WQ0019960_Annual Report_20060222

P IRECEIVED
FEB 2 71006
Asheville Regional Office
° ozx%
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CITY OF MARION sS�c 6
s, T
2005 ANNUAL REPORT
LAND APPLICATION PROGRAM
NC PERMIT NO. WQ0019960

ANNUAL LAND APPLICATION CERTIFICATION FORM
Permit#: WQ0019960 County: McDowell Year: 2005
Facility Name (as shown on permit): City of Marion
Land Application Operator: Southern Soil Builders, Inc. Phone: [phone]
Land application of residual solids as allowed by the permit occurred during the past calender year?
® Yes ❑ No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A:
Part B:
Facility was compliant during calendar year 2005 with all conditions of the land application permit
(including but not limited to items 1-12 below) issued by the Division of Water Quality. M Yes ❑ No
If no please, provide a written description why the facility was not compliant, the dates, and explain
corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites. F
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) N chid&ayoil p"H>of'at,
least 6.0 or the limit specified in the permit. �FRQ
3. Annual soils analysis were performed on each site receiving residuals during the past c�i'a��ea�r��3id three
(3) copies of laboratory results are attached. o�Ss��
4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attacrirl.
5. All other monitoring was performed in accordance with the permit and reported during the year as required
and three (3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Quality.
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed
in accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowin violations."
Permittee Name and Title (type or print) Signature of PermittDate
gn e of Preparer* Date Signature of Land Applier Date
(if different from Pern ittee) (if different from Permittee and Preparer)
Preparer is defined in 40 CFR Part 503.9 (r)
DENR FORM ACF (512003)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number:
WQ0019960
Facility Name: City of Marion
NPDES # or NCO031879
W Q#:
WWTP Name: City of Marion WWTP
Laboratory: . 1) A&L Eastern Agricultural Labs,Inc.
2)
3)
4)
5)
Sampleor
Composite Date
Percent Solids
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signa e of reparer Date
DENR FORM RSSF (5/2003)
we

t11\1\UL1L 1V1L' 1t1LJ I'1L'LL LVE�L11�lr.�U1Vl1VlAI(Y I�VK1Y1'
.t
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
City of Marion Total Dry Tons Applied (Annual):
WQ0019960 Cation Exchange Capacity (non 503 only):
Wayne Ross Owner: Wayne Ross
12 Acres Permitted: 12 Site #: R2 Field #: R2
13.32
Residual Analysis Data (Heavy Metals and Total Phosphorus use rug/kg, % Solids use Raw Percent #):
. •• • -
I ••
0
©
©
�
©
�
�
�
�
in
is
.
On
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
:..•
W
i I o :
. •• ••0000000000000
... -
®00000�00000®
t � i•
00000�0000�
� � �
•1•
I certify, under penalty of law, that this document was prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations"
S ature of Land Appher Date
* See bottom of FSF Form for helpful instructions for this MFLSF Form and the mathematically linked FSF Form
DENR FORM MFLSF (5/2003)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM r
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD.
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. »
Facility Name: City of Marion Permit #: WQ0019960 Annual Dry Tons Applied: 13.32
Owner: Wayne Ross Operator: Wayne Ross Cation Exchange Capacity (non 503):
Site #: R2 Field #: R2 Acres Utilized: 12 Acres Permitted:
12
o ��
a3 o
Q
` specifv
Totals
Per'
Acre
I
°
/0
Solids
Tons Per
Acre
Residual
Sources
(Summarize)
t e
Cond.
Dry
Wet
Moist
Inches
Preci p
Past 24
Hrs.
Appli-
cation
Meth-
od*
Voli-
tila-
zation
Rate**
Miner-
ala-
zation
Rate
TKN
Ammo-
nia-
Ni-
trogen
Ni-
trate
and
Nitrite
PAN 1
PAN 2
Must Select
Crop 1 or Crop
2
Gal.
Cu.Yd.
Report
Totals
>: in Gal.
Crop 1
Crop 2
1-05
100,000
8333.3
3.21
1.115475
VVWTP
dry
0
s
0.5
30%
58600
600
84
39.6752
#######
Fescue
1
0
0
0
0
2
0
0
0
0
3
0
0
0
0
4
0
0
0
0
5
0
0
0
0
6
0
0
0
0
7
0
0
0
0
8
0
0
0
0
9
0
0
0
0
10
0
0
0
0
11
0
0
0_
0
12
TOTALS:
8333
:'
As
Cd
Cr
Cu
Pb
Hg
Mo
Ni
Se
Zn
P
I PAN 1
PAN 2
Lime Applied
Annuallbs/acre
0.0043068
0.007991
0
1.12332
0.04894
0.00453
0.14874
0.04884
0.01132
2.42424
51.06
39.6752
0
Date
lbs/ac
'Current Cumulative lbs/ac
0.0207239 0.02442 0 3.46616 0.43401 0.30645 0.5913 0.17066 0.03333 7.44676
0.0164171 0.01643 0 2.34284 0.38517 0.30192 0.44256 0.12182 0.02201 5.02252
36 34 NA 1338 267 15 NA 374 89 2498
250
Prior Years Cumulative lbs/ac
Permitted C. P. L. R.***
'Permit PAN Limit l st/2nd Crop
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accoruance w,ui a SySLe«I
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
�� 4-� / - 9- 7- ° *Application Method: S - Surface, IN - Injection, INC - Incorporation
Signature of Land Applier Date **Volitilization Rate: Surface - 0.5. Iniection/Incorr)oration - 1.0
***C.P.L.R.: Cumulative Pollutant Loadine Rate
**** The RSSF Data and the Dry Tons Per Acre are to be entered on the MFLSF Form. The FSF and MFLSF are mathematically linked so this information needs to be entered
into the same numbered column on the MFLSF as is entered on the identically numbered FSF row to properly complete the metals equations. ie. FSF row # 1 to MFLSF
DENR FORM FSF (5/2003)

'%Ail Uf1L AM AL ` IJ3 r in' L1J LVAL11r lT 5 U 1V11V1AK T V UKM--
l�AttacIh this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Marion Total Dry Tons Applied (Annual): 92.96
Permit #: WQ0019960 Cation Exchange Capacity (non 503 only):
Operator: Toua & Tong Khang Owner: Toua & Tong Khang
Acres Used: 16 Acres Permitted: 16 Site #: K1 Field #: K1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
--
©
o
©
o
0
0
o
m
son
I�
t t
0�0000��000
t t
... .
0��0000�00000
m
t '
00000000000
t
t t
000000�0000
t t
y. :.
�a000000�■000
.
000000�.0000
.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations"
Signature of Land App 'er Date
• See bottom of FSF Form for helpful instructions for this MFLSF Form and the mathematically linked FSF Form
DENR FORM MFLSF (512003)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD.
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Marion Permit #: WQ0019960 Annual Dry Tons Applied: 92.96
Owner
Q;*P !#-
: Toua & Tong Khang Operator: Toua & Tong Khang Cation Exchange Capacity (non 503):
K1 Field #: K1 Acres Utilized: 16
Acres Permitted:
16
S i
t
Inches
Appli-
Voli-
Miner-
Ammo-
m
Ni-
Must Select
Gal.
o
Totals
%
Dry Tons Per
Residual
Cond.
Precip.
cation
tila-
ala-
TKN
nia-
trate
PAN 1
PAN 2
Crop 1 or Crop
Cu.Yd.
a
0 o
per
Solids
Acre
Sources
(Summarize)
Dry,
Past 24
Meth-
zation
zation
Ni-
and
2
Report
Q
Totals
Acre
Wet
Hrs.
od*
Rate**
Rate
trogen
Nitnte
Crop 1
Crop 2
in Gal.
3-05
292,500
18281
3.21
2.447073281
WWTP
dry
0
s
0.5
30%
58600
600
84
87.0375
####4##
Fescue
1
10-05
403000
25188
3.21
3.371523188
WWTP
dry
0
s
0.5
30%
58600
600
84
119.918
#######
Fescue
2
.5
0
0
0
0
3
0
0
0
0
4
0
0
0
0
5
0
0
0
0
6
0
0
0
0
7
0
0
0
0
8
0
0
0
0
9
0
0
0
0
10
0
0
0
0
11
0
0
0
0
12
TOTALS: 43469F,':,-.
As
Cd
Cr
Cu
Pb
H
Mo Ni Se Zn P PAN 1 -PAN 2
Lime Applied
Annual lbs/acre
0.0225428
0.04183
0
5.87972
0.25564
0.0237
0.77854 0.25564 0.05926 12.689 267.26 206.9561 0
Date
lbs/ac
Current Cumulative lbs/ac
0.0694694
0.07654
0
9.11732
1.20438
0.06218
2.2682 0.56278 0.13769 24.1697
1.48966 0.30714 0.07843 11.4807
NA 374 89 2498
250IFTA
Prior Years Cumulative lbs/ac
0.0469266
0.03471
0
3.2376
0.94874
0.03948
Permitted C. P. L. R***
36
34
NA
38
267
15
Permit PAN Limit I st/2nd Crop
::.
1338
"I certify, under penalty of law, that this document was prepared under my airecnon or supervision ui nLwi LIMILc W t I A aya «.-
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signaturelbf Land Applier
Date
*Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volitilization Rate: Surface - 0.5, Iniection/Incornoration - 1.0
***C.P.L.R.: Cumulative Pollutant Loading Rate
**** The RSSF Data and the Dry Tons Per Acre are to be entered on the MFLSF Form. The FSF and MFLSF are mathematically linked so this information needs to be entered
into the same numbered column on the MFLSF as is entered on the identically numbered FSF row to properly complete the metals equations. ie. FSF row # 1 to MFLSF
DENR FORM FSF (5/2003)

