WQ0004298_Residuals Annual Report 2016_20170719

Town of Mars Hill NC
2016 Land Application Report
WQ0004298
Attached are the required forms for the Town of Mars Hills 2016 land application
program.
The town has land applied 18.821 dry tons of sludge over 14.5 acres in the calendar year
2016. We have also maintained compliance with all terms and conditions.
Contact Information:
Preparer/ORC
Robert Sams
Land Application ORC
Town of Mars Hill
PO Box 368
Mars Hill NC 28754
Phone # [phone]
Permittee
Darhyl Boone
Town Manager
Town of Mars Hill
PO Box 368
Mars Hill NC 28754
Phone # [phone]
RECEIVED
Division of Water Resources
JUL 19 2017
Water Quality Regional Operations
Asheville Regional Office

ANNUAL LAND APPLICATION CERTIFICATION FORM
VVQc1'.1'ermit#: WQ0004298 County: Madison Year: 2016
Facility Name (as shown on permit): Town of Mars Hill
Land Application Operator: Robert M Sams Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
2 Yes ® No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Reeidnala Annlicatinn Summnrv:
Total number of application fields in the permit-F
2
Total number of fields utilized for land application during the year:
1
Total amount of dry tons applied during the year for all application sites:
18.821
Total number of acres utilizes for land application during the year:
14.5
Part B - Annual Comuiance Statement:
Facility was compliant during calendar year 2016 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Resources. 10 Yes ® No
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies
of laboratory results are attached.
4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant
Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503
regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior,
authorization was received from the Division of Water Resources.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as
specified in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information, including the
uossibility of fines and imprisonment for knowing violations."
Darhyl Boone- Town Manager
Permit Name jand Title (type or Pont)
6*Q- Z/
/t
Signature of0ermittee Date
Signature of Prepaier* • " / DaX Signature of Land Applier mate
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in
WQ Permit Number: WQ0004298 Laboratory: 1) Earth Envi
Facility Name: Town of Mars Hill 2) Environemtal T
Residual Source WQ # or NCO057151 3) A&L La1
NPDES #: 4)
WWTP Name: Town of Mars Hill WWTP 5)
Do....71 Arnlveia no+a
RSSF - B
Solutions
1\VAl\i 4f11 �ailaal .Jl.l YN4N
Parameter
(mg/kg)
Ceiling
Conc.
Limit
Sample or Composite Date
6101116
Percent Solids (%)
NA
20.7
Arsenic
.75
11.9
Cadmium
85
4.76
Copper
4,300
228
Chromium
NA
25.5
Lead
840
20.6
Mercury
57
1.2
Molybdenum
75
11.9
,
Nickel
420
17
Selenium
100
7.83
Zinc
7,500
514
Total Phosphorus
NA
16700
TKN
NA
43400
d' ,
Ammonia -Nitrogen
NA
1 11000
,/
Nitrate and Nitrite
NA
2961.33
W
8 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalti r submitting false infor ation, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer 7 bate
u,--*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FOR RSSF (12/2006)

Feb 1317 08:22a EARTH ENVIRONMENTAL SERVI
Earth Eoviroomeold Services
Michael Ladd
75 Bison Lane
Murphy, NC 28906
Robbinsville lab [phone]
Weavervlle Lab (828) 64"196
Residence [phone]
828-835-8631 p.1
Name and Address of Faclity.
Date: 1/16I2017
Town of Mars'Hill VAVTP
Sample Collector. JR
P.O. BOX 368
Date and Time Sample Received: 61V2016 11:00 AM
Mars Hill, NC 28754
Date and Time Sample Colledeck 611f2016 ?
Aft: Robert Sams
Date and Time Sample Analyzed: < MHT
Land Application Analyses - Note: All results in mg/Kg Dry Basis Unless otherwise noted.
Test
Bell Press Sludge
Soil Site 01
Scfl Site02
ReportLimit
Method
Units
ACIDITY
O.Omeg1100g
0.0meg1D0g
SCA
meglloog
TOTAL SUSPENDED RESIDUE
lau
SM2640D
mg/L
CATION'EXCHANGECAPACITY
15.8meq/t00g
13.7megi1cog .
SCA
meg1100g
PH
5.2
6.9
7.2
0-14
SCA
units
AMMONIA NITROGEN
11000
0.5
SCA
mg/L
NO2+.NO3-n----.....,_..... u................__.._......,..
;' 2961:33;:.....
:..,._.._....,.._,.....
.........,...
-....... 1:0....
......:.._,..SCA
OM K IELOAHL NITROGEN
43400
SCA
m9rL
TOTAL PHOSPHOROUS
16700
1280
1230
SCA
mg/L
PERCENT TOTAL RESIDUE
20.7%
82.570
828%
SCA
mg/L
% ORGANIC MATTER
5.7%
6.7%
SCA
NTU
% BASE SATURATION - K
13.5%
3.6%
SCA
mg1L
- H
0.096
0.0%
-Mg
25:8%,
25.5%
-Ca
60.8%
70.9%
- Na
0.7%
0.7%
PLANT AVAILABLE (surface)
47-84266
PPMIdw,
NITROGEN- PPM DRY WT (subsurf)
63.84266
PPMIdw
SAR
1-376289
ESP
9.9068350/a
17.26505%
MANGANESE
195
241
SCA
mg/L
MAGNESIUM
2460
4170
2200D
SCA
mgJL
SODIUM
499
36.0
544
SCA
mgJL
CADMIUM
< 4.76
1.20
3.31
SCA
mgJL
CHROMIUM
25.5
44.6
424
SCA
mWL
COPPER
228
36.8
57.9
SCA
mgJL
LEAD
20.6
13.4
11.2
SCA
mg/L
NICKEL
17.0
15.6
12.9
SCA
mgJL
ZINC
614
71.9
565
SCA
mgJL
CALCIUM
6440
6860
50900
SCA
m
POTASSIUM
3450
1610
1210
SCA
mg/L
ALUMINUM
7350
NIA
NIA
SCA
mgJL
ARSENIC
<11.9
<3.01
<2.97
SCA
mgll-
SELENIUM
7.83
a 3.01
< 1.19
SCA
mgJL
MOLYBDENUM
a11.9
<3.01
<2.97
SCA
91 L
IIIERCURY
1.2
0.085
0.14
SCA
mgJL
4.C. Laboratory )DO 352 Analyzed By: -% SCA
.ab Supervisor. Michael J. Ladd; EES-Robbinsvlle Certified 8y: %

Mars Hill Land Application Belt Press Sludge 6/1/16
PAN
Mineralization
as decimal
Total dry jAcres
tonslyear
Applied on
Rate
0.4
TKN
434d0
NH3
11000
NO3
2960
NO2
1.33
% Solids
0.207
PAN Surface
21421.331mglkg t 42.84266 IbsIdrVton
0 1 Ibs total PAN
#DIV/01 Ilbs PAN/acre
PAN In ection
26921.331 mgtkg 53.84266 Ibsld ton
0 lbs total PAN
#DIV/O1 I Ibs PAN/acre
Dry Tons/1000 gal.
0.86319
1st year PAN
Surface Ibs.
0
1 st year PAN
In'ected lbs.
01
lbs./acre
Surface.
#DIV/01
Ibs./acre
Injected
#DIVI01
MR(TKN-NH3)+ + .5(NH3)+NO3+NO2 =mg/kg
mg/kg x .002 =Ibs/dryton
MR(TKN-NH3) + 1(NH3)+NO3+NO2 =rn9ft
mg/kg x .002 =lbs/dry ton
1000 X 8.34 X %osolids X sp. gravity
2000
"=dry tons/1000gal."
CD
C7
W
y v
O
N
N
m
D
10
m
z
0
z
m
z
D
r
CO
m
00
N
O
W
(SD
C'
W

SAR &T&P Mars Hill Land Application Belt Press Sludge 7/21/15
Sodium Absorption Ratio
Na M il-
Ca M /L
M /L
Na: Sodium (Mg/L) Equivalent weight: 23
499
6440
2100
Ca: Calcium (Mg/L) Equivalent weight: 20
Mg: Magnesium (Mg/L) Equivalent weight: 12
Na MC
Ca E
21.69565
M ME
175
-322
Milli Equivalent = Mg/L / Equivalent weight
SAR= Na Milli Equivalent%[0.5 X (Ca Milli Equivalent + Mg Milli equivalent)]0,5 power
Mg/L entered above)
ME entered below)
Na ME
21--a
Ca ME
Ma (ME)
1322
205
-n
(D
Cr
W
v
O
IV
N
N
m
D
The amount of exchangeable sodium ions
z
amount of exchangeable calcium & magne
<
material.
Permitting guidance is If greater than 10 re
z
m
z
D
r
U)
m
<
w
N
W
OD
W
Ul
W
-P
W

i
IRR & ESP Mars Hill Land Application Soil Site Al 6/1/16
Exchangeable Sodium Percentage I
ESP = Na (Milli Equivalents) / CEC X 100 The percentage of sodium ions occupying the cation exchange complex of soils
Na (ME CEC I
1.56528 15.8
ESP 19.906835 % Should be less than 15% (15-20%)
. I
Na on NC soil test is expressed as meq.
i
i
I
f
I
I
I
CD
W
V
P
N
N
m
a
10
m
z
0
z
m
z
D
r
r�
m
CO
N
CO
W
CA
do
W
P
-?

SAR & ESP Mars Hill Land Application Soil Site #2 6/1/16
Exchangeable Sodium Percentage
ESP = Na (Milli Equivalents) / CEC X 100
ESP = 17.26505 %
Na on NC soil test is expressed as meq.
The percentage of sodium ions occupying th6 cation exchange complex of soils
Na ME GEC
2.36531200000 13.7
Should be less than 15% (15-20%)
E
00
N
W
W
cn
60
CD
W

ANNUAL METALS FIELD LOADING SUAEMIARY FORM*
r Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Town of Mars Hill Land Application Total Dry Tons Applied (Annual):
Permit #: WQ0004298 Cation Exchange Capacity (non 503 only):
Operator: Robert Sams Owner: Matthew Cody Predominant Soil Series:
Acres Used: 14.5 Acres Permitted: 14.5 Site #: 1 Field #:
18.82
15.8
Residual Analysis Data (heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
6/l/16
2
6/1/16
3
4
5
6
7
8
9
10
11
12
% Solids
20.7
20.7
Arsenic
11.9
11.9 V,
Cadmium
4.76
4.76 J
,.
Copper
228
228
Chromium
25.5
25.5 d
,
Lead
20.6
20.6 ✓
Mercury
1.2
1.2
Molyb-
denum
11.9
11.9
Nickel
17
17 ✓
Selenium
7.83
7.83
Zinc
514
514
Total
Phos-
horus
16700
16700
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
T--:!F
6
7
8
9
10
11
12
DT/Ac./
rt
App-
Event
0.65
0.65
Arsenic
0.015
0.015
1 0.000
0.000 1
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.031
Cadmium
0.606
0.006
0.000
0.000 1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.012
Copper
0.296
0.296
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.592
Chromium
0.033
0.033
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.666
Lead
0.027
0.027
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.053
Mercury
0.602
0.002
0.000,
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Molyb-
0.015.
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.031
denum
Nickel
0.022
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0:000
0.000
0.044
Selenium
0.010
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.020
Zinc
0.667
0.667
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.1.334
Total
Phos-
21.677
21.677
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
43.353
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisopmeelt for knowing violationg.
FA
Signature of Land Applier Date DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMA
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMI',
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APP:
Facility Name: Town of Mars Hill LA WQ Permit #: WQ0004298 _ Field #: 1
Land Owner: Matthew Cody Annual Dry Tons Appl:: M ( e 1 T Site #:
Operator: Robert Sams Predominant Soi Series
,_
Y FORM .
ED FOR EACH FIELD APPLIED ON
ABLE.
Acres Utilized: 14.5
Acres Permitted: 14.5
Cation Exchange Capacity (non 503): 15.8
Crop 1 Name: f eaQ vIQ Crop 1 Max. P : FJ _
�' C Name:
1 Crop 2 Max. PAN: �-
°
y
Volume applied
PP
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc )
Soil
Cond.
Wei'
Moist)
Precip.
Past 24
ems•
inches
a
b
a
c
�'
r 9
�_
*
oy
5
� �+
*
p'
TKN
mg/kgy
Z
a
o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
lbs/acre)
Name of CropType
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
7/16
54
20.7
0.649
Belt Press Sludge
Dry
0
s
0.5
30%
1 43400
11000
2961.33
23.608
NA
Fescue
29/16
54
20.7
0.649
Belt Press Sludge
Dry
0
s
0.5
30%
43400
11000
2961.3
23.608
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
n0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
U
0.000
0.000
0.000
/
0.000
0:000
0.000
0.000
0.000
0
0
#VALUE!
Residuals Applications totals
PP
on FORM FSF su attach
PP
FORM
FSF su to this form):
PP )
#######
#######
:.' ..
)TALs:
108
of
j
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
47.215
o.000
Lime Applied
nnual lbs/acre
rior Years Cumulative lbs/ac
0.031 r/
0.994
0.012
0.646
0.592
52.95
0.066
2.125
0.053
5.538
0.003
0.137
0.031
2.881
0.044.
2.6.73
0.020
1.685
1.334
8.907
10.241
2498
43.353
Date
lbs/ac
11/23/16
3448
urrent Cumulative lbs/ac
Irmitted C. P. L. R.****
1.025
36
0.658
34
53.542
1338
2.191
NL
5.591
267
0.140
15
2.912
NL
2.717
374
1.705
89
;rmit PAN Limit lst/2nd Crop
".
m�A
„ "
a
1 certify, under penalty of law, that this document was prepared under my direction or supervisi
ualified personnel properly gathered and evaluated the information submitted. I am aware that
iformation, iffOuding the possibility of es and imprisonment for knowing violations."
�j *Application M
**Volatilization
Signature of Land Applier
aerobically dil
****C.P.L.R.:
in accordance with a system designed to assure that
we are significant penalties for submitting false
)d: S - Surface, IN - Injection, INC - Incorporation
te: Surface - 0.5, Injection/Incorporation - 1.0
Rates: Compost -0.1, anaerobially digested -0.2,
1-0.3, raw sludge -0.4
ulative Pollutant Loading Rate
nFNR FnRM FSF f19/9nnR1

