WQ0013419_Sludge Landfill Monitoring Report July 2022_20221024

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
October 24, 2022
Mr. Mike Cody
Glatfelter Corp.
228 South Main Street
Spring Grove, PA 17362
RE: Project: Sludge LF 7/18
Pace Project No.: 92615455
Dear Mr. Cody:
Enclosed are the analytical results for sample(s) received by the laboratory between July 18, 2022 and July 19, 2022. The
results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC
Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
(Z/� ` -
Lord Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Sludge LF 7/18
Pace Project No.: 92615455
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
VirginiaNELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Sludge LF 7/18
92615455
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92615455001
SWP-1
EPA 6010D
DEC, RDT
18
PASI-A
EPA 8270E
PKS
74
PASI-C
EPA 8260D
SAS
63
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 2540C-2015
MAB2
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
SM 4500-CI-E-2011
DMN
1
PASI-A
SM 5310B-2014
MJP
1
PASI-A
92615455002
SWP-2
EPA 6010D
DEC, RDT
18
PASI-A
EPA 8270E
PKS
74
PASI-C
EPA 8260D
SAS
63
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 2540C-2015
MAB2
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
SM 4500-CI-E-2011
DMN
1
PASI-A
SM 5310B-2014
MJP
1
PASI-A
92615455003
Q06V09
EPA 6010D
DEC, RDT
18
PASI-A
EPA 8270E
PKS
74
PASI-C
EPA 8260D
SAS
63
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 2540C-2015
MAB2
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
SM 4500-CI-E-2011
ANM
1
PASI-A
SM 5310B-2014
MJP
1
PASI-A
92615455004
Q06V10
EPA 6010D
DEC, RDT
18
PASI-A
EPA 8270E
PKS
74
PASI-C
EPA 8260D
SAS
63
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 2540C-2015
MAB2
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
SM 4500-CI-E-2011
ANM
1
PASI-A
SM 5310B-2014
MJP
1
PASI-A
92615455005
Q06V11
EPA 6010D
DEC, RDT
18
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Project: Sludge LF 7/18
Pace Project No.: 92615455
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
EPA 8270E
PKS
74
PASI-C
EPA 8260D
SAS
63
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 2540C-2015
MAB2
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
SM 4500-CI-E-2011
ANM
1
PASI-A
SM 5310B-2014
MJP
1
PASI-A
92615455007 TRIP BLANK EPA 8260D
CL
63
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SUMMARY OF DETECTION
Project: Sludge LF 7/18
Pace Project No.: 92615455
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92615455001
SWP-1
Performed by
Pace
08/02/22 17:00
Collected By
S.Kline
08/02/22 17:00
Collected Date
7/18/22
08/02/22 17:00
Collected Time
13:25
08/02/22 17:00
pH
7.30
Std. Units
08/02/22 17:00
Temperature
19.1
deg C
08/02/22 17:00
Specific Conductance
20.5
umhos/cm
08/02/22 17:00
Oxygen, Dissolved
8.56
mg/L
08/02/22 17:00
REDOX
-179.2
my
08/02/22 17:00
Turbidity
135.6
NTU
08/02/22 17:00
Odor
None
08/02/22 17:00
Appearance
Clear
08/02/22 17:00
EPA 601 OD
Arsenic
13.4
ug/L
10.0
07/28/22 15:47
EPA 601 OD
Barium
312
ug/L
5.0
07/28/22 15:47
EPA 601OD
Calcium
132000
ug/L
500
08/01/2219:05
EPA 601OD
Cobalt
28.5
ug/L
5.0
08/01/2219:53
EPA 601 OD
Magnesium
61600
ug/L
100
07/28/22 15:47
EPA 601OD
Potassium
15000
ug/L
5000
08/01/2219:53
EPA 601 OD
Sodium
21600
ug/L
5000
07/28/22 15:47
EPA 601 OD
Zinc
1200
ug/L
10.0
07/28/22 15:47
EPA 8270E
3&4-Methyl phenol (m&p Cresol)
8AJ
ug/L
10.0
07/26/22 13:01
SM 2320B-2011
Alkalinity, Total as CaCO3
706
mg/L
5.0
07/27/22 21:57
SM 2540C-2015
Total Dissolved Solids
660
mg/L
50.0
07/22/22 11:48
EPA 300.0 Rev 2.1 1993
Sulfate
2.7
mg/L
1.0
07/22/22 15:04
SM 4500-CI-E-2011
Chloride
24.2
mg/L
1.0
07/27/22 10:53
SM 531OB-2014
Total Organic Carbon
18.4
mg/L
1.0
07/22/22 03:42
92615455002
SWP-2
Performed by
Pace
08/02/22 17:01
Collected By
S.Kline
08/02/22 17:01
Collected Date
7/18/22
08/02/22 17:01
Collected Time
14:20
08/02/22 17:01
pH
8.68
Std. Units
08/02/22 17:01
Temperature
29.3
deg C
08/02/22 17:01
Specific Conductance
249.3
umhos/cm
08/02/22 17:01
Oxygen, Dissolved
7.71
mg/L
08/02/22 17:01
REDOX
33.5
my
08/02/22 17:01
Turbidity
11.64
NTU
08/02/22 17:01
Odor
None
08/02/22 17:01
Appearance
Solids
08/02/22 17:01
EPA 601 OD
Barium
72.7
ug/L
5.0
07/28/22 15:51
EPA 601 OD
Calcium
22800
ug/L
100
07/28/22 15:51
EPA 601 OD
Cobalt
13.1
ug/L
5.0
08/01/22 20:04
EPA 601 OD
Magnesium
5150
ug/L
100
07/28/22 15:51
EPA 601 OD
Sodium
9250
ug/L
5000
07/28/22 15:51
SM 2320B-2011
Alkalinity, Total as CaCO3
102
mg/L
5.0
07/28/22 17:31
SM 2540C-2015
Total Dissolved Solids
113
mg/L
25.0
07/22/22 11:49
EPA 300.0 Rev 2.1 1993
Sulfate
5.6
mg/L
1.0
07/22/22 15:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
Sludge LF 7/18
92615455
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92615455002
SWP-2
SM 4500-CI-E-2011
Chloride
2.6
mg/L
1.0
07/27/22 10:56
92615455003
Q06V09
Performed by
Pace
08/04/22 09:03
Collected By
S.Warlick
08/04/22 09:03
Collected Date
7/19/22
08/04/22 09:03
Collected Time
12:00
08/04/22 09:03
pH
6.4
Std. Units
08/04/22 09:03
Temperature
22.1
deg C
08/04/22 09:03
Static Water Level
28.21
feet
08/04/22 09:03
Specific Conductance
1358
umhos/cm
08/04/22 09:03
Oxygen, Dissolved
1.7
mg/L
08/04/22 09:03
Total Well Depth
68.80
feet
08/04/22 09:03
REDOX
65.7
mV
08/04/22 09:03
Turbidity
15.0
NTU
08/04/22 09:03
Odor
No odor
08/04/22 09:03
Appearance
Clear
08/04/22 09:03
EPA 601 OD
Barium
266
ug/L
5.0
07/28/22 16:26
EPA 601OD
Calcium
168000
ug/L
500
08/01/2219:08
EPA 601 OD
Cobalt
18.0
ug/L
5.0
08/01/22 20:07
EPA 601OD
Magnesium
79800
ug/L
500
08/01/2219:08
EPA 601 OD
Nickel
12.2
ug/L
5.0
07/28/22 16:26
EPA 601 OD
Potassium
4760J
ug/L
5000
08/01/22 20:07
EPA 601 OD
Sodium
31600
ug/L
5000
07/28/22 16:26
SM 2320B-2011
Alkalinity, Total as CaCO3
756
mg/L
5.0
07/30/22 09:39
SM 2540C-2015
Total Dissolved Solids
804
mg/L
50.0
07/22/22 17:40
EPA 300.0 Rev 2.1 1993 Sulfate
3.1
mg/L
1.0
07/25/22 03:50
SM 4500-CI-E-2011
Chloride
51.1
mg/L
3.0
07/29/22 13:33
SM 531OB-2014
Total Organic Carbon
4.0
mg/L
1.0
07/25/22 23:09
92615455004
Q06V10
Performed by
Pace
08/04/22 09:10
Collected By
S.Warlick
08/04/22 09:10
Collected Date
7/19/22
08/04/22 09:10
Collected Time
10:30
08/04/22 09:10
pH
5.4
Std. Units
08/04/22 09:10
Temperature
19.3
deg C
08/04/22 09:10
Static Water Level
27.84
feet
08/04/22 09:10
Specific Conductance
45.4
umhos/cm
08/04/22 09:10
Oxygen, Dissolved
3.5
mg/L
08/04/22 09:10
Total Well Depth
34.43
feet
08/04/22 09:10
REDOX
129.8
mV
08/04/22 09:10
Turbidity
58.9
NTU
08/04/22 09:10
Odor
None
08/04/22 09:10
Appearance
Cloudy
08/04/22 09:10
EPA 601 OD
Arsenic
6.2J
ug/L
10.0
07/28/22 16:29
EPA 601 OD
Barium
22.2
ug/L
5.0
07/28/22 16:29
EPA 601 OD
Calcium
2310
ug/L
100
07/28/22 16:29
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 6 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Sludge LF 7/18
Pace Project No.: 92615455
Lab Sample ID Client Sample ID
Method Parameters
92615455004
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
SM 2320B-2011
EPA 300.0 Rev 2.1 1993
SM 4500-CI-E-2011
92615455005
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
EPA 6010D
SM 2320B-2011
SM 2540C-2015
EPA 300.0 Rev 2.1 1993
SM 4500-CI-E-2011
QO6V10
Chromium
Cobalt
Copper
Magnesium
Nickel
Sodium
Vanadium
Zinc
Alkalinity, Total as CaCO3
Sulfate
Chloride
Q06V11
Performed by
Collected By
Collected Date
Collected Time
pH
Temperature
Static Water Level
Specific Conductance
Oxygen, Dissolved
Total Well Depth
REDOX
Turbidity
Odor
Appearance
Barium
Calcium
Copper
Magnesium
Sodium
Zinc
Alkalinity, Total as CaCO3
Total Dissolved Solids
Sulfate
Chloride
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed Qualifiers
4.1 J
ug/L
5.0
07/28/22 16:29
6.1
ug/L
5.0
08/01/22 20:11
5.OJ
ug/L
5.0
07/28/2216:29
1070
ug/L
100
07/28/2216:29
4.3J
ug/L
5.0
07/28/2216:29
1870J
ug/L
5000
07/28/2216:29
4.2J
ug/L
5.0
07/28/2216:29
10.1
ug/L
10.0
07/28/2216:29
10.1
mg/L
5.0
07/29/22 21:57
1.0
mg/L
1.0
07/25/22 04:05
1.4
mg/L
1.0
07/29/2213:34
Pace
S.Warlick
7/19/22
11:00
5.6
19.0
38.83
78.1
3.6
56.98
113.3
37.5
None
Cloudy
8.5
4290
6.9
2080
4470J
26.4
23.2
44.0
2.8
2.3
Std. Units
deg C
feet
umhos/cm
mg/L
feet
mV
NTU
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
mg/L
mg/L
REPORT OF LABORATORY ANALYSIS
O8/04/22 09:13
O8/04/22 09:13
O8/04/22 09:13
O8/04/22 09:13
O8/04/22 09:13
O8/04/22 09:13
O8/04/22 09:13
O8/04/22 09:13
O8/04/22 09:13
O8/04/22 09:13
O8/04/22 09:13
O8/04/22 09:13
O8/04/22 09:13
O8/04/22 09:13
5.0 07/28/2216:33
100 07/28/2216:33
5.0 07/28/2216:33
100 07/28/2216:33
5000 07/28/2216:33
10.0 07/28/2216:33
5.0 07/29/22 22:02
25.0 07/22/2217:40
1.0 07/25/22 04:21
1.0 07/29/2213:35
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 7 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: SWP-1 Lab ID: 92615455001 Collected: 07/18/22 13:25 Received: 07/18/22 18:30 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
08/02/22 17:00
Collected By
S.Kline
1
08/02/22 17:00
Collected Date
7/18122
1
08/02/22 17:00
Collected Time
13:25
1
08/02/22 17:00
pH
7.30
Std. Units
1
08/02/22 17:00
Temperature
19.1
deg C
1
08/02/22 17:00
Specific Conductance
20.5
umhos/cm
1
08/02/22 17:00
Oxygen, Dissolved
8.56
mg/L
1
08/02/22 17:00
7782-44-7
REDOX
-179.2
mV
1
08/02/22 17:00
Turbidity
135.6
NTU
1
08/02/22 17:00
Odor
None
1
08/02/22 17:00
Appearance
Clear
1
08/02/22 17:00
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
1
07/27/2213:03
07/28/2215:47
7440-36-0
Arsenic
13.4
ug/L
10.0
1
07/27/2213:03
07/28/2215:47
7440-38-2
Barium
312
ug/L
5.0
1
07/27/2213:03
07/28/2215:47
7440-39-3
Cadmium
ND
ug/L
1.0
1
07/27/2213:03
07/28/2215:47
7440-43-9
Calcium
132000
ug/L
500
5
07/27/2213:03
08/01/2219:05
7440-70-2
Chromium
ND
ug/L
5.0
1
07/27/2213:03
07/28/2215:47
7440-47-3
Cobalt
28.5
ug/L
5.0
1
07/27/2213:03
08/01/2219:53
7440-48-4
Copper
ND
ug/L
5.0
1
07/27/2213:03
07/28/2215:47
7440-50-8
Lead
ND
ug/L
5.0
1
07/27/2213:03
07/28/2215:47
7439-92-1
Magnesium
61600
ug/L
100
1
07/27/2213:03
07/28/2215:47
7439-95-4
Nickel
ND
ug/L
5.0
1
07/27/2213:03
07/28/2215:47
7440-02-0
Potassium
15000
ug/L
5000
1
07/27/2213:03
08/01/2219:53
7440-09-7
Selenium
ND
ug/L
10.0
1
07/27/2213:03
07/28/2215:47
7782-49-2
Silver
ND
ug/L
5.0
1
07/27/2213:03
07/28/2215:47
7440-22-4
Sodium
21600
ug/L
5000
1
07/27/2213:03
07/28/2215:47
7440-23-5
Thallium
ND
ug/L
10.0
1
07/27/2213:03
08/01/2219:53
7440-28-0
Vanadium
ND
ug/L
5.0
1
07/27/2213:03
07/28/2215:47
7440-62-2
Zinc
1200
ug/L
10.0
1
07/27/2213:03
07/28/2215:47
7440-66-6
8270E RVE
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Acenaphthene
ND
ug/L
10.0
1
07/25/2216:52
07/26/2213:01
83-32-9
Acenaphthylene
ND
ug/L
10.0
1
07/25/2216:52
07/26/2213:01
208-96-8
Aniline
ND
ug/L
10.0
1
07/25/2216:52
07/26/2213:01
62-53-3
Anthracene
ND
ug/L
10.0
1
07/25/2216:52
07/26/2213:01
120-12-7
Benzo(a)anthracene
ND
ug/L
10.0
1
07/25/2216:52
07/26/2213:01
56-55-3
Benzo(a)pyrene
ND
ug/L
10.0
1
07/25/2216:52
07/26/2213:01
50-32-8
Benzo(b)fluoranthene
ND
ug/L
10.0
1
07/25/2216:52
07/26/2213:01
205-99-2
Benzo(g,h,i)perylene
ND
ug/L
10.0
1
07/25/2216:52
07/26/2213:01
191-24-2
Benzo(k)fluoranthene
ND
ug/L
10.0
1
07/25/2216:52
07/26/2213:01
207-08-9
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in
full,
Date: 10/24/2022 08:45 AM
without
the written consent of Pace Analytical Services, LLC.
Page 8 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: SWP-1 Lab ID: 92615455001 Collected: 07/18/22 13:25 Received: 07/18/22 18:30 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No
8270E RVE
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
Benzoic Acid
ND
ug/L
50.0
1
07/25/22 16:52
07/26/22 13:01
65-85-0
Benzyl alcohol
ND
ug/L
20.0
1
07/25/22 16:52
07/26/22 13:01
100-51-6
4-Bromophenylphenyl ether
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
101-55-3
Butylbenzylphthalate
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
85-68-7
4-ChIoro-3-methyl phenol
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
59-50-7
4-Chloroaniline
ND
ug/L
20.0
1
07/25/22 16:52
07/26/22 13:01
106-47-8
bis(2-Chloroethoxy)methane
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
111-44-4
2-Chloronaphthalene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
91-58-7
2-Chlorophenol
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
7005-72-3
Chrysene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
218-01-9
Dibenz(a,h)anthracene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
53-70-3
Dibenzofuran
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
132-64-9
1,2-Dichlorobenzene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
95-50-1
1,3-Dichlorobenzene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
541-73-1
1,4-Dichlorobenzene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
106-46-7
3,3'-Dichlorobenzidine
ND
ug/L
20.0
1
07/25/22 16:52
07/26/22 13:01
91-94-1
2,4-Dichlorophenol
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
120-83-2
Diethylphthalate
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
84-66-2
2,4-Dimethylphenol
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
105-67-9
Dimethylphthalate
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
131-11-3
Di-n-butylphthalate
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
20.0
1
07/25/22 16:52
07/26/22 13:01
534-52-1
2,4-Dinitrophenol
ND
ug/L
50.0
1
07/25/22 16:52
07/26/22 13:01
51-28-5
2,4-Dinitrotoluene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
121-14-2
2,6-Dinitrotoluene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
606-20-2
Di-n-octylphthalate
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
117-84-0
bis(2- Ethyl hexyl)phthalate
ND
ug/L
6.0
1
07/25/22 16:52
07/26/22 13:01
117-81-7
Fluoranthene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
206-44-0
Fluorene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
87-68-3
Hexachlorobenzene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
77-47-4
Hexachloroethane
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
67-72-1
Indeno(1,2,3-cd)pyrene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
193-39-5
Isophorone
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
78-59-1
1-Methylnaphthalene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
90-12-0
2-Methylnaphthalene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
91-57-6
2-Methylphenol(o-Cresol)
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
95-48-7
3&4-Methyl phenol (m&p Cresol)
8AJ
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
15831-10-4
Naphthalene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
91-20-3
2-Nitroaniline
ND
ug/L
20.0
1
07/25/22 16:52
07/26/22 13:01
88-74-4
3-Nitroaniline
ND
ug/L
20.0
1
07/25/22 16:52
07/26/22 13:01
99-09-2
4-Nitroaniline
ND
ug/L
20.0
1
07/25/22 16:52
07/26/22 13:01
100-01-6
Nitrobenzene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
98-95-3
REPORT OF LABORATORY ANALYSIS
M1
M1
M1
Qual
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Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 132

