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HomeMy WebLinkAboutWQ0035207_Application_20110203AQUIFER PROTECTION SEI RrECI,:— �Vc0 LPPLICATION REVIEW RE( Date: February 3, 2011 Asheville Regional Office To: ®Landon Davidson, ARO-APS ❑ David M ®lO�,sAl. P �t ��1f�� ❑ Art Barnhardt, FRO-APS ❑ Charlie Stehin-a WiRO= S}----- ❑ Andrew Pitner, MRO-APS ❑ Sherri Knight, WSRO-APS ❑ Jay Zimmerman, RRO-APS From: Chonticha McDaniel ❑AFO❑GW Protection❑GW Planning ®LAU E-Mail: chonticha.mcdaniel iincdenr.gov Telephone: (919) 715-6188 Fax:(919) 715-0588 A. Permit Number: WQ0035207 C. Facility/Operation: Town of Franklin WTP ® Proposed ❑ Existing D. Application: B. Owner: Synagro Central ❑ Facility ® Operation 1. Permit Type: ❑ Animal ❑ Surface Irrigation ❑ Reclaimed ❑ H-R Infiltration ❑ Recycle ❑ FE Lagoon ❑ GW Remediation (ND) ❑ UIC - (5A7) open loop geothermal ❑ Single Family Residence ® Residuals 2. Project Type: ® New ❑ Major Mod. ❑ Minor Mod. , ❑ Renewal ❑ Renewal w/ Mod. E. Comments/Other Information: ❑ I would like to accompany you on a site visit. Attached, you will find all information submitted in support of the above -referenced application for your review, comment, and/or action. Within 30 calendar days, please take the following actions: ® Return a Completed APSARR Form. ❑ BIMS indicates monitoring wells locations are not complete. Please update monitoring well locations not currently in BIMS. ❑ BIMS indicates ongoing ❑ NDMR ❑NDAR ❑ GW monitoring violations. Please investigate reoccurring compliance issues and summarize results in staff report. ❑ Attach Well Construction Data Sheet. ❑ Process Attachment B for Certification by the Land Application Unit (LAU). ❑ Issue an Attachment B Certification from the RO.* *coordinating site visits and reviews, as well as additional information requests with other RO-APS representatives in order to prepare a complete Attachment B for certification. Refer to the RPP SOP for additional detail. Please indicate the name and date assigned in the spaces below, make a copy of this sheet, and return it to the appropriate Central Office -Aquifer Protection Section contact person listed above. RO-APS Reviewer: Date: FORM: APSARR 03/10 Page 1 of 1 A M, ,-TT4 HCDEHR North Carolina Department of Environment and Natura Division of Water Quality Beverly Eaves Perdue Coleen H. Sullins Governor Director January 27, 2011 Marshall Puryear, Technical Services Director Synagro Central, LLC 284 Boger Road Mocksville, NC 27028 Subject: Acknowledgement of Application No. WQ0035207 Town of Franklin WTP Distribution of Residual Solids (503) Macon Dear Mr. Puryear: Resources Dee Freeman Secretary The Aquifer Protection Section of the Division of Water Quality (Division) acknowledges receipt of your permit application and supporting materials on January 7, 2011. This application package has been assigned the number listed above and will be reviewed by Chonticha McDaniel. The reviewer will perform a detailed review and contact you with a request for additional information if necessary. To ensure the maximum efficiency in processing permit applications, the Division requests your assistance in providing a timely and complete response to any additional information requests. Please be.aware that the Division's Regional Office, copied below, must provide recommendations prior to final action by the Division. Please also note at this time, processing permit applications can take as long as 60 - 90 days after receipt of a complete application. If you have any questions, please contact Chonticha McDaniel at 919-715-6188715-6188, or via e-mail at chonticha.mcDaniel@ncdenr.gov. If the reviewer is unavailable, you may leave a message, and they will respond promptly. PLEASE REFER TO THE ABOVE APPLICATION NUMBER WHEN MAKING INQUIRIES ON THIS PROJECT. Sincerely, for Jon Risgaard LAU Supervisor cc: 2ishewiileional Office Aqutfei_Ptoiecfion Section Permit Application File WQ0035207 AQUIFER PROTECTION SECTION 1636 Mail Service Center, Raleigh, North Carolina 27699-1636 Location: 2728 Capital Boulevard, Raleigh, North Carolina 27604 Phone: 919-733-3221 \ FAX 1: 919-715-0588: FAX 2: 919-715-6048 \ Customer Service: 1-877-623-6748 Internet: mm.nmateroualitv.ora ,an Equal Opportunity i ynirmarive.Action Employer One o1-ffiCarolinp- �1 i 1, - 4 s M .V0 SYNAGR.O A Residuals Management Company January 5, 2011 N.C. Department of Environment and Natural Resources Water Quality Section Non -Discharge Permitting Unit — Aquifer Protection Unit 1636 Mail Service Center Raleigh, NC 27699-1636 ATTENTION: Mr. John Risgaard REFERENCE: APPLICATION FOR NEW DISTRIBUTION OF RESIDUAL SOLIDS PERMIT FOR SYNAGRO CENTRAL, LLC Mr. Risgaard: Synagro Central, LLC is submitting a new permit application to be able to distribute the residual solids from the Town of Franklin North Carolina's water treatment plant. Synagro is planning on distributing these solids to agricultural fields in Macon County North Carolina. These residuals will be applied at agronomic rates based on the most recent nutrient and metals analysis. Synagro is enclosing the new permit fee of $810 as well as one original and two copies of the permit application as required on form DRS. This application package contains the information necessary to complete the modification of this permit. However, if you require any additional information or have further questions about the information presented herein, please contact me at mpuryeargsyna roxom or at phone number (336) 998-7150 ext 17. I look forward to working with you to ensure a timely and efficient review of this application. Sincerely, _ ., A Marshall Puryear Technical Services Director = ' Synagro Central, LLC a_ c-� 284 Boger Road • Mocksville, NC 27028-7619 • Ph: (336) 998-7150 • Fax: (336) 998-8450 e Toll Free: (877) 267-2687 Table of Contents Section # Title Section 1 Attachment Order 1: Distribution of Residual Solids Attachment Order l a: Signing Official Delegation Letter Section 2 Attachment Order 2: Residuals Source Certification Attachment Attachment Order.2-a: Vicinity Map Attachment Order 2-b: Process Flow Diagram Attachment Order 2-c: Quantitative Justification for Residuals Production Attachment Order 2-d: Sampling Plan Attachment Order 2-e Laboratory Analytical Reports (where applicable) Attachment Order 1: Distribution of Residual Solids (DRS form) State of North Carolina Department of Environment and Natural Resources Division of Water Quality DISTRIBUTION OF RESIDUAL SOLIDS (FORM: DRS 070807) (THIS FORM MAY BE PHOTOCOPIED FOR USE AS AN ORIGINAL) Application Number: I. OWNERSHIP INFORMATION: 1. Specify whether the process facility is owned by: ❑ County; ❑ Federal; ❑ Municipal; ❑ State; ® Non -Government. 2. Owner's name (please specify the name of the municipality, corporation, individual, etc.): Synagro (to be completed by DWQ) r { ' - Mailing address: 284 Boger Road = City: Mocksville State: NC Zip: 27028 Physical address: same City: State: Zip: Telephone number: ( 336 ) 998-7150 ext 17 Facsimile number:( 336 ) 998-8450 E-mail address: mpurvearAsynagro.com 3. Signing official's name and title: (See Instruction A) Marshall Purvear Technical Services Director Mailing address: 284 Boger Road City: Mocksville State: NC Zip: 27028 Physical address: Same City: State: Zip: Telephone number: ( 336 ) 998-7150 Ext 17 Facsimile number: ( 336 ) 998-8450 E-mail address: mpuryearAsynagro com II. PERMIT INFORMATION: 1. Application is for: ® new; ❑ modified; ❑ renewed permit (check all that apply). 2. Fee Submitted: $ 810 (See Instruction B) 3. If this application is being submitted to renew or modify an existing permit, provide the following: Permit number: Most recent issuance date: (please attach a copy of the existing permit). and the expiration date: FORM: DRS 070807 Page 3 of 6. Attachment Order 1 III. FACILITY INFORMATION: 1. Name of facility where residuals are processed: Town of Franklin WTP Physical address: 437 Industrial Park Road City: Franklin State: NC Zip: 28744 Telephone number: ( 828-369-8998) Facsimile number: ( ) County where facility is located: Latitude: 35 09'36.73" N Longitude: 83 26' 14.75" W of residual process facility. 2. Facility contact (person familiar with residuals preparation): Robert Hartzel Water Treatment Plant Superintendent Mailing address: 437 Industrial Park Road City: Franklin State: NC Zip: 28744 Physical address: City: Telephone number: ( 828-369-8998 ) E-mail address: State: Facsimile number: ( Zip: 3. Program contact person and/or consulting firm who prepared application (If different from the above): Marshall Purvear Mailing address: 284 Bojzer Road City: Mocksville State: NC Zip: 27028 Physical address: City: State: Zip: Telephone number: ( 336 ) 998-7150 ext. 17 Facsimile number: ( 336 ) 998-8450 E-mail address: mDurvear(@,synaizro.com 4. Is the residual process facility also the generator? ® Yes; ❑ No 5. If the residual process facility is not the same as the generator, please specify delivery frequency and quantity of residual to be processed: 6. Length of residuals storage at facility: 180 days days (the Division requires a minimum 30 days storage in units that are separate from treatment system, i.e. not in clarifiers, aeration basins, etc.). IV. RESIDUALS QUALITY INFORMATION: 1. Specify if residuals are regulated under (check one): ❑ 40 CFR Part 503 or 40 CFR Part 257. 'FORM: DRS 070807 Page 4 of 6 Attachment Order 1 2. Specify how these residuals will be distributed: ❑ sold or given away in bags or other containers; ❑ lawn (bulk); ❑ home garden (bulk); ® other; Land applied to agricultural fields 3. Complete the following if residuals are to be mixed with other materials: Type of Materials I Amounts to be added per 1.0 dry ton of residuals (dry ton) 4. Approximate amounts of the final product to be distributed 300 dry tons per year. 5. Provide a description of the onsite storage management plan for the treated residuals (including estimated average and maximum storage times prior to distribution): The residuals are stored in a half acre lagoon prior to being land applied which gives the town over 180 days storage time based on the amount of solids that they are currently producing V. ADDITIONAL REQUIRED INFORMATION: 1. Provide a narrative explaining the following: - a. How will. the materials be handled and transported from where the residuals were produced to where it will be treated? b. How will the residuals be processed/treated (attach process flow diagram). c. How will leachate collection be handled? d. Where will the residuals be stored until processed? e. How will the final product be distributed (packaging)? 2. Attach a marketability statement detailing destinations and approximate amounts of the final product to be distributed. 