t11\1\Ut1L LV 1t1LJ rMiu / LVt%mjulky 04j1V1111t1i%X V%JL%iVA
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
City of Marion Total Dry Tons Applied (Annual):
WQ0019960 Cation Exchange Capacity (non 503 only):
Toua & Tong Khang Owner: Toua & Tong Khang
38 Acres Permitted: 38 Site #: K2 Field #:
124.37
K2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
. 1 • -
• • 11
••
Annual Heavy Metal Field Loadings Calculated in lbs/acre:
Annual Heavy Metal Field Loadings Calculated in lbs/acre:
00000000000
••.
•
0000000�v00
,.
m
00000000000
. y - �•
�00000a00000
®�0000�.000000�
•1•
"I certify, under penalty of law, that this document was prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations"
Signature of Land AKIIer Date
* See bottom of FSF Form for helpful instructions for this MFLSF Form and the mathematically linked FSF Form
DENR FORM MFLSF (5/2003)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PT F.A.SF. MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD.
Facility Name:
Owner:
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Marion Permit #: WQ0019960 Annual Dry Tons Applied: 124.37
Toua & Tong Khang
Site #: K2
Cu.Yd.
QReport
Totals
in Gal.
1-27-05 71,500
3-05 468000
10-05 390000
TOTALS:
Annual lbs/acre
Current Cum_ ula
Prior Years C
'Permitted C. P.
Permit PAN Limit
Cum
Field #:
Operator:
K2
Toua & Tong Khang
Acres Utilized: 38
Cation Exchange Capacity (non 503):
Acres Permitted: 38
five
Dry Tons Per
Acre
Residual
Sources
(Summarize)
t e
Cond.
�,
Wet
Moist
Inches
Precip.
Past 24
fIrs.
Appli-
cation
Meth-
od*
Voli-
tila-
zation
Rate**
Miner-
ala-
zation
Rate
TKN
Ammo-
nia-
Ni-
trogen
Ni-
trate
and
Nitrite
PAN 1
PAN 2
Must Select
Crop 1 or Crop
2
*.
Totals
Per
Acre
%
Solids
Crop 1
Crop 2
1881.6
3.21
0.251862513
WWTP
dry
0
s
0.5
30%
58600
600.
84
8.95825
#######
Fescue
1
1.648554632
1.373795526
0
0
WWTP
WWTP
dry
dry
0
0
s
s
0.5
0.5
30%
30%
58600
58600
600
600
84
84
58.6358
48.8632
0
0
#######
#######
0
0
Fescue
Fescue
2
3
4
5
12316
3.21
10263
3.21
0
0
0
0
0
6
0
0
0
0
0
0
0
0
0
0
7
8
9
0
0
0
0
0
0
As
0.0126876
Cd Cr
0.02354 0
Cu
3.30924
Pb
0.14388
H
0.01334
Mo
0.43818
Ni
0.14388
Se
0.03335
Zn
7.14168
P
150.42
0
0
0
PAN 1
116 457
0
0
0
PAN 2
0
Lune Applied
Date
lbs/ac
1
11
12
0
0
0
24461
lbs/ac
0.0331376 0.04501 0 6.73484 0.73548 0.03961 1.18968 0.31814 0.0724 14.3453
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accor ance wt a y
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Lariff Applier
,- J+04-
Date
*Application Method: S - Surface, IN - Injection, INC - Incorporation
*Volitilization Rate: Surface - 0.5. In i ection/Incorno ration - 1.0
***C.P.L.R.: Cumulative Pollutant Loading Rate
**** The RSSF Data and the Dry Tons Per Acre are to be entered on the MFLSF Form. The FSF and MFLSF are mathematically linked so this information needs to be entered
into the same numbered column on the MFLSF as is entered on the identically numbered FSF row to properly complete the metals equations. ie. FSF row # 1 to MFLSF
DENR FORM FSF (5/2003)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM
Facility Name: City of Marion Permit Number:
WWTP Name: City of Marion WWTP NPDES Number:
Monitoring Period: From 1/1/2005 To 12/31/2005
WQ0019960
NCO031879
Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed:
Class A: I
Alternative 1 [17
Alternative 2 ❑
Alternative 3 ❑
Alternative 40 1
Alternative 5 ❑
Alternative 6 ❑
If applicable to alternative performed Class A only) indicate "Process to Further Reduce Pathogens":
Compost 0_1
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray [3
Pasteurization ❑
Class B:
Alternative 10
Alternative 2 ❑
Alternative 3 ❑
If applicable to alternative performed Class B onl indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
Air Drying ❑
Composting ❑
Aerobic Digestion KI
Anaerobic Digestion[]
If applicable to alternative performed Class A or Class B complete the following monit ring data:
Parameter
Level in
Pathogen Density
Number ot
Excee-
Frequency
of
Sample
Type
Analytical
Tech-niqu
mu
Geo. Mean
MaximumUnitsenmsys1s
Fecal Coliform
2x IOto e6
Power NTN Per
gram of total
solids or 2 x 10 to
the 6th power
CFU per uarn of
566667
1059965
1470588
MPN
0
7
grab
sm9221 e
740741
1438986
5228758
MPN
0
7
grab
sm9221 e
1000 mpn per
gram of total solid
(dry weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4
grams total solid
(dry wei t)
Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed:
Option 1 Option 2 ❑ Option 3 ❑ Option 4 ❑ Option 5 ❑
Option 6 ❑ Option 7 ❑ Option 8 ❑ Option 9 ❑ Option 10 ❑
No vector attraction reduction options were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
® "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the
system designed to ensure that qualified personnel properly gather and. evaluate the information
used to determine that the pathogen and vector attraction reduction requirements have been met. I
am aware that there are significant penalties for false certification including fine and imprisonment."
LP,4!1 rov-ae--, w-�—Lp SyA�Liwilr..a.�w7 Dennis Key Southern Soil Builders, Inc.
Xignatur'e
Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print)
of Preparer Date Sign ture of Land Applier (if applicable) Date
DENR FORM RF (5/2003)