�n
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Town of Mars Hill WQ Permit #: WQ0004298 Field #: 12
Land Owner: Micheal Cody Annual Dry Tons Applie`. ' 7. Site #: 1
Operator: Robert Sams Predominant Soil Series: j
Crop 1 Name: Crop 1 Max. PAN:
Crop 2 Name:
Acres Utilized: 0
Acres Permitted: 3.8
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
Volume applied
Volume
Residual Sources
Soil
Cond.
Precip.
a
b
c
n
Z
Nitrate
PAN Applied
Name of Crop Type
..0
s i
(enter one) Solids/
oho
Applied per
(NPDES #, WQ#,
Past 24
A
TKN
o
and
(]bs/acre )
Receiving Residual
.0 o
Liquid
Solids
Acre
Fert., Animal
wry'
ems•
*
* Ev'
�•
w
Nitrite
Application
Cu. Yds Gallons
(Dry TonslAc)
Waste, etc)
Wet,
Moist)
Inches
*o
p
*
*K
0
mglkg
mglkg
mg/kg
Crop 1
Crop 2
Crop 1
Crop 2
id Not
#DIV/01
Did Not Apply
#DIV/01
#DIV/01
kpply
#DIV/01
Did Not Apply
#DIV/0!
#DIV/01
#DIV/0!
Did Not Apply
#DIV/01
#DIV/01
#DIV/0!
Did Not Apply
#DIV/0!
#DIV/0!
#DIV/0!
Did Not Apply
#DIV/01
#DIV/01
#DIV/01
Did Not Apply
#DIV/0!
#DIV/0!
#DIV/01
Did Not Apply
#DIV/0!
#DIV/0!
#DIV/0!
Did Not Apply
#DIV/0!
#DIV/0!
#DIV/01
Did Not Apply
#DIV/01
#DIV/01
#DIV/01
Did Not Apply
#DIV/01
#DIV/01
#DIV/01
Did Not Apply
#DIV/01
#DIV/0l
#DIV/0!
Did Not Apply
#DIV/01
#DIV/01
11.N,
Residuals Applications totals
on FORM FSF supp (attach
FORM
FSF supp to this form):
)TALC:
o
o
;
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
0.000
0.000 .
Lime Applied
nnual lbs/acre
m e1 y —� `v
Date
lbs/ac
11/23/16
2631
-ior Years Cumulative lbs/ac
urrent Cumulative lbs/ac
#VALUE!
#######
#######
#######
####### ####### ####### #######
####### ####### 4
ice;
,rmitted C. P. L. R.****
Xs�
;rmit PAN Limit l st/2nd Cr o
5 f��
; kz
i��, NyeME
[ certify, under penalty of law, that this document was prepared under my direction or supervisi
ualified personnel properly gathered and evaluated the information submitted. I am aware that
iformation, PiclVding the possibility of fines and imprisonment for knowing violations."
*Application M
nL/ / V / 7 **Volatilization
Signature of Land Applier
Date
*** Mmawali�a+
aerobically di
****C.P.L.R.:
in accordance with a system designed to assure that
we are significant penalties for submitting false
ld: S - Surface, IN - Injection, INC - Incorporation
te: Surface - 0.5, Injection/Incorporation -1.0
Rates: Compost -0.1, anaerobially digested -0.2,
1-0.3, raw sludge -0.4
ulative Pollutant Loading Rate

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
' Fa&:.�ilitiy Name: Town of Mars Hill WQ Permit Number: WQ0004298
WWTP Name: Town of Mars Hill WWTP a NPDES Number: NCO057151
Monitoring Period: From i' j 1 '
-'Z-� 6A6 To
Pathogen Reduction (15A NCAC 02T 1 06) - Please indicate level achieved and alternative performed:
Class A
Alt. A (time/temp) ❑ Alt B (Alk Treatment) [IAlt. C (Prior Testing) ❑�`_
X K 4i3n 'L"�xxlg+i,,° �ts'F`7
� u
.r.,...:4Y C' •#..ai3:,` l:'�:Se;6;x;:k
A1t.D (No Prior Test) ❑ Process to Further Reduce Pathogengs ❑
Y Yk x l Milr 5
_
If applicable to alternative
performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
Heat Drying ❑
Heat Treatment ❑
yy}} rri
�,.Y1� ii' .5u f
Thermopluhc ❑ �
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑�'x�_�
-22
Class B:
jAlt. (1) Fecal Density ©
1 Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class
B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
Air Drying ❑ Composting ❑ Aerobic Digestion L7
Anaerobic Digestion ❑
'€.:w�.'y �1,S:��.�'7...�i.•s.u"�,�v;§s�����,yi...s�,',�f�.5'.°F}a�.,;zt�`i3�"3`.�•.'a�..�.'�fiaz�'i%�s z,�.�".73'�'s..:;�z34ii�`_ 'r-�'r.z���r.'."� z���"��.`is �
If applicable to alternative performed (Class A or Class B) complete the following
monitoring
data:
Parameter
Allowable Level
Pathogen Density
Number o
Frequency
Sample
a ytica
in Sludge
MinimumGeo.
Mean
axon
Units
Excee-
Exc
of Analysis
Type
Tech -
niaue
2 x 10 to the
WN
2300
10600
68000
col/gram
0
1/year
grab
9222d
6th power
per gram of
Fecal Coliform
total solids
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
3 WN per 4 grams
(in lieu of fecal
total solid (dry
coliform)
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.1 (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) R1
Alt. 4 (Spec. OZ uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
Alt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
CI "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
L7 "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Robert M Sams -Land App ORC
Prep r e and Tit a or riot) Land Applier Name and Title (if applicable)(type or print)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

' Y 0
EARTH ENVIRONMENTAL SERVICES
75 Bison Lane
Murphy, NC 28906
Residence — [phone]
Robbinsville Lab — [phone]
Weaverville Lab — [phone]
Fax — [phone]
E-Mail — earthenvsgQwebworkz.com\
November 18, 2016
NC ID #352
Mr. Robert Sams
Town of Mars Hill
P.O. Box 368
Mars Hill, NC 28754
Dear Mr. Sams:
Following is a report of laboratory analyses for digester sludge samples received 10/19, 10/20, 10/21,
10/24, 10/25, 10/26, 10/27/16.
Colony Counts
Sample Date Coliform Densities (colonies/exam) % Total Solids 0.100 ml n 010 M! n nm .,,i
1
10/19/16
42,000 Colonies/Gram
0.77
TNTC
32
5
2
10/20/16
34,000 Colonies/Gram
0.76
TNTC
26
4
3
10/21/16
68,000 Colonies/Gram
0.75
TNTC
51
8
4
10/24/16
3,800 Colonies/Gram
0.74
28
2
0
5
10/25/16
2,800 Colonies/Gram
0.75
19
4
0
6
10/26/16
2,300 Colonies/Gram
0.74
18
1
0
7
10/27/16
6,500 Colonies/Gram
0.71
46
10
0
Geometric mean for all seven samples: 10,600 colonies/gram. Thank you for your
business. If you have any question or need additional sample analyses performed, please
call.
Respectfully submitted,
Michael J. Ladd
Laboratory Director

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1 2 3 4 5 6
7 8 9 10 11 12 13 14 15 16
Time (minutes)

Feb 131708:38a EARTH ENVIRONMENTAL SERVI 828-835-8631 p.3
'It
Time
(minutes)
0
1
2
4
5
6
7
8
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility
Biosolids Permit N
Digester Temperature:
Sampling Date/Time:
Sampled By:
Analysis DaterTime:
Analyzed By.
Sample Volume:
Total Solids:
Beginning T
End T
Dissolved Oxygen Level
4.
4.
3.81
1
85 % Dry Solids
1.1 degrees Celsius
14 degrees Celsius
Slope: 0.1
Intercept: 4.8
Correlation Coefficient: 1.0
Oxygen Uptake Rate: 6.64 mg Oxygenlhr
Ambient Specific Oxygen Uptake Rate: 0.78 mg Oxygenlglhr
. Average Temperature: 14 degrees Celsius
Temperature Correction Factor. 1.500730352
Temperature Corrected Specific Oxygen Uptake Rate:1 1.17 mg Oxygenlglhr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

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Time (minutes)
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Feb 1317 08:39a EARTH ENVIRONMENTAL SERVI 828-835-8631 p.5
Time
(minutes)
0
1
2
4
5
6
7
8
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name.
Biosolids Permit Number_
Date:
Digester Temperature:
Sampling DateFf ime:
. Sampled By:
Analysis DatelTime:
Analyzed By.
Sample Volume:
Total Solids:
Beginning T
End T
Dissolved Oxygen Level
4.
4.0
3.
3.
1 15-Junl
Slope:
Intercept
Correlation Coefficient
Oxygen Uptake Rate:
Ambient Specific Oxygen Uptake Rate:
Average Temperature:
Temperature Correction Factor.
1
0.1
4.2
1.0
Dry Solids
grees Celsius
arees Celsius
5.61 mg Oxygen/hr
0.59 mg Oxygenfg/hr
18 degrees Celsius
1.1449
Temperature Corrected Specific Oxygen Uptake Rate: 0.68 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

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MEMO
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Time (minutes)

Feb 131708:39a EARTH ENVIRONMENTAL SERVI 828-835-8631 p.7
Specific Oxygen Uptake Rate
SOUR
Facility N
Biosolids Permit Nur
Digester Temperature:
Sampling DatelTme. 7115/201
Sampled By: Michael La
Analysis Daterl-ime: 7/151201
Analyzed By: Michael La
Sample Volume:
Total Solids:
Beginning Temperature.
End Temperature:
Time Dissolved Oxygen Level
Slope:
Intercept:
Correlation Coefficient:
1
0.1
4.0
1.0
Dry Solids
grees Celsius
grees Celsius
Oxygen Uptake Rate: 6.59 mg Oxygen/hr
Ambient Specific Oxygen Uptake Rate: 0.74 mg Oxygen/g/hr
Average Temperature: 18 degrees Celsius
Temperature Correction Factor. 1.1449
Temperature Corrected Specific Oxygen Uptake Rate.1 0.85 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

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y = -0,1098x + 4.1628
IMM
MOM
2 3 4
7 8 9 10 11 12 13 14 15 16
Time (minutes)

Feb 131708:40a EARTH ENVIRONMENTAL SERVI 828-835-8631 p.9
�•'„ � .
Time
Specific Oxygen Uptake Rate
SOUR
Facility
Biosolids Permit N
Digester Temperature:
Sampling Date/Time: 8/23/2016 1
Sampled By: Michael Ladd
Analysis Date/Time: 8/23/2016 1
Analyzed By: Michael Ladd
Sample Volume:
Total Solids:
Beginning Temperature:
End Temperature:
Dissolved Oxygen Level
Slope. 0.1
Intercept: 3.6
Correlation Coefficient: 1.0
Dry Solids
grees Celsius
arees Celsius
Oxygen Uptake Rate: 4.72 mg Oxygen/hr
Ambient Specific Oxygen Uptake Rate: 0.50 mg Oxygen/g/hr
Average Temperature: 19 degrees Celsius
Temperature Correction Factor. 1.07
Temperature Corrected Specific Oxygen Uptake Rate: mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and.the Spreadsheet execute automatically.

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Time (minutes)
ON
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Feb 1317 08:40a
EARTH ENVIRONMENTAL SERVI
828-835-8631 p.11
Time
Specific Oxygen Uptake Rate
SOUR
Facility
Biosolids Permit N
Digester Temperatu
Sampling Datefrn
Sampled I
Analysis Date/Tin
Analyzed I
Sample Volun
Total Solii
Beginning Temperatu
End Temperatu
Dissolved Oxygen Level
(Michael Ladd 1
Ladd
1000 milliliters
0.74 % Dry Solids
18.4 degrees Celsius
18.2 1
degrees Celsius
Slope: 0.1
Intercept: 4.8
Correlation Coefficient: 1.0
Oxygen Uptake Rate: 5.69 mg Oxygenthr
Ambient Specific Oxygen Uptake Rate: 0.77 mg Oxygenfglhr
Average Temperature: 18 degrees Celsius
Temperature Correction factor: 1.1449
Temperature Corrected Specific Oxygen Uptake Rate:j mmm O.8B mg Oxygenlglhr
Instructions: Enter Data in. the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

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Time (minutes)
LL �.j

Formulas for Land Application of Residuals
Area of Square or Rectangle (ft) = length x width
Area of Circle (ft) = 3.14 x radius2 = 7r x radius2 = Tc r2
Volume of Rectangular Tank (ft) = length x width x depth
Volume of Cylindrical Tank (ft) = area x height = Tc r2 x h
Volume of Tank (gal) = volume of tank (ft) x 7.48 gal/ft3
Detention Time (unit of time) = volume (.gallons or ft)
flow (volume/unit of time)
Pounds per day (Ibs/day) = concentration (mg/L) x flow (MGD) x 8.34 lb/gal
Pounds per year (Ibs/year) = mg/L x MGY (annual effluent application) x 8.34 lb/gal
Concentration (mg/L) _
Ibs
flow (MGD) x 8.34 lb/gal
mg/L
Dry weight concentration (mg/kg) _ % solids
Wet weight concentration (mg/L) = mg/kg x % solids
Pounds per dry ton = mg/kg x .002
D tons x 2000 Ibs/ton Gallons 8.34 l s/oat x bra solid:
Gallons = Dry o Dr/ tens) = v
8.34 Ibs/gal x /o solids 20c s/ton
Flow Rate (volume/unit time) = area (ft) x velocity (feet per minute)
Hydraulic Loading Rate (gpd/ft2) = flow (qpd)
area (ft)
Hydraulic Soils Loading Rate (in/day) = flow (gpd)
27,152 gal/acre-inch x area (acres)
Plant Available Nitrogen (PAN)
For Surface Application: [MR x (TKN — NH3)] + (0.5 x NH3) + (NO3 + NO2 )
For Subsurface Application or Incorporation: [MR x (TKN — NH3)] + (NH3 ) + (NO3 + NO2 )
3/28/2013 1

Sodium Adsorption Ratio (SAR) =
Na (meq)
V 0.5 x (Ca (meq) + Mg (meq))
Exchangeable Sodium Percentage (ESP) =
Na (meq) x 100
CEC (meq)
Site Life = Allowable Cumulative Pollutant Loading
Annual Pollutant Loading
ALE = tons sludge x tons ag-lime
tons ag-lime acre
Travel speed for spreader load (gallons or tons) x 495
spreader (mph) time (min) x width (ft) x application rate (gal or tons/acre)
3/28/2013

