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WQ0003699_Application_19980918
RECIRCULATION SYSTEM EVALUATION Proposed Bear Creek Plant Modifications Existing Permit No. WQ0003699 SR-1197 (Bear Creek Road) Mitchell County, NC Prepared For: Mr. Beau Thomas Zemex Corporation P.O. Box 99 Spruce Pine, NC 28777 September 18, 1998 Prepared By: Engineering & Environmental Science Company 3008 Anderson Dr. Suite 102 Raleigh, NC 27609 T. Patrick Shillington, P.E. President 62S els ENGINEERING & ENVIRONMENTAL SCIENCE COMPANY 3008 ANDERSON DRIVE, SUITE 102 RALEIGH, NC 27609 (919)781-7798 September 18, 1998 Mr. Beau Thomas Zemex Corporation P.O. Box 99 Spruce Pine, NC 28777 RE: Recirculation System Evaluation Proposed Bear Creek Plant Modifications Existing Permit No. WQ0003699 SR-1197 (Bear Creek Road) Mitchell County, NC Dear Mr. Thomas: Engineering & Environmental Science Company (E2S) has completed the evaluation of the proposed recirculation system modifications (Permit No. WQ0003699) at the Bear Creek Plant. This report contains a discussion of the system modifications, wastewater characteristics and other pertinent information. Submitted with this report are the "Plans and Specifications." Following is a brief discussion of the project. To increase the production of the plant facility, the existing sediment ponds will be replaced with two larger basins. No other modifications to the recirculation system are anticipated, except for the new pipeline and pumps to convey the water at a rate of 1500 gallons per minute. Each of the two new ponds will have a capacity of a least 1,195,154 gallons. The ponds will be cons-tructed -on- an approximately 8 to 10 percent slope with the base of the pond at least Oft above the groundwater table. The ponds will contain no more than 8ft of water depth and will have a 2ft thick soil liner having a coefficient of permeability slower than 1x10-6 cm/sec. Maximum embankment height will not exceed 14ft. An upslope interceptor ditch designed for the 50-year rain has been provided to prevent runoff in to the ponds during precipitation. No groundwater monitoring during the operation of these ponds is planned at this time. No monitoring at the existing ponds is required. However, some of the recently installed piezometers can be converted to permanent monitoring wells if needed. We appreciate serving you on this project. Please contact us, if you have any questions about these evaluations. Sincerely, �. Patrick i11ingto�, P. �. President .............. `� `''-; .�%''; •. a 1547, 1lrt9iiliilli 62S TABLE OF CONTENTS Page No. 1.0 General Project Information ................. 1 2.0 Waste Water Characteristics ................. 1 3.0 Pump and Pipe Line Evaluation ............... 1 4.0 Upslope-Interceptor Ditch Evaluation ........ 2 5.0 Subsurface Evaluation ...................... 2 5.1 Subsurface Conditions .................. 3 5.2 Soil Liner Materials .................. 4 5.3 Foundation Settlement .................. 5 5.4 Embankment Stability .................. 5 LIST OF TABLES Table No.1: Summary of Soil Test Results ........ 4 Table No.2: Groundwater Elevations .............. 4 ATTACHMENTS Attachment A: Figures Attachment B: Material Safety Data Sheets Attachment C: Pump and Pipe Line Evaluation Attachment D: Upslope Ditch Evaluation Attachment E: Boring Logs and Soil Test Results Attachment F: Embankment Stability Evaluation 62, Page 1 Zemex Corp. 1.0 General Project Information A modification is proposed for.the process water recirculation system at the Bear Creek Plant (existing permit No. WQ0003699). The plant facility is located northwest of Spruce Pine, North Carolina in Mitchell County (see Attachment A). The plant process is to recover mica, sand and clay materials. The sand and mica are collected at the plant and the clay is collected at a series of existing ponds (basins). To increase production at this facility, the water usage will increase from 18,0.00 gallons per day to a maximum of 900,000 gallons per day. Two new ponds will be constructed each with a minimum capacity of 1,195,154 gallons. Once these basins are in operation, the existing ponds will not be used for the recirculation system.. The ponds will have a clay soil liner two feet thick and the base of the ponds will be established about 4ft above the groundwater table. The proposed new recirculation system will also include two 8"x6" Denver -Solo SRL-C pumps capable of flow rates of 1,500 gallons per minute. The water will be conveyed from the plant to the ponds through an 8-inch P.E. pipe and from the ponds to the plant through a 6-inch P.E. pipe. Various valves will be required with this system. 2.0 Waste Water Characteristics After the wastewater has passed through the plant system it will primarily consist of clay sediment. Sulfiric acid and Econofloat A-50, A-55 and A-60 which contains about 30 to 40 percent C-4 to C-10 Alcohols (see Attachment B) are added to the plant process to cause flotation of the mica. However, these materials are only added sufficiently for---.th-e-separation process and generally are not present after usage in the plant as residual concentrations will impact the recirculated water effectiveness to separate the mica. No analytical test data is available as none has been required for this existing recirculation system. 3.0. Pump & Pipe Line Evaluation The plant facility is about 23ft lower that the top of the proposed pond embankment. To have at least a flow of 1500 62S Page 2 Zemex Corp. gallons per minute, two pumps will be - -required. One pump at the plant to convey the water to the ponds and one pump at the ponds to convey the water to the plant. The pipeline will be 8 inches in diameter for the conveyance of water to the ponds and will be 6 inches in diameter to convey the water to the plant. Based on the evaluation in Attachment C, the line will be Driscopipe with a SR19 thickness for the 8 inch pipe and SR11 thickness for the 6 inch pipe. The pumps will be 8"x6"x18" Denver -Solo SRL-C slurry pumps with a revolution per minute of 1200. Valves will be provided downstream of the pumps to manually control the flow rates. 4.0 Upslope Interceptor Ditch Evaluation The rational design method (see Attachment D) was used to determine the maximum flow rate for the 50-year rain event of the upslope watershed at two locations on the ditch. The ground cover of the watershed was assumed wooded as it presently exists. The ditch capacity was passed on tall grasses present. The depth of the ditch below the downslope embankment will vary from 2.5ft to 4.5ft deep. The need for temporary stabilization of the ditch and actual discharge point for the ditch is to be determined by Zemex Corporation when they modify their active erosion control plan. 5.0 Subsurface Evaluation A total of seven soil borings were conducted with a drill rig and five test pits were conducted with a track hoe. Four of the soil borings were converted to temporary piezometers with water levels measured 24 hours after drilling. The soil borings were advanced using hollow -stem auger drilling procedures, with subsurface materials sampled at select intervals using a split -spoon sampler. These samples were obtained in accordance with the Standard Method for Penetration Test and Split -Barrel Sampling of Soils (ASTM D- 1586). The borings were located at the approximate locations as indicated on Sheet 1 of -the -accompanying -plans...