A&L EASTERN AGRICULTURAL LABORATORIES, INC.
7621 Whitepine Road • Richmond, Virginia 23237 • [phone]
Fax No. [phone]
REPORT NUMBERQc> ;ci- 1'1 ACCOUNT a6331 Pr)c 1
SOUTHERN! SOIL BUILDERS
DEN N I S, KE-
950 HOOTS ROAD
R. OAR INlG RI':ER NC 286a9
LAD NUMBER = 40209
}AMPLE ID = MARION NC
RESULT RESULT
PARAMETER ( ) (MG/KG)
MARION NC
�lC C E R 1 # 2 57 7
ANAL'v' SIS REPORT
DETECTION!
LIMIT ANALYSIS
( MG/ KG ) AINA -YST DATE TIME
DENtN I J I Y
DA j E 5 � IFLED
DA 1 F R' ECEIVE Ci
DATE REPORTED
U y
EMAIL_
r01/12'��5
01/14/05
01/19i0j,
METHOD REFERENCE
-------------------------
SOLIDS(AS IS)-
3.21
3210,0
100
JCM
01/ 14: 05
1 G ! 0 0
SM
2540 G
NaITR0GEN!(TKN!)
5.36
58GOO
100
:CS
01/17/05
16:00
E PA
351.3
PHOSPHORUS
-2 30
23000
100
JCM
01/17/05
13e00
SW
846-6010B
POTASSIUM
0.47
4700
100
JCM
01/17/05
13:00
Sw
846-GOIOB
SULFUR-
1.04
10400
100
JCM
011117/05
13:00
CW
846-6010B
CALCIUM
1.61
16100
100
JCM
01/17/05
13:00
CW
846-6010B
MAGNESIUM
0.47
4700
100
JCM
01/17/05
13:00
Sk
846-60108
SODIUM
0.17
1700
100
JCM
01/17/05
13:00
CW
846-6010B
IRON!
0314
1
JCM
01/17/05
13:00
SW
846-601i36
ALUMINUM
24053
10
JCM
01/17/05
13-00
SW
846-GOIOB
MANGANESE
228
1
JCM
01/17 /05
13:00
SI!
346--6010B
COPPER
506
1
JCM
01/17/05
13.:00
S'!
846-6010B
ZItic
109'
1
JCM
01/17/05
13:00
SW
846-60106
AMMONlIA-NlITROGEN!
0.06
600
100
KCS
01/17/05
15:00
EPA
350.2
Nl03-Nl.17Z NITROGEN!
84
10'
KCS
01/17/ 05
15:30
SM
4500-N,IO? F
CADMIUM
3.6
1
JCM
01/17/05
13:00
SW
846-60106
NlICKE'L
22
5
JCM
01/1-1/05
13:00
SW
846-60108
LEAD
22
`i
JCM
011117/05
13:00
SW
846-6010B
ALL.. VALLIES ARE DIN A DRY WEIGHT BASIS EXCEPT AC NOTED.
This report applies only to the sample(s) tested. Samples are retained a maximum of thirty days after testing.
A&L EASTERN AGRICULTURAL LABORATORIES, INC.
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or in part,
nor may any reference be made to the work, the results. or the company in any advertising, news release, or other public_
announcements without obtaining our prior written authorization. Copyright 1977 by by xxxiii V
C. Noreen Jones Paul Chu

A&L EASTERN AGRICULTURAL LABORATORIES, INC.
7621 Whitepine Road • Richmond, Virginia 23237 • [phone]
Fax No. [phone]
REPORT NUMBERrC;r�g- 1 i ! ACCOUNT N �+��3s; PAGE
SOUTHERN SOIL BUILDERS
DENNIS KEY
958 HOOTS ROAD
ROARING RIVER NC 28669
LAB NUMBER = 40209
SAMPLE ID = MARION NC
RESULT RESULT
PARAMETER. ( 7.. ) (MG/KG)
MAR ION NC
NC CER.T # 257
ANALYSIS REPORT
DETECTION
LIMIT ANALYSIS
(MG/KG) ANALYST DATE TIME
------- ------- --------- -----
DES N10- KEY
DATE SAMPLED
r,
GATE RECEIVED
DATE REPORTED
EMAIL_
01/12/05
01/1rt/05
01/19/05
METHOD REFERENCE
------------------------
ARSENIC
1,94
0.2
KMM
01/19/05
16:00
SW
846-7061A
MERCURY
2.04
0:Q
KMM
01/19/05
1 G : 0 0
SW
84G-7471A
SELENIUM
5.10
0.1
KMM
01/19/05
16:00
S1!
8 4 6 - 7 7 4 1 A
PH (STD.UNITS,AS IS) G.50
RD
01/17/05
12:30
EPA
150.1
ORGANIC NITROGEN-. 5.79
57900
100
DCN
01/17/05
CALCULATION
MOLYBDENUM
67
5
JCM
0111710C
13:00
IN
846-GOIOB
ALL- VALUES ARE ON A DRY WEIGHT BASIS EXCEPT AS NOTED.
This report applies only to the sample(s) tested. Samples are retained a maximum of thirty days after testing.
A&L EASTERN AGRICULTURAL LABORATORIES, INC.
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or in part.
nor may any reference be made to the work, the results, or the company in any advertising, news release. or other public \ announcements without obtaining our prior written authorization. Copyright 1977 by by 2a,�
r; Nor an Jones Paul Chu

- - - - - - - - - -
SAMPLING LOG I
A & L EASTERN-
AGRICULTURAL LABS,
INC. CHAIN OF CUSTODY
7621 WhiteP ine
Road
RECORD AND ANALYSIS
Richmond, VA
23237
RECORD
tU51OMER:
804/743-9401
FAX: [phone]
PROJECT MANAGER:
I 'attest that the proper field sampling
procedures
were used during the col-
Phone-': 967 - 31
lecti.on of
these saimptes.
Ty
SM4.L!E-
U
1?1.r. All
Reli shed q i b b
-a up
..I
843233218731 P-4
to 1-13 FedEx Trac;Unu Number
?der's r; loll
me Phone
Company L 113!j I L-IJ,
'Address
D"Obr—WR—
a
r: n
state ZIP
ur latm=1 Billing Reference 'ANAL YSIS
w.
CA
,/ I /-- I /I - V1, I/
Rem-i-ved: by:
�Recej,40by:
;,T
Pb;
AS
�49,1
Se 1.
I-- 111111A/
SL.I: Total Solids- (MisUre), Total Kieldahl Nitrogen, ftiosftrus, and Potassium
C.- al d un, I i UN- Sodium; Iron, AlumiM num, an aril Zinc
SU-,: Bask. -Test SLI"p.11ri Sulfur;ganese. Cqver,

q Y
L
R
ATORIES, INC.
www. parlabs. com
PAR Laboratories, Inc.
2217 Graham Park Drive
PO Box 411483
Charlotte, NC 28241-1483
Phone: [phone]; Fax: [phone]
NC Cerr a 20; SC Cerr s 99003
REPORT OF ANALYSES
Attn: DENNIS KEY
SOUTHERN SOIL BUILDERS PROJECT NAME: JAN 05
958 HOOTS ROAD DATE: 02/11/05
ROARING RIVER, NC 28669-0000
SAMPLE NUMBER- 62408
SAMPLE ID- MARION
SAMPLE MATRIX- SO
DATE SAMPLED- 01/24/05
LOCATION- MARION
TT*,lE SAIMPLED- 1500
DATE RECEIVED- 01/25/05
SAMPLER- ZACK KEY
RECEIVED BY- RE
TIME RECEIVED- 1130
DELIVERED BY- ZACK
KEY
TYPE SAMPLE- Grab
Page 1 of 2
ANALYSIS
ANALYSIS
METHOD
DATE
TIME BY
RESULT UNITS
TCLP CHARACTERISTICS
TCLP
02/07/05
SUB
pH VALUE.
TCLP
02/07/05
SUB
6.7 S.U.
CORROSIVITY
TCLP
02/07/05
SUB
NON
REACTIVITY
TCLP
02/07/05
SUB
NON
FLASH POINT
TCLP
02/07/05
SUB
< 200 degrees F
IGNITABILITY
TCLP
02/07/05
SUB
NON
PAINT FILTER TEST
TCLP
02/07/05
SUB
NFL
TCLP METALS
TCLP
02/07/05
SUB
ARSENIC
TCLP
02/07/05
SUB
< 0.5 ppm
BARIUM
TCLP
02/07/05
SUB
< 10 ppm
CADMIUM
TCLP
02/07/05
SUB
< 0.1•ppm
CHROMIUM
TCLP
02/07/05
SUB
< 0.5 ppm
LEAD
TCLP
02/07/05
SUB
< 0.5 ppm
MERCURY
TCLP
02/07/05
SUB
< 0.02 ppm
SELENIUM
TCLP
02/07/05
SUB
< 0.1 ppm
SILVER
TCLP
02/07/05
SUB
< 0.5 ppm
TCLP PESTICIDES
TCLP
02/07/05
SUB
ENDRIN
TCLP
02/07/05
SUB
< 0.002 ppm
LINDANE
TCLP
02/07/05
SUB
< 0.04 ppm
METHOXYCHLOR
TCLP
02/07/05
SUB
< 1 ppm
TOXAPHENE
TCLP
02/07/05
SUB
< 0.05 ppm