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2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: SWP-1 Lab ID: 92615455001 Collected: 07/18/22 13:25 Received: 07/18/22 18:30 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
8270E RVE
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
2-Nitrophenol
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
88-75-5
4-Nitrophenol
ND
ug/L
50.0
1
07/25/22 16:52
07/26/22 13:01
100-02-7
M1,v1
N-Nitrosodimethylamine
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
62-75-9
N-Nitroso-di-n-propylamine
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
86-30-6
2,2'-Oxybis(1-chloropropane)
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
108-60-1
Pentachlorophenol
ND
ug/L
20.0
1
07/25/22 16:52
07/26/22 13:01
87-86-5
M1
Phenanthrene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
85-01-8
Phenol
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
108-95-2
Pyrene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
129-00-0
1,2,4-Trichlorobenzene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
120-82-1
2,4,5-Trichlorophenol
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
95-95-4
M1
2,4,6-Trichlorophenol
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:01
88-06-2
M1
Surrogates
Nitrobenzene-d5 (S)
85
%
10-144
1
07/25/22 16:52
07/26/22 13:01
4165-60-0
2-Fluorobiphenyl (S)
75
%
10-130
1
07/25/22 16:52
07/26/22 13:01
321-60-8
Terphenyl-d14 (S)
110
%
34-163
1
07/25/22 16:52
07/26/22 13:01
1718-51-0
Phenol-d6 (S)
29
%
10-130
1
07/25/22 16:52
07/26/22 13:01
13127-88-3
2-Fluorophenol (S)
11
%
10-130
1
07/25/22 16:52
07/26/22 13:01
367-12-4
2,4,6-Tribromophenol (S)
3
%
10-144
1
07/25/22 16:52
07/26/22 13:01
118-79-6
SO
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
07/20/22 17:02
67-64-1
Benzene
ND
ug/L
1.0
1
07/20/22 17:02
71-43-2
Bromobenzene
ND
ug/L
1.0
1
07/20/22 17:02
108-86-1
Bromochloromethane
ND
ug/L
1.0
1
07/20/22 17:02
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
07/20/22 17:02
75-27-4
Bromoform
ND
ug/L
1.0
1
07/20/22 17:02
75-25-2
Bromomethane
ND
ug/L
2.0
1
07/20/22 17:02
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
07/20/22 17:02
78-93-3
Carbon tetrachloride
ND
ug/L
1.0
1
07/20/22 17:02
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
07/20/22 17:02
108-90-7
Chloroethane
ND
ug/L
1.0
1
07/20/22 17:02
75-00-3
Chloroform
ND
ug/L
1.0
1
07/20/22 17:02
67-66-3
Chloromethane
ND
ug/L
1.0
1
07/20/22 17:02
74-87-3
2-Chlorotoluene
ND
ug/L
1.0
1
07/20/22 17:02
95-49-8
4-Chlorotoluene
ND
ug/L
1.0
1
07/20/22 17:02
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
07/20/22 17:02
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
07/20/22 17:02
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
07/20/22 17:02
106-93-4
Dibromomethane
ND
ug/L
1.0
1
07/20/22 17:02
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
07/20/22 17:02
95-50-1
1,3-Dichlorobenzene
ND
ug/L
1.0
1
07/20/22 17:02
541-73-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
07/20/22 17:02
106-46-7
Dichlorodifluoromethane
ND
ug/L
1.0
1
07/20/22 17:02
75-71-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: SWP-1
Parameters
8260D MSV Low Level Landfill
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
ANALYTICAL RESULTS
Lab ID: 92615455001 Collected: 07/18/22 13:25 Received: 07/18/22 18:30 Matrix: Water
Results Units
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
99 %
102 %
102 %
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
ND ug/L
PQL DF Prepared Analyzed CAS No
1.0
1
07/20/22 17:02
75-34-3
1.0
1
07/20/22 17:02
107-06-2
1.0
1
07/20/22 17:02
75-35-4
1.0
1
07/20/22 17:02
156-59-2
1.0
1
07/20/22 17:02
156-60-5
1.0
1
07/20/22 17:02
78-87-5
1.0
1
07/20/22 17:02
142-28-9
1.0
1
07/20/22 17:02
594-20-7
1.0
1
07/20/22 17:02
563-58-6
1.0
1
07/20/22 17:02
10061-01-5
1.0
1
07/20/22 17:02
10061-02-6
1.0
1
07/20/22 17:02
108-20-3
1.0
1
07/20/22 17:02
100-41-4
2.0
1
07/20/22 17:02
87-68-3
5.0
1
07/20/22 17:02
591-78-6
1.0
1
07/20/22 17:02
99-87-6
5.0
1
07/20/22 17:02
75-09-2
5.0
1
07/20/22 17:02
108-10-1
1.0
1
07/20/22 17:02
1634-04-4
1.0
1
07/20/22 17:02
91-20-3
1.0
1
07/20/22 17:02
100-42-5
1.0
1
07/20/22 17:02
630-20-6
1.0
1
07/20/22 17:02
79-34-5
1.0
1
07/20/22 17:02
127-18-4
1.0
1
07/20/22 17:02
108-88-3
1.0
1
07/20/22 17:02
87-61-6
1.0
1
07/20/22 17:02
120-82-1
1.0
1
07/20/22 17:02
71-55-6
1.0
1
07/20/22 17:02
79-00-5
1.0
1
07/20/22 17:02
79-01-6
1.0
1
07/20/22 17:02
75-69-4
1.0
1
07/20/22 17:02
96-18-4
2.0
1
07/20/22 17:02
108-05-4
1.0
1
07/20/22 17:02
75-01-4
1.0
1
07/20/22 17:02
1330-20-7
2.0
1
07/20/22 17:02
179601-23-1
1.0
1
07/20/22 17:02
95-47-6
70-130 1
70-130 1
70-130 1
2.0 1
REPORT OF LABORATORY ANALYSIS
07/20/22 17:02 460-00-4
07/20/22 17:02 17060-07-0
07/20/22 17:02 2037-26-5
07/20/22 14:38 123-91-1
Qual
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: SWP-1 Lab ID: 92615455001 Collected: 07/18/22 13:25 Received: 07/18/22 18:30 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
8260D MSV SIM Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
Surrogates
1,2-Dichloroethane-d4 (S)
111 %
70-130
1
07/20/22 14:38
17060-07-0 HS
Toluene-d8 (S)
111 %
70-130
1
07/20/22 14:38
2037-26-5
2320B Alkalinity
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
Alkalinity, Total as CaCO3
706 mg/L
5.0
1
07/27/22 21:57
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
660 mg/L
50.0
1
07/22/22 11:48
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Sulfate
2.7 mg/L
1.0
1
07/22/2215:04
14808-79-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
24.2 mg/L
1.0
1
07/27/2210:53
16887-00-6
5310B TOC
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
18.4 mg/L
1.0
1
07/22/22 03:42
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: SWP-2 Lab ID: 92615455002 Collected: 07/18/22 14:20 Received: 07/18/22 18:30 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
08/02/22 17:01
Collected By
S.Kline
1
08/02/22 17:01
Collected Date
7/18122
1
08/02/22 17:01
Collected Time
14:20
1
08/02/22 17:01
pH
8.68
Std. Units
1
08/02/22 17:01
Temperature
29.3
deg C
1
08/02/22 17:01
Specific Conductance
249.3
umhos/cm
1
08/02/22 17:01
Oxygen, Dissolved
7.71
mg/L
1
08/02/22 17:01
7782-44-7
REDOX
33.5
mV
1
08/02/22 17:01
Turbidity
11.64
NTU
1
08/02/22 17:01
Odor
None
1
08/02/22 17:01
Appearance
Solids
1
08/02/22 17:01
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2215:51
7440-36-0
Arsenic
ND
ug/L
10.0
1
07/27/22 13:03
07/28/2215:51
7440-38-2
Barium
72.7
ug/L
5.0
1
07/27/22 13:03
07/28/2215:51
7440-39-3
Cadmium
ND
ug/L
1.0
1
07/27/22 13:03
07/28/2215:51
7440-43-9
Calcium
22800
ug/L
100
1
07/27/22 13:03
07/28/2215:51
7440-70-2
Chromium
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2215:51
7440-47-3
Cobalt
13.1
ug/L
5.0
1
07/27/22 13:03
08/01/22 20:04
7440-48-4
Copper
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2215:51
7440-50-8
Lead
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2215:51
7439-92-1
Magnesium
5150
ug/L
100
1
07/27/22 13:03
07/28/2215:51
7439-95-4
Nickel
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2215:51
7440-02-0
Potassium
ND
ug/L
5000
1
07/27/22 13:03
08/01/22 20:04
7440-09-7
Selenium
ND
ug/L
10.0
1
07/27/22 13:03
07/28/2215:51
7782-49-2
Silver
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2215:51
7440-22-4
Sodium
9250
ug/L
5000
1
07/27/22 13:03
07/28/2215:51
7440-23-5
Thallium
ND
ug/L
10.0
1
07/27/22 13:03
08/01/22 20:04
7440-28-0
Vanadium
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2215:51
7440-62-2
Zinc
ND
ug/L
10.0
1
07/27/22 13:03
07/28/2215:51
7440-66-6
8270E RVE
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Acenaphthene
ND
ug/L
10.0
1
07/25/2216:52
07/26/2213:27
83-32-9
Acenaphthylene
ND
ug/L
10.0
1
07/25/2216:52
07/26/2213:27
208-96-8
Aniline
ND
ug/L
10.0
1
07/25/2216:52
07/26/2213:27
62-53-3
Anthracene
ND
ug/L
10.0
1
07/25/2216:52
07/26/2213:27
120-12-7
Benzo(a)anthracene
ND
ug/L
10.0
1
07/25/2216:52
07/26/2213:27
56-55-3
Benzo(a)pyrene
ND
ug/L
10.0
1
07/25/2216:52
07/26/2213:27
50-32-8
Benzo(b)fluoranthene
ND
ug/L
10.0
1
07/25/2216:52
07/26/2213:27
205-99-2
Benzo(g,h,i)perylene
ND
ug/L
10.0
1
07/25/2216:52
07/26/2213:27
191-24-2
Benzo(k)fluoranthene
ND
ug/L
10.0
1
07/25/2216:52
07/26/2213:27
207-08-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
Page 13 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: SWP-2 Lab ID: 92615455002 Collected: 07/18/22 14:20 Received: 07/18/22 18:30 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No
8270E RVE
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
Benzoic Acid
ND
ug/L
50.0
1
07/25/22 16:52
07/26/22 13:27
65-85-0
Benzyl alcohol
ND
ug/L
20.0
1
07/25/22 16:52
07/26/22 13:27
100-51-6
4-Bromophenylphenyl ether
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
101-55-3
Butylbenzylphthalate
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
85-68-7
4-ChIoro-3-methyl phenol
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
59-50-7
4-Chloroaniline
ND
ug/L
20.0
1
07/25/22 16:52
07/26/22 13:27
106-47-8
bis(2-Chloroethoxy)methane
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
111-44-4
2-Chloronaphthalene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
91-58-7
2-Chlorophenol
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
7005-72-3
Chrysene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
218-01-9
Dibenz(a,h)anthracene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
53-70-3
Dibenzofuran
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
132-64-9
1,2-Dichlorobenzene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
95-50-1
1,3-Dichlorobenzene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
541-73-1
1,4-Dichlorobenzene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
106-46-7
3,3'-Dichlorobenzidine
ND
ug/L
20.0
1
07/25/22 16:52
07/26/22 13:27
91-94-1
2,4-Dichlorophenol
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
120-83-2
Diethylphthalate
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
84-66-2
2,4-Dimethylphenol
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
105-67-9
Dimethylphthalate
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
131-11-3
Di-n-butylphthalate
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
20.0
1
07/25/22 16:52
07/26/22 13:27
534-52-1
2,4-Dinitrophenol
ND
ug/L
50.0
1
07/25/22 16:52
07/26/22 13:27
51-28-5
2,4-Dinitrotoluene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
121-14-2
2,6-Dinitrotoluene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
606-20-2
Di-n-octylphthalate
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
117-84-0
bis(2- Ethyl hexyl)phthalate
ND
ug/L
6.0
1
07/25/22 16:52
07/26/22 13:27
117-81-7
Fluoranthene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
206-44-0
Fluorene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
87-68-3
Hexachlorobenzene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
77-47-4
Hexachloroethane
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
67-72-1
Indeno(1,2,3-cd)pyrene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
193-39-5
Isophorone
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
78-59-1
1-Methylnaphthalene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
90-12-0
2-Methylnaphthalene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
91-57-6
2-Methylphenol(o-Cresol)
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
15831-10-4
Naphthalene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
91-20-3
2-Nitroaniline
ND
ug/L
20.0
1
07/25/22 16:52
07/26/22 13:27
88-74-4
3-Nitroaniline
ND
ug/L
20.0
1
07/25/22 16:52
07/26/22 13:27
99-09-2
4-Nitroaniline
ND
ug/L
20.0
1
07/25/22 16:52
07/26/22 13:27
100-01-6
Nitrobenzene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
98-95-3
REPORT OF LABORATORY ANALYSIS
Qual
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: SWP-2 Lab ID: 92615455002 Collected: 07/18/22 14:20 Received: 07/18/22 18:30 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
8270E RVE
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
2-Nitrophenol
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
88-75-5
4-Nitrophenol
ND
ug/L
50.0
1
07/25/22 16:52
07/26/22 13:27
100-02-7
v1
N-Nitrosodimethylamine
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
62-75-9
N-Nitroso-di-n-propylamine
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
86-30-6
2,2'-Oxybis(1-chloropropane)
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
108-60-1
Pentachlorophenol
ND
ug/L
20.0
1
07/25/22 16:52
07/26/22 13:27
87-86-5
Phenanthrene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
85-01-8
Phenol
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
108-95-2
Pyrene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
129-00-0
1,2,4-Trichlorobenzene
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
120-82-1
2,4,5-Trichlorophenol
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
10.0
1
07/25/22 16:52
07/26/22 13:27
88-06-2
Surrogates
Nitrobenzene-d5 (S)
51
%
10-144
1
07/25/22 16:52
07/26/22 13:27
4165-60-0
1g
2-Fluorobiphenyl (S)
24
%
10-130
1
07/25/22 16:52
07/26/22 13:27
321-60-8
Terphenyl-d14 (S)
93
%
34-163
1
07/25/22 16:52
07/26/22 13:27
1718-51-0
Phenol-d6 (S)
16
%
10-130
1
07/25/22 16:52
07/26/22 13:27
13127-88-3
2-Fluorophenol (S)
5
%
10-130
1
07/25/22 16:52
07/26/22 13:27
367-12-4
SO
2,4,6-Tribromophenol (S)
5
%
10-144
1
07/25/22 16:52
07/26/22 13:27
118-79-6
SO
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
07/20/22 17:21
67-64-1
Benzene
ND
ug/L
1.0
1
07/20/22 17:21
71-43-2
Bromobenzene
ND
ug/L
1.0
1
07/20/22 17:21
108-86-1
Bromochloromethane
ND
ug/L
1.0
1
07/20/22 17:21
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
07/20/22 17:21
75-27-4
Bromoform
ND
ug/L
1.0
1
07/20/22 17:21
75-25-2
Bromomethane
ND
ug/L
2.0
1
07/20/22 17:21
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
07/20/22 17:21
78-93-3
Carbon tetrachloride
ND
ug/L
1.0
1
07/20/22 17:21
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
07/20/22 17:21
108-90-7
Chloroethane
ND
ug/L
1.0
1
07/20/22 17:21
75-00-3
Chloroform
ND
ug/L
1.0
1
07/20/22 17:21
67-66-3
Chloromethane
ND
ug/L
1.0
1
07/20/22 17:21
74-87-3
2-Chlorotoluene
ND
ug/L
1.0
1
07/20/22 17:21
95-49-8
4-Chlorotoluene
ND
ug/L
1.0
1
07/20/22 17:21
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
07/20/22 17:21
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
07/20/22 17:21
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
07/20/22 17:21
106-93-4
Dibromomethane
ND
ug/L
1.0
1
07/20/22 17:21
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
07/20/22 17:21
95-50-1
1,3-Dichlorobenzene
ND
ug/L
1.0
1
07/20/22 17:21
541-73-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
07/20/22 17:21
106-46-7
Dichlorodifluoromethane
ND
ug/L
1.0
1
07/20/22 17:21
75-71-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: SWP-2
Parameters
8260D MSV Low Level Landfill
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
ANALYTICAL RESULTS
Lab ID: 92615455002 Collected: 07/18/22 14:20 Received: 07/18/22 18:30 Matrix: Water
Results Units
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
95 %
109 %
100 %
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
ND ug/L
PQL DF Prepared Analyzed CAS No
1.0
1
07/20/22 17:21
75-34-3
1.0
1
07/20/22 17:21
107-06-2
1.0
1
07/20/22 17:21
75-35-4
1.0
1
07/20/22 17:21
156-59-2
1.0
1
07/20/22 17:21
156-60-5
1.0
1
07/20/22 17:21
78-87-5
1.0
1
07/20/22 17:21
142-28-9
1.0
1
07/20/22 17:21
594-20-7
1.0
1
07/20/22 17:21
563-58-6
1.0
1
07/20/22 17:21
10061-01-5
1.0
1
07/20/22 17:21
10061-02-6
1.0
1
07/20/22 17:21
108-20-3
1.0
1
07/20/22 17:21
100-41-4
2.0
1
07/20/22 17:21
87-68-3
5.0
1
07/20/22 17:21
591-78-6
1.0
1
07/20/22 17:21
99-87-6
5.0
1
07/20/22 17:21
75-09-2
5.0
1
07/20/22 17:21
108-10-1
1.0
1
07/20/22 17:21
1634-04-4
1.0
1
07/20/22 17:21
91-20-3
1.0
1
07/20/22 17:21
100-42-5
1.0
1
07/20/22 17:21
630-20-6
1.0
1
07/20/22 17:21
79-34-5
1.0
1
07/20/22 17:21
127-18-4
1.0
1
07/20/22 17:21
108-88-3
1.0
1
07/20/22 17:21
87-61-6
1.0
1
07/20/22 17:21
120-82-1
1.0
1
07/20/22 17:21
71-55-6
1.0
1
07/20/22 17:21
79-00-5
1.0
1
07/20/22 17:21
79-01-6
1.0
1
07/20/22 17:21
75-69-4
1.0
1
07/20/22 17:21
96-18-4
2.0
1
07/20/22 17:21
108-05-4
1.0
1
07/20/22 17:21
75-01-4
1.0
1
07/20/22 17:21
1330-20-7
2.0
1
07/20/22 17:21
179601-23-1
1.0
1
07/20/22 17:21
95-47-6
70-130 1
70-130 1
70-130 1
2.0 1
REPORT OF LABORATORY ANALYSIS
07/20/22 17:21 460-00-4
07/20/22 17:21 17060-07-0
07/20/22 17:21 2037-26-5
07/20/22 14:58 123-91-1
Qual
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Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 132

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2225 Riverside Dr.
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ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: SWP-2
Lab ID: 92615455002 Collected: 07/18/22 14:20
Received: 07/18/22 18:30 Matrix: Water
Parameters
Results Units PQL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
Surrogates
1,2-Dichloroethane-d4 (S)
109 % 70-130
1
07/20/22 14:58
17060-07-0
Toluene-d8(S)
112 % 70-130
1
07/20/22 14:58
2037-26-5
2320B Alkalinity
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
Alkalinity, Total as CaCO3
102 mg/L 5.0
1
07/28/22 17:31
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
113 mg/L 25.0
1
07/22/22 11:49
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Sulfate
5.6 mg/L 1.0
1
07/22/2215:20
14808-79-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
2.6 mg/L 1.0
1
07/27/2210:56
16887-00-6
5310B TOC
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
ND mg/L 1.0
1
07/22/22 04:02
7440-44-0
Date: 10/24/2022 08:45 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 132

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2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: Q06V09 Lab ID: 92615455003 Collected: 07/19/22 12:00 Received: 07/19/22 16:15 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
08/04/22 09:03
Collected By
S.Warlick
1
08/04/22 09:03
Collected Date
7/19122
1
08/04/22 09:03
Collected Time
12:00
1
08/04/22 09:03
pH
6.4
Std. Units
1
08/04/22 09:03
Temperature
22.1
deg C
1
08/04/22 09:03
Static Water Level
28.21
feet
1
08/04/22 09:03
Specific Conductance
1358
umhos/cm
1
08/04/22 09:03
Oxygen, Dissolved
1.7
mg/L
1
08/04/22 09:03
7782-44-7
Total Well Depth
68.80
feet
1
08/04/22 09:03
REDOX
65.7
mV
1
08/04/22 09:03
Turbidity
15.0
NTU
1
08/04/22 09:03
Odor
No odor
1
08/04/22 09:03
Appearance
Clear
1
08/04/22 09:03
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2216:26
7440-36-0
Arsenic
ND
ug/L
10.0
1
07/27/22 13:03
07/28/2216:26
7440-38-2
Barium
266
ug/L
5.0
1
07/27/22 13:03
07/28/2216:26
7440-39-3
Cadmium
ND
ug/L
1.0
1
07/27/22 13:03
07/28/2216:26
7440-43-9
Calcium
168000
ug/L
500
5
07/27/22 13:03
08/01/2219:08
7440-70-2
Chromium
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2216:26
7440-47-3
Cobalt
18.0
ug/L
5.0
1
07/27/22 13:03
08/01/22 20:07
7440-48-4
Copper
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2216:26
7440-50-8
Lead
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2216:26
7439-92-1
Magnesium
79800
ug/L
500
5
07/27/22 13:03
08/01/2219:08
7439-95-4
Nickel
12.2
ug/L
5.0
1
07/27/22 13:03
07/28/2216:26
7440-02-0
Potassium
4760J
ug/L
5000
1
07/27/22 13:03
08/01/22 20:07
7440-09-7
Selenium
ND
ug/L
10.0
1
07/27/22 13:03
07/28/2216:26
7782-49-2
Silver
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2216:26
7440-22-4
Sodium
31600
ug/L
5000
1
07/27/22 13:03
07/28/2216:26
7440-23-5
Thallium
ND
ug/L
10.0
1
07/27/22 13:03
08/01/22 20:07
7440-28-0
Vanadium
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2216:26
7440-62-2
Zinc
ND
ug/L
10.0
1
07/27/22 13:03
07/28/2216:26
7440-66-6
8270E RVE
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Acenaphthene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
83-32-9
Acenaphthylene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
208-96-8
Aniline
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
62-53-3
Anthracene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
120-12-7
Benzo(a)anthracene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
56-55-3
Benzo(a)pyrene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
50-32-8 L1
Benzo(b)fluoranthene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
205-99-2 L1
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in
full,
Date: 10/24/2022 08:45 AM
without
the written consent of Pace Analytical Services, LLC.
Page 18 of 132

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2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: Q06V09 Lab ID: 92615455003 Collected: 07/19/22 12:00 Received: 07/19/22 16:15 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No
8270E RVE
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
Benzo(g,h,i)perylene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
191-24-2
Benzo(k)fluoranthene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
207-08-9
Benzoic Acid
ND
ug/L
50.0
1
07/26/22 13:58
07/27/22 09:31
65-85-0
Benzyl alcohol
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 09:31
100-51-6
4-Bromophenylphenyl ether
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
101-55-3
Butylbenzylphthalate
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
85-68-7
4-ChIoro-3-methyl phenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
59-50-7
4-Chloroaniline
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 09:31
106-47-8
bis(2-Chloroethoxy)methane
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
111-44-4
2-Chloronaphthalene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
91-58-7
2-Chlorophenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
7005-72-3
Chrysene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
218-01-9
Dibenz(a,h)anthracene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
53-70-3
Dibenzofuran
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
132-64-9
1,2-Dichlorobenzene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
95-50-1
1,3-Dichlorobenzene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
541-73-1
1,4-Dichlorobenzene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
106-46-7
3,3'-Dichlorobenzidine
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 09:31
91-94-1
2,4-Dichlorophenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
120-83-2
Diethylphthalate
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
84-66-2
2,4-Dimethylphenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
105-67-9
Dimethylphthalate
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
131-11-3
Di-n-butylphthalate
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 09:31
534-52-1
2,4-Dinitrophenol
ND
ug/L
50.0
1
07/26/22 13:58
07/27/22 09:31
51-28-5
2,4-Dinitrotoluene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
121-14-2
2,6-Dinitrotoluene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
606-20-2
Di-n-octylphthalate
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
117-84-0
bis(2- Ethyl hexyl)phthalate
ND
ug/L
6.0
1
07/26/22 13:58
07/27/22 09:31
117-81-7
Fluoranthene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
206-44-0
Fluorene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
87-68-3
Hexachlorobenzene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
77-47-4
Hexachloroethane
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
67-72-1
Indeno(1,2,3-cd)pyrene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
193-39-5
Isophorone
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
78-59-1
1-Methylnaphthalene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
90-12-0
2-Methylnaphthalene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
91-57-6
2-Methylphenol(o-Cresol)
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
15831-10-4
Naphthalene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
91-20-3
2-Nitroaniline
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 09:31
88-74-4
3-Nitroaniline
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 09:31
99-09-2
REPORT OF LABORATORY ANALYSIS
Qual
L1
L1
M1
L1
M1
M1
L1,M0
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Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 132

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2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: Q06V09 Lab ID: 92615455003 Collected: 07/19/22 12:00 Received: 07/19/22 16:15 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
8270E RVE
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
4-Nitroaniline
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 09:31
100-01-6
Nitrobenzene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
98-95-3
2-Nitrophenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
88-75-5
4-Nitrophenol
ND
ug/L
50.0
1
07/26/22 13:58
07/27/22 09:31
100-02-7
M1
N-Nitrosodimethylamine
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
62-75-9
N-Nitroso-di-n-propylamine
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
86-30-6
2,2'-Oxybis(1-chloropropane)
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
108-60-1
Pentachlorophenol
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 09:31
87-86-5
M1
Phenanthrene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
85-01-8
Phenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
108-95-2
Pyrene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
129-00-0
1,2,4-Trichlorobenzene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
120-82-1
2,4,5-Trichlorophenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 09:31
88-06-2
M1
Surrogates
Nitrobenzene-d5 (S)
76
%
10-144
1
07/26/22 13:58
07/27/22 09:31
4165-60-0
1g
2-Fluorobiphenyl (S)
56
%
10-130
1
07/26/22 13:58
07/27/22 09:31
321-60-8
Terphenyl-d14 (S)
121
%
34-163
1
07/26/22 13:58
07/27/22 09:31
1718-51-0
Phenol-d6 (S)
14
%
10-130
1
07/26/22 13:58
07/27/22 09:31
13127-88-3
2-Fluorophenol (S)
3
%
10-130
1
07/26/22 13:58
07/27/22 09:31
367-12-4
SO
2,4,6-Tribromophenol (S)
3
%
10-144
1
07/26/22 13:58
07/27/22 09:31
118-79-6
SO
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
07/20/22 17:40
67-64-1
Benzene
ND
ug/L
1.0
1
07/20/22 17:40
71-43-2
Bromobenzene
ND
ug/L
1.0
1
07/20/22 17:40
108-86-1
Bromochloromethane
ND
ug/L
1.0
1
07/20/22 17:40
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
07/20/22 17:40
75-27-4
Bromoform
ND
ug/L
1.0
1
07/20/22 17:40
75-25-2
Bromomethane
ND
ug/L
2.0
1
07/20/22 17:40
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
07/20/22 17:40
78-93-3
Carbon tetrachloride
ND
ug/L
1.0
1
07/20/22 17:40
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
07/20/22 17:40
108-90-7
Chloroethane
ND
ug/L
1.0
1
07/20/22 17:40
75-00-3
Chloroform
ND
ug/L
1.0
1
07/20/22 17:40
67-66-3
Chloromethane
ND
ug/L
1.0
1
07/20/22 17:40
74-87-3
2-Chlorotoluene
ND
ug/L
1.0
1
07/20/22 17:40
95-49-8
4-Chlorotoluene
ND
ug/L
1.0
1
07/20/22 17:40
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
07/20/22 17:40
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
07/20/22 17:40
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
07/20/22 17:40
106-93-4
Dibromomethane
ND
ug/L
1.0
1
07/20/22 17:40
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
07/20/22 17:40
95-50-1
1,3-Dichlorobenzene
ND
ug/L
1.0
1
07/20/22 17:40
541-73-1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 132

leAnalyiical
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: Q06V09 Lab ID: 92615455003 Collected: 07/19/22 12:00 Received: 07/19/22 16:15 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 10/24/2022 08:45 AM
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
98 %
104 %
101 %
1.0
1
07/20/22 17:40
106-46-7
1.0
1
07/20/22 17:40
75-71-8
1.0
1
07/20/22 17:40
75-34-3
1.0
1
07/20/22 17:40
107-06-2
1.0
1
07/20/22 17:40
75-35-4
1.0
1
07/20/22 17:40
156-59-2
1.0
1
07/20/22 17:40
156-60-5
1.0
1
07/20/22 17:40
78-87-5
1.0
1
07/20/22 17:40
142-28-9
1.0
1
07/20/22 17:40
594-20-7
1.0
1
07/20/22 17:40
563-58-6
1.0
1
07/20/22 17:40
10061-01-5
1.0
1
07/20/22 17:40
10061-02-6
1.0
1
07/20/22 17:40
108-20-3
1.0
1
07/20/22 17:40
100-41-4
2.0
1
07/20/22 17:40
87-68-3
5.0
1
07/20/22 17:40
591-78-6
1.0
1
07/20/22 17:40
99-87-6
5.0
1
07/20/22 17:40
75-09-2
5.0
1
07/20/22 17:40
108-10-1
1.0
1
07/20/22 17:40
1634-04-4
1.0
1
07/20/22 17:40
91-20-3
1.0
1
07/20/22 17:40
100-42-5
1.0
1
07/20/22 17:40
630-20-6
1.0
1
07/20/22 17:40
79-34-5
1.0
1
07/20/22 17:40
127-18-4
1.0
1
07/20/22 17:40
108-88-3
1.0
1
07/20/22 17:40
87-61-6
1.0
1
07/20/22 17:40
120-82-1
1.0
1
07/20/22 17:40
71-55-6
1.0
1
07/20/22 17:40
79-00-5
1.0
1
07/20/22 17:40
79-01-6
1.0
1
07/20/22 17:40
75-69-4
1.0
1
07/20/22 17:40
96-18-4
2.0
1
07/20/22 17:40
108-05-4
1.0
1
07/20/22 17:40
75-01-4
1.0
1
07/20/22 17:40
1330-20-7
2.0
1
07/20/22 17:40
179601-23-1
1.0
1
07/20/22 17:40
95-47-6
70-130 1
70-130 1
70-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
07/20/22 17:40 460-00-4
07/20/22 17:40 17060-07-0
07/20/22 17:40 2037-26-5
Page 21 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: Q06V09
Lab ID: 92615455003 Collected: 07/19/22 12:00
Received: 07/19/22 16:15 Matrix: Water
Parameters
Results Units PQL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND ug/L 2.0
1
07/20/22 15:17
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
108 % 70-130
1
07/20/22 15:17
17060-07-0
Toluene-d8 (S)
110 % 70-130
1
07/20/22 15:17
2037-26-5
2320B Alkalinity
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
Alkalinity, Total as CaCO3
756 mg/L 5.0
1
07/30/22 09:39
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
804 mg/L 50.0
1
07/22/22 17:40
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Sulfate
3.1 mg/L 1.0
1
07/25/22 03:50
14808-79-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
51.1 mg/L 3.0
3
07/29/2213:33
16887-00-6
5310B TOC
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
4.0 mg/L 1.0
1
07/25/22 23:09
7440-44-0
Date: 10/24/2022 08:45 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 22 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: Q06V10 Lab ID: 92615455004 Collected: 07/19/22 10:30 Received: 07/19/22 16:15 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
08/04/22 09:10
Collected By
S.Warlick
1
08/04/22 09:10
Collected Date
7/19122
1
08/04/22 09:10
Collected Time
10:30
1
08/04/22 09:10
pH
5.4
Std. Units
1
08/04/22 09:10
Temperature
19.3
deg C
1
08/04/22 09:10
Static Water Level
27.84
feet
1
08/04/22 09:10
Specific Conductance
45.4
umhos/cm
1
08/04/22 09:10
Oxygen, Dissolved
3.5
mg/L
1
08/04/22 09:10
7782-44-7
Total Well Depth
34.43
feet
1
08/04/22 09:10
REDOX
129.8
mV
1
08/04/22 09:10
Turbidity
58.9
NTU
1
08/04/22 09:10
Odor
None
1
08/04/22 09:10
Appearance
Cloudy
1
08/04/22 09:10
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2216:29
7440-36-0
Arsenic
6.2J
ug/L
10.0
1
07/27/22 13:03
07/28/2216:29
7440-38-2
Barium
22.2
ug/L
5.0
1
07/27/22 13:03
07/28/2216:29
7440-39-3
Cadmium
ND
ug/L
1.0
1
07/27/22 13:03
07/28/2216:29
7440-43-9
Calcium
2310
ug/L
100
1
07/27/22 13:03
07/28/2216:29
7440-70-2
Chromium
4.1J
ug/L
5.0
1
07/27/22 13:03
07/28/2216:29
7440-47-3
Cobalt
6.1
ug/L
5.0
1
07/27/22 13:03
08/01/22 20:11
7440-48-4
Copper
5.OJ
ug/L
5.0
1
07/27/22 13:03
07/28/2216:29
7440-50-8
Lead
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2216:29
7439-92-1
Magnesium
1070
ug/L
100
1
07/27/22 13:03
07/28/2216:29
7439-95-4
Nickel
4.3J
ug/L
5.0
1
07/27/22 13:03
07/28/2216:29
7440-02-0
Potassium
ND
ug/L
5000
1
07/27/22 13:03
08/01/22 20:11
7440-09-7
Selenium
ND
ug/L
10.0
1
07/27/22 13:03
07/28/2216:29
7782-49-2
Silver
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2216:29
7440-22-4
Sodium
1870J
ug/L
5000
1
07/27/22 13:03
07/28/2216:29
7440-23-5
Thallium
ND
ug/L
10.0
1
07/27/22 13:03
08/01/22 20:11
7440-28-0
Vanadium
4.2J
ug/L
5.0
1
07/27/22 13:03
07/28/2216:29
7440-62-2
Zinc
10.1
ug/L
10.0
1
07/27/22 13:03
07/28/2216:29
7440-66-6
8270E RVE
Analytical Method: EPA 8270E Preparation Method: EPA 351 OC
Pace Analytical Services - Charlotte
Acenaphthene
ND
ug/L
10.0
1
07/26/2213:58
07/27/2214:16
83-32-9
Acenaphthylene
ND
ug/L
10.0
1
07/26/2213:58
07/27/2214:16
208-96-8
Aniline
ND
ug/L
10.0
1
07/26/2213:58
07/27/2214:16
62-53-3
Anthracene
ND
ug/L
10.0
1
07/26/2213:58
07/27/2214:16
120-12-7
Benzo(a)anthracene
ND
ug/L
10.0
1
07/26/2213:58
07/27/2214:16
56-55-3
Benzo(a)pyrene
ND
ug/L
10.0
1
07/26/2213:58
07/27/2214:16
50-32-8 L1
Benzo(b)fluoranthene
ND
ug/L
10.0
1
07/26/2213:58
07/27/2214:16
205-99-2 L1
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except
in full,
Date: 10/24/2022 08:45 AM
without
the written consent of Pace Analytical Services,
LLC.
Page 23 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: Q06V10 Lab ID: 92615455004 Collected: 07/19/22 10:30 Received: 07/19/22 16:15 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No
8270E RVE
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
Benzo(g,h,i)perylene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
191-24-2
Benzo(k)fluoranthene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
207-08-9
Benzoic Acid
ND
ug/L
50.0
1
07/26/22 13:58
07/27/22 14:16
65-85-0
Benzyl alcohol
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 14:16
100-51-6
4-Bromophenylphenyl ether
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
101-55-3
Butylbenzylphthalate
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
85-68-7
4-ChIoro-3-methyl phenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
59-50-7
4-Chloroaniline
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 14:16
106-47-8
bis(2-Chloroethoxy)methane
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
111-44-4
2-Chloronaphthalene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
91-58-7
2-Chlorophenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
7005-72-3
Chrysene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
218-01-9
Dibenz(a,h)anthracene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
53-70-3
Dibenzofuran
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
132-64-9
1,2-Dichlorobenzene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
95-50-1
1,3-Dichlorobenzene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
541-73-1
1,4-Dichlorobenzene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
106-46-7
3,3'-Dichlorobenzidine
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 14:16
91-94-1
2,4-Dichlorophenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
120-83-2
Diethylphthalate
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
84-66-2
2,4-Dimethylphenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
105-67-9
Dimethylphthalate
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
131-11-3
Di-n-butylphthalate
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 14:16
534-52-1
2,4-Dinitrophenol
ND
ug/L
50.0
1
07/26/22 13:58
07/27/22 14:16
51-28-5
2,4-Dinitrotoluene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
121-14-2
2,6-Dinitrotoluene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
606-20-2
Di-n-octylphthalate
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
117-84-0
bis(2- Ethyl hexyl)phthalate
ND
ug/L
6.0
1
07/26/22 13:58
07/27/22 14:16
117-81-7
Fluoranthene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
206-44-0
Fluorene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
87-68-3
Hexachlorobenzene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
77-47-4
Hexachloroethane
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
67-72-1
Indeno(1,2,3-cd)pyrene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
193-39-5
Isophorone
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
78-59-1
1-Methylnaphthalene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
90-12-0
2-Methylnaphthalene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
91-57-6
2-Methylphenol(o-Cresol)
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
15831-10-4
Naphthalene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
91-20-3
2-Nitroaniline
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 14:16
88-74-4
3-Nitroaniline
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 14:16
99-09-2
REPORT OF LABORATORY ANALYSIS
L1
L1
L1
L1
Qual
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 24 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: Q06V10 Lab ID: 92615455004 Collected: 07/19/22 10:30 Received: 07/19/22 16:15 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
8270E RVE
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
4-Nitroaniline
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 14:16
100-01-6
Nitrobenzene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
98-95-3
2-Nitrophenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
88-75-5
4-Nitrophenol
ND
ug/L
50.0
1
07/26/22 13:58
07/27/22 14:16
100-02-7
N-Nitrosodimethylamine
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
62-75-9
N-Nitroso-di-n-propylamine
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
86-30-6
2,2'-Oxybis(1-chloropropane)
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
108-60-1
Pentachlorophenol
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 14:16
87-86-5
Phenanthrene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
85-01-8
Phenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
108-95-2
Pyrene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
129-00-0
1,2,4-Trichlorobenzene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
120-82-1
2,4,5-Trichlorophenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 14:16
88-06-2
Surrogates
Nitrobenzene-d5 (S)
69
%
10-144
1
07/26/22 13:58
07/27/22 14:16
4165-60-0
2-Fluorobiphenyl (S)
55
%
10-130
1
07/26/22 13:58
07/27/22 14:16
321-60-8
Terphenyl-d14 (S)
105
%
34-163
1
07/26/22 13:58
07/27/22 14:16
1718-51-0
Phenol-d6 (S)
36
%
10-130
1
07/26/22 13:58
07/27/22 14:16
13127-88-3
2-Fluorophenol (S)
31
%
10-130
1
07/26/22 13:58
07/27/22 14:16
367-12-4
2,4,6-Tribromophenol (S)
43
%
10-144
1
07/26/22 13:58
07/27/22 14:16
118-79-6
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
07/20/22 17:59
67-64-1
Benzene
ND
ug/L
1.0
1
07/20/22 17:59
71-43-2
Bromobenzene
ND
ug/L
1.0
1
07/20/22 17:59
108-86-1
Bromochloromethane
ND
ug/L
1.0
1
07/20/22 17:59
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
07/20/22 17:59
75-27-4
Bromoform
ND
ug/L
1.0
1
07/20/22 17:59
75-25-2
Bromomethane
ND
ug/L
2.0
1
07/20/22 17:59
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
07/20/22 17:59
78-93-3
Carbon tetrachloride
ND
ug/L
1.0
1
07/20/22 17:59
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
07/20/22 17:59
108-90-7
Chloroethane
ND
ug/L
1.0
1
07/20/22 17:59
75-00-3
Chloroform
ND
ug/L
1.0
1
07/20/22 17:59
67-66-3
Chloromethane
ND
ug/L
1.0
1
07/20/22 17:59
74-87-3
2-Chlorotoluene
ND
ug/L
1.0
1
07/20/22 17:59
95-49-8
4-Chlorotoluene
ND
ug/L
1.0
1
07/20/22 17:59
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
07/20/22 17:59
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
07/20/22 17:59
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
07/20/22 17:59
106-93-4
Dibromomethane
ND
ug/L
1.0
1
07/20/22 17:59
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
07/20/22 17:59
95-50-1
1,3-Dichlorobenzene
ND
ug/L
1.0
1
07/20/22 17:59
541-73-1
REPORT OF LABORATORY ANALYSIS
v1
v1
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 25 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: Q06V10 Lab ID: 92615455004 Collected: 07/19/22 10:30 Received: 07/19/22 16:15 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 10/24/2022 08:45 AM
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
94 %
106 %
102 %
1.0
1
07/20/22 17:59
106-46-7
1.0
1
07/20/22 17:59
75-71-8
1.0
1
07/20/22 17:59
75-34-3
1.0
1
07/20/22 17:59
107-06-2
1.0
1
07/20/22 17:59
75-35-4
1.0
1
07/20/22 17:59
156-59-2
1.0
1
07/20/22 17:59
156-60-5
1.0
1
07/20/22 17:59
78-87-5
1.0
1
07/20/22 17:59
142-28-9
1.0
1
07/20/22 17:59
594-20-7
1.0
1
07/20/22 17:59
563-58-6
1.0
1
07/20/22 17:59
10061-01-5
1.0
1
07/20/22 17:59
10061-02-6
1.0
1
07/20/22 17:59
108-20-3
1.0
1
07/20/22 17:59
100-41-4
2.0
1
07/20/22 17:59
87-68-3
5.0
1
07/20/22 17:59
591-78-6
1.0
1
07/20/22 17:59
99-87-6
5.0
1
07/20/22 17:59
75-09-2
5.0
1
07/20/22 17:59
108-10-1
1.0
1
07/20/22 17:59
1634-04-4
1.0
1
07/20/22 17:59
91-20-3
1.0
1
07/20/22 17:59
100-42-5
1.0
1
07/20/22 17:59
630-20-6
1.0
1
07/20/22 17:59
79-34-5
1.0
1
07/20/22 17:59
127-18-4
1.0
1
07/20/22 17:59
108-88-3
1.0
1
07/20/22 17:59
87-61-6
1.0
1
07/20/22 17:59
120-82-1
1.0
1
07/20/22 17:59
71-55-6
1.0
1
07/20/22 17:59
79-00-5
1.0
1
07/20/22 17:59
79-01-6
1.0
1
07/20/22 17:59
75-69-4
1.0
1
07/20/22 17:59
96-18-4
2.0
1
07/20/22 17:59
108-05-4
1.0
1
07/20/22 17:59
75-01-4
1.0
1
07/20/22 17:59
1330-20-7
2.0
1
07/20/22 17:59
179601-23-1
1.0
1
07/20/22 17:59
95-47-6
70-130 1
70-130 1
70-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
07/20/22 17:59 460-00-4
07/20/22 17:59 17060-07-0
07/20/22 17:59 2037-26-5
Page 26 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: Q06V10
Lab ID: 92615455004 Collected: 07/19/22 10:30
Received: 07/19/22 16:15 Matrix: Water
Parameters
Results Units PQL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND ug/L 2.0
1
07/20/22 15:37
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
107 % 70-130
1
07/20/22 15:37
17060-07-0
Toluene-d8 (S)
110 % 70-130
1
07/20/22 15:37
2037-26-5
2320B Alkalinity
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
Alkalinity, Total as CaCO3
10.1 mg/L 5.0
1
07/29/22 21:57
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
ND mg/L 25.0
1
07/22/22 17:40
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Sulfate
1.0 mg/L 1.0
1
07/25/22 04:05
14808-79-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
1.4 mg/L 1.0
1
07/29/2213:34
16887-00-6
5310B TOC
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
ND mg/L 1.0
1
07/25/22 23:28
7440-44-0
Date: 10/24/2022 08:45 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 27 of 132

