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WQ0019960_Annual Report_20090217
RECEIVED Ipn S DWQ MOW Pro FEB 1` 2009 City of Marion, NC 2008 Annual Report Land Application Program NC Permit No. WQ0019960 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ'tPermit#: WQ0019960 . County: Facility Name (as shown on permit): Land Application Operator: McDowell Year: 2008 City of Marion Southern Soil Builder, Inc. Phone: 336-957-8909 Land application of residuals as allowed by the permit occurred during the past calendar year? S Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A - Residuals Application Summary: Total number of application fields in the permit: 8 Total number of fields utilized for land application during the year: 5 Total amount of dry tons applied during the year for all application sites:1 101.41 Total number of acres utilizes for land application during the year: 1 57 Part B - Annual Compiance Statement: Facility was compliant during calendar year 2008 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality. Ea Yes ❑ No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1) Only residuals approved for this permit were applied to the permitted sites. 2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached, 6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1 105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities). 7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8) All monitoring and reporting requirements in 15A NCAC 02T .l 1 1 I were complied with (applicable to 40 CFR Part 503 regulated facilities). 9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified in the permit. 12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13) All buffer requirements as specified on the permit were maintained during each application of residuals. Part C - Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." riot Permittee Name and Tit e (type or print) r— ure of Permitte Date 2 Date SiAature of Land Applier Date (if different from Permittee) (if different from Permittee and Preparer) * Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) , DENR FORM ACF (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B W WQ Permit Number: WQ0019960 Laboratory: 1) Facility Name: City of Marion 2) Residual Source WQ # or NCO031879 3) NPDES #: 4) WWTP Name: 5) Recidnat Analvcic nata A&L Eastern Laboratories, Inc. Parameter Ceiling Conc. • - • •mposite D. I2 -- LOW Total Phosphorus Nitrate and "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false inprmation, including the possibility of fines and imprisonment for knowing violations." Signature of 2-12 - v � Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .I 102 (26) nr:nin GnDro pccP rioionnaN ANNUAL METALS FIELD LOADING SUMMARY FORM* 'Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Marion Total Dry Tons Applied (Annual): 24.83 Permit #: WQ0019960 Cation Exchange Capacity (non 503 only): Operator: Nancy Ross Owner: Predominant Soil Series: Hayesville Acres Used: 19.4 Acres Permitted: 19.4 Site #: R-01 Field #: R-01 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phorus Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 10 11 12 DT/Ac./ o App. Event 1.28 y Arsenic 0.007 0.000 0.000 0.000 1 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Cadmium 0.004. 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000. 0.000 0.004 Copper 0.097 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.097 Chromium 0.916 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.916 Lead 0.100 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.100 Mercury 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Molyb- 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 denum Nickel 0.051 0.000 0.000. 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0:000 1 0.051 Selenium 0.010 0.000 0.000 ' 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Zinc 1.792 0.000 0.000• 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.792 Total Phos- 52.480 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 52.480 horus "1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations / b a c) Signature of Land App er Date DENR FORM MFLSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: City of Marion Total Dry Tons Applied (Annual): WQ0019960 Cation Exchange Capacity (non 503 only): James Fisher Owner: Predominant Soil Series: 13.7 Acres Permitted: 13.7 Site #: F-01 Field #: 30.00 Braddock F-01 Residual Analvsis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): com- posite Date Annual Heavy Metal Field Loadings (Calculated in Ibs/acre): Total Annual Heavy Metal Field Loadings (Calculated in Ibs/acre): Total q 21 3 4 5 6 7 8 9 10 11 12 DT/Ac./ ° App. n Event 2.19 Arsenic 0.013 1 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.013 Cadmium 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Copper 0.166 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.166 Chromium 1.568 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.568 Lead 0.171 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.171 Mercury 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.0.00 0.000 0.000 0.000 0.000 0.007 Molyb- 0.031 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.031 denum Nickel 0.088 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0..088 Selenium 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 Zinc 3.066 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.066 Total Phos- 89.790 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 89.790 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations''. a�Gi-„ c1 Sig ature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Marion Total Dry Tons Applied (Annual): Permit #: WQ0019960 Cation Exchange Capacity (non 503 only): Operator: James Fisher Owner: Predominant Soil Series: Acres Used: 4.3 Acres Permitted: 4.3 Site #: F-02 Field #: 6.21 Braddock F-02 Residual Analvcis Data (Heavy Metals and Total Phosphorus use mpike. % Solids use Raw Percent #): Com- posite Date Molyb- denum Total Phos- phorusMENEENEENEEN Annual Heavv Metal Field Loadines (Calculated in Ibs/acre): Total 1 L 2 3 4 5 6 7 181 L9]10 11 12 DT/Ac./ 0 APP• in Event 1.45 Arsenic 0.008 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.008 Cadmium 0.005 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Copper 0.110 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.110 Chromium 1.035 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.035 Lead 0.113 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.113 Mercury 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Molyb- 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.020 denum Nickel 0.058 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.058 Selenium 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.012 Zinc 2.023 