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HomeMy WebLinkAbout20141127 Ver 1_Notes136_MDC_20141107Employment and program opportunities are offered to all people regardless of race, color, national origin, sex, age, or disability. North Carolina State University, North Carolina A&T State University, U.S. Department of Agriculture, and local governments cooperating. Printed on Recycled Paper NWQEP NOTESNWQEP NOTESNWQEP NOTESNWQEP NOTESNWQEP NOTES The NCSU Water Quality Group Newsletter Number 136 December 2011 ISSN 1062-9149 PROJECT SPOTLIGHT Minimum Detectable Change (MDC) Dr. Jean Spooner, Department Biological and Agricultural Engineering Department, North Carolina State University, Raleigh, NC Definition and Overview The Minimum Detectable Change (MDC) is the minimum change in a pollutant concentration (or load) over a given period of time required to be considered statistically significant. The calculation of MDC has several practical uses. Data col- lected in the first several years of a project or from a similar project can be used to determine how much change must be measured in the water resource to be considered statistically significant and not an artifact of system variability. Calculation of MDC provides feed- back to the project managers as to whether the proposed land treatment and water quality monitoring designs are sufficient to accomplish and detect the expected changes in water quality over a pre-specified length of time. These calculations facilitate realistic expectations when evaluating watershed studies. Calculation of the magnitude of the water quality change required can serve as a useful tool to evaluate water quality monitoring designs for their effectiveness in detecting changes in water quality. Closely related, these calculations can also be used to design effective water qual- ity monitoring networks (Spooner et al., 1987; 1988). Bernstein and Zalinski (1983) make a valid distinction between the magnitude of the ‘statistically’ and ‘biologically’ significant changes. The size of a statistically significant detectable change depends on the number of samples. For a fixed sample variability, a large number of samples results in a large number of degrees of freedom in the statistical trend test, and therefore, a relatively small value for the MDC. However, a small statistically significant dif- ference may have no biological or practical significance. In contrast, with small sample sizes, statistically significant detectable changes may be much larger than biologically significant changes. A sys- NWQEP NOTES is available on the World Wide Web at http://www.ncsu.edu/waterquality/issues/Default.htm. To subscribe or unsubscribe to the NWQEP NOTES listserv: Send e-mail to: mj2@lists.ncsu.edu (leave sub- ject field blank). 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IN THIS ISSUE Minimum Detectable Change (MDC)........1 Editor’s Note ..............................................2 Conference Report ..................................12 NRCS Revises Nutrient Standard ..........12 NRCS Initiative on Drainage Water Management ...........................................13 Ag NPS Regulations ...............................13 EPA Healthy Watersheds Initiative ..........13 Biological Assessment Primer ..............13 USGS Coop Water Program ...................14 USGS Finds No Consistent Nitrate Declines in Mississippi River Basin ......14 USGS Decision Support System for Regional Nutrient Assessment ..............14 Gulf Coast Ecosystem Restoration Task Force ...............................................15 Meetings ..................................................15 2 NWQEP NOTES — December 2011 MDC is a quantity that is calculated using the pre-planned statistical trend tests on the measured observations, typically in the pre-BMP project phase. MDC is used as a guide to calculate the minimum amount of change expected to be de- tected given the sample variability, number of samples, monitoring design and statistical trend tests and significance level. General Considerations The following assumptions are made in the calculation of MDC. Historical sample measurements are representative of the temporal and spatial variation of the past and future conditions. Variability due to sampling, transport or laboratory error is negligible compared to variability over time. Typically, the pollutant concentrations or load values ex- hibit a log-normal distribution. When this is the case, the MDC is expressed as a percent change relative to the initial annual geometric mean concentration. Given a particular monitor- ing scheme, the water quality observations and their variability can be used to calculate the MDC required in the geometric mean pollutant concentration over time. When the water quality values are log-normal, calcula- tions for the MDC values are performed on the base 10 logarithmic scale. Analyses on the logarithmic scale have sev- eral beneficial features: The log normal distribution generally fits the distribution of water quality data. One feature of a log normal distribution is skewed data on the original scale (e.g., many lower values with a few higher values). The logarithmic transformation on the water quality variables is usually required for the distributional assumptions of parametric trend analyses to be met. The results become dimensionless and are independent of the units of measurements. MDC can be expressed as a percentage, rather than an absolute difference, because the calculations are performed on the logarithmic scale. EDITOR’S NOTE This issue of NWQEP NOTES focuses upon Mini- mum detectable change (MDC). Minimum detectable change analysis can answer questions like: “How much change must be measured in a water resource to be con- sidered statistically significant?” or “Is the proposed monitoring plan sufficient to detect the change in con- centration expected from BMP implementation?” MDC analyses are useful for persons involved in wa- tershed nonpoint source monitoring and evaluation projects such as those in the National Nonpoint Source Monitor- ing Program (NNPSMP) and the Mississippi River Basin Initiative, where documentation of water quality response to the implementation of management measures is the objective. The MDC techniques discussed below are ap- plicable to water quality monitoring data collected under a range of monitoring designs including single fixed sta- tions and paired-watersheds. MDC analysis can be performed on datasets that include either pre- and post- implementation data or just the typically limited pre-implementation data that watershed projects have in the planning phase. Better datasets, however, provide more useful and accurate estimates of MDC. As always, please feel free to contact me with your ideas, suggestions, and possible contributions to this news- letter Jean Spooner Editor, NWQEP NOTES NCSU Water Quality Group Campus Box 7637, NCSU Raleigh, NC 27695-7637 Email: notes_editor@ncsu.edu MDC analysis must be consistent with and based on the planned statistical approach to analyzing project data. tem may have exhibited a biologically significant change that cannot be statistically detected because sample sizes are too small. MDC is an extension of the Least Significant Difference (LSD) concept (Snedecor and Cochran, 1967). The MDC for a system can be estimated from data collected within the same system or similar systems. A system is defined by the water- shed size, water resource, monitoring design, pollutants measured, sampling frequency, length of monitoring time, hydrology and meteorology. 3 NWQEP NOTES — December 2011 Sampling frequency determination is very closely related to MDC calculations. Sample size determination is usually per- formed by fixing a significance level, power of the test, the minimum change one wants to detect, the duration of moni- toring, and the type of statistical test. MDC is calculated similarly except the sample size (i.e., number of samples) is fixed and the power is set to 50% to solve for the minimum detectable change. MDC is the amount of change you can detect given the sample variability. Therefore, many of the same formulas that are used for confidence limit and sample size determination are similar to those used to calculate MDC. Factors Affecting the Magnitude of the MDC The MDC is a function of pollutant variability, sampling frequency, length of monitoring time, explanatory variables or covariates (e.g., season, meteorological, and hydrologic vari- ables) used in the analyses which ‘adjust’ or ‘explain’ some of the variability in the measured data, magnitude and structure of the autocorrelation, and statistical techniques and signifi- cance level used to analyze the data. Spatial and Temporal Variability The basic concept in the calculation of MDC is simple: variability in water quality measurements is examined to esti- mate the magnitude of changes in water quality needed to detect significant differences over time. Hydrologic systems are highly variable, often resulting in large