3. Provide either a label that shall be affixed to the bagged processed residual or an information sheet that shall be provided to the person who receives the processed residual. The label or information sheet shall contain, at a minimum, the following information: a. The name and address of the person who prepared the residual that is sold or given away in a bag or other container for application to the land. b. A statement that application of the residual to the land is prohibited except in accordance with the instructions on the label or information sheet. c. A statement that the residuals shall not be applied to any site that is flooded, frozen or snow-covered. d. A statement that adequate procedures shall be provided to prevent surface runoff from carrying any disposed or stored residuals into any surface waters. e. Information on all applicable setbacks in accordance with 15A NCAC 02T .1108(b). f. A statement that the residuals shall be applied at agronomic rates and recommended rates for intended uses. FORM: DRS 070807 Page 5 of 6 Attachment Order 1 Professional Engineer's Certification: (Application Packages Involving New or Changes to Treatment and Storage Units) attest that this application for has been reviewed by me and is accurate and complete to the best of my knowledge. I further attest that to the best of my knowledge the proposed design has been prepared in accordance with the applicable regulations. Although certain portions of this submittal package may have been developed by other professionals, inclusion of these materials under my signature and seal signifies that I have reviewed this material and have judged it to be consistent with the proposed design. North Carolina Professional Engineer's Seal, Signature, and Date: t J J J Applicant's Certification;' _ The applicant or any affiliate has not been convicted of an environmental crime, has not abandoned a wastewater facility without proper closure, does not have an outstanding civil penalty where all appeals have been exhausted or abandoned, are compliant with any active compliance schedule, and do not have any overdue annual fees under Rule 2T .0105. ® Yes F-J_ No, Explain; I, Marshall Purvear , attest that this application for Synagro has been reviewed by me and is accurate and complete to the best of my knowledge. I understand that if all required parts of this application are not completed and that if all required supporting information and attachments are not included, this application package will be returned to me as incomplete. Signature Date 0V C,51 / THE COMPLETED APPLICATION PACKAGE, INCLUDING ALL SUPPORTING INFORMATION AND MATERIALS, SHOULD BE SENT TO THE FOLLOWING ADDRESS: NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY AQUIFER PROTECTION SECTION LAND APPLICATION UNIT By U.S. Postal Service: 1636 MAIL SERVICE CENTER RALEIGH, NORTH CAROLINA 27699-1636 By Courier/Special Delivery: 2728 CAPITAL BOULEVARD RALEIGH, NORTH CAROLINA 27604 TELEPHONE NUMBER: (919) 733-3221 FORM: DRS 070807 Page 6 of 6 Attachment Order 1 FARM REPORT HARNETT CO. UTILITIES, NC Synagro Field#: Month & Year: April 2010 Landowner: County: HARNETT Operator: Latitude: 35.16'56" Crop: FESCUE Longitude: 78.41'53" Acres: 25 (10.13 ha ) Operator Address: Last Date Applied This Month: April 30, 2010 Month To Date Year To Date Cumulative Applied Amounts As Hauled Gallons Applied- 440,200.00 440,200.00 0.00 Applied Amounts Converted To Dry Weight Dry Tons/Acre Applied: 1.44 1.44 0.00 13.40 **************** POUNDS PER ACRE APPLIED (Kilograms Per Hectare Applied) MONTH YEAR PARAMETER TO DATE TO DATE CUMULATIVE MACRO NUTRIENTS Est. Avail Nitrogen 6.74 6.74 Est. Avail Phosphate 6.16 6.16 Total Phosphorus (P) 5.35 5.35 Total Potassium (K) 2.99 2.99 Total Potash (K20) 3.59 3.59 Calcium 8.00 8.00 Magnesium 3.94 3.94 Sulfur 19.66 19.66 MICRO NUTRIENTS Manganese 2.85 (3.19) 2.85 (3.19) 44.01 (49.29) Zinc 0.20 (0.22) 0.20 (0.22) 1.95 (2.18) Copper 1.18 (1.32) 1.18 (1.32) 25.14 (28.16) Molybdenum 0.01 (0.01) 0.01 (0.01) 0.25 (0.28) Iron 89.51 (100.25) 89.51 (100.25) TRACE METALS Arsenic 0.02 (0.02) 0.02 (0.02) 0.41 (0.46) Cadmium <.01 (<.01) <.01 (<.01) 0.03 (0.03) Chromium 0.16 (0.18) 0.16 (0.18) 1.73 (1.94) Lead 0.04 (0.04) 0.04 (0.04) 0.30 (0.34) Mercury <.01 (<.01) <.01 (<.01) 0.01 (0.01) Nickel 0.05 (0.06) 0.05 (0.06) 0.44 (0.49) Selenium <.01 (<.01) <.01 (<.01) 0.13 (0.15) * Note: Parameters are given in pounds per acre unless otherwise noted. NR = Data not reported to Synagro Technologies, Inc. or Data not required. Town of Franklin NC Water Treatment Plant Narrative for Class A Residuals This project involves the removal of alum residuals from the Town of Franklin's Water treatment plant. These residuals are produced by adding aluminum sulfate to raw water drawn from Cartoogechaye Creek. The water alum mixture is then allowed to settle in 3 settlement basins for a volume of about 150,000 gallons in order to allow the water and solids (mainly mud and silt) to separate. The solids are then moved by gravity to the holding ponds in order to settle out further. When the lagoons start to get full the lagoons will be mixed up and the solids pumped out as a liquid. The residuals will then be land applied to agricultural fields at rates well below the agronomic rate due to the low nitrogen content of the material. The residuals receive no further treatment after they are placed in the lagoon. The residuals will be transported in sealed tankers to the land application site that will be used for that event. No leachate will be collected from this process since the residuals are going to be land applied as a liquid. Attachment Order la: Signing Official Delegation Letter December 15, 2010 Division of Water Quality Land. Application Unit 1636 Mail Service Center Raleigh, NC 27699-1636 Subject: Permitting Signature Authority To Whom It May Concern: As an appropriate signing official for Synagro Central, LLC., as designated by .15A NCAC 2T .0106(c), I hereby delegate authority to sign and certify all permit applications, reports or other permit related documents to the following staff for the following permit types (sewer, spray, land application) and/or permit numbers: Position Person Currently in Position Permit Type or Permit Number Technical Services Director Marshall Puryear New .Distribution of Residual Solids (Synagro Central LLC) Regional Operations Director Bill Cotter New Distribution of Residual. Solids (Synagro Central .LLC) If you have any questions, please contact we at the following: PermtteelApplicant name (please print): Mark Miller Title: General Manager Services Division Complete mailing address: 7014 East Baltimore Street City: Baltimore State: MD Zip: 11224 Telephone number: (410) 284-4120 Facsimile number: (410) 2842-7466 Sincerely, Attachment Order. 