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WQ0031725_Annual Report_20120217
sop I. Annual Land Application Certification Form . • Was a certification form submitted? �S • Was lard application conducted during the reported year? Y • How many dry -tons and dry tons per acre were applied? /oo , "L (" 1O 7- • Were the applications within the pe.TM:itted amourt?y.es. pT (fly_ • Ver ify PA;N if more than 10 tors/acre • Did it indicate compliance?Ye_Y • Was it signed by the appropriate people? yt5 2. Monitoring + Were the analyses conducted at the required frequency? y,,-S + Were the metals analyses reportedIon the Residual Sampling Summary Form? y V_Y • Were the results reported in mg/kg?qt,3 • . Were the heavy metals within ceiling concentration permit limits?* • If no, were the lab analyses attached? • Were all the required parameters tested? �es • Was TCLP analysis conducted? yles 3. Field Summary • Were the land application. events recorded on the Field Summary Forms9 a • Was a Field Summary Form submitted for each Feld?�e5 • Were all the residuals applied to permitted land?qe,5 • Were all the residuals applied from permitted sources?q -3 • Were the field Ioading rates for each metal and PAN calculated (year to date)? • Were the cumulative pollutant loading rates calculated?y-es • Were the calculations correct?�,,_5 • Were the PA1V loading rates.within permit limits?y,,-S • Were the heavy metal cumulative pollutant loading rates within permit limits?pe-S • Were the residuals applied on a suitable crop?Y,e5 • Were the applications conducted during the crop's growing season?y, • Were the Field Summary Forms complete?,� 4. Pathogen and Vector Attraction Reduction • Was a signed copy of the Paten and Vector Attractions eduction Form subm tted? p� • Did the form indicatFIhe period of coverage,'the residual class, and the pathogen reduction alternative and the vector attraction reduction option used'? •. Was the appropriate documentation to show pathogen and vector attraction reduction included in the report? • Was pathogen and vector attraction reduction demonstrated according to 40 CFR Part 503?. 1W (i 4�0 �'S WY� GnO Qf E �i � fir^ Z 1-✓` 1 5. Soil Tests A 2 04[u(A�;o�r. • Was a Standard Soil Fertility Analysis conducted for each application field? � � �• 8' • Were the soil pH's 6.0 or greater for each application field? 9® 'a�2 =5;b ,$"� =S�g =�Ie`ilje,5 �P,G= • Were the copper and zinc indexes in the soil less than 3000 for each application DP2= 6'� time added }� o�ta, ol��� DP3 421�O 6. Generale pQ�, oQl-c� �-)-1 a3 ca • Was the report in the proper format? P S= S • Were. any parts of the annual report missing? N • Was the report submitted on time? q __S: : , * Any violations of ceiling concentrations should iie reported to. Pretreatment for -municipalities. only. l-.erne . no! ,aal gd 1110 F"e. JDr?V ?�' - tv.+`ao76 aoP1"cA4,,o" -h-)' OPO Class B Pathogen Review Alternative 1 - Fecal Coliform Density • Was the sampling conducted at the required frequency? ye-1 • Were seven samples taken? i es 6,"+ n b-�- o UJs-q //Q—' � • Was the geometric mean calculated and done correctly? �,65 • Did the results show compliance (less than either 2,000,000 MPN/gram of total solids or 2,000,000 Colony Forming Units/gram of total solids) eS Alternative 2 - Use of Process to Significantly Reduce Pathogens (one of five) • Was the sampling conducted at the required frequency? Aerobic Digestion • Was it an aerobic process (Inspection)? • Were logs submitted showing time and temperature? • Were temperatures within range for complete time period?. • Was the time and temperature between 40 days at 20°C (68T) and 60 days at 150C (590F)? Air Drying • Were residuals on sand beds or pave or unpaved basins for three months? • Was theambient.temperature above 0°C (32T) for two months? • Were the residuals partially digested? • Were residuals exposed to atmosphere during two months above 0°C '(not snow covered)? Anaerobic Di estion • Was it an anaerobic process (Inspection)? • Were logs submitted showing time and temperature? • Were temperatures within range for complete time period? • Was the time and temperature between 15 days at 35°C (95T) to 55°C (1311F) and 60 days at 200C (68°F)? Composting • Was it a, composting procedure (not natural decay under uncontrolled conditions)? • Were logs submitted showing time and temperature? • Was the temperature raised to 40°C (104°F) or higher and remained at 40°C (104T) for five days? • Did the temperature exceed 55°C (13 PF) for four hours during the five-day period? Lime Stabilization • Was alkaline material added to residuals a form of lime (hydrated lime, quicklime, lime containing kiln dust or fly ash)? • Were logs submitted showing time and temperature? • Was the pH raised to 12 after two hours of contact? • Were logs submitted showing time and pH? • Was the temperature corrected to 25°C (77 17)? Vector Attraction Reduction Review d� • Was the sampling conducted at the required frequency? 38% Volatile Solids Reduction • Was there 38% reduction?yo-S • Were lab sheets/calculations in report? N • Was the reduction on volatile solids (not -total solids)? • Was the samples taken at beginning of digestion process and before application (Inspection)? • Were calculations correct? L I 40-Day Bench Scale Test • Were residuals from anaerobically digested treatment (Inspection)? • Were residuals anaerobically digested in lab? • Was the test run for 40 days? • Was the test done between 30°C (86°F) and 37°C (990F)? • Was the reduction on volatile solids (not total solids)? • Was the reduction less than 17%? • Were lab sheets/calculations in report? • Were calculations correct? 30-Day Bench Scale Test • Were residuals from, aerobically digested treatment (Inspection)? • Were residuals aerobically digested in lab? • Were residuals 2% or less total solids? • Was the test run for 30 days? • Was the test done at 20°C (680F)? • Was the reduction on volatile solids (not total solids)? • Was the reduction less than 15%?. • Were lab" sheets/calculations. in report? • Were calculations correct? Specific Oxygen Uptake Rate (SOUR) • Were residuals from aerobically digested treatment (Inspection)? • Were residuals 2% or less total solids (dry weight basis) (not diluted)? • Was the test done between 10,°C (50°F) and 30°C (86°F)? • Was the temperature corrected to 20°C (68°F)? • Was the SOUR equal to or less than 1.5 mg of oxygen per hour per gram of total residual solids (dry weight basis)? • Was the sample holding time under two hours? • Was the test started within15 minutes of sampling or aeration maintained? 14-Day Aerobic Process • Were residuals from aerobically digested treatment (Inspection)? • Were the residuals treated for 14 days? • Was the residuals temperature higher than 400C (104T) for the 14-day period? • Was the average residuals temperature higher than 45°C (113°F)? Alkaline Stabilization • Was the pH of the residuals raised to 12 or higher by the addition of alkali? • Did the pH of residuals remain at 12 or higher for two hours without the addition of more alkali? • Did the pH of residuals remain at 11.5 or higher for an additional twenty-two hours without the addition of more alkali? • Was the pH corrected to 250C (770F)? Drying of Stabilized Residuals • Does the residuals contain any unstabilized residuals? • Were the residuals mixed with any other materials? • Were the residuals dried to 75% total solids? Drying of Unstabilized Residuals o Were the residuals mixed with any other materials? • Were the residuals dried to 90% total solids? . Injection • Was there any significant. amount of residuals on land surface one hour after injection (Inspection)? • Was injection done on pasture or hay field? " • Was injection done at time that crop was growing? • If Class A with respect to pathogen, were residuals injected within eight hours after discharge from pathogen treatment? Incorporation • Were the residuals incorporated into the soil within six hours after application? • Was incorporation done on pasture or hay field? • Was incorporation done at time that crop was growing? • If Class A with respect to pathogen, were residuals incorporated within eight _-.hours-aRer-discharge- fro-m-pathogen- treat menf? C�V Baxter 6/20/2012 p.