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 2.023 Total Phos- 59.245 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 59.245 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Apj6er Date DENR FORM MFLSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* ' Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Marion Total Dry Tons Applied (Annual): 23.81 Permit #: WQ0019960 Cation Exchange Capacity (non 503 only): Operator: James Fisher Owner: Predominant Soil Series: Hayesville Acres Used: 11.4 Acres Permitted: 11.4 Site #: F-03 Field #: F-03 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/ki!, % Solids use Raw Percent #l: Com- posite Date EBER Mon non a M W-- M110___________ Total os Ph S- �� �� Annual ueavy 1vietat Field Loadings (Ualculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 10 11 12 DT/Ac./ 0 App. ry Event 2.09 r4 Arsenic 0.012 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.012 Cadmium ..0.007 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.007 Copper" 0.159 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.159 Chromium 1.496 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.496 Lead 0.163 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.163 Mercury 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Molyb- denum 0.029 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.029 Nickel 0.084 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.084 Selenium 0.017 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.017 Zinc 2.925 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.925 Total Phos- 85.649 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 85.649 horus nr r__ �_ i curly, under penalty of law, tpat this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Ap ier Date DENR FORM MFLSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: City of Marion Total Dry Tons Applied (Annual): 16.56 WQ0019960 Cation Exchange Capacity (non 503 only): James Fisher Owner: Predominant Soil Series: Hayesville 8.2 Acres Permitted: 8.2 Site #: F-04 Field #: F-04 Residual Analvsis Data (Heavv Metals and Total Phosphorus use me/Ice. % Solids use Raw Percent #): Com- te Dadenum_============ Molyb- � Miiiiiiiiiii Annual Heavv Metal Field Loadings ((-'alculated in Ibs/acrel: Total _jj 2 J 3 141 L5J6J 7 8 qj i0j IIJ 12 DT/Ac./ 0 0 App. m Event 2.02 Arsenic .0.012 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 1. 0.012 Cadmium 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Copper 0.154 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.154 Chromium 1.446 0.000 6.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.446 Lead 0.158 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.158 Mercury 0.006 0.000 0:000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Molyb- 0.028 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.028 denum Nickel 0.081 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.081 Selenium 0.016 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.016 Zinc 2.828 1 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 1 2.828 Total Phos- 82.820 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 82.820 horus "I certify, under penalty of law, that this document was prepared under my aireetion or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Sign ure of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY 0.17 THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: City of Marion WQ Permit #: WQ0019960 Field #: R-01 Acres Utilized: 19.4 Land Owner: Nancy Ross Annual Dry Tons Applied: 24.8499 Site #: R-01 Acres Permitted: 19.4 Operator: Nangy floss Predominant Soil Series: Hayesville Cation Exchange Capacity (non 503): , •Crop 1 Name: Fescue ' ' Croit7 Max. PAN: 202 Crop 2• Name: - Crop 2-Max. PANT L Y o Q Volume applied PP (enter one) Solids/ Liquid Cu. Yds Gallons % Solids Volume PP per Applied r Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ##, Fen., Animal Waste, etc) Soil Cond. (D We ' Moist) Precip. Past 24 Hrs. inches > K a c'c o' °n ?: c w � _ ^' w * 0 TKN mg/kg z a o o = mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 5-2008 156000 3.82 1.281 WQ0019960 dry 0 s 0.5 1 0.3 70400 7100 39 57.844 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 156000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 57.844 0.000 Lime Applied Annuallbs/acre 0.007I/ 0.0346 0.042 36 0.004 0.029 0.033 34 0.097 5.6879 5.785 1 NA 1 0.916 0.223 1.139 1338 1 0.100 0.85263 0.952 267 1 0.004W 0.0387 0.043 15 1 0.018 1.146 1.164 NA 1 0.051 0.3376 0.389 374 1 0.010 0.0718 0.082 89 1 1.792 12.32 14.112 2498' 52.480 1 V, Date Ibs/ac Prior Years Cumulative lbs/ac 6-2008 1500 Current Cumulative Ibs/ac Permitted C. P. L. R.**** Permit PAN Limit Ist/2nd Crop 1 1 292 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier 9-v Date *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 *** Mineralization Rates: Compost -0.1, anserobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate nr7:Kio r-7nona rcc i1o1'3nn12N ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: City of Marion Land Owner: James Fisher ,Operator: James Fisher-. Crop 1 Name: Fescue WQ Permit #: WQ0019960 Field #: F-01 Annual Dry Tons Applied: 30.0269 Site #: F-01 Predominant Soil Series: $raddock Crop 1 Max. PAN: 239 Crop 2 Name: Acres Utilized: 13.7 Acres Permitted: 13.7 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: L ° y ° ° ,. ° 0 Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons % Solids Volume Applied per pP P Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc)' Soil Cond. D ( D' Wet Moist) Precip. Past 24 Hrs. inches D � b a o w n * o � � _ - * * w w �, * - * TKN mg/kg z Y q' o 9 ac o w. mg/kg Nitrate and Nitrite mg/lig PAN Applied ( Ibs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 5-2008 188500 3.82 2.192 W00019960 dry 0 s 0.5 1 0.3 70400 7100 1 39 98.975 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 188500 As . Cd Cu Cr Pb Hg Mo Ni Se Zn P 98.975 1 0.000 Lime Ap lied Annuallbs/acre 0.013 0.0083714 0.021 36 0.007 0.00881 0.016 34 1 0.166 2.18 2.346 NA 1 1.568 0.189 1.757 1338 0.171 0.255 0.426 267 0.007 0.017 0.024 15 1 0.031 0.1057 0.136 NA 0.088 0.136 0.224 374 1 0.018 0:0163 0.034 89 1 3.066 4.9788 8.045 2498 89.790 1 Date lbs/ac Prior Years Cumulative Ibs/ac 6-2008 1500 Current Cumulative lbs/ac Permitted C. P. L. R.**** Permit PAN Limit lst/2nd Crop 1 239 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier 9-q-0 Date *Application Method: S - Surface, IN Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate nFNR FORM FSF t19/9nnA) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: City of Marion WQ Permit #: WQ0019960 Field #: F-02 Acres Utilized: 4.3 Land Owner: James Fisher Annual Dry Tons Applied: 6.2125 Site #: F-02 Acres Permitted: 4.3 Operator: James Fisher Crop 1 Name: Fescue Predominant Soil Series: Braddock Crop-1 Max. PAN: 239 Crop 2 Name: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: t cd O Volume applied' (enter one) Solids/ Liquid q Cu. Yds Gallons % Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. D ( ry' vest) Precip. Past 24 Hrs. inches a 3 'd a m c «� a * w TKN mg/kg z > ;' a o 3 °O ER.