2: Residuals Source Certification Attachment (RS CA form) State of North Carolina Department of Environment and Natural Resources Division of Water Quality RESIDUALS SOURCE CERTIFICATION ATTACHMENT (FORM: RSCA 070807) (THIS FORM MAYBE PHOTOCOPIED FOR USE AS AN ORIGINAL) Applicant's name: Smagro Check all that apply: ® NEW RESIDUALS PROGRAM ❑ RENEWED RESIDUALS PROGRAM ❑ INCREASE ❑ DECREASE the maximum permitted annual dry tonnage for this residuals source - generating facility certified for this residuals program. Current: 0 Dry Tons/yr. and proposed: 300 Dry Tons/yr. ❑ ADD ❑ DELETE this residuals source -generating facility to/from those certified for this residuals program. ❑ OTHER Explain: I. RESIDUALS SOURCE -GENERATING FACILITY INFORMATION (See Instruction B.): 1. Name of facility: Town of Franklin Water Treatment Plant 2. Facility permit holder: Town of Franklin NC Facility permit holder is (check one): ❑ federal, ❑ state, ® local government, or ❑ private. Facility permit number: PWS 01-57-010 Facility permit issued by (check one): ❑ Div. of Water Quality, ® Div. of Environmental Health, or ❑ other (explain: ). 3. If the facility permit is not issued by the Div. of Water Quality, complete the following: a. Facility contact person and title: Robert Hartzel Water Treatment Plant Superintendent Facility complete mailing address: 437 Industrial Park Road City: Franklin State: NC Zip: 28744 Telephone number: ( 828-369-8998) Facsimile number: ( ) E-mail address: b. Facility complete location address: Same as above City: State: Latitude: 35 09' 36.73"N and longitude: 83 26' 14.75" w 4. County where facility is located: Zip: 5. Purpose of the facility (check one): ❑ treatment of municipal wastewater, ❑ treatment of 100% domestic wastewater, ® treatment of potable water, ❑ treatment of 100% industrial wastewater, ❑ treatment of industrial wastewater mixed with domestic wastewater, or (approximate percentages: % industrial and % domestic) ❑ other (explain: FORM: RSCA 070807 Page 2 of 8 Attachment Order 2 6. Does the facility have an approved pretreatment program: ❑ yes ® no 7. Facility permitted/design flow: 2.2 MGD and facility average daily flow: 1.5 MGD. 8. Average amount of residuals being generated at this facility 300 dry tons per year. 9. Specify the following regarding treatment and storage volumes available at the facility: Type and volume of residuals treatment: The residuals are stored in a concrete storage system before being transferred to the lagoon. The concrete storage is capable of holding approximately 275,000 gallons Type and volume of residuals storage (i.e., outside of residuals treatment units): The plant has 2 lagoons with a capacity of approximately 500,000 gallons each H. RESIDUALS QUALITY INFORMATION (See Instruction C.): 1. Specify if residuals are regulated under (check one): ❑ 40 CFR Part 503 or ® 40 CFR Part 257. 2. Specify if residuals are intended for (check one): ® Land Application/Distribution (Class A or Equivalent). Complete all items EXCEPT Items II.4b., 7b., and 7c. ❑ Land Application (Class B or Equivalent). Complete all items EXCEPT Items II.4b., 7a., and 7c. ❑ Surface Disposal. Complete all items EXCEPT Items II.4a., 5., 7a., 7b., and 8. ***FORM: RSCA CONTINUES ON NEXT PAGE*** FORM: RSCA 070807 Page 3 of 8 Attachment Order 2 3. Hazardous Waste Determination: Complete the following to demonstrate that the residuals are non- hazardous under RCRA: a. Are the residuals are listed in 40 CFR §261.31-§261.33: ❑ yes ® no. If yes, list the number(s): b. Specify whether or not the residuals exhibit any of the characteristics defined by 40 CFR §261.21- §261.24: ❑ yes ® no. Fill in the following tables with the results of the latest toxicity characteristic leaching procedure (TCLP) analysis as well as those for corrosivity, ignitability, and reactivity: laboratory: Summit Environmental Technologies and date of analysis: 10/12/2010 Passed corrosivity test: ® yes ❑ no. pH: 6.73 s.u. (2 < pH < 12.5). Passed ignitability test: ® yes ❑ no. Flashpoint: >140 OF (> 1400F). Passed reactivity test: ® yes ❑ no. HCN: ND mg/kg (<250) & H2S: ND mg/kg (<500). TCLP Parameter Limit (mg/L) Result (mg/L) TCLP Parameter Limit (mg/L) Result (mg/L) Arsenic 5.0 ND Hexachlorobenzene 0.13 <0.1 Barium 100.0 ND Hexachloro-1,3-Butadiene 0.5 <0.1 Benzene 0.5 <0.1 Hexachloroethane 3.0 <0.1 Cadmium 1.0 ND Lead 5.0 ND Carbon Tetrachloride 0.5 <0.1 Lindane 0.4 <0.002 Chlordane 0.03 <0.01 Mercury 0.2 ND Chlorobenzene 100.0 <0.1 Methoxychlor 10.0 <0.002 Chloroform 6.0 <0.1 Methyl Ethyl Ketone 200.0 <2.0 Chromium 5.0 ND Nitrobenzene 2.0 <0.1 m-Cresol 200.0 <5.0 Pentachlorophenol 100.0 <0.25 o-Cresol 200.0 <5.0 Pyridine 5.0 <0.25 p-Cresol 200.0 <5.0 Selenium 1.0 ND Cresol 200.0 <5.0 Silver 5.0 ND 2,4-D 10.0 <5.0 Tetrachloroethylene 0.7 <0.1 1,4-Dichlorobenzene 7.5 <0.1 Toxaphene 0.5 <0.1 1,2-Dichloroethane 0.5 <0.1 Trichloroethylene 0.5 <0.1 1,1-Dichloroethylene 0.7 <0.1 2,4,5-Trichlorophenol 400.0 <0.25 2,4-Dinitrotoluene 0.13 <0.1 2,4,6-Trichlorophenol 2.0 <0.25 Endrin 0.02 <0.002 2,4,5-TP (Silvex) 1.0 <0.5 Heptachlor and its Hydroxide 0.008 <0.002 Vinyl Chloride 0.2 <0.2 FORM: RSCA 070807 Page 4 of 8 Attachment Order 2 4. Metals Determination: Complete one of the following tables (i.e., as applicable) to demonstrate that the