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HomeMy WebLinkAboutNC0025909_Fact Sheet_20221109Page 1 of 14 Fact Sheet NPDES Permit No. NC0025909 Permit Writer/Email Contact Nick Coco, nick.coco@ncdenr.gov: Date: August 10, 2022 Division/Branch: NC Division of Water Resources/NPDES Municipal Permitting Fact Sheet Template: Version 09Jan2017 Permitting Action: ☒ Renewal ☐ Renewal with Expansion ☐ New Discharge ☐ Modification (Fact Sheet should be tailored to mod request) Note: A complete application should include the following: • For New Dischargers, EPA Form 2A or 2D requirements, Engineering Alternatives Analysis, Fee • For Existing Dischargers (POTW), EPA Form 2A, 3 effluent pollutant scans, 4 2nd species WET tests. • For Existing Dischargers (Non-POTW), EPA Form 2C with correct analytical requirements based on industry category. Complete applicable sections below. If not applicable, enter NA. 1. Basic Facility Information Facility Information Applicant/Facility Name: Town of Rutherfordton/Rutherfordton WWTP Applicant Address: 129 N. Main Street, Rutherfordton, NC 28139 Facility Address: 1021 S. Main Street, Rutherfordton, NC 28139 Permitted Flow: 1.0 MGD & 3.0 MGD (upon rolling average flow for any 12-month period exceeding 0.8 MGD) Facility Type/Waste: MAJOR Municipal; 97% domestic, 3% industrial Facility Class: 1.0 MGD tier: Grade III Biological Water Pollution Control System 3.0 MGD tier: Grade IV Biological Water Pollution Control System Treatment Units: mechanical bar screen, grit removal, equalization basin, three aeration basins, two secondary clarifiers, chlorine contact chamber, dechlorination, aerobic digester Pretreatment Program (Y/N) Y; STMP County: Rutherford Region Asheville Page 2 of 14 Briefly describe the proposed permitting action and facility background: The Town of Rutherfordton has applied for an NPDES permit renewal at 1.0 MGD for the Rutherfordton WWTP. The facility is rated for 3.0 MGD, and an expanded flow tier at 3.0 MGD is permitted, taking effect once the facility demonstrates a rolling average flow for any twelve (12) month period that exceeds 0.8 MGD. As review of the Town’s discharge monitoring reports (DMRs) during the period reviewed (January 2018 to June 2022) did not demonstrate a rolling average flow for any 12-month period exceeding 0.8 MGD, the 1.0 MGD flow tier and conditions have been maintained. This facility serves a population of approximately 4,030 residents, as well as 1 categorical significant industrial user (CIU) via an approved pretreatment program. Treated domestic and industrial wastewater is discharged into Cleghorn Creek, a class C waterbody in the Broad River Basin. The facility has a primary Outfall 001. Outfall 001 is approximately 3 miles upstream of waters designated as WS-IV that are listed in the 2022 303(d) list as impaired for benthos. Facility Background: Prior to the 2004 permit renewal, Rutherfordton anticipated the addition of a textile plant, with the flow to be treated at the Rutherfordton WWTP. Accordingly, the Town expanded the plant from 1 MGD to 3 MGD. The industry, however, never relocated to Rutherfordton. Sludge disposal: Sludge is land applied through the land application permit WQ32855. 2. Receiving Waterbody Information: Receiving Waterbody Information Outfalls/Receiving Stream(s): Outfall 001 – Cleghorn Creek Stream Segment: 9-26-(0.5) Stream Classification: C Drainage Area (mi2): 7.8 Summer 7Q10 (cfs) 1.86 Winter 7Q10 (cfs): 2.88 30Q2 (cfs): 4.02 Average Flow (cfs): 12 IWC (% effluent): 45% at 1.0 MGD 71% at 3.0 MGD 2022 303(d) listed/parameter: Yes; listed as exceeding criteria for benthos Subject to TMDL/parameter: Yes- State wide Mercury TMDL implementation. Basin/Sub-basin/HUC: Broad River/03-08-02/HUC: 03050105 USGS Topo Quad: F11SW Page 3 of 14 3. Effluent Data Summary Effluent data for Outfall 001 is summarized below for the period of January 2018 through June 2022. Table 1. Effluent Data Summary Outfall 001 Parameter Units Average Max Min Permit Limit Flow MGD 0.58* 6.058 0.122 MA 1.0 BOD mg/l 3.2 21 2 WA 45.0 MA 30.0 NH3N summer mg/l 0.26 2.91 0.02 WA 6.0 MA 2.0 NH3N winter mg/l 0.56 7.31 0.04 WA 14.1 MA 4.7 TSS mg/l 3.1 25 2.5 WA 45.0 MA 30.0 pH SU 6.9 7.4 6.0 6.0 ≥ pH ≤ 9.0 Fecal coliform #/100 ml 5.3 9700 < 1 (geometric) WA 400 MA 200 DO mg/l 8.0 14.3 5.1 DA ≥5.0 TRC µg/l 19.7 49 7 DM 28.0 (< 50 compliance) Temperature ° C 17.2 25 7 Monitor & Report TN mg/l 7.4 14.2 1.84 Monitor & Report TP mg/l 2.0 3.77 0.19 Monitor & Report Total Copper mg/l 6.9 9 2 Monitor & Report Total Zinc mg/l 56.6 145 36 Monitor & Report MA-Monthly Average, WA-Weekly Average, DM-Daily Maximum, DA=Daily Average *The 12-month rolling average monthly flow did not exceed 0.8 MGD. As such, the 3.0 MGD flow tier has not been triggered and the 1.0 MGD flow tier and limitations continue to apply. Page 4 of 14 4. Instream Data Summary Instream monitoring may be required in certain situations, for example: 1) to verify model predictions when model results for instream DO are within 1 mg/l of instream standard at full permitted flow; 2) to verify model predictions for outfall diffuser; 3) to provide data for future TMDL; 4) based on other instream concerns. Instream monitoring may be conducted by the Permittee, and there are also Monitoring Coalitions established in several basins that conduct instream sampling for the Permittee (in which case instream monitoring is waived in the permit as long as coalition membership is maintained). If applicable, summarize any instream data and what instream monitoring will be proposed for this permit action: The current permit requires instream monitoring for dissolved oxygen, temperature, and conductivity upstream just above the outfall and downstream at least 300 feet below the outfall. Instream monitoring is conducted three times per week during June, July, August and September, and once per week during the rest of the year. Data was observed from January 2018 to June 2022. The data has been summarized in Table 2 below. Table 2. Instream Monitoring Data Summary Parameter Units Upstream Downstream Average Max Min Average Max Min Temperature ° C 16.2 22 2 16.4 22 2 DO mg/l 7.1 13.8 3.4 7.1 14.2 3.8 Conductivity umhos/cm 100.2 862 43 99.3 965 43 Students t-tests were run at a 95% confidence interval to analyze relationships between instream samples. A statistically significant difference is determined when the t-test p-value result is < 0.05 Downstream temperature was not greater than 29 degrees Celsius [per 15A NCAC 02B .0211 (18)] during the period reviewed. Downstream temperature was not greater than upstream temperature by more than 2.8 degrees Celsius during the period reviewed. It was concluded that no statistically significant difference exists between upstream and downstream temperature. Downstream DO dropped below 5 mg/L [per 15A NCAC 02B .0211 (6)] on 7 occasions during the period reviewed. Upon further review, observed drops in downstream DO were consistent with drops in upstream DO. It was concluded that no statistically significant difference exists between upstr eam and downstream DO. It was concluded that no statistically significant difference exists between upstream and downstream conductivity. Per 15A NCAC 02B .0508, water quality limited wastewater facilities discharging primarily domestic waste shall monitor upstream and downstream fecal coliform. During the 2015 permit renewal, instream fecal coliform sampling was reviewed under the 2002 Guidance Regarding Conductivity and Fecal Coliform Monitoring. After concluding that the effluent was not causing elevated levels of fecal coliform downstream, and because the receiving stream is not Class B, the instream fecal coliform monitoring requirement was removed. Per the 2016 implementation of instream dissolved metals standards, facilities with pretreatment programs shall sample for total hardness in the effluent and upstream of the facility. As such, upstream and effluent hardness sampling has been added to the permit at a quarterly frequency. Page 5 of 14 No changes are proposed to instream temperature, dissolved oxygen or conductivity monitoring requirements. Is this facility a member of a Monitoring Coalition with waived instream monitoring (Y/N): NO Name of Monitoring Coalition: NA 5. Compliance Summary Summarize the compliance record with permit effluent limits (past 5 years): The facility reported no limit violations resulting in enforcement from June 2017 to June 2022. Summarize the compliance record with aquatic toxicity test limits and any second species test results (past 5 years): The facility passed 18 of 18 quarterly chronic toxicity tests, as well as all 4 second species chronic toxicity tests from January 2018 to April 2022. During the initial application for renewal, it was noted that the Permittee had not conducted second species chronic toxicity testing. The Town conducted this additional testing in accordance with construction provided by the DWR Aquatic Toxicology Branch and submitted this additional information. Summarize the results from the most recent compliance inspection: The last facility inspection conducted in November 2021 reported that the facility was compliant. 6. Water Quality-Based Effluent Limitations (WQBELs) Dilution and Mixing Zones In accordance with 15A NCAC 2B.0206, the following streamflows are used for dilution considerations for development of WQBELs: 1Q10 streamflow (acute Aquatic Life); 7Q10 streamflow (chronic Aquatic Life; non-carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). If applicable, describe any other dilution factors considered (e.g., based on CORMIX model results): NA If applicable, describe any mixing zones established in accordance with 15A NCAC 2B.0204(b): NA Oxygen-Consuming Waste Limitations Limitations for oxygen-consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits (e.g., BOD= 30 mg/l for Municipals) may be appropriate if deemed more stringent based on dilution and model results. If permit limits are more stringent than TBELs, describe how limits were developed: The existing limitations for BOD5 are secondary treatment standards based on 40 CFR 133.102. These limits were confirmed in a 1985 (1.0 MGD flow tier) and 1996 (3.0 MGD flow tier) Level B model. No changes are proposed. Page 6 of 14 Ammonia and Total Residual Chlorine Limitations Limitations for ammonia are based on protection of aquatic life utilizing an ammonia chronic criterion of 1.0 mg/l (summer) and 1.8 mg/l (winter). Acute ammonia limits are derived from chronic criteria, utilizing a multiplication factor of 3 for Municipals and a multiplication factor of 5 for Non-Municipals. Limitations for Total Residual Chlorine (TRC) are based on the NC water quality standard for protection of aquatic life (17 ug/l) and capped at 28 ug/l (acute impacts). Due to analytical issues, all TRC values reported below 50 ug/l are considered compliant with their permit limit. Describe any proposed changes to ammonia and/or TRC limits for this permit renewal: TRC limits have been reviewed in the attached WLA and have been found to be protective. No changes are proposed. The current ammonia permit limits for the 1.0 MGD flow tier were set based on IWC-based concentrations in the 2004 renewal for protection against oxygen-consuming waste. Ammonia limits have existed in the permit for the 3.0 MGD flow tier since 2000. The ammonia limits have been reviewed in the attached WLA for toxicity and have been found to be protective. No changes are proposed. Reasonable Potential Analysis (RPA) for Toxicants If applicable, conduct RPA analysis and complete information below. The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall. The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of ½ detection limit for “less than” values; and 4) streamflows used for dilution consideration based on 15A NCAC 2B.0206. Effective April 6, 2016, NC began implementation of dissolved metals criteria in the RPA process in accordance with guidance titled NPDES Implementation of Instream Dissolved Metals Standards, dated June 10, 2016. The RPA was conducted using WS standards to protect downstream WS-IV uses. As such, chlorinated phenolic compounds, total dissolved solids and nitrate were assessed. All chlorinated phenols were reported as non-detected in the 2017, 2018 and 2019 effluent pollutant scans. Nitrite + Nitrate values were used in conducting a reasonable potential analysis for nitrate. Total hardness was not greater than 100 mg/L as CaCO3 during the period reviewed. A reasonable potential analysis was conducted on effluent toxicant data collected between January 2018 and June 2022. Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. Based on this analysis, the following permitting actions are proposed for this permit: • Effluent Limit with Monitoring. The following parameters will receive a water quality-based effluent limit (WQBEL) since they demonstrated a reasonable potential to exceed applicable water quality standards/criteria: Nitrate (MA – 22.0 mg/L) • Monitoring Only. The following parameters will receive a monitor-only requirement since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria, but the maximum predicted concentration was >50% of the allowable concentration: Total Silver; The dataset of 10 samples shows one total silver detection at 0.3 ug/L. Upon further review of the date of detection, upstream and influent total silver was reported as detected at concentrations of 0.28 ug/L and 0.48 ug/L, respectively. To better characterize the Town’s silver contribution, monthly monitoring has been added but no limit has been applied based on best Page 7 of 14 professional judgement (BPJ). The Town has one industrial discharger. It is recommended that total silver be added to the pretreatment short term monitoring plan. • No Limit or Monitoring: The following parameters will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was <50% of the allowable concentration: Total Arsenic, Total Cadmium, Total Chromium, Total Copper, Total Lead, Total Nickel, Total Selenium, Total Zinc • POTW Effluent Pollutant Scan Review: Three effluent pollutant scans were evaluated for additional pollutants of concern. o The following parameter(s) will receive a water quality-based effluent limit (WQBEL) with monitoring, since as part of a limited data set, two samples exceeded the allowable discharge concentration: None o The following parameter(s) will receive a monitor-only requirement, since as part of a limited data set, one sample exceeded the allowable discharge concentration: None o The following parameters will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was <50% of the allowable concentration: Total Cyanide, Chloroform The RPA was conducted at both the 1.0 MGD and 3.0 MGD flow tiers. The above summary is applicable to both flow tiers for all parameters noted except total copper and total zinc. Both total copper and total zinc showed no reasonable potential for excursions above their respective allowable discharge concentrations. However, at the 3.0 MGD flow tier, the maximum predicted concentrations for each parameter were greater than or equal to the allowable discharge concentrations. As such, quarterly monitoring requirements have been maintained for total copper and total zinc at the 3.0 MGD flow tier. If applicable, attach a spreadsheet of the RPA results as well as a copy of the Dissolved Metals Implementation Fact Sheet for freshwater/saltwater to this Fact Sheet. Include a printout of the RPA Dissolved to Total Metal Calculator sheet if this is a Municipality with a Pretreatment Program. Toxicity Testing Limitations Permit limits and monitoring requirements for Whole Effluent Toxicity (WET) have been established in accordance with Division guidance (per WET Memo, 8/2/1999). Per WET guidance, all NPDES permits issued to Major facilities or any facility discharging “complex” wastewater (contains anything other than domestic waste) will contain appropriate WET limits and monitoring requirements, with several exceptions. The State has received prior EPA approval to use an Alternative WET Test Procedure in NPDES permits, using single concentration screening tests, with multiple dilution follow-up upon a test failure. Describe proposed toxicity test requirement: This is a Major POTW, and a chronic WET limit at 45% effluent at 1.0 MGD and 71% effluent at 3.0 MGD will continue on a quarterly frequency. Mercury Statewide TMDL Evaluation There is a statewide TMDL for mercury approved by EPA in 2012. The TMDL target was to comply with EPA’s mercury fish tissue criteria (0.3 mg/kg) for human health protection. The TMDL established a wasteload allocation for point sources of 37 kg/year (81 lb/year), and is applicable to municipals and industrial facilities with known mercury discharges. Given the small contribution of mercury from point Page 8 of 14 sources (~2% of total load), the TMDL emphasizes mercury minimization plans (MMPs) for point source control. Municipal facilities > 2 MGD and discharging quantifiable levels of mercury (>1 ng/l) will receive an MMP requirement. Industrials are evaluated on a case-by-case basis, depending if mercury is a pollutant of concern. Effluent limits may also be added if annual average effluent concentrations exceed the WQBEL value (based on the NC WQS of 12 ng/l) and/or if any individual value exceeds a TBEL value of 47 ng/l Table. Mercury Effluent Data Summary 2018 2019 2020 # of Samples 2 1 6 Annual Average Conc. ng/L 1.5 < 1 2.6 Maximum Conc., ng/L 2.4 < 1 7.6 TBEL, ng/L 47 WQBEL, ng/L 26.4 Describe proposed permit actions based on mercury evaluation: Since no annual average mercury concentration exceeded the WQBEL, and no individual mercury sample exceeded the TBEL, no mercury limit is required. Since the facility is < 2.0 MGD, a mercury minimization plan (MMP) is not required. However, as the facility has an expanded flow tier at 3.0 MGD and reported quantifiable levels of mercury (> 1 ng/l), a mercury minimization plan (MMP) has been added to the permit, to take effect upon expansion to the 3.0 MGD flow tier. Other TMDL/Nutrient Management Strategy Considerations If applicable, describe any other TMDLs/Nutrient Management Strategies and their implementation within this permit: NA Other WQBEL Considerations If applicable, describe any other parameters of concern evaluated for WQBELs: NA If applicable, describe any special actions (HQW or ORW) this receiving stream and classification shall comply with in order to protect the designated waterbody: NA If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 15A NCAC 2H.0107( c)(2)(B), 40CFR 122.47, and EPA May 2007 Memo: As nitrate demonstrated reasonable potential to exceed the facility’s allowable discharge concentration based on state surface water standards for the downstream WS-IV waters, monthly average limits have been put in the permit for nitrate at both flow tiers. After discussing the limits with the Permittee, the Permittee requested a schedule of compliance to provide time to locate issues and come into compliance with the new limits. A 3-year compliance schedule has also been put in the permit. Within 1 year of the permit’s effective date, the Permittee shall submit to DWR an Action Plan for Division approval, summarizing the strategy or actions to be taken to achieve compliance with the nitrate limitations. The plan will include specific dates for completion or implementation of each action. Within 2 years of the permit’s effective date, the Permittee shall submit a report to the Division summarizing actions taken in accordance with the Action Plan. The Town shall achieve compliance with nitrate limitations within 3 years of the permit’s effective date. Should the Rutherfordton WWTP expand to the 3.0 MGD flow tier, the Town shall achieve compliance with nitrate limitations upon expansion. Page 9 of 14 If applicable, describe any water quality standards variances proposed in accordance with NCGS 143- 215.3(e) and 15A NCAC 2B.0226 for this permit renewal: NA 7. Technology-Based Effluent Limitations (TBELs) Municipals (if not applicable, delete and skip to Industrials) Are concentration limits in the permit at least as stringent as secondary treatment requirements (30 mg/l BOD5/TSS for Monthly Average, and 45 mg/l for BOD5/TSS for Weekly Average). YES If NO, provide a justification for alternative limitations (e.g., waste stabilization pond). NA Are 85% removal requirements for BOD5/TSS included in the permit? YES If NO, provide a justification (e.g., waste stabilization pond). NA 8. Antidegradation Review (New/Expanding Discharge): The objective of an antidegradation review is to ensure that a new or increased pollutant loading will not degrade water quality. Permitting actions for new or expanding discharges require an antidegradation review in accordance with 15A NCAC 2B.0201. Each applicant for a new/expanding NPDES permit must document an effort to consider non-discharge alternatives per 15A NCAC 2H.0105( c)(2). In all cases, existing instream water uses and the level of water quality necessary to protect the existing use is maintained and protected. If applicable, describe the results of the antidegradation review, including the Engineering Alternatives Analysis (EAA) and any water quality modeling results: NA 9. Antibacksliding Review: Sections 402(o)(2) and 303(d)(4) of the CWA and federal regulations at 40 CFR 122.44(l) prohibit backsliding of effluent limitations in NPDES permits. These provisions require effluent limitations in a reissued permit to be as stringent as those in the previous permit, with some exceptions where limitations may be relaxed (e.g., based on new information, increases in production may warrant less stringent TBEL limits, or WQBELs may be less stringent based on updated RPA or dilution). Are any effluent limitations less stringent than previous permit (YES/NO): NO If YES, confirm that antibacksliding provisions are not violated: NA 10. Monitoring Requirements Monitoring frequencies for NPDES permitting are established in accordance with the following regulations and guidance: 1) State Regulation for Surface Water Monitoring, 15A NCAC 2B.0500; 2) NPDES Guidance, Monitoring Frequency for Toxic Substances (7/15/2010 Memo); 3) NPDES Guidance, Reduced Monitoring Frequencies for Facilities with Superior Compliance (10/22/2012 Memo); 4) Best Professional Judgement (BPJ). Per US EPA (Interim Guidance, 1996), monitoring requirements are not considered effluent limitations under Section 402(o) of the Clean Water Act, and therefore anti- backsliding prohibitions would not be triggered by reductions in monitoring frequencies. For instream monitoring, refer to Section 4. Page 10 of 14 Per 15A NCAC 02B .0508, Grade III and IV water quality limited wastewater facilities discharging primarily domestic waste shall monitor effluent conductivity 3/week and daily, respectively. However, as the facility has conducted upstream and downstream sampling, and no statistically significant difference was found between the two locations, effluent conductivity monitoring has not been added at this time. The Town of Rutherfordton was granted 2/week monitoring for BOD, ammonia, TSS and fecal coliform based on 2012 DWR Guidance Regarding the Reduction of Monitoring Frequencies in NPDES Permits for Exceptionally Performing Facilities during their 2016 renewal. The Town has requested continuation of this monitoring frequency reduction as part of their renewal application. The last three years of the facility’s data for these parameters have been reviewed in accordance with the criteria outlined in the guidance. As the facility is designed for 3.0 MGD and expansion from 1.0 MGD to 3.0 MGD of permitted flow is triggered by a rolling average and does not include a construction requirement, this assessment has been applied to the limit and violation requirements associated with the 3.0 MGD flow tier. Based on this review, 2/week monitoring frequency has been maintained for BOD, ammonia, TSS and fecal coliform at both flow tiers. To identify PFAS contamination in waters classified as Water Supply (WS) waters, monitoring requirements are to be implemented in permits with pretreatment programs that discharge to WS waters. As the Rutherfordton WWTP has a pretreatment program and discharges treated wastewater approximately 3 miles upstream of waters designated as WS-IV, monitoring of PFAS chemicals will be added to the permit at a frequency of quarterly. Since an EPA method for sampling and analyzing PFAS in wastewater is not currently available, the PFAS sampling requirement in the Permit includes a compliance schedule which delays the effective date of this requirement until the first full calendar quarter beginning 6 months after EPA has a final wastewater method in 40 CFR136 published in the Federal Register. This date may be extended upon request and if there are no NC-certified labs. 11. Electronic Reporting Requirements The US EPA NPDES Electronic Reporting Rule was finalized on December 21, 2015. Effective December 21, 2016, NPDES regulated facilities are required to submit Discharge Monitoring Reports (DMRs) electronically. While NPDES regulated facilities would initially be required to submit additional NPDES reports electronically effective December 21, 2020, EPA extended this deadline from December 21, 2020, to December 21, 2025. The current compliance date, effective January 4, 2021, was extended as a final regulation change published in the November 2, 2020 Federal Register. This permit contains the requirements for electronic reporting, consistent with Federal requirements. 