leAnalyiical
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: Q06V11 Lab ID: 92615455005 Collected: 07/19/22 11:00 Received: 07/19/22 16:15 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
08/04/22 09:13
Collected By
S.Warlick
1
08/04/22 09:13
Collected Date
7/19122
1
08/04/22 09:13
Collected Time
11:00
1
08/04/22 09:13
pH
5.6
Std. Units
1
08/04/22 09:13
Temperature
19.0
deg C
1
08/04/22 09:13
Static Water Level
38.83
feet
1
08/04/22 09:13
Specific Conductance
78.1
umhos/cm
1
08/04/22 09:13
Oxygen, Dissolved
3.6
mg/L
1
08/04/22 09:13
7782-44-7
Total Well Depth
56.98
feet
1
08/04/22 09:13
REDOX
113.3
mV
1
08/04/22 09:13
Turbidity
37.5
NTU
1
08/04/22 09:13
Odor
None
1
08/04/22 09:13
Appearance
Cloudy
1
08/04/22 09:13
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2216:33
7440-36-0
Arsenic
ND
ug/L
10.0
1
07/27/22 13:03
07/28/2216:33
7440-38-2
Barium
8.5
ug/L
5.0
1
07/27/22 13:03
07/28/2216:33
7440-39-3
Cadmium
ND
ug/L
1.0
1
07/27/22 13:03
07/28/2216:33
7440-43-9
Calcium
4290
ug/L
100
1
07/27/22 13:03
07/28/2216:33
7440-70-2
Chromium
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2216:33
7440-47-3
Cobalt
ND
ug/L
5.0
1
07/27/22 13:03
08/01/22 20:14
7440-48-4
Copper
6.9
ug/L
5.0
1
07/27/22 13:03
07/28/2216:33
7440-50-8
Lead
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2216:33
7439-92-1
Magnesium
2080
ug/L
100
1
07/27/22 13:03
07/28/2216:33
7439-95-4
Nickel
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2216:33
7440-02-0
Potassium
ND
ug/L
5000
1
07/27/22 13:03
08/01/22 20:14
7440-09-7
Selenium
ND
ug/L
10.0
1
07/27/22 13:03
07/28/2216:33
7782-49-2
Silver
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2216:33
7440-22-4
Sodium
4470J
ug/L
5000
1
07/27/22 13:03
07/28/2216:33
7440-23-5
Thallium
ND
ug/L
10.0
1
07/27/22 13:03
08/01/22 20:14
7440-28-0
Vanadium
ND
ug/L
5.0
1
07/27/22 13:03
07/28/2216:33
7440-62-2
Zinc
26.4
ug/L
10.0
1
07/27/22 13:03
07/28/2216:33
7440-66-6
8270E RVE
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Acenaphthene
ND
ug/L
10.0
1
07/26/2213:58
07/27/2217:46
83-32-9
Acenaphthylene
ND
ug/L
10.0
1
07/26/2213:58
07/27/2217:46
208-96-8
Aniline
ND
ug/L
10.0
1
07/26/2213:58
07/27/2217:46
62-53-3
Anthracene
ND
ug/L
10.0
1
07/26/2213:58
07/27/2217:46
120-12-7
Benzo(a)anthracene
ND
ug/L
10.0
1
07/26/2213:58
07/27/2217:46
56-55-3
Benzo(a)pyrene
ND
ug/L
10.0
1
07/26/2213:58
07/27/2217:46
50-32-8 L1
Benzo(b)fluoranthene
ND
ug/L
10.0
1
07/26/2213:58
07/27/2217:46
205-99-2 L1
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except
in full,
Date: 10/24/2022 08:45 AM
without
the written consent of Pace Analytical Services,
LLC.
Page 28 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: Q06V11 Lab ID: 92615455005 Collected: 07/19/22 11:00 Received: 07/19/22 16:15 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No
8270E RVE
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
Benzo(g,h,i)perylene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
191-24-2
Benzo(k)fluoranthene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
207-08-9
Benzoic Acid
ND
ug/L
50.0
1
07/26/22 13:58
07/27/22 17:46
65-85-0
Benzyl alcohol
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 17:46
100-51-6
4-Bromophenylphenyl ether
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
101-55-3
Butylbenzylphthalate
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
85-68-7
4-ChIoro-3-methyl phenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
59-50-7
4-Chloroaniline
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 17:46
106-47-8
bis(2-Chloroethoxy)methane
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
111-44-4
2-Chloronaphthalene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
91-58-7
2-Chlorophenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
7005-72-3
Chrysene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
218-01-9
Dibenz(a,h)anthracene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
53-70-3
Dibenzofuran
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
132-64-9
1,2-Dichlorobenzene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
95-50-1
1,3-Dichlorobenzene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
541-73-1
1,4-Dichlorobenzene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
106-46-7
3,3'-Dichlorobenzidine
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 17:46
91-94-1
2,4-Dichlorophenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
120-83-2
Diethylphthalate
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
84-66-2
2,4-Dimethylphenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
105-67-9
Dimethylphthalate
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
131-11-3
Di-n-butylphthalate
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 17:46
534-52-1
2,4-Dinitrophenol
ND
ug/L
50.0
1
07/26/22 13:58
07/27/22 17:46
51-28-5
2,4-Dinitrotoluene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
121-14-2
2,6-Dinitrotoluene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
606-20-2
Di-n-octylphthalate
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
117-84-0
bis(2- Ethyl hexyl)phthalate
ND
ug/L
6.0
1
07/26/22 13:58
07/27/22 17:46
117-81-7
Fluoranthene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
206-44-0
Fluorene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
87-68-3
Hexachlorobenzene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
77-47-4
Hexachloroethane
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
67-72-1
Indeno(1,2,3-cd)pyrene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
193-39-5
Isophorone
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
78-59-1
1-Methylnaphthalene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
90-12-0
2-Methylnaphthalene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
91-57-6
2-Methylphenol(o-Cresol)
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
15831-10-4
Naphthalene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
91-20-3
2-Nitroaniline
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 17:46
88-74-4
3-Nitroaniline
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 17:46
99-09-2
REPORT OF LABORATORY ANALYSIS
L1
L1
L1
L1
Qual
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 29 of 132