residuals do not violate the ceiling concentrations for metals regulated under 15A NCAC 02T .1105. a. For Class A or Class B: Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following metal parameters: Laboratory: A&L Eastern Labs and date of analysis: 10/04/2010 Parameter Ceiling Concentration Limits (ClassA & ClassB) - (mg/kg) Monthly Average Concentration Limits (For Class A Only) (mg/kg) Result (mg/kg) Arsenic 75 41 4.0 mg/kg Cadmium 85 39 <1.0 mg/kg Copper 4,300 1,500 61 mg/kg Lead 840 300 10 mg/kg 'Mercury 57 17 <0.4 mg/kg Molybdenum 75 n/a <5 mg/kg Nickel 420 420 22 mg/kg Selenium 100 100 <1.0 mg/kg Zinc 7,500 2,800 84 mg/kg b. For Surface Disposal: Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following metal parameters: Laboratory: and date of analysis: Closest Distance to Property Lines (meters) Arsenic (mg/kg) Chromium (mg/kg) Nickel > 0 but < 25 30 200 210 �t25 but < 50 34 220 240 >50 but < 75 39 260 270 >_75 but < 100 46 300 320 >_100 but < 125 53 360 390 >_125 but < 150 62 450 420 >_150 73 600 420 FORM: RSCA 070807 Page 5 of 8 Attachment Order 2 5. , Nutrient/Micronutrient Determination: Complete the following: a. Total solids: 4.71 %. b. Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following nutrient and micronutrient parameters: laboratory: A&L Eastern Labs and date of analysis: 10/04/2010 Parameter Result (mg/kg, dry weight) Aluminum 21700 mg/kg Ammonia -Nitrogen 1700 mg/kg Calcium 1130 mg/kg , Magnesium 2300 mg/kg Nitrate -Nitrite Nitrogen 23.4 mg/kg pH (Standard Unit) 6.47 Phosphorus 854 mg/kg Potassium 1260 mg/kg Sodium 185 mg/kg Total Kjeldahl Nitrogen 6790 mg/kg c. Using the results listed in Item II. 5b. above, calculate the sodium adsorption ration (SAR): 0.16 d. Specify the mineralization rate to be used in calculating the plant available nitrogen (PAN) of the residuals: 40 %. This rate is a ® default value or ❑ actually established. If the residuals are not generated from the treatment of municipal or domestic wastewater, explain or provide technical justification as to why the selected default value is appropriate to be applied to these residuals: Calculate the PAN for the residuals (i.e., on a dry weight basis) and list the results in the following table: Application Method First Year Five -Year PAN Maximum Adjusted PAN (mg/kg) (mg/kg) Surface 2909 mg/kg 4005 mg/kg Injection/Incorporation 3759 mg/kg 4855 mg/kg e. Are the residuals a registered fertilizer with the NC Department of Agriculture and Consumer Services: ❑ yes ® no. If yes, provide date of registration approval: the current registration number: and the fertilizer equivalent: %, %, and %. FORM: RSCA 070807 Page 6 of 8 Attachment Order 2 6. Other Pollutants Determination: Specify whether or not there are any other pollutants of concern in the residuals and list the results of the latest analyses: There are no pollutants of concern in the residuals from 7. Pathogen Reduction Determination: Specify which alternative(s) will be used to meet the pathogen reduction requirements: a. For Class A or Equivalent: ® A fecal coliform density that is demonstrated to be less than 1,000 MPN per gram of total dry solids. OR ❑ A salmonella sp. density that is demonstration to be less than 3 MPN per 4 grams of total dry solids. AND one of the following (except for residuals regulated under 40 CFR Part 257 that are to be distributed): ❑ Alternative 1 [40 CFR §50132 (a)(3)] - Time/Temperature Compliance. ❑ Alternative 2 [40 CFR §503.32 (a)(4)] - Alkaline Treatment. ❑ Alternative 3 [40 CFR §503.32 (a)(5)] - Prior Testing for Enteric Virus/Viable Helminth Ova. ❑ Alternative 4.[40 CFR §503.32.(a)(6)] - No Prior Testing for Enteric. Virus/Viable Helminth Ova. ❑ Alternative 5.[40 CFR §503.32 (a)(7)] - Process to Further Reduce Pathogens (PFRP). Specify one: ❑ composting, ❑ heat drying, ❑ heat treatment, ❑ pasteurization, ❑ thermophilic aerobic digestion, ❑ beta ray irradiation, or ❑ gamma ray irradiation. ❑ Alternative 6 [40 CFR §503.32 (a)(8)] - PFRP-Equivalent Process. Explain: b. For Class B or Equivalent: ❑ Alternative 1 [40 CFR §503.32. (b)(2)] - Fecal Coliform Density Demonstration. ❑ Alternative 2 [40 CFR §503.32 (b)(3)] -Process to Significantly Reduce Pathogens (PFRP). Specify one: ❑ aerobic digestion, ❑ air drying, ❑ anaerobic digestion, ❑ composting, or ❑ lime stabilization. ❑ Alternative 3 [40 CFR §503.32 (b)(4)] - PSRP-Equivalent Process. Explain: ® Not Applicable - Regulated under 40 CFR Part 257 with NO Domestic Wastewater Contribution. c. For Surfaee Disposal: ❑ Alternative for Surface Disposal Units Only [40 CFR §503.33 (b)(11)] - Soil/Other Material Cover. ❑ Select One of the Class A or Equivalent Pathogen Reduction Alternatives in Item II. 7a. above. ❑ Select One of the Class B or Equivalent Pathogen Reduction Alternatives in Item II. 7b. above. ® Not Applicable - Regulated under 40 CFR Part 257 with NO Domestic Wastewater Contribution. FORM: RSCA 070807 Page 7 of 8 Attachment Order 2 8. Vector Attraction Reduction Determination: Specify which alternatives) will be used to meet the vector attraction reduction requirements: ❑ Alternative 1 [40 CFR §503.33 (b)(1)] - 38% Volatile Solids Reduction (Aerobic/Anaerobic Digestion). ❑ Alternative 2 [40 CFR §503.33 (b)(2)] - 40-Day Bench Scale Test (Anaerobic Digestion). ❑ Alternative 3 [40 CFR §503.33 (b)(3)] - 30-Day Bench Scale Test (Aerobic Digestion). ❑ Alternative 4 [40 CFR §503.33 (b)(4)] - Specific Oxygen Uptake Rate Test (Aerobic Digestion). ❑ Alternative 5 [40 CFR §503.33 (b)(5)] - 14-Day Aerobic Processes. ❑ Alternative 6 [40 CFR §503.33 (b)(6)] - Alkaline Stabilization. ❑ Alternative 7 [40 CFR §503.33 (b)(7)] - Drying of Stabilized Residuals. ❑ Alternative 8 [40 CFR §503.33 (b)(8)] - Drying of Unstabilized Residuals. ❑ Alternative 9 [40 CFR §503.33 (b)(9)] - Injection. ❑ Alternative 10 [40 CFR §503.33 (b)(10)] - Incorporation. ❑ Alternative for Surface Disposal Units Only [40 CFR §503.33 (b)(11)] - Soil/Other Material Cover. ❑ Alternatives for Animal Processing Residuals Only: Specify one: ❑ injection, ❑ incorporation, or ❑ lime addition to raise pH to 10. ® Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution. FORM: RSCA 070807 Page 8 of 8 Attachment Order 2 Attachment Order 2-a: Vicinity Map SYNAGIRO LOCATION NIAP A Residuals Management Company N� ct, 4a� I Q Y1 `� Ali, 1 Lenka t iz eyf Ip 1 Any 0 , 1 — I `r ��.