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HomeMy WebLinkAboutWQ0019960_Annual Report_20120215ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Marion Total Dry Tons Applied (Annual): 15.06 Permit #: WQ0019960 Cation Exchange Capacity (non 503 only): 9 ,a 'eE� �g 20 Ashe'Ale Regional Office sieve oifPT Pro-tGGfIn® CITY OF MARION, NC 2011 ANNUAL REPORT LAND APPLICATION PROGRAM NC PERMIT NO. WQ0019960 F, Ely 1ritermation PrOc�-ssona tani'k DtNQi OG ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Marion Total Dry Tons Applied (Annual): Permit #: WQ0019960 Cation Exchange Capacity (non 503 only): Operator: James Fisher Owner: James Fisher Predominant Soil Series: Acres Used: 4.3 Acres Permitted: 4.3 Site #: F-02 Field #: 3.77 Braddock F-02 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): I-RUPWITI Com- posite Date W BOB Total Phos- �phorusMEEEEEEEEEEE Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 11 2 3 4 5 j 6 71 8 9 10 1 11 12 DT/Ac./ o App. Event 0.88 " Arsenic 1 0.009 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.009 Cadmium 0.004 0.000 0.000 1 0.000 0.000 0.0060 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Copper 0.620 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.620 Chromium 0.102 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.102 Lead 0.096 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.096 Mercury 0.004 0.000 0.000 0.000 0.000. 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Molyb- 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 denum Nickel 0.039 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.039 Selenium 1 0.005 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.005 Zinc 0.210 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 6:2fi6, Total Phos- 29.959 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 29.959 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". 1-11 t •-N,E Signature of Lan Applier Date DENR FORM MFLSF (1212006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Marion Total Dry Tons Applied (Annual): 11.29 Permit #: WQ0019960 Cation Exchange Capacity (non 503 only): Operator: James Fisher Owner: James Fisher Predominant Soil Series: Hayesville Anvac ITcari- 8.2 Acres Permitted: 8.2 Site #: F704 Field #: F-04 Residual An Com- posite Date 8/25/11 % Solids 4.63 Arsenic 5 Cadmium 2 Copper 354 Chromium 58 Lead 55 Mercury 2.1 ,..j. denum 10 Nickel 22 Selenium 3 Zinc 1291 Total Phos- 1710C __.l 11r 1 Dhhnrna nea ma/ka_ °/„ Solids use Raw Percent #): as ilaLa kiicavy 2 3 4 5 6 7 8 9 10 11 12 9b Annual Heavy Metal Wield Loaaings <<,aIcUMMU III .ua,a1691-1• 11 12 Total 1 2 3 4 5 6 7 8 9 10 c DT/Ac./ r. App. in .. Event 1.38 Arsenic 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Cadmium 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0:000 0.000 0.000 0.000 0.006 Copper 0.975 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.975 Chromiu 0.160 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.160 Lead 0.151 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.151 Mercury 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 ;006rc4 0.006-Ft 7,(! Molyb- 0.028 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.028 denum Nickel 0.061 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.0 1 Selenium 0.008 0`000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.008 Zinc 0.330 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 -9339 Total Phos- 47.093 0.000 0.000 0.000 0.000 0.000 0.000 0:000 0.000 0.000 0.000 0.000 47.093 - - __-horus_-- - "I of law, that this document was prepared under my direction or supervision in accordance certify, under penalty to that personnel properly gathered and evaluated the information submitted. with a system designed assure qualified for submitting false information, including the possibility of fines and I am aware that there are significant penalties imprisonment for knowing violations". '� i-3v-►a Sign ture of Land A lier Date DENR FORM MFLSF (12/2006) 9,1, ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT -APPLICABLE. 9960 Field #• K-01 Acres Utilized: 16 Facility Name: City of Marion WQ Permit ": WQ001 Acres Permitted: 16 Land Owner: Anna Deebold Annual Dry Tons Applied: 37.6488 Site #: K-Ol Predominant Soil Series: Hayesville Cation Exchange Capacity (non 503): Operator: Mario Deluca 202 Crop 2 Name: Crop 2 Max. PAN: Crop 1 Name: Fescue Crop 1 Max. PAN: Volume applied PP Volume 'Soil Residual Sources Precip. Cond. Y 3 ' < o :° w `; TKN z a o El Nitrate and PAN Applied Name of Crop Type Receiving Residual O (enter one) Solids/ % Applied per (NPDES #, WQ#, D Past 24 = i; m _ CD m ca0o a Nitrite (Ibs/acre) Application o Liquid Solids Acre Fert., Animal We ; Hrs. a mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 p Cu. Yds Gallons (Dry Tons/Ac) Waste, etc) inches Moist) 0 mglkg 0.3 49000 12500 1 80.950 1 NA I Fescue 9-2011 195000 4.63 2.353 W00019960 dry 0 s 0.5 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.(00 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 o00 0.000. 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form)' Cu Cr Ni I Se Zn P 80.950 0.000 Lime Applied Cd TOTALS: 0 195000 As 0.024 ✓ 0.009 66 0.273 0.259 010 047 0.104 0.014 8-5ffJ 80.473 Date lbs/ac Annual Ibs/acre 1204 0.538 1.801 V 0.088 2.372 0.845 0.218 35.306 �. 3-5-8�1 40 Prior Years Cumulative Ibs/ac 0.123 0.099 Current Cumulative Ibs/ac 0.147, 0.108 15.870 0.811 2.060 0.098 2.419 0.949 0.232 / 89 2498 I/ Permitted C. P. L. R.**** 36 34 WA- l 267 ]5 NA 374 202 Permit PAN Limit lst/2nd Crop -t,33$ Mai in accordance with a system designed to assure that "I certify, under penalty of law, that this document was prepared under my direction or supervision are significant penalties for submitting false qualified personnel properly gathered and evaluated the information submitted. I am aware that,there information, including the possibility of fines and imprisonment for knowing violations." INC - Incorporation *Application Method: S - Surface, IN - Injection, �� '� d I **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 �✓ *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, Signature of Land Applier Date aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Acres Utilized• 117 Facility Name: City of Marion. WQ Permlt #:. WQ0019960 Field #. F-01 Land Owner: James Fisher Annual Dry Tons Applied: 15.0595 Site #: F-01 Acres Permitted: 13.7 Operator: James Fisher Predominant Soil Series: Braddock Cation Exchange Capacity (non 503): d-v"., 1 N9mv• Cron I Max. PAN: 239 Crop 2 Name: Crop 2 Max. PAN: " Volume appliedL46 Volume Residual Sources Soil Cond. Precip.. K vD < o X fD z D • 9 o Nitrate PAN Applied Name of Crop Type Receiving Residual .c C (enter one) Solids/Applied per (NpDES #, WQ#, (Dry. Past 24 -0 r? 0 - w �. TKN o0 0 ' and (Ibs/acre) Application 0 QLiquid Acre Fert., Animal Wet Hrs. a 'o -• ' w Nitrite Crop 1 Crop 2 Crop 1 Crop 2 Cu. Yds Gallons(Dry TonslAc) Waste, etc) Moist) inches 0 mglkg mg/kg mglkg 10-2011 78000 1.099 W00019960 dry 0 s 0.5 0.3 49000. 