�shev@lle Regional office ft wn aifn' , Prr)RA6 o 9 Ms. Beverly Price Environmental Specialist NCDENR — Division of Water Quality Aquifer Protection Section 2090 US 70 Highway Swannanoa, NC 28778-8211 RE: Response to Request for Additional Information dated June 14, 2012. Below is the information you requested in a letter dated June 14, 2012. Volatile Solids A — Sample was taken from the sludge coming off the belt press Volatile Solids B — Sample was taken from digester No. 1 (digester closest to the press building) Volatile Solids C — Sample was taken from digester No. 2 Volatile Solids D — Sample was taken from the sampling point in the pump building that sends the sludge from the clarifiers to the digesters. If you have any questions on the data or the 2011 Annual Report please contact, Amanda Richcreek, Environmental Engineer, 828-756-6809. Sincerely, Mike Howell Plant Manager cc: David Allgood Michael Finnamore Amanda Richcreek Stephen Taylor Baxter Healthcare Corporation PO Box 1390, Marion, NC 28752 T 828-756-4151 0 6 I D"" HEALTHCARE CORPORATION - NOR1 OVE - MARION, NC 2FRE : DOCUMENT NUMBE NC 98- MISC. SHIPPERS SOLNCDENR-DIVISION OF WATER QUALITY ASHEVILLE REGIONAL OFFICE 2090 US 70 HIGHWAY SWANNANOA, NC 28778-8211 AMANDA RICCHCREEK I NC2200 SHNCDENR-DIVISION OF WATER QUALITY ASHEVILLE REGIONAL OFFICE 2090 US 70 HIGHWAY SWANNANOA, NC 28778-8211 ATTENTION OF: PAYMENT PACKED BY SHIPPED BY DATE SHIPPED RECV BY DATE RECV EVERLY PRICE P EPAID SHIPPING METHOD CARRIER NAME CARRIER NO. VOLUME GROSS WEIGHT CONT. RUCK UNITED PARCEL SERVICE FT 1 LBS 0CM KG 1 RETURNED GOODS: P/O#: INVOICE #: REASON FOR SHIPMENT: CREDIT DUE: -------------------------------------------------------------------------------- QUANTITY U/M DESCRIPTION VALUE -------------------------------------------------------------------------------- 1 EA (1) COPY OF RESPONSE TO RFAI DRIVER SIGNATURE: UN 22 20Z Asheville Regional Office DATE: BILLING BUSINESS UNIT: PREPARED BY: PR078494 **** END OF ORDER **** 1'2 FEB 29 All 10° 00 February 17, 2012 NCDENR - DWQ Aquifer Protection Section Land Application Unit 2728 Capital Boulevard Raleigh, NC 27604 RMCEU V ED -"IR 012�,12 Asheville Regional Office RE: 2011 Annual Land -Application Report Permit No. WQ0031725 Baxter Healthcare Corporation McDowell County Enclosed is the annual land application report for the calendar year 2011. If you have any questions or require additional information, please contact Anita Jensen at 828.756.6734 or Stephen Taylor at 828.756.6618. Sincerely, Z! /2 kz_ Mike Howell Plant Manager Cc: NC Division of Water Quality (3 copies with enclosures) WWTP File Copy EHS File Copy Baxter Healthcare Corporation PO Box 1390, Marion, NC 28752 T 828.756.4151 ANNUAL LAND APPLICATION ClERTI RCATION FORM WQ Permit#: WQ0031725 County: Facility Dame (as shown on permit): Land Application Operator: McDowell Year: 2011 Baxter Healthcare Corporation Southern Soil Builders, Inc. Phone: 336-957-8909 Land application of residuals as allowed by the permit occurred during the past calendar year? R1 Yes 0 No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Apart A-ABeciduals Anplicaton Summarv: Total number of application fields in thepermit: 14 Total number of fields utilized for land application during the year: 7 Total amount of dry tons applied during the year for all application sites: 100.26 Total number of acres utilizes for land application during the year: 70.97 Part B - Annual Commiance Statement: Facility was compliant during calendar year 2011 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality. ® Yes ® No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1) Only residuals approved for this permit were applied to the permitted sites. 2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities). _ 7) All general requirements in 'as specified in the Land Application Permit were complied with (applicable to-40 CFR Part 503 regulated facilities). ~` - 8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40.-CFR Part 503 regulated facilities).'' 9) All operations and maintenance requirements in the permit were complied with or, in the case of a -deviation;- prior authorization was received from the Division of Water Quality. 10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified in the permit. 12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13) All buffer requirements as specified on the permit were maintained during each application of residuals. Part C - Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and 'imprisonment for knowing violations." kvN- , [WI,- ul QJT A �v 1- -vf s`aa., Permittee Name and Vitle (type or print) N1 rz- ]�� do f Signature of Permittee Date Signature of Preparer* Date Signature of Land`Kpplier Date (if different from Permittee) (if different from Permittee and Preparer) * Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T. 1102 (26) DENR FORM ACF (1212006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: WQ0031725 Facility Name: Baxter Healthcare Corporation Residual Source WQ # or NC0006564 NPDES #: WWTP Dame: Residual Analysis Data Laboratory: 1) A&L Eastern Laboratories,Inc. 2) 3) 4) 5) Parameter " Cone. 1/ Sample or Composite Date lk Molybdenum Total Phosphorus Nitrate and Nitrite a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of Imes and imprisonment for knowing violations." Signature of �—Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF (12/2006) ANNUAL METALS FIELD WADE% SUAEMIARY FORM* Attach this form to the corresponding Field goading Summary Form to be submitted in Annual Report Facility Dame: Permit #: Operator: Acres Used: Baxter Healthcare WQ0031725 Total Dry Tons Applied (Annual): Cation Exchange Capacity (non 503 only): Derek Teague Owner: Larry Teague 10 Acres Permitted: 10 Site #: 2.28 Predominant Soil Series: MgC2 T-02 Field #: T-02 es i is ata (Heavv Metals and Total Phosphorus usepgjig, % Solids use Raw Percent #): i Com- posite Date _ Total P1 • /l 1 Annual' l 4etal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 10 11 12 H DT/Ac./ App. Event 0.23 Arsenic 0.004 0.000 0.000 0.000 1 0.000 0.000 0:000 0.000 0.000 0.000 0.000 0.000 0,004 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 0.093 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.093 Chromium 0.050 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.050 Lead 0.010 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Mercury 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Molyb- 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 denum Nickel 0.017 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.017 Selenium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Zinc 0.188 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.188 Total Phos- 7.114 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 7.114 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". / 3,,-,; �� Si ature of Land Applier Date u V DENR FORM MFLSF (12/2006) ANNUAL YATALS FIELD LOADING SCARY FORM Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Baxter Healthcare Permit #: WQ0031725 Operator: Derek Teague . Owner Acres Used: 25 Acres Permitted: Total Dry Tons Applied (Annual): 30.90 Cation Exchange Capacity (non 503 only): Trilby Setzer 25 Site #: Predominant Soil Series: HsB2 S-02 Field #: S-02 -Recidnal Analvsis Data (Heavy Metals and 'Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite DateF-T o, MEMO ME MENEM, Annual T-Teaw Moto] Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 61 7 8T 19 10 11 12 DT/Ac./ s� App. 14 Event 1.24 Arsenic 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.020 Cadmium 0.010 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Copper 0.502 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.502 Chromium 0.272 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.272 Lead 0.052 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.052 Mercury 0.001 0.000 0.000 0.000 0.000 0.000 0.0.00 0.000 0.000 0.000 0.000 0.000 0.001 Moiyb- 0.017 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.017 denum Nickel 1 0.09.1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.091 Selenium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 .0.000 0.002 Zinc 1.021 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.021 Total Phos- 38.563 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 38.563 horus "I certify, under penalty of law, that this document was. prepares under my direenon or supervision in accut-uanec with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". v V Signs re of Land Apprer Date DENR FORM MFLSF (1212006) ANNUAL MEETALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Baxter Healthcare Total Dry Tons Applied (Annual): 6.57 WQ0031725 Cation Exchange Capacity (non 503 only): Douglas Poplin Owner: Douglas Poplin Predominant Soil Series: FcB2 2.3 Acres Permitted: 2.3 Site #: DP1-C Field #: DPI-C Residual Analvsis Data (Heavv Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): .m posite IBM TotalDate Phos- phorus. .�� Annual Neaw Metal Field Loadings (Calculated in s acre : Total 1 2 3 4 5 7 8I 9 10 11 12 a3 DT/Ac./ App. Event 2.86 Arsenic 0.046 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.046 Cadmium 0.023 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.023 Copper 1.160 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.160 Chromium 0.628 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.628 Lead 0.120 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.120 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- 0.040. 