WQ0002349_Annual Report_20080221

North Carolina Department of Environmental and Natural Resources
Division of Water Quality
Non -Discharge Permitting Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Reference: 2007 LAND APPLICATION ANNUAL REPORT
Town of Spruce Pine
NPDES Permit No. NCO021423
Dear DWQ Representative:
FEB 2'5 2000
AEtei iiBia regional Office
,E a6fir Protection
Bio-Green Services, Inc. is submitting the monitoring and reporting information as
specified in the referenced permit for the Town of Spruce Pine. The report includes: 1)
Certification Form 2) Residuals Sampling Summary Form 3) TCLP 4) Field Application
Summary and Field Loading Rate Report 5) Annual pathogen and vector attraction
reduction monitoring and certification form 6) Soil Analysis Report 7)ESP and SAR.
Town of Spruce Pine applied wastewater treatment residuals on 2 permitted fields during
2007. A total of 4.65 tons of wastewater treatment residual solids were land applied.
If any further information is required regarding this land application program, please do
not hesitate to contact our office at 336-940-4544 for further assistance.
Sincerely,
Ra ambill
Land Application Manager
Enclosures
4
V
211
�i
FEB 2 1 2008
WATER OUA'r 1 Y SECTION
Information Processing Unit

2007 ANNUAL REPORT
LAND APPLICATION PROGRAMS
TOWN OF SPRUCE PINE, NC
PERMIT #WQ0002349
Compiled By:
Bio-Green Services, Inc.
383 Potts Road
Advance, NC 27006
January 23, 2007

TABLE OF CONTENTS
SECTION NO. TITLE
Facility Information Summary Page
1 Certification Form
2 Residual Sampling Summary Form
3 Toxicity Characteristics Leaching Procedure (TCLP) Analysis
4 Field Application Summary and Field Loading Reports
5 Pathogen/Vector Attraction Reduction Monitoring / Certification
6 Soil Analysis Reports
7 Exchangeable Sodium Percentage Calculation and SAR

FACILITY INFORMATION SUMARY PAGE
Facility name, Address, and telephone number:
Town of Spruce Pine
Post Office Box 189
Spruce Pine, North Carolina 28777
Facility NPDES permit Number:
NCO021423
NC Permit Number
WQ0002349
Name, address and telephone of responsible official (permittee)
Mr. Richard Canipe, Town Manager
Town of Spruce Pine
Post Office Box 189
Spruce Pine, North Carolina 28777
Additional Preparer/Applier:
Bio-Green Services, Inc.
383 Potts Road
Advance, NC 27006
Phone: [phone]
Dry tons of biosolids land applied:
4.65 Tons

Section One
Certification Form

2-12-08; 2:41PM;Town of Spruce Pine
;828+765+3014 # 2/ 2
ANNUAL LAND APPLICATION CERTIFICATION FORM
Permit#: WQ0002349 County: Mitchell Year: 2007
Facility Name (as shown on permit): Town of Spruce Pine
Land Application Operator: Bio-Green Services, Inc. Phone: [phone]
Land application of residual solids as allowed by the permit occurred during the past calender year?
® Yes [3 No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A:
sew /Vow
Part R:
Facility was compliant during calendar year 2007 with all conditions of the land application permit
(including but not limited to items 1-12 below) issued by the Division of Water Quality. ❑ Yes ❑ No
If no please, provide a written description why the facility was not compliant, the dates, and explain
corrective action taken.
1.• Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at
least 6.0 or the limit specified in the permit.
3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three
(3) copies of laboratory results are attached.
4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required
and three (3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities)..
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the .Division of Water Quality.
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed
in accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12, All buffer requirements as specified -on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there arc significant penalties for submitting false information,
including the possibility of fines and imprisonment for know'. violations."
rGi1 ly
errrai a Name and Title (type or print) Signature of Permitted gate
'A/G 4161091
gn ure of Preparer* Date
'different from Permittee)
Preparer is defined in 40 CFR Part 503.9 (r)
Signiture of farad Applier Date
(if different from Permittee and Preparer)
DENR FORM ACF (5/20031

NOTE
**Bio-Green land applied 4.6 dry tons or 98600 gallons in one event for the Town of
Spruce Pine. The remainder was transported by another company to Asheville per
agreement with DWQ.

Section Two
Annual Residual Sampling Summary Form

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: WQ0002349 Laboratory:
Facility Name: TOWN OF SPRUCE PINE
NPDES # or
WQ#:
NCO021423
WWTP Name: TOWN OF SPRUCE PINE
Residual Analvsis Data
P) A and L Eastern Laboratory
2)
3)
4)
5)
Sample or
mill �-41
one Mou
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."

Dosage Rate Evaluation Report
Product Type: SPRUCE PINE WWTFTP
Sample Date:
12/01/07 Usage From:
01/01/07 To:
Parameter
PPM (mg/kg)
Lbs/DryTon
PAN Surface
30190
60.38
TKN
84100 0
168.2
Ammonia Nitrogen (Am)
24800
49.6
Nitrate Nitrogen (Nin)
0
0
Organic Nitrogen (Orn)
59300
118.6
Total Phosphorus (P)
25600
51.2
Total Phosphate (P205)
na
0
Estimated Avail. P205
na
0
Total Potassium (K)
6700
13.4
Total Potash (K20)
na
0
Arsenic (As)
4
0.01
Cadmium (Cd)
0
0
Chromium (Cr)
41
0.08
Copper (Cu)
175
0.35
Lead (Pb)
18
0.03
Mercury (Hg)
4.4
0.01
Molybdenum (Mo)
6
0.01
Nickel (Ni)
17
0.03
Selenium (Se)
3.4
0.01
Zinc (Zn)
679
1.36
Aluminum (AI)
15900
31.8
Calcium (Ca)
63900
127.8
Iron (Fe)
12400
24.8
Sodium (Na)
3100
6.2
Sulfur (S)
8400
18.8
Magnesium (Mg)
4100
8.2
Manganese (Mn)
180
0.38
0
Percent So 1.13
PH Level. 1
6.95
ppm or mg/kg x .002 = Ibs/dry ton
Biosolids/Residuals Application State: NORTH CAROLINA
Organic Nitrogen Mineralization Rate: 0.30
12/31/07

