WQ0004298_2006 Residuals Annual Report_20070219

ANNUAL LAND APPLIUA ION CER11FICA ION Y01Cv1 14ICb
Permit#: WQ0004298 County:
Facility Name (as shown on permit):
Land Application Operator:
Madison
Year: 2006
Town of Mars Hill Land Application
Robert M. Sams Phone: [phone]
Land application of residual solids as allowed by the permit occurred during the past calendar year?
M Yes ❑ No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A:
Total number of application fields in permit: 2
Total number of fields land application occurred during the year: 2
Part B:
Facility was compliant during calendar year 2006 with all conditions of the land application permit
(including but not limited to items 1-12 below) issued by the Division of Water Quality. S Yes ' ® No
If no please, provide a written description why the facility was not compliant, the dates, an -explain-..
corrective action taken.
3
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil p-��H of -at Mu
least 6.0 or the limit specified in the permit. r w 0
3. Annual soils analysis were performed on each site receiving residuals during the past calendar ,y a�andtree
(3) copies of laboratory results are attached. f
4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are att the . Z
5. All other monitoring was performed in accordance with the permit and reported during the year=asrequired
and three (3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part=50-3.13-or the.
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a viation
prior authorization was received from the Division of Water Quality. C EIVt
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or ex lanati ns of
violations are attached to include appropriate actions and remediations. FES Z0[� t
a�CT101�
10• in accordanceetative cover
with theecrop managemecified in the nt planit s maintained on this site and the s goo ioved
o eS31"1 e -.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Darhyl Boone -Town Manager
PermittName and Title (type or print)
I'll /ye�l //
Signature of Preparer*
(if different from Permittee)
" Preparer is defined in 40 CFR Part 503.9 (r)
ate
Signatur of Permittee Date
Signature of Land Applier Date
(if different from Permittee and Preparer)
\ DENR FORM ACF (5/2003)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: WQ0004298 Laboratory: 1) Earth Environmental Inc.
Facility Name: Town of Mars Hill Land Application 2)
NPDES # or NCO057151 3)
WQ#:
4)
WWTP Name: Town of Mars Hill WWTP 5)
Residual Analysis Data
Sample or !,—Composite Date
-t®-t-
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant -penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer ate
DENR FORM RSSF (5/2003)

Feb• 12 07 081 12p
Name and Address Of Foollily;
TOWIN of Mars Hill WW7P
P.O. Box 308
Mars Hill. INC 2a'/54
Att: Hobert Sams
Earth Environmentai Svcs
Earl EnvronmeW senses
M"aelLadd
75 815on Lana
Murphy, NC 28908
RobbIM5418 LSD (82a)4798428
Madison County Lob [phone]
Resldenc*e [phone]
Dab: 9J52007 RS
sn& ColleteoP
Dabs and Tines Sample,Received; 7R52006 111 s AM
08ba find Timm Somple ColleOed: 7R5200B
Daand Time le Ana < MFR
bs
land l"Ion Anslyaes - Now: An nouft
In mgma ury e�B
w�.,,,.. ^.W
�•�
'
Units
Test
oy Bed %K+ F
Sal 'She N1
so Sits r12
Report
Harlot
1 g megll
1.0 nreyl
2.0
SM5210B
THIL
tiorfY
CTAL SUSPENOED RESIDUE
17.{
13.1
pen 100m1
CAPACITY
W4
SNK WH+
units
7,T07.00
NtT1ri00EN3910
pC®rrA:L
0.5
SM4a00NH3F
mgfL
1.0
SM55208JELDAHL
03�1373.00
NRROOEN
18100
SCA
"911-
OTAL PHOSPHOROUS
12100
SCA
PERCENT TOTAL RESIDUE
192%
61'"
774%
1.0
SM25408
moll.
5.2%
6.1%
1.0
SM21308
NTU
AMC MATrM
BIKE SATURATION - K
13.69E
21 AIA
1.0
SM25=
frok
.H
12.iSL
12.t�6
27B%
252%
-G
58.5%
40.3%
surTeea
8,ee0
5M2S708
PPMIdw
U DRY WY subs
6,88li
$M4b00CIG
PPM/dSv
SM2Ss08
d C
EAVALE
SUPSPENID£O SOLIDS
1.0
N/A
TIE
24M
t32D0
2080
SCA
nvA.