Ea�t6 Enu1100meotal services
i Michael Ladd
75 Bison Lane
�y Murphy, NC 28906
Robbinsville Lab [phone]
Weaverville Lab [phone]
Residence [phone]
11'MV=aV L-L
division of water Resources
JUL 19 2017
�nleter Cluality Regional Operations
Ashe\'Vle Regional Office
Name and Address of Facility:
Date: 1/16/2017
Town of Mars Hill WWTP
Sample Collector. JR
P.O. BOX 368
Date and Time Sample Received: 6/1/2016 11.00 AM
Mars Hill, NC 28754
Date and Time Sample Collected: 611/2016 .?
Aft: Robert Sams
Date and Time Sample Analyzed: < MHT
Land Aooliration Analvses - Note: All results in mall(a Dry Basis unless othenvise noted.
Test
Belt Press Sludge
Soil Site #1
Soil Site #2
Report Limit
Method
Units
ACIDITY
0.0 meq/100g
0.0 meq/100g
SCA
meq/100g
TOTAL SUSPENDED RESIDUE
.0
SM2540D
mg/L
CATION EXCHANGE CAPACITY
15.8 meq/100g
13.7 meq/100g
SCA
meq/100g
PH
5.2
6.9
7.2
0-14
SCA
un"rts .
AMMONIA NITROGEN
?1000�
0.5
SCA
mg/L
NO2 + NO3-n
2961.33
1.0
SCA
mg/L
TOTAL KJELDAHL NITROGEN
43400
SCA
mg/L
TOTAL PHOSPHOROUS
16700
1280
1230
SCA
mg/L
PERCENT TOTAL RESIDUE
20.7%
82.5%
82.8%
SCA
mg/L
• ORGANIC MATTER
5.7%
63%
SCA
NTU
% BASE SATURATION - K
13.5%
3.6%
SCA
mg/L
- H
0.0%
0.0%
-Mg
25.8%
25.5%
-Ca
60.8%
70.9%
-Na
0.7%
0.7%
PLANT AVAILABLE (surface)
42.84266
PPM/dw
NITROGEN- PPM DRY WT (subsurt)
53.84266
PPM/dw
SAR
1.376289
ESP
9.906835%
17.26505%
MANGANESE
195
241
SCA
mg/L
MAGNESIUM
2460
4170
22000
1
SCA
mg/L
SODIUM
499
36.0 '
64.4
SCA
mg/L
CADMIUM
< 4.76
< 1.20
3.31
SCA
mg/L
CHROMIUM
25.5
44.6
42.4
SCA
mg/L
COPPER
228
36.8
67.9
1 SCA
mg/L
LEAD
20.6
13.4
11.2
SCA
mg/L
NICKEL
17.0
15.6
12.9
SCA
mg/L
ZINC
514
71.9
565
SCA
mg/L
CALCIUM
6440
6860
50900
SCA
mg/L
POTASSIUM
3450
1610
1210
SCA
mg/L
ALUMINUM
7350
N/A
NIA
SCA
mg/L
ARSENIC
< 11.9
< 3.01
< 2.97
SCA
mg/L
SELENIUM
7.83
< 3.01
< 1.19
SCA
mg/L
MOLYBDENUM
< 11.9
< 3.01
< 2.97
SCA
mg/L
MERCURY
1.2
0.065
0.14
1 SCA
mg/L
N.C. Laboratory ID# 352
Lab Supervisor. Michael J. Ladd;EES-Robbinsville
Analyzed By: 44SC
Certified By:

Mars Hill Land Application Belt Press Sludge 6/1/16
PAN
Mineralization
as decimal
Total dry
tons/year
Acres
Applied on
Rate
0.4
TKN
43400
NH3
111000
NO3
2960
NO2
1 1.33
% Solids
0.207
PAN Surface
21421.33 mg/kg 42.84266 lbs/dry ton
0 1 lbs total PAN
#DIV/01 lbs PAN/acre
PAN Injection
26921.33 mg/kg 153.84266 lbs/,dry ton
0 lbs total PAN
#DIV/011 lbs PAN/acre
Dry Tons/1000 gal.
0.86319
1st year PAN
Surface lbs.
D
1st year PAN
Injected lbs.
0
lbs./acre
Surface
#DIV/0!
lbs./acre
Injected
#DIV/0!
MR(TKN-NH3)+ + .5(NH3)+NO3+NO2 =mg/kg
mg/kg x .002 =Ibs/dry ton
MR(TKN-NH3) + l(NH3)+NO3+NO2 =mg/kg
mg/kg x .002 =Ibs/dry ton
1000 X 8.34 X %solids X sp. gravity "=dry tons/1000gal."
2000
.01

SAR & Mars Hill Land Application Belt Press Sludge 7/21/15
Sodium Absorption Ratio
Na: Sodium (Mg/L) Equivalent weight: 23
Ca: Calcium (Mg/L) Equivalent weight: 20
Mg : Magnesium (Mg/L) Equivalent weight: 12
Milli Equivalent = Mg/L / Equivalent weight
Na M /L Ca M /L Ma M lL
499 1 6440 1 2100
Na ME
21.69565
Ca ME
M ME
322
175
SAR= Na Milli Equivalent/[0.5 X (Ca Milli Equivalent + Mg Milli equivalent)]0.5 power
SAR = 1.376289 (From Mg/L entered above)
SAR= 1.336595 (From ME entered below)
Na ME
21.69652
Ca (ME)
Mg (ME)
322
1 205
The amount of exchangeable sodium ions
amount of exchangeable calcium & magne
material.
Permitting guidance is if greater than 10 re
f>,V"

Sit & ESP Mars Hill Land Application Soil Site #1 6/1/16
Exchangeable Sodium Percentage
ESP = Na (Milli Equivalents) / CEC X 100 The percentage of sodium ions occupying the cation exchange complex of soils
Na ME CEC
1.56528 15.8
ESP 9.906835
Na on NC soil test is expressed as meq.
Should be less than 15% (15-20%)
k

SAW& ESP Mars Hill Land Application Soil Site #2 6/1/16
Exchangeable Sodium Percentage
ESP = Na (Milli Equivalents) / CEC X 100 The percentage of sodium ions occupying the cation exchange complex of soils
Na ME CEC
2.36531200000 13.7
ESP = 117.26505
Na on NC soil test is expressed as meq.
Should be less than 15% (15-20%)
r+

Envi
ronmental -resting solutions, lne-
Certificate of Analysis
Project name: Earth Environmental Services S
Collection date: 1-Jun-16 t
Date received: 2-Jun-16
Sample identification: 1261612
Result RL Units
Method
PO Box 7565
Asheville, NC
28802
Phone: (82g) ls0 9I64
Fax : (828) 35U-9369
Project number: 160602.524
Sample number: 137770
Analyst Footnotes
Parameter
SM 2540 G
20.7
0.10
%
7-Jun-16
AJ Y
DER
1
Total Solids
7471B
1.2 .,
0.19
mg/kg
9-Jun-16
MEC
1
Mercury
6010C
7350'
594
mg/kg
9-Jun-16
MEC
1
Aluminum
6010C
<11.9
11.9
mg/kg
9-Jun-16
MEC
1
Arsenic
6010C
<4.76
4.76
mg/kg
9-Jun-16
MEC
1
Cadmium
6010C
6440
1190
Mg/kg
9_]un-16
MEC
1
Calcium
6010C
25.5 ,
11.9
mg/kg
9-Jun-16
MEC
1
Chromium
6010C
228 �
4.76
mav /kg
9-Jun-16
MEC
1
Copper
6010C
20.6
11.9
mgf kg
9-Jun-16
MEC
1
Lead
6010C
2460
594
mg/kg
9-Jun-16
1
Magnesium
6010C
<11.9
11.9
mg/kg
9•Jun-16
MEC
1
Molybdenum
6010C
17.0
4.76
mg/kg
9-Jun-16
MEC
1
Nickel
6010C
3450
23.8
mP�g
9_JW_16
MEC
1
Potassium
6010C
7.83
4.76
mgfkg
9-Jun-16
MEC
1
Selenium
6010C
783
4.76
mg/kg
9-Jun-16
MEC
Silver
6010C
499
23.8
mg/kg
9-Jun-16
MEC
1
Sodium
?
6010C
514
11.9
mg/kg
9 Jun-16
MEC
1
Zinc
2961.33
95.88
mg/kg
16-Jun-16
1.2
Nitrate + Nitrite
6010C
16700
476
mg/kg
9-Jun-16
MEC
1
Total Phosphorus -
351.2
43400
772
mg/kg
21-inn-16
EDH
1
Total Kjeldahl Nitrogen
Calculation
46400
772
mg/kg
,]_]un_t6
LDP
1
Total Nitrogen
Ammonia Nitrogen
SM 4500 NH3 D
11000
278
mg/kg,
10-Jun-16
KEK
Percent Solids
SM 2540 G
18
%
a Jun-16
NG
H in Soil
SW 846 9045D
5.2
S.U.
3-Jun-16
NG
3
Footnotes:
RL = Reporting Limit. Values are reported down to the Reporting. Limit only.
1. Sample analyzed by Rogers & Callcott Environmental.
2. Methods EPA 9210A and SM 450ONO2 B by BMB and REH.
3. Sample analzyed outside hold time.
Date reviewed: CIO - R-4-MA
Data reviewed by: Kelley E. Keenan
Signature:
YL
NC Certification Number: 600
SC Certification Number: 99053
NC Drinking Water Certification Number: 37786
This report should not be reproduced, exept in its entirety, without the written consent of Environmental Testing Solutions, Inc.
The results in this report relate only to the samples submitted for analysis.

} Rogers & CallcOtt
ENVIRONMENTAL
Certificate of Analysis
Client Environmental Testing Solutions
Kelley E. Keenan
351 Depot St.
Asheville, NC 28801-4310
Sample Number Sample Description
6060251-01 Earth Environmental Services #061612
South Carolina Greenville Laboratory Identification 23105
South Carolina Colionbfa Laboratory Identification 40572
North Carolina Laboratol y Certification Number 27
North Carolina Drinking Water Lab Number 45710
NELAp Utah Certificate Number SC000042014-1
Georgia Drinking Water Lab ID 880
Project: Earth Environmental Services
Work Order. 6060251
Received: 06/07/2016 09:20
Matrix Sampled Type
Solid 06/01/16 00:00
PO Box 5655 1 Greenville, SC 29606 1 426 Fairforesc Way ? Greenville, SC 29607 1 main 864.232.1556 1 fax 864:232.6140 rogersandcallcott.com
-- � an employee -owned company
062412016 07.28 This report mqv not be reproduced, except in full, without written permission from Rogers R Calicort, Lic. Page 2 of 11

Rogers &callcott
ENVIRONMENTAL
Environmental Testing Solutions Project: Earth Environmental Services
351 Depot St. Work Order. 6060251
Asheville, NC 28801-4310 Reported: 06/24/16 07:28
Sample Data
Sample Number 6060251-01
Earth Environmental Services 4061612 collected on 06/01/16 00:00
Sample Description
Result
Reporting
Limit
Units
DF
Analyzed
Method
Flag Analyst
Batch
Parameter
GeneralChemistry Parameters
95.5
mg/l:g dry
5.00
06/16/16 13:30
EPA 921oA
BMB
B6F0639
Nitrate as N, extractable
2960
1.33
0.38
mE�g�Y
2.00
06/16/16 10:20
SM4500NO2B-2alt
REH
B6F0685
Nitrite as N, extractable
43400
772
mS&gdry
5.00
06/21/16 15:03
EPA351.2
EDH
B6F0784
Total Kjeldahl Nitrogen
772
mgikg dry
5.00
06/21/16 15:03
EDH
B6F0958
Total Nitrogen (TKN+Nitrate+Nitrite)
46400
P MY
B6F0272
20.7
0.10
%
1.00
06/07/16 10:33
SM 254OG
Total Solids
Total Metals
1.2
0.19
mg/kg dry
2.00
06/09/16 10:23
EPA 7471B
DER
B6F0360
Mercury
MO
594
mg/kg dry
50.0
06/09/16 11:16
EPA 6010C
MEC
B6F0299
Aluminum
N- I)
11.9
mg/kg dry
1.00
06/09/16 13:11
EPA 6010C
MEC
B6F0299
Arsenic
ND
4.76
mg/kg dry
1.00
06/09/16 13:11
EPA6010C
MEC
B6F0299
Cadmium
6440
1190
mg/k-g dry
50.0
06/09/16 11:16
EPA 6010C
NEC
136F0299
Calcium
25.5
11.9
mg/kg dry
1.00
06/09/16 13:11
EPA 6010C
NEC
B6F0299
Chromium
228
4.76
mglkg dry
1.00
06/09116 13:11
EPA 6010C
NEC
136F0299
Copper
.
20.6
11.9
mgtkg dry
1.00
06/09/16 13:11
EPA 6010C
MEC
136F0299
Lead
2460
594
mg/kg dry
50.0
06/09/16 11:16
EPA 6010C
MEC
B6170299
Magnesium
314
4.76
mg/kg dry
1.00
06/09/16 13:11
EPA 6010C
MEC
B6F0299
Manganese
ND
11:9
mg/kgdry
1.00
06/09/16 13:11
EPA 6010C
MEC
B6F0299
Molybdenum
17.0
4.76
mg/kg dry
1.00
06/09/16 13:11
EPA 6010C
MEC
136170299
Nickel
3450
23.8
mglkg dry
1.00
06/09/16 13:11
EPA 6010C
NEC
B6F0299
Potassium
ND
11.9
msikg dry
in
06/09/16 13:11
EPA 6010C
MEC
B6F0299
.Selenium
7.83
4.76
mg/kg dry
1.00
06/09/16 13:11
EPA 6010C
NEC
136170299
Silver
499
23.8
mgikg dry
1.00
06/09/16 13:11
EPA 6010C
MEC
136F0299
Sodium
16700
476
mgtkg dry
50.0
06/09/16 11:16
EPA 6010C
MEC
136F0299
Total Phosphorus as P
514
11.9
mg/kg dry
1.00
06/09/16 13:11
EPA 6010C
MEC
136F0299
Zinc
PO Box 5655 ;Greenville, SC 29606 i 426 Fairforesc Way i Greenville. SC 29607 1. main 864.232.1556 1 fax [phone] roger San dCallcott mom
062412016 07.28 This report imry not be reproduced, eccept in fiiU, without 1prinen permission fram Rogers d: Callco0, Ire. Page 3 ofi 11

f� Rogers & Callcott
ENVIRONMENTAL
Environmental Testing Solutions Project: Earth Environmental Services
351 Depot St. Work Order. 6060251
Asheville, NC 28801-4310 Reported: 06/24/16 07:28
General Chemistry Parameters
Quality
Control Summary
Reporting
Spike
Source
�oREC
RPD
Result
Limit
Units
Level
Result % REC
Limits RPD
Limit Flags
Parameter
Batch B6F0272 - General Prep - Solids
Duplicate (B6F0272-DUPI) Source: 6060251-01
Total Solids 16.8
0.10
/
20.7
21
15 P
Batch B6F0639 - Nitrate Extractable
Blank (B6F0639-BLKI)
Nitrate as N. extractable ND
4.0
mg/kg wet
LCS (B6F0639-BS1)
Nitrate as N. extractable 36.9
4A
mg/kg wet
39.7
93
85-115
Matrix Spike (B6F0639-MS1) Source: 6060251-01
Nitrate as N. extractable 3500
95.5
mg/kg dry
478
2960 112
65-136
Matrix Spike Dup (B6F0639-MSDI) Source: 6060251-01
Nitrate as N. extractable 3500
95.5
mg/kg dry
478
2960 112
65-130 0
30
Batch B6F0685 - Nitrite Extractable
Blank (B6F0685-BLK1)
Nitrite as N, extractable ND
0.04
mg/kg wet
LCS (B6F0685-BSI)
Nitrite as N, extractable 0.195
0.04
mg/Irg wet
0.198
98
85-115
Matrix Spike (B6170685-MSI) Source: 6060251-01
Nitrite as N. extractable 2.23
0.38
mg/kg dry
1.15
1.33 78
65-130
Matrix Spike Dup (B6F0685-MSD1) Source: 6060251-01
Nitrite as N. extractable 2.24
0.38
mg/kg dry
1.15
1.33 79
65-130 0.4
30
Batch B6F0784 - EPA 351.2-TKN
Blank (B6F0784-BLKI)
Total Kjeldahl Nitrogen ND
8.24
mg/kg wet
PO Box 5655 1 Greenville, SC 29606 1 426 Faiirforest Way I Greenville. SC 29607 1 main 864.232.1556 '•. fax [phone].Ogersandca11COtt.COm
an employee -owned company
0612412016 07: 23 This report may not be reproduced, ercept in fe+li, without writrett pennission from Rogers & Callcotl, hm Page 4 of 11