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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: Q06V11 Lab ID: 92615455005 Collected: 07/19/22 11:00 Received: 07/19/22 16:15 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
8270E RVE
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
4-Nitroaniline
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 17:46
100-01-6
Nitrobenzene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
98-95-3
2-Nitrophenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
88-75-5
4-Nitrophenol
ND
ug/L
50.0
1
07/26/22 13:58
07/27/22 17:46
100-02-7
N-Nitrosodimethylamine
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
62-75-9
N-Nitroso-di-n-propylamine
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
86-30-6
2,2'-Oxybis(1-chloropropane)
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
108-60-1
Pentachlorophenol
ND
ug/L
20.0
1
07/26/22 13:58
07/27/22 17:46
87-86-5
Phenanthrene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
85-01-8
Phenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
108-95-2
Pyrene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
129-00-0
1,2,4-Trichlorobenzene
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
120-82-1
2,4,5-Trichlorophenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
10.0
1
07/26/22 13:58
07/27/22 17:46
88-06-2
Surrogates
Nitrobenzene-d5 (S)
74
%
10-144
1
07/26/22 13:58
07/27/22 17:46
4165-60-0
2-Fluorobiphenyl (S)
61
%
10-130
1
07/26/22 13:58
07/27/22 17:46
321-60-8
Terphenyl-d14 (S)
140
%
34-163
1
07/26/22 13:58
07/27/22 17:46
1718-51-0
Phenol-d6 (S)
49
%
10-130
1
07/26/22 13:58
07/27/22 17:46
13127-88-3
2-Fluorophenol (S)
59
%
10-130
1
07/26/22 13:58
07/27/22 17:46
367-12-4
2,4,6-Tribromophenol (S)
107
%
10-144
1
07/26/22 13:58
07/27/22 17:46
118-79-6
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
07/20/22 18:18
67-64-1
Benzene
ND
ug/L
1.0
1
07/20/22 18:18
71-43-2
Bromobenzene
ND
ug/L
1.0
1
07/20/22 18:18
108-86-1
Bromochloromethane
ND
ug/L
1.0
1
07/20/22 18:18
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
07/20/22 18:18
75-27-4
Bromoform
ND
ug/L
1.0
1
07/20/22 18:18
75-25-2
Bromomethane
ND
ug/L
2.0
1
07/20/22 18:18
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
07/20/22 18:18
78-93-3
Carbon tetrachloride
ND
ug/L
1.0
1
07/20/22 18:18
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
07/20/22 18:18
108-90-7
Chloroethane
ND
ug/L
1.0
1
07/20/22 18:18
75-00-3
Chloroform
ND
ug/L
1.0
1
07/20/22 18:18
67-66-3
Chloromethane
ND
ug/L
1.0
1
07/20/22 18:18
74-87-3
2-Chlorotoluene
ND
ug/L
1.0
1
07/20/22 18:18
95-49-8
4-Chlorotoluene
ND
ug/L
1.0
1
07/20/22 18:18
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
07/20/22 18:18
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
07/20/22 18:18
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
07/20/22 18:18
106-93-4
Dibromomethane
ND
ug/L
1.0
1
07/20/22 18:18
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
07/20/22 18:18
95-50-1
1,3-Dichlorobenzene
ND
ug/L
1.0
1
07/20/22 18:18
541-73-1
REPORT OF LABORATORY ANALYSIS
v1
v1
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 30 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: Q06V11 Lab ID: 92615455005 Collected: 07/19/22 11:00 Received: 07/19/22 16:15 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 10/24/2022 08:45 AM
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
103 %
108 %
97 %
1.0
1
07/20/22 18:18
106-46-7
1.0
1
07/20/22 18:18
75-71-8
1.0
1
07/20/22 18:18
75-34-3
1.0
1
07/20/22 18:18
107-06-2
1.0
1
07/20/22 18:18
75-35-4
1.0
1
07/20/22 18:18
156-59-2
1.0
1
07/20/22 18:18
156-60-5
1.0
1
07/20/22 18:18
78-87-5
1.0
1
07/20/22 18:18
142-28-9
1.0
1
07/20/22 18:18
594-20-7
1.0
1
07/20/22 18:18
563-58-6
1.0
1
07/20/22 18:18
10061-01-5
1.0
1
07/20/22 18:18
10061-02-6
1.0
1
07/20/22 18:18
108-20-3
1.0
1
07/20/22 18:18
100-41-4
2.0
1
07/20/22 18:18
87-68-3
5.0
1
07/20/22 18:18
591-78-6
1.0
1
07/20/22 18:18
99-87-6
5.0
1
07/20/22 18:18
75-09-2
5.0
1
07/20/22 18:18
108-10-1
1.0
1
07/20/22 18:18
1634-04-4
1.0
1
07/20/22 18:18
91-20-3
1.0
1
07/20/22 18:18
100-42-5
1.0
1
07/20/22 18:18
630-20-6
1.0
1
07/20/22 18:18
79-34-5
1.0
1
07/20/22 18:18
127-18-4
1.0
1
07/20/22 18:18
108-88-3
1.0
1
07/20/22 18:18
87-61-6
1.0
1
07/20/22 18:18
120-82-1
1.0
1
07/20/22 18:18
71-55-6
1.0
1
07/20/22 18:18
79-00-5
1.0
1
07/20/22 18:18
79-01-6
1.0
1
07/20/22 18:18
75-69-4
1.0
1
07/20/22 18:18
96-18-4
2.0
1
07/20/22 18:18
108-05-4
1.0
1
07/20/22 18:18
75-01-4
1.0
1
07/20/22 18:18
1330-20-7
2.0
1
07/20/22 18:18
179601-23-1
1.0
1
07/20/22 18:18
95-47-6
70-130 1
70-130 1
70-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
07/20/22 18:18 460-00-4
07/20/22 18:18 17060-07-0
07/20/22 18:18 2037-26-5
Page 31 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: Q06V11
Lab ID: 92615455005 Collected: 07/19/22 11:00
Received: 07/19/22 16:15 Matrix: Water
Parameters
Results Units PQL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND ug/L 2.0
1
07/20/22 15:57
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
105 % 70-130
1
07/20/22 15:57
17060-07-0 HS
Toluene-d8(S)
108 % 70-130
1
07/20/22 15:57
2037-26-5
2320B Alkalinity
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
Alkalinity, Total as CaCO3
23.2 mg/L 5.0
1
07/29/22 22:02
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
44.0 mg/L 25.0
1
07/22/22 17:40
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Sulfate
2.8 mg/L 1.0
1
07/25/22 04:21
14808-79-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
2.3 mg/L 1.0
1
07/29/2213:35
16887-00-6
5310B TOC
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
ND mg/L 1.0
1
07/25/22 23:46
7440-44-0
Date: 10/24/2022 08:45 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 32 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: TRIP BLANK
Parameters
8260D MSV Low Level Landfill
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
2-Hexanone
p-Isopropyltoluene
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Methyl-tert-butyl ether
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
ANALYTICAL RESULTS
Lab ID: 92615455007 Collected: 07/19/22 00:00 Received: 07/19/22 16:15 Matrix: Water
Results Units
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
PQL DF Prepared Analyzed CAS No. Qual
25.0
1
07/20/22 18:20
67-64-1
1.0
1
07/20/22 18:20
71-43-2
1.0
1
07/20/22 18:20
108-86-1
1.0
1
07/20/22 18:20
74-97-5
1.0
1
07/20/22 18:20
75-27-4
1.0
1
07/20/22 18:20
75-25-2
2.0
1
07/20/22 18:20
74-83-9
5.0
1
07/20/22 18:20
78-93-3
1.0
1
07/20/22 18:20
56-23-5
1.0
1
07/20/22 18:20
108-90-7
1.0
1
07/20/22 18:20
75-00-3
1.0
1
07/20/22 18:20
67-66-3
1.0
1
07/20/22 18:20
74-87-3
1.0
1
07/20/22 18:20
95-49-8
1.0
1
07/20/22 18:20
106-43-4
2.0
1
07/20/22 18:20
96-12-8
1.0
1
07/20/22 18:20
124-48-1
1.0
1
07/20/22 18:20
106-93-4
1.0
1
07/20/22 18:20
74-95-3
1.0
1
07/20/22 18:20
95-50-1
1.0
1
07/20/22 18:20
541-73-1
1.0
1
07/20/22 18:20
106-46-7
1.0
1
07/20/22 18:20
75-71-8
1.0
1
07/20/22 18:20
75-34-3
1.0
1
07/20/22 18:20
107-06-2
1.0
1
07/20/22 18:20
75-35-4
1.0
1
07/20/22 18:20
156-59-2
1.0
1
07/20/22 18:20
156-60-5
1.0
1
07/20/22 18:20
78-87-5
1.0
1
07/20/22 18:20
142-28-9
1.0
1
07/20/22 18:20
594-20-7
1.0
1
07/20/22 18:20
563-58-6
1.0
1
07/20/22 18:20
10061-01-5
1.0
1
07/20/22 18:20
10061-02-6
1.0
1
07/20/22 18:20
108-20-3
1.0
1
07/20/22 18:20
100-41-4
2.0
1
07/20/22 18:20
87-68-3
5.0
1
07/20/22 18:20
591-78-6 v1
1.0
1
07/20/22 18:20
99-87-6
5.0
1
07/20/22 18:20
75-09-2
5.0
1
07/20/22 18:20
108-10-1
1.0
1
07/20/22 18:20
1634-04-4
1.0
1
07/20/22 18:20
91-20-3
1.0
1
07/20/22 18:20
100-42-5
1.0
1
07/20/22 18:20
630-20-6
1.0
1
07/20/22 18:20
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 33 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Sludge LF 7/18
Pace Project No.: 92615455
Sample: TRIP BLANK Lab ID: 92615455007 Collected: 07/19/22 00:00 Received: 07/19/22 16:15 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 10/24/2022 08:45 AM
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
99
%
97
%
99
%
Analytical Method:
EPA 8260D Mod.
Pace Analytical
Services - Charlotte
ND
ug/L
95
%
96
%
1.0
1
07/20/22 18:20
127-18-4
1.0
1
07/20/22 18:20
108-88-3
1.0
1
07/20/22 18:20
87-61-6
1.0
1
07/20/22 18:20
120-82-1
1.0
1
07/20/22 18:20
71-55-6
1.0
1
07/20/22 18:20
79-00-5
1.0
1
07/20/22 18:20
79-01-6
1.0
1
07/20/22 18:20
75-69-4
1.0
1
07/20/22 18:20
96-18-4
2.0
1
07/20/22 18:20
108-05-4
1.0
1
07/20/22 18:20
75-01-4
1.0
1
07/20/22 18:20
1330-20-7
2.0
1
07/20/22 18:20
179601-23-1
1.0
1
07/20/22 18:20
95-47-6
70-130 1
70-130 1
70-130 1
70-130 1
70-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
07/20/22 18:20 460-00-4
07/20/22 18:20 17060-07-0
07/20/22 18:20 2037-26-5
07/21 /22 19:36 17060-07-0
07/21 /22 19:36 2037-26-5
Page 34 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
QC Batch: 713124 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92615455001, 92615455002, 92615455003, 92615455004, 92615455005
METHOD BLANK: 3718205 Matrix: Water
Associated Lab Samples: 92615455001, 92615455002, 92615455003, 92615455004, 92615455005
Blank Reporting
Parameter Units Result Limit Analyzed
Antimony
ug/L
ND
5.0
07/28/2214:55
Arsenic
ug/L
ND
10.0
07/28/2214:55
Barium
ug/L
ND
5.0
07/28/2214:55
Cadmium
ug/L
ND
1.0
07/28/2214:55
Calcium
ug/L
ND
100
07/28/2214:55
Chromium
ug/L
ND
5.0
07/28/2214:55
Cobalt
ug/L
ND
5.0
08/01/2219:12
Copper
ug/L
ND
5.0
07/28/2214:55
Lead
ug/L
ND
5.0
07/28/2214:55
Magnesium
ug/L
ND
100
07/28/2214:55
Nickel
ug/L
ND
5.0
07/28/2214:55
Potassium
ug/L
ND
5000
08/01/2219:12
Selenium
ug/L
ND
10.0
07/28/2214:55
Silver
ug/L
ND
5.0
07/28/2214:55
Sodium
ug/L
ND
5000
07/28/2214:55
Thallium
ug/L
ND
10.0
08/01/2219:12
Vanadium
ug/L
ND
5.0
07/28/2214:55
Zinc
ug/L
ND
10.0
07/28/2214:55
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3718206
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
485
97
80-120
Arsenic
ug/L
500
459
92
80-120
Barium
ug/L
500
463
93
80-120
Cadmium
ug/L
500
469
94
80-120
Calcium
ug/L
5000
4800
96
80-120
Chromium
ug/L
500
477
95
80-120
Cobalt
ug/L
500
476
95
80-120
Copper
ug/L
500
490
98
80-120
Lead
ug/L
500
482
96
80-120
Magnesium
ug/L
5000
4950
99
80-120
Nickel
ug/L
500
474
95
80-120
Potassium
ug/L
5000
4870J
97
80-120
Selenium
ug/L
500
472
94
80-120
Silver
ug/L
250
234
94
80-120
Sodium
ug/L
5000
4740J
95
80-120
Thallium
ug/L
500
476
95
80-120
Vanadium
ug/L
500
472
94
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 35 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
LABORATORY CONTROL SAMPLE: 3718206
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits
Zinc ug/L 500 451 90 80-120
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3718208
3718209
MS
MSD
92615545006
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Antimony
ug/L
ND
500
500
482
492
96
98
75-125
2
Arsenic
ug/L
5.OJ
500
500
486
498
96
99
75-125
2
Barium
ug/L
77.3
500
500
544
557
93
96
75-125
2
Cadmium
ug/L
0.63J
500
500
474
484
95
97
75-125
2
Calcium
ug/L
88500
5000
5000
92200
95100
75
132
75-125
3 M1
Chromium
ug/L
322
500
500
803
821
96
100
75-125
2
Cobalt
ug/L
20.5
500
500
493
503
95
97
75-125
2
Copper
ug/L
121
500
500
629
649
102
106
75-125
3
Lead
ug/L
ND
500
500
477
487
95
97
75-125
2
Magnesium
ug/L
8710
5000
5000
13700
14000
99
105
75-125
2
Nickel
ug/L
145
500
500
619
631
95
97
75-125
2
Potassium
ug/L
10400
5000
5000
15600
15900
103
110
75-125
2
Selenium
ug/L
ND
500
500
500
515
100
103
75-125
3
Silver
ug/L
ND
250
250
244
250
98
100
75-125
2
Sodium
ug/L
38500
5000
5000
42700
44100
83
112
75-125
3
Thallium
ug/L
ND
500
500
451
463
90
93
75-125
3
Vanadium
ug/L
22.1
500
500
512
523
98
100
75-125
2
Zinc
ug/L
429
500
500
878
890
90
92
75-125
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
Page 36 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
QC Batch: 711710 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92615455001, 92615455002, 92615455003, 92615455004, 92615455005
METHOD BLANK: 3711209 Matrix: Water
Associated Lab Samples: 92615455001, 92615455002, 92615455003, 92615455004, 92615455005
Blank Reporting
Parameter Units Result Limit Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
07/20/22 15:10
1,1,1-Trichloroethane
ug/L
ND
1.0
07/20/22 15:10
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
07/20/22 15:10
1,1,2-Trichloroethane
ug/L
ND
1.0
07/20/22 15:10
1,1-Dichloroethane
ug/L
ND
1.0
07/20/22 15:10
1,1-Dichloroethene
ug/L
ND
1.0
07/20/22 15:10
1,1-Dichloropropene
ug/L
ND
1.0
07/20/22 15:10
1,2,3-Trichlorobenzene
ug/L
ND
1.0
07/20/22 15:10
1,2,3-Trichloropropane
ug/L
ND
1.0
07/20/22 15:10
1,2,4-Trichlorobenzene
ug/L
ND
1.0
07/20/22 15:10
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
07/20/22 15:10
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
07/20/22 15:10
1,2-Dichlorobenzene
ug/L
ND
1.0
07/20/22 15:10
1,2-Dichloroethane
ug/L
ND
1.0
07/20/22 15:10
1,2-Dichloropropane
ug/L
ND
1.0
07/20/22 15:10
1,3-Dichlorobenzene
ug/L
ND
1.0
07/20/22 15:10
1,3-Dichloropropane
ug/L
ND
1.0
07/20/22 15:10
1,4-Dichlorobenzene
ug/L
ND
1.0
07/20/22 15:10
2,2-Dichloropropane
ug/L
ND
1.0
07/20/22 15:10
2-Butanone (MEK)
ug/L
ND
5.0
07/20/22 15:10
2-Chlorotoluene
ug/L
ND
1.0
07/20/22 15:10
2-Hexanone
ug/L
ND
5.0
07/20/22 15:10
4-Chlorotoluene
ug/L
ND
1.0
07/20/22 15:10
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
07/20/22 15:10
Acetone
ug/L
ND
25.0
07/20/22 15:10
Benzene
ug/L
ND
1.0
07/20/22 15:10
Bromobenzene
ug/L
ND
1.0
07/20/22 15:10
Bromochloromethane
ug/L
ND
1.0
07/20/22 15:10
Bromodichloromethane
ug/L
ND
1.0
07/20/22 15:10
Bromoform
ug/L
ND
1.0
07/20/22 15:10
Bromomethane
ug/L
ND
2.0
07/20/22 15:10
Carbon tetrachloride
ug/L
ND
1.0
07/20/22 15:10
Chlorobenzene
ug/L
ND
1.0
07/20/22 15:10
Chloroethane
ug/L
ND
1.0
07/20/22 15:10
Chloroform
ug/L
ND
1.0
07/20/22 15:10
Chloromethane
ug/L
ND
1.0
07/20/22 15:10
cis-1,2-Dichloroethene
ug/L
ND
1.0
07/20/22 15:10
cis-1,3-Dichloropropene
ug/L
ND
1.0
07/20/22 15:10
Dibromochloromethane
ug/L
ND
1.0
07/20/22 15:10
Dibromomethane
ug/L
ND
1.0
07/20/22 15:10
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 37 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
METHOD BLANK: 3711209 Matrix: Water
Associated Lab Samples: 92615455001, 92615455002, 92615455003, 92615455004, 92615455005
Blank Reporting
Parameter Units Result Limit Analyzed
Dichlorodifluoromethane
ug/L
ND
1.0
07/20/22 15:10
Diisopropyl ether
ug/L
ND
1.0
07/20/22 15:10
Ethylbenzene
ug/L
ND
1.0
07/20/22 15:10
Hexachloro-1,3-butadiene
ug/L
ND
2.0
07/20/22 15:10
m&p-Xylene
ug/L
ND
2.0
07/20/22 15:10
Methyl-tert-butyl ether
ug/L
ND
1.0
07/20/22 15:10
Methylene Chloride
ug/L
ND
5.0
07/20/22 15:10
Naphthalene
ug/L
ND
1.0
07/20/22 15:10
o-Xylene
ug/L
ND
1.0
07/20/22 15:10
p-Isopropyltoluene
ug/L
ND
1.0
07/20/22 15:10
Styrene
ug/L
ND
1.0
07/20/22 15:10
Tetrachloroethene
ug/L
ND
1.0
07/20/22 15:10
Toluene
ug/L
ND
1.0
07/20/22 15:10
trans-1,2-Dichloroethene
ug/L
ND
1.0
07/20/22 15:10
trans- 1,3-Dichloropropene
ug/L
ND
1.0
07/20/22 15:10
Trichloroethene
ug/L
ND
1.0
07/20/22 15:10
Trichlorofluoromethane
ug/L
ND
1.0
07/20/22 15:10
Vinyl acetate
ug/L
ND
2.0
07/20/22 15:10
Vinyl chloride
ug/L
ND
1.0
07/20/22 15:10
Xylene (Total)
ug/L
ND
1.0
07/20/22 15:10
1,2-Dichloroethane-d4 (S)
%
104
70-130
07/20/22 15:10
4-Bromofluorobenzene (S)
%
100
70-130
07/20/22 15:10
Toluene-d8 (S)
%
102
70-130
07/20/22 15:10
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3711210
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
50
52.5
105
70-130
1,1,1-Trichloroethane
ug/L
50
50.3
101
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
50.2
100
70-130
1,1,2-Trichloroethane
ug/L
50
50.9
102
70-130
1,1-Dichloroethane
ug/L
50
46.8
94
70-130
1,1-Dichloroethene
ug/L
50
48.1
96
70-132
1,1-Dichloropropene
ug/L
50
53.1
106
70-131
1,2,3-Trichlorobenzene
ug/L
50
50.3
101
70-134
1,2,3-Trichloropropane
ug/L
50
49.3
99
70-130
1,2,4-Trichlorobenzene
ug/L
50
51.2
102
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
56.4
113
70-132
1,2-Dibromoethane (EDB)
ug/L
50
53.4
107
70-130
1,2-Dichlorobenzene
ug/L
50
50.7
101
70-130
1,2-Dichloroethane
ug/L
50
49.2
98
70-130
1,2-Dichloropropane
ug/L
50
47.0
94
70-130
1,3-Dichlorobenzene
ug/L
50
48.8
98
70-130
1,3-Dichloropropane
ug/L
50
50.4
101
70-130
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 38 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
LABORATORY CONTROL SAMPLE:
Parameter
3711210
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,4-Dichlorobenzene
ug/L
50
47.9
96
70-130
2,2-Dichloropropane
ug/L
50
51.0
102
70-130
2-Butanone (MEK)
ug/L
100
111
111
70-133
2-Chlorotoluene
ug/L
50
46.9
94
70-130
2-Hexanone
ug/L
100
111
111
70-130
4-Chlorotoluene
ug/L
50
47.6
95
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
109
109
70-130
Acetone
ug/L
100
109
109
70-144
Benzene
ug/L
50
46.4
93
70-130
Bromobenzene
ug/L
50
49.6
99
70-130
Bromochloromethane
ug/L
50
49.5
99
70-130
Bromodichloromethane
ug/L
50
51.6
103
70-130
Bromoform
ug/L
50
50.9
102
70-131
Bromomethane
ug/L
50
49.1
98
30-177
Carbon tetrachloride
ug/L
50
50.4
101
70-130
Chlorobenzene
ug/L
50
49.8
100
70-130
Chloroethane
ug/L
50
47.3
95
46-131
Chloroform
ug/L
50
48.2
96
70-130
Chloromethane
ug/L
50
54.3
109
49-130
cis-1,2-Dichloroethene
ug/L
50
46.9
94
70-130
cis-1,3-Dichloropropene
ug/L
50
52.7
105
70-130
Dibromochloromethane
ug/L
50
57.7
115
70-130
Dibromomethane
ug/L
50
46.9
94
70-130
Dichlorodifluoromethane
ug/L
50
56.1
112
52-134
Diisopropyl ether
ug/L
50
48.4
97
70-131
Ethylbenzene
ug/L
50
47.8
96
70-130
Hexachloro-1,3-butadiene
ug/L
50
53.4
107
70-131
m&p-Xylene
ug/L
100
96.2
96
70-130
Methyl-tert-butyl ether
ug/L
50
52.6
105
70-130
Methylene Chloride
ug/L
50
43.3
87
68-130
Naphthalene
ug/L
50
53.6
107
70-133
o-Xylene
ug/L
50
49.3
99
70-130
p-Isopropyltoluene
ug/L
50
51.0
102
70-130
Styrene
ug/L
50
48.8
98
70-130
Tetrachloroethene
ug/L
50
49.3
99
70-130
Toluene
ug/L
50
45.9
92
70-130
trans-1,2-Dichloroethene
ug/L
50
50.2
100
70-130
trans- 1,3-Dichloropropene
ug/L
50
53.3
107
70-130
Trichloroethene
ug/L
50
52.2
104
70-130
Trichlorofluoromethane
ug/L
50
50.1
100
61-130
Vinyl acetate
ug/L
100
102
102
70-140
Vinyl chloride
ug/L
50
56.4
113
59-142
Xylene (Total)
ug/L
150
145
97
70-130
1,2-Dichloroethane-d4 (S)
%
99
70-130
4-Bromofluorobenzene (S)
%
96
70-130
Toluene-d8 (S)
%
99
70-130
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 39 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3711211
3711212
MS
MSD
92615403004
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
22.1
21.2
110
106
70-135
4
1,1,1-Trichloroethane
ug/L
ND
20
20
23.7
22.4
119
112
70-148
6
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
20.8
19.5
104
97
70-131
7
1,1,2-Trichloroethane
ug/L
ND
20
20
21.6
19.9
108
99
70-136
8
1,1-Dichloroethane
ug/L
ND
20
20
20.7
20.6
104
103
70-147
1
1,1-Dichloroethene
ug/L
ND
20
20
22.9
20.8
115
104
70-158
9
1,1-Dichloropropene
ug/L
ND
20
20
23.1
22.2
116
111
70-149
4
1,2,3-Trichlorobenzene
ug/L
ND
20
20
21.2
19.2
106
96
68-140
10
1,2,3-Trichloropropane
ug/L
ND
20
20
21.5
20.4
108
102
67-137
5
1,2,4-Trichlorobenzene
ug/L
ND
20
20
21.9
21.4
109
107
70-139
2
1,2-Dibromo-3-chloropropane
ug/L
ND
20
20
23.0
22.3
115
112
69-136
3
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
21.8
20.3
109
101
70-137
7
1,2-Dichlorobenzene
ug/L
ND
20
20
22.7
21.2
113
106
70-133
7
1,2-Dichloroethane
ug/L
ND
20
20
21.3
20.8
107
104
67-138
2
1,2-Dichloropropane
ug/L
ND
20
20
20.9
19.8
104
99
70-138
5
1,3-Dichlorobenzene
ug/L
ND
20
20
21.0
20.8
105
104
70-133
1
1,3-Dichloropropane
ug/L
ND
20
20
20.9
19.9
105
100
70-136
5
1,4-Dichlorobenzene
ug/L
ND
20
20
20.8
19.9
104
100
70-133
4
2,2-Dichloropropane
ug/L
ND
20
20
22.7
21.5
113
108
52-155
5
2-Butanone (MEK)
ug/L
ND
40
40
43.6
46.6
109
117
61-147
7
2-Chlorotoluene
ug/L
ND
20
20
20.9
20.1
104
101
70-141
4
2-Hexanone
ug/L
ND
40
40
45.4
44.1
114
110
67-139
3
4-Chlorotoluene
ug/L
ND
20
20
21.2
20.4
106
102
70-135
4
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
40
40.8
41.1
102
103
67-136
1
Acetone
ug/L
ND
40
40
45.9
46.5
115
116
55-159
1
Benzene
ug/L
ND
20
20
20.5
19.8
102
99
67-150
3
Bromobenzene
ug/L
ND
20
20
22.0
20.3
110
101
70-134
8
Bromochloromethane
ug/L
ND
20
20
24.3
21.9
121
109
70-146
10
Bromodichloromethane
ug/L
ND
20
20
21.9
21.0
110
105
70-138
5
Bromoform
ug/L
ND
20
20
19.5
17.9
97
90
57-138
8
Bromomethane
ug/L
ND
20
20
19.3
19.4
97
97
10-200
0
Carbon tetrachloride
ug/L
ND
20
20
23.7
21.6
118
108
70-147
9
Chlorobenzene
ug/L
ND
20
20
23.5
21.9
117
109
70-137
7
Chloroethane
ug/L
ND
20
20
21.5
19.5
108
98
51-166
10
Chloroform
ug/L
ND
20
20
21.2
21.9
106
109
70-144
3
Chloromethane
ug/L
ND
20
20
25.2
25.5
126
128
24-161
1
cis-1,2-Dichloroethene
ug/L
ND
20
20
21.1
20.1
106
101
67-148
5
cis-1,3-Dichloropropene
ug/L
ND
20
20
21.3
20.6
106
103
70-142
3
Dibromochloromethane
ug/L
ND
20
20
23.4
21.0
117
105
68-138
11
Dibromomethane
ug/L
ND
20
20
20.0
19.3
100
97
70-134
3
Dichlorodifluoromethane
ug/L
ND
20
20
23.6
23.9
118
119
43-155
1
Diisopropyl ether
ug/L
ND
20
20
19.9
20.2
99
101
65-146
1
Ethylbenzene
ug/L
ND
20
20
22.8
21.0
114
105
68-143
8
Hexachloro-1,3-butadiene
ug/L
ND
20
20
24.9
23.2
124
116
62-151
7
m&p-Xylene
ug/L
ND
40
40
44.9
43.1
112
108
53-157
4
Methyl-tert-butyl ether
ug/L
ND
20
20
21.3
19.9
107
99
59-156
7
Results presented on this
page are in
the units indicated by the
"Units" column except where
an alternate unit is presented
to the right
of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 40 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3711211
92615403004
Parameter Units Result
MS
Spike
Conc.
MSD
Spike
Conc.
3711212
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
Methylene Chloride
ug/L
ND
20
20
18.3
18.3
92
92
64-148
0
Naphthalene
ug/L
ND
20
20
22.2
21.3
111
107
57-150
4
o-Xylene
ug/L
ND
20
20
22.2
21.2
111
106
68-143
4
p-Isopropyltoluene
ug/L
ND
20
20
22.7
21.4
113
107
70-141
6
Styrene
ug/L
ND
20
20
22.1
21.3
110
106
70-136
4
Tetrachloroethene
ug/L
ND
20
20
22.5
20.9
112
105
70-139
7
Toluene
ug/L
ND
20
20
20.5
19.4
102
97
47-157
5
trans-1,2-Dichloroethene
ug/L
ND
20
20
22.0
21.4
110
107
70-149
3
trans- 1,3-Dichloropropene
ug/L
ND
20
20
21.9
20.4
109
102
70-138
7
Trichloroethene
ug/L
ND
20
20
22.9
21.8
115
109
70-149
5
Trichlorofluoromethane
ug/L
ND
20
20
24.9
24.5
124
123
61-154
1
Vinyl acetate
ug/L
ND
40
40
38.6
40.2
97
101
48-156
4
Vinyl chloride
ug/L
ND
20
20
25.7
25.3
129
127
55-172
2
Xylene (Total)
ug/L
ND
60
60
67.0
64.4
112
107
66-145
4
1,2-Dichloroethane-d4 (S)
%
104
106
70-130
4-Bromofluorobenzene (S)
%
100
100
70-130
Toluene-d8(S)
%
96
97
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
Page 41 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
QC Batch: 711793 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92615455007
METHOD BLANK: 3711753
Associated Lab Samples: 92615455007
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
07/20/22 17:25
1,1,1-Trichloroethane
ug/L
ND
1.0
07/20/22 17:25
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
07/20/22 17:25
1,1,2-Trichloroethane
ug/L
ND
1.0
07/20/22 17:25
1,1-Dichloroethane
ug/L
ND
1.0
07/20/22 17:25
1,1-Dichloroethene
ug/L
ND
1.0
07/20/22 17:25
1,1-Dichloropropene
ug/L
ND
1.0
07/20/22 17:25
1,2,3-Trichlorobenzene
ug/L
ND
1.0
07/20/22 17:25
1,2,3-Trichloropropane
ug/L
ND
1.0
07/20/22 17:25
1,2,4-Trichlorobenzene
ug/L
ND
1.0
07/20/22 17:25
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
07/20/22 17:25
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
07/20/22 17:25
1,2-Dichlorobenzene
ug/L
ND
1.0
07/20/22 17:25
1,2-Dichloroethane
ug/L
ND
1.0
07/20/22 17:25
1,2-Dichloropropane
ug/L
ND
1.0
07/20/22 17:25
1,3-Dichlorobenzene
ug/L
ND
1.0
07/20/22 17:25
1,3-Dichloropropane
ug/L
ND
1.0
07/20/22 17:25
1,4-Dichlorobenzene
ug/L
ND
1.0
07/20/22 17:25
2,2-Dichloropropane
ug/L
ND
1.0
07/20/22 17:25
2-Butanone (MEK)
ug/L
ND
5.0
07/20/22 17:25
2-Chlorotoluene
ug/L
ND
1.0
07/20/22 17:25
2-Hexanone
ug/L
ND
5.0
07/20/22 17:25
4-Chlorotoluene
ug/L
ND
1.0
07/20/22 17:25
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
07/20/22 17:25
Acetone
ug/L
ND
25.0
07/20/22 17:25
Benzene
ug/L
ND
1.0
07/20/22 17:25
Bromobenzene
ug/L
ND
1.0
07/20/22 17:25
Bromochloromethane
ug/L
ND
1.0
07/20/22 17:25
Bromodichloromethane
ug/L
ND
1.0
07/20/22 17:25
Bromoform
ug/L
ND
1.0
07/20/22 17:25
Bromomethane
ug/L
ND
2.0
07/20/22 17:25
Carbon tetrachloride
ug/L
ND
1.0
07/20/22 17:25
Chlorobenzene
ug/L
ND
1.0
07/20/22 17:25
Chloroethane
ug/L
ND
1.0
07/20/22 17:25
Chloroform
ug/L
ND
1.0
07/20/22 17:25
Chloromethane
ug/L
ND
1.0
07/20/22 17:25
cis-1,2-Dichloroethene
ug/L
ND
1.0
07/20/22 17:25
cis-1,3-Dichloropropene
ug/L
ND
1.0
07/20/22 17:25
Dibromochloromethane
ug/L
ND
1.0
07/20/22 17:25
Dibromomethane
ug/L
ND
1.0
07/20/22 17:25
v1
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 42 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
METHOD BLANK: 3711753
Associated Lab Samples: 92615455007
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
Dichlorodifluoromethane
ug/L
ND
1.0
07/20/22 17:25
Diisopropyl ether
ug/L
ND
1.0
07/20/22 17:25
Ethylbenzene
ug/L
ND
1.0
07/20/22 17:25
Hexachloro-1,3-butadiene
ug/L
ND
2.0
07/20/22 17:25
m&p-Xylene
ug/L
ND
2.0
07/20/22 17:25
Methyl-tert-butyl ether
ug/L
ND
1.0
07/20/22 17:25
Methylene Chloride
ug/L
2.5J
5.0
07/20/22 17:25
Naphthalene
ug/L
ND
1.0
07/20/22 17:25
o-Xylene
ug/L
ND
1.0
07/20/22 17:25
p-Isopropyltoluene
ug/L
ND
1.0
07/20/22 17:25
Styrene
ug/L
ND
1.0
07/20/22 17:25
Tetrachloroethene
ug/L
ND
1.0
07/20/22 17:25
Toluene
ug/L
ND
1.0
07/20/22 17:25
trans-1,2-Dichloroethene
ug/L
ND
1.0
07/20/22 17:25
trans- 1,3-Dichloropropene
ug/L
ND
1.0
07/20/22 17:25
Trichloroethene
ug/L
ND
1.0
07/20/22 17:25
Trichlorofluoromethane
ug/L
ND
1.0
07/20/22 17:25
Vinyl acetate
ug/L
ND
2.0
07/20/22 17:25
Vinyl chloride
ug/L
ND
1.0
07/20/22 17:25
Xylene (Total)
ug/L
ND
1.0
07/20/22 17:25
1,2-Dichloroethane-d4 (S)
%
97
70-130
07/20/22 17:25
4-Bromofluorobenzene (S)
%
100
70-130
07/20/22 17:25
Toluene-d8 (S)
%
98
70-130
07/20/22 17:25
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3711754
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
50
55.3
111
70-130
1,1,1-Trichloroethane
ug/L
50
52.2
104
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
56.8
114
70-130
1,1,2-Trichloroethane
ug/L
50
53.6
107
70-130
1,1-Dichloroethane
ug/L
50
51.5
103
70-130
1,1-Dichloroethene
ug/L
50
52.5
105
70-132
1,1-Dichloropropene
ug/L
50
54.2
108
70-131
1,2,3-Trichlorobenzene
ug/L
50
54.9
110
70-134
1,2,3-Trichloropropane
ug/L
50
55.2
110
70-130
1,2,4-Trichlorobenzene
ug/L
50
54.4
109
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
57.8
116
70-132
1,2-Dibromoethane (EDB)
ug/L
50
54.2
108
70-130
1,2-Dichlorobenzene
ug/L
50
54.5
109
70-130
1,2-Dichloroethane
ug/L
50
49.3
99
70-130
1,2-Dichloropropane
ug/L
50
53.8
108
70-130
1,3-Dichlorobenzene
ug/L
50
53.8
108
70-130
1,3-Dichloropropane
ug/L
50
52.9
106
70-130
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 43 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
LABORATORY CONTROL SAMPLE:
Parameter
3711754
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,4-Dichlorobenzene
ug/L
50
52.8
106
70-130
2,2-Dichloropropane
ug/L
50
49.9
100
70-130
2-Butanone (MEK)
ug/L
100
110
110
70-133
2-Chlorotoluene
ug/L
50
53.9
108
70-130
2-Hexanone
ug/L
100
123
123
70-130 v1
4-Chlorotoluene
ug/L
50
53.9
108
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
117
117
70-130
Acetone
ug/L
100
106
106
70-144
Benzene
ug/L
50
50.7
101
70-130
Bromobenzene
ug/L
50
54.7
109
70-130
Bromochloromethane
ug/L
50
50.5
101
70-130
Bromodichloromethane
ug/L
50
52.7
105
70-130
Bromoform
ug/L
50
57.5
115
70-131
Bromomethane
ug/L
50
51.9
104
30-177
Carbon tetrachloride
ug/L
50
51.9
104
70-130
Chlorobenzene
ug/L
50
53.4
107
70-130
Chloroethane
ug/L
50
44.9
90
46-131
Chloroform
ug/L
50
49.4
99
70-130
Chloromethane
ug/L
50
57.7
115
49-130
cis-1,2-Dichloroethene
ug/L
50
52.0
104
70-130
cis-1,3-Dichloropropene
ug/L
50
54.3
109
70-130
Dibromochloromethane
ug/L
50
54.7
109
70-130
Dibromomethane
ug/L
50
53.5
107
70-130
Dichlorodifluoromethane
ug/L
50
52.0
104
52-134
Diisopropyl ether
ug/L
50
55.1
110
70-131
Ethylbenzene
ug/L
50
53.3
107
70-130
Hexachloro-1,3-butadiene
ug/L
50
53.0
106
70-131
m&p-Xylene
ug/L
100
107
107
70-130
Methyl-tert-butyl ether
ug/L
50
53.4
107
70-130
Methylene Chloride
ug/L
50
55.9
112
68-130
Naphthalene
ug/L
50
59.6
119
70-133
o-Xylene
ug/L
50
55.7
111
70-130
p-Isopropyltoluene
ug/L
50
54.9
110
70-130
Styrene
ug/L
50
56.2
112
70-130
Tetrachloroethene
ug/L
50
53.5
107
70-130
Toluene
ug/L
50
52.0
104
70-130
trans-1,2-Dichloroethene
ug/L
50
53.1
106
70-130
trans- 1,3-Dichloropropene
ug/L
50
54.4
109
70-130
Trichloroethene
ug/L
50
53.4
107
70-130
Trichlorofluoromethane
ug/L
50
48.0
96
61-130
Vinyl acetate
ug/L
100
115
115
70-140
Vinyl chloride
ug/L
50
56.8
114
59-142
Xylene (Total)
ug/L
150
163
109
70-130
1,2-Dichloroethane-d4 (S)
%
98
70-130
4-Bromofluorobenzene (S)
%
104
70-130
Toluene-d8 (S)
%
99
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 44 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3711755
3711756
MS
MSD
92615403006
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
23.1
23.6
115
118
70-135
2
1,1,1-Trichloroethane
ug/L
ND
20
20
22.3
23.0
112
115
70-148
3
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
21.3
22.1
107
111
70-131
4
1,1,2-Trichloroethane
ug/L
ND
20
20
22.3
23.3
111
116
70-136
4
1,1-Dichloroethane
ug/L
ND
20
20
21.3
21.0
106
105
70-147
1
1,1-Dichloroethene
ug/L
ND
20
20
21.3
22.0
107
110
70-158
3
1,1-Dichloropropene
ug/L
ND
20
20
23.2
23.8
116
119
70-149
3
1,2,3-Trichlorobenzene
ug/L
ND
20
20
23.1
23.7
115
118
68-140
3
1,2,3-Trichloropropane
ug/L
ND
20
20
20.3
20.7
102
103
67-137
2
1,2,4-Trichlorobenzene
ug/L
ND
20
20
22.9
23.3
114
116
70-139
2
1,2-Dibromo-3-chloropropane
ug/L
ND
20
20
21.1
22.0
105
110
69-136
4
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
22.0
23.0
110
115
70-137
5
1,2-Dichlorobenzene
ug/L
ND
20
20
22.8
24.2
114
121
70-133
6
1,2-Dichloroethane
ug/L
ND
20
20
20.9
21.3
104
107
67-138
2
1,2-Dichloropropane
ug/L
ND
20
20
20.9
21.2
104
106
70-138
2
1,3-Dichlorobenzene
ug/L
ND
20
20
22.6
23.5
113
118
70-133
4
1,3-Dichloropropane
ug/L
ND
20
20
21.5
22.4
108
112
70-136
4
1,4-Dichlorobenzene
ug/L
0.36J
20
20
22.4
24.0
110
118
70-133
7
2,2-Dichloropropane
ug/L
ND
20
20
22.0
22.3
110
112
52-155
1
2-Butanone (MEK)
ug/L
ND
40
40
44.7
43.9
112
110
61-147
2
2-Chlorotoluene
ug/L
ND
20
20
22.1
23.2
111
116
70-141
5
2-Hexanone
ug/L
ND
40
40
44.3
45.3
111
113
67-139
2
4-Chlorotoluene
ug/L
ND
20
20
22.0
23.2
110
116
70-135
5
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
40
41.2
42.5
103
106
67-136
3
Acetone
ug/L
ND
40
40
43.3
43.2
108
108
55-159
0
Benzene
ug/L
ND
20
20
20.6
21.5
103
108
67-150
4
Bromobenzene
ug/L
ND
20
20
21.6
23.0
108
115
70-134
6
Bromochloromethane
ug/L
ND
20
20
23.5
24.0
117
120
70-146
2
Bromodichloromethane
ug/L
ND
20
20
21.2
22.2
106
111
70-138
5
Bromoform
ug/L
ND
20
20
20.2
20.9
101
104
57-138
3
Bromomethane
ug/L
ND
20
20
12.3
14.1
61
71
10-200
14 v3
Carbon tetrachloride
ug/L
ND
20
20
23.4
24.3
117
122
70-147
4
Chlorobenzene
ug/L
1.6
20
20
23.8
24.6
111
115
70-137
3
Chloroethane
ug/L
ND
20
20
25.2
26.1
126
131
51-166
4
Chloroform
ug/L
ND
20
20
20.2
21.2
101
106
70-144
5
Chloromethane
ug/L
ND
20
20
18.8
18.9
94
95
24-161
1
cis-1,2-Dichloroethene
ug/L
ND
20
20
20.4
21.8
102
109
67-148
6
cis-1,3-Dichloropropene
ug/L
ND
20
20
19.4
21.4
97
107
70-142
10
Dibromochloromethane
ug/L
ND
20
20
21.4
21.4
107
107
68-138
0
Dibromomethane
ug/L
ND
20
20
21.6
22.9
108
114
70-134
6
Dichlorodifluoromethane
ug/L
ND
20
20
25.5
26.2
128
131
43-155
3
Diisopropyl ether
ug/L
ND
20
20
20.4
21.2
102
106
65-146
4
Ethylbenzene
ug/L
ND
20
20
22.1
23.1
110
115
68-143
4
Hexachloro-1,3-butadiene
ug/L
ND
20
20
24.7
26.2
124
131
62-151
6
m&p-Xylene
ug/L
ND
40
40
45.6
46.2
114
115
53-157
1
Methyl-tert-butyl ether
ug/L
ND
20
20
20.1
21.2
100
106
59-156
6
Results presented on this
page are in
the units indicated by the
"Units" column except where
an alternate unit is presented
to the right
of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 45 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3711755
MS
92615403006 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3711756
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
Methylene Chloride
ug/L
ND
20
20
15.4
16.6
77
83
64-148
8
Naphthalene
ug/L
1.1
20
20
24.5
25.7
117
123
57-150
4
o-Xylene
ug/L
ND
20
20
23.1
24.1
115
120
68-143
4
p-Isopropyltoluene
ug/L
ND
20
20
23.3
25.1
117
125
70-141
7
Styrene
ug/L
ND
20
20
22.0
23.1
110
116
70-136
5
Tetrachloroethene
ug/L
ND
20
20
22.9
23.5
115
118
70-139
2
Toluene
ug/L
ND
20
20
21.4
22.3
107
111
47-157
4
trans-1,2-Dichloroethene
ug/L
ND
20
20
21.1
22.6
106
113
70-149
7
trans- 1,3-Dichloropropene
ug/L
ND
20
20
19.8
20.8
99
104
70-138
5
Trichloroethene
ug/L
ND
20
20
22.6
24.4
113
122
70-149
8
Trichlorofluoromethane
ug/L
ND
20
20
21.6
21.9
108
109
61-154
1
Vinyl acetate
ug/L
ND
40
40
40.5
41.8
101
105
48-156
3
Vinyl chloride
ug/L
ND
20
20
24.4
24.8
122
124
55-172
1
Xylene (Total)
ug/L
ND
60
60
68.7
70.2
114
117
66-145
2
1,2-Dichloroethane-d4 (S)
%
91
91
70-130
4-Bromofluorobenzene (S)
%
99
99
70-130
Toluene-d8(S)
%
98
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
Page 46 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
QC Batch: 711732 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92615455001, 92615455002, 92615455003, 92615455004, 92615455005
METHOD BLANK: 3711349
Matrix:
Water
Associated Lab Samples:
92615455001, 92615455002, 92615455003, 92615455004, 92615455005
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
07/20/22 13:01
1,2-Dichloroethane-d4 (S)
%
110
70-130
07/20/22 13:01
Toluene-d8 (S)
%
113
70-130
07/20/22 13:01
LABORATORY CONTROL SAMPLE: 3711350
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 18.4 92 70-130
1,2-Dichloroethane-d4 (S) % 111 70-130
Toluene-d8(S) % 113 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3711351
3711352
MS
MSD
92615403001 Spike
Spike MS
MSD MS
MSD
% Rec
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 18.9
17.8 94
89
63-136 6
1,2-Dichloroethane-d4 (S)
%
100
98
70-130
Toluene-d8(S)
%
101
100
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
Page 47 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
QC Batch: 712183 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92615455007
METHOD BLANK: 3713815
Matrix:
Water
Associated Lab Samples: 92615455007
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
07/21/22 18:57
1,2-Dichloroethane-d4 (S)
%
95
70-130
07/21/22 18:57
Toluene-d8 (S)
%
97
70-130
07/21/22 18:57
LABORATORY CONTROL SAMPLE: 3713816
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 18.6 93 70-130
1,2-Dichloroethane-d4 (S) % 96 70-130
Toluene-d8 (S) % 97 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3713817
3713818
MS
MSD
92616147013 Spike
Spike MS
MSD MS
MSD
% Rec
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L <0.86 20
20 19.6
19.4 98
97
63-136 1
1,2-Dichloroethane-d4 (S)
%
95
94
70-130
Toluene-d8(S)
%
94
93
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
Page 48 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
QC Batch: 712603 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E Water MSSV RVE
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92615455001, 92615455002
METHOD BLANK: 3715397
Associated Lab Samples: 92615455001, 92615455002
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,2,4-Trichlorobenzene
ug/L
ND
10.0
07/26/22 08:56
1,2-Dichlorobenzene
ug/L
ND
10.0
07/26/22 08:56
1,3-Dichlorobenzene
ug/L
ND
10.0
07/26/22 08:56
1,4-Dichlorobenzene
ug/L
ND
10.0
07/26/22 08:56
1-Methylnaphthalene
ug/L
ND
10.0
07/26/22 08:56
2,2'-Oxybis(1-chloropropane)
ug/L
ND
10.0
07/26/22 08:56
2,4,5-Trichlorophenol
ug/L
ND
10.0
07/26/22 08:56
2,4,6-Trichlorophenol
ug/L
ND
10.0
07/26/22 08:56
2,4-Dichlorophenol
ug/L
ND
10.0
07/26/22 08:56
2,4-Dimethylphenol
ug/L
ND
10.0
07/26/22 08:56
2,4-Dinitrophenol
ug/L
ND
50.0
07/26/22 08:56
2,4-Dinitrotoluene
ug/L
ND
10.0
07/26/22 08:56
2,6-Dinitrotoluene
ug/L
ND
10.0
07/26/22 08:56
2-Chloronaphthalene
ug/L
ND
10.0
07/26/22 08:56
2-Chlorophenol
ug/L
ND
10.0
07/26/22 08:56
2-Methylnaphthalene
ug/L
ND
10.0
07/26/22 08:56
2-Methylphenol(o-Cresol)
ug/L
ND
10.0
07/26/22 08:56
2-Nitroaniline
ug/L
ND
20.0
07/26/22 08:56
2-Nitrophenol
ug/L
ND
10.0
07/26/22 08:56
3&4-Methyl phenol (m&p Cresol)
ug/L
ND
10.0
07/26/22 08:56
3,3'-Dichlorobenzidine
ug/L
ND
20.0
07/26/22 08:56
3-Nitroaniline
ug/L
ND
20.0
07/26/22 08:56
4,6-Dinitro-2-methyl phenol
ug/L
ND
20.0
07/26/22 08:56
4-Bromophenylphenyl ether
ug/L
ND
10.0
07/26/22 08:56
4-ChIoro-3-methyl phenol
ug/L
ND
10.0
07/26/22 08:56
4-Chloroaniline
ug/L
ND
20.0
07/26/22 08:56
4-Chlorophenylphenyl ether
ug/L
ND
10.0
07/26/22 08:56
4-Nitroaniline
ug/L
ND
20.0
07/26/22 08:56
4-Nitrophenol
ug/L
ND
50.0
07/26/22 08:56 v1
Acenaphthene
ug/L
ND
10.0
07/26/22 08:56
Acenaphthylene
ug/L
ND
10.0
07/26/22 08:56
Aniline
ug/L
ND
10.0
07/26/22 08:56
Anthracene
ug/L
ND
10.0
07/26/22 08:56
Benzo(a)anthracene
ug/L
ND
10.0
07/26/22 08:56
Benzo(a)pyrene
ug/L
ND
10.0
07/26/22 08:56
Benzo(b)fluoranthene
ug/L
ND
10.0
07/26/22 08:56
Benzo(g,h,i)perylene
ug/L
ND
10.0
07/26/22 08:56
Benzo(k)fluoranthene
ug/L
ND
10.0
07/26/22 08:56
Benzoic Acid
ug/L
ND
50.0
07/26/22 08:56
Benzyl alcohol
ug/L
ND
20.0
07/26/22 08:56
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 49 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
METHOD BLANK: 3715397
Associated Lab Samples: 92615455001, 92615455002
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
bis(2-Chloroethoxy)methane
ug/L
ND
10.0
07/26/22 08:56
bis(2-Chloroethyl) ether
ug/L
ND
10.0
07/26/22 08:56
bis(2-Ethylhexyl)phthalate
ug/L
ND
6.0
07/26/22 08:56
Butylbenzylphthalate
ug/L
ND
10.0
07/26/22 08:56
Chrysene
ug/L
ND
10.0
07/26/22 08:56
Di-n-butylphthalate
ug/L
ND
10.0
07/26/22 08:56
Di-n-octylphthalate
ug/L
ND
10.0
07/26/22 08:56
Dibenz(a,h)anthracene
ug/L
ND
10.0
07/26/22 08:56
Dibenzofuran
ug/L
ND
10.0
07/26/22 08:56
Diethylphthalate
ug/L
ND
10.0
07/26/22 08:56
Dimethylphthalate
ug/L
ND
10.0
07/26/22 08:56
Fluoranthene
ug/L
ND
10.0
07/26/22 08:56
Fluorene
ug/L
ND
10.0
07/26/22 08:56
Hexachloro-1,3-butadiene
ug/L
ND
10.0
07/26/22 08:56
Hexachlorobenzene
ug/L
ND
10.0
07/26/22 08:56
Hexachlorocyclopentadiene
ug/L
ND
10.0
07/26/22 08:56
Hexachloroethane
ug/L
ND
10.0
07/26/22 08:56
Indeno(1,2,3-cd)pyrene
ug/L
ND
10.0
07/26/22 08:56
Isophorone
ug/L
ND
10.0
07/26/22 08:56
N-Nitroso-di-n-propylamine
ug/L
ND
10.0
07/26/22 08:56
N-Nitrosodimethylamine
ug/L
ND
10.0
07/26/22 08:56
N-Nitrosodiphenylamine
ug/L
ND
10.0
07/26/22 08:56
Naphthalene
ug/L
ND
10.0
07/26/22 08:56
Nitrobenzene
ug/L
ND
10.0
07/26/22 08:56
Pentachlorophenol
ug/L
ND
20.0
07/26/22 08:56
Phenanthrene
ug/L
ND
10.0
07/26/22 08:56
Phenol
ug/L
ND
10.0
07/26/22 08:56
Pyrene
ug/L
ND
10.0
07/26/22 08:56
2,4,6-Tribromophenol (S)
%
89
10-144
07/26/22 08:56
2-Fluorobiphenyl (S)
%
77
10-130
07/26/22 08:56
2-Fluorophenol(S)
%
61
10-130
07/26/22 08:56
Nitrobenzene-d5 (S)
%
87
10-144
07/26/22 08:56
Phenol-d6 (S)
%
43
10-130
07/26/22 08:56
Terphenyl-d14 (S)
%
112
34-163
07/26/22 08:56
Qualifiers
LABORATORY CONTROL SAMPLE:
3715398
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,2,4-Trichlorobenzene
ug/L
50
25.9
52
18-130
1,2-Dichlorobenzene
ug/L
50
18.4
37
20-130
1,3-Dichlorobenzene
ug/L
50
16.5
33
18-130
1,4-Dichlorobenzene
ug/L
50
17.8
36
18-130
1-Methylnaphthalene
ug/L
50
34.5
69
29-130
2,2'-Oxybis(1-chloropropane)
ug/L
50
37.0
74
28-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 50 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
LABORATORY CONTROL SAMPLE:
Parameter
3715398
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
2,4,5-Trichlorophenol
ug/L
50
39.1
78
35-130
2,4,6-Trichlorophenol
ug/L
50
39.9
80
31-130
2,4-Dichlorophenol
ug/L
50
38.8
78
35-130
2,4-Dimethylphenol
ug/L
50
46.4
93
34-130
2,4-Dinitrophenol
ug/L
250
105
42
10-153
2,4-Dinitrotoluene
ug/L
50
42.2
84
37-136
2,6-Dinitrotoluene
ug/L
50
40.4
81
33-136
2-Chloronaphthalene
ug/L
50
37.7
75
26-130
2-Chlorophenol
ug/L
50
32.4
65
37-130
2-Methylnaphthalene
ug/L
50
32.6
65
29-130
2-Methylphenol(o-Cresol)
ug/L
50
33.3
67
35-130
2-Nitroaniline
ug/L
100
79.4
79
37-130
2-Nitrophenol
ug/L
50
35.9
72
32-130
3&4-Methyl phenol (m&p Cresol)
ug/L
50
29.7
59
34-130
3,3'-Dichlorobenzidine
ug/L
100
79.1
79
34-136
3-Nitroaniline
ug/L
100
77.6
78
37-138
4,6-Dinitro-2-methyl phenol
ug/L
100
73.1
73
21-157
4-Bromophenylphenyl ether
ug/L
50
42.7
85
38-130
4-ChIoro-3-methyl phenol
ug/L
100
79.7
80
37-130
4-Chloroaniline
ug/L
100
75.5
76
38-130
4-Chlorophenylphenyl ether
ug/L
50
39.1
78
33-130
4-Nitroaniline
ug/L
100
74.0
74
42-137
4-Nitrophenol
ug/L
250
104
41
10-130 v1
Acenaphthene
ug/L
50
39.8
80
33-130
Acenaphthylene
ug/L
50
38.4
77
35-130
Aniline
ug/L
50
29.9
60
22-130
Anthracene
ug/L
50
36.7
73
48-130
Benzo(a)anthracene
ug/L
50
41.0
82
48-137
Benzo(a)pyrene
ug/L
50
49.5
99
49-138
Benzo(b)fluoranthene
ug/L
50
51.8
104
52-138
Benzo(g,h,i)perylene
ug/L
50
52.7
105
48-140
Benzo(k)fluoranthene
ug/L
50
53.0
106
48-139
Benzoic Acid
ug/L
250
57.3
23
10-130
Benzyl alcohol
ug/L
100
65.4
65
35-130
bis(2-Chloroethoxy)methane
ug/L
50
36.5
73
34-130
bis(2-Chloroethyl) ether
ug/L
50
33.7
67
36-130
bis(2-Ethylhexyl)phthalate
ug/L
50
39.7
79
32-165
Butylbenzylphthalate
ug/L
50
40.3
81
34-161
Chrysene
ug/L
50
41.7
83
47-131
Di-n-butylphthalate
ug/L
50
38.1
76
39-144
Di-n-octylphthalate
ug/L
50
38.9
78
30-170
Dibenz(a,h)anthracene
ug/L
50
51.7
103
49-138
Dibenzofuran
ug/L
50
39.7
79
33-130
Diethylphthalate
ug/L
50
40.0
80
38-131
Dimethylphthalate
ug/L
50
39.5
79
37-130
Fluoranthene
ug/L
50
41.7
83
46-137
Fluorene
ug/L
50
39.5
79
37-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 51 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
LABORATORY CONTROL SAMPLE:
Parameter
3715398
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Hexachloro-1,3-butadiene
ug/L
50
21.0
42
11-130
Hexachlorobenzene
ug/L
50
42.8
86
38-130
Hexachlorocyclopentadiene
ug/L
50
26.6
53
10-130
Hexachloroethane
ug/L
50
15.6
31
14-130
Indeno(1,2,3-cd)pyrene
ug/L
50
53.1
106
41-130
Isophorone
ug/L
50
41.2
82
33-130
N-Nitroso-di-n-propylamine
ug/L
50
37.0
74
36-130
N-Nitrosodimethylamine
ug/L
50
33.8
68
34-130
N-Nitrosodiphenylamine
ug/L
50
41.0
82
37-130
Naphthalene
ug/L
50
27.6
55
30-130
Nitrobenzene
ug/L
50
39.7
79
36-130
Pentachlorophenol
ug/L
100
81.2
81
23-149
Phenanthrene
ug/L
50
41.8
84
44-130
Phenol
ug/L
50
23.4
47
18-130
Pyrene
ug/L
50
44.1
88
47-134
2,4,6-Tribromophenol (S)
%
105
10-144
2-Fluorobiphenyl (S)
%
78
10-130
2-Fluorophenol (S)
%
62
10-130
Nitrobenzene-d5 (S)
%
95
10-144
Phenol-d6 (S)
%
50
10-130
Terphenyl-d14(S)
%
110
34-163
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3715399
MS
92615455001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3715400
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
1,2,4-Trichlorobenzene
ug/L
ND
50
50
19.3
18.5
39
37
10-130
4
1,2-Dichlorobenzene
ug/L
ND
50
50
13.4
12.2
27
24
10-130
9
1,3-Dichlorobenzene
ug/L
ND
50
50
11.5
9.81
23
20
10-130
1,4-Dichlorobenzene
ug/L
ND
50
50
12.2
10.4
24
21
10-130
16
1-Methylnaphthalene
ug/L
ND
50
50
34.0
32.5
68
65
10-130
4
2,2'-Oxybis(1-chloropropane)
ug/L
ND
50
50
36.8
33.6
74
67
12-142
9
2,4,5-Trichlorophenol
ug/L
ND
50
50
4.OJ
3.2J
8
6
10-143
M1
2,4,6-Trichlorophenol
ug/L
ND
50
50
1.6J
ND
3
3
10-147
M1
2,4-Dichlorophenol
ug/L
ND
50
50
18.7
15.5
37
31
10-138
19
2,4-Dimethylphenol
ug/L
ND
50
50
51.0
47.6
102
95
25-130
7
2,4-Dinitrophenol
ug/L
ND
250
250
ND
ND
4
5
10-165
M1
2,4-Dinitrotoluene
ug/L
ND
50
50
49.1
46.3
98
93
29-148
6
2,6-Dinitrotoluene
ug/L
ND
50
50
49.0
48.1
98
96
26-146
2
2-Chloronaphthalene
ug/L
ND
50
50
39.4
37.3
79
75
11-130
5
2-Chlorophenol
ug/L
ND
50
50
19.8
17.6
40
35
10-133
12
2-Methylnaphthalene
ug/L
ND
50
50
32.0
31.1
64
62
13-130
3
2-Methylphenol(o-Cresol)
ug/L
ND
50
50
35.8
34.0
72
68
20-130
5
2-Nitroaniline
ug/L
ND
100
100
96.0
91.5
96
92
24-136
5
2-Nitrophenol
ug/L
ND
50
50
15.4
12.5
31
25
10-153
21
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
Page 52 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3715399
3715400
MS
MSD
92615455001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
3&4-Methyl phenol (m&p
ug/L
8AJ
50
50
45.6
41.5
75
66
16-130
10
Cresol)
3,3'-Dichlorobenzidine
ug/L
ND
100
100
95.8
91.6
96
92
10-153
4
3-Nitroaniline
ug/L
ND
100
100
101
89.9
101
90
22-151
12
4,6-Dinitro-2-methyl phenol
ug/L
ND
100
100
ND
ND
4
5
10-180
M1
4-Bromophenylphenyl ether
ug/L
ND
50
50
46.1
45.1
92
90
25-130
2
4-Chloro-3-methyl phenol
ug/L
ND
100
100
86.2
80.4
86
80
25-133
7
4-Chloroaniline
ug/L
ND
100
100
80.9
80.9
81
81
14-132
0
4-Chlorophenylphenyl ether
ug/L
ND
50
50
45.5
43.4
91
87
19-130
5
4-Nitroaniline
ug/L
ND
100
100
99.4
88.6
99
89
29-150
11
4-Nitrophenol
ug/L
ND
250
250
ND
ND
0
0
10-130
M1,v1
Acenaphthene
ug/L
ND
50
50
44.3
41.8
89
84
16-130
6
Acenaphthylene
ug/L
ND
50
50
42.7
40.9
85
82
15-137
4
Aniline
ug/L
ND
50
50
33.5
32.0
67
64
10-130
4
Anthracene
ug/L
ND
50
50
41.8
40.2
84
80
37-136
4
Benzo(a)anthracene
ug/L
ND
50
50
47.4
45.2
95
90
40-145
5
Benzo(a)pyrene
ug/L
ND
50
50
56.8
52.5
114
105
41-146
8
Benzo(b)fluoranthene
ug/L
ND
50
50
56.7
52.5
113
105
39-151
8
Benzo(g,h,i)perylene
ug/L
ND
50
50
59.7
55.9
119
112
40-147
6
Benzo(k)fluoranthene
ug/L
ND
50
50
57.1
55.1
114
110
40-146
4
Benzoic Acid
ug/L
ND
250
250
ND
ND
0
0
10-130
M1
Benzyl alcohol
ug/L
ND
100
100
74.7
73.6
75
74
25-130
1
bis(2-Chloroethoxy)methane
ug/L
ND
50
50
36.8
37.0
74
74
23-130
0
bis(2-Chloroethyl) ether
ug/L
ND
50
50
35.5
34.3
71
69
25-130
3
bis(2-Ethylhexyl)phthalate
ug/L
ND
50
50
47.5
46.5
95
93
28-166
2
Butylbenzylphthalate
ug/L
ND
50
50
50.7
48.8
101
98
33-165
4
Chrysene
ug/L
ND
50
50
47.1
44.7
94
89
38-141
5
Di-n-butylphthalate
ug/L
ND
50
50
45.5
43.6
91
87
32-153
4
Di-n-octylphthalate
ug/L
ND
50
50
49.9
47.6
100
95
30-175
5
Dibenz(a,h)anthracene
ug/L
ND
50
50
60.2
52.6
120
105
39-148
14
Dibenzofuran
ug/L
ND
50
50
45.2
43.3
90
87
20-130
4
Diethylphthalate
ug/L
ND
50
50
49.8
46.6
100
93
28-142
6
Dimethylphthalate
ug/L
ND
50
50
47.6
45.6
95
91
26-136
4
Fluoranthene
ug/L
ND
50
50
49.2
46.9
98
94
39-143
5
Fluorene
ug/L
ND
50
50
47.0
44.5
94
89
24-132
6
Hexachloro-1,3-butadiene
ug/L
ND
50
50
12.6
12.0
25
24
10-130
5
Hexachlorobenzene
ug/L
ND
50
50
47.1
44.9
94
90
29-130
5
Hexachlorocyclopentadiene
ug/L
ND
50
50
22.2
22.6
44
45
10-130
2
Hexachloroethane
ug/L
ND
50
50
9AJ
8.3J
19
17
10-130
Indeno(1,2,3-cd)pyrene
ug/L
ND
50
50
61.0
57.3
122
115
39-148
6
Isophorone
ug/L
ND
50
50
44.1
43.3
88
87
23-130
2
N-Nitroso-di-n-propylamine
ug/L
ND
50
50
42.4
41.0
85
82
25-130
3
N-Nitrosodimethylamine
ug/L
ND
50
50
35.0
33.7
70
67
22-130
4
N-Nitrosodiphenylamine
ug/L
ND
50
50
45.2
44.6
90
89
26-134
1
Naphthalene
ug/L
ND
50
50
22.6
23.2
45
46
14-130
3
Nitrobenzene
ug/L
ND
50
50
39.5
39.8
79
80
25-130
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
Page 53 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3715399
3715400
MS
MSD
92615455001 Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
Pentachlorophenol
ug/L
ND 100
100
ND
ND
0
0
10-175 M1
Phenanthrene
ug/L
ND 50
50
46.3
44.7
93
89
36-133 4
Phenol
ug/L
ND 50
50
21.6
20.0
43
40
10-130 8
Pyrene
ug/L
ND 50
50
48.4
47.2
97
94
40-143 3
2,4,6-Tribromophenol (S)
%
6
5
10-144 SO
2-Fluorobiphenyl (S)
%
74
80
10-130
2-Fluorophenol (S)
%
19
16
10-130
Nitrobenzene-d5(S)
%
92
90
10-144
Phenol-d6 (S)
%
43
40
10-130
Terphenyl-d14(S)
%
115
109
34-163
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
Page 54 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
QC Batch: 712828 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E Water MSSV RVE
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92615455003, 92615455004, 92615455005
METHOD BLANK: 3716742
Matrix:
Water
Associated Lab Samples: 92615455003,
92615455004, 92615455005
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
1,2,4-Trichlorobenzene
ug/L
ND
10.0
07/27/22 08:14
1,2-Dichlorobenzene
ug/L
ND
10.0
07/27/22 08:14
1,3-Dichlorobenzene
ug/L
ND
10.0
07/27/22 08:14
1,4-Dichlorobenzene
ug/L
ND
10.0
07/27/22 08:14
1-Methylnaphthalene
ug/L
ND
10.0
07/27/22 08:14
2,2'-Oxybis(1-chloropropane)
ug/L
ND
10.0
07/27/22 08:14
2,4,5-Trichlorophenol
ug/L
ND
10.0
07/27/22 08:14
2,4,6-Trichlorophenol
ug/L
ND
10.0
07/27/22 08:14
2,4-Dichlorophenol
ug/L
ND
10.0
07/27/22 08:14
2,4-Dimethylphenol
ug/L
ND
10.0
07/27/22 08:14
2,4-Dinitrophenol
ug/L
ND
50.0
07/27/22 08:14
2,4-Dinitrotoluene
ug/L
ND
10.0
07/27/22 08:14
2,6-Dinitrotoluene
ug/L
ND
10.0
07/27/22 08:14
2-Chloronaphthalene
ug/L
ND
10.0
07/27/22 08:14
2-Chlorophenol
ug/L
ND
10.0
07/27/22 08:14
2-Methylnaphthalene
ug/L
ND
10.0
07/27/22 08:14
2-Methylphenol(o-Cresol)
ug/L
ND
10.0
07/27/22 08:14
2-Nitroaniline
ug/L
ND
20.0
07/27/22 08:14
2-Nitrophenol
ug/L
ND
10.0
07/27/22 08:14
3&4-Methyl phenol (m&p Cresol)
ug/L
ND
10.0
07/27/22 08:14
3,3'-Dichlorobenzidine
ug/L
ND
20.0
07/27/22 08:14
3-Nitroaniline
ug/L
ND
20.0
07/27/22 08:14
4,6-Dinitro-2-methyl phenol
ug/L
ND
20.0
07/27/22 08:14
4-Bromophenylphenyl ether
ug/L
ND
10.0
07/27/22 08:14
4-ChIoro-3-methyl phenol
ug/L
ND
10.0
07/27/22 08:14
4-Chloroaniline
ug/L
ND
20.0
07/27/22 08:14
4-Chlorophenylphenyl ether
ug/L
ND
10.0
07/27/22 08:14
4-Nitroaniline
ug/L
ND
20.0
07/27/22 08:14
4-Nitrophenol
ug/L
ND
50.0
07/27/22 08:14 v1
Acenaphthene
ug/L
ND
10.0
07/27/22 08:14
Acenaphthylene
ug/L
ND
10.0
07/27/22 08:14
Aniline
ug/L
ND
10.0
07/27/22 08:14
Anthracene
ug/L
ND
10.0
07/27/22 08:14
Benzo(a)anthracene
ug/L
ND
10.0
07/27/22 08:14
Benzo(a)pyrene
ug/L
ND
10.0
07/27/22 08:14
Benzo(b)fluoranthene
ug/L
ND
10.0
07/27/22 08:14
Benzo(g,h,i)perylene
ug/L
ND
10.0
07/27/22 08:14
Benzo(k)fluoranthene
ug/L
ND
10.0
07/27/22 08:14
Benzoic Acid
ug/L
ND
50.0
07/27/22 08:14
Benzyl alcohol
ug/L
ND
20.0
07/27/22 08:14
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 55 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
METHOD BLANK: 3716742 Matrix:
Associated Lab Samples: 92615455003, 92615455004, 92615455005
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
bis(2-Chloroethoxy)methane
ug/L
ND
10.0
07/27/22 08:14
bis(2-Chloroethyl) ether
ug/L
ND
10.0
07/27/22 08:14
bis(2-Ethylhexyl)phthalate
ug/L
ND
6.0
07/27/22 08:14
Butylbenzylphthalate
ug/L
ND
10.0
07/27/22 08:14
Chrysene
ug/L
ND
10.0
07/27/22 08:14
Di-n-butylphthalate
ug/L
ND
10.0
07/27/22 08:14
Di-n-octylphthalate
ug/L
ND
10.0
07/27/22 08:14
Dibenz(a,h)anthracene
ug/L
ND
10.0
07/27/22 08:14
Dibenzofuran
ug/L
ND
10.0
07/27/22 08:14
Diethylphthalate
ug/L
ND
10.0
07/27/22 08:14
Dimethylphthalate
ug/L
ND
10.0
07/27/22 08:14
Fluoranthene
ug/L
ND
10.0
07/27/22 08:14
Fluorene
ug/L
ND
10.0
07/27/22 08:14
Hexachloro-1,3-butadiene
ug/L
ND
10.0
07/27/22 08:14
Hexachlorobenzene
ug/L
ND
10.0
07/27/22 08:14
Hexachlorocyclopentadiene
ug/L
ND
10.0
07/27/22 08:14
Hexachloroethane
ug/L
ND
10.0
07/27/22 08:14
Indeno(1,2,3-cd)pyrene
ug/L
ND
10.0
07/27/22 08:14
Isophorone
ug/L
ND
10.0
07/27/22 08:14
N-Nitroso-di-n-propylamine
ug/L
ND
10.0
07/27/22 08:14
N-Nitrosodimethylamine
ug/L
ND
10.0
07/27/22 08:14
N-Nitrosodiphenylamine
ug/L
ND
10.0
07/27/22 08:14
Naphthalene
ug/L
ND
10.0
07/27/22 08:14
Nitrobenzene
ug/L
ND
10.0
07/27/22 08:14
Pentachlorophenol
ug/L
ND
20.0
07/27/22 08:14
Phenanthrene
ug/L
ND
10.0
07/27/22 08:14
Phenol
ug/L
ND
10.0
07/27/22 08:14
Pyrene
ug/L
ND
10.0
07/27/22 08:14
2,4,6-Tribromophenol (S)
%
104
10-144
07/27/22 08:14
2-Fluorobiphenyl (S)
%
95
10-130
07/27/22 08:14
2-Fluorophenol (S)
%
65
10-130
07/27/22 08:14
Nitrobenzene-d5 (S)
%
103
10-144
07/27/22 08:14
Phenol-d6 (S)
%
52
10-130
07/27/22 08:14
Terphenyl-d14 (S)
%
130
34-163
07/27/22 08:14
v1
Qualifiers
LABORATORY CONTROL SAMPLE:
3716743
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,2,4-Trichlorobenzene
ug/L
50
36.1
72
18-130
1,2-Dichlorobenzene
ug/L
50
26.6
53
20-130
1,3-Dichlorobenzene
ug/L
50
24.0
48
18-130
1,4-Dichlorobenzene
ug/L
50
24.7
49
18-130
1-Methylnaphthalene
ug/L
50
44.5
89
29-130
2,2'-Oxybis(1-chloropropane)
ug/L
50
41.0
82
28-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 56 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
LABORATORY CONTROL SAMPLE:
Parameter
3716743
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
2,4,5-Trichlorophenol
ug/L
50
60.9
122
35-130
2,4,6-Trichlorophenol
ug/L
50
58.6
117
31-130
2,4-Dichlorophenol
ug/L
50
51.6
103
35-130
2,4-Dimethylphenol
ug/L
50
61.7
123
34-130
2,4-Dinitrophenol
ug/L
250
230
92
10-153
2,4-Dinitrotoluene
ug/L
50
60.4
121
37-136
2,6-Dinitrotoluene
ug/L
50
60.2
120
33-136
2-Chloronaphthalene
ug/L
50
50.8
102
26-130
2-Chlorophenol
ug/L
50
45.3
91
37-130
2-Methylnaphthalene
ug/L
50
43.8
88
29-130
2-Methylphenol(o-Cresol)
ug/L
50
44.4
89
35-130
2-Nitroaniline
ug/L
100
113
113
37-130
2-Nitrophenol
ug/L
50
50.6
101
32-130
3&4-Methyl phenol (m&p Cresol)
ug/L
50
42.1
84
34-130
3,3'-Dichlorobenzidine
ug/L
100
122
122
34-136
3-Nitroaniline
ug/L
100
114
114
37-138
4,6-Dinitro-2-methyl phenol
ug/L
100
127
127
21-157
4-Bromophenylphenyl ether
ug/L
50
61.4
123
38-130
4-ChIoro-3-methyl phenol
ug/L
100
109
109
37-130
4-Chloroaniline
ug/L
100
98.1
98
38-130
4-Chlorophenylphenyl ether
ug/L
50
54.8
110
33-130
4-Nitroaniline
ug/L
100
108
108
42-137
4-Nitrophenol
ug/L
250
197
79
10-130 v1
Acenaphthene
ug/L
50
51.1
102
33-130
Acenaphthylene
ug/L
50
51.3
103
35-130
Aniline
ug/L
50
37.6
75
22-130
Anthracene
ug/L
50
51.1
102
48-130
Benzo(a)anthracene
ug/L
50
59.1
118
48-137
Benzo(a)pyrene
ug/L
50
70.2
140
49-138 L1
Benzo(b)fluoranthene
ug/L
50
70.1
140
52-138 L1
Benzo(g,h,i)perylene
ug/L
50
70.8
142
48-140 L1
Benzo(k)fluoranthene
ug/L
50
73.9
148
48-139 L1
Benzoic Acid
ug/L
250
78.9
32
10-130
Benzyl alcohol
ug/L
100
91.9
92
35-130
bis(2-Chloroethoxy)methane
ug/L
50
49.3
99
34-130
bis(2-Chloroethyl) ether
ug/L
50
46.4
93
36-130
bis(2-Ethylhexyl)phthalate
ug/L
50
63.9
128
32-165
Butylbenzylphthalate
ug/L
50
66.0
132
34-161
Chrysene
ug/L
50
59.3
119
47-131
Di-n-butylphthalate
ug/L
50
57.4
115
39-144
Di-n-octylphthalate
ug/L
50
64.7
129
30-170
Dibenz(a,h)anthracene
ug/L
50
71.4
143
49-138 L1
Dibenzofuran
ug/L
50
53.5
107
33-130
Diethylphthalate
ug/L
50
58.4
117
38-131
Dimethylphthalate
ug/L
50
56.3
113
37-130
Fluoranthene
ug/L
50
57.7
115
46-137
Fluorene
ug/L
50
54.1
108
37-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 57 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
LABORATORY CONTROL SAMPLE:
Parameter
3716743
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Hexachloro-1,3-butadiene
ug/L
50
30.5
61
11-130
Hexachlorobenzene
ug/L
50
59.4
119
38-130
Hexachlorocyclopentadiene
ug/L
50
42.9
86
10-130
Hexachloroethane
ug/L
50
22.8
46
14-130
Indeno(1,2,3-cd)pyrene
ug/L
50
72.1
144
41-130 L1
Isophorone
ug/L
50
54.3
109
33-130
N-Nitroso-di-n-propylamine
ug/L
50
53.1
106
36-130
N-Nitrosodimethylamine
ug/L
50
43.3
87
34-130
N-Nitrosodiphenylamine
ug/L
50
58.9
118
37-130
Naphthalene
ug/L
50
36.2
72
30-130
Nitrobenzene
ug/L
50
51.4
103
36-130
Pentachlorophenol
ug/L
100
133
133
23-149 v1
Phenanthrene
ug/L
50
56.5
113
44-130
Phenol
ug/L
50
31.0
62
18-130
Pyrene
ug/L
50
64.0
128
47-134
2,4,6-Tribromophenol (S)
%
134
10-144
2-Fluorobiphenyl (S)
%
96
10-130
2-Fluorophenol(S)
%
74
10-130
Nitrobenzene-d5 (S)
%
109
10-144
Phenol-d6 (S)
%
60
10-130
Terphenyl-d14 (S)
%
146
34-163
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3716744
MS
92615455003 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3716745
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
1,2,4-Trichlorobenzene
ug/L
ND
50
50
29.8
31.4
60
63
10-130
5
1,2-Dichlorobenzene
ug/L
ND
50
50
19.0
20.0
38
40
10-130
5
1,3-Dichlorobenzene
ug/L
ND
50
50
16.6
17.4
33
35
10-130
4
1,4-Dichlorobenzene
ug/L
ND
50
50
17.8
18.1
36
36
10-130
1
1-Methylnaphthalene
ug/L
ND
50
50
42.8
42.6
86
85
10-130
0
2,2'-Oxybis(1-chloropropane)
ug/L
ND
50
50
39.2
39.7
78
79
12-142
1
2,4,5-Trichlorophenol
ug/L
ND
50
50
7.9J
6.1J
16
12
10-143
2,4,6-Trichlorophenol
ug/L
ND
50
50
3.2J
2.7J
6
5
10-147
M1
2,4-Dichlorophenol
ug/L
ND
50
50
21.5
17.4
43
35
10-138
21
2,4-Dimethylphenol
ug/L
ND
50
50
56.3
58.2
113
116
25-130
3
2,4-Dinitrophenol
ug/L
ND
250
250
ND
ND
4
4
10-165
M1
2,4-Dinitrotoluene
ug/L
ND
50
50
56.8
54.6
114
109
29-148
4
2,6-Dinitrotoluene
ug/L
ND
50
50
59.2
56.2
118
112
26-146
5
2-Chloronaphthalene
ug/L
ND
50
50
50.1
49.5
100
99
11-130
1
2-Chlorophenol
ug/L
ND
50
50
21.4
17.9
43
36
10-133
18
2-Methylnaphthalene
ug/L
ND
50
50
40.6
42.0
81
84
13-130
3
2-Methylphenol(o-Cresol)
ug/L
ND
50
50
41.3
39.6
83
79
20-130
4
2-Nitroaniline
ug/L
ND
100
100
108
108
108
108
24-136
0
2-Nitrophenol
ug/L
ND
50
50
18.5
14.3
37
29
10-153
26
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
Page 58 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Sludge LF 7/18
Pace Project No.: 92615455
MATRIX SPIKE & MATRIX SPIKE DUPLICATE
Parameter
3&4-Methyl phenol (m&p
Cresol)
3,3'-Dichlorobenzidine
3-Nitroaniline
4,6-Din itro-2-methyl phenol
4-Bromophenylphenyl ether
4-ChIoro-3-methyl phenol
4-Chloroaniline
4-Chlorophenylphenyl ether
4-Nitroaniline
4-Nitrophenol
Acenaphthene
Acenaphthylene
Aniline
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Benzoic Acid
Benzyl alcohol
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis(2-Ethylhexyl)phthalate
Butylbenzylphthalate
Chrysene
Di-n-butylphthalate
Di-n-octylphthalate
Dibenz(a,h)anthracene
Dibenzofuran
Diethylphthalate
Dimethylphthalate
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Isophorone
N-Nitroso-di-n-propylamine
N-Nitrosodimethylamine
N-Nitrosodiphenylamine
Naphthalene
Nitrobenzene
QUALITY CONTROL DATA
3716744
MS
92615455003 Spike
Units Result Conc.
ug/L ND 50
ug/L ND 100
ug/L ND 100
ug/L ND 100
ug/L ND 50
ug/L ND 100
ug/L ND 100
ug/L ND 50
ug/L ND 100
ug/L ND 250
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 250
ug/L ND 100
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
ug/L ND 50
MSD
Spike
Conc.
3716745
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
50
37.3
35.2
75
70
16-130
100
118
116
118
116
10-153
100
110
107
110
107
22-151
100
ND
ND
4
4
10-180
50
59.6
59.0
119
118
25-130
100
95.6
92.4
96
92
25-133
100
91.5
92.2
91
92
14-132
50
54.0
52.6
108
105
19-130
100
105
100
105
100
29-150
250
ND
ND
0
0
10-130
50
50.7
51.1
101
102
16-130
50
50.4
50.1
101
100
15-137
50
34.8
33.7
70
67
10-130
50
50.4
49.2
101
98
37-136
50
57.4
56.9
115
114
40-145
50
69.4
68.7
139
137
41-146
50
69.0
66.5
138
133
39-151
50
73.2
69.6
146
139
40-147
50
70.2
69.8
140
140
40-146
250
ND
ND
0
0
10-130
100
86.6
84.8
87
85
25-130
50
45.7
47.3
91
95
23-130
50
44.0
44.0
88
88
25-130
50
61.5
61.3
120
120
28-166
50
63.1
63.7
126
127
33-165
50
57.8
56.8
116
114
38-141
50
57.0
55.2
114
110
32-153
50
65.4
63.5
131
127
30-175
50
72.9
70.8
146
142
39-148
50
52.7
52.4
105
105
20-130
50
57.5
56.1
115
112
28-142
50
56.3
54.7
113
109
26-136
50
58.7
55.0
117
110
39-143
50
53.3
52.3
107
105
24-132
50
22.3
24.3
45
49
10-130
50
57.5
57.7
115
115
29-130
50
36.6
40.1
73
80
10-130
50
14.8
15.0
30
30
10-130
50
75.1
72.5
150
145
39-148
50
52.0
52.5
104
105
23-130
50
51.4
50.4
103
101
25-130
50
43.1
40.3
86
81
22-130
50
56.6
57.1
113
114
26-134
50
31.6
33.0
63
66
14-130
50
46.8
48.9
94
98
25-130
RPD Qual
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
6
1
3
M1
1
3
1
3
4
M1,v1
1
1
3
2
1
1
4
5
1
M1
2
3
0
0
1
2
3
3
3
1
2
3
7
2
9
0
9
1
3 MO
1
2
7
1
4
4
Page 59 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3716744
3716745
MS
MSD
92615455003 Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
Pentachlorophenol
ug/L
ND 100
100
ND
ND
0
0
10-175 M1
Phenanthrene
ug/L
ND 50
50
55.4
54.4
111
109
36-133 2
Phenol
ug/L
ND 50
50
22.7
20.4
45
41
10-130 11
Pyrene
ug/L
ND 50
50
58.7
60.3
117
121
40-143 3
2,4,6-Tribromophenol (S)
%
14
11
10-144
2-Fluorobiphenyl (S)
%
92
88
10-130
2-Fluorophenol (S)
%
17
12
10-130
Nitrobenzene-d5(S)
%
96
95
10-144
Phenol-d6 (S)
%
41
35
10-130
Terphenyl-d14(S)
%
123
129
34-163
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
Page 60 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
QC Batch: 712912 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92615455001
METHOD BLANK: 3717257
Associated Lab Samples: 92615455001
Parameter Units
Alkalinity, Total as CaCO3 mg/L
LABORATORY CONTROL SAMPLE: 3717258
Parameter Units
Alkalinity, Total as CaCO3 mg/L
LABORATORY CONTROL SAMPLE: 3717259
Parameter Units
Alkalinity, Total as CaCO3 mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 5.0 07/27/22 15:06
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
50 50.2 100 80-120
Spike LCS
Conc. Result
50 52.4
LCS % Rec
% Rec Limits Qualifiers
105 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3717260 3717261
MS MSD
92616383010 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Alkalinity, Total as CaCO3 mg/L 26.9 50 50 74.7 75.0 96 96 80-120 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3717262 3717263
MS MSD
92615273008 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Alkalinity, Total as CaCO3 mg/L 12.1 50 50 64.4 64.8 105 105 80-120 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
Page 61 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
QC Batch: 713287 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92615455002
METHOD BLANK: 3719079
Associated Lab Samples: 92615455002
Parameter Units
Alkalinity, Total as CaCO3 mg/L
LABORATORY CONTROL SAMPLE: 3719080
Parameter Units
Alkalinity, Total as CaCO3 mg/L
LABORATORY CONTROL SAMPLE: 3719081
Parameter Units
Alkalinity, Total as CaCO3 mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 5.0 07/28/22 17:11
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
50 51.5 103 80-120
Spike LCS
Conc. Result
50 53.3
LCS % Rec
% Rec Limits Qualifiers
107 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3719082 3719083
MS MSD
92615455002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Alkalinity, Total as CaCO3 mg/L 102 50 50 150 147 95 90 80-120 2
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3719084 3719085
MS MSD
92615476010 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Alkalinity, Total as CaCO3 mg/L 107 50 50 160 160 106 106 80-120 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
Page 62 of 132