° mglkg Nitrate and Nitrite mg/kg PAN Applied (Ibs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 5-2008 39000 3.82 1.445 W00019960 dry 0 s 0.5 0.3 70400 71001. 39 65.242 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 39000 As Cd Cu Cr Pb I H Mo Ni Se Zn P 65.242 0.000 Lime Applied Annuallbs/acre 0.008 0.005 0.110 1.035 0.113 0.005 0.020 0.058 0.012 2.023 59.245 Date Ibs/ac Prior Years Cumulative lbs/ac 0.0558 0.0061 1.519 0.132 0.178 0.0119 0.0737 0.0951 0.01136 3.469 6-2008 1500 Current Cumulative Ibs/ac 0.064 1 0.011 1.629 1.167 0.291 0.017 0.094 0.153 0.023 5.492 Permitted C. P. L. R.**** 36 34 1 NA 1 1338 267 15 NA 374 1 89 1 2498 Permit PAN Limit lst/2nd Crop 1 1 239 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, 1njection/Incorporation - 1.0 Signature Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: City of Marion WQ Permit #: WQ0019960 Field #: F-03 Acres Utilized: 11.4 Land Owner: James Fisher Annual Dry Tons Applied: 23.8145 Site #: F-03 Acres Permitted: 11.4 Operator: James Fisher Predominant Soil Series: Hayesville Cation Exchange Capacity (non 503):. Crop 1 Name: Fescue Crop 1 Max. PAN: 202 Crop 2 Name: Crop 2 Max. PAN: '- s O _ �; O m r) Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons % Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Wet' Moist) Precip. Past 24 Hrs. inches > K a co 'b = o a m " = o n, - * o. o � = a, , « RL * c 0 TKN mg/kg z a S o S ao 0 C, 2 mg/kg. Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 5-2008 149500 3.82 2.089 W00019960 dry 0 s 0.5 1 0.3 70400 7100 39 94.334 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 149500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 94.334 1 0.000 Lime Applied Annuallbs/acre 0.012 0.007 0.159 1.496 0.163 0.007 0.029 0.084 0.017 2.925 85.649 Date lbs/ac Prior Years Cumulative lbs/ac 0.00264 0.00264 0.63228 0.05676 0.06864 0.0029 0.01188 0.03168 0.00752 1.24872 Current Cumulative lbs/ac 0.015 0.009 0.791 1.552 0.232 0.010 0.041 0.115 0.024 4.173 Permitted C. P. L. R.**** 36 34 NA 1338 267 15 1 NA 374 1 89 2498 Permit PAN Limit 1 st/2nd Crop 202 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier Date *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: City of Marion Land Owner: James Fisher OperatpC: James Fisher Crop I Name: - FegCue- ' WQ Permit #: WQ0019960 Field #: F-04 Annual Dry Tons Applied: 16.5666 Site #• F-04 Acres Utilized: 8.2 Acres Permitted: 8.2 Predominant Soil Series: Hayesville Cation'Exchange Capacity (non 503): Crop 1 Max.' PAN: 202 Crop 2 Name: Crop 2 Max. PAN: L ° s ° ° C] Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume Applied per Acre D Tons/Ac (� ) Residual Sources (NPDES #; WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Wet, Moist) Preci p' Past 24 Hrs. inches > K b s o m a =• ° o w �, _ �, - N' * �_ ° > 7' w * - S > TKN mg/kg z a 4 o o w mg/kg Nitrate and Nitrite mg/kg PAN Applied (Ibs/acre) Name of CropType yp Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 5-2008 104000 1 3.82 2.020 WQ0019960 dry 0 1 s 0.5 0.3 70400 7100 39 91.233 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALSI 01 104000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 91.233 0. 000 Lime Applied Annuallbs/acre 0.012 0.01336 0.025 36 0.006 0.01336 0.020 34 0.154 3.19972 3.353 NA 1.446 0.28724 1.734 1338 0.158 0.34736 0.505 267 0.006 0.0147 0.021 15 0.028 0.06012 0.088 NA 0.081 0.16032 0.241 374 0.016 0.03808 0.054 89 2.828 6.31928 9.147 2498 82.820 Date Ibs/ac Prior Years Cumulative lbs/ac Current Cumulative Ibs/ac Permitted C. P. L. R.**** Permit PAN Limit Ist/2nd Crop 202 "1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including -the possibility of fines and imprisonment for knowing violations." Signature of Cand Applier _9.0 Date *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate Report Number: R08134-8007 A&L EASTERN LABORATORIES, INC. v Account Number: 7621 Whitepine Road • Richmond, Virginia 23237 IA4L 46381 (804) 743-9401 • Fax No. (804) 271-6446 - t Yo: SOUTHERN SOIL BUILDERS '958 HOOTS ROAD ROARING RIVER, NC 28669 ATTN: DENNIS KEY LAB NUMBER: 42753 SAMPLE ID: MARION 1 �6011111111&0:1[4L NC CERT #257 REPORT OF ANALYSIS copy: ZACH KEY DATE SAMPLED: 5/12/2008 0830 DATE RECEIVED: 5/13/2008 1000 DATE REPORTED: 5/15/2008 PAGE: 1 Solids, Total (As is) 3.82 38200 100 JM 05/13/08 16:00 SM 2540G Nitrogen, Total Kjeldahl 7.04 70400 10 JM 05/14/08 16:00 EPA 351.3 Phosphorus 2.05 20500 100 KM 05/14/08 16:00 SW 846-3051/601OB Potassium 0.52 5200 100 KM 05/14/08 16:00 SW 846-3051/6010B Sulfur 0.77 7700 100 KM 05/14/08 16:00 SW 846-3051/6010B Calcium 1.10 11000 100 KM 05/14/08 16:00 SW 846-3051/601OB Magnesium 0.50 5000 100 KM 05/14/08 16:00 SW 846-3051/6010B Sodium 0.17 1700 100 KM 05/14/08 16:00 SW 846-3051/6010B Iron 15000 1 KM 05/14/08 16:00 SW 846-3051/601OB Aluminum 24500 10 KM 05/14/08 16:00 SW 846-3051/601OB Manganese 211 1 KM 05/14/08 16:00 SW 846-3051/6010B Copper 358 1 KM 05/14/08 15:00 SW 846-3051/601OB Zinc 700 1 KM 05/14/08 16:00 SW 846-3051/601OB Nitrogen, Ammonia (as N) 0.71 7100 10 JM 05/14/08 14:00 EPA 350.2 Nitrogen, Organic (N) 6.33 63300 100 DCH CALCULATION Nitrogen, NO3+NO2 39 1 KS 05/14/08 15:00 SM 4500-NO3F Cadmium 1.6 1 KM 05/14/08 16:00 SW 846-3051/601OB Chromium 38 5 KM 05/14/08 16:00 SW 846-3051/601OB All values are on a dry weight basis except as noted. 'Detection Limit on all N series is on a wet basis. PAUL C. H. CHU Report Number: R08134-8007 A&L EASTERN LABORATORIES, INC. Account Number: 7621 Whitepine Road - Richmond, Virginia 23237 At 46381 (804) 743-9401 • Fax No. (804) 271-6446 To: SOUTHERN SOIL BUILD�RS • `958 HOOTS ROAD ROARING RIVER, NC 28669 ATTN: DENNIS KEY LAB NUMBER: 42753 SAMPLE ID: MARION FOR: MARION NC CERT #257 REPORT OF ANALYSIS cePv: ZACH KEY DATE SAMPLED: 5/12/2008 0830 DATE RECEIVED: 5/13/2008 1000 DATE REPORTED: 5/15/2008 PAGE: 2 Nickel 20 5 KM 05/14/08 16:00 SW 846-3051/6010B Lead 39 5 KM 05/14/08 16:00 SW 846-3051/6010B Arsenic 2.9 1.0 KM 05/14/08 15:00 SW 846-601 OB Mercury 1.6 0.4 KM 05/15/08 15:00 SW 846-7471A Selenium 4.0 1.0 KM 05/14/08 15:00 SW 846-601 OB pH (Std. Unit, As is) 6.76 0.01 RD 05/14/08 12:30 SW 846-9045C Molybdenum 7 5 KM 05/14/08 16:00 SW 846-3051/6010B All values are on a dry weight basis except as noted. "Detection Limit on all N series is on a wet basis. PAUL C. H. CHU ;aneAnalyfical ° www.pacelabs.com ISolid results are reported on a dry weight basis Lab Sample No: 928019926 Client Sample ID: CC PH/CORR S1 Pace Analytical Services, Inc. 