R Rogers &Callcott
K
ENVIRONMENTAL
Environmental Testing Solutions Project: Earth Environmental Services
351 Depot St. Work Order. 6060251
Asheville, NC 28801-4310 Reported: 06/24/16 07:28
General Chemistry Parameters
Quality Control Summary
Reporting Spike Source %REC RPD
Parameter Result ' Limit Units Level Result %REC Limits RPD Limit Flags
Batch B6FO784 - EPA 351.2-TKN
Duplicate (136170784-DUPI) Source: 6060251-01
Total Kjeldahl Nitrogen 36000 775 mg/kg dry
Reference (136170784-SRMI)
Total Kjeldald Nitrogen
43400
1020 32.2 mg/kg wet 987 104 57-143
18 30
PO Box 5655 1 Greenville, SC 29606 1 426 Fair%resc Way = Greenville. SC 29607 1 main 864.232.1556 1 fax [phone] rogersandeallcott.com
-� - - - — - - an employee -owned company
062412016 07:28 This report mnv trot be reproduced, eccept infull, without written permissionfrom Rogers & Callcon, Inc. page 5 of 11

Q
O
O
13.
E
a �
'CJ -
O o 0 0 0 o 0 0 0 0 0 0 0 0 0 0 l
o O O o 0 0 0 0 0 0 0 0 0 0 0 0 0
O O OO O G O CO OO O O O
9 B 9 9 9 9 9 9 9 9 9 9 9 9 9 9 3
E E E E E E E E E E E E< E E E E
O O O O O yl O O O O O O O ,O O O O
iA lA lA lA iA O to to IA - - - tJ1 lA lA to lA
0 9 0 0 0 o 0 0 0 0 0 0 0 0 0 0
Q P 4 P P P P P P 4 P P P P P Q P
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
p' py c Z pf n n o n en m
9 p
S
N
b
b
'TJ
v v v v o o o �d o o o v v o
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
pp o 'o b b b o 0 o b b O b
9 9 3 9 9 8 8 9 9 9 9 9 3 9 9 9 9
E E E E E E E e E E E E E E E E E
G
1.0

X - Rogers &Callcott
ENVIRONMENTAL
Environmental Testing Solutions
351 Depot St.
Asheville, NC 28801-4310
Project: Earth Environmental Services
Work Order. 6060251
Reported: 06/24/16 07:28
Total Metals
nnality f'nntral Summary
mac_-- -., ----- -- -
Reporting Spike Source %REC RPD
rameter Result Limit Units Level Result %REC Limits RPD Limit Flags
Batch B6F0299 - EPA 3050B
Reference (B6F0299-SRMI)
Aluminum
9970
249
mg/kg wet
9790
102
29.2-125.3
88.0
4.98
mg/kg wet
129
68
52.3-110
Arsenic
67.3
1.99
mA-g wet
84.9
79
65.8-114
Cadmium
5760
498
mg/kg wet
6340
91
68.1-116.9
Calcium
99.7
4.98
mg&g wet
117
85
61.4-115.2
chromium
99.0
1.99
mg&g wet
123
81
65.4-110
Copper
84.0
4.98
mg&g wet
107
79
63.9-116.9
Lead
2940
249
mg&g wet
3070
96
56.1-118.1
Magnesium
366
1.99
mg/kg wet
431
85
70.3-114.5
Manganese
93.2
4.98
mg/kg wet
109
86
60.6413.4
Molybdenum
138
1.99
mg/kg wet
173
80
64.5-111.3
Nickel
2180
9.96
mg/kg wet
2550
85
51.7-122.5
Potassium
143
4.98
mg/kg wet
182
78
59.7-116.7
Selenium
45.1
1.99
mg/kg wet
54.5
83
60-120.5
Silver
343
9.96
mg/kg wet
417
82
39.2-137A
Sodium
199
4.99
mg&g wet
230
86
69.9-128.5
Zinc
Reference (B6F0299-SRM2)
Total Phosphoms as P
662
20.0
mg&g wet
609
109
22.1-195.1
Batch B6F0360 - EPA 7471B
Blank (B6F0360-BLKI)
Mercury
ND
0.020
mg&g wet
Blank (B6F036(l-BLK2)
Mercury
ND
O.Ol9
mg/kg wet
LCS (B6F0360-BS1) .
0.48
0.020
mg/kg wet
0.500
96
80-120
Mercury
LCS (B6F0360-BS2)
0.50
0.020
mg/kg wet
0.489
103
80-120
Mercury
PO Box 5655 i Greenville SC 29606 i 426 Fair rest Way 1 Greenville, SC 29607 i main 864.232.1556 1 fax [phone] roger employee-owned
This report mw not be reproduced, ercepr in fidl, W11101tt written permission from Rogers & Callcott, /nc. page 7 of 11
0617 J/20/6 07:23

Rogers &Callc®tt
£d1 ENVIRONMENTAL
Environmental Testing Solutions Project: Earth Environmental Services
351 Depot St Work Order. 6060251
Asheville, NC 28801-4310 Reported: 06/24/16 07:28
Total Metals
Onality Control Summary
Reporting Spike Source %REC RPD
Parameter Result Limit Units Level Result %REC Limits RPD Limit Flags
Batch B6F0360 - EPA 7471B
Reference (B6F0360-SRMI)
Mercury 12 0.040 ms/ks wee 10.9 106 51-149
Sample Preparation Data
Parameter Batch Sample ID Prepared Analyst
EPA 3050B Metal Digestion
EPA 3050E B6F0299 6060251-01 06/08/2016 08:19 MEC
EPA 7471B Mercury Digestion
EPA 7471B B6F0360 6060251-01 06/08/2016 15:51 DER
PO Box 5655 1 Greenville, SC 29606 i 426 Fairforest Way i Greenville. SC 29607 1 main 864.232.1556 1 fax [phone] rogersandcalleott-com
- _ - —_— — - - an employee-oxvned company
0612412016 07.18 Thisn report mqv not be reproduced, except ifill, without written permission from Rogers & Callcon,1ne Page 8 of 11

Rogers &Callcott
'- ENVIRONMENTAL
Environmental Testing Solutions Project: Earth Environmental Services
351 Depot St. Work Order. 6060251
Asheville, NC 28801-4310 Reported: 06/24/16 07:28
Data Qualifiers and Definitions
ND Analyte NOT DETECTED at or above the reporting limit
NR Not reported
RPD Relative Percent Difference
P The RPD between the sample / duplicate or matrix spike / spike duplicate was not within control limits.
PO Box 5655 I Greenville, SC 29606 1 426 Fairroresc Way 1 Greenville, SC 29607 ! main 864.232.1556 I tax 864.2326140 rogersandcallcott.com
- - a i employee -owned company
0612412016 07.28 This report may not be reproduced, eccept in fidl, without written permission from Rogers X Calicon, Inc Page 9 of 11

-0
h
CD
0
0
y.
Rogers &CaLlcott CHAIN OF CUSTODY RECORD WORK ORDER Ca.0(P0X 1
" "-- ENVIRONMENTAL
Mailing PO Box 565S Shipping 426 Fairforest Way 225B Stonerldge Drive
Address: Greenville, SC 29606 Address: Greenville, SC 29607 Columbia, SC 29210
Phone [phone] Fax [phone] Phone [phone]
Client Name
Address
Report To:
Email Address
Telephone#
PO # Project #
v
c
,�
(13
z
o
V
E C2
`m
CL
4
Filtered (Yes/N )
Cooled (Yes/ o)
Conta(ner Type lasts /Glass)
Container Volume (mL) _VO
Sample Type (Grab/Composite)
Sample Source (WW, GW, DW, SW , ther)
Preservation Code(s)
A —None E—HCI I—ZnAcetate
B—HNOa F—NazS203 J—H3PO4
C—Hzs04 G—Boric Add K-MCAA
D — NaOH H —Ascorbic Add L-
J1
�-
S"'
R&C
WORK ORDER
YR_
DATE
M
11ME
0000
j� SAMPLE DESCRIPTION
* V i0 l 101Z
COMMENTS
/LLood rr(1 i
i
J
A
SAMP ER —RELINQUISHED BY:
1. 0)
DATEITIME:
(J (o C)
RECEIVED BY:
2.
DATE/TIME:
Composite Start Date:
Composite Start Time:
Time or Flow (Circle one) Initials:
RELIN ISHED BY:
3 re Ct�
DATE/TIME:
RECE BY*
4.
p' ^ATE/1•IME:
u `
RELINQUISHED BY:
5
DATE/TIME:
RECEIVED Y:
6.
DA E/TIME:
Temperature of blank or representative sample .
At time of collection °C
At time of lab receipt _ /J °C
RELINQUISHED BY:
7•
DATE/TIME:
RECEIVED BY:
DATE/TIME:
Possible hazards associated with samples: LJ Nan -Hazard UFlammable L jskin Irritant "Poison I unknown u0ther
Form Revised July, 2014 Page of

o ,h
-;
'C41@L`aai '
Sample Receipt Verification
S
ClientDate Work
Received:
Order:
Carrier Name: Client FedE UPS US Mail Courier Field Services Other.
Tracking Number: � � �-I �()
N
o
N
A
Comments
Damaged Leaking Other.
01
0,
Damaged Leaking other.
Ice Cold Packs Dry Ice None
If in-house preservation used — record Lot #
HCL Ii3PO4
Other
Comments:
Were non-conformance issues noted at -sample receipt? Yes oz No
Non Conformance issue other than noted above:
Revised July 2014 Completed
Page 11 of 11 1

ROBBINSVILLE LABORATORY EARTH ENVIRONMENTAL SERVICES
[phone] 0 0-9 8 3 5
WEAVERVILLE OFFICE MICHAEL LADD-OWNER
[phone] CHAIN -OF -CUSTODY RECORn -
FAX: [phone] P.O. BOX 2733 75 BISON LANE Analytical Request
RESIDENCE [phone] WEAVERVILLE, NC 28787 MURPHY, NC 28906na
•' �
FAX: [phone]
Client: rc� 64, 14 U W UJ (` Report To: /°C di
AddressBill To: �' �-�1 Init Lab Temp:
P.O. # / Billing Reference: Rec Lab Temp:
Phone: ��� a a 6^d`r FAX #:8'r'10Q!!2 — 2 ��� *Requested Due Da`
Sampled By (print):
y
LL
,.
1
JREMARKS
•
Sampler Signature Date
ITEM
# SAMPLE DESCRIPTION
SampledLA.,—
RESID , ••TIME MATRIX EES # r
COMMON
.
'RETU,.,;RELINQUSEDBYSHIPMENT METHODoUT/DATE•,=,RNED/D# , /AFrF. ILIATIONt a
s`
h c
;ACCEPTED BY/AFFILIATIONS `DATE TIMEADDITIONAL
COMMENTS:
N
1
SEE REVERSE SIDE FOR INSTRUCTIONS CP-0771-B

WaYpointo
„
ANALYTICAL
Submitted By,
Client:
EARTH ENVIRONMENTAL SVCS
75 BISON LN
MURPHY NC 28906
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 o Fax [phone]
www.waypointanalytical.com
Michael Ladd SOIL ANALYS
Grower: Report No: 16-161-0655
Earth Environmental Cust No -
PO:
Lab Number: 24687 Field Id:
avtL rr-K I ILI IY GUIDELINES
Crop: Lawn
N .
0 3.5
Crop:
Comment:
- 46220
Date Printed: 06/10/2016
Date Received: 06/09/2016
Date Analysis : 06/10/2016
Page: 1 of 4
Sample Id : 1 #061613 611 116
Rec Units: LB/1000 SF
Fe
0
Rec Units:
L& /L'-(�-
S; '+, % (at
Analysis prepared by: Waypoint Analytical Virginia, Inc.
Pauric McGroary

Waypoint(D
ANALYTICAL
Client:
EARTH ENVIRONMENTAL SVCS
75 BISON LN
MURPHY NC 28906
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www-waypointanalytical.com
Michael Ladd
Grower:
Earth Environmental
PO:
Report No:
16-161-0655
Cust No:
46220
Date Printed:
06/10/2016
Date Received:
06/09/2016
Date Analysis :
06/10/2016
Page:
2 of 4
Lab Number: 24687 Field Id : Sample Id : 1 #061613 611 116
SUGGESTED FERTILIZATION PROGRAM
First Application Second Application Third Application Fourth Application
#/1000 Sq. Ft. Fertilizer #/100D Sq. Ff. Fertilizer #/1000 Sq. Ft. Fertilizer #11000 Sq. Ft. Fertilizer
6 21-0-0 6 21-0-0 6 21-0-0
Comments:
Lawn
• Cation Exchange Capacity may be over -estimated due to high potassium level.
The amount of fertilizer recommended on the first page is the total amount needed for the entire growing season. Split into 3-4
applications to keep the lawn green and prevent fertilizer loss. You should not apply more than 0.7 Ibs of soluble nitrogen per 1000
square feet in a 30 day period. Or more than, 0.9 Ibs of nitrogen per 1000 square feet if you are using a slow or controlled release
product in a 30 day pedod.Custom blend is best to meet exactly the requirement, if this is impossible, the above specific fertilizer
application is a general guideline, if the specified grades can not be found, replace with fertilizer having similar N:P:K ratio. The best
time to apply fertilizer for cool season grass (bluegrass, fescue, ryegrass) is in the Fall when the grass is growing. For Mid -Atlantic
region the time is from late August to November. For Northeast region the time is from mid August to October. Fall application should
start as soon as the day time high temperature is below 80-85F, apply with the interval of one month. If you start application late in the
Fall and do not finish all three applications, repeat the same applications in the Fall of next year. Spring application is recommended
when exceptional fertilizer loss due to heavy spring rain leaching and the grasses look pale green. ,Spring application can start as soon
as the grass starts to grow in April. In the case of exceptional warm spring, the application can be made earlier.
• To reduce soil pH apply 2.5 pounds of elemental sulfur per 1000 square feet for every 0.1 of pH unit above 7.2. For example, a soil
pH of 7.4 requires 5 pounds of elemental sulfur (0.2 * 2.5). Do not apply more than 5 Ibs per 1000 square feet per application or more
than 10 Ibs of elemental sulfur per 1000 square feet per year. Timing between applications should be minimum of 3 months. Warm
temperature and moist soil are needed for sulfur to reduce soil pH. If sulfur is applied in winter or under drought conditions, it will take
longer for the the soil pH to be lowered.
• Use ammonium sulfate as all or portion of the N requirement to reduce pH.
• For a more in depth explanation of the soil test and recommendations, go to ourwebsite www.aleastdm.com and select the "lawn
and Garden" tab at the top of home page. Under the "How to Understand a Soil Test Report" header you will find the link to the:article
"Soil Test Report & Fertilizer Recommendation, Explained".
Analysis prepared by: Way point Analytical Virginia, Inc.
Pauric McGroary
i

