALCIUM
CARBONATE
CHLORIDE
CHROMIUM, TOTAL
/!i
/v U
D• U a
4 D• 0�
O• v g s
G d. t)z,
COBALT
COD
COLIFORM, FECAL
COLIFORM, TOTAL
COPPER
Al
G (sue. D /
% • D /SP
c =� • Ci f
CYANIDE
DISSOLVED SOLIDS
FLUORIDE
HARDNESS CaCo,
HARDNESS, NON -CARBONATE
IRON
LEAD
/yD
. T�5
o- i
.4 p. 0/D
0. D.S
LITHIUM

WELL NO. �� ✓
COUNTY /'9 / ' % G /4 C � L
DATE SAMPLED
//- = g�
3 - S- % l
- e /
//- - 9 /
s = 1,2 - V-Z
3--16 -gx
MBAS
MAGNESIUM
MANGANESE
MERCURY
NICKEL
NITROGEN, AMMONIA
NITROGEN, KJELDAHL
NITRATE & NITRITE
ORGANIC SCAN
pH
Af
�f
f
PHENOLS
PHOSPHORUS, TOTAL
POTASSIUM
SELENIUM
SILVER "
SODIUM
SPECIFIC CONDUCTANCE
•3
SULFATE
TOC (UNFILTERED)
ZINC
STATIC WATER LEVEL
00
13•
7. '%
/,3. 5

/j.
COS D i i I
DATE SAIPLED
ALKALINITY TO pH 4.5
Ao
ALKALINITY, TO pH 8.3
-
ALUMINUM
ARSENIC
'�O•�
�D.A?$
!
�aDOs
,
vcs"f
c o• ����
z . 0f0
< o. o0!'
3ARIUM
�3
�DD� Ira
uSp
�o•oSo��,vio
3ICARBONATE
`
:ADMIUM
L UDoZ
,ALCIUM
ARBONATE
t I
HLORI DE
HROMIUM, TOTAL
O L�
�O.O!
��.D 2
'� �• ooZd
�'
" vaS
D • D a
OD
3
DLIFORM, FECAL
i
OLIFORM, TOTAL
OPPER
�,D�Y
Q.!)�9
I
�, Q�Z
G G. f�/D
z
0,27
G ®. O10
YANIDE
Z
ISSOLVED SOLIDS
32., 3
(� ,
s`�
•� D. S
%
LUORIDE
ARDNESS, CaCO
ARDNESS NON-CARBONATE
RON
I
i
I C)
EAD
f0�/
D.03s
�v•b5v
�6. (�E�
c . v �0
< o. as
3AS
kGNES I UM
LNG S
;RCURY
_
cxL
-
01 0
T

(Continued)
7-f(/�-Z
DATE. SPIPLE0
NITkOGENj AMMQMTA
11,4
ivo
511a� 70
116fic
o f
7 - 9-90
NITROGEN ,KJELDAHL
NITRATE & NITRITR
• of
ORGANIC SCAN
pH
J,- fo
PHENOLS
PHOSPHORUS, TOTAL
POTASSIUMSELENIUM
0 0s
SILVER
0 d,5r
SODIUM
)PECIFIC CONDUCTANCE
;ULFATE'
70C (UNFILTERED)
+
,
',INC
O A 2
Or eve
4aL
S,3
/�.L[7

coil -IT)
i DATE SPIPLEn
ALKALINITY CaCO3
To pR.8.3
To pH 4.5
-
-
Aluminum _
Arsenic
G4
611C
4,0, d i
Bicarbonate
Cadmi um
GD d
1
QZ
Calcium
Q, $3
Carbonate
c
�-
G
Chloride
e_
-
Chlorinated Hydrocarbon
'
Chromium, Hexavalent
Chromium, Total
ZAA25
, AD
. Off
COD
j
1
Coliform, Fecal
Col i foIrm, Total
Cyanide
j
Dissolved Solids
,���
�'
�,6, �,
�d
"jj
1gN1
F1 uori de
Hardness as CaCO
Hardness, Non -carbonate
T-41
y
Iron
Lead
moods
LAB
Lithium
WAS
Magnesium
© 6
Manganese
Itrcury
�D.ODD
Nirkpl

DATE SA'1PL£Q -
a
017.21xs $ $�-
Ni Mogen.,-.k=ni -
Nitrogen, Meldahl
Nitrate & Ni trite-
'
a:
Organic' Scan
-
+
S
d ,D
s
s S 7o 5•�5
Phenols `
,
-
Phosphorus,'-TotaT
-
Potassium k
• .
i
-s
{v.;
Si'�Mer
�
Sodi un i
1
Sul
Sulf�it*`"
Zinc
°8ari um
Copper-„;dldla
1j�D
i.
k
A .

D Spj
11.�//7/1r�-t'-'-.L1
-4IT Y Cacc,,)
To - p 1H. g.3.
7 p 5
U m 41 n um.
Arsenic
Z1009-6
Bicarbonate
C ad,-, i i u mi
Cal ci um
C a r b. o na t e
t Chl! on de
car,
Chlorinated Hydrocarbon
hromium, H-axavalent-
_' -9
ium, ToLa,
Fc h. —ro - n 4,q OL5- i -1d, tas-
1
I /-A mr
1
1, Ze. d0l..,44.
n'5-T/0,
1
030
?
b ob 4
COD
Col is f orm, Fecal
Coli-formi, Total
j 1
Cyanide
Dissolved Solids
zkS
41
-Fluoride
Hardness as CaCO3
Hardness, Non Carbonate
Lead
G� aMS--�
Q.�
S
�D D
�D.D.�
,OOso
do03 .
.Li-t-hiurr!
Ld. ps-
11B AS
Magnesium
"Manganese
too' �_i
F
Oats
I
I
Mercury
Nickel

-'�-
!��. �'� � t Canti Hued; �
r-xuc L
CID li 411, "el
p �
DATE SA: ri�, L_O
J
Nitrogen, Ammonia
f Nitrogen, Kiel dah i
Nitrate & Nitrite
j
d
----
i Organic Scan
I
f
p
Phenols
I Phosphorus. Total
�Potassium0.�
G
-
LSel enium
I
I
i
ca
s
Si l•verL
Sodium
a,�LZ
7
f
Specific Conductance
Su1-fate
—�-s
Sulfite
f
zinc
iG
I

Type or Use a ball-point pen and press firmly.
Facility Name Unimin Corporation
Address P. 0. Box 588, 226 Bakersville Hwy.
Spruce Pine, NC 28777 County
PERMIT NUMBER: (REQUIRED)
Non -Discharge _
NPDES /ilk D00/) f 7:S
TYPE OF DISPOSAL OPERATION BEING MONITORED
Well Location Iota (REQUIRED)
Lagoon Septic Tank/Drain Field
Well Identification Number MW#2 Well Depth _z._S ;—Ft.
Well Diarneter/+-'" Sample (Screened) Interval 20 Ft. To 2_Ft.
Depth,,to Water Level 13. 04 ft. below measuring point (before sampling)
Measuting;point is-_ft. above land surface
Lllonsr.ofAwater pumped/bailed before sampling
fld y#nalysis: pH 6. 0 Specific Conductance 29 uMhos Temp. 12 °C Odor
Date Sargple Collected 3/20/95 Date Lab Sample Analyzed 3/20/95
Laboratory: -Name PACE, Incorporated Certification No.
SAMPLES`=F-OR METALS WERE COLLECTED UNFILTERED AND FIELD ACIDIFIED YES
Spray Field Subsurface Low -Pressure
Piping (LPP)
Land Application of Sludge
Other
Rotary Distributor
Appearance
40
NO
COD
mg/I
Nitrite (NO2) as N
mg/I
Ni - Nickel
cartFit
mg/I
Coliform:.MF Fecal
A 00ml
Nitrate (NO3) as N
rri�g/I
Pb - Lead_ L 0.05
mg/I
Colifonn': MF Total
A 00ml
Phosphorus: Total as P
L hg/I
Zn - Zinc
-
mg/I
(Note: UseMP:N:method for highly turbid samples)
AI - AIUmInUm
mg/I
Pesticides/Herbicides
Dissolved Solids: Total 27
mg/I
Ba - Barium L 0.10
mg/I
(Specify Compounds)
pH (when analyzed)
units
Ca - Calcium
mg/I
ug/I
TOC
mg/I
Cd - Cadmium
mg/I
= -'
ug/1
Chloride
mg/I
Chromium: Total T. 0.020
mg/I
�;a
ug/I
Arsenic L 0.005
mg/I
Cu - Copper L 0.01
mg/I
Other (Specify Compounds and
(-''ease and Oils
mg/I
Fe - Iron
mg/I
Concentration units)
_
irdness: Total
mg/I
Hg - Mercury
mg/I
Phenol
mg/I
K - Potassium
mg/I
Sulfate
mg/I
Mg - Magnesium
mg/I
Specific Conductance
uMhos
Mn - Manganese
mg/I
Total Ammonia
mg/I
Na - Sodium
mg/I
TKN as N
mg/I
CERTIFY AT THIS SPORT IS TRUE A `©ABC.
°= Note: Values should reflect dissolved and
�� I N 9 colloidal concentrations. (see #3 on back)
- 1 1 6 1 See back for instructions.
SI nat a of Permittee (or-Authoriz'ed iAgent Grounbiaker i:ecti R t ** Submit blue, green, and yellow copies only to address above.
GW-59 REV. 6/9
S;:;' k�

COLLECTION AND ANALYSIS OF GROUNDWATER SAMPLES
1. Samples should be analyzed as soon as possible after collection. SAMPLES WHICH ARE NOT ANALYSED WITHIN THE HOLDING TIME SPECI-
FIED FOR THE METHOD USED (SEE #4. BELOW) MUST BE DISCARDED AND NEW SAMPLES COLLECTED.
2. Metals Analyses:-Use`Startdard Method 30OC'for sample preparation (mercury excluded). DO NOT FILTER METALS SAMPLES IN THE FIELD !?+.
Unfiltered samples must be coll6'cte&f6r metals, then field acidified with 5 ml concentrated nitric acid per liter of sample, and should be submitted to the
lab within 24 hours.
Sample preparation in the laboratory (extraction and filtration) must be completed within.72 hours of collection.
3. ANALYSES ARE TO BE MADE OF THE MOSELE CONSTITUENTS (DISSOLVEb AS WELL AS "COLLOIDAL) N THE
GROUNDWATER, NOT THOSE THAT ARE A -PART OF SEDIMENT ASSOCIA T ED WITH WELL CONSTRUCTION OR SAMPLING PROCEDURES.
CHECK WITH YOUR LABORATORY ON PROPER PROCEDURES FOR SAMPLE COLLECTION ANiDJPRESERVATION. i•
4. As per Title 15, North Carolina Administrative Code, Subchapter 2L, analytical procedures shall be in accordance with the methods described in one of
the following publications, or by other methods approved beforehand by the Director, Division of Environmental
Management:
(a) Standard Methods for the' Examination of Water and Wastewater, 16th Edition, 1985 and 17th Edition, 1989, published jointly by
American Public Health Association, American Water Works Association and Water'Pollution Control Federation;
(b) Methods for Chemical Analysis of Water and Waste. 1979, U.S. Environmental Protection Agency publication number
t
EPA-60014-79-020, as revised March 1983:
(c) Test Methods for Evaluating Solid Wastes: Physical/Chemical Methods, 3rd Edition, 1986. U.S. Environmental Protection Agency
U publication number SW-846;
(d) Test Procedures for the Analysis of Poll uants Under the Clean Water Act, Federal Register Vol. 49. No. 209, 40 CFR Part 136,
October 26, 1984;
5. Mea f nd record the depth of water in the well prior to pumping or bailing any water from the well.
c; c ,
6. At least 3 volumes of water in the well should be pumped or bailed prior to collecting a sample for analysis. If the well is pumped/bailed dry before 3 well
volumes are.removed, samples can be collected as soon as the well recovers to the point where enough water is available to collect your sample.
7. Determination for pH, Specific Conductance, temperature, odor and appearance must be made in the field on unfiltered samples when the sample is
collected.
8. Field equipment must be calibrated in accordance with recommendations by the manufacturer.
9. Samples must be filtered through a 0.45 micron filter immediately after collection ",when a dissolved analysis is required. (See #r:4. above)
10. The sample container should be labeled at the time of collection with the facility n Ii iutification number and date and time collected.
1.1-"Authorized agent" is any corporate officer or public official authorized by.ttfe'c4mp,Gny, corporation,.or governrhental body to •sign off icial`documents.
4

:�:-_'�strd'ss����';�?::a�-;,u;•:_:i��*.Y3� :.�:iyi.;'�.�'��'2:Jg�:�_ -_
. :.. .'. ' • - - _ ..:�. :. - #.tit#''' :<_.x.Ft
An
.%i:�4: <-,f��ih:�'83:: `:'i:. �'.fi.FAY.``�•-{:,xz"ss ��;3icx..i>._. SY3� �- �r) � : �g�.��'r3:?•?.,�:�2:�.:.:-�,.c„�. - E'.�-.�3�.�cs
co Type or use a ball-point pen and press firmly -
Facility C0-:K" ation e:
Faciti'ty Nartns
_ Address P..0. Boz 588, 226 Sakexsrflle Hwy.
m
County.
PERMIT NUMBER: MIrQUIRED)
Non -Di ,
rYPE OF DISPOSAL OPE TION BEING MONITORED
IREQUMEM • �-
Well Location iota
,
Lagoon SeplcTankMmi►Field
Well Identiflet n Number 1102 c ell Depth — Ft
- t
- ter
Well Diameter Sample (Screened) Ins , Ft. TD _FL
;
'
�;
�rFEW Subsu LevfPmssure
_ Piping JLM
Depth to Water Level 1344 it below measuring point (before sampling)
Measuring is -fk land surf
LwdPfo' afaal of Sludge
�'�
pant above
Gallons of water pungx4Ybal1ed before sampling
Field Analysis: pK �►-0 rfic Carductagos 29
ulrAhos Temp: 12 DC
odor
Appearance
Data Sample Colected 3/ 20 95 Date Lab sample Analyzed 31.20!'95
- ;r
Laboratory Name PACE Inca rat4d
Certification No. _
40
SAMPLES FOR METALS WERE COLLECTED U FILTERED AND FIELD ACIDIFIED
YES
H4
COD gA
Nt'tM' a (NO2) as N -
mgA :_
Ni - Nickel mgA
Coliform: MF Fecal 11 ()o
Nitrate (NO3) as N
r�tgll;�
Pf, -Lead m
Coliiforin: MF Total 11 obml
Phosphorus: Total as P
gA :
Zn - Trlc mgA
INoW:urgWNnrftodierfighlrWrUdswoeo ,,
AI -Aluminum
mgA-;
Pesticides/Herbicides
Dissolved Solids: Total • 2s irr gA
Ba - Barium L C• 10
nrgA ,
(Specify compounds)
pH (when analyzed). units
Ca - Calcium
nvfi ;
ugA
TOC mgA
Cd - Cadmium
mgA,.
ugA
'Chloride mgA
Chromium: Total L 0.020
mgA.'-
ugA
Arsenic L 0.005 OiA
Cu - Copper L QeQ1
mg&.
Other (Specify Compounds and.
Grease and Oils M_QA
Fe - Iron
mgA .
Concentration units)
Hardness: Total -1hgA
Hg - Mercury
mgA-.
Phenol digA
K - Potassium
mgA
Suffate mgA
Mg - Magnesium
mg/t
Specific Conductance UM(ios
Mn - Manganese
mgA
Total Ammonia mgA
Na - Sodium
mgA.
TKN as N mgA
1 CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE
Note:,. Values should reflect dissolved and
colloidal concentrations. (4ee # 3 on back)
t
See back[ for instructions.
Si rta of Pe ittee (or Authori Agent') r
e
•• Submir
blue. green% and yelow copies only to address above.
GW-59 REV
j
7
f-

GROUNDW
Type or Use a ball-point pen and press finnly. PERMIT NUMBER: (REQUIRED)
Facility Name Unimin Corp. Non -Discharge
Address P. 0. Box 588, Spruce Pine, NC 28777 NPDES
County Spruce Pine TYPE OF DISPT-L949
ION BEING MONITORED
Well Location T o Y_a (REQUIRED) �� -oon Septic Tank/Drain Field
Well Identification Number MW#2 Well Depth Ft. 410
Well Diameter Sample (Screened) Interval. Ft. To FL - _
Depth to Water Level 14.82 ft. below measuring point (before sampling) -
Measuring point is ft. above land surface
Gallons of water pumped/bailed before sampling y _
Field Analysis: pH 5.5 Specific Conductance 0_ uMhos Temp. 16 °C Odor
Date Sample Collected 11/15/94 Date Lab Sample Analyzed 11/15/94
Laboratory Name PACE, Inc. Certification No.
SAMPLES FOR METALS WERE COLLECTED UNFILTERED AND FIELD ACIDIFIED YES
COD mgA
Coliform: MF Fecal /100ml
Coliform: MF Total /100ml
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total 35
mgA
pH (when analyzed) 5.5
units
TOC
mgA
Chloride
mgA
Arsenic T. 0, nn5
mgA
Grease and Oils
mgA
Hardness: Total
mgA
Phenol
mgA
Sulfate
mgA
Specific Conductance 30
uMhos
Total Ammonia
mgA
TKN as N
mgA
Spray Field Subsurface Low -Pressure
Piping (LPP)
Land Application of Sludge
Other
Rotary Distributor
Appearance
40
NO
Nitrite (NO2) as N
mg/l
Nitrate (NO3) as N
g/I
Phosphorus: Total as P
AA
Al - Aluminum
mgA
Ba - Barium T. 0,10
mgA
Ca - Calcium
mg/l
Cd - Cadmium
mgA
Chromium: Total L 0.020
mg/l
Cu - Copper L 0.01
mgA
Fe - Iron
mg/l
Hg - Mercury
mgA
K - Potassium
mgA
Mg - Magnesium
mg/l
Mn - Manganese
mgA
Na - Sodium
mgA
I CERTIFY THAT THIS REPORT IS TRUE AND ACC
Signature of Permittee (or Authorized Agent")
GW-59 REV. 6/93
Ni - Nickel mgA
Pb - Lead L 0.05 mg/l
Zn - Zinc mg/l
Pesticides/Herbicides
(Specify Compounds)
ugA
ugA
ug/I
Other (Specify Compounds and
Concentration units)
Note: Values should reflect dissolved and
colloidal concentrations. (see #3 on back)
• See back for Instructions.
'• Submit blue, green, and yellow copies only to address above.

Type or Use a ball-point pen and press firmly. PERMIT NUMBER: (REQUIRED)
Facility Name Unimin Corp. Non -Discharge
Address P. 0. Box 588, Spruce Pine, NC 28777 NPDES
County Spruce Pine TYPE OF DISPOSAL OPERATION BEING MONITORED
(REQUIRED)
Well Location Iota _ _ 4 Lagoon Septic Tank/Drain Field
Well Identification Number MW#2 i 1r —Well Depth Z , Ft. Spray Field Subsurface Low-&r ssure
Well Diameter Sample (Screened) Interval 2.0 Ft. To �Ft. Piping (LP r,l
Depth to Water Level 14.82 ft. below measuring point (before sampling) Land Application of Sludge Uq :K
Measuring point is ft. above land surface other .-n C):;0
Rotary Distributor I"1 �;u
allons of water pumped/bailed before sampling
eld Analysis: pH 5.5 Specific Conductance 30 uMhos Temp. 16 °C Odor Appearance
Date Sample Collected 11/15/94 Date Lab Sample Analyzed 11/15/94
Laboratory Name PACE, Inc. Certification No. 40
SAMPLES FOR METALS WERE COLLECTED UNFILTERED AND FIELD ACIDIFIED YES NO_
n1
COD m9 /I Nitrite (NO) as N m A Ni - Nickel m /I
Coliform: MF Fecal
A 00ml
Coliform: MF Total
A 00m1
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total 35
mg/I
pH (when analyzed) 5.5'
units
TOC
mg/l
Chloride
mg/I
Arsenic T. 0-005
mg/I
grease and Oils
mg/I
ardness: Total
mg/I
Phenol
mg/I
Sulfate -
mg/I
Specific Conductance 30
uMhos
Total Ammonia
mg/I
TKN as N
mg/I
2
Nitrate (NO3) as N
g
/IPhosphorus:
Total as P
4/1
Al - Aluminum
mg/I
Ba - Barium
mg/I
Ca - Calcium
mg/I
Cd - Cadmium
mg/I
Chromium: Total L 0,020
mg/I
Cu - Copper L 0.01
mg/I
Fe - Iron
mg/I
Hg - Mercury
mg/I
K - Potassium
mg/I
Mg - Magnesium
mg/I
Mn - Manganese
mg/I
Na - Sodium
mg/I
I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE.
Signature of Pe mittee (or Authorized Agent*) Date
GW-59 REV. 6/93
9
Pb -Lead L 0.05 mg/I
Zn - Zinc mg/I
Pesticides/Herbicides
(Specify Compounds)
u g/1
u g/I
u g/1
Other (Specify Compounds and
Concentrati t':9nl ---
Note: Values should reflect dissolved and
colloidal concentrations. (see #3 on back)
* See back for instructions.
** Submit blue, green, and yellow copies only to address above.

COLLECTION AND ANALYSIS OF GROUNDWATER SAMPLES
1 . Samples should be analyzed as soon as possible after collection. SAMPLES WHICH ARE NOT ANALYSED WITHIN THE HOLDING TIME SPECI-
FIED FOR THE -METHOD USED (SEE #4. BELOW) MUST BE DISCARDED AND NEW -SAMPLES COLLECTED.
2. Metals Analyses, Use Standard Method 3030C for sample preparation (mercury excluded), PQ __RQjfILTER METALS 5,AjA_EL.ES IN THE
Unfiltered samples mu§tbe Collected for.metals, then field acidified with 5 ml concentrated nitric acid per liter cisarnple, and should be submitted to the
lab within 24 hours.
Sample preparation in the laboratory (extraction and filtration) must be completed within 72 hours of collection,
3. ANALYSES ARE TO BE �JIADE OF THE MOBILE CONSTITUENTS (DISSOLVEVAS WELL A-S tOLLOIDAL) IN THE
Gft(�JNDWATER, NOT THOSE THAT ARE A PART? SEDIMENT ASSQCIATEQ WITH WELL, gQN _BTRfQ'_Q-GQN QR SAMPLING PRQQE2T!jR-_ES.
C -19-CK qTH YOUR LA130RATORY ON PROPER PROCEDURES FOR Sj%,MPLE C'OLLECTiON AND PRESERVATION.
4. r Tiiti- 15, North Carolina Administrative Code, Subchapler 2L, analytical procedures shall be in accordance with the methods described in one of
tij.Eljallo4ipg publications, or by other methods approved beforehand by the Director, Division of Environmental
Qn,ageRlent:
(a) Standard Methods for the Examination of Water and Wastewater, 16th Edition, 1985 and 17th Edition, 1989, published iointly by
American Public Health Association, American Water Works Association and Water Pollution Control Federation;
(b) Methods for k.., 4
Chemical Analysis of Water and Waste, 1979, U.S. Environmental Protection Agency publication number
EPA -600/4-79-020, as revised March 1983;
nvironmental Protection Agency
E
(c) Test Methods for Evaluating Solid Wastes: Physical/Chemical Methods, .01rd Edition, 1086, U.S. C
publication number SW-846;
(d) Test Procedures for the Analysis of Polluants Under the Clean Water Act, Federal Register Vol. 49, No. 209, 40 CFFR Part 136,
October 26,1984;
5. Measure and record the depth of water in the well prior to purrnping or bailing any water from the well.
6. At least 3 volumes of water.in th-ewell should be pumped or bailed prior to collecting a sample for analysis. If the well is pumped/bailed dry before 3 wel'
,
volumes are re ' ' Aar�l,o
Jbldrn,-.�in be collected as soon as the well recovers to the point where enough water is available to collect your sarnple.
7. DeterminationjprpYm, ifiC,01ohiNuctance, temperature, odor and appearance must be made in the field on unfiltered samples when the Sample is
collected.
S. Field equipment must be calibrated in accordance with recommendations by the manufacturer.
9. Samples must be filtered through a 0.45 micron filter immediately after collection when a dissolved analysis is required. (See #4. above)
10. The sample container should be labeled at the time of collection with the facility name, well identification number and date and time collected.
1 !."Authorized agent" is any corporate officer or oublic official authorized ley the company,
pany, corporation, or governmental body 16 -sign 6fflcial documents
It

Type or Use a ball-point pen and press firmly. PERMIT NUMBER: (REQUIRED)
Facility Name Unimin Corporation Non -Discharge
Address P. 0. Box 588 NPDES 7S
Spruce Pine, NC 28777 County Mitchell TYPE OF DISPOSAL OPERATION BEING MONITORED
Monitor' Well (REQUIRED)
Well LocationL--'Lagoon SepticTank/Drain Field
Well Identification Number #2 / I d� Well Depth ZS Ft'. Spray Field Subsurface Low -Pressure
Well Diameter oA ' Sample (Screened) Interval Za Ft. To ��Ft.
Depth to Water Level 14.50 Piping (LPP)
p ft. below measuring point (before sampling) Land Application of Sludge
Measuring point is /. jft. above land surface Other
^.Ilons of water pumped/bailed before sampling X,_ C1 a-yNess Rotary Distributor
old Analysis: pH 4.8 Specific Conductance,_ 38 uMhos Temp. 14 oC OdorA/Vive Appearance
Date Sample Collected 7/19/94 Date Lab Sample Analyzed 7/19/94
Laboratory Name PACE, Incorporated Certification No. 40
SAMPLES FOR METALS WERE COLLECTED UNFILTERED AND FIELD ACIDIFIED X YES NO
COD
mg/I Nitrite (NO2) as N
mg/I
Ni - Nickel
mg/I
Coliform: MF Fecal
/100ml Nitrate (NO3) as N
rpg/I
Pb - Lead L 0.05
in mg/I
Coliform: MF Total
/100ml Phosphorus: Total as P
Ong/I
Zn - Zinc U0
rp mg/I
(Note: Use MPN method for highly turbid samples)
Al - Aluminum
mg/I
Pesticides/Herbicides 40 `,ra
��
Dissolved Solids: Total 50
mg/I Ba - Barium L 0.10
mg/I
(Specify Compounds)
0ri
pH (when analyzed) 4.8
units Ca - Calcium
mg/I
TOC
mg/I Cd - Cadmium
mg/I
Chloride
mg/I Chromium: Total L 0.020
mg/I
Arsenic L 0.005
mg/I Cu - Copper T. 0.01
mg/l
Other (Specify Compounds and
s
r,rease and Oils
mg/I Fe - Iron
mg/I
Concentration units) ••
�'
frdness: Total
mg/I Hg - Mercury
mg/I;
vnenol
mg/I K - Potassium
mg/1
Sulfate
mg/I Mg - Magnesium
mg/I
Specific Conductance 38
uMhos Mn - Manganese
mg/I
Total Ammonia
mg/I Na - Sodium
mg/I
TKN as N
mg/I
I CERTIFY THAT THIS REPORT TRUEJI4G.CUF< <=E-= -�
I,
Note:
Values should reflect dissolved and
J,
Yf.'a {
colloidal concentrations. (see #3 on back
Signature o ermittee (or Authorized
4 199�_
Ag . i) Date
See back for instructions.
** Submit blue, green, and yellow copies only to address above.
GW-59 REV. 6/93
Grourdr,ater S00t:n

COLLECTION AND ANALYSIS OF GROUNDWATER SAMPLES
I. Samples should be analyzed as soon as possible after collection. SAMPLES WHICH ARE INOT ANALYSED WITHIN THE HOLDING TIME SPECI-
FIED FOR THE METHOD USED (SEE #4. BELOW) MUST BE DISCARDED AND NEW SAMPLES COLLECTED.
2. Metals Analyses:--U-se,-Standard,,MethoZi..3,030C for sample preparation (mercury excluded), DO NOTFILTERMETALS SAMPLES IN THE FIELD
, " �'­ collected .C.
Unfiltered samples must e co'lldcted f6rlietals, then field acidified with 5 ml concentrated nitric acid per liter of sample, and should be submitted to the
lab within 24 hours.
Sample preparation in the laboratory (extraction and filtration) must be completed within 72 hours of collectiorl.
3. ANALYSES ARE TO BE MADE OF THE MOBILE CONSTITUENTS (DISSOLVED -'AS WELL A9 COLLOIDAL) LN THE
GROUNDWATER, NOT THOSE THAT ARE A PART OF SEDIMENT ASSOCIATED WITH WELL CONSTRUCTION OR SAMPLING PROCEDURES.
CHECK WITH YOUR LABORATORY ON PROPER PROCEDURES FOR SAMPLE I COLLECTION AND PRESERVATION.
4. As per Title 15, North Carolina Administrative Code; 8,ub . thapter 2L, analytical procedures shall be in accordance with the methods described in one of
the following publications, or by other methods approved beforehand by the Director, Division of Environmental
Management: (a) Standard Methods for the Examination of Water and Wastewater, 16th Edition, 1985 and 17th Edition, 1989, published jointly by
American Public Health Association, American Water Works Association and Water Pollution Control Federation;
(b) Methods for Chemical Analysis of Water and Waste, 1979, U.S. Environmental Protection Agency publication number
EPA-600/4-79-020, as revised March 1983-,
(c) Test Methods for Evaluating Solid Wastes: Physical/Chemical Methods, 3rd Edition, 1986, U.S. Environmental Protection Agency
publication number SW-846;
(d) Test Procedures for the Analysis of Polluants Under the Clean Water Act, Federal Register Vol. 49. No. 209. 40 CFR Part 136,
October 26, 1984;
5. -Measure and record the depth of water in the well prior to pumping or bailing any water from the well.
6, <.At,603 volumes of water in the well should be pumped or bailed prior to collecting a sample for analysis. If the well is pumped/bailed dry before 3 well
vorurn6,6� are removed, samples can be collected as soon as the well recovers to the point where enough water is available to collect your sample.
7. Determination for pH, Specific Conductance, temperature, odor and appearance must be made in the field on unfiltered samples when the sample is
collected.
8. Field equipment must be calibrated in accordance with recommendations by the manufacturer.
9. Samples must be filtered through a 0.45 micron filter immediately after collection when a dissolved analysis is required. (See #4. above)
10. The sample container should be labeled at the time of collection with the facility name, well identification number and date and -time collected.
:X
Ahb cb Mkapy, corpora 6
-581%,rgovernmonta-r 6df-ta'signoffilial "d r�nts'
11e""Authorized agent" is any corporate officer or public official authorized. i�,ti