9800 Kincey Avenue, Suite 100 Nuntersville, NC 28078 Phone: 704.875.9092 Fax: 704.875.9091 Pace Analytical Services, Inc. 2225 Riverside Drive Asheville, NC 28804 Phone: 828.254.7176 Fax: 828.252.4618 Lab Project Number: 92138304 Client Project ID: CORPENING CREEK SLUDGE Project Sample Number: 92138304.001 Date Collected: 02/16/07 10:42 Matrix: Soil Date Received: 02/16/07 12:30 Parameters Results Units Report Limit Analyzed By CAS No. Qual RegLmt Wet Chemistry pH Method: EPA 9045 pH 6.83 units 02/22/07 16:00 MDK Date: 02/28/07 Page: 1 of 5 Asheville Cerfification IDs Charlotte Certification IN NC Wastewater ao REPORT OF LABORATORY ANALYSIS NC Wastewater 12 This report shall not be reproduced, except in full, NC Drinking Water 37712 NC Drinking Water 37706 without the written consent of Pace Analytical Services, Inc. SC 99030 SC 99006 FL NELAP E$7648.. " FL NELAP E87627 t ace Analytical ° www.pacelabs.com Lab Sample No: 928020007 Client Sample ID: CC TCLP-3- S1 Parameters Metals Trace ICP Metals, TCLP Leach Arsenic Barium Cadmium Chromium Lead Selenium Silver Date Digested Metals, Trace ICP Aluminum Arsenic Cadmium Calcium Copper Lead Magnesium Molybdenum Nickel Potassium Selenium Sodium Zinc Date Digested Mercury, CVAAS, TCLP Leachate Date Digested Mercury, CVAAS, TCLP•Leachate Mercury Mercury, CVAAS, in Soil Mercury Pace Analytical Services, Inc. 9800 Kincey Avenue, Suite 100 Huntersville, NC 28078 Phone: 704.875.9092 Fax: 704.875.9091 Pace Analytical Services, Inc. 2225 Riverside Drive Asheville, NC 28804 Phone: 828.254.7176 Fax: 828, 252.4618 Lab Project Number: 92138304 Client Project ID: CORPENING CREEK SLUDGE Project Sample Number: 92138304.002 Date Collected: 02/16/07 10:47 Matrix: Soil Date Received: 02/16/07 12:30 Results Units Report Limit Analyzed By CAS No, Qual RegLmt Prep/Method: EPA 3010 / EPA 6010 0,065 mg/l 0.025 02/22/07 13:57 EWS 7440.38.2 0.13 mg/l 0.025 02/22/07 13:57 EWS 7440-39-3 ND mg/l 0.0050 02/22/07 13:57 EWS 7440-43.9 ND mg/l 0.025 02/22/07 13:57 EWS 7440-47-3 ND mg/l 0.025 02/22/07 13:57 EWS 7439-92.1 ND mg/l 0.050 02/22/07 13:57 EWS 7782-49-2 ND mg/l 0.025 02/22/07 13:57 EWS 7440-22.4 02/21/07 07:00 02/21/07 07:00 -Prep/Method: EPA 3050 / EPA 6010 3900 mg/kg 280 ND mg/kg 14. ND mg/kg 2.8 3000 mg/kg 280 82. mg/kg 14. ND mg/kg 14. 1000 mg/kg 280 ND mg/kg 14. ND mg/kg 14. ND mg/kg 2800 ND mg/kg 28. ND mg/kg 2800 88. mg/kg 28. 02/23/07 06:45 Method: EPA 7470 02/19/07 13:30 02/23/07 20:00 EWS 7429.90-5 02/23/01 20:00 EWS 7440-38-2 02/23/07 20:00 EWS 7440-43-9 02/23/07 20:00 EWS 7440-70-2 02/23/07 20:00 EWS 7440.50.8 02/23/07 20:00 EWS 7439-92.1 02/23/07 20:00 EWS 7439-95-4 02/23/07 20:00 EWS 7439-98-7 02/23/07 20:00 EWS 7440.02-0 02/23/07 20:00 EWS 7440.09-7 02/23/07 20:00 EWS 7782-49.2 02/23/07 20:00 EWS 7440.23-5 02/23/07 20:00 EWS 7440-66-6 02/23/07 06:45 02/19/07 13:30 Method: EPA 7470 0.00036 mg/1 0.00020 02/20/07 11:29 ALV 7439-97.6 Method: EPA 7471 2.9 mg/kg 0.13 02/20/07 12:50 ALV 7439-97.6 Wet Chemistry Percent Moisture Method: X Moisture Percent Moisture 96.9 X 02/20/07 18:06 TNM Date: 02/28/07 Asheville Certification IN REPORT OF LABORATORY 'ANALYSIS NC Wastewater 40 . This report shall not be reproduced, ex 99030 Sc 9030 cept in full, NC Drinking Water without the written consent of Pace Analytical Services, Inc. FL NELAP E87648 Cf Page: 2 of 5 Charlotte Certification IDs NC Wastewater 12 NC Drinking Water 37706 Sc 99006 FL NELAP E87627 aceAnalytical ° www.pacelabs.com Lab Sample No: 928020007 Client Sample ID: CC TCLP=.3- S1 Parameters Total Percent Solids... Percent Solids Nitrogen, Ammonia Nitrogen, Ammonia Pace Analytical Services, Inc. 9800 Kincey Avenue, Suite 100 Huntersville, NC 28078 Phone: 704.875.9092 Fax: 704.875.9091 Pace Analytical Services, Inc. 2225 Riverside Drive Asheville, NC 28804 Phone: 828.254.7176 Fax: 828.252.4618 Lab Project Number: 92138304 Client Project ID: CORPENING CREEK SLUDGE Project Sample Number: 92138304.002 Date Collected: 02/16/07 10:47 Matrix: Soil Date Received: 02/16/07 12:30 Results Units Report Limit Analyzed By CAS No. Qual RegLmt Method: EPA 160.3 3.1 % 02/21/07 TNM Method: EPA 350.1 Modified 2900 mg/kg 340 Total Kjeldahl Nitroge6, Soil Method: EPA 351.2 Nitrogen, Kjeldahl. Total 59000 mg/kg 3100 Nitrogen, Nitrate plus Nitrite Method: EPA 353.2 Modified Nitrate as N NO mg/kg 27 Nitrate -Nitrite (as..N) 81. mg/kg 27 Phosphorus, Total, Soil Phosphorus Plant Available Nitrogen Nitrogen GUMS Semivolatiles Semivolatile Organics, TCLP 1,4-Dichlorobenzene 2,4-Dinitrotoluene Hexachloro-1,3-butadjene Hexachlorobenzene Hexachloroethane 2-Methylphenol (o-Cresol) 3&4-Methylphenol Nitrobenzene Pentachlorophenol Pyridine 2,4,5-Trichlorophen6.) 2,4,6-Trichlorophenol Nitrobehzene-d5 (S) 2-Fluordbiphenyl (S')� Terphenyl-d14 (S) Phenol-d5 (S) 2-Fluorophenol (S) 2,4,6-Tribromophenol. (S) Date: 02/28/07 Asheville Certification IDs NC Wastewater 40 NC Drinking Water 37712 Sc 99030 FL NELAP E87648 Method: EPA 365.2 13700 mg/kg 160 02/21/07 15:28 JMW 7727-37.9 02/28/07 20:05 JMW 02/27/07 14:28 EWS 02/27/07 14:28 EWS 7727.37.9 02/28/07 13:19 WWB 7723-14-0 Method: 18000 mg/kg 1.0 02/28/07 SHB 7727-37.9 Prep/Method: EPA 3510 / EPA 8270 NO mg/l 0.75 NO mg/l 0.013 NO mg/l 0,050 ND mg/1 0.013 NO mg/l 0.30 ND mg/1 0.050 NO mg/l 0.010 ND mg/1 0.20 NO mg/l 0.050 ND mg/l 0.50 NO mg/l 0.25 NO mg/l 0.20 69 X 62 X 76 X 29 X 43 X 58 X 02/27/07 09:21 BET 106-46.7 02/27/07 09:21 BET 121-14.2 02/27/07 09:21 BET 87.68-3 02/27/07 09:21 BET 118.74.1 02/27/07 09:21 BET 67-72-1 02/27/07 09:21 BET 95-48.7 02/27/07 09:21 BET 02/27/07 09:21 BET 98-95.3 02/27/07 09:21 BET 87.86-5 02/27/07 09:21 BET 110.86.1 02/27/07 09:21 BET 95.95-4 02/27/07 09:21 BET 88.06-2 02/27/07 09:21 BET 4165-60-0 02/27/07 09:21 BET 321.60.8 02/27/07 09:21 BET 1718.51.0 02/27/07 09:21 BET 4165.62.2 02/27/07 09:21 BET 367.12.4 02/27/07 09:21 BET 118-79-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. �N �CCpgo Page: 3 of 5 Charlotte Certification IDs NC Wastewater 12 NC Drinking Water 37706 SC 99006 FL NELAP E87627 ace Analytical ° www.pacelabs.com Lab Sample No: 928020007 Client Sample ID: CC TCLP-3- S1 Parameters Date Extracted GC Semivolatiles•• Pesticides, TCLP Leachate gamma-BHC (Lindan6) '. Chlordane Endrin Heptachlor Methoxychlor Toxaphene Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) Date Extracted GUMS Volatiles Volatile Organics, TCLP Leach, Benzene 2-Butanone (MEK) . Carbon tetrachloride Chlorobenzene Chloroform 1,4-Dichlorobenzene 1,2-Dichloroethane 1,1-Dichloroethene Tetrachloroethene Trichloroethene Vinyl chloride Toluene•d8 •(S) 4-Bromofluorobenzene (S) Dibromofluoromethane (S) 1,2-Dichloroethane-d4•(S) Date: 02/28/07 Asheville Certification lEs NC Wastewater' 40 NC Drinking Water 37712 SC 99030 FL NELAP I=87648 Results 02/25/07 Prep/Method NO NO ND ND NO ND 52 46 02/26/07 Pace Analytical Services, Inc. 9800 Kincey Avenue, Suite 100 Huntersville, NC 28078 Phone: 704, 875.9092 Fax: 704, 875. 