C i
Waypoint(D
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-94001 ° Fax [phone]
ANALYTICAL www.waypointanalytical.com
Submitted BY: Michael Ladd SOIL ANALYS
Client: Grower: Report No: 16-161-0655
EARTH ENVIRONMENTAL SVCS Earth Environmental Cust No: 46220
75 BISON LN Date Printed: 06/10/2016
MURPHY NC 28906 Date Received: 06/09/2016
Date Analysis : 06/10/2016
PO: Page : 3 of 4
Lab Number: 24688 Field Id : Sample Id : 2 #061614 611 116
SOIL FERTILITY GUIDELINES
Crop: Lawn
pbs).... LIME;:,. (tons)... Ni F2:(
0 3.5 0
Crop
Comment:
Analysis prepared by: Waypoint Analytical Virginia, Inc.
Rec Units: 1-8/1000 SF
K,ZQ.. Cu.
Fe -
0 0
Rec Units:
10 �,5 G(1��^:drtp�,f cj',
?of" OF 60W
Pauric McGroary

t(D
Waypoin
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www-wavnn inte—l..Q-1 ..
Submitted By. Michael Ladd
SOIL ANALYSIS
Client: Grower :
EARTH ENVIRONMENTAL SVCS Earth Environmental
Report No:
16-161-0655
75 BISON LN
oust No:
46220
MURPHY NC 28906
Date Printed:
06/10/2016
Date Received:
06/09/2016
Date Analysis :
06/10/2016
PO:
Page :
4 of 4
1 _hM.....L..•.. nennn
-------••--• • �_VVW MUM M : Sample Id: 2 #061614 611 116
SUGGESTED FERTILIZATION PROGRAIIA'..
First Application
Second Application
Third Application
Fourth Application
#/1000 Sq. FL;
Fertilizer
#11000 Sq. FL
Fertilizer
#/1000 Sq. FL
Fertilizer`:
M1000 Sq. Ft
Fertilizer
10
r`.nmmcnfa-
10-0-20
6
21-0-0
6
21-0-0
Lawn
• The amount of fertilizer recommended on the first page is the total amount needed for the entire growing season. Split into 3-4
applications to keep the lawn green and prevent fertilizer loss. You should not apply more than 07 Ibs of soluble nitrogen per 1000
square feet in a 30 day period. Or more than 0.9 Ibs of nitrogen per 1000 square feet if you are using a slow or controlled release
product in a 30 day period.Custom blend is best to meet exactly the requirement, if this is impossible, the above specific fertilizer
application is a general guideline, if the specified grades can not be found, replace with fertilizer having similar N:P:K ratio. The best
time to apply fertilizer for cool season grass (bluegrass, fescue, ryegrass) is in the Fall when the grass is growing. For Mid -Atlantic
region the time is from late August to November. For Northeast region the time is from mid August to October. Fall application should
start as soon as the day time high temperature is below 80-85F, apply with the interval of one month. If you start application late in the
Fall and do not finish all three applications, repeat the same applications in the Fall of next year. Spring application is recommended
when exceptional fertilizer loss due to heavy spring rain leaching and the grasses look pale green. Spring application can start as soon
as the grass starts to'grow in April. In the case of exceptional warm spring, the application can bd made earlier.
• To reduce soil pH apply 2.5 pounds of elemental sulfur per 1000 square feet for every 0.1 of pH unit above 7.2. For example, a soil
PH of 7.4 requires 5 pounds of elemental sulfur (0.2' 2.5). Do not apply more than 5 Ibs per 1000; square feet per application or more
than 10 Ibs of elemental sulfur per 1000 square feet per year. Timing between applications should be minimum of 3 months. Warm
temperature and moist soil are needed for sulfur to reduce soil pH. If sulfur is applied in winter or under drought conditions, it will take
longer for the the soil pH to be lowered.
Use ammonium sulfate as all or portion of the N requirement to reduce pH.
• For a more in depth explanation of the soil test and recommendations, go to our website www.aleastem.com and select the "Lawn
and Garden" tab at the top of home page.. Under the "How to Understand a Soil Test Report" header you will find the link to the article
"Soil Test -Report & Fertilizer Recommendation Fxpla�ned".
` t4} l� c�
Analysis prepared by: Waypoint Analytical Virginia, Inc.
Pauric McGroary

PO Box 7565
� Asheville, NC 28802
h{ s FF
Phone: [phone]
Fax: [phone]
Environmental Testing Solutions, Inc. Certificate of Analysis
Project name: Earth Environmental Services t r Project number: 160602.523
Collection date: 1-Jun-16 Q 44k
Date received: 2-Jun-16
Sample identification: H061613 J ( I Sample number: 137767
Parameter Method Result RL Units Date Analyst Footnotes
Analyzed
Percent Solids SM 2540 G 82.5 0.10 % 7-Jun-16 AJY 1
Mercury 7471B 0.065 0.048 mg/kg 9-Jun-16 DER 1
Arsenic 6010C <3.01 3.01 mg/kg 9-Jun-16 MEC 1
Cadmium 6010C <1.20 1.20 mg/kg 9-Jun-16 MEC 1
Calcium 6010C 6860 301 mg/kg 9-Jun-16 MEC 1
Chromium 6010C 44.6 3.01 mg/kg 9-Jun-16 MEC 1
Copper 6010C 36.8 1.20 mg/kg 9-Jun-16 MEC 1
Lead 6010C 13.4 3.01 mg/kg 9-Jun-16 MEC 1
Magnesium 6010C 4170 151 mg/kg 9-Jun-16 MEC I
Mangenese 6010C 195 1.20 mg/kg 9-Jun-16 MEC I
Molybdenum 6010C <3.01 3.01 mg/kg 9-Jun-16 MEC 1
Nickel 6010C 15.6 1.50 mg/kg 9-Jun-16 MEC 1
Potassium 6010C 1610 6.02 mg/kg 9-Jun-16 MEC 1
Selenium 6010C <3.01 3.01 mg/kg 9-Jun-16 MEC 1
Silver 6010C <1.20 1.20 mg/kg 9-Jun-16 MEC 1
Sodium 6010C 36.0 6.02 mg/kg 9-Jun-16 MEC 1
Zinc 6010C 71.9 3.01 mg/kg 9-Jun-16 MEC 1
Total Phosphorus 6010C 1280 120 mg/kg 9-Jun-16 MEC 1
pH in Soil 6010 C 6.7 S.U. 3-Jun-16 NG 3
Acidity (Soil Fertility) NCDA <0.1 0.1 meq/100g 14-Jun-16 ECHEM 2
pH NCDA 6.86 S.U. 14-Jun-16 ECHEM 2
% Total Solids SM 2540 B 83.4 % 9-Jun-16 ECHEM 2
This report should not be reproduced, eaept in its entirety, without the written consent of Environmental Testing Solutions, Inc.
The results in this report relate only to the samples submitted for analysis.

e i ' _1:l
The results in this report relate only to the samples submitted for analysis.
F
'x ' :N
Environmental Testing Solutions, Inc.
Project name:
Collection date:
Date received:
Certificate of Analysis
Earth Environmental Services
1-Jun-16
2-Jun-16
Sample identification: #061614
PO Box 7565
Asheville, NC 28802
Phone: [phone]
Fax: [phone]
Project number: 160602.523
l�t Sj4e- W
Sample number:
137768
Parameter
Method
Result
RL
Units
Date
Analyst
Footnotes
Analyzed
Percent Solids
SM 2540 G
82.8
0.10
%
7-Jun-16
AJY
1
Mercury
7471B
0.14
0.047
mg/kg
9-Jun-16
DER
1
Arsenic
6010C
<2.97
2.97
mg/kg
9-Jun-16
MEC
1
Cadmium
6010C
3.31
1.19
mg/kg
9-Jun-16
MEC
1
Calcium
6010C
50900
2970
mg/kg
9-Jun-16
NEC
1
Chromium
6010C
42.4
2.97
mg/kg
9-Jun-16
MEC
1
Copper
6010C
67.9
1.19
mg/kg
9-Jun-16
MEC
1
Lead
6010C
11.2
2.97
mg/kg
9-Jun-16
MEC
1
Magnesium
6010C
22000
1490
mg/kg
9-Jun-16
MEC
1
Mangenese
6010C
241
1.19
mg/kg
9-Jun-16
MEC
1
Molybdenum
6010C
<2.97
2.97
mg/kg
9-Jun-16
MEC
1
Nickel
6010C
12.9
1.19
mg/kg
9-Jun-16
MEC
1
Potassium
6010C
1210
5.95
mg/kg
9-Jun-16
MEC
1
Selenium
6010C
<2.97
2.97
mg/kg
9-Jun-16
MEC
1
Silver
6010C
<1.19
1.19
mg/kg
9-Jun-16
MEC
1
Sodium
6010C
54.4
5.95
mg/kg
9-Jun-16
MEC
1
Zinc
6010C
565
149
mg/kg
9-Jun-16
MEC
1
Total Phosphorus
6010 C
1230
1190
mg/kg
9-Jun-16
MEC
1
pH in Soil
SW 846 9045D
7.0�
S.U.
3-Jun-16
NG
3
Acidity (Soil Fertility)
NCDA
<0.1
0.1
m«yloos
14-Jun-16
ECHEM
2
pH
NCDA
7.15
S.U.
14-Jun-16
ECHEM
2
% Total Solids
SM 2540 B
80.5
%
9-Jun-16
ECHEM
2
Footnotes:
RL = Reporting Limit. Values are reported down to the Reporting Limit only.
1. Sample analyzed by Rogers & Callcott Environmental.
2. Sample analyzed by Enviro Chemists, Inc.
3. Sample anazlyed outside holding time.
Date reviewed: NC Certification Number: 600
Data reviewed by: Kelley E. Keenan SC Certification Number: 99053
NC Drinking Water Certification Number. 37786

Rogers & Callcott
ENVIRONMENTAL
Certificate of Analysis
Client Environmental Testing Solutions
Kelley E. Keenan
351 Depot St.
Asheville, NC 28801-4310
Sample Number Sample Description
6060250-01 Earth Environmental Services #061613
6060250-02 Earth Environmental Services #061614
NBpR Sp
South Carolina Greenville Laboratory Identification 23105
South Carolina Colinnbia Laboratory Identification 40572
North Carolina Laboratory Certification Number 27
North Carolina Drinking Water Lab Number 45710
NELAP Utah Certificate Number SC000042014-1
Georgia Drinking Water Lab ID 880
Project: Earth Environmental Services
Work Order: 6060250
Received: 06/07/2016 09:20
Matrix
Sampled
Solid
06/01/16 00:00
Solid
06/01/16 00:00
Type
PO Box 5655 1 Greenville, SC 29606 1 426 Fairforest Way I Greenville, SC 29607 1 main 864.232.1556 I fax [phone] rogersandcallcott.com
an employee -owned company
0611512016 10:25 This report mw not be reproduced, except in full, without written permission front Rogers & Callcon, Inc. Page 2 of 10

0��_
Rogers &Callcott
ENVIRONMENTAL
Environmental Testing Solutions Project: Earth Environmental Services
351 Depot St. Work Order: 6060250
Asheville, NC 28801-4310 Reported: 06/15/16 10:25
Sample Data
Sample Number 6060250-01
Sample Description Earth Environmental Services #061613 collected on 06/01/16 00:00
Reporting
Parameter Result Limit Units DF
Analyzed
Method
Flag Analyst
Batch
General Chemistry Parameters
Total Solids
82.5
0.10
%
1.00
06/07/16 10:33
SM 254OG
AJY
136F0272
Total Metals
Mercury
0.065
0.048
mg/kg dry
2.00
06/09/16 10:12
EPA 7471B
DER
B6F0360
Arsenic
ND
3.01
mg/kg dry
1.00
06/09/16 13:16
EPA 60I0C
MEC
136170299
Cadmium
ND
1.20
mg/kg dry
1.00
06/09/16 13:16
EPA6010C
MEC
136F0299
Calcium
6860
301
mg&g dry
50.0
06/09/16 11:12
EPA 6010C
MEC
136F0299
Chromium
44.6
3.01
mg/kg dry
1.00
06/09/16 13:16
EPA 6010C
MEC
B6170299
Copper
36.8
1.20
mg/kg dry
1.00
06/09/16 13:16
EPA 6010C
MEC
B6F0299
Lead
13.4
3.01
mg/kg dry
1.00
06/09/16 13:16
EPA 6010C
MEC
136170299
Magnesium
4170
151
mg/kg dry
50.0
06/09/16 11:12
EPA 6010C
MEC
B6F0299
Manganese
195
1.20
mg/kg dry
1.00
06/09/16 13:16
EPA 6010C
MEC
B6F0299
Molybdenum
ND
3.01
mg/kg dry
1.00
06/09/16 13:16
EPA 6010C
MEC
136F0299
Nickel
15.6
1.20
mg/kg dry
1.00
06/09/16 13:16
EPA 6010C
MEC
136F0299
Potassium
1610
6.02
mg/kg dry
1.00
06/09/16 13:16
EPA 6010C
MEC
B6F0299
Selenium
ND
3.01
mg/kg dry
1.00
06/09/16 13:16
EPA 6010C
MEC
136F0299
Silver
ND
1.20
mg/kg dry
1.00
06/09/16 13:16
EPA 601OC
MEC
B6F0299
Sodium
36.0
6.02
mg/kg dry
1.00
06/09/16 13:16
EPA 601OC
MEC
B6F0299
Total Phosphorus as P
1280
120
mg&g dry
50.0
06/09/16 11:12
EPA 6010C
MEC
B6F0299
Zinc
71.9
3.01
mg/kg dry
1.00
06/09/16 13:16
EPA 6010C
MEC
136F0299
PO Box 5655 1 Greenville, SC 29606 1 426 Fairforesc Way I Greenville, SC 29607 1 main 864.232.1556 1 fax [phone] rogersandcallcott.com
an employee -owned company
0611512016 10:25 This report mqv not be reproduced, ercept in jdl, rritlforrt rvritten pernrisrioa from Rogers & Callcott, Inc. Page 3 of 10

,R Rogers & Callcott
L _ ENVIRONMENTAL
Environmental Testing Solutions Project: Earth Environmental Services
351 Depot St. Work Order: 6060250
Asheville, NC 288014310 Reported: 06/15/16 10:25
Sample Number 6060250-02
Sample Description Earth Environmental Services 4061614 collected on 06/01/16 00:00
Reporting
Parameter Result Limit Units DF
Analyzed
Method
Flag Analyst
Batch
General Chemistry Parameters
Total Solids
82.8
0.10
%
1.00
06/07/16 10:33
SM 254OG
AJY
B6F0272
Total Metals
Mercury
0.14
0.047
mg/kg dry
2.00
06/09/16 10:21
EPA 7471E
DER
B6F0360
Arsenic
ND
2.97
mg/kg dry
1.00
06/09/16 13:21
EPA 6010C
MEC
136F0299
Cadmium
3.31
1.19
mg/kg dry
1.00
06/09/16 13:21
EPA 601oC
MEC
B6F0299
Calcium
50900
2970
mg/kg dry
500
06/09/16 10:41
EPA 6010C
MEC
B6F0299
Chromium
42.4
2.97
mg/kg dry
1.00
06/09/16 13:21
EPA 601oC
MEC
B6F0299
Copper
67.9
1.19
mg/kg dry
1.00
06/09/16 13:21
EPA 6010C
MEC
B6F0299
Lead
11.2
2.97
mg/kg dry
1.00
06/09/16 13:21
EPA 6010C
MEC
B6170299
Magnesium
22000
1490
mg/kg dry
500
06/09/16 10:41
EPA 6010C
MEC
B6F0299
Manganese
241
1.19
mg/kg dry
1.00
06/09/16 13:21
EPA 6010C
MEC
B6F0299
Molybdenum
ND
2.97
mg/kg dry
1.00
06/09/16 13:21
EPA 6010C
MEC
B6170299
Nickel
12.9
1.19
mg/kg dry
1.00
06/09/16 13:21
EPA 6010C
MEC
B6F0299
Potassium
1210
5.95
mg/kg dry
1.00
06/09/16 13:21
EPA 6010C
MEC
B6170299
Selenium
ND
2.97
mg/kg dry
1.00
06/09/16 13:21
EPA 601OC
MEC
136F0299
Silver
ND
1.19
mg/kg dry
1.00
06/09/16 13:21
EPA 6010C
MEC
B6170299
Sodium
54.4
5.95
mg/kg dry
1.00
06/09/16 13:21
EPA 6010C
MEC
B6F0299
Total Phosphorus as P
1230
119
mg/kg dry
50.0
06/09/16 l 1:14
EPA 6010C
MEC
B6F0299
Zinc
565
149
mg/kg dry
50.0
06/09/16 11:14
EPA 6010C
MEC
B6170299
PO Box 5655 1 Greenville, SC 29606 1 426 FalrForest Way I Greenville, SC 29607 1 main 864.232.1556 1 fax [phone] rogersandcallcott.com
an employee -owned company
0611512016 10.25 This report urgv not be reproduced, except in fill, without written permission from Rogers X Callcon, Inc Page 4 Of O

