WQ0010689_Annual Report_20070312

Annual Report Review SOP
1, Annual Land Application Certification Form
Was a certification form submitted? a.e S
• Was land application conducted during the reported year? d iS ��'b°"O `` rs OO
How many dry tons and dry tons per acre were applied? 16 7 ,5'-, 5 7 /D7-
• Were the applications within the permitted amount? yam'
sc 10
Verify PAN if more than 10 tons/acre ,v4 t-0
• Did it indicate compliance? Yes' ,A -S D'st
• Was it signed by the appropriate people? ° cG° � /0
5�``"P
.2. Monitoring 0 .
• Were the analyses conducted at the required frequency? V)t e. — yes Y,ij. Rend-
• Were the metals analyses reportedon the Residual Sampling SummaryForml y -N°t Av la
+ Were the results reported in mg/kg? I.P
• : Were the heavy metals within ceiling concentration permit limits?* a
• If no, were the lab analyses attached? OM
• Were all the required parameters tested? yes
• Was TCLP analysis conducted?,�e,
3. Field Summary AIA
• Were the land application. events recorded on the Field Summary Forms?
® Was a Field Summary Form submitted for each -field?
• Were all the residuals applied to permitted land?
• Were all the residuals applied from permitted sources?
• Were the field loading rates for each metal and PAN calculated (year to date)?
• Were the cumulative pollutant loading rates calculated?
• Were the calculations correct?
• Were the PAN loading rates- within permit Iimits?
• Were the heavy metal cumulative pollutant loading rates within permit limits?
+ Were the residuals applied on a suitable crop?
• Were the applications conducted during the crop's growing season?
Were the Field Summary Forms complete?
4. Pathogen and Vector Attraction Reduction OA-
• Was a signed copy of the Pathogen and Vector Attraction Reduction Form submitted?
• Did the form indicate the period of coverage,"the residual class, and the pathogen reduction alternative and the
vector attraction reduction option used?
+ Was the appropriate documentation to show pathogen and vector attraction reduction included in the report?
• Was pathogen and vector attraction reduction demonstrated according to 40 CFR Part 503?
5. Soil 'Tests NA-
• Was a Standard Soil Fertility Analysis conducted for each application field?
• Were the soil pH's 6.0 or greater for each application field?
• Were the copper and zinc indexes in the soil less than 3000 for each application field?
6. General
• Was the report in the proper format?
• Were any parts of the annual report missing? go
• Was the report submitted on time? 10
* Any violations, of ceiling concentrations should be reported"to: Pretreatment for mutiicipajitiea only. .
o �- ae'7- P6 3 41

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Ross submitted an invoice for a larger nozzle to correct this issue — the invoice is
dated May 3, 2006 with a paid d� t bf May 10, 2006; several days before the
May 15, 2007 release which suggests he was aware of the nozzle problem prior
to us documenting.a run-off as result of mis-application.
Mr. Ross has indicated in his remission request that his waste application system
has operated without an -approved CAW since at least 1999. On April 16,
1999, Soil and Water Conservation conditionally approved the waste
management system for the Ross Dairy. That certification was conditional
pending the purchase and installation of irrigation equipment. In a letter dated
October 14, 1999, Division of Soil and Water Conservation completed the
CAWMP certification process, thereby certifying that the irrigation equipment was
in place and "capable of applying waste at rates that do not exceed those
specified in the CAWMP". Mr. Ralph Ross received a cow copy p9this
letter.
$1000 was remitted from the original amount since Ross reportedly obtained
technical assistance in correcting the issues with his irrigation system.
Ralph Ross signed the conditional approval of the animal waster application plan
on April 16, 1999. Additionally, Mr. Ross signed the waste utilization plan on
October 9, 2000 that states "waste will be applied on the land according to this
plan at the appropriate times and at rates that no run-off occurs.
In summary, we the Division believe that the civil penalty amount assessed and
that amount already remitted is fair and in accordance with all applicable rules
and regulations.

SAC? z
Energy Generation NA
March 12, 2007
VIA FEDERAL EXPRESS # 7906 9060 1510
NCDENR-DWQ
Information Processing Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
RE: 2006 Annual Ash report — Amended cover letter
Permit No. WQ0010689
SUEZ Energy BioPower, Inc — North Cove, NC
MAR 19 2007
Asheviiie Regional Office
P� kaF glip, r ProtE;tdrion
This amended cover letter corrects the two typographical errors in the 2006 ash report
dated February 21, 2007 only. The corrections are for year 2006 vice 2007 and are.
underline below. All other report information contained in the annual report dated
2/21/07 is correct and not included with this corrected cover letter.
Enclosed is the annual ash distribution report for calendar year 2006, using the forms
provided by NCDENR-DWQ. During 2006, ash was distributed in only one form. Flyash
that was settled in the scrubber ponds was mixed with flyash from the multicyclone and
dry wood to reduce the moisture content. The ash was distributed for land application in
this form.
Average moisture content was obtained from several samples collected and .analyzed
periodically throughout the year. A composite sample was collected for chemical analysis
from the final product prior to distribution. All samples were analyzed by Pace Analytical
Services, Inc., a North Carolina -certified laboratory.
Notification was made to the DWQ on February 9, 2007 for the. following issues:
North Pond Ash was distributed in January and February 2006 and was not
sampled in accordance with the SOP which required analysis prior to distribution.
In addition, only one sample was taken and tested where the SOP required two
samples to be processed.
North Pond Ash was distributed in September 2006 and was not sampled per the
permit requirement 11I.5_. pry RECEIVED ( DEW /MAJ
AQU.
IFFE�•PPPTPr Ti�e:l .'CO3TiOl{
MAR 14. ZU/