9091 Pace Analytical Services, Inc. 2225 Riverside Drive Asheville, NC 28804 Phone: 828.254.7176 Fax: 828.252.4618 Lab Project Number: 92138304 Client Project ID: CORPENING CREEK SLUDGE Project Sample Number: 92138304.002 Date Collected: 02/16/07 10:47 Matrix: Soil Date Received: 02/16/07 12:30 Units Report Limit Analyzed By CAS No. Qual RegLmt 02/25/07 EPA 3535 / EPA 8081 mg/l 0.040 02/27/07 01:35 RCS1 58-89-9 mg/l 0.0030 02/27/•07 01:35 RCS1 57-74-9 mg/l 0.0020 02/27/07 01:35 RCS1 72-20.8 mg/1 0.00080 02/27/07 01:35 RCS1 76.44.8 mg/l 1.0 02/27/07 01:35 RCS1 72.43.5 mg/1 0.050 02/27/07 01:35 RCS1 8001-35-2 % 02/27/07 01:35 RCS1 877-09.8 % 02/27/07 01:35 RCS1 2051-24.3 02/26/07 Method: EPA 8260 ND mg/l ND mg/l ND mg/l NO mg/l NO mg/1 ND mg/1 ND mg/l ND mg/l ND mg/l ND mg/l NO mg/l 101 X 97 X 101 X 95 X 0.12 02/27/07 21:46 DLK 2.5 02/27/07 21:46 DLK 0.12 02/27/07 21:46 DLK 0.12 02/27/07 21:46 DLK 0.12 02/27/07 21:46 DLK 0.12 02/27/07 21:46 DLK 0.12 02/27/07 21:46 DLK 0.12 02/27/07 21:46 DLK 0.12 02/27/07 21:46 DLK 0.12 02/27/07 21:46 DLK 0.12 02•/27/07 21:46 DLK 02/27/07 21:46 DLK 02/27/07 21:46 DLK 02/27/07 21:46 DLK 02/27/07 21:46 DLK REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. �� iN AC COg01 71-43.2 78.93-3 56.23-5 108-90-7 67.66-3 106.46.7 107-06.2 75-35.4 127.18-4 79.01-6 75.01.4 2037-26.5 460.00.4 1868.53-7 17060.07-0 Page: 4 of 5 Charlotte Certification IDs NC Wastewater 12 NC Drinking Water 37706 SC 99006 FL NELAP E87627 Analytical Environmental Services, Inc. Date: 26-Feb-07 CLIENT: Pace Analytical Services, Inc. Client Sample ID: 928020023 Lab Order: 0702960 Tag Number: Project: 92138304 Collection Date: 2/16/2007 10:52:00 AM Lab ID: 0702960-OOIA Matrix: AQUEOUS Analyses Result Limit Qual Units BatchID DF Date Analyzed HERBICIDES, TCLP SW1311/8151A (SW3510B) Analyst: El 2,4,5-TP (Silvex) BRL 0.50 mg/L 82997 1 2/21/2007 4:25:00 PM 2,4-D BRL 0.50 mg/L 82997 1 2/21/2007 4:25:00 PM Surr: DCAA 98.2 25.2-164 %REC 82997 1 2/21/2007 4:25:00 PM Qualifiers: • Value exceeds Maximum Contaminant Level B Analyte detected in the associated Method Blank BRL Below Repotting Limit % E Value 3lbove quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits N Analyte not NELAC certifiedP NELAC analyte certification pending Rpt Limit Reporting Lilnit S Spike Recovery outside accepted recoveryiLe is, of 1 v. LI, LVV7 I LVnivi Irv. VJTV i PRECISION PETROLEUM LABS, INC. 5915 Star Lane Houston, TX 77057 Ph.713-680-9425 Fax:713-680-9564 CERTIFICATE OF ANALYSIS COMPANY: PACE ANALYTICAL INVOICE No.: 33069 LAB REFERENCE No.: 2007-02-442 PRODUCT ID: 928020056 PROJECT #92138304 2-16-2007 DATE RECEIVED: 02-21-2007 AUTHORIZED BY: TOM WILLIAMS TEST WTHOD REPORTING LINVZTT RESULTS 1pitabzlity (Flash Poo),.PMCC EPA-1010 -10°F > 230 Reactive Cyanides, Fp'm S.W. 9010 0.01 BRL Reactive Sulfides, ] PM S.W. 9030 1.0 BRL BRL =13ELOW REPORTING LIMIT PREC ISIONPETROLEum LABS, INC.'S RESPONSIBILITX FOR THE ABOVE ANAMB, OPINIONS OR 11MRPRETATIONS IS LB11TED TO THE INVOICE AMOUNT. • J ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Marion WQ Permit Number: W00019960 WWTP Name: City of Marion W WTP NPDES Number: NCO031879 Monitoring Period: From 1/1/2008 To 12/31/2008 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ Alt B (Alk Treatment)[] I Alt. C (Prior Testing)❑ Alt.D (No Prior Test) I Process to Further Reduce Pathogengs 0 If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ 'Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray ❑ Gamma Ray ❑ Pasteurization ❑ Class B: Alt. (1).Fecal Density 0 Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ I Air Drying ❑ Composting ❑ jAerobic Digestion 0 Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Allowable Level in in Sludge g Pathogen Density Number o Excee- n Frequency of Analysis y Sample Type na Tech - Tech- i oue Minimum Geo. Mean Units Fecal Coliform .2 x' 10 to the 6ih power per, gram of total solids. MPN 29412 281838 4248366 MPN/g 0 7 grab sm922 I e CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN. per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) -Please indicate alternative performed: Alt. l (VS reduction) 0 Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. O, uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) jAlt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) ❑ No vector attraction reduction alternatives were performed , ❑ CEWFIFICATION STATEMENT (please check the appropriate statement) "I certify,* tinder penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector afraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector -attraction reduction requirement in 15A NCAC 02T A 107 have not been met." (Please note if you ch&Wthis statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure.that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." t' A I e Aey,,t Preparer ame and Title (type or print) Z-fZ-a7 g re of Preparer* " Date Dennis Key President Southern Soil Builders, Inc. Land Applier Name and Title (if applicable)(type or print) Signature of Lan pplier (if applicable) Date *Preparer is defined, in 40 CFR Part 503.9(r) and 15A NCAC 2T .1 102 (26) DENR FORM PVRF 02T (12/2006) Analytical Results Pace Analytical -Asheville For: 92139247 2225 Riverside Drive Asheville NC 28804 Entered 3/2/2007 Reported: 3/6/2007 Sample Remark Sample ID Parameter Cust ID Result Units Method Date Analyzed Analyst 07032-5.1 % Solids 928073576 1.21 % SM2540B 3/2/07 CL 07032-5.1 Fecal Coliform MTF 928073576 132,231 MPN/g SM92210E 3/2/07 CL 07032-5.2 % solids. 928073584 1.02 % SM2540B 3/2/07 CL 07032-5.2 Fecal Conform MTF 928073584 29,412 MPN/g SM92210E 3/2/07 CL '032-5.3 ''/o Solids 928073592 1.01 % SM2540B 3/2/07 CL J32-5.3 Feca!•Coliform MTF 928073592 89,109 MPN/g SM92210E 3/2/07 CL 07032-5.4 % Solids928073600 1.10 % SM2540B 3/2/07 CL 07032-5.4 Fecal Coliform MTF 928073600 42,017 MPN/g SM92210E 3/2/07 CL Respectfully, submitted, Dena Myers NC Cert #440;•,..,. ; NCDW Cert #37755, EPA NCO0909 a • y r • P.O. Box 229 • Statesville, North Carolina 28687. 