WQ0005763_2006 Annual Report_20070226

fo):.
Annual Rersort R e v i c w S01> �.5� . 906 fp
1.. Annual'Land Application CertiflcationForm
• Was a certification form submitted? e
+ Was land application conducted during the reported yeai? E). js-_
• How many dry tons and 'dry tons per acre were applied? 73 y. 'VSS L-j,,E,4 ¢O'L'' 41- za05
• Were the applications within the permitted amount? parr+. i-�` l i�Vsb'r' �" 50 Dil�v.
• Verify PAN if more than 10 tons/acre
• Did it indicate compliance? yey,
• Was it signed by the appropriate people? yV�
2. Monitoring
• Were the analyses conducted at the required frequency? Tc`P—ye-SJ Aes%d"& ` er
• Were the metals analyses reported.on the Residual Sampling Summary Form? ye_1
+ Were the results reported in mg/kg? yam'
• : Were the heavy metals within ceiling concentration permit limits?* Ve5
• If no, were the lab analyses attached? ! f NoT ��uf�(
• Were all the required parameters tested? lam' M �SSir�ni �: Cd,�, /fie r , ,
• Was TCLP analysis -conducted? 5ee 2�$g.�zaoS /3/07
10 fp 1t19J'
3. Field Summary NA A/o 7-r_j J• s
PP lr�Sidua�S' ,.00f�2c c� O
• Were the land application. events recorded on the Field Summary Forms. P
• Was a Field Summary Form submitted for each field? a,,-4Ak i2ll(e /',er"'`��
• Were all the residuals applied to permitted land? .
• Were all the residuals applied from permitted sources?
• Were the field loading rates for each metal and PAN calculated (year to date)?
• Were the cumulative pollutant loading rates calculated?
• Were the calculations correct?
• Were the PAN loading rates -within permit limits?
• * Were the heavy metal cumulative pollutant loading rates within permit limits?
• . Were the residuals applied on a suitable crop?
• Were the applications conducted during the crop's growing season?
• Were the Field Summary Forms complete?
4. Pathogen and Vector Attraction Reduction
• Was a signed copy of the Pathogen and Vector Attraction Reduction Form submitted? ye-S
• Did the form indicate the perio�Pf coverage,'the residualass, and the pathogen reduction alternative and the
vector attraction reduction option used? p/ y,�� P SSuAS J11 2-ooS 44
• Was the appropriate documentation to show pathogen and vector attraction reducton included in the report?
• Was pathogen and vector attraction reduction demonstrated according to 40 CFR Part 503?
5. SoiI 'Pests N
• Was a Standard Soil Fertility Analysis conducted for each application field?
• Were the soil pH's 6.0 or greater for each application field?
• Were the copper and zinc indexes in the soil less than 3000 for each application field?
6. General
• Was the report in the proper format?1'e'$
• Were any parts of the annual report missing? No
• Was the, report submitted on time?*&3
* Any violations, of ceiling concentrations should be reported to Pretreatment for municipalities only.'

-- r-
Tuckaseigee Water & Sewer Authority
Serving Jackson County
1246 West Main Street
Sylva, NC 28779
Ph. [phone]'
Fax [phone]
February 22, 2007
DENR/DWQ/Water Quality Section
Non -Discharge Compliance Unit
1617 Mail Service Center
Raleigh NC 27699-1617
Attn: Non -Discharge Compliance Unit,
MAR 0 5 2007
FES 2 6 2007
Iwr
formation p 1, % .
rocess ng (Ai,
Enclosed is the Annual Residuals Report for theTuckaseigee Water and Sewer Lime
Stabilization facility (permit #WQ0005763) for the period of January 1, 2006 - December
31, 2006.
The facility did not produce any Class A residuals this year but did distribute residuals that
were produced during the 2005 calendar year. All of the analysis conducted during the
year were run on these "stored" residuals with the exception of the TCLP which was run
in the calendar year in which the residuals were produced.
Should you have any questions or if I can provide you any additional information, please
don't hesitate to contact me.
Sin rely,
Stan Bryson
Wastewater Plant Operations Superintendent
Tuckaseigee Water & Sewer Authority
Enc.

ANNUAL DISTRIBUTION AND:MARKETING% SURFAOE-DISPOSAL CERTIFICATION AND SUMMARY;FORM'
PERMIT #: Wo 0005763 FACILITY -NAME: TuckaSeic;ee. Water.. & Sewer Authority
PHONE: g 28 _ S R 6 _ 9 318 COUNTY: . Jackson OPERATOR: Start Bryson
FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A (Source(s) and "Residual'In" Volume.only) and Part C)
®. Distribution and Marketing (complete Parts A, B; and C)
Was the facility in: operation .during the past calendar year? " -[I Yes. No No.If No skip. parts A, B, C and certify form below.
Part A*:.: g*:
Part
Sources s include NPDES # if . Volume (dry tons) Recipient Information -
Mouth Amendment/
applicable). Residual In Product Out Name(s) Volume (dry tons) Intended use(s)
Bulking Agent
January
February o�
March
Aprilr r
May J o
June
July, a . See Attached Sheat
August ' ' Cx
¢ o
September
October .
November
December
Totals: Annual (dry tons): :.....:.:...:...
Amendment(s) used: -Bulking Agents used:
* If more space than given is required, please attach additional information sheet(s): ® Check boxif additional sheets) are attached
Part. C:
Facility was compliant during calendar year:' with Wconditions.of the.permit (including butnot limited to items 1-3 below) issued by the
Division. of Water. Quality. ® Yes ., .
0 No ' If No, please -pro written description why.the facility was not compliant:
1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies-ofcertified laboratory. results are attached.
2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water
Quality.
3.. No contravention of Ground Water Quality Standards occurred; at a monitoring well.
"I certify, under penalty of law, that the above information is; to the best of my knowledge and belief, true, accurate and complete. I am aware .
that t e are si ficant penalties for submitting faFiatidn,in cluding the possibility of fines: and imprisonment for knowing violations."
Signature of Permit e .Signature'of Preparer** D.ate
v -(if different from Permittee).**Preparer is defined'in 40 ,CFR'Part.503.9(r)
TI
DENR FORM DMSDF (11/2005)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM
Facility Name: Tuckaseiaee Water & Viewer Atthn.rily Permit Number: WO 0005763
WWTP Name: TWSA' Plant #1 NPDES Number: NC 0039578
To
Monitoring Period: From 1 / n 1./ 0 6 1.�31/06../
`77aAh;-tin„ ran VWR 503.321- Please indicate level achieved and alternative performed:
Class A: Alternative 1 ❑ Alternative 2. ❑ Alternative 3 ❑
Alternative 40 Alternative 5. ® Alternative 6 ❑
If .applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens".
Compost ❑ Heat Drying ❑ Heat Treatment [3Thermophilic [3
Beta Ray ❑ Gamma Ray [3 -. Pasteurization IM
Class. B: Alternative 1 ❑ Alternative. 2 ❑ Alternative 3 ❑ : `:: :
if. applicable to. alternative performed (Class B only) indicate "Process to. Significantly Reduce Pathogens
Lime .Stabilization � ❑ . rymg ❑ Composting ❑ Aerobic Digestion ❑
Air D .....
Anaerobic Digestion❑ .
.........
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Allowable Level f Pathogen Density er o Frequency Sample . Analytical
Excee-
Pararimeter � Sludge of Analysis Type Tech -pique
inim Geo. Mean axim Units deuces
2 x 10 to the 6th "
power MPN per
gram of total
solids or 2 x 10 .to
Fecal Coliform the 6th power
CFU-per grqujof
1000 mpn per
gram of total solid < 3.8 31 - 3 7 6 CFU / 0 1 / Grab . M
wei t
(may •gh) . gram month 9 2 210E
Salmonella bacteria 3 MPN per 4
(in lieu of fecal `.: grams total solid,
coliforrn)(dry weight)
Vector Attraction Reduction - -
Option 1 ❑ _Option 2 ❑` Option 3 ❑ Option 4 ❑ Option 5. ❑
Option 6 ❑: Option 7 ®.Option 8. ❑ Option 9 ❑ Option 10
No vector attraction reduction options were performed ❑, ' .. ;
CERTIFICATION STATEMENT (please check the appropriate statement)
❑ "I certify, under penalty of law, that the pathogen. requirements in 40 CFR 563.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
"I certify, under penalty of Jaw, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the
system designed to ensure that qualified.personnel properly gather and evaluate the information
used to determine that the pathogen and vector attraction reduction requirements have been met. I
am aware that there are significant, penalties for false certification including fine and imprisonment."
Stan Bryson, Superintendent
Prep5er Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print)