- _ Representative soil samples from each boring were sealed in plastic bags and were returned to E2S's laboratory, where a Geotechnical Engineer inspected and visually classified the samples in accordance with the Unified Soil Classification 62S Page 3 Zemex Corp System. Laboratory testing was performed on representative soil samples to confirm their visual classifications and to provide general index properties. Soil strength properties of cohesive soils were also estimated in the laboratory using a calibrated penetrometer. One permeability test was conducted on a remolded soil -sample.-The--soil" boring and test pit logs and soil tests are provided in Attachment E. The following evaluations and recommendations are based on our understanding of the project characteristics and on our evaluation of the general subsurface conditions indicated by the borings. Should the project characteristics change significantly or should significantly different subsurface conditions be encountered during construction, some of the recommendations presented may no longer be valid. In such cases, E 2 S should be further consulted. 5.1 Subsurface Conditions Iri accordance with the "Geologic Map of North Carolina," the site lies within the Alligator Back formation of the Blue Ridge Belt. Locally, muscovite -biotic gneiss, amphibolite and quartz diovite to grandiovite bedrock can be present. In accordance with the partially completed "USDA soil survey of Mitchell County, disturbed soils are predominate at the proposed pond locations. Upslope of the ponds are the Evard- Cowce soil complex. Typically at mid to lower slope portions, Saunock soils are present. These soils typically have a seasonally high water table of greater than 6 feet. At the borings and test pits, approximately 6 inches of topsoil and rootmat were encountered at groundsurface. At the upslope borings and test pits the soils to a depth of 7ft to 14ft below ground surface consisted of a CL to MH soil type. Below these depths, the soils were predominantly "ML" soil types with the presence of high mica content. The following table summarizes the analytical test results: 62S Page 4 Zemex Corp. Table No.l: Summary of Soil Test Results Location Depth (ft) Atterbers Limits, % Standard Proctor Coef. Of Perm CM/Sec LL PL PI O.M. % Max.Den. lb/ft3 P-1 3-5 67.9 60.5 7.4 29.5 87.5 (1) 8.1x10- P-1 13-15 45.5 41.9 3.6 ---- ---- ---- P-4 8-10 40.4 23.1 17.3 ---- ---- ---- (1) Soil compacted to 94.8 of Standard Proctor at 28.-9% moisture content. Auger cuttings collected from Oft. to 7£t. below groundsurface for sample representation. Upslope of the proposed ponds groundwater was about 14ft to 19ft below groundsurface. Downslope of the proposed ponds, the groundwater level was 1.5ft to 2.5ft below ground surface. The following table summarizes the groundwater levels. Table No. 2: Groundwater Elevations Location Top of Casing (ft) Water Depth (ft) Water Elevation (ft) P-1 128.6 16.09 113.85 P-2 109.02 3.41 105.61 P-3 98.05 4.80 93.25 P-4 123.29 21.02 102.27 5.2 Soil Liner Materials The shallow CL&MH soils present to a depth of 7ft. to 14ft. below groundsurface at the upslope and mid slope areas of the ponds appear suitable for the soil liner material. Using the less pervious MH soil types, the coefficient of permeability is 8.1x10-7 cm/sec, when compacted to 94.70 of standard Proctor maximum dry density (ASTM-D-698). The more plastic CL soil types would be expected to have a slower coefficient of permeability. To ensure adequate permeability in the field, the suitable soil types should be computed to at least 95 percent. Because the ponds will be periodically cleaned of sediments, the liner should be at least 2ft thick. 62S Page 5 Z—X Corp. 5.3 Foundation Settlement Subsurface materials below the 14ft high (maximum) embankment, consists of approximately 10 feet of ML soils, underlain by a partly -weathered rock. The analyses shown in Attachment F indicate that maximum settlement between the dam crest and toe would be less than 1.6 inches, with total settlement not exceeding 1.8 inches. 5.4 Embankment Stability Slope stability analyses downstream and upstream provided in Attachment F. were performed on the highest portions of the embankments as For the upstream embankment formed by cut, the factor of safety was determined using limited equilibrium theory. The factor of safety of the 22ft. high cut will be at least 1.8. For the downstream embankment formed primarily by fill, the stability factor of the embankment against sliding on the approximately 10 percent existing slope was estimated at greater than 2.3. These factors of safety are considered suitable for the proposed ponds. 62s ATTACHMENT A: FIGURES - - - - - - - 62$ ■ . 1 C N G j 300 I` TSCS SPRUCE PINE QUADRANGLE YAP VA 8 �X-Wffl jrcl No SITE ENGINEERING at ENVIRONMENTAL 2 SCIENCE COMPANY 3008 ITE ANDERSON OR- Sum 102 RALEIGH. NORTH CAROLINA 27609 (919) 781-7798 VICINITY MAP HATE- O8/18/8B BEAR CREEK PLANT PERMIT Nu. WQOOOS699 rrcvtu ra MITCHELL COUNTY. NC ATTACHMENT B: MATERIAL SAFETY DATA SHEETS 62S I PRODUCT IDENTIFICATION N NUFACTURER'SNAME Tennessee Chemical Company REGULAR TELEPHONE NO. 404-233-6811 EMERGENCY TELEPHONE NO.Chemtrec 800-424-930 3475 Lenox Rd. NE, Suite 670 A -DRESS Atlanta, Georgia 30326 1 ADE NAME Sulfuric Acid (See bill of lading for concentration) SYNONYMS Oil -of Vitriol DOT: Sulfuric Acid, Corrosive Liquid, UN 1830 RQ = 1000 lbs (454 kg) SHIPPING N AM E1 (ATA: 11 HAZARDOUS INGREDIENTS2 .-AT—.1:-.L OR COMPONENT =.... No. .. - .. I HAZARD DATA rros i v c :viateriaiS it Sulfuric Acid (H-;S0,1) ! 7664939 I Aquatic hazardous substank C50 = � 10 to = 10 i mQ / i 600 Be 77.0 40 CFR 116 & 118 (EPA) ealth hazards : 66 ° Be I 93 p Dehvdrator. Causes third degree burns to skin. 95% 95.0 Corrosive. LC 8 hrs = Mist inhalation 18 mg/m` 98% 98.0Iffor 1-2 month old 2. D. an 50 mg /m' for 18 month of Q. p. TLV or TWA 8 hr III PHYSICAL DATA exposure = 1 mg/m-'. b o / ° 66 ° = -26 °, 95% _ - 10 i ILING POINT,760 MM HIS 0 F. i375 529 560 640 MELTING POINT F 98% = 370 SPECIFIC GRAVITY (H O - 1) @ 600 F 2 1.7057 1.8407 1. 8354 1.8438 VAPOR PRESSURE - POR DENSITY (AIR - 1) 3. 38 3. 38 - - SOLUBILITY IN H2O % BY WT Completely % VOLATILES BY VOL. - EVAPORATION RATE (BUTYL ACETATE o 1) N � PEARANCEAND'OGOR Clear, colorless liqui Ph (AS IS) StrOna acid �o oaor Ph (1%SOLN.) IV FIRE AND EXPLOSION DATA _ASH POINT AUTOIGNITION (TEST METHOD) None TEMPERATURE None AMMABLE LIMITS IN AIR,% BY VOL. LOWER None UPPER None Acid itself is no.t flammable but may cause ignition by contact with coznbus t- I TINGUISHING ible liquids and solids. In fires where acid is present, use dry chemical, I DIA carbon dioxide or water fog. ,AL FIRE Do not allow water to enter storagecontainers as a violent reaction can occ Also hydrogen gas can accumulate n containers and care must be taken not i 1 iHTING I DCEDURES to ignite. Wear rubber suits, rubber gloves, rubber boots, goggles or face shield and hard hat. "'USUAL FIRE The acid will not burn but can start fires with organic materials, nitrat , Hydrogen, highly flammatle DEXPLOSION carbides, chlorates, and metallic powders. a ZARD and explosive gas is generated by acid action on most metals. Hydrogen gas can accumulate in containers and care must be taken not n ignite it r. V HEALTH H/\ZAIID ire,=7i1M�1T�oni j HEALTH HAZARD DATA �— HAZARD CLASS!FICA1 ION BASIS FOR CLASSIFICATION- SOURCE - — LC50 8 hrs. Sulfuric acid - - --- -- I UTF.SOFEY.POSURE mist = 18 mo/m3 for 1-2 mo. 1, 2 old guinea pigs or 50 cjlg/rn3 .NHALATION Corrosive for 18 mo. old g. p. 16 CFR 1500. 