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HomeMy WebLinkAboutWQ0004298_Permit Application_19940216UNITED STATES ENVIRONMENTAL PROTECTION AGENCY SEWAGE SLUDGE PERMIT APPLICATION TOWN OF MARS HILL MADISON COUNTY, NORTH CAROLINA hkAk M. KEITH WEBB, P.E. McGILL ASSOCIATES, P.A. CONSULTING ENGINEERS ASHEVILLE, NORTH CAROLINA FEBRUARY, 1994 .•��R� N CA Ro t�4 •.....,.p/ /fit✓,n,`�o a • 2 809 o v • O'•FR�G�� hEIV z- ito-94 GENERAL INFORMATION FACILITY NAME Mars Hill Wastewater Treatment Plant OWNER Town of Mars Hill, POTW CONTACT PERSON Darhyl Boone, Town Manager PLANT OPERATOR Robert M. Sams MAILING ADDRESS Post Office Box 368 Mars Hill, North Carolina 28754 TELEPHONE (704) 689-2301 and (704) 689-9850 LOCATION NC Highway 213, west of Mars Hill College Latitude: 350 49' 39", Longitude 820 31' 17" NPDES PERMIT NO. NCO057151 TOPOGRAPHIC LOCATION MAP: Attachment A SEWAGE SLUDGE POLLUTANT CONCENTRATIONS: Attachment B ATTACHMENT A TOPOGRAPHIC LOCATION MAP ATTACHMENT B SEWAGE SLUDGE POLLUTANT CONCENTRATIONS 34 . 1• 1-131- �. B•D • V:0 34 0 ANALYSIS T .p Extraction Arsenic-J C Baritm -T LP Cadmiumar P Qzramitm aAMP Lead-rCLP Mercury-rCLP Selenitmt TCLP Silver-TCIP Total Solids chloride Nitrate as N + Nitrite as N Sulfate Total Phosphorus Total Kjeldahl Nitrogen organic Nitrogen Ammonia as N pH Lead Capper Cadmium Sodium Magnesium potassium Zinc Nickel chromium Calcium 0 HydroLogic-Asheville PR930475 1652 Digester Sludge 2/19/93 MR7;pD UNITS SDL 1311 6010 mg/l 0.2 BDL 6010 mg/l 0.035 1.27 6010 mg/l 0.005 0.064. 6010 mg/l 0.006 0.006 6010 mg/l 0.08 BDL 7470 mg/l 0.0005 BDL 6010 mg/l 0.09 BDL 6010 mg/l 0.007 BDL Mod.. 160.3 mg/l 20 13700 mod. 300.0 mg/l 1 36 Mod. 300.0 mg/l 0.1 0.3 Mod. 300.0 mg/l 0.2 28.3 Mod. 365.1 mg/l 1 4.96. Mod. 351.4 mg/l 1 865 Calc. mg/l 1 805 350.3 mg/l --- 60• 9045 pH --- 6.39 7421 mg/kq 0.3 1.5 6010 mg/]aq 0.5 24.1 6010 mg/kq 0.3 0.5 6010 mq/kq 5 218 6010 mg/kg 0.2 56.1 6010 mg/kg 20 100 6010 mg/kg 0.3 13.9 6010 mg/kg 2 BDL 6010 mg/kg. 0.6 0.9 6010 mg/kg 0.2 205 BDL = Below Sample Detection Limit -SDL = Sample Detection Limit C V NIS : Cemetf COMPANY NAME: CENREF AwECT N[JMBm CE NREF SAMPIZ NUMBER: SAMPLE IDENMFTCATION: DATE SAMPLED: ANALYSIS 2,4-D 2,4,5-TP (silvex) Hydrologic -Asheville PM30475 1652 Digester Sludge 2/19/93 TCLP EXTRACTION METHOD EPA 8150 CAS NO. SDL ( ug/1) 94-75-7 4 93-72-1 1 BDL = Below Sample Detection Limit SDL = Sample Detection Limit 0344ENIS CemefLabS RESULT ( ug/1). BDL BDL OpMpy ; Hydrologic -Asheville CnZUT PR5J= NUMBER: PR930475 CENZE;F SAMPLE NUMBER: 1652 SAMPLE IDFN=CATION: Digester Sludge. DATESAMPLED: 2/19/93 TCLP EXTRALTIM METHOD EPA 8080 ANALYSIS CAS NO. iSDL RESULT ug/1) ( u9/1) Heptachlor 76-44-8 0.5 BDL Erdrin 72-20-8 1 BDL Chlordane 57-74-9 5 BDL Toxaphene 8001-35-2 10 BDL Methoxychlor 72-43-5 5 BDL Lindane 58-89-9 0.5 BDL BDL = Below Sanple Detection Limit SDL = Sample Detection Limit CAS CCrCM]PY NAME: HydroLogic-Asheville CENREF fRaTF]Cr NUMBER: PR930475 czNREF SAMPLE NUMBER: 1652 SAMPLE IDENTIFICATION: Digester Sludge DATE SLED: 2/19/93 TCZP EXTRAMON METHOD EPA 8270 ANALYSIS CAS NO. SQL RESULT ( ug/L) ( ug/L) 2-Mthylphenol 95-48-7 50 BDL (3+4)-Methylphenol 50 58 2,4-Dinitrotoluene 121-14-2 50 BDL Hexachlorabenzene 118-74-1 50 BDL Hexac-hlorobutadiene 87-68-3 50 BDL Hexachloroethane 67-72-1 50 BDL Nitrobenzene 98-95-3 50 BDL Pentachlorophenol 87-86-5 250 BDL Pyridine 110-86-1 50 BDL 2,4,5-I'richloraphenol 95-95-4 250 BDL 2,4,6-irrichlorophenol 88-06-2 50 BDL BDL = Below Sample Detection Limit SDL = Sample Detection Limit 0 6 /CCHPANY NAME: CENREF PkV= NUMBER: CE NREF SAMPLE NUMBER: SAMPLE IDENTIFICATION: DATE SAMPLED: HydroLogic-Asheville PR930475 1652 Digester Sludge 2/19/93 ZHE LION HETHD EPA 8240 ANALYSIS CAS NO. SDL RESULT i U!/L) u9/L) genZene 71-43-2 1 BDL Carbon Tetrachloride 56-23-5 1 BDL Chlorobenzene 108-90-7 1 BDL Chloroform 67-66-3 1 BDL 1,4-Dichlorobenzene 106-46-7 1 BDL 1,2-Dichloroethane 107-06-2 1 BDL 1,1=Dichloroethene 75-35-4 1 BDL 2-Butanone 78-93-3 5 BDL Tetrachloroethene 127-18-4 1 BDL Tric loroethene 79-01-6 1 BDL Vinyl Chloride 75-01-4 5 BDL n BDL = Below Sample Detection Limit SDL = Sample Detection Limit C70*om : C REPORT OF ANALYSES MARS HILL. TUWN OF' P.U. HUX 368 MARS HILL, HC 28754- Attn: DARYL BOONE Page 1 of 1) SAMPLE LAB No. DATE TIME SAMPLER 3395 02/14/92 HAROLD AND ROGER CLIENT STATION ID: LAB *: DATE: 04/03/92 SLUDGE 3395 DELIVERY TO LAB DATE TIME 02/14/92 1640 PH, LAB std units 6.1 AMMUNIA Ni'rRUUEH mo/l 2.2 TUTAL SULIUS ma/l 0.73% CHLUNIUL ma/1 282.5 NITRATE/Ni I'HiTE mo/1 1.89 'I'UI'AL PHUSPHURUS ma/1 96.80 TUTAL N1'rRUGEN ma/1 546.2 SULF'A'rE mq/1 16.4 CADMIUM, 'rU'rAL mq/1 0.028 CALCIUM. TOTAL mq/1 5.90 CHROMIUM, 'rU'rAL mq/1 0.135 COPPER, TU'rAL mg/l 13.720 LEAD. TOTAL mq/1 0.642 MAGNESIUM, 'rU'rAL mq/1 -23:2T NICKEL, TOTAL mg/l 0.216 SODIUM, TUTAL mg/l 323.0 ZINC. TOTAL mg/l 6.18 •• Potassium analysis not performed. Resample submitted, data will be submitted under separate cover. LABORATORY UI I 122 Lyman Street 9 P.O. Box 18029 9 Asheville. North Carolina 28814.0029 • 704/254.5169 or I+,l:.l Llltl �JI•' AIIAL I`I•.::; MAk', II1LL. IIJWII +!f I It'.!ir..I li�•AIL: I?A!r,uILl. L I., A ! I•• ` I-. U. HUB :.+n } ... -._ MAR'' HILL. III' Attn: L'ARM 1 -1WII: +. I'age 1 of 1 r oAPIFLr. I•i:I. I+'!:R Ti.',Lt-Is LAL+ W1. I'A i I:: I i ftE: L!-.k L)A 1 I:• 1 ! Plfi '1,UL,E.k R'rr•/_._. `+. !t'4"c} C:LiLtl'1' STA11011 ._1': MAfi�:1111-I_ _•I,!Il'tk L.Ab o: NH. LAU std units AMMUtliA NL I OULN Mq/ t TUI'AL 'SULII'+'a InU/1 '+�•'' /• GHLUR1LIE t4ll'RATE/N11-R1E MCI Id. Uz 111I AL NHUSPH01RU'�, MU/ 1 +•±'a. J.a l!JI'AL Hi'll(QUEN n'U SU LF A'l E UAL'I11U11, I LI VAL f°��/ 1 L,AL!"LUM. IIJI'AL I;IIIiL.+MLUt,. IU'IAL (,UPPER, I U l'AL mq! 1 '•' +' LIiAU, I II I AL mil/ 1 d. ;..•� 11AUf4L':)LUt1. IVIAL, , 1 J+± flIf,KEL, rol'AL MQ/1 tiUUil1M, TUrAL Z1114:. 1'UI AL �s IL^a� - �- 122 Lyman Street • P.O. Box 18029 *.Asheville. North Carolina 28814.0029 • 704/254-5169 REFURf OF ARALY�1:'3 MARS HILL. TOWN UF' f'Fa!!LI- I' 1IAME: IiAL:_HILL I1.Lf' P.U. BOX 3G8 UAfE: +dn/27/'9: MARS HILL. NC 28'i34-- Attn: DARYL BUO14E (Pane 1 of 1) SAMPLE DELIVERY TO LAN LAN No. DATE TIME SAMPLhR DATE: TIME 9399 07/28/92 k17iJ1/91 1300 CL1ENT STATION ID: IIARSHILL SLUDUE LAB +V : 9399 ARSENIC. TOTAL ma/1 <0.003 BARIUM, TOTAL ma/L 0.401 CADMIUM. TOTAL mq/l <16.001 LEAD. TOTAL mq/l 0.005 MERCURY. TUT'AL my/l <0.001 SELENIUM. TOTAL mq/1 <0.004 SILVER, TUTAL mg/1 <0.IDlob LABLINATUHY UIHIrUTUR A 122 Lyman Street • P.O. Box 18029 • Asheville. North Carolina 28814-0029 • 704/254.5169 L 0 G I C i PJ C N Y D R 0 4" REl CiRl' OF AIIALi L'j M:?R,HILL, IUNN f_)V HAliE: IIAICAIILL P.U. BOX 15-8 UA I1:: 11/ 1'.4 MARS HILL, till' 267!ill Attn: UARYL 901114E Page I of I) =,Allf LL ULLI VEh I 10 LAD LAb No. LWI E TINE=;ANPLLR Uhl E T111E, 1238 V 1;%+;'15 12; 01414 UEORUE IQI/1`.."/:12 14 Q) (11DIF _IATILIN IU: MAHti`:ULL �:LIILPUE LAB Al : 12 87 PH. LAN strl units 5. 1 A11MOI11A HUR06EN my/1 0.4 iU f AL rig / 1 .1. 4'1 WILUli1UE mqi 1 '{/. (i taTRATE/N1rRITE my/1 16. 1:j TUTAL PHOSPHORUS rig /I 'j4. R) TOTAL HITRUUE11 my/1 1'314. 1 SULFATE mg/ 1 91. 7 CADMIUM, TOTAL mp I LA.-A4'.3 CALILIUM. 1-U f AL mq 11 _13. 41i) CHROMIUM, TOTAL my/1 it).147 COPPER, TUfAL mq/1 11.4� �. LEAL). TOTAL my/1 HAGNE'SIUM, TOTAL 5.i NICKEL. TOTAL my/1 Id. Ib'2 sunuM, rU'fAL mg/1 4:5.016 ZINC, TUTAL mg/1 9.4160 POTASSIUM mg/1 J5. 5 LAULWATURY UlNEXl.111 P.O. BOX 18029 / ASHEVILLE, N[ 28814 / 122 LYMAN STREET / ASIIFVILIF, NC 7A80I / (704) 254.51 G9 / FAX: (704) 252.9711 / 1011 FRFF: 1-800-231.8889 LAND APPLICATION INFORMATION NCDEHNR, DEM LAND APPLICATION OF SLUDGE PERMIT: Attachment C ANNUAL LAND APPLICATION CERTIFICATION FORMS: Attachment D SLUDGE RECEIVER SITES: LAND APPLICATION OPERATOR: ADDRESS: TELEPHONE: Attachment E Robert M. Sams P. 0. Box 368 Mars Hill, NC 28754 (704) 689-9850 ATTACHMENT C STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT, HEALTH AND NATURAL RESOURCES DIVISION OF ENVIRONMENTAL MANAGEMENT LAND APPLICATION OF SLUDGE PERMIT State of North Carolina -Department of Environment, Health and Natural Resources Division of Environmental Management 512 North Salisbury Street • Raleigh, North Carolina 2761 James G. Martin, Governor William W. Cobey, Jr., Secretary March 22, 1991 Mr. Darhyl Boone, Town Manager Town of Mars Hill Post Office Box 368 Mars Hill, North Carolina 28754 George T. Everett, Ph.D. Director Subject: Permit No. WQ0004298 Town of Mars Hill Land Application of Sludge Madison County Dear Mr. Boone: In accordance with your application received October 19, 1990, we are forwarding herewith Permit No. WQ0004298, dated March 22, 1990, to the Town of Mars Hill for the operation of a land application of sludge program. This permit shall be effective from the date of issuance until February 28, 1996, and shall be subject to the conditions and limitations as specified therein. Please pay particular attention to the monitoring requirements in this permit. Failure to establish an adequate system for collecting and maintaining the required operational information will result in future compliance problems. If any parts, requirements, or limitations contained in this permit. are unacceptable to you, you have the right to request an adjudicatory hearing upon written request within 30 days following receipt of this permit. This request must be in the form of a written petition, conforming to Chapter 150B of North Carolina General Statutes, and filed with the Office of Administrative Hearings, P.O. Drawer 27447, Raleigh, NC 27611-7447. Unless such demands are made this permit shall be final and binding. One set of approved documents is being forwarded to you. If you need additional information concerning this matter, please contact Mr. Mark Hawes at 919/ 733-5083. George T. E reti cc: Madison County Health Departure tEC����® McGill Associates Asheville Regional Office Groundwater Section Nrn Training and Certification McG.LL ASSOC, P P• Pollution Prevention Pays P.O. Box 27687, Raleigh, North Carolina 27611-7687 Telephone 919-733-7015 An Equal Opportunity Affirmative Action Employer NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION DEPARTMENT OF ENVIRONMENT, HEALTH AND NATURAL RESOURCES RALEIGH SLUDGE LAND APPLICATION PERMIT In accordance with the provisions of Article 21 of Chapter 143, General Statutes of North Carolina as amended, and other applicable Laws, Rules, and Regulations PERMISSION IS HEREBY GRANTED TO Town of Mars Hill Madison County FOR THE operation of a sludge land application program consisting of the land application of sludge generated by the Town of Mars Hill's wastewater treatment facility to the sites listed in Condition VI-6 with no discharge of wastes to the surface waters, pursuant to the application received October 19, 1990 and in conformity with the project plan, specifications, and other supporting data subsequently filed and approved by the Department of Environment, Health and Natural Resources and considered a part of this permit. . This permit shall be effective from the date of issuance until February 28, 1996, and shall be subject to the following specified conditions and limitations: PERFORMANCE STANDARDS 1. The Asheville Regional Office, phone no. (704) 251-6208, and the appropriate local governmental official (county manager/city manager) shall be notified at least twenty-four (24) hours prior to the initial application of the sludge so that an inspection can be made of the application sites and application method. Such notification to the regional supervisor shall be made during the normal office hours from 8:00 a.m. until 5:00 p.m. on Monday through Friday, excluding State Holidays. Also the Madison County Manager's office must be notified prior to the initial application so that they will be aware that the operation has commenced. 2. This permit shall become voidable if the soils fail to adequately absorb the wastes and may be rescinded uriless the sites are maintained and operated in a manner which will protect the assigned water quality standards of the surface waters and ground waters. 3. The land application program shall be effectively maintained and operated as a non -discharge system to prevent the discharge of any wastes resulting from the operation of this program. 4. The issuance of this permit shall not relieve the Permittee of the responsibility for damages to surface or groundwaters resulting from the operation of this facility. 5. In the event that the land application program is not operated satisfactorily, including the creation of nuisance conditions, the Permittee shall cease applying sludge to the sites and take any immediate corrective actions, including the construction of additional or replacement wastewater treatment or disposal facilities. 6. No crops for direct human consumption shall be raised on these sites for a period of 18 months following sludge application. 7. Maximum slope for sludge application shall be 10% for surface application and for slopes from 10-18% application shall be by subsurface injection only. The following buffers zones shall be maintained: a) 400 feet from residences under separate ownership for surface application method, however the buffer zone requirement may be reduced to a minimum of 100 feet upon written consent of the owner. b) 200 feet from residences under separate ownership for injection method, however the buffer zone requirement may be reduced to a minimum of 100 feet upon written consent of the owner. c) 100 feet from "SA and SB" classified waters and public surface water supplies for both methods, d) 50 feet from "WS" classified waters and other streams, creeks, lakes, rivers, and surface water drainage ways for injection method. e) 100 feet from "WS" classified waters and other streams, creeks, lakes, rivers and surface water drainage ways for surface application method, f) 100 feet from property lines for both methods, g) 50 feet from public right of ways for surface application methods, h) 25 feet from public right of ways for subsurface disposal methods, i) 10 feet from upslope interceptor drains and surface water diversions for both methods, j) 25 feet from downslope interceptor drains, surface water diversions, groundwater drainage systems and surface drainage ditches for both methods. 9. A copy of this permit shall be kept at the land application site when sludge is being applied during the life of this permit. A spill prevention and control plan shall be kept in all sludge transport and application vehicles. 10. All sludges included in this permit must be stabilized by a process to significantly reduce pathogens (as described in 40 CFR Part 257, Appendix II) prior to application or incorporation. An evaluation of all sludges as specified in condition II 4 must be conducted as to their ability to demonstrate compliance with this requirement. A copy of this report must be submitted to the Assistant Chief for Operations, Division of Environmental Management, Water Quality Section, Operations Branch; PO Box 27687, Raleigh, NC 27611-7687, within six (6) months of the permit issue date. 11. Specific sludge application area boundaries shall be clearly marked on each site prior to and during sludge application. 12. No sludge at any time shall be stored at any application site. II. OPERATION AND MAINTENANCE REQUIREMENTS 1. The facilities and disposal sites shall be properly maintained and operated at all times. 2. A suitable vegetative cover of Fescue shall be maintained in accordance with the crop management plan approved by this Division. 3. The application rates shall not exceed 4.25 dry tons per acre per year. The application rates shall not exceed 13,612 gallons per acre per application (approximately 1/2 inch per acre per application). 