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.040 denum Nickel 0.211 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.211 Selenium 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.006 Zinc 2.350 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.359 Total Phos- 89.107 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 89.107 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Sign re of Land Applier ,� y10 -do 11 Date DENR FORM MFLSF (12/2006) ANNUAL METALS FIELD LOADING SYJMMARY FORM* Attach this form to the corresponding Field Loading Summary ]Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Baxter Healthcare WQ0031725 Douglas Poplin Owner: Douglas Poplin Predominant Soil Series: FcB2 5.02 Acres Permitted: 5.02 Site #: DP2 Field #: DP2 Total Dry Tons Applied (Annual): 13.89 Cation Exchange Capacity (non 503 only): Residual Analvsis Data (Heaw Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent 9): Com- posite ! Date Total h eheENEENEENEEN elf -- - - - - ---- Annual 1Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 10 11 12 H DT/Ac./ App. Event 2.77 Arsenic 0.044 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.044 Cadmium 0.022 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.022 Copper 1.123 0.000 0.000 0.000 0.000 0.000, 0.000 0.000 0.000 0.000 0.000 0.000 1.123 Chromium 0.609 0.000 0.000 0.000 0.000 0.000 0.000. 0.000 0.000 0.000 0.000 0.000 0.600 Lead 0.116 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.116 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- 0.039 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.039 denum Nickel 1 0.205 0.000 0.000 0.000 .0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.205 Selenium 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Zinc 2.285 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.285 Total Phos- 86.299 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 86.299 horns "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. lI am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signa re of Land Applier Date DENR FORM MFLSF (1212006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Baxter Healthcare Total Dry Tons Applied (Annual): 24.90 WQ0031725 Cation Exchange Capacity (non 503 only): Douglas Poplin Owner: Douglas Poplin Predominant Soil Series: FcB2 12.86 Acres Permitted: 12.86 Site #: DP3 Field #: DP3 Residual Analvsis Data (Heavv Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite • - __ -- - Non' 1 Total - Pho Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 10 11 12 H DT/Ac./ o APP- Event 1.94 Arsenic 1 0.031 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.031 Cadmium 0.015 0.000 1 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.015 Copper 0.786 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.786 Chromium 0.426 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.426 Lead 0.081 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.081 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.027 denum Nickel 0.143 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.143 Selenium 1 0.004 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Zinc 1.599 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.599 Total Phos- 60.403 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 60.403 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. 1 am aware that there are significant penalties for submitting false information, including.the possibility of fines and imprisonment for knowing violations". Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary ]Form to be submitted in Annual Report Facility blame: Baxter Healthcare Total Dry Tons Applied (Annual): 9.87 Permit #: WQ0031725 Cation Exchange Capacity (non 503 only): Operator: Douglas Poplin Owner: Douglas Poplin Predominant Soil Series: FcB2 Acres Used: 11.82 Acres Permitted: 11.82 Site #: DP5 Field #: DP5 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date . .., . phorus .,, Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 10 11 12 DT/Ac./ App. Event 0.84 Arsenic 0.013 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 1 0.000 0.013 Cadmium 0.007 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.007 Copper 0.339 0.000 0.000 0.000 0..000 0.000 '0.000 0.000 0.000 0.000 0.000 0.000 0.339 Chromium 0.184 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.184 Lead 0.035 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.035 Mercury 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Molyb- 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.012 denum Nickel 0.062 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.062 Selenium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002- Zinc 0.690 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.690 Total Phos- 26.052 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 26.052 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signafure of Land A plier -I o-ovo Date DENR FORM MFLSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Baxter Healthcare Total Dry Tons Applied (Annual): WQ0031725 Cation Exchange Capacity (non 503 only): 11.85 Operator: Douglas Poplin Owner: Douglas Poplin Predominant Soil Series: F cB2 Acres Used: 3.97 Acres Permitted: 3.97 Site #: DP6 Field #: DP6 Residual Analvsis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Rave Percent #): Com- posite Date Total h •11 Annual Heavv Metal Field Loadings (Calculate in s acre Total 1 D 3 4 v 5 6 7 8 9 10 11 12' H DT/Ac./ App. v Event 2.99 Arsenic 0.048 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.048 Cadmium 0.024 0.000 0.000 0.000 0.000 0.00.0 0.000 0.000 0.000 0.000 0.000 0.000 0.024 Copper 1.212 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.212 Chro ium 0.657 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.657 Lead 0.125 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.125 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000. 0.000 0.000 0.002 Molyb- 0.042 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.042 denum Nickel 0.221 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.221 Selenium 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 06 E2.466 Zinc 2.466 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Total Phos- 93.163 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 93.163 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. Y am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". K Signature of Land Ap ier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR SOX WHEN NOT APPLICABLE. Facility Name: Baxter Healthcare Land Owner: Larry Teague Operator: Derek Teague Crop 1 Name: Fescue WQ Permit #: WQ0031725 Field #: T-02 Acres Utilized: 10 Annual Dry Tons Applied: 2.2834 Site #: T-02 Acres Permitted: 10 Predominant Soil Series: MgC2 Cation Exchange Capacity (non 503): Crop 1 Max. PAN: 162 Crop 2 Name: Crop 2 Max. PAN: o o A Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons. % Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Co it on Wet Moist) Precip. Past 24 Hrs. inches > R p - E °p •, * x TKN mg/kg c w• mg/kg Nitrate and Nitrite mg/kg p AN Applied lbs/acre ( ) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 2-2011 25.97 10.44 0.228 WQ0031725 dry 0 s 0.5 0.3 86100 4690 11.5 12.229 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 J 0.000 '25.971 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): COTALS: 0 As Cd Cu. Cr Pb Hg Mo Ni Se Zn P 12.229 0.000 Lime Applied Annual lbs/acre 0.004 ✓ 0.076 0.080 36 0.002 0.028 0.030 34 0.093 2.284 2.377 1 1338 0.050 0.923 0.973 1 NA 0;010 0.197` 0.207 267 0.000 0.009 0.009 15 0.003 0.053 0.056 NA 0.017 0.347 0.364 1 374 0.000 0.011 0.011v 1 89 0.188 2.807 2.995 2498 7.114 Date lbs/ac Prior Years Cumulative lbs/ac 10-4-11 2500 Current Cumulative lbs/ac Permitted C. P. L. R.