12.Summary of Proposed Permitting Actions: A. Table. Current Permit Conditions and Proposed Changes Outfall 001 Parameter Current Permit Proposed Change Basis for Condition/Change Flow MA 1.0 MGD with expansion to 3.0 MGD No change 15A NCAC 2B .0505 BOD5 Both flow tiers: MA 30.0 mg/l WA 45.0 mg/l Monitor and report 2/Week No change TBEL. Secondary treatment standards/40 CFR 133 / 15A NCAC 2B .0406; 1985 and 1996 Level B Models; 2012 DWR Guidance Regarding the Reduction of Monitoring Frequencies in NPDES Page 11 of 14 Permits for Exceptionally Performing Facilities NH3-N 1.0 MGD tier: Summer: MA 2.0 mg/l WA 6.0 mg/l Winter: MA 4.7 mg/l WA 14.1 mg/l 3.0 MGD tier: Summer: MA 1.0 mg/l WA 3.0 mg/l Winter: MA 2.0 mg/l WA 6.0 mg/l Both tiers: Monitor and report 2/Week No change WQBEL. 2022 WLA review. 15A NCAC 2B; 2012 DWR Guidance Regarding the Reduction of Monitoring Frequencies in NPDES Permits for Exceptionally Performing Facilities TSS Both flow tiers: MA 30.0 mg/l WA 45.0 mg/l Monitor and report 2/Week No change TBEL. Secondary treatment standards/40 CFR 133 / 15A NCAC 2B .0406; 1985 and 1996 Level B Models; 2012 DWR Guidance Regarding the Reduction of Monitoring Frequencies in NPDES Permits for Exceptionally Performing Facilities Fecal coliform Both flow tiers: MA 200 /100ml WA 400 /100ml Monitor and report 2/Week No change WQBEL. State WQ standard, 15A NCAC 2B .0200; 2012 DWR Guidance Regarding the Reduction of Monitoring Frequencies in NPDES Permits for Exceptionally Performing Facilities DO Both flow tiers: > 5 mg/l 1.0 MGD tier: Monitor and Report 3/week 3.0 MGD tier: Monitor and Report daily No change WQBEL. State WQ standard, 15A NCAC 2B .0200; 15A NCAC 02B .0500 pH Both flow tiers: 6 – 9 SU 1.0 MGD tier: No change WQBEL. State WQ standard, 15A NCAC 2B .0200; 15A NCAC 02B .0500 Page 12 of 14 Monitor and Report 3/week 3.0 MGD tier: Monitor and Report daily Total Residual Chlorine 1.0 MGD tier: DM 28 ug/L 3.0 MGD tier: DM 24 ug/L No change WQBEL. 2021 WLA. Surface Water Monitoring, 15A NCAC 2B. 0500 Nitrate No requirement 1.0 MGD tier: MA 22.0 mg/L Monitor and Report Monthly 3.0 MGD tier: MA 14.0 mg/l Monitor and Report Monthly Based on results of Reasonable Potential Analysis (RPA) and BPJ; RP shown - apply Monthly Monitoring; Protection of downstream WS-IV designation Total Nitrogen Both flow tiers: Monitor and Report Quarterly No change Surface Water Monitoring, 15A NCAC 2B. 0500 Total Phosphorus Both flow tiers: Monitor and Report Quarterly No change Surface Water Monitoring, 15A NCAC 2B. 0500 Total Copper Monitor and Report Quarterly 1.0 MGD tier: Remove monitoring requirement 3.0 MGD tier: No change. Monitor and Report Quarterly Based on results of Reasonable Potential Analysis (RPA); 1.0 MGD tier: No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required 3.0 MGD tier: No RP, Predicted Max ≥ 50% of Allowable Cw – apply Quarterly Monitoring Total Zinc Monitor and Report Quarterly 1.0 MGD tier: Remove monitoring requirement 3.0 MGD tier: No change. Monitor and Report Quarterly Based on results of Reasonable Potential Analysis (RPA); 1.0 MGD tier: No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required 3.0 MGD tier: No RP, Predicted Max ≥ 50% of Allowable Cw – apply Quarterly Monitoring Total Silver No requirement Both flow tiers: No limit. Monitor and Report Monthly Based on results of Reasonable Potential Analysis (RPA) and BPJ; RP shown - apply Monthly Monitoring, as only one detection in a dataset of 10 samples was reported greater than Cw, monitoring will be added to better understand silver contributions but no limit will be applied. Page 13 of 14 Total Hardness No requirement Quarterly monitoring Upstream and in Effluent Hardness-dependent dissolved metals water quality standards approved in 2016 PFAS No requirement Add quarterly monitoring with delayed implementation Evaluation of PFAS contribution: pretreatment facility; Implementation delayed until after EPA certified method becomes available. Toxicity Test 1.0 MGD tier: Chronic limit, 45% effluent 3.0 MGD tier: Chronic limit, 71% effluent No change WQBEL. No toxics in toxic amounts. 15A NCAC 2B.0200 and 15A NCAC 2B.0500 Effluent Pollutant Scan Three times per permit cycle No change; conducted in 2024, 2025, 2026 40 CFR 122 Mercury Minimization Plan (MMP) No requirement Add MMP Special Condition; active upon expansion to 3.0 MGD flow tier WQBEL. Consistent with 2012 Statewide Mercury TMDL Implementation. Electronic Reporting Electronic Reporting Special Condition No change In accordance with EPA Electronic Reporting Rule 2015. MGD – Million gallons per day, MA - Monthly Average, WA – Weekly Average, DM – Daily Max 13. Public Notice Schedule: Permit to Public Notice: 08/17/2022 Per 15A NCAC 2H .0109 & .0111, The Division will receive comments for a period of 30 days following the publication date of the public notice. Any request for a public hearing shall be submitted to the Director within the 30 days comment period indicating the interest of the party filing such request and the reasons why a hearing is warranted. 14. NPDES Division Contact If you have any questions regarding any of the above information or on the attached permit, please contact Nick Coco at (919) 707-3609 or via email at nick.coco@ncdenr.gov. 15. Fact Sheet Addendum (if applicable): The draft was submitted to the Town of Rutherfordton, EPA Region IV, and the Division’s Asheville Regional Office, Aquatic Toxicology Branch, Basin Planning Branch and Operator Certification Program for review. No comments were received from any party. Were there any changes made since the Draft Permit was public noticed (Yes/No): NO If Yes, list changes and their basis below: NA Page 14 of 14 16. Fact Sheet Attachments (if applicable): • RPA Spreadsheet Summary • NPDES Implementation of Instream Dissolved Metals Standards – Freshwater Standards • NH3/TRC WLA Calculations • BOD & TSS Removal Rate Calculations • Mercury TMDL Calculations • Monitoring Frequency Reduction Evaluation • Pretreatment Information Request Form • WET Testing and Self-Monitoring Summary • Compliance Inspection Report • Requested Additional Information • Application Addendum Public Notice AFFP North Carolina Public Notice North Carolina Environmental Management CommissiontNPDES Unit 1617 Mail Service Center Affidavit of Publication Raleigh, NC 27699-1617 Notice of Intent to Issue a NP- DES Wastewater Permit STATE OF NC }NC0025909 Rutherfordton COUNTY OF RUTHERFORD SS WWTP The North Carolina En- vironmental Management Com- mission proposes to issue a LORI SPURLING, being duly sworn, says: NPDES wastewater discharge permit to the person(s) listed That she is PUBLISHER of the THE DAILY COURIER, a below. Written comments re- daily newspaper of general circulation, printed and garding the proposed permit published in FOREST CITY, Rutherford County, NC; that will be accepted until 30 days the publication, a copy of which is attached hereto, was after the publish date of this no- published in the said newspaper on the following dates: tics. The Director of the NC Di- vision of Water Resources August 17, 2022 DWR) may hold a public hear- ing should there be a signific- ant degree of public interest. Please mail comments and/or information requests to DWR at the above address. Interested persons may visit the DWR at That said newspaper was regularly issued and circulated 512 N. Salisbury Street, on those dates. Raleigh. NC 27604 to review in- SIGN formation on file. Additional in- r, ' formation on NPDES permits and this notice may be found on our website: PURL SHER http://deq.nc.gov/aboutidivi- Subscribed to and sworn to me this 17th day of August sionswater resourcesr`water re 2022. sources-permitsiwastewater- branchinAdes-wastewater/pu b- lic-notices,or by calling (919) 707-3601. The Town of Ruther- fordton [129 N. Main Street, Rutherfordton, NC 28139] has enise N. Downs, NOTARY , Rutherford County, NC requested renewal of NPDES permit NC0025909 for its My commission expires: July 16, 2027 Rutherfordton Wastewater Treatment Plant, located in Rutherford County. This permit- ted facility discharges treated 00013047 70440125 municipal and industrial wastewater to Cleghorn Creek, WREN THEDFORD (FC) a class C water in the Broad DEQ-DIVISION OF WATER RESOURCES (FC)River Basin. Ammonia, fecal 1617 MAIL SERVICE CENTER coliform, dissolved oxygen, pH, RALEIGH, NC 27699-1617 TRC and nitrate are water qual- ity limited. This discharge may affect future allocations in this segment of Cleghorn Creek. Aug. 17, 2022 ATTACHMENT II NARRATIVE DESCRIPTION OF PROCESS FLOW AND PROCESS FLOW SCHEMATIC NARRATIVE DESCRIPTION OF PROCESS FLOW Rutherfordton WWTP NPDES NC0025909 The Town of Rutherfordton Wastewater Treatment Plant (WWTP) is a 3.0 MGD design capacity facility. The facility treats wastewater from domestic, commercial and industrial sources. Wastewater is gravity flowed and pumped to the wastewater treatment plant. The current treatment scheme includes a mechanical bar screen, grit removal system, equalization basin, activated sludge treatment includes the use of 2 aeration basins high speed mechanical aeration. Treatment is followed by 2 secondary clarifiers. The treated effluent flow through a chlorine contact chamber and is disinfected by sodium hypochlorite followed by dechlorination through the use of sodium bisulfite. Final effluent is discharged into Cleghorn Creek. Excess biological solids are transferred to an aerobic digester for stabilization. The digested biosolids are decanted to thicken and land applied in liquid form on permitted sites. Attached is a flow schematic. ATTACHMENT VI REQUEST FOR REDUCED MONITORING FOR EXCEPTIONAL QUALITY EFFLUENT ATTACHEMENTI REQUEST FOR REDUCED MONITORING FOR EXCEPTIONALLY PERFORMING FACILITIES Town of Rutherfordton WWTP (NC0025909) DMR Data (1/1/2019 - 12/31/2021) Date Effluent BOD Effluent TSS Eff NH3 N Effluent Fecal mg/L mg/L mg/I 9/100 ml 1/2/2019 3.0 <2.5 0.1 2.0 1/7/2019 8.7 4.0 0.8 655.0 1/9/2019 4.8 5.1 0.1 3600.0 1/11/2019 <1.0 1/14/2019 4.7 3.5 0.1 12,0 1/16/2019 2.5 4.1 0.2 6.0 1/22/2019 6.2 2.9 0,1 24.0 1/25/2019 6.0 4.1 <0.04 8.0 1/28/2019 6.5 8 6 0.1 290.0 1/30/2019 3.2 3.4 0.1 1500.0 2/1/2019 5.0 2/4/2019 4.4 2.7 0.1 3.0 2/6/2019 5.3 <2.5 0.2 75.0 2/11/2019 3.8 2.6 0.1 3.0 2/13/2019 4.6 2.7 0,1 2.0 2/18/2019 7.2 5.7 0.6 5100.0 2/20/2019 3.3 8.0 0,2 2/21/2019 67.0 ` 2/22/2019 6 0 2/25/2019 3.5 3.6 0.1 6000.0 2/27/2019 <2.0 3.1 0.2 2.0 3/4/2019 2.1 3.5 0.1 3.0 3/6/2019 2.4 3.4 0.1 10 3f11/2019 2.9 2.8 0.1 <1.0 3/13/2019 <2.0 2.9 0.1 173.0 3/18/2019 2.1 <2.5 0.2 2.0 3/20/2019 2.1 2.9 0.1 1.0 3/25/2019 3.6 <2.5 0.1 <1.0 3/27/2019 2.5 <2.5 0.1 1.0 4/1/2019 <2.0 2,8 0.1 1.0 4/3/2019 2.3 <2.5 5.0 0.1 4/8/2019 2.1 <2.5 0.1 2.0 4/10/2019 <2.0 <2.5 0.1 1.0 4/15/2019 2.9 <2.5 0.1 182.0 4/17/2019 <2.0 <2.5 0.2 2-0 4/22/2019 <2.0 3.2 0.2 5-0 4/24/2019 <2.0 <2.5 0.2 1.0 4/29/2019 3,6 <2.5 0.4 3.0 5/1/2019 <2.0 <2.5 0.4 7.0 5/6/2019 <2.0 <2.6 0.2 37.0 5/8/2019 2.1 <2.5 0.1 14.0 5/15/2019 <2.0 . <2.5 0.1 2.0 5/16/2019 <2.0 <2.5 0.2 108.0 5/20/2019 <2.0 <2.5 0.2 5.0 5/22/2019 3.5 <2.5 0.4 6.0 5/28/2019 2.7 <2,5 0.2 8.0 5/30/2019 2.4 <L5 0.2 85.0 6/3/2019 2.0 <2.6 0.1 14.0 6/5/2019 2.7 <2.5 0.3 <1.0 6/10/2019 3.8 <2.5 0.2 6000.0 6/12/2019 <2.0 <25 0.1 <1.0 6/17/2019 2.6 <2.5 0.1 5.0 6/19/2019 4.5 2.6 0.1 48.0 6/24/2019 2.6 <2.6 0.1 2.0 6/26/2019 4.2 <2.5 0.4 5.0 7/1/2019 <2.0 <2.5 0.2 25.0 7/3/2019 2.5 <2.5 0.3 41.0 7/8/2019 3.0 <2.5 0.3 15.0 7/10/2019 2.1 <2.5 0.2 8.0 7/15/2019 2.4 <2.5 0.2 <1.0 7/17/2019 <2.0 <2.6 0.2 <1 0 7/22/2019 3.1 <2.5 0_2 <10 7/24/2D19 3 8 <2.5 0.2 10.0 7/29/2019 2 4 <2.5 0.2 <1-0 7/31/2019 2.1 <2.5 0.1 <1.0 8/5/2019 2.3 <2.5 0.2 2.0 8/7/2019 2.3 <2.5 0.5 <1.0 8/12/2019 2.1 <2.5 0.2 8.0 8/14/2019 2.0 <2.5 0.7 2.0 8/19/2019 <2.0 <2.5 0.1 3.0 8/21/2019 2.3 <2.5 0.4 1.0 8/26/2019 <2.0 <2.5 0.1 3.0 8/28/2019 <2.0 <2.5 0.6 <1.0 9/3/2019 2.1 <2.5 0.2 <1.0 9/5/2019 2.9 <2.5 0.3 <1.0 9/9/2019 2.7 <2.5 0.2 1.0 9/11/2019 <2.0 <2.5 1.0 <1.0 9/16/2019 3.7 <2.5 0.1 2.0 9/18/2019 3.6 <2.5 0.2 127.0 9/23/2019 <2.0 <2.5 0.1 310.0 9/25/2019 <2.0 <2.5 01 <1.0 WINTER MONTHS Date Effluent NH3-N mg/L 1/2/2019 0.11 1/7/2019 0.78 1/9/2019 0.10 1/11/2019 1/14/2019 0.08 1/16/2019 0.18 V22/2019 0.07 1,/25/2019 <0.04 1/28/2019 0.09 1/30/2019 0.11 2/1/2019 2/4/2019 0.12 2/6/2019 0.19 2/11/2019 0.11 2/13/2019 0.09 2/18/2019 0.61 2/20/2019 0.19 2/21,/2019 2/22/2019 2/25/2019 0.09 2/27/2019 0.21 3/4/2019 0.08 3/6/2019 0.11 3/11/2019 0.08 3/13/2019 0.11 3/18/2019 0.21 3/20/2019 0,14 3/25/2019 0,12 3/27/2019 0,09 11/4/2019 0.10 11/6/2019 0.47 11/11/2019 0.07 11/13/2019 0.26 11/18/2019 0.60 11/20/2019 0.74 11/25/2019 2.23 11/27/2019 1.34 12/2/2019 0.78 12/4/2019 0.29 12/9/2019 0.08 12/11/2019 0.64 12/16/2019 0.73 12/18/2019 0.62 12/23/2019 0.13 12/27/2019 0.42 12/30/2019 0.06 1/3/2020 0.24 1/6/2020 0.05 1/8/2020 0.24 1/13/2020 0.46 1/15/2020 0.28 1/21/2020 0.07 1/23f2020 0.22 1/27/2020 0 11 1/28/2020 0 21 1/29/2020 0.29 2/3/2020 0.09 2/5/2020 0.38 2/10/2020 0.21 2/11/2020 0.12 2/12/2020 0.05 2/17/2020 0.50 2/19/2020 0.98 2/24/2020 2/26/2020 2.86 2/28/2020 1.82 3f2f2020 0.38 3f4/2020 0.84 3/9/2020 1.52 3/11/2020 2.28 3/16/2020 0.29 3/18/2020 0.87 3/23/2020 1.07 3/25/2020 1.37 3/30/2020 0.38 11/2/2020 0.11 11/4/2020 0.05 11/9/2020 0.27 11/11/2020 0.08 11/16/2020 0.10 11/18/2020 0.62 SLIMMER MONTHS Date Effluent NH3-N mg/L 4/1/2019 0.12 4/3/2019 5.00 4/8/2019 0.07 4/10/2019 0.13 4/15/2019 0.11 4/17/2019 0.20 4/22/2019 0.24 4/24/2019 0.18 4/29/2019 0.36 5/1/2019 0.40 5/6/2019 0_17 5/8/2019 0_13 5/15/2019 0.12 5/16f2019 0.21 5/20/2019 0.18 5/22/2019 0.35 5/28/2019 0.15 5/30/2019 0,23 6/3/2019 0.10 6/5/2019 0.26 6/10/2019 0.21 6/12/2019 0.08 6/17/2019 0.10 6/19/2019 0.14 6/24/2019 0.09 6/26/2019 0.37 7f 1/2019 0.17 7/3/2019 0.27 7/8/2019 0.26 7/10/2019 0.22 7/15/2019 0.15 7/17/2019 0.18 7/22/2019 0.22 7/24/2019 0.16 7/29/2019 0.20 7/31/2019 0.14 8/5/2019 0.18 8/7/2019 0.47 8/12/2019 0,21 8/14/2019 0.65 8/19/1019 0.07 8/21/2019 0,36 8/26/2019 0.05 8/28/2019 0.61 9/3/2019 0.20 9/5/2019 0.27 9/9/2019 0.21 9/11/2019 1.04 9/16/2019 0.11 9/18/2019 0.18 9/23/2019 0.10 9/25/2019 0.11 9/30/2019 0.10 10/2/2019 0.28 10f7/2019 0.31 10/9/20191 0 11 10/14/2019 1.91 10/16/2019 0,12 10/21/2019 0.14 10/23/2019 L25 10/28/2019 0.11 10/30/2019 0.32 4/1/2020 0.90 4/6/2020 0.70 4/7/2020 0.12 4/8/2020 0.07 4/13/2020 0.26 4/15/2020 0-06 4/20/2020 0.17 4/22/2020 0.05 4/27/2020 0.06 4/29/2020 0.04 5/4/2020 0.05 5/5/2020 0.08 5/6/2020 0.32 5/11/2020 0.05 5/13/2020 0.16 5/18/2020 0.09 5/20/2020 1.94 5/26/2020 0.06 5/28/2020. 0.25 ATTACHEMENTI REQUEST FOR REDUCED MONITORING FOR EXCEPTIONALLY PERFORMING FACILITIES Town of Rutherfordton W WTP (NC0025909) DMR Data (1/1/2019 - 12/31/2021) Date 9/30/2019 10/2/2019 Effluent BOD Effluent TSS Eff NH3 N Effluent Fecal mg/L <2 0 26 mg/L 23 <2.5 mg/I 0.1 0.3 N/100 ml 1.0 <1.0 10/7/2019 <2.0 <2.5 0.3 4.0 10/9/2019 <2.0 <2.5 0.1 17.0 10/14/2219 2.7 <2.5 19 2.0 10/16/2019 2.3 <2.5 0,1 <1.0 10/21/2119 3.6 2.7 0,1 9,0 1D/23/2019 2.4 4.7 1.3 <1.0 10/28/2D19 10/30/2019 2.0 <2.0 <2,5 <2.5 0.1 0.3 1.0 <1.0 11/4/2019 <2.0 <2.5 0.1 127.0 11/6/2019 3,9 <2.5 0.5 250.0 11/11/2019 <2.0 <2,5 0,1 <1.0 11/13/2019 <2.0 <2,5 0.3 <1.0 11/18/2019 <2.0 <2,5 0.6 2.0 11/20/2019 <2.0 <2.5 0,7 20 11/25/2019 <2.0 <2.5 2.2 30 11/27/2019 2.2 <25 1.3 14.0 12/2/2019 2,7 <2.5 0.8 8.0 12/4/2019 5.0 <2.5 0,3 <1.0 12/9/2019 <2.0 <2.5 0.1 <1.0 12/11/2019 <2.0 <2.5 0.6 1.0 12/16/2019 <2.0 <2.5 0.7 <1,0 12/1B/2019 <2.0 <2.5 0.6 <1.0 12/23/2019 <2.0 <2.5 0.1 15.0 12/27/2019 <2.0 <2.5 0.4 1.0 12/30/2019 <2.0 <2.5 0.1 1.0 1/3/2020 <2.0 <2.5 0.2 12.0 1/6/2020 1/8/2020 <2 0 <2 0 <2.5 <2.5 0.1 0.2 3.0 10.0 1/11/2020 3,0 2.7 0.5 51.0 1/15/2020 3.4 <2.5 0.3 17.0 1/21/2020 2.9 2.8 0.1 <1.0 1/23/2020 2.3 3.8 0.2 4.0 1/27/2020 <2.0 <2.5 0.1 1.0 1/28/2020 <2,0 2.7 0.2 1/29/2020 <2,0 3.3 0-3 <1.0 1/3/2020 <2,0 <2.5 0-1 1.0 2/5/2020 <2.0 <2.5 0-4 <1.0 2/10/2020 <2.0 <2.5 0.2 155.0 2/11/2020 2.0 <2.5 0-1 2/12/2020 4.6 <2.5 0.1 <1.0 2/17/2020 5.3 25.0 0.5 1.0 2/19/2020 4.3 3.5 1.0 1.0 2/24/2020 <1.0 2/26/2020 4.4 3.0 2.9 <1.0 28/2020 6.3 9.0 3/2/2020 5.8 3.4 0.4 1.0 3/4/2020 5.7 4.1 0.8 1.0 3/9/2020 5.3 5.0 1.5 2.0 3/11/2020 5.1 5.8 2.3 2.0 3/16/2020 2.4 <25 0_3 <1.0 3/18/2020 2.9 <2-5 0_9 <1.0 3/23/2020 5.8 3.1 1_1 10 3/25/2020 5.6 3.6 1.4 34.0 3/30/2020 5.3 4.2 0,4 2.0 4/1/2020 7.0 4.4 0.9 <1.0 4/6/2020 2.4 <2.5 0.7 <1.0 4/7/2020 <2.0 <2.5 0.1 4/8/2020 2.2 2.6 0.1 1.0 4/13/2020 9.0 3.5 0.3 6000.0 4/15/2020 <2.0 <2.5 0.1 <1.0 4/20/2020 5.8 3_8 0.2 668.0 4/22/2020 8.4 4.0 0.1 1.0 4/27/2020 2.8 <2.5 0.1 2.0 4/29/2020 3.3 2.9 0.0 360.0 5/4/2020 2 6 <2.5 0.1 3.0 5/5/2020 <2.0 3.0 0.1 5/6/2020 3 8 2.9 0.3 <1,0 5/11/2020 3 1 3.1 0.1 3.0 5/13/2020 3 2 <2.5 0.2 <1.0 5/18/2020 3.1 <2_5 0.1 10 5/20/2020 7.8 6.4 1.9 6000.0 5/26/2020 <2.0 <2.5 0.1 <1.0 5/28/2020 <2_0 <2.5 0.3 2.0 6/1/2020 <2.0 <2,5 0.1 10 6/2/2020 2.4 <2,5 01 6/3/2020 6/8/2020 6/10/2020 6/15/2020 <2.0 2.8 <2.0 <2.0 <2.5 <2.5 <2.5 <2.5 0.2 2.9 0.1 0.1 <10 <1:0 1.0 4.0 WINTER MONTHS Date Effluent NH3-N mg/L 11/23/2020 0.07 11/25/2020 0.21 11/30/2020 0.22 12/2/2020 0.65 12/7/2020 0.09 12/9/2020 0.29 12/14/2020 0.27 12/16/2020 0,62 12/18/2020 12/21/2020 0.07 12/23/2020 0.12 12/28/2020 0.13 < 12/30/2020 0,28 1/4/2021 0.10 1/6/2021 0.10 1/11/2021 0.07 1/13/2021 0.33 1/19/2021 0-18 1/21/2021 D.76 1/25/2021 0.11 1/27/2021 0.08 2/1/2021 0.07 2/3/2021 0.27 2/8/2021 0.06 2/10/2021 0.07 2/15/2021 0.06 2/17/2021 0.05 2/22/2021 0.07 2/24/2021 0.08 3/1/2021 0.11 3/3/2021 0.08 3/8/2021 0.12 3/10/2021 0.08 3/15/2021 0.15 3/17/2021 0.10 3/22/2021 0.09 3/24/2021 0,08 3/29/2021 0.11 3/31/2021 0.05 11/1/2021 0.19 11/3/2021 0.12 11/8/2021 0.36 11/10/2021 0.06 11/15/2021 0.08 11/17/2021 0 44 11/22/2021 1.10 11/24/2021 0 08 11/29/2021 0.11 12/1/2021 0.36 12/6/2021 0,75 12/8/2021 0.08 12/13/2021 0.11 12/15/2021 <0.04 12/20/2021 4.53 12/22/2021 0.79 12/28/2021 1.04 12/30/2021 0.90 SUMMER MONTHS Date Effluent NH3-N mg/L 6/1/2020 0.11 6/2/2020 0.13 6/3/2020 0.19 6/8/2020 2.91 6/10/2020 0.09 6/15/2020 0.11 6/17/2020 0.46 6/22/2020 0.09 6/24/2020 0.86 6/29/2020 0-09 7/1/2020 0-83 7/6/2020 0.12 7/8/2020 0.46 7/13/2020 0.08 7/15/2020 0.08 7/20/2020 0.12 7/22/2020 0.08 7/27/2020 0.07 7/29/2020 0.24 8/3/2020 0.10 8/5/2020 0.09 8/10/2020 0.08 8/12/2020 0.07 8/17/2020 0.08 8/19/2020 0.06 8/24/2020 0.14 8/26/2020 0.08 8/31/2020 0,24 9/2/2020 0,06 9/8/2020 0,13 9/10/2020 0.49 9/14/2020 0.06 9/16/2020 0.06 9/21/2020 0.16 9/23/2020 0.25 9/28/2020 0.54 9/30/2020 0.47 10/5/2020 0.15 10/7/2020 0.18 10/12/2020 0.07 10/14/2020 0.42 10/11/2020 0.09 10/21/2020 1.15 10/26/202D 0.19 10/28/202D 0.72 4/5/2421 0.13 4/7/2021 0.18 4/120021 0.09 4/14/2021 0.10 4/19/2021 0.09 4/21/2021 0.08 4/26/2021 <0.04 4/28/2021 0.07 5/3/2021 0.13 5/5/2021 0,08 5/10/2021 0.11 5/12/2021 0,09 5/17/2021 0.14 5/19/2021 0.04 5/24/2021 0.05 5/26/2021 0.05 6/1/2021 0.06 6/3/2021 0.07 6/7/2021 <0.04 6/9/2021 0.07 6/14/2021 0.08 6/16/2021 0.08 6/21/2021 0.06 6/23/2021 0 08 6/28/2021 0 10 6/30/2021 0.09 7/6/2021 0 33 7/8/2021 0 08 7/12/2021 0 11 7/14/2021 0 48 7/19/2021 0 08 7/21/2021 0 10 7/26/2021 0.54 7/28/2021 0.14 8J212021 0.13 8/4/2021 0.08 ATTACHE MENTI REQUEST FOR REDUCED MONITORING FOR EXCEPTIONALLY PERFORMING FACILITIES Town of Rutherfordton WWTP(NC0025909) DMR Data (1/1/2019 - 12/31/2021) Date Effluent BOD Effluent TSS Eff NH3 N Effluent Fecal mg/L mg/L mg/I 4/100 ml 6/17/2020 <2.0 <2.5 0 5 1.0 6/22/2020 <2.0 <2.5 0.1 16,0 6/24/2020 <2.0 <2.5 0.9 <1,0 6/29/2020 <2.0 <2.5 01 24,0 7/1/2020 <2.0 <2.5 0.8 2.0 7/6/2020 <2.0 <2.5 0.1 90 7/8/2020 3.2 <2.5 0.5 5.0 7/13/2020 <2.0 <2.5 0.1 7.0 7/1 f2020 2.0 <2.5 0.1 1.0 7/20/2020 <2.0 <2.5 0.1 3.0 7/22/2020 <2.0 <2.5 0.1 <1.0 7/27/2020 <2.0 <2,5 0.1 <1.0 7/29/2020 <2.0 <2.5 0.2 2.0 8/3/2020 -I <20 <2.5 0.1 50.0 8/5/2020 <2.0 <2.5 0.1 <1.0 8/10/2020 <2.0 <2.5 0.1 51.0 8/12/2020 <2.0 <2 5 0.1 25.0 8/17./2020 <2.0 <2.5 0.1 11.0 9.119/2020 <2.0 <2.5 0,1 28.0 8/24/2020 <2.0 <2.5 0.1 10.0 8/26/2020 <2.0 <2.5 0.1 3.0 6/31/2020 <2-0 <2.5 0.2 12.0 9/2/2020 <2 0 <2-5 0.1 18.0 9/8/2020 <2,0 <2.5 0.1 5.0 9/10/2026 <2,0 <2.5 0,5 4,0 9/14/2020 <2,0 <2.5 0.1 14.0 9/16/2020 <2.0 <2.5 0.1 4.0 9/21/2020 <2.0 <2.5 0.2 6.0 9/23/2020 <2.0 <2.5 0.3 9.0 9/28/2020 <2.0 <2,5 0.5 <1.0 9/30/2020 3.7 <2.5 0.5 3.0 10/5/2020 <2.0 <2.5 0.2 <1.0 10/7/2020 <2.0 <2.5 0.2 7.0 10/12/2020 2.9 <2.5 0.1 24.0 10/14/2020 <2.0 <2.5 0-4 2.0 10/19/2020 <2,0 <25 0.1 31.0 10/21/2020 3.9 2.7 1-2 5.0 10/26/2020 3.5 <2.5 0.2 6.0 10/28/2020 2.2 2.6 0.7 1.0 11/2/2020 <2.0 <2.5 0,1 9.0 11/4/2020 <2.0 <2.5 0.1 43.0 11/9/2020 <2.0 <2.5 03 8,0 11/11/2020 <2.0 <2.5 0,1 4100.0 11,/16/2020 <2.0 <2.5 0.1 27.0 11/18/2020 <2.0 <2.5 0.6 8.0 11/23/2020 <2.0 <2.5 0.1 15.0 11/25/2020, <2.0 <2.5 0.2 4.0 11/30/2020 3.1 <2.5 0.2 56.0 12/2/2020 3 5 2.5 0.7 6.0 12/7/2020 49 2.8 0.1 146.0 12/9/2020 3.7 3,1 0.3 1.0 12/14/2020 3.4 <2.5 0.3 6000.0 12/16/2020 3.0 2.9 0.6 2200.0 12/18/2020 <1.0 12/21/2020 2.3 <2.5 0.1 3.0 12/23/2020 3.5 27 0.1 3.0 12/28/2020 2.1 26 0.1 1.0 1 230/2020 3.2 2.6 0 3 3.0 1/4/2021 3.1 <2.5 0.1 2 1/6/2021 3.7 <2.5 0_1 1.0 1/11/2021 4.5 2.8 0.1 <1.0 1/13/2021 3.7 3.3 0,3 1.0 1/19/2021 4.5 5.3 0.2 <1.0 1/21/2021 4.3 4.9 0.8 <1 0 1/25/2021 12.0 7.4 0.1 <1.0 1/27/2021 3.4 <2.5 0.1 1.0 2,/112021 6.1 3.0 0.1 220.0 2/3/2021 6.3 4.3 0.3 25.0 2/8/2021 4.2 3.3 0.1 <1.0 2/10/2021 3.6 2.5 0.1 2.0 2/15/2021 4.7 3.0 0.1 <1.0 2/17/2021 6.0 4.3 0.1 1.0 2/22/2021 4.4 3.5 0.1 10.0 2/24/2021 3.3 3.0 0.1 2.0 WINTER MONTHS Date Effluent NH3-N rng/L Average 0.39 NPDES Monthly Avg Limit (Winter) 4.7 50% of Monthly Average Limit 2.4 ;200% of Weekly Avg 28.2 Ik samples > 200% of Weekly Avg 0,0 SUMMER MONTHS Date Effluent NH3-N mg/L 8/9/2021 0.12 8/11/2021 0.07 8/16/2021 0.11 8/18/2021 0.11 6/23/2021 0.07 8/25/2021 0.58 8/30/2021 0.08 9/1/2021 0.16 9/7/2021 0.10 9/9/2021 0.05 9/13/2021 0,37 9/15/2021 0_10 9/20/2021 0.16 9/22/2021 0.09 9/27/2021 0.10 9/29/2021 0.41 10/4/2021 0 19 10/6/2021 0 12 10/11/2021 0 07 10/13/2021 0.85 10/18/2021 0.08 10/20/2021 0.30 10/25/2021 0.11 10/27/2021 0.33 ATTACHEMENT I REQUEST FOR REDUCED MONITORING FOR EXCEPTIONALLY PERFORMING FACILITIES Town of Rutherfordton WWTP (NC0025909) DMR Data (1/1/2019 - 12/31/2021) Date Effluent BOO Effluent TS5 Eff NH3 N Effluent Fecal mg/L mg/1 mg/I A/100 ml 3/1/2021 4.0 2.6 0.1 5.0 3/3/2021 3.5 <2.5 0.1 1.0 3/8/2021 3.8 <2.5 0.1 1.0 3/19/2021 4.0 3.2 01 <1.0 3/15/2071 <2.0 <2.5 0,2 <1.0 3/17/2021 4.1 3.5 0.1 <1.0 3/22/2021 2.5 <2.5 0.1 <1.0 3/24/2021 5.8 4.8 0.1 2.0 3/29/2021 4.8 3.0 0.1 1.0 3/31/2021 3.4 2.9 0.1 1.0 4/5/2021 4 3 4.0 " 0.1 1.0 4/7/2021 3.6 4.3 0.2 <1.0 4/12/2021 <2.0 <2.5 0.1 10 4/14/2021 3.2 <2.5 0.1 2.0 4/19/2021 <2.0 <2-5 0.1 1.0 4/21/2021 <2,0 <2.5 0.1 1.0 4/26/2021 <2.0 <2.5 <0,04 1.0 4/28/2021 2.3 <2.5 0.1 <1.0 5/3/2021 3.4 51 0.1 1.0 5/5/2021 2.8 3 6 0.1 8.0 5/10/2021 3.1 <2.5 0.1 1.0 5/12/2021 3.7 3.7 0.1 5.0 5/17/2021 5.2 3,1 0.1 2-0 5/19/2021 2.9 <2,5 0.0 <1-0 5/24/2021 2.8 3.2 0.1 1_0 5/26/2021 2.5 <2.5 0.1 2-0 6/1/2021 <2 0 <2.5 0.1 3.0 6/3/2021 2 5 <2.5 0.1 3.0 6/7/2021 2.1 2.7 <0.04 1.0 6/9/2021 <2.0 <25 0.1 3.0 6/14/2021 2.2 <2.5 0.1 7.0 6/16/2021 2.6 <2.5 0.1 3.0 6/21/2021 <2.0 <2.5 0.1 1.0 6/23/2021 <2.0 <2.5 0.1 5.0 6/28/2021 <2.0 <2.5 0.1 11.0 6/30/2021 <2.0 <2.5 0.1 10,0 7/6/2021 <2.0 <2.5 0.3 <1,0 7/8/2021 <2.0 <2.5 0,1 3.0 1/12/2021 <2.0 <2.5 0,1 12.0 7/14/2021 <2.0 <2.5 0.5 45.0 7/19/2021 <2.0 <2.5 0.1 210 7/21/2021 <2.0 <2S 0.1 1.0 7/26./2021 <2.0 <25 0.5 46.0 7/28/2021 <2.0 <25 0.1 12.0 8/2/2021 <2.0 <2-5 0.1 2.0 8/4/2021 <2.0 <23 0.1 8.0 8/9/2021 <2 0 <2S 0.1 4.0 8/11/2021 <2.0 <2.5 0.1 9.0 8/16/2021 <2.0 3.5 0.1 210.0 8/18/2021 <2.0 <2.5 0.1 4.0 8/23/2021 <2.0 <2.5 0.1 56.0 8/25/2021 3.2 <2.5 0.6 6.0 8/30/2021 <20 <2.5 0.1 12.0 9/1/2021 <2.0 <2.5 0.2 127 0 9/7/2021 <2.0 <2.5 0.1 50.0 9/9/2021 <2.0 <2_5 0.1 200.0 9/13/2021 <2.0 <2.5 0.4 11 0 9/15/2021 <2.0 <2_5 0.1 610 9/20/2021 <2.0 <2.5 0.2 42.0 9/22/2021 <2.0 <2.5 0.1 41.0 9/27/2021 <2.0 <2.5 0.1 62.0 9/29/2021 <2.0 <2.5 0.4 1.0 10/4/2021 <2.0 <2.5 0.2 310.0 10/6/2021 <2.0 <2.5 0.1 5.0 10/11/2021 <2.0 <2.5 0.1 <1.0 10/13/2021 <2.0 <2.5 0,9 1.0 10/18/2021 <2.0 <2.5 0,1 8.0 10/20/2021 <2.0 <2.5 0.3 <1.0 10/25/2021 <2.0 <2.5 0.1 30.0 10/27/2021 <2 0 <2.5 J 0.3 2.0 11/1/2021 <2.0 <2.5 0.2 3.0 11/3/2021 <2.0 <2.5 0_1 2.0 11/8/2021 <2.0 <25 0.4 5.0 11/10/2021 <2-0 <2.5 0,1 41.0 WINTER MONTHS Date Effluent NH3-N mg/L `-3bl,�J SI, Fr`a!� Irk Date Effluent NH3-N mg/L ,average 0.26 NPDES Monthly .Avg Limit Minter) inter) 2.0 :50%of Monthly .average Limit 1.0 200% of Weekly ,4vg 12,0 8 samples > 200% of Weekly Avg 0,0 ATTACHEMENT I REQUEST FOR REDUCED MONITORING FOR EXCEPTIONALLY PERFORMING FACILITIES Town of Rutherfordton WWTP (NC0025909) DMR Data (1/1/2019 - 12/31/2021) Date Effluent BOD Effluent TSS Eff NH3 N Effluent Fecal mg/L mg/L mg/I p/100 ml 11/15/2021 <2.0 <2.5 0,1 31.0 11/17/2021 <2.0 <2.5 0.4 7.0 11/22/2021 <2.0 <2.5 1,1 2.0 11/24/2021 <2.0 <2.5 0.1 19,0 11/29/2021 <2.0 <2.5 0.1 <1,0 12/1/2021 <2.0 <2.5 0.4 <1,0 12/6/2021 <2.0 <2.5 0.8 <1,0 12/8/2021 <2,0 <2-5 0.1 4,0 12/13/2021 2,9 <2.5 0.1 1,0 12/ 15/2021 2.6 <2.5 <0.04 1.0 12/20/2021 5.5 3 3 4.5 1.0 12/22/2021 3.3 <2.5 0.8 <1.0 12/2 B/2021 2.9 6.2 1.0 1.0 12/30/2021 5.6 5,3 0.9 <1.0 ,Average 3.7 3.9 7.6 NPDES Monthly Avg Limit 30.0 30 0 200.0 Weekly Avg Limit 45.0 45.0 400.0 50% of Monthly Avg Limit 15.0 15.0 100.0 200% of Weekly Avg 90.0 90.0 800.0 N samples > 200% of Weekly Avg 0 0 10 WINTER MONTHS Date Effluent NH3-N mg/L QUALIFICATION & JUSTIFICATION FOR REQUEST FOR REDUCED MONITORING 1) Requlremenl: mean < 50% of monthly average BOD Avg of 3.7 mg/I is <15 mg/I (50% of BOD Monthly Avg) TSS Avg of 3.9 mg/I is < 15 mg/I (50% of TSS Monthly Avg) Fecal Coliform Geomean Avg of 7.6/100 ml is < 100/100 ml (50% of Fecal Coliform Monthly Avg) NH3-N Winter Avg of 0.26 mg/I is < 2.4 mg/I (50% of NH3-N Winter Monthly Avg) NH3-N Summer Avg of 0.39 mg/I is < 1.0 mg/I (50% of NH3-N Summer Monthly Avg) 2) No more than 15 daily samples can be > 200% of the weekly average limit BOD: 0 Samples > 200% of weekly avg limit TSS: 0 Samples > 200% of weekly avg limit NH3-N (Winter): 0 Samples > 200% of weekly avg limit NH3-N (Summer): 0 Sample > 200% of weekly avg limit. 