4. No sludges other than the following are hereby approved for land application in accordance with this permit: Source County Permit Number Estimated Volume Town of Mars Hill Madison NCO057151 420,000 gal/yr 5. The lifetime heavy metal loadings shall not exceed the following for the corresponding Cation Exchange Capacities (CEC): Parameter CEC < 5 Lead (lbs/acre) 500 Zinc (lbs/acre) 250 Copper (lbs/acre) 1251 Nickel (lbs/acre) 125 Cadmium (lbs/acre) 4.51 1 Please be advised that at the proposed loading rate of 4.25 dry tons per acre per year the site life metal loadings for Copper and Cadmium will be reached in approximately 15 years per acre (this is based on continuous yearly applications and the site life may be longer based on management practices such as rotation of application on fields). 6. Upon classification of the facility by the Certification Commission, the Permittee shall employ a certified wastewater treatment plant operator to be in responsible charge of the wastewater treatment facilities. The operator must hold a certificate of the type and grade at least equivalent to the classification assigned to the wastewater treatment facilities by the Certification Commission. 7. Adequate procedures shall be provided to prevent surface runoff from carrying any disposed or stored sludge material into any surface waters. 8. Animals shall not be grazed on sludge applied land within a 30-day period following the sludge application. Application sites that are to be used for grazing shall have fencing that will be used to prevent access after each application. 9. Surface applied sludge will be plowed or disced within twenty-four (24) hours after application on lands with no cover crop established. 10. For areas that are prone to flooding or within the 100-year flood elevation, sludge may be applied only during periods of dry weather. The sludge must be incorporated into the soil within twenty-four (24) hours of application. 11. Appropriate measures must be taken to control public access to the land application sites during active site use and for. the 12-month period following the last sludge application event. Such controls may include the posting of signs indicating the activities being conducted at each site. 12. Adequate provisions shall be taken to prevent wind erosion and surface runoff from conveying pollutants from the sludge application area onto the adjacent property or into the surface waters. 3 III 13. Sludge shall not be applied in inclement weather or until 24 hours following a rainfall event of 1/2-inch or greater in 24 hours. Any emergency sludge disposal measures must first be approved by the Division of Environmental Management. 14. The site shall be adequately limed to a soil pH of at least 6.5 prior to sludge application. Sludge may be applied to sites with a pH of less than 6.5 provided a sufficient amount of lime is also applied to achieve a final pH of the lime, sludge and soil mixture of at least 6.5. MONITORING AND REPORTING REQUIREMENTS Any monitoring (including groundwater, surface water, sludge, soil, or plant tissue analyses) deemed necessary by the Division of Environmental Management to insure protection of the environment will be established and an acceptable sampling and reporting schedule shall be followed. If monitoring data indicates minimal or no concern to the Division, reduction of monitoring requirements may be pursued after two annual reporting periods. 2. Proper records shall be maintained by the Permittee tracking all disposal activities. These records shall include, but are not necessarily limited to the following information: a) source of sludge b) date of sludge application c) location of sludge application (site, field, or zone #) d) method of application e) weather conditions f) soil conditions g) type of crop or crop to be grown on field h) volume of sludge applied in gallons/acre and dry tons/acre i) annual and cumulative totals of dry tons/acre of sludge, annual and cumulative pounds/acre of each heavy metal (which shall include, but not be limited to lead,nickel, cadmium, copper and zinc), annual pounds/acre of plant available nitrogen (PAN), and annual pounds/acre of phosphorus applied to each field. A representative annual soils analysis (Standard Soil Fertility Analysis) shall be conducted of each site receiving sludge in the respective calendar year and the results maintained on file by the Permittee for a minimum of five years. The Standard Soil Fertility Analysis shall, include, but is not necessarily limited to, the following parameters: % Base Saturation Magnesium Phosphorus Potassium Lead Zinc pH Manganese Cation Exchange Capacity Sodium Nickel Cadmium Copper Calcium 4. A quarterly sludge analysis and annual Toxicity Characteristics Leaching Procedure (TCLP) analysis shall be conducted by the Permittee and the results maintained on file by the Permittee for a minimum of five years. If land application occurs at a frequency'less than quarterly, sludge analysis will be required for each instance of land application. The sludge analysis shall include but is not necessarily limited to the following parameters: 0 % total solids Magnesium Chlorides Sulfate Phosphorus Potassium Lead Zinc Copper Nickel Cadmium Chromium Sodium Calcium Total Nitrogen Ammonia Nitrogen Nitrate/Nitrite Nitrogen pH Plant Available Nitrogen (by calculation) The TCLP analysis shall include the following parameters: Arsenic Barium Benzene Cadmium Carbon tetrachloride Chlordane Chlorobenzene Chloroform Chromium o-Cresol m-Cresol p-Cresol Cresol 2,4-D 1,4-Dichlorobenzene 1,2-Dichloroethane 1,1-Dichloroethylene 2,4-Dinitrotoluene Endrin Heptachlor (and its hydroxide) Hexachlorobenzene Hexachloro-1,3-butadiene Hexachloroethane Lead Lindane Mercury Methoxychlor Methyl ethyl ketone Nitrobenzene Pentachlorophenol Pyridine Selenium Silver Tetrachloroethylene Toxaphene Trichloroethylene 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 2,4,5-TP (Silvex) Vinyl chloride 5. Three copies of all monitoring and reporting requirements as specified in conditions 1111, 1112, 1113 and III 4 shall be submitted annually on or before March 1 of the following year to the following address: NC Division of Environmental Management Water Quality Section Facility Assessment Unit PO Box 27687 Raleigh, NC 27611-7687 6. Noncompliance .Notification: The Permittee shall report by telephone to the Asheville, Regional Office telephone no. (704) 251-6208, as soon as possible, but in no case more than 24 hours or on the next working day following the occurrence or first knowledge of the occurrence of any of the following: a. Any occurrence with the land application program which results in the land application of significant amounts of wastes which are abnormal in quantity or characteristic. b. Any failure of the land application program resulting in a release.of sludge material to receiving waters. 5 c. Any time that self -monitoring information indicates that the facility has gone out of compliance with the conditions and limitations of this permit or the parameters on which the system was designed. d. Any process unit failure, due to known or unknown reasons, that render the facility incapable of adequate sludge treatment. e. Any spillage or discharge from a vehicle or piping system transporting sludge to - the application site. Persons reporting such occurrences by telephone shall also file a written report in letter form within 15 days following first knowledge of the occurrence. This report must outline the actions taken or proposed to be taken to ensure that the problem does not recur. IV. GROUNDWATER REQUIREMENTS 1. Prior to beginning waste disposal operations, three (3) monitor wells, one (1) upgradient and two (2) downgradient, shall be installed to monitor groundwater quality (see attached map). The well(s) shall be constructed such that the water level in the well is never above or below the screened (open) portion of the well at any time during the year. If the water table occurs within the bedrock unit, then the monitor wells must be constructed into this unit. The location and construction details for these wells must be approved by the Asheville Regional Office, from which a well construction permit must be obtained. 2. The monitor wells must be sampled initially after construction (and prior to waste disposal operations) and thereafter- every February, June, and October for the following parameters: NO3 (10.0) `IDS (500.0) TOC pH ( 6.5-8.5 standard units) Ammonia Nitrogen Chlorides (250.0) Water Level Total Coliforms (1/100 ml) Total Suspended Solids Volatile Organic Compounds - In October only (by Method 1 or Method 2 below) Method 1: Method 6230D ( Capillary - Column), Standard Methods for the Examination of Water and Wastewater", 17th edition, 1989 Method 2: Method 502.2 " Methods for the Determination of Organic Compounds in Drinking Water", United States Environmental Protection Agency - 600/4-88/039 The measurement of water level must be made prior to sampling for the remaining parameters. The measuring points (top of well casing) of all monitoring wells shall be surveyed relative to mean sea level (M.S.L.). The depth of the water in each well shall be measured from the surveyed point on the top of the casing. The water level elevations shall then be determined relative to (M.S.L.). The numbers in parentheses represent the maximum allowable concentrations in groundwater for the various analytical parameters, as specified in 15 NCAC 2L [Groundwater Classifications and Standards]. Unless otherwise noted, the concentrations are given in parts per million. C� If TOC concentrations greater than 10 mg/1 are detected in any downgradient monitoring well, additional sampling and analysis must be conducted to identify the individual constituents comprising this TOC concentration. If the TOC concentration as measured in the background monitor well exceeds 10 mg/l, this concentration will be taken to represent the naturally occurring TOC concentration. Any exceedances of this naturally occurring TOC concentration in the downgradient wells shall be subject to the additional sampling and analysis as described above. If any volatile organic compounds are detected by method 6230D, or the equivalent method 502.2, then EPA methods 604 and 611 must also be run to detect other organic compounds which may be present. The results of all analysis specified in the monitoring requirements, including 604 and 611 if required, must be submitted simultaneously The results of the sampling and analysis shall be sent to the N.C. Division of Environmental Management on Form GW-59 (Compliance Monitoring Report Form) every March, July, and November. 3. The Compliance Boundary delineated on the attached map for the disposal system is specified by regulations in 15 NCAC 2L, Classifications and Water Quality Standards applicable to the groundwater of North Carolina. An exceedance of Groundwater Quality Standards beyond the Compliance Boundary is subject to penalty provisions applicable under. General Statute 143-215.6(1)a. The sale of property, by the Permittee, which is within or contiguous to the disposal system site may alter location of the Compliance Boundary. For facilities permitted on or after December 30, 1983,.the Compliance Boundary is established at the lesser of 250 feet from the land application site, or 50 feet within the property boundary. If the title to any property which may affect the location of the Compliance Boundary is changed, the permittee shall notify the Division Director within 14 days. The Director shall then establish a modified Compliance Boundary which will be done as a modification to the Permit. The REVIEW BOUNDARY for the disposal system is specified by regulations in 15 NCAC 2L, Groundwater Classifications and Standards. A REVIEW BOUNDARY is established around disposal systems midway between the Compliance Boundary and the perimeter of the waste disposal area. When the concentration of any substance equals or exceeds the maximum allowable concentration of that substance at the REVIEW BOUNDARY, as determined by monitoring, the permittee shall either (i) demonstrate, through predictive calculations or modeling, that natural site conditions, facility design and operational controls will prevent a violation of standards at the Compliance Boundary; or, (ii) submit a plan for the alteration of existing site conditions, facility design or operational controls that will prevent a violation of standards at the Compliance Boundary, and implement that plan upon its approval by the Director. 4. Any groundwater quality monitoring as deemed necessary by the Division of Environmental Management shall be provided. 5. No land application of wastewater shall take place when the seasonal high water table is less than three feet below the surface of the land. 7 V. INSPECTIONS The Permittee or his designee shall inspect the sludge storage, transport, and disposal facilities to prevent malfunctions and deterioration, operator errors and discharges which may cause or lead to the release of wastes to the environment, a threat to human health, or a nuisance. The Permittee shall keep an inspection log or summary including at least the; date and time of inspection, observations made, and any maintenance, repairs, or corrective actions taken by the Permittee. This log of inspections shall be maintained by the Permittee for a period of three years from the date of the inspection and shall be made available upon request by the Division of Environmental Management or other permitting authority. 2. Any duly authorized officer, employee, or representative of the Division of Environmental Management may, upon presentation of credentials, enter and inspect any property, premises or place on or related to the disposal site and facility at any reasonable time for the purpose of determining compliance with this permit; may inspect or copy any records that must be kept under the terms and conditions of this permit; or may obtain samples of groundwater, surface water, or leachate. VI. GENERAL CONDITIONS 1. This permit shall become voidable unless the land application activities are carried out in accordance with the conditions of this permit and in the manner approved by this Division. 2. This permit is effective only with respect to the nature and volume of wastes described in the application and other supporting data. 3. This permit is not transferable. In the event there is a desire for the facilities to change ownership or a name change of the Permittee, a formal permit request must be submitted to the Division of Environmental Management accompanied by an application fee, documentation from the parties involved, and other supporting materials as may be appropriate. The approval of this request will be considered on its merits and may or may not be approved. 4. Prior to any transfer of this land, a notice shall be given to the new owner that gives full details of the materials applied or incorporated at this site. 5. This permit shall become voidable unless the agreements between the Permittee and the landowners/lessees are in full force and effect. 6. The following are approved sites for sludge application (see attached map): Site No. Owner/Lessee Application Area (excluding buffers) 1 Larry Cody f4.0 acres 2 Larry Cody 4.8 acres 7. Failure to abide by the conditions and limitations contained in this permit may subject the Permittee to an enforcement action by the Division of Environmental Management in accordance with North Carolina General Statute 143-215.6. :V 8. The annual administering and compliance fee must be paid by the Permittee within thirty (30) days after being billed by the Division. Failure to pay the fee accordingly may cause the Division to initiate action to revoke this permit as specified by 15 NCAC 2H .0205 (c)(4). 9. The issuance of this permit does not preclude the Permittee from complying with any and all statutes, rules, regulations, or ordinances which may be imposed by other government agencies (local, state, and federal) which have jurisdiction. 10. A set of approved documents for the subject project must be retained by the applicant for the life of the permit. 