ANNUAL SEWAGE SLUDGE REPORT
OF
TUCKASEIGEE WATER AND SEWER AUTHORITY
PLANT # 1-NPDES # NCO039578 (WQ0005763)
for the period of January 1, 2006-December 31, 2006
as required by
40 CFR, PART 503
STANDARDS FOR THE USE OR DISPOSAL OF- SEWAGE .SLUDGE
0
4

TABLE OF CONTENT
(1). REPORTINGREQU]REMENT'S/PERTINENT.INFORMATION
(2) CERTIFICATION
APPENDIX
(a) 2006 sludge data
(b) 2006 distrubuion and marketing summary
(c) 2006 laboratory analysis .
(d) 2006 lime -Stabilization record of operation
d

REPORTING REQUIREMENT
Facilities responsible for reporting annually are described in the regulations as:
1. Publicly Owned Treatment Works (POTW) with an average design
influent flow rate equal to or greater than 1:0 MGD.
2. POTW's serving a population of 10,000 or more.
3. Class 1. (facilities with anapproved pretreatment program) -sludge management
facilities.
The Tuckaseigee Water and Sewer Authority Wastewater Treatment Plant is a 1.5 MGD
design facility. The facility also treats the sludge from two additional plants owned by the
authority.
Pertinent information includes:
facility name- Tuckaseigee Water & Sewer Authority Plant # 1
NPDES # NCO03 9578
corresyondence address, 1246 West Main.St
Sylva NC 28779
physical address* 1871 North River Rd
Sylva NC 28779
facility operatm Stan Bryson
Wastewater Plant Operations Superintendent
ph. 828-586-9318
{

I
CERTIFICATION REQUIREMENTS
ART I - POLLUTANT CONCENTRATI
Arsenic
1.6 mg/kg
Cadmium
0.73 mg/kg
Chromium
13.0 mg/kg
Copper
110 mg/kg
Lead
8.5 mg/kg
Mercury
0.69 mg/kg
Molybdenum
2.1 . mg/kg
Nickel
6.7 mg/kg
Selenium
3.5 mg/kg
Zinc
280 mg/kg
PART II - PATHOGEN RFD
TION (40 CFR 503 32�
X Class A
Class B
PART III - VECTOR. ATTRACTION (40 CFR 503,33)
— Option 1 _ Option 2 — Option 3 _ Option. 4
— Option 5 _X Option 6 _ Option 7 —Option 8

PART W - CER ATION
" I certify under penalty of law, that the -Class A pathogen requirements in 40 CFR, Part
503. 32 have been met and the vector attraction reduction requirement in 40 CFR, Part
[503. 33(b)(6)] has been met. I am aware that there are significant penalties for false
certification including fine and imprisonment."
Signed:this 25th day of January , 2007.
Stan Bryson, Wast6watgr Superintendent

0

i
APPENDIX A
2006 SLUDGE DATA
TWSA PLANT # 1 (1.5 mgd)
NPDES # NCO039578
SLUDGE TO DIGESTOR...........:.........:...........................................8,646;549 gallons
totallb s........ ..::....:....:.......:........................:............... 4312441b s
totaltons.........:................._..............,...........................215.6 tons
total metric tons............................:.....:.:...................195.6 metric tons
TWSA PLANT # 2 (.5 mgd)
NPDES # NCO020214
SLUDGE HAULED TO PLANT # 1.............................:......................... 204,020 gallons
total tons ..............................................
.............. :............. .21.80 tons
total metric tons ........... :................................. ..........:...19.77 -metric tons
TWSA PLANT #. 3 (1 mgd)
NPDES # NCO063321
SLUDGE HAULED TO PLANT#.1...:..:.....:.............................:............: 144,719
gallons
totaltons......................................................,........................:. 8.76 tons
total metric tons..........................................................7.95 metric tons
-
All'of the sludge that was generated at the Tuckaseigee Water and Sewer Authority
during 2006 was hauled by a private contractor to a designated landfill.
Landfill: R&B Landfill
610 Frank Bennett Road
Homer GA 30080
A total of 1080.3 wet tons were hauled to the landfill during 2006.
Copies of haul tickets -can be provided if needed.
i

f
x Y
PROCESS SUMMARY SHEET
PLANT NAME TWSA #1
ANNUAL (2006)
FOR THE PERIOD OF
1/1/06 THROUGH 12/31/06
A
PLANT FLOW, mgd
0.918 daily avg
B
INFLUENT BOD, mg/I
214.1 daily avg
C
EFFLUENT SS, mg/I
24.7 daily avg
D
MLSS, mg/I
3184 daily avg
E
RSSS, mg/I
5973 daily avg
F
WAS RATE, mgd
0.02369 daily avg
G
AER..BASIN VOL., mg
. 0.468
H
CLARIFIER VOL, mg
0.1508
I
F/M RATIO
LB APPLIED/LB UNDER AERATION
J
MCRT
.............
_ -=___
;;; DAYS
ACTIVATED SLUDGE DATA
30 IN
DATE
JAN.
SETT.
SLUDGE
341
MLSS
m /I
3319
MLVSS
m /I
2583
EFF _
FLOW
MGD
1.121
RSSS
m /I
6221
ZSV
ft/hr
5.0
SVI
103
MCRT
da s
14
LUDGE WASTING
r"lonsIbs
523,200
24,977
FEB.
458
3221
2698
1.036
6032
4.4
141
12
724,500
37,468
MAR.
565
3043
2610
0.901
5670
4.3
185
11
810,000
38,533
APR. 776.
3401
2721
1.023
6413
3.2
230
20
369,099
18:508
$
.688,500
37,475
JUL.
503
3088
2551
0.891
6242
4.9
155
11
742,500
39,580
AUG..
659
3250
2502
0.841
5637
4.5
202
11
839,700
42,350
SEP.
692 "
3050
2356
0.940
5787
3.5
226
11
754,050
35,682
OCT.
765
3178
2560
0.863
6198
3.2
240
12
765,000
40,017
NOV.
796
3033
2499
0.851
5819
3.2
263
13
634,500
30,706
DEC.
675
2881
2390 I
0.763
5451
3.9
231
10
927,000 1
3.364
AVG 632 3184 2569 0.918
MAX 796 1 3401 1 2727 1 1.121
MIN 341 2881 2355 0.763
11
5973 4.0 198 12 720546
1181
6413 5.0 263 20 927000
43364
5451 3.2 103 10 369099
18508
Total Gallons 8,646,549
431,2 —
Daily Average 23 689
215.6
Total tons X .907 metric ton/English ton=
195.6 Dry Metric Ton
lbs.
tons

a T '
2006.
' TWSA #2 SLUDGE PRODUCTION
MONTH
To
# 1
AVG
%SOLIDS
TOTAL
DRY TONJanua0
RGaled
0.00
Februa34,500
3.25
4.67
:March
0
0.0
0.00
A ril
0
0.0
0.00
MaV
24 000
2.6...
2.60
June
0
0:0
0.00
Jul
0
' . 0:0
0:00.
t ,.. August `
34,500
.3.0
4.31
Septemberp .:.
0
0.0
---------------
0:00
October
33 000
2.6
3.58 .
November
20 520-
2.3
-' 1.97
December
57 500
2.0
.4.67
TOTAL
204 020
TOTAL'
21.86 X .907 metric ton/English Ton
=19.77 Dry Metric Tons