The issues above are due to personnel errors by experienced plant management.
Plant Management was counseled and a review of the permit requirements and
SOP was conducted.
If you have questions or require additional information, please contact Frankie Fox at
828-287-8832 or Tony Leopard at 828-287-5886.
Sincerely,
l(lo'ny W
Plant Man
Enclosures - none
RECEIVED / DENR I UWQ
AQUjPFR'PP0TPrT!r11,1 RFCT!ON

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Energy Generation
NA
February 21, 2007
VIA FEDERAL EXPRESS # 7922 9390 3132
NCDENR-DWQ
Information Processing Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
RE: 2006 Annual Ash report
Permit No. WQ0010689
'SUEZ Energy BioPower, Inc — North Cove, NC
MAR 0 5 2007
AsheviHe Regional office
- - A iter protection
Enclosed is the annual ash distribution report for calendar year 2006, using the forms
provided by NCDENR-DWQ. During 2006, ash was distributed in only one form. Flyash
that was settled in the scrubber ponds was mixed with flyash from the multicyclone and
dry wood to reduce the moisture content. The ash was distributed for land application in
this form.
Average moisture content was obtained from several samples collected and analyzed
periodically throughout the year. A composite sample was collected for chemical analysis
from the final product prior to distribution. All samples were analyzed by Pace Analytical
Services, Inc., a North Carolina -certified laboratory.
Notification was made to the DWQ on February 9, 2007 for the following issues:
North Pond Ash was distributed in January and February 2007 and was not
sampled in accordance with the SOP which required analysis prior to distribution.
In addition, only one sample was taken and tested where the SOP required two
samples to be processed.
North Pond Ash was distributed in September 2007 and was not sampled per the
permit requirement III.5.
The issues above are due to personnel errors by experienced plant management.
Plant Management was counseled and a review of the permit requirements and
SOP was conducted.
9

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: WQ0010689
Facility Name: SUEZ Energy BioPower, Inc. - North Cove
NPDES # or WQ0010689
WQ#:
WWTP Name: ?�
Residual Analysis Data /06, �ill�io� b� q� S0"
Laboratory: 7a1) Pace Analytical Services, Inc.
2)
5
4) ("
Po��`
-Sy b
Sample or
Composite Date
Flyash
1/23/06
Flyash
2/28/06
Flyash
2/28/06
Flyash
4/24/0
Poe-
h
Percent Solids
48.5
45.6
45.7
72.8
Arsenic
7.5
6.2
5.2
11 --
Cadmium
<0.18
<0.21 ,-
<0.19
<0.14
Chromium
34
18
16
37
,b
Copper
87
55 ✓
49
82
Lead
19
18
15
23
Mercury
<.00020
0.01
<.0091
<.0069
Molybdenum
1.5
1.3
<0.96
1.1
Nickel
26
15
14
21
Selenium
<0.92
<1.0 t,
1.3
<0.70
Zinc
170
130 ,�
110
170
Total Phosphorus
1420
<110
<109
30.6
TKN
920
ENitraote
Nitrite
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for bmitting false information, including the possibility of fines and imprisonment for knowing violations."
Sign a rep - er Date
DENR FORM RSSF (5/2003)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: WQ0010689 Laboratory:
Facility Name: SUEZ Energy BioPower, Inc, - North Cove
NPDES # or
WQ#: WQ0010689
WWTP Name:
Residual Analysis Data
1) Pace Analytical Services, Inc.
2)
3)
4)
5)
—Sample—or CompositeDate
Magnesium
Potassium
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
S' ure of reparer Date
DENR FORM RSSF-B (5/2003)

, ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM
Facility Name: SUEZ Energy BioPower, Inc. - North Cove Permit Number: WQ 0010689
NVVVTP Name: NPDES Number:
Monitoring Period: From
To
Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed:
Class A:
Alternative 1 ❑
Alternative 2 ❑
Alternative 3 ❑
Alternative 40
T Alternative 5 ❑
Alternative 6 ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
Alternative 1 ❑
Alternative 2 ❑
Alternative 3 ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
Air Drying ❑
1 Composting ❑
jAerobic Digestion ❑
Anaerobic Dig estion
......................................................................................................
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
g
Pathogen Density
Number ot
denc e-
deuces
Frequency
of Analysis
y
Sample
Type
Analytical
Tech-ni u
q
Geo. Mean
axim
Units
Fecal Coliform
2 x 10 to the 6th
power MPN per
gram of total
solids or 2 x 10 to
the 6th power
CFU per gram of
•
1000 mpn per
gram of total solid
(dry weight)
cz
Salmonella bacteria
(in lieu of fecal
coliform) 1
3 MPN per 4
grams total solid
(dry weight)
Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed:
Option 1 ❑ Option 2 ❑ Option 3 ❑ Option 4 ❑ Option 5 ❑
Option 6 ❑ Option 7 ❑Option 8 ❑ Option 9 ❑ Option 10 ❑
No vector attraction reduction options were performed ❑
P
CERTIFICATION STATEMENT (please check the appropriate statement)
❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the
system designed to ensure that qualified personnel properly gather and evaluate the information
used to determine that the pathogen and vector attraction reduction requirements have been met. I
am aware that there are sign ific t penalties for false certification including fine and imprisonment."
r. C6
Preparer Name itle a or print) Land Applier Name and Title (if applicable)(type or print)
----2 -�
Signature epar Date Signature of Land Applier (UrROPIROM) RF (5/2003) Date