3 5 mg/m3 is distinctly objec- 3, 4 tionable level. TWA - 8 hrs. - 1 lao/m3 set 29 CFR 1910. 1090 for xpos ?re. SKIN CONTACT Corrosive - 1, 2, 3 16 CFR 1500. 3 SKIN AP.SORPTION Corrosive - 1, ;'. , 3 I 16 CFR 1500. 3 EYE CONTACT i ` Ji'r Lire - 1, 2, 3 16 CFR 1500. 3 GESTION - - flSiVe - I, 2, 3 16 CFR 1500.3- C 9 a t t a n C FFECTS OF 0V'E X u:;i_ Tissue destruction upon exposure and dehydration. May cause ),CUTE t't_ird degree burns. :,ha.lation of mist can cause bronchitis hyperemia., epithelial degeneration i cHs;oNlcovEl� >' ,f the larvn.s, trachea, and bronchi with laryngeal or bronchial spasms. -- rf— n sl:�all amounts of sulfuric acid enter the eyes, immediately, _;:rERGEtiCY An D 1: 1; ;ID = u' irri,,ate iti- laroe amounts of •.Water for at least 15 minutes. Mold eyelids apart during irri.oation. Send patient to a physician or eve SIDecialist immediate- EYES:ly. Continue `..nshin ogyres (,urin'o transit if needed. ---------_---� 1'asi? it:, lar ':, ounts ;,f ,:.ester r-nd remove clothing and shoes under shoxcr. I - SKIN: G-`e k INHALATIC'd hl'i?�:ivC' ;'.':)ri',e..r !r71T1 :i[�ljh Q llld seek medical aid. Drink 11in-i 1edlately to reduce conceIltration. See't INGESTION'. Y1'��1C 11 <?1,1 iLPC_:�tU1c1iC1". 1'o not. Induce vomiting. TOPHYsICiAi: Treat as C rinSiye material. erenCeS: 1) The respiratory rC'S�'�)I1Sl' 01 ou1nea pins to sulfuric acid mists. AmdOr, i\L. O• Archives of Industrial :1calth. 18: 407-1.1. 1958. 2) Dangerous Properties of Industrial Materials. N. Irving Sax. 4th Edition. Van Nostrand Reinhold Co., INT. Y. 3) Properties and Essential Infori-rati,�n for Safe IIandlino and Use of Sulfuric Acid. Chemical Safety Data Shect SD-20. Manufacturing Chemists Assn., Washington, D. C. 4) Occupational Exposure to Sulfuric Acid. HEW Publication No. (NIOSI-I) 74-128. VI REACTIVITY DATA 'J1)ITIONS CONTRIBUTING To INSTABILITY ( tact with metal powders may release hydrogen, a highly flammable gas. Contact with bustible materials may cause them to ignite. :( PATIRILITY Do not pour water into acid. Do not store near nitrates, carbides, chlorates, - ides, or other combustible organic substances. Do not mix with metal powders as hydrogen, Highly flammable and explosive gas, can be generated.— .Y ;DOUS DECOMPOSITION PRODUCTS Hydrogen gas can be generated inside steel drums, tank cars, trucks, or metal storage tanks. As hydrogen is a flammable gas, expl9sive mixtures r under certain conditions may result. Smoking, fires, or open lights should not be permitted a-' these containers. Other products include sulfur dioxide and sulfur trioxide. 'i IO',JS CONTRIBUTING TO HAZARDOUS POLYNER!ZATIONI V11 DISPOSAL, SPILL OR LEAK PROCEDURES Aquatic toxicity range set by EPA as Category C, (LC50 range = >10 to 100 n1,/1). Reference 40 CFR § 118. '.STE DISPOSAL t,1ETHOD . in area where spills or leaks can be contained and dispostd of properly. Preferrably ,.__tralize v.:ith lime or soda ash. The resulting sulfate salts may be diluted, land filled, or ached to sewage plants if local ordinances permit. Ei'S-i O L'E -TAKEN IF IMATERIAL IS RELEASED OR SPILLED 1 taminated area should be thoroughly flushed down with large amounts of water and soda ash .I ame spread over area to neutralize residual acidity. If spill is sufficient to contaminate ev,!er system, neutralize washings ,,.,ith soda ash or other alkaline material. -1 'RALIZING CHEMICALS ;t.)aa ash, lime, or other alkaline material. Vill SPECIAL PROTECTION1 INFORMATIO�NI :al exhaust ventilation may be nec-_�Ssary to limit employee exposure in processes L` : ra__- ici mist. Ventilation :Fill also bc, necessary to clear storage tanks prior to entry. I log:' OSHA regulations for tani; entry. -CICICPERSONALPROTLCTIVE EQUIP-MENT For acid ',ases and mist concentrations less than 10 times the T, a chemical cartridge respirator approved by NIOSH for acid gases and mists may be _= d. Use a full facepiece if eye irritation is noted. See reference (4). For emergencies se approved self-contained breathing apparatus in pressure demand mode with full facepiece. Chemical safety ;,o11 ooles. Face shield may be worn. Rubber gloves should be .,,'orn if body contact is possible. ijT11F:Fi Ct:T'`11NG AND ECUII't'; NT Rubber safety shoes, or rubbers worn over leather safety shoes. Wear rubber apron if body contact is possible. L: IX SPECIAL PRECAUTIONS PRECAUTIONARY STATEMENTS Containers and carriers containing corrosive liquid must be properly labeled, placarded, shipping papers, and transported in accord with Federal regulations contained in 49 CFR Parts 171 - 177, and other applicable Federal, State and Local regulations. OTHER HANDLING AND STORAGE RECLUIREMENTS Hydrogen can be generated inside drums and tanks; therefore open lights, smoking or sparks should not be permitted near open drums or tanks. When diluting with water, add acid to water - never add water to acid. Do not allow water to enter storage tank as a violent reaction can occur. ADDITIONAL REGULATORY CONCERNS FEDERAL: FDA When used as a direct or indirect additive to foods or substances in contact with food substances. USDA - CPSC - TSCA I$ THl1 PRODUCT. OR ALL ITS INGREDIENTS; BEING CERTIFIED FOR INCLUSION ONI THE TOXIC SUBSTANCES CONTROL INVENTORY OF CHEMICAL SUBSTANCES? Yes OTHER EPA when used as a pesticide. STATE: T.Jnknown. OSHA: Product is a hazardous material as defined by 29 CFR g1 1) 10. 1200 because it is corrosive to ingest, skin, eyes, and sulfuric acid mist is regulated by 0SI-T1A as an air contaminant. Product is not listed by the National Toxicology Program, the International Agency for Research on Cancer, nor the Registry of Toxic Effects of Chemical Substances (1981-821 as a carcinogen or potential carcinogen. PREPARED BY Dr. Arthur F. Gohlke TITLE: Technical Service_Snecialist CO�.'PANY: Tennessee Chemical Company devised —' 475 Lenox Rd. NE, Suite 670 MATERIAL SAFETY DATA SHEET SECTION 1 - PRODUCT IDENTIFICATION PRODUCT NAME AND SYNONYMS: ECONOFLOAT A-50, A-55, & A-60 CAS NO.: Mixture, does not apply. CHEMICAL FAMILY: Mixture, see Section VI, Health Hazard Information. CHEMICAL FORMULA: Mixture, does not apply. MANUFACTURER'S NAME AND ADDRESS: Nottingham Company 1303 Boyd Avenue NW Atlanta, Georgia 30318 (404) 351-3501 EMERGENCY TELEPHONE NUMBER: CHEMTREC - (800) 424-9300 For Chemical Emergency- Spill, Leak, Fire, Exposure, or Accident CALL CHEMTREC - DAY OR NIGHT SECTION H - HAZARDOUS COMPONENTS ACGIH OSHA COMPONENT WT. % CAS. NO. TLV PEL C-4 to C-10 Alcohols 30-40 Mixture Not determined. HMIS RATING: HEALTH: 2 FLAMMABILITY: 2 REACTIVITY: 0 PERSONAL PROTECTION: B APPEARANCE AND ODOR: Amber liquid with characteristic odor. MOLECULAR WEIGHT: Mixture, does not apply. BOILING POINT (DEGREES FAHRENHEIT): Initial 192T. FREEZING POINT (DEGREES FAHRENHEIT). Not determined. VAPOR PRESSURE (mm of mercury) : Not determined. SPECIFIC GRAVITY (WATER = 1): < 1.0 . VAPOR DENSITY (AIR =1): Not determined. PERCENT VOLATILE (BY WEIGHT): Not determined. pH: Not determined. SOLUBILITY IN WATER: Dispersible. EVAPORATION RATE (BUTYL ACETATE = 1): Not determined. SECTION IV - FIRE AND EXPLOSION DATA FLASH POINT (DEGREES FAHRENHEIT): 110°F PMCC. a FIRE: EXTINGUISHING MEDIA: Water fog, Dry Chemical, Foam, CO2 . FLAMMABLE LIMITS (PERCENT BY VOLUME): Not determined. SPECIAL FIRE FIGHTING PROCEDURES & EQUIPMENT: Keep fire exposed containers cool with water. DO NOT USE WATER SPRAY AS PRODUCT MAY FLOAT AND CAUSE FIRE TO SPREAD ON SURFACE. UNUSUAL FIRE & EXPLOSION HAZARDS: Do not weld, cut or burn any drums, bulk storage tanks or associated piping used with this product. Heat generated by' welding, cutting, or burning can cause spontaneous combustion and/or explosion. An enriched oxygen atmosphere can cause spontaneous combustion and/or explosion. HAZARDOUS COMBUSTION PRODUCTS: CO2; CO, nitrogen compounds. MSDS9 94-0040.1) Approved by:' �- PAGE I OF 4 Revision D Dated: November 24, 1997 SECTION V - REACTIVITY DATA STABILITY: Stable. CONDITIONS TO AVOID: Do not store in close proximity with strong oxidizing agents. Avoid heat, sparks or flame. INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: COz, CO, nitrogen compounds.. HAZARDOUS POLYMERIZATION: Will not occur. SECTION VI - HEALTH HAZARD INFORMATION Regarding directives in the OSHA Hazards Communication Act 1910.1200 paragraph (i), the specific chemical identity of this product is being withheld as a trade secret. Information contained in this Material Safety Data Sheet discloses the properties and effects of this mixture. EFFECTS OF OVEREXPOSURE: EYE CONTACT: Liquid is severely irritating to the eyes. Vapors may also be irritating. SKIN CONTACT: Liquid is moderately irritating to the skin. Prolonged or repeated liquid contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis. Liquid is also moderately toxic and may be harmful if absorbed through the skin; may produce central nervous system (CNS) depression. INHALATION: Vapors may irritate the nose, throat and respiratory tract. High vapor concentrations may cause CNS depression. INGESTION: Liquid is moderately toxic and may be harmful if swallowed; may produce CNS depression. PROBABLE ROUTES OF EXPOSURE: Skin, eyes, ingestion. EMERGENCY AND FIRST AID PROCEDURES: EYE CONTACT: Thoroughly flush eyes with running water for at least 15 minutes, see a physician immediately. Remove contact lenses if worn. SKIN CONTACT: Remove contaminated clothing. Immediately wash skin with soap and plenty of water. Wash contaminated clothing before use. INHALATION: Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get medical attention. INGESTION: Do not give liquids if victim is unconscious or very drowsy. Otherwise, give no more than 2 glasses of water and induce vomiting by giving 30cc (2 tablespoons) syrup of Ipecac.* If Ipecac is unavailable, give 2 glasses of water and induce vomiting by touching finger to back of victim's throat. Keep victim's head below hips while vomiting. Get medical attention. NOTE TO PHYSICIAN: *If victim is a child, give no more than one glass of water and 15cc (1 tablespoon) syrup of Ipecac. If symptoms such as'loss of gag reflex, convulsions or unconsciousness occur before emesis, gastric lavage should be considered following intubation with a cuffed endotracheal tube. PAGE 2 OF 4 i\/ISDS4 94-0040.D SECTION VII - TOXICITY DATA ORAL: Not determined. DERMAL: Not determined. INHALATION: Not determined. CARCINOGENICITY: None of the contents of this product are listed by the National Toxicology Program, the International Agency for Research on Cancer, nor the Registry of Toxic Effects of Chemical Substances (1981-82) as a carcinogen. SECTION VIII - SPECIAL PROTECTION INFORMATION PERSONAL PROTECTIVE EQUIPMENT: PROTECTIVE GLOVES: Impervious rubber. EYE PROTECTION: Safety Goggles, Safety Glasses, or Face Shield RESPIRATORY PROTECTION (SPECIFY TYPE): Organic vapor canister mask or self-contained air mask. Use only in a well ventilated area. VENTILATION: LOCAL EXHAUST: Mechanical ventilation is usually adequate. SECTION IX - SPILL. LEAK AND DISPOSAL FRQUEDUKr:S STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Recover clean material for use as intended. Remaining material can be soaked onto absorbent and shoveled into waste containers. WASTE DISPOSAL METHODS: Dispose of contaminated absorbent material in accordance with local, state, and federal regulations. Under RCRA, it is the responsibility of the user of products to determine, at the time of disposal, whether products meet RCRA criteria for hazardous waste. This is because product uses, transformations, mixture, processes, etc. may render the resulting material hazardous. Waste Classification: Product has been evaluated for RCRA characteristics and does meet the criteria of a hazardous waste if discarded in its purchased form. SECTION X - REGULATORY INFORMATION USDA: Not determined. CPS: Not determined. TSCA: Pursuant to TSCA Section 8(e) Paragraph VII(c), this product complies with all requirements of TSCA. DOT: PROPER SHIPPING NAME: Combustible Liquid nos (contains alcohol) HAZARD CLASS: Combustible. LABEL REQUIRED: Combustible Liquid. IDENTIFICATION NO.: NA 1993. PACKING GROUP: III NMFC: item 50227sub 1, Industrial Process Water Treating Compound, Class 60 OTHER PERTINENT INFORMATION: None. PAGE 3 OF 4 MSDS-4 94-0040.D EPA: Superfund Amendments & Reauthorization Act (SARA) Title III; Section 302/304, Extremely Hazardous Substance: Chemical CAS 4 . Weight Percent R Lbs TP Lbs None---- ------ ---- ----- Title III; Section 311, Hazard Categorization: Acute, Fire. Title III; Section 313, Supplier Notification: This product is known to contain the following chemicals which are listed in 40 CFR 372.65 as toxic chemicals requiring notification: Chemical CAS # Weight Percent None --- --- CERCLA Section 102(a) Hazardous Substance: Chemical CAS # Weight Percent R Lbs Isobutyl Alcohol 78-83-1 13 5000 Your receipt of this MSDS fulfills our supplier notification obligation under SARA Section 313 (40 CFR 372.45). If you resell 6r distribute this product you must by law furnish a copy of the MSDS and appropriate warning label to your customers, advising them of their obligations to communicate the information provided here. SECTION XI - SPECIAL PRECAUTIONS AND COMMENTS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Store in a cool dry place, in tightly sealed containers. Do not use unlacquered aluminum. Do not store next to direct heat or flames. OTHER PRECAUTIONS: Store drums in a protected area to prevent mechanical damage. Avoid frequent or prolonged skin contact. IMPORTANT: The information and data herein are believed to be accurate and have been compiled from sources believed to be reliable. It is offered for your consideration, investigation and verification. Buyer assumes all risk of use, storage and handling of the product in