**** Permit PAN Limit lst/2nd Crop 162 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature ofLLand Applier `to-OVl Date *Application Method: S - Surface, IN - Injection, l[NC - Incorporation "`*Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0 *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ""C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (1212006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Baxter Healthcare WQ Permit #: WQ0031725 Field #: S-02 Acres Utilized: 25 Land Owner: Tribly Setzer Annual Dry Tons Applied: 30.9198 Site #: S-02 Acres Permitted: 25 Operator: Derek Teague Predominant Soil Series: HsB2 Cation Exchange Capacity (non 503): Crop 1 Name: Fescue Crop 1 Max. PAN: 216 Crop 2 Name: Crop 2 Max. PAN: o 0 Q Volume applied PP (enter one) Solids/ Liquid Cu. Yds Gallons % Solids Volume Applied" er PP P Acre (Dry Tons/Ac) Residual Sources (NPDES # WQ# Fert., Animal Waste, etc) Soil Cond. ��'° Wet, Moist) Precip. Past 24 Ms. inches Y c� 'd o w a o c x' i F sF p t�. w ��,. ° w' p TIN mg/kg Z Ff o ° ° is mg/kg Nitrate and Nitrite mg/kg PAN Applied PP (lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 2-2011 58.2 10.44 0.205 WQ0031725 dry 0 1 S 0.5 1 0.3 86100 4690 11.5 1 10.963 NA Fescue 3-2011 142 10.44 0.499 WQ0031725 dry 0 S 0.5 0.3 86100 4690 11.5 26.747 NA Fescue 4-2011 97.35 10.44 0.342 WQ0031725 dry 0 S 0.5 0.3 86100 4690 11.5 18.337 NA Fescue 5-2011 54.12 10.44 0.190 W00031725 dry 0 S 0.5 0.3 86100 4690 11.5 10.194 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 351.67 0 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 66.241 0.000 Lime A lied Annuallbs/acre 0.020 0.010 t,, 0.502 0.272 0.052 0.001 0.017 0.091 0.002 1.021 38.563 4216T Date lbs/ac Prior Years Cumulative lbs/ac. 0.035 0.015 1.728 0.729 0.099 0.009 0.026 0.269 0.003 2.234 10-4-11 2500 Current Cumulative lbs/ac 0.055 0.025 2.230 1.001 0.151 0.010 0.043 0.360 0.005 3.255 Permitted C. P. L. R. 36 34 1338 1 NA 1 267 115 NA 374 89 1 2498 Permit PAN Limit 1st/2nd Crop "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier u),a Date *Application Method: S - Surface, IN - Injection, INC - Incorporation "Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0 *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R: Cumulative Pollutant Loading Rate DENR FORM FSF (1212006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Baxter Healthcare Land Owner: Douglas Poplin Operator: Douglas Poplin Crop 1 Name: Fescue WQ Permit #: WQ0031725 Annual Dry Tans Applied: 6.5705 Predominant Soil Series: FcB2 Field #: DPI-C Acres Utilized: 2.3 Site #: DPI-C Acres Permitted: 2.3 Cation Exchange Capacity (non 503): Crop 1 Max. PAN: 194 Crop 2 Name: Crop 2 Max. PAN: ° 7 c Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons % Solids Volume Applied per pP P Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal(Dr Waste, etc) Soil Cond. Wet, Moist Precip. past 24 Hrs. inches > b �. o w p o w o � w # o' � TKN mg/kg Z o o w• mg/kg Nitrate and Nitrite mg/kg PAN Applied (N acre) Name of Crope ReceivingResidual Application Crop 1 Crop 2 Crop 1 Crop 2 6-2011 48.43 10.44 1.851 WQ0031725 dry 0 S 0.5 0.3 86100 4690 11.5 99.156 NA Fescue 7-2011 26.3 10.44 1.005 WQ0031725 dry 0 S 0.5 0.3 86100 4690 11.5 53.847 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this fo5153.0041 TOTALS: 74.73 o As Cd Cu Cr Pb H Mo Ni Se Zn 0.000 Lime Applied Annuallbs/acre 0.046 0.023 1.160 0.628 0.120 0.002 0.040 0.211 0.006 2.3591o, 89.107 V Date lbs/ac Prior Years Cumulative lbs/ac 0 0 0 0 0 0 0 0 0 0 12-23-11 2500 Current Cumulative lbs/ac 0.046 0.023 1.160 0.628 0.120 0.002 0.040 0.211 0.006 2.359 Permitted C. P. L. R.**** 36 34 1338 NA 267 15 NA 374 1 89 2498 Permit PAN Limit lst/2nd Crop 194 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier -4sdi2 Date "Application Method: S - Surface, IN - Injection, INC - Incorporation *Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0 *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested-0.3,-raw sludge -0.4 ****C.P.L.R: Cumulative Pollutant Loading Rate -f- DENR FORM FSF (12/2006) ANNUAL LAND APPLIECATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON Facility Name: Baxter Healthcare Land Owner: Douglas Poplin Operator: Douglas Poplin Crop 1 Name: Fescue PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. WQ Permit #: WQ0031725 Field #: DP2 Annual Dry Tons Applied: 13.8830 Site #: DP2 Predominant Soil Series: Fc$2 Crop 1 Max. PAN: 194 Crop 2 Name: Acres Utilized: 5.02 Acres Permitted: 5.02 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: o o � Cuce o A Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons % Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Wet, Moist) Precip. Past 24 Hrs. inches y � ,� �' o m a o p o � �• ;E p 7s w+ a �� TKN mglkg Z Gt o o � o �, mg/kg Nitrate and Nitrite mg/kg PAN Applied lbs/acre ( ) Name of CropType Receiving Residual g Application Crop 1 Crop 2 Crop 1 Crop 2 8-2011 109.2 10.44 1.913 WQ0031725 dry 0 S 0.5 1 0.3 86100 4690 11.5 102.436 NA Fescue 9-2011 48.7 10.44 0.853 WQ0031725 dry 0 S 0.5 0.3 86100 4690 11.5 45.684 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALSI 157.91 o As Cd Cu Cr Pb H Mo Ni Se Zn P 7148.120 0.000 Lime A lied Annuallbs/acre 0.044 0.022 1.123 0.609 0.116 0.002 0.039 0.205 0.006 2.285 86.299 Date lbs/ac Prior Years Cumulative lbs/ac 0 0 0 0 0 0 0 0 0 0 12-23-11 2500 Current Cumulative lbs/ac 0.044 0.022 1.123 0.609, 0.116 0.002 0.039 0.205 0.006 2.285 Permitted C. P. L. R.**** 36 34 1338 NA 267 15 NA 374 1 89 2498 Permit PAN Limit 1st/2nd Crop 194 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier i/'c.PV 3 Date *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0 *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH. FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Baxter Healthcare Land Owner: Douglas Poplin Operator: Douglas Poplin Crop 1 Name: Fescue WQ Permit #: WQ0031725 Field #: DP3 Acres Utilized: 12.86 Annual Dry Tons Applied: 24.8991 Site #: DP3 Acres Permitted: 12.86 Predominant Soil Series: FcB2 Cation Exchange Capacity (non 503): Crop 1 Max. PAN: 194 Crop 2 Name: Crop 2 Max. PANT: ° ° ° ° Q Volume applied enter one Solids/ ( ) Liquid q Cu. Yds Gallons u /o Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Wet, Moist) Precip, Past 24 Hrs. inches > o b �' oa o p o w w -« c 0 P �. r n<N mg/kg Z ct o p w. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 10-2011 110.17 10.44 1 0.753 WQ0031725 dry 0 S 0.5 1 0.3 86100 4690 1 11.5 40,342 NA Fescue 11-2011 113.8 10.44 0.778 WQ0031725 dry 0 1 0.3 86100 4690 11.5 45.320 NA Fescue 12-2011 59.2 10.44 0,405 WQ0031725 dry 0 S 0.5 0.3 86100 4690 11.5 21.686 1 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): e/ TOTALS: 283.17 0 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 107.348 0.000 Lime Applied Annual lbs/acre 0.031 0.015 0.786 0.426 0.081 0.002 0.027 0.143 0.004 1.599 60.403 3.j Date lbs/ac Prior Years Cumulative lbs/ac 0 0 0 0 0 0 0 0 0 0 12-26-11 2500 Current Cumulative lbs/ac 0.031 0.015 0.786 0.426 0.081 0.002 0:027 0.143 0.004 1.599 Permitted C. P. L. R.`k*" 36 34 1338 1 NA 267 15 1 NA 374 1 89 1 2498 Permit PAN Limit lst/2nd Crop 194 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier ,3 aR I14 � �52V.7 �6 �' ti�l Zj-I *Application Method: S - Surface, IN - Injection, INC - Incorporation IU ' ��` **Volatilization Rate: Surface - 0.5, rnjection/Incorporation -1.0 Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Baxter Healthcare Land Owner: Douglas Poplin Operator: Douglas Poplin Crop 1 Name: Fescue WQ Permit #: WQ0031725 Field #: DP5 Acres Utilized: 11.82 Annual Dry Tons Applied: 9.8649 Site #: DP5 Acres Permitted; 11.82 Predominant Soil Series: FcB2 Cation Exchange Capacity (non 503): Crop 1 Max. PAN: 194 Crop 2 Name: Crop 2 Max. PAN: 11 ° 5 ° ° +� o A Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons % Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. We ' Moist Precip. Past 24 Phs• inches y 12 0 p o � �« ; "' 1� P ° p � w w o 0 TKN mg/kg Z � o ° �• mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of CropType ReceivingResidual Application Crop 1 Crop 2 Crop 1 Crop 2 12-2011 112.2 10.44 0.835 WQ0031725 dry 0 S 0.5 0.3 1 86100 4690 11.5 44.700 NA Fescue 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 112.2 o As Cd Cu Cr Pb Hg Mo Ni Se Zn P 44.700 0.000 Lime A lied Annual lbs/acre 0.013 0.007 0.339 0.184 0 035 0.001 0.012 0.062 0.002 0,690 26.052 Date lbs/ac Prior Years Cumulative lbs/ac 0 0 0 0 0 0 0 .0 0 0 12-26-11 2500 Current Cumulative lbs/ac 0.013 1 0.007 0.339 0.184 0.'035 0.001 0.012 0.062 0.002 0.690 Permitted C. P. L. R.'i"I' r.* 36 34 1338 1 NA 267 1 15 . NA 374 89 1 2498 Permit PAN Limit lst/2nd Crop . - 194 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier Date d idz *Application Method: S - Surface, IN - Injection, INC - Incorporation '*Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0 *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ""C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Baxter Healthcare WQ Permit #: WQ0031725 Field #: DP6 Acres Utilized: 3.97 Land Owner: Douglas Poplin Annual Dry Tons Applied: 11.8555 Site #: DP6 Acres Permitted: 3.97 Operator: Douglas Poplin Predominant Soil Series: FcB2 Cation Exchange Capacity (non 503): Crop 1 Name: Fescue Crop 1 Max. PAN: 194 Crop 2 Name: Crop 2 Max. PAN: ° o o M, A Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons u /o Solids Volume Applied per Acre D Tons/Ac (Dry ) Residual Sources •.(NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. D (�' We Moist) Precip. Past 24 Hrs. inches Y o b t*r c; ° m a o o w w F; ao- ° o �, w ° w o' p TKN mg/kg Z q o oa ° ° p w mg/kg Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of CropType Receiving Residual Application pp Crop 1 Crop 2 Crop 1 Crop 2 9-2011 67.3 10.44 1.269 WQ0031725 dry 0 S 0.5 0.3 86100 4690 11.5 67.967 NA Fescue 10-2011 77.54 10.44 1.717 WQ0031725 dry 0 S 0.5 0.3 86100 4690 11.5 91.975 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 134.84 o As Cd Cu Cr Pb Hg Mo Ni Se Zn P 159.9421 0.000 Lime A lied Annuallbs/acre 0.048 1 0.024 1.212 0.657 0.125 0.002 0.042 0.221 0.006 2:466 93.163 J Date lbs/ac Prior Years Cumulative lbs/ac 0 0 0 0 0 0 0 0 0 0 12-26-11 2500 Current Cumulative lbs/ac 0.048 0.024 1.212 0.657 0.125 0.002 0.042 0.221 0.006 2.466 Permitted C. P. L. R.**** 36 34 1338 NA 267 15 NA 374 89 2498 'Permit PAN Limit 1st/2nd Crop 194 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." VL.I~ Signature ofEland Applier *Application Method: S - Surface, IN - Injection, INC - Incorporation -/y':20 1 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0 *xx Mineralization Rates: Compost -0.1, anaerobially digested -0.2, Date aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) Page: 1 of 2 Report Number: 11-063-0206 Account Number: 46381 Submitted By: ZACH KEY Send To: SOUTHERN' SOIL BUILDERS DENNIS KEY 958 HOOTS ROAD ROARING RIVER, NC 28669 ®1 A&L Eastern Laboratories, Inc. i ■Y 7621 Whitepine Road Richmond. Virginia 23237. (804) 743-9401 Fax (804) 271-6446 •m wwwaleastern.com Project: BAXTER NC CERT # 257 REPORT OF ANALYSIS Date Sampled: 311/2.011 12:30:00 Lab Number: 81218 Date Received: 03/04/2011 00:00 Sample Id: BAXTER Date Reported: 03/10/2011 Total Solids 10.44 104400 100.0 JM u3/u4/Gull "10:uu 01V1-40411V Moisture ` 89.56 100.0 JM 03/04/2011 15:00 SM-2540G Total K)eldahl Nitrogen 8.61 86100 10.0 JM 03/07/2011 08:50 SM-4500-NH3C-TKN Total Phosphorus 1.56 15600 100 KM 03/07/2011 13:34 SW 6010C Total Potassium 0.50 5030 100 KM 03/07/2011 13:34 SW 6010C Total Sulfur 1.51 15100 100 KM 03/07/2011 13:34 SW 6010C Total Calcium 1.49 14900 100 KM 03/07/2011 13:34 SW 6010C Total Magnesium 0.47 4680 100 KM .03/0712011 13:34 SW 6010C Total Sodium 0.39 3890 100 KM 03/07/2011 13:34 SW 6010C Total Iron 8690 1 KM 03/07/2011 13:34 SW 6010C Total Aluminum 2800 10 KM 03/07/2011 13:34 SW 6010C Total Manganese 157 1 KM 03/07/2011 13:34 SW 6010C Total Copper 203 1 KM 03/07/2011 13:34 SW 6010C Total Zinc 413 " 1 KM 03/07/2011 13:34 SW 6010C Ammonia Nitrogen 0.47 4690 . 10.0 JM 03/07/2011 08`50 SM-4500-NH3C Organic N 8.14 81410 10.0 03/07/2011 08:50 CALCULATION Nitrate+Nitrite-N 11.5-- 1.00 JM 03/07/201108:50 SM-450ONO3F Total Cadmium 4.0 - 1.0 KM 03/07/2011 13:34 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. / Debbie Holt Page: 2 of 2 Report Number: 11-063-0206 Account Number: 46381 Submitted By: ZACH KEY Send To: SOUTHERN SOIL BUILDERS DENNIS KEY 958 HOOTS ROAD ROARING RIVER, NC 28669 gftl A&L EasternLaboratories, Inc. 7621 Whitepme Road Richmond. Virginia 23237 (804) 743-9401 Fax (804(271-6446 www.aleastem.com Project: BAXTER NC CERT # 257 REPORT OF ANALYSIS Date Sampled: 3/1/2011 12:30:00 Lab. Number : 81218 Date Received: 03/04/2011 00:00 Sample Id: BAXTER Date Reported: 03/10/2011 Total Chromium Total Nickel Total Lead Total Arsenic Total Mercury Total Selenium pH (Standard Units)' Total Molybdenum Comments: 110 5 KM U3/U(lzull 13:34 JVV ou IUI. 37 5 KM 03/07/2011 13:34 SW 6010C 21 5 KM 03/07/2011 13:34 SW 6010C 81.0 1.0 KM 03/07/2011 13:34 SW 6010C 0.4 0.4 KM 03/07/2011 13:00 SW-7471 B <1.0 1.0 KM 03/07/2011 13:34 SW 6010C 7.81 JM 03/07/201108:50 SW-9045D 7 5 KM 03/07/2011 13:34 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Debbie Holt ,-'A N-1 III 46381 111111111111111MIN "Oba-04 151111511111 11:43:51 SoLrri_jERN SAIL BUILDERS BAXTER - )Jill JP._,tumer inTormation otijce Information Charp-.To , y I' aK3, a Rep.l# Southern Sail Builders m1 Acol 11 958 Hoots LRd ;co �Ak = Email n RingRiver.JNC 28669 1 j R 6z. 1% 1�, 4638 m -rnOo!LaLab Plumber (Lab Use 0 - nhr) Sample ID Container Ty.p.e Sampled Date: Glass (Yes cjr* a Sam led Tim. e: ).-I v Time Recd- Plastic QYe Er N101 Sampled N Recd By: Rel-viquished By: (Signature) Date Ti (Signature Date Tune v a V n Please Place a "V by Desired es' Internal Lab Code-- - S L, sou ------- :� - K.- ca� Na Fe'� At. Mn Cu -..Zh.. - NH4-N Solids _TKN.. x x x x x x x x x x x x x x x voiattl.d.., .53 -.Cd Pb. PH -:Eq':�'Xu� d' � Org-N- m Cl-CI_ B -a X x x x x x x Co ..Sn Be -ALK Ab- TF_ v Avail _SS P. SdI.K. 1 on WIN SOLB' Sjve#20-. m,.!gieva..6d,, sieve#10c) -ASH SOL NA,, TSS T!- CaCW�TM gC.03- - Mgo C-J.N TOC q,-,^Edv- n p CERT -C- E R.T REA�fT BT(Y�P,':,` -CBS CN F ECAL T.CLP IGR .4W., ,A., Tk H TN N State Certification Needed: NORTH CAROLINA Special Instructions or Remarks Comments 7. i Mineralization as decimal ITTotal dry tons/year Acres Applied on 1 70.97 Rate 0.3 TKN 86100 NH3 4690 NO3 11.5 NO2 0 % Solids 0.1044 1 100.26 PAN Surface 26779.5 1 mgikg 53.669 lbs/dry to 5359.825 lbs total PAN 76,65331 lbs PAN/acre PAN Injection 29124.5 nag/kg 58.249 lbsidry ton 6840.045 lbs tonal PAN 82.28892 lbs PAN/acre 'Dry Tons/1000 gal. 0.435348 1 st year PAN Surface lbs. 5369.82534 1st year PAN Injected lbs. , 5840.04474 lbs./acre Surface 75.66331323 lbs./acre Injected 82.28892123 MR(TKN-NH3)+ + .5(NH3)+NO3+NO2 =mg/kg - Mg/kg x .002 =1bs/dry ton MR(TKN-NH3) + 1(NH3)+NO3+NO2 =mg/kg mg/kg x .002 =1bs/dry ton 1000 X 8.34 X %solids X so. gravity "=dry tons/1000gal." 2000 4 � � SAR Sodium Absorption Ratio Na: Sodium (Mg/L) Equivalent weight: 23 Ca: Calcium (Mg/L) Equivalent weight: 20 Mg : Magnesium (Mg/L) Equivalent weight: 12 Milli Equivalent = Mg/L / Equivalent weight Na M /L Ca(Mg/L) Mgq/� 406.11 1 1555.56 488.59 Na ME Ca ME Mg (ME) 17.65696 77.778 40.71583 SAR= Na Milli Equivalent/[0.5 X (Ca Milli Equivalent + Mg Milli equivalent)]0.5 power SAR = 2.293945 (From Mg/L entered above) SAR= 2.293175 (From ME entered below) Na ME 17.65 Ca ME Mg (ME) 1 77.77 1 40.71 The amour amount of E Permitting! ' r Analytical results Southern Soil Builders 958 Hoots Road Roaring River NC 28669 Entered 3/1/2011 Reported: 3/21/2011 :or: Sample ID Parameter Cust ID Result Units Method Date Analyzed Analyst 11031-13 Corrosivity Baxter See Attached SW-846 3/16/11 PACE 11031A 3 Ignitability Baxter See Attached 101010 3116/11 PACE 11031-13 Reactivity Baxter See Attached SW-846 3/16/11 PACE 11031-13 TCLP Baxter See Attached 1311 3116/11 PACE Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, EPA NCO0909 P.O. Box 228 o Statesville, North Carolina 28687. 704/872/4697 Client: r< STATESVILLFANALYTIC'Al 122 C'uurl Sliver P.O. Box 228 -. Statesville.NC 25647 (704) 872-4697 Address: C15 � %i�� Contact Person: �` r Phone # ��� - r/} •/_ ��,� FAX# Chain of Custody �e�®�-� PO # (Z Requisitioned by: (firryg: Date) x�cr d oar, -f 11 Customer Sample ID# Lab -ID # Time Sampled Grab Onl Date Sampled Grab Onl E Matrix Parameters requested for analysis Sludge w ww Relinquished by: Received b y Relinquished b q Y Received by: Composite Sampling Time begin Time end Composite Sampling A T me begin e end / ��2' At am, pm Date _/_/_ am; pm .Date _/_/_ #2: am, pm Date am, pm Date _/ /_ Tirrie''�.. �j�� a pm Date Time . 2 an 2 a p . : Dateti"' Time am,,.pm.-Date Time.•am; pm' Date .dab Comments: — / (/ / / Sampled by: Transported by: l;,' .✓ , . Holding times met: Compliance work: Non-compliance work. aceAnalytical ti.. www.pacelabs.com Project: 11031-13 Pace Project No.: 9288966 Sample: 11031-13 Parameters Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 .Huntersville, NC 28078 (704)875-9092 Lab ID: 9288966001 Collected: 03/01/11 12:30 Received: 03/02/11 14:51 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides, TCLP Analytical Method: EPA 8081 gamma-BHC (Lindane) ND mg/L 0.0010 1 03/10/11 15:42 03/15/11 07:55 58-89-9 Chlordane (Technical) ND mg/L 0.0050 1 03/10/11 15:42 03/15/11 07:55 57-74-9 Endrin ND mg/L 0.0010 1 03/10/11 15:42 03/15/11 07:55 72-20-8 Heptachlor ND mg/L 0.0010 1 03/10/11 15:42 03/15/11 07:55 76-44-8 Heptachlor epoxide ND mg/L 0.0010 1 03/10/11 15:42 03/15/11 07:55 1024-57-3 Methoxychlor ND mg/L 0.0010 1 03/10/11 15:42 03/15/11 07:55 72-43-5 Toxaphene ND mg/L 0.0050 1 03/10/11 15:42 03/15/11 07:55 8001-35-2 Decachlorobiphenyl (S) 109 % 70-130 1 03/10/11 15:42 03/15/11 07:55 2051-24-3 Tetra chi oro-m-xylene (S) 106 % 70-130 1 03/10/11 15:42 03/15/11 07:55 877-09-8 8151 Chlorinate Herbicide TCLP Analytical Method: EPA 8151 2,4-D ND mg/L 0.010 1 03/10/11 16:00 03/11/11 01:37 94-75-7 2,4,5-TP (Silvex) ND mg/L 0.010 1 03/10/11 16:00 03/11111 01:37 93-72-1 2,4-DCPA (S) 86 % 70-130 1 03/10/11 16:00 03/11/11 01:37 19719-28-9 6010 MET ICP, TCLP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Leachate Method/Date: EPA 1311; 03/07/11 16:45 Arsenic ND mg/L 0.025 1 03/08/11 15:50 03/09/11 13:00 7440-38-2 Barium 0.73 mg/L 0.50 1 03/08/11 15:50 03/09/11 13:00 7440-39-3 Cadmium ND mg/L 0.0050 1 03/08/11 15:50 03/09/11 13:00 7440-43-9 Chromium ND mg/L 0.025 1 03/08/11 15:50 03/09/11 13:00 7440-47-3 