values for MDC. Variations occur in both spatial and temporal dimensions. Variations in water quality measurements are due to several factors includ- ing: A change in land treatment resulting in decreased concentrations and/or loadings to receiving waters (determining the amount of water quality change is usually a key objective of a watershed project) Sampling and analytical error Monitoring design (e.g., sampling frequency, sampling location, variables measured) Changes in meteorological and hydrologic conditions Seasonality Changes in input to and exports from the system. For example, changes in upstream concentrations can affect the downstream water quality. MDC is proportionally related to the standard deviation of the sample estimate of trend (e.g., standard deviation of the sample estimate of slope for a linear trend or standard devia- tion of samples in the pre-BMP time period for a step trend). This standard deviation is a function of the variability in Y that is not explained by the statistical trend model (i.e., error vari- ance). As such, any known sources of variation that can be added to the statistical trend model to minimize the error vari- ance will also serve to reduce the MDC and increase the ability to detect a real change in water quality due to land treatment. For example, adjusting for changes in explanatory variables such as streamflow or changes in land use (other than the BMPs) would reduce both the standard error and the MDC. It should be noted that sample variability may be affected by sampling frequency. For frequent sampling directed at in- cluding storm events, variability is usually higher than for fixed-interval sampling directed at monitoring ambient condi- tions. In addition, the nature of collection and data aggregation will directly affect the variability and the autocorrelation. Com- posite or aggregated samples are generally less variable than single grab samples and exhibit a lower degree of autocorrelation as compared to non-aggregated data. Sampling Frequency and Record Length The MDC calculation is the change required for a speci- fied sample frequency and duration. MDC decreases with an increase in the number of samples and/or duration of sam- pling. Increasing sampling frequency and/or record length (e.g., increasing the number of years for monitoring) results in an increase in the number of samples (N), and therefore increases the degrees of freedom in the statistical trend tests and results in a smaller MDC value. Increasing the number of samples results in a decrease in MDC (on the logarithmic scale) ap- proximately proportional to the increase in the square root of N. However, increasing N by increasing the sample frequency may not decrease the MDC by this total proportion due to the effects of temporal autocorrelation. Increasing record length has several advantages over in- creasing sampling frequency. Increasing record length serves to add degrees of freedom to the statistical trend models. In addition, increasing the number of years adds extra verifica- tion that the observed changes are real and not a result of an unknown or unmeasured variable that also exhibits large year- to-year variations. Increasing record length also serves to increase the time base from which extrapolations may be made. Seasonal, Meteorological and Hydrologic Variability The standard error of a trend estimate can effectively be reduced by accounting for seasonality and meteorological and hydrologic variables in the trend tests. Because these variables or covariates can help reduce the amount of variability that Sampling frequency and MDC are closely related parameters. The planned sampling frequency and duration strongly influence the MDC, and the MDC largely dictates the sampling frequency necessary to measure such change within a specified time period. 4 NWQEP NOTES — December 2011 cannot be ‘explained’ they are commonly called ‘explanatory variables.’ For example, Hirsch and Gilroy (1985) found that a model that removes variability in sulfate loading rates due to precipitation and varying seasonal mean values can reduce the step trend standard deviation by 32%, and therefore, the mag- nitude of change needed for statistically detectable change would be reduced by 32%. Incorporation of appropriate explanatory variables increases the probability of detecting significant changes and serves to produce statistical trend analysis results that better represent true changes due to BMP implementation rather than changes due to hydrologic and meteorological variability. Commonly used explanatory variables for hydrologic and meteorological variability include streamflow and total precipitation. Adjustment for seasonal, meteorological and hydrologic variability is also important to remove bias in trend estimates due to changes in these factors between sampling times and years. Interpretations regarding the direction, magnitude and significance in water quality changes may be incorrect if hy- drologic and/or meteorological variability is not accounted for in the statistical trend models. If significant variation exists between the seasonal means and/or variances and is not considered in the statistical trend models, then the assumptions of identical and independent dis- tribution of the residuals (from the statistical model) will be violated and the results for the statistical trend analyses (both parametric and nonparametric) will not be valid. Non-identical distributions can occur when the seasonal means vary from the overall mean and/or the variances within seasons are dif- ferent for each season. Non-independence can occur because seasons have cyclic patterns, e.g., winters are similar to win- ters, summers to summers, etc. Autocorrelation Temporal autocorrelation exists if an observation is related or correlated with past observations (not independent). Autocorrelation in water quality observations taken less fre- quently than daily is usually positive and follows an autoregressive structure of order 1, AR(1). More complicated autocorrelation models (AutoRegressive Integrated Moving- Average or ARIMA models with more lag terms and moving average terms) are usually needed for daily or more frequent sampling designs. Positive autocorrelation usually results in a reduction of information (e.g., less degrees of freedom than the actual number of samples) in a data series and affects statistical trend analyses and their interpretations. Each addi- tional sample adds information, but not a full degree of freedom if it’s not independent of the previous sample. If significant autocorrelation exists and is not considered in the statistical trend models, then the assumption of inde- pendence of the residuals will have been violated. The result is incorrect estimates of the standard deviations on the statistical parameters (e.g., mean, slope, step trend estimate) which in turn results in incorrect interpretations regarding the statisti- cal significance of these statistical parameters. Autocorrelation must be incorporated into the statistical trend models to obtain an accurate estimate of MDC (e.g., using time series analy- ses). Autocorrelation can also be reduce by data aggregation (e.g., weekly, monthly), but this will decrease the degrees of freedom. Statistical Trend Tests MDC is influenced by the statistical trend test selected. For the MDC estimate to be valid, the required assumptions must be met. Independent and identically distributed residuals are requirements for both parametric and nonparametric trend tests. Normality is an additional assumption placed on most parametric trend tests. However, parametric tests for step or linear trends are fairly robust and therefore do not require ‘ide- ally’ normal data to provide valid results. The standard error on the trend estimate, and therefore, the MDC estimate will be minimized if the form of the ex- pected water quality trend is correctly represented in the statistical trend model. For example, if BMP implementation occurs in a short period of time after a pre-BMP period, a trend model using a step change would be appropriate. If the BMPs are implemented over a longer period of time, a linear or ramp trend would be more appropriate. A step change can be examined by the use of tests such as the parametric Student’s t-test or the nonparametric Wilcoxon rank sum test. The two-sample Student’s t-test and the non- parametric Wilcoxon rank sum tests for step change are popular step change tests used in water quality trend analyses because they are easy to use. Analysis of Covariance (ANCOVA) can test for step changes after adjusting for variability in explana- tory variables or covariates (e.g., streamflow). When a sudden system alternation, such as BMP implementation occurs, the BMPs can be called an ‘intervention.’ In statistical terms, in- tervention analysis can be used to extend the two-sample Student’s t-test to include adjustments for autocorrelation. The most popular types of statistical models for linear change include the parametric linear regression and the non- parametric Kendall’s tau (with the Sen’s Slope Estimator). Autocorrelation is most easily accounted for by the use of linear regression models with time series errors. When using a statistical software package that can adjust for autocorrelation (e.g., PROC AUTOREG in SAS (SAS, 1999)), it requires no extra effort to correctly incorporate the needed time series as MDC is influenced by the statistical trend test selected. The MDC will be minimized if the correct statistical trend model (e.g., step vs. linear or ramp) is selected. 5 NWQEP NOTES — December 2011 well as explanatory variables. See USEPA (2011) for an over- view of other statistical software packages that may be also be used. Steps to Calculate the MDC The calculation MDC or the water quality concentration change required to detect significant trends requires several steps. The procedure varies slightly based upon: Pattern of the expected change and therefore appropriate statistical model (e.g., step, linear, or ramp trend). Whether the data used are in the original scale (e.g., mg/l or kg) or log transformed. Incorporation of time series to adjust for autocorrelation. Addition of explanatory variables such as streamflow or season. The following steps and examples are adopted from Spooner et al. (1987 and 1988): Step 1. Define the Monitoring Goal and Choose the Ap- propriate Statistical Trend Test Approach. One goal may be to detect a statistically significant linear trend in the annual mean (geometric mean if using log transformed data) pollut- ant concentrations that may be related to land treatment changes. A linear regression model using log-transformed data would then be appropriate. An alternative goal to detect a statistically significant change in the post-BMP period as compared to a pre-BMP period would require a step change statistical test such as the t-test or ANCOVA. For linear trends, an appropriate regression trend model would be a linear trend either without: Yt = β0 + β1DATE + eτ or, with explanatory variables as appropriate: Yt = β0 + β1DATE + ΣβiXi + eτ Where: Yt = Water quality variable value at time t. If Y is log normal, then Yt is the log-transformed water quality variable value. Xi = Explanatory variable, i=2,3,... (X2, X3, etc. could also be log transformed; the DATE variable is con- sidered Xi) β0 = Intercept β1 = Slope or linear trend on DATE βi = Regression coefficients for explanatory variables et = Error term (this is denoted at Vt if the error series has an autocorrelated structure, see Step 4 and Ex- ample 1) Note that even though no (zero) trend is expected if this test uses only the pre-BMP data, it is appropriate to include the trend (DATE) term in the statistical model when this is the planned statistical model. For a step trend, the DATE can have the values of 0 for pre-BMP or 1 for post-BMP data. When planning or evaluat- ing a monitoring design, there may not yet be any post-BMP data and only pre-BMP data would then be used in the MDC calculations. Note: the paired watershed study and the above/below- before/after watershed designs are analyzed using an Analysis of Covariance (ANCOV) where ‘Date’ is 0 or 1 and the ex- planatory variable is either the control watershed values (concentrations/loads) or the upstream values paired with the treatment or downstream values, respectively. Step 2. Perform Exploratory Data Analyses. Preliminary data inspections are performed to determine if the residuals are distributed with a normal distribution and constant vari- ance. Normal distribution is required in the parametric analyses; constant variance is required in both parametric and nonpara- metric analyses. The water quality monitoring data are usually not normal, however, and often do not exhibit constant vari- ance over the data range. The water quality data sets are examined using univariate procedures such as those available with the SAS procedure PROC UNIVARIATE or within JMP (SAS Institute 2010, 2008) to verify distributional assumptions required for statistical pro- cedures. Specific attention is given to the statistics on normality, skewness and kurtosis. Both the original and logarithmic trans- formed values are tested. Step 3. Perform Data Transformations. Water quality data typically follow log-normal distributions and the base 10 loga- rithmic transformation is typically used to minimize the violation of the assumptions of normality and constant variance. In this case, the MDC calculations use the log-transformed data until the last step of expressing the percent change. The natural log transformation may alternatively be used. The logarithmic base 10 transformation applies to the de- pendent water quality variables used in trend detection (i.e., suspended sediment, TP, ortho phosphorus and fecal coliform). Technically, explanatory variables in statistical trend models do not have any distributional requirements because it is only the distribution of the residuals that is crucial. However, if Exploratory data analysis (US EPA, 2005) is an important step in determining whether available data meet the assumptions (e.g., normality, constant variance) of planned statistical tests. 6 NWQEP NOTES — December 2011 they do exhibit log normal distributions, explanatory variables are also log transformed which usually helps with the distri- bution requirements of the residuals. Typical explanatory variables that are log transformed include upstream concen- trations and stream flow. Step 4. Test for Autocorrelation. Tests are performed on the water quality time series to determine if there is autocorrelation. An autoregressive, lag 1 (AR(1)) error struc- ture (i.e., correlation between two sequential observations) in the water quality trend data is common. The tests usually as- sume samples are collected with equal time intervals. The regression trend models used are the same as those planned for the future trend analyses (See Step 1). The data should be ordered by collection date. The Durbin Watson (DW) test for autocorrelation can be performed on the residuals from the linear regression models to determine if the concentration measurements are related to previous measurements. Several software packages will cal- culate the DW tests. For example, this test can be performed with the SAS procedure PROC REG or PROC AUTOREG (SAS Institute, 1999), or within the least squares regression analysis with JMP (SAS Institute, 2008). The Durbin Watson test assumes the residuals exhibit an AR(1) autocorrelation structure. Alternatively, the significance of the first order autocorrelation coefficient is tested in SAS using a time series statistical procedure such as PROC AUTOREG or time series analyses within JMP. It should be noted that PROC AUTOREG allows for missing Y-values, but equally-spaced date entries should all be included in the data set. Alternatively, the assumption of independent residuals can be tested by passing the residuals from these regression trend models to the SAS procedure PROC ARIMA (SAS Institute, 1999) or time series analysis within JMP (SAS Institute, 2008). The autocorrelation structure is examined to determine if the independence assumption is valid and, if not, to determine the appropriate autocorrelation structure for the simple trend mod- els. The chi-square test of white noise supplied by PROC ARIMA is also used to test whether the residuals are indepen- dent. Step 5. Calculate the Estimated Standard Error. The vari- ability observed in either historic or pre-BMP water quality monitoring data is used to estimate the MDC. Any available post-BMP data can also be included in this step. The estimated standard error is obtained by running the same statistical model that will be used to detect a trend once BMPs have been in- stalled (same trend models identified in Step 1). For a linear trend, an estimate of the standard deviation on the slope over time is obtained by using the output from statistical regression analysis with a linear trend, time series errors (if applicable), and appropriate explanatory variables. If additional duration of monitoring is planned, and therefore a longer data set will be the obtained in the future, the standard deviation of the future trend slope can be estimated from the existing data by: Where: sb = estimate for the standard deviation of the trend for the total planned duration of monitoring bs' = standard deviation of the slope for the existing data n = number of samples in the existing data C = correction factor equal to the proportional increase in planned samples. For example, if 4 years of existing data are available and 8 years of total monitoring is planned, C=2 (i.e., 8/4). This factor will reduce the standard error on the slope and, therefore, the amount of change per year required for statistical significance. A large sample approximation for the adjustment factor is: For a step trend, it is necessary to have an estimate of the standard deviation of the difference between the mean values of the pre- vs. post- data ( ). In practice, an estimate is