2006
TWSA .#3
Sludge Production
Gals Hauled To AVG TOTAL
MONTH TWSA # 1 % SOLIDS DRY TON
Jan. 16 ' 7,245 1.30 0.39.
17 2415 3.9 0.39
27 1995 . 1.91 0.16
2811
1.97
1 .0.54
Mar. 31 . 7,6651 1.701 0.54
-Apr. 2817 665 1.90 0.61
May 191, 1.60 0.56
Jun.8
9 975
- --71.651
0.69
-d231
13,5981
1.27
0..72
Jul: 7'
12 390
. 1.53
, .0.79
19
..6,1951
1.57
1.. 0.41
Aug..
6.0901
1:70
0.43
14
5,040
. 0.90
0.19` .
24
9 '660
2051.
0.83
31
4 200
1:601
0:28
Se .:6
-4305 11.6
_ 0:29
7
4095
A.-Ol
0.17.
:14
5985
1.71
0.42
21
4095
1.3
0.22'
Oct.3
6090 .
.1.71
0:43
10 _
. 5990
1.3
0.32
- . 1 g .
. - -- 2105.
1..-9-
-------- -- - -0.17
25
4620
2
0.39
..Nov. 1.
2100: 1.5
0.13
2
2205 2.3
0.21
9
6280 1.9:
-
0.50
21
5975 1.4
0.35
TOTAL '168,1381 1 11.42
TOTAL 11:42 X .907 metric ton/English Ton
= 10.36 Dry Metri! Tons

Appendix B.
200f`
Distribution.and Marketing
Summary

VOLUME
IN DRY TONS
MONTH
ADMENDMENT/
RESIDUAL
PRODUCT
BULKING AGENT IN
IN
OUT
January
.0.
28.71
`28.71
February
0
- 25.1 &
25.18
March
0
26.14
.26.14
April
0
22.95
22.95
May
0
31.48
31.48
June
0
15.16
15.16
July
0
16.08
16:08
August.
0
16.04
16 04
Se tember
0
18.58
18.58 .
October
0
12:06
12.06
November
0
15.36
15.36
�D'ecember
0
27`:42.
27.42.
Annual Dry Tonsl
0.00
265.16
-266.16

Appendix B
TWSA PLANT # I
ANNUAL DISTRIBUTION AND MARKETING SUMMARY
2006
Part B
Recipient Information
Volume
Month Name Address (wet tons). Intended Use
January
Monthly Total
l 20
Bobby Collins
Franklin NC
20
Pasture
February;
Monthly Total
0
March
Monthly Total
l 377.5
Verlin Bryson
Andy* Caldwell
Wayne Hooper
Parris.h.Farm
Sorrells Spreading
- 25, Fruitful Place Cullowhee NC 28723
67 Teepee Ridge Maggie Valley NC 28751
Cullowhee NC 28723 -
3343 Bryson City Rd. "Franklin NC 28734
274 Davis Cove Rd. Waynesville NC 28786
3
56
0.5
108
.210
Pasture
Commercial Hauler
Garden
Pasture/Hayfields
commercial Hauler
April
:Monthly Total
l 243.
Andy Caldwell
Sorrells Spreading
67 Teepee Ridge Maggie Valley NC 28751
274 Davis,Cove Rd. Waynesville NC 28786
35
208
Commercial Hauler
Commercial Hauler.
May I
Monthly Total
0
June
Monthly Total l
. 19
Sorrells S-preading
274 Davis Cove Rd. Waynesville NC 28786.
19
Commercial *Hauler.
July.
Monthly Total
::36
Sorrells Spreading
274 Davis Cove Rd. Waynesville NC 28786
36
Commercial Hauler
August
Monthly Total
11.26
Doyle Cogdill
Owen Parton 910
Old. Settlement Sylva NC 28779
Davis -Branch. Rd. Bryson City NC 28713
1
10.25,
Pasture
Commercial Hauler,
September
'Monthly Total,
0
October
Monthly Total l
0
November
Monthly Total
28
Sorrells
Spreading
274 Davis Cove Rd. Waynesville .NC 28786
28
Commercial Hauler
December
Monthly Total
0
Yearly Total
. . . ..
734.75 Tons
......

% X
Appendix C
2006
Laboratory Analysis
Summary

2006
Annual Residual Sam
pling'Summary Form
Attach this form to the corresponding Annual Report.
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this for
Permit Number: WQ •0005763 Laboratory: Pace Analytical
Facility Name:Tuckaseigee Water and Sewer Auth Asheville NC
NPDES # NC-0039578
WQ # : WQ 0005763
WWTP-Name:TWSA Plant # 1
P
A
R
A
M '
E
T
E
R
S
mg/
kg
Sample
Date
Percent Solids
Aluminum
1/26
52.4
2/14
46
12,000
3/8 _"
52.3
4/26
53
5/9
52.5
12000
6/8
53.3
7/27E12,000
53.851.5
10/4
1400051.9
12/19
52.1
Arsenic
<12,500
0.95
1.6
1,2
<1.0 -,
0.7 -
Cadmium
Calcium -
<0.19
220,000
<0.21
310,000
0 54
340,000
0.73
330,000
.
0.3
300,000.
Chromium
13
11
10
Copper11.3
110
1.10
100
94
104
'Lead
Ma nesium
85
.
3,600
7.0
4,100
<0.83
4,300 .
<1.0
3,900 .
4.1
3,975
Mercu ry
0.12
0.68
0.69
0.68
0.5
I
Molybdenum
1.9
•2.1
<0:83
<1.0
1.0
Nickel
.6:7
6:3
�
,
5.3
11.0
5.7
11.7
6:'::::::::::::
::.::.:::.:...::::...:._,
h �
Potassium
11.9
2,100
.
11.3
2,500
2,400
1.9
490
2,800
3.5
540
2,450
1.7
�413.
Selenium
Sodium
2 2
<1
350.
Zinc
280
280
280
270
277.5
TKN "
9,200.
.
7,300
8,300
53
9,200
7,300`
8,500
1862
Ammonia -Nitrogen
37
58
Nitrate -Nitrite
Plant Available N
210
3,000
230
2,5002,
<37:2
290
800
81170 .
°38
350
4;600
2,160
<376
<38:4
270.0
3,225os
Total Ph
Phosphorous
790
498
38
Fecal Coliform
3:8
<55
<3.8
38
<38
1654.5 .
12
My, unuer penalty of.law, that this document was prepared under'my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. f am aware that there are
si nifica _
g penalties for submitting false information, including the possibility of fines `and imprisonment'for knowing violations."
F
Sign tuts of Preparer (TwsA version)
to DENR FORM RSSF (7/2002)

Analytical Results
r
Pace Analytical -Asheville For: 92112163
2225 Riverside Drive -
Asheville NC 28804
Entered 1/27/2006
Reported: 1/30/2006
Sample Remark
Sample ID , Parameter Cust ID Result Units Metho
d Date Analyzed Analyst
060127-2 %Solids 926581539 _ 52 4 %
060127-2 Fecal Coliform MTF SM2540B 1/27/06 CL
926581539 3.8 MPN/g SM92210E 1/27/06,
CL
Respectfully submitted,
Dena Myers
NC Cert *440,
NCDW Cert#37755,
EPA NC00909
P.O. Box 228 • Statesville, North Carolina 28687. 704/872/4697

Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
' 9800
Kincey Avenue, Suite 100
2225 Riverside Drive
W.
Huntersvil/e, NC 28078
Asheville, NC 28804
a
Phne: 704.875.9092
Phone: [phone]i76ceAnl
704.875.9091aFax
Fax.- 828.252-4618
-`j www.pacelabs.com
I
Lab.Project Numbers-92113360
Solid results are reported on
a dryweight basis
Client Project ID:
TWSA Lime
Residual.2/14
Lab Sample No:-926646449..:,
Project -Sample Number: 92113360-001., Date
Collected: 02/14/66 09:30
Client Sample ID: TWSA LIME RESIDUAL
Matrix: Soil
Date
Received: 02/14/06 13:36
Parameters`
Metals
Results Units
Report Limit•_ Analyzed By
CAS No.
ual RegLmt
Metals, Trace ICP
Prep/Method: EPA 3050 /
EPA 6010
Aluminum
120001, mg/kg
19.
02/15/06 14:40 ALV
. 7429-90.5
Arsenic
ND v mg/kg
0.95
02/15/06'14:40 ALV
7440-38-2
Cadmium:^°
ND v mg/kg.
0.19
02/15/06 14:40 ALV
.7440-43.9
Ca,,lcium
220000 mg/kg
19.
.02/15/06,14:40 ALV
7440-70.2
=Chromium.
13.- mg/kg.
0.38.
02/15/06 14:40 ALV
7440-47-3
Copper
110 v mg/kg
0.38
02/15/06 14:40-ALV
7440=50 8
Lead
8.5 v mg/kg
0.95
02/15/06 14:40 ALV
7439-92.1
Magnesium
3600 mg/kg
. 19.
02/15/06 14:40 ALV
7439-95.4
Molybdenum
1;g mg/kg
0.95
02/15/06 14:40 ALV'
74394-7
Nickel
6:7 ,,- mg/kg
0.95
021/15/06 14:40 ALV
7440-02-0.
-Potassium
2100 mg/kg
190
02/15/06.14c40 ALV
7440 09=7
Selenium
1.2 ✓ mg/kg
0'95
02/15/06 14.:40'ALV
7782-49-2
Sodium
270 mg/kg.
190
.,02/15/06 14:40 'ALV
-7440-23-5
Zinc
280 -- mg/kg'
1.9
02/15/06 14:40 ALV
7440-66-6
_ Date Digested
02/15/06 10:00
02/15/06 16:00
Mercury, CVAA9, in Soil
Method: EPA.7471
Mercury.
0.12`.mg/kg
0.093
02/15/06 10.-30 EWS~
7439-97-6
Wet Chemistry ,
Percent Moisture
Method: Y. Moisture
Percent Moisture
54.0
02/17/06 09.:42 KDF
Total Percent Solids
Method: EPA 160.3
Percent Solids
46.0
02/17/06' OF
Nitrogen, Ammonia
Method: EPA 350.1 Modified
_Nitrogen: Ammonia----.
: : 37: _:_ ._-.... mg/kg -
-- 20 ----'
- 02/22/06 12:00 BMF 7727:37 .9
Total Kjeldahl Nitrogen, Soil
Method: EPA 351.2
Nitrogen, Kjel.dahl., Total -
92001 mg/kg
1100
02/14/06 23:00 CD1 "
Nitrogen, Nitrate plus Nitrite
Method: EPA 353.2 Modified
Nitrate -Nitrite (as N)
210 mg/kg
.22.
02/15/06 22:16 CD1 7727 37 9
Phosphorus, Total: Soil Method: EPA 365.2
Date:.02/27/06
Asheville certification IN NC Wastewater 40 REPORT OF LABORATORY ANALYSIS
NC Drinking Water 37712 This report shall not be reproduced, except in full.
Page: 1 of 14
Charlotte Certification IN
NC Wastewater 12

Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
2225 Riverside Drive
Huntersville, NC 28078
Asheville, NC 28804
Phone: [phone]
Phone: [phone]
Fax: [phone]
Fax., 828.252.4618
Lab Project Number:
92113360
Client Project ID:
TWSA Lime Residual 2/14
Lab Sample No: 926646449
Project Sample
Number:
92113360-001 Date Collected: 02/14/06 09:30
Client Sample ID: TWSA LIME.RESIDUAL
Matrix:
Soil
Date Received: 02/14/06 13:36
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Phosphorus
790.
mg/kg.
718.
02/22/06
17:55
ARH
7723-14-0
PH.
Method: EPA
9045
PH
11.9
units
02/15/06
16:30
SHB
Plant.•Avalable Nitrogen
Method:
Nit
Nitrogen
3000
mg/kg
1.0
02/27/06
11:00
EWS
7727-37-9
Date: 02/27/06
Page: 2 of 14
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS Charlotte Certification IDs
NC Wastewater 40 .
NC Drinkina Water 3NC Wastewater127712* This report shall not be reproduced, except in full, NC

Analytical. Results
.Pace Analytical -Asheville. For:' 92113360.
2225 Riverside Drive_
.Asheville NC 28804
Entered 2/15/2006
Reported: 2/21/2006
Sample Remark
Sample ID Parameter Cust ID Result 'Units Method ' Date Analyzed Analyst
060215-10 % Solids TWSA Lime 36.1 % SM2540B 2/15/06 MD
060215-10 _ Fecal,Coliform MTF TWSA Lime, <55 MPN/g SM92210E 2/15/06 MD
Respectfully submitted,
Dena Myers
NC Cert #440;: '
NCDW Cert #37755;
EPA NC00909

Analytical Results
Pace Analytical -Asheville For: 92114802
2225 Riverside Drive
Asheville NC 28804
Entered 3/9/2006
Reported: 3/13/2006
Sample Remark
Sample ID Parameter Cust ID, Result Units Method ' Date Analyzed Analyst
06039-1 1 % Solids 926728353 52.3 % SM2540B 3/9/06 MD
06039-11 Fecal Coliform IVITF 926728353 <3,8 MPN/g SM92210E 3/9/06 MD
Respectfully submitted,
Dena Myers
NC Cert #440,
NCDW Cert #37755,
EPA NC00909
P.O. Box 228 • Statesville, North Carolina 28687. 704/872/4697

Analytical Results
Pace Analytical Asheville For: .92118043
2225 Riverside Drive
Asheville NC 28604
Entered 412712006
Reported: 519/2006
Sample Remark
Sample 0 Parameter Cust ID Result Units Method Date Analyzed Analyst
060427-11 % Solids TWSA Lhne 53 % SM2540B 4/27/06 MD
0e0427-11 Fecal ColOoffn NITF TWSA Urne 37.7' MPNIg SM92210E 4127/05 MD
Respectfully submitted,
Dl'r 4 Myers'
NC Cert #440,
NCDW Cert #37755,
EPA NCO0909
P.O.v.
Box 228 • Statesville, North Carolina 28687 704/872/4697