compliance with applicable federal, state and local laws and regulations. Nottingham Company will not be liable for claims relating to any party's use of or reliance on information and data contained herein regardless of whether it is claimed that the information and data are inaccurate, incomplete or otherwise misleading. Note: Changes are distinguished by bold italics print. PAGE 4 OF 4 MSDST 94-0040.D ATTACHMENT C PUMP AND PIPE LINE EVALUATION C2a - -------- -- r . - - ----------- 45,31 ASO 0 2t 7t3 V/ ---- ---- --- - -- - ---------- --- - lo" 4- f/Z UUU�111"' 2- 464 2-000 12L 60- - 1 9 = w )P- ; C) .,Iploo = Pressure Loss In psi per 100 feet 9 M2 a 0 U � OMIM �m —wr. m MM 0 -3 -A MMMOME A A AA IF v TV CO Cf) 6.1 3i C @ 0 Of b v-; m CD M TS a iN 1 CD RO 10M a 12 1., MLm Ana 11 cl, 4m CD n a Bw m ch CD -n c-5 -n cn 0- cn '14 0 (D L3 W �-:3dldOOSAYCI a 0 SRcL•PUMP Soft Rubber Lined PUMP PERFORMANCE CURVE 200 180 160 140 120 ti 100 80 60 40 20 f 0 80 60 .40 20 40 - 20 SIZE: 8 X 6 X 18 FRAME: FOUR IMPELLER: AC 1800 MAXIMUM SOLIDS:17/a" DIA. EYE AREA: DATE: DEC. 25, 1974 ■■■■■■■■■■ ■■pn■■■■■: ■■■■■R■ ■ ■■■ ■ ■■■■ ■■: ■■ ■■ ■ ■■■■■11r, : :■u I :■o :..... %:■�::No v .... .. .......■ SKI "I; ,... MA OWMA OZONE ■ ■ WEBB! SEEN :: C ME 0 ■NEE:�: : ...■ �s�: :�•••:-----: �s on: :E :.10 : : 10M ■. ■�:=■::::�:a■::■ :: :: :�■•R :::: :: .�': .701=mmmnm��omHill':sa:: s:: :■N��:::::::::' ■■■■■ � ■■E■■■■■ ■■.■■mmmIII :MOSME� N.::ONE . mam,■ .IN ii- ■ Now ■ HEWW■■RW .....■. .■. WEER■■ ■ .. 00 2 4 6 8 10 12 14 16 18 20 a9Pfi Note: Beyond 122.8 inches (10.2 ft.) the soil friction will overcome the tensile force developed by thermal contraction of the pipeline. This is calculated by dividing the tensile force in the pipe by the frictional resistance of the soil (ie: 781.3 lbs. - 6.363 lbs./in. _ 122.8 Inches) Theoretical Movement of Unrestrained Ends: AL = L•s AL = (122.8 ins.)(.0024 in./in.) = .295 in. Design of Collar: By sidewall fusing branch saddles capable of taking the shear force onto the pipe near the terminal connection, and then pouring a square concrete collar around the pipe and branch saddles into undisturbed soil, the tensile force of 781.3 lbs. is removed from the pipe connection and is evenly distributed into the soil. Assume a collar 12 inches square and 6 inches wide is used. Area of Collar = (12" x 12") — (Cross Sectional Area of Pipe) A = (144 — 16) sq. in. A = 128 sq. in. surface area Compressive Stress on soil due to load transfer by collar face: S = F--A S = 71.3 lbs. --128 sq. in. = 6.1 psi EXAMPLE DESIGN SUMMARY Under a 20°F instantaneous temperature change, a 4" SDR 15.5 pipeline 1000 ft. long buried five feet deep will try to change length .295" at each end. The pipe is restrained by soil friction from further contraction. A concrete collar with a square face of 12" x 12" will absorb the tensile force of 781.3 lbs. due to thermal contraction, and distribute it into the soil at a compressive soil stress of 6.1 psi. Circumferential coefficient of expansion is 0.6 x 10-4 in/in/°F. Chart 16 Driscopipe Pressure Rating (psi) vs. Temperature (°F) Hoop Pipe SDR - Temp. Stress OF (psi) 32.5 26 21 119 17 .15.5 13.5 11 9.3 50 1820 58 73 90 00 113 125 145 180 215 60 1730 55 69 86 96 108 119 138 170 207 73.4 1600 51 64 80 90 100 110 128 160 190 80 1520 48 60 76 85 95 105 122 150 182 90 1390 44 56 70 77 87 96 111 140 167 100 1260 40 50 63 70 79 87 101 125 150 110 1130 36 45 57 63 .71 78 90 113 135 120 1000 32 40 50 56 63 69 80 100 120 130 900 28 36 45 50 56 62 72 90 108 140 800 25 32 40 45 50 55 64 80 96 Chart 17 Instantaneous Modulus of Elasticity i vs. Temperature 140°F . . . . . . . . . . . . . . . . . . . . 50,000 psi ....... 1 3.40F 73.4°F 1 00 0 50°F . . . .. . . . .......... . . . . . 1 000 psi 32°F . . . . . . . . . . . . . . . . . . . . 200,000 psi 0°F . . . . .. . . .. . . . . 260,000 psi —20°F . . . . . . . . . . . . . . . . . . . . 300,000 psi 31 ATTACHMENT D : UPSLOPE DITCH EVALUATION 62S I , - -- ------ ----- --- I !%(j --------- - -- 4, Pole ------------------- ----------- r -------------------------------- ------ EVAHU-GOWtt Ju' IU DU" NERA LITY T COMF"" 0 a5 0 a� 0 ca c 0 Q a� 0 E a� N 0 E 0 t m Note: Use nomograph Tc for natural basins with well-defined channels, for overland flow on bare earth, and for mowed -grass roadside channels. For overland flow, grassed surfaces, multiply Tc by 2. For overland flow, concrete or asphalt surfaces, multiply Tc by 0.4. For concrete channels, multiply Tc by 0.2. Figure 8.03a Time of concentration of small drainage basins. Tr(min) 200 100 50 10 5 417 5 8.03.4 Appendices 20 15 . � I 10 L n 4 a) L U 2 .N C (D I 0.8 ro 0.6 c 0.4 0.2 01 ■■lll ■■■■�mm MEN■■■ ■Nip■■■■■c��■■■■■�■■ . • • ■NNa����� MINIM 5 10 20 40 60 2 3 4 6 8 12 18 24 1 Minutes Hours Duration Figure 8.03f Rainfall intensity duration curves —Asheville. 20 15 Charlotte 10. 8 6 o ,4 4 i er�r7p °° c 2s° d`y� 0.8 0.6 c .@ 0.4 0.2 0.1 5 10 20 40 60 2 3 4 6 8 12 18 24 Minutes - Hours Duration Figure 8.03g Rainfall intensity duration curves —Charlotte. 8.03.7 G�it't/< �'1=U�3� �r65c���fo�! b�ltZdZ 3�� Z°3�la r- ----_ 6 -t 2d 74 7���1� "i .i F� :i tom° 2:1 0 %l 0 P/ 0 of 006 OPT o0L -OB% - OSi - OZ 007 • o�•o `y •o�n OTT gro Qi • 0 t'O sso oE•0 •52v oz n si•o :L CHART b = 2 FT. Appendices ©r3� 4. .08 CU .06 04 .02 .I Step 10. For grass -lined channels once the appropriate channel dimensions have been selected for low retardance conditions, repeat steps 6 through 8 using a higher retardance class, corresponding to tall grass. Adjust capacity of the channel by varying depth where site conditions permit. NOTE 1: If design velocity is greater than 2.0 ftjsec., a temporary lining may be required to stabilize the channel until vegetation is established. The temporary liner may be designed for peak flow from the 2-yr storm. If a channel requires temporary lining, the designer should analyze shear stresses in the channel to select the liner that provides protection and promotes establishment of vegetation. For the design of temporary liners, use tractive force procedure. NOTE 2: Design Tables —Vegetated Channels and Diversions at the end of this section may be used to design grass -lined channels with parabolic cross -sections. Step 11. Check outlet for carrying capacity and stability. If discharge velocities exceed allowable velocities for the receiving stream, an outlet protection struc- ture will be required (Table 8.05d, pg. 8.05.9). Sample Problem 8.05a illustrates the design of a grass -lined channel. -.-MENIMMEN W� 010110 oil Longer t—hm 30" .. than 2" 0111206. n 111... X, `".■.B�_ \ki ___i���_ Q11�.2 Ufr3t� .4 .6 .8 1.0 VR, Product of Velocity and Hydraulic Radius 6 8 10 20 Figure 8.05c Manning's n related to velocity, hydraulic radius, and vegetal retardance. Note: From Sample Problem 8.05a multiply Vp x Hydralulic Radius (4.54.54=2.43), then enter the product of VR and extend a straight line up to Retardance class "D", next project a straight line to the left to determine a trial manning's n. Rev. 12193 8.05.7 ATTACHMENT E : BORING LOGS AND SOIL TEST RESULTS 62S UNIFIED SOIL CLASSIFICATION SYSTEM MAJOR GROUP TYPICAL NAMES LABORATORY CLASSIFICATION CRITERIA DIVISIONS SYMBOL y WELL GRADED GRAVELS, Gy � D 2 60 c ; GW GRAVEL -SAND MIXTURES, o C -_ > 4 1 < C (D30) u < 3 LITTLE OR NO LINES. 