a wAnalytical
mm. pltse ba.o ra
January V. 2006
Ms. Lauren Billheinner. P.E.
Trlgen=BioPower, Im.
1931 Ni nsted Ct .
Charlotte. NC 28262
RE. Lab Project Nuater: 92110M
Client Project M. Marion Fly Ash
Dear ft . Billheiaer. P.E.:
Pace Malyfkaf Servkff. Irrs.
90M IOnceyAmue. Suite 100
Hu►rters►ft uc 2W78
Phone: [phone]=
Fax: [phone]
Enclosed we the analytical results for sample(s) received by the laboratory on January 9. 2006. Results
reported herein conform to the Most current MELAC standards. where applicable, unless otherwise narratad in the
body of the report.
InorgaMc Wet Chemistry and Metals Analyses mere performed at our Pace Asheville laboratory and Organic testing
Was performd at our Pace Charlotte laboratory unless otherrrtse footnoted.
If.you have any questions concerning this report please feel free to'contact me,
Sincerely,
AG e� . it. -1k
Kate Knauff
Kate.Knatrfftecel abs. cam
Project Manager
Enclosures
AshmAlla Certtflcation IOs
IVC Vi Wffwatar 40
NC Drinking. Water 37712
SC Environmental 89030
FL NELd1P E87648
REFORT OF LAOORATORY ANALYSIS
This repot shall not be reproduced. except in full,
without" written consent of Pace Anatydcal Sorvicm Inc.
nem
Charlotte Certilledon IAs
NC Wastewater 12
NC Drinldng Water 37705
5C 990136
FL WELAP E87627
r • d n4 T i -QC1 -Q;7R WO I HUW Z311S
Wd0T=S L002 OE UeC

A iwi
frrnmrpHrf�r.mm
Solid results are reported on a dry weight basis
Lab Sample No: 926620828
Client Sample ID: WRION FLY ASH
Ales Ankfkal Sets M. Me.
98t1t7KWAyAvenue, Suite 100
Nunfersvflle• NC 2807E
Phow 7f14.875.9092
Fax_ 7K8759091
Lab Project Number: 921109M .
Client Project ID: Marion Fly Ash
Project Sample Mmumtber: 9211OW8-001 Date Collected: 01/06/06 D0:00
Matrix: Soil Date Received: O1/09/06 11:00
Parametem Results lt_ nits flgp2q Limit DF Ana]yzed By CAS No. %al _ Re mt
Metals
Trace ICP Metals. TCLP Leach. Method: EPA 6010
Date Dlgested 01/12/06 12:00 01/12/06 12:00
Trace 1CP Metals. TCLP Leach.
Arsenic
Barium
CadmatmM
Chromium
Lead,
Selenium
Silver
Date Digested
Xetals. Trace ICP
Arsenic
Barium
Cadmium
Calcium
CMroaiumm
Capper
Iron
Lead
Magnelium
Manganese
Nolybdenaw
Nickel
Futassium
Selenium
Silver
Sodium
Zinc
Date Digested
Mercury. CVAAS, TCLP Leachate
Mercury
mercury. CVAAS, in Soil
Orate: AIM196
Prep/Method: EPA 3010 / EPA 6010
0.630
mg/l
0.025
3.2
mg/l
0.025
ND
mg/1
0.0050
0.015
mg/l
0.010
NO
lag/l
0.025
NO
mpg/1
0.025
ND
mpg/l
0.1010
O1/13/06 09.40
Prep/Method: EPA 3050 / EPA 6010
T.5
maglkg
0.92
1300
mg/kg
0.92
N0
rig/kg
0.19
70000
mg/kg
37.
34•.
mg/kg
0.37
87.
mg/kg
0.37
21080
mg/kg
18.
19.
NOW
0.92
14000
mg/kg
18.
2100
ag/kg
1.8
1.6
Wks
0.92
26,
mmglk9
0.92
24000
arglkg
1800
ND
mop/kg
0.92
NO
mg/kg
0.37
6700
mg/kg
370
170
Ng/kg
1.8
01112/06 10:30
1.0 01/14/06
JDAI 7440.3a-2
1.4 01/14/06
JDAI 7440.39.3
1.8 01/14/06
4DA1 7440-43-9 .
1.0 01/14/06
JDAI 7440-47.3
1-0 01/14/06
JDAI 7439.92-1
1.0 01/24/06
JDAI 7782-49-2
1.0 01/14/06
JDAI 7440-22-4
01/13/06 09:40
1.8 01/14/06 14:17 ALV
7440-38.2
1.8 01/14/06 34:17 ALV
7440.39.3
1.8 01/14/06 14:17 ALV
744D-43-9
3.7 O1/14/D6 14:17 ALV
7440-70.2
1.9 01/14106 14:17 ALV
7440-47-3
2.8 01/14/06 14:11 ALV
7440.50-8
3.7 01/14105. 14.17 ALV
X19-89-6
1.8 01/14/06 14:17 ALV
7439-92-1
1.8 01/14/06 14:17 ALV,
7439.95-4
3.7 01/14/06 14:17 ALV
7439.96-5
1.8 01/14/06 14.17 ALY
7439.98-7
1.8 01114/06 14:17 ALV
7440.02-0
18.4 01/14/06 14:17 ALV
7446-09.7
1.8 01/14/06 24:17 ALV
7782-49-2
1.8 01/14/06 14:17 ALV
7440-22.4
3.7 01/14/06 14:17 ALV
7440-23.5
1.8 01/24/06 14:17 ALV
7443.66-6.
01/12/06 iD:30
Method: EPA 7470
ND eg/l O.OD020 1.0 01/13/06 11:30 ALV .7439-97-6
Method: EPA 7471
REPORT OF LABORATORY MALYSiS
Asheym Cprtifiman IDS This report ftlf riot be teprodmd, except 1n full,
NC Wastewater 40 without the wrrttten consent t1f Pace Ana ftg Services, ins.
NC Drinking Water 37712' •' ,
SC Environmental 99030 s-
FL NELAP E97648 -
Fagot 1 of 3
Cbmktt>; Ced1liicariara 1Ds
NC Wastewater 12
NC Drinking Water 37706
SC M06
FL NELAP E97627
- A nor I _oci _QFQ NOIHUW Z3ns
WdOl:S LOOZ OE ueC