Pace Analytical Services, Inc.. Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 - 2225 Riverside Drive
Huntersville, NC 28078 Asheville, NC 28804
ace Analytical Phone: [phone] Phone:.[phone]
Fax:[phone] Fax.• 828.2524618
www. pacelabs. com
Lab Project Number: 92118951
Client Project ID: COMPOST/TCLP 5/9/06
Solid results are reported on a dry weight basis
Lab Sample No: 926960071- Project Sample Number: 92118951-001 Date Collected: 05/09/06 10:30
Client Sample, ID: TWSA LIME RESIDUAL Matrix: Soil Date Received: 05/09/06 15:30
Parameters
Results Units
ReDort Limit - Analyzed By
CAS No. Qual RegLmt
Metals
Metals, Trace ICP
Prep/Method: EPA.3050 / EPA 6010 .
Aluminum
12000 mg/kg
210
05/12/0.6 14:45 EWS
7429-.90.5
Arsenic
1.6 v mg/kg
1:0
05/12/06 14:45 EWS
7440 38 2
Cadmium,;.
ND mg/kg.
0.21
05/.12/06 14:45 EWS
7440-434
Calcium
310000 mg/kg
210
05/12/06 14:45 EWS
7440-70-2
Chromium_
11.�- mg/kg
0.42
05/12/06 14:45 EWS.
7440-47-3
Copper
110.1 mg/kg
:0.42
.05/12/06 14:45 EWS
7440-50-8
Lead
7.9 mg/kg.
1.0
'05/12/06 14:45 EWS
7439-92-1
Magnesium
4100 mg/kg
21.
05/12/06 '14:45 EWS
7439-95-4
Molybdenum
2.1 W7 mg/kg
1,0.
05/12/06 14:45 EWS
:7439 98 7
Nickel
6.3 -. mg(kg
1.0
05/12/06.14:46 EWS
7440702=0
Potassium
2500 mg/kg
210
05/12/06 14:45 EWS-
.7446-09-7
Selenium
ND " mg/kg
1.0
05/12/06 .14:45 EWS
7782-49=2
Sodium
350 mg/kg
210
.05/12/06 14:45 EWS'
7440-23-5
Zinc
280 mgAg
2.1
65/12/06.14:45 EWS
7440-66-6
Date Digested
05/.12/06 09:00
05/12/06 09:00
/ Mercury, CVAAS;.in Soil
Method: EPA 7471
Mercury
0.68 mg/kg
0.10
05/11/06 11:58 ALV,
7439-97.6
Wet Chemistry
Percent Moisture
Method: t Moisture
Percent Moisture
50.0 X
05711/06 11:36 OF
Total Percent Solids'Method:
EPA 160.3
.,Percent Solids
50.0 X
06/12/06 OF
Nitrogen, Ammonia
Method: EPA 350.1 Modified
.
Nitrogen. Ammonia
58. mg/kg
21
65/212/06.13:18_BMF.
7727,-_37-9 _....... ._,
Total Kjeldahl Nitrogen. Soil
Method: EPA 351.2
Nitrogen, Kjeldahl, Total
7300 mg/kg
400
05717/06 12:45 CD1
Nitrogen, Nitrate plus Nitrite
Method: EPA 353.2 Modified
Nitrate as N
230 mg/kg
19.
05/12/06 13:44 JDA1
Nitrate -Nitrite (as N)
230 mg/kg
19.
05/12/06 13:44 JDA1
7727-37-9
Date: 05/25/06
Page: 1 of 3
Asheville aication IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
t
NC Wastewwaterr40
NC Drinking Water 377.12
This report shall not be reproduced,
except in full,
NC Wastewater 12
C,n
%AA+hnn++h. ,.,��++.... .............
..,. -4 �_ �__I.
�� _1 - .. -- .
- NC Drinking Water s77nR

Pace. Analytical Services, Inca
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite.100
2225 Riverside Drive
Huntersville, NC 28078
Asheville, NC 28804
ace Analytical ®
Phone: [phone]
Phone: [phone]
Fax.,704.875.9091
Fax [phone]
www.pacelabs,com •.
%
Lab Project Number:
92118951
Client Project ID:
COMPOST/TCLP 5/9/06
Lab Sample No: 926960071
Project.Sample Number: 92118951-001 Date Collected: 05/09/06 10:30
Client Sample ID: TWSA LIME RESIDUAL°
Matrix: Soil
Date Received: 05/09/06 15:30
Parameters'Results. Units
Report Limit._ Analyzed By
CAS No. ual RegLmt
Phosphorus, Total, Soil Method: EPA 365.2
Phosphorus 498. mg/kg
100. 05/10/06 10:24 SAJ
7723-1470
PH- Method: EPA 9045
PH 11.3 units
05/16/06 12:55 TMR
Plant Available -,Nitrogen " -Method:
Nitrogen 2500 mg/kg
1:0 05%23/06 15:33 EWS
7727 37 9
Date: 05/25/06
Page: 2 of 3
Ashevilleacertification IN REPORTOF LABORATORY ANALYSIS
charlotte Certification IDs
NC Wastewater 40 .
NC Drinking Water, 37712 This report shall not be reproduced, except in full, .
NC Wastewater 12
,

Pace Analytical Asheville For: 92118951
2225 Riverside Drive
Asheville NC 28804
Entered 5/10/2006
Reported: 5/12/2006
Sample Remark
Sample ID - Parameter Cust ID Result Units- - Method - Date Analyzed Analyst
060510-7 % Solids 926960071 52.5. %SM2540B. 5/10/06 CL
060510-7 Fecal Coliform:'MTF 926960071 <38 MPN/g SM9221 CE 5/10/06 CL
Respectfully submitted,
Dena Myers
N.0 Cert #440, Z.
NCDW Cert #37755.

Analytical Results
Pace Analytical -Asheville For: 92120.908
2225 Riverside Drive
Asheville NC 28804
Entered 6/9/2006
Reported: 6/12/2006
Sample Remark
Sample ID Parameter Cust ID Result Units Method Date Analyzed Analyst
06069-'9 % Solids 927068387 53.3 %_ SM2540B 6/9/06 MD
06069-9 Fecal Coliform MTF 927068387 37.5 MPN/g SM92210E 6/9/06 MD
Respectfully submitted,
Dena Myers
NC Cert #440, .
NCDW Cert #37755,
EPA NC00909
.P.O. Box 228 • Statesville; North Carolina 28687. 704/872/4697

Analytical Results
Pace Analytical -Asheville For: Eff
2225 Riverside Drive
Asheville NC 28804
Entered 7/27/2006
Reported: 7/31/2006
Sample Remark
sample'ID Parameter Cust ID Result Units Method Date Analyzed Analyst
060728-3 % Solids 927244145 53.8 % SM2540B 7/28/06 MD
060728-3 Fecal Coliform MTF 927244145 <37.2 MPN/g SM92210E 7/28/06 MJp
Respectfully submitted,
Dena Myers
NC Cert #440,.
NCDW Cert #37755,
EPA NCO0909
J
chev
P.O. Box 228 • Statesville, North Carolina. 28687. 704/872/4667