Lead ND mg/L 0.025 1 03/08/11 15:50 03/09/11 13:00 7439-92-1 Selenium ND mg/L 0.10 1 03/08/11 15:50 03/09/11 13:00 7782-49-2 Silver ND mg/L 0.025 1 03/08/11 15:50 03/09/11 13:00 7440-22-4 7470 Mercury, TCLP Analytical Method: EPA 7470 Preparation Method: EPA 7470 Leachate Method/Date: EPA 1311; 03/07/11 16:45 Mercury ND ug/L 0.20 1 03/08/11 15:30 03/09/11 12:14 7439-97-6 8270 MSSV TCLP Sep Funnel Analytical Method: EPA 8270 Preparation Method: EPA 3510 Leachate Method/Date: EPA 1311; 03/14/11 10:00 1,4-Dichlorobenzene ND ug/L 50.0 1 03/15/11 14:00 03/16111 14:24 106-46-7 2,4-Dinitrotoluene ND ug/L 50.0 1 03/15/11 14:00 03/16/11 14:24 121-14-2 Hexachloro-1,3-butadiene ND ug/L 50.0 1 03/15/11 14:00 03/16/11 14:24 87-68-3 Hexachlorobenzene ND ug/L 50.0 1 03/15/11 14:00 03/16111 14:24 118-74-1 Hexachloroethane ND ug/L 50.0 1 03/15/11 14:00 03/16/11 14:24 67-72-1 2-Methylphenol(o-Cresol) ND ug/L 50.0 1 03/15/11 14:00 03/16111 14:24 95-48-7 3&4-Methylphenol(m&p Cresol) ND ug/L 50.0 1 03/15/11 14:00 03/16/11 14:24 Nitrobenzene ND ug/L 50.0 1 03/15/11 14:00 03/16/11 14:24 98-95-3 Pentachlorophenol ND ug/L 100 1 03/15/11 14:00 03/16/11 14:24 87-86-5 Pyridine ND ug/L 50.0 1 03/15/11 14:00 03/16/11 14:24 110-86-1 2,4,5-Tdchlorophenol ND ug/L 50.0 1 03/15/11 14:00 03/16/11 14:24 95-95-4 2,4,6-Tdchlorophenol ND ug/L 50.0 1 03/15/11 14:00 03/16/11 14:24 88-06-2 Nitrobenzene-d5 (S) 62 % 12-102 1 03/15/11 14:00 03/16/11 14:24 4165-60-0 2-Fluorobiphenyl (S) 63 % 13-107 1 03/15/11 14:00 03/16/11 14:24 321-60-8 Date: 03/18/2011 05:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, without the written consent of Pace Analytical Services, Inc.. O,M FCCOq Page 4 of 19 aceAnalyfical wwwpaceMbs.com Project: 11031-13 Pace Project No.: 9288966 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 11031-13 Parameters Lab ID: 9288966001 Collected: 03/01/11 12:30 Results Units Report Limit DF Received: 03/02/11 14:51 Matrix: Water Prepared Analyzed CAS No. Qual 8270 MSSV TCLP Sep Funnel Analytical Method: EPA 8270 Preparation Method: EPA 3510 Leachate Method/Date: EPA 1311; 03/14/11 10:00 Terphenyl-d14 (S) 71 % 21: 132 1 03/15/11 14:00 03/16/11 14:24 1718-51-0 25 % 10-110 1 03/15/11 14:00 03/16/11 14:24 13127-88-3 Phen Phenol-d6 (S) (S) 36 % 10-110 1 03/15/11 14:00 03/16/11 14:24 367-12-4 ro16 (S) 57 % 27-108 1 03/15/11 14:00 03/16/11 14:24 118-79 6 2,4,6-Tdbromophenol (S) 8260 MSV TCLP Analytical Method: EPA 8260 ND ug/L 100 20 03/14/11 15:23 71-43-2 Benzene 2-Butanone (MEK) ND ug/L 200 20 03/14/11 15:23 78-93-3 Carbon tetrachloride ND ug/L 100 20 03/14/11 15:23 03/14/11 15:23 56-23-5 108-90-7 Chlorobenzene ND ug/L 100 100 20 20 03/14/11 15:23 67-66-3 Chloroform ND ug/L ND ug/L 100 20 03/14/11 15:23 106-46-7 1,4-Dichlorobenzene ND ug/L 100 20 03/14/11 15:23 107-06-2 1,2-Dichloroetiiane ND ug/L 100 20 03/14/11 15:23 75-35-4 1,1-Dichloroethene ND ug/L 100 20 03/14/11 15:23 127-18-4 Tetrachloroethene ND ug/L 100 20 03/14111 15:23 79-01-6 Trichloroethene ND ug/L 100 20 03/14/11 15:23 75-01-4 Vinyl chloride 1,2-Dichloroethane-d4 (S) 95 % 70-130 20 03/14/11 15:23 17060-07-0 Toluene-d8 (S) 96 % 67-135 20 03/14/11 15:23 2037-26-5 4-Bromofluorobenzene (S) 100 % 70-130 20 03/14/11 15:23 03/14/11 15:23 460-00-4 1868-53-7 Dibromofluoromethane (S) 95 % 70-130 20 1010 Flashpoint,Closed Cup Analytical Method: EPA 1010 Flashpoint >200 deg F 70.0 1 03/15/11 14:49 734S Reactive Sulfide Analytical Method: SW-846 7.3.4.2 Modified Sulfide, Reactive ND mg/L 10.0 1 03/10/11 09:45 9040 pH Analytical Method: EPA 9040 pH 7.1 Std. Units 0.10 1 03/16/11 13:50 H6 733C Reactive Cyanide Analytical Method: SW-846 7.3.3.2 Modified Cyanide, Reactive ND mg/L 0.0050 1 03/09/11 16:07 Date: 03/18/2011 05:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. yC.C.rCy �LL_L]lG�+i Page 5 of 19 t, 4 Analytical Results Southern Soil Builders 958 Hoots Road Roaring River NC 28669 Entered 3/1/2011 Reported: 3/11/2011 For: Sample ID Parameter Cust ID Result Units Method Date Analyzed Analyst 11031-12.1 %Solids 1 1.47 % SM2540B 3/2/11 CL 11031-12.1 Fecal Coliform MTF 1 8844 MPN/g SM92210E 3/2/11 CL 11031-12.1 Geometric Mean 1 5300 MPN/g dry wt. basis 3/3/11 CL 11031-12.10 % Volatile Solids C V;gcYter , n_ 1.01 % SM254OG 3/3/11 CL 11031-12.11 % Volatile Solids D 10.3 % SM254OG 3/3/11 WL 11031-12.2 % Solids 2 1.37 % SM2540B 3/2111 CL 11031-12.2 Fecal Coliform MTF 2 9489 MPN/g SM92210E 3/2/11 CL 11031-12.3 % Solids 3 1.43� % ' SM2540B 3/2111 CL. 11031-12.3 Fecal Coliform MTF 3 11,888) MPN/g SM92210E 3/2111 CL 11031-12.4 % Solids 4 1.37 % SM2540B 3/2111 CL 11031-12.4 Fecal Coliform MTF 4 5839 MPN/g SM92210E 3/2/11 CL 11031-12.5 %Solids 5 1.40 % SM2540B 3/2/11 CL 11031-12.5 Fecal Coliform MTF 5 (2� MPN/g SM9221 CE 3/2111 CL 11031-12.6 % Solids 6 1.44 % SM2540B 3/2/11 CL. 11031-12.6 Fecal Coliform MTF 6 1389 MPN/g SM92210E 3/2/11 CL 11031-12.7 % Solids 7 1.44 % SM2540B 3/2/11 CL 1103T-12.7 Fecal Coliform MTF 7 (4861 MPN/g SM92210E 3/2/11 CL 11031-12.8 % Volatile Solids A Q, e-W-Ri-0 0.56 % SM2540G 3/3/11 CL 11031-12.9 % Volatile Solids B D�3ey6r , 1,22 . % SM2540G 3/3/11 CL P.O. Box 228 ° Statesville, North Carolina 28687 v 704/872/4697 Client: ,. _ , :.... SKATES V YLLE ANALY Il [Cih][ .Address:' ]22-CourtStreet• P.O.'B,ox228.:' 41 Statesville, NC 28687.'.. • , - � .. 704 8.72-4697 . Contac# Person ::: Phone #: ;:. FAX# fCj(�aIl&� ®iF ICdAS$�L3' �e�®lr . PO # ;.. , . Requisitioned. by " Cane Date) "Gustoiner Lab -ID # , '' Time Sampled bate Sampled •, �Y .• o Matrix. I Parameters requedted.for analysis. 'Sam le IN Grati:Onl Grab Only). ,fir •..q£: `� ,, A. F : - •.i.,. .. �, .ticti .;�. y. Relin uished b"' q , . .y. :. .• - Time' , am:, pm Date � =/_L — Sa d P - maple by: Received by: f, Ti me;,` am; p� Date -/-/- Transported by: Relinquished by: Time: am, pm:, Date _/_1_ Holding -times met: f Received by:. •Time am,.pm:Date'_/_�— Compl,ianee work: : Cbmposite.Sarnpling #1: ' 'Time begin.: '.., ..,.:am; pm Date _/—/-.: .. IVgn-compliance work:. . Time end am, pm: 'Date /_/_ ' Lab Comments: ', � .' � • " Composite -Sampling #2: Time,begin .. am,.pm Date.—/ /— Time end am; pm Date:_/ r ` � VS in 0.103 VS out 0.0101 VSFR= 0.911144 19 l ��l© r►�s�k-2 ,103— OtL N D 1N�(1N�Ot�> io 3 - (. 103 -�, ocot} 1 2-2 10 3-C10.3 x fl r-(,o6ot „; ,00 (,,) Oct z � F. 1 b-3 , 01�1_(,GaocuS�S� o 9 - , 'S9 2 Io176- _ , ool/s .q4/,?0 l o,oc)V s . ' ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Dame: Baxter Healthcare Corporation WWTP Dame: Baxter Healthcare Corporation Monitoring Period: From 1/1/2011 To WQ Permit Dumber: WQ0031725 DPDES Dumber: NC0006564 12/31/2011 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) 0 1 Alt B (Alk Treatment) 0 1 Alt. C (Prior Testing) 0 Alt.D (No Prior Test) 0 1 Process to Further Reduce Pathogengs 0 If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost 01 Heat Drying ® Heat Treatment 0 Thermophilic 0 Beta Ray 0 a a a R G mm y Pasteurization 0 Class B: I Alt. (1) Fecal Density 0 Alt. (2) Process to Significantly Reduce Pathogens 0 If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization 0 Ai Drying 0 Composting jAerobic Digestion 0 Anaerobic Di e stion An g If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Allowable Level Pathogen Density Number or Parameter Excee- Frequency Sample Analytical in Slud a inim Geo. Mean axim Units g deuces of Analysis Type e io n 2 x 10 to the WN 1389 5300 11888 MPN/g 0 7 grab sm9221 6th power per gram of Fecal Coliform total solids CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria 3 MPN per 4 grams (in lieu of fecal total solid (dry coliform weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.1 (VS reduction) Alt. 2 (40-day bench) 0 Alt. 3 (30-day bench) 0 JAIt. 4 (Spec. 02 uptake) 0 Alt. 5 (14-Day Aerobic) © Alt. 6 (Alk. Stabilization 0 Alt 7 (Drying - Stable) 0 JAR. 8 (Drying - Unstable) 0 Alt. 9 (Injection) ® Alt. 10 (Incorporation) ® No vector attraction reduction alternatives were performed 0 CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ® "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." SA-60,-k^ `�'�,�( w w-o 5j&,— Dennis Key Southern Soil Builders, Inc. Preparer Name and Title (type or print) �— Land Applier Name and Title (if applicable)(type or print) Signature of Preparer* Date Si ature of Lanpplier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) NCDAUS Agronomic Division Phone: (919)733-2655 Web site: www.acagr.gov/agronomi/ Report No: 18038 Grower, Southern Soil Builders, lose. Copies ?o, 958 Hoots Roaring Rd River, NC 28669 071 T est Report `>,sou , SERVING N.C. RESIDENTS FOR OVER 60 YEARS Farm,, Received: 11/23/2011 Completed: 12/15/2011 Links to Helpful Information Catawba Cou Agronomist Comments 12 Field Information Applied1imse Recommendations Sample No. Last Crop Mo Yr T'/A Crop or Year Lime N P205 K?0 Ng S Ca Ztt B Hn See Note T2 8 2011 1.5 