L
R
TORIES, INC.
www. parlabs. com
Page 2 of 2
PAR Laboratories, Inc.
2217 Graham Park Drive
PO Box 411483
Charlotte, NC 28241-1483
Phone: [phone]; Fax: [phone]
NC Cert H 20; SC Cerf H 99003
CONTINUATION OF DATA FOR SAMPLE NUMBER 62408
ANALYSIS
ANALYSIS
METHOD
DATE TIME
BY
RESULT
UNITS
CHLORDANE
TCLP
02,107/05
SUB
< 0.003
ppm
HEPTACHLOR (AND ITS EPDXIDE)
TCLP
02/07/05
SUB
< 0.0008
ppm
TCLP HERBICIDES
TCLP
02/07/05
SUB
2,4-D
TCLP
02/07/05
SUB
< 1
ppm
2,4,57TP(SILVEX)
TCLP
02/07/05
SUB
< 0.1
ppm
TCLP ORGANICS
TCLP
02/07/05
SUB
BENZENE
TCLP
02/07/05
SUB
< 0.05
ppm
CARBON TETRACHLORIDE
TCLP
02/07/05
SUB
< 0.05
ppm
CHLOROBENZENE
TCLP
02/07/05
SUB
< 10
ppm
CHLOROFORM
TCLP
02/07/05
SUB
< 0.6
ppm
o-CRESOL
TCLP
02/07/05
SUB
< 20
ppm
p-CRESOL
TCLP
02/07/05
SUB
< 20
ppm
m-CRESOL
TCLP
02/07/05
SUB
< 20
ppm
1,4-DICHLOROBENZENE
TCLP
02/07/05
SUB
< 0.75
ppm
1,2-DICHLOROETHANE
TCLP
02/07/05
SUB
< 0.05
ppm
1,1-DICHLOROETHYLENE
TCLP
02/07/05
SUB
< 0.07
ppm
2,4-DINITROTLUENE
TCLP
02/07/05
SUB
< 0.013
ppm
HEXACHLOROBENZENE
TCLP
02/07/05
SUB
< 0.013
ppm
HEXACHLOROBUTDIENE
TCLP
02/07/05
SUB
< 0.05
ppm
HEXACHLOROETHANE
TCLP
02/07/05
SUB
< 0.3
ppm
METHYL ETHYL KETONE
TCLP
02/07/05
SUB
< 20
ppm
NITROBENZENE
TCLP
02/07/05
SUB
< 0.2
ppm
PENTACHLOROPHENOL
TCLP
02/07/05
SUB
< 10
ppm
PYRIDINE
TCLP
02/07/05
SUB
< 0.5
ppm
TETRACHLORETHYLENE
TCLP
02/07/05
SUB
< 0.07
ppm
TRICHLOROETHYLENE
TCLP
02/07/05
SUB
< 0.05
ppm
2,4,5-TRICHLOROPHENOL
TCLP
02/07/05
SUB
< 40
ppm
2,4,6-TRICHLORPHENOL
TCLP
02/07/05
SUB
< 0.2
ppm
VINYL CHLORIDE
TCLP
02/07/05
SUB
< 0.02
ppm
LABORATORY DIRECTOR ,r

1L
R
TORIES, INC.
www.pariabs.com
Shipping:
2217 Graham Park Drive
Charlotte, NC 28273
CHAIN OF CUSTODY
PAR Laboratories, Inc
Phone [phone]
Fax [phone]
Mailing:
PO Box 411483
Charlotte, NC 28241-1483
It is essential that all information recorded on this Chain of Custody document for acceptance by PAR Laboratories, Inc. and the North Carolina
Department of Environmental and Natural Resources.
Company Name (billing)
SOUTHERN SOIL BUILDERS
Address
958 HOOTS RD
City, State & Zip Code
ROARING RIVER, NC 28669
Point of Contact & TelePhone,Number
DENNIS KEY 336-957-8909
Sample taken by:
COMMENTS/SPECIAL
INSTRUCTIONS
IS THIS FOR STATE or EPA REPORTING? YES )< NO
*Sample type: DW WW ) GWMW HW Soil Other
Sample Temp at time of sampling: °C Sample Temp upon receipt: °C
** Preserved: Yes No Teflon Liner/ Zero Headspace: Yes _ No _ N/A
* C=Composite. G=Grab DW=Drinking Water WW=Wastewater GWMW=Groundwater Monitoring Well HW=Hazardous Waste **See
Other Side

i
Pace Analytical Services; Inc.
ace Analytical ® Ashe Riverside Drive
Asheville, NC 28804
www.paC61abs.com Phone: 828. 254, 7176
Lab Project Number: 9285852 Fax: 828.252, 4618
Client P
Solid results are reported on a
dry weight basis
roJect
ID:
CORPENING CREEK - SLUDGE
9285852.001
Date Collected: 01/13/05 13:15
Lab Sample No: 925180192
Client Sample ID: CC SF1
Project Sample Number:
.
Matrix:
Soil
Date Received: 01/13/05 15:48
Parameters
Results Units
Report Limit Analyzed
By
CAS No. ual RegLmt
Microbiology
Fecal Coliform MPN Solid
Method: SM 9221B/E
Coliform, Fecal
451612.9
01/14/05
MMG
Wet Chemistry
Percent Moisture
Method: X Moisture
Percent Moisture
96.9 X
,
01/18/05
08:28
DHW
Total Percent Solids
Method: EPA 160.3
Percent Solids
3.2 X
01/14/05
15:21
EWS
�p w
( C)
g5
/
Date: 01/24/05
Page: 1 of 7
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs - This report shall not be reproduced, except in full, NC Wastewater 40 Charlotte Certification IDs
NC Drinking Water 37712 without the written consent of Pace Analytical Services, Inc. NC Wastewater 12

, A
Pace Analytical Services, Inc.
ace Analytical ®
2225 Riverside Drive
Asheville, NC 28804
www.pacelabs.com
Phone: [phone]
fax.' 828.252.4618
Lab Project Number:
9285852
Client Project
ID:
CORPENING CREEK • SLUDGE
c
Lab Sample No: 925180218
Project Sample Number: 9285852.002
Date Collected: 01/13/05 13:18
Client Sample ID: CC S172
Matrix: Soil
Date Received: 01/13/05 15:48
jParameters Results Units
Report Limit Analyzed
By
CAS No. Qual RegLmt
Microbiology
Fecal Coliform MPN Solid Method: SM 922113/E
i Coliform, Fecal 903225.8
01/14/05
MMG
Wet Chemistry
Percent Moisture Method: % Moisture
Percent Moisture 96.9 t
01/18/05 08:29
DHW
Total Percent Solids Method: EPA 160.3
! Percent Solids 3.2 t
01/14/05 15:21
EWS
Date: 01/24/05
Page: 2 of 7
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full, Charlotte Certification IDs
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc. NC Wastewater 12
NC Drinking Water 37712 NC Drinking Water 37706
SC Environmental 99030