12500 1 37.816 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0:000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 0 78000 As Cd Cu Cr Pb H Mo Ni Se Zn P 37.816 0.000 Lime A lied Annuallbs/acre 01• .01 0.004 0.778 0.127 0.121 0.005 0.022 0.048 0.007 0.264 37.586 / 1/ Date lbs/ac Prior Years Cumulative Ibs/ac 0.041 0.022 3.4 1.888 0.577 0.31 0.17 0.289 0.043 10.913 Current Cumulative Ibs/ac 0.052. " 0.026 4.178 2.015 0.698Y 0.315 0.192 0.337 0.050 11.177 Permitted C. P. L. R.**** 36 34 -NA - 3-3-9- 26.7 1-5 NA 374 89 - 2498 Permit PAN Limit lst/2nd Crop I ,33F1 239 "I certify, under penalty of law, that this document was prepared under my alrecnon or supervlsluu in nucu, uant-c w,.., a ayJ I... •b- qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land. Applier Date *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 *,** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. F' Id # Acres Utilized: AA Facility Name: City of Marion WQ Permit #: WQ0019960 e - F-02 Land Owner: James Fisher Annual Dry Tons Applied: 3.7649 Site #: F-02 Acres Permitted: 4_3 Operator: James Fisher Predominant Soil Series: Braddock Cation Exchange Capacity (non 503): _ Crop 1 Name: Fescue Crop 1 Max. PAN. 239 Crop 2 Name: Crop 2 Max. PAN: O QLiquid Volume applied pp enter one Solids/ ( ) Cu. Yds Gallons u /� Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Wet Moist) Precip. Past 24 Hrs. inches Y cis E• o 0- o o < o 7d w °» _ R `0 co * °=. 0 TKN mg/kg z a - o 9 °o o cc M mglkg Nitrate and Nitrite mg/kg PAN Applied (1bs/acre) Name of Crop Type Receiving Residual lication Application Crop 1 Crop 2 Crop 1 Crop 2 4.63 0.876 W00019960 dry 0 s 0.5 0.3 49000 12500 1 30.121 NA Fescue 10-2011 19500 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 - O. 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 19500 Annuallbs/acre Prior Years. Cumulative lbs/ac Current Cumulative lbs/ac Permitted C. P. L. R.**** As 0.009 0.079 0.088 36 Cd 0.004 0.1.5 0.154V 34 Cu 0.620 2.44 3.060 -NA I Cr 0.1.02 1.2,63 1.3-65 6 Pb 0.096 0.402 0.498 267 H 0.004 0.022 0.026v7 15 Mo 0.018 0.119 0.137. 137. NA Ni 0.039 0.201 0.240 374 Se 0.005V 0.029, 0.034 89 Zn 0.210 7.601 7.811 2498 P 30.121_1 0.000 29.959 V Lime Applied Date lbs/ac to accnrP that Permit PAN Limit lst/2nd Crop an rstFr 239 ...1.. ...... i r:*{, n .+- dPeron.,A "I certify, under penalty of law, that this document was' preparea under my u„ -L uu w aupa.- .,a..,.r .•. - ------ --__ _ ___ qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 7w 1 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. WQ Permit #: WQ0019960 Field #: F-04 Acres Utilized: 8.2 Facility Name: City of Marion - Acres Permitted: 8.2 Land Owner: James Fisher Annual Dry Tons Applied: 11.2947 Site #: 'F-04 - Operator: James !Fisher Predominant Soil Series: Hayesville Cation ExchangeCapacity (non 503):- Cro 1 Max PAN: 202 Crop 2 Name: Crop 2 Max. PAN: Crop 1 Name: Fescue P Residual Sources (NPDES #, WQ#, . Fert., Animal Waste, etc) Soil Cond. (Dry, Wet,Hrs. Moist) Precip. Past 24 inches a K r? 0 oa o < o � w 0 _. K CD * - * 0 TKN mg/kg z a 9 o o ? �, mg/kg ! Nitrate and Nitrite mg/kg PAN Applied (Ibs/acre) Name of Crop Type Receiving Residual Application o Q Volume applied PP (enter one) Solids/ Liquid Cu. Yds Gallons % Solids Volume Applied per Acre .(DryTons/Ac) Crop 1 Crgp 2 NA Crop 1 Fescue Crop 2 10-2011 58500 4.63 1.377 W00019960 dry 0 s 0.5 0.3 49000 12500 1 47.385 0.000 - 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 CIAO Residuals Applications totals Cu Cr !0.975 0.160gg on FORM Pb FSF 13 supp (:a ach FORM Mo Ni 0.028. 0.061 FSF supp Se to this forni): Zn P 47.385 0.000 W-4-3-� 202 Lime A lied Date lbs/ac FOTALSI 0 5850o Annuallbs/acre As 0.014 Cd 0.006 Prior Years Cumulative lbs/ac 0.044 0.058 36 0.025 0.031 34 4.368 '5.343 � 1.86 2.020 1338 0.121 0.149 NA 11 0.304 0.365 374 Current Cumulative lbs/ac Permitted C. P. L. R.**** Permit PAN Limit Ist/2nd Crop C33�i "I certify,under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there .are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0:5, Injection/Incorporation - 1.0 *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, Signa ure of Land Applier Date aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate \ DENR FORM FSF (12/2006) Page: I of 2 Report Number: 11-241-0202 Account Number: 46381 Submitted By: ZACH KEY Send To: SOUTHERN SOIL BUILDERS DENNIS KEY 958 HOOTS ROAD ROARING RIVER, NC 28669 wwwKaleadem.com A&L Eastern Laboratories, Inc. 7621 Whitepine Road Richmond, Virginia 23237 (604) 7434401 Fax (804) 271-6446 Project: MARION NC CERT#257 REPORT OF ANALYSIS Date Sampled: 8/25/2011 10:00:00 Lab Number: 83776 Date Received: 08/29/2011 00:00 Sample Id: MARION Date Reported: 09/01/2011 Total Solids * 4.63 46300 100.0 JM Uti/ZV/ZU11 1b:U4 Moisture * 95.37 100.0 JM 08/29/2011 15:04 Total Kjeldahl Nitrogen . 4.90 49000 10.0 JM 08/30/2011 08:44 Total Phosphorus 1.71 17100 100 KM 08/30/2011 10:00 Total Potassium 0.41 4100 100 KM 08/30/2011 10:00 Total Sulfur 0.89 8900 100 KM 08/30/2011 10:00 Total Calcium 1.40 14000 100 KM 08/30/2011 10:00 Total Magnesium 0.49 4920 100 KM 08/30/2011 10:00 Total Sodium 0.13 1250 100 KM 08/30/2011 10:00 Total Iron 20600 1 KM 08/30/2011 10:00 Total Aluminum 28500 10 KM 08/30/2011 10:00 Total Manganese 349 1 KM 08/30/2011 10:00 Total Copper 354 1 KM 08/30/2011 10:00 Total Zinc 1020 1 KM 08/30/2011 10:00 Ammonia Nitrogen 1.25 12500 10.0 JM 08/30/2011 08:44 Organic N 3.65 36500 10.0 08/30/2011 08:44 Nitrate+Nitrite-N <1.00 1.00 JM 08/30/201108:45 Total Cadmium 2.0 1.0 KM 08/30/2011 10:00 All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. JM-2Dlquu SM-2540G SM-4500-NH3C-TKN SW 6010C SW 6010C SW 6010C SW 6010C SW 6010C SW 6010C SW 6010C SW 6010C SW 6010C SW 6010C SW 6010C SM-4500-NI3C CALCULATION SM-450ONO3F SW 6010C Debbie Holt Page: 2 of 2 Report Number: 11-241-0202 Account Number: 46381 Submitted By: ZACH KEY Send To: SOUTHERN SOIL BUILDERS DENNIS KEY 958 HOOTS ROAD ROARING RIVER, NC 28669 �L A&L Eastern Laboratories, Inc. 7621 Whitepine Road Richmond, Virginia 23237 (604) 743.6401 Fax (604) 271-WS www.aleastern.com Project: MARION NC CERT#257 REPORT OF ANALYSIS Date Sampled: 8/25/2011 10:00:00 Lab Number: 83776 Date Received: 08/29/2011 00:00 Sample Id: MARION Date Reported: 09/01/2011 Total Chromium 58 5 KM 08/30/2011 1U:UU SW tiuIUU Total Nickel 22 5 KM 08/30/2011-10:00 SW 6010C Total Lead 55 5 KM 08/30/2011 10:00 SW 6010C Total Arsenic 5.0 1.0 KM 08/30/2011 10:00 SW 6010C Total Mercury 2.1 0.4 KM 08/30/2011 12:00 SW-7471 B Total Selenium 3.0 1.0 KM 08/30/2011 10:00 SW 6010C pH (Standard Units) * 7.73 JM 08/30/2011 09:00 SW-9045D Total Molybdenum 10 5 KM 08/30/2011 10:00 SW 6010C Comments: QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Se". ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt PAN Mineralization as decimal ITotal dry tons/year lAcres Applied on 1 Rate 0.3 TKN 49000 NH3 1 12500 NO3 1 1 NO2 1 0 % Solids 0.0463 1 166.9 PAN Surface 17201 mg/kgmg/kg 34.402 lbs/dry ton ✓ 5741.694 Ibs total PAN 73.61146 Ibs PAN/acre PAN Injection 23451 mg/kgmgikg 46.902 lbs/dry ton 7827.944 Ibs total PAN 100.3683 1 lbs PAN/acre Dry Tons/1000 gal. 0.193071 1st year PAN Surface lbs. 5741.6938 1st year PAN Injected lbs. 7827.9438 lbs./acre Surface 73.61145897 lbs./acre Injected 100.3582538 MR(TKN-NH3)+ + .5(NH3)+NO3+NO2 =mg/kg mg/kg x .002=lbs/dry ton MR(TKN-NH3) + l(NH3)+NO3+NO2 =mg/kg mg/kg x .002 =Ibs/dry ton 1000 X 8.34 X %solids X sp. gravity "=dry tons/1000gal." 2000 SAR Sodium Absorption Ratio Na(Mg/L) Ca(Mg/L) M M /L Na: Sodium (Mg/L) Equivalent weight: 23 57.8 648.2 227.8 Ca: Calcium (Mg/L) Equivalent weight: 20 Mg : Magnesium (Mg/L) Equivalent weight: 12 Na (ME) Ca (ME) M ME 2.513043 32.41 18.98333 Milli Equivalent = Mg/L / Equivalent weight The amour amount of E SAR= Na Milli Equivalent/[0.5 X (Ca Milli Equivalent + Mg Milli equivalent)]0.5 power Permitting � SAR = 0.495749 (From Mg/L entered above) SAR= 0.495164 (From ME entered below) Na (ME) 1 Ca (ME) 1 Mg (ME) 2.51 32.41 18.98 ' Environmental Testing Solutions, Inc, Project name: City of Marion Collection date: 22-Aug-1 I Date received: 22-Aug-I1 Sample identilieation: CC SE~ - #1 - Grab Certificate of Analysis 110 Box 7565 Asheville, NC 28802 Phone: (828) 350-9.16.1 l ax: (828) 350-9368 Project number: 110822.500 Sample: number: 86856 Dale I'aratueter Method Result ItL Units Analyze) Analyst Fuotitoles Percent Solids SM 2540 G 5.3 % 22-Aub-II CDJ Mulit Ie Tube Fermentation Procedure SM 9221-E 41870 9.5 MPN 22-Aub-I KFK Sample identification: CC SF - #2 - Grab Sample number: $6857 -- Date Analyst Footnotes Parameter Method Result RL Units Analyzed y I�rcent Solids SM 2540 G 5.3 % 22-Aug-I I CDJ Whi )le I ube Fermentation Procedure SM 9221-E 17490 9.5 NIPN 22-Aub-i i KI K Sample identilictttiun: CC SF - #3 - Grab Sample number: 86858 Date Parameter Method Result RL Units Aual Dato Analyst Footnotes Percent Solids SM 2540 G 5.3 % 22-Aug-I I CDJ t\1ulit le Tube Fermentation Procedure SM 9221-E 68900 9.5 MPN 22-Aub-1 I K F K Sample identilicalion: CC SF - #4 - Grab Sample number: 86859 Parameter Method Result IDale Analyst Footnotes tl Units Analyzed y Percent Solids SM 2540 G 5.3 % 22-Aub-I I CDJ molit Ic Tube Fermentation Procedure SM 9221-E 174900 9.5 MPN 22-Au9-1 i KFK Footnotes: RL = Reporting Limit. Values are reported down to the Reporting Limit only. Date reviewed: NC Certification Number: 600 Data reviewed by: _ Kelley E. Keenan SC Cerlillcation Number: 9905:3 NC Drinking Water Cel-611CtitiOn Number: 37786 Signautrc: 'this report should not be reproduced, exept in its entirety, without the written consent of Environmental Testing Solutions, Inc The results in this report relate only to the samples submitted for unalysis. 1 .112 y9 h r+tY d r 14 Environmental Testing Solutions, Inc. Project name: City of Marion Collection date: 29-Aug-11 Date received: 29-Aug-11 Sample identification CC SF-#5-Grab Certificate of Analysis PO Box 7565 Asheville, NC 28802 Phone: (829)350-9364 Fax: (828)350-9368 Project number: 110829.500 Sample number: 87056 st Footnotes Parameter Method Result RL Units Analyzed Date Analyst Percent Solids SM 2540 G 4.0 % 29-Aug-I I uui Mulit le Tube Femientation Procedure SM 9221-E 880000 7.2 MPN 29-Aug-I I KEK Sample identification: CC SF - #6 - Grab Sample number: 87057 Date Analyst Footnotes Parameter Method Result RL Units Analyzed y Percent Solids SM 2540 G 4.0 % 29-Aug-It CDJ �Mulit le Tube Fermentation Procedure SM 9221-E 960000 7.2 MPN 29-Au6-11 KEK Sample identification: CC SF - #7 - Grab Sample number: 87058 st Footnotes Parameter Method Result RL Units Analyzed Date Analyst Percent Solids SM 2540 G 4.0 % 29-Aug-I I CDJ Mulit le Tube Fermentation Procedure SM 9221-E 3680000 7.2 MPN 29-Aug-I I KEK 22-Jo/2. y U D Footnotes: RL = Reporting Limit. Values are reported down to the Reporting Limit only. Date reviewed: NC Certification Number: 600 Data reviewed by: Kelley E. Keenan SC Certification Number: 99053 NC Drinking Water Certification Number: 37786 Signature: This report should not be reproduced, exept in its entirety, without the written consent of Environmental Testing Solutions, Inc. The results in this report relate only to the samples submitted for analysis. Geometric mean calculation sheet 41870 17490 68900 174900 880000 960000 3680000 geomean 223012.4 Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name Biosolids Permit Number Date Digester Temperature Sampling Date/Time Sampled By Analysis Date/Time Analyzed By Sample Volume Total Solids Beginning Temperature End Temperature Dissolved Oxygen Level /mn/11 Cor enin Creek WQ 0019960 8/10/2011 25 8/10/11 0805 Lee Estes 8/10/11 1100 R. Carter 1000 0.92 25 25 9 7.5 7.27 7.18 7.09 6.76 6.63 s 6.44 6.26 5.87 5.49 5.16 4.83 4.61 4.44 4.27 4.11 rilliliters Yo Dry Solids degrees Celsius degrees Celsius Slope: 0.2 Intercept: 7.7 Correlation Coefficient: 1.0 Oxygen Uptake Rate: 14.68 mg Oxygen/hr Ambient Specific Oxygen Uptake Rate: 1.60 mg Oxygen/g/hr Average Temperature: 25 degrees Celsius Temperature Correction Factor: 0,783526166 f Temperature Corrected Specific Oxygen Uptake Rate: 1.25 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name. Biosolids Permit Number Date Digester Temperature Sampling Date/Time Sampled, By Analysis Date/Time Analyzed By Sample Volume Total Solids Beginning Temperature End Temperature Dissolved Oxygen Level 7.85 7.41 7.12 6.98 6.75 6.64 6.39 6.21 6.06 5.78 5.64 5.44 5.22 5.03 4.89 4.69 Corpening Creek WQ 0019960 8/12/2011 24 8/12/11 0805 Lee Estes 8/12/11 1100 R. Carter 1000 0.91 25 25 Slope: 0.2 Intercept: 7.6 Correlation Coefficient: 1.0 milliliters % Dry Solids degrees Celsius degrees Celsius Oxygen Uptake Rate: 11.92 mg Oxygen/hr Ambient Specific Oxygen Uptake Rate: 1.31 mg Oxygen/g/hr Average Temperature: 25 degrees Celsius Temperature Correction Factor: 0.783526166 Temperature Corrected Specific Oxygen Uptake Rate: 1.03 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 0 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number Date Digester Temperature Sampling Date/Time. Sampled By Analysis Date/Time Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level 6 5.68 5.37 5.07 4.8 4.54 4.23 Corpening Creek WQ 0019960 8/15/2011 23 8/15/2011 0750 Lee Estes 8/15/201.1 1035 R, Carter 1000 0.89 25 25 d2.62.62 \ 5 'nilliliters Yo Dry Solids 9egrees Celsius Degrees Celsius Slope: 0.3 Intercept: 6.2 Correlation Coefficient: 1.0 Oxygen Uptake Rate: 15.89 mg Oxygen/hr Ambient Specific Oxygen Uptake Rate: 1.79 mg Oxygen/g/hr Average Temperature: 25 degrees Celsius Temperature Correction Factor: 0.783526166 Temperature Corrected Specific Oxygen Uptake Rate: 1.40 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name Biosolids Permit Number Date Digester Temperature Sampling Date/Time Sampled By Analysis Date/Time Analyzed By Sample Volume Total Solids Beginning Temperature End Temperature Dissolved Oxygen Level Corpening Creek WQ 0019960 8/16/2011 22 8/16/2011 0725 Lee Estes 8/16/2011 1020 R. Carter 1000 0.91 25 25 Im9/I) 7.79 7.45 7.02 6.59 6.2 5.84 5.48 5.18 4.96 4.78 4.6 4.43 4.25 4.06 3.9 3.73 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: 