� � p tc °;P FRNeed IL ° 7T peck I 0Rp H'A A G� I: ..- LItKLOG CREEK i ve, I R ; c f ,`Knob f E CL Knob orner ` \♦a r-!_ I• d co Fi dg ° .. I^ n. Wr. oQ off♦ .r ` 4 ; fl�, o \I v i l - --o j '`N J`c `•� i.ac ou tte ^ - I NGL .Q• BI9 yMl R o o a J{ m 'teatherma G1e. 0 4 ak t. e _ "GAP OEQ . _ i -. • _c ... -_ y JDean / o �' ov¢oQsci .. -� � .q0�� `° o ` 2 NGL N�•.n�,x i .: . .. Stites G lhlend / tna !r- l `O`R'\ -J . kQ•7arS \f lLICO -y_ ...i .. _1310 e F rk •`'1 //i c ` ... 0 , pp• S B1dA � 4o C ¢prin � o ELC •0 � ,_-i`� :: 'i'�, � ALIEN °C4j'$�_.. I Ocl ' U . LKDn ,•. I o�� I r /' i I1� � 1 i Oo�O L b..AG9E n1 ! �h (/ `� I �iAl • s / y I oae son NGL .l Turkgl' . aa� >� `, '. ` or"i/�G� '3ac • - ��� "i- AAer o 1 .\ qq0 • r` Zj rf1 \� U r iKhod LYIe. Y. L. ' pry-- --'L F. 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COUNTY (i ,4 G o N OWNER o w N 4- FM o I L l l) Attachment Order 2-b: Process Flow Diagram �f 4: M/x TOWN OF FRANKLIN WATER TREATMENT PLANT w4Q pmW b. ;/ooal,F Z,,.?�s 00,65 Attachment Order 2-c: Quantitative Justification for Residuals Production Quantitative Justification for Residuals Production Rate Facility: Town of Franklin WTP Requested Permitted Rate: 300 dry tons/year Justification: The Town of Franklin currently produces and stores it's water plant residuals in a settling basin that it cleans out every 2-3 years. It is at this time that the volume of solids is calculated based on the percent solids of the lagoon and the depth of the solids. Calculations: The lagoons at this plant hold approximately 500,000 gallons each the percent solids are 4-5% solids. The requested dry tonnage should provide adequate volume to do a thorough cleaning of these lagoons without exceeding the permitted dry tonnage. Attachment Order 2-d: Sampling Plan Residuals Sampling Plan Town of Franklin WTP Land Application Class A Program Nutrients and Metals Analysis Sampling Point: Lagoon Sampling Frequency: Annually Sample Type: Composite Lab: A&L Eastern Agricultural Laboratories, Inc. Pathogen (Fecal Coliform Density Demonstration) Sampling.Point: Lagoon Sampling Frequency: Annually Sample Type: Composite Lab: Statesville Analytical Vector Attraction Reduction Not required due to being residuals being generated from the treatment of potable water with no domestic wastewater contribution. Sampling Points: Sampling Frequency: Sample Type Lab: TCLP + RCI Sampling Point: Lagoon Sampling Frequency: Annually Sample Type: Composite Lab: Summit Environmental Technologies; Inc Attachment Order 2-e: Laboratory Analytical Reports SUMMIT ENVIRONMENTAL TECHNOLOGIES, INC. Analytical Laboratories LABORATORY REPORT Client Synagro Southeast 284 Boger Rd. Mocksville, NC 27028 Order Number 1015564 Project Number Franklin WTP Issued Tuesday, October 12, 2010 Total Number of Pages 5 (excluding C.O.C. and cooler receipt form) Approved By : Q it4-i QA Manager NELAC Accreditation #E87688 "Analytical Integrity" - EPA Certified - NELAP Certified 3310 Win Street - Cuyahoga Falls, Ohio 44223 - Phone: 330-253-8211 - Fax: 330-253-4489 Web Site: www.settek.com SU M-MIT'... ENVIRONMENTAL TECHNOLOGIES, INC. October 12, 2010 Analytical Laboratories Client: Synagro Southeast Address: 284 Boger Rd. Mocksville, NC 27028 Received: 9/24/2010 Project #: Franklin WTP TCLP Metals Client ID# Lab ID# Collected Anal tc Rep Lmt Result Units Mahia Method DF Re Lvl Run Analyst Frankling NC WTP 1015564-01 16-Sep-10 Selenium 0.5 ND mg/I SL 1311 1 1 05-Oct-10 VVK Frankling NC WTP 1015564-01 16-Sep-10 Barium 5 ND mg/I SL 1311 1 100 05-Oct-10 VVK Frankling NC WTP 1015564-01 16-Sep-10 Arsenic 0.5 ND mg/I SL 1311 1 5 05-Oct-10 WK Frankling NC WTP 1015564-01 16-Sep-10 Chromium 0.2 ND mg/I SL 1311 1 5 05-Oct-10 VVK Frankling NC WTP 1015564-01 16-Sep-10 Silver 0.5 ND mg/I SL 1311 1 5 05-Oct-10 VVK Frankling NC WTP 1015564-01 16-Sep-10 Mercury 0.002 ND mg/1 SL 1311 1 0.2 05-Oct-10 WK Frankling NC WTP 1015564-01 16-Sep-10 Cadmium 0.1 ND mg/1 SL 1311 1 1 05-Oct-10 VVK Frankling NC WTP 1015564-01 16-Sep-10 Lead 0.5 ND mg/I SL 1311 1 5 05-Oct-10 VVK TCLP Volatiles Client ID# Lab ID# Collected Anal tc Rep Lmt Result tinits Mahix Method DF RegLvl Run Analyst Frankling NC WTP 1015564-01 16-Sep-10 Benzene 0.1 <0.1 mg/L SL _ 1311 1 0.5 05-Oct-10 MS Frankling NC WTP 1015564-01 16-Sep-10 2-Butanone (MEK) 2 <2.0 mg/L SL 1311 1 200 05-Oct-10 MS Frankling NC WTP 1015564-01 16-Sep-10 Vinyl Chloride 0.2 <0.2 mg/L SL 1311 _ 1 0.2 05-Oct-10 MS Frankling NC WTP 1015564-01 16-Sep-10 Chloroform 0.1 <0.1 mg/L SL 1311 1 6 05-Oct-10 MS Frankling NC WTP 1015564-01 16-Sep-10 Chlorobenzene 0.1 <0.1 mg/L SL 1311 1 100 05-Oct-10 MS Frankling NC WTP 1015564-01 16-Sep-10 Tetrachloroethene 0.1 <0.1 mg/L SL 1311 1 0.7 05-Oct-10 MS Frankling NC WTP 1015564-01 16-Sep-10 1,1-Dichloroethene 0.1 <0.1 mg/L SL 1311 1 0.7 05-Oct-10 MS Frankling NC WTP 1015564-01 16-Sep-10 Carbon tetrachloride 0.1 <0.1 mg/L SL 1311 1 0.5 05-Oct-10 MS Frankling NC WTP 1015564-01 16-Sep-10 1,2-Dichloroethane 0.1 <0.1 mg/L SL 1311 1 0.5. 