obtained by using the following formula: Where:= Estimated standard error of the difference between the mean values of the pre- and the post- BMP periods. MSE = sp 2 = Estimate of the pooled Mean Square Error (MSE) or, equivalently, variance (sp 2) within each period. The MSE estimate is obtained from the output of a statistical analysis using a t-test or ANCOVA with appropriate time series and explanatory variables. The variance (square of the standard deviation) of pre- BMP data can be used to estimate MSE or sp 2 for both pre and post periods if post-BMP data are not available and there are no explanatory variables or autocorrelation (see Example 2). For log normal data calculate this value on the log transformed data. Missing values are allowed. It is not important at this step if a trend is present or not because this step obtains the esti- mate on the standard deviation of the trend statistic. For both linear and step trends, if autocorrelation is present a time series statistical procedure such as SAS’s PROC AUTOREG that uses Generalized Least Squares (GLS) with Yule Walker methods should be employed because it takes into 2)n(C 2)(nss *bb − −=' C 1 bbss'= postpre postpre n MSE n MSEs)XX(+=− )xx(s postpre− )xx(s postpre− - - 7 NWQEP NOTES — December 2011 account the autocorrelation structure of the residuals to ob- tain valid standard deviations (Brocklebank and Dickey, 1986). The standard error on the trend estimate for simple trend models (e.g., step, linear, or ramp trends) with AR(1) error terms is larger than that (incorrectly) calculated by Ordinary Least Squares (OLS). Matalas (1967) cited theoretical adjustments that can be used. The true standard deviation has the follow- ing large sample approximation: Where: sb = true standard deviation of the trend (slope or difference between 2 means) estimate (e.g., calculated using GLS) bs'= incorrect variance of the trend estimate calculated without regard to autocorrelation using OLS (e.g., using a statistical linear regression procedure that does not take into account autocorrelation) ρ = autocorrelation coefficient for autoregressive lag 1, AR(1) Step 6. Calculate the MDC. MDC is essentially one-half of the confidence interval for the slope of a linear regression model or for the difference between the mean values of the pre- and post BMP periods. For a linear trend, the MDC is calculated by multiplying the estimated standard deviation of the slope by the t-sta- tistic and the total monitoring timeframe: MDC = (N) * t(n*N-2)df * 365 * sb1 Where: t(n*N-2)df = One-sided Student’s t-statistic (α = .05) N= Number of monitoring years n= Number of samples per year df= degrees of freedom 365= Correction factor to put the slope on an annual basis when DATE is entered as a Date (day) variable, e.g., the slope is in units per day. If DATE values were 1-12 for months and the slope was expressed ‘per month’ then this value would be “12.” sb1 = Standard deviation on the slope estimated for the total expected monitoring duration (from Step 5) MDC= the MDC on either the original data scale or the log scale if the data were log-transformed For a step trend, the MDC is one-half of the confidence interval for detecting a change between the mean values in the pre- vs. post- BMP periods. In practice, an estimate is obtained by using the following equivalent formula: Where: = one-sided Student’s t-value with (npre + npost -2) degrees of freedom. npre + npost = the combined number of samples in the pre- and post-BMP periods = estimated standard error of the difference between the mean values in the pre- and the post- BMP periods. MSE = sp 2 = Estimate of the pooled Mean Square Error (MSE) or, equivalently, variance (sp 2) within each period. The MSE estimate is obtained from the output of a statistical analysis using a t -test or ANCOVA with appropriate time series and explanatory variables. If post- BMP data are not available, no autocorrelation is present, and no explanatory variables are appropriate, MSE or sp 2 can be estimated by the variance (square of the standard deviation) of pre-BMP data. The pre- and post-periods can have different sample sizes but should have the same sampling frequency (e.g., weekly). The following considerations should be noted: The choice of one- or two-sided t-statistic is based upon the question being asked. Typically, the question is whether there has been a statistically significant decrease in pollutant loads or concentrations and a one-sided t-statistic would be appropriate. A two-sided t-statistic would be appropriate if the question being evaluated is whether a change in pollutant loads or concentrations has occurred. The value of the t-statistic for a two-sided test is larger, resulting in a larger MDC value. At this stage in the analysis, the MDC is either in the original data scale (e.g., mg/L) if non-transformed data are used, or, more typically in the log scale if log-transformed data are use. Step 7. Express MDC as a Percent Decrease. If the data analyzed were not transformed, MDC as a percent change (MDC%) is simply the MDC from Step 6 divided by the aver- age value in the pre-BMP period expressed as a percentage (e.g., MDC% = 100*(MDC/mean of Pre-BMP data). When calculating MDC as a percent change it is important to note whether the data analyzed were log transformed because the formula is different from that used for data that were not log transformed. p 1 p 1s s bb − +=' postpre postpre t n MSE n MSE*MDC )2nn(+=−+ )2nn(−+postpre t )XX()2nn(sMDC postprepostpre*t −−−= )xx(s postpre− 8 NWQEP NOTES — December 2011 If the data were log-transformed, a simple calculation can be performed to express the MDC as a percent decrease in the geometric mean concentration relative to the initial geo- metric mean concentration or load. The calculation is: MDC% = (1 - 10-MDC) * 100 Where: MDC is on the log scale and MDC% is a percentage. For log-transformed data MDC is the difference required on the logarithmic scale to detect a significant decreasing trend (calculated in Steps 5 and 6 using log transformed data). MDC% and MDC are positive numbers if mean concentra- tions decrease over time. For example, for MDC= 0.1 (10-0.1 = 0.79), the MDC% or percent reduction in water quality re- quired for statistical significance = 21%; for MDC = 0.2 (10-0.2 = 0.63), MDC% = 37%. In the cases where detection of a positive trend is desired (e.g., Secchi depth measurements), the per- cent decrease would be negative and the input for MDC must be forced to be negative. It should be noted that if the natural logarithmic transfor- mation had been used, then: MDC% = (1 - exp-MDC) * 100 MDC Calculation Examples Example 1: A linear trend with autocorrelation and covariates or explanatory variables; Y values log transformed. The basic statistical trend model used in this example is linear regression with time series errors, techniques documented by Brocklebank and Dickey (1986). Typically, Autoregressive Lag 1 or AR(1) is appropriate and a DATE explanatory variable is included in the model. The DATE variable is used to estimate the magnitude of a linear trend and to estimate the variation not accounted for by the linear trend term observed in the water quality measurements. The estimate of variation on the “slope” of DATE is then used to calculate an estimate of Mini- mum Detectable Change (MDC). The significance of the linear trend, its magnitude, or its direction is not important in the calculation of MDC. The important statistical parameter is the standard deviation on the slope estimate of the linear trend. The SAS procedure, PROC AUTOREG (SAS Institute, 1999) can be used in the analyses. The linear regression model estimated at each monitoring location is: Yt = β0 + β1DATE + Vτ or, with explanatory variables: Yt = β0 + β1DATE + ΣβiXi + Vτ Where:Yt = Log-transformed water quality variable value at time t, Vt = Error term assumed to be generated by an autoregressive process of order 1, AR(1) β0 = Intercept β1 = Slope or linear trend on DATE β1 = Unique regression coefficients for each explana- tory variables Xi = Explanatory variable, i=2,3,.., The standard deviations on the slope over time from linear regression models are used to calculate the MDCs. A signifi- cance level of α=.05 and a Type II error of b=0.5 are assumed. The standard deviation on the slope is a function of the mean square error (MSE or s2) estimated by the Yule Walker Method and Generalized Least Squares, degree of autocorrelation, and the degrees of freedom (d.f.). The d.f. is a function of the number of monitoring years and sample frequency. If contin- ued sampling is planned, the estimate of the standard deviation of the trend slope is adjusted by a correction factor given in Step 5. MDC is calculated by: MDC = (N) * t(n*N-2)df * 365 * sb1 Where: t(n*N-2)df = One-sided Student’s t-statistic (α = .05) N = Number of monitoring years n = Number of samples per year 365 = Correction factor to put the slope on an annual basis because DATE is assumed to be entered as a Date variable (i.e., the slope is in units per day). If DATE values were entered as 1-12 for months causing the slope to be expressed as ‘per month’ then this value would be “12.” sb1 = Standard deviation on the slope MDC = MDC on the log scale in this case The calculations are illustrated below with the following assumptions: N = 5 years existing (10 years planned) n = 52 weekly samples per year DATE was entered into the computer program as a DATE, so the slope is expressed in units per day t(n*N-2)df = t258 = 1.6513 (one-sided) sb1 = 0.0000229 (This is the standard deviation on the slope for the trend, which is log scale for this example because log transformed data are assumed. It is very important to carry several significant digits because the number might be small.) 