Report Nui
R07261-800-i"
Account Number:
46646
To: BIO-GREEN SERVICES INC
383 POTTS RD
ADVANCE, NC 27006
LAB NUMBER: 44560
SAMPLE ID: SPRUCE PINE
A&L EASTERN I-Af RATORIES, INC.
7621 Whitepine Road • Richmond, Virginia 23237
[phone] • Fax No. [phone]
FOR: SPRUCE PINE WWTP
NC CERT #257
REPORT OF ANALYSIS
REPORT PRINTED 9/24/2007
copy: RAY GAMBILL
DATE SAMPLED: 8/19/2007- 1000
DATE RECEIVED: 9/18/2007 1000
DATE REPORTED: 9/21 /2007 PAGE: 1
Solids, Total (As is)
1.13
11300
100
JM
09/18/07
16:00
SM 2540G
Nitrogen, Total Kjeldahl
8.41
84100
10
JM
09/19/07
16:00
EPA 351.3
Phosphorus
2.56
25600
100
DH
09/19/07
16:00
SW 846-3051/601OB
Potassium
0.67
6700
100
DH
09/19/07
16:00
SW 846-3051/601OB
Sulfur
0.84
8400
100
DH
09/19/07
16:00
SW 846-3051/601OB
Calcium
6.39
63900
100
DH
09/19/07
16:00
SW 846-3051/6010B
Magnesium
0.41
4100
100
DH
09/19/07
16:00
SW 846-3051/6010B
Sodium
0.31
3100
100
DH
09/19/07
16:00
SW 846-3051/601OB
Iron
12400
1
DH
09/19/07
16:00
SW 846-3051/601OB
Aluminum
15900
10
DH
09/19/07
16:00
SW 846-3051/601OB
Manganese
180
1
DH
09/19/07
16:00
SW 846-3051/6010B
Copper
175
1
DH
09/19/07
15:00
SW 846-3051/6010B
Zinc
679
1
DH
09/19/07
16:00
SW 846-3051/601OB
Nitrogen, Ammonia (as N)
2.48
24800
10
JM
09/19/07
14:00
EPA 350.2
Nitrogen, Organic (N)
5.93
59300
100
DCH
CALCULATION
Nitrogen, NO3+NO2
< 1
1
DH
09/19/07
15:00
SM 4500-NO3F
Cadmium
< 5
5
DH
09/19/07
16:00
SW 846-3051/601OB
Chromium
41
5
DH
09/19/07
16:00
SW 846-3051/601OB
All values are on a dry weight basis except as noted. *Detection Limit on all N series is on a wet basis.
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or'in part, nor may any reference be made
aj-
to the work, the results, or the company in any advertising, news release, or otherpublic announcements without obtaining our prior written authorization.
PAUL C. H. CHU

Report Nui
R07261-8007
Account Number:
46646
To: BIO-GREEN SERVICES INC
383 POTTS RD
ADVANCE, NC 27006
LAB NUMBER: 44560
SAMPLE ID: SPRUCE PINE
I
- A&L EASTERN I-AbORATORIES, INC.
7621 Whitepine Road • Richmond, Virginia 23237
[phone] • Fax No. [phone]
FOR: SPRUCE PINE WWTP
NC CERT #257
REPORT OF ANALYSIS
REPORT PRINTED 9/24/2007
copy: RAY GAMBILL
DATE SAMPLED: 8/19/2007 1000
DATE RECEIVED: 9/18/2007 1000
DATE REPORTED: 9/21 /2007 PAGE: 2
Nickel
17
5
DH
09/19/07
16:00
SW 846-3051/601OB
Lead
16
5
DH
09/19/07
16:00
SW 846-3051/601OB
Arsenic
4.0
1.0
DH
09/19/07
15:00
SW 846-601OB
Mercury
4.4
0.4
KM
09/19/07
15:00
SW 846-7471A
Selenium
3.4
1.0
DH
09/19/07
15:00
SW 846-601 OB
pH (Std. Unit, As is)
6.95
0.01
RD
09/19/07
12:30
SW 846-9045C
Molybdenum
6
5
DH
09/19/07
16:00
SW 846-3051/601013
All values are on a dry weight basis except as noted. 'Detection Limit on all N series is on a wet basis.
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or in part, nor may any reference be made
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
PAUL C. H. CHU

" - •TeST
67. 'iference L ,'Raleigh, NC 27607
ph: [phone] fax: (919}834.6497
NCWW Cedk87. NCDW CerW37731
M
M
Chain of �.:ustod
y Tritest W.0.4 r-•
fV
Report Results To: Bill To:
Company: &10 — ,e'rvi;c t5
Address: 33_ ,��F3 /9,1 /JF £,)l
Attn: e'a) / 5 e
Phone: Fax. - 37 6 I Q'k -7zGsr
Sampled by (signature):
O
m
Project Reference: kC, e All"el Vo
Project Number: V 7 m
Purchase Order
❑ Standard Report Delivery
❑ Rush Report Delivery (WI surcharge)
"Push projects are abject w My n9rovai by me bdcralury
Requested Due Date: Z —I
Receipt Conditions (Lab Use Only)
❑ 4±2"C ❑ Temp: % CP_. °C
Res. Chlorine ❑ Absent ❑ Present ❑ n/a
Acid preserv. <2? ❑ Yes ❑ No 8qn/a
Base preserv. >12? ❑ Yes ❑ No &/a

Feb 1.2 08 06:54p Tritest Clemmons 3367662314 p.1
TRITEST
CERTIFICATE OF ANALYSIS
February 12, 2008
CLIENT NAME
CLIENT NUMBER
SAMPLE NUMBER
COLLECTED DATE
RECEIVED DATE
DESCRIPTION
SAMPLE NUMBER UNITS RESULTS
278162-01
278162-02
278162-03
278162-04
278162-05
278162-06
278162-07
CERTIFICATION #
CERTIFIED BY:
BIO-GREEN SERVICES, INC.
800000
2111/08
2/11/08
SLUDGE
SPRUCE PINE
DATE UNITS
RESULTS DATE
FECAL % SOLIDS
#/GRAM
122850
2111/08
PERCENT
3.7
2111108
#/GRAM
372960
2/11108
PERCENT
3.9
2111/08
#!GRAM
101010
2111/08
PERCENT
3.6
2111/08
#/GRAM
50505
2111/08
PERCENT
3.6
2111108
#/GRAM
202020
2111/08
PERCENT
3.6
2111108
#/GRAM
328283
2/11/08
PERCENT
3.6
2111108
#/GRAM
< 26738
2111/08
PERCENT
3.4
2111/08
FECAL GEOMETRIC MEAN: 122522 CFU/GRAM
NC 103
NC 37733
MORGAN TOWE
TEL: [phone] FAX: [phone] WEB: www.tritestinc.com
6300 Ramada Drive, Suite C2, Clemmons. North Carolina 27012