0.3 7.4 1.0 ;7 > I \r 5 i milliliters % Dry Solids degrees Celsius degrees Celsius 16.02 mg Oxygen/hr 1.76 mg Oxygen/g/hr 25 degrees Celsius 0.783526166 Temperature Corrected Specific Oxygen Uptake Rater 1.38 mg Oxygen/g/hr Instructions: Enter Data in the Blue'Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 i 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name Biosolids Permit Number Date Digester Temperature Sampling Date/Time Sampled By Analysis Date/Time Analyzed By Sample Volume Total Solids Beginning Temperature End Temperature Dissolved Oxygen Level CorEening Creek WQ 0019960 8/17/2011 23 8/17/2011 0835 Lee Estes 8/17/2011 0900 R. Carter 1000 0.92 25 25 7.05 6.84 6.61 6.48 6.28 6.08 5.9 5.72 5.53 5.34 5.16 4.99 4.8 4.61 4.42 4.28 Slope: 0.2 Intercept: 7.0 Correlation Coefficient: 1.0 milliliters % Dry Solids degrees Celsius degrees Celsius Oxygen Uptake Rate: 11.09 mg Oxygen/hr Ambient Specific Oxygen Uptake Rate: 1.20 mg Oxygen/g/hr Average Temperature: 25 degrees Celsius Temperature Correction Factor: 0.783526166 Temperature Corrected Specific Oxygen Uptake Rate: 0.94 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 ;5 6 7 8 9 10 11 12 13 14 1.5 Specific Oxygen Uptake Rate SOUR Facility Name; Biosolids Permit Number; Date: Digester Temperature: Sampling Date/Time, Sampled By Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level Cor2ening Creek WQ 0019960 8/18/2011 23 8/18/2011 0819 Lee Estes 8/18/2011 1005 R. Carter 1000 0.95 25 25 7.78 7.47 7.29 7.12 6.94 q16.78 6.4 6.26 6.09 5.93 5.75 5.54 5.39. 5.19 Slope: I ntercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: 0.2 7.7 1.0 -milliliters Dry Solids legrees Celsius legrees Celsius 10.65 mg Oxygen/hr 1.12 mg Oxygen/g/hr 25 degrees Celsius 0.783526166 Temperature Corrected Specific Oxygen Uptake Rate:' 0.88 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. i Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number. Date Digester Temperature Sampling Date/Time Sampled By Analysis Date/Time Analyzed By Sample Volume Total Solids Beginning Temperature End Temperature Dissolved Oxygen Level Cor enin Creek WQ 0019960 8/19/2011 23 8/19/2011 0753 Lee Estes 8/19/2011 0925 R. Carter 1000 0.96 25 25 7.321 8.06 5.98 5.82 5.29 5.12 4.94 4.76 4.59 Slope: 0.2 Intercept: 7.1 Correlation Coefficient: 1.0 milliliters % Dry Solids degrees Celsius degrees Celsius Oxygen Uptake Rate: 11.55 mg Oxygen/hr Ambient Specific Oxygen Uptake Rate: 1.20 mg Oxygen/g/hr Average Temperature: 25 degrees Celsius Temperature Correction Factor: 0.783526166 Temperature Corrected Specific Oxygen Uptake Rate: 0.94 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Marion WWTP Name: City of Marion, WWTP Monitoring Period: From 1/l/201 1 To Q Permit Number: •�j NPDES Number: /201 1 WQ0019960 NCO031879 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ 1 Alt B (Alk Treatment) 0 Alt. C (Prior Testing)❑ A1t.D (No Prior Test) ❑ Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thetmophilic ❑ Beta Ray ❑ Gamma Ray ❑ Pasteurization ❑ Class B: Alt. (1) Fecal Density❑ Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ Composting ❑ Aerobic Digestion ❑ Anaerobic Digestion: ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density Number o dense- es Frequency of Analysis Sample Type Analytical Tech- nioue Minim Geo. Mean axim Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN 17490 223012 3680000 MPN 0 7 GRAB sm9221 CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal colifonn) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt. l (VS reduction) ❑ Alt., 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ lAlt. 4 (Spec. O, uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ lAlt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) ❑ No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) 1 "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." LAPA.1 CAqUf--- WI-)ir Dennis Key Southern Soil Builders, Inc. Prepar r N e and Title (type or print) Land Applier Name and Title (if applicable)(type or print) 2 /2 �,,_, I- 3,J )u 1, gnature of Preparer* Date Sig&ture of La Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) Report Number: 11-332-0721 n Account Number: 46381L Send To: SOUTHERN SOIL BUILDERS www.aleastem.com DENNIS KEY 958 HOOTS ROAD ROARING RIVER NC 28669 Date Received: 11/28/2011 Date Of Analysis: 11/29/2011 A &L Eastern Laboratories, Inc. - 7621 Whitepine Road Rlchmond, Virglnla 23237 (804) 743-9401 Fax (804) 271-6446 Grower: Submitted By: Z KEY SOUTHERN SOIL BUILDERS Farm ID: SOIL ANALYSIS REPORT Analytical Method(s): Mehlich 3 Date Of Report: 11/30/2011 Organic Matter Phosphorus Potassium Magnesium Calcium Sodium pH Acidity C.E.0 Sample ID - Lab % Rate ENR Mehlich 3 Reserve K Mg Ca Na Soil Buffer H Field ID Number Ibs/A ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate pH Index meq/100g meq/1009 K1 00921 2.6 M 93 87 H 34 VL 164 H 806 M 14 VL 6.1 6.84 0.9 6.4 NC=72 NC=17 K2 00922 3.7 M 113 149 VH 63 L 148 H 1025 M 19 VLJ 5.9 6.79 1.4 8.0 NC=124 NC=32 F1 00923 2.5 L 92 54 H 24 VL 196 H 739 M 14 VL 6.6 6.90 0.3 5.8 = NC 45 NC F2 00924 2.7 M 94 127 VH 32 VL 244 H 857 M 33 L 6.8 6.91 0.2 6.7 NC=106 NC=16 F3 00925 2.0 L 82 125 VH 31 VL 180 H 703 M 12 VL 6.3 6.87 -J 0.6 5.8 NC=104 NC=16 Percent Base Saturation Nitrate Sulfur Zinc Manganese Iron Copper Boron Soluble Salts Chloride Aluminum Sample ID Field ID K Mg Ca Na H NO3N S Zn Mn Fe Cu B SS Cl Al % % % % % ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ms/cm Rate ppm Rate ppm K1 12 L 6.3 H 26 H 99 VH 3.0 H 0.3 VL 0.09 VL 1.4 21.4 63.0 1.0 13.8 NC=30 NC=157.5 NC=163 NC=150.0 K2 11 L 9.9 VH 22 H VH H L VL 2.0 15.4 64.1. 1.0 17.1 Jill 13.4 10.4 10.11 NC = 28 NC = 247.5 1 NC = 138 NC = 170.0 F1 9 VL 3.5 H 32 H 87 VH 2.5 H 0.3 VL 0.08 VL 1.1 28.2 63.7 1.0 5.9 NC = 23 NC = 87.5 NC = 200 NC = 125.0 F2 8 VL H H VH 3.3 H 0.3 VL 0.08 VL 1.2 30.3 64.0 2.1 2.9 14.4 123 1114 NC=20 NC=110.0 NC=144 NC=165.0 F3 7 VL 5.2 H 70 VH VH 3.7 VH L 0.07 VL 1.4 25.9 60.6 0.9 10.5 �107 10.4 NC = 18 NC = 130.0 NC = 438 NC = 185.0 Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This repon applies to sample(s) tested. Samples are retained a soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testinH (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions. ppm x 2 = Ibs/A, Soluble by: gwic IncIn G Analysis prepared by, A&L Eastern Laboratories, Inc C.E.C. -Cation Exchange Capacity. Salts mslcm x 640 =ppm. Pauric McGroary Report Number: 11-332-0721 f � Account Number: 46381 Send To: SOUTHERN SOIL BUILDERS www.aleastem m DENNIS KEY 958 HOOTS ROAD ROARING RIVER NC 28669 Date Received: 11128/2011 Date Of Analvsis: 11/29/2011 A&L Eastem Laboratories, Inc. 