9 NWQEP NOTES — December 2011 The MDC for the existing 5 years of data can be calcu- lated. The calculations for MDC and then MDC% for this example using Y values that are log transformed are as fol- lows: MDC = (N) * t(n*N-2)df * 365 * sb1 MDC = 5 * 1.6513 * 365 * 0.0000229 MDC = 0.06901 (units on log scale) MDC% = (1 - 10-MDC) * 100 (percentage on geometric mean) MDC% = (1 - 10-0.06901) * 100 MDC% = 15% (percentage on geometric mean) or an average of 3% change per year Note: If a 2-sided t-statistic value was used then t=1.969 and MDC (log scale) is 0.0823 and MDC% is 17%. The MDC estimate if the sampling duration will be doubled to a total of 10 years: = 0.0000229 *0.70574 = 0.00001616 MDC (10 years) = 10 * 1.6513 * 365 * 0.00001616 = 0.0974 (units on log scale) = 20% over 10 years (or an average of 2% change per year) The addition of appropriate explanatory variables and sam- pling frequency can decrease the magnitude of the calculated MDC. For example, Spooner et al. (1987) demonstrated that adding salinity as a covariate in the Tillamook Bay, Oregon watershed study decreased the MDC% for fecal coliform over an 11-year period of time (with biweekly samples) from 42% to 36%. For the same study, the MDC% for fecal coliform decreased from 55% to 42% when comparing monthly to biweekly sampling over an 11-year study. Spooner et al. (1987 and 1988) also demonstrated that variability and therefore MDC is also affected by the pollutant measured, the size of the wa- tershed, and appropriate selection of explanatory variables. If a seasonal pattern is present, explanatory variables can be added to help adjust for this source of variability. Sin/ Cosine terms can be used for such adjustment (US EPA, 2011). Alternatively, a seasonal pattern can be included by adjusting for monthly means. In this case, monthly variables (Mi) can be added as explanatory variables where: Mi=1 for Month i, else 0 i=1 to 11 for January to November, respectively (De- cember values have “0” entered for all Mi variables. Example 2: A step trend, no autocorrelation, and no covariates or explanatory variables; Y values on original scale (not transformed). In this example, the plan would be to de- tect a significant change in the average values between the pre- and post-BMP periods. The pre- and post-periods can have different sample sizes but should have the same sampling frequency (e.g., weekly). In this simplified situation, the MDC would be equivalent to the Least Significant Difference (LSD). MDC would be calculated as: Where: = one-sided Student’s t-value with (npre + npost -2) degrees of freedom. npre + npost = the combined number of samples in the pre- and post-BMP periods MSE = Estimate of the pooled Mean Square Error (MSE) or variance (sp 2) within each period. The vari- ance (square of the standard deviation) of pre-BMP data can be used to estimate MSE or sp 2 for both pre and post periods if post-BMP data are not available (the usual case when designing monitoring programs). For log normal data calculate this value on the log transformed data. The calculations are illustrated below with the following assumptions: npre =52 samples in the pre-BMP period npost =52 samples in the post-BMP period Mean X = 36.9 mg/l, mean of the 52 samples in the pre-BMP period sp = 21.2 mg/L = standard deviation of the 52 pre- BMP samples MSE =sp 2 = 449.44 = t102 = 1.6599 The MDC would be: The addition of explanatory variables can decrease the magnitude of the MDC. 2)260(2 2)(2600000229.02)n(C 2)(nss ** b1(5years) years) (10 b1 − −= − −=' postpre postpre t n MSE n MSE*MDC )2nn(+=−− )2(−−postprennt )2(−−postprennt postpre postpre t n MSE n MSE*MDC )2nn(+=−− 10 NWQEP NOTES — December 2011 MDC = 6.9 mg/l Percent change required = MDC%=100*(6.9/36.9)=19%. Use the equation described under “Step 7” above to calcu- late percent change for log-transformed data. If the data are autorcorrelated, use a time series model, or the approximation given in Step 5 to adjust the standard error of the difference in the pre- and post-BMP means. Example 3: Paired watershed study or Above/Below-Be- fore/After watershed study analyzed using Analysis of Covariance (ANCOVA); Y values log transformed; no autocorrelation. The paired watershed approach requires a minimum of two watersheds, control and treatment, and two periods of study, calibration and treatment (Clausen and Spooner, 1993). The control watershed accounts for year-to- year or seasonal climatic variations. During the calibration period, the two watersheds are treated identically and paired water quality data are collected (e.g., event-based, weekly). During the treatment period, the treatment watershed is treated with a BMP(s) while the control watershed remains under the same management employed during the calibration period. Under the above/below-before/after approach water quality downstream and upstream of a BMP location is monitored for time periods before and after BMP implementation. Data from these two watershed designs can be analyzed with similar ANCOVA approaches. The Y values in the equa- tion below are taken from either the treatment watershed in a paired-watershed study or the downstream site in an above/ below study. The values for the explanatory (X) variable are taken from the control watershed in a paired-watershed de- sign or from the upstream site in an above/below design. The Yt and Xt are the pollutant concentrations or loads measured at the same time period t. Each monitoring design has another explanatory variable that is represented by 0 or 1 for the ‘pre- BMP’ and ‘post- BMP’ periods, respectively. The ANCOVA model is: Yt = β0 + β1(Period) + B2Xt + et Where: Yt = Water quality variable value at time t (from treat- ment watershed or downstream site). If Y is log normal, then Yt is the log-transformed water quality variable value. Period = ‘0’ for pre-BMP period and ‘1’ for post- BMP period (alternatively, period can be treated as a grouping variable and entered as characters). Xt = Explanatory variable value at time t (water qual- ity values from control watershed or upstream site). Values are log transformed if distribution is log-nor- mal. β0 = Y intercept β1, β2 = Regression coefficients et = Error term The SAS procedure PROC GLM (SAS Institute, 2010), JMP (SAS Institute, 2008), or SPSS (IBM, 2011) can be used for the analysis. Period would be identified as a ‘Class’ vari- able in PROC GLM or ‘Character’ variable in JMP. The “Fit Model” dialog box would be used in JMP. Users would select the Y variable, use the “Add” option to include the X (i.e., control) and Period variables, and then choose ‘Run Model.’ It is important to note that because MDCs are generally calculated prior to the treatment period, this example assumes that the slopes for the pre- and post- periods will be similar. The Durbin Watson statistic to check for autocorrelation can be calculated as an option under both SPSS and either SAS procedure. If autocorrelation is significant, PROC AUTOREG can be used for the analysis with Period values set to numeric ‘0’ and ‘1’. The treatment effect will be the difference in the least square means (lsmeans) between the pre- and post-BMP periods. The MDC is the difference that would be statistically significant and therefore based upon the standard error of the difference between lsmeans values. The lsmeans are the estimates of the values of Y for each of the pre- and post- BMP period evalu- ated at the overall average value of all the X (treatment) values collected during the entire study period. MDC is calculated from the standard error on the difference in lsmeans. The standard error is given by the JMP procedure when users choose the option for ‘detailed comparisons’. The MDC on the log values would be: MDC = Where:= One-sided Student’s t-value with (npre + npost -3) degrees of freedom (Note that the t- statistic given in JMP is the two-sided value). npre + npost = The combined number of samples in the pre- and post-BMP periods = Estimated standard error of the difference between the least square mean values in the Pre- and the Post- BMP periods. This is com- puted by using the following approximation (adapted from Snedecor and Cochran, 1967, p. 423): MSE is found in the Analysis of Variance table from the output of the applied statistical analysis, and