North Carolina
GROUNDWATER FIELD/LAB FORM Department of Environment, Health, and Natural Resources
DIVISION OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER SECTION
County ✓M I L-
Quad No T 61 L2 Serial No. /i!lX
Lat. j-6- S( / 14 Long. U 05 58
Report To: AR FRO, MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO, Fed. Trust, Central Off., Other:
Shipped by: Bus Courier and De Other
SAMPLE PRIORITY
KOUTINE EMERGENCY Mom_
CHAIN OF CUSTODY
i
MI/ NA/ i C/- Purpose:
Collector(s): R c , i Date Time / I -'i U A M Baseline,
MELD ANALYSES
400 Spec. Cond.94 at 250 C
Temp.10 oC Odor
Appearance
Field Analysis By:
LABORATORY ANALYSES
Owner
Lab Number fG `/
Date Received 6-1.7- 9 `/ Time 42 -3y
Rec'd by: Sv From: Bus, Courier and el;,
Other:
Data Entry By: St-- Ck: A LIE
Date Reported: (a.0 - 9 w
nt, ompliance�L LUST, Pesticide Study, Federal Trust, Other:
Location or site 1_7 DwiyG RA- b f ��v r 0 r- /- 4 G vo..s
Description of sampling oint�
Sampling Method Sample Interval -2 a S
Remarks (Pump, bailer, etc.)
A ying ae, air tem�, etc. /
. r7
GW-54 REV. 6/93 For Dissolved Analysis - submit filtered sample and write "DIS" in block. F
� ( i

North Carolina
Department of Environment, Health, and Natural Resources
GROUNDWATER FIELD/LAB FORM
DIVISION OF ENVIRONMENTAL MANAGEMENT- GROUNDWATER SECTION
County M y G H C L L. Lab Number v
Quad No �� "f Serial No. M1 / 36 is SAMPLE PRIORITY Date Received Time -
Lat. -3 SY -66 /`/- Long. 5� U-S S-S7 - QROUTINE EMERGENCY Rec'd by:A 2'2 From: Bus, ourie , Hand Del.,
CHAIN OF CUSTODY M VV Other: /
Report To: AR FRO, MRO, RRO, WaRO, WiRO, Data Entry By- � Ck:
WSRO, Kinston FO, Fed. Trust, Central Off., Other: Date Reported: % ��
Shipped by: Bus, Courie Hand Del., Other- Purpose:
M��v icK
CollecDate " i 3 ` y `. _ Time /.' JO1 %Q M Baseline, Complaint, om liance LUST, Pesticide Study, Federal Trust, Other:
r
rJELD ANALYSES Owner "/V / /-/Jill C: o�oy,E',rl ?o.`� C�r-cA2 i OBE
�.11400 Spec. Cond.94 at 250 C Location or site
Temp.10 oC Odor _ Description of sampling point W5 L L- A/ 5A D
Appearance Sampling Method 13A/ /_ c='Q Sample Interval .2 D - -2.5
Pump, ba ler etc.) i
Field Analysis By: _ Remarks S" %A ? I C. ► V14 T use L � ✓ZE L = / S . U
I ARnRATnRY ANALYSES X MCTA L S /-/4✓G- �/�E� r/�G!O/FicO 41,/z) F/L % ENCO Z 1-Y 1YR6
BOD 310 m I
Diss. Solids 70300 m /I
A Silver 46566 u I
COD High 340 mg/I
Flouride 951 <'D . / mcyl
Al - Aluminum 46557 u I
COD Low 335 mg/I
Hardness: Total 900 mcVl.
*DiS
As - Arsenic 46551 L /U u I
Coliiorm: MF Fecal 31616 A 00m]
Hardness non-carb 902 mcyl
'*D� 5
Ba - Barium 46558 O u 1
Coliiorm: MF Total 31504 A 00m1
Phenols 32730 u I
Ca - Calcium 46552 m /I
TOC 680 mg/1
S ecific Cond. 95 uMhos/cmz
Cd - Cadmium 46559 u I
Turbidity 76 NTU
Sulfate 945 m I
"1015
Cr - Chromium 46560 `5' u I
Residue., Suspended 530 mg/I
Sulfide 745 m I
Cu - Copper 46562 u I
Fe - Iron 46563 u I
Hg - Mercury 71900 u I
pH 403 unit
K - Potassium 46555 m I
Alkalinity to pH 4.5 410 mg/1
M - Magnesium 46554 m I
Alkalinity to pH 8.3 415 mg/1
Mn - Manganese 46565 u /I
Carbonate 445 mg/1
NH as N 610 m I
Na - Sodium 46556 m I
Bicarbonate 440 m /l
TKN as N 625 mg1l
Ni - Nickel u /I
Carbon dioxide 405 m /I
NO + NO as N 630 m I
S
Pb - Lead 46564 J u /I
Chloride 940 mg/1
P: Total as P 665 m I
Se - Selenium u I
Chromium: Hex 1032 u I
Zn - Zinc 46567 u I
Color: True 80 Pt -Co
Cyanide 720 mg/I
Lab Comments:
Organochlorine Pesticides
Organophosphorus Pesticides
Nitrogen Pesticides
Acid Herbicides
Semivolatile Organics
Volatile Organics (VOA bottle)
TPH - Gasoline Range
TPH - BTEX Gasoline
e
GW-54 REV. 6/93 For Dissolved Analysis - submit filtered sample and write "DIS" in block.

Please use ink pen and press firmly.
Facility Name Z)N-,M rAl C' 0!; P0), 4r-r6Af
Address PO. BOX -588
cl'P/?Vc,r PrAld ADC -23177' County 91relf U
Well Location /?171?ell P?W 4/',gIIPU419
Well Identification Number RI✓# 2 -rBAt 2. Well Depth .2- Ft.
Well Diameter �� Sample (Screened) Interval D Ft To Ft.
Depth to Water Level 7 ft. below measuring point (before
Measuring point is / ® ft. above land surface
illons of water pumped/bailed before sampling S7 .2�r
...;Id Analysis: pH r 9 Specific Conductance 2� uMhos Temp. Ir ° C
Date Sample Collected 0-7- 08- (/V Date Lab Sample Analyzed 03- 08- IN
Laboratory Name AOc'f, 1NCOf Pek'/arc®
sampling)
PERMIT NUMBER: (REQUIRED)
Non-Dischar�gI.e
NPDES Ne 00001- r
TYPE OF DISPOSAL OPERATION BEING MONITORED
(REQUIRED)
Lagoon Septic Tank/Drain Field
Spray Field Subsurface Low -Pressure
Piping (LPP)
Land Application of Sludge
Rotary Distributor
Odor Appearance
Certification No.
Other
r.,�
COD
mg/I
Nitrite (NO 2) as N
mg/I
Ni -Nickel
s�ns
=_q>Ig/I
Coliform: MF Fecal
A 00ml
Nitrate (NO 3) as N
mg/I
Pb - Lead L
g/I
Coliform: MF Total
A00ml
Phosphorus: Total as P
mg/I
Zn - Zinc
(Note: Use MPN method for highly turbid samples)
AI - Aluminum
mg/I
Pesticides/Herbicides:
c.a
Dissolved Solids: Total ��
m /I
g
Ba -Barium 4 ®• /o
mg/I
(Specify Compounds)
pH (when analyzed) - 3
units
Ca - Calcium
mg/I
=
5>ag/I
TOC
mg/I
Cd - Cadmium
mg/I
Chloride
m /I
g
Chromium: Total C O ©2
mg/I
Arsenic
mg/I
Cu - Copper 4 0• 0/
mg/I
Other (Specify Compound and
crease and Oils
mg/I
iardness: Total
mg/I
Phenol
mg/I
Sulfate
mg/I
Specific Conductance
uMhos
Total Ammonia
mg/I
TKN as N
mg/I
Fe - Iron
mg/I
Hg - Mercury
mg/I
K - Potassium
mg/I
Mg - Magnesium
mg/I
Mn - Manganese
mg/I
Na - Sodium
mg/I
Concentration units)
I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE. Note: Values should reflect dissolved and
colloidal concentrations. (see #2 on back)
See back for instructions.
Signature of ; ermit ee (or Authorized Agent*) Date " submit blue, green, and yellow copies orgy to address above.
GW-59 REV. 9/92

- - __ �, I- - �7_�
COLLECTION AND ANALYSIS OF GROUNDWATER SAMPLES
1. Samples should be analyzed as soon as possible after collection. SAMPLES WHICH ARE NOT ANALYSED WITHIN THE HOLDIIff'
TIME SPECIFIED FOR THE METHOD USED (SEE #3. BELOW) MUST BE DISCARDED AND NEW SAMPLES COLLECTED.
2. ANALYSES ARE TO BE MADE OF THE MOBILE CONSTITUENTS (DISSOLVED AS WELL AS COLLOIDAL) IN THE
GROUNDWATER, NOT THOSE THAT ARE, A PART OF SEDIMENT. CHECK WITH YOUR LABORATORY ONPROPER
PROCEDURES FOR SAMPLE COLLECTION AND PRESERVATION.
3. As per Title 15, North Carolina Administrative Code, Subchapter 2L, analytical procedures shall be in accordance with the methods
described in one of the following publications, or by other methods approved beforehand by the Director, Division of Environmental
Management:
(a) Standard Methods for the Examination of Water and Wastewater, 16th Edition, 1985 and .17th Edition,-1989, published
jointly by American Public Health Association, American Water Works Association and Water -Pollution Control Federation;
(b) Methods for Chemical Analysis of Water and Waste, 1979, U.S. Environmental Protection Ag6ncy 'publication number
EPA-600/4-79-020, as revised March 1983;
(c) Test Methods for Evaluating Solid Wastes: Physical/Chemical Methods, 3rd Edition, 1986, U.S. Environmental
Protection_' Agency publication number SW-846;
(d) Test Pro 6edures for the Analysis of Polluants Under the Clean Water Act, Federal Register Vol. 49, No. 209, 40 CFR
Part 136, October 26, 1984;
4. Measure and record the depth of water in the well prior to pumping or bailing any water from the well.
5. At least 3. volumes of water in the well should be pumped or bailed prior to collecting a sample for analysis. If the well is pumped/bailed dry
before 3 well volumes are removed, samples can be collected as'sa6n as the well recovers to the point where enough water is- available to
collect your sample.
6. Determination for pH, Specific Conductance, temperature, odor and appearance must be made in the field on unfiltered samples when the
sample is collected.
7. Field equipment must be calibrated in accordance with recommendations by the manufacturer.
8. Samples must be filtered through a 0.45 micron filter immediately after collection when a dissolved analysis is required. (See #3. above)
9. The sample container should be labeled at the time of collection with the facility name, well identification number and date and time col-
lected.
10."Authorized agent" is any corporate officer or public official authorized by the company, corporation, or governmental body to sign official
documents.

Please use ink pen and press firmly.
Facility Name Unimin Corporation
Address P. 0. Box 588
Spruce Pine, NC 28777 County
Well Location Nov. MW Sampling _
Well Identification Number rMW # 2 18t2 Well Depth Ft.
Well Diameter �' Sample (Screened) Interval -2O Ft To --52' Ft.
PERMIT NUMBER: (REQUIRED)
NPDES /, C,
TYPE OF DISPOSAL OPERAMON
(REQUIRED)
Lagoon
Depth to Water Level 45 .s ft. below measuring point (before sampling)
Measuring point is ✓ 0 ft. above land surface
dons of water pumpedlbailed before sampling 65
d Analysis: pH 4.8 Specific Conductance 29 uMhos Temp. 13 °C Odor
Date Sample Collected 11109193 Date Lab Sample Analyzed 11 / 09/ 93
Laboratory Name PACE, Incorporated Certification No.
7 1994
Subsurface Low -Pressure
Piping (LPP)
Land Application of Sludge
Other
Rotary Distributor
Appearance
40
Spray FWd
r-3
COD
mg/I
Nitrite (NO 2) as N
mg/I
Ni - Nickel'riig°/I
Coliform: MF Fecal
/100m1
Nitrate (NO 3) as N
mg/I
Pb - Lead L 0.1
Coliform: MF Total
A 00ml
Phosphorus: Total as P
mg/I
Zn - Zinc
(Note: Use MPN method for highly turbid samples)
AI - Aluminum
mg/I
Pesticides/Herbicides
-- '-'
Dissolved Solids: Total 76
mg/I
Ba - Barium L 0.10
mg/I
(Specify Compounds)
pH (when analyzed)
4.8 units
TOC
mg/I
Chloride
mg/I
Arsenic o 002
mg/I
Grease and Oils
mg/I
irdness: Total
mg/I
rrfenol
mg/I
Sulfate
mg/I
Specific Conductance
29 uMhos
Total Ammonia
mg/I
TKN as N
mg/I
Ca - Calcium
mg/I
Cd - Cadmium
mg/I
Chromium: Total
L 0.02 mg/I
Cu - Copper
L 0.01 mg/l
Fe - Iron
mg/I
Hg - Mercury
mg/I
K - Potassium
mg/I
Mg - Magnesium
mg/I
Mn - Manganese
mg/I
Na - Sodium
mg/I
Other (Specify Compounds and
Concentration units)
-Ug%I
'u,g/I
sUg/I
I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE. Note: Values should reflect dissolved and
colloidal concentrations. (see #2 on back)
A/V/©© � -See back for instructions.
Signatu of Permittee (or Authorized Agent*) Date '" Submit blue, green, and yell copies only to address above.
GW-59 REV. 9/92

COLLECLTION AND ANALYSIS OF GROUNDWATER SAMPLES
1. Samples should'beana6to,as soon as possible after collection. SAMPLES WHICH ARE NOT ANALYSED WITHIN THE HOLDING
TIME SPECIFIED F,9P THE.METHOD USED (SEE a BELOW) MUST BE DISCARDED,AND NEW SAMPLES COLLECTED.
2. ANALYSES -ARE TO BE MADE OFTHt MOBILE CONSTITUENTS (DISSOLVED - AS WELL AS COLLOIDAL) IN THE
GROUNDWATER, NOT THOSE THAT ARE A PART OF SEDIMENT.CHICK WITH YOUR'LABORATORY ON PROPER
PROCEDURES FOR SAMPLE COLLECTION AND PRESERVATION. P
3. As per Title 15, North Carolina Administrative Code, Subchapter 2L, analytical procedures shall be in accordance with the methods
described in one of the following publications, or by other methods approved beforehand by the Director, Division of Environmental
Management: -
(a) Standard Methods for the Examination of Water and Wastewater, 16th Edition, 1985 and 17th Edition, 1989, published
jointly by American Public Health Association, American Water Works Association and Water Pollution ontro e er ion;
(b) Methods for Chemi&al Analysis of Water and Waste, 1979, U.S. Environmental Protection Agency publication number
EPA-600/4-79-020, as revised March 1983;
(c) Test Methods for Evaluating Solid Wastes: Physical/Chemical Methods, 3rd Edition, 1986, U.S. Environmental
Protection Agency publication number SW-846;
(d) Test Procedures for the Analysis of Polluants Under the Clean Water Act, Federal Register Vol. 49, No. .209, 40 CFR
Part 136, October 26, 1984;
4. Measure and record the depth of water in the well prior to pumping or bailing any water from the well.
5. At least 3 volumes of water in the well should be pumped or bailed prior to collecting a sample for analysis. If the well is pumped/bailed dry
before 3 well volumes are removed, samples can be collected as soon as the well recovers to the point where enough water is available to
collect your sample.
6. Determination for pH, Specific Conductance, temperature, odor and appearance must be made in the field on unfiltered samples when the
sample is collected.
7. Field equipment must be calibrated in accordance with recommendations by the manufacturer.
8. Samples must be filtered through a 0.45 micron filter immediately after collection when a dissolved analysis is required. (See #3. above)
9. The sample container should be labeled at the time of collection with the facility name, well identification number and date and time col-
lected.
1 O."Authorized . agent" is any corporate officer or public official authorized by the company, corporation, or governmental body to sign official
documents.

A-C P,
Facility Name Unimin Corporation
Address P. 0. Box 588 `
Spruce Pine, NC 28777 County key
Well Location MW, Triannual
Well Identification Number MW#2 181t2 Well Depth 2S+ Ft.
Well Diameter '2'" Sample (Screened) Interval-212_ Ft. To —'S— Ft.
Depth to Water Level 14.0 ft. below measuring point (before sampling)
Measuring point is / • Q_ ft. above land surface
allons of water, pumped/bailed before sampling. � y�v
PERMIT NUMBER: (REQUIRED)
Non -Discharge .
NPDES
TYPE OF DISPOSAL OPERATION
(REQUIRED)
agoon
AUG 2 7 1993
Spray Field Subsurface Low -Pressure
Piping (LPP)
Land Application of Sludge
Other
Held Analysis: pH 5.6
Date Sample Collected 7
Laboratory Name
Specific
/ 13/ 93
PACE,
Conductance 35 uMhos Temp. 13.4 ° C
Date Lab Sample Analyzed 7 / 13 / 93
Incorporated
Odor lddWcs,ppearance
Certification No. 40
COD
mg/I
Nitrite (NO 2) as N
mg/I
Ni - Nickel
mg/I
Coliform: MF Fecal
/100ml
Nitrate (NO 3) as N
mg/I
Pb - Lead L 0.05
mg/I
Coliform: MF Total
/100ml
Phosphorus: Total as P
mg/I
Zn - Zinc
mg/I
(Note: Use MPN method for highly
turbid samples)
All - Aluminum
mg/I
Pesticides/Herbicides
Dissolved Solids: Total
28
mg/I
Ba - Barium L-0 -10
mg/I
(Specify Compounds) .
pH (when analyzed)
5.6
units
Ca - Calcium
mg/I
ug/I
TOC
mg/I
Cd - Cadmium
mg/I
ug/I
Chloride
mg/I
Chromium: Total L 0.02
mg/I
ug/I
Arsenic L 0.001
mg/I
Cu - Copper T. 0-01
mg/I
Other (Specify Compounds and
rease and Oils
mg/I
Fe - Iron
mg/I
Concentration units)
r,ardness: Total
mg/I
Hg - Mercury
mg/I
Phenol
mg/I
K - Potassium
mg/I
Sulfate
mg/I
Mg - Magnesium
mg/I
Specific Conductance
uMhos
Mn - Manganese
mg/I
-- NIZ
� !
Total Ammonia
mg/I
Na - Sodium
mg/I
�►:� gas
TKN as N
mg/I
L4\a,l4FYy111Lrx Jdj11101%
I CERTIFY THAT S
��
REPORT
IS TRUE AND
ACCURATE.
Note:
Values should reflect di9�fv `la*
_
colloidal � concentrations. (see #2 on back)
JSee back for instructions.
Signature of P rmittee (or Authonzed -Agent*) Date ** Submit blue, green, and yellow copies only to address above.
GW-59 REV. 4/91

..COLLECTION AN® ANALYSIS OF Ot Dlnl TER SAMPLES -- i
1. Sam'pjes should lie nalyzed as soon' as possible after collection. S PLES WHICH ARE NOT ANALYSED HIN._THE HOLDING
TIME SPECIFIED F "ffii-iE i D - USED (SEE, ... BELOW) MUST YE DISCARDED.AND _ NEW SAMPLES . DLLE _ ECG
41 "inITS 00A
2. ANALYSES ARE ,T'O" ESE MADE OF THE MOB LE N UENTS--.(DIS s LVED-- AS . WELL AS- COLLOIDAL)IN E
i UNC} ATER- -,NOT-`fH(7SE THA°i ''ARE A PART, ,OF SEDIMENt. CHECK H YOU_R LABORATORY- -PROPER
PROCEDURES _ F®R_IAMPLE GOLLEGTION ,AND, -PRES VATION.
3. -As.- per Title 15, North Carolina Administrative Code, Subchapter 2L, analytical. Mc e,dures shall be ,in :accordance with- the methods
described'in in one of . the . following publications, or by other :methods approved,_ befmrehand -'by the Director, Division of Environmental
Management: -
r
(a) Standard Methods for -the Examination of Water and Wastewater, • 16th - Edition, 1985 and 17th - Edition, 1.989; ; publishec,
jointly by American" Public Hedth `Association, American Water Works Association•' and -Water- Pollution Control � -Federation;
(b) Methods for Chemical Analysis of Water and Waste, 1919, U.'S: ' Environmental Protection Agency publication number' `
EPA-600/4-79-020, as revised March 1983;
(c) _ Test:_ Methods for Evaluating Solid Wastes: Physical/Chemical Methods, 3rd Edifiion,.-1.986, U.S.. Environmental -_-
Protection Agency . publication number SW-846,
(d) Test Praceelures for_'the Analysis of Polluants Under"the ,Clean WatEif Act, Federal Register Vol. 49, No. 209, 40-CFR-`;`
Part 136, October ' 26, .1984;
4. Measure and record the,deptli ' water in the ;well prior to pumping or bailing any.�rirater,from the well. ;
5:_ At least 3 volumes of water in the well should be pumped or bailed prior to. -collecting a- sample, for analysis. If the well is pumped/bailed dry--
before 3 well volumes are removed,_ samples can be collected as soon as :the well recovers to the point_ where enough water is available;to
collect your sample.
A6. Determination for -pH, Specific Conductance, temperature, odor and appearan&'rftust-be °made..in the field on unfiltered samples When the
sample - -is 'Collected.,
7. Field equipment- must -be calibrated- in accordance with rth4, manufacturer.'..
8: samples -must be filtered through a 0.45 micron filter immediately after collection. when .a _dissolved analysis is required. (See -#3. above)_-
.., , :- , - -. ,,,. ,,,. - . '- •- ---, •_ _ :, .- :: ,,.-_ - _ �;'
9. The sample-'Icontainet 'should- e- abeled, gat, thbLtiri e of collection with the facility name, well-identification"number' and -date and time .col- `
lected
10.'Authorized a ent",-.is an cor orate, officer."or ubl'ic official authorized_ b the com `arty ,\° cbr , oration or 6Vditnentai-lbo tci _sin official-
g Y P p _
Y p �` p _
- _ - _ - -

North Carolina
GROUNDWATER FIELD/LAB FORM Department of Environment, Health, and Natural Resources
DIVISION OF ENVIRONMENTAL MANAGEMENT GROUNDWATER SECTION
County Lab Number 8
Quad No Serial No. SAMPLE PRIORITY Date Received Time
Lat. Rec'd by: From Bus -Courier
Long. ROUTINE [—]EMERGENCY Other
D A,
Report To:,Akd, FRO, MRO, RRO, WaRO, WiRO, 0 Date Entry By: ' Ck.
,WSRO, Kinston FO, Other Date Reported: 6Z
Shipped by Bus, Courier, Other _! J L
Purpose: Baseline, Complaint,Compliance;.
Collector(s): rY Date E-ZL Time LUST, Other
(cir)
FIELD' ANALYSES Aj,;
pH 400 —,9pec. Cond. 94 — at 250 C
Temp.10 oc Odor
Appearance Taste
Field Analysis By:
Lab Comments:
Location or site
Description of sampling point
Sampling Method =
(Pump, bailer, eta) Sample Interval
Remarks
(pumping time, air temp. etc.)
GW-54 REV. 3/92 For Dissolved Analysis - submit filtered sample and write "D IS" in block
White Copy - Groundwater Central Office Yellow Copy - Regional Office Pink Copy - Central Files Goldenrod Copy - Lab

North Carolina
Department of Environment, Health, and Natural Resources
GROUNDWATER FIELD/LAB FORM
DIVISION OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER SECTION
County M/ ?C He4z- Lab Number 8
Quad No 8 f tom. Serial No. /" ► Z / 3640 SAMPLE PRIORITY Date Received Time -
Lat. 3 S SG / Y- Long. 82 O 5 58 �OUTINE EMERGENCY M,N- Rec'd by: From: Bu -our er
LLJJ�� �� Other
Report To:0 FRO; MRO, RRO, WaRO, WiRO,
Date Entry By:
WSRO, Kinston FO, Other Date Reported:
Shipped by: Bus, (�Zp Other
/vjiNNiCK
Collector(s): RuMaau GN Date Time /0: y5-14M Purpose: Baseline, Complaint,�plia LUST, Other
—1ELD ANALYSES Owner !.(N/Mid CyRPOR/IT/onJ tc��&"AAT:x 010E0qA'7"101Vs
�H 400
Spec. Cond. 94 at 25' C
Temp.10
oC Odor
Appearance
Taste
Field Analysis By:
I ARnRATnRV
ANIAI VCFC
Location or site
Description of sampling, point v/,6 t/E ff 4
Sampling Method /6A J I-« Sample Interval o °z 5
bailer V etc �-
Remarks S'TA ?/ C WA ER(Pump L e L.
*M E TA L f'FI ~Z- C 5 IM V4- /3E(�M g � l c�/ �E'O A evo F/LTC / e,0 %��'
GW-54 REV. 3/92 For Dissolved Analysis - submit filtered sample and write "DIS" in block
White Copy - Groundwater Central Office Yellow Copy - Regional Office Pink Copy - Central Files Goldenrod Copy - Lab
rl ,

Facility Name Lkdnin Corporation
Address P. 0. Box 588
Spruce Pine, NC 28777 County
Well Location
Wep is
PERMIT NUMBER: (REQUIRED)
Non -Discharge
NPDES • b [7 b b r•
TYPE OF DISPOSAL OPERATION BEING MONITORED
(REQUIRED)
Well Identification Number ITT #2 L Z$ I — ,dam Well Depth oS J Ft.
Well Diameter e9 "` Sample (Screened) Interval .20 Ft. To :;Z,'5- Ft.
Depth to Water Level 14.0 ft. below measuring point (before sampling)
Measuring point is /• b ft. above land surface// f
allons of water pumped/bailed before sampling k2 •-s
meld Analysis: pH 5.5 Specific Conductance uMhos Temp. 12 °C Odor
Date Sample Collected 3/9/93 Date Lab Sample Analyzed 319/93
Laboratory Name PACE, Incorporat.ad Certification No:
COD mg/I
Coliform: MF Fecal /100ml
Coliform: MF Total A 00ml
(Note: Use MOPN method for highly turbid sam s)
Dissolved Solids: Total 26 (2r
mg/I
pH (when analyzed) 5.5
units
TOC
mg/I
Chloride
mg/I
Arsenic L 0.001
mg/I
cease and Oils
mg/I
,ardness: Total
mg/I
Phenol
mg/I
Sulfate
mg/I
Specific Conductance
uMhos
Total Ammonia
mg/I
TKN as N
mg/I
Lagoon Septic TanWDrain Feld
Spray Field Subsurface Low -Pressure
Piping (LPP)
Land Application of Sludge
Appearance
Nitrite (NO 2) as N
mg/I
Nitrate (NO 3) as N
mg/I
Phosphorus: Total as P
mg/I
Al - Aluminum
mg/I
Ba - Barium L 0.10
mg/I
Ca - Calcium
mg/I
Cd - Cadmium
mg/I
Chromium: Total L 0-102
mg/I
Cu - Copper L 0.01
mg/I
Fe - Iron
mg/I
Hg - Mercury
mg/I
K - Potassium
mg/I
Mg - Magnesium
mg/I
Mn - Manganese
mg/I
Na - Sodium
mg/I
(2) Sample analyzed one day out of hold time due to
I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE.
Signature of Permittee (or Authorized Agent*) Date
GW-59 REV. 4/91
APR 2 21993
Ni - Nickel �gyl
Pb - Lead T. 0-1 mg/I
Zn - Zinc mg/I
Pesticides/Herbicides
(Specify Compounds)
ug/I
ug/I
ug/I
Other (Specify Compounds and.
Concentration units) �.
1
Note: Values should reflect dissolved and
colloidal concentrations. (see #2 on back)
* See back for instructions.
** Submit blue, green, and yellow copies only to address above.

COLLECTION AND, ANA I LYSIS OF GROUNDWATER SAMPLES
1, Samples should be analyzed as -anon as possible after collection. SAMPLESWHICH ARE NOT ANALYSED �HIRI, E. HOLDING
11ME SPECIFIED FOR THE- M E HOD USED (SEE 43. BELOW) -MUST 13E DISCARDED AND NEW SAMPLES COLLECTED.
2. ANALYSES ARE TO. BE MADE OF THE MOBILE CONSTITUENTS (DISSOLVED- AS WELL- AS COLLOIDAL) IN THE
GROUNDWATER, NOT` THOSE- `irHAT ARE_ A, �PA OF "SEDIMENT: CHECK : . H YOUR LABORATORY ON PROPER
PROCEDURES FOR SAMPLE COLLECTION- -AND PRESERVATION.
3.-As per Title -15, North - Carolina - Administrative Code, Subchapter 2L, analytical procedures shall ,in accordance with.the 'methods t
described in one of the following publications, or by other methods approved: beforehand ,.by . the Director, Division of Environmental
Management: -
(a) Standard Methods for the °Examination of Water and Wastewater, 16th Edition, :198& and17th - Edition;-1,989, publishes
jointly by American Public Health Association, American Water Works Association `and Water Pollution Control F4deration;'
o +) Methods for Chemical Anfysis of Water and Waste, 1979; U.S. Environmental- Protection Agency publication number'`
9 - .J "' A-60014-79-020, as revised March 1983; _
(c) Test Methods for -Evaluating Solid Wastes: ,Physicai/Chemicai Methods, 3rd Edition, 1.986,-_U.S. Environmental
Protection Agency publication number SW-846;
(d) Test Procedures for the Ahalysis of Polluants Under the Clean Water Act, 'Federal Register- Vol. 49, No. 209, 40 CFR -
r Part 136, October 26, 1984; _
4. Measure and record the .depth of water: in the -Well prior to pumping or bailing .any mater,,from the, well. -'
- -
5- . At least 3 volumes of water in the well should, be pumped or bailed prior to collecting a, sample , for analysis. If the well is pumped/bailed dry
before 3 well volumes are removed, samples ,can be collected as soon as,the well recoVers to',the, point where enough water- is _availablea'to�)
collect your sampler
6. Determination- for pH, Specific Conductance, temperature, odor and appearance' 'must bk madein the field on unfiltered samples when --the_,
sample is collected. --
7. Field equipment must W" calibrated in accordance with recommendations -by: , h'6..'.manufacturec, -,..
8. Samples mnust be- fiitered through a' 0.45 -micron filter immediately_ after colledon when . a dissolved: analysis is_: required. (See 43. above)
9. The s6 rEpia, 66"_htainer should -'be- labeled' at' the- time of collection with the facility name, *inreil idehtification `number -and date and- time'`c6k
10_"Authorized , agent" is any.r cc -,porat6 . ofJc'e_r,'or.;:public official authorized fly the;, company, corporation, -,:or gavemmerital'bo y -to sign official r.
documents. _ ::.