3) No more than 20 daily samples can be > 200% of the weekly average limit Fecal Coliform: 10 Samples > 200% of weekly avg limit 4) Sampling results shall not show more than two non -monthly avg. limit violations in past year 0 non -monthly violations occurred during th review period (1/1/2016 - 12/31/2020) SLIMMER MONTHS Effluent NH3-N mg/L J Date ATTACHMENT VI I CHEMICAL ADDENDUM TO NPDES APPLICATION CAS number Method Number (if  Applicable) Signed by: Signature Printed Name Date Date: Pollutant (Required)Reason Pollutant Believed Present in Discharge Estimated Concentration    (If  Known) EPA Identification Number NPDES Number Facility Name Outfall Number NC0025909 Rutherfordton WWTP 1 No pollutants were monitored that was not reported on the DMRs Doug Barrick , Town Manager 8/30/2022 August 30, 2022 March 17, 2021 1 Coco, Nick A From:Blackwell, Nadine <nadine.blackwell@veolia.com> Sent:Monday, August 8, 2022 2:50 PM To:Coco, Nick A Cc:Montebello, Michael J; Heim, Tim; Barrick, Doug; Reynolds, Phillip Subject:[External] Re: Additional Information Request: NC0025909 Rutherfordton WWTP CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to  Report Spam.    Hello,     The current NPDES Permit requires the monitoring of combined Nitrate and Nitrite on a quarterly basis.  There is no  additional monitoring results for Nitrate only.  With the absence of Nitrate data, the Town is requesting the reissued  Permit include a schedule of compliance to allow a 3‐year period to assess the true level of Nitrate in the discharge.     On Thu, Aug 4, 2022 at 10:48 AM Coco, Nick A <Nick.Coco@ncdenr.gov> wrote:  Hi Nadine,     I hope all is well on your end.     I have just about finished drafting the renewal NPDES permit NC0025909 for the Rutherfordton WWTP and wanted to  bring your attention one of the changes to be made to the permit:      Based on the reasonable potential analysis (RPA) showing reasonable potential to violate state water quality  standards for protection of downstream WS‐IV water uses, nitrate limits and monthly monitoring have been  added to the permit [See A.(1) and A.(2.)].     These changes will also be noted on the cover letter to your draft permit, but I wanted to just make you aware of the  changes ahead of time, in case there were any arrangements you wanted to get ahead of.      Regarding the proposed limit, upon request and justification, Permittees may be granted Schedules of Compliance for  newly added limits in their permits. I bring this up because the Rutherfordton WWTP did report nitrate samples  detected at levels near or above the parameter’s allowable discharge concentrations. If you wish to have  a compliance schedule, please let me know. If you believe that you will be able to achieve compliance with your permit  limits upon the effective date of the permit, we can skip the compliance schedule.  2    Summary of data  Parameter Flow Tier Maximum  Reported  Concentration  Maximum  Predicted  Concentration  Allowable  Discharge  Concentration  RPA Analysis  Decision  Nitrate 1.0 MGD 17.0 mg/L 24.9 mg/L MA 22.0 mg/L RP shown ‐ apply  Monthly Monitoring  with Limit  3.0 MGD 17.0 mg/L 24.9 mg/L MA 14.0 mg/L RP shown ‐ apply  Monthly Monitoring  with Limit       Let me know if you would like to have a compliance schedule for nitrate whenever you get the chance.     Best,  Nicholas A. Coco, PE  Engineer III  NPDES Municipal Permitting Unit  NC DEQ / Division of Water Resources / Water Quality Permitting     919 707‐3609    office  919 707 9000    main office  nick.coco@ncdenr.gov     Physical Address: 512 North Salisbury St.,Raleigh, NC, 27604  Mailing Address: 1617 Mail Service Center, Raleigh, NC, 27699‐1617     I'm working at home due to the State of Emergency and DWR policy for Covid-19. Thanks for being patient as we try to stay safe.  **Email is preferred but I am available to talk by via Microsoft Teams**     3      Email correspondence to and from this address is subject to the  North Carolina Public Records Law and may be disclosed to third parties.     Permit No. NC0025909 Page 1 of 4 NPDES Implementation of Instream Dissolved Metals Standards – Freshwater Standards The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. Therefore, metal limits in draft permits out to public notice after April 6, 2016 must be calculated to protect the new standards - as approved. Table 1. NC Dissolved Metals Water Quality Standards/Aquatic Life Protection Parameter Acute FW, µg/l (Dissolved) Chronic FW, µg/l (Dissolved) Acute SW, µg/l (Dissolved) Chronic SW, µg/l (Dissolved) Arsenic 340 150 69 36 Beryllium 65 6.5 --- --- Cadmium Calculation Calculation 40 8.8 Chromium III Calculation Calculation --- --- Chromium VI 16 11 1100 50 Copper Calculation Calculation 4.8 3.1 Lead Calculation Calculation 210 8.1 Nickel Calculation Calculation 74 8.2 Silver Calculation 0.06 1.9 0.1 Zinc Calculation Calculation 90 81 Table 1 Notes: 1. FW= Freshwater, SW= Saltwater 2. Calculation = Hardness dependent standard 3. Only the aquatic life standards listed above are expressed in dissolved form. Aquatic life standards for Mercury and selenium are still expressed as Total Recoverable Metals due to bioaccumulative concerns (as are all human health standards for all metals). It is still necessary to evaluate total recoverable aquatic life and human health standards listed in 15A NCAC 2B.0200 (e.g., arsenic at 10 µg/l for human health protection; cyanide at 5 µg/L and fluoride at 1.8 mg/L for aquatic life protection). Table 2. Dissolved Freshwater Standards for Hardness-Dependent Metals The Water Effects Ratio (WER) is equal to one unless determined otherwise under 15A NCAC 02B .0211 Subparagraph (11)(d) Metal NC Dissolved Standard, µg/l Cadmium, Acute WER*{1.136672-[ln hardness](0.041838)} ∙ e^{0.9151 [ln hardness]-3.1485} Cadmium, Acute Trout waters WER*{1.136672-[ln hardness](0.041838)} ∙ e^{0.9151[ln hardness]-3.6236} Cadmium, Chronic WER*{1.101672-[ln hardness](0.041838)} ∙ e^{0.7998[ln hardness]-4.4451} Chromium III, Acute WER*0.316 ∙ e^{0.8190[ln hardness]+3.7256} Chromium III, Chronic WER*0.860 ∙ e^{0.8190[ln hardness]+0.6848} Copper, Acute WER*0.960 ∙ e^{0.9422[ln hardness]-1.700} Copper, Chronic WER*0.960 ∙ e^{0.8545[ln hardness]-1.702} Lead, Acute WER*{1.46203-[ln hardness](0.145712)} ∙ e^{1.273[ln hardness]-1.460} Lead, Chronic WER*{1.46203-[ln hardness](0.145712)} ∙ e^{1.273[ln hardness]-4.705} Nickel, Acute WER*0.998 ∙ e^{0.8460[ln hardness]+2.255} Nickel, Chronic WER*0.997 ∙ e^{0.8460[ln hardness]+0.0584} Permit No. NC0025909 Page 2 of 4 Silver, Acute WER*0.85 ∙ e^{1.72[ln hardness]-6.59} Silver, Chronic Not applicable Zinc, Acute WER*0.978 ∙ e^{0.8473[ln hardness]+0.884} Zinc, Chronic WER*0.986 ∙ e^{0.8473[ln hardness]+0.884} General Information on the Reasonable Potential Analysis (RPA) The RPA process itself did not change as the result of the new metals standards. However, application of the dissolved and hardness-dependent standards requires additional consideration in order to establish the numeric standard for each metal of concern of each individual discharge. The hardness-based standards require some knowledge of the effluent and instream (upstream) hardness and so must be calculated case-by-case for each discharge. Metals limits must be expressed as ‘total recoverable’ metals in accordance with 40 CFR 122.45(c). The discharge-specific standards must be converted to the equivalent total values for use in the RPA calculations. We will generally rely on default translator values developed for each metal (more on that below), but it is also possible to consider case-specific translators developed in accordance with established methodology. RPA Permitting Guidance/WQBELs for Hardness-Dependent Metals - Freshwater The RPA is designed to predict the maximum likely effluent concentrations for each metal of concer n, based on recent effluent data, and calculate the allowable effluent concentrations, based on applicable standards and the critical low-flow values for the receiving stream. If the maximum predicted value is greater than the maximum allowed value (chronic or acute), the discharge has reasonable potential to exceed the standard, which warrants a permit limit in most cases. If monitoring for a particular pollutant indicates that the pollutant is not present (i.e. consistently below detection level), then the Division may remove the monitoring requirement in the reissued permit. 1. To perform a RPA on the Freshwater hardness-dependent metals the Permit Writer compiles the following information: • Critical low flow of the receiving stream, 7Q10 (the spreadsheet automatically calculates the 1Q10 using the formula 1Q10 = 0.843 (s7Q10, cfs) 0.993 • Effluent hardness and upstream hardness, site-specific data is preferred • Permitted flow • Receiving stream classification 2. In order to establish the numeric standard for each hardness-dependent metal of concern and for each individual discharge, the Permit Writer must first determine what effluent and instream (upstream) hardness values to use in the equations. The permit writer reviews DMR’s, Effluent Pollutant Scans, and Toxicity Test results for any hardness data and contacts the Permittee to see if any additional data is available for instream hardness values, upstream of the discharge. If no hardness data is available, the permit writer may choose to do an initial evaluation using a default hardness of 25 mg/L (CaCO3 or (Ca + Mg)). Minimum and maximum limits on the hardness value used for water quality calculations are 25 mg/L and 400 mg/L, respectively. If the use of a default hardness value results in a hardness-dependent metal showing reasonable potential, the permit writer contacts the Permittee and requests 5 site-specific effluent and upstream hardness samples over a period of one week. The RPA is rerun using the new data. Permit No. NC0025909 Page 3 of 4 The overall hardness value used in the water quality calculations is calculated as follows: Combined Hardness (chronic) = (Permitted Flow, cfs *Avg. Effluent Hardness, mg/L) + (s7Q10, cfs *Avg. Upstream Hardness, mg/L) (Permitted Flow, cfs + s7Q10, cfs) The Combined Hardness for acute is the same but the calculation uses the 1Q10 flow. 3. The permit writer converts the numeric standard for each metal of concern to a total recoverable metal, using the EPA Default Partition Coefficients (DPCs) or site-specific translators, if any have been developed using federally approved methodology. 4. The numeric standard for each metal of concern is divided by the default partition coefficient (or site-specific translator) to obtain a Total Recoverable Metal at ambient conditions. In some cases, where an EPA default partition coefficient translator does not exist (ie. silver), the dissolved numeric standard for each metal of concern is divided by the EPA conversion factor to obtain a Total Recoverable Metal at ambient conditions. This method presumes that the metal is dissolved to the same extent as it was during EPA’s criteria development for metals. For more information on conversion factors see the June, 1996 EPA Translator Guidance Document. 5. The RPA spreadsheet uses a mass balance equation to determine the total allowable concentration (permit limits) for each pollutant using the following equation: Ca = (s7Q10 + Qw) (Cwqs) – (s7Q10) (Cb) Qw Where: Ca = allowable effluent concentration (µg/L or mg/L) Cwqs = NC Water Quality Standard or federal criteria (µg/L or mg/L) Cb = background concentration: assume zero for all toxicants except NH3* (µg/L or mg/L) Qw = permitted effluent flow (cfs, match s7Q10) s7Q10 = summer low flow used to protect aquatic life from chronic toxicity and human health through the consumption of water, fish, and shellfish from noncarcinogens (cfs) * Discussions are on-going with EPA on how best to address background concentrations Flows other than s7Q10 may be incorporated as applicable: 1Q10 = used in the equation to protect aquatic life from acute toxicity EPA default partition coefficients or the “Fraction Dissolved” converts the value for dissolved metal at laboratory conditions to total recoverable metal at in-stream ambient conditions. This factor is calculated using the linear partition coefficients found in The Metals Translator: Guidance for Calculating a Total Recoverable Permit Limit from a Dissolved Criterion (EPA 823-B-96-007, June 1996) and the equation: _Cdiss__ = _______1_______________ Ctotal 1 + { [Kpo] [ss(1+a)] [10-6] } Where: ss = in-stream suspended solids concentration [mg/l], minimum of 10 mg/L used, and Kpo and a = constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A list of constants used for each hardness-dependent metal can also be found in the RPA program under a sheet labeled DPCs. Permit No. NC0025909 Page 4 of 4 QA = used in the equation to protect human health through the consumption of water, fish, and shellfish from carcinogens 30Q2 = used in the equation to protect aesthetic quality 6. The permit writer enters the most recent 2-3 years of effluent data for each pollutant of concern. Data entered must have been taken within four and one-half years prior to the date of the permit application (40 CFR 122.21). The RPA spreadsheet estimates the 95th percentile upper concentration of each pollutant. The Predicted Max concentrations are compared to the Total allowable concentrations to determine if a permit limit is necessary. If the predicted max exceeds the acute or chronic Total allowable concentrations, the discharge is considered to show reasonable potential to violate the water quality standard, and a permit limit (Total allowable concentration) is included in the permit in accordance with the U.S. EPA Technical Support Document for Water Quality-Based Toxics Control published in 1991. 7. When appropriate, permit writers develop facility specific compliance schedules in accordance with the EPA Headquarters Memo dated May 10, 2007 from James Hanlon to Alexis Strauss on 40 CFR 122.47 Compliance Schedule Requirements. 8. The Total Chromium NC WQS was removed and replaced with trivalent chromium and hexavalent chromium Water Quality Standards. As a cost savings measure, total chromium data results may be used as a conservative surrogate in cases where there are no analytical results based on chromium III or VI. In these cases, the projected maximum concentration (95th %) for total chromium will be compared against water quality standards for chromium III and chromium VI. 9. Effluent hardness sampling and instream hardness sampling, upstream of the discharge, are inserted into all permits with facilities monitoring for hardness-dependent metals to ensure the accuracy of the permit limits and to build a more robust hardness dataset. 10. Hardness and flow values used in the Reasonable Potential Analysis for this permit included: Parameter Value Comments (Data Source) Average Effluent Hardness (mg/L) [Total as, CaCO3 or (Ca+Mg)] 44.22 Average from January 2018 to May 2022 samples Average Upstream Hardness (mg/L) [Total as, CaCO3 or (Ca+Mg)] 31.22 Average from January 2018 to May 2022 samples 7Q10 summer (cfs) 1.86 USGS 1990 Low Flow Report 1Q10 (cfs) 1.56 Calculated in RPA Permitted Flow (MGD) 1.0 NPDES Files Date: _____8/1/2022________________________ Permit Writer: ______Nick Coco________________ REQUIRED DATA ENTRY Name WQS Type Chronic Modifier Acute PQL Units Facility Name Rutherfordton WWTP Par01 Arsenic Aquactic Life C 150 FW 340 ug/L WWTP/WTP Class III Par02 Arsenic Human Health Water Supply C 10 HH/WS N/A ug/L NPDES Permit NC0025909 Par03 Beryllium Aquatic Life NC 6.5 FW 65 ug/L Outfall 001 Par04 Cadmium Aquatic Life NC 0.7955 FW 4.6366 ug/L Flow, Qw (MGD)1.000 Par05 Chlorides Water Supply NC 250 WS mg/L Receiving Stream Cleghorn Creek Par06 Chlorinated Phenolic Compounds Water Supply NC 1 A ug/L HUC Number 03050105 Par07 Total Phenolic Compounds Aquatic Life NC 300 A ug/L Stream Class Par08 Chromium III Aquatic Life NC 162.7640 FW 1266.9732 ug/L Par09 Chromium VI Aquatic Life NC 11 FW 16 µg/L 7Q10s (cfs)1.860 Par10 Chromium, Total Aquatic Life NC N/A FW N/A µg/L 7Q10w (cfs)2.88 Par11 Copper Aquatic Life NC 11.0489 FW 15.4200 ug/L 30Q2 (cfs)4.02 Par12 Cyanide Aquatic Life NC 5 FW 22 10 ug/L QA (cfs)12.00 Par13 Fluoride Aquatic Life NC 1,800 FW ug/L 1Q10s (cfs)1.56 Par14 Lead Aquatic Life NC 4.5842 FW 119.6560 ug/L Effluent Hardness 44.22 mg/L (Avg)Par15 Mercury Aquatic Life NC 12 FW 0.5 ng/L Upstream Hardness 31.22 mg/L (Avg)Par16 Molybdenum Water Supply NC 160 WS ug/L Combined Hardness Chronic 37.13 mg/L Par17 Nickel Aquatic Life NC 52.0245 FW 474.4721 µg/L Combined Hardness Acute 37.7 mg/L Par18 Nickel Water Supply NC 25.0000 WS N/A µg/L Data Source(s)Par19 Selenium Aquatic Life NC 5 FW 56 ug/L Par20 Silver Aquatic Life NC 0.06 FW 0.6007 ug/L Par21 Zinc Aquatic Life NC 177.1796 FW 178.0248 ug/L Par22 Chloroform Water Supply NC 60 WS µg/L Par23 Par24 Follow directions for data entry. In some cases a comment menu list the available choices or a dropdown menu will provide a list you may select from. Error message occur if data entry does not meet input criteria. To appy a Model IWC %: Once the "Flow, Qw (MGD)" and and the "CHRONIC DILUTION FACTOR = " values are entered, the 7Q10s (cfs) flow is calculated and displayed. Enter the calculated "7Q10s (cfs)" flow value in Table 1. Table 1. Project Information Table 2. Parameters of Concern Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 C; upstream of WS-IV waters CHECK IF HQW OR ORW WQS CHECK TO APPLY MODEL Apply WS Hardness WQC 25909 RPA, input 8/2/2022 REQUIRED DATA ENTRY Name WQS Type Chronic Modifier Acute PQL Units Facility Name Rutherfordton WWTP Par01 Arsenic Aquactic Life C 150 FW 340 ug/L WWTP/WTP Class III Par02 Arsenic Human Health Water Supply C 10 HH/WS N/A ug/L NPDES Permit NC0025909 Par03 Beryllium Aquatic Life NC 6.5 FW 65 ug/L Outfall 001 Par04 Cadmium Aquatic Life NC 0.8496 FW 4.9840 ug/L Flow, Qw (MGD)3.000 Par05 Chlorides Water Supply NC 250 WS mg/L Receiving Stream Cleghorn Creek Par06 Chlorinated Phenolic Compounds Water Supply NC 1 A ug/L HUC Number 03050105 Par07 Total Phenolic Compounds Aquatic Life NC 300 A ug/L Stream Class Par08 Chromium III Aquatic Life NC 174.7878 FW 1355.8734 ug/L Par09 Chromium VI Aquatic Life NC 11 FW 16 µg/L 7Q10s (cfs)1.860 Par10 Chromium, Total Aquatic Life NC N/A FW N/A µg/L 7Q10w (cfs)2.88 Par11 Copper Aquatic Life NC 11.9019 FW 16.6711 ug/L 30Q2 (cfs)4.02 Par12 Cyanide Aquatic Life NC 5 FW 22 10 ug/L QA (cfs)12.00 Par13 Fluoride Aquatic Life NC 1,800 FW ug/L 1Q10s (cfs)1.56 Par14 Lead Aquatic Life NC 5.0518 FW 131.2383 ug/L Effluent Hardness 44.22 mg/L (Avg)Par15 Mercury Aquatic Life NC 12 FW 0.5 ng/L Upstream Hardness 31.22 mg/L (Avg)Par16 Molybdenum Water Supply NC 160 WS ug/L Combined Hardness Chronic 40.5 mg/L Par17 Nickel Aquatic Life NC 55.9991 FW 508.9010 µg/L Combined Hardness Acute 40.95 mg/L Par18 Nickel Water Supply NC 25.0000 WS N/A µg/L Data Source(s)Par19 Selenium Aquatic Life NC 5 FW 56 ug/L Par20 Silver Aquatic Life NC 0.06 FW 0.6926 ug/L Par21 Zinc Aquatic Life NC 190.7375 FW 190.9633 ug/L Par22 Chloroform Water Supply NC 60 WS µg/L Par23 Par24 Follow directions for data entry. In some cases a comment menu list the available choices or a dropdown menu will provide a list you may select from. Error message occur if data entry does not meet input criteria. To appy a Model IWC %: Once the "Flow, Qw (MGD)" and and the "CHRONIC DILUTION FACTOR = " values are entered, the 7Q10s (cfs) flow is calculated and displayed. Enter the calculated "7Q10s (cfs)" flow value in Table 1. Table 1. Project Information Table 2. Parameters of Concern Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 C; upstream of WS-IV waters CHECK IF HQW OR ORW WQS CHECK TO APPLY MODEL Apply WS Hardness WQC 25909 RPA, input 8/2/2022 REASONABLE POTENTIAL ANALYSIS H1 H2 Effluent Hardness Upstream Hardness Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 1 1/2/2018 40 40 Std Dev.10.1574 1 1/2/2018 40 40 Std Dev.6.4129 2 2/5/2018 44 44 Mean 44.2157 2 2/5/2018 36 36 Mean 31.2195 3 3/5/2018 36 36 C.V.0.2297 3 3/5/2018 32 32 C.V.0.2054 4 4/2/2018 48 48 n 51 4 4/2/2018 32 32 n 41 5 4/30/2018 44 44 10th Per value 35.00 mg/L 5 4/30/2018 12 12 10th Per value 25.00 mg/L 6 6/4/2018 68 68 Average Value =44.22 mg/L 6 7/9/2018 44 44 Average Value =31.22 mg/L 7 7/9/2018 48 48 Max. Value 81.00 mg/L 7 8/6/2018 36 36 Max. Value 48.00 mg/L 8 8/6/2018 48 48 8 9/4/2018 32 32 9 9/4/2018 36 36 9 10/1/2018 48 48 10 10/1/2018 64 64 10 11/5/2018 36 36 11 11/5/2018 56 56 11 1/7/2019 27 27 12 12/3/2018 45 45 12 2/4/2019 28 28 13 1/7/2019 31 31 13 3/4/2019 20 20 14 2/4/2019 40 40 14 5/6/2019 36 36 15 3/4/2019 72 72 15 6/3/2019 32 32 16 4/10/2019 38 38 16 7/8/2019 27 27 17 5/6/2019 55 55 17 8/5/2019 35 35 18 6/3/2019 48 48 18 9/3/2019 30 30 19 7/8/2019 31 31 19 12/2/2019 25 25 20 8/5/2019 35 35 20 1/6/2020 32 32 21 9/3/2019 49 49 21 4/6/2020 40 40 22 10/7/2019 41 41 22 6/1/2020 26 26 23 12/2/2019 35 35 23 8/3/2020 24 24 24 1/6/2020 38 38 24 8/31/2020 30 30 25 2/3/2020 40 40 25 10/12/2020 28 28 26 3/2/2020 44 44 26 11/2/2020 30 30 27 4/7/2020 40 40 27 12/2/2020 28 28 28 5/4/2020 44 44 28 2/1/2021 24 24 29 6/1/2020 81 81 29 3/1/2021 40 40 30 7/6/2020 53 53 30 4/5/2021 26 26 31 8/3/2020 46 46 31 5/3/2021 29 29 32 8/31/2020 42 42 32 6/1/2021 28 28 33 10/12/2020 34 34 33 7/12/2021 31 31 34 11/2/2020 40 40 34 8/2/2021 31 31 35 12/2/2020 32 32 35 9/7/2021 32 32 36 1/4/2021 36 36 36 10/4/2021 30 30 37 2/1/2021 40 40 37 12/6/2021 32 32 38 4/5/2021 40 40 38 1/3/2022 26 26 39 5/3/2021 37 37 39 1/31/2022 33 33 40 6/1/2021 42 42 40 2/28/2022 37 37 41 7/12/2021 57 57 41 4/11/2022 35 35 42 8/2/2021 51 51 42 43 9/7/2021 46 46 43 44 10/4/2021 40 40 44 45 11/1/2021 41 41 45 46 12/6/2021 36 36 46 47 1/3/2022 38 38 47 48 2/28/2022 43 43 48 49 4/11/2022 41 41 49 50 5/2/2022 37 37 50 51 5/31/2022 44 44 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 - 1 - 25909 RPA, data 8/5/2022 REASONABLE POTENTIAL ANALYSIS Par01 & Par02 Arsenic Date Data BDL=1/2DL Results 1 7/8/2019 <5 2.5 Std Dev.0.7500 2 1/28/2020 <2 1 Mean 1.5000 3 2/11/2020 <2 1 C.V. (default)0.6000 4 3/17/2020 <2 1 n 9 5 4/7/2020 <2 1 6 5/5/2020 <2 1 Mult Factor =1.81 7 6/2/2020 <2 1 Max. Value 2.5 ug/L 8 1/10/2017 <5 2.5 Max. Pred Cw 4.5 ug/L 9 4/2/2018 <5 2.5 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 - 2 - 25909 RPA, data 8/5/2022 REASONABLE POTENTIAL ANALYSIS Par04 Par10 Cadmium Chromium, Total Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 1 7/8/2019 <1 0.5 Std Dev.0.1250 1 7/8/2019 <5 2.5 Std Dev.0.0000 2 1/28/2020 <0.5 0.25 Mean 0.3333 2 1/28/2020 <5 2.5 Mean 2.5000 3 2/11/2020 <0.5 0.25 C.V. (default)0.6000 3 2/11/2020 <5 2.5 C.V. (default)0.6000 4 3/17/2020 <0.5 0.25 n 9 4 3/17/2020 <5 2.5 n 9 5 4/7/2020 <0.5 0.25 5 4/7/2020 <5 2.5 6 5/5/2020 <0.5 0.25 Mult Factor =1.81 6 5/5/2020 <5 2.5 Mult Factor =1.81 7 6/2/2020 <0.5 0.25 Max. Value 0.500 ug/L 7 6/2/2020 <5 2.5 Max. Value 2.5 µg/L 8 1/10/2017 <1 0.5 Max. Pred Cw 0.905 ug/L 8 1/10/2017 <5 2.5 Max. Pred Cw 4.5 µg/L 9 4/2/2018 <1 0.5 9 4/2/2018 <5 2.5 10 10 11 11 12 12 13 13 14 14 15 15 16 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 - 3 - 25909 RPA, data 8/5/2022 REASONABLE POTENTIAL ANALYSIS Pa11 Par12 Copper Cyanide Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 1 1/2/2018 <10 5 Std Dev.1.5757 1 7/8/2019 <5 5 Std Dev.0.0000 2 4/2/2018 <10 5 Mean 5.0313 2 1/10/2017 <5 5 Mean 5.00 3 7/9/2018 <10 5 C.V.0.3132 3 4/2/2018 <5 5 C.V. (default)0.6000 4 10/1/2018 <10 5 n 32 4 n 3 5 1/7/2019 <10 5 5 6 4/10/2019 <10 5 Mult Factor =1.10 6 Mult Factor =3.00 7 7/8/2019 <10 5 Max. Value 10.00 ug/L 7 Max. Value 5.0 ug/L 8 10/7/2019 <10 5 Max. Pred Cw 11.00 ug/L 8 Max. Pred Cw 15.0 ug/L 9 1/6/2020 <10 5 9 10 1/28/2020 3 3 10 11 2/11/2020 3 3 11 12 3/17/2020 4 4 12 13 4/6/2020 <10 5 13 14 4/7/2020 3 3 14 15 5/5/2020 5 5 15 16 6/2/2020 2 2 16 17 7/6/2020 <10 5 17 18 10/12/2020 <10 5 18 19 11/2/2020 3 3 19 20 11/9/2020 5 5 20 21 12/2/2020 4 4 21 22 12/7/2020 6 6 22 23 12/28/2020 5 5 23 24 1/4/2021 5 5 24 25 2/1/2021 9 9 25 26 4/5/2021 5 5 26 27 7/12/2021 7 7 27 28 10/4/2021 5 5 28 29 1/3/2022 7 7 29 30 4/11/2022 5 5 30 31 1/10/2017 10 10 31 32 4/2/2018 <10 5 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 - 4 - 25909 RPA, data 8/5/2022 REASONABLE POTENTIAL ANALYSIS Par14 Par16 Lead Molybdenum Date BDL=1/2DL Results Date Data BDL=1/2DL Results 1 7/8/2019 <5 2.5 Std Dev.0.6047 1 1/28/2020 <10 5 Std Dev.0.0000 2 1/28/2020 <2 1 Mean 1.2813 2 2/11/2020 <10 5 Mean 5.0000 3 2/11/2020 <2 1 C.V.0.4719 3 3/17/2020 <10 5 C.V. (default)0.6000 4 3/17/2020 <2 1 n 16 4 4/7/2020 <10 5 n 6 5 4/7/2020 <2 1 5 5/5/2020 <10 5 6 5/5/2020 <2 1 Mult Factor =1.36 6 6/2/2020 <10 5 Mult Factor =2.14 7 6/2/2020 <2 1 Max. Value 2.500 ug/L 7 Max. Value 5.0 ug/L 8 11/2/2020 <2 1 Max. Pred Cw 3.400 ug/L 8 Max. Pred Cw 10.7 ug/L 9 11/9/2020 <2 1 9 10 12/2/2020 <2 1 10 11 12/7/2020 <2 1 11 12 12/28/2020 <2 1 12 13 1/4/2021 <2 1 13 14 2/1/2021 <2 1 14 15 1/10/2017 <5 2.5 15 16 4/2/2018 <5 2.5 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 - 5 - 25909 RPA, data 8/5/2022 REASONABLE POTENTIAL ANALYSIS Par17 & Par18 Par19 Nickel