1st Crop: Fes/OG/Pim,M 0 120-200 90-110 50-70 0 0 0 0 .0 0 12 2nd Crop: 0 Test Results Soil Class IINN106 W/V CRC BS°6 Ac PH P-1 IU Ca,06 rifr% Nn-I Ilfpz-AI(t) Xn-AI(2) Zn-t Yn-Al Cog-1 s-d 5S-1 N®3-N Nfl4-N Na MIN 0.32 1.08 5.6 70.0 1.7 5.6 18 41 45.0 21.0 21 36 34 34 57 53 0.1 Field Information Applied Lime Recommendations Saample No. Last Crop No Yr' TIA Crop or Year ,Liszze N P205 K20 Ng s Cie Zu B Nit See Note T1 8 2011 1.5 1st Crop: Fes/OG/Tim,M 0 120.200 110-130 80-100 0 0 0 0 .0 0 12 2nd Crop: 0 Test Results Soil Class HN%6 WIV CPC BS%6 Ac PH r P-d K-1 COY,, lilg%S NU-t Nn-AI(L) Mn-AI(2) Z19-1 Zaz-Al Cu 1 S-1 SS-1 NO3-N 104 N Iva MIN 0.32 0.99 5.9 61.0 2.3 5.4 I 9 24 40.0 18.0 14 35 34 34 60 65 0.1 Field Information Applied Lime Recommendations Sample No. Last Crop Ado Yr TIA Crop or Year Liaaae N P205 Ili® Big S Co Zn d3 li21az See Note Sl 1st Crop: Fes/OGjIrn,M 0 120-200 0-20 30-50 0 0 0 0 .0 0 12 2nd Crop: 0 'Pest Results Soil Claws If X o WIV CPC BS°6 Ac pH P-P K-1 Cea%6 BW,6 Xn-t Xaa-AI(L) Nn-AI(2) Zaz-1 Zaz-AI Cle-d s-I SS-1 NO3-N NII1-N Na MIN 0.56 1.05 9.5 84.0 1.5 6.2 64 48 56.0 26.0 109 79 112 112 141 44 0.2 Field Information Applied Lime Recommendations Sample No. Last Crop Ko Yr TIA Crop or Year Lime N P205 K20 Illg S Czz Zaz B Ndaz See Note S2 isl Crop: Fes/OGif(m,M .3T 120-200 0 60-80 0 0 0 0 .0 0 12 2nd Crop: 0 Test Result's Soil Class lllll%6 WIV CPC A'S% Ac pH P-1 ICI Cao Me%, Mu-1 Ain-Al(l) !]laa-Al(2) Zaz-t Zaz-AI Cae-t s-d ss-t NO3-N IVH4-N Na MIN 0.66 . 1.07 8.1 75.0 2.0 5.9 104 32 52.0 21.0 ill 84 262 262 235 38 0.1 ,r NCDA&CS Agronomic Division Phone: (919)733-2655 Web site: www.neagr.gov/agronomi/ Grower: Southern Soil Builders, Report No: 24809 Pg 2 Field Information Applied Lime Recommendations Sample No. Last Crop No Yr T'lA Crop or Year Lime N P205 Kz® Igg S Cu Zn B Mn See Note Vest Results Soil Class HM96 W/V CEC ES96 Ac pH P-I K I Ca% Mg% Mn-I Mn-AI(1) Mn-AI(2) Zn-I Zn Al Cre d S-I SS-1 N®3-N NH4-N Na Field Information Applied Lime Recommendations Sample No. Last Crop DP1C No Yr T/A Crop or Year 1st Crop: Fes/OG/rim,M 2nd Crop: Lime .5T N 120-200 P2O5 0 K2O 0 Mg S 0 0 0 Cze 0 Zn 0 E Mn See Note .0 0 12 Test Results Soil Class HM96 W/V MIN 0.97 IN CEC ES96 10.4 83.0 Ac pH. P-I ICI 1.8 5.8 162 233 Ca% Mg% 51.0 20.0 Mn-1 87 Mn-AP(L) 69 Mn-AI(2) Zn-I Zn-AI 472 472 Cud 635 S-d 40 SS-1 NO3-N NH4-N Na 0.1 Field Information Applied Lime Recommendations Sample No. Last Crop DP2 Mo Yr I'/A Crop or Year lstCrop: Fes/OG/rhnM 2nd Crop: Lance LIT N 120-200 P205 0 K20 0 Mg S 0 0 0 Cu 0 Zn 0 E Mn See Note 0 0 12 Test Results Soil Class Hff% W/V MIN o.41 1.00 CEC ES90 9.1 76.0 Ac PH P I ICI 2.2 5.4 139 98 Ca% Mg96 52.0 18.0 Mn-1 63 Mn-AI(I) 55 Mat-AI(2) Zn-I Zn-AI 909 909 Car -I 618 S I 73 SS-1 NO3 N NH4-N Na 0.1 Field information Applied Lime Recommendations Sample No. Last Crop DP3 No Yr T/A Crop or Year 1st Crop: Fes/OG/Tim,M 2nd Crop: Lame .9T N 120-200 P2O5 0 IC2O 40-60 Mg S 0 0 0 Cu 0 Zn 0 E Mn See Note .0 0 12 Test Results Soil Class HM96 W/V MIN 0.32 1.07 CEC ES96 7.0 74.0 Ac PH P-I ICI 1.8 5.4 66 42 Ca% Mg% 52,0 19.0 Mn-1 89 Mn-AI(L) 70 Mn-AI(2) Zn-I Za-AI 316 316 Cu-I 327 S-I 44 S� I NO3-N NH4-N Na 0.1 Field Information Applied Lime Recommendations Sample No. Last Crop DP4 Mo Yr T/A Crop or Year 1st Crop: Fes/OG/rim,M 2nd Crop: Linre iAT N P2O5 N20 120-200 100-120 20-40 Mg S 0 0 0 Cu 0 Zu 0 E Mn See Note .0 0 12 Test Results Soil Class HM% WIV MIN a41 0.99 CEC ES96 5.6 59.0 Ac pH P-I ICI 2.3 5.0 13 57 Ca% Mg% 37.0 16.0 Mn-I 41 Mn-AI(I) 42 Mu-AI(2) Zu-I Zn-AI 366 366 Cu-1 310 S-I 84 SS-1 NO3-N NH4-N Na 0.1 , 7` NOWS Agronomic Division Phone: .(919)733-2655 Web site: www.neagr.gov/agrononli/ Grower: Southern_Soil.Builders, Report No: 24809 Pg 3 .Field Information Applied Lime Recommendations Sample No. bast Crop Ho Yr T/A Crop or Year Mane N P205 1C20 Mg S Cu Zn B Mil See Note DP5 1st Crop: Fes/OG/rhn,M X 120-200 0 20.40 0 0 0 0 .0 0 12 2nd Crop: 0 Test Results Soil Class LW% W/V C6C BS% Ac pli P-d K P Ca% Mg,06 Mn-1 Mn-.AI(l) Mn-AI(2) Zn 1 Zn-AI Ctt-I S d SS-1 NO3-N lEW4-N Na MIN 0.32 1.05 8.8 77.0 2.0 5.5 . 72 57 53.0 21.0 57 51 527 527 587 34 0.1 Field Information Applied Lime Recommendations sample No. Last Crop Mo Yr I/,A Crop or Year Liaise N P205 100 Mg 5 Cu ,Zu B Mn See Note DP6 1st Crop: Fes/OG/Tim,M 1T 120-200 50-70 90-110 0 0 0 0 .0 0 12 2nd Crop: 0 Test Results Soil Class Hm% W/P CBC BS016 Ac pll P-I &I Ca% Mg% Mn-1 Mn-AI(l) Mn-AI(2) Zn-I Zn-Al Cu-1 S-I SS-1 NO3-N Nlf4-N Na MIN 0.81 1.02 7.3 73.0 2.0 5.4 35 21 55.0 17.0 77 .63 415 415 530 33 0.1 North Carolina Tobacco Trust Fund Commission Reprogramming of the laboratory -information -management system that makes this report possible Is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture Report dumber: 11-332-0722 Account Number: 46381 i>1r45(tL81225i'F'7id,G0fii Send To: SOUTHERN SOIL BUILDERS DENNISKEY 958 HOOTS ROAD ROARING RIVER NC 28669 Date Received: 11/28/2011 Date Of Analvs➢s: 11/29/2011 &L Eastem Laboratories, inc. 7621 Whitepine Road Richmond, Virginia 23237 {804) 743.9401 Fax (SM) 271-8446 Grower: Submitted By: Z KEY SOUTHERN SOIL BUILDERS Farm ID: S®OL ANALYSIS REPORT Analytical Method(s): Mehlich 3 Date Of Renort: 11/30/2n11 Organic Matter Phosphorus Potassium Magnesium Calcium Sodium pH Acidity C.E.0 SampleID Lab ENR % Rate Mehlich 3 Reserve K Mg Ca Na Soil Buffer H FielddID Field Number lbs/A ppm Rate ppm Rake ppm Rate ppm Rate ppm Rate ppm Rate , pH Index meq/100g meq/1©0g S1 00927 4.8 M 132 96 H 151 H 342 H 1170 M 114 VL 1 6.4 6.84 0.9 10.0 NC=80 NC=77 S2 00928 4.6 M 130 69 1-NC=57 H 154 H 277 H 1005' M 1 12 VL 6.3 6.84 0.9 8.7 NC=79 T1 00929 4.6 M 130 50 M 180 L 278 H 1045 M 112 VL 6.3 6.84 0.9 8.7 NC=42 NC=41 T2 00931 3.7 M 115 155 H 142 VL 1110 11 699 M 14 VL 5.8 6.81 1.2 1-6-4 NC=46 NC=21 Percent Base Saturation Nitrate Sulfur Zinc Manganese Iron Copper Boron Soluble Salts Chloride Aluminum Sample ID Field ID K I Mg Ca Na H NO3N S Zn Mn Fe Cu B SS Cl A➢ % % % % % ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate pp m Rate ms/cm Rate ppm Rate ppm S1 11 L 6.1 H 26 H 110 VH 3.6 VH 0.7 M 0.24 VL 3.9 28.5 58.5 0.6 9.0 NC=28 NC=152.5 NC=163 1 1 NC=180.0 S2 L H 16 M VH H 0.6 M 0.18 VL 4.5 26.5 57.8 0.6 10.6 112 16.6 �94 13.3 NC = 30 NC = 165.0 NC = 100 NC = 165.0 T1 L H 6 L VH 2.6 H 0.5 L VL 26.6 60.1 0.6 10.6 1132.4 15.5 f9O 10.12 NC = 33 NC = 137.5 NC = 38 NC =130.0 T2 11 L M 6 L VH 1.9 H 0.4 L VL 1.7 23.4 54.6 1.0 19.0 13.0 1111 10.08 NC=28 NC=75.0 NC NC=95.0 Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. e� H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble by: fl W". m G C.E.C. - Cation Exchange Capacity. Salts ms/cm x 640 = ppm. Analysis prepared by: A&L Eastern Laboratories, Inc. Pauric McGroary Page 1 of 4 Report Number: 11-350-0638. Account Number: 46381 Send To: SOUTHERN SOIL BUILDERS DENNIS KEY 958 HOOTS ROAD ROARING RIVER NC 28669 A� A&L Eastern Laboratories, Inc. 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271.6446 t. www.aleastern.com Grower: Submitted By: ZACH KEY SOUTHERN SOIL BUILDERS Farm ID: SOIL ANALYSIS REPORT Analytical Method(s): - Date Received: 12/16/2011 Date Of Analvsis: 12119/2011 Data_ of P4-nnrt• 19/9ni9ni d Mehlich 3 r .4. , .e .: g. ;2, . , - . t _ . ,.• i , , ."' , ;..,--r..�•. C a .-.,..,:. f ;�._...tiOrgantc_,�Matter-. ::. ':. }, , , P,hos :g '- , horus', w' , .. P.otasstum3-j,.•,Ma T. •=.;t'y" .._..C� ^ nestum. I! - a,, s•+•x "fCal t +;�, - .: 3 ° T.::• : , �; --:=:1 - _, ,,,; �;,, - j P � --•� , - - _,�,"� r ",.:; �tSample�IDr 1 lLab�` - _ _ . m Fieltl ID>, ; ?-: Number {� ENR° Rate �Solli or 0 t� m r, m rR m 'Rate IiPpm Rate, i ` ',Rater - r _,.. _ ,.Rates _ _ :_ . ,PP..: .._,ate.i pR._ _ ., .. F., . t , ,pp m , Rate ppm pH� _'Index:'' _ meq/1;OOg, meq/100g DP1C 13002 4.8 M 132 234 VH 294 VH 197 H 1144 M 23 VL NC=195 NC=150 5.8 6.74 1.9 10,1 DP2 13003 4.0 'M 117 184 VH 133 H 221 H 928 M 23 VL NC=153 NC=68 5.6 6.72 2.1 9.0 DP3 T;3004 3.1 M 102 161 VH 117 M 100 M 577 L 16 VL NC=134 NC=60 1 F4.9 6.61 3.2 7.3 DP4 13005 4.8 M 137 28 L 143 H 127 H 514 L 13 VL NC=23 NC=73 5.2 6.72 2.1 6.2 DP5 13006 4.8 M 135 133 VH 90 M 188 H 894 M 14 VLF5.7 NC=111 NC=46 6.76 1.7 8.0 • . �., _ Percent Base,$aturatton - •'- :Nitrate .."yo-_.R Sulfur• : .. -• _§ Zmc• ..:.� -_ _,., i .'-;=. �^ _Manganese.)Iron, --, t . , f •-'" _ -•r j �_ . , ,Copper,, , r .°..emu; Bpron soluble 5alts� Chloride;,Aluminum ,6p .r. r I- i • .,, .1 ,;� fP 3V NOyN - S Zn t`" •,• Y ,� � k f' Cu+ ..0 -_i `.AIs p, ,Mn: r Fed i -_ #a :. m Rate:' pp.:_ m._ Rater m: ?Rate PP m' jpP. a pm. Rate pm ate p R., p pm Rate Rate Rate _....._z •P..P,.