Facility Name Unirnin Corporation PERMIT NUMBER: (REQUIRED)Non-Discharge
Address P. 0. Box 588 NPDES 10 420 Z
Spruce Pine, NC County M; tr•ha1 TYPE OF DISPOSAL OP RATION BEING MONITORED
Well Location Monitoring Well (REQUIRED)'
Lagoon Septic TanWDrain Feld
Well Identification Number MW /p2 r V /— Well Depth ZS Ft.
Well Diameter &2 " Sample (Screened) Interval a Ft. To 7-3-Ft.
Depth to Water Level 14.0 ft. below measuring point (before sampling)
Measuring point is / .y ft. above land surface
allons of water pumped/bailed before sampling
Field Analysis: pH 5.6 Specific Conductance 28 uMhos Temp. 13 °C Odor
Date Sample Collected 11 19 / 92 Date Lab Sample Analyzed 11 / 19 / 92
Laboratory Name_ PACE, Incorporated Certification
COD mg/I
Coliform: MF Fecal A 00ml
Coliform: MF Total A 00ml
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total 62
mg/I
pH (when analyzed) 5.6
units
TOC
mg/1
Chloride
mg/I
Arsenic L o o01
mg/I
rease and Oils
mg/1
"ardness: Total
mg/1
Phenol
mg/I
Sulfate
mg/1
Specific Conductance 28
uMhos
Total Ammonia
mg/1
TKN as N
mg/I
Spray Field Subsurface Low -Pressure
Piping (LPP)
Land Application of Sludge
Appearance
QrC 31 1992
No. 4.0 f L I!
Nitrite (NO 2) as N
mg/I
Nitrate (NO 3) as N
mg/I
Phosphorus: Total as P
mg/I
Al - Aluminum
mg/I
Ba - Barium L o .1 o
mg/I
Ca - Calcium
mg/I
Cd - Cadmium
mg/I
Chromium: Total L 0.02
mg/I
Cu - Copper L 0 - 01
mg/I
Fe - Iron
mg/I
Hg - - Mercury
mg/I
K - Potassium
mg/I
Mg, - Magnesium
mg/I
Mn - Manganese
mg/I
Na - Sodium
mg/I
I CERTIFY THAT T IS REPO IS TRUE AND ACCURATE.
Signature of Wrmittee (or Authorized Agent*) Date
GW-59 REV. 4/91
Ni - Nickel mg/I
Pb - Lead L o 05 mg/I
Zn - Zinc mg/I
Pesticides/Herbicides
(Specify Compounds)
Other (Specify Com' 4 r'OIS4,
ffxw%jj�09-C �k�992
Concentration ul�i'� `
GRO'lNDVATl"R SUCTION
Note: Values should reflect dissolved and
ug/I
ug/I
ug/I
colloidal concentrations. (see #2 on back)
* See back for instructions.
** Submit blue, green, and yellow copies only to address above.

COLLECTION AND , OF GROUNDWATER
1. Samples should be analyzOd"4 as soon as possible after collection. SAMPLES WHICH ARE NOT ANALYSED WITHIN THE HOLDING
TIME SPECIFIED FOR THE I METHOD USED E # :; COLLECTED.
;- a
2. ANALYSES ARETO BE MADE. -.OF THE1*40BILE CONSTITUENTS (DISSOLVED AS WELL AS.COLLOWAL) IN THE
GROUNDWATER, N H NT. CHEC H YOUR LABORATORY ON PROPER
PROCEDURES FOR SAMPLE COLLE"ON-AND t •. z i
3. As per Title 15, North Carolina Administrative Code, Subchapter 2L, anato-Qal procedures 'shall be, in accordance with the methods
described in one of the following publications, or by other methods approved beforehand by,the Director, Division of Environmental-
rf^
(a) Standard Meth6ds for the Examination'of Water and Wastewater, "16th- Edition, '1985 and 17th'Edftion, 1989, publishk
jointly by American- Public Heafth Association, American Water Works Association and Water Pollution Control Federation',
(b) Methods for Chemical Anal is of Water and -Waste, 1979; Environm6ntal Protection Agency publication number
EPA-600/4-79-020, as revised 'March '1983;
Methods --.for f •Wastes: Physical/Chemical • • • • •••U.S. Environmental
Protection Agency publication ' ins
(d) Test -Procedures for the Analysis of Polluants Under the Cleari.Water Act, Federal Register Vol. 49, No. 209i - 40 CFR
4. Measure and recordthedepthof prior topumping or bailing any waterfrom
5. `At least 3 volumes of water in the well should be pumped or bailed prior to collecting a,sample for analysis. -if the - well_is pumped/bailed.dry.
before 3 well volumes are._ removed, samples can be. collected as soon as, the well recovers to the point where enough water -is available to-,
collect.. your sample.,
6. Determination for . pH, Specific •Conductance, temperature, odor and appearance must be made in the field on unfiltered samples when the
sample is 'collected.
7. Field equipmpp,I most be calibrated in accordance with recommendations by, the,.manufacturer.r
6. Samples must be _filtered through -a _ 0.45 micron filter i-Mmediately after collection when a. -dissolved- _analysis is required. .(See #3. above)
9. The sample 'container `should 'be labeled at the time of collection with the facility nami=,' w6ll identification number and date and time' col
lected.
.may-'` .:, ..
10."Authorized- agant" is any. corporate ,officer,, or public official .authorized by the company, corporation, or, yoverrimental body Cosign official_
documents.-

GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Division of Environmental Management
Groundwater Section
P.O. Box 27687
Raleigh, NC 27611-7687
�' �Fto� additional forms please write or call: [phone]
. n
Facility Name Unimin Corporation
���!
County �C
t��n�l� I
i+
Address P. Q. Box
588 (i
PERMIT NUMBER: (REQUIRED)
d
Spruce Pine NC 287771
Non -Discharge
Well Location Monitoring;
..."U'Vatra OtAwUll
Wells AsheEille Re tonal tSffice I
_
NPDES� ODG�I %S
Well Identification Number
MW #2 1 21 k -"—Well Depth a-S-- Ft.
TYPE OF DISPOSAL OPERATION BEING MONITORED
�y z--2-Ft.
(REQ411RED)
Well Diameter
Sample (Screened) -Interval Ft. To
_1�Lagoon _ Septic Tank/Drain Field
Depth to Water Level 12.0
ft. below measuring point. (before sampling)
— Spray Field — subsurface Low -Pressure
MeasuringPiping
point is 1.01 feet
above land surface
(LPP)
Land Application of sludge
Gallons of water pumped/bailed before sampling 6.5
Rotary Distributor Other
Field Analysis: pH 5.7
Specific Conductance 25 uMhos Temp. 13° C Odor Appearance
Date Sample Collected
7/7/92 Date Lab Sample Analyzed
7/7/92
Laboratory Name PACE, Incorporated Certification
No. 40
COD
mg/I NO2 as N
mg/I Ni - Nickel mg/I
Coliform: MF Fecal
/100ml NO3 as N.
mg/I Pb -Lead L 0.05 mg/1
Coliform: MF Total
/100ml Phosphorus: Total as P
mg/I Zn - Zinc mg/I
Dissolved Solids: Total 39
mg/I Al - Aluminum
mg/I Pesticides/Herbicides (Specify Compourrds)
pH (when analyzed) 5.7 units
TOC mg/I
Chloride
Arsenic L 0.001
Grease and Oils
Hardness: Total
Phenol
mg/I
mg/I
mg/I
mg/I
mg/I
Sulfate mg/I
Specific Conductance 25—_uMhos
Ba - Barium L 0.10
mg/I
'U'g/I
Ca - Calcium
mg/I
a ! ;''t�If;i ','1 t r
u"/I
Cd - Cadmium
mg/I
ug/i
Chromium: Total L 0.02
mg/I
Other (Specf+kY
ug/l
Cu- Copper 0 016
mg/I
-,� �Ci`T11
ug/I
Fe - Iron
mg/I
ug/I
a °-
Hg - Mercury-
mg/I
K - Potassium
mg/I
ug/I
Mg - Magnesium
mg/I
.ug/I
Total Ammonia(NH3 1- NH 4) mg/I Mn - Manganese mg/I
TKN as N mg/I Na - Sodium mg/I
ERTIFY AT THIS REPORT IS TRUE AND ACCURATE.
SIGNATURE dF PERMITTEE (OR AUTHORIZED AGENT*) DATE
NOTE, --
Values Values should reflect dissolved concentrations
(See #2. on reverse)
* See back for instructions.
** Submit blue, green, and yellow copies only to address above.
(,1A1_r,O DPW 010n

I
alzed as aiaVma s pi Ma shan
rim: SPECIREDVOR THE V3, SELJOV,�-�� N�7-117 Ur- 0 MCARDI!r) MM'C, N!EVV SA'r0!7�LE:,S t�(RLEWTEED�
1- I I Sm
ARE, TO UE MADE CIF VIS TION&MUE-US DIFSOOIN . 01 N'THE GROUNDVIATS! NCQTHQSE,T3IAT ARE A PART
JkLn;SC-;RBED ONTO, S(3H-ISHCjMFN-V PAMOLL3L 1)4�,VFPI YOUR ON P'NOPER Pt-nC-X-;!7-i,:)URE25 !FOtH
As per Tie 1 -6, C.75T`)�,na k1m;iii,�,!tmWev Cade, SubMapar 21, �3,-,a.'VVga; qroczdures Wl be m accordance Tvith the methads
dose„ bed in one of N-following pubMalons, or 1q, ot'he- Ppproved i�eforennnd by thd [Direi-tor, D�vjsjor� of EriviccnmPritai
Management:
'a S.'�.-.ndard methodfor the Exarr!inotion `.,,f IN-ater and Wastevvater, VVY Ediborri, 1985, published jointly by American
FILM Hea3h Assodabon, Arns-ican Slater %sows Asmo,ociat�on ar.d VVa'
ter Pofluiion Contro! Federation;
M e for Clent cai An aiys!,�� of Water aod, Vjas;,,e-, 1, 979, 1 U. S, En vj r.unmental PrMection Qg e my pu U i cation n umber
600/4-79-020, as revis:.c, ;�rch 1983i
(c) 11 ce s,
P-.,-o-:ecctton Agericy p,"bkat'�cin rui-,!�iar S*1-845:
(d) US Flocedures tar the Walks of Pekamis Undcr the Uzari `,Wxer Act, Raderad Register vol. 49, No. 2091, 40 Cfl�
4. Mepsurs Vnc de,,pth cf, vvaSOS- !�n 'ell to rnnpi,gPr 'oi!�nyemfl,lu.ag aaio* we�i.
5, PO i.3 -yolwres of wamr in the ;vNI s+,,ou!d 00 punped ew baded prior to --ollecing a sampie for analysis. it thewell is pumped/Icailed dry
re-r3vec,, be ;mhemea as is 1;�P, view 1000WS To the p�);nt whiere enuug is avai�able lo
�i wa
i, oi Corductancc,�, odor and appeamm- musI., be rn=id8 in the ,ield on urtfi!tered Samples vvimn mo,
c,,a'�bralos,.J �n acr�ordzarjcc: by Vw;
S�1`11"-I'ii�,S- rti!IMI be himmi through,� r,,415 Nuar, OT-Mmotlateo We" is �Sao 93, abovs-,)
ej t cIN PI 'deMn, -nNkm.� VWQW%. vNunnan,datp

GROUNDWATER FIELD/LAB FORM
County M I r C. P L "-
Quad No..Z- 8/ t a Serial No. M 1 / 3 6 6
Lat. 3 5 J'6 "I Long.9-1 PS 5 8
Report To: o FRO, MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO, Other
Shipped by: Bus, ourie ,Other
North Carolina
Department of Environment, Health, and Natural Resources
DIVISION OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER SECTION
Lab Number 8 -'
SAMPLE PRIORITY Date Re ce' ed _
Time �'
OUTINE EMERGENCY Rec'd b From: B -Courier
M 1N' i- Other
Date Entry By:
Date Reported: — 02 �—
Collector(s): Ru�Jf�►c7t1G/l Date A Time //: O!r A M Purpose: Baseline, Complaint LUST, LUST, Other
FIFI n ANAI YSFS Owner u./V/"lAd Cd� ®Rr�!'i �d LC.�1 -fZ OAC!rA TIONS
PH 400
Temp.10
Appearance
Field Analysis By:
LABORATORY
Spec. Cond. 94 at 250 C
oC Odor
Taste
ANALYSES
Location or site Do W N GRA 0/ 6AJ 7- O r L f1 G 4,0^4
Description of samplin pointyV e L l-
Sampling Method �AI G 4-R Sample Interval
Remarks
(Pump, bailor, etc.)
"
.S rA -l' / C WA A L ,, V E L, r (p � pi..7 %im ir1emp. etc.)
BODs 310 m n
Diss. Solids 70300 m /I
A - Silver 1077 u /I
COD High 340 mg/I
OIS
Flouride 951 m /I
Al - Aluminum 1105 u /I
COD Low 335 m /I
Hardness: Total 900 m /I
OiS
Ba - Barium 1007 4 10 u /I
Coliform: MF Fecal 31616 /100ml
Hardness non-carb 902 m /I
Ca - Calcium 916 m /I
Coliform: MF Total 31504 A 00m1
Phenols 32730 u /I
Cd - Cadmium 1027 u /I
TOC 680 m /I
Specific Cond. 95 uMhos/cm2
I)IS1
Chromium: Total 1034 .2; /I
Turbidity 76 NTU
Sulfate 945 m /I
Cu - Copper 1042 u /I
Sulfide 745 m /I
Fe - Iron 1045 u /I
H - Mercury 71900 u /I
pH 403 units
K - Potassium 937 mg/I
Alkalinity to pH 4.5 410 mg/I
Mg - Ma nesium 927 mg/I
Alkalinity to pH 8.3 415 mg/I
Mn - Manganese 1055 u /I
Carbonate 445 mg/I
Na - Sodium 929 m /I
Bicarbonate 440 mg/I
NH3 as N 610 m /I
Ni - Nickel 1067 u /I
_
D#S
Arsenic: Total 1002 u /I
TKN as N 625 m /I
D)S
Pb - Lead 1051 d u /I
Carbon dioxide 405 mg/I
NO + NO3 as N 630 m /I
Se - Selenium 1147 u /I
Chloride 940 mg/I
P: Total as P 665 m /I
Zri - Zinc 1092 u /I
Chromium: Hex 1032 u /I
Color: True 80 Pt -Co
Cyanide 720 mg/I
Lab Comments:
Or anochlorine Pesticides
Organophosphorus Pesticides
Nitrogen Pesticides
Acid Herbicides
Base/Neutral Extractable Organics
Acid Extractable Organics
Purgeable Organics (VOA bottle)
1,2 - Dibromoethane (EDB)
AI
. — Imo' a
Ashetnlle
GW-54 R'-' 3/92 For Dissolved Analysis - submit filtered sample and write "DIS" in b'
White Copy - Groundwater Central Office Yellow Copy - Reg,- I Office Pink Copy - Central Files
Goldenrod Copy - Lab

North Carolina
GROUNDWATER FIELD/LAB FORM Department of Environment, Health, and Natural Resources
DIVISION OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER SECTION
County
Quad No - Serial No.
Lat. = Long.
Report To ARO, FRO, MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO, Other -
Shipped by: Bus, Courier, Other, F
Collector(s): '- Date
-I'ELD ANALYSES
r'H 400 Spec. Cond. 94 at 25°
Temp.10 oC Odor
Appearance Taste
Field Analysis By:
Lab Comments:
SAMPLE PRIORITY
EROUTINEEMERGENCY
Lab Number 8
Date Received Time
0 Rec'd by --From. Bus -Courier
Other
Date Entry By: Ck
Date Reported':
Time Purpose: Baseline, Complaint .-Compliahce, LUST, Other
Owner -
Location or site
Description of sampling point L "
Sampling Method _ Sample Interval
Remarks (Pump, bailer, etc.) '
GW-54 REV. 3/92 For Dissolved Analysis - submit filtered sample and write "DIS" in block
White Copy - Groundwater Central Office Yellow Copy - Regional Office Pink Copy - Central Files Goldenrod Copy - Lab

GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Division of Environmental Management
Groundwater Section_
P.O. Box 27687
Raleigh, NC 27611-7687
For additional forms please write or call: [phone]
Facility Name Unimin Corporation
Address P. D. Bose 588
Spruce Pine. NC 28777
Well Location Monitoring Well
Well Identification Number MW #2 Well Depth Ft.
Well Diameter Sample (Screened) Interval Ft. To Ft.
County
PERMIT NUMBER: (REQUIRED)-,
Non -Discharge ,Ju
(REQUIRED
— Lagoon
MAY 2 7 1992
!'ING3'NI0.'NITO,RED
— Septic Tank/Drain Field
Depth to Water Level
ft. below measuring point. (before sampling)
— Spray Field
— subsurface Low -Pressure
(LPP)
MeasuringPiping
point is ,feet above land surface
Land Application of sludge
Other
Gallons of water pumped/bailed -before
sampling
— Rotary Distributor
Field Analysis: - pH'- " 5.6' .
Specific Conductance 30 uMhos Temp.
oC Odor
Appearance'
Date Sample Collected 3/16/92 Date Lab Sample Analyzed
3/16/92
Laboratory Name PACE, Incorporated Certification No. 40
COD
mg/l NO2 as N
mg/I Ni - Nickel
mg/I
Coliform: MF'Fecal
/100ml NO3 as N.
mg/I Pb -Lead
L 0.05 mg/l
Coliform: MF Total
/100ml Phosphorus: Total as P
mg/I Zn - Zinc
mg/I
Dissolved Solids: Total 28
mg/I Al - Aluminum
mg/I Pesticides/Herbicides. (Specify Compounds)
pH (when analyzed) 5.6
units Ba - Barium, L 0.10
mg/I
ug/I
TOC
mg/I -Ca - Calcium
mg/I
ug/I
Chloride
mg/I
Arsenic L 0.001
mg/I
Grease and Oils
mg/I
Hardness: Total
mg/I
Phenol
mg/I
Sulfate
mg/I
Specific Conductance 30
uMhos
Cd - Cadmium mg/I
Chromium: Total L 0.02 mg/I
Cu - Copper L 0.01 mg/I
Fe - Iron mg/I
Hg - Mercury
A
K - Potassium mg/I
Mg - Magnesium mg/I
Total Ammonia(NH3 + N 4) mg/I Mn - Manganese mg/I
TKN as N . mg/I Na - Sodium mg/I
I CERTI HAT S E RT IS TRUE AND ACCURAT .
SIGNATURE O PERmi EE (OR AUTHORIZED AGENT`) ATE
llw_rlq Rr-\/ :>/on
ug/I
Other (Specify) ug/I
_ ug/I
ug/I
a q ug/I
- - Sam
ug/I
GROUNDWATER SECTION ug/i
RALEIGH, NC
NOTE:.
Values should reflect dissolved concentrations
(See #2 on reverse)
* See back for Instructions.
** Submit blue, green, and yellow copies only to address above.

Ij kyll'alm agIAT, to gau
Esiffim
2. ANALYSES ARE TO BE MADE OF THE CONSITITUENTS DISSOLVED IN THE GROUNDWATER, NOT THOSE THAT ARE A PART
OF, OR ADSORBED ONTO, SOIL/SEDIMENT PARTICLES. CHECK WITH -YOUR LABORATORY ON PROPER PROCEDURES FOR
SAMPLE COLLECTION AND PRESERVATION.
3. As per Title 15, North Carolina Administrative Code, Subchapter 2L, analytical proc.edures.shall be in accordance with the methods,
described in one of the following. publications, or by other methods approved beforehand by the Director, Division of Environmental
Management:
(a) Standard- methods fortho Examination of Water and Wastewater, 16th Edition; 1985, -published-jointly by AmOrican'
Public Health Association, American Water Works Association -and Water Pollution Control- Fed6ration
(b) Methods for Chemical Analysis of Water -and Waste, 1979, U.S. Environmental Protection Agency publication number
EPA-600/4-79-020, as revised March 1983;
(c) T6st'Methods for s:hys"ical/6 P emical Method . s, 3rd Edition, 1986, U.S.En'vi'ron mental
Evaluating Solid Waste''
Protection Agency publication number SW-846;
(d) Test Procedures for the Analysis of Polluants Under the-Cleari WatdrAct, Federal Register Vol. 49, No. 209, 40. C­FR1'
Part 136, October- 26,1984;
4. Measu-re and record the depth of water in the well.prior to pumping or bailingany water from the well.
,
5.'Aleast 3 volumes of water in th-6 well'should be pumped or bailed prior to colleoting'a saMple'for analysis.- If the well is pumped/ballei'&dry
before 3 well volumes are removed, samples can be collected as soon as the Wdll recovers to the point where enough water is available to
,,collect your sample-
6. Determination fQr PH, Specific Conductance, temperature, odor and appearance -must be.made in the field on unfiltered samples when the
sample
7. s'Fjeld 4`6fpment m wst be callib'�ated -in-accordance, with recommendations by the manufactdrer:'
S. Samplp4���',#Itor!.Od-thr�'obgh a 0.45 micron filter immediately after collection when a dissolved analysis .is required, (See #3. above}
-
9. The sample container should -be labeled at the time of collection with the facility name, well identification number and date and time col-
lected.
1 0."Autho'rized'age'nt" is any corporate officer or public official authorized by -the company, corporation; or. governmental body to sign official
documents,

GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Division of Environmental Management
Groundwater Section
P.O. Box 27687
Raleigh, NC 27611-7687
For additional forms please write or call: [phone]
Facility Name
Unimin Corporation
County
PERMIT NUMBER: (REQUIRED)
Non -Discharge
p DFC 1 6 1991
IIU ' �� i —m
Address P. 0. Box 58B, 226 Bakersville Hwy.
Spruce Pine, NC 28777
Well Location
Monitoring Well
NPDES
Well Identification Number f�W #2 Well Depth Ft.
TYPE OF DISPOSAL OPERAITION &E'IN;G
(REQUIRED)
Well Diameter
Sample (Screened)'Interval Ft. To Ft.
_ Lagoon
— Septic Tank/Drain Field
Depth to Water Level
17.75 ft. below measuring point. (before sampling)
— Spray Field
— Subsurface Low -Pressure
Piping (LPP)
Measuringpoint is_
feet above land surface
Land Application of Sludge
Gallons of water pumped/bailed
before sampling
Other
— Rotary Distributor
Field Analysis: pH
5.6 Specific Conductance 19 uMhos Temp. 13
°C Odor Appearance
Date Sample Collected __
11/7/91 Date Lab Sample Analyzed
12/2/91
Laboratory Name
PACE, Incorporated ' Certification
No.
COD
mg/I NO2 as N
mg/I Ni - Nickel
mg/I
Coliform: MF'Fecal
/100ml NO3 as N.
mg/I Pb -Lead L 0.1
mg/l
Coliform: MF Total
/100ml Phosphorus: Total as P
mg/I Zn - Zinc
mg/I
Dissolved Solids: Total
57 mg/ -I Al - Aluminum
mg/I Pesticides/Herbicides. (Specify Compounds)
pH (when analyzed)
units Ba - Barium L 0.1:0
mg/I
-ug/I
TOC
mg/I Ca - Calcium
mg/I
ug/I
Chloride
mg/I Cd - Cadmium
mg/I
11n1l
Arsenic L 0.001
mg/I
Grease and Oils
mg/I
Hardness: Total
mg/I
Phenol
mg/I
Sulfate
mg/I
Specific Conductance
uMhos
Chromium: Total L 0.02 mg/I
Cu - Copper 0.015 mg/I
Fe - Iron
g/I
Hg - Mercury mg/I
K - Potassium mg/I
Mg - Magnesium mg/I
Total Ammonia(NH3 * NH 4) mg/I Mn - Manganese_
Zas mg/I Na - Sodium
REPORT IS TRUE AND ACCURATE.
SIONAPURE OF PER-MITTEE (OR AUTHORIZED AGft-NT*) DATE
mg/I
mg/I
Other (SpegjV) _. ug/.I
•-- ug/I
c , 9/1 .
i t1 'g/I
:. DEC 1 P
ug/I
Airinl#;1. 4At;1k��� C�f`.Ti4�t'�g/I
NOTE: PLALEIG14. I d
Values should riefleot dissolved concentrations
(See #2. on reverse)
See back for instructions.
"Submit blue, green, and yellow copies only to address above.
rw-r.q Rw gion

I I I I * , "
:q:ffYXN;J:qJ! WTI
2. ANALYq�,�S ARE TO BE MADE OF THE CON SITITUENTS DISSOLVED IN THE GROUNDWATER, NOTTHOSETHAT ARE A PART
- OF, OAIDSORBED ONTO, SOIL/SEDIMENT PARTICLES. CHECK WITH YOUR LABORATORY ON PROPER PROCEDURES FOR
SAMPLE COLLECTION AND PRESERVATION.
3. As per Title 15, North Carolina Administrative Code, Subchapter'2L, analytical procedures shall.be int accordance with the methods
described in one of the following publications, or by other methods approved beforehand by the, Director, Division of Environmental
Managemont.--.'
(a) Standard methods for the Examination of Water and Wastewater, 16th Edifibn, 1985, published join ' tly by Ame'rican
Public Health Association, American Water Works Association and Water Polkition Control Federation;
(b) -Methods for Chemical Analysis of Water and Waste, 1979, U.S. Environmental Protection Agency publication number
EPA-600/4-79-020, as revised March 1983;
'(c) Test Methods for Evaluating Solid Wastes: Physical/Chemical Methods,- 3rd Edition, 1986, U.S. Environmental
Protection -Agency publication number'SW-846;
(d) Test Procedures for the' Analysis of Polluants Under the Clean Wate'rAct, Federal Re'gister-Vol. 49, No. 209, 40 CFR,
Part 136, October 26, 1984;
4.'Measure and record the depth of water in the. well prior to pumping or bailing any water from the well.
5. At least 3 volumes of water in the well should be pumped or bailed prior. to collecting a sample f6 I r analysis. If the well'is . pumped/bailod dry
-before 3 well -volumes.-are-removed,,sa'mples can be collected -as soon as the well recovers to the point where enough water is available
le to
collect yoursample,_.-
.6. Determination for pH,.SpecFr1c,6.onductance, temperature, oclor. and appearance must be.made in the field on unfiltered samples when the
7. IF t e calibrat,�d in.a'c6rdahce with recbmme'ndations b- the, manufacturer.
Field e meqtmus c y
8. Sarpp)es,,m�,be,filterocl fhroUgh.a 0.45 micron-filter.immediately. after collecti6n When a dissolved analysis..is required (See 48. 'above),
.=Wdo the - fadility-h me
9'. The sample container should :be"labefedat. the time. pt' I 4i 'n with'Wbil-identifid6t -ber and date'and time.col-
iorl. nurn
lected..,,
I O."Aoihorized agent." is -any cor0orate officer -tar p'blicoffitial.aut�6.i2pd.0y.h&c&npany,,corp otati6n,.& jovernmenta bogy to sign:pffiC"ia 1.
documehts. ,*.

Division of Environmental Management
GROUNDWATER QUALITY MONITORING
: COMPLIANCE REPORT FORM Groundwater section
P.O. Box 27687
Raleigh, NC 27611-7687
For additional forms please write or call: [phone]
Facility Name Unimin Corporation County
Address P. 0. Box 588 PERMIT MBER: (REQUIRED)
Spruce Pine, NC 28777 Non -Discharge
Well Location MW #2
NPDES
Well Identification Number
Well #2
Well Depth Ft.
TYPE OF DISPOSAL OPERATION BEING MONITORED
(REQUIRED)
Well Diimeter
Sample (Screened) -interval Ft. To - Ft.
Lagoon Septic Tank/Drain Field
Depth to Water Level 13.50 ft. below measuring point. (before sampling)
— Spray Field — subsurface Low -Pressure
MeasuringPiping
point is
feet above land surface
(L'PP)
.Land Application of sludge
Gallons of waterpumped/bailed before sampling 6
A Rotary Distributor Other
Field Analysis: pH: 5.20 . Specific Conductance
35 uMhos Temp. -
15.5 ° C Odor Appearance
Date Sample Collected
7/9/91
Date Lab Sample Analyzed
7/17/91
Laboratory Name
PACE, Inc.
Certification No.
COD
mg/1
NO2.as N
mg/I Ni - Nickel
mg/1
Coliform: MF Fecal
/100ml
NO3 as N.
mg/I Pb - Lead " T. 0:05
mg/l
Coliform: MF Total
/100ml
Phosphorus: Total as P
mg/I Zn - Zinc
mg/I
Dissolved Solids: Total
55 mg/1
AI - Aluminum
mg/I Pesticides/Herbicides. (Specify Compounds)
PH (when analyzed)
units
Ba - Barium L 0.10
mg/I
ug/I
TOC
mg/i
Ca - Calcium
mg/I
ug/I
Chloride
mg/I
Cd - Cadmium
mg/I
ug/I
Arsenic L 0.001
mg/I
Chromium: Total L 0.02
L,, • ug/I
mg/I OtherI.-ItIsIf"t-IF56cC
Grease and Oils
m /I
9
Cu-Co L 0.01
Copper
g � .�
m /I
; "
ug/I
Hardness: Total
mg/I
Fe - Iron
�
I iK I, la
u 9 /I
Phenol
mg/I
Hg -Mercury
_
g
l�
�.,
ug /I
Sulfate
mg/i.
K - Potassium
_
m
I
u /I
g
Specific Conductance
uMhos
Mg - Magnesium
NN
I All(,
mg
e� ��1 marf
R!A fi;G .
ug/I
nrs�lc��a�'1. K'+a�i':
Total Ammonia( 3 * H 4)
mg/I
Mn - Manganese
mg
11
T K N as N
rpg/I
Na - Sodium
GROUNDWATER SECTION '
c ri It G/I
NOTE:
Values should reflect dissolved concentrations
SIGNAYURE OV
C.lW-r%Q RF\/ 9/on
' I� HIS REPORT IS TRUEAND
ElIMITTEE (OR AUTHORIZED AGENT')
URATE.
DATE
(See, #2. on reverse)
* See back for Instructions.
"Submit blue, green, and yellow copies only to address above.