Selenium Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 1 7/8/2019 <10 5 Std Dev.0.0000 1 7/8/2019 <10 5 Std Dev.2.2500 2 1/28/2020 <10 5 Mean 5.0000 2 1/28/2020 <1 0.5 Mean 2.0000 3 2/11/2020 <10 5 C.V. (default)0.6000 3 2/11/2020 <1 0.5 C.V. (default)0.6000 4 3/17/2020 <10 5 n 9 4 3/17/2020 <1 0.5 n 9 5 4/7/2020 <10 5 5 4/7/2020 <1 0.5 6 5/5/2020 <10 5 Mult Factor =1.81 6 5/5/2020 <1 0.5 Mult Factor =1.81 7 6/2/2020 <10 5 Max. Value 5.0 µg/L 7 6/2/2020 <1 0.5 Max. Value 5.0 ug/L 8 1/10/2017 <10 5 Max. Pred Cw 9.1 µg/L 8 1/10/2017 <10 5 Max. Pred Cw 9.1 ug/L 9 4/2/2018 <10 5 9 4/2/2018 <10 5 10 10 11 11 12 12 13 13 14 14 15 15 16 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 Use "PASTE SPECIAL-Values" then "COPY" . Maximum data points = 58 - 6 - 25909 RPA, data 8/5/2022 REASONABLE POTENTIAL ANALYSIS Par20 Par21 Silver Zinc Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 1 7/8/2019 <5 2.5 Std Dev.1.1157 1 1/2/2018 63 63 Std Dev.21.7126 2 11/2/2020 <1 0.5 Mean 0.8925 2 4/2/2018 73 73 Mean 57.3462 3 11/9/2020 <0.25 0.125 C.V.1.2501 3 7/9/2018 52 52 C.V.0.3786 4 12/2/2020 <0.25 0.125 n 10 4 10/1/2018 56 56 n 26 5 12/7/2020 <0.25 0.125 5 1/7/2019 37 37 6 12/28/2020 <0.25 0.125 Mult Factor =2.63 6 4/10/2019 43 43 Mult Factor =1.16 7 1/4/2021 <0.25 0.125 Max. Value 2.500 ug/L 7 7/8/2019 67 67 Max. Value 145.0 ug/L 8 2/1/2021 0.3 0.3 Max. Pred Cw 6.575 ug/L 8 10/7/2019 44 44 Max. Pred Cw 168.2 ug/L 9 1/10/2017 <5 2.5 9 1/6/2020 48 48 10 4/2/2018 <5 2.5 10 1/28/2020 45 45 11 11 2/11/2020 48 48 12 12 3/17/2020 49 49 13 13 4/6/2020 47 47 14 14 4/7/2020 46 46 15 15 5/5/2020 67 67 16 16 6/2/2020 37 37 17 17 7/6/2020 145 145 18 18 10/12/2020 38 38 19 19 1/4/2021 36 36 20 20 4/5/2021 48 48 21 21 7/12/2021 79 79 22 22 10/4/2021 66 66 23 23 1/3/2022 58 58 24 24 4/11/2022 66 66 25 25 1/10/2017 61 61 26 26 4/2/2018 72 72 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 - 7 - 25909 RPA, data 8/5/2022 REASONABLE POTENTIAL ANALYSIS Par22 Par23 Chloroform Nitrate Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 1 1/10/2017 8.3 8.3 Std Dev.2.6514 1 4/1/2019 2.66 2.66 Std Dev.4.0428 2 4/2/2018 10 10 Mean 10.6000 2 7/1/2019 12.3 12.3 Mean 8.3 3 7/8/2019 13.5 13.5 C.V. (default)0.6000 3 7/8/2019 8.8 8.8 C.V.0.5 4 n 3 4 9/30/2019 10 10 n 14 5 5 4/6/2020 3.1 3.1 6 Mult Factor =3.00 6 7/6/2020 9.4 9.4 Mult Factor =1.43 7 Max. Value 13.5 µg/L 7 10/5/2020 10.64 10.64 Max. Value 17 mg/L 8 Max. Pred Cw 40.5 µg/L 8 4/5/2021 7.6 7.6 Max. Pred Cw 25 mg/L 9 9 7/6/2021 6.38 6.38 10 10 10/4/2021 9.62 9.62 11 11 4/4/2022 7.24 7.24 12 12 1/10/2017 17.4 17.4 13 13 4/2/2018 2.16 2.16 14 14 7/8/2019 8.8 8.8 15 15 16 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 Use "PASTE SPECIAL-Values" then "COPY" . Maximum data points = 58 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 - 8 - 25909 RPA, data 8/5/2022 REASONABLE POTENTIAL ANALYSIS Par24 TDS Date Data BDL=1/2DL Results 1 1/10/2017 327 327 Std Dev.71.0422 2 4/2/2018 202 202 Mean 245.0000 3 7/8/2019 206 206 C.V. (default)0.6000 4 n 3 5 6 Mult Factor =3.00 7 Max. Value 327.000000 mg/L 8 Max. Pred Cw 981.000000 mg/L 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL- Values" then "COPY" . Maximum data points = 58 - 9 - 25909 RPA, data 8/5/2022 Rutherfordton WWTP ≥Outfall 001 NC0025909 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 1 MGD MAXIMUM DATA POINTS = 58 Qw (MGD) = 1.0000 WWTP/WTP Class:III COMBINED HARDNESS (mg/L) 1Q10S (cfs) = 1.56 IWC% @ 1Q10S = 49.8392283 Acute = 37.7 mg/L 7Q10S (cfs) = 1.86 IWC% @ 7Q10S = 45.45454545 Chronic = 37.13 mg/L 7Q10W (cfs) = 2.88 IWC% @ 7Q10W = 34.98871332 30Q2 (cfs) = 4.02 IWC% @ 30Q2 = 27.82764811 Avg. Stream Flow, QA (cfs) = 12.00 IW%C @ QA = 11.43911439 Effluent Hard: 0 value > 100 mg/L Receiving Stream:Stream Class:C; upstream of WS-IV watersEffluent Hard Avg = 44.22 mg/L PARAMETER RECOMMENDED ACTION Chronic Applied Standard Acute n # Det.Max Pred Cw Acute (FW):682.2 Arsenic C 150 FW(7Q10s)340 ug/L 9 0 4.5 Chronic (FW):330.0 C.V. (default)Max MDL = 5 Arsenic C 10 HH/WS(Qavg)ug/L Note: n ≤ 9 NO DETECTS Chronic (HH):87.4 Limited data set Max MDL = 5 Acute:9.303 Cadmium NC 0.7955 FW(7Q10s)4.6366 ug/L 9 0 0.905 Note: n ≤ 9 C.V. (default)Chronic:1.750 Limited data set NO DETECTS Max MDL = 1 Acute:2,542.1 Chromium III NC 162.7640 FW(7Q10s)1266.9732 µg/L 0 0 N/A Chronic:358.1 Acute:32.1 Chromium VI NC 11 FW(7Q10s)16 µg/L 0 0 N/A Chronic:24.2 Chromium, Total NC µg/L 9 0 4.5 Note: n ≤ 9 C.V. (default) Limited data set NO DETECTS Max MDL = 5 Acute:30.94 Copper NC 11.0489 FW(7Q10s)15.4200 ug/L 32 19 11.00 Chronic:24.31 No value > Allowable Cw Acute:44.1 Cyanide NC 5 FW(7Q10s)22 10 ug/L 3 0 15.0 Note: n ≤ 9 C.V. (default)Chronic:11.0 Limited data set NO DETECTS Max MDL = 10 Acute:240.084 Lead NC 4.5842 FW(7Q10s)119.6560 ug/L 16 0 3.400 Chronic:10.085 NO DETECTS Max MDL = 5 Acute:NO WQS Molybdenum NC 160 WS(7Q10s)ug/L 6 0 10.7 Note: n ≤ 9 C.V. (default)Chronic:352.0 Limited data set NO DETECTS Max MDL = 10 Acute (FW):952.0 Nickel NC 52.0245 FW(7Q10s)474.4721 µg/L 9 0 9.1 Chronic (FW):114.5 YOU HAVE DESIGNATED THIS RECEIVING STREAM AS WATER SUPPLY PQ L UN I T S TYPE Allowable Cw REASONABLE POTENTIAL RESULTSNC STANDARDS OR EPA CRITERIA Cleghorn Creek HUC 03050105 No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required All non-detects < 1 ug/L and < 0.5 ug/L- No Monitoring required No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required All non-detect < 5 ug/L - No Monitoring required Max reported value = 2.5 No RP , Predicted Max ≥ 50% of Allowable Cw - apply Quarterly Monitoring a: No monitoring required if all Total Chromium samples are < 5 µg/L or Pred. max for Total Cr is < allowable Cw for Cr VI. No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required Page 1 of 2 25909 RPA, rpa 8/2/2022 Rutherfordton WWTP ≥Outfall 001 NC0025909 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 1 MGD Note: n ≤ 9 C.V. (default)Max MDL = 10 Nickel NC 25.0000 WS(7Q10s)µg/L Limited data set NO DETECTS Chronic (WS):55.0 Max MDL = 10 Acute:112.4 Selenium NC 5 FW(7Q10s)56 ug/L 9 0 9.1 Note: n ≤ 9 C.V. (default)Chronic:11.0 Limited data set NO DETECTS Max MDL = 10 Acute:1.205 Silver NC 0.06 FW(7Q10s)0.6007 ug/L 10 1 6.575 Chronic:0.132 5 value(s) > Allowable Cw Acute:357.2 Zinc NC 177.1796 FW(7Q10s)178.0248 ug/L 26 26 168.2 Chronic:389.8 No value > Allowable Cw Acute:NO WQS Chloroform NC 60 WS(7Q10s)µg/L 3 3 40.50000 Note: n ≤ 9 C.V. (default)Chronic:132.000 Limited data set No value > Allowable Cw All non-detect < 10 ug/L and < 1 ug/L - No Monitoring required No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required No RP , Predicted Max ≥ 50% of Allowable Cw - apply Quarterly Monitoring BPJ; apply Monthly Monitoring Page 2 of 2 25909 RPA, rpa 8/2/2022 Rutherfordton WWTP ≥Outfall 001 NC0025909 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 3 MGD MAXIMUM DATA POINTS = 58 Qw (MGD) = 3.0000 WWTP/WTP Class:III COMBINED HARDNESS (mg/L) 1Q10S (cfs) = 1.56 IWC% @ 1Q10S = 74.87922705 Acute = 40.95 mg/L 7Q10S (cfs) = 1.86 IWC% @ 7Q10S = 71.42857143 Chronic = 40.5 mg/L 7Q10W (cfs) = 2.88 IWC% @ 7Q10W = 61.75298805 30Q2 (cfs) = 4.02 IWC% @ 30Q2 = 53.63321799 Avg. Stream Flow, QA (cfs) = 12.00 IW%C @ QA = 27.92792793 Effluent Hard: 0 value > 100 mg/L Receiving Stream:Stream Class:C; upstream of WS-IV watersEffluent Hard Avg = 44.22 mg/L PARAMETER RECOMMENDED ACTION Chronic Applied Standard Acute n # Det.Max Pred Cw Acute (FW):454.1 Arsenic C 150 FW(7Q10s)340 ug/L 9 0 4.5 Chronic (FW):210.0 C.V. (default)Max MDL = 5 Arsenic C 10 HH/WS(Qavg)ug/L Note: n ≤ 9 NO DETECTS Chronic (HH):35.8 Limited data set Max MDL = 5 Acute:6.656 Cadmium NC 0.8496 FW(7Q10s)4.9840 ug/L 9 0 0.905 Note: n ≤ 9 C.V. (default)Chronic:1.189 Limited data set NO DETECTS Max MDL = 1 Acute:1,810.7 Chromium III NC 174.7878 FW(7Q10s)1355.8734 µg/L 0 0 N/A Chronic:244.7 Acute:21.4 Chromium VI NC 11 FW(7Q10s)16 µg/L 0 0 N/A Chronic:15.4 Chromium, Total NC µg/L 9 0 4.5 Note: n ≤ 9 C.V. (default) Limited data set NO DETECTS Max MDL = 5 Acute:22.26 Copper NC 11.9019 FW(7Q10s)16.6711 ug/L 32 19 11.00 Chronic:16.66 No value > Allowable Cw Acute:29.4 Cyanide NC 5 FW(7Q10s)22 10 ug/L 3 0 15.0 Note: n ≤ 9 C.V. (default)Chronic:7.0 Limited data set NO DETECTS Max MDL = 10 Acute:175.267 Lead NC 5.0518 FW(7Q10s)131.2383 ug/L 16 0 3.400 Chronic:7.072 NO DETECTS Max MDL = 5 Acute:NO WQS Molybdenum NC 160 WS(7Q10s)ug/L 6 0 10.7 Note: n ≤ 9 C.V. (default)Chronic:224.0 Limited data set NO DETECTS Max MDL = 10 Acute (FW):679.6 Nickel NC 55.9991 FW(7Q10s)508.9010 µg/L 9 0 9.1 Chronic (FW):78.4 YOU HAVE DESIGNATED THIS RECEIVING STREAM AS WATER SUPPLY PQ L UN I T S TYPE Allowable Cw REASONABLE POTENTIAL RESULTSNC STANDARDS OR EPA CRITERIA Cleghorn Creek HUC 03050105 No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required All non-detects < 1 ug/L and < 0.5 ug/L- No Monitoring required No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required All non-detect < 5 ug/L - No Monitoring required Max reported value = 2.5 No RP , Predicted Max ≥ 50% of Allowable Cw - apply Quarterly Monitoring a: No monitoring required if all Total Chromium samples are < 5 µg/L or Pred. max for Total Cr is < allowable Cw for Cr VI. No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required Page 1 of 2 25909 RPA, rpa 8/2/2022 Rutherfordton WWTP ≥Outfall 001 NC0025909 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 3 MGD Note: n ≤ 9 C.V. (default)Max MDL = 10 Nickel NC 25.0000 WS(7Q10s)µg/L Limited data set NO DETECTS Chronic (WS):35.0 Max MDL = 10 Acute:74.8 Selenium NC 5 FW(7Q10s)56 ug/L 9 0 9.1 Note: n ≤ 9 C.V. (default)Chronic:7.0 Limited data set NO DETECTS Max MDL = 10 Acute:0.925 Silver NC 0.06 FW(7Q10s)0.6926 ug/L 10 1 6.575 Chronic:0.084 10 value(s) > Allowable Cw Acute:255.0 Zinc NC 190.7375 FW(7Q10s)190.9633 ug/L 26 26 168.2 Chronic:267.0 No value > Allowable Cw Acute:NO WQS Chloroform NC 60 WS(7Q10s)µg/L 3 3 40.50000 Note: n ≤ 9 C.V. (default)Chronic:84.000 Limited data set No value > Allowable Cw All non-detect < 10 ug/L and < 1 ug/L - No Monitoring required No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required No RP , Predicted Max ≥ 50% of Allowable Cw - apply Quarterly Monitoring BPJ; apply Monthly Monitoring Page 2 of 2 25909 RPA, rpa 8/2/2022 Date Upstream Downstream Date Upstream Downstream 1/2/2018 107 127 8/7/2018 95.7 113 1/8/2018 88.4 103 8/8/2018 95.9 110 1/16/2018 90.5 97.5 8/13/2018 97.4 110 1/22/2018 96.8 119 8/14/2018 100 117 1/29/2018 84.1 95.4 8/15/2018 99.9 116 2/5/2018 83 89.3 8/20/2018 92.6 105 2/12/2018 77.9 83.8 8/21/2018 96.1 109 2/19/2018 90 106 8/22/2018 89.2 110 2/26/2018 92.8 107 8/27/2018 97.4 115 3/5/2018 93.8 102 8/28/2018 98 119 3/12/2018 73.5 88.5 8/29/2018 98.3 117 3/19/2018 89.1 104 9/4/2018 96.4 115 3/26/2018 90.7 103 9/5/2018 102 121 4/2/2018 90.9 103 9/6/2018 95.5 122 4/9/2018 89.6 103 9/10/2018 73.7 92.5 4/16/2018 61.1 65.1 9/11/2018 80.3 98.5 4/23/2018 88.8 98.8 9/12/2018 92.7 109 4/30/2018 87.7 97.8 9/18/2018 92.9 117 5/7/2018 91.7 107 9/19/2018 96.8 116 5/14/2018 90 101 9/20/2018 97.7 120 5/21/2018 91.4 104 9/24/2018 97.5 126 5/29/2018 77 91.3 9/25/2018 96.5 113 5/30/2018 70.6 76.3 9/26/2018 96.3 119 5/31/2018 82.2 90.1 10/1/2018 92.3 108 6/4/2018 86.6 95.7 10/8/2018 96.8 125 6/5/2018 91.5 97.4 10/15/2018 93.4 110 6/6/2018 92 104 10/22/2018 95 210 6/11/2018 80.8 107 10/29/2018 95.4 103 6/12/2018 77.7 86.7 11/5/2018 88 109 6/13/2018 91.2 106 11/12/2018 95.3 114 6/18/2018 94.2 113 11/19/2018 98.3 97.1 6/19/2018 95.5 106 11/26/2018 94.7 93.4 6/20/2018 95.3 114 12/3/2018 90.3 102 6/25/2018 95.5 112 12/11/2018 105 109 6/26/2018 88.1 99.7 12/17/2018 90.5 92.3 6/27/2018 80.8 87.9 12/26/2018 89 90.6 7/2/2018 86 107 12/31/2018 80.9 83.8 7/3/2018 97.6 111 1/7/2019 85.4 89.2 7/5/2018 99.2 120 1/14/2019 107 98.1 7/9/2018 96.2 109 1/22/2019 81.4 85.5 7/10/2018 96.5 98.6 1/28/2019 85.1 90.2 7/11/2018 96.8 111 2/4/2019 84.2 94.9 7/16/2018 97.8 119 2/11/2019 78.2 84.1 7/17/2018 99.3 117 2/18/2019 57.7 60.9 7/18/2018 99.4 122 2/25/2019 76.4 69.6 7/23/2018 91.9 111 3/4/2019 77.6 81.1 7/24/2018 89 101 3/11/2019 79.5 85.2 7/25/2018 74 84.1 3/18/2019 81.2 86.1 7/30/2018 102 124 3/25/2019 80.3 86.1 7/31/2018 98.9 127 4/1/2019 75.8 84.9 8/1/2018 94.9 119 4/8/2019 75.9 86.6 8/6/2018 94.7 107 4/15/2019 80.4 84.3 4/22/2019 115 91.3 9/23/2019 252 111 NC0025909 Instream Conductivity Analysis [umhos/cm] 4/29/2019 82.3 91.1 9/24/2019 94.3 100 5/6/2019 86.6 93.7 9/25/2019 86.2 97.1 5/13/2019 81.1 88.4 9/30/2019 84.8 110 5/20/2019 84.7 94.6 10/7/2019 84.2 102 5/28/2019 85.1 101 10/14/2019 78.2 99.8 6/3/2019 83.1 99 10/21/2019 87.7 105 6/4/2019 85.7 93.1 10/28/2019 862 104 6/5/2019 85.3 97.9 11/5/2019 86.9 97.9 6/10/2019 61.6 65.4 11/11/2019 119 95.5 6/11/2019 73.6 77.1 11/18/2019 85 97 6/12/2019 112 84.2 11/25/2019 88 90 6/17/2019 84.6 99 12/2/2019 85 94 6/18/2019 241 75.3 12/9/2019 84 92 6/19/2019 82.3 89.7 12/16/2019 81 91 6/24/2019 84 95.4 12/23/2019 51 62 6/25/2019 110 85.9 12/30/2019 76 86 6/26/2019 83.7 96.4 1/6/2020 80 87 7/1/2019 89.6 103 1/13/2020 69 70 7/2/2019 84.3 96.8 1/21/2020 93 92 7/3/2019 151 107 1/27/2020 91 97 7/8/2019 84.6 96.3 2/3/2020 84 88 7/9/2019 86 99.3 2/10/2020 129 90 7/10/2019 843 95.8 2/17/2020 84 93 7/15/2019 87.3 96 2/24/2020 81 87 7/16/2019 86.9 99.5 3/2/2020 105 86 7/17/2019 86.3 106 3/9/2020 106 88 7/22/2019 87.5 99 3/16/2020 82 88 7/23/2019 74 84.2 3/23/2020 79 86 7/24/2019 82.2 96.8 4/1/2020 81 86 7/29/2019 89.5 104 4/6/2020 84 91 7/30/2019 87.2 97.5 4/13/2020 154 51 7/31/2019 94 105 4/20/2020 74 69 8/5/2019 82.4 104 4/27/2020 83 86 8/6/2019 83.4 99.4 5/4/2020 96 86 8/7/2019 83.8 97.1 5/11/2020 97 98 8/12/2019 85.8 110 5/18/2020 95 97 8/13/2019 86.3 104 5/26/2020 105 83 8/14/2019 71.3 81.4 6/1/2020 77 84 8/19/2019 90.3 102 6/2/2020 80 86 8/20/2019 92 112 6/3/2020 80 86 8/21/2019 104 107 6/8/2020 87 91 8/26/2019 86.8 92.8 6/9/2020 89 92 8/27/2019 308 114 6/10/2020 90 104 8/28/2019 88.4 110 6/15/2020 79 89 9/3/2019 84.8 107 6/16/2020 92 85 9/4/2019 89.8 107 6/17/2020 89 89 9/5/2019 92 108 6/22/2020 102 92 9/9/2019 87.9 104 6/23/2020 81 99 9/10/2019 112 109 6/24/2020 84 91 9/11/2019 248 105 6/29/2020 103 102 9/16/2019 87.1 965 6/30/2020 114 95 9/17/2019 85.8 93.5 7/1/2020 90 88 9/18/2019 107 103 7/6/2020 84 97 7/7/2020 79 123 1/25/2021 81 92 7/8/2020 74 82 2/1/2021 79 86 7/13/2020 96 97 2/8/2021 93 94 7/14/2020 95 95 2/15/2021 77 79 7/15/2020 84 92 2/22/2021 107 90 7/20/2020 88 91 3/1/2021 90 91 7/21/2020 77 88 3/8/2021 81 89 7/22/2020 79 83 3/15/2021 80 90 7/27/2020 84 94 3/22/2021 87 79 7/28/2020 84 93 3/29/2021 87 91 7/29/2020 85 93 4/5/2021 76 85 8/3/2020 75 62 4/12/2021 80 88 8/4/2020 89 88 4/19/2021 79 84 8/5/2020 88 100 4/26/2021 94 83 8/10/2020 97 92 5/3/2021 97 88 8/11/2020 96 88 5/10/2021 80 86 8/12/2020 91 89 5/17/2021 82 88 8/17/2020 87 83 5/24/2021 81 91 8/18/2020 87 88 6/1/2021 86 92 8/19/2020 93 89 6/2/2021 81 90 8/24/2020 89 91 6/3/2021 81 92 8/25/2020 91 93 6/7/2021 95 93 8/26/2020 94 93 6/8/2021 99 88 8/31/2020 80 72 6/9/2021 102 91 9/1/2020 98 94 6/14/2021 81 97 9/2/2020 103 94 6/15/2021 90 91 9/8/2020 79 108 6/16/2021 84 90 9/9/2020 94 95 6/21/2021 94 94 9/10/2020 115 101 6/22/2021 107 95 9/14/2020 109 94 6/23/2021 105 95 9/15/2020 96 93 6/28/2021 100 100 9/16/2020 107 100 6/29/2021 105 101 9/21/2020 95 88 6/30/2021 98 99 9/22/2020 99 97 7/6/2021 87 103 9/23/2020 108 97 7/7/2021 105 104 9/28/2020 74 89 7/8/2021 99 99 9/29/2020 81 87 7/12/2021 146 97 9/30/2020 81 86 7/13/2021 98 88 10/5/2020 93 87 7/14/2021 109 98 10/12/2020 80 80 7/19/2021 80 90 10/19/2020 102 92 7/20/2021 96 95 10/26/2020 98 110 7/21/2021 96 54 11/2/2020 88 90 7/26/2021 100 94 11/9/2020 105 92 7/27/2021 110 90 11/16/2020 88 85 7/28/2021 106 88 11/23/2020 92 98 8/2/2021 98 99 12/2/2020 88 50 8/3/2021 61 54 12/7/2020 81 91 8/4/2021 100 94 12/14/2020 195 50 8/9/2021 111 95 12/21/2020 91 85 8/10/2021 83 98 12/28/2020 88 84 8/11/2021 95 94 1/4/2021 84 81 8/16/2021 81 100 1/11/2021 78 86 8/17/2021 50 56 1/19/2021 78 85 8/18/2021 70 78 8/23/2021 105 97 1/3/2022 89 43 8/24/2021 101 97 1/10/2022 96 87 8/25/2021 98 94 1/18/2022 324 298 8/30/2021 102 130 1/24/2022 108 102 8/31/2021 86 107 1/31/2022 106 101 9/1/2021 112 80 2/7/2022 96 94 9/7/2021 100 105 2/14/2022 150 116 9/8/2021 173 107 2/21/2022 100 106 9/9/2021 111 184 2/28/2022 104 95 9/13/2021 203 108 3/7/2022 87 99 9/14/2021 108 103 3/14/2022 102 100 9/15/2021 205 106 3/21/2022 89 95 9/20/2021 211 100 3/28/2022 93 97 9/21/2021 89 91 4/4/2022 84 101 9/22/2021 92 88 4/11/2022 89 96 9/27/2021 114 100 4/18/2022 43 45 9/28/2021 246 104 4/25/2022 95 95 9/29/2021 276 113 5/2/2022 92 104 10/4/2021 111 99 5/9/2022 98 106 10/11/2021 110 107 5/16/2022 103 105 10/18/2021 104 97 5/23/2022 94 102 10/25/2021 120 102 5/31/2022 118 102 11/1/2021 98 97 Average 100.2 99.3 11/8/2021 108 102 Max 862 965 11/15/2021 92 96 Min 43 43 11/22/2021 140 107 11/29/2021 114 97 12/6/2021 72 105 12/13/2021 96 103 12/20/2021 147 111 12/28/2021 106 99 Date Upstream Downstream Date Upstream Downstream 1/2/2018 7.7 8.4 8/8/2018 5.4 5.5 1/8/2018 12.5 11.9 8/13/2018 5.2 5.4 1/16/2018 11.9 10.7 8/14/2018 5.7 5.5 1/22/2018 7.7 9.6 8/15/2018 5.3 5.8 1/29/2018 11.3 11.3 8/20/2018 5.5 5.1 2/5/2018 10.1 10.3 8/21/2018 5.5 4.7 2/12/2018 7.4 7.7 8/22/2018 5.1 4.9 2/19/2018 7.7 8.1 8/27/2018 5.6 5.7 2/26/2018 7.1 7.2 8/28/2018 5.7 5.5 3/5/2018 10.6 10 8/29/2018 5.4 5.4 3/12/2018 10.4 9.5 9/4/2018 5.5 5.4 3/19/2018 7.8 8.1 9/5/2018 5.7 5.2 3/26/2018 8.8 9 9/6/2018 4.6 4.7 4/2/2018 7.4 7.7 9/10/2018 4.9 5.3 4/9/2018 6.9 5.5 9/11/2018 6.4 6 4/16/2018 5.4 5.6 9/12/2018 5.4 6.4 4/23/2018 6.6 6.3 9/18/2018 5.4 5.7 4/30/2018 8.4 9.4 9/19/2018 6.3 6.4 5/7/2018 7.2 7.9 9/20/2018 5.4 5.8 5/14/2018 6.4 5.9 9/24/2018 7 7.7 5/21/2018 6 5.4 9/25/2018 7.8 7.7 5/29/2018 5.8 5.4 9/26/2018 6.8 6.9 5/30/2018 4.4 4.2 10/1/2018 6.6 6.5 5/31/2018 6.1 6.2 10/8/2018 6.3 7.1 6/4/2018 6.7 6.3 10/15/2018 6.2 7.3 6/5/2018 7.4 6.7 10/22/2018 6.8 6.2 6/6/2018 7.3 7 10/29/2018 8 8.5 6/11/2018 5.7 5.9 11/5/2018 7.4 7.6 6/12/2018 6.1 5.9 11/12/2018 9.3 9 6/13/2018 6.6 6.3 11/19/2018 8.2 6.9 6/18/2018 5.5 5.7 11/26/2018 7.8 7.4 6/19/2018 5.8 5.5 12/3/2018 8.6 8.1 6/20/2018 4.7 4.9 12/11/2018 10.5 9.8 6/25/2018 6.1 5.5 12/17/2018 8.9 8.4 6/26/2018 5.5 6.2 12/26/2018 9.4 9.5 6/27/2018 6.2 5.4 12/31/2018 7.4 7.8 7/2/2018 5.4 5.9 1/7/2019 8.7 9 7/3/2018 5.3 6 1/14/2019 9.5 8.7 7/5/2018 4.9 6.5 1/22/2019 9.9 9.1 7/9/2018 6.8 6.9 1/28/2019 9.6 9.7 7/10/2018 6.3 6.5 2/4/2019 10.7 11.2 7/11/2018 5.3 6.1 2/11/2019 8 8 7/16/2018 5.6 5.3 2/18/2019 8.3 8.7 7/17/2018 5.1 5.4 2/25/2019 9.2 9.5 7/18/2018 5.1 5.2 3/4/2019 8.7 9.2 7/23/2018 6.4 6.1 3/11/2019 9.5 9.6 7/24/2018 6.3 6.5 3/18/2019 8.2 9.5 7/25/2018 5.8 5.9 3/25/2019 8.1 8.2 7/30/2018 5.6 5.4 4/1/2019 8.9 8.9 7/31/2018 5.7 5.5 4/8/2019 7.1 7 8/1/2018 5.1 5.5 4/15/2019 7.1 7.3 8/6/2018 5.2 5.2 4/22/2019 7.5 7.6 8/7/2018 5.1 5.3 4/29/2019 7.5 7.1 NC0025909 Instream Dissolved Oxygen Analysis [mg/L] 5/6/2019 7 6.7 9/30/2019 5.9 6.5 5/13/2019 6.3 6.4 10/7/2019 6.5 6.2 5/20/2019 5.9 6.2 10/14/2019 6.9 6.6 5/28/2019 6.3 6.4 10/21/2019 7.3 6.9 6/3/2019 6.9 6.9 10/28/2019 7.5 7.7 6/4/2019 6.5 6.7 11/5/2019 9 8.9 6/5/2019 6.1 6.4 11/11/2019 8.9 9.4 6/10/2019 6.5 6.7 11/18/2019 8.2 7.8 6/11/2019 6.3 6.7 11/25/2019 9.3 8.3 6/12/2019 7.1 7.2 12/2/2019 7.9 7.7 6/17/2019 6.1 6.4 12/9/2019 8.9 8.9 6/18/2019 5.5 6.6 12/16/2019 9 8 6/19/2019 6.4 6.5 12/23/2019 8.3 8.8 6/24/2019 7 6.3 12/30/2019 7.3 7.6 6/25/2019 6.3 6.5 1/6/2020 9.5 9.6 6/26/2019 6.8 6.9 1/13/2020 8.2 7.7 7/1/2019 6 6.1 1/21/2020 9.3 10.4 7/2/2019 5.9 6.3 1/27/2020 9.6 8.5 7/3/2019 6.5 5.9 2/3/2020 10.4 8.8 7/8/2019 6.1 5.6 2/10/2020 9.1 8.7 7/9/2019 5.4 5.6 2/17/2020 8.6 8.6 7/10/2019 6.4 5.8 2/24/2020 8.6 8.4 7/15/2019 5.6 5.9 3/2/2020 9.1 9.2 7/16/2019 5.6 5.8 3/9/2020 10.2 9.3 7/17/2019 5.7 5.1 3/16/2020 8.7 8.3 7/22/2019 5.4 6.6 3/23/2020 8.5 8.7 7/23/2019 5.6 6 4/1/2020 8.8 8.2 7/24/2019 7.2 7.6 4/6/2020 7.6 7.5 7/29/2019 6.5 6.3 4/13/2020 6.4 7.5 7/30/2019 5.9 6.2 4/20/2020 8 7.6 7/31/2019 5.9 6 4/27/2020 8.5 8.6 8/5/2019 6.2 6.6 5/4/2020 7.6 7.6 8/6/2019 6.8 6.7 5/11/2020 8.4 8.1 8/7/2019 6.1 6.9 5/18/2020 7 6.7 8/12/2019 6.2 5.6 5/26/2020 7 6.7 8/13/2019 5.7 6.1 6/1/2020 7.3 7.2 8/14/2019 5.1 5.2 6/2/2020 7.1 7 8/19/2019 6 6.3 6/3/2020 6.9 7.2 8/20/2019 5.8 5.8 6/8/2020 6.4 6 8/21/2019 6 5.9 6/9/2020 6.7 6.3 8/26/2019 6.6 7 6/10/2020 6 6.1 8/27/2019 6.3 6.3 6/15/2020 7.5 6.3 8/28/2019 6.2 6.3 6/16/2020 7.2 7.4 9/3/2019 5.8 6 6/17/2020 7.2 6.8 9/4/2019 5.9 6.2 6/22/2020 6.5 6.1 9/5/2019 5.2 6 6/23/2020 6.5 6.3 9/9/2019 5.7 6.1 6/24/2020 6.9 6.1 9/10/2019 5.8 5.9 6/29/2020 6.2 5.7 9/11/2019 5.3 6.1 6/30/2020 6.8 6.2 9/16/2019 5.9 5.9 7/1/2020 5.4 5.6 9/17/2019 5.9 6.2 7/6/2020 6.1 6.4 9/18/2019 4.6 5.7 7/7/2020 6.2 5.9 9/23/2019 4.8 5.8 7/8/2020 6 6.7 9/24/2019 6.4 6.7 7/13/2020 6.7 5.3 9/25/2019 5.6 6.2 7/14/2020 6.6 6.3 7/15/2020 5.9 5.6 3/1/2021 7.7 7.7 7/20/2020 5.6 5.8 3/8/2021 9.1 9.2 7/21/2020 5.8 5.6 3/15/2021 7.8 7.9 7/22/2020 5.6 6.4 3/22/2021 8.2 8.2 7/27/2020 5.6 5.4 3/29/2021 8.8 7.8 7/28/2020 5.8 5.5 4/5/2021 8.5 8.2 7/29/2020 5.5 6 4/12/2021 7.9 8.2 8/3/2020 6.3 6 4/19/2021 7.9 7.3 8/4/2020 6.2 6.2 4/26/2021 7.9 8 8/5/2020 5.4 6 5/3/2021 7.2 6.9 8/10/2020 6.4 6.1 5/10/2021 7 7 8/11/2020 6.2 5.8 5/17/2021 7.2 7.6 8/12/2020 5.6 5.6 5/24/2021 7.1 6.9 8/17/2020 5.9 6.2 6/1/2021 7.1 7 8/18/2020 7.1 6.4 6/2/2021 6.5 6.7 8/19/2020 5.9 6.2 6/3/2021 7.2 7 8/24/2020 6.1 5.9 6/7/2021 6.6 6 8/25/2020 6.1 5.9 6/8/2021 6.2 6.3 8/26/2020 5.7 6 6/9/2021 5.7 6 8/31/2020 5.8 5.8 6/14/2021 5.7 5.6 9/1/2020 5.7 5.7 6/15/2021 6.6 6.6 9/2/2020 5.8 5.7 6/16/2021 6.5 6.2 9/8/2020 6.8 6.8 6/21/2021 6.5 6.3 9/9/2020 6 5.6 6/22/2021 5.9 5.5 9/10/2020 5.9 5.9 6/23/2021 6.4 6.6 9/14/2020 6.3 6.4 6/28/2021 6.1 6.2 9/15/2020 6.2 6.3 6/29/2021 6.1 5.5 9/16/2020 6.8 6.5 6/30/2021 5.7 6.3 9/21/2020 7.9 7.5 7/6/2021 5.8 5.7 9/22/2020 7.9 7.8 7/7/2021 6.6 6 9/23/2020 7.5 7.4 7/8/2021 6.2 5.3 9/28/2020 6.7 6.5 7/12/2021 6.2 6.2 9/29/2020 6.5 6.3 7/13/2021 6.3 6.2 9/30/2020 7.3 7.5 7/14/2021 6.1 7.2 10/5/2020 7.9 7.4 7/19/2021 5.2 5 10/12/2020 6.8 6.7 7/20/2021 5.6 5.9 10/19/2020 8.2 7.6 7/21/2021 6.8 6 10/26/2020 7 6.6 7/26/2021 5.6 5.6 11/2/2020 9.1 8.3 7/27/2021 6.5 5.9 11/9/2020 7.8 7.4 7/28/2021 5.9 5.7 11/16/2020 8.7 8.7 8/2/2021 6.2 5.4 11/23/2020 7.9 7.9 8/3/2021 6.1 6.4 12/2/2020 9.3 9.3 8/4/2021 6 6 12/7/2020 9.2 9.3 8/9/2021 6.1 5.7 12/14/2020 7.4 8.4 8/10/2021 5.7 5.4 12/21/2020 9 9.3 8/11/2021 5.8 5.9 12/28/2020 9.7 8.9 8/16/2021 5.4 5.7 1/4/2021 9.6 9 8/17/2021 5.8 5.9 1/11/2021 10 9.3 8/18/2021 6 6 1/19/2021 10.4 10.3 8/23/2021 5.3 5 1/25/2021 8.8 8.5 8/24/2021 5.86 5.47 2/1/2021 9.3 9.4 8/25/2021 5.3 5.1 2/8/2021 9.2 8.9 8/30/2021 5.7 5.7 2/15/2021 9.1 9 8/31/2021 5.4 5.5 2/22/2021 9.1 9.2 9/1/2021 3.4 3.8 9/7/2021 6.1 5.36 9/8/2021 5.77 5.43 9/9/2021 5.33 5.4 9/13/2021 4.98 5.21 9/14/2021 6.3 6.4 9/15/2021 5.6 6.36 9/20/2021 6.3 6.1 9/21/2021 6.1 6.3 9/22/2021 5.57 4.6 9/27/2021 7.2 8.1 9/28/2021 7.2 7.4 9/29/2021 6.8 7.1 10/4/2021 6.4 5.9 10/11/2021 6.3 6.6 10/18/2021 8.1 8.2 10/25/2021 6.4 6.3 11/1/2021 6.3 6.6 11/8/2021 7.6 7.3 11/15/2021 9.5 9.9 11/22/2021 7.8 7.8 11/29/2021 9.3 9.6 12/6/2021 8.9 9 12/13/2021 9.7 10.3 12/20/2021 9.4 9.8 12/28/2021 10 10.3 1/3/2022 9.1 8.7 1/10/2022 10.3 10.5 1/18/2022 13.8 14.2 1/24/2022 12.8 12.3 1/31/2022 12.9 12.5 2/7/2022 12 12.6 2/14/2022 12 11.7 2/21/2022 9.8 10.5 2/28/2022 10.5 10.7 3/7/2022 8.4 8.3 3/14/2022 11.2 11 3/21/2022 10.2 10.5 3/28/2022 10.9 10.6 4/4/2022 10.1 10.4 4/11/2022 8.6 9.4 4/18/2022 8.8 9.1 4/25/2022 8 8 5/2/2022 8.2 8.4 5/9/2022 8.6 8.7 5/16/2022 7.9 8 5/23/2022 7.3 6.9 5/31/2022 7.1 7.2 Average 7.1 7.1 Max 13.8 14.2 Min 3.4 3.8 Date Upstream Downstream Date Upstream Downstream 1/2/2018 2 2 8/7/2018 21 22 1/8/2018 5 3 8/8/2018 21 21 1/16/2018 4 3 8/13/2018 20 21 1/22/2018 7 7 8/14/2018 20 21 1/29/2018 11 11 8/15/2018 20 20 2/5/2018 7 7 8/20/2018 21 22 2/12/2018 13 14 8/21/2018 21 22 2/19/2018 12 12 8/22/2018 20 21 2/26/2018 15 14 8/27/2018 20 20 3/5/2018 8 8 8/28/2018 20 21 3/12/2018 9 9 8/29/2018 20 21 3/19/2018 13 13 9/4/2018 22 21 3/26/2018 9 9 9/5/2018 21 22 4/2/2018 13 13 9/6/2018 21 22 4/9/2018 11 11 9/10/2018 21 22 4/16/2018 12 12 9/11/2018 21 22 4/23/2018 14 14 9/12/2018 21 22 4/30/2018 11 10 9/18/2018 21 22 5/7/2018 15 15 9/19/2018 19 20 5/14/2018 18 18 9/20/2018 20 21 5/21/2018 19 18 9/24/2018 20 21 5/29/2018 20 20 9/25/2018 20 20 5/30/2018 20 20 9/26/2018 19 20 5/31/2018 19 19 10/1/2018 20 20 6/4/2018 19 19 10/8/2018 20 20 6/5/2018 18 17 10/15/2018 17 17 6/6/2018 18 17 10/22/2018 10 11 6/11/2018 20 20 10/29/2018 13 13 6/12/2018 20 19 11/5/2018 15 14 6/13/2018 20 19 11/12/2018 10 10 6/18/2018 21 21 11/19/2018 10 10 6/19/2018 21 21 11/26/2018 12 12 6/20/2018 21 21 12/3/2018 10 11 6/25/2018 21 21 12/11/2018 6 7 6/26/2018 21 21 12/17/2018 9 9 6/27/2018 20 20 12/26/2018 6 6 7/2/2018 21 22 12/31/2018 12 12 7/3/2018 21 22 1/7/2019 10 10 7/5/2018 21 22 1/14/2019 9 9 7/9/2018 18 19 1/22/2019 5 5 7/10/2018 19 20 1/28/2019 7 7 7/11/2018 20 21 2/4/2019 8 8 7/16/2018 21 22 2/11/2019 9 9 7/17/2018 21 22 2/18/2019 10 10 7/18/2018 21 22 2/25/2019 9 10 7/23/2018 19 20 3/4/2019 10 11 7/24/2018 20 21 3/11/2019 12 12 7/25/2018 20 21 3/18/2019 8 8 7/30/2018 21 22 3/25/2019 11 11 7/31/2018 21 22 4/1/2019 9 8 8/1/2018 20 21 4/8/2019 15 15 8/6/2018 21 22 4/15/2019 13 14 4/22/2019 11 11 9/23/2019 18 17 NC0025909 Instream Temperature Analysis [degC] 4/29/2019 15 15 9/24/2019 18 19 5/6/2019 16 16 9/25/2019 18 18 5/13/2019 17 18 9/30/2019 20 20 5/20/2019 18 19 10/7/2019 18 18 5/28/2019 18 19 10/14/2019 16 17 6/3/2019 18 18 10/21/2019 16 15 6/4/2019 17 17 10/28/2019 14 14 6/5/2019 18 19 11/5/2019 9 10 6/10/2019 19 20 11/11/2019 9 9 6/11/2019 18 19 11/18/2019 11 11 6/12/2019 