Section Three
Toxicity Characteristics Leaching Procedure (TCLP) Analysis

UTE*"
. Conference Di- d:l}eigh,.NC 27607-
[phone] fax:[phone]
W Gert#67. NCDW Cen#37731
)ort Results To:
npany: 9,lei -Gre—wg
S�er'v-,C
ES
tress: 32; 3 ��� 1-; t-g
All
Auj/a rt- e. e- /V'C.
2
7 GAO �
I A ae 6-0 -1 b;
3ne: 336If0 y-%0 E 3
Fax: 3 31-
r'997U's-
-npled by (signature):
opts Descriptlliil
Cps:«
. 'Siart;Dafe
S•I)aFt 7itve: �E.
Y
�
Chain of'., stocly
Bill To:
Sa r•• �P Project R
eference:
Project plumber:
Purchase Order #:
Tritest
O Standard Report Delivery
❑ Rush Report Delivery (wi surchargs)
-. '•(lush p'Cleo. gre.ubiecl to Or'� approval by Ne laboratory
Requested Due Date:
nd Date- :. Matrix... Analyses -Requested
• Wyr.gw-sw. . ,
nd rnie �w, ser as
2-27�
2.-7-7
C,1-17 t
.-- . . .. .... t .. .
4elinquished by (signature) JFWie7c.
ceived by (signature)
9elinquish d by (signature) ceived by (signalure)
P.eInquished by (signature) r•d by (signature)
Ca
fV
.A
0
m
0
tU
rn
Ln
a
00)
N
Data Tame Receipt Conditions (Lab Use Oily)
oC
❑ a±2-c ❑ Temp:
Date Time.
Res. Chlorine ❑Absent ❑ PresPrl'L ❑ nl a �.
Acid presl:rv. <2? ❑Yes ❑ irlO U nla
Dare Time
Base preserv->12? ❑ Yes 0 r4to Q "I

TRITEST
www.tritestinc.com
January 24, 2008
CLIENT NAME
CLIENT NUMBER
SAMPLE NUMBER
COLLECTED DATE
RECEIVED DATE
DESCRIPTION
TEST
TCLP
CERTIFICATION #
CERTIFICATE OF ANALYSIS
UNITS
CERTIFIED BY: MORGAN TOWE
NC 103
NC 37733
BIO-GREEN SERVICES INC
800000
277487
277488
12/27/07
12/27/07
12/27/07
12/27/07
SPRUCE
GRANITE
PINE
FALLS
RESULTS
ATTACHED ATTACHED
DATE
6701 Conference Drive, Raleigh, NC 27607 6300 Ramada Dr., Suite C2, Clemmons, NC 27012 6624 Gordon Road, Unit G, Wilmington, NC 28411
Ph: [phone], Fax: [phone] Ph: [phone], Fax: [phone] Ph: [phone], Fax: [phone]

Jan 24 08 02:56p Tritest Clemmons
Jan.24. 2008 10:12AN Tritest i a x o
7RUTEST
6701 Conference Drive
Raleigh, NC 27607
Teleph". [phone]
Fax: [phone]
Laboratory Report
... Prepared for ---
MORGAN TOWE-LAB MGR.
TRITEST I CLEMMIONS
6= RAMADA DRIVE
C-2
CLPMMONS, NC 27012
3367662314 p.2
No. 9f i i r. t
Page 1 of 2
NCMrW C•rL c: 067
NCIM Cart. #I: 37731
Report Data:
1121120011
Date Received:
12127/2007
Work Order*:
071Z-01568
Cuel. Code:
C1L7646
Project No.: 01
CUS1, P.O.IR:
Project ID- 2774671TCLP
Date Sampled
To* Sampled Mallix
Sample Type Condition
No. Sample ID
1?12712007
0:00 Sludge
Composite 4+1.2 d C
e9
001 277467 5
Analyzed
Method
Results
Date
Time Qualifier
Test Performed
Mloials TCLP Package
EPA 1311
<0.050 mg/L
1/6/08
110105
9:56
9:56
r TCLP Arsenic
EPA 2002
EPA 2DO8
<1.0 M91L
1/8108
9:56
_TCLP Barium
T
.
EPA 200.8
40.050 mWL
Its=
9:56
TCLP Cadmium
EPA 200.8
mg1L
<0.060 mg1L
118108
9:56
TCLP Chromium
EPA 200.8
<0.050 mg1L
118100
9:56
aTCLP Lead
EPA 200.8
c0.010 mg/L
11S108
9:56
-aTCLP Selenium
EPA 200.6
40.050 mg/L
f1s108
9:56
—?TCLP Silw
_TCLP Mercury Analysis
EPA 245.1
4.2 ug1L
t/T/08
13:27
metals/SVDA TCLP Extractlen
EPA 1311
done
1110108
13.52
Metaie digest. of TCLP Ext.
EPA 200.5
done
1110108
13:62
TCLP Pesticides; Llquida
EPA 8081A
117108
11:00
gamma-BHC (l indane)
EPA 8081A
4.05 ug1L
117me
11:00
EPA 8081A
<0.2 ugfL
WIN
11:00
—Chlordane
Endrin
EPA 0031A
<0.06 ug1L
11108
11:00
�-•
.. Heptachlor
EPA B081A
<0.05 ug1L
117me
11:00
Heptachlor Epoxide
EPA 8081A
m.9 ug/L
117108
11:00
—Methoxychlor
EPA 3051A
4.5 ug/L
1R108
11:00
—*'Toxaphene
EPA 8081A
4.4 ug1L
117103
11:00
TCLP volatlRs by 82608
EPA 8200E
114108
14:05
—Benzene
EPA 82608
<5 ug1L
114108
W05
, Carbon talrachlontle
EPA 0260E
<5 ug1L
114f08
14:05
.-Chlorabenzene
EPA 8260E
<5 uglL
1MIOB
14:05
—Chloroform
EPA 82508
<S uglL
11410E
14:05
<-+1,2-Dlchloromhane
EPA 82608
<5 ug1L
114i08
14:05
A,1-Dichloroedmw
EPA 8280B
<5 ug1L
114MS
14:05
Methyl ethyl ketane (MEK)
EPA 82608
<50 u91L
114108
14:05
—TmtrachloroetMne
EPA 62608
<5 ug1L
Ila$
14:05
' Trlchtofoelhene
EPA 8260B
<5 ug1L
114109
14:05
®°Vinyl chloride
EPA 32508
<10 UOPL
114108
14:05
TCLP 8270
EPA 8270C
1/8W
14:00
1,4-Dichlorobenzans
EPA 8270C
<0.050 mg1L
118106
14:00
EPA B270C
0.040 mg1L
1/8108
14:00
__1,4-Dlnitrotoluene
"Hexachlorobenze»o
EPA B270C
<0.050 mgn.
118108
14:00
__wxachlorobutadlene
EPA 6270C
4.050 m91L
Ile=
14:00