'
Pace Analytical Services, Inc,
Analytical
®
Riverside Drive
ace
Ashe
Asheville, NC 28804
www.pacelabs.com
Phone:[phone]
Fax: [phone]
Lab Project Number:
9289657
Client Project
ID:
CORPENING CREEK
5
y;
Date Collected: 03/09/05 10:27
Lab Sample No: 925372716
Project Sample Number: 9289657.003
Client Sample ID: CC SF-4
Matrix: Soil
Date Received: 03/09/05 15:14
Parameters
Results Units
Report Limit Analyzed
By
CAS No. Qual RegLmt
Microbiology
Fecal Coliform MPN Solid
Method: SM 9221B/E
Coliform, Fecal
1470588.2
03/10/05 07:35
MMG
Wet Chemistry
Percent Moisture
Method: % Moisture
Percent Moisture
96.6 X
03/10/05 09:50
TNS
Total Percent Solids
Method: EPA 160.3
Percent Solids
3.4 X
03/11/05
TNS
Date: 03/16/05
Asheville Certification IDs
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
M AGCOR
Page: 3 of 13
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706

ace Analytical
www.pacelabs.com
r."
Lab Sample No: 925372724
Client Sample ID: CC SF-5
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 9289657
Client Project ID: CORPENING CREEK
Project Sample Number: 9289657.004 Date Collected: 03/09/05 10:28
Matrix: Soil Date Received: 03/09/05 15:14
Parameters Results Units Report Limit Analyzed By CAS No. Qual RegLmt
Microbiology.
Fecal Coliform MPN Solid Method: SM 92216/E
Coliform, Fecal 400000 03/10/05 07:35 MMG
Wet Chemistry
Percent Moisture Method: % Moisture
Percent Moisture 96.5 % 03/10/05 09:51 TNS
Total Percent Solids
Percent Solids
Date: 03/16/05
Method: EPA 160.3
3.5
03/11/05 TNS
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full,
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc.
NC Drinking Water 37712
Page; 4 of 13
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706

.-_ *; _ 1,
Analytical
www.pacelabs.com
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 9289657
Client Project ID: CORPENING CREEK
Lab Sample No: 925372732 Project Sample Number: 9289657.005 Date Collected: 03/09/05 10:29
Client Sample ID: CC SF-6 Matrix: Soil Date Received: 03/09/05 15:14
Parameters Results Units Report Limit Analyzed By CAS No. Qual RegLmt
Microbiology
Fecal Coliform MPN Solid
Method: SM
9221B/E
Coliform. Fecal
909090.9
Wet Chemistry
Percent Moisture
Method: X
Moisture
Percent Moisture
96.7
X
Total Percent Solids
Method: EPA 160.3
Percent Solids
3.3
X
Date: 03/16/05
03/10/05 07:35 MMG
03/10/05 09:51 TNS
03/11/05 TNS
REPORT OF LABORATORY ANALYSIS
Page 5 of 13
Asheville Certification IDs
This report shall not be reproduced, except in full,
NC Wastewater 40
without the written consent of Pace Analytical Services, Inc.
NC Drinking Water 37712
N �Cpgo
SC Environmental 99030
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
Sc 99006

� � n
ace Analytical
www.pacelabs.com
Lab Sample No: 925372740
Client Sample ID: CC SF-7
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 9289657
Client Project ID: CORPENING CREEK
Project Sample Number: 9289657.006 Date Collected: U3/09/US 1U:3U
Matrix: Soil Date Received: 03/09/05 15:14
Parameters
Results Units
Report Limit Analyzed
By CAS No. Qual RegLmt
Microbiology
Fecal Coliform MPN Solid
Method: SM 9221B/E
Coliform• Fecal
566666.66
03/10/05 07:35
MMG
Wet Chemistry
Percent Moisture
Method: k Moisture
Percent Moisture
96.7 %
03/10/05 09:51
TNS
Total Percent Solids
Method: EPA 160.3
Percent Solids
3.3 %
03/11/05
TNS
Date: 03/16/05
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full,
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc.
NC Drinking Water 37712 w "°
Cr rnvirnnmont2l oonzn .a'%`1 •t'''.,.`'�
Page: 6 of 13
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006

t " 1
Analytical Results
Pace Analytical -Asheville For: 92104542
2225 Riverside Drive
Asheville NC 28804
Entered 10/5/2005
Reported: 10/11 /2005
Sample Remark
Sample ID
Parameter
Cust ID
Result Units
Method
Date Analyzed
Analyst
051.05-10.1
% Solids
926175183/1
3.06 %
SM2540B
10/5/05
MD
05105-10.1
Fecal Coliform MTF
926175183/1
5228758' MPN/g
SM92210E
10/5/05
MD
05105-10.2
% Solids
926175191/2
3.1 %
SM2540B
10/5/05
MD
05105-10.2
Fecal Coliform MTF
926115191/2
2903226 V MPN/g
SM92210E
10/5/05
MD
05105-10.3
% Solids
926175209/3
6.0 %
SM2540B '
10/5/05
MD
05105-10.3
Fecal Coliform MTF
926175209/3
1r000p00v MPN/g
SM92210E
10/5/05
MD
05105-10.4
% Solids
926115217/4
2.95 %
SM2540B
10/5/05
MD
05105-10.4
Fecal Coliform MTF
926175217/4
1,016�49 MPN/g
SM92210E
1015/05
MD
05105-10.5
% Solids
92617522515
2.93 %
SM2540B
10/5/05
MD
05105-10.5
Fecal Coliform MTF
926175225/5
955631' MPN/g
SM92210E
10/5/05
MD
05105-10.6
% Solids
926175233/6
3.06 %
SM2540B
10/5/05
MD
05105-10.5
Fecal Coliform MTF
92617523316
1633987 MPN/g
SM92210E
10/5/05
MD
05105-10:7
% Solids
926175241/7
2.93 %
SM2540B
10/5/05
MD
05105-1G.7
Fecal Coliform MTF
92617524in
1r023P90 `' MPN/g
SM92210E
10/5/05
MD
05105-10.8
% Solids
926175258/8
2.97 %
SM2540B
10/5105
MD
05105-10.8
Fecal Coliform MTF
926175258/8
740741V MPN/g
SM92210E
10/5105
MD
05105-10.8
Geometric Mean
926175258/8
1438986 MPN/g
dry wt. basis
10/6/05
MD
Respectfully submitted,
Dena Myers
NC Cert #440,
NCDW Cert #37755,
EPA NC00909
P.O. Box 228 • Statesville, North Carolina 28687. 704/872/4697