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-W1 Fax (80412714446 Grower: f Submitted By: Z KEY SOUTHERN SOIL BUILDERS Farm ID: SOIL ANALYSIS REPORT Analytical Method(s): Mehlich 3 Date Of Report: 11/30/2011 Sample ID Lab Organic Matter Phosphorus Potassium Magnesium Calcium Sodium pH Acidity C.E.0 % Rate ENR Mehlich 3 Reserve K Mg Ca Na Soil Buffer H Field'ID Number Ibs/A ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate pH Index meq/100g meq/100g F4 00926 3.1 M 100 94 H 52 VL 323 H 1114 M 14 VL NC = 78 NC = 27 7.1 0.0 8.5 Sample ID Percent Base Saturation Nitrate Sulfur Zinc Manganese Iron Copper Boron Soluble Salts -Chloride Aluminum K Mg Ca Na H NO3N S Zn Mn Fe Cu B SS Cl 'Al Field ID % % % % ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ms/cm Rate ppm Rate ppm F4 1.6 31.7 65.5 0.7 0.0 9 VL 5.9 H 40 H 98 VH 4.8 VH 0.5 L 0.1 VL NC = 23 NC = 147.5 NC = 250 NC = 240.0 - - --- -• — •,-ram • � �= P- n dvanauiv nuuiencs in the txplanatwn of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. H (High), VH (Very High). ENR - Estimated Nitrogen Release. by: p�za � GO-r 9 (milli equivalent per 100 grams). Conversions: ppm x 2 =Ibs/A, Soluble C.E.C. -Cation Exchange Capacity. Salts ms/cm x 640 =ppm. Analysis prepared by: A&L Eastern Laboratories, Inc. Pauric McGroary BP A. .-A lan11a lzlk! r'.e, r SOP 1.. Annual Land Application Certification Form, • Was a certification form submitted? :� Ve-5 • - Was lard application conducted during the reported year? y�f • How many dry tons and dry tons per acre were applied? Ibr; q • Were the applications within the permitted amount? OT �; w. • Verify P A;Ni if more than 10 tors/acre • Did it indicate compliance? ,ins • Was it signed by the appropriate people?P l' _ 7e-,5 2. iblonitoring • Were the analyses conducted at the required frequency? qMMPO sp-05 • Were the metals analyses reported -on the Residual Sampling Summary Form? IffiW V e"s ® Were the results reported in mg/lcg?4MVe-5 • . Weie the heavy metals within ceiling concentration permit limits?* qMW �s If no, were the lab analyses attached? y • Were all the required parameters tested? • Was TCLP analysis conducted?,' 3. Field Summary • Were the land application. events recorded on the Field Summary Forms?�W I q-5 • Was a p ield Summary Form submitted for each -field?yM \1-0-5 • Were all the residuals applied to permitted land?, ,5 • Were all the residuals applied from permitted sources?i.M qZ • Were the field loading rates for each metal and PAN calculated (year to date)?4& • Were the cumulative pollutant loading rates calculated? VW .,eS • Were the calculations correct?�-rrtl. • Were the PAN Ioading rates. within permit Iimits?�Nw Y`e'S • Were the heavy metal cumulative pollutant loading rates within permit limits? y ej • Were the residuals applied on a suitable crop? ,& • Were the applications conducted during the crop's growing season?f �ely • Were the Field Summary Forms complete?, 4. Pathogen and Vector Attraction Reduction • - Was a signed copy of the Patoven and Vector Attractio Reduction Form subnq ted� +�(� • Did the farm icatehe perio of cerage, fhe resi ua class, and the pathogen reduction alternative and the vector attraction re action option used'? •. Was the appropriate documentation to show pathogen and vector attraction reduction included in the report? • Was pathogen and vector attraction reduction demonstrated according to 40 CFR Part 503? qA •5e ' 5. Soil Tests • Was a Standard Soil Fertility Analysis conducted for each application field? y� 'e5 • Were the soil pH's 6.0 or greater for each application field? • Were the copper and Zinc indexes in the soil less than 3000 for each application field? 6. General __ _ btk all tsC- I#Ns S 64,Dw 301DO � 1' • Was the report in the propet format? • Were. any parts of the annual report missing?joW Nb t� • Was the report submitted on time? ,. ;Q,S * Any violations of ceiling concentrations should be reported to. Pretreatment for.. municipalities. only. 0► . Class B Pathogen Review Alternative 1- Fecal Coliform Density • Was the sampling conducted at the required frequency? Y/ e _5 • Were seven samples taken? je • Was the geometric mean calculated and done correctly? y25 • Did the results show compliance (less than either 2,000,000 MPN/gram of total solids or 2,000,000 Colony Forming Units/gram of total solids) I �I ZS Alternative 2 - Use of Process to Significantly Reduce Pathogens Lone of five) • Was the sampling conducted at the required frequency? Aerobic Digestion • Was it an aerobic process (Inspection)? • Were logs submitted showing time and temperature? • Were temperatures within range for complete time period? • Was the time and temperature between 40 days at 20°C (68T), and 60 days at 150C (590F)? Air DEying • Were residuals on sand beds or pave or unpaved basins for three months? • Was theambient.tempe'rature above 0°C (32T) for two months? • Were the residuals partially digested? • Were residuals exposed to atmosphere during two months above 0°C (riot snow covered)? Anaerobic Di eg sti"on • Was it an anaerobic process (Inspection)? • Were logs submitted showing time and temperature? • Were temperatures within range for complete time period? • Was the time and temperature between 15 days at 35°C (95T) to 55°C (13IT) and 60 days at 20°C (68o17)?'. Composting • Was it a. composting procedure (not natural decay under uncontrolled conditions)? • Were logs submitted showing time and temperature? • Was the temperature raised to 40°C (104°F) or higher and remained at 40°C (104T) for five days? • Did the temperature exceed 55°C (13IT) for four hours during the five-day period? Lime Stabilization • Was alkaline material added to residuals a form of lime (hydrated lime, quicklime, lime containing kiln dust or fly ash)? • Were logs submitted showing time and temperature? • Was the pH raised to 12 after two hours of contact? • Were logs submitted showing time and pH? • Was the temperature corrected to 25°C (77°F)? ai - � Vector Attraction Reduction Review • Was the sampling conducted at the required frequency? 38% Volatile Solids Reduction • Was there 38% reduction? • . Were lab sheets/calculations in report? • Was the reduction on volatile solids (not -total solids)? • Was the samples taken at beginning of digestion process and before application (Inspection)? • Were calculations correct? 40-Day Bench Scale Test • Were residuals from anaerobically digested treatment (Inspection)? • Were residuals anaerobically digested in lab? • Was the test run for 40 days? • Was the test done between 30°C (86°F) and 37°C (99°F)? • Was the reduction on volatile solids (not total solids)? • Was the reduction less than 17%? • Were lab sheets/calculations in report? • Were calculations correct? 30-Day Bench Scale Test • Were residuals from aerobically digested treatment (Inspection)? • Were residuals aerobically digested in lab? • Were residuals 2% or less total solids? • Was the test run for 30 days? • Was the test done at 20°C (68°F)? • Was the reduction on volatile solids (not total solids)? • Was the reduction less than 15%? • Were lab sheets/calculations in report? • Were calculations correct? Specific Oxygen Uptake Rate (SOUR) • Were residuals from aerobically digested treatment (Inspection)? YCE3. • Were residuals 2% or less total solids (dry weight basis) (not diluted)? yeS • Was the test done between 10,°C (50°F) and 30°C (86°F)? I Q-5 • Was the temperature corrected to 20°C (68°F)? yes • Was the SOUR equal to or less than. 1.5 mg of oxygen per hour per gram of total residual solids (dry weight basis)? �c5 • Was the sample holding time under two hours? SO Mp[ d nd • Was the test started within15 minutes of sampling or aeration maintained? y-eo ` � je_& � � S Souffiern S Soil $ Builders, Inc. Tuesday, September 11, 2012 Beverly Price Aquifer Protection Section Asheville Regional Office 2090 US 70 Highway Swannanoa, NC 28778-8211 �eference: City of Marion WQ00199.60 Annual Field Summary Forms 958 Hoots Road Roaring River, NC 28669 (336) 957-8909 .9 Fax (336) 957-8940 ECEUVED e1P 17 2612 1.