Jan 24 09 02:56p Tritest Clemmons 3367662314 P.3
Jan,24. 2008 10:12AM Irilest Tax o "V. ""'
9 °R "TEST
Page 2 of 2
6T01 COnferenCe Drive
Raleigh, NC 27601 NCAVW Cart. *: 067
Telephone: [phone]
NCIDW Cere. It- 37731
Fax: (919) 83" 497
Laboratory Report
Work Order t 0712-0150
Date. Sampled Time Sampled Matrix
Semple Type Condition
Composite 4 +!- 2 deg C
No. Sample ID
12r2712007 0:00
Sludge
001 277487
Analysed
Results
Date Time Qualifier
Test Performed
Method
<0.050 rrdL
116106 14:00
�HexachloraMhane
EPA 82TOC PA WOW8270C
E
c0.050 mg11.
1 fa108 14:00
14:00
2-Methylphanal
EPAa270C
40.100mgfL
1B10B
3• a 4-MethylphOnol
EPA e27oc
<o.oSO moll.
Ite10tt 14:00
,.-Nitrobenzene
EPA a270C
4.250 mWL
118/0s 14:00
14:00
ro
Pentachloph"61
EPA a270C
<O.050 rrjWL
1l8los
Pyridine
EPA 270C
c0.O6o mg1L
1/BIOS 14:00
2,4.5-Trlehlorophenol
EPA 8270C
$0.0mglL
50
1iBI09 14:00
,.2,4,r,.Trichiorophenol
EPA®151
1/1410s 15:45
TCLP Herbicides by 0"1
EPA 81 SO
<5.0s mg L
1114108 15:45
-r2.4-D
15
EPA 8150
t0.5r11 molt.
1114109 16:45
r.2,4,5.TP (Sotvex)
EPA 0
>140a1 deg-F
1114/013 15:46
r.tmhpoint (Setsllesh)
EPA 45D0CaE
<0.50 mpg
1111103 15.45
Readies Cyanide
3Wa4�30A
<2S.0s mglkg
1171108 15:45
Reactive Sulfide
SWO46-i110
7.11I1 ea016.5C
1111108 iSA5
corroeivity to Steel
EPA 3510
DONE
J 2127107 8:00
Extraction, ON, TCLP
EPA 1311
done
IMaffl8 13:52
Extr.. ZHE, TCLP Volatile$
EPA 3510
done
113M 14:00
Extraction, 8270 TCLP
£PA 814i0
DONE
1212TI07 6:00
Extr., Herbleide4, TCLP
SWMG 1311
done
1110108 13,52
Initlai TCLP Prep (non vat)
#Analyzed by Summit Environmental Technologies,lrtc., Akron, Ohio
Reviewed by.
for Tritest, Inc.

rnn au. JJU LOJ 44tSy
MSUMMIT
ENVIRONMENTAL TECHNOLOGIES, INC.
Analytical 4aboratorles
January 15, 2008
Client: Tritest,1=c
Address: .6701 Conference Dr.
Raleigh, N.C. 27607
Date Collected:
12/27,/2008
Date Reccived: '
1/8/2008
Projact #:
N/A
Client ID #:
0712-01568-001
]Laboratory ID #:
0800259-01
Matrix:
Sludge
Extraction Method. 1311
Date of Analysis. 1/14/2008
TCLLP Herbicides
Parameter
2,4,5-1P(Silvex)
2,4,D
Reportin,�,Limit
Rest is
0.50
<0.5
5.0
<5.0
F. 006/014
4
Reeulatory Level
LmS-11
1.0
10.0
`Analytical Integrity" - A21-A Accreditation #0724.01 - NELAP Certified
595 East Tallmadge Avenue • Akron, Ohio 44310 . Phone: [phone] • Fax: [phone]
Web Site: www.seitek.com
Received Time —Jan, 15.-

LUDO/ JKLI/ IJ/ LUr. UJ:JL rM aUi4ulll NIVIEUNMENT FAX No. 330
253 4489 P. 008/014
SUMMIT.
ENVIRONMENTAL TECHNOLOGIES, INC.
Analytical Laboratories .
6
January 15, 2008
Client: Tritest, Iztc
Address: 6701 Conference Dr.
Raleigh, N.C. 27607
Date Collected: 12/27/2008
Date Received 1/8/2008
Project #: N/A
Client M #: - 0712-01568-001
Laboratory 1p•#: 0800258-01
Matrix: Sludge
Analyst: CRB
parameter Meth is
'Date of Axalvsis '
Flash Point 1010 >140F
1/14/2008
pH ' 9040 7.11 su@16.5C
1/11/2008
Analytical Integrity" - A2LA Accreditation *0724.01 NELAP Certified
\` 595 East Tailmadge Avenue • Akron, Ohio 44310 . Phone: [phone] Fax: [phone]
- 1 Web Site: www.settek.com
Received Time —Jan. 15.— 2:30P ....... - —