11. The Permittee, at least six (6) months prior to the expiration of this permit, shall request its extension. Upon receipt of the request, the Commission will review the adequacy of the facilities described therein, and if warranted, will extend the permit for such period of time and under such conditions and limitations as it may deem appropriate. 12. This permit may be modified, or revoked and reissued to incorporate any conditions, limitations and monitoring requirements the Division of Environmental Management deems necessary in order to adequately protect the environment and public health. 13. The applicant shall delineate all slopes greater than 10% in the field. These areas shall be limited to subsurface injection only. Permit issued this the 22nd day of March, 1991 CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION George T. Ev tt, r e t Division of E amen agement By Authority of ental Management Commission Permit No. WQ0004298 9 \\ �-,,,,(—PROPERTY LINE 1 I � MON 1T'oti WELL PoG - PiR�MG7L�R bF Co�tpc�Aat6 w ATTACHMENT D ANNUAL LAND APPLICATION CERTIFICATION FORM 1993 AND 1992 UOUl d 9$ LAND APPLICATION CERTIFICATION FORM Permit No. 1 1 51 Cbunty Mcld i 5' n Year /9 Facility Name (as shown on p mit) `T'ou) n aP rn n, - wiii Land Application Operator En6 nt M . . n.M5 Land application of residuals as allowed by the above permit occurred during the past calendar year ✓ YES NO. If NO, skip Part I and Part II and proceed to the certification. Part I *Total number of application sites in permit. *Total number of sites land application occurred during the year. c� _ *Total number of sites land application did not occur during the year. O *Total amount of dry tons applied during the year for all application sites. 6.ba Part II Facility was compliant during calendar year 1993 with all conditions of the land application permit (inclu5Ymg but not limited to items 1-10 below) issued by the Division of Environmental Management gl YES NO. IF NO, PLEASE PROVIDE A WRITTEN DESCRIPTION WHY THE FACILITY WAS NOT COMPLIANT, THE DATES, AND EXPLAIN CORRECTIVE ACTION TAKEN. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.5 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. All operations and maintenance requirements were complied with or, in the case of a deviation, prior authorization was received from the Division of Environmental Manpgement. 7. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 8. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed in accordance with the crop management plan. 9. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 10. All buffer requirements as specified on the permit were maintained during each. application of residuals. I CERTIFY THAT THE ABOVE INFORMATION IS ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE, AND ALL THE INFORMATION IN THE SUCCEEDING PAGES IS ACCURATE AND COMPLETE. Permittee S gnature Date J l - 3 / - 97 Operator or Agent Signature Date ANNUAL LAND APPLICATION SITE SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION SITE. � l � 1�&T-s l PERMIT # PLACE A'WA' IN A BLANK OR BOX WHEN NOT APPLICABLE. oW(\ 6ll &c °o04a91 FACILITY NAMES n S% i S I APPLICATION METHOD OWNER Lx C , C01 y FIELD # CROP re- 5; r S& CATION EXCHANGE CAPACITY (CEC) 7 OPERATOR ^ 1 rn SITE ilk ACRES PERMITTED % y . Q ACRES UTILIZED I i RESIDUAL SOURCE(S) r �g� a ,. u 10 p TOTAL DRY TONS APPLIED (ANNUAL) TOTALS: ter. • :: � • - � n�� �� . � .._��� • • �����' LIME APPLICATION DATE LBSJACRE Permit limit (lbs.lacre/year) Lifetime Permit Limit (lbsJacre) I I I I q.5 I I i as 5 0 Q 1 1 1 l a J I�5 i X --- --- --=---------=.7� = 95� (SIGNATURE OF OPERATOR OR AGENT) DATE BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE. • Additional monitoring required by 40 CFR Part 503 effective July 20, 1993. ANNUAL LAND APPLICATION SITE SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION SITE. PLACE A'N/A' IN A BLANK OR BOX WHEN NOT APPLICABLE. FACILITY NAME �dL�JV� �� 1 �a�S I�►i I, PERMIT # NCO rJ-7 1 S I APPLICATION METHOD OWNER Lci.r-vtit (��. FIELD # a OPERATOR 'Cog/rH+, T MI. Scimrn 5 SITE # Er tr RESIDUAL SOURCES) n.a,o.,r- -'5/ 1 l-i ds P CROP 1"C.S c- �L ACRES PERMITTED g Ur r CAPACITY (CEC) ACRES UTILIZED T TOTAL DRY TONS APPLIED (ANNUAL) . S CATION EXCHANGE OEM I Newt. LIME APPLICATION DATE LBSJACRE - 5-9 10; Ood Permit limit (lbs./acre/year) Lifetime Permit Limit (lbaJacre) ( 5 a 5 X.z 3/ (SIGNATURE OF OPERATOR OR AGENT) DATE BY THIS SIGNATURE, I CERTIFY THAT THIS REPORT IS ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE. • Additional monitoring required by 40 CFR Part 503 effective July 20, 1993. 695 North Seventh Street Brighton, Colorado 80601-1559 —� Telephone 303 659-0497 CCMWL(3bs Analytical Chemistry Laboratories Mare 8, 1993 yt-j- 4i1 �4a11 Hydrologic -Asheville P.O. Box 18029 Asheville, NC 28814 Attention: Dinah Trammel CEWW PFIDIECT NUKBE t: PR930475 D�ITE : Mare 8, 1993 MM RBGEIVED: February 24, 1993 HydroLogic-Asheville P.O. Box 18029 Asheville, NC 28814 Attention: Dinah Trammel r 1 sludge and 2 soil samples for Hydrologic -Asheville, Town of Mars Hill Project, taken on 2/19/93. Enclosed is the laboratory report for the project described above. If you have any questions or if we can be of further assistanoe, please feel free to contact us. We appreciate your business and look forward. to serving you again soon. Alan Kerschen Vice President / COMPANY NAME: ic-Asheville � HY�� CENREF PRf17EX.T NUMBER: PR930475 SAMPLE IDENTIFICATION CENREF SAMPLE NUMBER CLIENT SAMPLE IDENTIFICATION SAMPLE DATE 1652 Digester Sludge 2/19/93 1653 Soil -Field #1 2/19/93 1654 Soil -Field #2 2/19/93 Cerimf Labs HYDROLOGIC, INC. Chain- of -Custody Client information: Name: Address: Contact: Sample information: Phone: Sample. Description Sample Date(rime Analysis Required (Be specific) Sample type Grab/Composite Preservation (Be specific) Type of Container Id 41- A, Sampler's Signature: Relinquished by: -7��4dv- Received by: Date/Time: QUl y3 i Date/Time: e.,73 9 .3 /P 5— Relinquished by: Received by: Date/Time: Date/Time: Relinquished by: Received by: Date/Time: Date/Time: Comments: COMPANY NAME: MCI 11 01 • 0P 1:1�1• j but •I• • ANALYSIS Benzene Carbon Tetrachloride C hl.orabenzene Chloroform 1,4-Dichlorobenzene 1,2-Dichloroethane 1,1-Dichloroethene 2-Butanone Tetrachlorcethene Tridhloroethene Vinyl Chloride HydroLogic-Asheville PR930475 1652 Digester Sludge 2/19/93 ZHE EXTRACPIM HETHM EPA 8240 CAS NO. SDL RESULT i ug/L) i ug/L) 71-43-2 1 BDL 56-23-5 1 BDL 108-90-7 1 BDL 67-66-3 1 BDL 106-46-7 1 BDL 107-06-2 1 BDL 75-35-4 1 BDL 78-93-3 5 BDL 127-18-4 1 BDL 79-01-6 1 BDL 75-01-4 5 BDL BDL = Below Sample Detection Limit SDL = Sample Detection Limit COMENTS: Cerve(Labs 1 1 ANY NAME: SAMPLE iDENPMCATION: DATE SAMPLED: ANALYSIS 2-Methylphenol (3+4)-Mthylphenol 2,4-Dinitrotoluene Hexachlorabenzene Hexachlorobutadiene tHexacfiloroethane Nitrobenzene Pientachlorophenol Pyridine 2, 4, 5-iyichloraphenol 2,4,6-Prichlorophenol HydroLogic-Asheville PR930475 1652 Digester Sludge 2/19/93 TCLP EXTRALTICK I+h'Ii OD EPA 8270 CAS NO. SDL RESULT ( ug/L) ( ug/L) 95-48-7 50 BDL 50 58 121-14-2 50 BDL 118-74-1 50 BDL 87-68-3 50 BDL 67-72-1 50 BDL 98-95-3 50 BDL 87-86-5 250 BDL 110-86-1 50 BDL 95-95-4 250 BDL 88-06-2 50 BDL BDL = Below Sample Detection Limit SDL = Sample Detection Limit MI5 CervWLobS i COWANY NAME: C zww Pic= Nth: C 4; EF SAMPLE MZTMR: SAMPLE IDEN=CATION: DATE SAMPLED: . ANALYSIS Heptachlor E'rvdrin Chlordane Toxaphene Methoxychlor Lindane HydroLogic-Asheville M30475 1652 Digester Sludge 2/19/93 TCLB EXTRALTI0�1 MEAD EPA 8080 CAS NO. SDL RESULT u9/1) ( ug/1) 76-44-8 0.5 BDL 72-20-8 1 BDL 57-74-9 5 BDL 8001-35-2 10 BDL 72-43-5 5 BDL 58-89-9 0.5 BDL BDL = Below Sale Detection Limit SDL = Sample Detection Limit CCMMENIS. Ce iWLab ,r ri MANY NAME: of W"001,1-mm ANALYSIS 2,4-D 2,4,5-TP (silvex) HydroLogic-Asheville P12930475 1652 Digester Sludge 2/19/93 TCLP EILTR kMON MEAD EPA 8150 CAS NO. SDL RESULT ( Ug/1) ( U!/1) 94-75-7 4 BDL 93-72-1 1 BDL BDL = Below Sample Detection Limit SDL = Sample Detection Limit ODMIKEfIS : Covef Lobs CIMPpNY : HydroLogic-Asheville CENREF PFoTEcr NUKEER: PR930475 C'ENREF SAMPLE NUMBER: 1652 SAMnE IDENfl'MCMCki: Digester Sludge DATE SAMPLED: ANALYSIS MMMOD UNITS SDL RESULT TCLP Extraction 1311 mg/1 0.2 BDL Arsenic-TCLP Barium-TCLP 6010 6010 mg/l mg/l 0.035 0.005 1.27 0.064 Cadmi m-TCLP Chrcmium.TCIP 6010 6010 mg/l 0.006 0.006 Teal- IKIP 6010 mg/l mg/l 0.08 0.0005 BDL BDL Merctry-TCLP Selenitm -TCLP 7470 6010 mg/l mg/1 0.09 0.007 BDL BDL Silver-TCLP 6010 Total Solids Mod. 160.3 mg/l 20 13700 Chloride mod. 300.0 mg/l 1 36 0.3 Nitrate as N + Nitrite as N Mod. 300.0 mg/l 0.1 Sulfate Mod. 300.0 mg/1 0.2 28.3 Total phosphorus Mod. 365.1 mg/1 1 4.96 Total Kjeldahl Nitrogen Mod. 351.4 mg/1 1 865 Organic Nitrogen Calc. Mg/1 '1 805 60 Ammonia as N 350.3 M1/1 � 6.39 pH 9045 pH --- lead 7421 Mg/jug 0.3 0.5 1.5 24.1 6010 mg/309 Copper Cadmium 6010 m9/k9 0.3 0.5 Sodium 6010 6010 mg/kg mg/lag 5 0.2 218 56.1 Magnesium Potassium 6010 mg/kg 20 100 Zinc 6010 mg/kg 0.3 13.9 Nickel 6010 mg/kg mg/kg 2 0.6 BDL 0.9 Chromium 6010 6010 mg/kg 0.2 205 calcium BDL = Below Sanple Detection Limit SDL = Sample Detection Limit CerxdL--bs ,(`7 v� �a j,. OCMPANY NAME: HydroLogic-Asheville CENREF PROTECT NUMBER: PR930475 CENREF SAMPLE NLWER: 1653 SAMPLE IDENTIFICATION: Soil -Field #1 DATE SAMPLED: 2/19/93 ANALYSIS METHOD UNITS SDL RESULT Total Phosphorus Mod. 365.1 mg/kg 1 373 PH 9045 pH --- 7.32 Magnesium 6010 mg/kg 0.2 1410 Potassium 6010 mg/kg 20 900 lead 7421 mg/kg 0.6 5.7 Zinc 6010 mg/kg 0.3 23.9 Manganese 6010 mg/kg 0.4 252 Sodium 6010 mg/kg 5 345 Nickel 6010 mg/kg 2 9 Cadmium 6010 mg/kg 0.3 4.7 calcium 6010 mg/kg 0.2 1260 Copper 6010 mg/kg 0.5 BDL BDL = Below Sample Detection Limit SDL = Sample Detection Limit OCMKENrS : CemefLDbS �� COMPANY NAME: CENREF PRi17Ecr NUMBER: CENREF SAMPLE NUMM: SAMPLE IDEnIFICATION: DATE SAMPLED: Hydrol.ogic-Asheville PR930475 1654 Soil -Field #2 2/19/93 ANALYSIS MEIHOD UNITS SDL RESULT Total Phosphorus Mod. 365.1 mg/kg 1 382 pH 9045 pH --- 6.27 Magnesium 6010 mg/kg 0.2 3 Potassium 6010 mg/kg 20 4010 Lead 7421 mg/kg 1.2 11.4 ,64.2 Zinc 6010 mg/kg 0.3 Manganese 6010 mg/kg 4 130 Sodium 6010 mg/kg 5 1100 Nickel 6010 mg/kg 2 15 Cadmium 6010 mg/kg 0.3 12.1 Calcium 6010 mg/kg 0.2 677 Copper 6010 mg/kg 0.5 BDL BDL = Below Sample Detection Limit SDL = Sample Detection Limit I Well Location "E"" ou` Well Identificatior�,Number K8691 Wm Depth �.Ft. spray Field subsurface Low -Pressure PO Well Diameter Sample (Screened) Interval 7" Ft To Ft X. land nicaoor, of sk,dgen9 (�� Depth to Water Level • ft. below measuring point (before sampling) other Measuring point is ft. above land surface" Rotary distributor Gallons of water pumped/bailed before sampling 1p F o Appearance Field Anaysis: pH G .5 Specific Conductance Whos Tem • 04-! Odor Date Sample Collected 1C►/5/a Date lab Sample Analyzed�0/5/_. Laboratory Name Hyd�roLog i c , nc . Certification No. 4 -PTO; aerformed by senret Labs f384 COD — Coliform: Conform: mgA MF Fecal /100ml MF Total /100m1 (Note: Un WN nu#W for ttlg * urrbld strrtplas) 67, mgA Dissolved Solids: Total 1.0 pH (when analyzed) units * TOC 1 ' mgA Chloride 3.3 mgA Arsenic mgA Grease and Oils m� m Hardness: Total mgA Phenol mgA Sulfate Specific Conductance uMhos Total Ammonia . 2 mg/l Nitrite (NO 2) as N mgA � . .. m gA Nitrate (NO 3) as N mgA Phosphorus: Total as P mgA AI - Aluminum mgA Ba - Barium mgA Ca - Calcium mgA Cd - Cadmium m� Chromium: Total m Cu - Copper mgA Fe - Iron mgA Hg - Mercury mgA K - Potassium mgA - Magnesium mgA Mn - Manganese Na - Sodium mgA Ni - NmgA Pb - Lead mgA Zn - Zinc mgA Pesticides/Herbicides (Specify Compounds) ug/I ug/l ug/I Other (Specify Compounds and Cotr 1�5ation units) , see a ar, e TKN as N mgA I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE. Note: Values should reflect dissohred and colloidal concentrations. (see 42 on back) See back for instructions Signature of Pem-kee (or Authorized Agent] Date •' Sulxrtit blue, green, end yellow copies �Y IDaddress above. GW-59 REV. BW I Y D R 0' L 0 G I C I COMPANY NAME: Hydrologic -Asheville, Inc HYDROLOGIC PRta7Bt'P NUMBER: FL932425 HYDROLOGIC SAMPLE NUMBER: 21895 SAMPLE IDENTIFICATION: MW-1 Mars Hill DATE SAMPLED: 10/5/93 DATE. EXTRACTED: N/A DATE/TIME ANALYZED: 10/14/93 MER3IQOD EPA 502.2 ANALYSIS CAS NO. SDL RESULT ( ug/1) ( ug/1) Benzene 71-43-2 1.0 BDL Branobenzene 108-86-1 1.0 BDL Branochloranethane 74-97-5 1.0 BDL Branodichloranethane 75-27-4 .1.0 BDL Branofonn 75-25-2 1.0 BDL Branomethane 74-83-9 1.0 BDL n-Butylbenzene 104-51-8 1.0 BDL sec-Butylbenzene 135-98-8 1.0 BDL tert-Butylbenzene 98-06-6 1.0 BDL Carbon tetrachloride 56-23-5 1.0 BDL Chlorabenzene 108-90-7 1.0 BDL, Chloroethane 75-00-3 1.0 Bm Chloroform 67-66-3 1.0 BDL Chloranethane 74-87-3 1.0 BDL 2-Chlorotoluene 95-45-8 1.0 BDL 4=Chlorotoluene 106-43-4 1.0 BIDL D;hrrm chloranethane 124-48-1 1.0 BDL 1, 2-Dibraro-3-chlorgmWane 96-12-8 1.0 BDL 1,2-Di(EDB) 106-93-4 1.0 BDL Dibr 74-95-3 1.0 BDL 1,2-Dichlorcbenzene 95-50-1 1.0 BDL 1,3-Dichlorobenzene 541-73-1 1.0 BDL 1,4-Dichlorobenzene 106-46-7 1.0 BDL Dichlorodifluaranethane 75-71-8 1.0 BDL 1,1-Dichloroethane 75-34-3 1.0 BDL 1491 Twilight Trail 0 Frankfort, KY 40601 0 502/223-0251 U FAX 502/875-8016 L1 Toll Free 1-800/728-2251 H Y D R 0 L 0 G I C I N C Page 2 continued HYDROLOGIC PRa7BCP NL*EM: HYDROLOGIC SAMM N[)MBER: SAMPLE IDENMICATIC N: DAB . ANALYSIS 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichlorepmrapene cis-1,3-Dichloroprapene trans-1,3-Dichlorapropene Ethy]benzene Hexachlorcbutadiene Isapropylbenzene p-Iscprapyltoluene Methylene Chloride Naphthalene n-Prcpylbenzene Styrene 1,1,1,2-Petrachloroethane 1,1,2,2-Tetrachloroethane Tetrach orvetheoe Toluene 1, 2, 3--T.richlorcbenzene 1,2,4--wichlor benzene Hydrologic -Asheville, Inc FL932425 21895 MW--1 Mars Hill 10/5/93 METHM EPA 502.2 CAS NO. SDL (. ug/1) 107-06-2 1.0 75-35-4 1.0 156-59-4 1.0 156-60-5 1.0 78-87-5 1.0 142-28-9 1.0 590-20-7 1.0 563-58-6 1.0 10061-01-5 1.0 10061-02-6 1.0 100-41-4 1.0 87-68-3 1.0 98-82-8 1.0 99-87-6 1.0 75-09-2 1.0 91-20-3 1.0 103-65-1 1.0 100-42-5 1.0 630-20-6 1.0 79-34-5 1.0 127-18-4 1.0 108-88-3 1.0 87-61-6 1.0 120-82-1 1.0 RESULT ( ug/1) BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 4.54 BDL BDL BDL 1491 Twilight f rail ❑ Frankfort, KY 40601 El 502/M-02.51 111 FAX 502/815-8016 U loll Free 1-800/728-2251 H Y D R 0 L 0 G I C Page 3 continued CCHPpNy NAM: Hydrologic -Asheville, Inc HYDROLOOGIC PROTECT NUMBER: FL932425 HYDROLOGIC SAMPLE NUMBER: 21895 SAMPLE IDENfrMCATION: N1sn1-1 Mars Hill DATE SAMPLED: 10/5/93 MET Kv EPA 502.2 ANALYSIS CAS NO. SDL ( u9I1) RESULT ( u9/1) 1,1,1-Trichloroethane 71-55-6 1.0 BDL 1,1,2-Prichloroethane 79-00-5 1.0 1.0 BDL BDL Trichloroethene 79-01-6 1.0 BDL Trichlorofluorcmethane 75-69-4 1,2,3-,rrich1-oreprcpane 96-18-4 1.0 BDL 1,2,4-Trimethylbenzene 95-63-6 1.0 BDL 1,3,5-Trimethylbenzene 108-67-8 1.0 BDL Vinyl Chloride 75-01-4 1.0 BDL Xylenes (total) 1330-20-7 1.0 BDL BDL - Below Sanple Detection Limit Sm = Sanple Detection Limit COMRPS • 1491 Twilight 'frail C1 Frankfort, KY 40601 1-1 509/??8-0251 F1 FAX 50?./875-8016 LI Toll Free 1-800/728-2251 Well Location Downgradient � (REQUIRED) Lagoon Septic Tar"rain Field Well Identification Number K86g2 WW12 Well Depth60 Ft. Well Diameter (Screeram Int3erval Ft To Ft. �y Fier subsurface � Pressure Depth to Water Level ft below measuring point (befom sampling) X Land Application of Sludge, Measuring pant is ft. above land Wriaoe Omer Gallons of water puma�iled before sampling 11 Rotary Distributor Field Analysis: pH 7/ 7/ $$ppaeciafic Conductance uMhos Tempp. 