-/, Asheville Regional Office -c'—Ulfer Protection- , In a letter received from the Asheville Regional Office dated August 27, 2012, it was discovered during an inspection that Zinc was reported on the FSF forms as 120 mg/kg instead of the correct amount of 1020 mg/kg. The forms MFLASF and FSF have been resubmitted with the correct total for Zinc reported If you have any questions, please contact me at zachkey@southernsoilbuilders.com or at 336-957-7871 Sincerely, Zach Key Southern Soil Builders, Inc. ANNUAL METALS FIELD LOADING SUMMARY FORM[* Attach this form to the corresponding -Field Loading Summary Form to be submitted in Annual Report . lg Facility Name: City of Marion Total Dry Tons Applied (Annual): Permit #: WQ0019960 Cation Exchange Capacity (non 503 only): Operator: James Fisher Owner: James Fisher Predominant Soil Series: Braddock Acres Used: 13.7 Acres Permitted: 13.7 Site F-01 Field #: F-01 mAr-i- ---i w6_._h_a vza .ao manta_ 0/. qnlids use Raw Percent ft Com- posite Date Total Annual Heavy metal rieict juou lugs 9 9 L 14 Total DT/Ac./ App. vent Event 1.10 0.000 :-6.000 0 000 -0-000" 0.000 : J60 Q.'.QQQ' 3':. .000" "0."0 '0'. �­06" O. . 0.0 00 Q.Q00 0..000 10.000 io.0,60 0000 0.000 .�L 6�000 I 0.000 0.000., 0.000, 0.000 -0.000. .0.000 .0. . 000 0.000 0.011 0.004 0.779 0.128 Arsenic 0.011. ono., -Cadmium 0.004 0.006'" 0.000- 0 000 Copper 0.779 0.000 00 romi Lead 0.121. 0.000' 6.000' 0.000 0 000' 1 0 - .00,0 1'.00.660 0.0 00 .0.000 0.000 0.000 0.121, 0.000 0-'600. 777R _,O� .000 EO 0.006 0.000 0.000 0.000 0.000 0.005, Mercury 0.005 0.000, 0.000 Molyb- 0.022 0.000 0.000 0.000, Q4 0.0010 9.090 0.000 OL.000 0.000 0.000 0.022 denum Nickel 0.048 -0-000 0 0.000 0.048 0.000, '006.11 ON., 0.606" 0.000 .0.0* omo 0.000 0.000 0 `0 Selenium 0.007 .0.000 001, 0.000 0.00o 0.000 0.000 0.007 0 0.000. 0.000 0.0, �' 0.000 0.000 0-000 0.00 Zinc 2.244 0.000 '. . 0.000 0.0000.000 '00.0 '0_000 0.000 0.000 0.000 0.000 0.000 2.244 Total 0.000 , 0..000 OQQO:V, - 0'.600' 0.000 0.000 '0.0 1 00 0.000 0.000 37.620 00 9,00 Phos- 37.620 .� , �0,000 phorus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. --,-.I��,7fa'!-s-e-information, including the possibility of fines and I am aware that there are significant penajtj&46Fg'Ubffii ng imprisonment for knowing violations". Sigdature off-Lanid Applies A URer Pr0t§_C_b0_n q-) I -. 1a Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON Facility Name: City of Marion Land Owner: James Fisher Operator: James Fisher PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. WQ Permit #: WQ0019960 Field #: F-01 Annual Dry Tons Applied: =15.0595. ;:„-- Site #: F-01 Acres Utilized: 13.7 Acres Permitted: 13.7 Predominant Soil Series: Braddock Cation Exchange Capacity (non 503): Cron 1 Name: Fescue Crop 1 Max. PAN: 239 Crop 2 Name: Crop 2 Max. PAN: ` Volume applied Volume Residual Sources Soil Precip. Y o Z Nitrate PAN Applied pp Name of Crop Type ' Q (enter one) Solids/ "�u Applied per (NPDES #, WQ#, Cond. P� 24 a b w 11{l� o � and (Ibs/acre) Receiving Residual a) Liquid Solids Acre Fert., Animal �rY� Hrs. �' a c ; w' * Ki w Nitrite Application Q Cu. Yds Gallons (Dry Tons/Ac) Waste etc) Wet, Moist) inches ° * mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 10-2011 78000 4.63 1.099 WQ0019960 dry 0 s 0.5 0.3 49000 12500 1 - 37 816 NA Fescue 00 7. 0.000- 0:000 r k 000, 0000 0�000 '�. 0.000 =0 000 Os000' < :: Q.000 -0 000 : = 'o 000 `=o�000 0.000 `o 000 -0floo 0.000 :. 0 000 0 000 '. Residuals Applications totals on FORM FSF supp (attach FORM FSF supp to this form) " . 71 TOT ::.. o 7s000 , "" As Cd Cu Cr Pb H Mo Ni Se Zn P 0 000 Lime A lied 37 816. _ Annual lbs/acre 0.,011 .4 ,• :0.004 ° . 0.779. 0.128 0121, . L _0 005 0.022 ' 0.048 , : Q007 2244 37 620 Date lbs/ac Prior Years Cumulative lbs/ac 0.041 0.022 3.4 1.888 0.577 0.31 0.17 0.289 0.043 10.913 Current Cumulative Ibs/ac 0.052 ' . :0.026 -- A.179 1016 ' : 0.698 , 0.315 0 192 ' 0 337:. 0,050 13157 Permitted C. P. L. R.**** 36 34 1 NA 1338 1 267 1 15 NA 374 89 2498 Permit PAN Limit Ist/2nd Crop - r239 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �w Signature of Land Appl *Application Method: S - Surface, IN - Injection, INC - Incorporation n/�= **Dolatihzat�o[Ra—te: Surface - 0.5, Injection/Incorporation -1.0 � D to � � i1Vlxneral�za_,tion Rat s: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3�, raw sludge -0.4 R,: Cumulative Pollutant Loading Rate ailr- T Office 'e `�i14ei� 9 tCC,�li�i3c. Aquifer DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Marion Total Dry Tons Applied (Annual): Permit #:. WQ0019960 Cation Exchange Capacity (non 503 only): Operator: James Fisher Owner: James Fisher Predominant Soil Series: Acres Used: 4.3 Acres Permitted: 4.3 Site #: F-02 Field #: 3.77 Braddock F-02 Residual Analysis Data (Heavy Metals and Total Phosphorus use mglkg, % Solids use Raw Percent ft Com- .. Date ® i Total P -EENNNE'EMMEN, phorus M Annual Heavv Metal Field Loadings (Calculated in s acre): Total 1 2 3 4 v "5 6 7 S 9 10 11 12 y DT/Ac./ 0 App. m Event 0.88 Arsenic 0.009 0.000 0.000' ' 0.000 `0,60' _'0:000` ` 0.0.00' '' '.' `0 000 - 0 ;, 0 ` `0:000 0.000 0.009 Cadmium 0.004 0.000 0.000 O.000 O OUO O:000; 0:000 0.000, 0.000 : 0 000 0.000 0.000 0.004 Copper 0.623 0.000 0.000. 0.000,0.000 .0.000 0.000 0.000. 0.000° 0.000 0:000 0.000 0.623 Chromium 0.102 0.000 0.000' 0.000 0:000 1 : 0.000; • 0.000-° 0.000, • 0.000 - 0000 0.000 0.000 0.102 Lead 0.097 1 0.000 0.000 '. 0.000 0.000 = 0.000" ' 0.000 0.000 0.000 0.000 1 0.000 0.000 0.097 Mercury 0.004' 0.000 0.000 0.000 0.000 0.000 0.000 0.'000 '0.000 '0.000 1 0.000 0.000 0.004. Molyb- 0.018 0.006 0.000 0.000, 0.000 0.000 . 0.600, 0.000, 0.000 0.000 0.000 0.000 0.018 denum Nickel 0.039 0.000 4.000 *0.000 : '0.000' 0.,000 • 0.000. 