..,...,1 rnA iv u. JJu Z�J 44H P. 007/014
flflsumMiT
ENVIRONMENTAL TECHNOLOGIES, .INC.
Analytical Laboratories

Section Four
Field Application Summary and Field Loading Rate Report

ANNUAL LAND APPLICATION I` ' F .D SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD.,
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name:
TOWN OF SPRUCE PINE Permit #: WQ0002349
Owner: K.T. FELDSPAR CORP.
Site #: SP I Field #:
Operator: PENLAND-BAILEY CO.
01A Acres Utilized: 7.2
Annual Dry'Tons Applied: 3.85
Cation Exchange Capacity (non 503):
Acres Permitted: 7.2
�
S
0 g
�
A
S eci
Totals
Per
Acre.
%
Solids
Dry Tons Per
Acre
Residual Sources
(Summarize)
Site
Cond.
D �''
Wet,
Moist
Inches
Precip.
Past 24
Hrs.
Appli-
cation
Meth-
od*
Voli-
tila-
zation
Rate**
Miner-
ali-
zation
Rate
TKN
Ammo-
nia-
Ni-
trogen
Ni-trate
and
Nitrite
PAN 1
PAN 2
Must Select
Crop 1 or Crop
p p
2
Gal.
Cu.Yd.
Report
Totals
in Gal.
Crop 1
Crop 2
7/13
81600
11,333
1.13
0.53
WWTP
DRY
0
S
0.5
30.00%
84100
24800
0
32.25
Err:502
fescue
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
111,333
0
0
0
TOTALS:
As
Cd
Cr
Cu
Pb
Hg
Mo
Ni
Se
Zn
P
PAN 1
PAN 2
ime A
lied
uallbs/acre
0
0
0.04
0.19
0.02
0
0.01
0.02
0
0.72
27.14
32.25
0
Date
ibs/ac
rent Cumulative lbs/ac
fre
0.12
0.08
0.04
90.8
68.07
0.39
0.35
3.36
0.23
99.07
r Years Cumulative Ibs/ac
0.12
0.08
0
90.61
68.05
0.38
0.34
3.34
0.22
98.35
mitted C. P. L. R.***
36
34
1338
267
15
na
374
89
2498
Permit PAN Limit 1 st/2nd Crop
250
50
I cernfy, under penalty of law, tnat this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant enalties for submitting false information, including the po sibility of fines and imprisonment for knowing violations."
l d *Application Method: S - Surface, IN - Injection, INC - Incorporation
Signature of tand Applier Date **Volitilization Rate: Surface - 0.5, Injection/Incorporation -1.0
***C.P.L.R: Cumulative Pollutant Loading Rate
**** The RSSF Data and the Dry Tons Per Acre are to be entered on the MFLSF Form. The FSF and MFLSF are mathematically linked so this information needs to be entered intc

ANNUAL Ml:'1'AL.h' FIELD LUADING SUMMARY FUKMV
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: TOWN OF SPRUCE PINE Total Dry Tons Applied (Annual): 0.8
Permit #: WQ0002349 Cation Exchange Capacity (non 503 only):
I )perator: PENLAND-BAILEY CO. Owner: K.T.FIELDSPAR CORP.
Acres Used: 2 Acres Permitted: 7.8 Site #: SP Field #: 01B
Residual Analvsis Data (Heave Metals and Total Phosphorus use mWkg, % Solids use Raw Percent #):
Total
pho rus�WEEEEEEEEEE
►nnual Heave Metal Field Loadines (Calculated in lbs/acre):
1
2
3
4
5
6
7
8
9
10
11
12
o
a6'
9
[Arsenic
0.4
0
0
0
0
0
0
0
0
0
0
0
0
0
dmium
0
0
0
0
0
0
0
0
0
0
0
0
0
omi
0.03
0
0
0
0
0
0
0
0
0
0
0
0.03
Copper
0.14
0
0
0
0
0
0
0
0
0
0
0
0.14
Lead
0.01
0
0
0
0
0
0
1 0
0
0
1 0
0
0.01
Mercury
0
0
0
0
0
0
0
0
0
0
0
0
0
Molyb-
0
0
d
0
0
0
0
0
0
0
0
0
0
denum
Nickel
0.01
0
0
0
0
0
0
0
0
0
0
0
0.01
Selenium
0
0
0
0
0
0
0 1
0
0
0
0
0
0
Zinc 1
0.54
0
0
0
0
0
0
0
0
0
0
0
0.54
Total
Phos-
20.49
0
0
0
0
0
0
0
0
0
0
0
20.49
phorus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information,
icludi the pos ' ility of fines and imprisonment for knowing violations"
��.
SignattWof Land Applier Date
* See bottom of FSF Form for helpful instructions for this MFLSF Form and the mathematically linked FSF Form

ANNUAL LAND APPLICATION I ' ',D SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD.
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: TOWN OF SPRUCE PINE Permit #: WQ0002349 Annual Dry Tons Applied: 0.8
Owner: K.T. FELDSPAR CORP. Operator: PENLAND-BAILEY CO. Cation Exchange Capacity (non 503):
Site #: SP Field #: 01B Acres. Utilized: 2 Acres Permitted: 7.8
specifx
Site
Gal.
0 5
Totals
on
Inches
Appli-
Voli-
Miner-
Ammo-
Must Select
Cu.Yd.
o
Per
%
Dry Tons Per
Residual Sources
'
Precip.
cation
tila-
ali-
nia-
Ni-trate
Crop 1 or Crop
p P
Report
14
Acre
Solids
Acre
(Summarize)
Dry,
Past 24
Meth-
zation
zation
TKN
Ni-
and
PAN 1
PAN 2
2
'totals
in Gal.
Wet,
Moist
Hrs.
od*
Rate**
Rate
trogen
Nitrite
Crop 1
Crop 2
7/14
17000
8500
1.13
0.4
WWTP
DRY
0
S
0.5
30.00%
84100
24800
0
24.18
Err:502
fescue
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
OTALS:
8500
As
Cd
Cr
Cu
Pb
H
Mo
Ni
Se
Zn
P
PAN 1
PAN 2
Lime A lied
nnuallbs/acre
0
0
0.03
0.14
0.01
0
0
0.01
0
0.54
20.49
24.18
0
Date
lbs/ac
urrent Cumulative lbs/ac
0.12
0.08
0.03
90.75
68.06
0.39
0.35
3.36
0.23
98.9
rior Years Cumulative lbs/ac
0.12
0.08
0
90.61
68.05
0.38
0.34
3.34
0.22
98.35
ermined C. P. L. R.***
1 36 1
34
1338
267
15 1
na
374
89
2498
ermit PAN Limit 1 st/2nd Crop
250
1 50
A %.UX Uly, U11UV1 PCuteuy ui li, tua< this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and 'imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
S' ture of Land Applier Date **Volitilization Rate: Surface - 0.5, Injection/Incorporation -1.0
***C.P.L.R.: Cumulative Pollutant Loading Rate
* * * * The RSSF Data and the Dry Tons Per Acre are to be entered on the MFLSF Form. The FSF and MFLSF are mathematically linked so this information needs to be entered int(