15 C Odor Appearance Date Sample Cdlecled 10/5/93 _Deb Lab Sample a 10% 11 /5/9� Laboratory Name Hy roLog c, nc. Certification No. 47 k' C performed by Cenref Labs 1384 COD _ Coliform: Coliiform: mnA MF Fecal /100ml MF Total >23 /100ml (Notia: ue. WN nodmi for I%"y hAW aernploe) Dissolved Solids: Total 51.0 mgn pH ��e units * 1,1 TOC� mgn Chloride 2.3 mgn Arsenic mgn Grease and Oils mgn Hardness: Total mgn Phenol mgn Sulfate mgn Specific Conductance uMhos Total Ammonia 0.1 mgn TKN as N mgn Nitrite (NO 2) as N mgn Nitrate (NO 3) as N mgn Phosphorus: Total as P mgn AI - Aluminum mgn Ba - Barium mgn Ca - Calcium mgn Cd - Cadmium mgn Chromium: Total mg/I Cu - Copper mgn Fe - Iron mgn Hg - Mercury mgn K - Potassium mgn Mg - Magnesium mgn Mn - Manganese mgn Na- Sodium mgn Ni - Nickel mgn Pb - Lead mgn Zn - Zinc mgn Pesticides/Herbicides (Specify Compounds) ug/I ugn Other (Specify Compounds and ugn Conation units) 802.0 T;g/1 i02.2 see Mciched I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE. Note: Values should reflect dissolved and . colloidal concentrations. (see #2 on back) � — see bads for frstn,rtlons.. Signature of Permittee (or Authorized Agent] Date " S,bnd tee, sue, and yellow copies «iy to address above. GW-59 REV. SW H Y D R 0 L 0 G I C I COMPANY NAME: Hydrologic -Asheville, Inc HYDROLOGIC PRO►TECP N[lr'18ER: EL932425 HYDROLOGIC SAME NUMBER: 21896 SAMPLE I CATION: MF1=2 Mars Hill DATE SA14DIIED: 10/5/93 DATE EXTRACTED: N/A DATE/TIME ANALYZED: 10/14/93 EPA 502.2 ANALYSIS CAS NO. SDL RESULT ( ug/1) ( ug/1) Benzene 71-43-2 1.0 BDL Brcanobenzene 108-86-1 1.0 BDL E Lai blorcrosthane 74-97-5 1.0 BDL Branodichl.oranethane 75-27-4 1.0 BDL Branoform 75-25-2 1.0 BDL Branco ethane 74-83-9 1.0 BDL n-Butylbenzene 104-51-8 1.0 BDL sec-Butylbenzene 135-98-8 1.0 BDL tent-Butylbenzene 98-06-6 1.0 BDL Carbon tetrachloride 56-23-5 1.0 BDL Chlorcbenzene 108-90-7 1.0 BDL Chloroethane 75-00-3 1.0 BDL Chloroform 67-66-3 1.0 BDL Chlorcmethane 74-87-3 1.0 BDL 2-Moratoluene 95-45-8 1.0 BDL 4-Moratoluene 106-43-4 1.0 BDL D3bramchlorcanethane 124-48-1 1.0 BDL 1,2-Dibrano-3-chlorcprcpane 96-12-8 1.0 BDL 1,2-D,brrn methane (EDB) 106-93-4 1.0 BDL Dibrcmmiethane 74-95-3 1.0 BDL 1,2-D1chlorcbenzene 95-50-1 1.0 BDL 1,3-Dichlorobenzene 541-73-1 1.G BDL 1,4-Dichlorcbenzene 106-46-7 1.0 BDL Dichlorodiflumcmethane 75-71-8 1.0 BDL 1,1-Dichloroethane 75-34-3 1.0 BDL 1491 Twilight Trail 0 Frankfort, KY 40601 L] 502/223-0251 1.1 FAX 502/87.5-8016 C) Toll Free 1-800/728-2251 H Y D R Page 2 continued CCI4PANY NAME: 0 L 0 G I C HMFDI GIC PRCl7ECT NU MBER: HYDRdIAGIC SAMPLE NUM M: SAMPIE IDMMFICATICN: DATE SAMPLED: ANALYSIS 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-DlchlOroethene 1,2-Dichlorcprcpane 1,3-Dichloroprapane 2,2-Dichloropropane 1,1-Dichloroprcpene- cis-1,3-Dichloropropene trans-1,3-Dich1oroprapene Ethylbenzene Hexachlorcbutadiene Isaprapylbenzene p-Iscprapyltoluene Methylene Chloride Naphthalene n-Prcpylbenzene Styrene 111,112-;Petrachloroethane 1, 1, 2, 2-Tetrachloroethane Toluene Ir2,3-Trichlorobenzene 1, 2, 4-Itichlordbenzens Hydrologic -Asheville, Inc FL932425 21896 MW--2 Mars Hill 10/5/93 MEAD EPA 502.2 CAS NO. SDL ( ug/1) 107-06-2 1.0 75-35-4 1.0 156-59-4 1.0 156-60-5 1.0 78-87-5 1.0 142-28-9 1.0 590-20-7 1.0 563-58-6 1.0 10061-01-5 1.0 10061-02-6 1.0 100-41-4 1.0 87-68-3 1.0 98-82-8 1.0 99-87-6 1.0 75-09-2 1.0 91-20-3 1.0 103-65-1 1.0 100-42-5 1.0 630-20-6 1.0 79-34-5 1.0 127-18-4 1.0 108-88-3 1.0 87-61-6 1.0 120-82-1 1.0 0 RESULT ( ug/1) BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 4.05 BDL BDL BDL I N C 1491 Twilight Trail 0 Frankfort, KY 40601 ❑ 502/223-0251 ❑ FAX 502/875-8016 U Toll Free 1-800/728-2251 H Y D R 0 L 0 G I C Page 3 continued COMPANY NAME: Hydrologic Asheville, Inc HYDROLOGIC PROJECT NUMBER: FL932425 HYDROLOGIC SAMFLE NICER: 21896 SAMPLE IDENTIFICATION: MW-2 Mars Hill DATE SAMPLED: 10/5/93 MEi'1E�OD EPA 502.2 ANALYSIS CAS NO. SDL ( ug/1) 1,1,I-Trichloroethane 71-55-6 1.0 1,1,2-Irrichloroethane 79-00-5 1.0 Trichloroethene 79-01-6 1.0 Trichlorofluorcmethane 75-69-4 1.0 1,2,3-Trichl0rcprapane 96-18-4 1.0 1,2,4-Jrrimethylbenzene 95-63-6 1.0 1,3,5-Trimethylbenzene 108-67-8 1.0 Vinyl Chloride 75-01-4 1.0 Xylenes (total) 1330-20-7 1.0 BDL = Below Sample Detection Limit SDL = Sample Detection Limit 0 RESULT ug/1) BDL BDL BDL BDL BDL BDL BDL BDL BDL 1491 Twilight frail C1 Frankfort, KY 40601 [J 50J/'1I3-0251 IJ FAX 507/815-80161] loll Free 1-800/728-2251 Please use kik pen and pa ss tirrrrdy. Facility Name Town of Mars Hill Ackjress PO Box 368 Mars Hill, NC 28754 County Madison Q d' PERMIT NUMBER: (REcxi11 %004298 Non -Discharge NPDES TYPE OF DISPOSAL OPERATION BEING MONITORED (REQUIREDI Well. Location owngra lent Well. Identification Dumber K8593 MW13 Depth 38 Ft. Well Diameter 2Sam pie(Saeerled) Interval Ft T�—Ft. Depth to Water Level 25 fL below measuring point (before sampling) Measuring point is 2 fL above land surface 10 Gallons of water pum led before sampling Field Analysis: pH Bpific Conductance uMhos Temp. Dala Lab Sample Analyzed 1 15 93C11 /5/93 r �� � fiy ro0o5gicc�, Inc. Certification *TOC performed by Cenref labs #384 Lagoon ' Spray Field X Land Appliccelon of Sludge Rotary Distributor _ Appearance No. 47 ATER SECnoN Septic TanWDrain Field Subsurface Low -Pressure Piping (am) Other COD mg/l Nitrite (NO 2) as N mg/I Ni - Ni mg/I Coliform: MF Fecal /100ml Nitrate (NO 3) as N mg/I Pb - bead mg/I Coliform: MF Total > 23 /100ml Phosphorus: Total as P mg/I Zn - Zinc mgA lam; Um WN ,nwdwd for Hgwy bxW earn ples) Al - Aluminum mg/I Pesticides/Herbicides Dissolved Solids: Total 58.0 mg/I Ba - Barium mg/I (Specify Compounds) analyzed) - Calcium mg/I Ug/I ,pH TOC(when 0.0 mg/l Cd - Cadmium mgA ugA Chloride mgA Chromium: Total mg/I ugA Arsenic mgA Cu - Copper mg/l Other (specify Compounds and Grease and Oils mg/I Fe - Iron mg/I CoVation units) 637.5 mg/1 Hardness: Total mg/I `' Phenol mgA K9- Potassium mg/I Sulfate mgA Mg - Magnesium mg/I Specific Conductance 0.1 uMhos Mn - Manganese mg/I Total Ammonia mgA Na - Sodium mg/I TKN as N mg/l I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE. Signature or PerrTi tee (or Authorized Agent] Date Note: Values should reflect d'rssohied and colloidal concentrations. (see 42 on back) • See bads for Instructions •• at" blue green% and yellow oopie9 only to above. GW-59 REV. 9/92 H Y D R 0 L 0 G I C I N C CX M MY NAME: Hydrologic -Asheville, Inc V4FRoia �- • a i-.. HYDFDTMIC SAMPLE NUMBER: 21897 SAMPLE IDENTIFICATION: MW-3 Mars Hill DATE SAMPLED: 10/5/93 DATE EXTRACTED: N/A DATE/TIME ANALYZED: 10/14/93 MEZ'1 M EPA 502.2 ANALYSIS CAS NO. SUL RESULT ( ug/1) ( ug/1) Benzene 71-43-2 1.0 BDL Brambenzene 108-86-1 1.0 BDL Branochloranethane 74-97-5 1.0 BDL Branodichloranethane 75-27-4 1.0 BDL Branoform 75-25-2 1.0 BDL Brcmcmethane 74-83-9 1.0 BDL n-Butylbenzene 104-51-8 1.0 BDL sec-Butylbenzene 135-98-8 1.0 BDL tent-Butylbenzene 98-06-6 1.0 BDL Carbon tetrachloride 56-23-5 1.0 BDL Chlorcbenzene 108-90-7 1.0 BDL Chloroethane 75-00-3 1.0 BDL Chloroform 67-66-3 1.0 BDL Chloranethane 74-87-3 1.0 BDL 2-Chlorotoluene 95-45-8 1.0 BDL 4-Chloratoluene 106-43-4 1.0 BDL Dibramchloranethane 124-48-1 1.0 BDL 1,2-Dibiano-3-chloroprcpane 96-12-8 1.0 BDL 1,2-Dibrananethane (EDB) 106-93-4 1.0 BDL D; brcmumthane 74-95-3 1.0 BDL 1,2-Dichlorabenzene 95-50-1 1.0 BDL 1,3-Dichlorabmzene 541-73-1 1.0 BDL 1,4-Dichloro3enzene 106-46-7 1.0 BDL Dichlorodifluaremethane 75-71-8 1.0 BDL 1,1-Dichloroethane 75-34-3 1.0 BDL 1491 Twilight Trail 0 Frankfort, KY 40601 0 502/223-0251 0 FAX .502/875-8016 U Toll Free 1-800/728-2251 H Y p R 0 Page 2 continued COMPANY NAME: HyDRpIpGIC PROJECT NfM HYDR(7LlOGIC SAMPLE NUMBER: SAMFI� IIF'ICATION: DATE SAMPLED: ANALYSIS 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichlorcethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-DichloraPrWane 2,2-DichloroproPa1e 1,1-Dichloropropene cis-1,3-Dichl0ropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlordmtadi-ene Isvprvpylbenzene p-Isopropyltoluene Methylene Chloride Naphthalene n-prcW1benzene styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-ibtrachloroethane TetrachlOroet>l me Toluene 1,2,3�I'richlorabenZene 1,2,4-irrichlorabenZene Hydrologic -Asheville, Inc FL932425 21897 Ili]-3 Mars Hill 10/5/93 - HEDM EPA 502.2 CAS NOS ( SDL ug/l) 107-06-2 1.0 75-35-4 1.0 156-59-4 1.0 156-60-5 1.0 78-87-5 1.0 142-28-9 1.0 590-20-7 1.0 563-58-6 1.0 10061-01-5 1.0 10061-02-6 1.0 100-41-4 1.0 87-68-3 1.0 98-82-8 1.0 99-87-6 1.0, 75-09-2 1.0 91-20-3 1.0 103-65-1 1.0 100-42-5 1.0 630-20-6 1.0 79-34-5 1.0 127-18-4 1.0 108-88-3 1.0 87-61-6 1.0 120-82-1 1.0 I RESULT ( ug/l) BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1.77 BDL BDL BDL 1491 Twilight fr ail ❑ Frankfort, KY 40601 ❑ 502/923-0251 f] FAX 502/875-8016 U 1 oil Free 1-800/728-2251 H Y D R 0 L 0 G I +C , Page 3 continued COMPANY NAME: Hydrologic -Asheville, Inc HYDROLOGIC PROJECT NUMBER: EL932425 HYDROLOGIC SAMPLE NUMBER: 21897 SAMPLE IDEMiIF'ICATION: M-3 Mars Hill DATE SAMPLED: 10/5/93 1 En= EPA 502.2 ANALYSIS CAS NO. SDL RESULT ( ug/1) ( ug/1) 1,1,1-Trichloroethane 71-55-6 1.0 BDL 1,1,2-Trichloroethane 79-00-5 1.0 BDL Trichloroethene 79-01-6 1.0 BDL Trichlorofluorcmethane 75-69-4 1.0 BDL 1,2,3-Prichloropropane 96-18-4 1.0 BDL 1,2,4-Trimethylbenzene 95-63-6 1.0 BDL 1,3,5-Trimethylbenzene 108-67-8 1.0 BDL Vinyl Chloride 75-01-4 1.0 BDL Xylenes (total) 1330-20-7 1.0 BDL BDL = Below Sample Detection Limit SDL = Sample Detection Limit COMMENTS* 1491 Twilight Troil 0 Frankfort, KY 40601 ❑ 502/223-0251 F] FAX 502/875-8016 1.1 roll Free 1-800/728-2251 COD mgA Col form: MF Fecal /100ml Coliform: MF Total Z.Z A 00ml (Mob: Un MPN nudwd for turbid G) Dissolved Solids: Total-'' mgA k pH (when analyzed) units TOC mgA Chloride mgA Arsenic mgA Grease and Oils mgA Hardness: Total mgA Phenol mgA Sulfate mgA Specific Conductance uMhos Total Ammonia <0.1 mgA TKN as N mgA Nitrite (NO 2) as N mgA Nitrate (NO 3) as N 0.1- mgA Phosphorus: Total as P mgA Al - Aluminum mgA Ba - Barium mgA Ca - Calcium mgA Cd - Cadmium mgA Chromium: Total mgA Cu -. Copper mgA Fe - Iron mgA Fig - Mercury mgA K - Potassium mgA Mg - Magnesium mgA Mn - Manganese mgA Na - Sodium mgA I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE. Signature of Permittee (or Authorized Agent*) GW-59 REV. 9/'92 Ni - Nickel mgA Pb - Lead mgA Zn - Zinc mgA Pesticides/Herbicides (Specify Compounds) ug/I ug/I ugA Other (specify Compounds and CopgMtration units) Note: Values should reflect dissolved and colloidal concentrations. (see 42 on back) ESeads forinstrucdorm Date t blue, green, and yellow copies only to address abova '; SECTION . Septic TanWDrain Field Well Identification Number - NOW.! "!W#�! el. Depth Jn Z) Ft. Well Diameter L RZA (S d) Interval `W. b Ft To T �Y Field Suryb�ssurfacep�Lnw-Pressure Depth to Water Level ft below measunng point (before sampling) Land Apoica°on of Sludge Other Measuring pant is —ft above, land surface 1 Rotary Distributor Gallons of water pumpw 'led before sarrnpling Field Anatys�: pH � Conductance uMhos Temp. 24 o C Odor . Appearance Data Sample Collec�� Dab Lab Sample Analyzed / 0 93 — 7/19/93 Laboratory Name YCIMLogic, Inc. Certification No. 1 *IOC perrormed by CenreT Labs #384 COD _ Coliform: Conform: t!"ti mnIl MF Feel /100ml MF Total ' ' ' A 00ml (NoW: us. IrPN nudwd for Wg* turhid,r9 Dissolved Solids: Total mgA PH (when analyzed) units TOC mgA Chloride -• mgA Arsenic mgA Grease and Oils mgA Hardness: Total mgA Phenol mgA Sulfate mgA Specific Conductance uMhos Total Ammonia ' •'' mgA TKN as N mgA Nitrite (NO 2) as N Nitrate (NO 3) as N Phosphorus: Total AI - Aluminum Ba - Barium Ca - Calcium Cd - Cadmium Chromium: Total _ Cu - Copper Fe - Iron Hg - Mercury K - Potassium Mg - Magnesium _ Mn - Manganese _ Na - Sodium I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE. Signature of Pem-kee (or Authorized Agent] PERMrr NUMBER: (REQUIRED) Non -Discharge N nnna20R NPDES TYPE OF DISPOSAL OPERATION BEING MONITORED (REQUIRED) Lagoon mgA _.31 mgA as P mgA mgA mgA mgA mnA mgA mgA ma/I maA maA maA maA mgA Ni - Nickel mgA Pb - Lead mgA Zn - Zinc mgA Pesticides/Herbicides (Specify Compounds) ugA ug/I ug/I Other (Specify Compounds and Concentration units) _ Note: Values should reflect dissolved and colloidal concentrations. (see 42 on beck) ' See bad* for Insuucdon& Date " Submft blue, green, and yellow c6pies only to address above. GW-59 REV. W/92 Plem Town of Ma Hill ak* Pen and P� ffmtly. e Facility Nam Address P.O. Box 368 Mars H County Madison Well Location owngra 1 en Well Identification Dumber KU6g—Z MWOZ 1��,iAell Depth Ft. Well Diameter 2 Sa[rnla (Srneerted) Iraval 3" Ft To -WFL Depth to Water Level 47� , ft.(be , below meamxrg point bre sampling) Measuring pant is —T—fL above land swims 7.2 Gallons of water pum before sampGrtg PERMrr NUMBER: (REal1OR42413 Non -Discharge bbiill�� NPDES ICE OF DISPOSAL OPERATION BEING MONfrORED (REQUIRED) Lagoon Spray Field Land Ap*adon of Sedge Rolary Distributor Field Analysis: pH � Specific Conductanoa uMhos Temp. 15 oc 7�tC do �_ Appearance Data Sample /" Dais Lab Sample Analyzed Laboratory Name 0 0 , Certification No. 47 *TOC performed by Cenref labs 1384 COD Col'torm: Coltorm: MnIl MF Fecal A 00ml MF Total 0.1 /100ml (roc.: Us. MPN trnttrod for h%o" turbid, W. go Dissolved Solids: Total mgA pH (when analyzed) units TOC •' mgA Chloride 1.4 mgA Arsenic mgA Grease and Oils mgA Hardness: Total mgA Phenol mgA Sulfate mgA Specific Conductance uMhos Total Ammonia mgA TKN as N mgA Nitrite (NO 2) as N mgA Nitrate (NO 3) as N k mgA Phosphorus: Total as P mgA Al - Aluminum mg/I Ba - Barium mg/I Ca - Calcium mgA Cd - Cadmium mgA Chromium: Total mg/I Cu - Copper mg/I Fe - Iron mg/I Hg - Mercury mgA K - Potassium mgA Mg - Magnesium mgA Mn - Manganese mgA Na - Sodium mgA I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE. _v1-4_�_ Signature of" Pernkee (or Authorized Agentl Date Sepik TanWDrain Field Subsurface Low -Pressure PiOn9 , (U'P) Other Ni - Nickel mgA Pb - Lead mgA Zn - Zinc mgA Pesticides/Herbicides (Specify Compounds) ug/I ug/I ugA Other (Specify Compounds and Concentration units) Note: Values should reflect dissolved and colloidal concentrations. (see ##2 on back) ' See bads for instructions. " Submit blue, green, and yellow copies orgy to address above. GW-59 REV. SW ROUNDWATER FIELD/LAB FORM North Carolina Department of -Environment, Health, and Natural Resources DIVISION OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER SECTION County MA D i S On! Lab.Number 8 2� Quad No k a 6 `r / Serial No. -� y s. `-'^ SAMPLE PRIORITY - Date Received �' �- -Time' 1 U Lat 3 - 2. Long. E -2 3 3 7 S � 1 LITINE EMERGENCY M �_ ( RO h d by ' ��1 � From: Bus -Courier Report To: RO FRO, MRO, RRO, WaRO, WiRO, 1L—J�� Date Entry By �`'�� Ck. 5 WSRO, Kinston FO, Other Date Reported: L� ` �- 3 Shipped by: Bus, Courier Other H-9 MO V", j,� , c- k i 9 3 Time 1.2 P�`! Collector(s): Ru M a o u G H Date Purpose: Baseline, Complaint, liance LUST, Other FIELD ANALYSES Owner TV w12 o r /_" R s rf I `tr PH 40o Spec. Cond. 94 at 25° C Location or site 4e G G I e'Pi- ' C 't I , c "f L ' 1 R �' y c a Temp.1 p °C Odor Description of sampling, point 4 v �- `- ' ` G Appearance Taste Sampling Method 1- '�j , L L K Sample Interval urtq,baigr wa) Field Analysis By;.- Remarks 6 .4 1 L. C_ 0 a Le T i ,(pC- f+ 7 p ar t ADnDATnRV AAIAI VCF-q S %.1T1C ►%/--A-r4 R Lit/=L �"ppi.l'•, lctarp Flouride 951 Hardness: T Hardness (n maA Al - Aluminum 1105 mqA Ba - Barium 1007 902 mqA Ca - Calcium 916 u A Cd - Cadmium 102i _LA.n.,nm2 r:hrnminm• Total In Sulfide 745 m9/I as N 61 Cu - Copper 1042 Fe - Iron 1045 Hg - Mercury 71900 K - Potassium 937 Mg - Magnesium 927 Mn - Manganese 105 Na - Sodium 929 Ni - Nickel 1067 NO2 + NOS as N 630 mqA I Se - Selenium 1147 u 11 P: Total as P 665 mqA Zn - Zinc 1092 uqA Lab Comments: I OroanoDhosohorus Pesticides Pesticides I Acid Herbicides I Base/Neutral Extractable Organics F_ Acid. Extractable Organics - i 1,2 - bottle) GW-54 REV. 3/92 For Dissolved Analysis - submit filtered sample and write 'DIS* in block White Copy - Groundwater Central Office Yellow Copy - Regional Office Pink Copy -Central Files Goldenrod Copy -Lab GROUNDWATER FIELD/LAB FORM County MA O / S c ,--j Quad No /-(, 8(0 z SerialNo. -� `f 8� S SAMPLE PRIORITY Lat. 35 48 ` - Z Long. 5.2 3 3 / 8 ROUTINE rJEMERGENCY Report To:49DFRO, MRO, RRO, WaRO, WiRO, WSRO, Kinston FO, Other Shipped by: Bus, gJJCjU Other M_ , IV N r C hC Collector(s): R u ^•r r3ouG /-1 Date 6,11.193 Time North Carolina Department of Environment, Health, and Natural Resources -DIVISION OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER SECTION Lab Number 8 1, 1!