A x'
v Rogers & Callcott
-' ENVIRONMENTAL
Environmental Testing Solutions Project: Earth Environmental Services
351 Depot St. Work Order: 6060250
Asheville, NC 288014310 Reported: 06/15/16 10:25
Total Metals
Quality Control Summary
Reporting Spike Source %REC RPD
Parameter Result Limit Units Level Result % REC Limits RPD Limit Flags
Batch B6F0299 - EPA 3050B
Blank (B6F0299-BLK1)
Arsenic
ND
0.05
ntg/kg wet
Cadmium
ND
0.02
mg/kg wet
Calcium
ND
0.10
mg/kg wet
Chromium
ND
0.05
mg/kg wet
Copper
ND
0.02
mg/kg wet
Lead
ND
0.05
mg/kg wet
Magnesium
ND
0.05
mg/kg wet
Manganese
ND
0.02
mg/kg wet
Molybdenum
ND
0.05
mg/kg wet
Nickel
ND
0.02
mg/kg wet
Potassium
ND
0.10
mg&g wet
Selenium
ND
0.05
mg/kg wet
Silver
ND
0.02
mg/kg wet
Sodium
ND
0.10
mg/kg wet
Total Phosphorus as P
ND
0.04
mg/kg wet
Zinc
ND
0.05
mg&g wet
LCS (B6F0299-BS1)
Arsenic
0.49
0.05
mg/kg wet
0.500
99
80-120
Cadmium
0.50
0.02
mg/kg wet
0.500
99
80-120
Calcium
0.55
0.10
mg/kg wet
0.500
109
80-120
Chromium
0.50
0.05
mg/kg wet
0.500
100
80-120
Copper
0.52
0.02
tng/kg wet
0.500
104
80-120
Lead
0.50
0.05
mg&g wet
0.500
100
80-120
Magnesium
0.51
0.05
mg/kg wet
0.500
102
80-120
Manganese
0.51
0.02
mg/kg wet
0.500
102
80-120
Molybdenum
0.53
0.05
mg/kg wet
0.500
105
80-120
Nickel
0.50
0.02
mg/kg wet
0.500
101
80-120
Potassium
5.38
0.10
mg/kg wet
5.00
108
80-120
Selenium
0.50
0.05
mg/kg wet
0.500
100
80-120
Silver
0.51
0.02
mg/kg wet
0.500
103
80-120
Sodium
0.53
0.10
mg/kg wet
0.500
106
80-120
Total Phosphorus as P
0.50
0.04
mg/kg wet
0.500
99
80-120
Zinc
0.50
0.05
mg/kg wet
0.500
99
80-120
PO Box 5655 1 Greenville, SC 29606 1 426 Fairioresc Way I Greenville, SC 29607 1 main 864.232.1556 1 fax [phone] rogersandcalleott.com
an employee -owned company
0611512016 10:25 This report taw not be reproduced, except in fill, without written pennission from Rogers & Callcon, Inc. Page 5 of 10

of
y Rogers & Callcott
s�F ENVIRONMENTAL
Environmental Testing Solutions Project: Earth Environmental Services
351 Depot St. Work Order: 6060250
Asheville, NC 28801-4310 Reported: 06/15/16 10:25
Total Metals
Quality Control Summary
Reporting Spike Source %REC RPD
Parameter Result Limit Units Level Result % REC Limits RPD Limit Flags
Batch B6F0299 - EPA 3050B
Reference (B6F0299-SRMI)
Arsenic
88.0
4.98
mg/kg wet
129
68
52.3-110
Cadmium
67.3
1.99
mg/kg wet
84.9
79
65.8-114
Calcium
5760
498
mgikg wet
6340
91
68.1-116.9
Chromium
98.7
4.98
mg/kg wet
117
85
61.4-115.2
Copper
99.0
1.99
mg/kg wet
123
81
65.4-110
Lead
84.0
4.98
mgAcg wet
107
79
63.9-116.9
Magnesium
2940
249
mgAcg wet
3070
96
56.1-118.1
Manganese
366
1.99
mg/kg wet
431
85
70.3-114.5
Molybdenum
93.2
4.98
mg/kg wet
109
86
60.6-1 t3.4
Nickel
138
1.99
mg/kg wet
173
80
64.5-111.3
Potassium
2180
9.96
mg/kg wet
2550
85
51.7-122.5
Selenium
143
4.98
mg/kg wet
182
78
59.7-116.7
Silver
45.1
1.99
mg/kg wet
54.5
83
60-120.5
Sodium
343
9.96
mgAcg wet
417
82
39.2-137.4
Zinc
199
4.98
mg/kg wet
230
86
69.9-128.5
Reference (B6F0299-SRM2)
Total Phosphorus as P
662
20.0
mg/kg wet
609
109
22.1-195.1
Batch B6F0360 - EPA 7471B
Blank (B6F0360-BLKI)
Mercury
ND
0.020
mg1kg wet
Blank (B6F0360-BLK2)
Mercury
ND
0.019
mg&cg wet
LCS (B6F0360-BSI)
Mercury
0.48
0.020
mg/kg wet
0.500
96
80-120
LCS (B6F0360-BS2)
Mercury
0.50
0.020
mg/kg wet
0.489
103
80-120
PO Box 5655 1 Greenville, SC 29606 1 426 Fairforesc Way I Greenville, SC 29607 1 main 864.232-1556 1 fax [phone] rogersandcallcott.com
an employee -owned company
0611512016 10:25 This report nrgv not be reproduced, except in fill, without wrillen permission front Rogers & Callcot, Inc. Page 6 of 10

y Rogers & Callcott
ENVIRONMENTAL
Environmental Testing Solutions Project: Earth Environmental Services
351 Depot St. Work Order: 6060250
Asheville, NC 28801-4310 Reported: 06/15/16 10:25
Total Metals
Quality Control Summary
Reporting Spike Source ' %REC RPD
Parameter Result Limit Units Level Result %REC Limits RPD Limit Flags
Batch B6F0360 - EPA 7471B
Reference (B6F0360-SRMI)
Mercury
12
0.040 mg/kg wet
10.9 106
51-149
Sample Preparation Data
Parameter
Batch
Sample ID
Prepared
Analyst
EPA 3050B Metal Digestion
EPA 3050B
1300299
6060250-01
06/08/2016 08:19
MEC
EPA 3050B
B6F0299
6060250-02
06/08/2016 08:19
MEC
EPA 7471B Mercury Digestion
EPA 7471B
B6F0360
6060250-01
06/08/2016 15:51
DER
EPA 7471B
136170360
6060250-02
06/08/2016 15:51
DER
PO Box 5655 I Greenville, SC 29606 1 426 Fairforest Way i Greenville, SC 29607 1 main 864.232.1556 1 fax [phone] rogersalldCallCOtt.C011l
an employee -owned company
0611512016 10.25 This report ntuv not be reproduced, eccept is ftdl, without wrillen permission from Rogers & Callcoa, Inc. Page 7 of 10

Rogers & Callcott
ENVIRONMENTAL
Environmental Testing Solutions Project: Earth Environmental Services
351 Depot St. Work Order: 6060250
Asheville, NC 28801-4310 Reported: 06/15/16 10:25
Data Qualifiers and Definitions
ND Analyte NOT DETECTED at or above the reporting limit
NR Not reported
RPD Relative Percent Difference
PO Box 5655 1 Greenville, SC 29606 1 426 Fairforesc Way I Greenville, SC 29607 1 main 864.232.1556 1 fax [phone] rogersandcallcott.com
an employee -owned company
0611512016 10.25 This report may not be reproduced, except in fill, without ivrinen permission from Rogers & Callcou, Inc. Page 8 of 10

CM
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p} '_
�.����®}� CHAIN OF CUSTODY RECORD WORKORDER (00M�V
r''' ENVIRONMENTAL
I�`, .
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Filtered (Yes/N )
Cooled (Yes/ o
Mailing PO Box 5655 Shipping 426 Fairforest Way 2158 Stoneridge Drive
-
Container Type(P StIC GI2S5)
—
Address: G�eenvllle,SC29606 Address: Greenville,SC29607 Columbia, SC29210
Phone [phone] Fax [phone] Phone [phone]
Container Volume (mL) Wo
Client Name
Sample Type Lrab/Composite)
Address
Sample Source (WW, GW, DW, S(s, ther)
L
m
c
Report To: l
o
Preservation Code(s)
Email Address
4
o
e"
A —None E—HCl I—ZnAcetate
v
_
B—HNO3 F—Na2S203 J—H3PO4
Telephone#
L
Cu
o
C—H2SO4 G—Boric Add K-MCAA
PO # Project #
E
Z
o
E
m
D—NaOH H—Ascorbic Acid L-
R&C
YR_
WORKORDER
DATE
TIME
SAMPLE DESCRIPTION
COMMENTS
•-Q
Coup
000u
b 101-5
` 4.'
X
x
x
Wad
Y
t
s4
a
3
SAMPLER —RELINQUISHED BY:
DATE/TIME:
RECEIVED BY:
DATE/TIME:
2 rto nQ, _ „
( ow 1(9
Composite Start Date:
Composite Start Time:
RELI UIIS�1H�E,D BY:
DATE/TIME:
RE V D B
DATE/TI E:
��}
��vV
3. e
'
4'
" r
Time or Flow (Circle one) Initials:
RELINQUISHED BY:
DATE/TIME:
RECEIV Y:
DATE/TIME:
5•
6•
Temperature of blank or representative sample
Attime of collection 'C
RELINQUISHED BY:
DATE/TIME:
RECEIVED BY:
DATE/TIME:
7.
8. -
At time of lab receipt "C
Possible Hazards associated with samples: Non -Hazard DFIammable Elkin Irritant Poison l dnnknown ❑Other Form Revised July, 2014 Page of

y
r -tt
Sample Receipt Verification
Date
Client: Received:
Carrier Name: Client FedE UPS US Mail Courier
Tracking Number: _7(1(�
Work /�
Order:DO U O X 6
Field Services Other:
Receipt Criteria
Y
e
s
o
A
Comments
Shipping container / cooler intact?
Damaged Leaking Other:
Custody seats intact?
COC included with samples?
COC signed when relinquished and received?
Sample bottles intact?
Damaged Leaking Other:
Sample ID on COC agree with label on bottle(s)?
Date / time on COC agree with label on bottle(s)?
Number of bottles on COC agrees with number. of bottles received?
Samples received within holding time?
Sample volume sufficient for analysis?
VOA vials free ofheads pace (<6mm bubble)?
Samples cooled? Temp at receipt recorded on COC
Temp measured with nt thermometer - SN: 97050067
Ice�Col�dP�aeks­&r�yIce None
Samples requiring pH preservation at proper pH? _XE:l
Note: Samples for metals analysis may be preserved upon receipt in the lab.
X
Samples dechlorinated for parameters requiring chlorine removal at
the time of sample collection?
I
Y_
If in-house preservation used — record Lot #
HCL
H3PO4
H2SO4
NaOH
HNO3
Other
Comments:
Were non-conformance issues noted at. sample receipt? Yes or No
Non -Conformance issue other than noted above:
Revised July 2014 Completed by:
Page 10 of 10

LLenvirochem
SM
ANALYTICAL & CONSULTING CHEMISTS
Environmental Testing Solutions, Inc.
Post Office Box 7565
Asheville NC 28802
Attention: Kelley Keenan (ETS)
Environmental Chemists, Inc.
6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax
710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax
255-A Wilmington Highway, Jacksonville, NC 28540 v 910.347.5843 Lab/Fax
[e-mail]
Date of Report: Jun 16, 2016
Customer PO #:
Customer ID: 081.00055
Report #:. 2016-07509
Project ID: Earth Environmental
Lab ID Sample ID: 061613 Collect Date/Time Matrix Sampled by
16-17947 Site: 6/1/2016 Solid/Sludge Client
Test Method Results Date Analyzed
Acidity (Soil Fertility) NCDA Agronomic Division <0.1 meq/100g 06/14/2016
pH NCDA-Agronomic Division 6.86 units 06/14/2016
Total Solids (%) SM 2540 B 83.4 % 06/09/2016
Lab ID Sample ID: 061614 Collect Date/Time Matrix Sampled by
16-17948 Site: 6/1/2016 Solid/Sludge Client
Test Method I Results Date Analyzed
Acidity (Soil Fertility) NCDA-Agronomic Division <0.1 meq/100g 06/14/2016
pH NCDA-Agronomic Division 7.16 units 06/14/2016
Total Solids (%) SM 2540 B 80.5 % 06/09/2016
Comment:
Reviewed by:
Report #.: 2016-07509 Page 1 of 1

OF .i
Environmental Testing Solutions, Inc.
PO Box 7565, Asheville,. NC 28802
Phone: [phone], Fax: [phone]
n_..e....a wr.....,..
CHAIN -OF -CUSTODY / Analytical Request
Client Name:
Address:
Report to:
Phone:
PO Number:
- �' r hi C
Fax:
I tp-0-75013
RprmpeMd Annlvepe
Project Number:
pH Checked Upon Recei t
Cl, < 0.2 mp/I Upon Receipt
d
a
Preservatives
Sample Identification
a >~
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U m a
vOi O
x O
O N
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Field
n
R
F pCN x z Z
Temp. (°C) Comments
UP
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try,:
Temperature (°C) 16 lr/
,
0 .�
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(wd�
Received on Ice:
Y / N
�LP
Igo
' D3a
Sealed Cooler:
enl N
Samples Intact: .—'9
.sC
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Addition-C-7om`ments:Sampler
Name and Signature
Datc
ed'A/ ,/4 a n,.� 1 -li
� �
Printed N o am lep r:
Signature ofSampler:-