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
QC Batch: 713558 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92615455003, 92615455004, 92615455005
METHOD BLANK: 3720276
Matrix:
Water
Associated Lab Samples: 92615455003, 92615455004, 92615455005
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Alkalinity, Total as CaCO3
mg/L
ND
5.0
07/29/22 19:01
LABORATORY CONTROL SAMPLE:
3720277
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Alkalinity, Total as CaCO3
mg/L
50
50.2
100 80-120
LABORATORY CONTROL SAMPLE: 3720278
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 49.3 99 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3720279 3720280
MS MSD
92615466001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Alkalinity, Total as CaCO3 mg/L 32.0 50 50 82.2 82.3 100 101 80-120 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3720281 3720282
MS MSD
92615466011 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Alkalinity, Total as CaCO3 mg/L 39.6 50 50 92.7 89.3 106 99 80-120 4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
QC Batch: 712109 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92615455001, 92615455002
METHOD BLANK: 3713177 Matrix: Water
Associated Lab Samples: 92615455001, 92615455002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 07/22/22 11:45
LABORATORY CONTROL SAMPLE: 3713178
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids mg/L 252 252 100 90-110
SAMPLE DUPLICATE: 3713179
92615318002 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 460 446 3
SAMPLE DUPLICATE: 3713180
92615403002 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L ND ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
QC Batch: 712394 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92615455003, 92615455004, 92615455005
METHOD BLANK: 3714489 Matrix: Water
Associated Lab Samples: 92615455003, 92615455004, 92615455005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 07/22/22 17:39
LABORATORY CONTROL SAMPLE: 3714490
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids mg/L 252 252 100 90-110
SAMPLE DUPLICATE: 3714491
92615656005 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L ND ND
SAMPLE DUPLICATE: 3714492
92615601009 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 58.0 54.0 7
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
QC Batch: 712182 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92615455001, 92615455002
METHOD BLANK: 3713809
Matrix:
Water
Associated Lab Samples: 92615455001, 92615455002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Sulfate
mg/L
ND
1.0
07/22/22 07:06
LABORATORY CONTROL SAMPLE:
3713810
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Sulfate
mg/L
50
52.2
104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3713811 3713812
MS MSD
92614350006 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfate mg/L 39.9 50 50 89.3 91.3 99 103 90-110 2
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3713813 3713814
MS MSD
92615456010 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfate mg/L 741 50 50 799 773 116 65 90-110 3 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
QC Batch: 712537 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92615455003, 92615455004, 92615455005
METHOD BLANK: 3715161
Matrix:
Water
Associated Lab Samples: 92615455003, 92615455004, 92615455005
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Sulfate
mg/L
ND
1.0
07/24/22 20:39
LABORATORY CONTROL SAMPLE:
3715162
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Sulfate
mg/L
50
51.5
103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3715163 3715164
MS MSD
92616379001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfate mg/L 3.8 50 50 58.6 58.8 110 110 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3715165 3715166
MS MSD
92615452002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfate mg/L ND 50 50 55.3 54.7 110 108 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
Page 67 of 132