1020
a 240
c 250
SCA
MOIL
c 5.09
< 1.20
c 125
SCA
L
cHRWpJm
17.0
42A
40B
SCA
m
COPPER
225
32.7
13.3
SCA
LF %D
2&9
12.0
*As
SCA
m
XMIKEL
16.5
6.14
125
SCA
6ei3
70.6
36.7
SCA
m
am
11100
25W
SCA
tPINASSIUMM
2160
20"
2440
$CA
9380
N/A
ILIA
SCA
e &09
c 1.20
4125
SCA
5ELI:MIJM
10.6
c 2.40
< 2.50
SCA
SUN
a 115.3 ,
e 3.60
43.74
SCA
m
WZ�RY
2.11
< O.t 18
a 0.126
SCA
m0A
N.C. Labomemy M0 352 Ana*M 8y:
Lab Smmmmer: Mxhaul J. Lurid: EES-RObbin6ville Gerund Idy:

Al llr UAL AM 1 IVLJO r 1L' Lll LIJALl1r l7 0 U 1r1 v1A11 I r "IVIVI
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Town of Mars Hill WWTP Total Dry Tons Applied (Annual): 39.63
WQ0004298 Cation Exchange Capacity (non 503 only): 17.4
Robert M. Sams
14.5 Acres Permitted:
_ Owner: Larry Cody
14.5 Site #: 1 Field #: 1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
11
3
4
6
7
8j
9j
10
11
12
�a�
_5j
y
< d
a �• a
o
39.63
Arsenic
1 0
0
0
0
0
0
0.4034
' 0
0
0
0
0
0.4034
Cadmium
0
0
0
0
0
0
0.4034
0
0
0
0
0
0.4034
Chromium
0
0
0
0
0
0
1.3474
0
0
0
0
0
1.3474
Copper
0
0
0
0
0
0
17.834
0
0
0
0
0
17.834
Lead
0
0
0
0
0
0
1.9736
0
0
0
0
0
1.9736
Mercury
0
0
0
0
0
0
0.1672
0
0
0
0
0
0.1672
Molyb-
0
0
0
0
0
0
1.2127
0
0
0
0
0
1.2127
denum .
Nickel
0
0
0
1 0
0
0
1.2919
0
1 0
0
0
0
1.2919
Selenium
0
0
0
0
0
0
0.8402
0
0
0
0
0
10.8402
Zinc
0
0
0
0
0
0
54.135
0
0
0
0
0
54.135
Total
Phos-
0
0
0
0
0
0
959.05
0
0
0
0
0
959.05
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted., I am aware that there are significant penalties for submitting false information,
includin possibility of fines an •mprison ent for knowing violations"
o2 ? D
Signature of Land Applier ate
* See bottom of FSF Form for helpful instructions for this MFLSF Form and the mathematically linked FSF Form
DENR FORM MFLSF (5/2003)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD.
Facility Name:
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Town of Mars Hill
Owner: Larry Cody Operator:
Site #: 01 Field #: 01
Permit #: WQ0004298
Robert M. Sams
Acres Utilized: 14.5
Annual Dry Tons Applied: 39.63168
Cation Exchange Capacity (non 503): 17.4
Acres Permitted: 14.50
o
�,
o
A
:::I
Specify
Totals
Per
%
Solid
s
Dry Tons Per
Acre
Residual
Sources
(Summarize)
i e
Cond.
Dry,
Wet
Inches
Precip.
Past 24
Hrs.
Appli-
cation
Meth-
od*
Vola-
tili-.
zation
Rate**
Miner-
ali-
zation
Rate
TKN
Amino
nia-
Ni-
trogen
Ni-
trate
and
Nitrite
PAN 1
PAN 2
Must Select
Crop 1 or Crop
2
al.
Cu.Yd.
Report TotalsAcre
in Gal.
Crop 1
Crop 2
7/18/06
16,500
1137.9
19.2
0.911073103
Drying Bed Sludge
Dry
0
S
0.5
30%
19100
3910
373
12.5455
#######
Fescue
1
7/19/06
10,500
724.14
19.2
0.579773793
Drying Bed Sludge
Dry
0
S
0.5
30%
19100
3910
373
7.98349
#######
Fescue
2
7/20/06
6000
413.79
19.2
0.33129931
Drying Bed Sludge
Dry
0
S
0.5
30%
19100
1 3910
373
4.56199
#######
Fescue
3
7/25/06
4500
310.34
19.2
0.248474483
Drying Bed Sludge
Dry
0
S
0.5
30%
19100
1 3910
373
3.42149
#######
Fescue
-
4
8/1/06
4500
310.34
19.2
0.248474483
Drying Bed Sludge
Dry
0
S
0.5
30%
19100
1 3910
373
3.42149
########
Fescue.