ANN UAL NI H;'1•ALS FIELD LOADING SUM1V "Y JFO M'
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: TOWN OF SPRUCE PINE Total Dry Tons Applied (Annual): 3.85
Permit #: WQ0002349 Cation Exchange Capacity (non 503 only):
perator: K.T.FELDSPAR CORP. Owner: PENLAND-BAILEY CO.
Acres Used: 7.2 Acres Permitted: 7.2 Site #: SP Field #: 01A
sidual Analvsis Data Meaw Metals and Total Phos horus use , % Solids use Raw Percent #):
nnual eavv Metal Field Loa din s Calculated in lbs/acre :
1
2
3
4
5
6
7
8
9
10
11
12
[Arsenic
0.53
0
0
0
0
0
0
0
0
0
0
0
0
0
dmium
0
0
0
0
0
0
0
0
0
0
0
0
0
omi
0.04
0
0
0
0
0
0
0
0
0
0
0
0.04
Copper
0.19
0
0
0
0
0
0
0
0
0
0
0
1 0.19
Lead
0.02
0
0
0
0
0
0
0
0
0
0
0
0.02
Mercury
0
0
0
0
0
0
0
0
0
0
0
0
0
Molyb-
0.01
0
0
0
0
0
0
0
0
0
0
0
0.01
, denum
Nickel
0.02
0
0
0
0
0
0
0
0
0
0
0
0.02
Selenium
0
0
0
0
0
0
0
0
0
0
0
0
0
Zinc
0.73
0
0
0
0
0
0
0
0
0
0
0
0.73
Total
Phos-
27.34
0
0
0
0
0
0
0
0
0
0
0
27.34
phorus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information,
icluding the possibil!ij of fines and imprisonment for knowing violations"
Si ature and Applier Date
* See bottom of FSF Form for helpful instructions for this MFLSF Form and the mathematically linked FSF Form

`A Residuals Applic ._ ,bn Summary
Operating Period: From J ci %U J.; •-427
Thru —D 7
roject:_,_ Application State: A C /haI,rt:,hell
omments: 2 �� u,g e a v,, S'1 / 8
Complete Where Required:
Site conditions: ,a Moist Wet Frozen
Weather conditions: Partl Cloudy Cloudy Rain
Temperature (degrees F): z90 0-9 32-70 s32
Date
Time at
Field
Load (s)
Landowner
County/Site/Field
Facility
Residuals
Type
Quantity
Unit
(G/WT/CY/LBS
App.
Method
Zone
Allowed
App. Rate
Limit Factor
N/P/L/T
L.—
30,600
Z 50
l/
ui I
AlbcAell P
�IV iv�
IZ 4"49
G
f
.25-0
le" 460
f 13io Green is responsible for meeting the Vector Attraction Reduction (VAR) requirements through injection or incorporation, complete the items below when filing out the Daily Summary
keport Form (this is not applicable to Truck Reports):
1. List hours of land application operations Start End
2. VAR was met through (check one): ❑ Injection . or ❑ Incorporation within 6 hours after biosolids application. Manager's Signature:1=5w
White - Office
Yellow - Client

Transportation/Application Log
For Liquid Biosolids
Name:A a Project: S�r-Kce Date: Tu /V 15 62 f-rl
Vehicle No: 0 Quantity: 3 S'GC> Hub Meter -Start: Hub Meter -Stop:
Alkaline Stabilization: Yes ❑ . No L'1
Temperature: >90 70- 32-70 <32 Miles to Field
Site Conditions: qa:� Moist Wet
Rainfall: .'
<Y2" rainfall
>%:' rainfall
Load
No.
WWTP
Time
Out
Time At
Field
Gallons
Landowner
Site No.
Field
No.
Acres
Crop
APPI
Method
(S/SI/1)
1
102-
a
3y6a
S
)
S
2
)
// / C
3�4) &
s r
s P
114-
7, Z
/=
3
l 2
`/`
7 Yol>
AT a
S
A
?,2
rs
a
S7lZJ8'
3y6
T
SP
1A
7,2
S
5
z30
/ Z(-jr
3 o
Feld ue—
5P
/A -AI
6
O©
/
L 0
Id M
-5
'7. 2�
S
7
31-/4a
A e d
/
/A
2, 2
F
s
8
2CF�2j'-
y dA
I- )Cc lob
/
71 Z
f
s
9
JAy0
2-5-9
3906
A-t- Fe lefsoea,
7, Z
S
10
31 S
31
-7 06
T /6
11
23
J �
7 d r2
lol�4
Op
A7.,
S
12
/—e 141-
% r Z
13
'1 5'3
6d
d S' e,c
l�
7 Z
f-
1a
S`l
5'3 2
19 00
, !d S
Zf}
7, Z
F
5
15
5��
%
37d0
h /
1A
7,
16
17
18
19
20
Comments: .1-aI P/ (/Od *Application method: S=Surface; S/I=Surface with Incorporation; I=Injection
❑Certified Operator Aze
Inspected LK9na a License No. perator's Signature