17 17 11/25/2019 8 8 6/17/2019 19 20 12/2/2019 10 11 6/18/2019 20 20 12/9/2019 10 10 6/19/2019 19 20 12/16/2019 11 12 6/24/2019 20 20 12/23/2019 11 11 6/25/2019 20 20 12/30/2019 15 15 6/26/2019 19 19 1/6/2020 7 7 7/1/2019 21 21 1/13/2020 13 13 7/2/2019 20 20 1/21/2020 6 5 7/3/2019 20 21 1/27/2020 8 8 7/8/2019 21 21 2/3/2020 8 8 7/9/2019 21 22 2/10/2020 8 8 7/10/2019 21 22 2/17/2020 8 8 7/15/2019 20 21 2/24/2020 11 10 7/16/2019 21 21 3/2/2020 9 9 7/17/2019 20 21 3/9/2020 7 8 7/22/2019 21 22 3/16/2020 12 12 7/23/2019 21 22 3/23/2020 13 13 7/24/2019 20 19 4/1/2020 11 11 7/29/2019 19 20 4/6/2020 13 13 7/30/2019 20 20 4/13/2020 16 16 7/31/2019 20 20 4/20/2020 14 14 8/5/2019 20 20 4/27/2020 12 12 8/6/2019 19 20 5/4/2020 17 17 8/7/2019 20 20 5/11/2020 12 12 8/12/2019 21 21 5/18/2020 17 17 8/13/2019 21 21 5/26/2020 18 18 8/14/2019 21 22 6/1/2020 16 16 8/19/2019 20 21 6/2/2020 16 17 8/20/2019 20 21 6/3/2020 18 18 8/21/2019 20 21 6/8/2020 19 20 8/26/2019 19 19 6/9/2020 19 20 8/27/2019 19 20 6/10/2020 20 21 8/28/2019 19 20 6/15/2020 17 17 9/3/2019 19 19 6/16/2020 16 17 9/4/2019 20 20 6/17/2020 16 17 9/5/2019 20 21 6/22/2020 19 17 9/9/2019 19 19 6/23/2020 19 19 9/10/2019 20 20 6/24/2020 19 19 9/11/2019 21 20 6/29/2020 22 21 9/16/2019 19 19 6/30/2020 21 21 9/17/2019 19 20 7/1/2020 20 20 9/18/2019 20 21 7/6/2020 21 21 7/7/2020 21 21 1/25/2021 9 9 7/8/2020 21 21 2/1/2021 8 8 7/13/2020 21 21 2/8/2021 6 6 7/14/2020 21 21 2/15/2021 9 9 7/15/2020 22 22 2/22/2021 9 8 7/20/2020 21 21 3/1/2021 14 14 7/21/2020 20 21 3/8/2021 7 6 7/22/2020 21 21 3/15/2021 13 13 7/27/2020 20 21 3/22/2021 11 10 7/28/2020 20 21 3/29/2021 10 10 7/29/2020 21 21 4/5/2021 11 11 8/3/2020 21 22 4/12/2021 12 12 8/4/2020 19 20 4/19/2021 13 12 8/5/2020 20 20 4/26/2021 12 12 8/10/2020 20 20 5/3/2021 17 17 8/11/2020 20 21 5/10/2021 16 17 8/12/2020 20 21 5/17/2021 15 15 8/17/2020 20 20 5/24/2021 17 18 8/18/2020 19 19 6/1/2021 15 16 8/19/2020 20 20 6/2/2021 17 17 8/24/2020 20 20 6/3/2021 17 18 8/25/2020 21 21 6/7/2021 20 20 8/26/2020 20 20 6/8/2021 20 20 8/31/2020 21 21 6/9/2021 20 20 9/1/2020 21 22 6/14/2021 20 20 9/2/2020 21 22 6/15/2021 20 20 9/8/2020 17 18 6/16/2021 19 19 9/9/2020 19 20 6/21/2021 20 20 9/10/2020 20 21 6/22/2021 21 21 9/14/2020 19 20 6/23/2021 19 19 9/15/2020 19 19 6/28/2021 21 21 9/16/2020 18 18 6/29/2021 21 21 9/21/2020 13 14 6/30/2021 21 21 9/22/2020 13 13 7/6/2021 20 20 9/23/2020 15 15 7/7/2021 20 20 9/28/2020 19 19 7/8/2021 21 21 9/29/2020 20 20 7/12/2021 22 22 9/30/2020 15 15 7/13/2021 21 21 10/5/2020 13 13 7/14/2021 21 21 10/12/2020 17 18 7/19/2021 21 21 10/19/2020 12 12 7/20/2021 21 21 10/26/2020 16 16 7/21/2021 20 20 11/2/2020 10 11 7/26/2021 22 22 11/9/2020 16 16 7/27/2021 22 22 11/16/2020 11 11 7/28/2021 22 21 11/23/2020 12 12 8/2/2021 20 20 12/2/2020 7 7 8/3/2021 21 21 12/7/2020 10 10 8/4/2021 20 20 12/14/2020 13 12 8/9/2021 20 20 12/21/2020 10 10 8/10/2021 21 21 12/28/2020 6 7 8/11/2021 21 21 1/4/2021 8 8 8/16/2021 22 22 1/11/2021 8 7 8/17/2021 22 22 1/19/2021 6 6 8/18/2021 22 22 8/23/2021 21 21 1/3/2022 12 11 8/24/2021 21 21 1/10/2022 8 8 8/25/2021 21 21 1/18/2022 3 3 8/30/2021 21 21 1/24/2022 5 5 8/31/2021 21 21 1/31/2022 5 5 9/1/2021 22 22 2/7/2022 8 7 9/7/2021 19 19 2/14/2022 6 6 9/8/2021 21 21 2/21/2022 6 5 9/9/2021 21 21 2/28/2022 8 8 9/13/2021 20 20 3/7/2022 15 15 9/14/2021 19 19 3/14/2022 11 7 9/15/2021 21 21 3/21/2022 9 9 9/20/2021 20 20 3/28/2022 8 8 9/21/2021 20 20 4/4/2022 10 10 9/22/2021 20 20 4/11/2022 10 10 9/27/2021 15 15 4/18/2022 14 13 9/28/2021 15 15 4/25/2022 15 15 9/29/2021 16 16 5/2/2022 17 17 10/4/2021 19 19 5/9/2022 14 14 10/11/2021 18 18 5/16/2022 18 19 10/18/2021 12 11 5/23/2022 20 20 10/25/2021 15 15 5/31/2022 19 19 11/1/2021 12 12 Average 16.2 16.4 11/8/2021 9 9 Max 22 22 11/15/2021 9 8 Min 2 2 11/22/2021 12 12 11/29/2021 8 8 12/6/2021 12 12 12/13/2021 7 7 12/20/2021 8 7 12/28/2021 11 11 Reduction in Frequency Evalaution Facility: Permit No. Review period (use  3 yrs)Note: Evaluation conducted using limitations assigned to the 3.0 MGD flow tier.  Criteria have been met at both flow tiers. Approval Criteria:Y/N? Y Y N Data Review Units Weekly  average  limit Monthly  average  limit 50%  MA 3‐yr mean  (geo mean  for FC) < 50%?200%  MA # daily  samples  >200% <15?200%  WA # daily  samples  >200% < 20? # of non‐ monthly  limit  violations > 2?# civil penalty  asessment > 1? Reduce  Frequency?  (Yes/No) BOD mg/L 45 30 15 1.6888641 Y 60 0 Y 0 N 0 N Y TSS mg/L 45 30 15 0.8561118 Y 60 0 Y 0 N 0 N Y Ammonia (summer) mg/L 3 1 0.5 0.1649455 Y 2 2 Y 0 N 0 N Y Ammonia (winter) mg/L 6 2 1 0.2868627 Y 4 1 Y 0 N 0 N Y Fecal Coliform #/100 400 200 100 3.4932421 Y 800 7 Y 0 N 0 N Y 1. Not currently under SOS 2. Not on EPA Quarterly noncompliance  report 3. Facility or employees convicted of CWA  violations Rutherfordton WWTP NC0025909 6/2019 ‐ 6/2022 date Parameter Param Class Sample UoM Value Modifier Cell Type Location Subbasin 2/1/2021 01077 - Silver, Total (as Ag)Metal Grab ug/l 0.25 LESSTHAN DLYVALUE Downstream 03-08-02 2/1/2021 01077 - Silver, Total (as Ag)Metal Composite ug/l 0.3 DLYVALUE Effluent 03-08-02 2/1/2021 01077 - Silver, Total (as Ag)Metal Composite ug/l 0.48 DLYVALUE Influent 03-08-02 2/1/2021 01077 - Silver, Total (as Ag)Metal Grab ug/l 0.28 DLYVALUE Upstream 03-08-02 Rutherfordton WWTP Total Silver 2/1/2021 Summary NH3/TRC WLA Calculations Facility: Rutherfordton WWTP PermitNo. NC0025909 Prepared By: Nick Coco Enter Design Flow (MGD):1 Enter s7Q10 (cfs):1.86 Enter w7Q10 (cfs):2.88 Total Residual Chlorine (TRC)Ammonia (Summer) Daily Maximum Limit (ug/l)Monthly Average Limit (mg NH3-N/l) s7Q10 (CFS)1.86 s7Q10 (CFS)1.86 DESIGN FLOW (MGD)1 DESIGN FLOW (MGD)1 DESIGN FLOW (CFS)1.55 DESIGN FLOW (CFS)1.55 STREAM STD (UG/L)17.0 STREAM STD (MG/L)1.0 Upstream Bkgd (ug/l)0 Upstream Bkgd (mg/l)0.22 IWC (%)45.45 IWC (%)45.45 Allowable Conc. (ug/l)37 Allowable Conc. (mg/l)1.9 Capped at 28 ug/L.Consistent with current limit. Maintain limit. Maintain limit. Ammonia (Winter) Monthly Average Limit (mg NH3-N/l) Fecal Coliform w7Q10 (CFS)2.88 Monthly Average Limit:200/100ml DESIGN FLOW (MGD)1 (If DF >331; Monitor)DESIGN FLOW (CFS)1.55 (If DF<331; Limit)STREAM STD (MG/L)1.8 Dilution Factor (DF)2.20 Upstream Bkgd (mg/l)0.22 IWC (%)34.99 Allowable Conc. (mg/l)4.7 Consistent with current limit. Maintain limit. Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/l to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/l, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals) 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis) If the allowable ammonia concentration is > 35 mg/L, no limit shall be imposed Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non-Muni) NH3/TRC WLA Calculations Facility: Rutherfordton WWTP PermitNo. NC0025909 Prepared By: Nick Coco Enter Design Flow (MGD):3 Enter s7Q10 (cfs):1.86 Enter w7Q10 (cfs):2.88 Total Residual Chlorine (TRC)Ammonia (Summer) Daily Maximum Limit (ug/l)Monthly Average Limit (mg NH3-N/l) s7Q10 (CFS)1.86 s7Q10 (CFS)1.86 DESIGN FLOW (MGD)3 DESIGN FLOW (MGD)3 DESIGN FLOW (CFS)4.65 DESIGN FLOW (CFS)4.65 STREAM STD (UG/L)17.0 STREAM STD (MG/L)1.0 Upstream Bkgd (ug/l)0 Upstream Bkgd (mg/l)0.22 IWC (%)71.43 IWC (%)71.43 Allowable Conc. (ug/l)24 Allowable Conc. (mg/l)1.3 Consistent with current limit.Consistent with current limit. Maintain limit. Maintain limit. Ammonia (Winter) Monthly Average Limit (mg NH3-N/l) Fecal Coliform w7Q10 (CFS)2.88 Monthly Average Limit:200/100ml DESIGN FLOW (MGD)3 (If DF >331; Monitor)DESIGN FLOW (CFS)4.65 (If DF<331; Limit)STREAM STD (MG/L)1.8 Dilution Factor (DF)1.40 Upstream Bkgd (mg/l)0.22 IWC (%)61.75 Allowable Conc. (mg/l)2.8 Consistent with current limit. Maintain limit. Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/l to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/l, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals) 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis) If the allowable ammonia concentration is > 35 mg/L, no limit shall be imposed Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non-Muni) NC0025909 Rutherfordton WWTP 8/2/2022 Month RR (%)Month RR (%)Month RR (%)Month RR (%) January-18 97.88 July-20 98.97 January-18 97.18 July-20 98.32 February-18 95.76 August-20 98.81 February-18 92.51 August-20 97.24 March-18 97.75 September-20 98.87 March-18 93.32 September-20 98.50 April-18 95.36 October-20 98.96 April-18 95.65 October-20 98.10 May-18 96.90 November-20 99.10 May-18 97.25 November-20 98.98 June-18 96.27 December-20 98.17 June-18 96.40 December-20 98.20 July-18 97.93 January-21 97.30 July-18 97.55 January-21 96.63 August-18 97.14 February-21 97.67 August-18 97.77 February-21 93.74 September-18 98.54 March-21 98.04 September-18 97.88 March-21 98.37 October-18 97.60 April-21 98.86 October-18 97.31 April-21 98.60 November-18 97.56 May-21 98.71 November-18 96.77 May-21 97.78 December-18 96.56 June-21 99.18 December-18 96.38 June-21 98.17 January-19 97.00 July-21 99.21 January-19 96.12 July-21 97.97 February-19 97.19 August-21 98.72 February-19 96.60 August-21 97.75 March-19 98.91 September-21 98.57 March-19 98.02 September-21 97.14 April-19 98.95 October-21 98.86 April-19 97.67 October-21 98.41 May-19 98.95 November-21 98.92 May-19 98.43 November-21 97.45 June-19 98.65 December-21 98.59 June-19 98.29 December-21 97.98 July-19 99.28 January-22 97.83 July-19 98.04 January-22 96.01 August-19 99.23 February-22 98.79 August-19 98.63 February-22 97.27 September-19 99.20 March-22 98.74 September-19 98.52 March-22 96.78 October-19 99.26 April-22 98.55 October-19 98.48 April-22 97.23 November-19 99.08 May-22 98.80 November-19 98.19 May-22 98.47 December-19 98.36 June-22 December-19 97.26 June-22 January-20 98.63 July-22 January-20 96.97 July-22 February-20 98.14 August-22 February-20 95.45 August-22 March-20 97.71 September-22 March-20 95.40 September-22 April-20 97.46 October-22 April-20 96.66 October-22 May-20 98.35 November-22 May-20 97.64 November-22 June-20 98.99 December-22 June-20 97.96 December-22 Overall BOD removal rate 98.24 Overall TSSD removal rate 97.27 BOD monthly removal rate TSS monthly removal rate 7/22/22 WQS = 12 ng/L V:2013-6 Facility Name /Permit No. : Total Mercury 1631E PQL = 0.5 ng/L 7Q10s = 1.860 cfs WQBEL = 26.40 ng/L Date Modifier Data Entry Value Permitted Flow = 1.000 47 ng/L 1/22/18 2.4 2.4 5/23/18 <1 0.5 1.5 ng/L - Annual Average for 2018 7/10/19 <1 0.5 0.5 ng/L - Annual Average for 2019 1/6/20 1.4 1.4 2/11/20 4 4 3/17/20 7.6 7.6 4/7/20 1.1 1.1 5/5/20 1 1 6/2/20 <1 0.5 2.6 ng/L - Annual Average for 2020 Rutherfordton WWTP/NC0025909 No Limit Required MERCURY WQBEL/TBEL EVALUATION No MMP Required Rutherfordton WWTP/NC0025909 Mercury Data Statistics (Method 1631E) 2018 2019 2020 # of Samples 2 1 6 Annual Average, ng/L 1.5 0.5 2.6 Maximum Value, ng/L 2.40 0.50 7.60 TBEL, ng/L WQBEL, ng/L 26.4 47 7/22/22 WQS = 12 ng/L V:2013-6 Facility Name /Permit No. : Total Mercury 1631E PQL = 0.5 ng/L 7Q10s = 1.860 cfs WQBEL = 16.80 ng/L Date Modifier Data Entry Value Permitted Flow = 3.000 47 ng/L 1/22/18 2.4 2.4 5/23/18 <1 0.5 1.5 ng/L - Annual Average for 2018 7/10/19 <1 0.5 0.5 ng/L - Annual Average for 2019 1/6/20 1.4 1.4 2/11/20 4 4 3/17/20 7.6 7.6 4/7/20 1.1 1.1 5/5/20 1 1 6/2/20 <1 0.5 2.6 ng/L - Annual Average for 2020 Rutherfordton WWTP/NC0025909 No Limit Required MERCURY WQBEL/TBEL EVALUATION MMP Required Rutherfordton WWTP/NC0025909 Mercury Data Statistics (Method 1631E) 2018 2019 2020 # of Samples 2 1 6 Annual Average, ng/L 1.5 0.5 2.6 Maximum Value, ng/L 2.40 0.50 7.60 TBEL, ng/L WQBEL, ng/L 16.8 47 EPA United States Environmental Protection Agency Washington, D.C. 20460 Water Compliance Inspection Report Form Approved. OMB No. 2040-0057 Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCS) Transaction Code NPDES yr/mo/day Inspection Type Inspector Fac Type 1 N 52 NC0025909 21/11/24 C S31112171819 20 21 66 Inspection Work Days Facility Self-Monitoring Evaluation Rating B1 QA ----------------------Reserved------------------- N67707172 73 74 75 80 Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include POTW name and NPDES permit Number) Rutherfordton WWTP NC Hwy 221 Rutherfordton NC 28139 Entry Time/Date Permit Effective Date Exit Time/Date Permit Expiration Date 10:00AM 21/11/24 16/07/01 Name(s) of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) /// Phillip E Reynolds/ORC/828-287-2141/ Other Facility Data 12:00PM 21/11/24 20/07/31 Name, Address of Responsible Official/Title/Phone and Fax Number Doug Barrick,129 N Main St Rutherfordton NC 28139/Town Manager/828-287-3520/Contacted No Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Permit Flow Measurement Operations & Maintenance Records/Reports Self-Monitoring Program Sludge Handling Disposal Facility Site Review Compliance Schedules Pretreatment Effluent/Receiving Waters Laboratory Storm Water Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) of Inspector(s)Agency/Office/Phone and Fax Numbers Date Stephanie A Williams DWR/ARO WQ/828-296-4500/ Mikal Willmer DWR/Division of Water Quality/828-296-4686/ Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete. Page#1 NPDES yr/mo/day 21/11/24 Inspection Type C3111218 1 Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) Mikal Willmer and Stephanie Williams, with the Asheville Regional Office, conducted a compliance evaluation inspection of the Rutherfordton WWTP on November 24, 2021. This inspection was conducted in conjunction with the facilities pretreatment Audit. Suez personnel were present and assisted in the inspection. Overall, the facility appeared to be maintained in compliance with the requirements of the permit. Headworks: The current screw auger is only rated for 1.5 MGD. While average daily flows remain under 1.5 MGD, the screen cannot handle wet weather flows. Currently there is no separate grit removal system. Grit removal may reduce pass-through debris to the aeration basins. There is a manual bar screen that is used when flows bypass the auger during rain events. The grating is spaced too far apart and contributes to additional debris passing into the system. Debris from the screw auger is removed from the headworks by Republic once a week. Rutherford plans to include a new mechanical bar screen sized for the 3 MGD tier and grit removal during upgrades. EQ Basin: Staff indicate there is adequate capacity in the EQ basin during heavy flow events. Operators hope to install a permanent pump to aid in transfer of wastewater back into the system. AB’s: The ORC attempts to keep the DO at approximately 3 mg/L. Rutherford is running staged aeration to maintain pH’s within the system. The #2 liner has not been repaired but is slated for repair in the upcoming fiscal year. Liner #1 will be replaced once #2 is operational. Solids Handling: Budgeted to install new loading station and thickener to aid in solids management. Approximately 56 loads were hauled during the most recent land application event. No new land has been added to the facility RLAP Permit WQ0032855, which is currently in renewal. Chlorine Contact Chamber: The second half of contact chamber has been rehabilitated. Permit Renewal: The facility’s permit is currently in renewal. Permits that go to public notice after April 6, 2016, will require site-specific effluent hardness data to implement the new dissolved metals standard. The permittee can anticipate quarterly hardness sampling of the effluent and the facility's upstream monitoring location. NC0025909 17 (Cont.) Page#2 Permit:NC0025909 Inspection Date:11/24/2021 Owner - Facility: Inspection Type: Rutherfordton WWTP Compliance Evaluation Compliance Schedules Yes No NA NE Is there a compliance schedule for this facility? Is the facility compliant with the permit and conditions for the review period? No compliance schedules in 2016 permit.Comment: Laboratory Yes No NA NE Are field parameters performed by certified personnel or laboratory? Are all other parameters(excluding field parameters) performed by a certified lab? # Is the facility using a contract lab? # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees Celsius)? Incubator (Fecal Coliform) set to 44.5 degrees Celsius+/- 0.2 degrees? Incubator (BOD) set to 20.0 degrees Celsius +/- 1.0 degrees? Certificate of analysis displayed in office. pH and temperature are analyzed in-house. All other parameters are analyzed by Environmental one. Comment: Operations & Maintenance Yes No NA NE Is the plant generally clean with acceptable housekeeping? Does the facility analyze process control parameters, for ex: MLSS, MCRT, Settleable Solids, pH, DO, Sludge Judge, and other that are applicable? MLSS is analyzed once a week by Environmental One. Sludge judge readings are monitored in clarifiers. Comment: Permit Yes No NA NE (If the present permit expires in 6 months or less). Has the permittee submitted a new application? Is the facility as described in the permit? # Are there any special conditions for the permit? Is access to the plant site restricted to the general public? Is the inspector granted access to all areas for inspection? Permit is renewal and under review.Comment: Record Keeping Yes No NA NE Are records kept and maintained as required by the permit? Is all required information readily available, complete and current? Are all records maintained for 3 years (lab. reg. required 5 years)? Page#3 Permit:NC0025909 Inspection Date:11/24/2021 Owner - Facility: Inspection Type: Rutherfordton WWTP Compliance Evaluation Record Keeping Yes No NA NE Are analytical results consistent with data reported on DMRs? Is the chain-of-custody complete? Dates, times and location of sampling Name of individual performing the sampling Results of analysis and calibration Dates of analysis Name of person performing analyses Transported COCs Are DMRs complete: do they include all permit parameters? Has the facility submitted its annual compliance report to users and DWQ? (If the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified operator on each shift? Is the ORC visitation log available and current? Is the ORC certified at grade equal to or higher than the facility classification? Is the backup operator certified at one grade less or greater than the facility classification? Is a copy of the current NPDES permit available on site? Facility has copy of previous year's Annual Report on file for review? Comment: Influent Sampling Yes No NA NE # Is composite sampling flow proportional? Is sample collected above side streams? Is proper volume collected? Is the tubing clean? # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees Celsius)? Is sampling performed according to the permit? Set to time composite. Thermometer is replaced annually, and sample volume is checked monthly and set to 100 mL. Comment: Flow Measurement - Effluent Yes No NA NE # Is flow meter used for reporting? Is flow meter calibrated annually? Is the flow meter operational? Page#4 Permit:NC0025909 Inspection Date:11/24/2021 Owner - Facility: Inspection Type: Rutherfordton WWTP Compliance Evaluation Flow Measurement - Effluent Yes No NA NE (If units are separated) Does the chart recorder match the flow meter? Calibrated annually by Delta.Comment: Bar Screens Yes No NA NE Type of bar screen a.Manual b.Mechanical Are the bars adequately screening debris? Is the screen free of excessive debris? Is disposal of screening in compliance? Is the unit in good condition? The auger is screening most debris and pass-through has not caused significant issues to date; however, the spacing on the manual screen is oversized and the mechanical screw auger is only rated for 1.5 MGD. No separate grit system downstream of bar screens and auger. Comment: Grit Removal Yes No NA NE Type of grit removal a.Manual b.Mechanical Is the grit free of excessive organic matter? Is the grit free of excessive odor? # Is disposal of grit in compliance? No separate grit removal. Facility currently utilizes a screw auger.Comment: Standby Power Yes No NA NE Is automatically activated standby power available? Is the generator tested by interrupting primary power source? Is the generator tested under load? Was generator tested & operational during the inspection? Do the generator(s) have adequate capacity to operate the entire wastewater site? Is there an emergency agreement with a fuel vendor for extended run on back-up power? Is the generator fuel level monitored? Page#5 Permit:NC0025909 Inspection Date:11/24/2021 Owner - Facility: Inspection Type: Rutherfordton WWTP Compliance Evaluation Standby Power Yes No NA NE Contract with Lutz Petroleum for fuel. Camp Electric and Nixon service the generator. The generator exercises automatically every Monday and is tested under load once a month. Comment: Equalization Basins Yes No NA NE Is the basin aerated? Is the basin free of bypass lines or structures to the natural environment? Is the basin free of excessive grease? Are all pumps present? Are all pumps operable? Are float controls operable? Are audible and visual alarms operable? # Is basin size/volume adequate? EQ basin is used primarily during storm events. Currently a portable pump is used to transfer diverted flow to the aeration basins. Comment: Aeration Basins Yes No NA NE Mode of operation Ext. Air Type of aeration system Surface Is the basin free of dead spots? Are surface aerators and mixers operational? Are the diffusers operational? Is the foam the proper color for the treatment process? Does the foam cover less than 25% of the basin’s surface? Is the DO level acceptable? Is the DO level acceptable?(1.0 to 3.0 mg/l) Only one of the two 1 MG basins are currently in use due to a tear in basin #2's liner. Slated for repair this fiscal year. Facility receives dye from textile mill. ORC reported he attempts to maintain an MLSS of 2900 to 3000 mg/L. Comment: Secondary Clarifier Yes No NA NE Is the clarifier free of black and odorous wastewater? Is the site free of excessive buildup of solids in center well of circular clarifier? Are weirs level? Is the site free of weir blockage? Page#6 Permit:NC0025909 Inspection Date:11/24/2021 Owner - Facility: Inspection Type: Rutherfordton WWTP Compliance Evaluation Secondary Clarifier Yes No NA NE Is the site free of evidence of short-circuiting? Is scum removal adequate? Is the site free of excessive floating sludge? Is the drive unit operational? Is the return rate acceptable (low turbulence)? Is the overflow clear of excessive solids/pin floc? Is the sludge blanket level acceptable? (Approximately ¼ of the sidewall depth) Only running one clarifier due to average daily flows. Facility staff monitor the sludge blanket and attempt to keep a one-foot blanket in the clarifier. Comment: Pumps-RAS-WAS Yes No NA NE Are pumps in place? Are pumps operational? Are there adequate spare parts and supplies on site? Comment: Aerobic Digester Yes No NA NE Is the capacity adequate? Is the mixing adequate? Is the site free of excessive foaming in the tank? # Is the odor acceptable? # Is tankage available for properly waste sludge? Facility plans to install a sludge thickener and new loading station. The Town has land application events twice a year on their permitted fields under their Class B permit. Comment: Chemical Feed Yes No NA NE Is containment adequate? Is storage adequate? Are backup pumps available? Is the site free of excessive leaking? Tubing is replaced as needed. Double-walled chemical storage tanks are utilized. Spill control kit located in building with sodium hypochlorite and sodium bisulfite. Storm drain mats are also available if needed; however, any spills would drain to the old sludge loading station which drain back to the plant. Comment: Page#7 Permit:NC0025909 Inspection Date:11/24/2021 Owner - Facility: Inspection Type: Rutherfordton WWTP Compliance Evaluation Disinfection-Liquid Yes No NA NE Is there adequate reserve supply of disinfectant? (Sodium Hypochlorite) Is pump feed system operational? Is bulk storage tank containment area adequate? (free of leaks/open drains) Is the level of chlorine residual acceptable? Is the contact chamber free of growth, or sludge buildup? Is there chlorine residual prior to de-chlorination? Comment: De-chlorination Yes No NA NE Type of system ?Liquid Is the feed ratio proportional to chlorine amount (1 to 1)? Is storage appropriate for cylinders? # Is de-chlorination substance stored away from chlorine containers? Are the tablets the proper size and type? Chlorination and dechlor chemicals are stored in same room; however, they are in double walled HDPE chemical bulk storage carboys. Comment: Are tablet de-chlorinators operational? Number of tubes in use? See above. Liquid chemicals used.Comment: Effluent Sampling Yes No NA NE Is composite sampling flow proportional? Is sample collected below all treatment units? Is proper volume collected? Is the tubing clean? # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees Celsius)? Is the facility sampling performed as required by the permit (frequency, sampling type representative)? Flow paced composite sampler. Delta was scheduled to come out on November 30th to calibrate all meters. Mag meters are utilized and calibrated onsite. Comment: Effluent Pipe Yes No NA NE Is right of way to the outfall properly maintained? Are the receiving water free of foam other than trace amounts and other debris? Page#8 Permit:NC0025909 Inspection Date:11/24/2021 Owner - Facility: Inspection Type: Rutherfordton WWTP Compliance Evaluation Effluent Pipe Yes No NA NE If effluent (diffuser pipes are required) are they operating properly? Comment: Upstream / Downstream Sampling Yes No NA NE Is the facility sampling performed as required by the permit (frequency, sampling type, and sampling