1. Samples should be analyzed as-sobn as possible after collection. SAMPLES WHICH ARE NOT ANALYSED WITHIN THE HOLDING
TIME SPECIFIED FOR THE MET`H6Q USED (SEE #3. BELOW) MUST BE DISCARDED AND NEW SAMPLES COLLECTED.
2. ANALYSES ARE TO BE MADE OF -THE CONSITITUENTS DISSOLVED IN THE GROUNDWATER, NOT THOSE THAT ARE A PART
- OF,.OR ADSORBED ONTO, SOIL/SEDIMENT PARTICLES. CHECK WITH YOUR LABORATORY ON PROPER PROCEDURES FOR
SAMPLE. COLLECTION AND PRESERVATION.
3. As per Title 15, North Carolina Administrative Code; Subchapter 2L, analytical procedures shall be inaccordance with the methods.
described in''one of the following publ.ications, or by other methods approved beforehand by the Director, Division of Environme.nta.1
Management:
(a) Standard methods for the -Examination of Water and Wastewater, 16th Edition, 1985-, published jointly by American
Public Health Association, American Water Works Association and Water Pollution Control Federation;
(b) Methods for Chemical Analysis of Water. and Waste, 1979, U.S. Environmental Protection -Agency publication number
EPA-600/4_79-00, as revised Mar6h'1983;
(c) Test Methods for Evaluating Solid"Wast0s'': Physic'aVChemical Methods, 3rd Edition, 1986, U.S. Environmental
Protection Agency publication number SW-846;
-(d) Test Procedures, for'the, Analysis -of Polluants Under the Clean Water Act, Pederal Register Vol. 49, No. 209, 40 CFR
Pars
36, October 26, 1984;
4. Measure and record the depth of water in the well prior to pumping or bailing any water from the well.
5. At least 3-volumes of water in the We. fl -should be pumped or --bailed prior to collectin.g'a sample for analysis.- If the well is pu'mped/baile'd dry
.'before 3 well volumes'are removed, samples can be collected as soon as the Well- recovers to th6'point where enough water is -available to
collect your sample.
6. betermihiiilpl I n"for "l ,,Ppecific.Co'ndijctarice,.temperature, oclor'andappearance"imust be-made,ih the field on unfiltered samples whpq,the
sample ip c*ollbctOd.
7.,.'Field. equipment must be calibrated in .&c6rda.n 0 -with recbrilmehdations* by 1h'e:(nanufActurbr.'-.'- -7
.8. Samples must bdfiltbr6d throbq'"h.a,-0A5 r­nidrqh.filtgJRmedrat6Jy .4fte'r'collOdtiob'.Wheh..a.dissoly d anal' -rewired-. (See 0. -above). aMP -
pie contailne'r-sh6uld b-01'' Ith" 4; io-ri �&lith the fa; ' ,'w 1'.* � , , "' * '6 '."umb'' r and:d' t
9. The sample abeled.at. 6 dim cility:h e a e and time col.: I dentif ic, tion. n
lebted.
f r 'b d -c �n co _d
1Q!.Auth&ized a'gent"Js.any coirpo.�atO o fiGa - or-pu,�.lic-off official auth&ize b t . 0 -o
y he. r t*' tq -�iqp :official
pan.yi; ton . , r g.9vernrrye y
docuroents..

GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Division of Environmental Management
Groundwater Section
P.O. Box 27687
For additional forms please write or call: " Raleigh, NC 27611-7687
()19)733-3221
Facility Name Unimin Corporation
County %
uu d
�'d Br�=U= `�--IN
Address P.O. Box 588
C,1Hill
PERMIT NUMBER: (REQUIREpDVI .. ,�9`
Spruce Pine, NC. 28777
Non -Discharge
II P
Well Location Monitoring Well #2
NPDES
�I II r��nee�,�ttiaz�erS�ctlorf
Well Identification Number M.W. #2 Well Depth 25 Ft
TYPE OF DISPOSAL OPERATti ON-83�EIN'G'-'M'O'N1T0•FtED-=
(REQUIRED)
Well Diameter `r Sample (Screened)"Interval Ft. To Ft.
Lagoon
Septic Tank/Drain Field
Depth to Water Level 1 4. 00 ft. below measuring point. (before sampling)
— SprayField—
Subsurface Low -Pressure
Piping (LPP)
Measuringpoint is �� feet above lane! surface
Land Application of sludge
Gallons of water pumped/bailed before sampling 6
Rotary Distributor
Other
Field Analysis: pH 5.8 Specific Conductance 29 uMhos Temp. 13
° C Odor
Appearance
Date Sample Collected 03/05/91 Date Lab Sample Analyzed
03/05/91
Laboratory Name Pace, Inc. Certification
Na. 40
COD mg/I NO2 as N
mg/I _ Ni - Nickel
mg/I
Coliform: MF Fepal /100m1 NO3 as N.
mg/I Pb - Lead
ND mg/'I
Coliform: MF Total /100ml Phosphorus: Total as P
mg/I Zn - Zinc
mg/I
-Dissolved Solids: Total 42 mg/I
PH (when analyzed) units
TOC mgJI
Chloride mg/I
Arsenic ND mg/I
Grease and Oils mg/I
Hardness: Total mg/I
Phenol mg/I.
Sulfate mg/I
Specific Condu�,tance uMhos
Total Ammo fa H3 * NH
TKN as
I C IFY T
SIGNATU
Al - Aluminum mg/I Pesticides/Herbicides. (Specify Compounds)
Ba - Barium ND mg/I vg/I
Ca - Calcium mg/I ug/I
Cd - Cadmium mg/I ug/l
Chromium: Total ND
mg/I
Cu- Copper ND
mg/I
Fe - Iron
mg/I
Hg - Mercury
mg/I
K - Potassium
mg/I
Mg - Magnesium
mg/I
Mn - Manganese
— mg/I Na - Sodium
FIT IS TRUE AND ACC TE
ITTEE (OR AUTHORIZED AGENT*) DATE
mg/I
mg/I
Other (S ecif ug/I
�Y 4� ug/I
211,
ug/I
ug/I
ug/I
g
NOTE:
Values should reflect dissolved concentrations
(See #2. on reverse)
* See back for instructions.
** Submit blue, green, and yellow copies only to address above.
rW_j;a Rf=v Dion

1. Samples should be analyzed as soorl ps possible -after collection. SAMPLESWHICH ARE NOT ANALYSED WITHIN THE HOLDING
TIME SPECIFIED FOR THE METHOD 'USED (SFE #3. BELOW) MUST BE DISCARDED AND NEW SAMPLES COLLECTED.
2. ANALNS)ES ARE TO BE MADE OF TH . E CONSITITUENTS DISSOLVED IN THE GROUNDWATER, NOT THOSE THAT ARE A PART
OF, OR ADSORBED ONTO, SOIL/SEDIMENT PARTICLES. CHECK WITH YOUR LABORATORY ON PROPER PROCEDURES FOR
SAMPLE COLLECTION AND PRESERVATION.
3. As per Title 15, North Carolina Administrative Code, Subchapter 2L, analytical procedures shall be in.accordance with the methods
desdribed in one of the following publications, or by other methods approved beforehand by the Director, Division of Environmental
Management.''
(a) Standard methods for the Examination of Water and Wastewater, 16th Edition, 1985, published -jointly by American
Public Health Association, American Water Works Association and Water -Pollution Control Federation;-
Methods for Chemical Analysis of Water. and Waste, 1979, U.S. Eny,ironmental Pr6tection Agency, publication number
EPA-600/4-79-020, as revised March 1983;
(c)-Test Mdthodb for -Evaluating Solid Wastes: Physical/theimi6l, Methods, 3rd Edition, 1986, U.S. Environmental
Protection Agency publication number SW-846;
(d) -Test Procedures for the Analysis of Polluants Under the Clean Water -Act, Fbderal Register Vol. 49, No. 209, 40 CFR
Part 136, October. 26,1984;
4. Measure and, record the depth of water,in the well prior to pumping or bailing ,any water from the well.
pumped -or bailed ecti , 11 " , pumped/baited 'I " 5. At' least 3-volumes of water in the well should be -prior collecting a sample for'analysi8. If the we is dry
before -3 well volumes are removed, samples can 'be collected as soon as the well'tecovers to the point -where enough water --is available to
collect your -,sample.
6., Determination for pH, Specific Conductance, temperature, odor and appearance, must be made in the field on unfiltered samples when the
sample. is collected.
17. Field"qu '-d-i" ipment must be calibrated in-accordahce with recommendations -by the rfianufa6tbrer.
-
8. Samo'6s rfilust be filtered through a 0.45 micron filter immediately after collection when a dissolved analysis is required.. {See #3. above)
_
9. The sample container should be labeled at the time of -collection with the facility name, well identification number and date and time col-
lected.
1 0."Au6orized agent" is any corporate officer or public official authoriz'ed by the company, corporation, or governmental body to sign official
documents.

V7�
m.of Environmental iwcanagemerit
GROUNDWATER QUALITY MM
ONITORING: COS, REPORT FORM
DIVWon
Groundwater Section
P-0- Box 2 M7
Raleigh, NIC - 27611-7687
For additional forms r)leaae write or call:
Facility Name
n courly
Address
PERMIT NUMBER:
Non -Discharge
Well Location
NPIDES.
Well Identification Number
6'2
•Depth
Well _Ft.
TYPE OF CLISPOSAL OPERATION BEING MONITORED
(R—E-5VIRED)
Well Diameter
Sample CScreened) lnlem�al _Ft. -ro _Ft.
— Lagr-m
— Septic Tank/Drain Field
Depth to Water Lever
— ft. be'$ow measuring point. iLbaflore sampling)
— Smy F)Wd
Subsudace Lotei--�ressure
Meastifing pant is
feet above land awface
— Lard Appgcafrcort of 84Age
1
Piping 01p]
Galions of water pumped/bailed before sampling
!)jsfnbutor
Other
Field Analysis: pH S,4 SP601fic Conductanca
uMhos Temp.
Y C Odor
Appearance
Date SarriPle Collected
Date Lab Sample Analyzed
Laboratory Name
Certification Na.
GOD
mg/I
NO2 as N
mg/I Ni Nickel
-Mgli
Collform: MF Fevaf
/100MI
NO3 as N
—mgfl Pb Lead
mg/1
Coliform: CIF To'lal
1 oarnt
Phosphorus. Total as P
mg/I Zn - Zinc
Mg/I
Dissolved Solids: Total
njb/j
Al - Alluminum
Mg/I Pesficides/hlerbic>des
(Specify CompoLrids)
P11 (when analyzed)
units
Ba - Barium
M-g/I
ugyl
LL
TOC
mg/4
Ga - Calcium
mg/I
Lpg/l
0
Chloride
mg/1
Cd -Cadmium
Mgj1
ugiff
Arsenic
mg/l
Chromium: Total
--mg/l Other (Specify)
ag"I
Grease and Oils
mg/I
Cu - Capper
—rng/j
ug/l
n
i
Hardness: Total
mg/I
Fe -Iran
Mg/I
Ug/I
1E i
Phenol
mg/1
;fig - Mercury
mgA
ug/l
Sulfate
mg/I
K - Polassium—
mg/1
ugyj
T
Specific Conduclance--uMhos
Mg - Magn 9siurn
rn,311
Ug/1
0
Total A-rnrnon(NH wt
ia4.1--
mg/I
Mn - Manganese
rngf I
>
TKN as r�j
-- mg/1
Na - Sodium —
•L421E
rng /I V� Auss should reflec!
dissolheed concentratbw
I CERTi FFY THAT THIS
REPORT IS TRUE AND ACCURATE.
-A2- on ravers-G)
* Ss-- ?aa, for instrixtions.
S.) GNATU RE OF PE RM ITTE—E (OR AUTHORIZED AGERT�)— DXTE Submit blue, green, and yelgow mpies 2a-[X to address above-
GW-59 REV. 2W

COMPLIANCE MONITORING
REPORT FORM
Facility Name
Address
Division of Environmental Management
Groundwater Section
P.O. Box 276%7
Raleiggh, N.C. 2761 1
For additional forms please write or call: [phone]
County
Permit Number:
---) OF _ r- I nC� , ) VI'.— • of _6 / 1 / Non -Discharge_
Well Location V�{ oT C� ``-i,�I� I NPDES ZZC -Qd(!2" S�
Well Identification Number ��• �'V. a' Well Depth a!t) Ft. Water Use
Well Diameter Cq Sample (Screened) Interval Ft. To Ft. Injection Well ✓{rl s
Depth to Water Level I I , 10 ft. below measuring point. (before sampling) Well Construction ;`C'
Measuring point is �_ feet above land surface Other q 190
Gallons of water pumped/bailedbefore sampling J'
r7 0 aal 1 r- o GR0U1''i�'''V"A Lei
Field Analysis: pH�� Specific Conductance uMhos Temp. 1 C Odor Apr'paae
n.n
Date Sample Collected 0 -7- 9 -90 c tl8h
Date Lab Sample Analyzed ^_
Laboratory Name PC�EP. ;�C Certification No. 40
COD mg/I
Coliform: MF Fecal /100ml
Coliform: MF Total /100ml
Dissolved Solids: Total ! mg/I
pH (when analyzed) 5.(0 units
TOC mg/I
Chloride mg/I
Arsenic L 0.005 mg/I
Grease and Oils mg/I
Hardness: Total mg/1
Phenol m g /l
Sulfate
Specific Conductance
Total Ammonia(NH3 tt
TKN as N
I CER-TtFY T
4)
- mg/I
uMhos
NO2 as N
mg/I
NO 3 as N
mg/I
Phosphorus: Total as P
mg/I
Al - Aluminum
mg/I
1
Ba - Barium L C).05
mg/I
Ca - Calcium
mg/I
Cd - Cadmium—
mg/I
Total LO•U�-
Chromium:
mg/l
Cu - Copper 1_O. O
10 mg/I
Fe - Iron
mg/I
Hg -Mercury
mg/I
K - Potassium
mg/I
Mg - Magnesium
mg/I
mg/I Mn - Manganese mg/I
mg/I Na - Sodium mg/I
LS TRUE AND ACCURATE.
OF PERMITTEE (OR AUTHORIZED AGENT't) -DATE
Ni - Nickel mg/I
1
Pb - Lead 0.05 mg/f
Zn - Zinc mg/I
Pesticides/Herbicides (Specify Compounds)
ug/I
ug/I
ug/l
Other (Specify) ug/I
Note
iU
b
Groundwater Section
Y=�-�'' heville R 'onal Office
_ ug/I
_ug/I
_ ug/I
_ ug/I
_.ug/l
Values should reflect total concentrations
# See back for instructions.
* 'Submit blue and green copies only to address above.
GW-59 Revised 6/88

t �-
� �� ` % �-- Z 14=
0 162
couNTv —1--1— N.C.
DEPARTMENT OF NATURAL. RESOURCES
LAB NUMBER s
QUAD NO.' 1 �' '- SERIAL NOr� / ��G
&COMMUNITY DEVELOPMENT DATE RECEIVED"'-
_
' ''J Time �6'
LAT. ✓' A, LONG. .� ', >
DEM
! l
Rec'd by:`: "
From: Bus -Courier
GROUNDWATER FIELD/LAB FORM
Other
Report to:. RO;P FRO, MRO, RRO, WaRO, WiRO,
SAMPLE PRIORITY
DATA ENTRY BY:
j C
6110F CK:
WSRO, Kinston FO ( Other 1
O" ROUTINE ❑
EMERGENCY
DATE REPORTED:
Shipped by: Bus, Courier, Other
COLLECTORDATE
TIME Oe" -f PURPOSE: BASELINE, COMPLAINT ,`CO PLM IANCE 1-UG-., OTHER
(cIroI orre)--
FIELD ANALYSES Owner
U 'A..'/ue,
i ! '3!� r�l �jr"' I :r
C tr ! /;:%.; �, ,ns
ph1400 -
F Temp` 10
Spec. Cond.94
—oC Odor _
Appearance Taste
Field Analysis By:
LABORATORY ANALYSES
BOD5 3,10
mg/I
COD High 340
mg/I
o COD Low 335
�a
mg/I
tr%
Coliform:MF Fecal 31616 Z_ qJ
/loom[
Coliform:MF Total 31504 4 i
/loom]
TOO 680
mg/I
Turbidity 76
NTU
pH 403
units
1.1'
Alkalinity to pH 4.5. 410
mg/]
t,�'
Alkalinity to pH 8.3 415
mg/1
Carbonate 445
1
mg/l
f-�
Bicamonate 440
�a
mg/1
Arsenic:Total 1002
ug/1
Carbon dioxide 405
mg/I
u
Chloride 940
G� It
mg/1
Chromium:Hex 1032
ug/I
Color:True 80
Pt -co
Cyanide 720
mg/1
Lab Comments:
at 250C Location or site
Description of sampling point
Sampling Method'` F Sample Interval afi / ' /.�? ✓
_ (pump, bailer, etc*.)
Remarks / '� 1 1/- _ 1 C- 1 ,1 �4. / , /-_ F; r
015
Diss. Solids 70300
mg/1
Fluoride 951
mg/1
ois
Hardness:Total 900
r mg/1
�(e,
Hardness (non-carb) 902
mg/I
Phenols 32730
ug/I
Specific Cond. 95
uMhos/cm2
Sulfate 945
mg/I
Sulfide 745
mg/I
NH3 as N 610
mg/I
TKN as N 625
mg/1
NO2 -t NO3 as N 630
mg/I
P:Total as P 665
mg/I
Ag - Silver 1077 ug/I
A'[ - Aluminum 1105 ug/I
Be - Barium'1007 ug/1
Ca - Calcium 916 mg/I
Cd - Cadmium 1027 ug/I
Chromium:Total 1034 ug/I
Cu - Copper 1042 ug/I
Fe - Iron 1045 ug/I
Hg - Mercury 71900 ug/I
K - Potassium 937 mg/1
Mg - Magnesium 927 mg./I
Mn - Manganese 1055ug/I
Na - Sodium 929 mg/I
Ni - Nickel 1067 ug/I
Pb - Lead 1051 ug/1
Se - Selenium 1147 ug/I
Zn - Zinc 1092 ug/I
ng time, air temp, etc.
Organochlorine Pesticides
Organophosphorus Pesticides
I I Acid Herdicides I
Base / Neutral Extractable organics
Acid Extractable Organics
I I Purgeable Organics (VOA bottle) I
I I 1,2 - Dibromoethane (EDB)
GW-54 Revised 7/85 For Dissolved Analysis - submit filtered sample and write 'DIS' in block
White copy - Headquarters Pink copy - Region Yellow copy - Lab

couNrY "TG!-f[. GL N.C. DEPARTMENT OF NATURAL RESOURCES t Ci&9C(
QUAD NO I �/ LAB NUMBER 8
.SERIAL NO. o & COMMUNITY DEVELOPMENT -Z—
LAT�SSG. �`fG 8� O� 5r7 DATE RECEIVED Time 9-00
LONG.
DEM Rec'd by: C1­0") From: Bus Cowrie
Report to: ARO FRO, MRO, RRO, WaRO, WIRO, GROUNDWATER FIELD/LAB FORM 0 Other
WSRO, Kinston FO Other SAMPLE PRIORITY DATA ENTRY BY: j CK:
Shipped by: Bus, Courier Other ROUTINE ❑ EMERGENCY DATE REPORTED:
COLLECTOR(S): G�rAi DATE2 � — O
I
r TIME S D� PURPOSE: BASELINE, COMPLAINT, COMPLIANCE I.US", OTHER
(circle o
FIELD ANALYSES is Owner L.�N/ M /nl C•O R/�p,ef} TON Q (,(s}I� 7 Z CiPEIr?�iT/ on)S
p11400 Spec. Cond.94 at 250C Location or site DO►V'Q&RAO/ EN'T
Temp.t0 oC Odor Description of sa I' wCLL 1
Appearance Taste
Field Analysis By:
LABORATORY ANALYSES
BOD5 310 mg/I
COD High 340 mg/I
COD Low 335 - mg/I
Colilorm:MF Fecal 3416 /10oml
Colilcrm:MF Total 3144 /loom)
TOC 680 mg/I
Turbidity 76 NTU
i
PH 403 units
Alkalinity to pH 4.5 410 mg/I
Alkalinity to pH 8.3 415 mg/I
Carbonate 445 mg/1
pl
Bicaruonate 440 mg/I
Arsenic:Total 1002 L I ug/i
Carbon dioxide 405 i mg/I
Chloride 940 mg/1
Chromium:Hex i032 ug/l
Color:True 80 ! Pl-Co
Cyanide 720 mg/I
Lab Comments:
mp I ng point EAD
Samplinq Method — A4 / L_ Sample Interval a
(pump, bailer, etc.)
Remarks
57_,4TIG vVAT4M LgVC_Z__ ��,S7 (pumping time, air
Liss. Solids 70300
mg/I
Qr$
fluoride 951 • II
mq/I
Ilardness:Total 900
mg/I
1,araness (non-carb) 902
mg/I
Pnenols 32730
ug/I
S :,ecilic Cond. 95
yullate 945 L
uMhos/cm2
mg/l
OIS
Sulfide 745
mg/I
015
N113 as N 610 /
mg/I
015
1KN as N 625 ,
mg/I
/
NO2 + NO3 as N 630 ,
mg/l
0/
P:Total as P 665 Q�
mg/I
p15
Ag - silver 1077
4 !,C)
ug/l
O!S
At - aluminum 1105
4 JQ
ug/I
015
Ba - Barium 1007
41
ug/1
P 1A
Ca - Calcium 916
,
mg/1
Q15
Cd - Cadmium 1027
Z,Q
ug/I
O1S
Chromium:Total 1034
LzJ
ug/I
D15
Cu - Copper 1042
z, 7
ug/I
Fe - Iron 1045
uq/I
/
HQ - Mercury 71900
C
uq/I
1$
K -Potassium 937
mg/I
[)IS
Mg - Magnesium 927
r
mg/l
1
Mn - Manganese 1055
ug/l
Q/
Na - Sodium 929
I,
mg/I
/
r
Ni - Nickel 1067
Pb - Lead 105.1
l-. �O
I
ug/I
ug/I
pl
Se - Selenium 1147
—
uq/I
Vj<
Zn - Zinc,1092
uq/I
GW-54 i-ed 7/85
For Dissolved Analysis - sui,mit fil' d sample and write 'DIS' in block
�.% White copy - Headquarters Pink�py - Region Yellow *copy - Lab
Orga ob l•oilne Pesticides , I!
Organ ph6i phorus Pesticides
' g 1
Acid icides
`
Base / Noutr&R x r I O nits
Acid Extractable Organics
Purgeable Organics (VOA bottle)
1.2 - Dibromoelhane (EDB)
G^
V

COMPLIANCE MONITORING
REPORT FORM
a
Facility Name
Address
Division of Environmental Management
Groundwater Section
P.O. Box 27687
Ralei , M.C. 27611
For additional forms please write or call: (91 )733-3221
Well Location
Well Identification Number 4 2 Well Depth 15 Ft.
Well Diameter 2 !) Sample (Screened) Interval Ft. To Ft.
711-1
County ►` e
Permit Number:
Non -Discharge
NPDES
Water Use
Injection Well
Depth to Water Level
i2 ft. below measuring point. (before sampling)
Well Construction
Measuring point ism_ feet above land surface
Other
II
Gallons of* water pumped/bailed before sampling
APR 31 ]Pot
Field Analysis: pH
Specific Conductance uMhos Temp.
° C Odor �_A �arance
U,18 . I"d;�AI ER .-
Date Sample Collected
3 f? %�� Date Lab Sample Analyzed
q(-)
SFnT
'
i
Laboratory Name
-� �n
� ��_: �nc� Certification No.
F G � I �i U
COD
mg/1 NO2 as N
mg/I Ni - Nickel
mg/I
Coliform: MF Fecal
/100ml NO3 as N
mg/I Pb - Lead
C I cs=-o
mg/I
Coliform: MF Total
/100ml Phosphorus: Total as P
mg/I Zn - Zinc
mg/1
Dissolved Solids: Total (-D4� C_) mg/1
pH (when analyzed)units
TOC mg/I
Chloride mg/I
Arsenic CO oc75 mg/I
Grease and Oils
mg/I
Hardness: Total
mg/1
Phenol
m g /I
Sulfate
mg /1
Specific Conductance
uMhos
Total Ammonia(NH3 t NH 4)
mg/I
�
TKN as N ! 2
, mg/I
I CERTIFY TH REST IS;0
Al - Aluminum mg/I Pesticides/H,etbici;des (Speci.fy.Corppounds)
Ba - Barium
mg/I
Ca - Calcium
mg/I
Cd - Cadmium
mg/I
Chromium: Total <1 020
mg/I
Cu- Copper <o,Oto
mg/I
Fe - Iron
mg/I
Hg - Mercury
mg/I
K - Potassium
mg/I
Mg - Magnesium
mg/1
Mn - Manganese
17a - Sodium
AND ACCURATE.
SIGNATURE OFMITTEI''(OR AUTHORIZED AGENT
GW-59 Revised 6/88
�i"P ug/I
• •' 414�/Vl l,l J•.4 a1 V1�
Other (Specify)?°1slile Regional Ji7iC ug/I
ug/I
mg/I
Note:
mg/1
Values should reflect total conce
ug/I
ug/I
ug/I
* See back for instructions.
* 'Submit blue and green copies only to address above.

COMPLIANCE MONITORING
REPORT FORM
Facility Name Jr) 1LI' ('�r V-41c�v�
Address PCB _E>�X 8p
c��C'Uce tit-, e arc
Division of Environmental Management
Groundwater Section
P,O. Box 27687
Raleigh, N.C. 27611
For additional forms please write or call: [phone]
Well Location
Well Identification Number -)42 Well Depth )16—Ft.
Well Diameter 2" Sample (Screened) Interval -65 Ft. To_I Ft.
Depth to Water Level I'163 ft. below measuring point. (before sampling)
Measuring point is 0 feet above land surface t
Gallons of water pumped/bailed before samplings
County NA
Permit Number:
Non -Discharge '-
NPDESe--��:��'
,R
Water Use
Injection Well
Well Construction
Other
Field Analysis: pH Specific Conductance uMhos Temp. o C Odor Appearance
Date Sample Collected `9 tqlq Date Lab Sample Analyzed
Laboratory Name ���� r�nrr��r�T�t� 1� �;, �n c . Certification No.
COD mg/I NO2 as N mg/I Ni - Nickel mg/I
Coliform: MF Fecal
1100ml NO 3 as N mg/I
Coliform: MF Total /100ml
Dissolved Solids: Total M.EL mg/I
pH (when analyzed) J5 < LB units
TOC
Chloride
Phosphorus: Total as P
mg/I
Al Aluminum mg/I
Ba - Barium <Q ,QEQ mg/I
mg/I Ca - Calcium mg/I
mg/I
Arsenic ©,OCY mg/1
Grease and Oils mg/I
Hardness: Total.
Cd - Cadmium mg/I
Chromium: Total . <0. 0ZO mg/I
Cu - Copper { 0 0 (% mg/I
mg/I Fe - Iron
Phenol mg/I Hg - Mercury
Sulfate
mg/I K - Potassium
7U
_mg/I
.mg/I
Specific Conductance uMhos Mg - Magnesium mg/I
Total Ammonia(NH3 t NH 4) mg/I Mn - Manganese mg/I
TKN as N I Na - Sodium mn/I
I CERTIFY T O ZTFRUE AND ACCURATE.
SIGNATU OF PERMITTEE (OR AUTHORIZED AGENT*)
GW-59 Revised 6/88
Pb - Lead mg/I
Zn - Zinc mg/1
Pesticides/Herbicides (Specify Compounds)
Other (Specify)
ug/I
ug/I
ug/1
ug/I
ug /I
4 '
-- ug/I
ug/I
ug/I
Groundwater section
Asheville Regional Offic;7/n-
Note: F Values shoLld reflect total concenos/
V-
5 - ' ee back for instructions.
DATE ** Submit blue and green copies only to address above.

Environmental Management Division
COMPLIANCE MONITORING Groundwater Section
,
REPORT FORM P.O. Box 27687
A44�Ic E ,d V a
Raleigh,N.C. 27611
[phone]
„�,r� Q.
Facility Name linimin CorpT
,
County plt;ahgil
Address PO Box 545
Permit Number: Groundwater Section
Achavilie Regional Office ,
Spruce Pine, NC 28777
Non -Discharge f
Well Location __ #2
NPDES NC OOjo,0475
Well Identification Number # 2" Well Depth 15 Ft.
Water Use 'I►77-+ `<<
Well Diameter 211 Sample, (Screened) Interval ri Ft. To 1_ Ft _
Injection Well ! aj
Depth to Water Level 1 3 13e' .ft. below measuring point. (before sampling)
Well Constructi{i
Measuring point is n feet above land surface.
Other `
Gallons of* water pumped/bailed before sampling To dryness
GROUNDWATER SECTION
Field Analysis: . pH 5.92 Specific Conductance uMhos Temp.
oC OdoradiGniFlLi
Date Sample -Collected 7/1 n.4gg Date Lab Sample Analyzed
7.4 1S./a0
Laboratory Name Environmental Testing Tnc: Certification No. 4n.
COD mg/I NO2 as N
.
mg/f Ni - Nickel g/I
m
Coliform: MF Fecal /100ml NO3 as N.
mg/I Pb - Lead <0.005 mg/I
Coliform: MF Total /100ml Phosphorus: Total as P
mg/I Zn - Zinc mg/I
Dissolved Solids: Total 58.6 mg/1 Al - Aluminum
mg/I Pesticides/Herbicides (Specify Compounds)'
pH (when analyzed) 5.92 units Ba - Barium- <0. 050
mg/I vg/I
TOC
mg/I
Chloride
mg/I
Arsenic <0 , 005
mg/I
Grease and Oils
Hardness: Total
Phenol
mg/I
mg/I
mg/I
Ca - Calcium _
Cd - Cadmium
mg/I
mg/I
Chromium: Total, <0.020 mg/I
Cu - Copper 0.012 mg/I
Fe - Iron mg/I
Hg - Mercury mg/I
Sulfate
mg/I
K - Potassium
mg/I
Specific Conductance
uMhos
Mg - Magnesium
mg/I
Total A"wnonia.(NH3.t NH4)—mg/I
Mn - Manganese
mg/I
TKN as N
mg/I
Na - Sodium-
mg/I
I CERTI T AT THI
POU IS TRUE AND ACCURATE.
Other (Specify)
ug /I
ug/I
ug/I
ug/I
ug/I
ug/I
ug/I
..ug/I
Note:
Values should reflect total'concenttatlons
* j,back #ovinstructions.
"ATAE OF PE TEE (OR AUTHORIZED AGENT*) AT ** Submit blue and green copies only to address above.
GW-59 Revised 3/88

Environmental Management Division
COMPLIANCE MONITORING Groundwater Section
REPORT FORM P.O. Box 27687 � C E I V
Raleigh,N.C. 27611
[phone] MAY
Facility Name UNIMIN Corporation County Kitchell
Address PO Box 588 Permit Number: Asjrou Regional Office
Spruce Pine, NC 28777 Non -Discharge H'
Well Location NPDES NC 0000175
Well Identification Number #2 Well Depth 151 Ft. Water Use
Well Diameter 2" Sample (Screened) -Interval 5 Ft. To 15 Ft. Injection Well
Depth to Water Level 14,22' ft. below measuring point. (before sampling) Well Construction
Measuring point is 0 feet above land surface. Other
Gallons of water pumped/bailed before samp-ing To Dr)rnPss
Field Analysis: PH 6.20 Specific Conductance uMhos Temp. ° C Odor Appearance
Date Sample Collected 3/6/89 Date Lab Sample Analyzed 3/12/89
Laboratory Name _ _ +Environmental Testing Inc. Certification No. 40
COD
Coliform: MF Fecal
Coliform: MF Total
- mg/I
1100ml
/ 100ml
Dissolved Solids: Total 6.0
mg/I
PH (when analyzed) 6.20
units
TOC
mg/I
Chloride
mg/I
Arsenic <0.005
mg/I
Grease and Oils mg/I
Hardness: Total mg/I
Phenol m g /I
NO2 as N
N0 3 as N
Phosphorus: Total as P
Al - Aluminum
mg/I Ni - Nickel mg/I
mg/I Pb - Lead <0.050 mg/1
mg/I Zn - Zinc mg/I
mg/I Pesticides/Herbicides (Specify Compounds)
Ba - Barium <0.010
mg/I
Ca - Calcium
mg/I
Cd - Cadmium
mg/I
Chromium: Total <0.020
mg/I
Cu - Copper ' 0.010
mg/I
Fe - Iron
Hg - Mercury mg/I
Sulfate
mg/I
K - Potassium
mg/I
Specific Conductance
uMhos
Mg - Magnesium
mg/I
Total Ammonia.(NHS.t NH 4)
mg/I
Mn - Manganese
mg/I~
TKN as N
mg/I
Na - Sodium,
mg/I
I CERT HA7THI PORT IS TRUE AND ACCURATE.
zo
GN E OF PERMITTEE (OR AUTHORIZED AGENT*) ATE
GW-59 Revised 3/88
c
ug /I
ug /I
ug/1
c i-f y)
ug/I
'
-` ug/I
Note:
Values should reflect total concentrations
*-See back for.instructions.
** Submit blue and green copies only to address above.