aceAnalytical
Lab Sample No: 926520m
Client SaWe ID: MARION FLY ASH
PM ARW/ia! Serrtces, hr-
s800 Kinrxy Rvenc Suite 700
MmterstllUe, AIC 20078
Phwre- 71Jc875 90s2
l . 704.875 Mgt
Lab Project Number: 92110938
Client Project I0: Marion Fly Ash
Project Semple Number: 92110938-001 Date Collected: D1/06/06 00:00
Matrix: Soil Date Recelved: 01/04ID6 11:00
Perimeters
- Results UY s _ Bacon Limit �F _ Analyzed By
CAS No. Dual ReLmt
ND Wg/kg
0.008e
1.8 01/17/06 15:37 Al.Y
7439.97-5
Mercury
Wet Chemistry
Percent 11isture
Method: I Moisture
Percent Moisture
51.5 4
1.0 01/10/06 is:22 Tm
Total Kjeldahl Nitrogen, Soil
Method: EPA 351.2
Nitrogen, Kjeldehl, Total
92D mg/kg
21.
2.1 01/11105 19.20 CD1
Nitrogen, Nitrate plus Nitrite
Method: EPA 353.2 Modified
Nitrate as N
ND mg/kg
21..
2.1 01/11/06 20:11 CD1
Nitrate -Nitrite (as N)
Np mg/kq
22.
2.1 01/11/% 20:21 M1
1727-37-9
Nitrite as N
ND mg/kg
21.
2.1 01/11105 20:11 CD1
Phosphorus, Total, Soil
Method- EPA 365.2
Phosphorus
1420 awkq
468.
46.6 OV19/06 23:D5 ARN
1723-14-0
PH
Method: EPA 9045
py
10.3 units
2.0 01/17/O6 14:00 TMR
oatat OV23M
AahW ie Certification IDs
NC Wastewater 40
NC (kinking Water 37712
SC Environmental 9903D
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
This report shag not be reproduced. except In fu8,
w Mmut the written consent of Pace Analytical Servleas, Inc.
d
Pape: 2 of 3
GUddo Cedicaflon IDs
KC Wastewater 12
NC Drinking Water 37706
5C 99006 ! ,'
FL•NELAP E37527
- -.J n0T / _00J _R7R
W0I HU14 Z3f1S Wd0 i S GOOZ OE;

Analytical®
w1Mlr lol ulaft.ram
f*0 A+reh► I&W Sarwwess, IN.
9M)Mcay A►anue, Sulfa 1ao
ffwaVmvffle, NO 28078
Mom 704.87&902
W. 704.875 9091
Lab Project Number: 92110938 '
Client Project ID: Marion Fly Ash
i
PARAMETER FOOTNOTES
Dilution factor shown represents the factor applied to the reported result and reporting limit due to changes
in sample preparation, dilution of the extract. or moisture content
Method 90719 modified to use ASE.
All pH, Free Chlorine. Total Chlorine and Ferrous Iron analyses conducted outside of EPA recaaalended immediate
hold time.
Depending on the moisture content the PRU can be elevated for all soil samples reported on a dry weight basis.
2-C#1loroetW vinyl ether has been shown to degrade in the presence of acid.
ND Not detected at or above adjusted reporting. lihnit
NC Not Calculable
J Estimated concentration above the adjusted wkhod detection limit and below the adjustedreporting limit
MDL Adjusted Method Detection Limit
orte_ MOMS
REPORT OF LABORATORY ANALYSIS
AshewHis Certif gdon Ills This report shall not be ropmduced. except in full,
NG vlFa awater 40 without the written consent of Pace Analytical Services, Inc.
NG Drinking Watar 37712
SC Environmental 99030
FLNELAP E87648)_I�as<.e
I
page: 7 or 3
Chada Cedfflcation IDs
NG Wastewater 12
NC Drinking Water 37706'
Sc 99006
FL NELAP E87827
.A --" rnOT I _OnI _Qaa wnTNHW zAns WdOT =S LODE 06 Uer