location)? Comment: Page#9 Whole Effluent Toxicity Testing and Self Monitoring Summary  Roxboro Steam Electric Power Plant NC0003425/006 24hr LC50 ac monit eFthd24AcBegin:8/1/2021 Freq:ANonComp: County:Person Region:RRO Basin:ROA05 7Q10:Lake IWC:NA SOC_JOC: PF:NA J FMA M J J A SOND 2018 ‐‐‐‐>100 ‐‐‐‐‐‐‐ 2018 ‐‐Pass ‐‐Pass ‐‐Pass ‐‐Pass 2019 ‐‐Pass ‐‐Pass ‐‐Pass ‐‐Pass 2019 ‐‐>100 ‐‐‐‐‐‐‐‐‐ 2020 ‐‐‐‐‐‐‐‐Pass ‐‐Pass 2020 ‐‐‐>100 ‐‐‐‐‐‐‐‐ 2020 ‐‐Pass ‐‐Pass ‐‐Pass ‐‐Pass 2021 ‐‐‐‐‐H ‐‐‐‐‐‐ 2021 ‐‐Pass ‐‐Pass ‐‐Pass ‐‐Pass 2021 ‐‐Pass ‐‐Pass ‐‐Pass ‐‐H 2022 ‐‐Pass ‐‐‐‐‐‐‐‐‐ 2022 ‐‐Pass ‐‐‐‐‐‐‐‐‐ Roxboro WTP NC0003042/001 Chr Monit:  90%Ceri7dPF Begin:4/1/2018 Freq:Q Jan Apr Jul Oct NonComp: County:Person Region:RRO Basin:ROA05 7Q10:IWC: SOC_JOC: PF: J FMA M J J A SOND 2018 Pass ‐‐Pass ‐‐Pass ‐‐Pass ‐‐ 2019 Pass ‐‐Pass ‐‐Pass ‐‐Pass ‐‐ 2020 Pass ‐‐Pass ‐‐Pass ‐‐Pass ‐‐ 2021 Fail ‐‐Pass ‐‐Fail ‐‐Pass ‐‐ 2022 Pass ‐‐Pass ‐‐‐‐‐‐‐‐ Roxboro WWTP NC0021024/001 chr lim: 90%Ceri7dPF Begin:11/1/2018 Freq:Q Mar Jun Sep Dec NonComp:Single County:Person Region:RRO Basin:ROA05 7Q10:0.0 IWC:100 SOC_JOC: PF:5.0 J FMA M J J A SOND 2018 ‐‐Pass ‐‐Pass ‐‐Pass ‐‐Pass 2019 ‐‐Pass ‐‐Pass >100(P)‐‐Pass ‐‐Pass 2020 ‐‐Pass >100(P)‐‐Pass ‐‐Pass ‐‐Pass 2021 ‐‐Pass ‐‐Pass ‐‐Pass ‐‐Pass 2022 ‐‐Pass ‐‐‐‐‐‐‐‐‐ Rutherfordton WWTP NC0025909/001 chr lim: 1MGD @ 45Ceri7dPFBegin:7/1/2016 Freq:Q Jan Apr Jul Oct NonComp:Single County:Rutherford Region:ARO Basin:BRD02 7Q10:1.7 IWC:71 SOC_JOC: PF:3.0 J FMA M J J A SOND 2018 Pass ‐‐Pass ‐‐Pass ‐‐Pass ‐‐ 2019 Pass ‐‐Pass ‐‐Pass ‐‐Pass ‐‐ 2020 Pass ‐‐Pass ‐‐Pass ‐‐Pass ‐‐ 2021 Pass ‐‐Pass >100 (P)>100 (P)>100 (P) Pass >100 (P)‐Pass ‐‐ 2022 Pass ‐‐Pass ‐‐‐‐‐‐‐‐ Page 93 of 117Legend:  P= Fathead minnow (Pimphales promelas), H=No Flow (facility is active), s = Split test between Certified Labs Environmental Testing Solutions, Inc. June 24, 2021 Ms. Ann Baynor Environment 1, Inc. PO Box 7085 Greenville, NC 27835 ETS Project Number: 15990 Test Start Date: June 08, 2021 Facility Tested: Rutherfordton WWTP PO Box 7565 Asheville, NC 28802 Phone: (828) 350-9364 Fax: (828) 350-9368 Enclosed are toxicity test results for samples received by Environmental Testing Solutions Inc. Parameter Code Test Procedure, Method Number Result (ChV) THP6C Fathead minnow, Pimephales promelas, Larval Survival and Growth Chronic EPA-821-R-02-013, Method 1000.0 )100% All toxicity testing results required as part of your permit must be entered on the Effluent Discharge Monitoring Form (MR-1) for the month in which it was performed, using the parameter code THP6C. Additionally, the DMR Reporting Form AT-5 must be signed and e-mailed or mailed to the following address: ATForms.ATB(c�ncdenr.gov North Carolina Division of Water Resources Water Sciences Section / Aquatic Toxicology Branch 1621 Mail Service Center Raleigh, NC 27699-1621 Please call if you have any questions concerning these results. Sincerely, ti Jim Sumner Laboratory Supervisor North Carolina Certificate Numbers: Biological Analyses: 037, Drinking Water: 37786, Wastewater: 600 South Carolina Certificate Number: Clean Water Act: 99053-001 Environmental Testing Solutions, Inc. PO Box 7565 Asheville, NC 28802 Phone: (828) 350-9364 Fax: (828) 350-9368 Effluent Toxicity Report Form - Chronic Fathead Minnow Multi -Concentration Test Date: June 24, 2021 Facility: Environment 1, Inc. Rutherfordton WWTP Laboratory Performing Test: Environmental Testing Solutions, Inc., Certificate # 037 Signature of Operator in Responsible Charge (ORC): ORC Phone / E-mail: Signature of Laboratory Supervisor: e-Mail to: ATForms.ATB@ncdenr.Rov NPDES #: NC 0025909 Pipe #: 001 County: Rutherford Or Mail Original to: North Carolina Division of Water Resources Water Sciences Section / Aquatic Toxicology Branch 1621 Mail Service Center Raleigh, NC 27699-1621 Test Start Date: June 08, 2021 Control Organisms % Effluent 11.25% % Effluent 22.5% % Effluent 45% % Effluent 72.5% % Effluent Water Quality Data Control pH (SU): DO (mg/L): Temp. (°C): High Concentration pH (SU): DO (mg/L): Temp. (°C): 100% Comments Project U: 15990 Sample 9: 210607.02, 210609.02, 210611.0: Test Organisms: Pimephales pramelas Replicate number 1 2 3 Supplier 4 In-house Culture Begin hatch: End hatch: Surviving number of larvae 10 10 10 10 Original number of larvae 10 10 10 10 Weight/original (mg/larvae) 0.884 1 0.849 0.966 0.988 Surviving number of larvae 10 10 10 10 Original number of larvae 10 10 10 10 Weight/original (mg/larvae) 0.867 0.931 0.988 0.984 Surviving number of larvae 10 10 10 10 Original number of larvae 10 10 10 10 Weight/original (mg/larvae) 0.879 0.870 0.796 0.886 Surviving number of larvae 10 10 10 10 Original number of larvae 10 10 10 10 Weight/original (mg/larvae) 0.976 0.914 0.788 0.917 Surviving number of larvae 10 10 10 10 Original number of larvae 10 10 10 10 Weight/original (mg/larvae) 0.742 I 0.882 0.926 0.828 Surviving number of larvae 10 9 10 10 Original number of larvae 10 10 10 10 Weight/original (mg/larvae) 0.890 0.805 0.875 0.888 06-07-21 1500 06-08-21 0500 Survival (%) Average wt (mg) Average wt / surviving (mg) Survival (%) Average wt (mg) Survival (%) Average wt (mg) Survival (%) Average wt (mg) Survival (%) Average wt (mg) Survival (%) Average wt (mg) 100.0 0.922 0.922 100.0 0.943 100.0 0.858 100.0 0.899 100.0 0.845 97.5 0.865 Day 0 Day 1 Day 2 Day 3 Day 4 Day 5 Day 6 Initial Final Initial Final Initial Final Initial Final Initial Final Initial Final Initial Final 8.17 8.00 8.08 8.00 8.14 7.70 8.17 7.94 8.12 7.98 8.21 8.01 8.23 7.98 7.7 7.6 7.8 7.6 7.7 6.7 7.6 7.5 7.9 7.8 7.8 7.4 7.9 7.3 24.8 24.5 24.7 24.6 24.8 24.7 24.7 24.3 24.7 24.4 24.6 24.8 24.8 24.2 7.94 7.81 7.94 7.70 7.99 7.50 7.90 7.66 7.95 7.76 8.00 7.74 7.94 7.70 7.7 7.4 7.9 7.3 8.0 6.5 8.1 7.6 8.0 7.7 8.1 7.3 8.2 7.4 25.0 24.8 24.9 24.7 25.0 24.5 24.9 24.5 25.0 24.3 24.9 24.6 25.0 24.3 Sample Information Collection start date: Grab: Composite duration: Alkalinity (rng/L CaCO3): Hardness (mg/L CaCO3): Conductivity (µmhos/cm): Total residual chlorine (mg/L): Sample Temp. at Receipt (°C): Overall Analysis: Sample 1 Sample 2 Sample 3 Control 06-06-21 06-08-21 06-10-21 24-h 24-h 24-h 45 47 46 59-62 36 34 36 84-86 279 261 263 305-323 < 0.10 < 0.10 < 0.10 0.9 1.6 3.1 Analyses Normal: Hom. Var. NOEC: LOEC: ChV: Method: Survival Growth Yes Yes Yes Yes 100% 100% >100% >100% >100% >100% Visual Insp. Dunnett's Survival Growth % Effluent Critical Calculated Critical Calculated 11.25% 2.410 -0.469 22.5% . 2.410 1.447 45% 2.410 0.520 72.5% 2.410 1.747 100% 2.410 1.295 Result: PASS LOEC: >100% NOEC: 100% ChV: >100% DWR Report Form AT-5 Page 1 of 5 Environmental Testing Solutlons, Inc. Chronic Whole Effluent Toxicity Test (EPA-821-R-02-013, Method 1000.0) Species: Pimephales promelas Client: Rutherfordton WWTP NPDES #: NC 0025909 Project#: \5`lei o Dilution preparation: County: Rutherford Outfall #: 001 Dilution prep (%) 11.25 22.5 45 72.5 100 Sample was not aerated or treated unless otherwise Effluent volume (mL) 112.5 225 450 725 1000 noted on this form. Sample was warmed to 25.0 ± 1.0°C Diluent volume (mL) 887.5 775 550 275 0 in a warm water bath and then diluted to the test concentrations with moderately hard synthetic water Total volume (mL) 1000 1000 1000 1000 1000 (MHSW). Test organism information: Test information: Organism source: In-house culture Randomizing template: Gaget3 Age: < 24-hours old Incubator number and shelf location: 1 E Spawn date: t°4,,•O\-1L\ Artemia CHM number: CHM1149 Hatch dates and times: 06. tr' • -u t. SCO —CO Olt-Ut? U OS00 Drying information for weight determination: Date / Time in oven: ot,• 1S•-LI on S *Initial oven temperature: tot ' L Transfer vessel information: pH (5. U.) = g . Vs' Temperature (°C) "1: - Date / Time out of oven: ®b•tb •'1.\ O'1A0 *Final oven temperature: Average transfer volume (mL): < 0.25 mL Total drying time: "IA •taoodz S *60°C Oven, Thermometer SN: 14-985B5 Daily feeding and renewal information: Day Date Morning feeding Afternoon feeding Test initiation, renewal, or termination Sample number used MHSW batch used Time Analyst Time Analyst Time Analyst 0 06-08-21 U 5 OS 1110 1,( ins- 0 yt 110bifl- crL 06• LI A 1 06-09-21 OSoO '(/\ t11� k Ori I O 1 2 06-10-21 OS'tt IN \\30 .� cn-ko In -LA 0bal. 01--ol,•(s./1 C 3 06-11-21 OS OO 1� 1\ l L l� 0"l l l \,( A,, 4 06-12-21 o�oo { t oo , o Pio 6 V\ -t oLtt. rt 06•oi.ti A 5 06-13-21 ()°O It. IIIAS ro ` 1 6 06-14-21 OSoo I(� \1\S 1l olio d .1 Ob-IO.21' 7 06-15-21 0 �`Al Chemical analyses: Parameter Reporting Limit Method number Meter Serial number pH 0.15.U. SM 4500-H+ B-2011 Accumet AR20 93312452 Dissolved Oxygen (D.0.) 1.0 mg/L SM 4500-0 G-2011 YSI Model 52CE 18D104324 Conductivity 14.9 µmhos/cm SM 2510 B-2011 Accumet AR20 93312452 Alkalinity 5.0 mg CaCO3/L SM 2320 B-2011 Accumet AR20 93312452 Hardness 5.0 mg CaCO3/L SM 2340 C-2011 Not applicable Not applicable Chlorine, Total Residual 0.1 mg/L ORION 97-70-1977 Accumet AB250 92349123 Temperature 0.1°C SM 2550E-2010 Digital Thermometer 13Ob6y6$ S Control information: Acceptance criteria Summary of test endpoints: Mortality: 0 %• _< 20% 7-day LC50 (%) 7 1001. Average weight per initial larvae: U •602- NOEL (%) I OCA. Average weight per surviving larvae: 0 •i°!•lL.- >_ 0.25mg/larvae LOEC (%) "7 1007. ChV (%) 1b07• IC25 (%) `% 1 o07_ SOP AT2O-Revision 6—Exhibit AT20.3 Page 2 of 5 Environmental Testing Solutions, Inc. Species: Pimephales promelas Client: Rutherfordton WWTP Survival and Growth Data Date: 06-08-21 Day CONTROL 11.25% 22.5% A BCDE F G H I J K L 0 10 10 10 10 10 10 10 10 10 10 10 10 1 I o (0 ltj 10 LU 10 (D /0 (0 10 10 /0 2 (0 10 10 I0 10 10 10 ID IO /0 io 10 3 (0 ID 10 to 10 10 10 10 1u 10 10 ►D 4 /0 (0 10 (0 10 10 10 /0 10 ID 10 lb 5 '0 (0 10 10 10 (0 (O (0 10 10 10 /O 6 IO ('0 tp (p Ip tO CO 10 Ip ip 10 ID 7 10 10 10 10 10 /0 10 CO /D '0 r0 (D *A = Pan weight (mg) Tray color code: pCc? o e. 14.5G, 1,23 1y.(05 It1.1•-3/ 15.68 13.91 14.05 14.1$ 15.22 14.05 d'4,405 15•Zt-1 Analyst: cvtit- Date: Oda - 2.La- 2,\ *B = Pan + Larvae weight (mg) Analyst: J ( 2.1.�d0 2%: t 7.a.%`,9 1..4.4 s • 3. as -`•s,•a.2 14.-1I •64.tm1- 1°t. D I 2Z: \5 22. SI lg. 4 0 Date: n< 7 3 t1 C = Larvae weight (mg) = B —A Analyst: il.gel e.t-Vt el).t.oU et. is g.b1 1.t)% ti.%g 9,.8.4 b.`A g.io Lilo l;•e.L1 Weight per initial number of larvae (mg) = C / Initial number of larvae Analyst: �0, 0. c). D. c•re C7• ��� 0 ma's 0 �,e 0' 0,C6 0• ON 0• % Ca p 0' if p• qz' Average weight per initial number of larvae (mg) Percent reduction from control (%) 0 .e\- L- 0.`114,5 `2.-5 -40.g Sg 6•9 7. Weight measurements performed using Cahn 28 Automatic Electrobalance, SN 41520. Comment codes: c = clear, d = dead, fg = fungus, k = killed, m = missing, sk = sick, sm = unusually small, Ig = unusually large, d&r = decanted and returned, w = wounded. Comments: SOP AT2O-Revision 6-Exhibit AT20.3 Page 3 of 5 Environmental Testing Solutions, Inc. Species: Pimephales promelas Client: Rutherfordton WWTP Survival and Growth Data Date: 06-08-21 Day 45% 72.5% 100% M N 0 P Q R S T U V W X 0 10 10 10 10 10 10 10 10 10 10 10 10 1 (Z 10 ID ID Io Ip (0 IQ (0 (0 10 /0 2 i0 10 10 10 10 10 10 (0 10 10 10 10 3 10 It, 10 10 10 /0 Ib 10 10 10 ►0 10 4 16 iu 10 10 10 10 10 10 Ip Ip 10 I� 5 I'D ID ID ID ID 10 10 IO 10 `0 10 I1 6 ID ID 10 f0 10 10 I lD ►0 10 (0 10 7 )0 ID ID 10 ts,N9 I0 10 I0 10 /0 °I `� 10 Icy *A = Pan weight (mg) Tray color code: Orcu-N iLl.81g IN.1°I 13.(05 0- 24 ► 5, 2,2. 13.50 16.0w v3.-1 14•Bl 14%.00 114,5to 16.59 13.2.1 Analyst: MR, Date: 06 - 2(n - 7_1 *B = Pan + Larvae weight (mg) Analyst: zi.61- "2.3. 3 lt.S' "1.4.A 2%.11. 2 a. Iv 1.2..e % '1.3 .tr'� 3.'1..°ub U.6l Z.t.3`.i 22 in Date: ®�' Isi • 3{ C = Larvae weight (mg) = B —A Analyst: c1.11.1 R.ILi 1, ge 41.11 1.4/ 6•e'2, 9t.1;1 E•Ig a.cio 1;.©s .'Bs g.gg Weight per initial number of larvae (mg) = C / Initial number of larvae Analyst: fi` O. (i'O ®' i`• 0- Q. fi cy 0• 0 0' 0 ® 0. %,-- 0- Average weight per initial number of larvae (mg) Percent reduction from control (%) ®' 2 Z.� i. td ®. 8 15 .� I . ®. 4I35 % • 7., *Weight measurements performed using Cahn 28 Automatic Electrobalance, SN 41520. Comment codes: c = clear, d = dead, fg = fungus, k = killed, m = missing, sk = sick, sm = unusually small, Ig = unusually large, d&r = decanted and returned, w = wounded. Comments: SOP AT20-Revision 6—Exhibit AT20.3 Rutherfordton WWTP June 08, 2021 Project number: 15990 Sample numbers 210607.02, 210609.02, 210611.02 Weight / Initial number Mean survival Meanweight/Initial Coefficient of variation Percent reduction from of larvae(rn) (%)number of larvae (%) control (%) (mg) a = o. 0 z '� a ri 00 of ry �o N N O i0 enm 00 00 of ai N 00 N C 00 m 0 m m tel o a,N al ea ea e o Ln ea0m o 0 0 2 0 0 o 0 0 2 0 0 0 0 o n m 0.884 0.849 0.966 0.988 N a, w 0 0 0.988 0.984 0.879 0.870 0.796 0.886 LO CrN m m 0 0 0.788 0.917 N n m 0 0 t0 COm m m 0 0 0.890 0.805 0.875 0.888 Coefficient of variation Ime.o •.4111 per r.r.:.i.e number el lervee)(%) o v? m 00 m m o Mean weight/ Surviving number of larvae (mg) N Om m m a co In m o m amo 0 m 0 Nm m 0 m E .2 31 - 3 E 0.884 0.849 10 m 0 0 N m m m 0 0 CO Cr m m 0 0 0.879 0.870 0.796 0.886 0.976 0.914 0.788 0.917 0.742 0.882 'fO m m 00000 0 0 0.890 0.894 0.875 CO m 0 E f.. a - 3 ,m, z z 8.84 8.49 tO m In rn m 8.67 9.31 9.88 9.84 m 0 N N^ o0 o m m c m- ai m N m .+ n ai 7.42 8.82 9.26 8.28 O �n P. m 0 m 00 m m m 9 E °p 3 31 23.40 23.72 24.34 24.65 23.85 23.22 24.73 24.62 o P. N N N m o N P N N 24.62 23.33 21.53 24.39 21.22 23.88 22.97 23.09 m 0 m N N N N N N - 3 a O01 N 00 00 b N 00 00 15.18 13.91 14.85 14.78 15.22 14.05 m N c ui LO m 0 v c o N m 000 O ni vi N ro ni v ID 0 LO IT v v m N Final number of larvae 0 0 0 0 0T OT 0T 0T 10 10 10 10 0 0 0 0 0 0 0 0 o m O o Initial number of larvae OT 0T 0 0 0 0 0 0 0 0 0 0 0T 0T 0T 0T 0 0 0 0 0 0 0 0 _ ¢muo vaLLtgx --x� 2zoa Ccoi- => x Concentration (%) Control m N Vy N N 00 N N ti a whole effluent toxicity t E E E E E w o i a a Outfall 001: 0 0 00 0 0 0 O • oc V 0 s o E n o w H � 00 o E 0 • v a a `o q • 0 a a .51 O � m o E Oo O v o' 0 3 a 'o w 0 0 a 3 a � 3 0 E 00 v11-1 0 r a 0 0 00 7 Statistical Analyses Environmental Testing Solutions, Inc. ivEntered by: Kelley Kcon.n Reviewed by: lin,Semner Start Date: 6/8/2021 End Date: 6/15/2021 Sample Date: Comments: Larval Fish Growth and Survival Test-7 Day Growth Test ID: PpFRCR Sample ID: Rutherfordton Lab ID: ETS-Envir. Testing Sol. Sample Type: DMR-Discharge Monitoring Report Protocol: FWCHR-EPA-821-R-02-013 Test Species: PP-Pimephales promelas Conc-% 1 2 3 4 D-Control 0.8840 0.8490 0.9660 0.9880 11.25 0.8670 0.9310 0.9880 0.9840 22.5 0.8790 0.8700 0.7960 0.8860 45 0.9760 0.9140 0,7880 0.9170 72.5 0.7420 0.8820 0.9260 0.8280 100 0.8900 0.8050 0.8750 0.8880 Transform: Untransformed 1-Tailed Isotonic Conc-% Mean N-Mean Mean Min Max CV% N t-Stat Critical MSD Mean N-Mean D-Control 0.9218 1.0000 0.9218 0.8490 0.9880 7.159 4 0.9321 1.0000 11.25 0.9425 1.0225 0.9425 0.8670 0.9880 6.010 4 -0,469 2.410 0.1066 0.9321 1.0000 22.5 0.8578 0.9306 0.8578 0.7960 0.8860 4.860 4 1.447 2.410 0.1066 0.8783 0.9422 45 0.8988 0.9750 0.8988 0.7880 0.9760 8.808 4 0.520 2.410 0.1066 0.8783 0.9422 72.5 0.8445 0.9162 0.8445 0.7420 0.9260 9.381 4 1.747 2.410 0.1066 0.8545 0.9167 100 0.8645 0.9379 0.8645 0.8050 0.8900 4.652 4 1.295 2.410 0.1066 0.8545 0.9167 Auxiliary Tests Statistic Critical Skew Kurt Shapiro-Wilk's Test indicates normal distribution (p > 0.01) 0.92924 0.884 -0.584 -0.635 Bartlett's Test indicates equal variances (p = 0.82) 2.22799 15.0863 Hypothesis Test (1-tail, 0.05) NOEC LOEC ChV TU MSDu MSDp MSB MSE F-Prob df Dunnett's Test 100 >100 1 0.10656 0.11561 0.00607 0.00391 0.2239 5, 18 Treatments vs D-Control Linear Interpolation (200 Resamples) Point % SD 95% CL(Exp) Skew IC05 20.982 IC10 >100 IC15 >100 IC20 >100 IC25 >100 IC40 >100 IC50 >100 1.0 0.9 0.8 0.7 0.6 N c 0.5 0.4 CC 0.3 0.2 0.1 0.0 0.1 .0 0 50 100 150 Dose 1.2 Dose -Response Plot L 0.8 - 2 t7 0.6 0.4 0.2 u7 n 8 1-tail, 0.05 level of significance Page 4 of 5 Environmental Testing Solutions, Inc. Species: Pimephales promelas Client: Rutherfordton WWTP Date: 06-08-21 Daily Chemistry: Temperatures performed at the time of test initiation, renewal or termination by the analyst identified in the Daily Renewal Information table located on Page 1. Alkalinity, hardness and chlorine (total residual) performed by the analyst identified on the bench sheet specific for each analysis and transcribed to this bench sheet. Analyst Day (Analyst identified for each day, performed pH, D.O. and conductivity measurements only.) 0 1 2 i PT5' IA - Concentration Parameter CONTROL, MHSW pH (S.U.) 6,1'1- ODD 0r4)8 8-Oa p C1•fzi Dissolved oxygen (mg/L) -7-7 lAo /3,r 7, (0 4-1 (' 1 -f Conductivity (µmhos/cm) 31n1 3Ia 3/9 Alkalinity (mgCaCO3/L) toll Hardness (mg CaCO3/L) gtp t r`, gto Temperature(°C) IA • e 1._1-S 1-`1•-1 -1:4,_b '\ k- k -,A. 1 11.25% pH(S.U.) G poi qq®1..;36 8-00 t4-r1 '4.`4-1 Dissolved oxygen (mg/L) -1, (o 1..40 (0 S-0 Le- Conductivity (µmhos/cm) 32,0 ;2 �Z Temperature (°C) -1-1•G 1 1 —N.A.• rf p —VA. A `IA- R. 1-�` ! -^►� `� 22.5% pH (S.U.) aa U• 1 1.AS +i4 -y i-Q-4 6t%4a /-6 7+t0•;r (0.5 Dissolved oxygen (mg/L) 1 /1� c 7' 6 d Conductivity (µmhos/cm) 312 x 314 .zqy Temperature (°C) ' LL r; -N.`� • d Zy - EE 1_4 , 6 '1„`A ak Zi, An 45% pH(S.U.) d•.p`-C 4.01- 0AT g% at0 4,.1/t Dissolved oxygen (mg/L) .R, <:„, 1. to igi --4-•4- Q O (o. Conductivity(µmhos/cm) jot( s1• ZB� Temperature (°C) 1-'1. i41 . . ..,-1p G -L'•b 14_ZI-1 6 pH (S.U.) 6?.-00 r+R� 0,00 4. e'o 8'..ors - /!•510 72s% Dissolved oxygen (mg/L) (q f, 19 -I- S YS O (0.g Conductivity (µmhos/cm) 2t38 A4k( Z.73 Temperature(°C) —.,1 -1L1..5 -LA '��� -LA-C pH (S.U.) -t 7. 9L( I`�.1/4/0, �P.edI 'i iN 1 1-0 lei9 �i:ec� Dissolved oxygen (mg/L) -/.-7 1,t,4 -7T�`'7j 4, 3 S_ 41 (9eS- Conductivity (µmhos/cm) PI lea 74,1 100% Alkalinity (mg CaCO3/L) 14 S. 4 1 Hardness (mg CaCO3/L) ?1ta z1 Chlorine (mg/L) 4 0. I D 4. 0,10 Temperature (°C) 1-S • 0 1.L`. S. lit .1 1A.-1 -Ls -O litS Initial Final Initial Final Initial Final SOP AT2O-Revision 6-Exhibit AT2O.3 Page 5 of 5 Environmental Testing Solutions, Inc. Species: Pimephales promelas Client: Rutherfordton WWTP Date: 06-08-21 Analyst Day (Analyst identified for each day, performed pH, D.O. and conductivity measurements only.) 3 4 5 6 er-A, eSt, IDS PO p J / , Yy��/ P Concentration Parameter CONTROL, MHSW pH(S.U.) yr�� ta!+ �/ pp 4."1'F Q O.IZ q p 1 /l• 8.21 ^ p S.o{ ®a23 3.n(8 Dissolved oxygen (mg/L) I1(0 1.5 zr._. �6i 6 q-g '4.�.! 7 • '9 7 3 Z Conductivity(pmhos/cm) 30S 10 �\ 3o' 3 23 Alkalinity (mg Ca CO,/L) \ 4ws• j� s!1 Hardness (mg CaCO3/L) 6 8� �`�`�� R_ 1 Temperature(°C) ^\�, Z.�- 1 ,1 1 1.\• J `, �•► 1 - 1 A..A.4 1 -\..�i. /� Z/.y. a ^� 11.25% pH (S.U.) 0•04 3.84E .t,'l• 8.Iv q-?s- 0�.�'p•O Cs_ I V '1CI R 03 A3 -]A.,.�.1. 'l-81 Dissolved oxygen (mg/L) l301 1,/ gna 4.' 8-1 1., °4 ® 6,0 V L i Conductivity (pmhos/cm) 2�1 2_ •311 " & 0 Temperature(°C) —L�\ • \ -IAA. -% •6 �.� -S �-6 Z Z 'NA- Z1.A , �l -S ` 22.5% pH(S.U.) 6060 7.1a %.14 q•grt, 8.9g" /\{j 12 F.to v.84 Dissolved oxygen (mg/L) op 1 S•to 7.v e k s l.•3 777 ✓i,-94 CJ lJ 7,yl I Conductivity (µmhos/cm) 2•°i.1--1 •3o 05 3o0 000 Temperature (°C) 11 �\1- 1 -LA- t Z-'1 - 8 '``t .1 Z�.-9 a t, -IA. 6 -IA1J 'y • 1 -IA. S 45% pH(S.U.) 116 I./3 c S 11. &-t g r-z. ' •P.co ®,0(a 4.db Dissolved oxygen(mg/L) 63•0 1.� C.o O•o 4 B e--Z /13 7 IA�1-� T Conductivity (pmhos/cm) 2g2. 4qo ZQ`-t `zoi 2 Temperature (°C) R ZA-S Z.LI • 6 -. ••i ��t• 1 ' • S ��. l TA -S pH (S.U.) ^AA. Bf 3 J 7 .00 �.90 `- - 9`'t " 9-d 1 199 4.76 72.5% Dissolved oxygen (mg/L) 63•1 .1r -6 e•.Z �.() �,�.` t conductivity(pmhos/cm) �1 y 1X1,��9 47S z.c.G 2ao //AS Temperature (°C) ( . - ..q 5 .. ' •\ �41 •I -NA-, •�0j u pH (S.U.) /�1L. • T• 1° �y quit �y o-'\ ` . { C. 7- 7 , — o LS 14•14 ,�0'1 '"i%.l'/S� T- 0 Dissolved oxygen(mg/L) 8,1 -� )-a -1 ,.3 ®, T.y Conductivity(pmhos/cm) A91 DIO.12- 1 4(p3 Z6,1 2 w„ei 100% Alkalinity (mg CaCO,/L) 4l Hardness (mg CaCO3/L) mb Chlorine (mg/L) < 0 • 1 0 Temperature (°C) G{ •Itt • 1 --A • S AS -0 `+ g Z•'6 • .D Q, —LA • e , ` Z`l - lo L . 0 TA-3 Initial Final Initial Final Initial Final Initial Final SOP AT2O-Revision 6-Exhibit AT20.3 351 Depot Street Asheville, NC 28801 Phone: (828) 350-9364 Fax: (828) 350-9368 Environmental Testing Solutions, Inc. Whole Effluent Toxicity Chain -of -Custody Form Facility: SEUZ Rutherfordton WWTP Species: Pimephales promelas Test type: Chronic Definitive NPDES #: NC0025909 Pipe #: 001 County: Rutherford Purchase order: Effluent dilution: 11.25, 22.5, 45, 90, 100% Parameter code: THP6C Sample information: (to be completed by sample collector) Composite sample: Sample location: 0 0 t Start date: `3 o c&.Dr-'Z., Time: qO`z 1w". Volume collected for testing: 1- End date: ao• Time: ktp Y Number of containers filled for testing: 2_ Number of samples per hour: Chilled during collection? If chilled, specify temperature: 0-6 Method of transport to laboratory: 4A( . Comments: Triple rinse sample container with sample before filling. Completely till the sample container with no air space. Pack the sample container completely in ice. The sample must be < 6.0°C upon receipt at the laboratory. Sample custody: (to be completed by sample collector and facility personnel) BY SIGNING BELOW, I CERTIFY THAT THE PERMIT AND TEST REQUIREMENTS IDENTIFIED ON THIS FORM ARE ACCURATE Sample collected by: Relinquished by: �22up � Prim Relinquished by: coLLYP Dale and time Print Signature Date and lime Sample receipt information: (to be completed by ETS personnel) Relinquished to ETS by: Custody seals intact?: Signature Yes No Not used Samples received in good condition?: 71 Tracking number: Comments: Yes N Pc tOigatia Date and time No Received by: Print Received by: Signauui iG--7.1I (Zyt+l Date and time Print Signature I):ue:md time Received at ETS by: 0%• - tf1-t k IOIQ Print Signature Sample temperature upon receipt at ETS (°C): Total residual chlorine upon receipt at ETS: Dale and lime oR `C MEI (DPD Presence/Absense Indicator, MDL = 0.10 mg/L) r,�A�1 Project number :C 4OSample number: It v1Q01 z Absent 351 Depot Street Asheville, NC 28801 Phone: (828) 350-9364 Fax: (828) 350-9368 Environmental Testing Solutions, Inc. Whole Effluent Toxicity Chain -of -Custody Form Facility: SEUZ Rutherfordton WWTP Species: Pimeph ales promelas Test type: Chronic Definitive NPDES #: NC0025909 Pipe #: 001 County: Rutherford Purchase order: Effluent dilution: 11.25, 22.5, 45, 90, 100% Parameter code: THP6C Sample information: (to be completed by sample collector) Composite sample: Start date: D-o4--i' End date: 0., ear Number of samples per hour: Time: L 9 Time: 4 o S e.c•- Chilled during collection? If chilled, specify temperature: Sample location: QO\ Volume collected for testing: Z-(? Number of containers filled for testing: "L— Method of transport to laboratory: 14.i1-Q� Comments: Triple rinse sample container with sample before filling. Completely fill the sample container with no air space. Pack the sample container completely in ice. The sample must be < 6.0°C upon receipt at the laboratory. Sample custody: (to be completed by sample collector and facility personnel) BY SIGNING BELOW, 1 CERTIFY THAT THE PERMIT AND TEST REQUIREMENTS IDENTIFIED ON THIS FORM ARE ACCURATE Sample collect by: by: lti: w id ..9 ea- 04)-,..1. w LNSgS .s-,,,==> 414f. `5' Relinquished by: Print Relinquished by: tit Date and time Received by: r1ace Dlo. D 9- 2/ Print Received by: *nature Dale and lime Print Signature Dale and time Sample receipt information: (to be completed by ETS personnel) Relinquished to ETS by: 00,032-1 la4-10 Print Custody seals intact?: Yes Signature No Not used Samples received in good condition?: Yes Tracking number: Comments: �A Dale and lime No Pant Received at ETS by: Print Signature Signature Sample temperature upon receipt at ETS (°C): Total residual chlorine upon receipt at ETS: Dale and Bare Date and time (DPD Presence/Absence Indicator, MDL = 0.10 mglL) Pre.,.•nl Akent Project number:I Sample number: R 1 oc9.0Z,. 351 Depot Street Asheville, NC 28801 Phone: (828) 350-9364 Fax: (828) 350-9368 Environmental Testing Solutions, Inc. Whole Effluent Toxicity Chain -of -Custody Form Facility: SEUZ NPDES #: NC0025909 Pipe #: 001 County: Rutherford Rutherfordton WWTP Purchase order: Species: Pimephales promelas Effluent dilution: 11.25, 22.5, 45, 90, 100% Test type: Chronic Definitive Parameter code: THP6C Sample information: (to be completed by sample collector) Composite sample: Sample location: 0" Start date: t . - iQ-'t-{ Time: wv-•• Volume collected for testing: j. (T End date: Vc tL- "t \ Time: (.\.a ( , Number of containers tilled for testing: Number of samples per hour: Chilled during collection? If chilled, specify temperature: •} Method of transport to laboratory: K.A,Le . Comments: Triple rinse sample container with sample before filling. Completely fill the sample container with no air space. Pack the sample container completely in ice. The sample must be < 6.0°C upon receipt at the laboratory. Sample custody: (to be completed by sample collector and facility personnel) BY SIGNING BELOW, I CERTIFY THAT THE PERMIT AND TEST REQUIREMENTS IDENTIFIED ON THIS FORM ARE ACCURATE Sample collected by: 'VW b'-t; \ `-" S Ots- 11-1-1 'sus / A t 5 c p —__) Relinquished by: etlIt kint Relinquished by: Print s ignature Sigmmuin Date and time Dale and lime Sample receipt information: (to be completed by ETS personnel) Relinquished to ETS by: Print Signature Custody seals intact?: No Samples received in good condition?: Tracking number: Comments: 0&-ii.0 Date1V time Not used Yes OP, No Received by: I ce. 00.Iran Print Received by: Signature Date and time Print Received at ETS by: Signature Dale and time 00.114 Date and time Print Signature Sample temperature upon receipt at ETS (°C): Total residual chlorine upon receipt at ETS: (DPD Presence/Absense Indicator, MDL = 0.10 mg/L) Absent Project number: I I Sample number: p'2k(Sb II.ot 7-day IC25 (g/L KCI) Environmental Testing Solutions, Inc. 0.9 0.8 0.7 0.6 1.2 1.0 0.8 0.6 0.4 Pimephales promelas Chronic Reference Toxicant Control Chart Source: In-house Culture Control Limits (± 2 Standard Deviations) 1 1 1 1 1 1 I 1 1 1 1 1 1 1 1 1 1 1 1 I Warning Limits —'— • • • • • • • • • 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 O3.