1.2
Transportation/Application Log
For Liquid Biosolids
Name: J)2-af,./ Project: 'cYGzC�, �i6h
Vehicle No: © Quantity: 3 f¢ 0 (D Hub Meter -Start:
Alkaline Stabilization: Yes ❑ No
Temperature: >90 0-9 32-70
Site Conditions: Xlr-y-) Moist Wet
Date:ru / 4/ - 0:2
Hub Meter -Stop:
<32 Miles to Field
Rainfall: 0 <%11 rainfall >V2# rainfall
ffim
Time At
Landowner
mom
Appl
Method
mm
I -
mm
mmmm
MM
UA
M
mm
M
mm
mm
=MIMI
MMUS70
MIN
"Q
==affl
=====
MMMM,
, mo,
mmmmw
Comments: �� / f 301GOD *Application method: S=Surface; S/I=Surface with Incorporation; I=Injection
/.7,0©0
y 71 00
❑Certified Operator
Inspected L.%fgnatTre lcense No. ' Operator's Signature
,nn,:+- n4#*.,o / V.11na.,-- lion* / Din4—TriirV,-r

Section Five
Pathogen and Vector Attraction Reduction Monitoring
And Certification

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM
Facility Name: . Town of Spruce Pine Permit Number: WQ0002349
WWTP Name: Town of Spruce Pine WWTP NPI)ES Number: NC0021423
Monitoring Period: From l/l/2007 To 12/31/2007
Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed:
Class A:
Alternative 1 ❑
Alternative 2 ❑
Alternative 3 ❑
Alternative 4❑
Alternative 5 ❑
Alternative 6 ❑
...........
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
Alternative lj
Alternative 2 ❑
Alternative 3 ❑
............
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑ T
Air Drying ❑
Composting ❑
Aerobic Digestion ❑
Anaerobic D i i
g est on
.......................................................
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g tY
Number o
Excee-
Frequency
of Analysis
Sample
Type
Analytical
Tech-nique
Minimurr
Geo.'Mean
aximu
Units
Fecal Coliform
2 x 10 to the 6th
power MPN per
gram of total
solids or 2 x 10 to
the 6th power
CFU per gram of
50505
122522
372960
MPN/g
0
7
C
sm9221 E
1000 mpn per
gram of total solid
(dry weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4
grams total solid
(dry weight)
Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed:
Option 1 ❑ Option 2 ❑ Option 3 19 j0ption 4 ❑ Option 5 ❑
Option 6 ❑ Option 7 ❑ Option 8 ❑ Option 9 ❑ 10ption 10 ❑
No vector attraction reduction p
options were performe
d
❑
p
CERTIFICATION STATEMENT (please check the appropriate statement)
I" "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
❑ "I certify, under.penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an' explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the
system designed to ensure that qualified personnel properly gather and evaluate the information
used to determine that the pathogen and vector attraction reduction requirements have been met. I
am aware that there are significant penalties for false certification including fine and imprisonment."
Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print)
z/
Signature of Preparer Date Signa re of Land Applier (if applicable) Date
DENR FORM RF (5/2003)

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12/15/2006 11:44 7045888333
PAR LAB5 U-AAt< rvk,
m
BENCH TOP DERCENr ?TOTAL SOLIDS and
TOTAL VOLITILE SOLIDS
VpV KLE8K FORMULA
S S 3 Start: 10/26/09
74685 Bndt 11/30/06
TARE
1.7.327
ml5 smpl
18.5
DRIED WT •
L5 . D04
SVR.NED WT.
L7.622
TVs
0.382
TVS�20,648154a6
TAJlIi
16.351
mis smpl
19.3
DRIED WT.
17.041
BURNED WT.
16.65i
TV$
0.387
TV6 g/I+
20,05181.35
TA"
2.8.49a
mla nmpl
19.767
n?Txn WT
1q 177
BURNED wr.
18.798
TV$
0.379
TVG g/L
20.1050232
,Tx"
13.04 S
rnle envl
18.316
DRIED WT.
1-6 .442
BURNED wr.
16,112
IM79
n . 3 g
TVS g/L
18.0170343
TARE
17.678
mlg amp,
17.598
DRIED WT.
18.25
RUZTRD 10I - 113.932
TVs 0,317
TVS g/L 19.0134106
0
5.16216226 t Solids
0.677 t TVs-
o.�e�z5�os
0
5.01295337 4 Solids
0.69 b TV$-
0.56086957 4 VS LOS
n
5.04875579 f SOlidt
0.679 % TVS`
0.55017370 v VG L06
0 `
4.50425657 v Solids
0.597 t Mi.
0.55276382 4 VS L06
1600
o.s6425406
3.66
56.43
0.560©6957
0.9940018
3.58
56.09
0.60
0.55
0.99519357
3.62
55.82
0.48
0.55276382
0.99030174
3.26
$6.30
0.97
0 .5541958
1.00259059
0
1,50336366 $ Eolidb 3.40
0.572 % TVs- 55.43
0.5541958 t VS LOSS -0.26

12/15/2006 11: a4 704588833'q CHAIN OF CUSTODY
PAMWC.PAR Laboratories, Inc
Phone [phone]
Fax (704•) 588-9335
Shipping:
2217 Graham Park Drive
Charlotte, NC 28273
Mallinp:
PO Box 41148.3
Charlotte, NC 28241.1483
k is aswntipl that al lnfwmatlor recorded on this Chan of CVstody documom for aoceManc® by PAR LaboratDrieS. Inc. and tM North
Cuounn oepertment of Environmental and NatUral RaeaUreea.
Cuinvany Nwrle Wiling)
SOUTHERN SOIL BUILDERS
Address
068 HOOTS RD
City, State & Zip Code —
ROARING RIVER, NC 28689
Polm of Contew rG Telaphr.,,a
Samplo taken by:
COMMENTSISPICfAL
INS"UC71ONS
IS THIS FOR 37 or EPA REPORTING? YES NO
+$arnpte typelgW , WWLY
_ QWMW _ HHV _ Sol] , Other „
8atriple Temp at time of aarrrplinS; 3 eC Semple Temp upon rvicelpt: °C
Proaerved: Yee No , Teflon Liner/ Zero Heedspabe: Yea No _, N/A _
lyt`, �3a,oli!w,;llfl';-"
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DateMrns Received by:
E.
C •Compoeito 0=Orab DW=Drinking Water WW -Westewater GWMW -Groundwater Monitprin0 Wnd HW wHaurdoue Wme
$rn other Side
r