Jan.11. 2006 3:36AM No.0399 P. 1
PRECISION PETROLEUM LASS, INC.
5915 . scar Lane HoustM TX 77057
Ph.713-680-9425 Fax:[phone]
CERTMCA.TE OF ANALYS.IS 1
COWANY: PACE ANALY-nCAL
INVOICE Nw 28776
LAD REFERENCE No.: 2006-01-297 j
PRODUCT III: 929620818 /)AARION FLY ASH 01-06-2006
DATE RED: 01-10-2006
AUTHORIZED BY: KATE KNAUFF
I
TEST REPORTING TEST �
g'
Sulfur, Wt% D-4294 .0.001 ®.013 8 i
BJ-,-B LOW REPORTING LiMFi
pXTAoLJWKL&q& M 3MWoN3E3UMTKMTW ADO" ANALTW%
cwmluomm OR iATi i811I�fI D 7!O i� tS A�d04JN%
llnTNWW 7-4nc WATT :G f.nn;7 nE uer

aceAndlj4cal e
WWW. 1J&.
,February 28, 2006
'Ms. Lauren Sillheimer, P.E,
Trigen-bioftmr. Inc.
1931 Winsted Ct.
Charlotte, NC 28262
BE. Lab Pro;vct rttanber: 921137M
Client Project ID: Harion Fly Ash
Dear Ms. Billhelmr, P..E.:
AmW MW >r��Sm&qr00
fttersvft NC 28078
Far. 794-875 -COO
Enclosed are the analytical results for sample(s) received by the laboratory of February.20, aoo6, Results
reported herein conform to the 90st carrot NELAC standards. where opplieable, unless othendse narrated in ttw
body of the report,
irwVanlc Net Chonistry and Metals Analyzes were perforged at our Pace Asheville laboratory and Organic testing
was perPOrmed at our Pace 0mr7ott:e'ioboratory unless otherWse footnoted.
It yuu have any quastions concerning this report please feel free to contact in.
. 1 ..
Sin M ely,
Kate Kneuff
Kate . Knaufmpacelabs. cm
Project Manager .
Ertcloaurea
REPORT OF LABORATORY ANALYSIS
n TM 1`e1110►t SW not be reproduced, fifeW in tell,
Nt: Yl&st0uster 40 wtthout tm written cunt of Pace Anivikil Services, Ina.
NCOfinklnnWitter 37712 H Alft
SC ErMmamarifgl 29031)
FL NELAP E87MB 2• S
r�idn utiiiGat.DID Of
NC Wastewabar 12
NC Drinking Watar 37706
SC 99008
FL NELAP E07627
T •d 09IL-9SL-9213 IJOINUW Z3f1S
WdLS=6 L002 IE UeC

4,AaCeAnalyticalab
rrwr I"Ceh;Ds.rm
Solid re;lilts are reported on a dry Weight basis
Page Aarll pl►ts/ dar"ns� k.
MW KfaWArrenue &d7o 100
hwfv;sww4 NC 28078
Phom'704 9W
Lab Project num&r: 92II3f06 FBX.'Ifl4.dP3.909/
Client Project 10: Martoo Fly Ash
Lab Sample No: 926666405 Project Semple- Mxftr: 92113706.001 Date Collected: C2116/06 16:00
Client Sample 10: MAR1®N FLY ASH 2O11 Matrix; Other Data Itviceived: 02/20/06 09:20
Perameters
RfUlts nits
82RW-t !„ie•1t
_OF _ � I=d y
CAS No. RegLn
Metals"
Metals, Trace ICP
Prop/Method:
EPA 3050 ! EPA 60i0
Arsenic
6.2
mg/kg
1.0
2.1 02/27/06 22:34 ALV
7440.38-2.
gartum
850
vq/kg
1.9
2.1 02/27/06 22.34 ALV
7440.39.3
Cadmium
HD
mg/kg
0.21
2.1 02/27/06 22:34 ALY
7440-43.9
Grlcium
48000
mg/ke
21.
2,1 02127/06 22:34 ALY
7440-70.2
Chmiu n
Ia.
mg/kg
0.41
2.1 02/27/06 22:34 ALY
7440-47.3
Copper
55_
w9ft
0.41
2.1 02/27/Db 22:34 ALY
7440-50.9
Iron
11000
109/4
10.
2.1 02/27/96 22.-34 ALY
7439.419-6
Lead
1s.•
mgikg
1.0
2.1 02/27/06 22:34 ALV
7439.92.1
WaQneainee
8000
m9/kg
21,
2.1 02/27/06 22:34 ALY
7439.95.4
MangargS®
1400
mg/kg
1.0
2.2 CZ/27/06 22:34 ALV
7439.96.5
Molybdenum
1.3
mir/kg
1.0
2.1 02/27/06 22:34 ALV
7439.98-7
Mickel
15.
alift
1.0
2.1 OS/27/06 22:34 ALY
7440.02.0
Potassium
Is=
mg/kg
ID00
10.3 D2/27/06 22;34 ALY
7440.09-7
Selenium
N0
s81k4
1.0_
2.1 02/Z7/06 22:34 ALV
7782.49•A
Silver
0.59
aW/kg
0.41
2.1 02/27/06 22:34 ALY
7440.22.4
Sodium
4500
mg/kg
210
2.2 02/2746 22,34 ALY
7440.23.5
Zinc
130
spy/kg
2.1
2.1 02/27106 22.34 ALY
7440.66.6
Date Digested
02/22/06 11:10
02/a2lOS 11:10
Mercury. CVAAS, in Sol
Method. EPA 7471
Mercury
D.010
mg/kg
0.010
2.0 U122106 10:54 ALV
709.97.6
Wet Chemistry
Percent Moisture
Percent Hui sture
Phoaphoras. Total, SofI
Phosph*m
044: 02/26/06
Method: t Hoisturg
$4.4 . lr
Method: EPA 365.2
MD' ffig1kg 110.
1.0 02/21/46 Rt1:26 TNM
11.0 02/22/06 17:55 ARH 7723-14.0
REPORT OF LABORATORY ANALYSIS
nsneVn►e ugmto non nos Pft report shag not be reprodutx:d, eft in full,
NGWN slwater . 40 wrtMd the wry CoMnt of Pace Analytical Services, Inc.
NC Drlrtldnq Water 37712 ...,,,
SC lrtlWdMlrrlenfa)
FL NELAP i:87648 ;
•fee i 1 of 3
mfirlomt Cer1111eetim 103
NC VlylstaWAW 12
NG Drinking Yllater 37706
SC 99M
FL NJELAP E87627
Z-d 09IL-99L-82B NOI21dW Z3ns
WHLS:6 L00a IE ueC