- /�eX,fi Date Re!1��F Time eRec'd by: rom: Bu Courie Other Date Entry By: Ck. Date Report S tot l Purpose: Baseline, Complaint, o ii lian , LUST, Other FIELD ANALYSES Owner 7D wN OF MAR-6 i�% r L-t- PH Spec. Cond. 94 at 250 C Location or site S L- C-t o G C -I RPL 4ot) Te 400 oC Odor Description of samplin point w£L L Appearance Taste Sampling Method Field Analysis By: Remarks aA 1 L. EG O K 7- / 5 CAI'/CI%/.. /- A LABORATORY ANALYSES S 7A7" C ►NATE.Z L c vE L __- BOD5 310 m A Diss. Solids 70300 m A A- Silver 1077 u A COD High 340 mgA Flouride 951 mgA Al -Aluminum 1105 u A COD Low 335 mgA Hardness: Total 900 m A Ba - Barium 1007 u A Coliform: MF Fecal 31616 /100ml Hardness non-carb 902 m A Ca - Calcium 916 mgA oliform: MF Total 31504 /100m1 Phenols 32730 u A Cd - Cadmium 1027 u A TOC 680 < m A Specific Cond. 95 uMhos/cm2 Chromium: Total 1034 u A Turbidity 76 NTU Sulfate 945 m A Cu - Copper 1042 u A Sulfide 745 m A Fe - Iron 1045 u A H - Mercury 71900 u A PH 403 units K - Potassium 937 mgA Alkalinity to pH 4.5 410 mgA M - Ma nesium 927 mgA Alkalinity to pH 8.3 415 mgA Mn - Man anese 1055 u A Carbonate 445 mgA Na - Sodium 929 m A Bicarbonate 440 mgA OtS1 NH3 as N 610 6, 0 7 r^ it Ni - Nickel 1067 u A Arsenic: Total 1002 u A TKN as N 625 mgA Pb - Lead 1051 A Carbon dioxide 405 m A rS NO 2 + NOi as N 630 , • /m A Se - Selenium 1147 u A Chloride 940 mgA oiS P: Total as P 665 0, D mgA Zn - Zinc 1092 u A Chromium: Hex 1032 u A Color: True 80 Pt -Co Cyanide 720 mgA ooy F'ARr1 Sample Interval 8 y - 9 T Or anochlorine Pesticides Organophosphorus Pesticides Nitrogen Pesticides Acid Herbicides Base/Neutral Extractable Organics Acid Extractable Organics Pdrgeable Organics (VOA bottle) 1,2 - Dibromoethane (EDB) ►, Rr rn tr r Lab Comments: �i GW-54 REV. 3/92 For Dissolved Analysis - submit filtered sample and write'DIS' in block I' •��, _,i b — r White Copy - Groundwater Central Office Yellow Copy - Re•' gal Office Pink Copy -Central Files Goldenrod Copy -Lab BHAR/DEH LABORATORY VOLATILE ANALYTICAL REPORT LAB NO. 3G 822 REPORTED BY SUPERVISOR CHECKED BY DATE ENTERED BY RBVIBNBD BY CKBCKBD BY SAMPLE TYPE: WATER ANALYSIS RESULTS CAS.�.r_.VOA TARGET COKPOUND TQL DETECTED CAST VOA TARGET COMPOUND TQL DETECTED ugll ugll uq/1 uq/l 75-35-4 1,1-Dichloroethene 0.75 U 96-18-4 1,2,3-Trichloropropane 0.25 U 75-09-2 methylene Chloride 0.25 U 108-86-1 Bramobenzene 1 U 156-60-5 trans-1,2-Dichloroethene 0.75 U 95-49-8 2-Chlarotoluene 0.25 U 75-31-3 1,1-Dichloroethane 0.25 U 106-43-4 4-Chlorotoluene 0.25 U 590-20-7 2,2-Dichloropropane 0.25 U 541-73-1 1,3-Dichlorobenzene 0.25 U 156-59.4 cis-1,2-Dichloroethene 0.25 U 106-46-7 1,4-Dichlorobenzene 0.25 U 67-66.3 Chloroform 0.25 U 95-50-1 1,2-Dichlorobenzene 0.25 U 74-97-5 Bromochloromethane 0.75 U 96-12-8 1,2-Dibromo-3-Chloropropane 1 U 71-55-6 1,1,1-Trichlaroethane 0.25 U 120-82-1 1,2,4-Trichlorobenzene 0.25 u 563-58-6 1,1-Dichlorapropene 0.25 U 87-68-3 Hexachlorobutadiene 0.25 U 56-23-5 Carbon Tetrachloride 0.75' U 87-61-6 1,2,3-Trichlorobenzene 0.75 U 107-06-2 1,2-Dichloroethane 0.25 U 1634-04-4 Hethyl-tert-butyl ether 5 U 79-01-6 Trichloroethene 0.25 U 71-43-2 Benzene 1 U 78-87-5 1,2-Dichloropropane 0.25 U 108-88-3 Toluene 1 U 75-27-4 Bromodichloromethane 0.25 U 100-41-4 Ethyl benzene 1 U 74-95-3 Dibromomethane 1 U 108-38-3 m,p-Kylenes 2 U 10061-01-5 cis-1,3-Dichloropropene 0.25 U 95-47-6 o-%ylene I U 10061-02-6 trans-1,3-Dichloropropene 0.25 U 100-42-5 Styrene I U 79-00-5 '1,1,2-Trichloroethane 0.25 U 98-82-8 Isopropylbenzene 1 127-18-4 Tetrachloroethene 0.25 U 103-65-1 n-Propylbenzene 1 U 142-28-9 1,3-Dichloropropane 0.25 U 108-61-8 1,3,5-Trimethylbenzene 1 U 124-48-1 Dibromachloromethane 0.75 U 98-06-6 tert-Butylbenzene 1 U 106-93-4 1,2-Dibroaoethane 1 U 95-63-6 1,2,4-Tri2ethylbenzene 1 U 108-90-7 Chlorobenzene 0.25 U 135-98-8 sec-Butylbenzene 1 U 630-20-6 1,1,1,2-Tetrachloroethane 0.25 U 99-87-6 p-isopropyltoluene 1 U 75-25-2 Bromoform 0.5 U 104-51-8 n-Butylbenzene 1 U 79-34-5 1,1,2,2-Tetrachloroethane 0.75 U 91-20-3 Naphthalene 1 U TQL- Target Quantitation LAit- Subject to Other purgeables detected Detected change due to instruient sensitivity (up to 10 highest peaks) T- Tentatively Identified, not confirmed B- Estimated Value NO VOLATILE ORGANIC COMPOUNDS DETECTED ET U- Samples analyzed for this compound but GC/BLCD/PID. not detected N- Sample not analyzed for this compound D- Detected below quantitation limit K- GC/KS Analysis performed COKKBNTS: GROUNDWATER FIELD/LAB FORM County M 4 f 4-- Quad No '`r c Serial No. ' " ' SAMPLE PRIORITY Lat. � '� .J Long. - ROUTINE . MEMERGENCY Report To: ikRO, FRO, MRO, RRO, WaRO, WiRO, WSRO, Kinston FO, Other Shipped by: Bus, Courier, Other / r- North Carolina Department of Environment, Health, and Natural Resources DIVISION OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER SECTION Lab Number 8 -•713 0 Date Received " /" ' Time ' Rec'd by: = From: Bus -Courier Other Date Entry By Ck. ' 0Date Reported: %, - ' 7 Collector(s): ­7 e = = Date L ' ' / '' Time I ! r1 purpose: Baseline, Complaint��plia�?LUST, Other :FIELD ANALYSES Owner C' ""�- c ' M PH 400 Spec. Cond. 94 at 250 C Temp., p oC Odor Appearance Taste Field Analysis By: LABORATORY ANALYSES Lab Comments: Location or site — - f - n"�_ v .•.. Description of sampling point Sampling Method - - Sample Interval (pump.ba"er.ati) �._ • Remarks (Pumpmo DMGL air NNW. etc.) Or anochlorine Pesticides Organophosphorus Pesticides Nitro en Pesticides Acid Herbicides Base/Neutral Extractable Organics Acid Extractable Organics Purgeable Organics (VOA bottle) 1,2 - Dibromoethane (EDB) GW-54 REV. 3/92 For Dissolved Analysis - submit filtered sample and write 'DIS' in block White Copy - Groundwater Central Office Yellow Copy -. Regional Office Pink Copy - Central Files Goldenrod Copy - Lab N o r i n Carolina GROUNDWATER FIELD/LAB FORM DIVISION of Environment, Health, and Natural Resources OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER SECTION County f� D /SON - Lab Number 8 Quad No_LL Serial No. y 3 `f L SAMPLE PRIORITY Date Received Rec'd by: Time From: B ourler Lat. 3.5 `f 3 7 Long. 9.1 3 3 a 6 �OUTINE EMERGENCY — Other _ /1 vV � Ck.? Report To:40lFRO, MRO, RRO, WaRO, WiRO, Date Entry By: Date Reported: _1"1 WSRO, Kinston FO, Other Shipped by: Bus, Other ^1 //v^V 0 G K -�� M Pur Baseline, Com laint Com lia LUST, Other G 9 3 Time Collector(s): RN /"rQ o�tG H Date Pose: P (Ca 'GELD ANALYSES owner TowAj of SL" a G E MARS HIL-L- APPL / r-A-7'i t N- L /f i2/e Y C ovy `t,erq PN40o Spec. Cond. 94 at 25° C Location or site °C Odor Description of samplinhpoint V✓t L-L f/Eft Tem P Taste Sampling Method A i L CA Sample Interval rance .. Appearance Remarks QAiL ED ou T P w�lar• •Ic.) !o G(fi7', Field Analysis By: t ABORATORY ANALYSES 57A-rl c WATER IP�mPnG trtn ar wmp. •Ic.) L ��EL = �l• SF' _. _ ... A_ r:1.— In-7-7�i�n Oroanochlonne Pesticides Lab Comments: Organophosphorus Pesticides Nitrogen Pesticides Acid Herbicides Base/Neutral Extractable Organics Acid Extractable Orqanics I ✓ I Purgeable Organics (VOA bottle) I 1.2 - - _ 4 Ij 1►� IC 1,4,; r +- I r'rn, r1..•�tnr be GW 54 REV. 3/92 For Dissolved Analysis - submit filtered sample and write in block White Copy - Groundwater Central Office Yellow Copy - Re,' '(al Office Pink Copy Central Files ""Ootdenrrnf CaEip' �S1H8HHOO posio;iad slsLleug SHM -H alsll uolaeglauenb nolaq paaoaga0 =0 punod000 slyg io; pazLleue Zou aldseS -H pagaagap aou 'aIaIQO'I8�O9 qnq punodsoo slya io; pazdleue soldseS -n L8 Q819818a SWO000 0IHB9ll0 89I1V'iOA OR anlee pageslgs8 -a pasil;uoo qou 'palilluapI dlaelgejual -1 ead bly Oi oq dn) L11ATITsuas auasnigsul oq onp abueyo 115n (s gsago as n s uo a uen 861eb -'101 pagaagaQ pag�agap salgea6ind iayg0 g 7 Gg S -qi l7 IZ qI1 0 7 oualeglgdeN f-OZ-16 n SL'0 aueylaoiolgoeija1-Z'Z'I'I S-tE•6L A 1 auazuaglLlns-u B-IS-t01 n S'0 sio;osoi8 Z-SZ-SL n i SZ10 aueygaoioly3eilal-Z'I'I'i 9-01-OE9 n 1 auanloglddoldosl-d 9-L8-66 n n i auazuaglLgne-oas 8-86-SEI n SZ'0 auazuagoiolyO 1-06-80I n I auuaazzuuaaaugalLzLuy�agagasjslLligllnl-e-t-Sl'ZiEa'iqi 9-f9-S6 n I aueyaosoigla-Z'i t-E6-90E n SL0 aueyasoiolposigla I-St-IZi n 9-90-86 8-L9.801 a SZ'0 auedoidoiolyolQ-Ell 1-81-LZI Weauayaao�olyueigal -B-ZI auazuagjldola-u I-S9-EDI 0 n I SZ'0 aueyaaoiolgallt-Z'I'I 5-00-61 n 1 euazuaglldoidosI B-ZO-86 n auadoldoiolgnlQ-E'l-sueiq 9-ZO-19001 ,.. n 1 aualils S-Zt-001' n SZ'0 OU0111-o 9-Lt-S6 n SZ10 auadoidoioig0la-f'I-sl3 S•I0-I900I n i auegaasosoigla E-S6-iL n Z saualLI-d's E-9E-80I n 1 aueygasoiolyalposoi8 t-LZ-SL n i ouazuaq ILglg t-it-001 n SZ'0 auedoidoiolyolQ-Z'l S-LB-8L n 1 auanlol E-99-901 n SZ10 9uaggaoioly3l1l 9-10-6L n i auazua8 Z-Et-1L n SZ10 0 iaH t-to-tE9I n . SZ'auegaaoiolyolQ-Z'1 Z-90-LDi n S , ayaa Idgnq-qua-ILy�, Sappoly0eigal uogie0 S-EZ-9S p SL'0 auazuagoiolg3lll-f Z I 9-19-LO n nn auadoidoio IgIQ-1'T 9S- SZ'0 aualpeangoiolg3esaH E-89-LB n SZ10 -11 auazuagoiolgolil-t'Z'1 NO -ON S0 auegaaoiolg3111-1'i'i 9-SS SZ'0 n I auedoidoiolyO-E-osoigla-Z i B-ZI-96 n Weaueggasoiolyo0soi8 S-LHL n SZ'0 auazuagoiolgoiQ-Z'I I-OS-S6 n SZ10 sio;oiolq f-99-L9 n SZ10 auazuagoiolgolQ-t I L,9t-901 n SZ10 auegaaoiolyalQ-Z'i-sl0 t-6s-95I n SZ10 auazuagoiolyalQ-E'i I-EL-ItS n SZ'0 auedoid0ioly3la-Z'Z L-OZ-069 n SZ'0 auanlogoiolp-t t-Et-90I n SZ10 aueygaoiolpla-I'l E-tE-SL n SZ'0 auanloaoiolgo-Z B-6t-S6 n WO auagaaoiolyala-Z'I-suer S-09-9Si auezuegosola 1-98-BOi n SZ'O apliolgD aualLyaaH Z-60-SL n I , , auaygaoio 0 n SZ'o auedoidoioly3lil-f Z I t-81-96 n SL'0 I4 lQ-i'I t-SE-SL I n lIbn lIbn I n MUM761 aHnoaHoo i898Y1 VOA #SY3 a81o818a 7b1 aHnoiNoo 18sbV1 ion tsYo silns88 SISLIM valvA :8dll lldmvs is mom L8 Gull 88 LB a8881H8 L8 HUM viva aoslnbsans � Le aslaoasa;:. EZB 9f OR 8Y'I 180a88 1voillivKV allivloh LHoluDayl HSa/UHB North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment, Health, and Natural Resources DIVISION OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER SECTION County tit '"� r_' ! a 4 tf Quad No f-ta :r Serial No. ! - `i / Lat - - .' Long. - Report To:;A FRO, MRO, RRO, WaRO, WiRO, SAMPLE PRIORITY ' - ElROUTINE EMERGENCY WSRO, Kinston FO, Other Shipped by: Bus, Courier, Other Collector(s):."'- m ez--: ,rDated 11 % 3 Time Lab Number 8 Date Received b " �- ' ` Time 0 Rec'd by: From: Bus -Courier `''i �� - Other _ Date EntryBy Date Reported: U Purpose: Baseline, Comp Owner�- /0:�? LUST, Other PH 400 Spec. Cond. 94' at 250 C Location or site i = ` .� >r. L 1 r'r� r c K - h- �' L �• �� ; , .r Temp.10 °C Odor Description of samplingpoint Appearance Taste Sampling Method Sample Interval Field Analysis By: Remarks =; / �• = / 4 °`� LABORATORY ANALYSES BOD5 310 mciA Diss. Solids 70300 m A A - Silver 1077 u A Or anochlorine Pesticides COD High 340 mgA Flouride 951 mgA Al - Aluminum 1105 ugA Organophosphorus Pesticides COD Low 335 mgA Hardness: Total 900 m A Ba - Barium 1007 u A Nitrogen Pesticides Coliform: MF Fecal 31616 /100ml Hardness non-carb 902 mgA Ca - Calcium 916 mgA �-- Coliform: MF Total 31504—/100ml Phenols 32730 u A Cd - Cadmium 1027 u A Acid Herbicides TOC •680 mgA SDecific Cond. 95 uMhos/cm2 Chromium: Total 1034 u A Turbidity 76 NTU Sulfate 945 mgA Cu - Copper 1042 u A Base/Neutral Extractable Organics -/ 2_ I,': �- Sulfide 745 m A Fe - Iron 1045 u A Acid Extractable Organics _ ', ; . • :. j ° ci • LA H - Mercury 71900 u A - " pH 403 :. units --• k' K - Potassium 937 mgA Purgeable Organics (VOA bottle) Alkalinity to pH 4.5 .41.0 mgA M - Magnesium 927 mgA Alkalinity to pH 8.3 415 mgA Mn -Manganese 1055 UgA 1,2 - Dibromoethane (EDB) Carbonate 445 mgA Na - Sodium 929 m A Bicarbonate 440 mgA NH3 as N 610 mgA Ni - Nickel 1067 uoA Arsenic: Total 1002 u A TKN as N 625 mgA Pb - Lead 1051uaA Carbon dioxide 405 mgA NO + NOn as N 630 m A Se - Selenium 1147 u Chloride 940 j mgA P: Total as P 665 mgA In -Zinc 1092 uqA Chromium: Hex 1032 ugA Color: True 80 Pt -Co Cyanide 720 mgA IL 'I I I Lab Comments: GW-54 REV- 3/92 For Dissolved Analysis - submit filtered sample and wrhe'DIS' in block White Copy - Groundwater Central Office Yellow Copy - Regional Office Pink Copy - Central Files Goldenrod Copy - Lab GROUNDWATER FIELD/LAB FORM County Quad No K 80 Serial No. /S A� F -7% SAMPLE PRIORITY Lat. 3-s_ `f P 3 S 19 Long. � 3 3 3 ROUTINE EMERGENCY Report To:Q FRO, MRO, RRO, WaRO, WiRO, Vl--,RO, Kinston FO, Other Shipped by: Bus, ourie Other Collector(s): 9to G 14 Date (O 9-3 Time North Varoiina Department of Environment, Health, and Natural Resources DIVISION OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER SECTION Lab Number 8 9( Date Received Time UL, Rec'd by: From: Bus- ou� M tN - 3 Other Date Entry By: — Ck. _5& Date Reported: ����� 3 M Purpose: Baseline, Compla FIELD ANALYSES owner %own/ *I M�4RS H Spec. Cond. 94 at 250 C Location or site SL "- G E i9 P�°L i c Tem0� oC Odor Description of sampling point 1n/ELL N p 10 Taste Sampling Method /.S A i L ER Appearance 191 Field Analysis By: Remarks L3A i 44 a D u T At ��°' STATI C WATER L-EV£L la Lab Comments: /O;SO ,4 ?ion EA D LUST, Other /Z R R Sample Interval 3 S G I I Organophosphorus Pesticides I I Nitrogen Pesticides I Acid Herbicides 1 Base/Neutral Extractable Organics I Acid Extractable Organics rgeable Organics (VOA bottle) I A tnn. ter se,. ,aa GW-54 REV. 3/92 For Dissolved Analysis submit filtered sample and write'DIS' in block Central Files Goldenrod.C6py_r r`L fi:.�C^ White Copy - Groundwater Central Office Yellow Copy - Rem' --+al Office Pink Copy LAB NO. 3G 824 \ REPORTED BY CHECKED BY REVIEWED BI SAMPLE TYPE: HATER ENNR/DER LABORATORY VOLATILE ANALYTICAL REPORT ANALYSIS RESULTS CAS# VOA TARGET COMPOUND TQL DETECTED uo/1 ua/l SUPERVISOR DATE 6 ENTERED BY CHECKED BY CAST VOA TARGET COMPOUND TQL DETECTED ua/1 uo/1 75-35-4 1,1-Dichloroethene 0.75 U 96-18-4 1,2,3-Trichloropropane 0.25 75-09-2 Methylene Chloride 0.25 U 108-86-1 Broaobenzene 1 156-60.5 trans-1,2-Dichloroethene 0.75 U 95-49-8 3-Chlorotoluene 0.25 75-34-3 1,1-Dichloroethene 0.25 U 106-43-4 4-Chlorotoluene 0.25 590-20-7 2,2-Dichloropropane 0.25 U 541-73-1 1,3-Dichlorobenzene 0.25 156-59-4 cis-1,2-Dichloroethene 0.25 U 106-46-7 1,4-Dichlorobenzene 0.25 67-66-3 Chlorofori 0.25 U 95.50-1 1,2-Dichlorobenzene 0.25 74-97-5 Broaochloroiethane 0.75 U 96-12-8 1,2-Dibromo-3-Chloropropane 1 71-55-6 1,1,1-Trichloroethane 0.25 U 120-82-1 1,2,4-Trichlorobenzene 0.25 563-58-6 1,1-Dichloropropene 0.25 U 87-68-3 eexachlorobutadiene 0.25 56-23-5 Carbon Tetrachloride 0.75 U 81-61-6 1,2,3-Trichlorobenzene 0.75 107-06-2 1,2-Dichloroethane 0.25 U 1634-04-4 Methyl-tert-butyl ether 5 79-01-6 Trichloroethane 0.25 U 71-43-2 Benzene 1 78-87-5 1,2-Dichloropropane 0.25 U 108-88-3 Toluene s 1 75-27.4 Bromodichloromethane 0.25 U 100-41.4 Ethyl benzene 1 74-95.3 Dibromomethane 1 U 108-38-3 m,p-lylenes 2 10061.01-5 cis-1,3-Dichloropropene 0.25 U 95-47-6 o-lylene 1 10061-02-6 trans-1,3-Dichloropropene 0.25 U 100-42-5 Styrene 1 79-00-5 1,1,2-Trichloroethane 0.25 U 98-82-8 Isopropylbenzene 1 127-18-4 Tetrachloroethane 0.25 U 103-65-1 n-Propylbenzene 1 142-28-9 1,3-Dichloropropane 0.25 U 108-67-8 1,3,5-Trimethylbenzene 1 124-48-1 Dibroaochloromethane 0.75 U 98-06-6 tert-Butylbenzene 1 106.93-4 1,2-Dibromoethane 1 U 95-63-6 1,2,4-Trimethylbenzene 1 100-90-7 Chlorobenzene 0.25 U 135-98-8 sec-Butylbenzene 1 630-20-6 1,1,1,2-Tetrachloroethane 0.25 U 99-87-6 p-isopropyltoluene 1 75-25-2 Bromoform 0.5 U 104-51-8 n-Butylbenzene 1 19-34-5 1,1,2,2-Tetrachloroethane 0.75 U 91.20-3 Naphthalene _, 1 TQL- Target Quantitation Limit- Subject to Other purgeables detected change due to instrument sensitivity jup to 10 highest peaks) T- Tentatively Identified, not confirmed E- Estimated Value NO VOLATILE ORGANIC COMPOUNDS DETECTED BY U- Samples analyzed for this compound but GC/BLCD/PID. not detected N- Sample not analyzed for this compound D- Detected below quantitation limit M- GC/KS Analysis performed COMMENTS: Detected ug/1 U, U U U U' U DIVI ... ' :. SION OF ENVIRONMENTAL MANAGEMENT -GROUNDWATER SECTION rROUNDWATER- QUAL[TY:MONITQRING P.O. Box 29535 OMPLIANCE REPORT FARM -For: aMdo� .ions+, NC :zrsis osas wrr 1) 731=� :please . 