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2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
QC Batch: 713128 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92615455001, 92615455002
METHOD BLANK: 3718211
Matrix:
Water
Associated Lab Samples: 92615455001, 92615455002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Chloride
mg/L
ND
1.0
07/27/2210:45
LABORATORY CONTROL SAMPLE:
3718212
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Chloride
mg/L
20
20.7
104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3718213 3718214
MS MSD
92614950002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 56.5 10 10 59.6 59.8 31 33 90-110 0 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
Page 68 of 132

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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
QC Batch: 713592 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92615455003, 92615455004, 92615455005
METHOD BLANK: 3720529
Matrix:
Water
Associated Lab Samples: 92615455003, 92615455004, 92615455005
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Chloride
mg/L
ND
1.0
07/29/2213:18
LABORATORY CONTROL SAMPLE:
3720530
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Chloride
mg/L
20
20.7
104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3720531 3720532
MS MSD
92615919003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 9.8 10 10 20.4 20.5 106 107 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3720533 3720534
MS MSD
92615919004 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 33.6 10 10 44.8 45.0 111 113 90-110 0 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
Page 69 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
QC Batch: 711959 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92615455001, 92615455002
METHOD BLANK: 3712401
Matrix:
Water
Associated Lab Samples: 92615455001, 92615455002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Total Organic Carbon
mg/L
ND
1.0
07/21/22 21:01
LABORATORY CONTROL SAMPLE:
3712402
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Total Organic Carbon
mg/L
25
23.8
95 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3712403 3712404
MS MSD
92615936002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L ND 25 25 24.3 24.4 94 94 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3712405 3712406
MS MSD
92615403001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 0.77J 25 25 24.4 24.6 94 95 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
Page 70 of 132

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Sludge LF 7/18
Pace Project No.: 92615455
QC Batch: 712522 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92615455003, 92615455004, 92615455005
METHOD BLANK: 3715133
Matrix:
Water
Associated Lab Samples: 92615455003, 92615455004, 92615455005
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Total Organic Carbon
mg/L
ND
1.0
07/25/22 21:45
LABORATORY CONTROL SAMPLE:
3715134
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Total Organic Carbon
mg/L
25
23.6
94 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3715135 3715136
MS MSD
92615452005 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L ND 25 25 24.2 24.3 94 94 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3715137 3715138
MS MSD
92615601011 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L ND 25 25 24.9 25.0 98 98 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/24/2022 08:45 AM without the written consent of Pace Analytical Services, LLC.
Page 71 of 132

Pace Analytical Services, LLC
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Asheville, NC 28804
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QUALIFIERS
Project: Sludge LF 7/18
Pace Project No.: 92615455
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
1g Re -extraction conducted in excess of EPA method holding time. Results confirm original analysis performed in hold time.
HS Results are from sample aliquot taken from VOA vial with headspace (air bubble greater than 6 mm diameter).
L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
SO Surrogate recovery outside laboratory control limits.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
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Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Sludge LF 7/18
92615455
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92615455001
SWP-1
92615455002
SWP-2
92615455003
Q06V09
92615455004
Q06V10
92615455005
Q06V11
92615455001
SWP-1
EPA 3010A
713124
EPA 6010D
713301
92615455002
SWP-2
EPA 3010A
713124
EPA 6010D
713301
92615455003
Q06V09
EPA 3010A
713124
EPA 6010D
713301
92615455004
Q06V10
EPA 3010A
713124
EPA 6010D
713301
92615455005
Q06V11
EPA 3010A
713124
EPA 6010D
713301
92615455001
SWP-1
EPA 3510C
712603
EPA 8270E
712804
92615455002
SWP-2
EPA 3510C
712603
EPA 8270E
712804
92615455003
Q06V09
EPA 3510C
712828
EPA 8270E
713075
92615455004
QO6V10
EPA 3510C
712828
EPA 8270E
713075
92615455005
Q06V11
EPA 3510C
712828
EPA 8270E
713075
92615455001
SWP-1
EPA 8260D
711710
92615455002
SWP-2
EPA 8260D
711710
92615455003
Q06V09
EPA 8260D
711710
92615455004
Q06V10
EPA 8260D
711710
92615455005
Q06V11
EPA 8260D
711710
92615455007
TRIP BLANK
EPA 8260D
711793
92615455001
SWP-1
EPA 8260D Mod.
711732
92615455002
SWP-2
EPA 8260D Mod.
711732
92615455003
Q06V09
EPA 8260D Mod.
711732
92615455004
Q06V10
EPA 8260D Mod.
711732
92615455005
Q06V11
EPA 8260D Mod.
711732
92615455007
TRIP BLANK
EPA 8260D Mod.
712183
92615455001
SWP-1
SM 2320E-2011
712912
92615455002
SWP-2
SM 2320E-2011
713287
92615455003
Q06V09
SM 2320B-2011
713558
92615455004
Q06V10
SM 2320B-2011
713558
92615455005
Q06V11
SM 2320B-2011
713558
92615455001
SWP-1
SM 2540C-2015
712109
92615455002
SWP-2
SM 2540C-2015
712109
92615455003
Q06V09
SM 2540C-2015
712394
92615455004
Q06V10
SM 2540C-2015
712394
92615455005
Q06V11
SM 2540C-2015
712394
92615455001
SWP-1
EPA 300.0 Rev 2.1 1993
712182
92615455002
SWP-2
EPA 300.0 Rev 2.1 1993
712182
92615455003
Q06V09
EPA 300.0 Rev 2.1 1993
712537
92615455004
Q06V10
EPA 300.0 Rev 2.1 1993
712537
92615455005
Q06V11
EPA 300.0 Rev 2.1 1993
712537
REPORT OF LABORATORY ANALYSIS
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Date: 10/24/2022 08:45 AM
without the written consent of Pace Analytical Services, LLC.
Page 73 of 132

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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Sludge LF 7/18
Pace Project No.: 92615455
Lab ID
Sample ID
QC
Batch Method
QC Batch
92615455001
SWP-1
SM
4500-CI-E-2011
713128
92615455002
SWP-2
SM
4500-CI-E-2011
713128
92615455003
Q06V09
SM
4500-CI-E-2011
713592
92615455004
Q06V10
SM
4500-CI-E-2011
713592
92615455005
Q06V11
SM
4500-CI-E-2011
713592
92615455001
SWP-1
SM
5310E-2014
711959
92615455002
SWP-2
SM
5310E-2014
711959
92615455003
Q06V09
SM
5310B-2014
712522
92615455004
Q06V10
SM
5310B-2014
712522
92615455005
Q06V11
SM
5310B-2014
712522
Date: 10/24/2022 08:45 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical Method
Analytical
Batch
Page 74 of 132