10 DIO x D60 ., v 4 WAN � W � 1" POORLY GRADED GRAVELS, NOT MEETING ALL GRADATION GP GRAVEL -SAND MIXTURES, LITTLE OR NO LINES. - Q W 0.Q REQUIREMENTS FOR GW. W S o ti vtb-o $ e�. H CM SILTY GRAVELS, GRAVEL -SAND -SILT MIXTURES. W v ggqw, W ATTERBERG LIMITS "" BELOW ALINE OR ABOVE "A" LINE WITH F W ?o4� 5 W 4 P I. LESS THAN 4. P.I. BETWEEN 4 AND 7 ARE BORDERLINE N G a m a W ti > N y�� q � ti p CASES REQUIRING USE OF DUAL SYMBOLS. ATTERBERG LIMITS CLAYEY GRAVELS, GRAVEL -SAND -CLAY MIXTURES. �� ' ABOVE "A" LINE WITH q v q U W tgh4bg P.I. GREATER THAN 7. W ti E, W Q ��� y M W Sw WELL GRADED SANDS, GRAVELLY SANDS, rn o o D 2 Cu = > 8 1 < C� _ (D30) < 3 � LITTLE OR NO LINES. W Nib 10 DIO x D6O q c y ti gxyr'i POORLY GRADED SANDS, NOT MEETING ALL GRADATION a q o a y� W q o F N N O a N G SP GRAVELLY SANDS, LITTLE OR NO LINES. x W � o REQUIREMENTS FOR SW. y F SM SILTY SANDS, 4 F ATTERBERG LIMITS BELOW "A" LINE OR 4 a ti W SAND -SILT MIXTURES. r P.I. LESS THAN 4. LIMITS PLOTTING IN HATCHED ZONE WITH A y W y y v y k P.I. BETWEEN 4 AND 7 q N CLAYEY SANDS, N N W 1 ATTERBERG LIMITS ARE BORDERLINE CASES REQUIRING USE SC SAND -CLAY MIXTURES. Er' W b i ABOVE "A" LINE WITH OF DUAL SYMBOLS. W q 0i y U P.I. GREATER THAN 7. INORGANIC SILTS, ROCK FLOUR, L PLOT INTERSECTION OF AND LL AS DETERMINED FROM ML VERY FINE SANDS, SILTY OR ATTERBERG LIMITS TESTS.I. p CLAYEY FINE SANDS, CLAYEY 2. POINTS PLOTTED ABOVE a LINE INDICATE CLAY SOILS, y n SILTS WITH SLIGHT PLASTICITY. THOSE BELOW THE A LINE INDICATE SILT. V INORGANIC CLAYS OF LOW TO 70 CL MEDIUM PLASTICITY, GRAVELLY C i? CLAYS, SANDY CLAYS, 60 SILTY CLAYS, LEAN CLAYS. CH `4 y OL INORGANIC SILTS AND ORGANIC 50 PL u� a SILTY CLAYS OF LOW PLASTICICTY. CL o 40 0 INORGANIC SILTS, MICACEOUS OR W 30 W MH DIATEMACEOUS FINE SANDY OR SOILS, ELASTIC SILTS. q 0 o SILTY �'(1 20 v v y q F CH INORGANIC CLAYS OF HIGH PLASTICITY, FAT CLAYS. y i0 MH OH 7 w �° 0. 4 0 ML OL 0 10 20 30 40 50 60 70 80 90 100 y OH ORGANIC CLAYS OF MEDIUM a HIGH PLASTICITY, ORGANIC SILTS. y LIQUID LIMIT (LL) PEAT AND OTHER HIGHLY PLASTICITY CHART PI ORGANIC SILLS. o� 14 ENGINEERING do ENVIRONMI SCIENCE COMPANY UNIFIED SOIL CLASSIFICATION SYST%.- RALEIGH, 3ooe NORTH DR.. SUITE NOH CAROUNA ASTM DESIGNATION D-2487# G2S (919) 781-7798 ENGINEERING Qt ENVIRONMENTAL 6�^ SCIENCE COMPANY 3008 ANDERSON DR.. SUITE 102 RALEIGH. NORTH CAROLINA 27609 .(919) 781-7798 KEY TO SOIL SYMBOLS AND CLASSIFICATION The abbreviations commonly employed on each "Record of Subsurface Exploration". on the figures and in the text of the report, are as follows: I. SOIL DESCRIPTION (a) Cohesionless Soils Relative Density N. blows/ft. Very Loose 0 to 4 Loose 5 to 10 Medium Dense 11 to 30 Dense 31 to 50 Very Dense Over 50 (b) Cohesive Soils Consistency Qu, TSF N, blows/ft. Very Soft Less Than .25 0 to 3 Soft .25 to .50 4 to 5 Medium Stiff .50 to 1.00 6 to 10 Stiff 1.00 to 2.00 11 to 15 Very Stiff 2.00 to 4.00 16 to 30 Hard Over 4.00 31 or more II. PLASTICITY Degree of Plasticity Plasticity Index None to Slight 0 to 4 Slight 5 to 10 Medium 11 to 30 High to Very High Over 30 III. RELATIVE PROPORTIONS Descriptive Term Percent Trace 1 to 10 Little 11 to 20 Some 21 to 35 And 36 to 50 IV. PARTICLE SIZE IDENTIFICATION Boulder: 8 inch diameter or more. Cobbles: 3 to 8 inch diameter. Gravel: Coarse: 3/4 to 3 inch. Fine: 5.0 mm to 3/4 inch. Sand: Coarse: 2.00 mm to 5.0 mm. Medium: 0.40 mm to 2.00 mm. Fine: 0.07 mm to 0.40 mm. Silt: 0.002 mm to 0.07 mm. Clay: up to 0.002 mm. V. SOIL PROPERTY SYMBOLS N: Standard Penetration Resistance: Number of blows by a 140 lb. hammer dropped 30 inches required to drive a 2" O.D. split —spoon sample one foot. Qu: Unconfined Compression Strength, TSF Q: Penetrometer Unconfined Compression Strength, TSF Od: Natural Density, PCF V: Apparent groundwater level at time 0: Noted after completion Mc: Water Content LL: Liquid Limit, % PL: PLastic Limit, % SL: Shrinkage Limit PI: Plasticity Index LI: Liquidity -index (Mc=PL/PI) e: Void Ratio Gs: Specific Gravity of Solid Particles k: Coefficient of Permeability is Hydraulic Gradient q: Rate of Discharge h: Hydraulic Head or Potential CLIENT: Zemex Corp. BORING NO.: P-1 DATE: 09109198 PROJECT NAME: Bear Creek Plant JOB NO.: PROJECT LOCATION: Mitchell County STATION: .BORING METHOD: HSA FOREMAN: Dais Ferrell ROCK CORE DIA.: INSPECTOR: SHELBY TUBE O.D.: **SPT a WELL DIAGRAM w DESCRIPTION &REMARKS �� aw � ww any ca �j 2I3 Av hq �R S W o 02 �U VFWF SURFACE ELEVATION: 128ZO (TOC) w x Ceiw q T Topsoil and root mat 05 Reddish —brown & maroon silty/ CLAY (MH), with minor black mica particles, moist 5 8-7 14-18 4.0 7.0 Reddish —brown to dark —brown fine sandy SILT (ML), with , minor black mica particles & feldspar and quartz fragments moist to very moist 10 11-34 34-40 2 0 14.0 Reddish —brown, white, & mica mottled SILT (ML), wet 15.0 13-13 0.75 — 15 11-2 Reddish —brown, black & light —brown mottled highly — micaceous SILT (ML), wet. 20 22.77 X. Auger refusal at 22.77 feet 25 WELL LEGEND ®-BENTONITE EJ -SAND -2"DIA. No.10 SCREEN, SCHEDULE 40 PVC -2" DIA. PVC 30 SOLID PIPE 35 BORING METHOD GROUND WATER HSA — HOLLOW STEM AUGER NOTED ON RODS FT. _ AFTER HRS. FT. CFA — CONTINUOUS FLIGHT AUGER *ORGANIC VAPOR METER, DC — DRIVEN CASING PARTS PER MILLION � AT COMPLETION FT. _ AFTER HRS. FT. MD — MUD DRILLING RC — ROCX.CORING "STANDARD PENETRATION TES AFTER HRS. FT. AFTER HRS. FT. CLIENT: Ze7nex Corp. BORING NO.: P-2 DATE: 09 O9 9B PROJECT NAME: Bear Creek Plant JOB NO.: PROJECT LOCATION: Mitchell County STATION: BORING METHOD: HSA FOREMAN. Dan Ferrell ROCK CORE DIA.: INSPECTOR: SHELBY . TUBE O.D **SPT WELL DIAGRAM DESCRIPTION & REMARKSh no Q4 qF w� as �5 o oy SwF „ SURFACE ELEVATION: 1oeo2 (Toc) w a . Topsoil and root 7ncLt Reddish —brown slighty micaceous silty CLAY (CHIMH) very motst Feldspar fragments at 4S to 5.0 ft 5A tJ—B 5 1 10-16 IB Reddish —brown, gold and black very micaceous SILT (ML) wat — 2 3-4 4-4 1.0 10 12A Boring terminated at 12.0 ft 15 20 WELL LEGEND ® —BENTONITE 25 —SAND —2"DIA. No.10 SCREEN, SCHEDULE 40 PVC —2" DIA. PVC SOLID PIPE 30 35 BORING METHOD GROUND WATER HSA — HOLLOW STEM AUGER i0 NOTED ON "RODS FT. — AFTER HRS. FT. CFA — CONTINUOUS FLIGHT AUGER *ORGANIC VAPOR METER, DC — DRIVEN CASING PARTS PER MILLIONyn'.W7 AT COMPLETION FT. _AFTER HRS. FT. MD — MUD DRILLING RC — ROCK CORING "STANDARD PENETRATION TEST AFTER HRS. , FT. AFTER HRS. FT. Zemex Corr. BORING NO.: P-9 DATE: 09 10 98 AME: Bear Creek Plant JOB NO.: F OCATION: Mitchell County STATION: BORING METHOD: HSA FOREMAN: Dan Ferrell ROCK CORE DIA.: INSPECTOR: SHELBY TUBE O.D.: **SPT WELL DIAGRAM m a DESCRIPTION & REMARKS N w 9X, rA F z �o� o > o� yWti 22IJ„ r h Q� W C :21 V -q:i : V4 SURFACE ELEVATION: 98.05 (TOC) oa x 1 To soil and root mat Reddish —brown, ,gold & black, very micaceous, SILT (ML), very moist 5 1 8-5 4-5 1.0 Wet after 5 ft. Feldspar and quartz fragments after 9 ft. 2 18-28 0.76 10 21—H — Boring terminated after LZ1 ft 15 20 W . T, , r, F r FF IV ®-BENTONITE 25 -SAND -2"DIA. No10 SCREEN, SCHEDULE 40 PVC -2" DIA. PVC SOLID PIPE 30 35 BORING METHOD GROUND WATER HSA — HOLLOW STEM AUGER NOTED ON RODS FT. _ AFTER HRS. FT. CPA — CONTINUOUS FLIGHT AUGER *ORGANIC VAPOR METER, DC — DRIVEN CASING PARTS PER MILLION ;qqV AT COMPLETION FT. S AFTER HRS. FT. MD — MUD DRILLING RC — ROCK CORING **STANDARD PENETRATION TEST AFTER HRS. FT. _ AFTER HRS. FT. �L� I CLIENT: Zemex Corp. BORING NO.: P-4 DATE: 09 10 96 PROJECT NAME: - -- Bear Creek Plant . JOB NO.: PROJECT LOCATION: Mitchell County STATION: BORING METHOD: HSA FOREMAN: Dan Ferrell ROCK CORE DIA.: INSPECTOR- SHELBY TUBE O.D.: **SPT WELL DIAGRAM •�• ti DESCRIPTION & REMARKS 4 D� Cqr4y ca 0. �� 0.