'te . (9 9 or .call ; . Facility Name Town of Mars Hill Address P.O. Box 368 Mars Hill, NC 28754 County Madison Well LocationTopCorner Field #1 Well Identification Number #3 Well Depth 38 Ft. Well Diameter 2„ Sample (Screened) Interval Ft To Ft. PERMIT NUMBER: (REQUIRED) Non -Discharge WQOOD4298 NPDES TYPE OF DISPOSAL OPERATION BEING MONITORED (REQUIRED) Depth to Water Level 25.5 ft. below measuring point (before sampling) Measuring point is 1.25 ft. above land suriaoe Gallons of water pumpedlbailed before sampling 13.5 Field Analysis: pH Specific Conductance uMhos Temp. 11 o C Odor Date Sample 2/18/93 D� And 2/18/93 - 3/2/93 Laboratory Name HydroLo4ic, Inc. Certification *TOC performed by Cenref Labs, Inc. COD _ Coliform: Col'iform: maA MF Fecal <1.1 /100ml MF Total <1.1 /100ml (Note: Use MPN method for highly turbld sernples) Dissolved Solids: Total 67.0 mgA pH (Men. analyzed) 6.2 units *TOC 3.0 mgA Chloride 3.0 mgA Arsenic mgA Grease and Oils mgA Hardness: Total mgA Phenol mgA Sulfate 1.5 mg/l Specific Conductance uMhos Total Ammonia 0.1 mg/l TKN as N mgA Lagoon Spray Field x lard Application of SUdge Rotary Distributor Appearance No. 47 Nitrite (NO 2) as N mgA Nitrate (NO 3) as N 0.33 mgA Phosphorus: Total as P mg/l Al - Aluminum mg/l Ba - Barium mgA Ca - Calcium mg/l Cd - Cadmium mg/l Chromium: Total Q . 025 mgA Cu - Copper mgA Fe - Iron mgA Hg - Mercury mg/l K - Potassium mg/l Mg - Magnesium mgA Mn - Manganese mgA Na - Sodium mgA Septic TanWDrain Field Subsurface Low -Pressure Piping (LPP) Other Ni - Nickel mg/l Pb - Lead mg/l Zn - Zinc mg/l Pesticides/Herbicides (Specify Compounds) Ug/1 ug/I Other (Specify Compounds and ug/I Concentration units) TSS 79.0 mg/1 I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE. Note: Values should reflect dissolved and colloidal concentrations. (see #2 on back) G' See bade for instructions. Signature of Ffermittee (or, Authorized Agent') Date " Submit Flue, green, and yellow copies orgy to address above. GW-59 REV. 4/91 :DIVISION OF ENVIRONMENTAL 'MANAGEMENT - GROUNDWATER .SECTION GROUND IUATER .. QUALITY MONITORING:. P.O.BOX 29535 COMPLIANCE :REPORT .:FORM ,raaeortel forms �;.:.R, ALEIG+, NC .2762s os csl .(919) : T33 322 Facility Name Town of Mars Hill Address P . 0. Box 368 rs Hil PERMIT NUMBER: (REQUIRED) Non -Discharge WOOOO 298 NPDES TYPE OF DISPOSAL OPERATION BEING MONITORED Well Location— _RottM1 Cornel�(REQUIRED)_F�pld �1 Lagoon Septic Tank/Drain Field Well Identification Number #1 Well Depth 100 Ft. Well Diameter 2" le (Screened) Interval 88 Ft To 100 Ft. Spray Field subsurface Low -Pressure Depth to Water Level . 7 f . below measuring point before Il x Piping (LPP) �P n9 Po ( sampling) Lard Application of Sk,dge Measuring pant is 1.25 ft. above laird surface Other Gallons of water pumpedlbailed before sampling 24.0 Rotary Distributor Field Analysis: pH Specific Conductance uMhos Temp. 12 °C Odor Appearance Date Sample Collected 2 / 18 /93 Dale Lab Sample Analyzed 2 / 18 /9 3 - 3 / 2 / 9 3 Laboratory Name HydroLogic, Inc. Certification No. 47 *TOC performed by Cenref Labs #384 COD mg/I Col'Iform: MF Fecal 0.1 /100ml Col'Iform: MF Total 2.2 A 00ml (Note: Use tiIIPN ffwdW for highly turbid samples) Dissolved Solids: Total 70.0 mgA pH (when analyzed) 6.2 units *TOC 3.0 mgA Chloride 1.5 mgA Arsenic mgA Grease and Oils mgA Hardness: Total mgA Phenol mgA Sulfate 0.8 mgA Specific Conductance uMhos Total Ammonia 0.3 mgA TKN as N mg/I County Madison Nitrite (NO 2) as N mgA Nitrate (NO 3) as N 0.17 mgA Phosphorus: Total as P mgA AI - Aluminum mgA Ba - Barium mgA Ca - Calcium mgA Cd - Cadmium mgA Chromium: Total < 0,025 mg/l Cu - Copper. mgA Fe - Iron mg/I Hg - Mercury mgA K - Potassium mgA Mg - Magnesium mgA Mn - Manganese mgA Na - Sodium mgA Ni - Nickel mg/1 Pb - Lead mg/1 Zn - Zinc mg/1 Pesticides/Herbicides (Specify Compounds) ug/1 ug/l ug/1 Other (Specify Compounds and Concentration units) TSS 14.0 mg A I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE. Note: Values should reflect dissolved and colloidal concentrations. (see #2 on back) 3 — " �3 • see bads for Instructions. Signature o Permittee (or Authorized Agent') Date " Submit blue, green, and yellow copies only to address above. GW-59 REV. 4/91 ;`..•'-.-DIVISION OF ENVIRONMENTAL :MANAGEMENT - GROUNDWATER SECTION GROUNDWATER ;QUALITY MONITORING P.O. Box 29535 COMPLIANCE .. REPORT >FORM For �+ forms-o +, NC r�s� os.� Plem :wrh9 orral l ::: ;:(919) ,733 Facilit y Name Town of Mars Hill Address P , 0 . Box 368 Mars Hill, NC 28754 County Madison Well Location PERMIT NUMBER: (REQUIRED) Non -Discharge WQ0004298 NPDES TYPE OF DISPOSAL OPERATION BEING MONITORED (REQUIRED) Lagoon Septic TanWDrain Field Well Identification Number YZ Well Depth ou Ft. Well Diameter 2 ° Sample ($CreenAd) interval 50 Ft. To 60 Ft. Spray Field Subsurtaoe Low -Pressure Piping (LPP) Depth to Water Level 50.4 ft.below measuring point (before sampling) x Land Apprcauon of s►,dge Measuring point is 1.25 fL above land surface other Gallons of water pumpedbailed before sampling 9.0 Rotary Distributor Field Analysis: pH Specific Conductance uMhos Temp.12°C Odor Appearance Date Sample Collected 2/18/93 Date Lab Sample Analyzed 2/18/93 - 3/2/93 Laboratory Name HydroLog i c Inc. Certification No. 47 *TOC performed by Cenref Labs #384 COD Coliform: Coliform: mall MF Fecal <1.1 /100ml MF Total 0.1 /100ml (Note: Use MP N method for highly �) Dissolved Solids: Total 68.0 mgA g pH (when analyzed) 6.3 units *TOC 2.5 mgA Chloride 3.2 mgA Arsenic mg/I Grease and Oils mg/I Hardness: Total mgA Phenol mg/I Sulfate 2.3 mgA Specific Conductance uMhos Total Ammonia 0.5 mgA TKN as N mg/I Nitrite (NO 2) as N mgA Nitrate (NO 3) as N <0.10 mg/I Phosphorus: Total as P mgA Al - Aluminum mg/I Ba - Barium mgA Ca - Calcium Cd - Cadmium <0.025 mg g/I Chromium: Total mgA Cu - Copper mgA Fe - Iron mg/I Hg - Mercury mg/I K - Potassium mg/I Mg - Magnesium mg/I Mn - Manganese mgA Na -Sodium mgA I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE. Signature of Perrnittee (or Authorized Agent') Date Ni - Nickel mg/I Pb - Lead mg/1 Zn - Zinc mg/1 Pesticides/Herbicides (Specify Compounds) ug/I ug/I ug/I Other (Specify Compounds and Concentration units) TSS 293-9 mg/1 Note: Values should reflect dissolved and colloidal concentrations. (see #2 on back) See back for instructions. •' Submit blue, green, and yellow copies only to address above. GW-59 REV. 4/91 ANNUAL REPORT RESIDUAL LAND APPLICATION Permit No. 0 a n 0 0 H a 9'6 _ County , '� ,n Year 19 9 Facility Name (as shown on permit) I oV.) n YYIc, r H i t Land Application Operator n e r - ,arnf-3 Facility was compliant during calendar year 1992 with all conditions of the land application permit (including but not limited t9 items 1-10 below) issued by the Division of Environmental Management V YES NO. IF NO, PLEASE PROVIDE A WRITTEN DESCRIPTION WHY THE FACILITY WAS NOT COMPLIANT, THE DATES, AND EXPLAIN CORRECTIVE ACTIONS TAKEN. 1. Only residuals approved for this permit were applied to the pet mitted sites. 2. Soil pH was adjusted as specified in the permit and lime (if needed) was applied to achieve a soil pH of at least 6.5. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. TCLP analysis were performed as required by the permit and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. All operations and maintenance requirements were complied with or, in the case of a deviation, prior authorization was received from the Division of Environmental Management. 7. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 8. Vegetative cover as specified in the permit was maintained on this site and that the crops grown were removed in accordance with the crop management plan. 9. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 10. All buffer requirements as specified on the permit were maintained during each application of residuals. I CERTIFY THAT THE ABOVE INFORMATION IS ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE, AND ALL THE INFORMATION IN THE SUCCEEDING PAGES IS ACCURATE AND COMPLETE. C�14 y - a- t- 93 Pern-dttee Signature Date Land Application Operator Date Signature APPLICATION RATE REPORT FORM • BEFORE YOU BEGIN, PLEASE MAKE COPIES OF THIS BANK FORM IF ADDITIONAL FORMS ARE NEEDED • FILL IN ONLY THOSE ITEMS APPLICABLE TO YOUR PERMIT • PLACE AN N/A IN BLANK WHEN NOT APPLICABLE PERMIT # WQ OW 1 ' a 9 SITE # I FIELD # FARM # OWNER/LESSEE L o,r r y Cody ACREAGE (APPLIcAmoN AREA MUM AS SHOWN ON PERNM 1 � • 0 ACREAGE (AcrvAL AREA IunL imD ON Tm Srrn 14, Q APPLICATION METHOD 5 inr CROP NAME Ft 5 " LA, CROP NAME (\I APPLICATION RATES( LBSIACRFIYR ) PERMITTED AMOUNT LIMIT. APPLIED PAN NJA NIA PHOSPHORUS / METALS LOADING ( LBS/ACRE ) REPORT ACCUM. LIFETIME CEC YEAR TOTAL PERMIT TOTAL LIMIT LEAD = 5� 7 .5 6 500 140 ZINC �'i,Ua. a 5n �p COPPER 1�• �- / (� i�f; 0 NICKEL CADMIUM , - a].0 LIME APPLICATION DATE ( LBS/ACRE ) LIME 6 a S 5 DATE APPLIED I- 5' 9'� LIME DATE APPLIED LIME DATE APPLIED PERMIT # WQ0QQ � a 9 I SITE # / FIELD # �. FARM # I OWNER/LESSEE Q ACREAGE (AppucA 7ONAREAPERSrM SHOWNONPERI D �• c� ACREAGE (AcraAL AREA tmL= M stro , APPLICATIONMETHOD 5 k-ia.cA CROP NAME -Fe S C v-(-- CROP NAME ter,/ A APPLICATION RATES( LBS/ACRFJYR ) PERMITTED AMOUNT LIMIT _ APPLIED N PAN /fl PHOSPHORUS METALS LOADING ( LBS/ACRE ) REPORT ACCUM LIFETIME CEC YEAR TOTAL PERMIT TOTAL LIMIT LEAD &36 E;00 1/•y ZINC 310 i 11 rAo ?ISO 8. 0 COPPER SIN I ,0 I a s 1 I. C NICKEL l0q .-dy`f / as CADMIUM U dD 1 0 5 6 y. 5 LIIdE APPLICATION RATE ( LBS/ACRE ) LIME / U O o o DATE APPLIED LIME DATE APPLIED LIME DATE APPLIED 51ud6e Lend Applie■tlon/Dlsporal Report rots. Annual Loading Suesnty rr ('�� - m Oer (�Ut'r �oCl'Tleld Ne. �` a No. Aeree 4, $ Field Crop lA Appllcntlon Iictl.o.l (clrcl enrlate eubsnrleee ',sell ptl;? •Soil K ; !qE slodRRe Appilcetlon Sludge Tntel AppllcAtlon f.Allons Callone Per Acre •• Total lletals and Ih1tr ent I.oedlnF. Dry Tone IlltrnRen Pbeeplmroc T(tt:' lbs/Acre __ _—/�] Supplewent., A.IJ- pions lbs_/Acr. Date Drr tom Per Acre P.A.It. POi AA P G6 L�a•I Iticwel t:a.l. 'ota.^..•.I� L1.� .:' / a -9 off- 7.n t b ql -- Cd K ISO `')oOCO — — - --- — - 9d Ed�L ao ( ,OC) p -- 0 13 ? a? *Sell pR and K must be analyzed and reported annually "Dry Tone -Wet Callone K I nolld■ 2i.000 j Sludge Land Applltatlon/bisposal Report Form Annue( Loading Suwwwry II Owner eIrt-1/ C41"eld Ro. / lie Acres ! rleld Crop des 1 u� Appllcntlon I1rtl.nd (Circle): arfeee eubsnrfnce *so lt pit :7,d 1 Sl"dle SludgIte Appif tlon lletals'eod Is 11 K C T"ta1 Callene Application Cellons Per Aere bate •• "Total Ocr Tone Dry Tone rer Acre Ilotrlent Loading. Ibs/acre Rltrngen Re—. nrua lnf:' Coppre ZI„� — -- I.ra.l Supplewental Add - (tfon� Ibs_/acr- 70•30-9 11600p P.A.it PO` ae P fn Zn t'h IllcMel f:a.l. ltl Cd R LIw� 1'��aysf..:. �4-9 101 — I- :26 �`L'— - -- i Q. — _ — 26 sr o 101 a q. 27i -qD 2011 , / L_rj L -- -- — — � _ 4141 Annuei155)00lIal6 " • S �7, l 7— — -- *Sell pR end [ uuat be ena(yted and reported annually r-- "Jo. 1_ aebr7 Tone -pet Callone 2 I aollde 2irOOO H Y D R 0 L 0 G I C , COMPANY NAME: Hydrologic -Asheville, Inc HYDROLOGIC PROJECT NUMBER: EL920090C HYDROLOGIC SAMPLE NUMBER: 10252 SAMPLE IDENTIFICATION: Mars Hill Well #1 DATE SAMPLED: 11/2/92 DATE EXTRACTED: N/A DATE/TIME ANALYZED: 11/10/92 METHOD EPA 502.2 ANALYSIS CAS NO. SDL RESULT ( ug/1) ( ug/1) Benzene 71-43-2* 0.5 BDL Branobenzene 108-86-1 0.5 BDL Branochloranethane 74-97-5 0.5 BDL Branodichloranethane 75-27-4 0.5 BDL Branoform 75-25-2 0.5 BDL Bramnethane 74-83-9 0.5 BDL n-Butylbenzene 104-51-8 0.5 BDL sec-Butylbenzene 135-98-8 0.5 BDL tert-Butylbenzene 98-06-6 0.5 BDL Carbon tetrachloride 56-23-5 0.5 BDL Chlorobenzene 108-90-7 0.5 BDL Chloroethane 75-00-3 0.5 BDL Chloroform 67-66-3 0.5 BDL Chloranethane 74-87-3 0.5 BDL 2-Chlorotoluene 95-45-8 0.5 BDL 4-Chlorotoluene 106-43-4 0.5 BDL Dibranochlorav--thane 124-48-1 0.5 BDL 1,2-Dibrano-3-ch1orvprcpane 96-12-8 0.5 BDL 1,2-Dibranoethane (EDB) 106-93-4 0.5 BDL Dibrancmethane 74-95-3 0.5 BDL 1,2-Dichlorobenzene 95-50-1 0.5 BDL 1,3-Dichlorobenzene 541-73-1 0.5 BDL 1,4-Dichlorobenzene 106-46-7 0.5 BDL Dichlorodifluoranethane 75-71-8 0.5 BDL 1,1-Dichloroethane 75-34-3 0.5 BDL 1003 Twilight Trail • Frankfort, Ky. 40601 • (502) 223-0251 • FAX: (502) 227-9451 • Toll Free: 1-800-728-2251 Fi �- -- ---- U - ---- ---- -- Page 2 continued CCWANY ram: Hydrologic -Asheville, Inc _ HYDROIDGIC PROJECT NUMBER: FL920090C HYDROLOGIC SAMPLE NUMBER: 10252 SAMPLE IDENTIFICATION: Mars Hill Well #1 DATE SAMPLED: 11/2/92 MMM EPA 502.2 ANALYSIS CAS NO. SDL ( u9/1) RESULT ( u9/1) 1,2-Dichloroethane 107-06-2 0.5 0.5 BDL BDL 1,1-Dichloroethene 75-35-4 156-59-4 0.5 BDL cis-1,2-Dichloroethene trans-1,2-Dichloroethene 156-60-5 0.5 BDL 1,2-Dichloropropane 78-87-5 0.5 BDL 1,3-Dichloropropane 142-28-9 0.5 0.5 BDL BDL 2,2-Dichloropropane 590-20-7 563-58-6 0.5 BDL 1,1-Dichloropropene cis-1,3-DichloroproPene 10061-01-5 0.5 BDL trans-1,3-Dichloropropene 10061-02-6 0.5 BDL Ethylbenzene 100-41-4 0.5 0.5 BDL BIDL Hexachlorobutadiene 87-68-3 0.5 BDL Iscpropylbenzene 98-82-8 99-87-6 0.5 BDL p-Isopropyltoluene Methylene Chloride 75-09-2 0.5 BDL Naphthalene 91-20-3 0.5 0.5 BDL BUL n-Propylbenzene 103-65-1 0.5 BDL Styrene 1,1,1,2-Tetrachloroethane .100-42-5 630-20-6 0.5 BDL 1,1,2,2-Tetrachlamethane 79-34-5 0.5 BDL Tetrachloroethene 127-18-4 0.5 0.5 BDL BDL Toluene * 108-88-3 87-61-6 0.5 BDL 1,2,3-Trichlorobenzene 120-82-1 0.5 BDL 1,2,4-Trichlorcbenzene 1003 Twilight Trail • Frankfort, Ky. 40601 • (502) 223-02511 • FAX: (502) 227-9451 • Toll Free: 1-800-728-2251 Y D Fi 0 L G I..-. C Page 3 continued COMPANY NAME: HYDROIDGIC PROJECT NUMBER: HYDROLOGIC SAMPLE NUMER: SAMPLE IDEWIFICATION: DATE SAMPLED: ANALYSIS 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoremethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl Chloride Xylenes (total) Hydrologic -Asheville, Inc EL920090C 10252 Mars Hill Well #1 11/2/92 mign OD EPA 502.2 CAS NO. SDL RESULT ( u9/1) ( ug/1) 71-55-6 0.5 BDL 79-00-5 0.5 BDL 79-01-6 0.5 BDL 75-69-4 0.5 BDL 96-18-4 0.5 BDL 95-63-6 0.5 BDL 108-67-8 0.5 BDL 75-01-4 0.5 BDL 1330-20-7 0.5 BDL BDL-= Below Sample Detection Limit SDL = Sample Detection Limit COMMENTS:--------- nn� T-,•,iligI,t 7rnil - Fr'trll-inrt Kv nnsoi • (502) 223-0951- • FAX: (rw) 227--9451 • 1 oil Frei: 1-SOU-728 2251 Fi O L 0 -G I C .�6 u1I ; ►1 ►i_�„I�F HYDROLOGIC PR0= NUMBER: HYDROU GIC SAMPLE NUMBER: SAMPLE IDIINTIFICATION: DATE SAMPLED: DATE EXTRACTED: DATE/TIME ANALYZED: ANALYSIS Benzene Bromobenzene Brcmmhloromethane Bromodichloranethane Bromoform Brcoomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chlorcmethane 2-Chlorotoluene 4-Chlorotoluene Dibromochlorcmethane 1,2-Dibram -3-chloropropane 1,2-Dibramoethane (EDB) Dibrcmamethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoranethane 1,1-Dichloroethane Hydrologic -Asheville, Inc FL920090C 10253 Mars Hill Well #2 11/2/92 N/A 11/10/92 I ETHOD EPA 502.2 CAS NO. SDL ( ug/1) 71-43-2 0.5 108-86-1 0.5 74-97-5 0.5 75-27-4 0.5 75-25-2 0.5 74-83-9 0.5 104-51-8 0.5 135-98-8 0.5 98-06-6 0.5 56-23-5 0.5 108-90-7 0.5 75-00-3 0.5 67-66-3 0.5 74-87-3 0.5 95-45-8 0.5 106-43-4 0.5 124-48-1 0.5 96-12-8 0.5 106-93-4 0.5 74-95-3 0.5 95-50-1 0.5 541-73-1 0.5 106-46-7 0.5 75-71-8 0.5 75-34-3 0.5 RESULT ug/1) BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1003 Twilight Trail • Frankfort, Ky. 40601 • (502) 223-0251 • FAX: (502) 227-9451 • Toll Free: 1-800-728-2251 U R 0 L 0 1 Page 2 continued ke ui• z& HYDROLOGIC PROJECT NUMBER: HYDROLOGIC SAMPLE NUMBER: SAMPLE IDENTIFICATION: DATE SAMPLED: ANALYSIS 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Iscpropylbenzene p-Isopropyltoluene Methylene Chloride Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethene 1,1,2,2-Tetrachloroethene Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1;2,4-Trichlorobenzene Hydrologic Asheville, Inc EL920090C 10253 Mars Hill Well #2 11/2/92 1 MMM EPA 502.2 CAS NO. SDL ( ug/1) 107-06-2 0.5 75-35-4 0.5 156-59-4 0.5 156-60-5 0.5 78-87-5 0.5 142-28-9 0.5 590-20-7 0.5 563-58-6 0.5 10061-01-5 0.5 10061-02-6 0.5 100-41-4 0.5 87-68-3 0.5 98-82-8 0.5 99-87-6 0.5 75-09-2 0.5 91-20-3 0.5 103-65-1 0.5 100-42-5 0.5 630-20-6 0.5 79-34-5 0.5 127-18-4 0.5 108-88-3 0.5 87-61-6 0.5 120-82-1 0.5 RESULT ug/1) BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BQL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1003 Twilight 'Trail Frankfoi t, Ky. 40601 • (502) 223-0251 • FAX: (502) 2.'l_7-9451 • 'f oll Free: 1-800-728--2251 Page 3 continued dui' : kl HYDROLOGIC PROJECT NUMBER: HYDROLOGIC SAMPLE NUMBER: SAMPLE IDENTIFICATION: DATE SAMPLED: Hydrologic -Asheville, Inc FL920090C 10253 Mars Hill Well #2 11/2/92 METHOD EPA 502.2 ANALYSIS CAS NO. SDL RESULT ( ug/1) ( ug/1) 1,1,1-Trichloroethene 71-55-6 0.5 BDL 1,1,2-Trichloroethane 79-00-5 0.5 BDL Trichloroethene 79-01-6 0.5 BDL Trichlorofluoramethane 75-69-4 0.5 BDL 1,2,3-Trichloropropane 96-18-4 0.5 BDL 1,2,4-Trimethylbenzene 95-63-6 0.5 BDL 1,3,5-Trirmthylbenzene 108-67-8 0.5 BDL Vinyl Chloride 75-01-4 0.5 BDL Xylenes (total) 1330-20-7 0.5 BDL BDL = Below Sa[:ple Detection Limit SDL = Sanple Detection Limit COMMENTS: L0------------ COMPANY NAME: HYDROLOGIC PROJECT NUMBER: HYDROLOGIC SAMPLE NUMBER: SAMPLE IDENTIFICATION: DATE SAMPLED. 