DC#_Title: ENV-FRM-HUN1-0083 v01_Sample Condition Upon Receipt
,ace
l wu'ai:tv�ct';
Effective Date: 0611212022
Laboratory rec .ving samples:
Asheville 0 Eden❑ Greenwood ❑ Huntersville ❑ Raleigh[] Mechanicsville❑ Atlanta❑ Kernersville❑
SampleCondition Client Name: 92615455
•
Upon ReceiptnI
Project #: o•
Courier: ❑FedEx ❑UPS ether: []ClientClient IN 1111111111
❑e
Commercial 2I ❑ 92613455
Custody Seal Present? [:]YesSeals Intact? [-]Yes ❑No
Date/tnitials Person Examining Contents: C ! % )q/
Packing MaterlaL ❑Bubble Wrap
EfBubble Bags ❑None ❑ other
Thermome er:
IR Gun ID: j �� Type of Ice: [Wet
Correction Factor:
Coo ter Temp: Add/Subtract('Q �1
Cooler Temp Corrected {"C): a
USDA Regulated Soil ( [2'N/A, water sample)
Did samples originate In a quarantine zone within the United States: CA, NY, or SC
rA-1, _ .,.t1 r-ivor r W ,
❑Blue ❑None
Biological Tissue Frozen?
❑Yes ❑No ❑N/A
Temp should be above freezing to 6°C
❑Samples out of temp criteria. Samples on ice, cooling process
has begun
Did samples originate from a foreign source (internationally,
ineludirn, Hawaii and Puerto Rico)? rlYes rINo
Comments/Discrepancy:
Chain of Custody Present?
Zryes
❑No
[]NIA
11
Samples Arrived within Hold Time?
2fYes
❑No
❑N/A
2.
Short bald Time Analysis (<72 hr.)?
❑Yes
EfNo
❑N/A
3.
Rush Turn Around Time Requested?
❑Yes
No
❑N/A
4.
Sufficient Volume?
Zes
[]No
❑NIA
5.
Correct: Containers Used?
-Pace Containers Used?
Yes
Yes
[:]No
[]No
❑N/A
❑N/A
G.
Containers Intact?
OYes
❑No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
[]No
N/A
8.
Sample Labels Match COO
-Includes Date/Time/iD/Analysis Matrix:
Yes
(�;T
❑No
❑N/A
9,
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❑Yes
RINa
❑N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
[]Yes
❑Yes
Pa
ONo
❑N/A
6N/A
11.
COMMENTS/SAMPLE D15CREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager 5RF Review:
Lot ID of split containers:
Date/Time:
r1Y u u4 R iu11Cu.- "i— —
Date:
Date: a�
Page 75 of 132
Qualtrax ID: 69614 Page 1 of 2

4DC# Title: ENV-FRM-HUN1.0083 v01_Sample Condition Upon Receipt
,ce
Effective Date: 05112/2022
*Cheek mark top half of box if pH and/or dechlorinatlon is verified and Project
within the acceptance range for preservation samples,
Exceptions: VOA, coliform, TOC, Oil and Grease, ORO/8015 (water) DOC, LLHg
** Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
WO#:92615455
PM: LJP Due Date: 08/01/22
CLIENT: 93-Glatfelte
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Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina UENR Certitication urnce;i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 76 of 132
Qualtrax ID: 69614 Page 2 of 2

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Page 77 of 132

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Page 78 of 132

f� DC#_Title: ENV-FRM-HUNI.0083 vOI Sample Condition Upon Receipt
f xvuracsEe-srrs
Effective Date: 0511212022
Laboratory recei,.ring samples:
Asheville Eden❑ Greenwood ❑ Huntersville ❑ Raleigh[] Mechanicsville[] Atlanta❑ Kernersville❑
sample Condition Client Name:
ReceiptUpon Project #:
Courier:
❑ Commercial
Ie, L T ( .r
❑Fed Ex ❑UPS ❑LISPS []Client
eErpace ❑Other:
Custody Seal Present? ❑Yes [5N!6-- Seals Intact?
Packing Materlal: Pubble Wrap Bubble Bags
Des 6]No
Date/Initials Person Examining Contents: 7 r `� —�
❑None ❑ Other
Thermome:
IR Gun ID: a7 r(i "7 f Type of Ice: et
Correction Factor,
cooler Temp: - Lf Add/Subtract(°C) 0
Cooler Temp Corrected ('C):
USDA Regulated 50il (L2'19/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or 5C
!,K.,rr .ri 0? I—lYac 17[Nn
❑Blue ❑None
Biological Tissue Frozen?
❑Yes ❑fJa L71''
Temp should be above freezing to 6°C
05arnples Out of temp criteria. Samples on ice, cooling process
has begun
Did samples originate from a foreign source (internationally,
including Hdwail and Puerto Ricol? ❑Yes MNo
Comments/Discrepancy:
Chain of Custody Present?
Yes
[]No❑NIA
1.
Samples Arrived within Hold Time?
_ey�s
EINNo
❑fit/A
2.
Short Hold Time Analysts (<72 hr.)?
❑Yes
EjNo,
❑N/A
3.
Rush Turn Around Time Requested?
❑Yes
ETNO
❑N/A
4.
Sufficient Volume?
es
❑No
[]N/A
5.
Correct Containers Used?
-Pace Containers Used?
10yes
EYees
[]No
❑No
❑N/A
❑N/A
6.
Containers Intact?
es
[:]NO
[]NIA
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
❑No
I/A
8.
Sample Labels Match CDC?
-Includes Date/Time/ID/Analysis Matrix:
;D'�es
I
❑No
❑N/A
9.
HeadspaceinVOA Vials (?5-6mm)?
[—]Yes
[]N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
Z es
Yes
❑No
❑No
❑NIA
❑N/A
11.
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Revlew:
Project Manager SRF Review:
Lot ID of split containers:
Date/Ti me:
rieiouatanequirear fires uno
Rate: 000
Date:
Page 79 of 132
Qualtrax ID: 69614 Page 1 of 2

Aac
DC#r—Title: ENV-FRM-HUNT-0083 v0l Sample Condition Upon Receipt
Ee
Effective Date: 0 511212 022
*Check mark top half of box if pH and/or dechlorination is verified and
within the acceptance range for preservation samples.
Exceptions: VOA, colitorm, TOC, Oil and Grease, DROf8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
Project #
_
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot #
Note: Whenever there is adiscrepancy affecting North Carolina compliance samples, a copy of this farm will be sent to the North Carolina DENR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 80 of 132
Qualtrax ID: 69614 Page 2 of 2

0
aceAnalytical
Report of Analysis
Pace Analytical Services, LLC
2225 Riverside Drive
Asheville, NC 28804
Attention: Lord Patton
Project Name: Sludge LF 7-18
Project Number: 92615455
Lot Number:XG20027
Date Completed:07/28/2022
07/28/2022 4:16 PM
Approved and released by:
Project Coordinator 1: Jenna S. Holliday
pCC/►F0
ANSI National Accreditation Board
qe�
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 81 of 132
Page 1 of 12

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Pace Analytical Services, LLC
Lot Number: XG20027
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 82 of 132
Page 2 of 12

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Pace Analytical Services, LLC
Lot Number: XG20027
Project Name: Sludge LF 7-18
Project Number: 92615455
Sample Number Sample ID Matrix Date Sampled Date Received
001 SWP-1 Aqueous 07/18/20221325 07/20/2022
002 SWP-2 Aqueous 07/18/20221420 07/20/2022
(2 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 83 of 132
Page 3 of 12

PACE ANALYTICAL SERVICES, LLC
Detection Summary
Pace Analytical Services, LLC
Lot Number: XG20027
Project Name: Sludge LF 7-18
Project Number: 92615455
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 SWP-1 Aqueous Mercury(CVAFS) 1631E 3.43 ng/L 5
(1 detection)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 84 of 132
Page 4 of 12

Mercury (CVAFS)
Client: Pace Analytical Services, LLC Laboratory ID:XG20027-001
Description: SWP-1 Matrix: Aqueous
Date Sampled:07/18/2022 1325 Project Name: Sludge LF 7-18
Date Received:07/20/2022 Project Number: 92615455
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631 E 1 07/23/2022 1000 KSH2 07/22/2022 1435 48798
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Mercury (CVAFS) 7439-97-6 1631 E 3.43 0.500 ng/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 12
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page 85 of 132

Mercury (CVAFS)
Client: Pace Analytical Services, LLC Laboratory ID:XG20027-002
Description: SWP-2 Matrix: Aqueous
Date Sampled:07/18/2022 1420 Project Name: Sludge LF 7-18
Date Received:07/20/2022 Project Number: 92615455
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631 E 1 07/23/2022 1005 KSH2 07/22/2022 1435 48798
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Mercury (CVAFS)
7439-97-6 1631E ND 0.500
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 12
ng/L 1
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page 86 of 132

QC Summary
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: XG20027
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 87 of 132
Page 7 of 12

Mercury (CVAFS) - MB
Sample ID: XQ48798-001 Matrix: Aqueous
Batch:48798 Prep Method:
Analytical Method: 1631 E Prep Date: 07/22/2022 1435
Parameter Result Q Dil LOQ Units Analysis Date
Mercury (CVAFS) ND 1 0.500 ng/L 07/23/2022 0820
LOQ = Limit of Quantitation
ND = Not detected at or above the LOQ
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 12
QC Data for Lot Number: XG20027
Page 88 of 132

Mercury (CVAFS) - LCS
Sample ID: XQ48798-002 Matrix: Aqueous
Batch:48798 Prep Method:
Analytical Method: 1631 E Prep Date: 07/22/2022 1435
Spike
Amount Result %Rec
Parameter (ng/L) (ng/L) Q Dil % Rec Limit Analysis Date
Mercury (CVAFS) 5.00 5.43 1 109 75-125 07/23/2022 0831
LOQ = Limit of Quantitation
ND = Not detected at or above the LOQ
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 12
QC Data for Lot Number: XG20027
Page 89 of 132

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 90 of 132
Page 10 of 12

PACE ANALYTICAL SERVICES, LLC
t
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 12
Page 91 of 132

PACE ANALYTICAL SERVICES, LLC
Sam FALs Receipt Checklist 6,K) IMWOLBC-L5) Revised:9{29
�r ArkTp7 7� Issui:,aAuVor[ty_Nick! ENV-'lJCCL PW.
Ample Receipt Checklist (SRQ
Olieq' Cooler 3n; ected yldate-LC { UrAMW2 Lot #: XC-21)027
cans of rcLci t: Pa-" Ljcilellt IJM LdFadTx 0t11er. - --
J
Yeshie
1. Were custody seals pmseatt ort the mol er? --
JI' costary Seals ware PrCSM, wore thOy intact and r:nbrOken? _.._.
t
Noj
h Al2_
Strip TD: } Chlorine Strip ID _—_-- T a[cd by; ran —
FHY
Original tetnneralum upun receipt 1 Derived 4Connwed) teirpeaatum, r:por rewipl- OAS;olid Snap -Cup 1J1: MA -
22.7 f21 7 aC T A j A -C NA ++VA cC NA DNA °C
echod; ©Tcxnperututc 13iaatk ✓ ' P inst Botfies iR rcurt jr)- I R [;,1n Coma-,ticuz Factor: E °C
la4ed7nlc,r'«xxlsrnt; ❑ tVetic Tceltcls ❑ Tc tl�rnr
❑ Yes
L*' I Yes
❑1+In
QNA
3. J€trmFcratum of any cooJer exceeded 6_01C, was Pmje+cc Mar.ngot Not[f'cd7 ----
PM wm Not ificd by,. phony I ernsi I i face-to-Fwe (d role oil e)-
4. Js the cwnmerciat courier's pack=ng slip Allmh.�J ui 1his foern7 - -- -
5, Wm propar cwtudy procadures (reiinquishedirnO-,oa) :ullowcdl
LTKA
Yes
No
J
Yes
TTv
6, W= sample 1Us listed on the CCJC2
3. %Were. sample TDs listed Va all sample containets7 — -
6. WZ& COHEniAn d M0 & time fisted on tha UOC? i
9_ %V s cvl1e4ifii d; kl & time listed on alJ sari* eouta[ners? A - -
Yes
1'es
L11401
hlu
Q Ye"
No
Yes
IJO
10_ Did al. €onttincr Jabal information (1D. date, time) agree with ,}ro,; Co('-)
'es
EIN,1
[ 1. WCr o fex4ta IxJ. W pq•fornrrd llstod on Me COCF
12. Did all sarnpies arrive iil the prnF.--a r c-etainrrs for each test andlor in goed conditioa -
(3131)rrAen, Iiclsain,elr•_}7
J❑Y9s
❑ No
❑ Yes
No
13. Was adequate sarEp le vniumc available?
Yi
ld_Vdtweall saaclriesrecxibud'W4hinV,IhrhiMingtime or40hotim,whiclf%,eroomesfr;i%
Yes
r Info
35. Were mmm las c--Mtaitrers (cimk onc) &amj[os Nat fisted ❑n C F i
❑''es
❑ No
71NA
�.111
16. 1'or VnA and RSK-175 sar.kplas, wife lsubb1e_s pr 8nt GUM] in dia ietN-)
ctny of th-c VOA aImI l
Yc3
`fes
No
Or NA
17. Wcrc a=1 DRt]lmetzWn! trienL Urn les Mzte ad ar a rH ofC 7.?
! NAl '
1 S. Wereall c.�anide same les rece 11'ed aL 3 PH > 12 and su Itld9 sample: received at a pM > 97
❑ Yes
❑ No
2]NA
lne!;[Atal
1$. Were ar app tea a NH31TKMcyanr e7ld,ernut1625_l,h6O$-3 (e 0-.5-n&+ sump m
d11Qrh-e`?
❑yCS
CNo
❑NAB
' Were elide remwkalmquesla (id:, Tcquc=ddVufiuns, h1S1M.SDJe_Rignalinrrs, elc„_)
ct►rrecl.y lnmuribcd EmEn the COC irroa the cammert section in TANTS'
Yea
No
21, 'N�s the quote number lisred on tha concainec 1.3be-
Samplie ProsorvAtiOR (P1 w' be ccanplacd for any samplo(s) incpmrVy pre.;,e-ad or with htadep:ter..)
sample(s) x^-_ _ -. urere mueivW invurmutl;y pruscmud and wore aijinted accordingly
in sample receiving with INA InL 04Arele one: H2SO4, HNO3, HC.i, NPOH usiu� SR 9 �A -------
Dine of pr'eS nratiolf NA [f MM lhdn are pr�9eryadve is net�Cell, p.casa nt0x in the cummRots WOW.
SMnple(s) NA —_ _.. _ were received with bLtlrbles>61nnr in diarnefer.
Sahtiplos(s) 1"' wL�i ec[vll ti4itfr TRC > b.S nrIL {IfJX:9 Lc ao j aridwe,
adjugmd acczrdingly in sample receivingwid-I sand=urr thins-jlfatz(Na,58C13)w[th LShe21y ID:
P barcode labels appFed tvy- TBC --- Date- OPXY21322 -
IS
C�mmenls;
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 92 of 132
Page 12 of 12

0
aceAnalytical
Report of Analysis
Pace Analytical Services, LLC
2225 Riverside Drive
Asheville, NC 28804
Attention: Lord Patton
Project Name: Sludge LF 7-18
Project Number: 92615455
Lot Number:XG21012
Date Completed:07/27/2022
07/28/2022 4:22 PM
Approved and released by:
Project Coordinator 1: Jenna S. Holliday
pCC/►F0
ANSI National Accreditation Board
qe�
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 93 of 132
Page 1 of 14

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Pace Analytical Services, LLC
Lot Number: XG21012
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 94 of 132
Page 2 of 14

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Pace Analytical Services, LLC
Lot Number: XG21012
Project Name: Sludge LF 7-18
Project Number: 92615455
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
Q06V09
Aqueous
07/19/20221200
07/21/2022
002
Q06V10
Aqueous
07/19/20221030
07/21/2022
003
Q06V11
Aqueous
07/19/20221100
07/21/2022
004
FIELD BLANK
Aqueous
07/19/2022 1200
07/21/2022
(4 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 95 of 132
Page 3 of 14

PACE ANALYTICAL SERVICES,
LLC
Detection Summary
Pace Analytical Services, LLC
Lot Number: XG21012
Project Name: Sludge LF 7-18
Project Number: 92615455
Sample Sample ID
Matrix Parameter Method
Result Q
Units Page
001 Q06V09
Aqueous Mercury (CVAFS) 1631E
5.08
ng/L 5
002 Q06V10
Aqueous Mercury(CVAFS) 1631E
11.7
ng/L 6
003 Q06V11
Aqueous Mercury(CVAFS) 1631E
6.81
ng/L 7
(3 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 96 of 132
Page 4 of 14

Mercury (CVAFS)
Client: Pace Analytical Services, LLC Laboratory ID:XG21012-001
Description: Q06V09 Matrix: Aqueous
Date Sampled:07/19/2022 1200 Project Name: Sludge LF 7-18
Date Received:07/21/2022 Project Number: 92615455
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 10 07/26/2022 0857 JAB2 07/25/2022 1030 48927
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Mercury (CVAFS) 7439-97-6 1631E 5.08 5.00 ng/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 14
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page 97 of 132

Mercury (CVAFS)
Client: Pace Analytical Services, LLC Laboratory ID:XG21012-002
Description: Q06V10 Matrix: Aqueous
Date Sampled:07/19/2022 1030 Project Name: Sludge LF 7-18
Date Received:07/21/2022 Project Number: 92615455
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 10 07/26/2022 0903 JAB2 07/25/2022 1030 48927
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Mercury (CVAFS) 7439-97-6 1631E 11.7 5.00 ng/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 14
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page 98 of 132

Mercury (CVAFS)
Client: Pace Analytical Services, LLC Laboratory ID:XG21012-003
Description: Q06V11 Matrix: Aqueous
Date Sampled:07/19/2022 1100 Project Name: Sludge LF 7-18
Date Received:07/21/2022 Project Number: 92615455
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 10 07/26/2022 0908 JAB2 07/25/2022 1030 48927
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Mercury (CVAFS) 7439-97-6 1631E 6.81 5.00 ng/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 14
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page 99 of 132

Mercury (CVAFS)
Client: Pace Analytical Services, LLC Laboratory ID:XG21012-004
Description: FIELD BLANK Matrix: Aqueous
Date Sampled:07/19/2022 1200 Project Name: Sludge LF 7-18
Date Received:07/21/2022 Project Number: 92615455
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 07/26/2022 0914 JAB2 07/25/2022 1030 48927
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Mercury (CVAFS)
7439-97-6 1631E ND 0.500
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 14
ng/L 1
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Page 100 of 132

QC Summary
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: XG21012
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 101 of 132
Page 9 of 14

Mercury (CVAFS) - MB
Sample ID: XQ48927-001 Matrix: Aqueous
Batch:48927 Prep Method:
Analytical Method: 1631E Prep Date: 07/25/2022 1030
Parameter Result Q Dil LOQ Units Analysis Date
Mercury (CVAFS) ND 1 0.500 ng/L 07/26/2022 0841
LOQ = Limit of Quantitation
ND = Not detected at or above the LOQ
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 14
QC Data for Lot Number: XG21012
Page 102 of 132

Mercury (CVAFS) - LCS
Sample ID: XQ48927-002
Matrix:
Aqueous
Batch:48927
Prep Method:
Analytical Method: 1631E
Prep Date:
07/25/2022 1030
Spike
Amount
Result
%Rec
Parameter
(ng/L)
(ng/L) Q Dil
% Rec Limit Analysis Date
Mercury (CVAFS)
5.00
5.53 1
111 75-125 07/26/2022 0852
LOQ = Limit of Quantitation
ND = Not detected at or above the LOQ
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 14
QC Data for Lot Number: XG21012
Page 103 of 132

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 104 of 132
Page 12 of 14

PACE ANALYTICAL SERVICES, LLC
a ■
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 14
Page 105 of 132

PACE ANALYTICAL SERVICES, LLC
Sarnples Receipt Cher:klisr�:SRQ (MEOt}1$C- L5j kevisud.!3 f 29f 2
W !ssuingAutlxFrily: Pace ENV WCOL Page 1
Sample Receipt Cheekffist (SRC-)
C HLnt! P;ux { ooler Iris ettxj b 'fdatc. 7Pf` 141L U2022 I of 4 XC321012
olds ofrcoeirt face U, t UP FedSxOthcr:
Yes No i. Vdeee custt}� seats prat W the evoler"
E Yes Fj N0 NAB 2. IfOWWdW seal suar +scnt.were li • oltactar:d rrnhmlknn`?
pl1 Strip Tf): � Ch]crinv titrip ID. "r., Testec] b }..i
_.
Original Inrnpeintui-8 upon receipt.' Deri-Bd (Ccrrecf d) tCm�} 1rP, upon reeeilrt NSoAd Snap-Cl2p TD: vA
5•¢ 1 {[ h_A } VA a, -NA fCIA tC NA + hA or
Method'. r7T,-mperature Blank [✓ 4 irh P.rml� ]F Cun ID: _ fht C;un Correa ucn FActor: 0 �c
1 cfhod of caolimt EJ Wcl- Ice P lrs ❑ Dry Tce sue - —
Ycs ] No Q1hTa, 3. If terlperat>arc afa11 a,,1cr Cx eceJ 6,L� C, xas Project 7arager Neu.-Lud'�
r
FLA was 101tfi d .. pfxmn } P11k911 facc-to-face (circle one).
Yes
l]t� NA
4_ K the o mmercW oour[GrE pEr:king slip attached W Ili is farm?
-5. Werc piuper ewapdy procedures (rclin ishejh3=usivad) tb,]oweti?
5. WON sam le TDs listed on The C OC?
d Ye.;
Na
Nl0
{ Yet
✓' Yen
NI0
7_ WcrL earn le IDs lisred on all sumpl- containers?
9. W83 collection df,lx: these I iSted on the coc? -
.71 Y
N0
i /I Yes
Na
9, Wak coll(�c#iou date & Ime listed ort a]I sali ple cwttain-;r37
Yes
N1a
10. Did 0 container 1 1 informatiot, [II], dam, time) ;IQrce. wi'1t 11FG COC,�
No
J YES
I1_ WOM tast3 to 1c:pufonncd I:Fied on the-COC?
W1 Yen
El No
1?, Did kill -j1q,3 arrive in the proper conlaincrs for each t+✓St an(Vej- i i i good eonditbrt
(unbroken, li& on, eta.)? —
L!�JYe,� LJNc? 3. NYW aregttatCsumpie volumr available? -
YeF El No 114. Wwc all sarnp]es re;,eiued wilhin the hnld`mg tirne of 4S hours, WH011 n:F c3a flu: I irv''
Lj Yam; VJ No ] i. Wrm any snrriplo containers miss' excrNs (.7ircle org samples too! Iis"l c„ C-C)C?
I Yes [ Nu DNA 15. Fur VUA and TASK-175 S31❑pilCV, were bublilns preselrt?"pea-sloe:' (114':W'6trim in F
to any oftha YCIA ,13?
'Cs Ra 7NA 17. kVere kill 1}�4imeialsinuirientsale -,m received ate H of :2?
'Ycs NO NA l 8_ e,-c all cyanide stun les reoeiv,-d at t pl I > T 2 arld sulfide sdrri pl" reoei kred �t a pli � n?
EYcs O:Nu 0t A "- Were all al,plic,a ]eltiFi,ItKNleyanidelplleno G25_I�b78,3 { 0_Sm;rJL) satrap vs Frir7 i
Yes EIN' Do' 7d,� 1 2'J. W2recikmt mmarks}rcxpo s (i.c. ri-giimrrd dihidons, ms"MSDdeg lgnatiou.3, eic,,.)
ssnrrectly 1rr-vseribed fi4Arl &; COC. i'W tho cominm suction in LINTS?
Yn NIJ 21. Was the quata natnbcv listed on lhr container lah�1? Irves. Queue i€
ply. i'mervation (Must bec,Knplrted forarty saialtpla A) dnNgTectly prv9ervc30rmlitlt ht`adspaoe_)
r"r'wk�jy ... were re"Ived inaarrectiy prescrv2d and vimr.. adjusted aee;jed.in!1I%..�
sample rc.�Viving with NA _mL ofi,Arple one. H2SC4, HNO3, T-TCJ, lvaoi l ua'.tkg SR g "A
ME r1 F pre5e€va1ian NA If more fl= One prrscrVative iS MCdej, pl CLINL' rote in the t.um.menk5 k; clew.
RA
NA
warn receiv!d WA hubbles>6 Tnin iji Jiarno,&.
:}f-. mere feCtivedIVIIII, TRC. > 0.v tng+'L (I
acC4d&R91y in somplc receiving with sodiurn Ih65ulfare (Nft2S2%' with Shealy !D: NA
barootk labels appiic! by- TEC 1 Ix: 07221112M
Comments:
ilzuI and we1-e
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 14 of 14
Page 106 of 132

AtalyticaliM
�
www.pacelabs.com
Report Prepared for:
Lorri Patton
PACE Charlotte
9800 Kincey Avenue
Huntersville NC 28078
REPORT OF
LABORATORY
ANALYSIS FOR
TCDD
Report Prepared Date:
August 2, 2022
Pace Analytical Services, LLC.
1700 Elm Street
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
Report Information:
PaceProject#:10617699
Sample Receipt Date: 07/20/2022
Client Project #: 92615455 Glatfelter Cor
Client Sub PO #: N/A
State Cert #: N/A
Invoicing & Reporting Options:
The report provided has been invoiced as a Level 2
2,3,7,8-TCDD Report. If an upgrade of this report
package is requested, an additional charge may be
applied.
Please review the attached invoice for accuracy and
forward any questions to Matt Ray, your Pace Project
Manager.
This report has been reviewed by:
4XC7
August 02, 2022
Matt Ray,
(fax)
Report of Laboratory Analysis
Thi sreport shouldn o tbereproduced, exc eptinfull,
withoutthewrittenconsentotPaceAnalyticalServices,Inc.
The results reIate onIytothesamp lesincluded inthis report.
Page 107 of 132
Report No ..... 10617699_1613TCDD_DFR Page 1 of 26

aceAnalytical
DISCUSSION
Pace Analytical Services, LLC.
1700 Elm Street
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
This report presents the results from the analyses performed on five samples submitted
by a representative of Pace Analytical Services, LLC. The samples were analyzed for
the presence or absence of 2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD) using
USEPA Method 1613B. The reporting limits were set to correspond to the lowest
calibration point and a nominal 1-Liter sample amount, and the sensitivity was verified
by signal-to-noise measurements. The quantitation limits, adjusted for sample
extraction amount, may be somewhat higher or lower than the reporting limits provided
in this report.
The isotopically -labeled TCDD internal standard in the sample extracts was recovered
at 49-71 %. All of the labeled standard recoveries obtained for this project were within
the target ranges specified in Method 1613B. Also, since the quantification of the native
TCDD was based on isotope dilution, the data were automatically corrected for
recovery and accurate values were obtained. Values obtained from the analysis of a
diluted extract were flagged "D".
A laboratory method blank was prepared and analyzed with each sample batch as part
of our routine quality control procedures. The results show the blanks to be free of
2,3,7,8-TCDD at the reporting limit.
Laboratory spike samples were also prepared using clean reference matrix that had
been fortified with native standard material. The results show that the spiked native
TCDD was recovered at 93-110% with a relative percent difference of 0.0-6.2%. These
results were within the target ranges for the method. Matrix spikes were not prepared
with the sample batch.
REPORT OF LABORATORYANALYSIS
This report shall not be reproduced, except in full,
withoutthe written consentof Pace Analytical Services, Inc. Page 108 of 132
Report No ..... 10617699_1613TCDD_DFR Page 2 of 26