ROBBINSVILLE LABORATORY EARTH ENVIRONMENTAL SERVICES
[phone]
WEAVERVILLE OFFICE MICHAEL LADD-OWNER
[phone]
FAX: [phone] P.O. BOX 2733 75 BISON LANE
RESIDENCE [phone] WEAVERVILL.E, NC 28787 MURPHY, NC 28906
'FAX: [phone]
417
r_
Client: ��-�"� �`f� f <�'� FA'�,� �e11`\ c� f Report To:
Address: Bill To: -S
/N L P.O. # / Billing Reference:
Phone: FAX #:
009839
CHAIN -OF -CUSTODY RECOP#'
Analytical Request
T
Init Lab Temp:
Rec Lab Teri
*Reque"&U Date:
Sampled By (print):
I _
Sampler Signature Date Sampled
• '•„ ..;b••,_'.:.., :.,, ,,
ITEM , •CL
:
�
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:
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�� RAARKS
# SAMPLE DESCRIPTION RESID. TIME* *MATRIX -. EES # ,:'
E sloomommoson■©NE
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02101
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ACCEPTED BY/AFFILIATION_..
1_
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-®
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ADDITIONAL COMMENTS:■
SEE 9,EVE9SE
SIDE FOR INSTRUCTIONS
J
II�In_ r 0 A tc Y1 le) l ( 1 A 1\� (0 (\OAQ' P .1 /T\ (Tr

ROBBINSVILLE LABORATORY
[phone]
WEAVERVILLE OFFICE
[phone]
FAX: [phone]
RESIDENCE [phone]
FAX: [phone]
GdAMNEW EARTH ENVIRONMENTAL SERVICES
MlCHAEL LADD-OWNER
P.O. BOX 2733 75 BISON LANE
WEAVERVILLE, NC 28787 MURPHY, NC 28906
Client` ri wx r t13� l�' �' `C� R-1 u bu
Address: / r U 180� 3 (D
Phnne:lS 3_k-aCJQ—a_'�' a-r 8--2?-.20,) -2)LC 4 R
Report To: �&eo-f- yZ�
Bill To: V✓✓l l�
P.O. # / Billing Reference:
� P w1A
009336
CHAIN -OF -CUSTODY RECO Y*�
Analytical Request
a
Init Lab Temp: �-
Rec Lab Te G
*Requ? t Date:
Sampled By (print):
co
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Sampler Signature fpate Sampled
<< .
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ACCEPTED BY/AFFILIATION
` -,DATE TIME '.
ADDITIONAL COMMENTS:
_4
SEE REVERSE SIDE FOR INSTRUCTIONS cP-0771-B

c. a -4
P-1-0
Town of Mars Hill NC
2016 Land Application Report
WQOOO4298
Attached are the required forms for the Town of Mars Hills 2016 land application
program.
The town has land applied 18.821 dry tons of sludge over 14.5 acres in the calendar year
2016. We have also maintained compliance with all terms and conditions.
Contact Information:
Preparer/ORC
Robert Sams
Land Application ORC
Town of Mars Hill
PO Box 368
Mars Hill NC 28754
Phone # [phone]
Permittee
Darhyl Boone
Town Manager
Town of Mars Hill
PO Box 368
Mars Hill NC 28754
Phone # [phone]
FEB 2 8 2017
Water MAY ReglwW OpwdW&
GT,GN
l 'rOWAAT10i rKCH,'s.rGUNIT

ANNUAL LAND APPLICATION CERTIFICATION FORM
4k. WQ Permit#: WQ0004298 County: Madison Year: 2016
Facility Name (as shown on permit): Town of Mars Hill
Land Application Operator:
Robert M Sams
Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
2, Yes [i No - If No, slip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Recidualc Annliention Summarv:
Total number of application fields in the permit:
2
Total number of fields utilized for land application during the year:
1
Total amount of dry tons applied during the year for all application sites:
18.821
Total number of acres utilizes for land application during the year:
14.5
Part B - Annual Comniance Statement:
Facility was compliant during calendar year 2016 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Resources. 2 Yes 0 No
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies
of laboratory results are attached.
4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant
Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503
regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the. Division of Water Resources.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as
specified in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Darhyl Boone- Town Manager
Permit Name and Title (type or p;int)
row, ONE NAW
�.
Signature of Prepaier* v / DaX Signature of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in
WQ Permit Number: WQ0004298 Laboratory: 1) Earth Envi
Facility Name: Town of Mars Hill 2) Environemtal T
Residual Source WQ # or NCO057151 3) A&L Lat
NPDES #: 4)
WWTP Name: Town of Mars Hill WWTP 5)
Residual Analysis Data
RSSF - B
Solutions
Parameter
(mg/kg)
Ceiling
Conc.
Limit
Sample or Composite Date
6/Ol/16
Percent Solids (%)
NA
20.7
Arsenic
.75
11.9
Cadmium
85
4.76
Copper
4,300
228
Chromium
NA
25.5
Lead
840
20.6
Mercury
57
1.2
Molybdenum
75
11.9
Nickel
420
17
Selenium
100
7.83
Zinc
7,500
514
Total Phosphorus
NA
16700
TKN
NA
43400
Ammonia -Nitrogen
NA
11000
Nitrate and Nitrite
I NA
12961.33
For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalti r submitting false mfor tation, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer ate
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FOR RSSF (12/2006)

Feb 131708:22a EARTH ENVIRONMENTAL SERVI
-3 Earfh byhomeohl Sarvins
Michael Ladd
75 Bison Lane
Murphy, NC 28906
Robbinsville Lab [phone]
Weaverville Lab (828) 64"196
Residence [phone]
828-835-8631
Name and Address of Facility: Date: 111 B12017
Town of Mars Hill WWTP Sample Collector. JR
P.O. Box 368 Date and Time Sample Received: 61V2016 11:00 AM
Mars Hill, NC 28754 Date and Time Sample Collected: 61IJ2016 ?
At Robert Sams Date and Time Sample Analyzed: < MHT
Land Application Analyses -Note: All results in mg/Kg Dry Basis unless otherwise noted.
Test
Belt Press Sludge
Soil Site 91
Sol Site #2
IRLportUmii
Method
Units
ACIDITY
TOTAL SUSPENDED RESIDUE
OA megl100g
0.0 megll Dog
.0
SCA
SM2540D
megl100g
mill -
CATION EXCHANGE CAPACITY
PH " ✓
15.8 m 100g
6 9
13.7 meg11 Dog
7.2
0-14
SCA
SCA
meg1100g
units
AMMONIA NITROGEN ✓
NO2t..NO3-n.,,...w..,...._.__......_..........._..::.........;..,_
TOTAL KJELDAHL NITROGEN ✓
TOTAL PHOSPHOROUS `�
:.............:_.....,._..........;
...296L'33.........
43
16700
.....,,...w._..._._...........:.........,..:.,..:�..._w
1280
1230
0.5
._._,...,1:i(_.............,....
SCA
SCA _..._.,...�..m�-
SCA
SCA
mgn_
mill -
mg1L
PERCENT TOTAL RESIDUE
20.7%
82.5'Yo
828%
SCA
mg1L
°% ORGANIC MATTER
S.7%
6.7%
SCA
NTU
% BASE SATURATION - K `
13.5%
3.6°%
SCA
mglL
' H
0.0%
0.0%
-Mg
25.8°%
25.5%
-Ca
60.8%
70.9%
• Na
0.7°%
0.7%
PLANT AVAILABLE (surb-ce)
4ZB4266
PPM1dw
NITROGEN- PPM DRY Y1rT (subsurf)
53.84266
PPM1dw
SAR
1.376289
ESP _
9.9%835'Yo
17.26505%
MANGANESE
195
241
SCA
mg1L
MAGNESIUM V
2460
4170 °/
2200D
SCA
mgR
SODIUM
499
36.0
54A
SCA
mg/L
CADMIUM
g4.76J
c 1.20
3.31
SCA
mg1L
CHROMIUM
25.5
44.6
42A
SCA
mg1L
COPPER ✓
22a
1 36. '�
ro 6T.9
SCA
mg1L
LEAD
20.6
13A
11.2
SCA
mall
NICKEL
EE
15.6
12.9
SCA
m91LZINC
CALCIUM ✓
71.9
6860
565
50900
SCA
SCA
mgl-
m
POTASSIUM
3450
1610
1210
SCA
mglL
ALUMINUM
735
NIA
NIA
SCA
ARSENIC ✓
< 1 9
< 3.01
1297
SCA
4mg1L
SELENIUM
< 3.01
< 1.19
SCA
MOLYBDENUM
11.9
< 3.01
< 2.97
SCA
mg1L
MERCURY ✓
1.
0.065 1
0.14
SCA
my/L
P.1
V.C. Laboratory IDS 362 Analyzed By:
.ab Supervisor. Mchael J. Ladd; EES-Robbinsville Certified By:
it j
0-c J4 ry�s 0 r,

Mars Hill Land Application Belt Press Sludge 6/1/16
PAN
iralization
Rate TKN NH3 NO3 --T— NO2
0-4_ 11000 2960 1 1.33
PAN Surface
42.84266 lbsEld2r ton
0
lbr, total PAN
#DIV/O!
bs PAN/acre
PAN Imection
26 .331 mqfkg
63.84266 lbs/dry to
011bs
total PAN
#DIV/01 I
lbs PAN/acre
1000 gal.
0.86319
1st year PAN
lbs./acre
Surface lbs.
01
Surface
-7
#DIV/91
lot year PAN
lbs./acre
112L,ected lbs.
Injected
#DIVIOI
as decimal
Total dry Acres
% Solids
tons/year Applied on
0.207
MR(TKN-NH3)+
+.5(NH3)+NO3+NO2
mg/kg
mg/kg x.002
=Ibs/dry ton
MR(TKN-NH3) +
I(NH3)+NO3+NO2
Mg/kg
mg/kg x.002
=lbs/dry ton
1000 X 8.34 X %s blids X sg. -gravity
2000
"=dry tonsil 000gal."
w
vp --4
C)
m
]z
m
z
0
m
z
Cn
m

#-n
co
SAR &-T&P &
SodlUm Absorption R2
Na: Sodium (Mg/L)
Ca : Calcium (Mg/L)
Mg: Magnesium (Mg/L)
Milli Equivalent = Mg/L /
SAR= Na Milli Eauivaler
ars Hill Land Application Belt Press Sludge 7121/15
do
Na M /L
Ca M /L
M /L
Equivalent weight: 23
499
fi440
2100
Equivalent weight: 20
Equivalent weight: 12
Na MG
Ca E
21.69565
175
322
Equivalent weight
i, 0.5 X (Ca Milli Equivalent + Mg Milli equivalent)]0.5 power
i
'rom Mg/L entered above)
(From ME entered below)
Na ME
21.69652
Ca ME
; 322
M ME
205
The amount of exchangeable sodium ions
amount of exchangeable calcium & magne
material.
Permitting guidance Is if greater than 10 re
00
N
W
OD
W
(J7
60
0)
W

m
Cr
• � �iw
SRR & ESP Mars Hill Land Application Soil Site Al 611116 C)
CO
Exchangeable Sodium Percentage w
ESP = Na (Milli Equivalents) / CEC X 100 The percentage of sodium ions occupying the cation exchange complex of soils
i
Na ME m
CEC j D
1.56528 15.8
ESP = 19.906835 % Should be less than 15% (15-20%) <
Na on NC soil test Is expressed as meq. o
CD
N
W
CO
W
C11
CO
W
W
R

SAR & ESP Mars Hill Land Application Soil Site #2 6/1/16
Exchangeable Sodium Percentage
ESP = Na (Milli Equivalents) / CEC X 100 The percentage of sodium ions occupying
Na ME CEC
2.36531200000 113.7
ESP = 117,26506
Na on NC soil test is expressed as meq.
cation exchange complex of soils
Should be less than 15% (15-20%)
M
—A, Co
s
CO
rV
00
00
W
Y,
Oo
0)
W

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Town of Mars Hill Land Application Total Dry Tons Applied (Annual):
WQ0004298 Cation Exchange Capacity (non 503 only):
Robert Sams Owner: Matthew Cody Predominant Soil Series:
14.5 Acres Permitted: 14.5 Site #: 1 Field #: 1
18.82
15.8
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Soral-
ample2
Com-
posite
Date
611116
611116
3
.
4
5
6
7
8
9
10
11
12
% Solids
20.7
20.7
Arsenic
11.9
11.9
Cadmium
4.76
4.76
Copper
228
228
Chromium
25.5
25.5
Lead
20.6
20.6
Mercury
' 1.2
1.2
Molyb-
denum
11.9
11.9
Nickel
17
17
Selenium
7.83
7.83
Zinc
514
514
Los
16700
16700
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
Lif
L2J
LIJ4
5
6
7
8
9
10
11
12
DT/Ac./
o
App.
y
Event
0.65
0.65
"
Arsenic
0.015
1 0.015
0.000
0.000
1 0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.000
1 0.000
0.031
Cadmium
0.606
0.006 '
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.012
Copper
0.296
0.296
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.592
Chromium
0.033 `
0.033
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.0.666
Lead
0.027
0.027
0.000
0.000
0.000
0.000
0.000
0.000
6.000
0.000
0.000
0.000
0.053
Mercury
0.002
0.002
0.000.
0.000
0.000
0.000
0.000
0.600
0.000
0.000
0.000
0.000
0.003
Molyb-
0.015 ,
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.031
denum
Nickel
0.022
0.022.
.0.000
0.000
0.000
0.000
0.000 1
0.000
0.000
0.000
0.000
0.000
0.044
Selenium
0.010
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.020
Zinc
0.667
0.667
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
6.000
0.000
1.334
Total
Phos-
21.67.7
21.677
0.000.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
43.353
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
impriso t for knowing violation
9131.
Signature of Land Applier Date DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMU
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMI'.
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APP.
Facility Name: Town of Mars Hill LA WQ Permit #: WQ0004298 Field #: 111
Land Owner: Matthew Cody Annual Dry Tons Appt: F Site #:
Operator: Robert Sams Predominant Soil Seri .
Crop 1 Name:
Crop 1 Max.
2 Name:
Y FORM
ED FOR EACH FIELD APPLIED ON
Acres Utilized: 14.5
Acres Permitted: 14.5
Cation Exchange Capacity (non 503): 15.8
.Crop 2 Max. PAN:
o
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
lied per
Applied P
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc )
Cond.
Wei'
Moist)
recap.
Past 24
Hrs.
inches
�Y
c; 'b
�.
oa
* o
o
o
`�.
* w
��°
`D
P.
* P.
TKN
mg/kg
Z
o o
w.
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
pp
( lbs/acre )
Name of Crop Type
ReceivingResidual
Application
Crop 1
Crop 2
Crop 1
Crop 2
27/16
54
20.7
0.649
Belt Press Sludge
Dry
0
s
0.5
30%
43400 1
11000
2961.33
23.608
NA
Fescue
29/16
54
20.7
0.649
Belt Press Sludge
Dry
0
s
0.5
30%
43400
11000
2961.3
23.608
NA
Fescue
0.000
0.000
0.000
0.000
0.000
a.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
f
I
I
1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0:000
0
0
#VALUE!
Residuals Applications totals
on FORM
FSF supp ( attach FORM
FSF supp to this form):
#######
#######
Lime Applied
TALS:
108
0
yaw ,S
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
47.215
0.000
usual lbs/acre
for Years Cumulative lbs/ac
zrrent Cumulative lbs/ac
:rmitted C. P. L. R.****
0.031
0.994
1.025
36
0.012
0.646
0.658
1 34
0.592
52.95
53.542
1 1338
0.066
2.125
2.191
1 NL
0.053
5.538
5.591
267
0.003
0.137
0.140
15
0.031
2.881
2.912
NL
0.044
2.673
2.717
374
0.020
1.685
1.705
1 89
1.334
8.907
10.241��
2498�
43.35
%
.,
Date
11/23/16
lbs/ac
3448
rmit PAN Limit lst/2nd Cropa
certify, under penalty of law, that this document was prepared under my direction or supervisi
talified personnel properly gathered and evaluated the information submitted. I am aware that_
formation, ' uding the possibility of P
es and imprisonment for knowing violations."
J �� *Application M
**Volatilization
Signature of Land Applier
aerobically dil
****C.P.L.R.:
in accordance with a system designed to assure that
-re are significant penalties for submitting false
)d: S - Surface, IN - Injection, INC - Incorporation
te: Surface - 0.5, Injection/Incorporation - 1.0
Rates: Compost -0.1, anaerobially digested -0.2,
l -0.3, raw sludge -0.4
.ulative Pollutant Loading Rate
nPNR FORM PRF tiq/9nnm