-Rate .:p .r; _ . .,. -ms/cm hppm pP.m'- . DP1C 13 L 19.1 VH 19 M 188 7VH 15.6 VH 0.9 M 0.15 VL 7.5 16.3 56.6 1.0 19.1 NC=33 NC=477.5 NC=119 NC=780.0 DP2 19 M 33.2 VH 17 M VH 12.6 VH 0.9 M 0.2 VL 3.8 20.5 51.6 1.1 23.4 [156 NC = 48 NC = 830.0 NC = 106 NC = 630.0 DP3 17 M 19.2 VH 21 H 94 VH 6.1 VH 1.0 M 0.15 VL 4.1 11.4 39.5 1.0 43.8 NC=43 NC=480.0 NC=131 NC=305.0 DP4 16 M 17.5 VH 11 M 118 VH 4.3 VH 0.8 M VL 5.9 17.1 41.5 0.9 33.8 10.12 NC=40 NC=437.5 NC=69 NC=215.0 DP5 11 L VH 14 M 163 VH 9.5 VH M 0.14 VL 2.9 19.6 55.9 0.8 21.1 131.7 10.8 NC = 28 NC = 792.5 NC = 88 NC = 470 vdrues on uus report represent me prant.avauaore numents in the =planation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. me Gov H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per100 grams). Conversions: ppm x 2 = Ibs/A, Soluble by: C.E.C. - Cation Exchange Capacity. Salts rns/cm x 640 = ppm. Analysis prepared by: A&L Eastern Laboratories, Inc. Pauric McGroary Report Number: 11-350-0638 Account Number: 46381 1 #1jW �,1fiR3r/d 0I2�StETe1g03iH Send To: SOUTHERN SOIL BUILDERS DENNIS KEY 956 HOOTS ROAD ROARING RIVER NC 28669 Date Received: 12/16/2011 Date Of Analvsis: 12/19/2011 i� A L Eastem Laboratonfes, inc. 7621 Whltepine Road Richmond, Virginia 23237 (804) 743-S401 Fax 1804) 271-8446 Grower: Submitted By: ZACH KEY SOUTHERN SOIL BUILDERS Farris ID: SOOL ANALYSIS REPORT Analytical Method(s): Mehlich 3 Date Of Reocrt: 12/20/2011 Sample ID Field ID Lab Number/o Organic Matter Phosphorus Potassium Magnesium Calcium Sodium pH Acidity C.G.0 c IENR Rat® Jiffs/A Mehlieh 3 ppm Rate Reserve ppm Rate K ppm Rate Mg ppm Rate Ca ppm Rate Na ppm Rate Soil pH Buffer Index H meq/100g meq/100g DP6 13008 5.3 H 144 88 H NC=73 42 VL NC=21 186 H 899 M 16 VL 5.6 6.74 1.9 8.1 Sample ID Field ID Percent Base Saturation Nitrate Sulfur Zinc Manganese Iron Copper Boron Soluble Salts Chloride Aluminum K % Mg % Ca % Na % H % NO3N ppm Rate S ppm Rate Zn ppm Rate Mn ppm Rate Fe ppm Rate Cu ppm Rate B ppm Rate SS mslcm Rate Cl- ppm Rage Al ppm DP6 1.3 19.1 55.5 0.9 23.4 10 L NC=25 20.6 VH NC=515.0 15 M NC=94 148 VH 12.9 VH NC=645.0 0.7 M 0.09 VL Values on this report represent the plant available nutrients In the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples arc retained a soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble C.E.C. - Cation Exchange Capacity. Salts ms/cm x 640 = ppm. Analysis prepared by: Aal Eastern Laboratories, Inc. by:p�a Pauric McGroary 'JFIS CampusShip: Shipment Label UPS CampusShlp: View/Print Label Page 1 of 1 1. Ensure there are no other shipping or tracking labels attached to your package. Select the Print button on the print dialog box that appears. Note: If your browser does not support this function select Print from the File menu to print the label. 2. Fold the printed sheet containing the label at the line so that the entire shipping label is visible. Place the label on a single side of the package and cover it completely with clear plastic shipping tape. Do not cover any seams or closures on the package with the label. Place the label in a UPS Shipping Pouch. If you do not have a pouch, affix the folded label using clear plastic shipping tape over the entire label. 3. GETTING YOUR SHIPMENT TO UPS UPS locations include the UPS Store®, UPS drop boxes, UPS customer centers, authorized retail outlets and UPS drivers. Find your closest UPS location at: www.ups.com/dropoff Take your package to any location of The UPS Store®, UPS Drop Box, UPS Customer Center, UPS Alliances (Office Depot@ or Staples@) or Authorized Shipping Outlet near you. Items sent via UPS Return Services(SM) (including via Ground) are also accepted at Drop Boxes. To find the location nearest you, please visit the Resources area of CampusShip and select UPS Locations. Customers with a Daily Pickup Your driver will pickup your shipment(s) as usual. FOLD HERE w O Ln a � o ozz jOO W'4 E M CJ �.I ¢N � y W V OH W wxyz H a8 Q N flrg ID I� N p� LO 1�1 �� q cy �I FI Z E- o � Cq CO Ib 00 U o :: z ci • .: • • 0. �4�•�V• .••i• .: i•S • O• ••• . f•�.•Ln httDs://www.campusship.ups.com/cship/create?ActionOriginPair=default PrintWindowPage&k... 2/23/2012 Page 1 of 2 Report Number: 11-332-0722 Account Number: 46381 Send To: SOUTHERN SOIL BUILDERS DENNIS KEY 958 HOOTS ROAD ROARING RIVER NC 28669 www.aleastern,com Date ReceivedW Date Of Analysis: 11/29/2011 A &L Eastern Laboratories, Inc. 7621 Whitepine Road Richmond, Virginia 23237 (804);743-9401 Fax;(804) 271-6446 Grower: Submitted By- Z KEY SOUTHERN SOIL BUILDERS Farm ID: SOIL ANALYSIS REPORT Analytical Method(s): Mehlich 3 Date Of Report: 11/30/2011 Organic Matter _ Phosphorus :: Potasswm , `„. Ma nesium. 9 Calcium ;' Sodruin p Hn' Acrdlty C.E.C';-. a Sam le ID P ID Lab .. Number. ;; ° ENR " `Rate Arlehlch 3 Reserve Kr. Mg , Na t Soll Buffer H .Field /° ° bs/A PPm41�= Rate ppm Ratez Rate^. "Ppm�Itate Rate , �pH °`Index"megl100g •megl700g,. F_-A w ;ppm* .PPm°`Rate ;pPm S1 96 H 151 H 342 H 1170 M 14 VL 00927 4.8 M 132 6.4 6.84 0.9 10.0 NC=80 NC=77 S2 69 H 154 H H 1005 M 12 VL 00928 4.6 M 130 1277 6.3 6.84 0.9 8.7 NC=57 NC=79 T1 50 M 80 L 278 H 1045 M VL 00929 4.6 M 130 112 6.3 6.84 0.9 8°7 NC=42 NC=41 T2 55 H 42 VL H 699 M VL 00931 3.7 M 115 1-180 1 114 1 5.8 6.81 1.2 6.4 NC=46 NC=21 HE10 104 H 32 VL 228 H M VL 00932 3.7 M 113 1 181-5 I'll 1 5.6 6.74 1.9 8.0 NC=87 NC=16 ,, R Percent<;Base Saturatwn , , K ,^;Ndrate� �` e' ,; Sulfur _ _ "" Zmc .-'°` Margane"se Iron'b, „ _ "Copper.: Boron 'Soluble Salts ChlorideF", Aluminum ; Sample ID Field ID tr K M Ca fUa ; H :NON '" a . ` S _ Zn Mn Fe' Cu B SS : - CI AC /o °. to ; `ppm - Rate ppm.. ;Rate 'ppm Rafe ppm - Rate ppm Rate „. ppm Rate ppm °`Rate ms/cm Rate ppm Rate ppm S1 11 L 6.1 26 , 110 VH 3.6 0.7 M 0.24 VL 3.9 28.5 58.5 0.6 9.0 NC = 28 ,��� � - 18 S2 12 L M VH 0.6 M VL 4.5 26.5 57.8 0.6 10.6 1 NC=30 16.6 116 NC=100 194 13.3 amowIll 10.18 T1 L D- 6 L VH 0.5 L VL 2.4 26.6 60.1 0.6 10.6 113 NC=33 15.5 MaXEMP NC=38 190 12.6 1 10.12 T2 - 11 L l 6 L VH 1.9 L VL 1.7 23.4 54.6 1.0 19°0 13.O 1111 10.4 10.08 NC=28 NC=75.0 NC=38 HE10 9 VL 6.3 H M VH H 0.5 L 0.08 VL 1.0 50.9 0.6 23.2 115 196 12.0 . . - NC = 23 NC = 157.5 NC = 94 � NC = 100.0 , . _ ..:_..,.: :.. ... ...... . Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. samples are retained a soi - by �Ay/ca m i1 Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds.per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. ewr H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Analysis prepared by: AB:L Eastern Laboratories, Inc. C.E.C. -Cation Exchange Capacity. Soluble Salts ms/cm x 640 =ppm. Pauric McGroary 1k4-- Page 2 of 2 Report Number: 11-332-0722� Account Number: 46381 wwwaleastern.com Send To: SOUTHERN SOIL BUILDERS DENNIS KEY ' ..._............ 958 HOOTS ROAD ROARING RIVER NC 28669 nntP RPr-Piva_dr 11/28/2011 Data Of Analvsis: 11/29/2011 A &L Eastern Laboratories, Inc. 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax'(804) 271-6446 Grower: Submitted By: Z KEY SOUTHERN SOIL BUILDERS., Farm ID: SOIL ANALYSIS REPORT Analytical Method(s): Mehlich 3 Date Of Reoort: 11/30/2011 Organic'Matter'. e PhospFiorus' Potassium ",, Magriesium" Calcium Sodium pH ,.` Acidity :.." CE6 Sample ID Field,ID Lab "'"' o ENR AAehlich 3 Reserve K Mg - Ca '. Na ; 'Soil `.Buffer H ,,,Numberlo. Rate ; IbslA ppm.,.-,.,,-_ n Rate' 'ppm , ' Rate . ppm MRate ppm Rate ppm Rate ppm Rate P H lridex 4megM OOg' meq/100g`,. HE11 00933 3.4 M 109 144 VH 30 VL 155 H 709 M 10 VL 5.6 6.78 1.5 6.5 NC=120 NC=15 HE7 00934 2.8 M 96 193 H 1 1 53 VL 1153 H 1-590 L 113 VL 5.1 6.66 2.7 7.1 NC=77 NC=27 ' • 3 = -Percent=Base Saturation ; ; , Nftraf� �, ,Sulfur ��,,Zmc• °. ° �Manganese °:.- Iron s, "Copper.' , Boron Soluble:$alts . ' "-Cfilonde .Aluminum, Sample 1D Field ID K Mg " Ca" " Na H w NON 3 S Zn Mn Fe =Cu B' SS' CI "Al ,. a7o 070., %. 070 0, ppR► Rate 'ppm 'Rate ppm Rate ppm, Rate ppm Rate `ppm, m.Rate ppma.. Rate ,ms/cm Rate ppm Rate' : .".ppm HE11 10 L 7.5 H 16 M 115 VH 1.4 M 0.5 L 0.07 VL 1.2 19.9 54.5 0.7 23.2 NC=25 NC=187.5 NC=100 NC=70.0 HE7 15 L H 10 M VH H VL VL 1.9 18.0 41.5 0.8 37.5 NC=38 14.6 NC=115.0 NC=63 1170 11.9 NC=95.0 10.3 10.1 Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent); ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. by; Pori. me 607-' H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Analysis prepared by: A&L Eastern Laboratories, Inc. C.E.C. - Cation Exchange Capacity. Soluble Saks ms/cm x 640 = ppm. Pauric McGroary 38% Volatile Solids Reduction Calculation Simplified Van Kleeck equation from Page 124 of White House Manual: FVSR = VSf - VSb VSf - (VSf x VSb) VSf = VS(Feed) = Volatile fraction of raw and/or thickened sludges fed to digesters or volatile fraction of sludge added to bench test vessels at beginning of the test period_ VSb = VS(Bottom or Stabilized) = Volatile fraction of digested sludge removed from digesters or bench test vessels after 40 days. EXAMPLE DIGESTER CALCULATION 0.8140 - 0.6171 0.8140 - (0.8140 x 0.61.71) 63.2 o Volatile Solids Reduction Z5�3 0.1969 = 0.6317 or 0.3117 NY Pr' qj yam. � ,2