� j A yq hx O O " C� SURFACE ELEVATION: 12329 (TOC) w a ow 4 Topsoil and root mat Light reddish —brown & reddish —brown mottled sandy. silty - CLAY (CL) , +hoist 5 1 5—B 15-12 4.0 10 - 2 -- 4-6 B-10 - - - -4D — Reddish —brown, and minor black micaceous SILT (ML), vary moist — Feldspar fragements after 14 ft. — 15 3 I6-20 1.5 — 26-26 — B—B 0.5 — 20 4 14-14 = 22.2 1 1 1 1— Auger refusal at 222 ft. WELL LEGEND ®-BENTONITE 25 EI-SAND -2"DIA. No.10 SCREEN, SCHEDULE 40 PVC -2" DIA. PVC SOLID PIPE 30 35 BORING METHOD GROUND WATER HSA — HOLLOW STEM AUGER NOTED ON RODS AFTER—HRS. FT. CFA — CONTINUOUS FLIGHT AUGER �ORCANIC VAPOR METER, NOTED FT. _ DC — DRIVEN CASING PARTS PER MILLION "•7 AT COMPLETION FT. AFTER—HRS. FT. MD — MUD DRILLING RC — ROCS CORING -STANDARD PENETRATION TEST AFTER—HRS. FT. AFTER—HRS. FT. CLIENT: Zemex Corp. BORING NO.: B-1 DATE: 09110198 PROJECT NAME: Bear Creek Plant JOB NO.: PROJECT LOCATION: Mitchell County STATION: BORING METHOD: HSA FOREMAN: Dan Ferrell ROCK CORE DIA.: INSPECTOR: SHELBY TUBE O.D.: **SPT WELL DIAGRAM E" DESCRIPTION & REMARKStz W WW SURFACE ELEVATION: Al x oW 4 Topsail & roots 0.5 Reddish —brown silty CLAY (CHIMH), moist .. with minor bllck mica particles 5 5.0 1 0-7 7-10 9.0 y 6-7 30-40 Reddish —brown micaceous SILT (ML), black mottled, moist 10 Quartz and feldspar fragments after 10 ft. 11.5 Auger refusal at 11.5' 15 20 25 30 35 BORING METHOD GROUND WATER HSA — HOLLOW STEM AUGER £' Q NOTED ON RODS FT. _ AFTER HRS. FT. CFA —CONTINUOUS FLIGHT AUGER *ORGANIC VAPOR METER, DC — DRIVEN CASING PARTS PER MILLION 1:,AjU7 AT COMPLETION FT. _ AFTER HRS. FT. MD — MUD DRILLING RC — ROCK CORING #tSTANDARD PENETRATION TEST ' AFTER - HRS. FT. AFTER—HRS. FT. M CLIENT: ZeTnez Corp. BORING NO.: D-2 DATE: 09110198 PROJECT NAME: Bear Creek Plant JOB NO.: PROJECT LOCATION: Mitchell County STATION. BORING METHOD: HSA FOREMAN: -Dan Ferrell_ ROCK CORE DIA.: INSPECTOR: SHELBY TUBE O.D.: **SPT x w WELL DIAGRAM DESCRIPTION &REMARKS F Fw gy-4gq SURFACE ELEVATION: w a Topsail & roots 0.5 Reddish —brown silty CLAY (CHIMH), moist with minor baack mica particles 5 5.0 1 5-7 7-10 gD 2 6-7 30-40 Reddish —brown micaceous SILT (HL), black mottled, moist 10 Quartz and feldspar fragments after 10 ft. Auger refusal at 11.9 15 20 25 30 35 BORING METHOD GROUND WATER HSA — HOLLOW STEM AUGER NOTED ON RODS FT. AFTER HRS. FT. CFA — CONTINUOUS FLIGHT AUGER *ORGANIC VAPOR METER, DC — DRIVEN CASING PARTS PER MILLION i AT COMPLETION FT. AFTER—HRS. FT. MD — MUD DRILLING RC — ROCK CORING **STANDARD PENETRATION TEST, AFTER—HRS. FT. AFTER HRS. FT. vLV CLIENT: Zemez Corp. BORING NO.: 13-9 DATE: 09110196 PROJECT NAME: Bear Creek Plant JOB NO.: PROJECT LOCATION: Mitchell County STATION: BORING METHOD: HSA FOREMAN: Dan Ferrell ROCK CORE DIA.: INSPECTOR: SHELBY TUBE O.D: **SPT WELL DIAGRAM DESCRIPTION & REMARKS a - �" w .w, 44 �� �FF rq SURFACE ELEVATION: "n Topsoil & roots 0.6 Reddish —broom silty CLAY (MH), moist 5 5.5 1 10-7 6-7 10 15 20 25 30 35 BORING METHOD GROUND WATER A —HOLLOW STEM AUGER CF� NOTED ON RODS FT. _ AFTER—HRS.—FT. CFA —CONTINUOUS FLIGHT AUGER *ORGANIC VAPOR METER, DC —DRIVEN CASING PARTS PER MILLION `� AT COMPLETION FT. ® AFTER—HRS.—FT. MD — MUD DRILLING RC — ROCK CORING -STANDARD PENETRATION TEST AFTER HRS. FT. 1W AFTER—HRS.—PT. CLIENT: Zemex Corp. BORING NO.: TP-1 DATE: 09110198 PROJECT NAME: Bear Creek Plant JOB NO.: PROJECT LOCATION: Mitchell County STATION: BORING METHOD: Track hoe FOREMAN: Dan Ferrell ROCK CORE DIA.: INSPECTOR: SHELBY TUBE O.D.: **SPT x WELL DIAGRAM a DESCRIPTION &REMARKSEl F 4� 4i aa� w �E'h Av y4 �� W o � 02 a s w -qw SURFACE ELEVATION: w g Topsail & roots 0.6 Cray silty SAND (SM), with bolders to 1' dia. moist 3.0 Reddish —brown silty CLAY CH MH , moist 5 7.0 Reddish=brown and black, micaceous sandy SILT (ML), vary moist to wet 10 15 17.5 20 25 30 35 BORING METHOD GROUND WATER HSA — HOLLOW STEM AUGER CPA — CONTINUOUS FLIGHT AUGER `ORGANIC VAPOR METER, 0 NOTED ON RODS FT. AFTER—HRS.—FT. DC — DRIVEN CASING PARTS PER MILLION 114JE7 AT COMPLETION FT. AFTER—HRS.—FT. MD — MUD DRILLING RC — ROCK CORING *oSTANDARD PENETRATION TESTP= AFTER HRS. FT. 'Vv AFTER HRS. FT. CLIENT: Zemez Corp... BORING NO.: TP-2 DATE: 09110198 PROJECT NAME: Bear Creek Plant JOB NO.: PROJECT LOCATION: Mitchell County STATION: BORING METHOD: Track hoe FOREMAN: Dan Ferrell ROCK CORE DIA.: INSPECTOR: SHELBY TUBE O.D : **5PT 6� a F WELL DIAGRAM a DESCRIPTION & REMARKS q �y ¢zF SURFACE ELEVATION: '� w Topsoil & roots :0.5 Light, roddish—brown silty. CLAY (CHIM14 moist - 5 s.o Light-6rmon and black micaceous sandy SILT (ML), moist to very moist 10 15 28.5 20 25 30 35 BORING METHOD GROUND WATER XSA — HOLLOW STEM AUGER 0 NOTED ON RODS FT. _ AFTER HRS. FT. CFA — CONTINUOUS FLIGHT AUGER *ORGANIC VAPOR METER, DC —DRIVEN CASING PARTS PER MILLION f `� AT COMPLETION FT. _ AFTER HRS. FT. MD — MUD DRILLING RC — ROCK CORING **STANDARD PENETRATION TEST ._ AFTER—HRS. FT. _AFTER HRS. FT. c CLIENT: Zemea Corp. BORING NO.: TP—s DATE: 09110196 PROJECT NAME: Bear Creek Plant JOB NO.: PROJECT LOCATION: Mitchell County STATION: BORING METHOD: Track Hoe FOREMAN: Dan Ferrell ROCK CORE DIA.: INSPECTOR: SHELBY TUBE O.D.: **EPT w WELL DIAGRAM mC4a E� DESCRIPTION & REMARKS �� !M W Fw 4F a�D3 pq �FF wv F Ca D _O SURFACE ELEVATION: 04 Topsail & roots 0.5 Light —brown SILT (ML) with quartz and feldspar fragments, moist 5 5.0 Reddish —brawn, maroon and black, micaceous SILT (ML), vary moist ' 10 14.0 15 20 25 30 35 BORING METHOD GROUND WATER HSA — HOLLOW STEM AUGER CFA — CONTINUOUS FLIGHT AUGER *ORGANIC VAPOR METER, 0 NOTED ON RODS FT. _ AFTER—HRS.—FT. DC — DRIVEN CASING PARTS PER MILLION {Q AT COMPLETION FT. AFTER—HRS.—PT. MD — HUD DRILLING RC — ROCK CORING **STANDARD PENETRATION TEST _ AFTER—HRS. FT. _ AFTER—HRS. FT. �L� Ze�mex Corp. FPROJECT BORING NO.: TP-4 DATE: 09/10/98 AME: Bear Creek Plant JOB NO.: PROJECT LOCATION: Mitchell County STATION: BORING METHOD: Track hoe FOREMAN: Dare Ferrell ROCK CORE D'IA.: INSPECTOR. SHELBY TUBE O.D.: **SPT be 9: F WELL DIAGRAM a DESCRIPTION & REMARKS � a El' q Q rn 02 � rn a V 0 eZ 0 o NWh SURFACE ELEVATION: raQ Topsail & roots •0.5 Brown sandy silty CLAY (CL), trace of feldspar fragments` moist to very moist 5 7.0 _ Light reddish —brown and black, micaceous SILT (ML). moist to very moist 10 Fhite and maroon mottled after 12 ft. i 15 20 25 30 35 BORING HSA'— CFA = DC — MD — RC — 18.0 METHOD HOLLOW STEM AUGER CONTINUOUS FLIGHT AUGER *ORGANIC VAPOR METER, DRIVEN CASING PARTS PER MILLION MUD DRILLING ROCK CORING **STANDARD PENETRATION TEST 0 j 141[7 NOTED AT COMPLETION AFTER ON RODS HRS. GROUND WATER AFTER—HRS.