Environmental Management Division -
COMPLIANCE MONITORING Groundwater Section
REPORT FORM P.O. Box 27687
Raleigh,N.C. 27611DEC
,'
FacilityName UNIMIN Corporation i919)733-3221 Mitchell
County
Address PO Box 588 Permit Number: �aR � RG
_- Spruce Pine, NC 28777 Non -Discharge f' 4
Well Location NPDES NC 000045:.k,
Well Identification Number #2 Well Depth 15 Ft. Water Use
Well Diameter 211 Injection Well Sample (Screened) ��
Interval _ Ft. To Ft, �
Depth to Water Level 1F.6' ft. below measuring point. (before sampling) Well Construction
Measuring point is 0 feet above land surface Other Asheyilie Regional Offic-e
t
Gallons of water pumped/bailed before sampting to dryness
Field Analysis: -pH 6.10 Specific Conductance uMhos Temp. - oC Odor Appearance
Date Sample Collected 11_11n/RR Date Lab Sample Analyzed 11/IBAB
Laboratory Name Environmental Testing Inc. Certification No. 40:
COD
mg/I
Coliform: MF FeOal
/100ml
Coliform: MF Total
/100ml
Dissolved Solids: Total 32.3
mg/I
PH (when analyzed) 6.10
units
TOC
mg/I
Chloride
mg/I
Arsenic <0.005
mg/I
Grease and Oils
mg/I
Hardness: Total
mg/I
Phenol
mg/I
Sulfate
mg /I
Specific Conductance
uMhos
Total Alaxnonia.(NH3.t NH 4)
mg/I
NO2 as N
NO3 as N.
Phosphorus: Total as P
Al - Aluminum
Ba - Barium
Ca - Calcium
Cd - Cadmium _
Chromium: Total
Cu - Copper
0.437
<0.010
0.019
mg/I
Ni - Nickel
mg/l.
mg/I
Pb - Lead n_n.�F
mg/I
mg/I
Zn - Zinc
mg/4
mg/I
Pesticides/Herbicides (Specify Compounds)'
.mg/I
ug/I
mg/l ,
ug/I
m g /I
ug/l
.mg/I
Other (Specify)
ug/I
m g /I
ug /I
Fe - Iron mg/I
Hg - Mercury mg/l
K - Potassium mg/I
Mg - Magnesium mg/I
Mn - Manganese mg/I
TKN as N mg/I Na - Sodium` mg/I
I CERTIFY 'THIS REP IS TRUE AND ACCURATE.
12 12 88
SIGNATO OF PERMITTEE (OR AUTHORIZED AGENT*) DATE
GW-59 Revised 3/88
ug/I
ug/I
ug/I
..ug/I
Note:
Values should reflect total'concentrations
*,See back for instructions.
** Submit blue and green copies only to address above.

�__) ,�11 � W/
^`APARTMENT
COUNTY /�C�ilr°
/� N.C.:
OF NATURAL RESOUR
LAB NUMBER 8
_V��/i/
OUAD NO.
LAT. �.5^.��%y.
SERIAL NO.
LONG. �� bJ�g
& COMMUNITY DEVELOPMENT
DEM
DATE RECEI D Tim ,
Rec'd by:1 /_/ From: Bu Cour er
V�
Report to ARO FRO,
MRO, RRO, WaRO, WiRO,
GROUNDWATER FIELD/LAB FORM
Other
l 7
SAMPLE PRIORITY
'
TA ENTRY BY. CK:
WSRO, Kinston FO
Other
ROUTINE ❑ EMERGENCY
W
ATE REPORTED:
Shipped by: Bus, ou r,//Other
COLLECTOR(S): 1 , DATE TIME
FIELD ANALYSES
PH400 Spec. Cond.94
Temp. 70 oC Odor —
Appearance Taste
Field Analysis By:
LABORATORY ANALYSES
BOD5 310 mg/I
COD High 340 mg/I
COD Low 335 mg/I
Coliform;MF Fecal 31616 /loom[
Colilorm:MF Total 31504 /t00ml
TOC 680 mg/I
Turbidity 76 NTU
pH 403 units
Alkalinity to pH 4.5 410 mg/I
Alkalinity to PH 8.3 415 mg/I
Carbonate 445 mg/I
Bicarbonate 440 mg/I
i
Arsenic;Total 1002ug/[
Carbon dioxide 405 mg/I
Chloride 940 mg/I
Chromium:Hex 1032 ug/I
Color:True 80 Pt -co
Cyanide 720 mg/i
Owner /r
a t 250C Location or site0 u//� f��•�,'%''
Description of sampling point
LGl
Sampling Method `���,Z Sample Interval
(pump, bailer, -etc.)
PURPOSE: BASELINE, COMPLAINT, MPLIANCE UST, OTHER
(circle one
Remarks
(pumping time, air temp, etc.)
Diss. Solids 70300 mg/I
Fluoride 951 �d1 mg/I
Hardness:Total 900 mg/I
Hardness (non-carb) 902 mg/I
Phenols 32730 ug/I
Specific Cond. 95 uMhos/cm2
'
Sulfate 945 .--mg/I
Sulfide 745 mg/1
NH3 as N 610 mg/I
TKN as N 625 mg/I
NO2 + NO3 as N 630 mg/I
P:Total as P 665 mg/l.
Ag - Silver 1077 -e_"
ug/I
/'
Al - Aluminum 1105 L
ug/I
Ba - Barium 1007 , d
ug/I
Lc
Ca - Calcium 916 n ,
mg/I
/'
Cd - Cadmium 1027 "-C;�.0
ug/I
,_S
I Chromium:Total 1034 L
ug/I
r
Cu - Copper 1042 ­4
ug/I
Fe - Iron 1045
ug/1
Hg - Mercury 71900 ,
ug/I
K - Potassium 937 3
mg/I
Mg - Magnesium 927
mg/l
/
Mn - Manganese 1055 100
ug/I
Na - Sodium 929
mg/I
NI - Nickel 1067 .e:
ug/I
Pb - Lead 1051 L /
ug/I
Se - Selenium 1147
ug/I
Zn - Zinc 1092
ug/1
Organochlorine Pesticides
Organophosphorus Pesticides
Acid Herdicides
Base / Neutral Extractable Organics
Acid Extractable Organics
Purgeable Organics (VOA bottle)
1.2 - Dibromoethane (EDB)
. .., rNr'al'il Sfy''' �tiir'.
i
% y
1 �
J,J
Lab Comments: u:if�lUU�i�tl`.Iliil� ' •.Di: ��u1
GW-54 Revised 7/85 For Dissolved Analysis - submit filtered sample and write "DIS' in block
White copy - Headquarters Pink copy - Region Yellow copy - Lab

COUNTY
N.C. DEPARTMENT OF NATURAL RESOURCES
LAB NUMBER 8-
QUAD NO. f '" �_"
SERIAL NO.
& COMMUNITY DEVELOPMENT
DATE RECEIVED -
/' Time
LAT. t `
LONG.
DEM
0
Rec'd by: I
From: Bus-Couri',er
GROUNDWATER FIELD/LAB FORM
Other'
Report to: AR&, --FRO, MRO., RRO, W'aRO, WiRQ,
SAMPLE PRIORITY
DATA ENTRY BY:
CK:
WSRO, Kinston FO
Other
❑
_
ROUTINE EMERGENCY
DATE REPORTED:
Shipped by: Bus, Courier;
0fher_-
r DATE
P.!/ •' TIME PURPOSE: BASELINE, COMPLAINT,
COMPLIANCE, LUST,
OTHER
(circle
FIELD ANALYSES
Owner
pH400 Spec.
Cond.94 at 250C
Location or site
Temp.10 - oC
Odor
Description of sampling point
Appearance
.'Taste
y4
Sampling Method e°�-''�� � � �'�
Sample Interval
(pump,-bailsri etc.)
"
Field Analysis By:
LABORATORY ANALYSES
8005 310
mg/I
COD Nigh 340
mg/I
COD Low 335
mg/I
Coliform:MF Fecal 31616
/loom]
Coliform:MF Total 31504
/100ml
TOC 680
mg/I
Turbidity 76
NTII
pH 403
(,.� -
units
Alkalinity to pH. 4.5 410
-r
mg/I
Alkalinity to pH 8.3 415.
-s
mg(1
Carbonate 445
i
mg/I
Bicarbonate 440
Q
mg,/I
Arsenic:Total 1002
ug/r
Carbon dioxide 405
mg/I
Chloride 940
m9/I
Chromium:Hex 1032
ug/I
Color:True 80
Pt -Co
Cyanide 720
mg/I
Lab Comments:
GW-54 Revised 7/85
R-emarks
(pumping time, air temp, etc.)
-,;
'�Diss. Solids 70300
mg/l.
Fluoride 951
mg/I
/.Hardness:Total 900
a�
mg/I
j4ardhess (non-carb) 902
1
mg/I
Phenols 32730
,
ug/I
Specific Cond. 95
uM.hos/cm2
Sulfate 94.5
mg/I
Sulfide 745
mg/I
NH3 as N 610
mg/I
TKN as N 625
mg/I
NO2+NO3 as N 630
mg/I
P:Total as P 665
mg/I
Ag = Silver 1077 ug/I
Al - Aluminum 1105 ug/I
Be - Bar! urn '1007 ug/I
Ca - Calcium 916 mg/I
Cd - Cadmium 1027 ug/I
Chromium:Total 1034 ug/I
Cu - Copper 1042 ug/I
Fe - Iron 1045 ug/I
Hg - Mercury 71900 ug/I
K - Potassium 937 mg/I
Mg - Magnesium 927 mg/I
Mn -Manganese 1055 ug/I
Na - Sodium 929 mg/I
NI - Nickel 1067 ug/I
Pb - Lead 1051 ug/I
Se -'Selenium 1147 ug/I
Zn - Zinc 1092 ug/6
For Dissolved Analysis - submit filtered sample and write 'DIS' in block
White copy - Headquarters Pink copy - Region Yellow copy - Lab
Organochlorine Pesticides 'I
Organophosphorus Pesticides
I I Acid. Herdicides I
�+
Base / Neutral Extractable Organic s
Acid Extractable Organics
I I Purgeable Organics (VOA bottle) I
I I 1.2, - Di,bromoethans (EDB) I

Environmental Management Division ,`•, 'f{/ `'
COMPLIANCE MONITORING Groundwater Section
REPORT FORM P.O. Box 27687
Raleigh,N.C.. 27611 ' O
(919)733=5083
Facility Name County nac
Address '-' "`=r �,' Permit Number:
- E u nawer�er ection
N" 'fit' 7`?'r Non -Discharge Asheville Ref?ional Office
Well Location NPDES ISi` ODOPl'
Well Identification Number ?t'-, Well Depth 15 Ft. Water Use
Well Diameter 211 Sample CScreened) Interval 5 Ft. To 15 Ft. Injection Well _
Depth to Water Level 14_,5:� ft. below measuring point. Cbefore sampling') Well Construction
Measuring point is i feet above land surface Other
Gallons of'water pumped bailed before sampling To cr;�ness
Field Analysis: pH !'°`jti Specific Conductance -uMhos Temp. C Odor Appearance
Date Sample Collected 7/8/8 Date Lab Sample Analyzed 7/16/3E
Laboratory Name r.u4rctTen4-:L 7-1i14-1 I 4G
C O-D m g /1
Coliform: MF Fecal /100MI
Coliform. MF Total /100ml
Dissolved Solids: Total mg/I
pH (when analyzed') 5°90 units
TOG mg /I
Chloride
mg/I
Arsenic
-mg/I
Grease and Oils
mg/I
Hardness: Total
m;g/I -
Phenol
rng /I
o r�° Certification No.
NO2 as. N
mg/I
N0 3 as N
mg/I
Phosphorus: Total as P-
mg/I'
Al - Aluminum
mg/I
Ba - Barium u°(Ji3U
mg/I
Ca - Calcium
mg/I
Cd - Cadmium __ _
mg/I
Chromium: Total, --' 0°010
m4/I
Cu - Copper i„ li4_ - mg/I
Fe - Iron mg/I ug/I
Ni Nickel mg/I
Pb 7 Lead <0°101) mg/1
Zn - Zinc mg/I
Pesticides/Herbicides (Specify Compounds)
ug/I
Hg - Mercury -
Sulfate mg/I K - Potassium
Specific Conductance uMhos
Total Ammonia(NH3 t NH 4)- mg/I
TKN as N mg/I
g/I
Mg - Magnesium rng/l
Mn - ,Manganese mg/I
Na - Sodium mg/I
I CERTIFY THAT -THIS REPORT IS TRUE AND ACCURATE.
SIGNATURE~OF PERMITTEE COR. AUTHORIZED AGENT*) . DATE
GW-59 Revised 7/85
ug/I
ug/l
Other CSpecify) ug/I
Re idtle Total Fil-era.ble--?_Jog ug/I
ug/I
ug/I
ug/I
Note:
Values should reflecttota'I concentrations
* See back for instructions
**.Submit blue and green copies to address above.

Environmental Management Division
COMPLIANCE MONITORING
Groundwater 'Section
sl,
REPORT FORM
P.O. Box 27687
C I `
Raleigh,N.C. 27611
[phone]
Cl.
Facility Name Unimin Corporation
County Mitchell
Address PO Box 586
Permit Number: Grrnn .dwafar Section
4sheville Regional Office
Spri r,g Ping, NIf'
?R777
Non -Discharge
Well Location
NPDES NC 000017
Well Identification Number #2
Well Depth 15 Ft.
Water Use
Well Diameter 2" Sample (Screened) Interval 5 Ft. To 15 Ft.
Injection Well
Depth to Water Level 14.53
ft. below measuring point. (before sampling)
Well Construction
Measuring point is 0 feet above land surface
Other.
Gallons of water pumped bailed
before sampling
To dryness
Field Analysis: pH 5.90
Specific Conductance
uMhos Temp.
oC Odor Appearance
Date Sample Collected 7/8/88
Date Lab Sample Analyzed
7/16/88
Laboratory Name Environmental Testing
Inc. Certification No. 40
COD
mg/I
NO2 as N
mg/I Ni - Nickel mg/I
Coliform: MF Fecal
/100m[
NO 3 as N
mg/I Pb - Lead <0.100 mg/I
Coliform: MF Total
/100ml
Phosphorus: Total as P
mg/I Zn - Zinc mg/I
Dissolved Solids: Total
mg/I
Al - Aluminum
mg/I Pesticides/Herbicides (Specify Compounds)
pH (when analyzed) 5'90
units
Ba - Barium 0.080
mg/I ug/I
TOC
mg/I
Ca - Calcium
mg/I ug/I
Chloride
mg/l
Cd - Cadmium _
mg/I ug/1
Arsenic <0.010
mg/I
Chromium: Total <0.4u. mg/I Other (Specify):, ug/I
Grease and Oils
mg/I
Cu - Copper 0-1i
mg/I Residue, -.Total Filterable-29.9 ug/I
Hardness: Total
mg/I
Fe - Irorlr '��'� ,"r:?
mg/I ug/I
Phenol
mg/I
�±; `
Hg -ja'.els
mg/I ug/I
Sulfate
mg/I
K - P"�
um r �.d
m /I u /I
g g
Specific Conductance
uMhos
Mg -lum
mg/I .ug/I
" `�
Total Ammonia(NH3 t NH 4)
mg/I
Mn - Mango`.
.
mg/I
Note:
TKN N
Na - Sodium ` W
as
mg/I
mg/I
Values should reflect total concentrations
I CERTIF IS
FIT IS TRUE
AND ACCURATE.
#See back for instructions
i
## Submit blue and green copies to address above.
SIGN RE OF PERMITTEE
(OR. AUTHORIZED AGENT#) DATE
GW-59 Revised 7/85

r
COMPLIANCE MONITORING
REPORT FORM
Facility Name UNMAN Corporation
Well Location
Environmental Management Division
Groundwater Section
P.O. Box 27687
Raleigh,N.C. 27611
[phone]
Well Identification Number #2 Well Depth A5 Ft.
Well Diameter 2" Sample (Screened) Interval _ 0,20 Ft. To 25 Ft.
Depth to Water Level 14.53 ft. below measuring point. (before sampling)
Measuring point is 0 feet above land surface
Gallons of water pumped bailed before sampling To dryness
County Mitchell
Permit Number:
Non -Discharge __ - - 1
NPDES NC 0000175
Water Use
Injection Well
Well Construction
Other.
Field Analysis: pH F, gFi Specific Conductance uMhos Temp. o C Odor Appearance
Date Sample Collected 3/10/88 Date Lab Sample Analyzed 3/18/88
Laboratory Name Enviromental Testing Inc. Certification No. 40
COD
Cofiform: MF Fecal
- mg/I
/l00ml
Coliform: MF Total
/loom]
Dissolved Solids: Total 19.1
mg/I
pH (when analyzed) T units
TOC
mg/I
Chloride
mg/I
Arsenic <0.010
mg/I
Grease and Oils
mg/I
Hardness: Total
Phenol
mg/I
mg/I
NO2 as N
NO 3 as N.
Phosphorus: Total as P
mg/I Ni - Nickel
mg/I
mg/I
Al - Aluminum mg/I
Ba - Barium <0.mo mg/I
Ca - Calcium.
Cd - Cadmium
mg/I
mg/I
Chromium: Total <0.010 mg/I
Cu - Copper <0.010 mg/I
Fe - Iron mg/I
Hg - Mercury
/I
Sulfate
mg/I
K - Potassium
mg/I
Specific Conductance
uMhos
Mg - Magnesium
mg/I
Total Ammonia(NH3 t NH 4)
mg/I
Mn - Manganese
mg/I
TKN as N
mg/l
Na - Sodium
mg/I
CERTIFY TH7REPORT TRUE AND ACCURATE.
SIGNATUR OF PERMITTEE (OR AUTHORIZED AGENT#) DATE
GW-59 Revised 7/85
mg/I
Pb - Lead <0 050 mg/I
Zn - Zinc mg/I
Pesticides/Herbicides (Specify Compounds)
Other (Specify)
ug/1
ug/I
ug/1
ug/I
,ug/I
!`1
ug/I
14
GR®U4�D"',1T n _�i��v
Note: �� �n
n.Ld �Llly Y��
Values should reflect total concentrations
# See back for instructions
## Submit blue and green copies to address above.

Environmental Management Division
COMPLIANCE MONITORING Groundwater Section — -�
REPORT FORM P.O. Box 27687 "`
I
RA PHI N (. 77R i i lU3g
s
Facility Name
Address
Well Location
Well Identification Number "111t Well Depth _Ft.
Well Diameter Z !` Sample (Screened) Interval 20 Ft. To 2-S' Ft.
Depth to 'Water Level
ft. below measuring point. (before sampling)
�j
County � I I_P� ► ► Isq,tinn
Permit Number: Asheville Regional Office
Non -Discharge
NPDES A).6_DD0Z) I h_
Water Use
Injection Well D
Well Construction
L
Measuring point is
feet above land surface 7Z_ �`�
Other - J11
Gallons of water pumped
bailed before sampling
Field Analysis: pH S 42 Specific Conductance uMhos Temp.
° C
Appearance
Date Sample Collected
2 - 2 - rf�/ Date Lab Sample Analyzed
rOdor
Laboratory Name aA)Z
M In) � p . Certification No'. IS-2—
COD
mg/I NO2 as N
mg/I
Ni - Nickel mg/I
Coliform: MF Fecal
/100m1 NO 3 as N
mg/I
Pb - Lead mg/l
Coliform: MF Total
/100MI Phosphorus: Total as P
mg/1
Zn - Zinc mg/I
Dissolved Solids: Total
mg/I Al - Aluminum
mg/I
Pesticides/Herbicides (Specify Compounds)
PH (when analyzed) < units
TOC mg/I
Chloride
Arsenic
mg/I
mg/I
Grease and Oils mg/I
Hardness: Total mg/I
Phenol mg/I
Sulfate
Specific Conductance
Ba - Barium
mg/.I
Ca - Calcium
mg/I
Cd - Cadmium_
mg/I
Chromium: Total mg/I Other (Specify)
Cu - Copper mg/I
Fe - Iron mg/I
Hg - Mercury mg/I
- mg/I K - Potassium mg/I
uMhos Mg - Magnesium mg/I
Total Ammonia(NH3 t NH 4) mg/I Mn - Manganese mg/I
TKN as N mg/I Na - Sodium mg/I
CERTIFY T IS REPO TRUE AND ACCURATE.
SIGNATUR F PERMITTEE COR AUTHORIZED AGENT*) DATE
GW-59 Revised 7/K
ug/1
ug/I
ug/1
ug/I
ug/I
ug/I
ug/I
ug/I
ug/I
Note:
Values should reflect total concentrations
See back for instructions
** Submit blue and green copies to address above.

rOMPLIANCE MONITORING
REPORT FORM
Facility Name
Address
Well Location _
Well Identificati
Well Diameter _
UNIMIN Corporation
P. 0. Box 588
Spruce Pine, N. C.
Environmental Management Division
Groundwater Section
P.O. Box 27687
Raleigh,N.C. 27611
[phone] ` . A : ;r )
County Mitchell -
Permit Number: P Groundwater Section
G
rtegbarlal Office
Non -Discharge g
NPDES NC0000175
Number
#2
Well Depth
25'
Ft.
211
Sample (Screened) Interval
20' Ft.
To 25
Ft.
Depth to Water Level 15.12 ft. below measuring point. (before sampling)
Measuring point is feet above land surface
Gallons of" water pumped bailed before sampling
Field Analysis: pH 4.75 Specific Conductance
Date Sample Collected 11-05-87
Laboratory Name Environmental Testing, Inc.
i p
E
Water Use
Injection Well
Well Construction 60-0018-WM-0004
Other = I S I -V
uMhos Temp. o C Odor Appearance
Date Lab Sample Analyzed 11-06-87 - 11-19-87
Certification No. 40
COD mg/1 NO2 as N mg/I
Coliform: MF Fecal /100ml NO3 as N mg/I
Coliform: MF Total /100ml Phosphorus: Total as P mg%l
Dissolved Solids: Total 50.0 mg/I Al - Aluminum mg/I
pH (when analyzed) 4.75 units Ba - Barium <•050 mg/I
TOC mg/I Ca - Calcium mg/I
Chloride mg/I Cd - Cadmium _ mg/I
Arsenic <•010 mg/I Chromium: Total <•010 mg/I
Grease and Oils mg/I Cu- Copper mg/I
Hardness: Total mg/I Fe - Iron mg/I
Phenol mg/I Hg - Mercury mg/I
Sulfate mg/I K - Potassium mg/I
Specific Conductance uMhos Mg - Magnesium mg/I
Total Ammonia(NH3 t NH 4) mg/I Mn - Manganese mg/I
TKN as N rng/I Na - Sodium mg/I
I CERTI AT THIS ORT IS TRUE AND ACCURATE.
SIGNAfURE OF PERMITTEE (OR AUTHORIZED AGENT#) A
GW-59 Revised 7/85
Ni - Nickel
mg/I
Pb - Lead <.050 mg/I
Zn - Zinc mg/I
Pesticides/Herbicides (Specify Compounds)
Other (Specify)
ug/I
ug/I
ug/1
ug/I
ug/I
1
fi
- ug/I ;1, r ug/I
_ ug/I
.ug/I
Note:
RALEIG-H, NC
Values should reflect total concentrations
# See back for instructions
## Submit blue and green copies to address above.

Environmental Management Division
OMPLIANCE MONITORING Groundwater Section
REPORT FORM _ P.O. Box 27687
Raleigh,N.C. 27611
[phone]
Facility Name UNIMIN Corporation
Address P • 0. Box 588
Spruce Pine. N. C. 28777
Well Location
County Kitchell
Permit Number:
Non -Discharge
NPDES NC0000175
Well Identificati&n Number
#2 Well Depth 25' Ft.
Water Use
Well Diameter 211
Sample (Screened) Interval 20' Ft. To 25' Ft.
Injection Well
Depth to Water Level
15.12 ft. below measuring point. (before sampling)
Well Construction 60-0018-WIC-0004
Measuring point is
feet above land surface.
Other .
Gallons of water pumped
bailed before sampling
Field Analysis: pH 4.75 Specific Conductance uMhos Temp.
o C Odor Appearance
Date Sample Collected
11-05-87 Date Lab Sample Analyzed
11-06-87 - 11-19-87
Laboratory Name __ Environmental Testing, Inc. Certification No. 40
COD
mg/I NO2 as N
mg/I Ni- - Nickel
mg/I
Coliform: MF Fecal
/100m1 NO3 as N
mg/I Pb - Lead <.050
mg/f
Coliform: MF Total
/100ml Phosphorus: Total as P
mg/I Zn - Zinc
mg/l
Dissolved Solids: Total
50.0 mg/I AI - Aluminum
mg/I Pesticides/Herbicides (Specify Compounds)
pH (when analyzed)
4.75 units Ba - Barium <.050
mg/I
ug/I
TOC
mg/I Ca - Calcium
mg/1
ug/I
Chloride
mg/I Cd - Cadmium
mg/I
ug/1
Arsenic <.010
mg/I Chromium: Total <.010
mg/I Other (Specify)
ug/I
Grease and Oils
mg/I Cu - Copper
mg/I
ug/I
Hardness: Total
Phenol
mg/I
mg/I
Sulfate mg/I
Specific Conductance uMhos.
Fe - Iron mg/I
Hg - Mercury mg/l
K - Potassium mg/I
Mg - Magnesium mg/I
Total Ammonia(NH3 t NH 4) mg/I Mn - Manganese mg/I
TKN as N mg/I Na - Sodium mg/I
I CERTI AT THIS ORT IS TRUE AND ACCURATE.
SIGNA E OF PERMITTEE (OR. AUTHORIZED AGENT*) A
I�i
GW-59 Revised 7/85
ug/I
ug/I
ug/I
.ug/I
Note:
Values should reflect total concentrations
* See back for instructions
**Submit blue and green copies to address above.