aCoAnalyticals
wda! parala *.sax
Lab SA*Plo No: 926666421
Client Sample 1D: MARION FLY ASH-2012
P1#Aft"ags, lac.
2800 OwAwerwa, Ufa 100
HtrnkrvvI4 he 28078
PYwrre: M4 875.9092
Fax 704.875.901
Lab Project Nwibvr: 92113706
Client Project 1D: Mwion Fly Ash
Project Suple ftober: 92113706.002 Mate Collected: 02/16/06 10:00
Matrix: Dther Mate Received: 02/20/06 09:20
Parameters
Results _ Units _
Upart Limit DF Anily-M 91
CAS 1g, 2UL keaLa
Metals
Metals, Tray ICP
Prep/Method: EPA 3D59 / EPA 6010
Arsenic
5.2 ng/kg
0.96
2.9 02/27/06 22:39 ALY
7440-38-2
Earius
760 mg/kg
0.95
1.9 02/27/06 22.39 ALV
7440.30-3
Cadmium
ND mg/97
4.39
1.9 02/27/06 22:39 ALV
7440-43.9
Calcium
43000 mg/kg
19.
1.9 02/Z7/ofi 22.39 ALY
7440-70-2
Chromic
26. :eg/kg
0.38
1.9 02/27/06 22:39 ALY
7440-4.7-3
Capper
49. noft
0.36
1.9 02/27106 22:39 ALV
7440.SO-8
Iron
1000D wg/kg
9.6
1.9 02127/06 22:39 ALY
7439-69.6
Lead
25. wg1kg
0.96
1.9 02/2710 22!39 ALY
7439.92.1
Nageeslum
7900 MgAg
is. '
1.9 02/27/06 22:39 ALV
7439.95.4
A mganese
1300 sng/kg
0.95
2.9 02127/06 22:39 ALV
7439.96.5
Nolybdewn
No vlg/k9
0.96
1.9 02/27/06 22:39 ACV
7439,9®•7
Nickel
14. mg/kg
9.96
1.9 02127/06 22:39 ALV
7440.02-0
Potasatum
15000 MOP
%a
9.6 02/27106 22:39 ALY
7440.09.7
Selenium
1.3 wg/k9
0.96
1.9 02/27/06 22:39 ALY
7762-49.2
Silver
ND mg/kg
0.30
1.9 02/27/06 22:39 ALY
7440.22.4
Sodium
4300 mg/kg
1"
1.9 02/27/05 22:39 ALV
7449-23-5
Zinc
110 eg/kg
1.9
1.9 02/27JOS 22:39 ALV
7440.66.6
Gate Digested
02/22/05 11:10
02/22/06 11:10
Mercury, CVAAS. in Soil
!Method: EPA 7471
Mercury
ND mg/kg
0.W91
1.8 02/22/06 20;54 ALY
7439-97.6
Wet Chelnistry
Percent Moisture
Method: I Moisture
Ferment Moisture
54.1 x
1.9 02/21/06 08:26 TMH
Phosphorus. Total -Sail
Method: EPA 365.2
Phosphorus
ND mg/kg
109.
10.9 02/22/06 17:55 AM
7723.14-0
RM: 02/28/06
REPORT OF LABORATORY ANALYSIS
As eewa.Celpfuallon loll This report ON[ not be reproduced, except to full.
INC 1NkstrWer 40 without On written cement of Pace Allalytlell &erAces, hi0.
NC OrinklnpYl>ater 37712 a ••�
SC Enulrwv mnlW 99080
FL NELAP • E87M
Flow 2 9f b
charlotte Cal iintim
me wastewater
IM
t2
NC aflntdng Watar
377DG
SC
99006
FE NELAP
EU527
g-al 09iL-9SL-B2B NOINUW Z3f1S
WHLS:6 LOOZ 1E UeC

PM ANE yOW "WWI Im.
OW Kl&WAvanua, &0 i0
Analytical ® xur►rMrr� Arc 2076
om W,8738W
p it�r.f Fic 704;875.WSI
Lab Project WuWber: 92113705
client Project ID: Marian Fly Ash
PARMETER FOOTNU ES
Dilution factor sham represents the tenor applied to the reported result.and reporting litrlt due to changes
In sample preparation,- dilution of'the extract, or moisture owtent
Method 911719 mdditied to use A5E.
All pH, Frbe Chlorine, Total Chlorine end Ferrous Iron analyses =4acted outsfde of I:PA recomgaended iaaaediate
hold tiara.
DeWding an the moisture content the PRLs can be elevated for all %oil samples reported on a dry weight ball&,
2-chloraethyl vinyl ether has been shown to degrade in the presence of acid.
No }tat detected at or above adjusted ralwtinQ limit
NC Not Calculable
J Estionted concentration above the adjusted method detect"on•limit and below the adjusted reporting lis%it
MDL Adjusted Method Detection Limit
Este: 02infDe
REPORT DP LABORATORY ANALYSIS
Amh@gNe Certitiratim )Ds This report shall not be repraducad, except in iull.
SIC WUtevrater 40 without the wdltan consent of Pecs Analylital Servings, inc_
NC Drinking Weber 37712 .ra ' ""�!
SC Environmental 9M Is
FL NELAP E87M = t, .,
Par- 3 p1 3
Charlotte CerilffegionIDS
Me Wastawaler 12
NC Orinldnq Water 377DS
SC 9M
FL MELAP E97627
4.•d 091L-9SL—B28 WOINUW Z3f1S
WdLS:G L002 1E UeC