°D1,0Oa3O�0O0tiO10O1\Oa011&031 0AO OO6- 00%L 11..V 1.03a9.60.1,$9.01"1.01:03.a096. Test date • 7-day IC25 = 25% inhibition concentration. An estimation of the potassium chloride concentration which would cause a 25% reduction in Pimephales growth (calculated using ToxCalc). �....:, Central Tendency (mean logarithmic IC25 converted to anti -logarithmic values) Control Limits (mean logarithmic IC25 ± 2 standard deviations converted to anti -logarithmic values) Laboratory Warning Limits (mean logarithmic IC25 ± 2 coefficent of variations converted to anti -logarithmic values) USEPA Warning Limits (mean logarithmic IC25 ± SA 75 converted to anti -logarithmic values, SA 75 = 75th percentile of CVs reported nationally by USEPA) iIlntered ad viewed by m Sumner Environmental Testing Solutions, Inc. July 26, 2021 Ms. Ann Baynor Environment 1, Inc. PO Box 7085 Greenville, NC 27835 ETS Project Number: 16066 Test Start Date: July 13, 2021 Facility Tested: Rutherfordton WWTP PO Box 7565 Asheville, NC 28802 Phone: (828) 350-9364 Fax: (828) 350-9368 Enclosed are toxicity test results for samples received by Environmental Testing Solutions Inc. Parameter Code Test Procedure, Method Number Result (ChV) THP6C Fathead minnow, Pimephales promelas , Larval Survival and Growth Chronic EPA-821-R-02-013, Method 1000.0 ,100% All toxicity testing results required as part of your permit must be entered on the Effluent Discharge Monitoring Form (MR-1) for the month in which it was performed, using the parameter code THP6C. Additionally, the DMR Reporting Form AT-5 must be signed and e-mailed or mailed to the following address: ATForms.ATB(a�ncdenr.gov North Carolina Division of Water Resources Water Sciences Section / Aquatic Toxicology Branch 1621 Mail Service Center Raleigh, NC 27699-1621 Please call if you have any questions concerning these results. Sincerely, i Sumner Laboratory Supervisor North Carolina Certificate Numbers: Biological Analyses: 037, Drinking Water: 37786, Wastewater: 600 South Carolina Certificate Number: Clean Water Act: 99053-001 Environmental Testing Solutions, Inc. PO Box 7565 Asheville, NC 28802 Phone: (828) 350-9364 Fax: (828) 350-9368 Effluent Toxicity Report Form - Chronic Fathead Minnow Multi -Concentration Test Date: July 26, 2021 Facility: Environment 1, Inc. NPDES #: NC 0025909 Pipe #: 001 County: Rutherford Rutherfordton WWTP Laboratory Performing Test: Environmental Testing Solutions, Inc., Certificate # 037 Signature of Operator in Responsible Charge (ORC): ORC Phone / E-mail: Signature of Laboratory Supervisor: e-Mail to: ATForms.ATB@ncdenr.Rov Comments Project 0: 16066 Sample 0 210712.01, 210714.01, 210716.0: Or Mail Original to: North Carolina Division of Water Resources Water Sciences Section / Aquatic Toxicology Branch 1621 Mail Service Center Raleigh, NC 27699-1621 Test Start Date: July 13, 2021 Control Organisms % Effluent 11.25 % % Effluent 22.5% % Effluent 45% % Effluent 72.5% % Effluent Water Quality Data Control pH (SU): DO (mg/L): Temp. (°C): High Concent pH (SU): DO (mg/L): Temp. (°C): 100% Test Organisms: Pimephales promelas Replicate number 1 2 3 Supplier 4 In-house Culture Begin hatch: End hatch: Surviving number of larvae 10 10 10 10 Original number of larvae 10 10 10 10 Weight/original (mg/larvae) 0.930 0.860 0.808 0.891 Surviving number of larvae 10 10 10 10 Original number of larvae 10 10 10 10 Weight/original (mg/larvae) 0.750 0.824 0.732 0.768 Surviving number of larvae 10 10 10 10 Original number of larvae 10 10 10 10 Weight/original (mg/larvae) 0.730 0.758 0.888 0.936 Surviving number of larvae 10 10 10 10 Original number of larvae 10 10 10 10 Weight/original (mg/larvae) 0.718 0.805 0.704 0.895 Surviving number of larvae 10 10 10 10 Original number of larvae 10 10 10 10 Weight/original (mg/larvae) 0.811 0.835 0.810 0.827 Surviving number of larvae 10 10 10 10 Original number of larvae 10 10 10 10 Weight/original (mg/larvae) 0.831 0.787 0.819 0.741 07-12-21 1430 07-13-21 0505 Survival (%) Average wt (mg) Average wt / surviving (mg) Survival (%) Average wt (mg) Survival (%) Average wt (mg) Survival (%) Average wt (mg) Survival (%) Average wt (mg) Survival (%) Average wt (mg) 100.0 0.872 0.872 100.0 0.769 100.0 0.828 100.0 0.781 100.0 0.821 100.0 0.795 Day 0 Day 1 Day 2 Day 3 Day 4 Day 5 Day 6 Initial Final Initial Final Initial Final Initial Final Initial Final Initial Final Initial Final 7.97 7.83 7.89 7.64 7.86 7.52 8.03 7.76 7.94 7.85 8.14 7.87 7.99 _ 7.77 7.7 7.8 7.6 7.5 7.7 6.7 7.7 7.4 7.7 7.6 7.8 7.5 7.7 7.5 24.8 24.5 24.7 24.5 24.8 24.5 24.8 24.5 24.7 24.6 24.8 24.6 24.7 24.6 7.09 6.98 6.99 6.85 7.66 7.31 7.83 7.56 7.89 7.70 7.94 7.76 7.88 7.65 8.0 7.7 7.8 7.4 8.0 6.8 8.0 7.3 8.0 7.4 8.0 7.6 7.8 7.6 25.0 24.5 24.8 24.6 25.0 24.6 25.0 24.6 24.9 24.5 25.0 24.5 24.9 24.5 Sample Information Collection start date: Grab: Composite duration: Alkalinity (mg/L CaC0a): Hardness (mg/L CaC05): Conductivity ()mhos/cm): Total residual chlorine (mg/L): Sample Temp. at Receipt (°C): Overall Analysis: Sample 1 Sample 2 Sample 3 Control 07-11-21 07-13-21 07-15-21 24-h 24-h 24-h 20 47 45 58-59 42 38 36 83-87 285 267 266 301-318 < 0.10 < 0.10 < 0.10 1.7 3.3 2.2 Analyses Normal: Hom. Var. NOEC: LOEC: ChV: Method: Survival Growth Yes Yes Yes Yes 100% 100% >100% >100% >100% >100% Visual Insp. Dunnett's Survival Growth % Effluent Critical Calculated Critical Calculated 11.25% 2.410 2.332 22.5% 2.410 0.995 45% 2.410 2.062 72.5% 2.410 1.158 100% 2.410 1.748 Result: PASS LOEC: >100% NOEC: 100% ChV: >100% DWR Report Form AT-5 Page 1 of 5 Environmental Testing Solutions, Inc. Chronic Whole Effluent Toxicity Test (EPA-821-R-02-013, Method 1000.0) Species: Pimephales promelas Client: Rutherfordton WWTP NPDES #: NC 0025909 Project #: llootolo Dilution preparation: County: Rutherford Outfall #: 001 Dilution prep (%) 11.25 22.5 45 72.5 100 Sample was not aerated or treated unless otherwise Effluent volume (mL) 112.5 225 450 725 1000 noted on this form. Sample was warmed to 25.0 ± 1.0°C Diluent volume (mL) 887.5 775 550 275 0 in a warm water bath and then diluted to the test Total volume (mL) 1000 1000 1000 1000 1000 concentrations with moderately hard synthetic water (MHSW). Test organism information: Test information: Organism source: In-house culture Randomizing template: hp l(,i- ()pa. Age: < 24-hours old Incubator number and shelf location: l Spawn date: 61.01..-11 Artemia CHM number: CHM1149 Hatch dates and times: 61. ‘Z• -IA 6`4 1 0 0-1- V'S•I_ OS OS Drying information for weight determination: Date / Time in oven: 61.1 A-11 RA 1 *Initial oven temperature: ia+J • C. Transfer vessel information: pH (S.U.) = $. •, 5 Temperature (°C) = tip. (1 Date/rime out of oven: 01-IN•21 Ole-k& *Final oven temperature: (0(1 C. Average transfer volume (mL): < 0.25 mL Total drying time: '1."‘•kkOJIILS *60°C Oven, Thermometer SN: 14-985B5 Daily feeding and renewal information: Day Date Morning feeding Afternoon feeding Test initiation, renewal, or termination Sample number used MHSW batch used Time Analyst Time Analyst Time Analyst 0 07-13-21 OS ID 11J1S '� U135 1A 'U fn►Z- o l a-1• o a zl L 1 rot 1 "LOp OR I 0 ( ( 2 07-15-21 C3(9o0 11. o0 1�1 0 g ID U � K ZI TWA. 0 t 0-1• It 7.1 I 3 07-16-21 01900 11,00 kt 0 �, I D Ai 4 07-17-21 O(, GO p 6 OU (j{ (? I O 116166. O l 6'1. 1c 1.1 A 5 07-18-21 0.S00 1100 ' ` lt olio rt? 01-15-u& 6 07-19-21 OS UQ 11 I ((7O Li 0-1, ® fj( 5✓ L 7 07-20-21 l Oi G Chemical analyses: Parameter Reporting Limit Method number Meter Serial number pH 0.1 S.U. SM 4500-H+ B-2011 Accumet AR20 93312452 Dissolved Oxygen (D.0.) 1.0 mg/L SM 4500-0 G-2011 YSI Model 52CE 18D104324 Conductivity 14.9 µmhos/cm SM 2510 B-2011 Accumet AR20 93312452 Alkalinity 5.0 mg CaCO3/L SM 2320 B-2011 Accumet AR20 93312452 Hardness 5.0 mg CaCO3/L SM 2340 C-2011 Not applicable Not applicable Chlorine, Total Residual 0.1 mg/L ORION 97-70-1977 Accumet AB250 92349123 Temperature 0.1°C SM 2550E-2010 Digital Thermometer tjbb(nc'V5 Control information: Acceptance criteria Summary of test endpoints: Mortality: Q 1, 5 20% 7-day LC so( ) ) 61301, Average weight per initial larvae: 0. 811- NOEC (%) 1007. Average weight per surviving larvae: 0 • (L 1 Z >_ 0.25mg/larvae LOEC (%) ) 1001, ChV (%) e 1007 IC25 (%) "0 106 1. SOP AT2O-Revision 6—Exhibit AT20.3 Page 2 of 5 Environmental Testing Solutions, Inc. Species: Pimephales promelas Client: Rutherfordton WWTP Survival and Growth Data Date: 07-13-21 Day CONTROL 11.25% 22.5% A B C D E F G H 1 J K L 0 10 10 10 10 10 10 10 10 10 10 10 10 1 10 (o io 10 10 10 10 to 10 io to (o 2 (0 /0 10 10 10 (0 1D 10 (p 10 to io 3 lb /0 10 10 l0 ID 10 10 10 10 10 10 4 IQ (v 10 10 10 10 1.0 10 ID 10 (u ID 5 10 10 10 10 10 10 10 10 10 10 10 10 6 I0 10 10 10 10 10 (0 10 10 10 (0 ID 7 l0 10 10 ID +(3 10 10 10 ►0 ID ►0 1t *A = Pan weight (mg) Tray color code: eLV P1 t,t1.6J 1S.11 1.Q 13.6-1 13.-A IS. l % IS.c(O IS. g1 l5.li ty.6g p(.5°( t`{.13 Analyst: X( Date: C' n'v *B = Pan + Larvae weight (mg) Analyst: (Y),1. 23.°i3 2.4•3-ir 23.210 21.9 g 21.29 23.43 22: r2 23.y9 22.44 22 210 2`1F 2-9 •`l Date: 0";-7_2-2) C = Larvae weight (mg) = B -A Analyst: Gl.10 gasp ,.0Q o t "1.50 g. I.A '1 •'S2 1,( 'i. �D -1.s E' g, a ci.510 Weight per initial number of larvae (mg) = C / Initial number of larvae Analyst: q O 04) 0 O G‘ ® CS' 17 O. cri O bQ ' O . O. n' A, O. (V Ae=' ® ^� kY c'� 4� ® � V. r�0 1%� 0. (1 ' Average weight per initial number of larvae (mg) Percent reduction from control (%) 0. %i`— 0.16E 11.`1 I_ d, g La S. 1 %. *Weight measurements performed using Cahn 28 Automatic Electrobalance, SN 41520. Comment codes: c = clear, d = dead, fg = fungus, k = killed, m = missing, sk = sick, sm = unusually small, Ig = unusually large, d&r = decanted and returned, w = wounded. Comments: SOP AT20-Revision 6—Exhibit AT20.3 15 Page 3 of 5 Environmental Testing Solutions. Inc. Species: Pimephales promelas Client: Rutherfordton WWTP Survival and Growth Data Date: 07-13-21 Day 45% 72.5% 100% M N 0 P Q R S T U V W X 0 10 10 10 10 10 10 10 10 10 10 10 10 1 (p ID 10 ID 10 10 (0 10 (0 10 10 ID 2 (0 ID ID I1) 10 ID 10 10 10 (0 10 /0 3 ID /0 /0 /0 10 10 10 10 10 10 10 10 4 10 (0 10 10 10 10 10 10 10 10 10 10 5 10 /0 11) 11 10 10 10 10 10 /() 10 /0 6 10 10 ID 10 10 10 (0 to 10 I0 r0 '0 7 10 l0 Ip 110 10 10 Ip Ip i0 1p 10 10 *A = Pan weight (mg) Tray color code: i,.Ue>1 Iy. g& I�.1,ti I gl A 15.2V 13 .`1ti 1 `l. to3 322 14.21 ISM_ 13. S 1 3.gd I 3LgAnalyst: Date: Ql • UI•'2.1 *B = Pan + Larvae weight (mg) Analyst: MII` 22.o(o �9q. -J -71 bs 2a01 24.21 22.05 2:2-fl,G 2.1.32 24.L B 23.A3 2-1.02 219101 2A,1,9 Date: r . tit-11 C = Larvae weight (mg) = B — A Analyst: V, g G•os 1.64 6'•`1S s.11 &. 5s S• 10 L. ").-1 g.31 1.0 pb.16$ 1.41 Weight per initial number of larvae (mg) = C / Initial number of larvae Analyst: w n 0. (1 0 o N O g/ Co 0. 0 h 41 O. o � 0. N Q''Cb� 0. \ 0. iNc& 1j• qD\ 0• 0' Average weight per initial number of larvae (mg) Percent reduction from control (%) 0.1i;\ IU.57• CD.��-` S.°1 7. (�. 1�t5 8 7. *Weight measurements performed using Cahn 28 Automatic Electrobalance, SN 41520. Comment codes: c = clear, d = dead, fg = fungus, k = killed, m = missing, sk = sick, sm = unusually small, Ig = unusually large, d&r = decanted and returned, w = wounded. Comments: SOP AT2O-Revision 6—Exhibit AT20.3 Rutherfordton WWTP N 0 N J N O N 0 O 0 O ct tn N O N O N. O O D N N N 0 • a E E • c 0 u 0 W 'o' E In Mean weight/Initial Coefficient of variation Percent reduction from number of larvae (%) control (Y.) (mg) Not applicable VI ru.1 ea O Ill N Vl ti eill .1 Ill N m O 0 m n O coV N con O m O O O Meansurvival (%) o O o O O 0 O M O O O 0 O O O O . Weight/ Initial number of larvae (mg) O 0 m 0 0 m .i 0 Ol 0 0 0.750 0.824 0.732 0,768 O N m n n O O m 1O m m m m o 0 0.718 0,805 0.704 0.895 m CO 0 0 0.810 0.827 co n 0 0 .m-I V 0 0 Coefficient of variation 'Pe.. weight v.r..ravi.e number al ur eel(%) Lori cul 0 3 E E co 0 e 0 w 0 CO 0 CO 0 v1 n 0 Weight / Surviving number of larvae (mg) 0.930 0.860 0.808 0.891 0 N m m 0ooa N m m 1p � n 0.730 0.758 0.888 0.936 W n 0000 0 v1 O 01 m 0.811 0.835 0.810 0.827 rt~I CO m m CO 0000 O. � Larvae weight (mg) =B-A m0 c ai ao o m 0) co eo 7.50 8.24 7.32 7.68 7.30 7.58 8.88 9.36 7.18 8.05 7.04 8.95 8.11 8.35 8.10 8.27 Tilt 69'0Z 8Z'ET 0T 0T X 61'8 66'TZ 08'ET 0T 0T M L8'L Z9'TZ SCET 0T 0T A TE'8 £L'EZ Zb'ST 0T 0T fl 3 01 = 3 23.93 24.37 23.26 21.98 21.29 23.43 n v N N 22.47 22.26 23.47 23.49 22.06 22.65 23.01 24.21 22.05 22.98 21.32 24.48 A = Pan weight (mg) v1 00 o m all n 0 .y Cr m 15.17 14.68 14.59 14.13 14.88 14.60 15.97 15.26 13.94 14.63 CA CA rrilc Final number of larvae 10 10 0 0 0 0 0 0 0 0 0 0 0T OT O o 0 0 0 0 Initial number of larvae 10 10 10 10 0T 0T 0T 0T 0 0 0 0 0 0 0 0 0 0 0 0 1 Q m V n W LL l7 2- -• - E Z 0 m a K.,- Concentration (%) Control N . N N V N n O 0 0 n 0 O cally significant in a whole effluent toxicity test. the minimum percent difference between the control and treatment that can be declared s Statistical Analyses Environmental Testing Solutions, Inc. Entered by: Kelley Keen Reviewed by.: tint Sumner tl Larval Fish Growth and Survival Test-7 Day Growth Start Date: 7/13/2021 Test ID: PpFRCR Sample ID: Rutherfordton End Date: 7/20/2021 Lab ID: ETS-Envir. Testing Sol. Sample Type: DMR-Discharge Monitoring Report Sample Date: Protocol: FWCHR-EPA-821-R-02-013 Test Species: PP-Pimephales promelas Comments: Conc-% 1 2 3 4 D-Control 0.9300 0.8600 0.8080 0.8910 11.25 0.7500 0.8240 0.7320 0.7680 22.5 0.7300 0.7580 0.8880 0.9360 45 0.7180 0.8050 0.7040 0.8950 72.5 0.8110 0.8350 0.8100 0.8270 100 0.8310 0.7870 0.8190 0.7410 Transform: Untransformed 1-Tailed Isotonic Conc-% Mean N-Mean Mean Min Max CV% N t-Stat Critical MSD Mean N-Mean D-Control 0.8723 1.0000 0.8723 0.8080 0.9300 5.907 4 0.8723 1.0000 11.25 0.7685 0.8811 0.7685 0.7320 0.8240 5.180 4 2.332 2.410 0.1072 0.7994 0.9165 22.5 0.8280 0.9493 0.8280 0.7300 0.9360 12.031 4 0.995 2.410 0.1072 0.7994 0.9165 45 0.7805 0.8948 0.7805 0.7040 0.8950 11.332 4 2.062 2.410 0.1072 0.7994 0.9165 72.5 0.8208 0.9410 0.8208 0.8100 0.8350 1.497 4 1.158 2.410 0.1072 0.7994 0.9165 100 0.7945 0.9109 0.7945 0.7410 0.8310 5.061 4 1.748 2.410 0.1072 0.7945 0.9109 Auxiliary Tests Statistic Critical Shapiro-Wilk's Test indicates normal distribution (p > 0.01) 0.97155 0.884 Bartlett's Test indicates equal variances (p = 0.07) 10.2973 15.0863 Skew Kurt 0.26798 -0.2758 Hypothesis Test (1-tail, 0.05) NOEC LOEC ChV TU MSDu MSDp MSB MSE F-Prob df Dunnett's Test 100 >100 1 0.10722 0.12293 0.00572 0.00396 0.25666 5, 18 Treatments vs D-Control Linear Interpolation (200 Resamples) Point % SD 95% CL(Exp) Skew IC05` 6.7384 IC10 >100 IC15 >100 IC20 >100 IC25 >100 IC40 >100 IC50 >100 indicates IC estimate less than the lowest concentration 0 50 100 Dose 150 0.9 0.8 0.7 t 3 0.6 2 (7 0.5 a p 0.4 1'- 0.3 0.2 0.1 0 Dose -Response Plot 1-tail, 0.05 level - - of significance U O N N N Q LO 8 Page 4 of 5 Environmental Testing Solutions, Inc. Species: Pimephales promelas Client: Rutherfordton WWTP Date: 07-13-21 Daily Chemistry: Temperatures performed at the time of test initiation, renewal or termination by the analyst identified in the Daily Renewal Information table located on Page 1. Alkalinity, hardness and chlorine (total residual) performed by the analyst identified on the bench sheet specific for each analysis and transcribed to this bench sheet. Analyst Day (Analyst identified for each day, performed pH, D.O. and conductivity measurements only.) 0 1 2 rtsiit- L► p 1 tr-f Q••LJ) Lk -,Concentration Parameter CONTROL, MHSW pH (S.U.) .97 /� .83 " 6 sp -/ 4, ( -1•e�ti /� -i, Dissolved oxygen (mg/L) 3 a 4 -t-S -1/4 to.4 Conductivity (µmhos/cm) 3 (g 311- 3l42_ Alkalinity (mg CaCO3/L) 5.q ,.0 .�Iz-- 5A, Hardness (mg CaCO3/L) c� s AS Temperature(°C) ti-1. k -LA •S •A.A.1 Z4.5 -LA .k .'-' 11.25% pH (S.U.) -7• `1Z 11-ke f 5 45,1 B`t 14.4"1 Dissolved oxygen (mg/L) 3•q 4.'1 / CO 4-'4 ( 6, o (P/'� Conductivity (µmhos/cm) 30(0 310 303 Temperature (°C) %.4 . ci\\L9y,,�-, 1App,'��1 1..4.1 (o c zzsi pH (S.U.) -i• `Jg '4.': , f+4,2- s 7 -y1 t $� i-r/ 1{, 7 Dissolved oxygen (mg/L) Zr> ��,C� - ,11- 7` 1 aeo /,t,. 0.4 Conductivity (µmhos/cm) z� 3o0 bp). Zgl Temperature (°C) '\`(. C1 "Iy' 3 ,+ "v-k. • i -0. (� .1 -' • (= 45% pH(S.U.) 7•43 /� Q. 7.?'1 ..e-) -1•�11 1. %' 'JN3 te. O Dissolved oxygen (mg/L) .3.9 11 �4 Q �Y ` -r.-( 6-0 Conductivity(µmhos/cm) Z' 5 boL. Zr3(.9 Temperature (°C) "\", • 1 1_.-1.1. "LA. o L 1. 6 Itty.6t, Z-`�• t pH(S.U.) 3-53 37 �•`i' �2G "7•81 74.30 72.5 % Dissolved oxygen (mg/L) 6,0 ..y 1'.0 •.7 6.0 (0.6 Conductivity (µmhos/cm) Z9Z 2614 Z �r-5 Temperature (°C) IS. 0 Zi1.lo •\ ►l• ' / ---1,•.1 L't.9 1A - pH(S.U.) -y 'L-01 (D.1tc3 e ,(• .11 6.65 -4.U. 1.31 kLet oxygen (mg/L) , .0Dissolved (IA- - 'r.1,61 • N 6O,0 Conductivity (µmhos/cm) ZS 2q 3 ZG I- 100% Alkalinity (mg CaCO3/L) 'LO r41 Hardness (mg CaCO3/L) 41, -1? Chlorine (mg/L) < () . 10 'O .l 0 Temperature (°C) -LS • 0 "IA . S -l- 8 1-'1. 6 ,0 ti (0 Initial Final Initial Final Initial Final SOP AT2O-Revision 6-Exhibit AT20.3 Page 5 of 5 Environmental Testing Solutions, Inc. Species: Pimephales promelas Client: Rutherfordton WWTP Date: 07-13-21 Analyst Day (Analyst identified for each day, performed pH, D.O. and conductivity measurements only.) 3 4 5 6 i/L, list, 0-1 r iMP 4 1' Concentration Parameter CONTROL, MHSW pH (S.U.) 0,1)3 1.34.0 4.94 4. es- P. r9 '4 '•1'c ?• 74 Dissolved oxygen (mg/L) 1. 7 1.4 7 q '7 (o ,moo ? ?- s '7 '7 -y- 5- T Conductivity(pmhos/cm) aDt 30 31 .7P-i-7 Alkalinity (mg CaCO3/1) St\ SR �`1 Hardness (mg CaCO3/1) �-'$. g -1 .g' - t% Temperature (°C) •.�O -Vt. Z.�•b r! .1A, Q 1, 1 1 .. �•1��,y-5 t: t ..'1 A.:\ •Lo 11.25% pH(S.U.) Btu\ 7415 J5_ TV ("NA .1 3.03 7.eo St.O �''']l 7 L9 -9W 7-el Dissolved oxygen (mg/L) 1q 715 11 7AI e- O ' -S 3-6' 3 5 7 Conductivity (pmhos/cm) 2'9'; 302. : - -_ 312. Temperature (°C) i.`A 1� -- -, i .� -1 • IA- •Q'IA�� . \ -N.A. d .. 22.5% pH (S.U.) /• N. 6 1.3 t 4.63 U Qq 4 (Ig-- 9t� �71.q.t� Z"• _r q Dissolved oxygen (mg/L) ' A 3.4. .' A- 6-A 7-.5- q oa "/ y Conductivity(pmhos/cm) Z:i O.4 491W„ ro‘ 3 Temperature (°C) i�l ."1 ,.,t• b 1}11l • ¢ ^ IA- to -.b p 6' 4 •"vit �LkJ 'L • t, i.A' S 45% pH(S.U.) gen 4 ► 3.Rl• /-30 S-ec 1-62s 7:19 1,q3 Dissolved oxygen (mg/L) ^-a `f -1.4 1 i 4,ei e ,0 45 �l3 S Conductivity (pmhos/cm) 1lo yQ p Z e_ ?Tea Temperature(°C) AAA .1 11.`►•tj `( p ` ,ter AS.-.S "'!•& -1 "LA.1 pH (S.U.) 766 3.62. y�•'9•b -A2. y1!'a 'f •71, y-LS.0 4-16 1-'9 7. 9" 1 71 72.5% Dissolved oxygen (mg/L) 1.4 1.,41 1, [J 6 0-.o 7. c) 7 g >,S 7 Conductivity (pmhos/cm) eV/e) 07 rto C LpZ, 2 i' Temperature (°C) 1.S ..�0 • S -1 . C t"6 • S ZS .0 �i�-'- -S `' .1, -i.\ . S pH (S.U.) rr - j'.e.3 -1-tA .C.54, '7 43 1 g40 I �7� ' ‹.. '`yA,, 7. de eas- Dissolved oxygen (mg/L) l7t . 4, Ito • c.t C-O Co '$.e. -7 Conductivity (pmhos/cm) a 69 40 Qe.247 Z6-4- ._7ia 4 7S 100% Alkalinity (mg CaCO,/L) , 1; Hardness (mg CaCO3/L) 6 Chlorine (mg/L) C©• 1 O Temperature (°C) 1-5 . O -VA. to -A A .1 't .S Z. O -S U, -• S y`� .' 6• ,+ 1.'i..S Initial Final Initial Final Initial Final Initial Final SOP AT20-Revision 6-Exhibit AT20.3 351 Depot Street Asheville, NC 28801 Phone: (828) 350-9364 Fax: (828) 350-9368 Environmental Testing Solutions, Inc. Whole Effluent Toxicity Chain -of -Custody Form Facility: SEUZ Rutherfordton WWTP Species: Pimephales promelas Test type: Chronic Definitive NPDES #: NC00259O9 Pipe #: 001 County: Rutherford Purchase order: Effluent dilution: 11.25, 22.5, 45, 90, 100% Parameter code: THP6C Sample information: (to be completed by sample collector) Composite sample: Start date: O U Time: C(9, End date: 0'1. C2--" Time: toz• Number of samples per hour: Chilled during collection? Y"2-S If chilled, specify temperature: Triple rinse sample container with sample before filling. Sample location: Volume collected for testing: Number of containers filled for testing: Method of transport to laboratory: Comments: Completely fill the sample container with no air space. Pack the sample container completely in ice. The sample must be < 6.0°C upon receipt at the laboratory. Sample custody: (to be completed by sample collector and facility personnel) BY SIGNING BELOW, I CERTIFY THAT THE PERMIT AND TEST REQUIREMENTS IDENTIFIED ON THIS FORM ARE ACCURATE Sample collected lay: ,-,..tot Relinquished by: Relinquished by: `-- 07.E z- `f t..\:\kr: Q xVs- Print Relinquished by: lure Date and time Received by: 1ftv1%00I -7- I2-2.1 - raW►.t�,' %lam riot Received by: Signature Dale and time Print Signature Dam and lime Sample receipt information: (to be completed by ETS personnel) Relinquished to ETS by: VOrb1 v0.W 12-2,1 1 p'- i rent Custody seals intact?: F Yes Signature No Samples received in good condition?: Tracking number: Comments: Not used Yes Date and lime No +ix+ 1Z7-f Print Received at ETS by: Signature Date and time lib- IA- u+•12.21 /17 4 1 Print Signature Sample temperature upon receipt at ETS (°C): Total residual chlorine upon receipt at ETS: Date and time (DPD Presence/Absense Indicator, MDL = 0.10 mg/L) Pre.rnt Absent Project number: (paou,Sample number: Zi 17}IL.01 Environmental Testing Solutions, Inc. Whole Effluent Toxicity Chain -of -Custody Form 351 Depot Street Asheville, NC 28801 Phone: (828) 350-9364 Fax: (828) 350-9368 Facility: SEUZ NPDES #: NCOO259O9 Pipe #: 001 County: Rutherford Rutherfordton WWTP Purchase order: Species: Pimephales promelas Test type: Chronic Definitive Effluent dilution: 11.25, 22.5, 45, 90, 100% Parameter code: THP6C Sample information: (to be completed by sample collector) Composite sample: Start date: CP—lS-14 End date: pi Number of samples per hour: Chilled during collection? If chilled, specify temperature: Time: Time: sz yzi Sample location: Volume collected for testing: Number of containers filled for testing: Method of transport to laboratory: Comments: Triple rinse sample container with sample before filling. Completely fill the sample container with no air space. Pack the sample container completely in ice. The sample must be < 6.0°C upon receipt at the laboratory. Sample custody: (to be completed by sample collector and facility personnel) BY SIGNING BELOW, I CERTIFY THAT THE PERMIT AND TEST REQUIREMENTS IDENTIFIED ON THIS FORM ARE ACCURATE Sample collected by: o L `...— Q.r— --t. �" - 1'D Relinquished by: tl I"— e. 0. + cs)-''(4 -t-i not Relinquished by: Si nature Dale and time Received by: Ma ct 0,,, *74 tint Received by: Signature Date and lime Print Signature Date and time Sample receipt information: (to be completed by ETS personnel) Relinquished to ETS by: 1Q(4-' Ouoo not Custody seals intact?: J Yes Signature No Samples received in good condition?: Tracking number: Comments: Nol used Yes Date and time No Print Received at ETS by: Signature Date and time l ,c, 0.4A y,14 not Signature Sample temperature upon receipt at ETS (°C): Total residual chlorine upon receipt at ETS: (DPD Presence/Absense Indicator MDL = 0.10 mg/L) Project number: 1 "1 T Sample number: /1 1(4 •01 tit Wu) Date and time 33. Present Absent 351 Depot Street Asheville, NC 28801 Phone: (828) 350-9364 Fax: (828) 350-9368 Environmental Testing Solutions, Inc. Whole Effluent Toxicity Chain -of -Custody Form Facility: SEUZ Rutherfordton WWTP Species: Pimephales promelas Test type: Chronic Definitive NPDES #: NC0025909 Pipe #: 001 County: Rutherford Purchase order: Effluent dilution: 11.25, 22.5, 45, 90, 100% Parameter code: THP6C Sample information: (to be completed by sample collector) Composite sample: Start date: co -1, (- •t- Time: ') c'10 End date: co') Number of samples per hour: Time: Chilled during collection? Va-s) If chilled, specify temperature: '4 • Sample location: Volume collected for testing: Number of containers filled for testing: Method of transport to laboratory: Comments: Triple rinse sample container with sample before filling. Completely fill the sample container with no air space. Pack the sample container completely in ice. The sample must be < 6.0°C upon receipt at the laboratory. Sample custody: (to be completed by sample collector and facility personnel) BY SIGNING BELOW, I CERTIFY THAT THE PERMIT AND TEST REQUIREMENTS IDENTIFIED ON THIS FORM ARE ACCURATE Sample collected by: - Relinquished by: -rtolds o �- t o I Print Relinquished by: Signature Date and time Received by: Ki2/Ct- (l� I !