Y>
Pace Analytical Services, Inc.
9600 Kincey Avenue, Suite i00
x Huntersville, NC 28078
ace Analytical , y Phone: [phone]
Fax. [phone]
www. pacelabs.
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
I Lab Project Number: 92124884
Client Project ID: TWSA LIME RESIDUAL
Solid results are reported on a dry werght basis
Lab Sample No: 927285189
Client Sample ID: TWSA LIME.
Metals
Metals, Trace
Aluminum
Arsenic
Cadmium.: t ``
Calcium;_
.:Chromium
',Copper
Lead
Magnesium
Molybdenum
Nickel
Potassium
Selenium
Sodium
Zinc
,Date Digested
iMercury, CVAAS, in Soil
Mercury
Wet Chemistry
Percent Moisture
Percent Moisture
Project Sample Number: 92124884-001 Date Collected: 08/08/06 09:45
-Matrix: Soil Date Received: 08/08/06 12:57
_ Results
Units
Report Limit Analyzed
By
CAS No. Qual RegLmt
Prep/Method:
EPA 3050 /
EPA 6010
12000
mg/kg
83.
09/10/06
15:00
JDA1
7429-96-5
1.2,'
mg/kg
0.83
09/10/06
15:00
JDA1
7440-38.2
0.54
mg/kg
0.17
09/10/06
15:00
JDA1
7440-43.9
340000
mg/kg
1700
09/10/06
15:00
JDA1
7440-70.2
10.-
mg/kg
0.83
09L10/06
15:00
JDA1
7440-47.3
100
mg/kg
0.83
09/10/06
15:00
JDA1
7440-50-8
ND.
mg/kg'
0.83
09/10/06
15:00-JUAl
7439-92.1
4300
mg/kg
83.
09/10/06
15:00
JDA1
7439.95.4
ND,-
mg/kg
0.83
09/10/06
15:00
JDA1
7439-98-7
5..3a-
mg/kg
0.83 .•
09/10/06
15:00
JDA1
7440-02-0
2400
mg/kg
830
09/10/06
15:00
JDA1
7440-09-7
1.9
mg/kg
1.7
09/10/06
15:00
JDA1
7782-49.2'
490
mg/kg
170
09/10/06
15.:00
JDA1
7440-23.5
280 ✓
mg/kg
1.7
09/10/06
15:00
JDA1
7440-66.6
09/10/06 09:30
09/10/06
09:30
Method: EPA 7471
.
0.69 w
mg/kg
0.096 .
08/10/06
10:44 ALV
7439-97.6
Method: X Moisture
48.2
Y.
08/17/06 17:59 TNM
Nitrogen, Ammonia Method: EPA 350.1 Modified
Nitrogen, Ammonia 53. mg/kg 20. 08/14/06 18:56 SAJ 7727-37-9
Total Kjeldahl Nitrogen, Soil Method: EPA 351.2.
Nitrogen, Kjeldahl, Total 8300 mg/kg 890 08/17/06 21:10 JMW
Nitrogen, Nitrate plus Nitrite Method: EPA 353.2 Modified
Nitrate as N 240 mg/kg 14. 08/16/06 14:17 EWS
Nitrate -Nitrite (as N) 290 mg/kg 14. 08/16/06 14:17 EWS 7727-37-9 -
Phosphorus, Total, Soil Method: EPA 365.2
Phosphorus 3170 mg/kg 1160 08/16/06 09:14 NIW 7723-14-0
e
Q � �1
Date: 09/11/06 !
' 1 4 2005 d
Page:
Asheville Certification IDs REPORT $
NC Wastewater 40 ORAT-ORY-ANALiSIS Charlotte Certification IDs
Wastewater 12
NC Drinking Water 37712 This report shall not be reproduced, except in full, NC NG . .

0
Analytical.
www.pacelabs.com
Pace Analytical Services, Inc. Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 2225 Riverside Drive
Huntersville, NC 28078 Asheville, iVC28804
Phone: [phone] Phone: [phone]
Fax: [phone] Fax., 828.252.4618
Lab Project Number: 92124884
Client Project ID: TWSA LIME RESIDUAL
Lab Sample No: 927285189
Project Sample Number: 92124884-001 Date Collected: 08/08/06 09:45
Client Sample ID: TWSA LIME RE
Matrix: Soil Date Received: 08/08/06 12:57
Parameters z Results Units Report Limit PH Analyzed By _CAS No. Qual RegLmt
Method: EPA 9045
PH
11.0 units
08/16/06 11:45 TMR
Plant Available ro en Method:
Nitrogen t 2800 mg/kg 1.0 08/21/06 16:00 EW a.
S
Date: 09111/06
Page: 2 of 3
Asheville Certification lDs charlotte Certification IDs
NC Wastewater 40 REPORT OF LABORATORY ANALYSIS
NC Drinking Water 37712 Thisreport shall not be reproduced, except in full, NC Wastewater 12

r •
Analytical Results
Pace Analytical Asheville For 92124884
2225 Riverside Drive
Asheville NC .28804
Entered 8/9/2006
Reported: 8/17/2006
Sample Remark
Sample ID. Parameter Cust ID Result Units Method Date Analyzed Analyst
06089-4 % Solids 927285189 51.9 % SM2540B 8/9/06 DM
06089-4 Fecal Coliform MTF 927285189 38 MPN/g SM92210E 8/9/06 DM
Respectfully; submitted,
Liens Myers
NC ert #440,
NCDW Cert #37755,
EPA NC00909

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 2225 Riverside Drive
Huntersville, NC 28078 Asheville, NC 28804
aceAnalytical Phone: [phone] Phone: [phone]
Fax: [phone] FaX [phone]
www. pacelabs. cam ,
( 1 Lab Project Number: 92129254
Client Project ID: LIME RESIDUAL 10/4
Solid results are reported on a •dry, bight basis
Lab Sample No: 927512848 Project Sample Number: 92129254401 Date Collected: 10/04/06 09:30
Client Sample ID: TWSA LIME -„RESIDUAL Matrix: Soil Date Received: 10/04/06 14:50
Parameters
Metals -
Results
Units
Report Limit _ Analyzed
By
CAS No. Dual RegLmt
Metals, Trace ICP._%;-
Prep/Method:
EPA 3050 /
EPA 6010
Aluminum
14000
mg/kg
20.
10/11/06
21:22
SHB
7429-90-5
Arsenic
ND v
mg/kg
1.0
10/11/06
21:22
SHB
7440-38-2
Cadmium,.':(°
0.73 v
mg/kg
0.20
10/11/06
21:22
SHB
7440.43-9
Calcium`'.
330000
mg/kg
400
10/11/06
21:22-SHB
7440-70-2
.;Chromium
11,
mg/kg
1.0
10/11/06
21:22
SHB
7440-47-3
-=--'Copper
94.v
mg/kg
1.0
10/11/06
21:22
SHB
7440 50 8
Lead
ND'�- -
mg/kg
1.0-
10/11/06
21:22
SHB
.7439-92-1
Magnesium
3900
mg/kg
.20.
10/11/06
21:22
SHB
7439-95-4
Molybdenum
ND
mg/kg
1.0
10/11/06
21:22
SHB,
7439-98-7
Nickel
'5.7 v .
mg/kg
1.0
10/11/06
21:22
SHB
7440-02-0
Potassium
2800
mg/kg
200
10/11/06
21:22
SHB
7440-09-7
Selenium
3.5
mg/kg
.2.0
10/11/06
21:22
SHB
7782.49-2
Sodium
540
mg/kg
200
10/11/06
21:22
SHB
7440-23-5
Zinc.
270'+-I .,mg/kg
2.0
10/11/06
21:22
SHB
7440-66-6
Date -Digested
10/11/06 13:40'
10/11/06
13:40
Mercury, CVAAS,.in Soil
Method: EPA 7471
Mercury
0.68 v .
mg/kg
0.096
10/09/06
15eo8
Al
7439-97_e
Wet Chemistry
Percent Moisture
Percent Moisture
Total Percent Solids
Percent Solids
Nitrogen, Ammonia
Nitrogen, Ammonia
Method: X Moisture.
48.5 %
Method: EPA 160.3
51.5 %
Method: EPA 350.1 Modified
7300 mg/kg - 1100
Total Kjeldahl Nitrogen, Soil Method: EPA 351.2
Nitrogen, Kjeldahl; Total 9200 mg/kg 400
Nitrogen, Nitrate plus Nitrite Method: EPA 353.2 Modified
Nitrate as N 350 mg/kg 14.
Nitrate -Nitrite (as N) 350 mg/kg 14.
Date: 10/17/06
10/09/06 13:11 KDF
10/10/06 TNM
10/06/06 09:58 TMR 7727-37-9
10.113/06 18:20 JMW
10/16/06 12:44 JDA1.
10/16/06 12:44 JDA1 7727-37-9
Page: l.of 3
Asheville Certification IDs
NC Wastewater 40
NC Drinking Water 37712
Rr oangn
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pare Analvtirnl .Ranfirae Inr
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706

Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
2225 Riverside Drive
Huntersville, NC 28078
Asheville, NC 28804
aceAnalytical
Phone: 704:875.9092
Phone: [phone]
Fax., 704.875.9091
Fax., 828.252.4618
www. pacelabs. com ,
j
Lab Project Number:
92129254
I
Client Project ID:
LIME RESIDUAL 10/4
Lab Sample No: 927512848
Project Sample Number: 92129254-001 Date Collected: 10/04/06 09:30
Client Sample ID: TWSA LIME RESIDUAL
Matrix: Soil
Date Received: 10/04/06 14:50
Parameters Results Units
Report Limit Analyzed By
CAS No. Qual RegLmt
Phosphorus,' Total, Soil :,' Method:
EPA 365.2
Phosphorus 2160
mg/kg
1210 10/13/06 07:03 JMW
7723-14-0
PH Method:
EPA 9045
PH 11.7 units
10/10/06 14:30 JDA1
P1an_—t,, able Nitrogen Method:
Nitrogen 4600
mg/kg
1.0 10/16/06 16:08 EWS
7727-37-9
.Date: 10/17/06
Page: 2 of 3
1
Asheville Certification IDs
NC Wastewater 40
NC Drinking Water 37712
REPORT OF LABORATORY ANALYSIS Charlotte Certification IDs
This report shall not be reproduced, except in full, NC Wastewater 12
withnnt tha wriffan rnncanf of Para Ann1%Ainn1 0an4— i— NC Drinking Water 37706

f � �
Analytical Results
Pace Analytical -Asheville For: 921292514
2225 Riverside Drive
Asheville NC 28804
Entered 10/5/2006
Reported: 10/10/2006
Sample Remark
Sample ID Parameter Cust ID Result Units -.Method Date Analyzed Analyst
06105-9 % Solids. .927430124 53.2 % SM2540B 10/5/06 CL
06105-9 Fecal Coliform MTF 927430124 <376 MPN/g SM92210E 10/5/06 CL
Respectfully submitted,
Dena Myers
NC Cert #440,
NCDW Cert #37.755,
EPA NCO0909

Pace Analytical -Asheville
For: 921.34455
-
,2225 Riverside Drive
Asheville NC 28804
Entered 12/20/2006
Reported: 12/22/2006
Sample Remark
Sample ID Parameter Cust ID
Result Units Method Date Analyzed. Analyst
061220-8 % Solids 927813378,
52A % SM2540B _ 12/20/06 MD_
061220-8 . Fecal Coliform MTF 927813378 .
<38.4 MPN/g. SM9221 CE 12/20/06 MD
Respecffully submitted,
uena Myers
NC Cert #440;
NCDW Cert #37755,
EPA -NCO0909
P.O. Box 228 • Statesville, North Carolina 28687.704/872/4697

race Analytical Services, inc.
9800 Kincey Avenue, Suite 100
Huntersville, .NC 28078
Phone: [phone]
Fax:[phone]
January 10, 2006 .
f<";
Mr. Stan Bryson;''
Tuckaseigeek�-Water & Sewer Auth
1246 West=Main Street
"M..a
Sylva`s'NC 28779
Pace Analytical Services, inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax.• 828.252.4618
,00
RE: Lab Project Number: 92109812
'Client Project ID: TCLP
Dear Mr. Bryson:
Enclosed.are the analytical results for sample(s) received by the laboratory on December 20, 2065. Results
reported herein conform to the most current NELAC standards,' where applic
body of the report. able, unless otherwise narrated in the
Inorganic Wet Chemistry and Metals Analyses were performed at our. Pace Asheville laboratory and Organic'testing-
} was performed at our Pace.Charlotte laboratory unless otherwise,footnoted.
If you have any questions concerning this report please feel free to contact me.; .
Since
m Williams
[e-mail] .
Project Manager
Enclosures
l '
Asheville Certification IDs
NC Wastewater 40
NC Drinking Water 37712
Sc 99030
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
�� \N ACC,,4 .
Charlotte Certification IDs
NC .Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627

lFr '
ace Analytical °
www.pacelabs.com
I "
Solid results are reported on a dry weight basis
Lab Sample No: 926463092 .
Client Sample ID: TWSA #1 BIORESIDUAI
Metals
Trace ICP Meta
Date Digested
. arc mnalyncdl services, Inc.
9800KinceyAvenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax.' 704.875.9091
Lab Project Number: 92109812
Client Project ID: TCLP
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax.- 828.252.4618
Project Sample Number: 92109812-001. Date Collected: 12/20/05 00:00
Matrix: Soil Date Received: 12/20/05 12:02
Results Units Report Limit Analyzed By CAS No.
�_ ual RegLmt
Leach. Method: EPA 6010
12/21/05 13:45
12/21/05 13:45
Trace ICPaMetals. TCLP Leach.
Prep/Method: EPA 3010
/ EPA 6010
Arsem cy
..P
Barium
0.027
mg/l
0.625 12/23/05 15:16 ALV 7440-38 2
Cadmium
0.28
NO
mg/1
0.025 12/23/05 15:16 ALV 7440-39.3
Chromium
ND
mg/1
0.0050 12/23/05 15:16 ALV 7440-43-9
Lead
mg/l
0.010
12/23/05 15:16 ALV
7440-47-3
Selenium
0.041
mg/l
0.025
12/23/05 15:16 ALV
7439-92.1
Silver
0.027
mg/l
0.025
12/23/05 15:16 ALV
7782-49-2
Date Digested
NO
12/22/05 09:00
mg/l
0.010
12/23/05 15:16 ALV 7440-22-4
12/22/05 09:00
Mercury, CVAAS, TCLP Leachate
Method: EPA
7470
Mercury
0.00035
m /1
9
0.00020 12/22/05 13:03 ALV 7439-97-6
-")GUMS Semivolatiles
Semivolatile Organics; TCLP
Prep/Method:
EPA 3510 /
EPA 8270.
1,4-Dichlorobenzene
ND
mg/1
2,4 Dinitrotoluene
NO
0.75
01/05/06 15:52 BET
106 46-7
Hexachloro-1,3-butadiene
NO
mg/l
0.013
01/05/06 15:52 BET
121-14-2
Hexachlorobenzene
ND
mg/l
0.050
01/05/06 15:52 BET
87-68-3
Hexachloroethane
ND
mg/l
0.013
01/05/06 15:52 BET
118-74-1
2-Methylphenol (o=Cresol)
NO
-mg/l
0.30
01/05/06 15:52 BET
67-72-1
3&4. Methylphenol
0.60
mg/1'
0.050
01/05/06 15:52 BET
95 48 7
Nitrobenzene
mg/l
0.010
01/05/06 15:52 BET
Pentachloroplienol
NO
NO
mg/l
0.20 —
01/05/06 15:52 BET
98-95-3
Pyridine
NO
mg/l
10.
01/05/06 15:52 BET
87-86-5
2,4,5-Trichlorophenol
NO
mg/l
0.50
01/05/06 15:52 BET
110 86 1
NO
mg/1
40.
O1/05/06 15:52 BET
.110-86-
95-95-4
NitrobTrichlorophe)
Nitrobenzene-d5 ((S
72
mg/1
0.20
01/05/06 15:52 BET
88-06-2
2 Fluorobiphenyl (S)
63
Z
01/05/06 15:52 BET
4165-60-0
Terphenyl-d14 (S)
80
Y
01/05/06 15:52 BET
321-60-8.
Phenol-d5 (S)
33
01/05/06 15:52 BET
1718-51-0
2-FluorophS)
(S)
48
i
01/05/06 15:52 BET
4165-62-2
2,4,6-Tribromophenol (S)
71
Z
01/05/06 15:52 BET
367-12-4
Date Extracted 01/04/06
i
01/05/06 15:52 BET
118 79 6
01/04/06
Date: 01/10/06
Asheville Certification IDs
NC Wastewater 40
NC Drinking Water 37712
Sc 99030
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,N ACC,.,
1
Page: 1 of 12
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627