n is the number of samples within each period. The adjustment “Factor” is 1 or greater and increases 52 449 52 4496599.1MDC += )lsmeanlsmean(*)3nn(postprepostprest−−+ )3nn(−+postpret )lsmeanlsmean(postpre s − Factor*n 2*MSE 11 NWQEP NOTES — December 2011 when the difference between the mean of the X (control watershed or upstream) data in the pre- period compared to the post-BMP period increase. It is assumed to be “1” for MDC calculations. This “Factor” adjustment makes clear the importance of collecting samples in the pre- and post- periods that have similar ranges and variability in hydrological conditions. To express MDC as a percentage change required in geo- metric mean value: MDC% = (1 - 10-MDC) * 100, where MDC is on the log scale MDC Summar y The Minimum Detectable Change (MDC) is the minimum change in a pollutant concentration (or load) over a given pe- riod of time required to be considered statistically significant. MDC calculations can be very helpful in the design of cost- effective monitoring programs, as well as increasing awareness regarding the potential a watershed project has for achieving measurable results. These calculations also illustrate the value of adjusting for changes in hydrologic and meteorological vari- ables. Not only is the ability to detect real changes increased, but valid conclusions regarding the magnitude and direction of measured change(s) in a water quality variable can be made. Calculation of MDC can also be used to illustrate the impor- tance of relatively long monitoring time frames. In addition, comparison of the actual changes in water quality to the MDC values can be used to document BMP effectiveness on a subwatershed basis. The magnitude of MDC is often larger than expected by watershed projects and funding agencies, leading to misun- derstanding regarding the needed level of BMP implementation, intensity of monitoring, and duration of monitoring. The mag- nitude of MDC can be reduced by: Accounting for changes in discharge, precipitation, ground water table depth or other applicable hydrologic/meteoro- logical explanatory variable(s). Accounting for changes in incoming pollutant concentrations upstream of the BMP implementation sub- watershed (i.e., upstream concentrations). Increasing the length of the monitoring period. Increasing the sample frequency. Applying the statistical trend technique that best matches the implementation of BMPs and other land use changes. References Bernstein, B.B. and J. Zalinski. 1983. An optimum sampling design and power tests for environmental biologists. Jour- nal of Environmental Management 16(1):35-43. Brocklebank, J.C. and D. Dickey. 1986. SAS system for fore- casting time series, 1986 Edition. SAS Institute Inc., Cary, North Carolina. 240 p. Clausen, J. and J. Spooner. 1993. Paired watershed study de- sign. USEPA, 841-F-93-009. Office of Water, Washington, D.C. Hirsch, R.M. and E.J. Gilroy. 1985. Detectability of step trends in the rate of atmospheric deposition of sulfate. Water Re- sources Bulletin 21(5):773-784. IBM. 2011. IBM SPSS Statistics, IBM, http://www- 01.ibm.com/software/ [Accessed September 23, 2011]. Matalas, N.C. 1967. Time series analysis. Water Resources Research, 3(3):817-829. SAS Institute Inc. 2010. SAS Software, Version 9.1. SAS In- stitute Inc. Cary, North Carolina. SAS Institute Inc. 1999. SAS/ETS User’s Guide, Version 8. SAS Institute Inc. Cary, North Carolina. SAS Institute Inc. 2008. JMP Software: Version 8. SAS Insti- tute Inc., Cary, North Carolina. Snedecor, G.W. and W.G. Cochran. 1967. Statistical Meth- ods, Sixth Edition. The Iowa State University Press, Ames, Iowa. 593 p. Spooner, J., R.P. Maas, M.D. Smolen and C.A. Jamieson. 1987. Increasing the sensitivity of nonpoint source control moni- toring programs. p. 243-257. In: Symposium On Monitoring, Modeling, and Mediating Water Quality. Ameri- can Water Resources Association, Bethesda, Maryland. 710p. Spooner, J., S.L. Brichford, D.A. Dickey, R.P. Maas, M.D. Smolen, G.J. Ritter and E.G. Flaig. 1988. Determining the sensitivity of the water quality monitoring program in the Taylor Creek-Nubbin Slough, Florida Project. Lake and Reservoir Management, 4(2):113- 124. US EPA. 2005. Monitoring data: exploring your data, the first step. NNPSMP Tech Note 1. Office of Water, Washing- ton, DC. http://ncsu.edu/waterquality/319monitoring/ TechNotes/technote1_exploring_data.pdf [Accessed 11-17- 2011]. US EPA.. 2011. Statistical analysis for monotonic trends, NNPSMP Tech Note 6, Office of Water, Washington, DC. http://ncsu.edu/waterquality/319monitoring/TechNotes/ technote6_monotonic_trends.pdf [Accessed 11-17-2011 ].  12 NWQEP NOTES — December 2011 CONFERENCE REPORT The 19th Annual National Section 319 Nonpoint Source Monitoring Program (NNPSMP) Workshop was held on September 25-28, 2011 in Philadelphia, PA. This symposium integrated the 19th National 319 Non Point Source Monitoring Workshop, 2011 Pennsylvania Stormwater Management Symposium and the 5th International Low Im- pact Development Conference. The conference showcased approximately 250 platform presentations, 70 professional posters, several specialized talks, panels, LID short courses, vendor booths and tours. Attendance was 722 participants. The symposium was a joint effort of Villanova University, NC State University and the University of Maryland along with 13 cooperators. The PowerPoint presentations will be accessible from http://www.bae.ncsu.edu/stormwater/2011lid/.  INFORMATION USDA NRCS Revises National 590 Nutrient Management Standard USDA NRCS Revised the National 590 Nutrient Manage- ment Standard to achieve maximum agricultural and environmental benefits. This update stresses increased use of technology and local information. The following press release gives details: Syracuse, N.Y., December 13, 2011 – Agriculture Secre- tary Tom Vilsack today announced that the U.S. Department of Agriculture has revised its national conservation practice standard on nutrient management to help producers better manage the application of nutrients on agricultural land. Proper application of nitrogen and phosphorus offers tremendous benefits to producers and the public, including cost savings to the producer and the protection or improvement of ground and surface water, air quality, soil quality and agricultural sustainability. “Protecting America’s supply of clean and abundant water is an important objective for USDA,” Vilsack said. “This pre- cious resource is the foundation for healthy ecosystems and sustainable agricultural production. USDA provides voluntary technical and financial assistance to help producers manage their nutrients to ensure a clean and abundant water supply while maintaining viable farm and ranch operations.” The nutrient management conservation practice is an im- portant tool in the USDA Natural Resources Conservation Service conservation toolbox. The agency’s staff uses this conservation practice to help farmers and ranchers apply their nutrients more efficiently. Proper management of nitrogen and phosphorus, including the use of organic sources of nitrogen such as animal manure, legumes and cover crops, can save producers money. The nutrient management standard provides a roadmap for NRCS’s staff and others to help producers apply available nutrient sources in the right amount, from the right source, in the right place, at the right time for maximum agricultural and environmental benefits. NRCS’s nutrient management experts worked with uni- versities, non-government organizations, industry and others to revise the standard to ensure it is scientifically sound. Key changes in the standard include expanding the use of technol- ogy to streamline the nutrient management process and allowing states more flexibility in providing site-specific nutrient man- agement planning using local information when working with producers. NRCS staff offices will have until January 1, 2013 to comply with erosion, nitrogen and phosphorus criteria for their state nutrient management standard. The revised national standard is being released at a time when the agency is working with various partners to address nutrient management concerns identified in three recently re- leased Conservation Effects Assessment Project (CEAP) cropland studies. These CEAP studies assessed the effective- ness of conservation practices in the Upper Mississippi Basin, the Chesapeake Bay Watershed and the Great Lakes Basin. One significant resource concern identified in all three studies is the loss of nitrogen and phosphorus from cropland. Most nitrogen losses are attributed to nitrate leaching through the soil to groundwater. Most phosphorus is lost due to erosion because phosphorus attaches itself to displaced soil particles that are transported by runoff to nearby waterways. Improved nutrient management and effective erosion control work to- gether to reduce the loss of nutrients from agricultural land, resulting in improved water quality in downstream rural and urban communities. The revised standard will provide tools and strategies to help producers address the natural resource concerns relating to excess nutrients on agricultural land. NRCS offers voluntary technical and financial assistance to producers nationwide for planning and implementing on- farm nutrient management plans. Producers can use this assistance to help meet Federal, State, Tribal and local envi- ronmental regulations. Nutrient Management (590) Standard: http://www.nrcs. usda.gov/Internet/FSE_DOCUMENTS/stelprdb1046177.pdf For more information about how nutrient management fits into NRCS’s conservation work, visit our Nutrient and Pest Management web page: http://www.nrcs.usda.gov/wps/por- tal/nrcs/main/national/landuse/crops/npm. Or contact your local USDA-NRCS office. 