704/872/4697 Report Number: R09002-0165 A&L Eastern Laboratories, Inc. Account Number: 7621 VVhitepine Road Richmond, Virginia 23237 (804) 743-9401 46381 Fax No. (804) 271-6446 Email: office@al-labs-eastern.com Send To.. SOUTHERN SOIL BUILDERS Grower: MARION 958 HOOTS ROAD ROARING RIVER, NC 28669 SOIL ANALYSIS REPORT Page: 1 Date Received: 1/2/2009 Date of Analysis: 1/3/2009 Date of Report: 1/6/2009 ILI�,- Submitted By: SOUTHERN SOIL BLDRS Analytical Method(s): Mehlich III Sample Number Lab Number Organic Matter Phosphorus Potassium Magnesium Calcium Sodium pH Acidity C.E.C. % ENR Ibs/A Rate Available ppm Rate Reserve ppm Rate K ppm Rate Md ppm Rate CA ppm Rate NA ppm Rate Soil pH 'Buffer Index H meq/100g meq/100g F2 15309 2.3 87 L 105 VH . NC=87 67 L NC=34 100 M 740 M 5.5 6.8 1.6 6.3 F3 15310 2.6 93 M 84 H NC=70 95 M NC=49 110 M 620 M 5.3 6.7 1.9 6.2 F4 15311 1.8 80 L 87 H NC=72 89 M NC=46 100 H 440 M 5.6 6.8 1.0 4.3 R1 15312 1.8 80 L 54 H NC=45 63 L NC=32 75 M 450 M 5.4 6.8 1.2 4.2 Sample Number Percent Base Saturation Nitrate Sulfur Zinc Manganese Iron Copper Boron Soluble Salts Chloride Aluminum K % Mg % Ca % Na % H % NO3-N ppm Rate SO4-S ppm Rate ZN ppm Rate MN ppm Rate FE ppm Rate Cu ppm Rate B ppm Rate CL ppm Rate AL ppm Rate ms/cm Rate F2 2.7 13.1 58.4 25.8 F3 3.9 14.8 50.2 31.0 F4 5.4 19.6 51.7 23.3 R1 3.8 14.8 53.1 28.3 This report applies to the sample(s) tested. Samples are retained a Values on this report represent the plant available nutrients in the soil on a dry weight basis. Explanation of symbols: % (percent), ppm (parts per million), Ibs/A (pounds per acre), maximum of thirty days after lest A & L EASTERN LABORATORIES. Soil Analysis prepared by: INC. Rating after each value: VL (Very Low), L (Low), M (Medium), H (High), VH (Very High). ms/cm (milli -mhos per centimeter), meq/100g (milli -equivalent per 100 grams).^ ENR - Estimated Nitrogen Release. C.E.C. - Cation Exchange Capacity. Conversions: ppm x 2 = Ibs/A, Soluble Salts ms/cm x 640 = ppm. by: Paul Chu, Ph.D. NC NCDAKS Agronomic Division Phone: (919)733-2655 Web Site: www.acagr.com/agronomi/ Report No: 22161 Grower: Southern Soil Builders, Inc. Copies To: �\ 958 Hoots Rd roil 'atRe'port Roaring River, NC 28669 Farm: .02/12/2808. ,, , • SERVING N.C. RESIDENTS FO! OVER 60 )J, RS - MCDowQll County.: . Agronomist Comments C 12, $ Field Information Applied Lime Recommendations Sample No. Last Crop silo. Yr T/A Crop or Year Lime N P205 K20 Mg S Cu Zn B Mn See Note F3 1st Crop: Fes/OG/rim,M 0 120-200 0 90-110 0 15-20 0 0 .0 pH$ 12 2nd Crop: 15-20 Test Results Soil Class HM% W/V CEC BS•.6 Ac pH P-1 K-1 Ca% Mg% Mn-1 Mn-AI(1) Mn-AI(2) Zn-! Zn-A! Cu-1 S-1 SS-1 NO3-N NH4-N Na MIN 0.51 L02 8.4 93.0 0.6 6.9 118 22 61.o 30.0 127 80 97 97 159 25 0.1 Field Information Applied Lime Recommendations Sample No. Last Crop Mo Yr T/A Crop or Year Lime N P2O5 K20 Mg S Cu Zn B Mn See Note F4 1st Crop: Fes/OG/rim,M 0 120-200 30-50 60-80 0 0 0 0 .0 pH$ 12 2nd Crop: 0 Test Results Soil Class HM% W/V CEC BS•06 Ac pH P-1 K 1 Ca% Mg% Mn-1 Mn-AI(I) Mn-AI(2) Zn-1 Zn-A! Cu-1 S-I SS-1 NO3-N NHa-N Na MIN 0.46 0.89 9.1 96.0 0.4 6.8 41 35 61.o 32.0 157 99 137 137 277 28 0.1 Field Information Applied Lime Recommendations .. Sample No. Last Crop Mo Yr T/A Crop or Year Lime N P2O5 K20 Mg S Cu Zn B Mn See Note K1C 1st Crop: Fes/OG/rim,M LIT 120-200 0 0 0 0 0 0 .0 0 12 2nd Crop: 0 Test Results Soil Class HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% Mn-1 Mn-AI(1) Mn-AI(2) Zn-1 Zn-Al Cu-1 S-1 SS-1 NO3-N NN4-N Na MIN 0.92 1.04 10.5 80.0 2.1• - 5.3 201 135 620 12.0 256 171 360 360 187 76 0.1 Field Information Applied Lime Recommendations Sample No. Last Crop Mo Yr T/A Crop or Year Lime N P2O5 K2O Mg S Cu Zn B Mn See Note K2A 1 st Crop: Fes/OG/rim,M 0 120-200 0 0 0 0 0 0 .0 0 12 2nd Crop: 0 Test Results Soil Class HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% Mn-1 Mn-AI(1) Mn-Al(2) Zn-1 Zn-AI Cu-1 S-1 SS-1 NO3-N NH4-N Na MIN 0.81 1.00 11.0 90.0 1.1 6.2 128 110 73.0 12.0 221 147 303 303 213 48 0.1 '> -2G WebSite:wmv:rica-':con%agronoiiii/ Grower:.: Southe"'ySoil,;:=:,'`<'ReportMNoO8622;82 Agronomic Division Phone:.(919)733 55 a,,.•, b'� .. -NCDAKCS - ' Applied'Li>ine `Recommeri .<' .�<: ��_: ... .. .ti _ ., ... Field°Information Sample No. Last Crop Mo Yr T/A Crop or Year Lime P205 K20 Mg S Cu Zn B Mn See Note x Ist Crop Fes/mG rini,M .6•r 120-200 (l 60-80 0 0 0 0 .0 0 12 FI 0 2nd (:rop. Test Results Soil Class. HM% W/V CEC BS% Ac p 11 P-I K-1 Cd% -- Mg% Mn-1 Mir-AI(I)Mn-AI(2) Zn-1 Zn-AI Cu-1 S-7..-. SS -I NO3-N NHa-N Na MIN 1.37 1.02 9`4 •8I.O 1 8. 5.T ' 231 -33- 65.0 15.0 64 ?. 337 )37 777 85 0.1 ;Field Information• • Applied Lime • Recommendations ,.• Sample No. Last Crop, Mo. Yr. .T/A Crop, or Year Lime P205' K20 Mg S•• Cu • Zn, B Mn See Note NW11 lst (:rup_ Fcs/OG/rin1,M 0 120-200 0 00 0 0 0 .0 0 12 211d Crop. 0 Test Results Soil Class' IIM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% Mn-1 Mn-AI(I)Mn-AI(2) Zn I Zn-AI Cu-1 S-I SS-1 NO3-N NH4-N 1Va MIN 1.08 1.11 14.3 87.0 1.8 6.0 440 114 62.0 210 88 70 905 905 973 65 O 1 Feldanformation `.,... Applied Lime Recommendations �... , . &°_, -� , �,? . . ,.:. Sample No. Last Crop Mo Yr T/A Crop or Year Lime P205 K20 Mg S Cu Zn B Mn See Note NW13 1st Crop: Fes/OG/rim,M 0 120-200 0 0-20 0 0 0 0 .0 0 12 2nd Crop: 0 Test Results Soil Class HM% W/V CEC BS% Ac pH P-I K-1 Ca% Mg% Mn-1 Mn-AI(1)Mn-AI(2) Zn-I Zn-AI Cu-1 S-1 SS-1 NO3-N NH4-N Na MIN 0.56 1.23 10.4 87.0 1.4 6.2 355 78 66.0 17.0 92 69 512 512 553 552 r te7d Information �,.,. A 1%ed;;Lme pp ""Recommendations.,- Y yJ :. _ Sample No. Last Crop ^ - Mo Yr T/A Crop or Year Lime P205 K20 Mg S Cu Zn B Mn See Note NW31 1 st Crup: Fes/OG/rim,M 0 120-200 0 60-80 0 0 0 0 .0 0 12 2nd Crop: 0 Test Results Soil Class IIM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% Mn-1 Mn-AI(I)Mn-AI(2) Zn-I Zn-AI Cu-1 S-1 SS-1 NO3-N NH¢-N Na MIN 0.97 0.99 12.2 90.0 12 6.4 181 34 68.0 21.0 71 54 534 534 1289 41 0.1 nformation Applied Lime Recommendations ' �.. �; ••~ I tF�ieldsROPER Sample No. Last Crop Mo Yr T/A Crop or Year Lime P205 K2O Mg S Cu Zn B Mn. See Note NW81 Ist (:rop: Fes/OG/rirrt,M 0 120-200 0 0-20 0 0 0 0 .0 pH$ 12 2nd Crop: 0 Test Results Soil Class IIM% W/V CEC BS% Ac p11 P-1 K-1 Ca% Mg% Mn-1 Mn-AI(1)Mn AI(2) Zn-1 Zn-AI Cu-I S 1 SS-1 NO3-N NH4-N Na MIN 0.81 1.17 11 2 93.0 o 8 6.6 247 82 79.0 10.0 119 79 281 281 819 38 0.1 Ci+y oT Aa.rion P Annual Report Review SOP Class B Land Application 1. Annual Land Application Certification Form • Was a certification form submitted? Yes -p • Was land application conducted during the reported year? Ye-s • How many dry tons and dry tons per acre were applied? td t ..t-� • Were the applications within the permitted amount? y�S\ 5QJ ® Verify PAN if more than 10 tons/acre . Q • Did it indicate compliance? 