It I3
VaceAnalyficale
www.pacelabs.com
Lab Sample No: 925216459
Client Sample ID: CC S-TCLP
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 9286481
Client Project ID: CORPENING CREEK SLUDGE
Project Sample Number: 9286481.006 Date Collected: 01/24/05 10:45
Matrix: Soil Date Received: 01/24/05 15:30
t9.{Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
fry, Metal s
Trace ICP Metals, TCLP Leach.
Prep/Method:
EPA 3010 /
EPA 6010
Arsenic
NO
mg/l
0.025
01/24/05
16:09
ALV
7440.38.2
Barium
0.33
mg/1
0.025
01/24/05
16:09
ALV
7440.39.3
Cadmium
NO
mg/l
0.0050
01/24/05
16:09
ALV
7440.43.9
Chromium
0128
mg/l
0.010
01/24/05
16:09
ALV
7440.47.3
Lead
0.044
mg/l
0.025
01/24/05
16:09
ALV
7439.92.1
Selenium
0.035
mg/1
.0.025
01/24/05
16:09
ALV
7782.49-2
Silver
NO
mg/l
0.010
01/24/05
16:09
ALV
7440.22.4
Date Digested
01/26/05 05:30
01/26/05
05:30
Mercury, CVAAS, TCLP Leachate•
Method: EPA
7470
Date Digested
01/25/05 05:00
01/25/05
05:00
Mercury, CVAAS, TCLP Leachate
Method: EPA
7470
Mercury
0.00022
mg/l
0.00020
01/28/05
ALV
7439.97.6
GUMS Serni vol ati l es
Semivolatile Organics, TCLP
Prep/Method:
EPA 3510 /
EPA 8270
1,4-Dichlorobenzene
NO
mg/l
0.75
02/07/05
12:01
BET
106.46.7
2,4-Dinitrotoluene
NO
mg/l
0.013
02/07/05
12:01
BET
121.14.2
Hexachloro-1,3-butadiene
NO
mg/l
0.050
02/07/05
12:01
BET
87.68-3
Hexachlorobenzene
NO
mg/l
0.013
02/07/05
12:01
BET
118.74.1
Hexachloroethane
NO
mg/l
0.30
02/07/05
12:01
BET
67.72.1
2-Methylphenol (o-Cresol)
NO
mg/l
0.050
02/07/05
12:01
BET
95.48.7
3&4-Methylphenol
NO
mg/l
0.010
02/07/05
12:01
BET
Nitrobenzene_
NO
mg/l
0.20
02/07/05
12:01
BET
98.95.3
Pentachlorophenol
ND
mg/l
10.
02/07/05
12:01
BET
87.86.5
Pyridine
NO
mg/l
0.50
02/01/05
12:01
BET
110.86.1
2,4,5-Trichlorophenol
NO
mg/l
40.
02/07/05
12:01
BET
95.95.4
2,4,6-Trichlorophenol
NO
mg/l
0.20
02/07/05
12:01
BET
88.06.2
Nitrobenzene-d5 (S)
55
%
02/07/05
12:01
BET
4165.60.0
2-Fluorobiphenyl (S)
60
.%
02/07/05
12:01
BET
321.60.8
Terphenyl-d14 (S)
78
X
02/07/05
12:01
BET
1718.51.0
Phenol-d5 (S)
30
X
02/07/05
12:01
BET
4165.62.2
2.-Fluorophenol (S)
42
X
02/07/05
12:01
BET
367.12-4
2,4,6-Tribromophenol (S)
72
%
02/07/05
12:01
BET
Date Extracted
02/04/05
02/04/05
Date: 02/09/05
Page: 6 of 33
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full, Charlotte Certification IDs
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc. NC Wastewater 12
NC Drinking Water 37712 NC Drinking Water 37706
SC Environmental 99030

It A
'
Pace Analytical Services, Inc.
aceAnalytical
®
Riverside Drive
Asheville,
Asheville, NC 28804
www.pacelabs.com
Phone: [phone]
Fax. [phone]
Lab Project Number:
9286481
•
Client Project ID:
CORPENING CREEK SLUDGE
Lab Sample No: 925216459
R::Client
Project Sample
Number:
------------ —
9286481.006 Date Collected: 01/24/05 10:45
Sample ID: CC S-TCLP
Matrix:
Soil
Date
Received: 01/24/05 15:30
{'�
1r••
Parameters
Results
Units
Report Limit Analyzed
By
CAS No.
Qual RegLmt
•GMemivolatiles
a.
Pesticides, TCLP Leachate
Prep/Method:
EPA 3510 /
EPA 8081
gamma-BHC (Lindane)
NO
mg/l
0.040
02/05/05
02:00
RPJ
58-89.9
#f
Chlordane
ND
mg/l
0.0030
02/05/05
02:00
RPJ
57.74.9
Endrin
Heptachlor
NO
mg/1
0.0020
02/05/05
02:00
RPJ
72.20.8
Methoxychlor
NO
mg/l
0.00080 02/05/05
02:00
RPJ
76.44.8
Toxaphene
NO
mg/l
1.0
02/05/05
02:00
RPJ
72.43.5
'
Tetrachloro-m-xylene (S)
ND
41
m g71
0.050
02/05/05
02:00
RPJ
8001.35.2
Decachlorobiphenyl (S)
38
Y,
02/05/05
02:00
RPJ
877.09-8
Date Extracted
02/04/05
y,
02/05/05
02:00
RPJ
2051.24.3
02/04/05
Acid Herbicides, TCLP Leachate
Prep/Method:
EPA 3510 /
EPA 8151
2.4-D
ND
mg/l
1.0
02/08/05
18:56
JEM
94.75.7
2,4,5-TP (Silvex)
ND
mg/l
0.10
02/08/05
18:56
JEM
93.72.1
2.4-DCPA (S)
86
X
02/08/05
18:56
JEM
19719.28-9
Date Extracted
02/07/05
02/07/05
GUMS Vol ati l es
Volatile Organics, TCLP Leach.
Method: EPA 8260
Benzene
2-Butanone (MEK)
NO
mg/l
0.0050
01/30/05
18:40
MSF
71.43.2
Carbon tetrachloride
ND
ND'
mg/l
0.10
01/30/05
18:40
MSF
78-93.3
Chlorobenzene
mg/l
0.0050
01/30/05
18:40
MSF
56.23.5
Chloroform
NO
mg/l
0.0050
01/30/05
18:40
MSF
108.90.7
1,2-Dichloroethane •
NO
mg/l
0.0050
01/30/05
18:40
MSF
67.66.3
1.1-Dichloroethene
NO
mg/l
0.0050
01/30/05
18:40
MSF
107.06.2
Tetrachloroethene
NO
mg/l
0.0050
01/30/05
18:40
MSF
75.35.4
Trichloroethene
NO
mg/l
0.0050
01/30/05
18:40
MSF
127.18.4
Vinyl chloride
NO
mg/l
0.0050
01/30/05
18:40
MSF
79.01.6
Toluene•d8 (S)
NO
mg/l
0.0050
01/30/05
18:40
MSF
75.01.4
4•Bromofluorobenzene (S)
73
85
X
X
01/30/05
18:40
MSF
2037.26.5
1
Dibromofluoromethane (S)
88
X
01/30/05
18:40
MSF
460.00.4
1,2-Dichloroethane.d4 (S)
82
X
01/30/05
18:40
MSF
1868.53.7
01/30/05
18:40
MSF
17060.07.0
Date: 02/09/05
Page: 7 of 33
REPORT OF LABORATORY ANALYSIS
Asheville Certification IN REPORT
report shall not be reproduced, except in full, NC Wastewater 40 without the written consent of Pace Analytical Services, Inc. NCaWastewat rlotte Certification I
NC Drinking Water 37712 12
SC Environmental 99030 t°
�"° NC Drinking Water 37706

s race nffaly—�,
2225 Riverside Drive
Asheville, NC 28804
® 828,254.7176
Fax: 828.252.461
8
acIIn�
www,pacelabs.crn Lab Project Number:.928
6481
RPENING CREEK SLUDGE
b'.Samp 925216467
ient Sample ID: CC SLUDGE LIMP
Parameters
i.,.Phosphorus, Total, Soil
Phosphorus
PH
E
PH
` Plant Available Nitrogen
'Nitrogen
Date: 02/09/05
Ash vill Qertification40 s
NC Wastewater
NC Drinking Water 37712
SC Environmental 99030
ri MCI AP E87648
Client Project ID: CO
Project Sample Number: 9286481.0te Collected: 01/24/05 13:00
07 Da
Date Received: 01/24/05 15:30
Matrix: Soil
'I— CA=— ual RegLmt
Report Limit Analyzed
Results Una ep�—
Method: EPA 365.2 7720 01/25/05 JDA1 7723 14 0
20500 mg/kg
Method: EPA 9045 01/25/05 12:10 TMR
2
5.90 units
Method: 1.0 02/04/05 10:00 EWS 7727-37.9
18000 mg/kg
REPORT OF LABORATORY except
ANAMIS
This report shall not be reproduced,
without the written consent of Pace Analytical Services, Inc.
a r eh&!
Page: 9 of 33
Charlotte Certification 101
NC Wastewater 12
NC Drinking Water ggo0
Sc Ga7.f
F1 NIP DP

e a ;<
aceAnalytical QD
www.pacelats.com
Solid results are reported on a dry weight basis
Lab Sample No: 926175282
Client Sample ID: CC SL MO-4
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax- 704.875.9091
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax., 828.252.4618
Lab Project Number: 92104542
Client Project JD: CORPENING CREEK SLUDGE
Project Sample Number: 92104542.009 Date Collected: 10/04/05 14:00
Matrix: Soil Date Received: 10/04/05 15:39
Parameters
Results Units
Report Limit Analyzed
By CAS No. Qual RegLmt
Metals
Metals. Trace JCP
Prep/Method: EPA 3050 /
EPA 6010
Molybdenum
42. mg/kg
17. 10/11/05
19:39 ALV 7439.98.7
Date Digested
10/07/05 12:45
10/07/05
12:45
Wet Chemistry
Percent Moisture
Method: X Moisture
Percent Moisture
97.2 X
10/05/05
13:17 TNS
Date: 01/30/06
Asheville Certification IN
REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712
This report shall not be reproduced, except in full,
Sc 99030
without the written consent of Pace Analytical Services, Inc.
FL NELAP E87648
Page: 1 of i
hart
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627