13 NWQEP NOTES — December 2011 USDA NRCS Initiative on Drainage Water Management - Mississippi River Basin USDA NRCS has put a priority emphasis on drainage wa- ter management in the Mississippi River Basin. NRCS has a new initiative to increase the adoption of agricultural drainage water managment (ADWM) for conservation benefits. The NRCS Ag Water Management Summit was held in October 2011 to help stimulate increased adoption of ADWM nation- wide as a part of a conservation system. The Summit highlighted previous research and adoption experiences, the current situation, and future opportunities. Specific goals of the Summit were: Differentiate ADWM from the traditional practice of draining land for the production of crops. Explain the current ADWM technologies and potential innovations (bioreactors, buffers, wetlands, two-stage ditches, and companion practices) Assure sound environmental management and protect ecosystem values. Action items and observations from the Summit included: NRCS is developing a strategy to reach out to the agriculture and conservation communities across the country over the next year to promote drainage water management implementation A systems approach is the most effective way to address nitrates in our water resources There is a need to identify viable economic incentives for producers to implement drainage water management More information and data on innovative practices are needed There is broad support for NRCS’s effort to promote drainage water management to protect and improve water quality Information and presentations are available at http:// www.nrcs.usda.gov/wps/portal/nrcs/detail/national/water/ manage/?&cid=stelprdb1045304. Ag NPS Regulations An excellent compilation of state water regulations can be found at http://www.nationalaglawcenter.org/readingrooms/ waterlaw/. In addition, the Mississippi River Collaborative, with the Environmental Law and Policy Center (Chicago) in the lead, issued a report in May 2010 on agricultural NPS regulations. Nonpoint source regulations in California, Delaware, Iowa, Kentucky, Maryland, Oregon and Wisconsin were highlighted. In addition, vegetative buffer regulations were summarized for North Carolina and Minnesota. Land application setback regulations were summarized for Alabama, Arkansas, Colo- rado, Georgia, Illinois, Iowa, Maine, Minnesota, New Jersey, Pennsylvania and Wyoming. Winter manure restrictions for Colorado, Delaware, Illinois, Indiana, Iowa, Kansas, Maine, Maryland, Minnesota, Tennessee, Vermont and Wyoming were summarized. Existing state regulations for livestock exclusion were summarized for Colorado, Kentucky, Minnesota, New Jersey and Wisconsin. Fall fertilizer restrictions were summa- rized for Maryland, Minnesota, Nebraska, West Virginia, and Wisconsin. Titled, “Cultivating Clean Water,” the full report can be found at http://elpc.org/elpc-publications?PHPSESSID= 87c19f7a767adfa9c8fd4e9b4a79084b USEPA Healthy Watersheds Initiative The U.S. Environmental Protection Agency (EPA) recently announced the release of the Healthy Watersheds Initiative (HWI) National Framework and Action Plan. The HWI is intended to protect the nation’s remaining healthy watersheds, prevent them from becoming impaired, and accelerate resto- ration successes. The HWI National Framework and Action Plan aims to provide a clear, consistent framework for action, both internally among EPA’s own programs and externally in working with the Agency’s partners. EPA will work with states and other partners to identify healthy watersheds at the state scale and develop and implement comprehensive state healthy watersheds strategies that set priorities for protection and in- form priorities for restoration. Healthy watersheds provide many ecological services as well as economic benefits. If successfully implemented, the HWI promises to greatly enhance our ability to meet the Clean Water Act Section 101(a) objective of restoring and maintain- ing the chemical, physical, and biological integrity of the nation’s waters. The HWI National Framework and Action Plan is available at http://www.epa.gov/healthywatersheds. Biological Assessment Primer The EPA has published A Primer on Using Biological As- sessment to Support Water Quality Management. This technical document serves as a primer on the role of biological assess- ments in a variety of water quality management program applications including reporting on the condition of aquatic biota, developing biological criteria, and assessing environmen- tal results of management actions. The Primer provides information on new technical tools and approaches for devel- oping strong biological assessment programs and includes examples of the application of biological assessment informa- tion by states and tribes. More information is available at http:/ /water.epa.gov/scitech/swguidance/standards/criteria/aqlife/ biocriteria/uses_index.cfm. 14 NWQEP NOTES — December 2011 USGS Cooperative Water Program The USGS Cooperative Water Program monitors and as- sesses water in every state, protectorate, and territory of the U.S. in partnership with nearly 1,600 local, state and Tribal agencies. The CWP is the foundation for USGS’ robust water moni- toring networks (quantity and quality), including, for example, the collection of data at more than 75 percent of the nation’s 7,700 stream gauges. The CWP also supports about 700 in- terpretative studies annually, covering a wide range of issues that are important to the USGS water mission and that inform local, state, and tribal water decisions. Learn more from the CWP’s revised website at: http://water.usgs.gov/coop/ No Consistent Declines in Nitrate Levels in Large Rivers in the Mississippi River Basin The following USGS findings were released in the journal of Environmental Science & Technology, accessible at: http:/ /water.usgs.gov/nawqa/pubs/nitrate_trends. Despite efforts to reduce nitrate in the Mississippi River basin, nitrate concentrations and transport at eight mainstem or large tributary sites have not declined from 1980-2008. The results are based on a new statistical method developed by the USGS that takes into account variation in river flows, in order to paint an accurate picture of long-term trends. These results reflect the cumulative changes over time in nitrate sources and conservation practices throughout the Mississippi River basin, and highlight the need for comprehensive nutrient man- agement strategies that will reduce nutrient levels in both streams and groundwater. Key findings: Nitrate concentrations increased considerably at two sites (Mississippi River at Clinton, IA and at Missouri River at Hermann, MO) Nitrate concentrations remained very nearly the same or increased at the other six sites (Iowa River at Wapello, IA; Illinois River at Valley City, IL; Ohio River near Grand Chain, IL; and along the Mississippi River at Grafton, IL; at Thebes, IL; and near the Old River Outflow Channel) Nitrate transport to the Gulf of Mexico increased from 1980 to 2008 Increases in nitrate concentrations in groundwater are having a substantial effect on nitrate concentrations in rivers and transport to the Gulf of Mexico. The evidence for this comes from the fact that increases in nitrate concentrations are particularly large during low flow conditions. Contacts: Lori Sprague, lsprague@usgs.gov, 303-236-6921 Robert Hirsch, rhirsch@usgs.gov, 703-648-5888 New Online Management Tool to Help Guide Action on Excessive Nutrients in Rivers and Estuaries The USGS recently released a decision support system using SPARROW (Spatially Referenced Regressions On Wa- tershed attributes) that provides access to six newly-developed regional models that describe how rivers receive and trans- port nutrients from natural and human sources to nutrient sensitive waters such as those along the Atlantic Coast, Gulf of Mexico, and Pacific Northwest Coast. Each region and locality has a unique set of nutrient sources and characteristics that determine how those nutrients are trans- ported to streams. “Using the decision support system, users can evaluate combinations of source reduction scenarios that target one or multiple sources of nutrients and see the change in the amount of nutrients transported to downstream waters - a capability that has not been widely available