oo
ceMalytical
WWW.pacoiabs.com
4. 2006
:ky Styles
Biopower, Inc.
d Linville Rd.
NC 28752
_ab Project Number: 92116722
:lient Project ID: South Pond Ash/201
9800VnceyAKenrle,,aiUM Wv
Hunterswlle, NC 28078
Phone: [phone]
Fax. [phone]
,=ICU n/rcraiuc "I".
Asheville, NO 28804
Phone: [phone]
Fax.. [phone]
r. Styles:
ril
06.
ed are the analytical
���entsf��gC�ndardsrewheredby appltcableboratory on unless otheprwise6narrated insthi:sbody of
reportedconform to the most
port.
nic Wet Chemistry and Metals Analyses were performed at our Pace Asheville laboratory and Organic testing
rforned at our Pace Charlotte laboratory unless otherwise footnoted.
i have any questions concerning this report please feel free to contact me.
-ely.
Cnauff
Cnaufflapacelabs.cam
:t Manager
sures
t cation
;er 40
Water 37712
99030
E87648
09TL-9GL_8?_3
REPORT Of LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc.
"% le Q0'90
♦O ty 4
woiduW zinc 6 LOOZ 1E U e r
�arlott r�atian
IDs
NC Wastewater
12
NG Drinking Water
37706
sc
99006
FL NELAP
E87627

Feb 08 2007 3:55PM SUEZ MRRION
' A
aOAnalytical
6vww.pacel�bs.EORf
April 24, 2006
Mr. Ricky Styles
Trigen-BioPower. Inc.
2859 Old Li nvi l l a Rd.
Marion., NC 26752
RE: Lab Project Number: 92116722
Client Project ID: South Pond Ash/201
828-756-7160
Pace AnaWcal Services, lac.
9900 Kincey Avenue, Sulte 100
Nuntmille, NC 28078
Phone: 704,875.9092
For 704,875.9091
P.1
Pate Ansiolva/ S&Wces, me.
2225RIvers/de Drim
A080, NC 28304
Phone: 82R254.7176
Far 826.252.4618
Dear Mr. Styles:
Enclosed are the analytical results for sample(s) received by the laboratory on April 6. 2006. Results reported
herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of
the report.
Inorganic Wet Chemistry and Metals Analyses were performed at our Pace Asheville laboratory and Organic testing
was performed at our Pace Charlotte laboratory unless otherwise footnoted.
If you have any questions concerning this report please feel free to contact me.
Sincerely.
Kate Knauff
[e-mail]
Project Manager
Enclosures
Seville Certification II)s
REPORT OF LABORATORY ANALYSIS
Charlotte Certification
Jos
NC Wastewater 40 '
NC Wastewater
12
NC Drinking Water 3T71299030
This report shah not be reproduced, except in full,
NC Drinking Wager
SC 99030
'without the written consent of Pace Analytical Services, Inc.
SC
99006
99006
FL NELAP E87648
a
FL NELAP
E87627

Feb 08 2007 3:55PM SUEZ MRRION 828-756-7160 p.2
a ce Analytical
www.pacelabs.aom
*Solid results are reported on.a dry weight basis
Lab Sample No: 926832593
Client Sample ID: 040506.01
Pace Analytkal servkas' Inc.
9800IGmayAvenue, Suite 100
Nuntersville, NGZ6076
Phone: [phone]
Fax: [phone]
Pace Analytical Services, krc.
2225 Riverside Drive
Ashevlile, NO 28804
Phase: 828.254.7176
Fax 828.252,4618
Lab Project Number: 92116722
Client Project ID: South Pond Ash/2D1
Project Sample Number: 92116722-001 Date Collected: 04/05/06 10:30
Matrix: Other Date Received: 04/06/06 09:15
Parameters
Results
Units
Report Limit
DF Analyzed
By
CAS No. Qual Re9Lmt
Metals
Metals. Trace ICP
Prep/Method: EPA 3050 /
EPA 6010
Arsenic
11,
mg/kg
0.70
1.4 04/21/D6
11:49 SAJ
7440-38-2
Barium
1100
mg/kg
C.70
1.4 04/21/06
11:49 SAJ
7440-39-3
Cadmium
NO
mg/kg
0.14
1.4 04/21/06
11:49 SAJ
7440-43.9
Calcium
70000
mg/kg
140
14.0 04/21/06
11:49 SAJ
7440-70-2
Chromium
37.
mg/kg
0.28
1.4 04/21/06
11:49 SAJ
7440-47-3
Copper
82.
mg/kg
0.28
1.4 04/21/06
11:49 SAJ
7440-50-8
Iron
25000
mg/kg
70.
14.0 04/21/06
11:49 SAJ
7439-89.6
Lead
23.
mg/kg
0,70
1.4 04/21/06
11:49 SAJ
7439-92-1
Magnesium
12000
mg/kg
14.
1.4 04/21/06
11:49 SAJ
7439-95-4
Manganese
•2000
mg/kg
7.0
14.0 04/21/06
11:49 SAJ
7439.96-5
Molybdenum
1.1
mg/kg
0.70
1.4 04/21/06
11:49 SAJ
7439.98-7
Nickel
21.
mg/kg
0.70
1.4 04/21/06
11:49 SAJ
7440.02-0
Potassium
29000
mg/kg
1400
14.0 04/21/06
11:49 SAJ
7440.09-7•
Seleniun
ND
mg/kg
0.70
-1.4 04/21/06
11:49 SAJ
7782-49-2
Silver
ND
mg/kg
0.28
1.4 04/21106
11:49 SAJ
7440-22-4
Sodium
7600
mg/kg
1400
14.0 04/21/06
11:49 SAJ
7440-23-5
Zinc
170
mg/kg
1.4
1.4 04/21/06
11:49 SAJ
7440.66-6
Date Digested
04/07/06 20:45
04/07/06
20:45
Mercury. CVAAS, in Soil
Mercury
Wet Chemistry
Percent Moisture
Percent Moisture
Phosphorus. Total, Soil
Phosphorus
Date: 04/24/06
Asheville Certification IDS
NC Wastewater 40
NC Drinking Water 37712
SC 99D30
FL NELAP E87648
Method: EPA 7471
NO mg/kg
Method: % Moisture
27.2 %
method: EPA 365.2
30.6 mg/kg
0.0069 1.4 04/10/06 13:04 ALV 7439.97-6
1.0 04/10/06 16:26 KDF
1V. 12.7 1.3.04/13106 OB:00 TMR 7723-14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 1 of 2
Charlotte Certification Ws
NC Wastewater 12
NC Drinking Water 37706
5 C 99006
FL NELAP E87627