/ -( Print Received by: Signature Date and time Print Signature Dale and limo Sample receipt information: (to be completed by ETS personnel) Relinquished to ETS by: 9 1-0 Print Signature Custody seals intact?: Yes No Not used Samples received in good condition?: 111 Yes Tracking number: Comments: Date and time No Print Received at ETS by: Print Signature Signature Sample temperature upon receipt at ETS (°C): Total residual chlorine upon receipt at ETS: Dale and time Date and limo (DPD Presence/Absense Indicator, MDL = 0.10 mg/L) PfSenl Absent Project number A�b� Sample number: Ai (51'b'0 7-day IC25 (g/L KC!) Environmental Testing Solutions, Inc. 0.9 0.8 0.7 0.6 1.2 1.0 0.8 0.6 0.4 Pimephales promelas Chronic Reference Toxicant Control Chart Source: In-house Culture I I 1 1 I 1 11 1 1 1 1 1 1 1 I 1 1 11 • • • Control Limits (± 2 Standard Deviations) • • • • • • • • • • • • • • • 11 III 11 III 11 III 11 III 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Warning Limits • • • • 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 0101 � �,0�0O,03,O0� .050'SS'6 3 ��'�1 1-3y6" -3�)oS)90.01011,.0�,0$p-01 �O1'a06�0DO0a-01'�11.y6.1, Test date • 7-day IC25 = 25% inhibition concentration. An estimation of the potassium chloride concentration which would cause a 25% reduction in Pimephales growth (calculated using ToxCalc). Central Tendency (mean logarithmic IC25 converted to anti -logarithmic values) Control Limits (mean logarithmic IC25 ± 2 standard deviations converted to anti -logarithmic values) Laboratory Warning Limits (mean logarithmic IC25 ± 2 coefficent of variations converted to anti -logarithmic values) USEPA Warning Limits (mean logarithmic IC25 ± SA 75 converted to anti -logarithmic values, SA75 = 75th percentile of CVs reported nationally by USEPA) Inter,ed ed iewedby m 5umne Environmental Testing Solutions, Inc. May 19, 2021 Ms. Ann Baynor Environment 1, Inc. PO Box 7085 Greenville, NC 27835 ETS Project Number: 15940 Test Start Date: May 04, 2021 Facility Tested: Rutherfordton WWTP PO Box 7565 Asheville, NC 28802 Phone: (828) 350-9364 Fax: (828) 350-9368 Enclosed are toxicity test results for samples received by Environmental Testing Solutions Inc. Parameter Code Test Procedure, Method Number Result (ChV) THP6C Fathead minnow, Pimephales promelas , Larval Survival and Growth Chronic EPA-821-R-02-013, Method 1000.0 >100% All toxicity testing results required as part of your permit must be entered on the Effluent Discharge Monitoring Form (MR-1) for the month in which it was performed, using the parameter code THP6C. Additionally, the DMR Reporting Form AT-5 must be signed and e-mailed or mailed to the following address: ATForms.ATBia'?,ncd enr. qov North Carolina Division of Water Resources Water Sciences Section / Aquatic Toxicology Branch 1621 Mail Service Center Raleigh, NC 27699-1621 Please call if you have any questions concerning these results. Sincerely, Jim Sumner Laboratory Supervisor North Carolina Certificate Numbers: Biological Analyses: 037, Drinking Water: 37786, Wastewater: 600 South Carolina Certificate Number: Clean Water Act: 99053-001 Environmental Testing 5olutimn, Inc PO Box 7565 Asheville, NC 28802 Phone: (828) 350-9364 Fax: (828) 350-9368 Effluent Toxicity Report Form - Chronic Fathead Minnow Multi -Concentration Test Date: May 19, 2021 Facility: Environment 1, Inc. NPDES #: NC 0025909 Pipe #: 001 County: Rutherford Rutherfordton WWTP Laboratory Performing Test: Environmental Testing ions, In er Mate # 037 Signature of Operator in Responsible Charge (ORC): ORC Phone / E-mail: Signature of Laboratory Supervisor: 44.{0.}.1;?...-" Comments Project SI: 15940 Sample 0: 210503.02, 210505 01, 210507 0 e-Mail to: ATForm5.AT8C1ncdenr.8ov Or Mail Original to: North Carolina Division of Water Resources Water Sciences Section / Aquatic Toxicology Branch 1621 Mail Service Center Raleigh, NC 27699-1621 Test Start Date: L My 04, 2021 Control Organisms % Effluent Test Organisms: Pimephales promelas Supplier Replicate numbe 1 2 3 4 In-house Culture Begin hatch: End hatch: Surviving number of larvae 10 10 10 10 Original number of larvae 10 10 10 10 Weight/original (mg/larvae) 0.796 0.755 0.746 0.850 Surviving number of larvae 10 10 10 10 11,25% % Effluent % Effluent f 45% % Effluent Original number of larvae W eight/original (mg/larvae) 10 10 0.752 0.806 10 0.783 10 0.794 Surviving number of larvae 10 10 10 10 Original number of larvae 10 10 10 10 'Weight/original (mg/larvae) 0.766 0.775 0.782 0.785 Surviving number of larvae Original number of larvae 10 10 10 10 10 10 10 10 72.5% Effluent Weight/original (mg/larvae) 0.800 0.831 0.817 0.768 Surviving number of larvae 10 10 10 10 Original number of larvae 10 10 10 10 Weightioriglnal (mg/larvae) 0.870 0.782 0.912 I 0.842 100% Water Quality Data Control pH (SU): DO (mg/L) Temp. (°C): High Concent pH (SU): DO (mg/L): Temp- (°C): Surviving number of larvae 10 10 10 10 Original number of larvae 10 10 10 10 'Weight/original (mg/larvae) 0.767 0.822 0.853 0.817 05.03-21 1430 05.04-21 0557 Survival (%) Average wt (mg) Average wt / surviving (mg) Survival (%) Average wt (mg) Survival (%) Average wt (mg) Survival (%) Average wt (mg) Survival (%) Average wt (mg) Survival (%) Average wt (mg) 100.0 0.787 0.787 100.0 0.784 100.0 0.777 100.0 0.804 100.0 0.852 100.0 0.815 Day 0 Initial Final Day 1 Initial 1 Final Day 2 initial Final Day 3 Initial r Final Day 4 Initial Final Day 5 Initial Final Day 6 Initial Final 8.09 7.49 7.57 7.47 7.63 7.38 7.80 7.39 7.63 7.54 7.74 8.20 8.42 8.05 7.6 7.7 7.7 7.8 7 7 7.4 7.7 7.3 7.9 7 4 7.7 7.5 7.7 7.5 24.8 25.0 24.8 24.7 24.7 24.8 24.8 24.7 24.8 24.5 24.7 25.0 24.8 24.5 7.97 7.29 7,41 7.39 7.40 7.00 7.42 7.07 7.25 7.08 7.24 7.80 7.79 7.62 7.9 7.7 7.8 7.9 7.8 7.3 8.1 7.2 7.9 7 3 7.8 7 4 7.9 7.6 25.0 24.9 25,0 24.9 25.0 24.7 25.0 24.7 _ 25.0 24.5 24.8 . 24.9 25.0 24.6 Sample Information Collection start date: Grab: Composite duration: Alkalinity (mg/L CaCOs): Hardness (mg/L CaCO3): Conductivity (pmhos/cm): Total residual chlorine (mg/L): Sample Temp. at Receipt (°C): Overall Analysis: Sample 1 Sample 2 Sample 3 Control J 05-02-21 05-04-21 05-06-21 24-h 24-h 24-h 42 32 27 59,61,61 36 36 36 83,87,83 261 253 254 306-318 < 0.10 < 0,10 < 0.10 3,3 1.3 3.3 Analyses Normal: Horn, Var. NOEC: LOEC: ChV: Method: Survival Growth Yes Yes Yes Yes 10096 100% >100% >100% >100% >100% Visual Insp. Dunnett's Survival Growth % Effluent Critical Calculated Critical Calculated 11.25% . 2.410 0.098 22.5% . 2.410 0.381 45% - 2.410 -0.674 72.5% - - 2.410 -2.531 100% 2.410 -1.095 Result: PASS LOEC: >100% NOEC: 100% ChV: >100% DWR Report Form AT-5 Page 1 of 5 EnvlranmentalTesling Solull°ns, Inc. Chronic Whole Effluent Toxicity Test (EPA-821-R-02-013, Method 1000.0) Species: Pirnephales pramelas Client: Rutherfordton WWTP NPDES #: NC 0025909 Project #: ‘Sa-to Dilution preparation: County: Rutherford Outfall #: 001 Dilution prep (%) 11.25 22.5 45 72.5 100 Sample was not aerated or treated unless otherwise Effluent volume (mL) 112.5 225 450 725 1000 noted on this form. Sample was warmed to 25.0 ± 1,0°C Diluent volume (mL) 887.5 775 550 275 0 in a warm water bath and then diluted to the test Total volume (mL) 1000 1000 1000 1000 1000 concentrations with moderately hard synthetic water (MHSW). Test organism information: Test information: Organism source: In-house culture Randomizing template: 02-NJliQ Age: < 24-hours old Incubator number and shelf location: to 11 Spawn date: n.1.-14 *IA Artemia CHM number: CHM1149 Hatch dates and times: OS •6S'1.% i%k Q -rDrying OS-0`1- IA 0 SS"1 information for weight determination: Date / Time in oven: DS-1l1J QUO *Initial oven temperature: Ir o • C Transfer vessel information: pH (S.U.) = 8. O Temperature (°C) = 1.4. Date / Time out of oven: n5-t1-•l.4 of 10 i o •C *Final oven temperature: Average transfer volume (mL): < 0.25 mL Total drying time: -1A-Aodtt$ *60°C Oven, Thermometer SN: 14-985B5 Daily feeding and renewal information: Day Date Morning feeding Afternoon feeding Test initiation, renewal, or termination Sample number used MHSW batch used Time Analyst Time Analyst Time Analyst 0 05-04-21 o to 00 K 11-00 IA 0 e s t -1.1 aStr5.e-. 4.j1.1•u A 1 05-05-21 O SOO x 1l oo g cis — t 1 .tom 2 05-06-21 aeon u • rEoO o$ a 9 1tOSD5 .0 oil Z1uC 3 05-07-21 oSOc I- 1 01SL pi I 1.r a OS-Os-21 pt.00 hr I ZpV�.14_ j� o f SO 1(14 6CI, ok ns•ob-u A 5 05-09-21 OtooO t vlo Os�Q 6 05-10-21 6,,rM $oSo') MU A �SU \.. - 7 05-11-21 () 8 g lk Chemical analyses: Parameter Reporting Limit Method number Meter Serial number pH 0.1 S.U. SM 4500-H+ B-2011 Accumet AR20 93312452 Dissolved Oxygen (D.0.) 1.0 mg/L SM 4500-0 G-2011 YSI Model 52CE 18D104324 Conductivity 14.9 µmhos/cm SM 2510 B-2011 Accumet AR20 93312452 Alkalinity 5.0 mg CaCO3/L SM 2320 B-2011 Accumet AR20 93312452 Hardness 5.0 mg CaCO3/L SM 2340 C-2011 Not applicable Not applicable Chlorine, Total Residual 0.1 mg/L ORION 97-70-1977 Accumet AB250 92349123 Temperature 0.1°C SM 25506-2010 Digital Thermometer t3oblo 468S Control information: Acceptance criteria Summary of test endpoints: % Mortality: r o7. <_ 20% 7-day LCso (%) , I Op 7. Average weight per initial larvae: 0.1 kl NOEC (%) 1 bpi. Average weight per surviving larvae: 0.1 (t 1 L. 0,25mg/larvae LOEC (%) > I OQi. ChV (%) 160 1, IC25 (%) > I on 7. SOP AT2O-Revision 6—Exhibit AT20.3 Page 2 of 5 EnvIron mental Testing Solutions, Inc. Species: Pimephales promelas Client: Rutherfordton WWTP Day 0 1 2 3 4 5 6 7 *A = Pan weight ) Tray color codee4C n Analyst: Date: 1 i . W .24 *B = Pan + Larvae weight (mg) Analyst: Date: AS - t6 • II C = Larvae weight (mg) = B — A Analyst: Weight per initial number of larvae (mg) = C / Initial number of larvae Analyst: Average weight per initial number of larvae (mg) Percent reduction from control (%) A 10 10 10 10 10 /0 da to 27,.5°1 hP r CONTROL B 10 ID 10 to 10 /U /0 10 Il b2fo 1Z.Q1 •.'.SS y� 1- 0.'1% 1 C 10 to 10 10 10 JV /1 10 INAS 1•yb _ 10 10 1 0 ID Ip /0 10 11,118 /4- so 1O O Survival and Growth Data E 10 10 10 10 1p /0 /0 10 811 1.57. 11.25% F 10 10 10 I0 10 /0 /0 10 /y.UB R. O. f o ."111 10 to 10 10 10 /0 /0 10 Iy q► -1.1 b n *Weight measurements performed using Cahn 28 Automatic Electrobalance, SN 41520. 10 1p 10 l 1J (0 /0 lO 10 15,4 O Date: 05-04-21 10 ID (0 16 10 /v l0 10 139i 0. 22.5% J 10 I0 10 IO 10 10 l0 /0 12.310 O Comment codes: c = clear, d = dead, fg = fungus, k = killed, m = missing, sk = sick, sm = unusually small, Ig = unusually large, d&r = decanted and returned, w = wounded. 10 10 10 10 10 l0 ID 1D 114.32 1.12 N O' r Comments: L 10 Cb 10 ID 10 /l JD 0 /3.►6 1.&S n O SOP AT20-Revision 6—Exhibit AT20.3 Page 3 of 5 Environmental Testing Solutions, Inc, Species: Pimephales promelas Client: Rutherfordton WWTP Date: 05-04-21 Survival and Growth Data Day 0 10 45% N 0 10 10 P 10 10 72.5% R 10 S T 10 10 u 10 10 100% w 10 x 10 1 10 (0 10 2 3 4 5 6 7 *A = Pan weight (mmj, Tray color code Analyst: VI—. Date: 01(.10•2.( *B = Pan + Larvae weight (mg) Analyst: a� Date: O S. 11 C = Larvae weight (mg) = B — A Analyst: Weight per initial number of larvae (mg) = C / Initial number of larvae Analyst: , Average weight per initial number of larvae (mg) Percent reduction from control (%) 0 to I0 10 to 0' Ip 1p 1 0 1 0 l0 10 10 ID (0 10 5.01 13A o -1:1431 11.m g•31 !i•►1 4.3 O• O• 10 10 10 /0 (0 15.36 O• a•goa -2.21. 10 l0 10 (D /0 ID u.r- 10 (10.44 n0 O tp (0 10 l0 o 10 115.2 es.�N 0.IsS2 10 10 l0 t0 (D (0 (D 10 /0 10 ID la L 10 rb l3.(ta 13.93 11.1& 1.1.-35 g.lt 8•1-11.. 00' 10 I0 10 Ip 10 13.24 1.11 O' 10 (0 10 I0 /1) /D 10 alit° g•11. O. 0.cAS 10 1D Ip 10 /0 lo /0 I3.941 -LZ.4'l 8.53 0 10 1 0 1 0 1p /0 /0 1O 115.90 8.1'1 O• *Weight measurements performed using Cahn 28 Automatic Electrobalance, SN 41520. Comment codes: c = clear, d = dead, fg = fungus, k = killed, m = missing, sk = sick, sm = unusually small, Ig = unusually large, d&r = decanted and returned, w = wounded. Comments: SOP AT2O-Revision 6—Exhibit AT20.3 Quality Control: Verification of Data Entry, Calculations, and Statistical Analyses Rutherfordton WW1? Project number: 15940 Sample numbers 210503.02, 210505.01, 210507.01 Percent reduction front control Ixl A - o. Z d O .Ni N N N W ; $ X _ x 0 z. 0 .o m .'i i 0 rri v 1n e e Mean .., hht 11041 number of ame lmrl 0 o m n m F O O O N O .N. O rt X T O Ft 0 o O 5 O N O o O 0 E 1 ..2..nn 3 0 o 0.746 0.850 n 0 0 n o 0 n•n 0 0 0 .0 a°w 0 0 o° 0 0 0.870 0.782 0.912 0.842 0 0 mm 0 0 ' 9 X 8 ° m m o m 0 e il 3 E o i 2 - n 0 n 0 E. o m a w o a 0 co ial - 3 E Low 0 0 0 o 0.746 0 850 now 0 w d o ono. 6 0 loom o a 0 0 0.782 0.785 oo-In 0 0 O O co 0 0 O O o ru N 0 O G cti co 0 0 O O nt noon, 0 0 O O 0 00 O O E .'a 3 m i 9 88 n N 42 h °G v`n''i.o h O wm n n 2 n r n aq8 n n o m.ai m o° 2 ro r Po mr.�,c 10 •r. °i mo 1 r'm.n-i^ r� r4 c0 m 8 = Pan, Lama weicM (me) q E7,, N RI 32 ry N n."+nm N N N N 2115' N P.; N .N 22.74 23.32 oryrym N N 26.14 7 22.94 rvm ry N mma7m N N ry ry E - O a .G Vry .y to m m.r to .. n 8 rv0mv , H .-I 4 to ti ni °� mm .'-i `"a N m.'O+ .-i .. n om .. .-I O m .. �.�. O ry vui .1Oi . T nirn ..'a n l00 w .... m Om .1 s .. $ 3 0T Pc•0 0 o O5 10 10 00 0 0 0 o O Pc 00 10 10 52 li EE S '' 0 0 o o 5 o o 0 0 0 0 0„ 0 0 0 „ D 0 0 0 0 0 0 9 <ouowLLax.-,x-o2zooarocolnm>x : o 9 Control . N V n 8 ° 0 co 2 O O ti w 2 stically significant in a whole effluent toxicity test. ri Lower and upper PMSD bounds were determined from the 10th and 90th percentile, respectively, of PMSD data from EPA's WET Interlaboratory Variability Study (USEPA, 2001a; 0 .57 USEPA. 2001a, 2001b. Final Report: Interlaboratory Variability Study of EPA Short-term Chronic and Acute Whole Effluent Toxicity Test Methods, Volumes land 2-Appendix. EPA-821-8-01-004 and EPA-821-8-01-005. US Environ men:al Protection Age Statistical Analyses Environmental Testing 5olullons, Inc. Larval Fish Growth and Survival Test-7 Day Growth Start Date: 5/4/2021 Teal ID: PpFRCR Sample ID: Rulherfordton End Date: 5/11/2021 Lab ID: ETS-Envir. Testing Sol. Sample Type: DMR-Discharge Monitoring Report Sample Date: Protocol: FWCHR-EPA-821-R-02-013 Test Species: PP-Pimephales promelas Comments: Conc-% 1 2 3 4 0-Control 0,7960 0.7550 0.7460 0.8500 11.25 0.7520 0.8060 0.7830 0.7960 225 0.7660 0.7750 0.7820 0.7850 45 0.8000 0.8310 0,8170 0.7680 72.5 0.8700 0.7820 0.9120 0.6420 100 0 7670 0.8220 0,8530 0.8170 Transform: Untransformed 1-Tailed Isotonic Conc-% Mean N-Mean Mean Min Max CV% N t-Stat Critical MSD Mean N-Mean D-Control 0.7868 1.0000 0.7868 0.7460 0.8500 6.031 4 0,8030 1,0000 11.25 0,7843 0.9968 0.7843 0.7520 0.8060 2.993 4 0.098 2.410 0.0616 0.8030 1.0000 22.5 0.7770 0.9876 0.7770 0,7660 0.7850 1.087 4 0.381 2.410 0.0616 0.8030 1.0000 45 0.8040 1.0219 0.8040 0.7680 0.8310 3.376 4 -0.674 2.410 0.0616 0.8030 1.0000 72.5 0.8515 1.0823 0.8515 0.7820 0.9120 6.405 4 -2.531 2.410 0.0616 0.8030 1.0000 100 0.8148 1.0356 0.8148 0.7670 0.6530 4.369 4 -1.095 2.410 0,0616 0.8030 1.0000 Auxiliary Tests Statistic Critical Skew Kurt Shapiro-Wirles Test Indicates normal dis1ribullon ip > 0.01) 0.97037 0.884 -0 0786 0.20229 Bartlell'e Test indicates equal variances (.0 = 0.16) 8.0145 15.0863 Hypothesis Test (1-tail, 0.05) NOEC LOEC ChV TU MSDu MSDp MSB MSE F-Prob df Dunnett's Test 100 >100 1 0.06165 0.07036 0.00303 0.00131 0 08668 5, 18 Trealments vs D-Control Point IC05 >100 IC10 >100 IC15 >100 IC20 >100 IC25 >100 IC40 >100 1050 >100 Linear Interpolation (200 Resamples) SD 95% CL(Exp) Skew 1.0 0.9 0.8 0.7: 0.6 0.5 c a 0.4 g 0.3 - C 0.2 - 0.1 0.00p-0 D 9 -0.1 0.2 0 50 100 Dose % 150 Dose -Response Plot 0.9 a- 0.8 0.7 5 0.6 e c1 0.5 0.4 • 03 0.2 0.1 0 2 N ry N • N A O U O 1-tail, 0.05 level of significance Page 4 of 5 EnvironmentalTesting Solutions, Inc. Species: Pime_phales pramelas Client: Rutherfordton WWTP Date: os-o4-21 Daily Chemistry: Temperatures performed at the time of test initiation, renewal or termination by the analyst identified in the Daily Renewal Information table located on Page 1. Alkalinity, hardness and chlorine (total residual) performed by the analyst identified on the bench sheet specific for each analysis and transcribed to this bench sheet. Analyst Day (Analyst identified for each day, performed pH, D.O. and conductivity measurements only.) 0 1 2 _ Mr KO KD ICD Ko 1 i t' Concentration Parameter ` CONTROL, MHSW pH (S.U.) ��pp e. 09 7.'41 .-1.--; •1.'ri 7 .(j3 13 Dissolved oxygen (mg/L) . .1 -7.1 -7.-1 '). 3 -I.1 04 Conductivity (µmhos/cm) 3 l % '3Is 1'S Alkalinity (mg CaCO3/L) SC1 Ls Hardness (mg CaCO3/L) g j 6 fl:•t S-1 Temperature (°C) LA.. & %S.O • $ 1A.1 1?1• 1 t' • t 11.25% pH(S.U.) 46.ie -1.6I 1•671 1. 43 1.Lvv 1.1:1- /•'JJ Dissolved oxygen (mg/L) . Zg '%. Co 1.1 -1. 9 1.1 Conductivity (µmhos/cm) 3Ca13 3 r"1 71 1 Temperature (°C) 1A. $ 1` i • 1 "1-4 . -Ls- 0 1:1.1 1-c1• to 22.5% pH (S.U.) 8. IS 1. &18 1-C`i '1. 1.(tq 1.(.4 :4$ Dissolved oxygen (mg/L) `7.. 1g --j . (9 -1 .2) -L g -)•') .5 Conductivity (µmhos/cm) Zqy Sit, 3v3 Temperature (°C) AA. k •b •1 -LA -di 1,`1.. a. 1V'• $ �j-IA-I. i ,,ZZ 45% pH(S.U.) g0, 1. 1-1-1 1.5ci "1.yt.l 7.'% Dissolved oxygen (mg/L) 4 f9 1. t.9 % e 1 .1 7. ') 4.3 Conductivity (µmhos/cm) 2 rj I 10a 2e7 Temperature (°C) _\ .g LA .9 15 .1 1-4. g Z44. t 72 5/o pH(S.U.) 8.p'� '1.`12 1.`18 '1.`i3 1.53 �1�.el '1.110 Dissolved oxygen (mg/L) `4.1 1. V -2. g 1 . °I • ). $ 1.3 Conductivity (µmhos/cm) -2. Z 283 27Fa Temperature (°C) -).. t. \ NA, . ¢ ZS :0 '. . gP Z4. i 1.4.1 pH(S.U.) araY21 a.1.97/).-LnI 1.41 1.34 1.6Iv '1..00 Dissolved oxygen (mg/L) '1.ri 1. Z '7 .6 7. °( -I . % 1,3 Conductivity (µmhos/cm) 2 (, 1 2 (fr 2 S3 100% Alkalinity (mg CaCO3/L) LIZ 1-2_- Hardness (mg CaCO3/L) IL 3IQ Chlorine (mg/L) L Q , (0 ' 0 .ID Temperature (°C) IS, 0 1_y.9 tS . 0 14. `t 't-5.0 t 4.r1 Initial Final Initial it Final Initial Final SOP AT2O-Revision 6-Exhibit AT20. 3 Page 5 of 5 Environmental Testing Solutions. Inc. Species: Piimepholes prornelos Client: Rutherfordton WWTP Date: 05-04-21 Analyst Day (Analyst identified for each day, performed pH, D.O. and conductivity measurements only.) 3 4 5 6 IX Pbla_._P5•-• ` et5 i4-4S HI' SC r1S Concentration Parameter CONTROL, MHSW pH(5.U.) 14.Qo 1.ai 3.113 -9-9 3-'3 ! e,11?jEALrz 8-a5 Dissolved oxygen (mg/L) 153 1.3 4..9 '4' aI -1.3- ' a 1, i- s- 77 5 Conductivity(µmhos/cm) 3I.i i3 310 ?17 Alkalinity (mg CaCO,/L) Eat ~ Hardness (mg C.CO,/L) y.tYs� ? 8 S -1�-0K'V'I L Temperature(°C) Aak-a 1.`,.-1 1,4• 6 c 1.�`5 Zo.k.1 .0 'C,. I 1...5 11.25% pH(5.U.) '1%05 1.40 1./11 4.53 7. (.6, e-49 846 &03 Dissolved oxygen (mg/L) I O .1.2.• -4 At 3. 3 4.0 7. 3 4.9 -• 7 Conductivity (µmhos/cm) 310 Q� .�OS 3e1 Temperature(°C) 1.�-i ZA-1 "to-k•q 1..4-b -A-1 1A. a 'K. p\ Z Z'1.5 . zz.5i° rpH(s.u.) f.t[cj 13.41 1.(4 4 50 -4-(.'3 ezr5 ea 4-9� Dissolved oxygen (mg/L) e.0 1. 2 •1.1 '4.7 -B 4.3 7,9 7•5- Conductivity µmhos cm y( /) 3os a14 3o�t. .z96 Temperature (°C) '.1 a 0 i 1`1 `'l.. L ' L4-111 Z�• i `, q 1 .l 1. . 45% pH(5.U.) /•St. y\ - T.�J .y-17. i.'3 ak,� 1.51 4 3V S2 �p 601z) �i4A. 5!a -y .64 Dissolved oxygen (mg/L) 0y.0 -13 I.9 4.3 - 7 .�i 'r-.3 hers, z i 1.6 Conductivity (µmhos/cm) L�1 aO 1 `'-'lnrwx, L� Temperature(°C) Z.-� AA.k li, 1-A-1 Q \ y r7Z��pi-1 T'7 pH(5.U.) fNo`ko9 l.1 144- +/..•'_4•� Y4.s'17 7--2..G 7yt..,2 -y -�f.4s ypZL,r• 7�• ! Dissolved oxygen BD +.z. . 1•3 I. •8 7-3 'r-9 4. 72.5% Conductivity(µmhos/cm) 2ii a111 2 ZF Temperature 1°C) tia.9 lt{.!o 15- co 1` -5 1. ! _ , \'' -1 -Ls. 0 Z 1.1 pH(5.U.) x. 1.yz -3.01, 1.25 4.08 r� �,/ 41 "f -/ .6O 479 3-. 6-1 Dissolved oxygen (mg/L) 0.1 1.2... 3•9 7.3 7 6 7.9 7, fo Conductivity(µmhos/cm) 250 .514. 2E2- Z61 100% Alkalinity (mg CaCO3/L) 21 Hardness (mg CaCO,/L) 31* Chlorine (mg/L) Co -ID Temperature MI ♦S,0 Zi.1 17e• o iA-S ``Ali -Li . n ♦ "tCi . 0 Z`,-b , Initial Final Initial Final Initial Final Initial Final SOP AT2O-Revision 6-Exhibit AT20.3 351 Depot Street Asheville, NC 28801 Phone: (828) 350-9364 Fax: (828) 350-9368 Environmental Testing Solutions, Inc. Whole Effluent Toxicity Chain -of -Custody Form Facility: SEUZ Rutherfordton WWTP Species: Pimephales promelas Test type: Chronic Definitive NPDES #: NC0025909 Pipe #: 001 County: Rutherford Purchase order: Effluent dilution: 11.25, 22.5, 45, 90, 100% Parameter code: THP6C Sample information: (to be completed by sample collector) Compositc sample: Sample location: Start date: E7; FYI %\ Time: --cot, DVolume collected for testing: End date: s - t Time: d \ i3Ea Number of containers filled for testing: Number of samples per hour: Method of transport to laboratory: Chilled during collection? a- Comments: If chilled, specify temperature: ----4 Triple rinse sample container with 'amply before filling. Completely fill the sample container with no air space. Pack the sample container completely in ice. The sample must be <6.0°C upon receipt at the laboratory. Sample custody: (to be completed by sample collector and facility personnel) BY SIGNING BELOW, I CERTIFY THAT THE PERMIT AND TEST REQUIREMENTS IDENTIFIED ON THIS FORM ARE ACCURATE Sample collected by: Rclinqulslied b Pontt-SL,r40"VIk 14-95LI-S:L4 rrV Relinquished by: yOs.'-\ -fc\QLp I lak and 1wne Received by: I4Ce. N 0810 Pit o Received by: s0M,°re I'r°o 1,Nu:°ie P)ne and lime Stinl Sample receipt information: (to be completed by ETS personnel) Relrncluia bed to ETS by: KALE E14%) OS- p5rt1 05�3 Prielt Custody seals intact?: Yes Nu Noi used Samples received in good condition?: r, Yes No Tracking number: Comments: pA Received at ETS by: ZS‘M Sample temperature upon receipt at ETS (°C): o5-('s-- 09,43 Eire MI Ilnu I 3.1 '(_ Total residual chlorine upon receipt at ETS: ri ri (DPD Presence/Absense Indicator, MDL = 0.10 mg/L) Project number%'' Sample number: u°jD,3Uz— 351 Depot Street Asheville, NC 28801 Phone: (828) 350-9364 Fax: (828) 350-9368 Environmental Testing Solutions, Inc. Whole Effluent Toxicity Chain -of -Custody Form Facility: SEUZ NPDES #: NC0025909 Pipe #: 001 County: Rutherford Rutherfordton WWTP Purchase order: Species: Pimephales promelas Test type: Chronic Definitive Effluent dilution: 11.25, 22.5, 45, 90, 100% Parameter code: THP6C Sample information: (to be completed by sample collector) Composite sample: Start date: i o'f a_ \ Time: c-L: OJ Ilk No. Volume collected for testing: End date: 0 4,, i*— a 1 Time: %LIDO al ,Number of containers filled for testing: Number of samples per hour: Chilled during collection? If chilled, specify temperature: Lt Sample location: Method of transport to laboratory: Comments: Triple rinse sample container with sample before filling. Completely fill the sample container with no air space. Pack the sample container completely in ice. The sample must be < 6.0°C upon receipt at the laboratory. Sample custody: (to be completed by sample collector and facility personnel) BY SIGNING BELOW, I CERTIFY THAT THE PERMIT AND TEST REQUIREMENTS IDENTIFIED ON THIS FORM ARE ACCURATE Sample collected by: riclinq NOS bed y: t�fnr Relinquished by: ciOCD now• Ana um: Received Ly: & c..Q p5- s=2-1 Of 6 s,;nr.Ire Received by: <-1,1c an<1<<nw ['rite tiiy<vr<<a Oak aix.rlinty Sample receipt information: (to be completed by ETS personnel) Relinquished to ETS by: Custody seals intact?: J05-24 ,),e,ni,In.. Y, Nu Nol usnl Samples received in good condition?: Ye< Nu Tracking number: Comments: .yr Nponinc P)ac :rvl dnu Received at ETS by: K- 06'054/ <r 1Due v30 ✓L Sample temperature upon receipt at ETS (°C): I l3 Total residual chlorine upon receipt at ETS: (DPD Presence/Abscnsc Indicator, MDL = 0 10 mg/L) I'o. nt nMem Project numbcr:G9‘0 Sample number: ZL050S•O1 Relinquished by: PriN Relinquished by: • 351 Depot Street Asheville, NC 28801 Phone: (828) 350-9364 Fax: (828) 350-9368 _ Environmental Testing Solutions, Inc. Whole Effluent Toxicity Chain -of -Custody Form Facility: SEUZ NPDES #: NC0025909 Pipe #: 001 County: Rutherford Rutherfordton WWTP Purchase order: Species: Pimephales promelas Effluent dilution: 11.25, 22.5, 45, 90, 100% Test type: Chronic Definitive Parameter code: THP6C Sample information: (to be completed by sample collector Composite sample: Start date: pc. Ct.O. Time: End date: DY 0:57-1.1 Time: Number of samples per hour: Chilled during collection? If chilled, specify temperature: 0 Sample location: Volume collected for testing: � (! .r Number of containers filled for testing: Method of transport to laboratory: Comments: Triple rinse sample container with sample before filling. Completely ill the sample container with no air space. Pack the sample container completely in ice. The sample must be < 6.0°C upon receipt at the laboratory. Sample custody: (to be completed by sample collector and facility personnel) BY SIGNING BELOW, I CERTIFY THAT THE PERMIT AND TEST REQUIREMENTS IDENTIFIED ON THIS FORM ARE ACCURATE Sample ecc&I et by: I , (6"15) C?1"...k.neure Dole soli time ct Received I'y: 0S- cr1•1.1 of 10 nve Received iiY• flik nnJ umr :on Ikle and wee • Sample receipt information: (to be completed by ETS personnel) R eliiiquisi,cd to ETS by: Pain — lAk enl am Received at ETS by: OS-tn 1031 Pnnl Custody seals intact?: Z/ Y. No Nm used Samples received in good condition?: = Ye. No Tracking number: Comments: rtr Deo MA lime Sample temperature upon receipt at ETS (°C): Total residual chlorine upon receipt at ETS: 11 (DPD Prom ncNAbsetve i,C. i�r�twltiL = 0J 0 mg/LI �"�'"Anv.n Project numbeL]�jt 4 sU ample number:2,105D-_J) 1b 7-day IC25 (g/L KCI) Environmental Testing Solutions, Inc. 0.9 0.8 0.7 0.6 1.2 1.0 0.8 0.6 0.4 Pimephales promelas Chronic Reference Toxicant Control Chart Source: In-house Culture • • • • • Control Limits (± 2 Standard Deviations) • • • • • ■ • • • • • • ■ • • 1 1 1 1 1 1 1 1 I 1 I 1 1 1 1 1 1 1 I I 1 1 1 1 1 1 1 1 1 1 1 r 1 1 1 1 1 1 1 1 • • Warning Limits ••_ • • • • • • • • • • • 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I I 1 I c19 319AryZOOaZ0 $102sy0 UZO -70 1:LOaLQ y.O 6'0�irIPy1-%0:1Oy10;1 .03 1Z0is oEvd-00-OOct' ot11100•0 11: 01 03'�pa 05 Test date • 7-day IC25 = 25% inhibition concentration. An estimation of the potassium chloride concentration which would cause a 25% reduction in Pimephales growth (calculated using ToxCalc). Central Tendency (mean logarithmic IC25 converted to anti -logarithmic values) Control Limits (mean logarithmic IC25 ± 2 standard deviations converted to anti -logarithmic values) Laboratory Warning Limits (mean logarithmic IC25 ± 2 coefficent of variations converted to anti -logarithmic values) USEPA Warning Limits (mean logarithmic IC25 ± Sn 75 converted to anti -logarithmic values, SA 75 = 75th percentile of CVs reported nationally by USEPA)