in the past,” said Stephen Preston, USGS hydrologist and coordinator for these regional models. For example, the decision support system indicates that reducing wastewater discharges throughout the Neuse River Basin in North Carolina by 25 percent will reduce the amount of nitrogen transported to the Pamlico Sound from the Neuse River Basin by 3 percent; whereas a 25 percent reduction in agricultural sources, such as fertilizer and ma- nure, will reduce the amount of nitrogen by 12 percent. Based on the six regional modeling results, wastewater ef- fluent and urban runoff are significant sources of nutrients in the Northeast and mid-Atlantic, while agricultural sources such as farm fertilizers and animal manure contribute heavily to nutrient concentrations in the Midwest and Central regions of the nation. Atmospheric deposition is the largest contributor of nitrogen in many streams in the eastern United States, and naturally occurring geologic sources are a major source of phosphorus in many areas. Additionally, the six models used in the decision support system show that the amount of nutrients transported varies greatly among the regions, because nutrients can be removed in reservoirs or used by plants before they reach downstream waters. Temperature and precipitation variation across the country also affect the rates of nutrient movement and loss on the land and in streams and reservoirs. 15 NWQEP NOTES — December 2011 The USGS developed the SPARROW water-quality mod- els to assist with the interpretation of available water-resource data and provide predictions of water quality in unmonitored streams. The regional SPARROW models incorporate geospatial data on geology, soils, land use, fertilizer, manure, wastewater treatment facilities, temperature, precipitation and other wa- tershed characteristics, from USGS, NOAA, USDA, and USEPA. These data are then linked to measurements of stream flow from USGS streamgages and water-quality monitoring data from approximately 2,700 sites operated by 73 monitor- ing agencies. Access the new USGS online decision support system on nutrients at http://water.usgs.gov/nawqa/sparrow/mrb. Gulf of Mexico Regional Ecosystem Restoration Strategy The Gulf Coast Ecosystem Restoration Task Force released the Gulf of Mexico Regional Ecosystem Restoration Strategy in December 2011. Four overarching goals were stated: Restore and conserve habitat Restore water quality Replenish and protect living coastal and marine resources Enhance community resilience Specific goals and strategies are detailed in the report: http:/ /www.epa.gov/gulfcoasttaskforce/pdfs/GulfCoast Report_Full_12-04_508-1.pdf  MEETINGS Meeting Announcements — 2012 January/Februar y 5th International Perspective on Water Resources & the Environment (IPWE 2012). Marrakech, Morocco. January 5-8, 2012. http://www.asce.org/events/EventDetail.aspx?id= 12884905950 2012 National Association of Conservation Districts (NACD) Annual Meeting. Las Vegas, NV. January 29-Feb- ruary 1, 2012. http://www.nacdnet.org/events/annualmeeting/ March AWWA 2012 Sustainable Water Management Conference & Exposition. Marriott Portland Waterfront Hotel, Portland, Oregon. March 18 - 21, 2012. http://www.awwa.org/Con- ferences/SustainableManagement.cfm?ItemNumber= 56511&navItemNumber=56514 AWRA Spring Specialty Conference: GIS & Water Re- sources VII. Sheraton New Orleans Hotel, New Orleans, LA. March 26-28, 2012. http://awra.org/meetings/Spring2012/ AridLID 2012 Conference: Green Infrastructure and Low Impact Development in Arid Environments. Tucson, Ari- zona. March 27-29, 2012. http://AridLID.org April/May 2012 Student Water Conference. Oklahoma State Uni- versity, Stillwater, OK. April 4-5, 2012. Only graduate and undergraduate students are invited to submit abstracts for oral and poster. http://agwater.okstate.edu/news-events/student-wa- ter-research-conference (Abstracts are due by 1/6/2012) 8th National Water Monitoring Conference - Water: One Resource - Shared Effort - Common Future. Portland, OR. Apr 30 - May 4, 2012. http://acwi.gov/monitoring/conference/ 2012/ New England Interstate Water Pollution Control Com- mission (NEIWPCC) and the New Hampshire Department of Environmental Services 23rd Annual Nonpoint Source Pollution Conference for the New England Region. Sheraton Harborside Hotel, Portsmouth, NH. May 15-16 , 2012. Information and previous years’ presentations: http:// www.neiwpcc.org/npsconference. 2012 Land Grant and Sea Grant National Water Confer- ence. Marriott Waterfront Hotel, Portland, OR. May 20-24, 2012. http://www.usawaterquality.org/conferences/2012/ (Ab- stracts are due by 1/2/2012) June Society of Wetland Scientists and the Greater Everglades Ecosystem Restoration Conference with 9th INTECOL In- ternational Wetlands Conference. Orlando, FL June 3-8, 2012. http://www.conference.ifas.ufl.edu/INTECOL/ 2012 Ohio Stormwater Conference. SeaGate Convention Center. Toledo, OH. June 7-8, 2012. http:// www.ohioswa.com/calendar-events/annual-conference/ Urban Environmental Pollution 2012: Creating Healthy, Liveable Cities. Amsterdam, Netherlands. Jun 17-20, 2012. http://www.uepconference.com/ (Abstracts due 1/16/2012) 16 NWQEP NOTES — December 2011 July/August 11 th International Conference on Precision Agriculture. Hyatt Regency, Indianapolis, IN. July 15-18, 2012. https:// www.ispag.org/ (Abstracts still being accepted) WEF Stormwater Symposium 2012. Sheraton Baltimore City Center, Baltimore, Maryland, July 18 – 20, 2012. http:// www.wef.org/stormwater2012/ 67th Annual International Conference for the Soil and Water Conservation Society (SWCS): Choosing Conser- vation: Considering Ecology, Economics and Ethics. Ft. Worth, TX. July 22-25, 2012. http://www.swcs.org/12ac 2012 American Society of Agricultural & Biological Engi- neers (ASABE) Annual International Meeting. Dallas, TX. July 29-August 1, 2012. http://www.asabemeetings .org/ October 2012 Stream Restoration Conference. Wilmington, NC. October 15-18, 2012. http://www.bae.ncsu.edu/training_and_ credit/workshops.php 20th Annual Nonpoint Source (NPS) Monitoring Work- shop. Double Tree Hilton at Warren Place in Tulsa, OK. October 14-17, 2012. http://npsmonitoring.tetratech-ffx.com/ November The 32nd International Symposium of the North Ameri- can Lake Management Society. Madison, WI. November 7 – 9, 2012. http://www.nalms.org/ 2012 Annual Water Resources Conference. Hyatt Regency Jacksonville Riverfront, Jacksonville, FL. Nov. 12-15, 2012. http://awra.org/ December ACES and Ecosystem Markets 2012. Ft. Lauderdale, FL. December 10-13, 2012. http://www.conference.ifas.ufl.edu/ aces (Abstracts still being accepted)  Production of NWQEP NOTES is funded through U.S. Environmental Protection Agency (USEPA) contract #EP-C-08-004. Task Order Manager: Paul Thomas, Water Division, EPA Region 5. 77 W. Jackson St., Chicago, IL 60604. 20th Annual Nonpoint Source Monitoring Workshop The Secrets of Success Making the Most of Available Resources Tulsa, Oklahoma | October 14–17, 2012 The Annual Nonpoint Source (NPS) Monitoring Workshop is an important forum for sharing informa- tion and improving communication on ways to control and track NPS pollution at its source and in receiving waterbodies. The focus of the 20th National Workshop is cost-efficiency across a range of topics including plan- ning and implementation of land treatment to solve NPS problems, water quality monitoring for NPS problem assessment and project effectiveness, data sharing for multiple purposes, and communication of NPS water quality issues and findings to the general public. This event will bring together NPS monitoring and management personnel from state, federal, Tribal and municipal governments, the private sector, academia, en- vironmental groups and local watershed organizations to provide examples of lessons learned from completed NPS projects, demonstrations of new technologies and moni- toring approaches, and documentation of successful application of NPS control practices and measures. A number of technical workshops and interactive learning sessions will be offered to build knowledge and skills, transfer technology, and promote innovative moni- toring and evaluation techniques. Field tours will be offered in both agricultural and urban settings. Please mark your calendar and check the conference website (http://npsmonitoring.tetratech-ffx.com) for de- tails on abstract topics, the workshop agenda, and registration information. The deadline for abstract sub- mittal is May 1, 2012. Abstracts and short bios should be emailed to Liz.Hiett@tetratech.com. 17 NWQEP NOTES — December 2011 NCSU Water Quality Group Campus Box 7637 North Carolina State University Raleigh, NC 27695-7637 Telephone: (919) 515-3723 Fax: (919) 515-7448 Website: http://www.ncsu.edu/waterquality/ Personnel Jean SpoonerKaren R. Hall Robert O. EvansWilliam F. Hunt Kristopher BassGregory D. Jennings Jamie BlackwellBonnie Kurth Michael R. Burchell IIDaniel E. Line Barbara A. DollCatherine S. Smith Garry L. GrabowLaura Lombardo Szpir NC STATE UNIVERSITY