0.000 0.000, 0.000 0.000 0.000 1 0.039 Selenium 0.005 0.000 0.000 0.006 ` ''A000' -0.000 0.000' 0.000 ' ' 0.000 1 0.000 0.000 0.000 0.005 Zinc 1.795 0.000 0.000 0.000 0.000 0:00,6 `0;000 0.000 0.000 =0.000 0.000 0.000 1.795 Total Phos- 30.096 0.000 0.000 0.000 0.000 0.000, 0.000 0.000 0.000 0.000 0.000 0.000 30.096 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accoraance with a system designed to assure that.qual fied--penonneW­o-p6rlathered and evaluated the information submitted. I am aware that there are significant penal,,tie iorVdbmi~tti'ug false information, including the possibility of fines and imprisonment for knowing violatioiis". `I P R 7 . e Sign re of Land Applier , � v,sce'1�.P91Pna1, f viiier, Protection Date DENR FORM MFLSF (1212006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON Facility Name: City of Marion Land Owner: James Fisher Operator: James Fisher Crop 1 Name: Fescue PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. WQ Permit #: WQ0019960 Field #: F-02 Annual Dry Tons Applied: 3.7649 Site #: F-02 Predominant Soil Series: Braddock Crop 1 Max. PAN: 239 Crop 2 Name: Acres Utilized: 4.3 Acres Permitted: 4.3 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: Volume applied Volume Residual Sources Soil Cond. Precip. b C o iv %h o _Z `x Nitrate PAN Applied Name of Crop Type ReceivingResidual o (enter one) Solids/ % Applied per (NPDES #, WQ#, Past 24 �' 7O w �• co � w TICI�i aoc o and ( lbs/acre) N C Liquid Solids Acre Fert., Animal (Dry, Hrs. n oK. c +« # w. ? o w Nitrite Application Q Cu. Yds Gallons (Dry Tons/Ac) Waste, etc) Wet, Moist) inches o 0 o o mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 10-20111 19500 4.63 0.876 .- ' W00019960 dry 0 s 0.5 0.3 49000 12500 1 1 30121 : NA Fescue 0:000 o:000;; : o'000. o000 o oo0 -0.000 : _ 0;0000 000 10000 :- 6.000 '0.000 . -0.000 -0.000 0 000 ' ' 0:000 Residuals Applications totals on FORM FSF supp (attach FORM FSF supp to this form) - TOTALS. 0 19500 As Cd Cu Cr Pb H Mo Ni Se Zn P 30 121 ': 0 000 ' Lime Applied Annual lbs/acre - .0.009 0.004 0.623' 0.102 , 0.097 - 0.004 0.018 0.039 " :0:005 -1.795 : 30:096. Date lbs/ac Prior Years Cumulative lbs/ac 0.079 0.15 2.44 1.263 0.402 0.022 0.119 0.201 0.029 '.' 0.034 -. 89 7.601 9.396 - 2498 Current Cumulative lbs/ac --.0.088 0.154 3.063 1.365" 0.499 0.026 0.137, 0 240:' Permitted C. P. L. R.**** 36 34 NA 1338 267 IS NA 374 Permit PAN Limit lst/2nd Crop "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure Luad qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 U-Q L�; vk,� is C V i E I *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, . Signature of Land Applie q D to aerobically digested -0.3, raw sludge -0.4 l 2612 ****C.P.L.R.: Cumulative Pollutant Loading Rate -, - Asheville Regional office DENR FORM FSF (12/2006) _ Agtliser Protection ANNUAL METALS FIELD LOADING SUMMARY FORM* - Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Marion Total Dry Tons Applied (Annual): Permit #: WQ0019960 ! Cation Exchange Capacity (non 503 only): Operator: James Fisher Owner: James Fisher Predominant Soil Series: Hayesville Acres Used: 8.2 Acres Permitted: 8.2 Site #: F-04 Field #: F-04 Recidual Analysis Data (Heave Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phorusMENNNEMENEEN, Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 _�jj L5J 6 7 8 9 10 11 12 H DT/Ac./ 0 App. 14 Event 1.38 Arsenic 0.014 0..000 0.000 0.000 ' ' 0.000 03000.`." 0 000°, A.000 ; " 0.000 1 0 0,00 0.000 '0.000,1 0.014 Cadmium 0.006 0.000 6 000 0.00.0 0.000 0 000 O.Q00 0 0- 0• 0.000 0.000 0.000 0.0.06 0.006 Copper 0.977 0.000 0.000 0.0.00 0.009 0 0 000°: 0000_ .0.000. 0.000 0.060 0.000 0.000 0.977 Chromium 0.160 0.000 O o00 ' 000 ' 0.000 0 000` ; °' 0,000 � ' ' 0.0 - 0.000 `0:000 0.006 . 0.006 0.160 Lead 0.152 0.000 0.000 0.000 0.000.- 6.666.]., 0 000 "0.000 0.000 0.000 0.000 0.000 0.152 Mercury • 0.006 0.000 0.000 0.000 0.000 0 000. 0.000' 0.000 0.000 0.000 0.000 0.000 0.006 Molyb- 0.028 0.000 0.0.00, 0.000 0 000 -0 000 ,` . 0 600. 0.000 0.000 0.000 0.000 0.000 0.028 denum - Nickel 0.061 0.000 0.000 0.000 0.000' "0.000,.: 0:00,0 0..000 0.000 0.000 0.000 0.000 0.061 Selenium 0.008 0.000 0.000 0.000 1 0;000 :•'0 "000' 0,000 0.000 0.000 0.000 0.000 0.000 0.008 Zinc 2.815 0.000 0.000 0.000 0.000, 0.000 0 000 • :0.000 '0.000 0.000 0.000 0.000 2.815 Total Phos- 47.196 0.000 Q.000 0.000 • • 0.000 ; "0.000 0 000 0.000 0.000 .:0.000 0.000 0.000 47.196 horus '.'. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". F." F1ECE 2D -0,,1a- RIN of Land pplier Asheville FIckgIon al Office Awifer Protection DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON Facility Name: City of Marion Land Owner: James Fisher Operator: James Fisher Cron 1 Name: Fescue PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. WQ Permit #: WQ0019960 Field #: F-04 Annual Dry Tons Applied: 11.2947 Site M F-04 Predominant Soil Series: Hayesville Crop 1 Max. PAN: 202 Crop 2 Name: Acres Utilized: 8.2 Acres Permitted: 8.2 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: Volume applied Volume Residual Sources Soil Precip. 0 c 'b C o %e Z Nitrate PAN Applied pp Name of Crop Type o (enter one) Solids/ a/o Applied per (NPDES #, WQ#, Cond. Past 24 cY b iv w �_ cV � T 1 M o and ( lbs/acre) Receivin Residual g °� o Liquid Solids Acre Fert., Animal (Dry, Hrs. o $ a * �' � �' ° w' Nitrite Application Q Cu Yds Gallons (Dry Tons/Ac) Waste, etc) Wet, Moist) inches c o # mg/kg mg/kg nig/kg Crop 1 Crop 2 Crop 1 Crop 2 10-2011 58500 4.63 1377 _' W00019960 dry 0 s 0.5 0.3 49000 12500 1 47 385 'NA _ Fescue �0:000 :0:000 ;0 000 4- � - 0000 0000 0 0003 A000 0.000 0 000 0000 0000 U fl00 , '0000 '• 0�000 ,, t: 0 00U,;; 0000 0000 -0 000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form) 5A TOTALS 0 '` 58500 -.. T AS u Cr Pb H Mo Ni Cdr4.368 Se Zn P 47 385 0 000 Lime lied _ Annual lbs/acre "0.0667T -0.160 0 1 -V-006 . '-'0.028 =` " 0.061', -`0.008 1815 47 196 ..-. 4` .. Date lbs/ac Prior Years Cumulative lbs/ac 0.044 0.025 1.86 0.65 0.027 0 121 0 304 0 062 0 070 . 89 11.91Current ; 14.725 2498 Cumulative lbs/ac 0.058_ " =- A03145 ' 2.020 - 0.802 0.033 0 149_ 0.365 - " Permitted C. P. L. R.**** 36 34 NA 1338 267 15 NA 1 374 Permit PAN Limit 1st/2nd Crop "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possi ility of fines and imprisonment for knowing violations." Ole/•Z *Application Method: S - Surface, IN - Injection, INC - Incorporation .1 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Mineralization Rates: Compost -0.1, anaerobially digested -0.2, Date aerobically digested -0.3, raw sludge -0.4 C, R 1 Zo `� ****C.P.L.R.: Cumulative Pollutant Loading Rate Ashev.Ile Re ,106 ai ®dice ,.,;,f,r Pir6 eb::,1C3�e �- DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Marion Total Dry Tons Applied (Annual): : y37 GS Permit #: WQ0019960 Cation Exchange Capacity (non 503 only): Operator: Mario DeLuca Owner: Anna Deebold Predominant Soil Series: Hayesville Acres Used: 16 Acres Permitted: 16 Site #: K-01 Field #: K-01 Raeirinal Analveic data Monvv Metal% and T/ tnl Phnsnhorus use mff/kLy. % Solids use Raw Percent ft com- posite Date denum============' Total Phos- phorus A. vial 41aoww Matal Ntiald 1 .nadinae 1/ 'alenlate(1 In inwnerel: Total 1 2 J 3 4 V 5 171 L8J L 9 10 IIJ 12 , H DT/Ac./ ° App. iv Event 2.35 Arsenic . 0.024 0.000 0;000 0:000' 0`U.00 O'.000 ` ' 0 000 . OJ0,00 . 0 000. ':0;0,00 0;. 0.'000' 0.024 Cadmium 0:009 0:000. 0.`000 ' 0.000 "0.000 . 0:000 0 000 ' 0 00U , "`'0000 , ` "0:000 0;.000 :0.000 0.009 Copper 1..6.64 0.000: 0.000 . `0 000 0 OQ0 0;000 ` .'0 OOU- 0.000 0.000 O'UQO 0.000: 0.000 1.664 Chromium0.273 0.000: 0.000"" ' 0.000, 0.000 0:000 . a-: 0.000 ' •0.000 • 0.000 =0000 0:000 0.000 0.273 Lead 0.259 0.006 0.000:. 0.000 . 0 000. 0.000 :,`:0.0,00 . 