'DATE EXTRACTED: DATE/TIME ANALYZED: ANALYSIS Benzene Branobenzene Branochloranethane Branodichloranethane Branoform Brann:nethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloranethane 2-Chlorotoluene 4-Chlorotoluene Dibranochloramethane 1,2-Dibrano-3-chloropropane 1,2-Dibranoethane (EDB) Dibra[:cmethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorcbenzene Dichlorodif luoranethane 1,1-Dichloroethane Hydrologic -Asheville, Inc EL920090C 10254 Mars Hill Well #3 11/2/92 N/A 11/10/92 METHOD EPA 502.2 CAS NO. SDL ( ug/1) 71-43-2 0.5 108-86-1 0.5 74-97-5 0.5 75-27- 4 0.5 75-25-2 0.5 74-83-9 0.5 104-51-8 0.5 135-98-8 0.5 98-06-6 0.5 56-23-5 0.5 108-90-7 0.5 75-00-3 0.5 67-66-3 0.5 74-87-3 0.5 95-45-8 0.5 106-43-4 0.5 .124-48-1 0.5 96-12-8 0.5 106-93-4 0.5 74-95-3 0.5 95-50-1 0.5 541-73-1 0.5 106-46-7 0.5 75-71-8 0.5 75-34-3 0.5 RESULT ( ug/1) 1.5 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL, BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1003 Twilight Trail • Frankfort, Ky. 40601 (502) 223-0251 • FAX: (502) 227-9451 • Toll Free: 1-800-728 2251 e Y D R 0 L 0 G Page 2 continued COMPANY NAME: Hydrologic -Asheville, Inc HYDROLOGIC PROJECT NUMBER: FL920090C HYDROOLOGIC'SAMPLE NUMBER: 10254 SAMPLE IDENTIFICATION: Mars Hill Well #3 DATE SAMPIED: 11/2/92 METHOD EPA 502.2 ANALYSIS CAS NO. SDL RESULT ( ug/1) ( ug/1) 1,2-Dichloroethane 107-06-2 0.5 BDL 1,1-Dichloroethene 75-35-4 0.5 BDL cis-1,2-Dichloroethene 156-59-4 0.5 BDL trans-1,2-Dichloroethene 156-60-5 0.5 BDL 1,2-Dichloropropane 78-87-5 0.5 BDL 1,3-Dichloropropane 142-28-9 0.5 BDL 2,2-Dichloropropane 590-20-7 0.5 BDL 1,1-Dichloropropene 563-58-6 0.5 BDL cis-1,3-Dichloropropene 10061-01-5 0.5 BDL trans-1,3-Dichloroprcpene 10061-02-6 0.5. BDL Ethylbenzene 100-41-4 -0.5 BDL Hexachlorobutadiene 87-68-3 0.5 BDL Iscpropylbenzene 98-82-8 0.5 BDL p-Isopropyltoluene 99-87-6 0.5 BDL Methylene Chloride 75-09-2 0.5 BDL Naphthalene 91-20-3 0.5 BDL n-Propylbenzene 103-65-1 0.5 BDL Styrene 100-42-5 0.5 BDL- 1,1,1,2-Tetrachloroethane 630-20-6 0.5 BDL 1,1,2,2-Tetrachloroethene 79-34-5 0.5 BDL Tetrachloroethene 127-18-4 0.5 BDL Toluene 108-88-3 0.5 BDL 1,2,3-Trichlorcbenzene 87-61-6 0.5 BDL 1,2,4-Trichlorcbenzene 120-82-1 0.5 BDL 1003 Twilight Trail • Frankfort, Ky. 40601 • (502) 223-0251 • FAX: (502) 227-9451 roil Free: 1 800-728-2251 -- -- ---- --- L. -- - - -- C �- -- - - --- -- - -- - N Page 3 continued • i• Dui HYDROLOGIC PROJECT NUMBER: HYDROLOGIC SAMPLE NUMBER: SAMPLE IDENTIFICATION: DATE SAMPLED: ANALYSIS 1,1,1-Trichloroethene 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloroprcpane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vial Chloride Xylenes (total) Hydrologic -Asheville, Inc EL920090C 10254 Mars Hill Well #3 11/2/92 METHOD EPA 502.2 CAS NO. SDL ( ug/1) 71-55-6 0.5 79-00-5 0.5 79-01-6 0.5 75-69-4 0.5 96-18-4 0.5 95-63-6 0.5 108-67-8 0.5 75-01-4 0.5 1330-20-7 0.5 BDL = Below Sanple Detection Limit SDL = Sanple Detection Limit RESULT ug/1) BDL BDL BDL BDL BDL BDL BDL BDL BDL 1003 Twilight Trail • Frankfort, Ky. 40601 • (502) 223-0251 • FAX: (502) 227-9451 • Toll Free: 1-800-728-2251 H•vdroLogic, Inc. r 13.� Lyman Street. Asheville, NC 28801 � .� �.+. � • .�, ,o �. �.'' � �,,. r. ?ter �, November 15, 1991 LABS?RATORY RESULT'S CONTROL #: 6143 SAMPLE 'ID: MW1/ 0-441 RECEIVED 10/31/91 MATRIX WATER ANALYZED 11/13/91 METHOD 502.2 SmirLED 10/25/ 91 PROJECT MARS HILL METHOD 502.2 PARAMETER AMOUNT UNITS BENZENE ND<0.009 ug/[, BROMOBENZENE ND<0.006 " B5',OMODICHLOROMETHANE ND<0.01 RROMODICHLOROMETHANE ND<0.02 pF(:'t' 0FORM ND < 1.6 BPOMOMETHANE ND'< 1.1 " n--BUTYLBENZENE ND <0. 02 sec-BUTYLBENZENE ND<0.02 tert-BUTYLBENZENE ND<0.06 CARBON TETRACHLORIDE ND<0.01 C:HLOROBENZENE ND<0.003 C"HLOPOETHANE HD<0 . 1 CILURUFORM ND<0.02 CHLOROMETHANE ND<.03 " P.O. Box 4204 9 1003 Twilight Trail • Frankfort, Ky 40604 • (502) 223-0251 Work • (502) 223-0454 Mobile 06148 PARAMETER AMOUNT UNITS 2-CHLOROTOLUENE ND<0.01 ug/I, 4-CHLOROTOLUENE ND<0.01 DIBR.OIIOCHLOROMETHANE W0.03 1.2-DIBROMO-3-CHLOROPROPANE ND: 3.0 " 1,2-DIBROMOETHANE ND<Q.8 DIBROMOMETHANE ND< 2.2 1,2-DICHLOROBENZENE ND<0.02 " 1,3-DICHLOROBENZENE ND<0.02 " 1,4-DICHLOR.OBENZENE ND<0.007 " DICHLORODIFLUOROMETHANE ND<.05 1,1--DICHLOROETHANE ND<0.07 " 1,2-DICHLOROETHANE ND<0:03 1,1-DICHLOROETHENE ND<0.07 cis-1,2-DICHLOROETHENE ND<0.02 " trans-1,2-DICHLOROETHENE ND<0.05 1,2--DICHLOROPROPANE HD<0.006 " 1,3-DICHLOROPR.OPANE ND<0.03 " 2,2-DICHLOROPROPANE ND<0.05 .1,1-DICHLOROPROPENE ND<0.02 " ETHYLBENZENE ND<0.005 HEXACHLOROBUTADIENE ND<0.02 ISOPROPYLBENZENE ND<0.05 " p-.ISOPROPYLTOLUENE ND<0.01 " METHYLENE CHLORIDE ND<0.02 " NAPHTHALENE ND<0.06 ttE31 4R PARAMETER AMOUNT UNITS n-PROPYLBENZENE MD<0.004 ug/L, STYRENE ND<0.01 " 1,1,1,2-'TETRACHLOROETHAHE ND<0.005 1,1,2,2-TETRACHLOROETHANE ND<0.01 TETRACHLOROETHENE ND<0.04 TOLUENE ND<0.01 " 1,2,3-TRICHLOROBENZENE ND<0.03 1,2,4-TRICHLOROBENZENE ND<0.'03 " 1,1,1-TR.ICHLOROETHANE ND<0.03 1,1,2-TRICHLOROETHA14E ND<0.03 TRICHLOROETHENE ND<0.01 TRICHLOROFLUOROMETHANE ND <0 . 03 " 1. , 2 , 3-TRIC'HLOROPROPANE ND<0 . 4 1 , 2 , 4-'rP iME'FHYLBENZENE ND<0 . 05 " 1,3,5-TRIMETHYLBENZENE ND,0.004 VINYL CHLORIDE ND<.02 o-XYLENE ND<0.02 " rn-XYLENE ND<0.01 p-XYLEt•IE ND <0 . 01 AREVIENILD BY M!,.R,-" HILL. 1I-1wN F.Cl. UA�L: 11:1;., MARS HILL, I'll- Attn: UAl"CYL LIUUNE F I of i MIT- Ll- LlL L RY I Flo. L) A'i E I RI L ':-:;AlII'LLR L -fl U 2 38'.7 .1 15 , 92 10 E.14 U E Ci H U E' CLIENT z-:,'iA'11UN IV: LAP, # Hi.LAb std units A11111JI41A UlUROUEN mg/1 fu(AL mail 4 GAILOR DE mg/1 U i I 1A 1* E /111 i F.JTE mail 'rljrAL Plilj!6PiWRUb coca/1 4. 1,) TOTAL NITROUEN ULFAlE mg/ 9i. D I:ALIMIUM. 11JUAL ")4 (I-AULlUll. TUrAL Mail Z!A. 4o CHRUMIUM, TUrAL 1-1). 147 COFFER, r0l'AL mg/1 LEAD. '1'0'1'AL mg/1 ld 41:) tIAGNESIUM. TOTAL my/1 Nl'--KEL. TOTAL mg/1 id. I b2 souium, 'ro'rAL mg/l 45. Q) 0 'Znu, TOTAL mQ/l 4 PUTAS'SIUM ma/l '35.5 LABLIUAlUlt'Y DINECH-1k P.O. BOX 18029 / ASHEVILLE, N( 28814 / 122 LYMAN STREET / ASHEVILI F, fl(. 28901 / (704) 254.5169 1/ FAX: (704) 251-7711 i 1011. r RFF: 1 -S(10-23 1-8p)F)'? REFURf OF ANALY'Ji:3 MARS HILL, IOWN IJF' P.O. BOX 368 MARS HILL, NG 2+3 �j4•- Attn: DARYL HIJO14E 1+'JJE'_ i' NAME: HAh"-HiILL i+_i 1 (Pane 1 of 1) SAMPLE DELIVERY TO LAB LAB No. DATE TINE SAMFLEK I?A-1E TIME CLIENT STATION ID: MARSHILL SLUbUE LAN # : 9399 ARSENIC. TOTAL mQ/1 <v_l, 003 BARIUM, TOTAL mQ/1 @. 401 CADMIUM. 'TOTAL mq/1 <+c1.00,31 LEAD. TU 17AL mq/ i 005 MERGURY. TOTAL mq/1 <0. @!?+1 SELENIUM, TUTAL mq/1 <0.004 SILVER. TOTAL mq/1 PAV; LABORATORY DINEC] Lik 122 Lyman Street • P.O. Box 18029 • Asheville. North Carolina 28814-0029 9 704/254-5169 MAH - HILL, !OWN OF M ARs HILL. N, _ n ' A SAMF I t. LAb N.. .•0b i ME _•AN! LW. tip}`- w- io%4_ 1414 l..`.;•il4(i)•. •I'.!JL(:.i'. ,. ioLhy! - CLIENT _'IA11UH Q: PtWH?LL .'.L'I•'_}_ LAb 9: _. FH. LAB Std units AMMUNIA N11I OUL.N Ma/1 !. L TUfAL bULIPS MUM GHLURIUL ma; 1 :wRATE/NITRIM. rra!I �•'_=• YLVAIL ^w1 ..AL'UUM. IWIAL ❑q%1 uHHUMLUM. IWAL nail 1,I1Fi'L'R. I U LA.L ^!ai 1 LKAU, iutAL, -00 MAUNMUN. I U AL Tq! - - N ICKE•L, TU I AL Ma/1 %�. 1 :i�.:• SUD101. TurAL mail ='< LIM. M AL -a/1 _. • . vurA:_S1UM i1I:JiL F 4. - LAIUMAlMi MR; 10 122 Lyman Street • P.O. Box 18029 • Asheville. North Carolina 28814-0029 • 704/254-5169 REPURF OF ANALt5E5 MARS HILL. TOWN OF' N. U. BUX J68 MARS HILL, NC 28754- Attn: DARYL BOONE (Peae 1 of 1) SAMPLE LAB No. DATE TIME SAMPLER 3395 02/14/92 HAROLD AND ROGER CLIENT STATION ID: LAB *: DATE: 04/03/92 SLUDGE 3395 DELIVERY TO LAB DATE TIME 02/14/92 1640 PH, LAB std units 6.1 AMMONIA N1'rROUEN mq/1 2.2 FUrAL SOLIDS mq/1 0.7:3`/. WHLURIUE mq/1 282.5 NITRATE /N1 FRITE: mq/1 1.89 FUI'AL PHOSPHORUS mq/I 96.80 TOTAL NII'RUUEN ma/l 54b.2 SULFATE: mq/1 lb. 4 CADMIUM, TUTAL mq/1 0.028 GALLIUM, TOTAL mq/1 5.90 CHROMIUM, TOTAL mq/1 0.135 COPPER, TOTAL mg/l 13.720 LEAD, TUTAL mq/1 0.642 MAGNESIUM, TOTAL mq/1 -73:-2.T NICKEL, TOTAL mg/l 0.216 SODIUM, TOTAL mg/l 323.0 ZINC, TOTAL mg/l 6.18 ++ Potassium analysis not performed. Resample submitted, data rill be submitted under separate co••� LABORATORY DI 122 Lyman Street 9 P.O. Box 18029 + Asheville. North Carolina 28814-0029 9 704/254-5169 COMPANY NAME: Hydrologic, Inc. CQIREF PRQ7ECT NUMBER: PR921889 .0 NREF SAMPLE NUMBER: 8535 SAMPLE IDENTIFICATION: Marshill soil DATE SAMPLED: 10/15/92 ANALYSIS METHOD UNITS SDL RESULT Magnesium 6010 mg/kg 0.2 1240 Potassium 6010 mg/kg 20 779 Lead 7421 mg/kg .1.0 9 Zinc 6010 mg/kg 0.3 19.1 Manganese- 6010 mg/kg 0.6 288 Sodium 6010 mg/kg 5 268 Nickel 6010 mg/kg 2 9 Cadmium 6010 mg/kg 0.3 BDL Copper 6010 mg/kg 0.6 BDL Calcium 6010 mg/kg 36 880 pH 9045 pH --- 7.29 Total phosphorus Mod. 365.1 mg/kg 10 595 C.E.C. --- meq/100g --- 11.0 Base Saturation --- % 1 85.5 Excharxteable Cations Magnesium meq/100g 2.3 Sodium, meq/100g 0.1 Potassium meq/100g 0.6 Calcium meq/100g 6.4 BDL = Below Sample Detection Limit SDL = Sample Detection Limit COMMENTS: : C VLafLabs 7�> ��y j?��:C •� •jail ��. ���' R� August 7, 1992 Hydrologic, Inc. 122 Lyman Street Asheville, NC 28814 a LABORATORY RESULTS CONTROL #: 8761 SAMPLE ID: MARS HILL RECEIVED : 07/31/92 MATRIX : EXTRACT ANALYZED : 08/05/92 METHOD : TCLP 8240 ANALYZED : 08/04/92 METHOD : TCLP 8270 ANALYZED : 08/04/92 METHOD : TCLP 8080 ' ANALYZED : 08/06/92 METHOD : TCLP 8150 SAMPLED : 07/17/92 PARAMETER AMOUNT UNITS BENZENE ND<0.005 mg/L CARBON TETRACHLORIDE ND<0.005 CHLOROBENZENE ND<0.005 " CHLOROFORM 10.0 " o-CRESOL ND<0.05 " m-CRESOL ND<0.05 " P-CRESOL ND<0.05 " 1,4-DICHLOROBENZENE ND<0.005 " 1,2-DICHLOROETHANE ND<0.005 " 1,1-DICHLOROETHYLENE ND<0.005 " 2,4-DINITROTOLUENE ND<0.05 " HEXACHLOROBENZENE ND<6.05 " HEXACHLORO-I,3-BUTADIENE ND<0.05 P.O. Box 4204 • 1003 Twilight Trail • Frankfort, Ky 40604 • (502) 223-0251 Work • (502) 227-9451 Fax 1 #8761 PARAMETER HEXACHLOROETHANE METHYL ETHYL KETONE NITROBENZENE PENTACHLOROPHENOL PYRIDINE TETRACHLOROETHYLENE TRICHLOROETHYLENE 2,4,5-TRICHLOROPHENOL 2,4,6-TRICHLOROPHENOL VINYL CHLORIDE CHLORDANE ENDRIN HEPTACHLOR LINDANE METHOXYCHLOR TOXAPHENE 2,4-D 2,4,5-TP AMOUNT UNITS ND<0.05 mg/L ND<0.10 " ND<0.05 if M1 ND<0.05 of ND<0.10 To ND<0.005 of ND<0.005 of ND<0.05 of ND<0.05 it ND<0.005 of ND<0.005 " ND<0.005 " ND<0.005 " ND<0.005 " ND<0.005 ND<0.01 " ND<0.05 " ND<0.01 " PAGE: 01 of 02 LABORATORY REPORT (Element Analysis Results) Client: Hydrologic, Inc. Project Code: Post Office Box 18029 Asheville, North Carolina 28814-0029 Date Received: Attn: Mr. Mike Edwards Project: Monitering Well / Sludge Date Analyzed: 911028 October 28, 1991 November 22, 1991 SAMPLE ID # MATRIX ELEMENT ANALYZED ANALYTICAL METHOD RESULTS Monitering Well TCLP Pb EPA 3020 / 7420 < 0.1 mg/L Monitering Well TCLP Cu EPA 3020 / 220.1 0.874 mg/L Monitering Well TCLP Cd EPA 3020 / 215.2 0.020 mg/L Monitering Well TCLP Mg EPA 3020 / 242.1 6.25 mg/L Monitering Well TCLP K EPA 3020 / 258.1 20.07 mg/L Monitering Well TCLP Zn EPA 3020 / 289.1 3.319 mg/L Monitering Well TCLP Ni EPA 3020 / 249.1 0.092 mg/L Monitering Well TCLP Cr EPA 3020 / 218.1 0.013 mg/L Monitering Well TCLP pH EPA 3020 / 9045 6.23 Monitering Well TCLP Chlorine EPA 3020 / 325.3 3900 mg/kg Monitering Well TCLP Total Phosphorus EPA 3020 / 365.3 13.800 mg/kg Monitering Well TCLP Sulfate EPA 3020 / 375.3 8900 mg/kg LABORATORY: HYDROLOGIC,. INC.. ADDRESS: .2500 GATEWAY CENTRE/STE 900,. MORRISVILLE, NC., 27560 Q21'--Z,._A Nov. 26, 1991 DATE: Parker Shieh ANALYST 021z"-n DATE: Nov. 26, 1991 PARKER G. SHIEH LABORATORY SUPERVISOR 2500 Gateway Centre Boulevard • Suite 900 • Morrisville, N.C. 27560 • 1-800/522-9952 LABORATORY REPORT (Element Analysis Results) PAGE: 02 of 02 Client: Hydrologic, Inc. I'r Post Office Box 18029 Asheville, North Carolina 28814-0029 Attn: Mr. Mike Edwards Project: Monitering Well / Sludge oject Code: 911028 Date Received: October 28, 1991 Date Analyzed: November 22, 1991 SAMPLE ID # MATRIX ELEMENT ANALYZED ANALYTICAL METHOD RESULTS Monitering Well TCLP Total Solid EPA 3020 1% Monitering Well TCLP Ammonia Nitrogen EPA 3020 / 350.3 1250 mg/kg Monitering Well TCLP Total Nitrogen EPA 3020 / 351.3 52.100 mg/kg Monitering Well TCLP Nitrate EPA 3020 / 352.1 420 mg/kg Monitering Well TCLP Nitrite EPA 3020 / 354.1 3710 mg/kg LABORATORY: HYDROLOGIC, INC. ADDRESS: 2500 GATEWAY CENTRE/STE 900, MORRISVILLE, NC 27560 —6 q� ,, DATE: Nov. 26, 1991 Parker Shieh ANALYST DATE: Nov. 26, 1991 PARKER G. SHIEH LABORATORY SUPERVISOR 2500 Gateway Centre Boulevard • Suite 900 9 Morrisville, N.C. 27560 9 1-800/522-9952 GROUNDWATER SECTION DIVISION OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER QUALITY MONITORING: a_o. Box 29535 For additional forms RALEIGH, NC 27626-0535 COMPUANCE REPORT FORM pkxm W^p Or Ca'!: (s,$) 733322, Please use Irk pert and press firTnly. PERMIT NUMBER: (REQUIRED) Facility Name ''f'' t°drs Ht 11 Non -Discharge Address ' . 