05-Oct-10 MS Frankling NC WTP 1015564-01 16-Sep-10 Tdchloroethene 0.1 <0.1 mg/L SL 1311 1 0.5 05-Oct-10 MS TCLP BNA Client 1D# Lab ID# Collected Anale Rep Lmt Result Units Matrix Method DP RegLvl Run Analyst Frankling NC WTP 1015564-01 16-Sep-10 Hexachloro-1,3-butadiene 0.1 <0.1 mg/I SL 1311 1 0.5 05-Oct-10 AE Frankling NC WTP 1015564-01 16-Sep-10 Nitrobenzene 0.1 <0.1 mg/1 SL 1311 1 2 05-Oct-10 AE Frankling NC WTP 1015564-01 16-Sep-1,0 2,4-Dinitrotoluene 0.1 <0.1 mg/I SL 1311 1 0.13 05-Oct-10 AE Frankling NC WTP 1015564-01 16-Sep-10 Hexachloroethane 0.1 <0.1 mg/1 SL .1311 1 3 05-Oct-10 AE Frankling NC WTP 1015564-01 16-Sep-10 1,4-Dichlorobenzene 0.1 <0.1 mg/1 SL 1311 1 7.5 05-Oct-10 AE Frankling NC WTP 1015564-01 16-Sep-10 Pentachlorophenol 0.25 <0.25 mg/I SL 1311 1 100 05-Oct-10 AE Frankling NC WTP 1015564-01 16-Sep-10 2,4,6--Trichlorophenol 0.25 <0.25 mg/1 SL 1311 1 2 05-Oct-10 AE Frankling NC WTP 1015564-01 16-Sep-10 2,4,5-Trichlorophenol 0.25 <0.25 mg/1 SL 1311 1 400 05-Oct-10 AE Frankling NC WTP 1015564-01 16-Sep-10 Pyridine 0.25 <0.25 mg/I SL 1311 1 5 05-Oct-10 AE Frankling NC WTP 1015564-01 16-Sep-10 Cresols 5 <5.0 mg/1 SL 1311 1 200 05-Oct-10 AE Frankling NC WTP 1015564-01 16-Sep-10 Hexachlorobenzene 0.1 <0.1 mg/l SL 1311 1 0.13 05-Oct-10 AE Page 4 "Analytical Integrity" - EPA Certified • NELAP Certified 3310 Win Street • Cuyahoga Falls, Ohio 44223 o Phone: 330-253-8211 - Fax: 330-253-4489 Web Site: www.settek.com TCLP Pesticides Client [DO Lab I # ('ollLcted Anal yte Rep Lmt Result Frankling NC WTP 1015564-01 16-Sep-10 Heptachlor Epoxide 0.002 <0.002 Frankling NC WTP 1015564-01 16-Sep-10 Toxaphene 0.1 <0.1 Frankling NC WTP 1015564-01 16-Sep-10 Chlordane 0.01 <0.01 Frankling NC WTP 1015564-01 16-Sep-10 Methoxychlor 0.002 <0.002 Frankling NC WTP 1015564-01 16-Sep-10 Endrin 0.002 <0.002 Frankling NC WTP 1015564-01 16-Sep-10 Heptachlor 0.002 <0.002 Frankling NC WTP 1015564-01 16-Sep-10 Gamma-BHC 0.002 <0.002 Client ID# Lab ID# Colleted Analyte Frankling NC V fP 1015564-01 16-Sep-10 2,4,5-TP(Silvex) Frankling NC WTP 1015564-01 16-Sep-10 2,4,D Clime ID# lab 11)# Colleeted Analyte Frankling NC WTP 1015564-01 16-Sep-10 Flash Point Client ID# Lab ID# Collected Analyze Frankling NC WTP . 1015564-01 16-Sep-10 pH TCLP Herbicides Rep Lmt Result 0.5 <0.5 5 <5.0 Result >140F October 12, 2010 Client: Synagro Southeast Address: 284 Boger Rd. Mocksville. NC 27028 Received: 9/24/2010 Project #: Franklin WTP Units Matrix Method 2F RegLyl Run Analyst mg/I SL 1311 1 0.008 06-Oct-10 KMG mg/I SL 1311 1 0.5 06-Oct-10 KMG mg/1 SL 1311 1 0.03 06-Oct-10 KMG mg/I SL 1311 1 10 06-Oct-10 KMG mg/I SL 1311 1 0.02 06-Oct-10 KMG mg/I SL 1311 1 0.008 06-Oct-10 KMG mg/I SL 1311 1 0.4 06-Oct-10 KMG Units Matrix Method llF RggLvi Run Analyst mg/I SL 1311 1 1 06-Oct-10 KMG mg/I SL 1311 1 10 06-Oct-10 KMG Units Matrix Method DF LOQ Run Analyst SL 1010 1 12-Oct-10 DVW Result Units Matrix Method DF LOQ Run Analyst 6.73 su@23.9C SL 9010 1 0.01 29-Sep-10 DHC Client ID# Lab ID# Collected Analvtc Result Frankling NC WTP 1015564-01 16-Sep-10 Reactive Cyanide ND Client ID# Lab ID# Collected Analvie Result Frankling NC WTP 1015564-01 16-Sep-10 Reactive Sulfide ND Ihlits Matrix Method N. LOQ Run Analyst mg/kg SL 7.3.3.2 1 0.5 27-Sep-10 TIR Units Matrix Method DF LOQ Run Analyst mg/kg SL 7.3.4.2 1 25 27-Sep-10 TIR Page 5 "Analytical Integrity" - EPA Certified - NELAP Certified 3310 Win Street - Cuyahoga Falls, Ohio 44223 - Phone: 330-253-8211 - Fax: 330-253-4489 Web Site: www.settek.com Report Narrative Client: Synagro Southeast Order Number: 1015564 3 No problems were encountered during analysis of this order number, except as noted. Data Qualifiers: B = Analyte found in the method blank J = Estimated concentration of analyte between MDL (LOD) and Reporting Limit (LOQ) C = Analyte has been confirmed by another instrument or method E = Analyte exceeds the upper limit of the calibration curve. D = Sample or extract was analyzed at a higher dilution X = User defined data qualifier. S = Surrogate out of control limits U = Undetected a = Not Accredited by NELAC ND = Non Detected at LOQ DF = Dilution Factor Limit Of Quantitation (LOQ) = Laboratory Reporting Limit (not adjusted for dilution factor) Limit Of Detection (LOD) = Laboratory Detection Limit Estimated uncertainty values are available upon request. Matrices: A=Air C = Cream DW = Drinking Water L = Liquid O = Oil SL = Sludge SO = Soil S = Solid T = Tablet TC = TCLP Extract WW = Waste Water W = Wipe The test results meet the requirements of the NELAC standard, except where noted. The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the client. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the client for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. "Analytical Integrity" - EPA Certified • iVELAP Certified 3310 Win Street - Cuyahoga Falls, Ohio 44223 m Phone: 330-253-8211 - Fax: 330-253-4489 Web Site: www.settek.com MIN , I` 1 1 • , • Sample Summary Client: Synagro Southeast Order Number: 1015564 Laboratory ID Client ID 1015564-01 Frankling NC WTP 2 Matrix Sampling Date Sludge 9/16/2010 "Analytical Integrity" - EPA Certified • NELAP Certified 3310 Win Street - Cuyahoga Falls, Ohio 44223 o Phone: 330-253-8211 • Fax: 330-253-4489 Web Site: www.settek.com Summit Environmental Ti �jologles, Inc. Cooler Receipt - Client: Order Number; Date Received: Time Received: '3 Number otoxes: N/A Shipper:UPS DHL Airborne US Postal Walk-in Pickup Other: Packaging: Peanuts Bu ble Paper Foam None Other: Tape on cooledbox: (YDN WA Custody Seals intact Y N !A C-O-C in plastic / N NIA IceBlue ice t// I absent / melted N/A Sample Temperature °C NIA C-O-C filled out property O` N N/A Samples in separate bags Y (ZN:_�) N/A Sample containers intact` CID N N/A *If no, list broken sample(s): Sample label(s) complete (ID, date, etc.) N N/A Label(s) agree with C-O-C Of ) N N/A Correct containers used (10 N N/A Suffrclent sample received 1 Y� N NIA Bubbles absent from 40 mL vials- ►l ** Samples with bubbles less than the size of a pea are acceptable. N /A Was client contacted about samples Y N Will client send new samples Y N Client contact: Date/Time: Logged in by: Comments: Rev. 6 Summit Environmental Technologies, Inc. Analysis Request/Chain of Custody 3310 Win Street n.... t, .. n..yt., r,>,: AAI)I)o rr 1. "I , 1C— '10n n« Anon For Summit Environmental Technologies, Inc. use only =� Vuyallvsa IULIl, U111V YYGGJ 161. JJV.GJJ.OGI 1 1'aA. JJV.GJJ.