109 . Was it signed by the appropriate people? '..zS 2. Monitoring • Were the analyses conducted at the required frequency? • Were the metals analyses reported on the Residual Sampling Summary Form? yes • Were the results reported in mg/kg? 4eS • Were the metals within ceiling concentration permit limits? y ,9-S • If no, were the lab analyses attached? • Were all the required parameters tested? tl 'O -4 S A R • Was TCLP analysis conducted? ,4,P-5 :r,5 I React. l • Were the TCLP contaminants within regulatory limits?y,0's' 3. Field Summary I Were the land application events recorded on the Field Summary Forms? ye-5 • Was a Field Summary Form submitted for each field applied on? y O-X • Were all the residuals applied to permitted land? Y45� • Were all the residuals applied from permitted sources?yes • Were the field loading rates for each metal and PAN calculated (year to date)? I5 • Were the cumulative pollutant loading rates calculated? Yes • Were the calculations correct? • Were the. PAN loading rates within permit limits? Y6S • Were the heavy metal cumulative pollutant loading rates within permit limits? • Were the residuals applied on a suitable crop? �, a • Were the applications conducted during the crop's growing season? Y 25 S �✓� t� �' • Were the Field Summary Forms complete? Y-e5 • Was lime application on Field Summary Form? y,15 4'. Pathogen and Vector Attraction Reduction 1 • Was a signed copy of.the Path en and Vector Attractior�Reduction Form submitted?':V.cps • Did the form�ii dicate the period of coverage, the residu4al class, and the pathogen reduction alternative and the vector attraction reduction option used? oh • Was the. appropriate documentation to show pathogen and vector attraction reduction included in the report? • Was pathogen and vector attraction reduction demonstrated according to 40 CFR Part 503*-or 2T? 5. Soil Tests Tht e*t • Was a Standard Soil Fertility Analysis conducted for each field applied on? y-05 • Were the soil pH's 6.0 or greater for each application field? IJO P-t ->p sa P?� thz�o8 dd��%S' Were the copper and zinc indexes in the soil less than 3000 for each application4 p0 6.6 a�� 6109field (state soils lab)? yes F-2.tln-,e. � Sa, pto-d xoo8 (?� � F-q pN 5.4 too t M'&, sa,..pItj 6. General-t� 3 04 &.3 tea klf-e- say., ldd Aoog (:) C-0 • Was the report in the proper format'lley • Were any parts of the annual report missing?�-os -�I; YAR c u,�►e�+}e���bn R-t PA C-4 Irmo- ad"A • Was the report submitted on time?yiw 61-0 � sa—pt,-d aooq (?) Vector Attraction Reduction Review �i GA ® Was the sampling conducted at the required frequency? 38% Volatile Solids Reduction's ► o � u nte� ��'f ✓O�'1 ® Was there 38% reduction? ® Were lab sheets/calculations in report? ® Was the reduction on volatile solids (not total solids)? ® Was the samples taken at beginning of digestion process and before application (Inspection)? ® Were calculations correct? 40-Day Bench Scale Test 0 Were residuals from.anaerobicallydigested treatment (Inspection)? 0 Were residuals anaerobically digested in lab? 0 Was the test run for 40 days? • Was the test done between 300C (86°F) and 370C (99°F)? • Was. the reduction.on volatile solids (not total solids)? ® Was the reduction less than 17%? ® Were lab sheets/calculations in report? . ® Were calculations correct? 30-Day Bench Scale Test 0 Were residuals from aerobically digested treatment (Inspection)? © Were residuals aerobically digested in lab? • Were residuals 2% or less total solids? 0 Was the test nun for 30 days? ® Was the test done at 20°C (68°F)? ® Was the reduction on volatile solids (not total solids)? • Was the reduction less than 15%?. ®: Were lab'sheets/calculations. in report? ® Were calculations correct? Specific Oxygen Uptake Rate (SOUR) ® Were residuals from aerobically digested treatment (Inspection)? Y-P-5 . ® Were residuals 2% or less total solids (dry weight basis). (not dilufed)? V2S ® Was the test done between 10°C (50°F) and 30°C (86°F)?� 5 ® Was the temperature corrected to 20°C •(68°F)?V- ,5 ® Was the SOUR equal to or less than 1.5 mg of oxygen per hour per gram of total residual solids (dry weight basis)?�iS ® Was the sample holding time under two hours? ® Was the test started within15 minutes of sampling or aeration maintained? S Southern S Soil $ Builders, Inc.. Monday, May 25, 2009 Ed Hardee NCDENR/ DWQ/ Aquifer Section Land Application Unit 1636 Mail Service Center Raleigh, NC 27699-1636 Mr. Hardee, 958 Hoots Road Roaring River, NC 28669 (336) 957-8909 1, Fax (336) 957-8940 Nshejille Rea. ionel Office Af1t_ ll This is in response to a letter received from NCDENR dated May 15, 2009 regarding the compliance evaluation inspection conducted on May 5, 2009. The evaluation stated 3 items were missing from the annual report. The first issue is the sodium Adsorption Ratio (SAR). The SAR is 2.39. The second issue is the Alternative 1 for vector attraction was selected. This was mistakenly selected instead of option 4 which is a Sour test. A copy of this test result in triplicate is included with this letter. The second issue is with fields F-04 and F-03 showing pH values of 5.6 and 5.3. I have included soil test taken in February of 2008 that show the values of 6.9 and 6.8. This soil test along with ones taken in late 2008 that showed the low pH was included in the annual report. Lime is planed to spread this spring when all the hay has been removed from the fields. If there are any questions or concerns, feel free to contact me at anytime at (336) 957- 8909 or at zkey@southernsoilbuilders.com. Thank you, Za h Key Southern Soil Builders, Inc. RECEIVED / DENR / DWQ Aquifer Protection Section MAY 2.9 2009 May 27 09 09:55a i CITY OF MRRION 828 659 1959 Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number Date: Digester Temperature: Sampling DatefTime: Sampled By: Analysis DatelTime: Analyzed By: Sample Volume, Total Solids: Beginning Temperature End Temperature: Dissolved Oxygen Level 7. 61 4. Corming Creels WQ 0019960 10126/2008 18 10/26/2008--1040 stes 10/26/2008--1521 R. CARTER 1000 0.85 22 25 Slope: 0.2 Intercept: 8.0 Correlation Coefficient: 1.0 nilliliters Yo Dry Solids degrees Celsius iegrees Celsius Oxygen Uptake Rate: 13,14 mg Oxygen/hr Ambient Specific Oxygen Uptake Rate: 1.55 mg Oxygen/g/hr Average Temperature: 24 degrees Celsius Temperature Correction Factor: 0.822702475 Temperature Corrected Specific Oxygen Uptake Rate:1 1.27 mg Oxygenlg/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. RECEIVED / DENR I DWQ Aquifer Protection Section MAY 2 9 2009 May 27 09 09:54a C I T'Y OF MAR I ON HP-U bbU lbbU Time (minutes) 0 1 2 4 5 6 7 8 9 10 �1 ,2 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: C Siosolids Permit Number: V Date: Digester Temperature: Sampling DatelTime: 1 Sampled By: L Analysis Date/Time: 1 Analyzed By: f Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level 1.1 4.99' 4.8 1 Slope. 0.2 Intercept'. 7.2 Correlation Coefficient 1.0 liliters Dry Solids grees Celsius orees Celsius Oxygen Uptake Rate: 12.96 mg Oxygenlhr Ambient Specific Oxygen Uptake Rate: 1.58 mg Oxygenlglhr Average Temperature 25 degrees Celsius Temperature Correction Factor 0.783526166 Temperature Corrected Specific Oxygen Uptake Rate:1 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. May 27 OS 09:54a CITY OF MRRIUN ucu OZZ 1.7D:7 r. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Facility Na Biosolids Permit Numb D Digester Temperat Sampling Date/Ti Sampled Analysis DatelTi Analyzed Sample Volu Total Soli Beginning Temperat End Temperat Nan Specific Oxygen Uptake Rate SOUR Eorn7en,eeker:ate: 2008ure:18.5 me: 10/22/08--1002 By: L. ESTES me: 10/22/08--1214 By: R. CARTER me: 1000 mi ds: 0.84 % ure: d ure: 25 de Dissolved Oxygen Level 7.61 7.38 7.13 6.89 6.66 6.42 6.22 6 5.78 Ililiters Dry Solids egrees Celsius arees Celsius Slope: 0.2 Intercept: 7.8 Correlation Coefficient: 1.0 Oxygen Uptake Rate: 13.77 mg Oxygen/hr Ambient Specific Oxygen Uptake Rate: 1.64 mg Oxygen/g/hr Average Temperature: 24 degrees Celsius Temperature Correction Factor: 0.822702475 Temperature Corrected Specific Oxygen Uptake Rate: 1,35 mg Oxygen/g/hr Instructions Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. May 27 09 09:54a CITY OF MHHIUn dcd 0MZ1 lao� r•, Time (minutes) 0 1 2 3 4 5 6 7 6 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name Biosolids Permit Number Date Digester Temperature Sampling Date/Time Sampled By Analysis Date/Time Analyzed By Sample Volume Total Solids Beginning Temperature End Temperature Dissolved Oxygen Level ..1 5.92 5.74 5.54 10/23108--1005 L. ESTES 5.181 11 Jr 3° ZC tilliliters o Dry Solids egrees Celsius egrees Celsius Slope: 0.2 Intercept: 7.5 Correlation Coefficient 1.0 Oxygen Uptake Rate: 10.81 mg Oxygen/hr Ambient Specific Oxygen Uptake Rate: 1.30 mg Oxygen/g/hr Average Temperature: 24 degrees Celsius Temperature Correction Factor: 0.822702476 Temperature Corrected Specific Oxygen Uptake Rate: 1.07 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsl-eet execute automatically. May 27 09 09:55a C11Y OF MHNI UM acc ooa ia�o f• Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Corpening Creek Biosolids Permit Number: WQ 0019960 Date: Digester Temperature: Sampling DatelTime: V Sampled By: L. Analysis Date/Tlme: 1( Analyzed By: R Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level 7.29 7.1 6.85 6.62 6.39 6.15 5.94 5.63 5.42 6.16 4.92 1211 11000 milliliters 0.86 % Dry Solids 2 degrees Celsius 25 degrees Celsius Slope: 0.2 Intercept: 8.2 Correlation Coefficient: 1.0 Oxygen Uptake Rate: 13.82 mg Oxygen/hr Ambient Specific Oxygen Uptake Rate: 1.63 mg Oxygen/g/hr Average Temperature: 24 degrees Celsius Temperature Correction Factor: 0.822702475 Temperature Corrected Specific Oxygen Uptake Rate: 1.34 mg Oxygen/g/hr Instructions. Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. May 27 09 09:55a CITY OF MRRION 020 659 1959 p.6 Specific Oxygen Uptake Rate SOUR Facility Name Biosolids Permit Number Date Digester Temperature Sampling DatelTime Sampled By Analysis DaterTime Analyzed By Sample Volume Total Solids Beginning Temperature End Temperature Time Dissolved Oxygen Level (minutes) m /I 0 7.8J 1 7.7 2 7.4 3 7.2; 4 7.0� 5 6A 6 6.9 7 6.41 8 6.21 9 6.0� 10 5.9 11 5.6; 12 5.4; 13 6.2, 14 5.0. 15 4.7 ECoeoningCreek9960 008 181 10/25108-0900 : R. CARTER : 10/25/08--1115 : R. CARTER 1000 m 0.73 % 2 de 25 de Ililiters Dry Solids igrees Celsius agrees Celsius Slope: 0.2 Intercept: 7.8 Correlation Coefficient: 1.0 Oxygen Uptake Rate: 12.03 mg Oxygen/hr Ambient Specific Oxygen Uptake Rate: 1.65 mg Oxygen/glhr Average Temperature: 24 degrees Celsius Temperature Correction Factor: 0.822702475 Temperature Corrected Specific Oxygen Uptake Rate: 1.36 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. May 27 09 09:513a CITY OF MRRION 828 659 1959 P.8 Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number. Date: Digester Temperature: Sampling DatefTime: Sampled By: Analysis DateMme: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level r++ rQ 0019960 10/272008 17 in197/nR__1nF1 1.211 L0221 milliliters 0.81 % Dry Solids 12 degrees Celsius 2degrees Celsius Slope: 0.2 Intercept: 7.1 Correlation Coefficient: 1.0 Oxygen Uptake Rate: 14.52 mg Oxygen/hr Ambient Specific Oxygen Uptake Rate: 1.79 mg Oxygen/g/hr Average Temperature: 25 degrees Celsius Temperature Correction Factor: 0.783526166 Temperature Corrected Specific Oxygen Uptake Raterr 1.40 mg Oxygen/g/hr Instructions: Enter Data In the Blue Boxes, The Calculation and the Spreadsheet execute automatically Mai 27 09 09:59a CITY OF MARION 828 G59 1959 p•1 rr Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name Biosolids Permit Number Date Digester Temperature Sampling Date/Time Sampled By Analysis Date/Time Analyzed By Sample Volume Total Solids Beginning Temperature End Temperature Dissolved Oxygen Level 9 4. ICARTER Creek99600/28/200816--0952--1320ER 100 0.83 mmmw�5 25 MYI 2. Slope: 0.2 Intercept: 6.5 Correlation Coefficient: 1.0 milliliters % Dry Solids Degrees Celsius Degrees Celsius Oxygen Uptake Rate: 14.19 mg Oxygen/hr Ambient Specific Oxygen Uptake Rate: 1.71 mg Oxygen/g/hr Average Temperature: 25 degrees Celsius Temperature Correction Factor. 0.783526166 Temperature Corrected Specific Oxygen Uptake Rate: 1.341mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. NCDA&CS Agronomic Division Phone: (919)733-2655 Web Site: www.ncagr.com/agronomi/ Report No: 22161 Grower: Southern Soil Builders, Inc. Copies To: 958 Hoots Rd j, \ Roaring River, NC 28669 oil Test kohort Farm: 02/12/2008 SERVING N.C. RESIDENTS FOR OVER 60 YEARS McDowell County Agronomist Comments C -- 12 $ Field Information Applied Lime Recommendations Sample No. Last Crop Mo Yr T/A Crop or Year Lime N P2O5 K20 Mg S Cu Zn B Mn See Note F3 1st Crop: Fes/OG/1°im,M 0 120-200 0 90-110 0 15-20 0 0 .0 pH$ 12 2nd Crop: 15-20 Test Results Soil Class HM% W/V CEC BS06 Ac pH P-1 K-1 Ca% Mg% Mn4 Mn-AI(1) Mn-AI(2) Zn-I Zn-AI Cu-1 S-1 SS-1 NO3-N NH4-N Na MIN 0.51 1.02 8.4 93.0 0.6 6.9 118 22 61.0 30.0 127 80 97 97 159 25 0.1 Field Information Applied Lime Recommendations Sample No. Last Crop Mo Yr T/A Crop or Year Lime N P2O5 K20 Mg S Cu Zn B Mn See Note F4 Ist Crop: Fes/OG/Pim,M 0 120-200 30-50 60-80 0 0 0 0 .0 pH$ 12 2nd Crop: 0 Test Results Soil Class HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% Mn-1 Mn-AI(I) Mn-AI(2) Zn-1 Zn-Al Cu-1 S-I SS -I NO3-N NH4-N Na MIN 0.46 0.89 9.1 96.0 0.4 6.8 41 35 61.0 32.0 157 99 137 137 277 28 0.1 Field Information Applied Lime Recommendations Sample No. Last Crop Mo Yr T/A Crop or Year Lime N P2O5 K2O Mg S Cu Zn B Mn See Note K1C Ist Crop: Fes/OG/fim,M LIT 120-200 0 0 0 0 0 0 .0 0 12 2nd Crop: 0 Test Results Soil Class HM% W/V CEC BS•06 Ac p H P-1 K-1 Ca% Mg% Mn-1 Mn-AI(1) Mn-AI(2) Zu-1 Zn-AI Cu-1 S-1 SS-1 NO3-N NH4-N Na MIN 0.92 1.04 10.5 80.0 2.1 5.3 201 135 62.0 12.0 256 171 360 360 187 76 0.1 Field Information Applied Lime Recommendations Sample No. Last Crop Mo Yr T/A Crop or Year Lime N P2O5 K2O Mg S Cu Zn B Mn See Note K2A Ist Crop: Fes/OG/Pim,M 0 120-200 0 0 0 0 0 0 .0 0 12 2nd Crop: 0 Test Results Soil Class HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% Mn-1 Mn-AI(1) Mn-AI(2) Zn-1 Zn-Al Cu-1 S-1 SS-1 NO3-N NH4-N Na MIN 0.81 1.00 11.0 90.0 1.1 6.2 128 110 73.0 12.0 221 147 303 303 213 48 0.1