J,i
o'
COUNTY N.C. DEPARTMENT OF NATURAL. RESOURCES
QUAD NO y-` r''- SERIAL NO." & COMMUNITY DEVELOPMENT
LAT. -> } r i LONG. DEM
Report to l An0,� FRO, M'RO, RRO, WaRO, WiRO,
WSRO, Kinston FO Other.
Shipped by: Bus, Courier, Other�FX%7
COLL;ECTOR(S): X , i_'� r. DATE -
FIELD ANALYSES
pH400 - Spec. Cond,94 at 250C
Temp.1.0, - oC Odor
Appearance - - Taste _
Field Analysis By:
LABORATORY- ANALYSES
BOD.5 310
mg/I...
COD Nigh 340:
mg/1
COD Low 335
mg/1
Coli'form:MF Fecal. 316�1.6
/looml
Coliform:MF Total 31504
/loom.[
TOG. 680
mg/I
Turbidity '76
NTU
pH 4.03
units
✓`
Alkalinity to pH 4.5 410
�'*�
mg/I
�1",Alkalinity'to
pH 8.3 415
"`"
mg/I
�i
Carbonate 445
mg/I
Bicarbonate 440
.�
mg/.I
Arsenic:Total, 1002
ug/1
Carbon dioxide. 405
mg/1
Chloride. 940 Z_ �
mg/I
Chromium:Hex 1032
ug/1
Color:True 80
Pt -Co
Cyanide 720
mg/I
Lab Comments:
GROUNDWATER FIELD/LAB FORM
SAMPLE PRIORITY
0" ROUTINE ❑ EMERGENCY
LAB NUMBER 8
DATE RECEIVED Time
i,
Rec'd by: From: Bus -Courier
Other
DATA ENTRY BY: ^' CK:
DATE REPORTED: _
TIME - PURPOSE: BASELINE, COMPLAINTcc-OMPLIA�N,CE�, LUST, OTHER
(circle one_j
Owner %%✓rs t";; t o t '��i `j `.
Locati on or site l!tr : ;e /! s' 'F ✓� /6
Description of sampling point'
Sampling Method ✓I/t,7f r` c ;r
(pump, bailer,
Remark's
uf'
Diss. Solids 70300
'
mg/1
Fluoride 951 _
mg/1
v
'Hardness:Total 900
mg/1
Hardness (non-carb) 902
,l.� 'i
mg/l
Phenols 32730
ug/I
Specific Cond. 95
uMhos/cm2
Sulfate 945
mg/I -
Sulfide 745
mg/I
NH3 as N 610
mg/I
TK.N as N 625
mg/1
'NO2 +NO3 as N 630
mg/I
P:Total as P 665
mg/I,
I A "
Sample Interval C, "U
Ag - Silver 1077 ug/l
AI - Aluminum 1105 ug/1'
Be - Barium'1007 ug/l
Ca - Calcium 916 mg/I
Cd - Cadmium 1027 ug/I
Chromium:Total 1034 ug/I
Cu - Copper 1042 ug/I
Fe - Iron '1045 ug/I
H.g - Mercury 719.00 ug/I
K - Potassium 93T mg/I
Mg - Magnesium 927 mg/I
Mn - Manganese 10.55 ug/I
Na - Sodium 929 mg/I
Ni--'Nickel 1.067 ug/i
Pb - Lead 1051 _ - ug/I
Se - Selenium 1147 ug/I''.
Zen - Zinc 1092 ug/I
GW-54 Revised 7/85 For Dissolved Analysis - submit filtered sample and write 'DIS' in block
White copy - Headquarters Pink copy - Region Yellow copy - Lab
r temp, etc.
Organoch'I'orine Pesticides
Organophosphorus Pesticides
I Acid Herdicides I
J _ I Base / Neutral Extractable Organics
Acid Extractable Organics
I I Purgeable Organics (VOA bottle) I
I I 1,2 - Di'bromoethane (EDB) I

COUNTY " . ' `" N.C.
QUAD NO. �~ �' / SERIAL NO.
LAT. LONG.
Report to "ARO "FRO, MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO Other
Shipped by: Bus�Courie.r, Other
COLLECTOR(S): 1 .f s:£/ti •. DATE
FIELD ANALYSES
pH400 Spec-. Cond.94at250C
Temp.1'0 oC Odor
Appearance Taste
:PARTMENT OF NATURAL. RESOUI i LAB NUMBER 8
& COMMUNITY DEVELOPMENT DATE RECEIVED i Time
DE'NI 01)Reed by:l" From: Bus-Courie'e
GROUNDWATER FIELD/LAB FORMOther
('SAMPLE PRIORITY ,1 1' ;�n DATA ENTRY BY: �. t ! CK: -
l/ ROUTINE EMERGENCY ', �i I J' DATE REPORTED:
TIME PURPOSE: BASELINE, COMPLAINT„ COMPLIANCE; LUST, OTHER
(circle ones''--
rlwnar ./"., I�`- r
Location or site f „
>✓
Description of sampling poi nt,
Sampling Method %�t� �''I Sample Interval
(pump, bailer, etc.)
Field ,Analysis By: Remarks
LABORATORY ANALYSES
BOD5 310 mg/I
COD High'340 mg/l.
COD tow 335 mg/l
Collform:MF Fecal 31616 /looml
Col[form:MF Total 31504 /loom[
TOC 680 mg/I
Turbidity 76 NTU
pH 403 units
Alkalinity to pH 4.5' 410 mg/1
Alkalinity to pH 8.3 415 mg/I
Carbonate 445 mg/I
Bicarbonate 440 mg/I
7;­7
9
Arsenic:Total 1002 g/I
Carbon dioxide 405 mg/l
Chloride 940 mg/I
Chromlum:Hex 1032 ug/I
Color:True 80 Pt -Co
Cyanide 720 mg/I
Diss. Solids 70300
_ mg/(
tt
Fluoride 951 �-� v t 1
mg/l
H a rdness:Tota 1900
mg/1
Hardness (non-carb) 902
mg/I
Phenols 32730
ug/l
Specific Cond. 95
uMhos/cm2
Sulfate 945 4mg/1-
Sulfide 745
mg/1
NH3 as'N 610
mg/l
TKN as N 625
mg/1
NO2 i NO3 as N 630
mg/1
P:Total as P 665
mg/1
Ag - Silver 1077
ugh
AI - Aluminum 1105
ug/1
611-1
Be - Barium'1007
4�J9
ug/I
Ca - Calcium 916
'mg/1
Cd Cadmium 1027
ug/l
5
Chromium:Total 1034.t."�
ug/I
Cu - Copper 1042
ug/I
Fe - Iron 1045
ug/I
Hg - Mercury 71900
ug/1
K - Potassium. 937
mg/I
Mg - Magnesium 927
mg/I.
Mn - Manganese 1055
ug/1
Na - Sodium 929
mg/1
Ni - Nickel 1067
ug/I'
Pb - Lead 1051
< (,)
ug/I
Se - Selenium 1147
ug/1
Zn - Zinc 1092
ug/l.
mp,
Organochlorine Pesticides
Organophosphorus Pesticides
Acid Herdicides
Base / Neutral .Extractable Organics
Acid Extractable Organics
Purgeabie Organics (voA bottle)
1.2 - Dibromoethane (EDB)
r E C E IV E
iJaV - CI7
/
Groundwater Section
Lab Comments:'- -t' -C{ - e - A4hPuilla Roninnal (]ffirP
GW-54 Revised 7/85 For Dissolved Analysis submit filtered sample and write 'DIS' in block
White copy - Headquarters Pink copy - Region Yellow copy - Lab

PPLIANCE MONITORING
REPORT FORM
Facility Name
Address
UNIKIN Corporation
P. 0. Box 588
Environmental Management Division
Groundwater Section
P.O. Box 27687
Raleigh,N.C. 27611
[phone]
Spruce Pine, N. C. 28777
Well Location Hwy. 226 North, Spruce Pine, N. C.
Well Identification Number Well # 2 Well D th 25 Ft.
Well Diameter 2 in. Sample (Screened) IntervFt. TQORUWFt.
Depth to Water Level 12 ft. 6 in. ft. below measuring point. (before sampling)
Measuring point is U feet above land surface
Gallons of water pumped bailed before sampling
County Kitchell
Permit Number: NC0000175
f
Non -Discharge
_ S
NPDES
Water Use
Injection Well
Well Construction �er�
Other .
Field Analysis: pH 5.05 Specific Conductance uMhos Temp.
o C
Odor Appearance
Date Sample Collected July 28, 1987
Date Lab Sample Analyzed
August
3, 1987
Laboratory Name Environmental Testing,
Inc. Certification No'. 40
COD mg/I
NO2 as N
mg/I
Ni - Nickel
mg/I
Coliform: MF Fecal /100ml
NO3 as N
mg/I
Pb - Lead < 0.050
mg/l
Coliform: MF Total /100ml
Phosphorus: Total as P
mg/I
Zn - Zinc
mg/I
Dissolved Solids: Total 56.2 mg/I
Al - Aluminum
mg/1
Pesticides/Herbicides. (Specify Compounds)
pH (when analyzed) units
Ba - Barium 0.095
mg/l
ug/1
TOC mg/I
Ca - Calcium
mg/I
ug/I
Chloride
mg/I
Arsenic < 0.010
mg/I
Grease and Oils
mg/I
Hardness: Total
mg/I
Phenol
mg/I
Sulfate
mg /I
Specific Conductance
uMhos
Cd - Cadmium
mg/I
Chromium: Total 0.018 mg/I
Cu - Copper mg/I
Fe - Iron
mg/I
Hg - Mercury mg/I
K - Potassium mg/I
Mg - Magnesium
mg/I
Total Ammonia(NH3 t NH 4) mg/I Mn - Manganese mg/I
TKN as N mg/I Na - Sodium mg/I
I CER F THAT THIS FIT IS TRUE AND ACCURATE.
SIGN E OF PERMITTEE (OR. AUTHORIZED AGENT*) DATE
GW-59 Revised 7/85
ug/1
Other (Specify) ug/I
f r; - TMOT55Aug/
{{ J
n E ug/I
ug/I
ug/I s
it11L>_lv;i,
Note:
Values should reflect total concentrations
# See back for instructions
>�* Submit blue and green copies to address above.

COMPLIANCE MONITORING
REPORT FORM
Facility Name
Address
Environmental Management Division
Groundwater Section
P.O. Box 27687
Raleigh,N.C. 27611
County '
Permit Numb r:
Well Location ee�1/,'�?!>.©// l_i17�s�%lc.
i
Well Identification Number LlJcDZZ2- Well Depth Ft.
Well Diameter A Sample (Screened) Interval 2& Ft. To_o�3' Ft.
Depth to Water Level L3, ft. below measuring point. (before sampling)
Non -Discharge
NPDES Z& 400121.7,r
Water Use
Injection Well
Well Construction--���re�-rv�
Measuring point is feet above land surface
Other .
Gallons of water pumped bailed before
sampling e__`�
Field Analysis: pH . 9 3 Specific
Conductance
uMhos Temp.
o C
Odor Appearance
Date Sample Collected 3—
-- 497
Date Lab Sam le Analyzed
-Z
3- Z 4r, 3 -3U vt 3— 3/nf
Laboratory Name Lim' �fdd
P r
�e'
4k Certification
No. e 77� f
>1` •��,2g
COD
mg/I
NO2 as N
mg/I
Ni - Nickel
mg/I
Coliform: MF Fecal
/100m1
NO3 as N
mg/I
Pb - Lead
_mg/I
Coliform: MF Total
/100ml
Phosphorus: Total
as P
mg/I
Zn - Zinc
mg/I
Dissolved Solids: Total
mg/I
Al - Aluminum
mg/I
Pesticides/Herbicides (Specify Compounds)
PH (when analyzed)
units
Ba - Barium
-
mg/I
ug/I
TOC
mg/I
Ca - Calcium
mg/I
ug/I
Chloride
mg/I
Cd - Cadmium
mg/I
ug/l
Arsenic GD 1,4
mg/I
Chromium: Total
mg/I
Other (Specify)
ug/I
Grease and Oils
mg/I
Cu - Copper
mg/I
ug/I
Hardness: Total
mg/I
Fe - Iron
mg/I
ug/I
Phenol
mg/I
Hg - Mercury
mg/I
ug/I
Sulfate
mg/I
K - Potassium
mg/I
ug/I
Specific Conductance
uMhos
Mg - Magnesium
mg/I
.ug/I
Total Ammonia(NH3 t NH 4)
mg/I
Mn - Manganese
mg/I
Note:
TKN as N
mg/I
Na - Sodium
mg/I
Values should reflect total concentrations
I CERTIFY AT THIS R
FIT IS TRUE AND ACCURATE.
# See back for instructions
rj/��
*# Submit blue and green copies to address above.
SIGN A E OF PERMITTEE
(OR UTHORIZED
AGENT*)
DATE
GW-59 Revised 7/85

COMPLIANCE MONITORING
REPORT FORM
Facility Name
Address
1
L-
Environmental Management Division
Groundwater Section
P.O. Box 27687
Raleigh,N.C. 27611
, (919),733-5083
oun y
Permit Number:
Non -Discharge
Well Location
N P D E S" /: "f2
Well Identification Number
Well Depth Ft.
Water Use
Well Diameter
Sample (Screened) Interval Ft. To Ft.
Injection Well
Depth to Water Level - ft. below measuring point. (before sampling)
Well Construction
Measuring point is
feet above landsurface
Other .
Gallons of" water pumped
bailed before sampling
Field Analysis: pH
Specific Conductance uMhos Temp.
o C Odor Appearance
Date Sample Collected
- �Date Lab Sample Analyzed
Laboratory Name
-'.`, -<< �`,- r, l i<-- = Certification
No. -
COD
mg/I NO2 as N
mg/l,, Ni - Nickel
mg/1
Coliform: MF Fecal
/100ml NO3 as N
mg/I Pb - Lead
mg/1
Coliform: MF Total
/100ml Phosphorus: Total as P
mg/I Zn - Zinc
mg/I
Dissolved Solids: Total
mg/1 Al - Aluminum
mg/I Pesticides/Herbicides (Specify Compounds)
pH (when analyzed)
units Ba - Barium
mg/I:
ug/I
TOC
mg/I Ca - Calcium
mg/I
ug/I
Chloride
mg/I Cd - Cadmium
mg/I
ug/1
Arsenic
mg/I Chromium: Total
mg/I: Other (Specify)
ug/I
Grease and Oils
mg/I Cu- Copper
m g A =
ug/I
Hardness: Total
mg/I Fe - Iron
mg/I
ug/l
Phenol
mg/I Hg - Mercury
rng/I
ug/I
Sulfate
mg/I K - Potassium
mg/I -
ug/I
Specific Conductance
uMhos Mg - Magnesium
mg/I
,ug/I
Total Ammonia(NH3 t NH
4) mg/I Mn - Manganese
mg/I
Note:
TKN as N
, rng/I Na - Sodium
mg/I
Values should reflect total concentrations
I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE.
-
-
# See back for instructions
Submit blue and green copies to address
above.
SIGNATURE OF PERMITTEE COR. AUTHORIZED AGENT*) DATE
GW-59 Revised 7/85

COUNTY f N.C. PARTMENT OF NATURAL RESOW
QUAD NO. ` ` SERI:AL NO. & COMMUNITY DEVELOPMENT
LAT. _; LONG. DEM
GROUNDWATER FIELD/LAB FORM
Report to: ARO, FRO, MRO, RRO, WaRO, W'iRO,
SAMPLE PRIORITY
WSRO, Kinston FO Other �
❑, "ROUTINE ❑ EMERGENCY
Shipped by: Bus,. Co-urier;,,Other
COLLECTOR(S): < <j_,-f , DATE TIME
FIELD ANALYSES
PH400 Spec. Cond.94 at 250C
j Temp.10 oC Odor
Appearance Taste
Field Analysis By:
LABORATORY ANALYSES
BOD5 310 mg/1
COD High, 340 mg/1
COD Low 335 mg/I
Coliform:MF Fecal 31616 /loom[
Coliform:MF Total 31504 /100ml
TOC 68o mg/I
Turbidity 76 NTIJ
pH 403 units
Alkalinity to pH 4.5 410 mg/I
Alkalinity to pH 8.3 415 mg/1
Carbonate 445 mg/I
Bicarbonate 440 mg/I
/is
Arseni.c:Total 1002 / t ug/f
Carbon dioxide 405mg/I
Chloride 940 mg/I
Chromium:Hex 1032 ug/I
Color:True 60 Pt -Co
Cyanide 720 mg/I
Lab Comments:
Owner
Location or site
LAB NUMBER 8 - 1
DATE RECEIV'E0-�`?ti/2 -sf) Time `
7
0 Rec'd by: f 11)r^)r7 {/ ) From: Bus -Courier
Other
DATA ENTRY BY:.: CK:
DATE REPORTED:v
PURPOSE: BASELINE, COMP'LA,INT,4COMPLIANCE;,�LUST, OTHER
Description of sampling point ✓ - {
Sampling Method - ' - r"., !! Sample Interval
(pump, bailer, etc'.)
Remarks
(pumping time, air temp, etc.)
Diss. Solids 70300 mg/L
"
Fluoride 951 ( j(_i mg/I
Hardness:Total 900 -� mg/I
Hardness (non-carb) 902 mg/I
Phenols 32730 ug/I
Specific Cond. 95 uMh'os/cm2
Sulfate 945 mg/I
Sulfide 745 mg/1
NHg. as N 610 mg/I
TKN as N 625 mg/I
NO2+NO3 as N 630 mg/I
P:Total as P 665 mg/I
Ag -Silver 1077
ug/I
Al - Aluminum 1105
ug/I
_
Be - Barium *1007
%'t! } ug/1
Ca - Calcium 916
mg/I
Cd - Cadmium 1027
,r
ug/I
i•l
Chroml'um:Total1034
.� =i ate'
ug/1
Cu - Copper 1042
S
ug/I
Fe - Iron 1045
ug/I
Hg - Mercury 71900
ug/I
K - Potassium 937
mg/I
Mg - Magnesium 927
mg/I
Mn - Manganese 1055
ug/I
Na - Sodium 929
mg/I
Ni - Nickel 1067
�. j
ug/I
Pb - Lead 1051
4 �//
ug/I
Se - Selenium 1.147
,...
ug/I
Zn Zinc 1092
ug/I
- - r
GW-54 Revised 7/85 For Dissolved Analysis - submit filtered sample and write 'DIS' in block
White copy Headquarters Pink copy Region Yellow copy - Lab
Organochlorine Pesticides
Organophosphorus Pesticides
Acid Herd'icides
Base / Neutral Extractable Organics
Acid Extractable Organics
Purgeable Organics .(VOA bottle)
1.2 - Dibrom.oethane (EDB:)
p Y %e E C E I _ i
87
n _ v
Groundwater Section
Asheville Regional Office t

COUNTY
N.C.
DEPARTMENT 'OF
NATURAL RESOURCES LAB NUMBER $
1 `°
QUAD NO. -
SERIAL NO.,,",'
& COMMUNITY
DEVELOPMENT
DATE RECEIVED �"� Time
LAT.
LONG. r
DEM
Rec'd by:
0
From: Bus -Courier
GROUNDWATER
FIELD/LAB FORM
Other
Report to:,ARO;
FRO, MRO, RRO, WaRO, WiRO,
SAMPLE
PRIORITY
DATA ENTRY BY:
CK:
WSRO, Kinston
FO Other
El ROUTINE
Shipped by: Bus, Courie Other
EMERGENCY
DATE REPORTED:
°
COLLECTOR(S):
•_',,:.7 DATE -
TIME
PURPOSE: BASELINE,
COMPPLAINT, C�OMPLIA CN LUST,
OTHER
(circle one) --..-,-
FIELD ANALYSES
PH400 Spec. Cond.94 at 250C
Temp.10 oC Odor
Appearance Taste
Field Analysis By:
LABORATORY ANALYSES
BOD5 310
mg/I
COD High 340
mg/I
COD Low 335
mg/1
Coliform:MF Fecal 31616
/100m1
Coliform:MF Total 31504
/100ml
TOC 680
mg/I.
Turbidity 76
NTU
pH 403 -
u n I is
Alkalinity to pH. 4.5 410
.Jl
mg/I
Alkalinity to pH 8.3 415
mg/I
Carbonate 44.5 -
mg/I
Bicarbonate 44.0
mg/I
Arsenic:Total 1002
ug/I
Carbon dioxide 405
mg/I
' Chloride 940
mg/I
Chromium:Hex 1032
ug/I
Color:True 80
Pt -co
Cyanide 720
mg/I
Lab Comments,:
Owner
Location or site
i
Description of sampling point
Sampling Method Sample Interval _71 11/
(pump; bailer, etc.)
Remarks
'IDiss. Solids 70300 mg/l.
Fluoride 951 mg/I
Hardness:Total 900 mg/I
!Hardness (non-carb) 902. + mg/I
Phenols 32730 ug/I
Specific Cond. 95 uMhos/cm2
Sulfate 945 mg/I
Sulfide 745 mg/1
NH3 as N 610 mg/I
TKN as N 625 mg/I
NO2 + NO3 as N 630 mg/I
P:Total as P 665 mg/I
,­ r
Limping time; air temp, etc
Ag - Silver 1077 ug/I
AI - Aluminum 1105 ug/l
Ba - Bari um'1007 ug/I
Ca -.Calcium 916 mg/l
Cd - Cadmium 1027 ug/l
Chromium:Total 1034 ug/I
Cu - Copper 1042 ug/I
Fe - Iron 1045. ug/I
Hg - Mercury 71900 ug/l
K - Potassium 937 mg/I
Mg - Magnesium 927 mg/I
Mn - Manganese 1055. ug/I
Na - Sodium 929 mg/I
Ni - Nickel 1067 - ug/I
Pb - Lead 1051 ug/I
Se - Selenium. 114.7 ug/.I
Zn _ Zinc 1092 ug/l.
GW-54 Revised 7/85 For Dissolved Analysis - submit filtered sample and write 'DIS' in block
White copy - Headquarters Pink copy - Region Yellow copy - Lab
Organochlorine Pesticides
Crganophosphorus. Pesticides
Acid Herdicides
Base / Neutral Extractable Organics
Acid Extractable. Organics
Purgeable. Organics (VOA bottle)
1..,2 - D.ibromoethane (E.DE),

COMPLIANCE MONITORING
REPORT FORM
Environmental Management Division
Groundwater Section
P.O. Box 27687
Raleigh,N.C. 27611
[phone]
Facility Name Unimin Corp. Quartz Operations
Address P. 0. Box 588
Spruce Pine, NC 28777
Well Location Off NC226 Mitchell Counts
Well Identification Number Well #2 Well Depth 25 Ft.
Well Diameter 211 Sample (Screened) Interval 20 Ft. To 25 Ft.
Depth to Water Level '115 ft. below measuring point. (before sampling)
County Mi tchel 1
Permit Number:
Non -Discharge
NPDE I NC 0000175
Water Use
Injection Well
Well Construction 60-0018-WM-0004
Measuring point is feet above land surface Other .
Gallons of water pumped bailed before sampling 8
Field Analysis: pH 5 A Specific Conductance uMhos Temp. o C Odor Appearance
Date Sample Collected Nov. 25, 1986 .Date Lab Sample Analyzed 12/05, 12/15, and 12/18/86
Laboratory Name CompuChem, Research Triangle Park Certification No. NC # 37723, EPA # NCO28
COD
Coliform: MF Fecal
Coliform: MF Total
- mg/I
/ 100ml
1100ml
Dissolved Solids: Total o • mg/I
pH (wher, analyzed) S• ? units
TOC mg/I
NO2 as N
mg/I
NO 3 as N
mg/1
Phosphorus: Total as P
mg/I
AI - Aluminum
mg/I
$ Barium •
Ca - Calcium
ma/I
Chloride
mg/I
Cd - Cadmium_
mg/I
Arsenic 3 an
mg/I
0-00
_: Tote I �, lJ
mg/I
Grease and Oils
mg/I
Cu - Copper
mg/I
Hardness: Total
Phenol
mg/I
mg/I
Sulfate mg/I
Specific Conductance uMhos
Total Ammonia(NH3 t NH 4) mg/I
TKN as N . mg/I
Fe - Iron
Hg - Mercury
K - Potassium_
Mg - Magnesium
Mn - Manganese
Na - Sodium
I CERTIF AT THI EPORT IS TRUE AND ACCURATE.
SIGNAT RE OF PERMITTEE (OR AUTHORIZED AGENT*) 4De
GW-59 Revised 7/85
g/I
g/I
.mg/I
Ni - Nickel mg/I
Pb -Lead �� ..- n-
Zn - Zinc mg/l
Pesticides/Herbicides (Specify Compounds)
ug/I
ug/I
ug/1
Other (Specify) ug/I
V.�
i ug/I
_ ug/I
E G 1
ug/I
_ 0Q ug/I
mg/I ug/I
Groundwatcr aeL;uviI
mg/I Asheville Redior,.,l ,itl, e f
Note: •• �
mg/I
Values Auld reflect total concentrations
* See back for instructions
** Submit blue and green copies to address above.

COUNTY
QUAD NO. SERIAL ND.�f-}
LAT. LONG
Report to-r" ARO,-FRO, MRO, R_RO, W'aRO, WiRO;
N.C. DEPARTMENT OF NATURAL_ RESOURCES' LAB NUMBER $
& COMMUNITY DEVELOPMENT DATE RECEIVED "' Time
WSRO', Kinston. FO Other
Shipped by: Bus-"Covrier-_)Other
COLLECTOR(S):l/ysNtt'Crr`cY_14/55°DATE
r � r
FIELD ANALYSES
PH400 fSpec. Cond.94 at 250C
Temp ,) oC Odor
Appearance Taste
Field' Analysis By:
LABORATORY ANALYSES
BOD5 310 mg/I
COD High 340 - mg/l
COD Low 335 mg/I
Coliform:MF Fecal 3161.6' %100ml
Coliiorm:MF Total 31.504 /100ml
TOC 680 mg/l
Turbidity 76 NTU
pH 403 [' units
Alkalinity to pH 4.5 410 mg/I
Alkalinity to pH 8.3 415 mg/I
Carbonate 445 mg/1
Bicarbonate 440 mg/l
Arsenic:Total 1002 'ug/1
Carbon dioxide 405 mg/I
Chloride 940 mg/l
Chromium:Hex. 1032 ug/1
Colbr:True 80. Pt -Co
Cyanide 720 mg/1
Lab Comments:
Owner
r'' � �
DEM
Rec''d by: From: Bus -Courier
U
GROUNDWATER
'FIELD/LAB FORM
Other
SAMPLE
PRIORITY
DATA ENTRY BY: '' CK:
l ROUTINE
❑ EMERGENCY
DATE REPORTED: �
TIME
PURPOSE: BASELINE,
COMPLAIN( COMPLIANCE, LUST, OTHER
(circle untO-"`"—�y
Location or site
Description of sampling point
Sampling Method
r /V
(pump, bailer, etc'.)
Sample Interval, /F
Remarks
(pumping time, air temp, etc'.)' _
'Diss. Solids i0300' fys''r mg/I.
Fluoride 951 mg/1
Hardness:Total 900 mg/1
Hardness (non-carb) 902 mg/l
Phenols 32730 ug/I
Specific Cond. 95 uMhos/cm2
" 'Sulfate 945 mg/li
Sulfide 745 mg/1
NH3 as N 6'10 mg/1
TKN as N 625 m8/l
'NO2 s N.03 as N 630 mg/1
P:Totai as P 665 mg/I
Ag -:Silver 1077 - - ug/1
Al - Aluminum 1105 ug/1
Be - Barium'100.7 ug/I
Ca = Calcium 91.6 mg/I
Cd - Cadmium 1.027 ug/1
Chromium;Total 1'034 ug/1
Cu - Copper 1042 ug/I
Fe - Iron. 1045 ug/I
Hg - Mercury 71900 ug/I
K - Potassium 937 mg/l
Mg - Magnesium 927 m9/I
Mn -',Manganese 1.055 ug/I
Na - Sodium 929 mg/I'
Ni - Nickel 1.667 ug/1
Pb = Lead 1.051 ug/I
Se - Selenium 1147 uug/I
Zn - Zinc 1092, ug/l
GW-54 Revised 7/85 For Dissolved Analysis - submit filtered sample and write *DIS' in block
White copy - Headquarters Pink copy Region Yellow copy Lab
- Organochlorine Pesticides:
Organophosphorus Pesticides
I IAcid H.e,rd'icides I
Base / Neutral Extractable Organics
Acid Extractable. Organics
I' Purgeable Organics (VOA bottle) I
I I 1.2 - Dibromoethane (EDB) I

�4
COUNTY J1:j,. �f--
/ qq
QUAD NO;­:`� SERIAL NO. )',/ ` /
LAT. �`+� ? LONG..2 Of5
Report tol:.-_AR451' FRO, MRO, RRO, W,RO, WiRO,
WSRO, Kinston FO Other
N.0 :PARTMENT OF NATURAL- RESOU
& COMMUNITY DEVELOPMENT
DEM
Shipped by: Bus; Gouri'er Other
yb- _l- _ J
COLLECTORS) /Ifate�l'�-__>e A1DATE
" 1
FIELD ANALYSES
pH400 eond 94zo at 250C
4 Ter-ttpt 0 1 r7- oC Odor
Appearance Taste
Field Analysis By:
LABORATORY ANALYSES
B005 310 mg/I
COD High 340 mg/l
COD .Low 335 mg/I
Coliform:MF Fecal 31616 /100ml
Coliform:MF Total 31504 /100ml
TOC 680 mg/I
Turbidity 76 NTU
pH 403 units
Alkalinity to pH 4..5 410 mg/I
Alkalinity to pH B.3 4.15 mg/I
Carbonate 445 mg/I
Bicarbonate 440 mg/I
did
Arsenic:Total 1002 FV ug/I
Carbon dioxide 405 mg/I
Chloride 940 mg/I
Chromium:Hex 1032 ug/I
Color:True 80 Pt -Co
Cyanide 720 m9/I
Owner
GROUNDWATER FIELD/LAB FORM
S LAB NUMBER 8
0 DATE RECEIVED % "'���u% Time
Rec'd by: D + From: Bus -Courier,;
Other
SAMPLE PRIORITY
S�ROUTINE ❑ EMERGENCY
r
TIME PURPOSE: BASELINE, COMPLAI
of
Location or site
l A%
DATA ENTRY BY: = CK:
DATE REPORTED:
COMPLIANCE' LUST, OTHER
one)--_. -
Description of sampling point
Sampling Method c/ ( Sample Interval
(pump, bai-ler, etc.)
Remarks
Diss. Solids 70300 mg/t
f�
Fluoride 951 t�6 mg/I
Hardness:Totai 900 mg/I
Hardness (non-carb)'902 mg/I
Phenols 32730 ug/I
Specific Cond. 95 uMhos/cm2
Sulfate 945 mg/I
Sulfide 745 mg/l
NH3 as N 610 mg/I
TKIJ as N 625 mg/I
NO2 i NO3 as N 630 mg/I
P:Total as P 665 mg/I
11 a _:�
Ag - Silver 1077
ug/I
Al - Aluminum 1105
ug/I
Be - Barium'1007
�j-U t„f
ug/I
Ca - Calcium 916.
mg/I
Cd - Cadmium 1027
ug/I
8c
Chromium:Total 1.034
ug/I
Cu - Copper 1042
ug/I
Fe - Iron 1045
ug/I
Hg - Mercury 71900
ug/I
K - Potassium 937
mg/I
Mg - Magnesium 927
mg/I
Mn - Manganese 1055
ug/I
Na - Sodium 929
mg/I
Ni - Nickel 1067
ug/l
Pb - Lead 1051v.
ug/I
Se - Selenium 1147
ug/I
Zn - Zinc 1092
ug/I•
, etc.
Organochlorine Pesticides
Organophosphorus Pesticides
Acid Herd.i'cides
Base / Neutral Extractable Organics.
Acid Extractable Organics
Purgeabie Organics (VOA bottle)
i�
1,20-- P4, romoethane (EDB)
T
f\ fsa VE(af.
I e` 1986
nt
Iluwaler Suction
••51G lUlldl VIIILC
-bt
r��� .��CE►t�
OA/ -OF
Lab Comments: n fvOJ
NI
GW-54 Revised 7/85 For Dissolved Analysis - submit filtered sample and write 'DIS' in block
White copy - Headquarters Pink copy - Region Yellow copy - Lab
I
d
v(y

A
3�
a
Environmental Management Divis'orF
C E I V -
`�
C 6 E
COMPLIANCE MONITORING
Groundwater Section
REPORT FORM
P.O. Box 27687I"41�
Raleigh,N.C. 27611
_
[phone]
Groundwater S r
Asheville RFMipTCI 11
Groundwater Section
Facility Name INTERNATIONAL MINERALS
CHEMICAL CORP. _
County
As" villa gie al8ffip-
Address P. 0. Box 545'
Permit N tuber:
SPRUCE PINE, NC 28777
Non -Discharge
Well Location Off NC #226, Mitchell County.
Well Identification Number Well #2 Well Depth �5 Ft.
Well Diameter 211 Sample (Screened) Interval 20 Ft. To �5 Ft.
Depth to Water Level �3 ft. below measuring point. (before sampling)
NPDES —
Water Use
NC 0000175
Injection Well
Well Construction 60-0018-WM-0004
Measuring point is feet above Land surface Other
Gallons of water pumped bailed before sampling
•.+ 8
Field Analysis: pH 6.5 Specific Conductance uMhos Temp, oC Odor None Appearance
Date Sample Collected Date Lab Sample Analyzed 8-1-86 and 8-6-86
Laboratory Name CompuChem Research Triangle Park Certification No.
COD
mg/I
NO2 as N (D)
mg/I
Coliform: MF Fecal
/100m1
NO3 as N CD)
mg/I
Coliform: MF Total
/100ml
Phosphorus: Total as P
mg/I
Dissolved Solids: Total
12 mg/I
Al - Aluminum, CD)
ug/I
pH (when analyzed)
5';6 units
Ba - Barium (D) 0.20 mg/1
ug/I
TOC
mg/I
Ca - Calcium CD)
mg/I
Chloride (D)
mg/I
Cd - Cadmium (D)
ug/I
Arsenic (D)
<0+0050 mg/ulg/I
Chromium: Total CD) : 0.030 mg/1
ug/I
Grease and Oils
Hardness: Total (D)
Phenol
Sulfate CD)
Specific Conductance
mg/I Cu - Copper CD) ug/I
mg/l Fe - Iron CD) ug/I
ug/I Hg Mercury (D) ug/I
_ mg/I
uMhos
K - Potassium CD)
Mg - Magnesium (D)
Total AmmoniaCNH3 t NH 4)(D) mg/I Mn - Manganese (D
k,.-
TKN as N (D) mg/I Na - Sodium (D)_
I CERTIFY T THIS REPOR S TRUE AND ACCURATE..
e � G W-59 -
SIGNA E U OF PERMITTEE OR AUTHORIZED AGENT
8-13-86
DATE
ug/I
mg/I
ug/I
mg/I
Ni - Nickel (D) ug/I
Pb - Lead CD) 4, 0.0050 mg/1 ug/I
Zn -Zinc CD) ug/I
Pesticides/Herbicides (Specify Compounds)
ug/I
ug/I
ug/1
Other (Specify)
ug/I
�_ZiAN
ug/I
.,
4
} _
ug/I
0_ 1
��i•A SEP1A
ug/I
D = Dissolved Analysis -
Submit Filtered
Sample
See back for instructions
Submit blue and green copies to address above.