`Y-t07 Page of SET No. Company Name (Please Print) � Project Name Analytical Parameters and Methods � Company Address Project Address �o /J p °O tii Client Phone No. Report to .G Client Fax No. 2 lee Fax Result ✓ ElPO# .7 �AZ a A Bent Email Please Email Results ✓ Quote No. Con Pers t p `� n d a,� � o Sample/ram by / ,„ P Check if Ohio VAP samples ✓ rig # Sample Identification ate Timea Collected Collected �°� ranA. z lit Please Check Analytical Box MENNEN ■/I1 M WEI, ! !�e ram► ANN A 1 MUSL 1' approved Requested Date , manager i Llw. a�, �'' White and yellow pages should accompany samples to the laboratory. The client retains the pink page. t r c n n Page: 1 of 2 Report Number: 10-273-0201 Account Number: 46622 Submitted By: MARSHALL PURYEAR Send To: SYNAGRO CENTRAUTECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 78750 Sample Id: FRANKLIN WTP AFL Eastern Laboratories, Inc. 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271-6446 www.al-labs-east6rn.com Project: FRANKLIN WTP NC CERT#257 REPORT OF ANALYSIS Date Sampled: 9/29/2010 10:13:00 Date Received: 09/30/2010 00:00 Date Reported: 10/04/2010 Total Solids * 4.71 47100 100.0 JM 09/30/2010 15:00 SM-2540G Moisture * 95.29 100.0 JM 09/30/2010 15:00 SM-254OG Total Kjeldahl Nitrogen 0.68 6790 10.0 JM 10/01/2010 08:05 SM-4500-NH3C-TKN Total Phosphorus 0.09 854 100 KM 10/01/2010 08:00 SW 6010C Total Potassium 0.13 1260 100 KM 10/01/2010 08:00 SW 6010C Total Sulfur 0.33 3340 100 KM 10/01/2010 08:00 SW 6010C Total Calcium 0.11 1130 100 KM 10/01/2010 08:00 SW 6010C Total Magnesium 0.23 2300 100 KM 10/01/2010 08:00 SW 6010C Total Sodium 0.02 185 100 KM 10/01/2010 08:00 SW 6010C Total Iron 29600 1 KM 10/01/2010 08:00 SW 6010C Total Aluminum 217000 10 KM 10/01/2010 08:00 SW 6010C Total Manganese 544 1 KM 10/01/2010 08:00 SW 6010C Total Copper 61 1 KM 10/01/2010 08:00 SW 6010C Total Zinc 84 1 KM 10/01/2010 08:00 SW 6010C Ammonia Nitrogen 0.17 1700 10.0 JM 10/01/2010 08:05 SM-4500-NH3C Organic N 0.51 5090 10.0 10/01/2010 08:05 CALCULATION Nitrate+Nitrite-N 23.4 1.00 JM 10/01/2010 08:05 SM-450ONO3F Total Cadmium <1.0 1.0 KM 10/01/2010 08:00 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole orpart, nor may any reference be made Pof� C.to the work. the results, or the company in any advertising, news release, or otherpublic announcements without obtaining our prior written authorization. Pauric McGroary Page: 2 of 2 Report Number: 10-273-0201 Account Number: 46622 Submitted By: MARSHALL PURYEAR Send To: SYNAGRO CENTRAL/TECHNICAL MARY BREWER 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 78750 Sample Id: FRANKLIN WTP Y A&L Eastern Laboratories, Inc. 7621 Whitepine. Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271-6446 www.al-labs-eastem.com Project: FRANKLIN WTP NC CERT#257 REPORT OF ANALYSIS Date Sampled: 9/29/2010 10:13:00 Date Received: 09/30/2010 00:00 Date Reported: 10/04/2010 Total Chromium 79 5 KM 10/01/2010 08:00 SW 6010C Total Nickel 22 5 KM 10/01/2010 08:00 SW 6010C Total Lead 10 5 KM 10/01/2010 08:60 SW 6010C Total Arsenic 4.0 1.0 KM 10/01/2010 08:00 SW 6010C Total Mercury <0.4 0.4 KM 10/01/2010 09:00 SW-7471B Total Selenium <1.0 1.0 KM 10/01/2010 08:00 SW 6010C pH (Standard Units) * 6.47 JM 10/01/2010 08:30 SW-9045D Total Volatile Solids 25.65 256500 100.0 JM 09/30/2010 15:00 SM-2540G Total Molybdenum <5 5 KM 10/01/2010 08:00 SW 6010C Comments: IE LRB WAS SLIGHTLY OUT OF LIMITS FOR "Cu" AND Mn". ALL OTHER QC IS ACCEPTABLE. -IE MATRIX SPIKE RESULTS FOR "AI", "Cr", "Fe", AND "Se" ARE OUT OF LIMITS. ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. / Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made ?Wi 1 Vto the work. the results, or the company in any advertising, news release, or other public announcements withoutobtaining our prior written authorization. a Pauric McGroary Analy deal Results Synagro Central 284 Boger Rd. Mocksville NC 27028 Entered 11123/2010 Reported: 1212/2010 For: -Sample ID Parameter Cust 1,13 Result Units - Method Date Analyzed Analyst 1001 123-5:4 % Soli.ds F4 5.1 % SM2540B 11/23/10 MID 1001123"5.4 Fecal Collform, MTF F4 <4 MPN/g SM92210E, 11/23/10 MID Respectfully submitted, Dena Myers N.CQert #440, N6-DW Cert #37756, EPA NCOG9,09 - I P.O. Box 228 • Statesville, North Carolina 28687 • 704/872/4697 Client: 0" STATESVILLE ANALYTICAL 122Court Street - P.O.Box 228 Statesville, NC 28687 (704) 872-4697 Address: '> e." 'o Contact Person: Phone # IlDe- FAX# Chain of PO # Requisitioned by: Crime Date) Custody Record Customer Lab -ID # Time Sampled Date Sampled E 0 Matrix Parameters requested for analysis Sludge l W 1 VVW Sample 1D# (Grab Only) (Grab Only) 0 Q X12 '5' X 5W) 2/ 6E '2L 61V 17- If it f; 4 Relinquished Time 1Gi am, pm Date," /0-3/ /0 Sampled by: Received by: Time am, pm Date Transported by: Relinquished by: Time am, pm Date Holding times met: 'eM,�PM Received by: Time JID at Compliance work: Composite Sampling #11: Time begin- am, pm Date Non-compliance work: Time end am, pm Date Lab Comments: Composite Sampling #2: 6 1 Time begin- am, pm Date Time end am, pm Date