0.000 0.000 0.000 0.000 0.000 0.259 Mercury 0.010 0.000 0.000: 0 000 ` 0.000 •0:000 ' :0.000'. . 0 000 0.000 0.000 0.000 0.000 0.010. Molyb- 0.047 0.000 0.000 :,_ 0.000 0.000 0.000,; • .. 0.000 0.000 0.000: 0.000 0.000 0.000 0.047 denum . Nickel 0.103- 0.000 0:000 0.000 ' "0:000 0 000 : ,' 0.000 ' 0.000, 0.000 1 0.000 0.000 0.000 0.103 Selenium .0.014 0.000 0.000 '.. 0 000, 0.000 -0;000" '.0.000 0.000 0;000 0.000 0.000 0.000 0A14 Zinc 4.794 0.000 0.000 0 .00 ".b 000 ' ' 0:000 " ``0.000 0.000 . 0.000 0.000 0.000 0.000 4.794 Total Phos- 80.370 0.000 0.000, 0.000 0.060 0.000;, 0.000 0.000 0.000 .0.000 0.000 0.000 80.370 horus "1 certify, under penalty of taw, tnat this aocument was prepareu under uiy uu-e.uLAUH yr NUFVI V151UH III acwr uaua,o with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant fpenalties-for submitting false -in ormation, including the possibility of fines and imprisonment for knowing violations". ��`� p55���, [ r`' Ij,^/ { 1 L tS 4.'c, '�'�'P 6'1� 1 i 9 ... of Land C,`--P 1 7 2G 12 Ashevil16 Realoneq Office f -1(--0- Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: City of Marion WQ Permit #: WQ0019960 Field #: K-01 Acres Utilized: 16 Land Owner: Anna Deebold Annual Dry Tons Applied: 37.6488,= Site #: K-01 Acres Permitted: 16 Operator: Mario DeLuca Predominant Soil Series: Hayesville Cation Exchange Capacity (non 503): Crop 1 Name: Fescue Crop 1 Max. PAN: 202 Crop 2 Name: Crop 2 Max.. PAN: A Volume applied (enter one) Solids/ Liquid Cu Yds Gallons % Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. wry' Wet, Moist) Precip. Past 24 �• inches Y � b a w, * c o : w 0 TKN 1 mg/kg Z Q R. mg/kg Nitrate and Nitrite mg/kg PAN Applied (lbs/acre ) Name of Crop p Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop-2 9-2011 195000 4.63 2 333 .` WQ0019960 dry 0 s 0.5 0.3 49000 12500 1 8Q 950, yNA Fescue . 0000 '_ 0,000, �0 000 0000 0 000 0,000 '0 000 ,0;000 0000 �`0 000 0000_, , Ob00 . 0 000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form) _ „ = TOTALS: - 0 •= . 195000 AS Cd Cu Cr Pb H Mo Ni Se Zn P 80 9,50 0 000 Lime ADDlied Annual lbs/acre 0 024 ' , 0.123 ,_0,147; 36 :0 009' ` 0.099 0:108 - 34 1.66-4. 14.204 15.868- NA 0 273 0.538 , 0 A1=1 1338 0 239 ' 1.801 ;2.060 267 ,-0 010 - 0.088 O 098 15 0 047 2.372 : � 2 419 _; NA 0 103 -. 0.845 . 0 948 ' 374 0:014 0.218 0.281 89 4 994 35.306 2498 9 V0 Date lbs/ac Prior Years Cumulative lbs/ac Current Cumulative lbs/ac Permitted C. P. L. R.**** Permit PAN Limit lst/2nd Crop "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed -to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the .possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5 Injection/Incorporation oration -1.0 9 In ] P M L *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, ate aerobically digested -0.3, raw sludge -0.4 -P % ��lZ ****C.P.L.R.: Cumulative Pollutant Loading Rate %sE�ct/iil 10, - Office DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Marion Total Dry Tons Applied (Annual): 99.13: . Permit #: WQ0019960 Cation Exchange Capacity (non 503 only): Operator: Mario DeLuca Owner: Anna Deebold Predominant Soil Series: Hayesville Acres Used: 35.8 Acres Permitted: 35.8 Site #: K-02 Field #: K-02 D...Aviol Analvaia nata mpaw Metals and Total Phosphorus use niujU, % Solids use Raw Percent #): Com- posite Total phorusMENEEMENEENE, A.,n»al Maaw 1%4ptal Fiplrl 1.na(linov. (Calculated in lbs/acre): 6 7 8 91 10 11 12 Total 1 2 3 4 Jj H DT/Ac./ ° a App. Event 2.77 Arsenic 0.028 0.000 0:000 " 0:000 ` ' 0.000 0:000'' 0.000 0:000 ' �0 000 0.000 ''_0.000 0:028 Cadmium 0.011 0.000 0,.000 . 0.000 " 0 00, Q.000 0.00. a 0.0001 .0.000 . '0.000 0.000 0.000 0.011 Copper 1.961 0.000. 0.000 ' 0.000' _0.000 0.0001. 0.000 - ' ' 0.000 0:000 :0.000 0.000 ' 0.000 1.961 Chromiuml 0.321 0.000 0.000 0400 ` 0.000 0.000 �;.,b.000 -0:000 0.0001 ' 0.000 .0.060 0.000 0.321 Lead 1 0.305 0.000 0'000 ,. 6.000 , ' 0:000 .0.000 . '' 0.000 , Q.000 " 0.000" 0.000 "0.000' 0.000 0.305 Mercury 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.012 Molyb- 0.055 0.000 0.000 0.000' 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.055 denum Nickel 0.122 0.000 0.000 0.000 O.OQO 0.000 :.0.000 0.000 0.000 0.000 0.000 0.000 0.122 Selenium 1 0.017 0.000 0.000 0.006 " ' 0.060 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.017 Zinc 5.651 1 0.000 0.000 0.000 A.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 5.651 Total Phos- 94.734 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 94.734 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision In accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the13) �posLa siibility of( Wes and imprisonment for knowing violations".0111-� . i' u ` L' �' �- 'S`=P 17 Signs re of Land pplier Date Asheville Regional gio oaf Office Aquifer Protection DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM. PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: City of Marion WQ Permit #: WQ0019960 Field #: K-02 Acres Utilized: 35.8 Land Owner: Anna Deebold Annual Dry Tons Applied:'991420 .r _ Site #: K 02 Acres Permitted: 35.8 Operator: Mario DeLuca Predominant Soil Series: Hayesville Cation Exchange Capacity (non 503): .—__ . , iv.,...e. P-- Cron t Max. PAN: 202 Crop 2 Name: Crop 2 Max. PAN: �• Volume applied, Volume Residual Sources Soil Cond. Precip. F � c 7y �, o Z Nitrate PAN Applied Name of Crop Type Receiving Residual a0i � (enter one) Solids/ % Applied per (NPDES #, WQ#, (Dry, Past 24 � � a � � * � TKN � � and Nitrite (lbs/acre) Application Liquid Solids Acre Fert., Animal Wet, 0. c ; * w' w Crop I Crop 2 Crop 1 Crop 2 Q Cu. Yds Gallons (Dry Tons/Ac) Waste, etc) Moist) inches ] 0 mg/kg mg/kg mg/kg 9-2011 58500 4.63 O'315 WQ0019960 dry 0 s 0.5 0.3 49000 12500 1 ' 10 854 NA ` Fescue 10-2011 156000 4.63 v 0 841 _ WQ0019960 dry 0 s 0.5 0.3 49000 12500 1 28 943 DNA °- Fescue 11-2011 g 299000 4.63 1613 W00019960 dry 0 s 0.5 0.3 49000 1250� 1 55 74 ' Fescue 4.0 000 �YU.000 (]NA 4S1 UOtj _ 0:000 .0. (100 . _ 0 000 ;Q 000 ,0 000 ;. Oi000`' O OOO 6000 0 {100 0 000� l)00 0 000 0 000 N 006 -u OiQ00 'Q 000 z'0 000 _' . 0Q00 =0 Residuals Applications totals on FORM FSF supp (attach FORM FSF supp to this form) TOTALS r o ; s1.35o0 As Cd Cu Cr Pb H Mo Ni Se Zn P 9,5 270 U �D00 ,' Lime A lied _ Annual lbs/acre OU28 0 011 1961;, 0321 0305 0 012, 0 055': .0122;_ 0:017 3651 94734 r Date lbs/ac 11-2011 1000 Prior Years Cumulative lbs/ac 0.116 0.099 14.399 0.537 1.816 0.088 2.372 0.849 0.11 35.556 Current Cumulative lbs/ac 0:144 _ 0110. . 16 360 0 858 2121 0,100 2.427 0 971 89 2498 Permitted C. P. L. R.**** 36 34 NA 1338 267 15 NA 374 Permit PAN Limit lst/2nd Crop 202 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accvruaucC wieu a 3y3LU1H uCeD.r�,.V.. LU "00— . W— qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 I *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, Signature of Land Applier` � V E rl V E ® ll to aerobically digested -0.3, raw sludge -0.4 J Syr ****C.P.L.R-: Cumulative Pollutant Loading Rate �.�(} i- 17 GUG2 DENR FORM FSF (12/2006) Ashevldlc� -Regional ottice ACallife-pro'cocYgpf-; -