I
f `7
�
COUNTY �." ::' .
N.C. DEPARTMENT OF NATURAL. RESOURCES LAB NUMBER a
QUAD NO. ~'d' SERIAL NO.
& COMMUNITY DEVELOPMENT
f ^ Time
DATE RECEIVED,-
LAT. ~ " f LONG.
'
DEM
Rec'd by: �' ^� From: Bus -Courier
GROUNDWATER FIELD/LAB FORM
Other
Report to:�,ARO,,FRO, MRO, RRO,
WaRO, WiRO,
SAMPLE PRIORITY
-
DATA ENTRY BY: CK:
WSRO, Kinston FO Other
,
I<' ROUTINE ❑ EMERGENCY
DATE REPORTED: r ^
Shipped. by: Bus, Courier, Other
COLLECTOR(S):��'' -% ,'
DATE
TIME >jr' - PURPOSE: BASELINE,
COMPLAI'NT,-OMPLIA E�LUST, OTHER
-
(cf role One)
FIELD ANALYSES
Owner yf. �'/ r•j>'�` `-'. r - �:�`
- '�`{'
pH400 - Spec. Cond.94
at 250C
Location or site
Tem,p.10 oC Odor
Description of sampling ,point
Appearance Taste
Sampling, Method s -`
Sample Interval
(pump, bailer, etc.)
Field Analysis By:
Remarks
.(pumping time; air temp, etc.)
LABQRATORY ANALYSES
BOD5 310
mg/I
COD High 340
mg/I
COD Low 335
mg/I
Col[form:MF Fecal 31616
/100ml
Col[form:MF Total 31504
/loom[
TOC 680
mg/I
Turbidity 76
NTU
/
pH 403 p.Y�
units
Alkalinity to pH 4.5 410
i
mg/I
✓
Alkalinity to pH 8.3 415
mg/l
Carbonate 445
fl
mg/l
Bicarbonate 440
CC.
mg/I
Arsenic:Total 1002
ug/1
_
Carbon dioxide 405
_
mg/I
Chloride 940
ln1
Y
mg/I
Chromium:Hex 1032
ug/I
Color:True 80
Pt -co
Cyanide. 720
mg/I
Lab Comments:
Diss. Solids 70300
mg/1
Fluoride 951
t
mg/l
Hardness:Total 900
mg/1
Hardness .(non-carb) 902
mg/I
Phenols32730
ug/I
Specific Cond. 95
uMhos/cm2
Sulfate 945
mg/I
Sulfide 745
mg/I
NH3 as N 610
mg/f
TKN as N. 625
mg/l
NO2 + NO3 as N 630
mg/I
P:Total as P 665
mg/I
A9 -.silver 1077 ugh
At - Aluminum 1106 ug/I
Be - Barium'1007 ug/I
Ca - Calcium 916 mg/I
Cd - Cadmium 1027 ug/I
Chromium:Total 1034 ug/I
Cu - Copper 1,042 ug/I
Fe - Iron 1045 ug/I
Hg - Mercury 71900 ug/I
K - Potassium 937 mg/I
Mg - Magnesium 927 mg/I
Mn - Manganese 1055 ug/I
Na - Sodium 929 mg/I
Ni ='Nickel 1067 ug/l
Pb - Lead 1051 ug/1
Se = Selenium 1147 ug/I
Zn - Zinc 1092 ug/I•
GW-54 Revised 7/85 For Dissolved Analysis - submit filtered sample 'and write 'DIS' in block
White copy - Headquarters Pink copy - Region Yellow copy - Lab
r�rganochlorine Pesticides
Organophosphorus Pesticides
I I Acid Herdici'des I
Base / Neutral Extractable Organics
Acid Extractable Organics
I I Purgeable Organics (VOA bottle) I
1 1 1,2 - Dibromoethane (EDB) I

COUNTY A�
IPARTMENT OF NATURAL, RESOUO
4 LAB NUMBER 8
--r _
-47 fL_Jt3SER'IAL
) i
%8� _ ..
& COMMUNITY DEVELOPMENT
DATE RECEIVED,f: 1�tT f Time �'f'
QUAD NO NO.
? F�'/ 212
'
From: Bus,Gouurier-�
LAT. LONG_
-7
DEM
Rec'd by:�
v
�_�
Report to:(ARO,�FRO, MRO, RRO,
WaRO, WiRO,
GROUNDWATER FIELD/LAB FORM
Other
SAMPLE PRIORITY
DATA ENTRY BY:
c CK: JL­
WSRO, Kinston FO Other
!'
lr4 ROUTINE ❑ EMERGENCY
DATE REPORTED:
Y:
Shipped b Bus Cou-_ ri�eer>�Oth:er/f`
/
COLLECTOR(S): i1. A kiz-sf
J
DATE l f.. tc
!/ ' `
TIME F PURPOSE: BASELINE,
COMPLAINT, COMPLIANCE, LUST, OTHER
`
•/ ✓
(circle one),_'""' ,
FIELD ANALYSES
Owner
p'H400 Spec. Cond.94
at 250C Location
or site
r i
d
T'emp.10 oC Odor
Appearance - Taste
Field Analysis By:
LABORATORY ANALYSES
BO,D5 310
COD High 340 r, mg/I
COD Low 335 mg/I
Coliform:MF Fecal 31616 /looml
Coliform:MF Total 31.504. /loom]
TOC 660 mg/I
Turbidity 76 NTLI
OH 403 units
Alkalinity to pH 4.5, 410 mg/I
Alkalinity to pH 8.3 415 mg/I
Carbonate, 445 mg/I
Bicarbonate 440 mg/1
ins
Arsenic:Total 1002 �(� ug/l
Carbon dioxide 405 mg/I
Chloride 940. mg/f
Chromium:Hex 1032 ug/I.
Color: rue 80 Pt -co
Cyanide 720 mg/I'
Description of sampling point d,`>
Sampling Method - A9,'�
(pump, bailer, etc
Sample Interval %f Y-
Remarks,
(pumping time, air temp, etc..)
Diss. Solids 70300 mg/L
Fluoride 961t mg11
Hardness:Total 900 mg/I'
Hardness (non-carb) 902 'mg/I
Phenols 32730 ug/I
Specific. Cond. 95 uMhos/cm2
Sulfate 945 mg/I
Sulfide 745 mg/I
NH3 as N 610 mg/I
TKN as-N 625 mg/l
'.NO2 + NO3 as N 630 mg/I
P:Total as. P665 mg/I'
Ag - Silver 1077
ug/I
AI - Aluminum 1105
ug/I
Be -. Barium '1007
G.5'06 ug'/I
Ca - Calcium.9'16
mg/I
Cd - Cadmium '1027
ug/I
/22.
Chromium:Total 1034
ug/I
Cu - Copper 1,042
ug/I
Fe - Iron 1045
OO
V
ug/I
Hg - Mercury 71900
ug/I
k - Potassium 937
mg/I
Mg - Magnesium 927
mg/I
Mn - Manganese 1.056
ug/I
Na - Sodium 929
mg/I
Ni - Nickel 1067
ug/I..
Pb - Lead 1051
.c, A,
ug/I
Se Selenium 1147
ug/I
Zn - Zinc 1092
ug/I•
L. Organochlorine Pesticides
Organophosphorus Pesticides
I I. Acid Herdicides I
Base J Neutral: Extractable Organics
Acid Extractable Organics
I I Purgeable Organics. (VOA bottle) I
I I 1.2 - Dibromoeth_ane (EDB) I
0
Lab Comments: FEB
Ew v t ., u 2 08 " nr.
d...^`V"ri
Asheville Regional Office
-54 Revised 7/85 For Dissolved Analysis - submit filtered sample and write 'DIS' in block
White copy - Headquarters Pink copy - Region Yellow copy - Lab }, 9

Environmental Management Division
COMPLIANCE MONITORING Groundwater Section
REPORT FORM P.O. Box 27687
Raleigh,N.C. 27611
[phone]
Facility Name j.in-nn nr- <.. . �.
ucb:.1J
County_ -
Address 11 ox
5L5
Permit Number:
oprruc.e P nr• >(0 2877
Non -Discharge
S�, ?j oG
Well Location `�-� �
22u .At�c'liel . �our3t; T-
N'PDES ;;, VJQ;;;';,7S
Well Identification Number
?.:-s . Well Depth 25 Ft.
Water Use
Well Diameter
Sample (Screened) Interval 20 Ft. To 25 Ft.
Injection Well
Depth to Water Level
ft. below measuring point. (before sampling)
Well Construction'50-OC'18a"I-C',.C"
Measuring point is
feet above land surface
Other
Gallons of water pumped
bailed before sampling - ` -"
Field Analysis: pH -"
Z-:, " Specific Conductance uMhos Temp.
o C Odor Appearance
Date Sample Collected
Noy.25Ai98S Date Lab Sample Analyzed
tr -
Laboratory Name Gimp' (.hen, Research o'r'iF_a le Fart,- Certification.
No. `
COD
mg/l NO2 as N (D)
mg/l Ni - Nickel'(D) ug/I
Coliform; MF Fecal
/100ml N'O3 as N (D)
mg/I �_P'6 - Lead (D)-I'.ug/I
Coliform; MF Total
/100rn1 Phosphorus: Total as. P
mg/I Zn - Zinc {D) ug/I
y,Dissolved Solids: Total
mg/I Al - Aluminum, (D)
ug/l Pesticides/Herbicides (Specify Compounds)
` pH (when analyzed) -S units
TOC mg/I
Chloride (D) mg/I
Arsenic ('D) z pug/I
Grease and Oils
Hardness: Total (D)
Phenol
Sulfate (D)
Specific Conductance
Total Ammonia(,N'1­13 t NH 4)(D)
mg/I
mg/I
ug /I
_ mg/I
uM'hos
_ mg/I
�8a - Barium (D)
ug/I
Ca - Calcium (D)
mg/I
Cd - Cadmium (D)
ug/1
,QKromium: Total (D)
! ug/I
Cu - Copper CD)
ug/I
Fe - Iron (D)
ug/I
Hg - Mercury (D)
ug/I
K - Potassium (D)
ug/I
Mg - Magnesium (D)
mg/I
Mn - Manganese (D)
- ug/I
TKN as N (D) mg/I Na Sodium (D) mg/I
GW-59
I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE.
SIGNATURE OF PERMITTEE OR AUTHORIZED AGENT DATE
Other (Specify)
ug/I
ug/I
ug/t
ug/I
ug/I
ug/I
ug/I
ug/I
.ug/I
D = Dissolved Analysis - Submit Filtered
Sample
See back for instructions
;lE Submit 'blue and ,green copies to address above.

COMPLIANCE MONITORING Environmental Management Division
Groundwater Section
REPORT FORM P.O. Box 27687
Raleigh,N.C. 27611
[phone]
Name /+
County
ja
f , rFacility
e
Address ,_.;g" t'
Permit
Number:
o
Non -Discharge
Well Location
NPDES
Well Identification Number *, i :,:xL_ Well Depth 2?S_ Ft.
Water Use
Well Diameter r <<r.: Sample CScreened) Interval :a.f Ft. To .z: Ft.
Injection Well
f
Depth to Water Level 7
ft. be.low measuring point. (before sampling)
Well Construction
Measuring point is feet above land surface
Other
Gallons of water pumped bailed
before sampling ('�
Field Analysis: pH
Specific Conductance uMhos Temp.
o C
Odor Appearance
Date Sample Collected Date Lab Sample Analyzed
Laboratory Name `� �. ',��
`,.; ®c , / ,,, . _ % Ef .c Certification No. %�
`
f
COD
mg/I NO2 as N (D)
mg/I
Ni Nickel CO)
ug/I
Coliform: MF Fecal
/100MI NO 3 as N CD)
mg/I
Pb - Lead (D)
ug/I
Coliform: MF Total
/100m1 Phosphorus: Total as P
mg/I
Zn - Zinc CD)
ug/I
Dissolved Solids: Total
mg/I AI - Aluminum (D)
ug/I
Pesticides/Herbicides (Specify Compounds)
PH Cwhen analyzed)
units Ba - Barium CD) ! / : , : , li.%
ug/I
ug/I
TOC
mg/I Ca - Calcium CD)
mg/I
ug/I
Chloride CD)
mg/I Cd = Cadmium CD)
ug,/I
ug/l
Arsenic (D) t`--a< <% -
ug/I Chromium: Total (D) /J, is :.�� %n ug/I
Other (Specify)
ug/I
Grease and Oils
mg/I Cu - Copper CD)
ug/I
_ ug/I
Hardness: Total CD)
mg/1 Fe - Iron CD)
ug/I
ug/I
Phenol
ug/I Hg - Mercury CD)
ug/I
ug/I
Sulfate (D)
mg/I K - Potassium (D)
ug/I
-ug/I
Specific Conductance
uMhos Mg - Magnesium (D)
mg/I
.ug/I
Total Ammonia(NH3t NH'4)(D)
mg/I Mn - Manganese(D)
ug/I
D =Dissolved Analysis— Submit
Filtered
TKN as N CD)
mg/I Na - Sodium (D)
mg/I
Sampfe
I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE.
CIF See back for instructions
CIE-* Submit blue and green copies to address above.
GW-59 SIGNATURE OF PERMITTEE OR AUTHORIZED AGENT
DATE

Environmental Management Division
COMPLIANCE MONITORING Groundwater Section
REPORT FORM P.O. Box 27687
Raleigh,N.C. 2.7611
[phone] -y ,`
Facility Name s %. .,i A;;County
Address Permit Number:
A,'
Well Location <:.': ' fr%.7` ,: fl
Well Identification Number %. - Well Depth 'V5' Ft.
Well Diameter A Sample (Screened) Interval .> Ft. To ZS— Ft.
Depth to Water Level - ft. below measuring point. (before sampling)
Non -Discharge
NPDES c Ell 242 /
Water Use
Injection Well
Well. Construction
Measuring point is feet above land surface
Other
Gallons of water pumped bailed
before sampling
Field Analysis: pH
Specific Conductance
uMhos Temp.
o C
Odor Appearance
Date Sample Collected s.// r`S`
Date Lab, Sample Analyzed
Laboratory Name
Certification
No.
COD
m'g/I
NO2 as N CD)
mg/I
Ni Nickel,(
ug/I
Coliform: MF Fecal
/100m1
NO3 as N (D)
mg/l
Pb - Lead (D)
ug/I
Coliform: MF Total
/100m1
Phosphorus: Total as P
mg/I
Zn - Zinc (D)
ug/l
Dissolved Solids: Total
mg/I
Al - Aluminum CD)
ug/I
Pesticides/Herbicides (Specify Compounds)
PH (when analyzed)
units
Ba - Barium CD) �- f ,� Ze:
ug/I
ug/I
TOC
mg/I
Ca - Calcium (D)
mg/I
ug/I
- Chloride CD)
mg/I
Cd - Cadmium (D)
ug/I
ug/l
Arsenic (D) ��< <%`�t� �Io
ug/I
Chromium: Total CD) �� .l� �L��,�,/�
ug/I
Other (Specify)
ug/I
Grease and Oils
mg/I
Cu - Copper CD)
ug/I
ug/I
Hardness: Total (D)
mg/I
Fe - Iron (D)
ug/I
ug/I
Phenol
ug/I
Hg - Mercury CD)
ug/I
ug/I
Sulfate CD)
mg/I
K - Potassium (D)
ug/1
ug/I
Specific Conductance
uMhos
Mg - Magnesium (D)
mg/I
ug/I
Total Ammonia(NH3 t NH4 )CD)
mg/I
Mn - Manganese (D)
ug/I
=
D Dissolved Analysis— Submit
Filtered
TKN as N (D)
mg/I
Na -Sodium (D)
mg/I
Sample
ICERTIFY THAT THIS REPORT IS TRUE
AND ACCURATE.
X See back for instructions
�IEAE Submit blue and green copies to address
above.
SIGNATURE OF PERMITTEE OR AUTHORIZED
AGENT DATE
GW-59

COLLECTION AND ANALYSIS OF GROUNDWATER SAMPLES
1. Samples should be analyzed as soon as possible after collection.
2. The Laboratory making the analysis should be consulted concerning proper procedures for sample
collection and preservation.
3. Measure and record the depth of water in the well prior to pumping or bailing any water from
the well.
4. At least six volumes of water in the well should be pumped or bailed prior to collecting a sample
for analysis.
5. Determination for pH, Specific Conductance, temperature, odor and apperance must be made in the
field on unfiltered samples when the sample is collected.
6,. Field equipment must be calibrated in accordance with recommendations by the manufacturer.
7. Samples must be filtered through a 45 micron filter immediately after collection when a dissolved
analysis is required.
8. The sample container should be labeled with the facility name, well identification number and date
and time collected.

COUNTY , `�' .� N. C. DEPARTMENT OF NATURAL RESOURCES
QUAD xo.:3 ''`;r=\ SERIAL NO. }'./j$ COMMUNITY DEVELOPMENT
DEM
REPORT To: (circle one) GROUNDWATER FIELD/LAB FORM
_ARO;'WSRO, MRO, FRO, WaRO,
WiRO, RRO, Ahoskie FO,
OTHER
PURPOSE: (circle one) baseline,'pollution~monitor other
LAB NUMBER °
DATE REC'D e
• 't
REC'D BY -
r.2
DATA ENTRY BY _ CK r
DATA REPORTED 6
DATE COLLECTED -dam I f ~s- YTime % sy }I " l '`r' Location or site
Description of sampling point Sampled interval;a
t r-
.Remarks Z r
Field Analysis By:.
pH _
Lab Analysis
• / - Long ,+ "I
LrV
F
JUrN 2 1985
o Groundwater Section
Spec. Cond. Temp. C )dor, Appearance Tast0l.0ps, rr. .-
p P� rr Y;onai Office
Alkalinity to pH 4.5 P00410 mg/l
Alkalinity, hydroxide__ P71830 mg/l
Carbonate P00445 mg/l
Binarborla'te. P00440 mg/l
W pH value (tmen analyzed) P00400 :5 Y units _
-,Arsenic (D) _ Pol000 4' � � ug/l
Carbon dioxide 200405 mg/l
Chloride (D) P00940 mg/l
Color (True) P00080 units
Cyanide
P00720
mg/1
Dissolved solids (D)
P70301
mg/1
t Fluoride (D)
P00951 c �
mg/l
Hardness (as CaCO,)(D)- PG0900
mg/1
Hardness (non--carbonate)(D)
P00902
mg/1
MBAS (D)
P38260
mg/1
Phenol (D)
P34466
Silica (D)
P00955 e'�<
mg/1.
—Sulfate (D)
P00946�p`� �
mg/1
--jSpecific Cond,
P00094* K UMHOS/cm.
GW-54 Revised 1/12/82
BOD
o
P00310
mg/l
COD
P00341
m /l
Coliform (Fecal MF)
1131616
/100ml
Coliform (total MF)
B31505
/100m1
TOC
P00680'`
mg/1
Turbidity
P82079
NTU
Ammonia (as Nitoogen) (D)
P00612
'mg/l
Kjeldahi (as Nitrogen)"(D)
P00623
mg/l
Nitrate + Nitrite (as Nitrogen)'(D)
p00631
mg/1
Phosphorus, total as P (D)
P00666
mg/l
Dissolved Solids - cond. meter
P70304
MR/1—
-`'Pb-Lead (D) P01049 " / Q 0 ug/1
'' n-Zinc (D) P01090 �� 6T 4T O ug/1
-..--K-Potassium' (D) P00935 i�mg/1
D = Dissolved'Analysis —submit filtered sample
White copy - Headquarters Pink copy - Region
ther Analyses:
191 hj f
e .
Yellow copy Lab '2ROUND iTATER SECT101,1
7.40&1, 11. G

COUNTY fi.i't', f�j✓ 1°r
QUAD N0. rySERIAL NO.
.� • - =`'
REPORT TO: '(circle one)
1 ARO, WSRO, MRO, FRO, WaRO,
'-WiRO, RRO, Ahoskie FO,
OTHER
=LAB NUMBER If '' 3/t`!J
DATE REC ' D
REC° D BY
DATA. ENTRY BY/ �;�- ,, - CR `
DATA REPORTED
PURPOSE: (circle one) baseline,(%llution monitor, other
DATE COLLECTED A°. ._ j '�+ Time , (1 ,' By / Location or site
V
Description of sampling
N. C. DEPARTMENT OF NATURAL RESOURCES '" >..:;...;, ::;.•i
& COMMUNITY DEVELOPMENT r IT E C E 4 V -I
DEM u
GROUNDWATER FIELD/LAB FORM J L L I -S i985
Groundwater Section
Asheville Regional Office.
a i'. I/ Sampled interval
(pumping time, air temp, etc,)
a "
Field Analysis By: Lat. ? 6 r ! �/ Long, t.,v
pH Spec. Cond. Temp, oC )dor Appearance Taste
Lab Analysis
Alkalinity to pH 4.5
P00410
mg/l
Alkalinity,, HydrexAde
P71830
m9/1
Carbonate
P00445
mg/1
Bicarbonate
P00440
mg/l
pH value Cynen analyzed)
P00400
units
,Ars nic (D)
PO1000
G // ug/1
Carbon dioxide
P00405_
mg/l
Chloride (D)
P00940
mg/l
Color (True)
P00080
units
Cyanide
P00720
mg/l
Dissolved solids (D)
P70301
mg/l
iF-li:oride (D)
P00951
/�. 9mg/1
Hardness (as CaCO-1)(D)
P00900
mg/1
Hardness (non-,carbonate)(D)
P00902
mg/l
MBAS (D)
P38260
mg/1
IP enol (D)
P34466
.e ug/l
\-Silica (D)
P00955
_
d(- mg/l
�,Syl.fate (D)
P00946
mg/1
,Specific Cond,
P00094
LC OS/cm
GW-54 Revised 1/12/82
\AgrSilver (D)
P01075
.C..� (_';ug/1
Al' -"Aluminum (D)
P01106
—'/00ug/1
Ba.-'Barium (D)
P01005
1tj1'i,rhg/1
_Ca12�6alcium (D)
P06915
�^- Ar mg/1
Cd'-Cadmium (D)
P01025
on ug/l
`Gr:eChromium CD)
P01030
/) ug/l
Cu- Copper (D)
P01040
f _ /`' ug/l
`Ee-Ziron (D)
P01046
/Jill ug/l.
-Hg=Mercury
P71900
�^,(" ug/l
Li -Lithium (D)
P01130
-°'T)ug/1
,MgeMagnesium (D)
P00925
d. Q mg/1
Mn-P3anganese (D)
P01056
"='/ ;ug/l
Na,Aod).um (D)
P00929
mg/l
-Eb`fLiad (D)
P01049
{! in. ug/1
,Zn Zinc (D)
P01090
ug/1
K-Potassium (D)
P00935
tl) • /::�' : mg/1
D = Dissolved Analysis - submit filtered sample
White copy - Headquarters Pink copy - Region
BOD
P00310
mg/1
COD
P00341
/1
Coli form (Fecal MF)
P31616
/100ml
Coliform (total MF)
P31505
/100011
TOG"
Turbidity
P00680 t! ,c; ° mg/l
P82079 NTU
Ammonia (as Nitorgen) (D)
P00612
mg/1
`KjelAahl (as Nitrogen)' (D)
P00623
/)� =4 mg/l
t Nitrite (as Nitrogen) (D)
Nitros,phorus,
FPhotal
P00631
_ , .;1(,) mg/l
tate,
as P (D)
P00666
mg/l
Dissolved Solids - cond. meter
P70304
MR/1
Other Analyses:
Yellow copy - LabGROU D 67ATER SECTiCIN
ULEIG+u, M r.

COUNTY
QUAD N0SERIAL NO.
REPORT TO: (circle one).
..AR'O; WSRO, MRO, FRO, WaRO,
`WiRO, RRO, Ahoskie FO,
OTHER
PURPOSE: (circle one) baseline,ep611�utio`n monitor, other
DATE COLLECTED Time ° :flt
j 1
Description of sampling point
Remarks
N. C. DEPARTMENT OF NATURAL RESOURCES
& COMMUNITY DEVELOPMENT
DEM
GROUNDWATER FIELD/LAB FORM
R
BY f ?. ' Location or site ,
etc.
Field Analysis By: Lat. --- _ f - r to Long. ' r
Lab Analysis
LAB NUMBER
DATE REC'D�
'r
REC' D BY
DATA ENTRY BY CK
DATA REPORTED 6 / -2 ?� s
interval
Spec. Cond. Temp, oC )dor Appearance Taste
Alkalinity to, pH 4.5
P00410
mg/l
,Alkalinity., KydraxAde
P71830
mg/l
Carbonate
P00445
2
mg/l
B narbotra`te
P00440
J &,/
mg/l
pH, -%blue (fatten analyzed)
P00400
C"_(
units
Arsenic (D)
P01000
V
ug/l
_
Carbon dioxide
P00405
mg/l
Chloride (D)
P00940
v i
mg/l
Color (True)_
P00080
units
Cyanide
P00720
mg/l
jAssolvedsolids (D)
P70301
JJ -7
mg/l
Fluoride (D)
P00951
mg/l
Hardsleas (as CaCO3) (D)
P00900
mg/l
Hardness (non-carbonate)(D)
P00902
1
mg/l
~MBAS (D)
P38260
mg/1
Phenol (D)
P34466
u9/1
Silica (D)
P00955
mg/1
Sulfate (D)
P00946
m
Specific Cond,
P00094
UMHOS/cm
GW-54 Revised 1/12/82
Ag-Silver (D)
P01075
ug/l
Al -Aluminum (D)
P01106
ug/1
Ba-Barium (D)
F01005
ug/1
Ca -Calcium (D)
P00915
mg/l
Cd-Cadmium (D)
P01025
ug/1
Cr-Chromium (D)
P01030
ug/1
Cu-Copper (D)
P01040
ug/1
Fe -Iron (D)
P01046
ug/l
Hg-Mercury
F71900
ug/l
Li -Lithium (D)
P01130
ug/l
Mg -Magnesium (D)'
P00925
mg/l
Mn-Ranganese (D)
_P01056
ug/1
Na,Sodium (D)
P00929
mg/l
Pb-Lead (D)
P01049
ug/1
Zn-Zinc -(D)
P01090
ug/l
K-Potassium (D)
P00935
mg/1
BOD
COD
P00310
P00341
mg/l
mg/1
Coliform (Fecal MF)
P31616
/100m1
Coliform (total NO
P31505
/100m1_
TOC
Turbidity
P00680
P82079
mg/l
NTU
Ammonia (as Nitorgen) (D)
P00612
mg/1
Kjeldahl (as Nitrogen)'(D)
PO0623
mg/1
Nitrate t Nitrite (as Nitrogen)(D)
P00631
mg/l
Phosphorus,_ total as P (D)
P00666
mg/l
Dissolved Solids - cond. meter
P70304
mg/1
Other Analyses:
D = Dissolved Analysis - submit filtered sample
White copy - Headquarters Pink copy- Region Yellow copy Lab

. .,.:ram-.R-�-y...... ,...._ r......, .._�_,....•.-nti..�ra.
t'
State of North Carolina
Department of Environment,
Health and Natural Resources
Asheville Regional Office
James B. Hunt, Jr„ Governor
Jonathan B. Howes, Secretary
Nann B. Guthrie, Regional Manager
GROUNDWATER SECTION
June 16, 1995
Mr. Roy Riddle
Unimin Corporation Quartz Operations
P. O. Box 588
Spruce Pine, North Carolina 28777
Dear Mr. Riddle:
Subject: Cessation of Groundwater Monitoring
Permit No. NC0000175
Authorization to Construct
Unimin Corp. (formerly IMC Corp.)
Mitchell County
The Authorization to Construct dated April 19, 1985 issued
under Permit No. NC0000175 required that groundwater monitoring
be conducted at the. facility presently known as Unimin
Corporation. The purpose of this letter is to inform you that
groundwater monitoring is no longer required at this site.
Our records indicate that groundwater monitoring has been
conducted at the subject site since May 1985. A review of the
historical data shows that no apparent groundwater standard
violations have been confirmed since groundwater monitoring was
initiated. This NPDES permitted facility has been in compliance
with the groundwater standards for the past 10 years, therefore
groundwater monitoring is no longer required.
The two groundwater monitor wells shall be properly
abandoned in accordance with NCAC Title 15A subchapter 2C, the
well construction standards. I have enclosed a copy of the
applicable section on well abandonment and a record of well
abandonment to be submitted to this office upon completion.
Interchange Building, 59 Woodfin Place, Asheville, N.C. 28801
An Equal Opportunity Affirmative Action Employer
Telephone [phone] FAX [phone]
50% recycled/ 10% post -consumer paper

Mr. Roy Riddle
June 16, 1995
Page 2
If you have any questions or comments regarding groundwater
issues, please contact me at [phone]. Your cooperation
and responsiveness has always been appreciated.
Sincerely,
Laura Kay Dechant
Hydrogeologist
\lkd
cc: Bob Cheek
Betty Wilcox

d sa $GT£ o
•� paw �'
State of North Carolina
Department of Natural Resources and Community Development
Asheville Regional Office
James G. Martin, Governor
DIVISION OF ENVIRONMENTAL MANAGEMENT
GROUNDWATER SECTION
October 8, 1987
Mr. Roy Riddle
Unimin Corporation Quartz Operations
P. 0. Box 588
Spruce Pine, North Carolina 28777
Dear Mr. Riddle:
S. Thomas Rhodes, Secretary
Subject: Compliance Monitoring Reports
Unimin Corporation
NPDES Permit No. NC0000175
Mitchell County, North Carolina
The Groundwater Section has assigned well identification numbers to
the two monitor wells constructed under Well Construction Permit No.
60-0018-WM-0004 at the subject site. Please refer to these numbers, as
they relate to our data entry records, on the Compliance Monitoring Report
Forms submitted in the future. The well identification numbers are as
follows:
I81tl
Well
#1
Depth
15'
Screened
5'
- 15'
I81t2
Well
#2
Depth
25'
Screened
20'
- 25'
As stated in my letter dated August 12, 1987, continue to submit the
blue and green copies of the Compliance Monitoring Report Forms to the
Groundwater Section in Raleigh.
If you have any questions or comments regarding compliance monitoring,
please contact me at [phone].
Sincerely,
Kay "Dechant
Hydrogeological Technician
KD:ar
cc: Nargis Toma
Paul R. Smith
Interchange Building, 59 Woodfin Place, P.O. Box 370, Asheville, N.C. 28802-0370 • Telephone [phone]
An Equal Opportunity Affirmative Action Employer