—FT. AFTER—HRS. FT. AFTER—HRS. FT. FT. FT. FT. CLIENT: Zemex Corp. BORING NO.: TP-5 DATE: 09110198 PROJECT NAME: Bear Creek Plant JOB NO.: PROJECT LOCATION: Mitchell County STATION: BORING METHOD: Track Hoe FOREMAN: Dan Ferrell ROCK CORE DIA.: INSPECTOR: SHELBY TUBE O.D.: **SPT w WELL DIAGRAM m DESCRIPTION & REMARKS w,w a 5z qow as w y q.. hw Q -q:4 SURFACE ELEVATION: g Topsoil & roots 0.6 ` Brown silty CLAY (CL), moist 5 Trace of mica after 5 ft. 10 14.0 Light reddish —brown and black micaceous SILT (ML). 15 very moist, trace of feldspar fragments 18.0 20 25 30 35 BORING METHOD GROUND WATER HSA — HOLLOW STEM AUGER 0 NOTED ON RODS FT. _ AFTER—HRS.—FT. CFA — CONTINUOUS FLIGHT AUGER *ORGANIC VAPOR METER, DC — DRIVEN CASING PARTS PER MILLION 11U7 AT COMPLETION FT. AFTER HRS. FT. MD — MUD DRILLING RC — ROCK CORING **STANDARD PENETRATION TEST; AFTER—HRS.—FT. AFTER HRS. FT. '�t) FALLING HEAD PERMEABILITY TEST Project: ��u�-C�P�� r/yN Test By: r Location: � << `Gy�CGl Reviewed By: h=l 2.303aL/AtI[log1o(ho/hf) ]RT L=sample length, cm: 12., %® RT=temperature correction factor for viscosity of water different than at 200 C _ A=sample area, cm2: 1.16, 5 t=elapse time,sec. hJ= initial height of water head, cm h = final height of water head, cm f - a =inside area of standpipe, cm-: ei u 62S ATTERBERG LIMITS TEST I Date project: Arlo i Test BY: Location: c� Reviewed By: J LIOUID LIMIT TEST wt. wet - tare,g wt. dry - tare,g moisture weiaht, g tare No. tarp ight,c dry we-Cht,c moil-urc content, 1 1 I r 1 1 correc z i Gn _.c•.- tJr Corr. Molssture CCntc:lt, �u�c � G0,3q Z i 3 2Z,231 ���� � o�f2 3�,tr 5 0,0�1 7,? 61,7 -7"Tl 25 i 5- PLASTIC LIMIT TEST Swt. 7J wet - tare,g wt. dry - tar , g moisture weight,g tare NO. tare weight, g 2G,z�6 dry we i ght, g moisture content A19 Average Moisture Content: pl J _ P I = LL - PL : h;t;" D 423 TABLE 1 N'Rlues of 1.�. 25 ��`== I' io !I �' 1 �' 2? ATTERBERG LIMITS TEST Project: /��� Date: F-. t Test By: It: Location: A— f Reviewed By: v " wt. wet tare,g wt . dr'v' - tare , g moisture weight,g tare No. tare welgnt,C d ry �Ve-ght, g moisture con tent,cs rio. b10-;�s correCticn actor Corr. Moisture Conte=1t .•! . '!! e - tare , Q vet . dr- - tare , g moisture weight,g tare No . tare weight,g dry weight,g moisture content,' Average Moisture Content: LIOUID LIMIT TEST 6 3A ?M 4 13 j�/ %r /7 I 2- ,�f�r lj 5 "2r� F s. 3 46. 31 4% I i PLASTIC LIMIT TEST 503 � I 22•-?l 33.C2 qv O PI = LL - PL 3' 5P "' " D 423 TABLE 1 Values of =5 n p •; q _ i 09 67 - ATTERBERG LIMITS TEST Project: Location: A,il ���,©, wt. wet } tare,g wt. dry - tare,g moisture weight,g tare No. tare weight,g dry weight,g moisture content,% No. blows correction factor �:= � corr. moisture con��nL-, Date: �// y: . 7/yC �J Test B `� Reviewed By: LIQUID LIMIT TEST s': f o-:9 -i 7s, f I ��, - I Average Corrected i.rp; sturc Content : !; PLASTIC LIMIT TEST y w�. Wei tare,g tare,g wt . dry moisture weight, g ; tare No. tare weight, g f� dry weight, g moisture content, g Average Moisture Content: :�-'Fd4 PI = LL — PL : /7, 3 ajj(7 D 423 TABLE I Values of l "•,'25" ' (V/iS to io v I II `. , ( 20 U )-q ,, I U ,) .I 0.Q"Q ,G I., CO) Ula U 98` :h i I QU> ill I„ - 0,99U - I I I n9 i P2, ENGINEERIN(; & ENVIRONMENTAL SCIENCE COMPANY 3008 ANDERSON DRIVE, SUITE 102 RALEIGH, NC 27609 (919) 781-7798 1 MOISTURE DENSITY RELATIONSHID I I 9/12/98 I I I I I I Job No. Date I I I I I I I I Project Name and Location Beit'Creek Plant, Mitchell 130 11 1 1 I I I I I 1 I I I County, ]P-1 I I I I I I - p-1, Oft to loft, Auger Cuttings I I I I I I I Source of Material I I I I I I I Clayey SILT (MH) 125 I I I I I I I I I Description of Material I I I I I I I I I I I I I I I I! I! I I I I I I I I! I I Material Designation I I I I I I I l i l ASTM-D-698 120 I I I I I I I i l I Test Method I I I I I I I I I I I I I I I I I I I I I I I I I! I I I I I N 115 I ! ( I ! ! ! U 1-1 0 ! ! i n 10J5 ! I ! ! I I I I !! I! I! I I! I I I I I I 100 } 95 11 ! ! I I I I I 1 I i ! I I I I I I I I I I I I I I I I I I I I I I I I I I I I 90 I! I I I I I I I I I I I I! I I I I I I I I I I I I I I I I I I I I I I w TEST RESULTS Maximum Dry Density 87•5 PCF 29.5 Optimum Water Content °o CURVES OF 100°a SATURATION ! FOR SPECIFIC GRAVITY EQUAL TO: I I 2.80 ' I - 2.70 III 75 0 5 10 15 20 25 30 35 40 45 %AlotnhO JPCFORM NO 261D6A ATTACHMENT F : EMBANKMENT STABILITY EVALUATION e2S -- d ------- FW _ � �---ter-- - --- --- - --- ---- -- -- - .; %oz- ---------- I--------- - ----- - --------- - P.►' �r2��'o a � v � � . /ram. _ Av - J %t�5- s�✓vr %! 6�roPa��✓ --- - — / ®_-- r i . . ------ Wit.- ------- -- ---- --- - - __ . �' S _-1-2 5 - ---- Z �iQoo 0 Fig. 4.35 Per/off et 0, 0 x/H=0 x/H t H L/H=� z/H 0.5 5 0 1 3 I U.5 1 5 10 50 z/H I' -' I .r/H = (L + H cot a)/H L r(L Hx/H 7/Hica)IH z/H t 3 - L'11=5 - 0.5 0 t n; z'll :e diagrams for vertical normal stress alone I I I I I 1 III . Hx.11=0 i r/Il =1H `•� 5 0 ,5 3 I \ _ 1 i 0 i u.5 I 5 10 50 1.0 0.8 0.6 0.4 1.0 0.8 0.6 0.4 I I I I I I I I I x/H = (L + H cot a)/2H L H s/H (L + H cot a)/i2H z/H 0.5 11 L/H=W I.I �•� 1 5 10 50 100 z/H I I I III I I I I I I I x/H = 3(L + H cot a)/2H rL1 /l .r/ll i 3(L + 11 cot a)12_H _1 vo, awal ZC-Ullb -C rV elastc eIIII)GnKrnent, µ = u.s, of = l b . IArter 1.0 0.8 0.6 0.4 1.0 0.8 0.6 0.4 0.2 0 I I � I I I III I I I I L r,•/1=IL+//cot a1;211 • 11 L; 11 = (L + H cut 3 I \- 0.5 I i I�I I O 1 0.5 ' 1 5 10 50 100 x/11 = 3(L +11 rot a)12ll H ll1 3(L + // Cut 0,)12/1 I 3 L/11=5 0.5 0 ..' 1 5 I 50 IOU 0.1 0.5 1 5 10 50. IOU Fig. 4.36 Influence diagrams for vertical normal stress along selected vertical sections due to elastic embankment, µ - 0.3, ot = 30°. (After Per/off et al., 1967.) R. ------------ - -- -- - ------ --- --- - --------- -- - - --- �i---- ---- ---- -- r/ (�,�u�c�/u/fCV' ��� C�iyu✓ ��f �P fk5 �Vcrl�r�J%``, dSP� P 1, ---1.. 1 � -C /Ott, ®-- - 50�'� S7r� f �0vv� f�-ci %5 �I N� �Q YIPvaf/ ----- - - ---- - -- -- - --- f � %i �' �� ¢ �� ��?ra �✓��.r ff-�t-- �1°t��a a 3.r(� �%b �C �v^1 a, � %f �`�a �� ��c op v ------------------------ - vImP t'd I% ° �J v „� :'� r✓a — --- ---- - --Gslr�ll�tL/iv/ ��. �'` a — ---- ------ - --- --- - - 3 -30 --- �o,gr t�- V/, ) 30 /$/L.�3 +, iII r i /0N 2.2C30te TABLE /C�y'v) 6/� � BLE 10,3 / r/ARISON OF STABI6�i��,l� LIMIT EQUILIBR ULITY FACTOR AND LIMITANgLYS1S (a NS - Hc'Y/c BY 0)• METHODS OF S/opeAng/e Frictio Limit 0, Degrees n Angle E4ui/ibrium Degrees Fe/lenius LiinitAn 90 Cuimann Slices � La/Psis og_ 5 4.00 Circle Spiral S og- Straight 15 4.36 3.83 p/ral Line 4.19 3.83 75 25 5.20 5.02 4.89 4.19 3.83 4.00 0 6.30 6.06 5.02 4.19 4.57 5 5.22 6.06 6.06 5.02 5.20 155.13 6.06 6.30 60 25 45 6.49 513 5.14 4.57 5.22 0 9.80 8.48 6.52 5.13 5.85 5 6.95 5.24 7.45 8.54 6.57 8.59 9.80 45 25 77.30 8.33 8 18 6.18 6.17 5.25 6.95 0 72.20 12.65 8.63 8.64 8.06 5 9.60 5.88 12.82 11.30 15 12.00 7.09 5.88 5.88 72.75 17.30 30 25 20.20 11.77 7.36 5.86 9.60 0 43.50 -12.04 7.33 20.83 22 73 12.00 5 14.90 12.05 20.20 21.20 6.41 6.41, 22.92 15 43.50 15 25 55.50 0.84 9.09 6•.41 6.51 14.90 0 500.00 21.74 9.17 21.20 5 30.40 4 111.1 125.0 21.77 55.50 10 6.90 120.0 500.00 250,00 13.89 43 2 1 q .90 14.80 30.40 Ay d�Yl�lyylPyp/ 45.53 2506.60. 1�/r�A a.00 Al [[ _ I fill//`' 1��7� Ki ✓� �c �V2)(2 5" �1 Td/o laolt ---------- -7 tl4j 375 --- ___ )_ 10q 262-7q Wj 5