Section Six
Soil Analysis Reports

NCDA&CS Agrop-nic Division Phone:'(919)7534055. W t6k.W W--W 4 cagnc-W-- �
ii7
r
Groove. lo-Green Services, Inc
Copies To: Canipe, Rich.
383 Potts Rd
Advance, NC 27006
Soil Test -Report
Farm: Spruce Pine
8/1/2007 SERVING N.C. RESIDENTS FOR OVER 60 YEARS Mitchell County
Agronomist Comments
ATTENTION: This report was flagged with a "C" and/or "Z" to alert you that copper and/or zinc have accumulated in
C — 12
the soil and are approaching a level that could be detrimental to crop production. The C and Z symbols are printed
on your report for soil test index levels of 2000 or more; for peanuts with zinc, the level is 300. This note is
designed to be a "trigger" that allows enough time to either reduce the rate of application or find another field for
application of biosolids and/or waste water. The CTL (critical toxic level) for Cu & Zn has been set at 3000 index;
for peanuts with zinc, the level is 500. These levels are used by DENIZ as a benchmark to determine when
application of waste products should be stopped. The CTL for copper and zinc was set to prevent levels from
accumulating to the point where they become toxic to crops grown on a field.
David H. Hardy, Agronomist
Field Information
A ime ppjie&.L
Recommendatiogs,--.-
Sample No. last Crop
No Yr TIA
Crop or Year Lime N P205 K20
Mg S Cu Zn B Mn See Note
SPOIB
1st Crop: Fes/OG/Tim,M .6T 120-200 0 50-70
0 0 0 0 .0 0 12
2nd Crop: Fes/OG/rim,M 0 120-200 0 50-70
0 0 0 0 .0 0 12
Test Results
Soil Class HM% WIV CEC BS% Ac pH� P-I K-1 Ca% Mg% Mn-1 Mn-AI(1)Mn-AI(2) Zu-1
Zn-AI Cu-1 S-1 SS-1 NO3-N NH4-N Na
MIN 0.13 1.18 4.5 73.0 1.2 5.4 411 41 50.0 18.0 164 115 115 510
510 258 33 0.1
Field Information.
AppliedLune
Aoo
Sample No. Last Crop
Mo Yr TIA
Crop or Year Lime N P205 K20
Mg S Cu Zn B Mn See Note
SP01A
1st Crop: Fes/OG/Tim,M I-3T 120-200 0 0
0 0 0 Z .0 0 12
2nd Crop: Fes/OG/rimM 0 120-200 0 0
0 0 0 Z .0 0 12
Test Results
Soil Class HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% Mn-1 Mn-A1(1)Mn-A1(2) Zn-1
Zn-AI Cu-1 S-1 SS-1 NO3-N AWN Na
MIN 0.41 0.83 12.4 80.0 2.5 5.4 838 105 57.0 19.0 209 142 1.42 2718
2718 1491 53 0.1

Section Seven
Exchangeable Sodium Percentage and SAR

EXCHANGEABLE SODIUM PERCENTAGE
Field_ SPO1B_
NA CEC
(0.1 MEQ/100G / 4.5 MEQ/100G) x 100% = 0.2
Field SPO 1 A
NA CEC
(O.1MEQ/100G / 12.4 MEQ/100G) x 100% = 0.0
SODIUM ABSORPTION RATIO
Town of Spruce Pine WWTP .34

NCDA&CS Agronomic Division Phone: [phone] Web Site: www.neagr.com/agronomi/
Report No: 01750
Grower:
Bio-Green Services, Inc
Copies To: Canipe, Richard
383 Potts Rd
Soil Test Report
Advance, NC 27111
•
Farm: Spruce Pine
07/31/2007 SERVING N.C. RESIDENTS FOR OVER 60 YEARS
Mitchell County
Agronomist Comments
C -- 12
ATTENTION: This report was flagged with a "C" and/or "Z" to alert you that copper and/or zinc have accumulated in
the soil and are approaching a level that could be detrimental to crop production. The C and Z symbols are printed
on your report for soil test index levels of 2000 or more; for peanuts with zinc, the level is 300. This note is
designed to be a "trigger" that allows enough time to either reduce the rate of application or find another field for
application of biosolids and/or waste water. The CTL (critical toxic level) for Cu & Zn has been set at 3000 index;
for peanuts with zinc, the level is 500. These levels are used by DENR as a benchmark to determine when
application of waste products should be stopped. The CTL for copper and zinc was set to prevent levels from
accumulating to the point where they become toxic to crops grown on a field.
David H. Hardy, Agronomist
Field Information
Applied Lime
Recommendations
Sample No. Last Crop
Mo Yr T/A
Crop or Year Lime
N P205 K20
Mg S Cu Zn B Mn See Note
SPO1B
1st Crop: Fes/OG/Pim,M .6T
120-200 0 50-70
0 0 0 0 .0 0 12
2nd Crap: Fes/OG/I'im,M 0
120-200 0 50-70
0 0 0 0 .0 0 12
Test Results
Soil Class HM% W/V CEC BS06 Ac pH P-I K-I Ca% Mg•O6
Mn-I Mn-AI(1) Mn-AI(2) Zn-I
Zn-AI Cu-I S-I SS -I NO3-N NH4-N Na
MIN 0.13 1.18 4.5 73.0 1.2 5.4 411 41 50.0 18.0
164 115 115 510
510 258 33 0.
Field Information
Applied Lime
Recommendations
Sample No. Last Crop
Mo Yr T/A
Crop or Year Lime
N P205 K20
Mg S Cu Zn B Mn See Note
SPOIA
1st Crop: Fes/OG/fim,M 1.3T
120-200 0 0
0 0 0 Z .0 0 12
2nd Crop: Fes/OG/Pim,M 0
120-200 0 0
0 0 0 Z .0 0 12
Test Results
Soil Class HM% W/V CEC BS% Ac pH P-I K-I Ca% Mg•O
Mn-I Mn-AI(1) Mn-AI(2) Zn-I
Zn-AI Cu-I S-I SS-1 NO3-N NH4-N Na
MIN 0.41 0.83 12.4 80.0 2.5 5.4 838 105 57.0 19.0
209 142 142 2718
2718 1491 53 0.