State of North Carolina
Department of Natural Resources and Community Development
Asheville Regional Office
James G. Martin, Governor
DIVISION OF ENVIRONMENTAL MANAGEMENT
GROUNDWATER SECTION
August 12, 1987
Mr. Roy Riddle
Unimin Corporation
Quartz Operations
P. 0. Box 545
Spruce Pine, North Carolina 28777
Dear Mr. Riddle:
S. Thomas Rhodes, Secretary
Subject: Compliance Monitoring Reports
Unimin Corporation
Permit No. NC0000175
Mitchell County, North Carolina
In order for the Groundwater Section to review and process compliance
monitoring reports in a consistent manner, please send the report forms
directly to the Groundwater Section in Raleigh at the address at the top
of the form. Submit the blue and green copies to Raleigh and keep the
white copy for your files. If an agent is authorized to submit the forms
in your behalf, notify them of this procedure.
If you have any questions or comments regarding compliance monitoring,
please contact me or Don Link at [phone].
Sincerely,,,
Kay Dechant
Hydrogeological Technician
KD:ar
cc: Nargis Toma
Interchange Building, 59 Woodfin Place, P.O. Box 370, Asheville, N.C. 28802-0370 • Telephone [phone]
An Equal Opportunity Affirmative Action Employer

/5EATEE DIVISION OF
ENVIRONMENTAL
?� MANAGEMENT
A niin
Groundwater
Section
State of North Carolina
Department of Natural Resources and Community Development
Asheville Regional Office
James G. Martin, Governor S. Thomas Rhodes, Secretary
June 17, 1985
Mr. Roy Riddle
International Minerals & Chemical Corporation
P. 0. Box 545
Spruce Pine, North Carolina 28777
Subject: Groundwater Monitoring
Permit No. NC0000175
International Minerals & Chemical
Corporation
Mitchell County, North Carolina
Dear Mr. Riddle:
In reference to our previous conversations, it will not be necessary
-to construct a background monitor well at the site of the stabilization
ponds as stipulated in Permit No. NC0000175, since a suitable area for
such a well was not available on site. However, if the quality of ground-
water is degradated at the site of the two downgradient monitor wells, it
may be necessary to construct a background monitor well at another area
on the property.
If you have any questions, please do not hesitate to contact me at
704-253-3341.
Sincerely,
ago.
Donald R. Link
Regional Hydrologist
DRL/ar
cc: Perry Nelson
Forrest Westall
Dennis Ramsey
Interchange Building, 59 Woodfin Place, P.O. Box 370, Asheville, N.C. 28802-0370 • Telephone [phone]
An Equal Opportunity Affirmative Action Emplover

.4
-,IAL MINERALS DIVISION
Sox 545 o Spruce Pine, North Carolina 26777 Y�D
Telephone: [phone]
F. C
CIL—)
INTERNATIONAL MINERALS & CHEMICAL CORPORATION
MIMarchL 2�001985
r
Mr. A. R. Hagstrom
State Engineering Group
N. C. Dept. of Natural Resources and
Community, Development
P. 0. Box 27687
Raleigh, N. C. 27611-7687
Dear Mr. Hagstrom:
RECEIVED
ED
Water Quality Division
APR 22 1985
Western Reeional Office,
Asheville, North Carolina
In response to your January 17, 1985 request for additional
information, we respectfully provide the following:
Re nest•#1 - Provide detailed drawings of the proposed modifi-
cations. Attached are two (2) copies of the requested drawings.
Request #2(a)Provide analysis of lime neutralized MRL waste.
Attached are two (2) copies of a wastewater analysis "as is". Sample
was analyzed for principal constituents. Additionally, a semi-
"`' quantitative analysis was performed on the.solids that were contained
in the sample.
A second portion of the -composite sample was filtered and the- '
filtrate and solids were analyzed for toxic heavy metals. This sample
was collected -February 12, 1985 (24 hr. composite)°and -the sample had
a pH of 9.50.
(b) What is MRL waste. The raw material for IMC's
operation is pegmatite ore. A quartz fraction is separated from a
feldspar and mica fraction during mineral processing; the MRL process
"purifies" the quartz fraction. This purification process involves the
acid dissolution and removal of undesirable constituents.
The diluted spent acids are neutralized with chemical lime prior
-to being mixed with the main plant's waste waters which undergo an
additional chemical lime treatment.
�4 •
We request that the above described material regarding IMC's MRL
process be kept confidential.
11

Page 2
3/21/85
Request #3 - Provide detailed explanation of how the new
components will be used. The proposed impoundment areas will
provide equalization and stabilization for MRL waste waters.
This will provide more constant flow and composition of waste'
waters reaching the main waste water treatment'facil-ity.
Current MRL waste water -handling operates in a batch mode.
This has caused a marked fluctuation in plant flow, pH, and
other parameters at the main waste water tr'batment plant, and
has caused pH violations of our NPDES permit.
Request #4 - Provide site location map. 'Attached is a
copy of a portion of a U.S. Geological Survey map. The site is
located near the old.Gudger'Mine, next to IMC's solid waste
disposal site, which is under our mining permit #61-4.
The area around these impoundments are proposed to be
enclosed with a chainlink fence.
-We trust that the foregoing information adequately
furnishes the requested information. Should you have any
questions, or need additional information, please do not hesitate
to contact us at [phone].
DH/vb
cc: G.J. Widger
D. K. Larsen
Jack Harris
R. McKenzie
Peter Goodwin
J. C. Higgins
R.,C. Wilson
Sincerely y�prs,
�In-a
Dewey Hall
Southeast Area Mgr.

Water Quality Division
APR 22 1985
Western Regional Office.
Asheville, North Carolina
INTERNATIONAL MINERALS & CHEMICAL CORPORATION
RESEARCH & DEVELOPMENT
MR-1618
Library.- R&D (2)
Patent Department - TEH
Mr. S.S. Iyer '
Mr. L.W. Ferrara
Mr. J.A. Sickmann
Dr. T.B. MacRury
Mr. R. Riddle
Mr. D. Hall
Mr. C . ' Kangas

INTERNATIONAL MINERALS & CHEMICAL CORPORATION
RESEARC. i ,AND DEVELOPMENT DIVISION
Report No. MR-1618
Date March 14 1985
Legal Signature
TITLE' MRL Waste Water, IMC, Spruce Pine, North Carolina
AUTHOR(S): M. Iyer
INTRODUCTION:
A sample identified "Minerals Research Lab Waste Water,
IMC, Spruce Pine" was received from Mr. Roy Riddle for the
following:
1) On a well -mixed sample analyze for Total solids,,
Fluoride, Ca,.Si
2) Filter the sample and analyze the filterate and
non -filterable solids for toxic inorganic heavy metals (Ag, Ba,
Cr, Cd, Pb, As, Hg, Se)
SUMMARY:
The sample was assigned lab T.D. 8518009 and analyzed as
requested.
A copy of the lab report is attached.
05381
KEY TERMS: PROJ. 779S; LAB I.D. 8518009
APPROVALS: MG VP

kTIONAL MINERALS & _.._MICAL CORPORATION
JICAL SERVICES LAB REPORT
FORM 0.2094
PRINTED IN U,SA
SAMPLEDESCRIPTION
,DESCRIPTION
Waste Water
— DATE RECEIVED
21/ 8 5
SAMPLEORIGIN
Mineral Research. Lab,
SMC Spruce Pine,
NC
REQUESTED BY Roy E . Riddle cc • Dewey Hall, Cliff Kangas
SERVICE PERFORMED Total Solids, Fluoride, Ca, Si and Semiquantitatiye analysis
for major and minor elements in total solids..
COMMENTS: Sample of waste water from quartz purification process.
(Analysis reported on a well mixed sample.)
RESULTS:
QUANTITATIVE ANALYSIS
Fluoride 0.45 %
Ca 0.62
Si. 0.22
Total Solids 1,86%
SEMIQUANTITATIVE ANALYSIS For Major,& Minor Elements
The following are reported as oxides--o± the elements
as found in the above reported total solids.
Ca
Principal Constituent
Si
r 25. %
Al
3.5
Mg
2.
Na
0.4
Fe
,6
Ba
.02
Mn
.015
Ti
.05
Sr
.03
Cr
.002
Cu
<,001
Ni
<.005
Zr
<.005
K
<Q5
DATE COMPLETED 3/04/85 �'-
CERTIFIES BY DATE
SUPERVISOR — TECHNICAL SERVICES
DATA COORDINATION AND TRANSMITTAL
SAMPLE No. 8518009
CUSTOMER,
Pltrdb`O�GE No.
IMCORE
779S
DATE 3/13/85
S 1 A 19
occlnro f'SC
APPROVED DATE
3 Z—
Y
OUTS W. FERRARA, MANAGER
TECHNICAL SERVICES

VINTERVATIONAL MINERALS &-___MICAL CORPORATION
TECHNICAL SERVICES LAB.REPORT'.
=
SAMPLE DESCRIPTION MRL Waste Water DATE RECEIVED 2/21/85
SAMPLE ORIGIN Mineral Research Lab, IMC Spruce Pine, NC
REQUESTED BY Roy E . Riddle cc: Dewey Hall , Cliff Kangas
SERVICE PERFORMED Toxic inorganic heavy metals as repolrted in non -filterable
solid portion of the sample.
COMMENTS: Sample of waste water from quartz purification ,process .
RESULTS:
NON -FILTERABLE SOLIDS
Ag
<,1 mg/1
Ba
15
Cr
12 `
Cd
<.l
Pb
1.7
As
1.5
Se
<.02
Hg
<.01
LJ
DATECOMPLETED 3/14./85 CERTIFIED BY DATE
SUPERVISU — TECHNICAL S VICES
FORM 0.20ia0
PRINTED IN UZ
DATA COORDINATION AND TRANSMITTAL
SAMPLE NO. 8518009
CUSTOMER IMCORE
)ro]ect 779S
� NO.
DATE 3/13/85 ` 4 i
APPROVED BY DATE�Y/ 6 Z�
S 1 A 8 LOUIS W. FERRARA, MANAGER
TECHNICAL SERVICES
FiFCI II TC.`Pl uA„C /MA,l 3/14/85

NTE
HONAL MINERALS & !_ 1ICAL CORPORATION
ICAL SERVICES LAB REPORT
"� �•
SAMPLE DESCRIPTION MRL Waste Water DATE RECEIVED 2/21/85
SAMPLE ORIGIN ' Mineral Research 'Lab, ' IMC Spruce Pine, NC
REQUESTEDBY Roy E. Riddle cc: Dewey Hall, Cliff Kangas
SERVICE PERFORMED Toxic inorganic heavy metals as reported below in the
filterable portion of'the sample.
COMMENTS: Sample of waste waters from quartz purification process.
RESULTS:
FILTrR7A:TF
Ag <.1 mg/l
Ba <1
Cr <.01
Cd <.l
Pb <.1
As <.01
Hg <.O1
Se <.02
DATECOMPLETED 3/12/85 CERTIFIEDBY DATE
SUPERVISOR - TECHNICAL SERVICES
FORM 0.2090
PRINTED IN US.A.
DATA COORDINATION AND TRANSMITTAL
SAMPLE NO. 8518009
CUSTOMER IMCORE
Project 779S _
tNVaCE NO.
DATE 3/13/85 APPROVED B DATE
S 1 A 8 LOUIS W. FERRARA, MANAGER
TECHNICAL SERVICES
DrcInTc 3/14/25 r- ---

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RECEIVED
`eater ?._,w`iiy Diyision
Dear
forth Carolina Department a
sN
Resources & Commuity- e e
at raj� 7. 1985•
rs Regsonal 0 Tice
lie, North Carolin'z
DIVISION OF ENVIRONMENTAL MANAGEMENT
PROJECT ti"a
f r ,
a �
We acknowledge receipt of. the following documents: , 19�,
permit application - APN'S
engineering plans
specifications
other _
Your project has been assigned to for a detailed
engineering review. All project documents will be reviewed with respect to'the J
proposed wastewater facilities. This review will not commit this Division to
approving any expansion of these treatment facilities or increase of flowrate in
rthe future.
Prior to the issuance of the permit, you will be -advised of the recommendations
and comments of this -Division. You will also be informed of any matter which needs
to be resolved.
Our reviews are scheduled based on receipt date.of complete informations. The
items checked below are needed before your project can be reviewed.
permit application (copies enclosed)
engineering plans (signed and sealed .by N.C.P.E.)
specifications (signed and sealed by N.C.P.E.)
other additional information detailed on attachment
The above checked information is needed by If not received,
your application package will be returned as incomplete. Please be aware that the
Division's Regional Office must provide RECOMMENDATIONS from
1S r- - 15 - rA
If you have any questions, please call the review engineer at this telephone number
919/733-5083.
Sincerely,
cc:
Box 27607 Paleicihi. N C.=7611.7687

3..)L,4.-Hube-r Corporation
Route _ Luber
�Jacon, Georgia 31298
�.8-5
taus. Wilms, Acting Director
C. Div -is -;on of -Environmental Management
., Box 27687
al.eigh; v. C. 27611-7687
TM-EPHONE
[phone]
t
GP _ ..'.tjYC�'
Re: Renewal of Permit # 6281-R3
J. M. Huber
Wet Ground Mica Plant
Mitchell Co., N. C.
Dear Mr. Wilms:
There is no change proposed for the wastewater facility at our Mitchell
County Plant; therefore, please accept -this letter as our official request
for renewal of permit # 6281-R3.
I am enclosing a check for $25.00 to cover the renewal processing fee for
this non -discharging type wastewater treatment facility.
Thank you for your attention to this matter.
Sincerely,
J. M. HUBER CORPORATION
Jay utto
Div sion Environmental Coordinator
cc -Michael R. Parker - Env. Eng. Technician �..

DIVISION OF ENVIRONMENTAL MANAGEMENT
ASHEVILLE REGIONAL OFFICE
GROUNDWATER SECTION
March 8, 1985
.MoxA�aDUM -
TO: Lee Laymon, Assistant Chief
Groundwater Section
THROUGH: Roy M. Davis, Regional Supervisor
Division of Environmental Management
FROM: Don Link, Regional Hydrologist
Groundwater Section )an
SUBJECT: Permit No. 6281-R3
J. M. Huber Corporation
Wet -Ground Mica Plant
Mitchell County, North Carolina
It is my recommendation that the following condition be placed in the
above permit:
1. Groundwater Monitoring:
The permit holder shall, upon written notification
from the Division of Environmental Management, construct
groundwater monitoring wells and sample and analyze the
intercepted groundwater in the manner determined necessary
by the Division of Environmental Management to monitor the
quality of the groundwater as that groundwater may be
impacted by this facility.
DL/ar
cc: Mike Parker

_`VtD
Water 11
-y D! I I daffy vision
ep a me.,_ n, N9
Car�i.�na
o IthD
sourcesA.
-r%mmuhitv
Dbvel��r��`'
he.&
N sc, .,
V)Iest&WRegion'al'Office
As6,AJ'J6'N6rth Caroffna
DIVISION_,OF ENV ; IRO MtNTA' MANAGEMENT'
4
"t 14 0 1 ffu, A"',
Y PROJECT
PRO
_
Dear I, If -TI K
WeALcknowledgereceipt of 'f­EM, followifig documents, rf.�
Aplf� 1 4) _141
s
--epc1ineering pla�h
_sp6ci ications,
other ssg 1
f
detailed
Your project has ..been assigned to. Y or,
respect to the
-engineer-r ' eview,. All project documents, will,. be ..reyiew6d -.with. d
proposed' wastewater, facilities:' This'-reView, w1l I TibtF Comm -it t i.ofv: to
approving •any ies, o
expansion of these,"treatient: facile t* r_,increase ,of flowr a:te.lin.-
o' r to, the issuance of, the you lj� will --be advised of the recommendations. P-ki n permit.,
of this D"'iv.isi:o or
­an&,�coiments n;� �y6u _U111, a1go be informed any 4 " tter- which needs
to,be--resolved.
oTr,receipt .'date of - ormat-Ons., The
Our'reviews are scheduled based
items i- checked below are needed -,`before, your project can be reviewed
A
A
i"
_p erinit ap lication (copies enclosed)
MK
,
.-:.engineering plans (:signed and eale'd,-by, C PE specifications (signed .ana seale by
C.P.E.)."Y4 I
L
A0
g.
4
otheradditionalinformation,-At�I d received.,
F.
�
�The,�abovd%&hecked information,is needed -by, 41 10L�.t" If not,
pase,'be- A
"Your app re:Tthat -the
','
Iication� package wiil, 1�e -ie'tutned
provide RECOMMENDATIONS from
Divisions -Regional,Office' must_,pT'6v"
VJ
.:,the-Regional'.,Supervisor or aPro�cedure Four.- ,Evaluations 'Pr
qj tf,prior
.final,
action by, the :.Division..
6 '
If'the any�questions, 'please call h review` , engi4e'er,-a, t this telephone. •number
`1
919/7313"5083. 2
-Sincerely'v,'
cc:
P, 0. Box 27687 Raleigh, N. C. 27611:76£17
4 (fir—otive Action Emoloyer

'hone: 17041 785 <2E i
JA
I
IN T ERNATIGNAL MINERALS � C,HEMICAL CORPORA+ 1C
December 17, 1984
CERTIF±ED MAIL -
Return Receipt. Requested
Mr. Arthur Mouberry , Supervisor
PCE VE
Permi is and Engineering Section 141 2
Div. of Environmental Management ! __
P. 0. Box 2l68!`�#t,4 QUALM( 5ECT
Ral ei.g�, -, 'North Carolina 27611
�x �I�
Dear.'Mr. Mouberr,/:
Enclosed.are copies of our application and other supporting data
for anon -discharge water permit. The present m�atf�od' of handling
process waste requires occasional suspension of plant operations- in,
order to meet N.P.D.E.S. permit requirements (?enilit No: N.C.0000175').
To remedy this situation we propose stabilizing the lime
neutralized MRL waste before it reaches the waste .water treatment plant.
We are proposing to construct impoundment areas (see'attachmen6s) where
we can stabilize the neutralized was:te.stream and'.have, a'constant.fl-.ow.
to our waste water, treatment plant.
This proposed system is a vital component in our efforts to
maintain NPDES permit requirements, productio., and to improve water
quality..
Should there by any questions, or if you need additional.infor-mation,
please contact me at (7'04)765-4283. Your cooperation -in this matter is
apprec.i•ated.. A check far the $50...00• processing'. fee; is enclosed.
,Si ncerel.b' yours
.. r
RER; vb Poly Riddle .
Enc i osures Area;,!! Environmental Mgr.
cc:- Robert McKenzie
Dewey hall
J. C.. Higgins
P. Goodwiri
R. A. Falconer
D. K. Larsen
R_ C. WiIson

OIL A E STASILIZATION SYSTE'..
The presepz method of handling proccss.wasre requircs occasional
suspension of plant operations in. order to' inlet N.P.D.E.3. discharge
requiremznts YPermit No. 0000175). To remedy this situation we prop sr
stAN the lime neutralized MRL waste before it reaches the wask-
treatmen: plant.
Adjacent to toe piddilopera tmined. ka _avea is a min.out arca (a
I, mica recovery opyril"l-ion). Most of this area has, and isv bei,
used for solid.waste df5pol,sal. arVis'coveNdAy our Min iqg Permit #61.4�
This sectjon of this m0eQut greaAlkest to the plznt�site has not
been fillet. 11 w1ptsolly,aste ay Igo,
at akakd.
We- ar2.prQsjng ze' th ' Saxistif - terrab tp caylyrutt
P&Iea�.ZrW Ahe'"Achi led -areel kSep,
a0achad SAM)! he neditralkedwaite Areapyglye MRL will enter
•
the.-uppar en '05 'thr,t aea-andfhe WrITMO w8ter dmanted
Aclhe-presunqqoj; ficy,from thl Ponf,01 b,combined;Vkh feldspar
PlAt Naste K07-bekre I pQrIng the:wagte treat.le nt.plan! rill" jindl
T11, t in,` c n stabilized -AN to' Cali;"
-,osayte, teeatment plent. 11
ME& SylteM will be the addition of
TO sNy m p pr
tha areas )a ykabilize the MRUwaste"stream. This—propusad
Ustem is a vitatdcmpanenkh Ar effarts'to maintain producti4n and
improve watar. quality. jl

DIVISION OF ENVIRONMENTAL MANAGEMENT
GROUNDWATER SECTION
April 15, 1985
R E c v" D
APR 1085
Grounciwater Section
Asheville Regional Office
MEMORANDUM
TO: Arthur Mouberry
FROM: Bob Cheek �n
RE: Modification of Existing Wastewater Disposal System, International
Minerals and Chemical Corp., Mitchell County (AC-0000175)
The Groundwater Section has reviewed the expansion proposal and Don
Link's evaluation. We would have no objection to the proposal with the
following stipulations:
(1) Construction of a minimum of 3 monitor wells (1 upgrade, 2 down-
grade to monitor any changes in groundwater quality. The exact
location and construction details should be by approval of the
Asheville Regional Office.
(2) The wells should be sampled, upon completion and every March,
July and November thereafter for the following constituents:
Barium, Chromium, Arsenic, Lead, TDS, pH and Water Levels.
BC/ls
cc: Roy Davis
imuglay
Central Files
a

DIVISION OF ENVIRONMENTAL MANAGEMENT
GROUNDWATER SECTION
April 15, 1985
RL7C� Ems V 'a
Groundwater Section
Asheville Regional Office
MEMORANDUM
TO: Arthur Mouberry
FROM: Bob Cheek 93
RE: Modification of Existing Wastewater Disposal System, International
Minerals and Chemical Corp., Mitchell County (AC=0000175)
The Groundwater Section has reviewed the expansion proposal and Don
Link°s evaluation.' We would have no objection to the proposal with the
following stipulations:
(1) Construction of a minimum of 3 monitor wells (1 upgrade,.2 down-
grade to monitor any changes in groundwater quality. The exact
location and 'construction details should be by approval of the
Asheville Regional.Office.
(2) The wells should be sampled, upon completion and every March,
July and November thereafter for'the following constituents:
Barium, Chromium, Arsenic, Lead, TDS, pH and Water Levels.
BC/ls
cc:
Don Link
Central Files

HNORTH CAROLINA DEPARTMENT *ATURAL
RESOURCES AND COMMUNITY DEVELOPMENT (�
Date 19
1951�+
To: Dool L / /N 14
From: 3of v C44tk
Remarks:
AAMI Ak a,
A44 WwuaIF 4F
R�9�csf
r
K gV
acnoN glintiWate ` t!
❑ Note and file
❑ Not'gQ
❑ Note and return to me
❑ Your wJJ�lmllments, please
❑ Note and see me about this
❑ For your Information
❑ For your approval
❑ Prepare reply for my signature
❑ Per our conversation
❑ Prepare Information for me to reply
❑ Per your request
❑ Please answer, with copy to me

a
iIMPORTANT
Foil
.
To
Date ` Ti e
WHILE YOU WERE OUT 'r
M i,i Y1 ♦ y a 7+ C y
of
Phone
AREAOD CE _ N AIER ' ' 4, kXTENSIdN
s
Message
Signed
TELEPHONED��#�
EA$�f eAl:t: ';• �
'�
CALLED TO SEE YOU
WILL CALL AGAIN
WANTS TO SEE YOU
URGENT
RETURNED YOUR CALL
N. C. Dept. of Natural Resources and Community Development

Mrr INTERNATIONAL MINERALS & CHEMICAL CORPORATION
IIIIU RESEARCH AND DEVELOPMENT DIVISION
1
Report No. MR-1618
Date March 14 - 1985
Legal Signature 2
TITLE: MRL Waste Water, IMC, Spruce Pine, North Carolina
M.
AUTHOR(S): M. 1yer
INTRODUCTION:
A sample identified "Minerals Research Lab Waste Water,
IMC, Spruce Pine" was received from Mr? Roy Riddle for the
following:
1) On a well -mixed sampler analyze for Total solids,.
Fluoride, Ca, Si
2) Filter the sample.and analyze the filterate and
non -filterable solids for toxic inorganic heavy metals (Ag, Ba,
Cr, Cd, Pb, As, Hg, Se)
SUMMARY:
The sample was assigned lab I.D. 8518009 and.analyzed as
requested.
A copy of the lab report is attached.
MAR 25 as
PERMITS &ENGINEERING
05381
KEY TERMS: PROD. 779S; LAB I.D. 8518009
APPROVALS: MG VP

AMC INTERNATIONAL MINERALS & LPLIAICAL CORPORATION
TECHNICAL SERVICES LAB REPORT
MRL Waste Water 2 SAMPLE DESCRIPTION DATE RECEIVED /21/85
SAMPLE ORIGIN Mineral Research Lab, IMC Spruce Pine, NC
REQUESTED BY Roy E . Riddle cc: Dewey Hall, Cliff Kangas
FORM 0-2090
PRINTED IN US.A.
SERVICE PERFORMED Total Solids, Fluoride, Ca, Si and Semiquantitatiye analysis
for major and minor elements in total solids
COMMENTS: Sample of waste water from quartz purification process.
(Analysis reported on a well mixad sample.)
RESULTS:
QUANTITATIVE ANALYSIS
Fluoride 0.45 %
Ca • 0.62
Si 0.22
Total Solids 1.86%
SEMIQUANTITATIVE ANALYSIS For Major & Minor Elements
The following are reported as oxides of the elements
as found in the above reported total solids.
Ca Principal Constituent
Si 25. %
Al 3.5
Mg 2.
Na 0.4 h G
Fe .6
Ba .02
Mn .015
Ti .05
Sr .03
N�5�
Cr .002
Cu <, 001
Ni <.005
Zr <.005
K <t5
3/04/85 Q^^^ �' lit y ?I'
DATECOMPLETED CERTIFIED BY DATE /
SUPERVISOR - TECHNICAL SERVICES
DATA COORDINATION AND TRANSMITTAL
SAMPLE NO.
i :11•
CUSTOMER IMCORE
PI4l6E No. 7 7 9 S
DATE 3/13/85 APPROVED BY DATE
OUIS W. FERRARA, MANAGER
S 1 - A-' 9 TECHNICAL SERVICES
RESULTS If HAVE (DATE 3/14/85 ) 0 HAVE NOT BEEN TRANSMITTED VERBALLY

INTERNATIONAL MINERALS & ui,L'MICAL CORPORATION
TECHNICAL SERVICES LAB REPORT
MRL Waste Water2/21/85
SAMPLE DESCRIPTION DATE RECEIVED
SAMPLE ORIGIN Mineral Research Lab, IMC Spruce Pine, NC
REQUESTED BY Roy E . Riddle cc: Dewey Hall , Cliff Kangas
SERVICE PERFORMED Toxic inorganic heavy metals as reported in non -filterable
solid portion of the sample.
COMMENTS: Sample of waste water from quartz purification process.
M
RESULTS:
NON -FILTERABLE SOLIDS
Ag < , l mg/11j
Ba 15 V
Cr 12 6
Cd <.l M
Pb 1.7 u
As 1.5 k
Se <. 0 2 M MAR 255
Hg < . 01 of TS &ENGINEERING
PERM} ,
FORM 0-2W
PRINTED IN U.S.
DATECOMPLETED' 3/14./85 CERTIFIED BY DATE
SUPERVISU — TECHNICAL S VICES
DATA COORDINATION AND TRANSMITTAL
SAMPLE NO. 8518009
CUSTOMER IMCORE
Project 7795
:IWM ^ NO.
DATE 3 / 13/ 8 5 APPROVED BY DATE Z__
LOUIS W. FERRARA, MANAGER
S 1 A 8 TECHNICAL SERVICES
3/14/85
RESULTS ZI HAVE (DATE 1C3HAVE NOT BEEN TRANSMITTED VERBALLY

MC INTERNATIONAL MINERALS &—,MICAL CORPORATION
TECHNICAL SERVICES LAB REPORT
MRL Waste Water 2/21/85
SAMPLE DESCRIPTION DATE RECEIVED
SAMPLE ORIGIN Mineral Research Lab, IMC Spruce Pine, NC
REQUESTED BY Roy E . Riddle cc: Dewey Hall, Cliff Kangas
SERVICE PERFORMED Toxic inorganic heavy metals as reported below in the
filterable portion of the sample.
COMMENTS: Sample of waste waters from quartz purification process.
M
RESULTS
FILTEp,7�TE
Ag
<.1 mg/1
Ba
<1
Cr
<.O1
Cd
<.1
Pb
<.1
As
< . 01 < 01
Hg
<.01
`
Se
<.02
25 lga5
Y
DATE COMPLETED 3/12/85 CERTIFIEDBY DATE
SUPERVISOR — TECHNICAL SERVICES
DATA COORDINATION AND TRANSMITTAL
SAMPLE NO. 8518009
CUSTOMER
Project
Its rOlCE NO.
DATE 3/13/85
S 1 A 8
RESULTS q. HAVE (DAi✓c 3/14/85
IMCORE
779S
APPROVED B DATE
LOUIS W. FERRARA, MANAGER
TECHNICAL SERVICES
_) ❑ HAVE NOT BEEN TRANSMITTED VERBALLY
FORM n-wo-
PRINTED IN UL

. a
1MC INTERNATIONAL MINERALS & 61ILIAICAL CORPORATION
TECHNICAL SERVICES LAB REPORT
MRL Waste Water 2/21/85
SAMPLE DESCRIPTION DATE RECEIVED
SAMPLEORIGIN Mineral. Research Lab, IMC Spruce Pine, NC
REQUESTED BY Roy E. Riddle cc: Dewey Hall, Cliff Kangas
SERVICE PERFORMED Toxic inorganic heavy metals as reported below in the
filterable portion of the sample.
COMMENTS: Sample of waste waters from quartz purification process.
w
RESULTS:
FILTIE T,E
Ag <.1 mg/l
Ba <1
Cr <.O1
Cd <.1
Pb <.l
As <.01
Hg <.Ol
Se <.02 - {
�5 v5
eE
DATECOMPLETED 3/12/85 CERTIFIEDBY DATE
SUPERVISOR - TECHNICAL SERVICES
DATA COORDINATION AND TRANSMITTAL
SAMPLE NO. 8518009
CUSTOMER IMCORE
Project 779S
MVaCE NO.
DATE T 3/13/85
S 1 A 8
RESULTS M HAVE (DATE
3/14/85
FORM 0+ 9001
PRINTED IN U.:.
APPROVED B DATE
l/t'/ems'
LOUIS W. FERRARA, MANAGER
TECHNICAL SERVICES
1 ❑ HAVE NOT BEEN TRANSMITTED VERBALLY