30X 368 l NPDES rs Hill, NC 20754 i 'gin TYPE OF DISPOSAL OPERATION BEING MONITORED Well Location -, . tori (7orner of Fliold,r I County (REQUIRED) Lagoon Sept ic TanWDrain Field Well Identification Number 11 Well Depth " Ft. Spray Field Subsurface Low -Pressure Well Diameter ` Sample (Sasened) Interval 1138 Ft To ~' Ft. Piping (LPP) Depth to Water Level 73 ft below measuring point (before sampling) Land Application of Sludge Measuring point is I R. above land sur" t Rotary Distributor Ocher Gallons of water pumped/bailed before sampling Field Analysis: pH 6.2 Specific Conductance uMhos Temp. �' ° C Odor Appearance " Date Sample Collected i11-15-�? Date Lab Sample Analyzed 10-15-9? Laboratory Name HydroLog i c , Inc. Certification No. 17 Pled 11-1 -92 COD mgA Nitrite (NO 2)' as N mgA Ni - Nickel mg/I Col'iform: MF Fecal A 00ml Nitrate (NO 3) as N ' ' '` mgA Pb - Lead mg/I Coliform: MF Total /100ml Phosphorus: Total as P mgA Zn - Zinc mg/I (Note: Use MPN awlhod for h%ft turbid wimples) AI - Aluminum mgA Pesticides/Herbicides Dissolved Solids: Total �� r, mg/I Ba - Barium mgA (Specify Compounds) pH (when analyzed) units Ca - Calcium mgA ug/1 " TOC mgA Cd - Cadmium mgA ug/I Chloride mgA Chromium: Total mgA ug/I Arsenic mgA Cu - Copper mgA Other (Specify Compounds and Grease and Oils mgA Fe - Iron mg/I C�oncentralion units) Hardness: Total mgA Hg - Mercury mg/I ", Phenol mgAK - Potassium mgA - Sulfate mgA Mg - Magnesium mg/I Specific Conductance uMhos Mn - Manganese mg/I Total Ammonia- mgA Na - Sodium mgA TKN as N mgA I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE. . jr . Signature of 'Permittee (or Authorized GW-59 REV. 9/92 Agent`) Date Note: Values should reflect dissolved and colloidal concentrations. (see #2 on back) ' See back for instructions. •' Submit blue, green, and yellow copies orgy to address above. DIVISION OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER SECTION GROUNDWATER QUALITY .MONITORING P.O. Box 29535 .. RALOW, NC 27626-0535 COMPLIANCE `REPORT FORM : ,Foradditional forms .. write ; or call: (919) 733,3221 PERMIT NUMBER: (REQUIRED) Facility Name r q '.f flll Non -Discharge a'`'TV' Address I`{'x °F� NPDES ark 4' f l I MC 2Pf164 County { + TYPE OF DISPOSAL OPERATION BEING MONITORED (REQUIRED) Well Location rU)t-t am m +•gof Field h Lagoon Septic TanWDrain Field Well Identification Number 11111 Well Depth I rr Ft. Well Diameter a" Sample (Screened) Interval t' , Ft. To t �'t' Ft. Spray Field Subsurface Low Pressure Piping (LPP) Depth to Water Level T ft. below measuring point (before sampling) x Land Application of Sludge Other Measuring point is ? ft. above land surface Rotary Distributor Gallons of water pumpedbailed before sampling 14 Field Analysis: pH 6.0 Specific Conductance uMhos Temp. °C Odor Appearance Date Sample Collected 7 Date Lab Sample Analyzed Laboratory Name ",irt C. IrY Certification No. rn Coliform: MF Fecal Coliform: MF Total f' (Note: Use MPN method for highly turbid samples) Dissolved Solids: Total •r' pH (when analyzed) ,,TOC Chloride I -d Arcpnir Grease and Oils Hardness: Total Phannl C, �If�tn Specific Conductance Total Ammonia r' ' TKN as N mg/I A 00ml /100ml mg/I _units _ mg/I _ mg/I _ mg/I _ mg/I _ mg/I _ mg/I mg/I uMhos mg/I mg/I Nitrite (NO 2) as N Nitrate (NO 3) as N Phosphorus: Total as P Al - Aluminum Ba - Barium Ca - Calcium Cd - Cadmium Chromium: Total Cu - Copper Fe - Iron Hg - Mercury K - Potassium Mg - Magnesium Mn - Manganese Na - Sodium I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE. Signature of Permittee or Authorized Agent*) GW-5J REV.'1%91y mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I Ni - Nickel mg/I Pb - Lead mg/I Zn - Zinc mg/I Pesticides/Herbicides (Specify Compounds) Other (Specify Compounds and Concentration units) ug/I ug/1 u g/I Note: Values should reflect dissolved and colloidal concentrations. (see #2 on back) �7 See back for instructions. Date '" Submit blue, green, and yellow copies only to address above. North Carolina Department of Environment, Health, and Natural Resource: GROUNDWATER FIELD/LAB FORM DIVISION OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER SECTION County > 't 1 �� % �til Lab Number 8 � 7 y Quad No KK 94 A Serial No. / -3 `f � � 6 SAMPLE PRIORITY Date Received w / `% - +L Time n � - v Lat -3 5 'f -� 7 Long. 9 -U 3 3 -2 (aRec'd' by: � From: Bus -Courier ROUTINE EMERGENCY r1knl - .1 Other �; :,--c%� Report To: D� FRO, MRO, RRO, WaRO, WiRO, Date Entry By- S ''` Ck. WSRO, Kinston FO, Other Date Reported:_ Y - : ti Z Shipped by: Bus Courier Other 0,4 Nif-1: Collector(s): Date Time / D / 3Y A M Purpose: Baseline, Complaint,6�� LUST, Other FIELD ANALYSES Owner -rc wr%o cF Nt .•i R s O + it- L- pH 400 Spec. Cond. 94 at 250 C Location or site 5 a D G C f1 i°r'� < < •'t ° ^I " A. -1 'Q- `t y C Temp.10 - oC Odor Desaipfwn of samplin point `' l ci.1y _ Sampling Method I�'1 i -L 4 R «w Sample Interval y `� 4' t) Appearance Taste PI�n9 Field Analysis By: Remarks. .1-3.4 , t C. i7 r u "7 & �: • wro• I eumo �. LABORATORY ANALYSt_5 `' ' ' " '" - " - — ' — ' BOD5 310 mgA COD High 340 mgA Dos Diss. Solids 70300 mg Flouride 951 • mgA I A - Silver 1077 uQA Al - Aluminum 1105 ugA Or anochlorine Pesticides Pesticides Nitrogen Pesticides COD Low 335 mgA Hardness: Total 900 m-QA Ba - Barium 1007 uQA Coliform: MF Fecal 31616 A OPPI Hardness non -cart 902 mgA Ca - Calcium 916 m A Coliform: MF Total 31.504< I Phenols 32730 u A Cd - Cadmium 1027 u Acid Herbicides TOC 660 mgA Specific Cond. 95 uMhos/cm2 I Chromium: Total 1034 u Base/Neutral Extractable Organics Turbidity76 NTU Sulfate 945 m A Cu - Copper 1042 u Sulfide 745 m Fe - Iron 1045 ugA Acid Extractable Organics a aL - PS H - Mercury 71900 ugA vj pH 403 , 3 units S K - Potassium 937 m Purgeable Organics (VOA bottle) Alkalinity to pH 4.5 410 mgA Mg - Magnesium 927 mgA 1,2 - Dibromoethane (EDB) Alkalinity to H 8.3 415 m Mn - Manganese 1055 ugA Carbonate 445 mgA Na - Sodium 929 mgA Bicarbonate 440 m NH3 as N 610 m A Ni - Nickel 1067 uqA Arsenic: Total 1002 u Carbon dioxide 405 m NO + NO as N 630 m Se - Selenium 1147 uQA ?, Chloride 940 a m P: Total as P 665 mgA_ Zn - Zinc 1092 uQA Chromium: Hex 1032 u A Color: True 80 Pt -Co Cyanide 720 mgA Lab Comments n i E ., c t %. �O : i, • { c r, C `r- vn Gc - C o 1 ; kv • �► . G t GW-54 REV. 3/92 For Dissolved Analysis - submit filtered sample and write'DIS' in block White Copy - Groundwater Central Office Yellow Copy - Regional Office Pink Copy - Central Files Goldenrod Copy - Lab GROUNDWATER FIELD/LAB FORM North Carolina Department of Environment, Health, and Natural Resources DIVISION OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER SECTION County MA 13, S ON Lab Number 8 V Ly Quad No Serial No. -?'� %t 2 6 SAMPLE PRIORITY Date Receiv Time Lat. 3S +d 2 % Long. ?a 3 3 -2 G Rec'd b From: Bus(ODun g ROUTINE EMERGENCY M W- A y' Other Report To: RO FRO, MRO, RRO, WaRO, WiRO, Date Entry By Ck. WSRO, Kinston FO, Other Date Reported: Shipped by: Bus, Other M�NN� Collector(s): Raadodtad Date Time /4: 3S'�IM Purpose: Baseline, Complaint om lian LUST, Other FIELD ANALYSES Owner TowAa of mmx HrLL PH400 Spec. Cond. 94 at 250 C Location or site SI-U,04E AP*LrC.4TrON — LAAAy C coy FAqm Temp.10 oC Odor Description of samplingppooint WELL HEAD Appearance Taste Sampling Method 504 IL CA Sample Interval =S�a -' 6 0 Field Analysis By: Remarks- 4AiLED ou T 4 iiL, `"`� tdm� aM tsnlp. etc.) LABORATORY ANALYSES S?A-r o e WATE14 A.EvEL BODS 310 mgA Diss. Solids 70300 rrA A- Silver 1077 u A COD High 340 mgA Flouride 951 mgA Al - Aluminum 1105 ugA COD Low 335 mgA Hardness: Total 900 m A Ba - Barium 1007 u A Coliform: MF Fecal 31616 A 00ml Hardness non -cart 902 mgA Ca - Calcium 916 mgA oliform: MF Total 31504 /100mI Phenols 32730 uciA Cd - Cadmium 1027 u A vOO'TOC 680 15 mgA Specific Cond. 95 uMhos/cm2 Chromium: Total 1034 u A Turbidity 76 NTU Sulfate 945 m A Cu - Copper 1042 u Sulfide 745 mgA Fe - Iron 1045 u A H - Mercury 71900 u A pH 403 units K - Potassium 937 mgA Alkalinity to pH 4.5 410 mgA M - Magnesium 927 mgA Alkalinity to pH 8.3 415 mgA Mn - Manganese 1055 u A Carbonate 445 mgA Na - Sodium 929 m A Bicarbonate 440 mgA Dis NH3 as N 610 mgA Ni - Nickel 1067 ugA Arsenic: Total 1002 u A TKN as N 625 mqA Pb - Lead 1051 ugA Carbon dioxide 405 m A — Dig NO + NOq as N 630 6A m A Se - Selenium 1147 u A Chloride 940 mgA Dig P: Total as P 665 mgA Zn - Zinc 1092 uoA Chromium: Hex 1032 u A Color: True 80 Pt -Co Cyanide 720 mgA Lab Comments: GW-54 1( 3/92 For Dissolved Analysis - submit filtered sample and write •DIS' in Or anochlorine Pesticides Organophosphorus Pesticides Nitrogen Pesticides Acid Herbicides Base/Neutral Extractable Organics Acid Extractable Organics Purgeable Organics (VOA bottle) 1,2- Dibromoethane (EDB) r• n n I i-• �i li �:1•VIM I DIVISION OF ENVIRONMENTAL MANAGEMENT - GROUNDWATER SECTION GROUNDWATER QUALITY MONITORING: P.O. sox 29535 For additional forms RALEIW, NC 27626-0�535 COMPLIANCE REPORT. FORM :"please write or call: (919) 733-Ml Facility Name Address PERMIT NUMBER: (REQUIRED) Non -Discharge NPDES N- L,r:.: ii t 11 NC 28754 County „ i :, „ TYPE OF DISPOSAL OPERATION BEING MONITORED Well Location- Lam; L. Lui,, C(,rrter of Field ;, . (REQUIRED) Well Identification Number Well #1 Well Depth (Aj Ft. Well Diameter Sample (Screened)' Interval Ft To Ft. Depth to Wafter Level ft. below measuring point (before sampling) Measuring point is-ft. above land surface Gallons of water pumped/bailed before sampling Field Analysis: pH 6'2 Specific Conductance y uMhos Temp. C Odor Date Sample CollecW 1U-25--91 Date Lab Sample Analyzed Laboratory Name Name riydrU"is, IKILCertification No. rnn f;.:i : Itiil Coliform: MF Fecal Coliform: MF Total (Note: Use WN. method for highly turbid s M Ales) Dissolved Solids: Total 3 pH (when analyzed) TOC r`hinriria Areanirr Grease and Oils Hardness: Total phannl CIfnfa Specific Conductance Total Ammonia G . 1 TKN as N mg/l /100ml /I00ml _ mg/I _units _ mg/I _ mg/I _ mg/I _ mg/I _ mg/I _ mg/I _ mg/I uMhos mg/I mg/I Lagoon Spray Field Land Application of Sludge Septic TanWDrain Field Subsurface Low -Pressure Piping (LPP) Other Rotary Distributor Appearance ;; . , , L-. l L L`. L: Nitrite (NO 2) as N mg/I Nitrate (NO 3) as N C5. mg/I Phosphorus: Total as P mg/I AI - Aluminum mg/I Ba - Barium mg/I Ca - Calcium mg/I Cd - Cadmium mg/I Chromium: Total mg/I Cu - Copper mg/I Fe - Iron mg/I Hg - Mercury mg/I K - Potassium mg/I Mg - Magnesium mg/1 Mn - Manganese mg/1 Na - Sodium mg/I I CERTIFY THAT THIS REPORT IS TRUE AND ACCURATE. Signature 1'of Permittee (or Authorized Agent*) Date GW-59 REV. 4/91 Ni - Nickel mg/1 Pb - Lead mg/I Zn - Zinc mg/I Pesticides/Herbicides (Specify Compounds) u g/I ug/1 ug/1 Other (Specify Compounds and Concentration units) Note: Values should reflect dissolved and colloidal concentrations. (see #2 on back) ' See back for instructions. " Submit blue, green, and yellow copies only to address above. ATTACHMENT E SLUDGE RECEIVER SITE TOWN OF MARS HILL AGREEMENT FOR THE LAND APPLICATION OF WASTE SLUDGE ON PRIVATE LAND NAME OF WWTP: Town of Mars Hill OWNER OF WWTP: Town of Mars Hill LOCATION OF WWTP: NC 213 TYPE OF SLUDGE: Municipal Wastewater FARM NO. One FIELD NO. 1 LOCATION OF LAND:SR 1560 OWNER OF PROPERTY:Mr. Larry Cody LAND USE OR CROPPING PATTERNS: Pasture Land for livestock INTENDED USE OR DISPOSITION OF CROPS: Livestock grazing The undersigned land owner or his representative hereby permits the Town of Mars Hill hereinafter referred to as the Permittee, to apply sludge from the Town of Mars Hill's Wastewater Treatment Plant upon the land at the location shown as in the attached documents in accordance with the restrictions, stipulations and exceptions shown below. The landowner or his representative receives, in consideration, full use of the nutrient value of the applied sludge while the Permittee receives, in consideration, the use of the land described above for the disposal of digested wastewater sludge. This agreement remains in effect for an initial period of Five (5) years. Following the initial Five (5) year period, this agreement shall remain in effect from one year to the next year until cancelled as stipulated below. The undersigned land owner or his representative and the Permittee agree to abide with the following restrictions and stipulations until such time as written notification, given one hundred twenty (120) days in advance, modifies or cancels this agreement. Page 1 RESTRICTIONS: 1. No sludge shall be applied during periods when the ground is frozen or excessively wet. 2. Should cumulative applications of metals exceed those limitations allowed by the Division of Environmental Management, the landowner may be required to have the following statement recorded as a part of the property deed: "Portions of this property have received solid waste at high metals application rates and care should be taken if food chain crops are grown due to a possible health hazard." 3. Where sludge is applied to land which requires cultivation, (i.e. corn) the landowner shall be responsible for plowing the land within one week of completion of sludge application. STIPULATIONS: 1. The landowner or his representative hereby authorizes the Permittee, County and State officials or their representatives to inspect each parcel of property prior to, during, and after sludge application and to establish monitoring • facilities on or near the applicatlon site as required by the sludge disposal permit. 2. The landowner or his representative authorizes the Permittee, County and State officials or their representatives to take necessary soil, surface and ground water samples during the term of, and eighteen (18) months after termination of, this Agreement. 3. The Permittee will provide each landowner or his representative with a copy of the land application permit as issued by the N. C. Department of Environment, Health and Natural Resources (NCDEH&NR) Division of Environmental Management (DEM) for the land described above prior to commencement of sludge application. The NCDEH&NR-DEM permit will delineate maximum application rates, limitations and other restrictions prescribed by the laws and regulations. 4. The Permittee has provided the landowner or his representative with information and data concerning the program for land application of sludge to privately owned lands which includes an analysis of constituents of the sludge, sludge application methods and schedules for typical cropping patterns and a description of the equipment used by the Permittee for sludge applications. 5. The Permittee will furnish each landowner or his representative with a copy of laboratory analysis stating constituents of the sludge prior to the commencement of each sludge application. Page 2 6. The Permittee will furnish each landowner or his representative with a copy of the results of each soil analysis. 7. The Permittee will be responsible for properly liming the land to a pH of 6.5 before each application of sludge. The pH of the land before and after the application of lime will be determined in accordance with Stipulation 2 above. 8. The landowner or his representative will inform the Permittee of any revisions or modifications to the intended use and cropping patterns shown above at least twelve (12) months prior to each planting season to enable to Permittee to amend this Agreement and schedule applications at appropriate periods. Within the limits of the NCDEH&NR permit, the owner or his representative and the Permittee will determine sludge application rates and schedules based on crop patterns and the results of soil samples. 9. No crops for direct human consumption shall be raised on the land for a period of 18 months following the land application of wastewater sludge. 10. The landowner or his representatives or successors shall adhere to the provisions of this Agreement for a period of twelve (12) months from the date of the most recent sludge application. 11. The Permittee will exercise all reasonable care and precaution in the execution of this Agreement. The Permittee will not be held liable for any damage to the property or persons in the execution of this Agreement not due directly to negligence on behalf of the Permittee. 12. Should the landowner or his representative lease or otherwise permit the use of the land by a third party, the landowner shall be responsible to insure the third party agrees and complies with the terms and conditions of this Agreement. 13. The existing lessee, if any, of the site agrees, by execution of this Agreement, to comply with all provisions of this Agreement. 14. In consideration of the signing of this Agreement, the parties thereto for themselves, their agents, officials, employees and servants agree not to discriminate in any manner on the basis of race, color, creed or national origin with reference to the subjectmatter of this Agreement, no matter how remote. 15. This Agreement shall be binding on the &rantees, the successors and assigns of the parties hereto with reference to the subject matter of this Agreement. 16. The land application disposal sites shall not be grazed within thirty (30) days after the last sludge application by any animals whose products (including their meat) is consumed by humans. The landowner shall provide adeaquate fencing to prevent access of livestock to the site after each application. Page 3 17. In any future transfer of the land where sludge has been applied, a notice shall be given to the new land owner that gives full details as to the sludge constituents, volume, etc. that was applied or incorporated at this site. 18. The landowner will be notified approximately one (1) month prior to the scheduled date of application. EXCEPTIONS: Page 4 STATE OF NORTH CAROLINA) COUNTY OF MADISON ) /J I, the undersigned Notary Public, do hereby certify tha / 4 ��C , personally this day and acknowledged the due execution of the forgoing instrument. WIT MESS my hand and notarial seal this da N( TARY PUBLIC My Commission Expires: ATTEST: i STATE OF NORTH CAROLINA) COUNTY OF MADISON BY: o-s.t . PERMI E (Town of Mars Hill) DATE: V —; 7-90 I, the undersigned Notary Public, do hereby certify that " personally appeared before me this.day and acknowledged the due executiopf of the forgoing instrument. WITNESS my hand and notarial seal this y o 17 9—. e,� N&)TARY PUBLIC My Commission Expires: C �' GD Page 5