4 • X
r aceAnalytical
www.pacelabs.com
Lab Sample No: 925216467
Client Sample ID: CC SLUDGE LTMP
Metals
Metals, Trace ICP
Aluminum
Arsenic
Cadmium
Calcium
Copper
Lead
Magnesium Molybdenum L,45 P .Te.;r,20
Nickel V
Potassium
Selenium
Sodium
Zinc
Date Digested
Mercury, CVAAS, in Soil
Mercury
Wet Chemistry
Percent Moisture
Percent Moisture
Flash Point, Closed Cup
Flash Point
Total Percent Solids
Percent Solids
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
- Fax:[phone]
Lab Project Number: 9286481
Client Project ID: CORPENING CREEK SLUDGE
— ---------------------
Project Sample Number: 9286481.007 Date Collected: 0.1/24/05 13:00
Matrix: Soil Date Received: 01/24/05 15:30
Results
Units
Report Limit
Analyzed
By CAS No. Oual RegLmt
Prep/Method:
EPA 3050 /
EPA 6010
16000
mg/kg
.270
01/29/05
18:36
LBG. 7429.90 5
NO
mg/kg
13.
01/29/05
18:36
LBG 7440.38.2
ND�
mg/kg
2.7
01/29/05
18:36
LBG 7440.43.9
12000
mg/kg
270
01/29/05
18:36
LBG 7440.70.2
480
mg/kg
5.3
01/29/05
18:36
LBG 7440.50-8
68:
mg/kg
13.
01/29/05
18:36
LBG 7439-92.1
4200
mg/kg
270
01/29/05
18 36
LBG 7439.95.4
92,
' lei,
mg/kg
mg/kg
13.
13.
01/29/05
01/29/05
1Ep
1E
3900
mg/kg
2700
01/29/05
1E'
NO
mg/kg
13.
01/29/.05
It
NO
mg/kg
2700
01/29/05
lE
1100
mg/kg
27.
01/29/05
1E
O1/28/05
01/28/05
1
IVA
Method: EPA 7471
1.2 mg/kg
Method: X Moisture
96.4 X
Method: EPA 1010
>140 F
Method: EPA 160.3
3.6 %
0.14 01/26/05
Nitrogen, Ammonia Method: EPA 350.1 Modified
Nitrogen, Ammonia NO mg/kg 240
Total Kjeldahl Nitrogen, Soil Method: EPA 351.2
Nitrogen, Kjeldahl', Total 61000 mg/kg 270C
Nitrogen, Nitrate plus Nitrite Method: EPA 353.2 Modified
Nitrate -Nitrite (as N) NO mg/kg 230
Date: 02/09/05
O1/25/05 0
02/01/05 1
O1/25/05 TSE
O1/25/05 12:03 TMR 7727.37.9
01/25/05 JDA1
02/03/05 14:39 SHB 7727.37.9
REPORT OF LABORATORY ANALYSIS
Asheville IN This report shall not be reproduced, except in full,
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc.
NC Drinking Water 37712
Page: 8 of 33
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
sr 99nn6

_� c•. .../gym-nnnml/
Resort No: 10075
NCDA&CS Agrononllc ulvts1011 Ylloile: ---5-.....•.,•-b-
Grower:
•- ----.
Southern Soil Builders, Inc.
Copies To.
:.
958 Hoots Rd
SoilTest Report
Roaring; River, NC 28669
Farm:
'
11/14/2005
SERVING N.C. RESIDENTS FOR OVER 60 YEARS
McDowell County
C 12,
$
Agronomist Comments
Field;Information
Applied Lime
Recommendations
S
Cu
Zn B
Mn
See Note
Sample No. Last Crop Mo Yr T/A
Croy or Year Lime
P205 K20
Mg
12
Kl
1st Crop: Fes/OG/rim,M
.9T
120-200 0 40 60
0 0
0
0 .0
0
2nd Crop:
0
Test Results
Soil Class HM%
W/V CEC BS%
Ac pH P-1 K-1 Ca%
Mg%
Mn-I Mn-AI(1)Mn-AI(2) Zn-1
Zn-AI
Cu-I
S-I
SS-1
NO3-N NHS-N
Na
0.1
MIN 0.56
1.03 11.9 82.0
2.2 5.6 84 43 64.0
16.o
169 118 380
380
163
51
Field Information
Applied Lime
Recommendations `
S
Cu
Zn B
Mn
See Note
Sample No. Last Crop Mo Yr T/A
Crop or Year Lime
P205 K
Mg
0
12
R1
1st Crop: Fes/OG/rim,M
0
0
-120-200� 0 0
0 0
0
.0
pH$
2nd Crop:
0
Test Results
CEC BS%
Ac pH P-I K-I Ca%
Mg%
Mn-1 Mn-AI(1)Mn-AI(2) Zn-I
Zn-AI
Cu-1
S-1
SS-1
NO3-N NH4-N
Na
Soil Class HM%
MIN 0.6
W/V
1.02 13.8 94.0
0.8 6.8 80 110 59.0
31.0
143 91 125 125
90
36
0.1
Field Information_
Applied Liine
Recommendations ,
Zn B
Mn
See Note
Sample No. Last Crop Mo Yr T/A
Crop or Year Lime
P205K2
. 0
Mg S
0
Cu
0
12
K2
1st Crop: Fes/OG/rim,M
0
120-200 0 0-20
0
0
.0
pH$
2nd Crop:
0
Test Results
W/V CEC BS%
Ac pH P-1 K I Ca%
Mg%
Mn-1 Mn-AI(1)Mn-AI(2) Zn I
Zn-AI
Cu 1
S-I
SS-1
NO3-N NHS-N
Na
0.1
Soil Class HM%
MIN 0.66
1.07 13.5 91.0
1.2 6.5 173 77 71.0
18.0
319 201 459
459
255
42
Field Information
Applied Lime
Recommendations
K20
Mg S
Cu
Zn B
Mn
See Note
Sample No. Last Crop Mo Yr T/A
Crop or Year Lime
PzOs
0
12
R2
1st Crop: Fes/OG/1'im,M
1.7T
120-200 0 30-50
0 0
0
0 .0
2nd Crop:
0
Test Results
BS%
Ac P-1 K-1 Ca%
Mg%
Mn-1 Mn-AI(1)Mn-AI(2) Zn-I
Zn-AI
Cu-I
S-1
SS-1
NOs-N NH4-N
Na
Soil Class HM%
W/V CEC
pH
- A
0
()S 74 130
H0
98
75
(),I
MIN 081 099 85 660 2.9 5.1 60 5S 1.0 _