Lab Sample No: 926463092
Client Sample ID: TWSA #1 BIORESTnI'lAI
GC Semivblatiles
Pesticides, TCLP Lei
gamma-BHC (Lindane)
Chlordane
Endrin
or
Tetrach.loro-m-xylene (S)
Decachlorobiphenyl (S)
Date Extracted
GUMS Vol ati l es
Volatile Organics, TCLP Leach.
Benzene
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroform
1,4-Dichlorobenzene
1,2-Dichloroethane
1,1-Dichloroethene
Tetrachloroethene
Trichloroethene
Vinyl chloride
Toluene-d8 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S).
1,2-Dichloroethane-d4 (S)
Date: 01/10/06
Asheville Certification IDs
NC Wastewater 40
NC Drinking Water 37712
Sc 99030
FL NELAP E87648
•,••••,••tea, OVIVIces, /nC.
9800 Kincey Avenue, suite 100
Huntersville, NC 28078
Phone: [phone]
Fax- 704.875.9091
Lab Project Number: 92109812
Client Project ID: TCLP
Pace Analytical. Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax.• 828.252.4618
rruiect bample Number: 92109812.001 Date Collected: 12/20/05 00:00
Matrix: Soil Date Received: 12/20/05 12:02
Results
Una Reoorit Analyzed By CAS ual RegLmt
Prep/Method: EPA 3510 / EPA 8081
NO mg/l 0.040 01/06/06 17:41,JEM 58 89 9
NO mg/1
0.0030 01/06/06 17:41 JEM 57.74-9
Nmg/l 0.0020 01/06/06 17:41 JEM 72-20-8
NDO mg/l 0.00080 01/06/06 17:41 JEM -76-44.8
ND mg/1
1.0 01/06/06 17:41 JEM 72-43.5
52 mg/1 0.050 01/06/06 17:41 JEM 8001-35-2
52 i 01/06/06 17:41 JEM 877-09-8
46 % 01/05/06 01/06/06 17:41 JEM 2051-24-3
01/05/06
Method: EPA 8260
ND
mg/l
0.62
mg/1
ND
mg/l
NO
mg/l
NO
mg/l
0.12
mg/l
ND
mg/l
NO
mg/1.
0.00.83
mg/1'
NO
mg/1
NO
mg/l
87.
.71
45
88
y,
0.-0050 01/03/0'6 14:05 DLK 71-43-2
0.10 01/03/06 14:05 DLK 78-93-3
0.0050 01/03/06 14:05 DLK 56-23-5
0.0050 01/03/06 14:05 DLK 108-90-7
0.0050 01/03/06 14:05 DLK .67-66-3
0.0050 01/03/06' 14:05 DLK 106-46-7
0.0050 01/03/06 14:05 DLK '107-0672
0.0050 .01/03/06 14:05 DLK 75-35-4
0.0050 01/03/06 14:05 DLK 127.-18-4
0.0050 01/03/06 14:05 DLK 79-01-6
0.0050' 01/03/06 14:05 DLK 75-01-4
01/03/06 14:05 DLK 2037-26-5
01/03/06 14:05 DLK 460-00-4
01/03/06 14:05 DLK 1868-53-7
01/03/06 14:05 DLK 17060-07-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
1
2
2
3
3
Page: 2 of 12
Charlotte Certification IDs
NC Wastewater ' 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627

•••"•,••�Q7UJVJce5, Inc. Pace Analytical Services, Inc.
r ti ` s 9800 Kincey Avenue, Suite 100 H2225 Riverside Drive
® untersvil/e, NC 28078
I' Phone: Asheville, NC 2880
�C, a AI /ntal ical ne. 704.875.9092 4
/�
.! Phone: [phone]
I www. pacelabs. com _ ': Fax [phone] fax.- 828.252-4618
I Lab Project Number: 92109812
Client Project ID: TCLP
PARAMETER FOOTNOTES
Method 90716 ,modified to use ASE.
All pH, Free Chlorine; Total Chlorine and Ferrous Iron analyses cond
hold timucted outside of EPA recommended -immediate
e
i
Depending on the moisture content the PRLs can be elevated for all soil samples reported on a dry weight basis.
"2-Chloroethyl vinyl ether has been shown to degrade in the presence of acid..
t
'ND Not detected at or above adjusted reporting limit
NC Not Calculable
J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
(S) Surrogate
[1] Compound concentration exceeds the calibration.range of the instrument (CLP E-Flag).
C21 Sample results may be biased high due to, i
C37 nterference with internal standard.
The surrogate recovery was outside QC acceptance limits due to matrix interference.
,Date: 01/10/06
Page: 3 of 12
Asheville Certification IDs REPORT OF LABORATORY NC Wastewater 40 ANALYSIS Charlotte Certification IDs
NC Drinking Water 37712 This report shall not be reproduced, except in full, NC Wastewater 12
Sc 99030 without the written consent of Pace Analytical Services, Inc. NC Drinking Water 37706
Ac`°'
FL NELAP E87648 Sc
�N ° 99006
FL NELAP E87627
e

Analytical Environmental Services,
Inc.
Date:
28-Dec-05
,
CLIENT: Pace Analytical. Services, Inc.
Project: 92109812.
Client Sample ID: 926463092
Lab ID: 05121302-001
Collection Date: 12/20/2005
`
Matrix: SLUDGE
Analyses Result
Reporting.
Limit
Qual Units BatchID Dilution
Factor
Date Analyzed
HERBICIDES, TCLP
2,4,5-TP (Silvex)
BRL'
SW1311/8151A
0.50
SW3510B
.. )
Analyst: MM
2,4-D
BRL
0.50
mg/L 657,31 1
12/23/2005 6:44 PM
Surr. DCAA
87.3
21.3-162
mg/L 65731 1
%REC
12/23/2005 6:44 PM
65731 1
12/23/2005 6:44 PM
Qualifiers: * Value exceeds Maximum Contaminant Level
BRL Below Reporting Limit
E Estimated (Value above quantitation range)
H Holding times for preparation or analysis exceeded
S Surrogate Recovery outside. accepted recovery limits
N Analyte not NELAC certified
.
Nary See Case Narrative
B Analyte detected in the associated Method Blank
NC Not Confirmed
Pagel of 1

Appendix. D
20.06
Residual Operation
Summary Sheet

TWSA RESIDUAL
ANNUAL OPERATION TOTALS
2006
fE
Jan.
SLUDGE FEED LIME FEED
%Solids Gallons. D Ton D Ton
2.2 319,069 28.71 No Lime
Polymer
Jbs
684.9
Usage Press Run Time Slud a Hauled to Landfill
da s da s with lime hrs Wet Ton Ti in Fee Haul Fee
8 0 91.E 64.96
Feb.
2.2
267,900
25.18
No Lime
542.2
6 0 70.3 152.53
Mar.
1.8
347,700
26.14
No Lime
754.3
7 0 84.7 109.14
Apr.
4.3
118,200
22.95
No Lime
286
2 0 23 0.00
Aaa.7
31.48
No Lime
1370.4
10 0 107 153.65
Jun.
E237,145
15.1E
No Lime
632.3
5 0 56.2 72.94
Jul.
16.08
No Lime
665.7
6 0 64.7 46.73
kug.
1.6
237,515
16.04
No Lime
734.2.
6 0 64.2 109.37
'ep.1.5
310,741
18.58
No Lime
1098.E
8 0 86.7 98.27
Dct.
1.6
189,984
12.0E
No Lime
499.3
5 0 52 89.73
lov.
1.7
224,054
15.3E
No Lime
489.8
5 0 57-------------
93.80
►ec.
hl
1.8
394,746
27.42
No Lime
855.7
13 0 128.8 89.18
1v
2.0
271,365
21.2E
0.00
717.8
7 73.9
)tal
3,256,375
255.1E
0.00
8,613.4
81 0 886.2 $0.00 1080.30
# of days press
was run
81
Total # of hours press was ran
886.2
# of days lime was added
0
Avg. # of hours press was run/day
10.9
Estimated Annual wet ton of Residuals produced
1343
Estimated Annual wet ton of Class A Residual produced
0
Estimated Annual wet ton of Class A Residual distributed to the public
. 735
40
R