ANNUAL LAND APPLICATION FIELD
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND
Facility Name: Town of Mars Hill
Land Owner: Micheal Cody
Operator: Robert Sams
Crop 1 Name:
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT
WQ Permit #: WQ0004298
Annual Dry Tons ApplieL. Q
Predominant Soil Series:
Crop 1 Max. PAN:
Field #: L
Site #: 1
Crop 2 Name:
FORM
1 FOR EACH FIELD APPLIED ON
Acres Utilized: 0
Acres Permitted: 3.8
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
Volume applied
pp
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp ' p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
WetHrs.
Moist)
Precip.
Past 24
inches
a
b
a
* p
C
o
�'
* w'
c
o
S
0"
*
* '*
0
TKN
mg/kg
Z �
=t
aro c
a w.
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(Ibs/acre)
Name of CropType
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
.d Not
#DIV/0!
Did Not Apply
#DIV/0!
#DlV/0!
,PPIy
#DIV/01
Did Not Apply
#DIV/0!
#DIV/0!
#DIV/0!
Did Not Apply
#DIV/0!
#0IV/0!
#DIV/0!
Did Not Apply
#DIV/0!
#DIV/0!
#DIV/0!
Did Not Apply
#DIV/0!
#DIV/0!
#DIV%0!
Did Not Apply
#DIV/0!
#DIV/0!
#DIV/01
Did Not Apply
#DIV/01
#DIV/01
#DIV/0!
Did Not Apply
#DIV/0!
#DIV/0!
#DIV/0!
Did Not Apply
#DIV/0!
#DIV/01
#DIV/0!
Did Not Apply
#DIV/0!
#DIV/0!
#DIV/0!
Did Not Apply
#DIV/0!
#DIV/0!
f7R
#DIV/0!
Did Not Apply
#DIV/0!
#DIV/0!
�
Residuals Applications totals
on FORM FSF supp ( attach
FO101
FSF supp to this form):
TAls:
o
o
&_w =
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
0.000
0.000 .
Lime Applied
mual lbs/acre
�
Date
lbs/ac
for Years Cumulative lbs/acagg
E,
�
11/23/16
2631
irrent Cumulative lbs/ac
:rmitted C. P. L. R.
#VALUE!
#######
#######
#######
#######
#######
#######
#######
#######
#######-�.�
rmit PAN Limit l st/2nd CropF�
certify, under penalty of law, that this document was prepared under my direction or supervisigI n in accordance with a system designed to assure that
ialified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
formation,ding the possibility of fines and imprisonment for knowing violations."
*Application M#hod: S - Surface, IN - Injection, INC - Incorporation
_ **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
IIFNR Ff1RhA FCF (19/9nnA)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Town of Mars Hill . WQ- ermit Number: WQ0004298
WWTP Name: Town of Mars Hill W SNP ES Number: NCO057151
Monitoring Period: From 10/19/2016 To('-10/27/201
Pathogen Reduction (15A NCAC (02T .1106),rPCase indicate le 'eyed and alternative performed:
Class A
Alt. A (time/temp)—'
r Alt B (Alk Treatment) ®
Alt. C (Prior Testing) ❑�
A1t.D o Prior Test ❑
Process to Further Reduce Patho ens ❑`
r '
If applicable to alternative
performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray
Pasteurization ®
Class B:.
Alt. (1) Fecal Den ty ❑
Alt. (2) Process to Significantly Reduce Pathogens ❑��
If applicable to alternative
performe ass
B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
Air Drying ❑ Composting ❑ Aerobic Digestiqd 2
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following
monitoring
data:
Parameter
Allowable Level
in Sludge
in
Pathogen Density
Number ot
Excee-
d
Frequency
of Analysis
Y
Sample
Type
Analytical
Tech -
i one
inim
Geo. Mean
axim
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
2300
10600
68000
col/gram
0
1/year
grab
9222d
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.1 (VS reduction) ®
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) (]
1 Alt. 4 (Spec. 02 uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization [:3Alt
7 (Drying - Stable) ❑
Alt. 8 (Drying - Unstable)
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) [3
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
L� "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
® "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Robert M Sams -Land App ORC
Prepar e and Tit a or rint)
Signature of Preparer*
Land Applier Name.and Title (if applicable)(type or print)
R I
1Y-1 7
ate Signature of Land Applier (if applicable)
Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

S tJ
NC ID #352
Mr. Robert Sams
Town of Mars Hill
P.O. Box 368
Mars Hill, NC 28754
Dear Mr. Sams:
EARTH ENVIRONMENTAL SERVICES
75 Bison Lane
Murphy, NC 28906
Residence — [phone]
Robbinsville Lab — [phone]
Weaverville Lab — [phone]
Fax — [phone]
E-Mail — earthenvser@u,webworla.com\
November 18, 2016
Following is a report of laboratory analyses for digester sludge samples received 10/19, 10/20, 10/21,
10/24, 10/25, 10/26, 10/27/16.
...- ..... ......... ....
._..._. _.. — -- ----- .. ----- ----- -- -----.._._.. f ---- -- - --- --------- -- -- - --
Colony Counts
# Samnle Date Cnlifnrm T)rnsitirc (rnlnnirs/vram) %Tntal Snlirlc n 10O m1 n MO m1 n M1 mi
1
10/19/16
42,000 Colonies/Gram
0.77
TNTC
32
5
2
10/20/16
34,000 Colonies/Gram
0.76
TNTC
26
4
3
10/21/16
68,000 Colonies/Gram
0.75
TNTC
51
8
4
10/24/16
3,800 Colonies/Gram
0.74
28 -
2
0
5
10/25/16
2,800 Colonies/Gram
0.75
19
4
0
6
10/26/16
2,300 Colonies/Gram
0.74
18
1
0
7
10/27/16
6,500 Colonies/Gram
0.71
46
10
0
Geometric mean for all seven samples: 10,600 colonies/gram. Thank you for your
business. If you have any question or need additional sample analyses performed, please
call.
Respectfully submitted,
e 4P
Michael J. Ladd
Laboratory Director

Feb 131708:38a EARTH ENVIRONMENTAL SERVI
828-835-8631 p.1
Specific Oxygen Uptake Rate
SOUR
Facility Name:
Biosolids Permit Number.
Date:
Digester Temperature:,
Sampling Date/Time:
Sampled By:
Analysis DateTme:
Analyzed By:
Sample Volume:
Total Solids:
Beginning Temperature:
End Temperature:
Time Dissolved Oxygen level
1
16 13-351 I/
1000 milliliters
0.77 % Dry Solids
14.5 degrees Celsius /
14.3 degrees Celsius l/
Slope: 0.1
Intercept: 5.4
Correlation Coefficient: 1.0
Oxygen Uptake. Rate: 8.27 mg Oxygen/hr
Ambient Specific Oxygen Uptake Rate: 1.07 mg Oxygen/g/hr
Average Temperature: 14 de rees Celsius
Temperature Correction Factor. 1.500730352 I/
Temperature Corrected Specific Oxygen Uptake Rate:; 1.61 mg Oxygenlg/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. A
D
�Le

cli
Oxygen Uptake Rate Chart y =-0.1378x + 5.5298
OP
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Time (minutes)

Feb 131708:38a EARTH ENVIRONMENTAL SERVI
� a
828-835-8631 p.3
Specific Oxygen Uptake Rate
SOUR
Facility Name:
Biosolids Permit Number.
Digester Temperature:
Sampling Date/Time:
Sampled By:
Analysis DatefTime:
Analyzed By.
Sample Volume:
Total Solids:
Beginning Temperature:
End Temperature:
Time Dissolved Oxygen Level
Slope:
Intercept:
Correlation Coefficient:
000 milliliters /
).85 % Dry Solids V
14.1 degrees Celsius
14 degrees Celsius V/
a.1
4.8
1.0
Oxygen Uptake Rate: 6.64 mg Oxygenlhr
Ambient Specific Oxygen Uptake Rate. 0.78 mg Oxygenlglhr
Average Temperature: 14 degrees Celsius
Temperature Correction Factor. 1.500730352�
Temperature Corrected Specific Oxygen Uptake Rate: 1.17 mg Oxygenlglhr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

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1 2 3 4 5 6
i
Oxygen Uptake Rate Chart
y =-0.1107x + 4.8775
I
7 8 9 10 11 12 13 14 15 16
Time (minutes)

Feb 131708:39a EARTH ENVIRONMENTAL SERVI
828-835-8631 p.5
Time
(mina
0
1
2
4
5
6
7
8
9
1C
11
12
1�
14
1!
Specific Oxygen Uptake Rate
SOUR
Facility Nam
Biosolids Permit Numbe
Digester Temperature:
Sampling Daterrime:
Sampled By:
Analysis Date[Time:
Analyzed By.
Sample Volume:
Total Solids:
Beginning Temperature:
End Temperature:
Dissolved Oxygen Level
Slope:
Intercept:
Correlation Coefficient:
1 611512016 15:051
1000 milliliters
0.95 %Dry Solids /
18.2 degrees Celsius
18 degrees Celsius V
0.1
4.2
1.0
Oxygen Uptake Rate: 5.61 mg Oxygen/hr
Ambient Specific Oxygen Uptake Rate: 0.59 mg Oxygenfgfhr
Average Temperature: 18 degrees Celsius
Temperature Correction Factor. 1.1449
Temperature Corrected Specific Oxygen Uptake Rate: 0.68 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

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y =-0.0935x + 4.2925
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Time (minutes)

Fib 13 17 08:39a
.r
EARTH ENVIRONMENTAL SERVI
828-835-8631 p.7
Time
Specific Oxygen Uptake Rate
SOUR
Facility Name
Biosolids Permit Numbei
Date
Digester Temperature
Sampling DateMme
Sampled By
Analysis Date/71me
Analyzed By
Sample Volume
Total Solids
Beginning Temperature
End Temperature
Dissolved Oxygen Level
ars Hm
0004298
15-Jul
18.3
7/15/201610:05
lchaei Ladd
7/15/2016 10:05
1000 milliliters
0.89 % Dry Solids
18.5 degrees Celsius
1 ..4 degrees Celsius
Slope:
0.1
Intercept:
4.0
Correlation Coefficient:
1.0
Oxygen Uptake Rate:
6.59 ring Oxygen/hr
Ambient Specific Oxygen Uptake Rate:
0.74 mg Oxygen/g/hr
Average Temperature:
18 degrees Celsius
Temperature Correction Factor.
1.1449,/
Temperature Corrected Specific Oxygen
Uptake Rate: 0.85 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

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n Uptake Rate Chart
y =-0.1098x + 4.1528
ON
=mom=
MEN=
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Imm
Time (minutes)

e
Feh/13 17,08:40a
�_
EARTH ENVIRONMENTAL SERVI
828-835-8631 p,9
Time
Specific Oxygen Uptake Rate
SOUR
Facility Name:
Biosolids Permit Number:
Digester Temperature:
Sampling Datefl'ime: 8/23120161
Sampled By: Michael Ladd
Analysis Date/Time: 8/23/2016 1
Analyzed By: Michael Ladd
Sample Volume:
Total Solids:
Beginning Temperature:
End Temperature:
Dissolved Oxygen Level
Slope: 0.1
Intercept: 3.6
Correlation Coefficient: 1.0
Ililiters
Dry Solids
grees Celsius
grees Celsius
Oxygen Uptake Rate: 4.72 mg Oxygen/hr
Ambient Specific Oxygen Uptake Rate: 0.50 mg Oxygen/g/hr
Average Temperature: / 19.degrees Celsius
Temperature Correction Factor. ✓ 1.07
Temperature Corrected Specific Oxygen Uptake Rate: 0.54 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

O
Q y =-0.0786x + 3.696
Oxygen Uptake Rate Chart
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NINE
Time (minutes)

Feb 1317 08:40a EARTH ENVIRONMENTAL SERVI
828-835-8631 p,11
Time
(mil
Specific Oxygen Uptake Rate
SOUR
Facility Name:
Biosolids Permit Number
Digester Temperature: 17.9
Sampling DatelTime: 9/22/2016 9:20
Sampled By: Michael Ladd r/
Analysis Date/Time: 9/22/2016 9:20
Analyzed By: Michael Ladd
Sample Volume: 1000 milliliters
Total Solids: 0.74 % Dry Solids t1'/
Beginning Temperature: 18.4 degrees Celsius
End Temperature: 18.2 degrees Celsius
Dissolved Oxygen Level
Slope: 0.1
Intercept: 4.8
Correlation Coefficient: 1.0
Oxygen Uptake Rate: 5.69 mg Oxygenthr
Ambient Specific Oxygen Uptake Rate: 0.77 mg Oxygen/glhr
Average Temperature: 18 degrees Celsius
Temperature Correction Factor: 1.1449 ,,/
Temperature Corrected Specific Oxygen Uptake Rate: 0.8B mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

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Uptake Rate Chart y =-0.0949x + 4.854
7 8 9 10 11
Time (minutes)
12 13 14 15 16

Feb 131708:41a
EARTH ENVIRONMENTAL SERVI
828-835-8631 p.13
Time
Specific Oxygen Uptake Rate
SOUR
Facility Name:
Biosolids Permit Number:
Digester Temperature: 1
Sampling Date/Time: 10/24/2016 14
Sampled By: 1 Michael Ladd
Analysis Date/Time: 10/24/2016 14
Analyzed By: Michael Ladd
Sample Volume: 11
Total Solids: 0
Beginning Temperature: 1
End Temperature:1
Dissolved Oxygen Level
Slope: 0.1
Intercept 4.3
Correlation Coefficient: 1.0
iilliliters
Dry Solids
egrees Celsius
egrees Celsius
Oxygen Uptake Rate: . 5.03 mg Oxygen/hr
Ambient Specific Oxygen Uptake Rate: 0.69 mg Oxygenlglhr
Average Temperature: 15 degr es Celsius
Temperature Correction Factor. 1.402551731 kX V/
Temperature Corrected Specific Oxygen Uptake Rate: t}.97 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

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7 8 9 10 11
Time (minutes)
y =-0.0839x + 4.3575
12 13 14 15 16
a)
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