Gllf� ®+ lvio-foh :200115
Annual Retort Review SOP
1.. Annual Land Application Certification Form
• Was a certification form submitted? Y"
• Was land application conducted during the reported year? yes ff
® How many dry tons and dry tons per acre were applied? 3c).G 5 1.. L 6p f/1 c-
,gl� s�` ..r-
• Were the applications within the permitted amount? Ylls"
• Verify PAN if more than 10 tons/acre N A
• Did it indicate compliance? IDS
• Was it signed by the appropriate people?YS
2. Monitoring
• Were the analyses conducted at the required freq y y e5
• Were the metals analyses reported on the Residual Sampling Summary Form? y� J
• Were the results reported in mg/kg? at5
• , Were the heavy metals within ceiling concentration permit limits?),O-s
• If no, were the lab analyses attached?
• Were all the required parameters tested? Yes
• Was TCLP analysis conducted?,/ V-5
3. Field Summary
• Were the land applicationevents recorded on the Field Summary Forms? y.Q5
• Was a Field Summary Form submitted for each field?
• Were all the residuals applied to permitted land? YSS
• Were all the residuals applied from permitted sources?yes
• Were the field loading rates for each metal and PAN calculated (year to date)?ys
• Were the cumulative pollutant loading rates calculated?
�t�
• Were the calculations correct? Y.@-5
• Were the PAN loading rates within permit limits?Yes
• Were the heavy metal cumulative pollutant loading rates within permit limits? yve5
• Were the residuals applied on a suitable erop?jeS
• Were the applications conducted during the crop's growing season?Y&5
• Were the Field Summary Forms complete?�IP-5
4. Pathogen and Vector Attraction Reduction
• Was a signed copy of the Pathogen and Vector Attraction Reduction Form submitted?ye
• Did the form indicate the period of coverage, the residual class, and the pathogen reduction alternative and the
vector attraction reduction option used? yeS
• Was the appropriate documentation to show pathogen and vector attraction reduction included in the report? yes
• Was pathogen and vector attraction reduction demonstrated according to 40 CFR Part 503? y�g
5. Soil Tests
• Was a Standard Soil Fertility Analysis conducted for each application field? yes sh°old i�,r, -Pln5
• Were the soil pH's 6.0 or greater for each application field? po K 1- 5.0 a^G kai-o ' 6 o
• Were the copper and zinc indexes in the soil less than 3000 for each application field? diCJ,SAa,
6. General
Was the report in the proper format?y.._s
Were any parts of the annual report missing? No
Was the report submitted on time?j,-s
* Any violations of ceiling concentrations should be reported to Pretreatment for municipalities only.

�l9 =. 0 ..3 X CTt�N - N 3)
= 0.3 (69,&oo- Gob) + (0. !S x Good j gq
+ ®o y
17` (791/ w► 1�g �c , 0"0 J 1,C> 7-
3.3715A3 .D7/Ac--
V DT�HL
0l Y , 00 � ; .00gO� lb/DT X 2.`fy7o73 o i924 V'IAC
oogoQ X
3, 3�t513 = 0, D/!pS r161nc-
.off 373 )''' 15�A
0d7,2- Y. 3.3��"
c� �?l

VS in 0.96
VS out. 0.72
VSFR= 0.892857 All
VS in 0.80 /
A
VS outS Ols�Ste�
0.72
VSFR= : 0.357143
a

CITY OF MARION
CREEK WASTE TREATMENT PLANT LABORATORY
VOLATILE SUSPENDED SOLIDS WORKSHEET
STANDARD METHODS 20TH EDITION ---METHOD # 2540 E
RUN DATE: �~ `b S� TIME IN:
ANALYST: IRA
y TIME OUT:4SP
ANALYST: 0� TIME WEIGHED: /95-S-
A C A-C
z0 pv
�za 'C
VSS FIXED
B A-B B -C
Sample
DATE
Collected
Sample
Vol.
ML
Filter
Num.
FILTER +
Residue
betore
Ignition, Gr.
FILTER
Wt.
Gm.
Residue
before ign.
Wt., Gr.
Residue
before ign.
Wt, Mg/L
FILTER + ASH
After Ignition
(GRAMS)
ASH +
FILTER
(GRAMS)
ASH
Gr.
TOTAL
Fixed
Solids
MG/L
TOTAL
VSS
MG/L
% VSS
Blank
qp
`/v
Btii99Op
�[
CC Inf.
-z,S o5
25 mi.
z
ZZ
e 4/1Z1
0, 0163
U
25 mi.
�- 313
297
bO'
393
�Z %
0, b oo
0, (�nb
�0
i6 96
,.r
Digester
-2 5
2 mi.
1
(
67/S
?ba
D, b�l
�ZD7
�2 Sid D
- 0 /OG
2 mI.
- ' 2,
. �r`�z/
0, 7(1
. S53,T
: �2-
Q• o5�/0
C, Iwol.
70-Ve
&-S S
I " Z
, �75
0, (0373
W& D
., 8 �
0 0 0
0, ba7
5 1f
S-9 2 0
7 1 91
V,07
tl `f/� S
lP V37Z
7 4�o
o
0, 03 03
0• l0G
8 D
0(oo
8/ Z�
0, o a
--Zv86
8 (080
go
5- 2,b
z
0, 00`29
; s-3 1
0, to/b ?
0: b/�bd
. om_
�z
9Gf3
`�z •
o�' `
i
. l 6
r
"` , P /J 2,
Q�
'G' %� 0O
, ` 4' ;- /r
lY (0 l �T
010007,
O Q
/
Goa
L !Q
DILUTION 1000000
FACTOR = ML OF Sample
Mg Volatile Solids / L = (A - B ) X 1000000
Sample Vol., ML.
Mg Fixed Solids / L = ( B - C) X 100000
Sample Vol., ML.
% Volatile Solids = Total VSS
Tot. Vss + Tot. Fixed
'* BALANCE CALIBRATED DAILY AND RECORDED IN THE ANALYTICAL
BALANCE CALIBRTION BOOK
LOT #'S
GLASS FIBER FILTER:

3)b
CITY OF MARION
CREEK WASTE TREATMENT PLANT LABORATORY
VOLATILE SUSPENDED SOLIDS WORKSHEET
STANDARD METHODS 20TH EDITION ---METHOD. # 2540 E
RUN DATE: �b S� TIME IN:
ANALYST: TIME OUT: /? /5-' Zo
ANALYST: TIME WEIGHED: /902-
A . C A-C
VSS FIXED
B A-B B-C
Num.
Residue
• - • -
•
-Residue
lbefore ign.'biefore
Residue
ign.�"
.
After Ignition
-A
FILTER
-.MEMO"
Fixed
Solids
VSS
F4=1
� • - -
_��
ice✓
�
i I
6!1 I r
/ � a
_ � � �
/ ! _
l i
r I ♦•
� I
��IWON
DILUTION 1000000
FACTOR = ML OF Sample
Mg Volatile Solids / L = (A - B ) X 1000000
Sample Vol.,'ML.
Mg Fixed Solids / L = B - C) X 1000000
Sample Vol., ML.
% Volatile Solids = Total VSS
Tot. Vss + Tot. Fixed
** BALANCE CALIBRATED DAILY AND RECORDED IN THE ANALYTICAL
BALANCE CALIBRTION BOOK
LOT #'S
GLASS FIBER FILTER:
�Z�lD

CITY OF MARION
CORPENING CREEK WASTE TREATMENT PLANT LABORATORY
TOTAL SUSPENDED SOLIDS WORKSHEET
STANDARD METHOD 20TH EDITION ---METHOD 2540D
RUN DATE: / �� TIME IN; lS�/� TEMP. IN c
ANALYST: TIME OUT: l �-/0, TEMP. OUT
TIME WEIGHED:
A B A-B
LOT #'S
GLASS FIBER FILTER: 42690
MINIMUM REPORTING VALUE = <2
IA - B11000
SAMPLE
ID
DATE
COLLECTED
Sample
Volume
ML
FILTER #
FILTER+
Dry Residue
(GRAMS)
FILTER
Weight
(GRAMS)
RESIDUE
Weight
(GRAMS)
RESIDUE
WEIGHT
MG
TOTAL
SUSPENDED
SOLIDS MG/L
REPORTED'
TSS .
MG/L
111 LSs •
/� �as
s"
Yr513
D r<l1 �(r,
3 � •
� 3 � O
?a qt� .
�r
,r—
p
�9 /
�(� I
!7. 6 �7 c
3 7• d
`Z 6 0.
Total Suspended Solids, Mg / L = (A - B) X 1000000
Sample Vol_, ML.
A = WT. OF DRIED RESIDUE +, Filter, Gr.
B = WT. OF Filter, Gr.
TSS Duplicates Limits
UWL = 0.9 UWL = Upper Warning Limits
UCL = 1.2 UCL = Upper Control Limits.
;_ t