Pace Analytical Services, LLC
TM 1700 Elm Street - Suite 200
fr. al Minneapolis, MN 55414
Tel:[phone]
Fax: [phone]
Minnesota Laboratory Certifications
Authority
Certificate #
Authority
Certificate #
Mississippi
MN00064
Missouri
10100
A21LA
2926.01
Montana
CERT0092
Alabama
40770
Nebraska
NE-OS-18-06
Alaska-DW
MN00064
Nevada
MN00064
Alaska -UST
17-009
New Hampshire
2081
Arizona
AZ0014
New Jersey
MN002
Arkansas - WW
88-0680
New York
11647
Arkansas-DW
MN00064
North Carolina-
27700
California
2929
North Carolina-
530
Colorado
MN00064
North Dakota
R-036
Connecticut
PH-0256
Ohio-DW
41244
Florida
E87605
Ohio-VAP (170
CL101
Georgia
959
Ohio-VAP (180
CL110
Hawaii
MN00064
Oklahoma
9507
Idaho
MN00064
Oregon- rimary
MN300001
Illinois
200011
Oregon -Second
MN200001
Indiana
C-MN-01
Pennsylvania
68-00563
Iowa
368
Puerto Rico
MN00064
Kansas
E-10167
South Carolina
74003
Kentucky-DW
90062
Tennessee
TN02818
Kentucky-WW
90062
Texas
T104704192
Louisiana-DEQ
AI-84596
Utah
MN00064
Louisiana-DW
MN00064
Vermont
VT-027053137
Maine
MN00064
Virginia
460163
Maryland
322
Washington
C486
Michigan
9909
West Virginia-D
382
Minnesota
027-053-137
West Virginia-D
9952C
Minnesota-Ag
via MN 027-053
Wisconsin
999407970
Minnesota-Petr
1240
Wyoming -UST
via A21LA 2926.
REPORT OF LABORATORYANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page 109 of 132
Report No ..... 10617699_1613TCDD_DFR Page 3 of 26

ace Analytical
Appendix A
Sample Management
REPORT OF LABORATORY ANALYSIS
Pace Analytical Services, LLC
1700 Elm Street, Suite 200
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
www.pacelabs.com
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Report No ..... 10617699_1613TCDD_DFR
Page 110 of 132
Page 4 of 26

Internal Transfer Chain of Custody
11111 I11 EI 11I 1I� 111 EiI 1111 1I F—]samples Pre -Logged into °°°°
Workorder: 92615455 Workorder Name: Sludge LF 7/18
State Of Origin: NC aceAnalytical o
www.pacelabs.com
Cert. Needed: ❑ Yes ❑ No
Owner Received Date: 7/18/2022 Results Requested By: 8/1/2022
Report To
Subcontract To
Requested Analysis
Lord Patton
Pace Analytical Minnesota
Pace Analytical Asheville
1700 Elm Street SE
2225 Riverside Dr.
Suite 200
0
Asheville, NC 28804
Minneapolis, MN 55414
°
Phone [phone]
Phone [phone]
N
Preserved Containers
0
n
>
a
c
Sample
Collect
Item
Sample ID
Type
Date/Time
Lab ID
Matrix
o
LAB USE ONLY
1
SWP-1
PS
7/18/202213:25
92615455001
Water
1
X
2
SWP-2
PS
7/18/202214:20
92615455002
Water
1
X
3
Q06V09
PS
7/19/202212:00
92615455003
Water
1
X
4
Q06V10
PS
7/19/202210:30
92615455004
Water
1
X
5
Q06V11
PS
7/19/202211:00
192615455005
1Water
1
X
Comments
Transfers
Released By
Date/Time
Received By
Date/Time
1
2
3
Cooler Temperature on Receipt
°C TCustody
Seal Y or N
Received on Ice Y or N
Samples Intact Y or N
***In order to maintain client confidentiality, location/name of the sampling site, sampler's name and signature may not be provided on this COC document.
This chain of custody is considered complete as is since this information is available in the owner laboratory.
Thursday, July 21, 2022 1:06:55 PM
FMT-ALL-C-002rev.00 24March2009
Report No ..... 10617699_1613TCDD_DFR Page 5 of 26
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w

n
DC#_Title: ENV-FRM-MIN4-0150 v05_Sample Condition Upon Receipt
(SCUR)
wwgx `"uw"
Effective Date: 04/12/2022
Client Name: Project #:
P�� l��-
Courier: fed Ex [—]UPS❑USPS ❑Client
❑Pace ❑SpeeDee ❑Commercial
See Exceptions
71 ��a°�Cc� EZ V-FRM-MIN4-
Tracking Number: (/
Custody Seal an Cooler/Box Present? 2rs ❑No Seals Intact? es []No
Packing Material: kErBubble Wrap ,%ubble Bags ❑None
Thermometer: ❑ T1(0461) ❑ T2(1336) 3(0459) ❑ T4(0254) ❑ T5(0489) ❑ T6(0235)
1- 1 T7100421 1- 1 01339252/1710 F1122639816 F1140792808
Biological Tissue Frozen? [-]Yes [-]No ZIN/A
❑Other: Temp Blank? Yes ❑No
Type of tro• et ❑Blue ❑None ❑Dry ❑Melted
Did Samples Originate in West Virginia? Dyes < Were All Container Temps Taken? ❑Yes ❑No
Average Corrected ❑see Exceptions
C
Temp (no temp blank ENV-FRM-MIN4-0142
Temp should be above freezing to/6°C Cooler Temp Read w/temp blank: 3- t oC
only): oC ❑1 Container
Correction Factor: flue, Cooler Temp Corrected w/temp blank: aC
USDA Regulated Soil: water sample% : ) Date/Initials of Person Examining Contents: "Zf - 2 ;1-_il =
nidsamples-originate-in-a= ain the-U.nited-5tates-ALTAR-C-ArELrGATID,_LA Didsamples-originate-fcoma-foreignsourconternationally-including
MS, NC, NM, NY, OK, OR, SC, TN, TX or VA (check maps)? ❑Yes ❑No Hawaii and Puerto Rico)? Dyes ❑No
If Yes to either question, fill out a Regulated Soil Checklist ENV-FRM-MIN4-0154 and include with SCUR/COC paperwork.
Location (check one): 0 Duluth 0Minneapolis ❑ Virginia
COMMENTS:
Chain of Custody Present and Filled Out?
Yes
❑No
1.
Chain of Custody Relinquished?
es
No
2.
Sampler Name and/or Signature on COC?
Yes
No
N/A
3.
Samples Arrived within Hold Time?
.214-es
❑No
4. If Fecal: 171<8 hrs >8hr, <24 hrs, 0>24 hrs
Short Hold Time Analysis (<72 hr)?
[]Yes
Af No
5. ❑Fecal Coliform ❑HPC ❑Total Coliform/E coli ❑BOD/cBOD
❑Hex Chrome
Turbidit Nitrate Nitrite Ortho hos Other
Rush Turn Around Time Requested?
❑Yes
No
6.
Sufficient Volume?
es
❑No
7.
Correct Containers Used?
es
❑No
8. 1 Li D�,{� �j'LYi'Y1���j
-Pace Containers Used?
RNo
Containers Intirt?
Yes
FIN.
Field Filtered Volume Received for Dissolved Tests?
❑Yes
❑No
1/A
10. Is sediment visible in the dissolved container? Dyes ❑No
Is sufficient information available to reconcile the
11. If no, write ID/ Date/Time on Container Below:
See Exception ❑
samples to the COC?
,Yes
❑No
ENV-FRM-MIN4-0142
Matrixzwater ❑Soil ❑Oil ❑Other-
AII containers needing acid/base preservation have
❑Yes
❑No
N/A
12. Sample #
been checked?
All containers needing preservation are found to be in
compliance with EPA recommendation?
❑Yes
❑No
,fN/A
❑ NaOH ❑ HNO3 ❑H2SO4 ❑Zinc Acetate
(HNO3, H2SO4, <2pH, NaOH >9 Sulfide, NaOH>10
Cyanide)
Exceptions: VOA, Coliform C/DOC Oil Grease,
�es
[:]No❑N/A
Positive for Res. ❑Yes
See Exception ❑
ENV-FRM-MIN4-0142
and
Chlorine? [:]No pH Paper Lot#
DRO/8015 (water) loxi PFAS
Res. Chlorine
0-6 Roll
0-6 Strip
0-14 Strip
Headspace in Methyl Mercury Container?
❑Yes
❑No
/A
Extra labels present on soil VOA or WIDRO containers?
❑Yes
❑No
/A
13.
See Exception ❑
Headspace in VOA Vials (greater than 6mm)?
❑Yes
❑No
N/A
ENV-FRM-MIN4-0140
Trip Blank Present?
❑Yes
❑No
ZWA
14.
Trip Blank Custody Seals Present?
❑Yes
❑No
N/A
Pace Trip Blank Lot # (if purchased):
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Resolution:
A
Date/Time:
Field Data Required? ❑Yes ❑No
Project Manager Review: Date: 07/22/22
Note: Whenever there is a discrepancy affecting North Car Ina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (L of hold, incorrect
preservative, out of temp, incorrect containers). Labeled by:
_ Qualtrax ID: 52742 — _ Paae 1 Of-1 Page 113 of 132
epo o..... _ _ age 7 o

AAnalvtical�
Reporting Flags
A = Reporting Limit based on signal to noise (EDL)
B = Less than 1 Ox higher than method blank level
C = Result obtained from confirmation analysis
D = Result obtained from analysis of diluted sample
E = Exceeds calibration range
= Isotope ratio out of specification
J = Estimated value
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
L = Suppressive interference, analyte may be biased low
Nn = Value obtained from additional analysis
P = PCDElnterference
R = Recovery outside target range
S = Peak saturated
U = Analyte not detected
V = Result verified by confirmation analysis
X = %D Exceeds limits
Y = Calculated using average of daily RFs
* = See Discussion
10I l- f 1.11 Afill]
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, Page 114 of 132
without the written consentof Pace Analytical Services, Inc.
Report No ..... 10617699_1613TCDD_DFR Page 8 of 26

ace Analytical
Appendix B
Sample Analysis Summary
REPORT OF LABORATORY ANALYSIS
Pace Analytical Services, LLC
1700 Elm Street, Suite 200
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
www.pacelabs.com
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Report No ..... 10617699_1613TCDD_DFR
Page 115 of 132
Page 9 of 26

Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Dry Weight Extracted
ICAL ID
CCal Filename(s)
Method Blank ID
Native
Isomers
Method 1613B Sample Analysis Results
Client - PACE Charlotte
SWP-1
92615455001
L220727A_17
MS4
961 mL
NA
NA
L220718
L220727A_01
BLANK-100182
Conc EMPC
pg/L pg/L
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Matrix
Water
Dilution
NA
Collected
07/18/2022 13:25
Received
07/20/2022 08:50
Extracted
07/22/2022 11:25
Analyzed
07/27/2022 23:14
RL Internal
ng's Percent
pg/L Standards
Added Recovery
2,3,7,8-TCDD ND ----- 10 2,3,7,8-TCDD-13C 2.00 71
Recovery Standard
1,2,3,4-TCDD-13C 2.00 NA
Cleanup Standard
2,3,7,8-TCDD-37CI4 0.20 101
Conc = Concentration (Totals include 2,3,7,8-substituted isomers). ND = Not Detected
EMPC = Estimated Maximum Possible Concentration NA = Not Applicable
RL = Reporting Limit NC = Not Calculated
R = Recovery outside target range
E= Exceeds calibration range
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10617699_1613TCDD_DFR
Page 116 of 132
Page 10 of 26

Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Dry Weight Extracted
ICAL ID
CCal Filename(s)
Method Blank ID
Native
Isomers
Method 1613B Sample Analysis Results
Client - PACE Charlotte
S W P-2
92615455002
1-22072713_08
MS4
1000 mL
NA
NA
L220718
L220727A_18
BLANK-100182
Conc EMPC
pg/L pg/L
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Matrix
Water
Dilution
NA
Collected
07/18/2022 14:20
Received
07/20/2022 08:50
Extracted
07/22/2022 11:25
Analyzed
07/28/2022 05:42
RL Internal
ng's Percent
pg/L Standards
Added Recovery
2,3,7,8-TCDD ND ----- 10 2,3,7,8-TCDD-13C 2.00 71
Recovery Standard
1,2,3,4-TCDD-13C 2.00 NA
Cleanup Standard
2,3,7,8-TCDD-37CI4 0.20 96
Conc = Concentration (Totals include 2,3,7,8-substituted isomers). ND = Not Detected
EMPC = Estimated Maximum Possible Concentration NA = Not Applicable
RL = Reporting Limit NC = Not Calculated
R = Recovery outside target range
E= Exceeds calibration range
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10617699_1613TCDD_DFR
Page 117 of 132
Page 11 of 26

Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Dry Weight Extracted
ICAL ID
CCal Filename(s)
Method Blank ID
Native
Isomers
Method 1613B Sample Analysis Results
Client - PACE Charlotte
Q06V09
92615455003
U220729A_08
JRH
1020 mL
NA
NA
U220725
U220729A_03
BLANK-100237
Conc EMPC
pg/L pg/L
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Matrix
Water
Dilution
NA
Collected
07/19/2022 12:00
Received
07/21 /2022 08:50
Extracted
07/26/2022 14:15
Analyzed
07/29/2022 19:27
RL Internal
ng's Percent
pg/L Standards
Added Recovery
2,3,7,8-TCDD ND ---- 10 2,3,7,8-TCDD-13C 2.00 49
Recovery Standard
1,2,3,4-TCDD-13C 2.00 NA
Cleanup Standard
2,3,7,8-TCDD-37CI4 0.20 79
Conc = Concentration (Totals include 2,3,7,8-substituted isomers). ND = Not Detected
EMPC = Estimated Maximum Possible Concentration NA = Not Applicable
RL = Reporting Limit NC = Not Calculated
R = Recovery outside target range
E= Exceeds calibration range
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10617699_1613TCDD_DFR
Page 118 of 132
Page 12 of 26

Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Dry Weight Extracted
ICAL ID
CCal Filename(s)
Method Blank ID
Native
Isomers
Method 1613B Sample Analysis Results
Client - PACE Charlotte
Q06V10
92615455004
U220729A_09
JRH
979 mL
NA
NA
U220725
U220729A_03
BLANK-100293
Conc EMPC
pg/L pg/L
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Matrix
Water
Dilution
NA
Collected
07/19/2022 10:30
Received
07/21 /2022 08:50
Extracted
07/27/2022 10:55
Analyzed
07/29/2022 20:14
RL Internal
ng's Percent
pg/L Standards
Added Recovery
2,3,7,8-TCDD ND ---- 10 2,3,7,8-TCDD-13C 2.00 57
Recovery Standard
1,2,3,4-TCDD-13C 2.00 NA
Cleanup Standard
2,3,7,8-TCDD-37CI4 0.20 87
Conc = Concentration (Totals include 2,3,7,8-substituted isomers). ND = Not Detected
EMPC = Estimated Maximum Possible Concentration NA = Not Applicable
RL = Reporting Limit NC = Not Calculated
R = Recovery outside target range
E= Exceeds calibration range
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10617699_1613TCDD_DFR
Page 119 of 132
Page 13 of 26

Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Dry Weight Extracted
ICAL ID
CCal Filename(s)
Method Blank ID
Native
Isomers
Method 1613B Sample Analysis Results
Client - PACE Charlotte
Q06V11
92615455005
U220729A_10
JRH
984 mL
NA
NA
U220725
U220729A_03
BLANK-100293
Conc EMPC
pg/L pg/L
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Matrix
Water
Dilution
NA
Collected
07/19/2022 11:00
Received
07/21 /2022 08:50
Extracted
07/27/2022 10:55
Analyzed
07/29/2022 21:01
RL Internal
ng's Percent
pg/L Standards
Added Recovery
2,3,7,8-TCDD ND ---- 10 2,3,7,8-TCDD-13C 2.00 67
Recovery Standard
1,2,3,4-TCDD-13C 2.00 NA
Cleanup Standard
2,3,7,8-TCDD-37CI4 0.20 80
Conc = Concentration (Totals include 2,3,7,8-substituted isomers). ND = Not Detected
EMPC = Estimated Maximum Possible Concentration NA = Not Applicable
RL = Reporting Limit NC = Not Calculated
R = Recovery outside target range
E= Exceeds calibration range
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10617699_1613TCDD_DFR
Page 120 of 132
Page 14 of 26

Lab Sample Name
Lab Sample ID
Filename
Total Amount Extracted
ICAL ID
CCal Filename(s)
Native
Isomers
TM
�ical
Method 1613B Blank Analysis Results
DFBLKRZ
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
BLANK-100182
Matrix
Water
L220727A_09
Dilution
NA
983 mL
Extracted
07/22/2022 11:25
L220718
Analyzed
07/27/2022 17:30
L220727A 01
Injected By
MS4
Conc EMPC RL Internal ng's Percent
pg/L pg/L pg/L Standards Added Recovery
2,3,7,8-TCDD ND ---- 10 2,3,7,8-TCDD-13C 2.00 60
Recovery Standard
1,2,3,4-TCDD-13C 2.00 NA
Cleanup Standard
2,3,7,8-TCDD-37CI4 0.20 90
Conc=Concentration (Totals include 2,3,7,8-substituted isomers)
EMPC= Estimated Maximum Possible Concentration
RL = Reporting Limit
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10617699_1613TCDD_DFR
Page 121 of 132
Page 15 of 26

Lab Sample Name
Lab Sample ID
Filename
Total Amount Extracted
ICAL ID
CCal Filename(s)
Native
Isomers
TM
�ical
Method 1613B Blank Analysis Results
DFBLKTE
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
BLANK-100293
Matrix
Water
1-22072913_03
Dilution
NA
987 mL
Extracted
07/27/2022 10:55
L220718
Analyzed
07/29/2022 14:12
1-22072913_01
Injected By
JRH
Conc EMPC RL Internal ng's Percent
pg/L pg/L pg/L Standards Added Recovery
2,3,7,8-TCDD ND ---- 10 2,3,7,8-TCDD-13C 2.00 67
Recovery Standard
1,2,3,4-TCDD-13C 2.00 NA
Cleanup Standard
2,3,7,8-TCDD-37CI4 0.20 87
Conc=Concentration (Totals include 2,3,7,8-substituted isomers)
EMPC= Estimated Maximum Possible Concentration
RL = Reporting Limit
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10617699_1613TCDD_DFR
Page 122 of 132
Page 16 of 26

Lab Sample Name
Lab Sample ID
Filename
Total Amount Extracted
ICAL ID
CCal Filename(s)
Native
Isomers
TM
�ical
Method 1613B Blank Analysis Results
DFBLKSN
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
BLANK-100237
Matrix
Water
1`22072913_09
Dilution
NA
981 mL
Extracted
07/26/2022 14:15
F220529
Analyzed
07/29/2022 19:23
F22072913_01
Injected By
JRH
Conc EMPC RL Internal ng's Percent
pg/L pg/L pg/L Standards Added Recovery
2,3,7,8-TCDD ND ---- 10 2,3,7,8-TCDD-13C 2.00 35
Recovery Standard
1,2,3,4-TCDD-13C 2.00 NA
Cleanup Standard
2,3,7,8-TCDD-37CI4 0.20 60
Conc=Concentration (Totals include 2,3,7,8-substituted isomers)
EMPC= Estimated Maximum Possible Concentration
RL = Reporting Limit
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10617699_1613TCDD_DFR
Page 123 of 132
Page 17 of 26

AAnalvtical�
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Method 1613B Laboratory Control Spike Results
Lab Sample ID
LCS-100183
Filename
L220727A_02
Matrix
Water
Total Amount Extracted
1010 mL
Dilution
NA
]CAL ID
L220718
Extracted
07/22/2022 11:25
CCal Filename
L220727A_01
Analyzed
07/27/2022 12:29
Method Blank ID
BLANK-100182
Injected By
MS4
Lower
Upper %
Compound
Cs Cr
Limit
Limit Rec.
2,3,7,8-TCDD
10
11
7.3
14.6
110
2,3,7,8-TCDD-37CI4
10
9.8
3.7
15.8
98
2,3,7,8-TCDD-13C
100
51
25.0
141.0
51
Cs = Concentration Spiked (ng/mL)
Cr = Concentration Recovered (ng/mL)
Rec. = Recovery (Expressed as Percent)
Control Limit Reference: Method 1613, Table 6, 10/94 Revision
R = Recovery outside of control limits
Nn = Value obtained from additional analysis
*=See Discussion
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10617699_1613TCDD_DFR
Page 124 of 132
Page 18 of 26

AAnalvtical�
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Method 1613B Laboratory Control Spike Results
Lab Sample ID
LCS-100294
Filename
F22072913_02
Matrix
Water
Total Amount Extracted
989 mL
Dilution
NA
]CAL ID
F220529
Extracted
07/27/2022 10:55
CCal Filename
F22072913_01
Analyzed
07/29/2022 14:04
Method Blank ID
BLANK-100293
Injected By
JRH
Lower
Upper %
Compound
Cs Cr
Limit
Limit Rec.
2,3,7,8-TCDD
10
9.6
7.3
14.6
96
2,3,7,8-TCDD-37CI4
10
9.1
3.7
15.8
91
2,3,7,8-TCDD-13C
100
66
25.0
141.0
66
Cs = Concentration Spiked (ng/mL)
Cr = Concentration Recovered (ng/mL)
Rec. = Recovery (Expressed as Percent)
Control Limit Reference: Method 1613, Table 6, 10/94 Revision
R = Recovery outside of control limits
Nn = Value obtained from additional analysis
*=See Discussion
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10617699_1613TCDD_DFR
Page 125 of 132
Page 19 of 26

AAnalvtical�
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Method 1613B Laboratory Control Spike Results
Lab Sample ID
LCS-100238
Filename
F22072913_04
Matrix
Water
Total Amount Extracted
1000 mL
Dilution
NA
]CAL ID
F220529
Extracted
07/26/2022 14:15
CCal Filename
F22072913_01
Analyzed
07/29/2022 15:34
Method Blank ID
BLANK-100237
Injected By
JRH
Lower
Upper %
Compound
Cs Cr
Limit
Limit Rec.
2,3,7,8-TCDD
10
9.4
7.3
14.6
94
2,3,7,8-TCDD-37CI4
10
7.0
3.7
15.8
70
2,3,7,8-TCDD-13C
100
39
25.0
141.0
39
Cs = Concentration Spiked (ng/mL)
Cr = Concentration Recovered (ng/mL)
Rec. = Recovery (Expressed as Percent)
Control Limit Reference: Method 1613, Table 6, 10/94 Revision
R = Recovery outside of control limits
Nn = Value obtained from additional analysis
*=See Discussion
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10617699_1613TCDD_DFR
Page 126 of 132
Page 20 of 26

AAnalvtical�
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Method 1613B Laboratory Control Spike Results
Lab Sample ID
LCSD-100184
Filename
L220727B_16
Matrix
Water
Total Amount Extracted
1010 mL
Dilution
5
]CAL ID
L220718
Extracted
07/22/2022 11:25
CCal Filename
L220727A_18
Analyzed
07/28/2022 11:26
Method Blank ID
BLANK-100182
Injected By
SMT
Lower
Upper %
Compound
Cs Cr
Limit
Limit Rec.
2,3,7,8-TCDD
10
11
7.3
14.6
110
D
2,3,7,8-TCDD-37CI4
10
8.7
3.7
15.8
87
D
2,3,7,8-TCDD-13C
100
62
25.0
141.0
62
D
Cs = Concentration Spiked (ng/mL)
Cr = Concentration Recovered (ng/mL)
Rec. = Recovery (Expressed as Percent)
Control Limit Reference: Method 1613, Table 6, 10/94 Revision
R = Recovery outside of control limits
Nn = Value obtained from additional analysis
*=See Discussion
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10617699_1613TCDD_DFR
Page 127 of 132
Page 21 of 26

AAnalvtical�
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Method 1613B Laboratory Control Spike Results
Lab Sample ID
LCSD-100295
Filename
F22072913_03
Matrix
Water
Total Amount Extracted
990 mL
Dilution
NA
]CAL ID
F220529
Extracted
07/27/2022 10:55
CCal Filename
F22072913_01
Analyzed
07/29/2022 14:49
Method Blank ID
BLANK-100293
Injected By
JRH
Lower
Upper %
Compound
Cs Cr
Limit
Limit Rec.
2,3,7,8-TCDD
10
9.3
7.3
14.6
93
2,3,7,8-TCDD-37CI4
10
11
3.7
15.8
112
2,3,7,8-TCDD-13C
100
76
25.0
141.0
76
Cs = Concentration Spiked (ng/mL)
Cr = Concentration Recovered (ng/mL)
Rec. = Recovery (Expressed as Percent)
Control Limit Reference: Method 1613, Table 6, 10/94 Revision
R = Recovery outside of control limits
Nn = Value obtained from additional analysis
*=See Discussion
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10617699_1613TCDD_DFR
Page 128 of 132
Page 22 of 26

AAnalvtical�
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Method 1613B Laboratory Control Spike Results
Lab Sample ID
LCSD-100239
Filename
F22072913_05
Matrix
Water
Total Amount Extracted
997 mL
Dilution
NA
]CAL ID
F220529
Extracted
07/26/2022 14:15
CCal Filename
F22072913_01
Analyzed
07/29/2022 16:20
Method Blank ID
BLANK-100237
Injected By
JRH
Lower
Upper %
Compound
Cs Cr
Limit
Limit Rec.
2,3,7,8-TCDD
10
10.0
7.3
14.6
100
2,3,7,8-TCDD-37CI4
10
7.8
3.7
15.8
78
2,3,7,8-TCDD-13C
100
46
25.0
141.0
46
Cs = Concentration Spiked (ng/mL)
Cr = Concentration Recovered (ng/mL)
Rec. = Recovery (Expressed as Percent)
Control Limit Reference: Method 1613, Table 6, 10/94 Revision
R = Recovery outside of control limits
Nn = Value obtained from additional analysis
*=See Discussion
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10617699_1613TCDD_DFR
Page 129 of 132
Page 23 of 26

a
Client
Spike 1 ID
Spike 1 Filename
Compound
TM
►cal
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Method 1613B
Spike Recovery Relative Percent Difference (RPD) Results
PACE Charlotte
LCS-100183 Spike 2 ID LCSD-100184
L220727A 02 Spike 2 Filename L22072713_16
Spike 1 Spike 2
%REC %REC %RPD
2,3,7,8-TCDD 110 110 0.0
%REC = Percent Recovered
RPD = The difference between the two values divided by the mean value
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10617699_1613TCDD_DFR
Page 130 of 132
Page 24 of 26

a
Client
Spike 1 ID
Spike 1 Filename
Compound
TM
►cal
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Method 1613B
Spike Recovery Relative Percent Difference (RPD) Results
PACE Charlotte
LCS-100294 Spike 2 ID LCSD-100295
F220729B_02 Spike 2 Filename F220729B_03
Spike 1 Spike 2
%REC %REC %RPD
2,3,7,8-TCDD 96 93 3.2
%REC = Percent Recovered
RPD = The difference between the two values divided by the mean value
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10617699_1613TCDD_DFR
Page 131 of 132
Page 25 of 26

a
Client
Spike 1 ID
Spike 1 Filename
Compound
TM
►cal
Pace Analytical Services, LLC
1700 Elm Street - Suite 200
Minneapolis, MN 55414
Tel: [phone]
Method 1613B
Spike Recovery Relative Percent Difference (RPD) Results
PACE Charlotte
LCS-100238 Spike 2 ID LCSD-100239
F220729B_04 Spike 2 Filename F220729B_05
Spike 1 Spike 2
%REC %REC %RPD
2,3,7,8-TCDD 94 100 6.2
%REC = Percent Recovered
RPD = The difference between the two values divided by the mean value
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10617699_1613TCDD_DFR
Page 132 of 132
Page 26 of 26