Feb 08 2007 3:55PM SUEZ MARION
aeeAnalytkal
. www.pacslabs.conr
PARMETER FOOTNOTES
828-756-7160
Pace Analytical Serving, Inc.
9800 Kincey Avenua, Suite 100
NuntersvlUe, NO 28076
Phone: [phone]
Fax.' 704.875.9091
P.3
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92116722
Client Project ID: South Pond Ash/201
Dilution factor shown represents the factor applied to the reported result.and reporting limit due to changes
in sample preparation, dilution of the extract, or moisture content
Method 90718 modified to use ASE.
All pH, Free Chlorine, Total Chlorine and Ferrous Iron analyses conducted outside of EPA.recommended immediate
hold time.
Depending on the moisture content the PRLs can be elevated for all soil'samples reported on a dry weight basis.
2•Chloroethyl vinyl ether has been shown to degrade in the presence of acid.
ND Not detected at or above adjusted reporting limit
NC Nat Calculable
J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
Date; W20/06
Asheville Certification IDs
NC Wastewater 40
NC Drinking Water 37712
SC D9030
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 2 of 2
tte Certifi
NC Wastewater
12
NC Drinking Water
37706
SC
99006
-FL NELAP
E87627

Feb 08 2007 3:11PM SUEZ MARION 828-756-71SU p.1
PH Field Parameter Worksheet
Trigen-BioPower, Inc.
Date: 01 _A0 —o Analyst:
Facility. /�,�,.° �,ti!
Calibration
Calibration I Cal Buffer Cal Buffer. Check
Time 4.0 . 12.64 Buffer 7.0* S Comments
' pH buffer checks are t4 be within f 0.1 pH units of the standards true value
pH Analyses
mubuiis snouts De wrmm ± o.7 pH units of the standard's true value.

Feb'08 2007 3:11PM SUEZ MARION 828-756-7160 p.2
-PH Field Parameter Workah"t
Tfigen-BioPower, Inc.
Date: -
Facility:
Analyst.
Calibration
Time
Callf1fallon
Cal Buffer Cal Buffer Check
4.0 12-54 Buffer 7.0,6 sto
.0 Comments
7,/
PH buffer checks are to be within 0.1PH u -
nft of the sta TrIm value
PH Anatys"
-w —olluaru a ume mue.

4/18/2006
Growet- Trigen-ElloPower copies 1-0:
cYoRicky Styles, ,
2859 Old Linville Road
Marion, NC 28752
Waste A naly*sis R D11) ort Farm
McDowell County
.• ............
1 � 1 . f i
.
SOON.
M Cl
amplem;
N
P
x
Ca
mg
S PO
Mn
Zn
Cu
D
W111- 81-11i'1111111311ilil
Total
31.1
1923
18619
48966
7734
949 7624
1141
91.4
59.3
57.7
ZNr-N
vaste code:
SAR '
-NH4
-NO3
Na
Ni
Cd
A
Al so
Li
PH
_SS
GN
DM% can
)eScriptioll:
OR-N
3847
10.5
1.64
25.6
10.14
67.69 17.25
ndust.-Stack Ash.
Uroa
-Ve
......
...... ...... ....
Oplication Method
N
P205
K20 Ca
mg-, S
Fe
Mn
Zn Cis B
&
-Na.
Ni
6w- AV
Broadcast
0.02
4.2
14.2 46.4
7.3 0.90
7.2
1.1
0.09 0.06 0.05
5.2
0.01
T 0.03
Soil 111carp
0.03
4.8
27.2 53 -0
8.4 1.0
.8.3
.1.2
vo o.o6 o.o6
.5.2
G.01
T 0.03
Neutralizing value Is very
low. -
C
7.70
M!