5
8/2/06
3000
206.9
19.2
0.165649655
Drying Bed Sludge
Dry
0
S
0.5
30%
19100
3910
373
2.281
#######
Fescue
6
8/28/06
4500
310.34
0
19.2
0.248474483
0
Drying Bed Sludge
Dry
0
S
0.5
30%
19100
3910
373
3.42149
0
#######
0
Fescue
7
8
0
0
0
0
9
0
0
0
0
10
0
0
0
0
11
0
0
0
0
12
TOTALS:
3414
::::::::=::
As
Cd
Cr
Cu
Pb I
Hg
Mo 1
Ni
Se
Zn
P
PAN 1 I
PAN 2
Lime Applied
knnual lbs/acre
0.4034334
0.40343
1.34742
17.8335
1.97357
0.16724
1.21268
1.29194
0.84016
54.1346
959.046
37.6364
0
Date
lbs/ac
�urrent Cumulative lbs/ac
1.1927838 0.95778 2.81298 63.8969 7.0544 0.26295 3.86353 3.51483 2.27346 78.3662::::::::::::::::::::::::::::::::::::::::::::::::::::::
0.7893504 0.55435 1.46556 46.0634 5.08083 0.09571 2.65085 2.222891 1.4333 24.2316
36 34 nl 1338 267 15 1 nl 374 89 2498 .................
:.;.
'rior Years Cumulative lbs/ac
?ermitted C. P. L. R.***
"ermit PAN Limit 1 st/2n d Cro P
I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
lesigned to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant alties for submittin false information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
Signature of Lan Applier bate **Volatilization Rate: Surface - 0.5. Iniection/Incornoration -1.0
***C.P.L.R.: Cumulative Pollutant LoadinE Rate
* * The RSSF Data and the Dry Tons Per Acre are to be entered on the MFLSF Form. The FSF and MFLSF are mathematically linked so this information needs to be entered into
the same numbered column on the MFLSF as is entered on the identically numbered FSF row to properly complete the metals equations. ie. FSF row # 1 to MFLSF column # 1.
DENR FORM FSF (5/2003)

AININ UAL YIEIALN r1L+'1,L LUA INU NUNINLA-KY 1N' MW
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Town of Mars M11 WWTP Total Dry Tons Applied (Annual): 15.6
WQ0004298 Cation Exchange Capacity (non 503 only): 7.00
Robert M. Sams Owner: Larry Cody
3.8 Acres Permitted: 3.8 Site #: 1 Field #: 2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
0
1
2j
31
4 j
5j
6
7
8
9
10
11
12
� � w
y�
y
d
a
y
o �
15.6
Arsenic
0
0
0
0
0
0
0.1588
0
0
0
0
0
0.1588
Cadmium
0
0
0
0
0
0
0.1588
0
0
0
0
0
0.1588
Chromiurr
0
0
0
0
0
0
0.5304
0
0
0
0
0
0.5304
Copper
0
0
0
0
0
0
7.02
0
0
0
0
0
7.02
Lead
0
0
0
0
0
0
0.7769
0
0
0
0
0
0.7769
Mercury
0
0
0
0
0
0
0.0658
0
0
0
0
0
0.0658
Molyb-
0
0
0
0
0
0
0.4774
0
0
0
0
0
0.4774
denum
Nickel
0
0
0
0
0
0
0.5086
0
0
0
0
0
0.5086
Selenium
0
0
0
0
0
0
0.3307
0
0
0
0
0
0.3307
Zinc
0
0
0
0
0
0 1
21.31
0
0
0
0
0 1
21.31
Total
Phos-
0
0
0
0
0
0
377.52
0
0
0
0
0
377.52
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that the a are significant penalties for submitting false information,
includ pos ibility of fin and imp ' onment for knowing violations"
ignature of Land Applier Date
* See bottom of FSF Form for helpful instructions for this MFLSF Form and the mathematically linked FSF Form
DENR FORM MFLSF (5/2003)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD.
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name:
Owner:
Site #: 01
Larry Cody
Town of Mars Hill
Field #:
Operator:
01
Permit #: WQ0004298
Robert M. Sams
Acres Utilized: 3.8
Annual Dry Tons Applied: 15.61248
Cation Exchange Capacity (non 503): 13.1
Acres Permitted: 3.80
S. �
o
Specify
Totals
Per
Acre
I
%
Solid
s
Dry Tons Per
Acre
l
Residual
Sources
(Summarize)
Summarize
1 e
Cond.
Dry,
Wet,
Moist
Inches
Precip.
Past 24
Hrs.
Appli-
cation
Meth-
od*
Vola-
tili-
zation
Rate**
Miner-
ali-
zation
Rate
TKN
Ammo
nia-
Ni-
trogen
Ni-
trate
and
Nitrite
PAN 1
PAN 2
Must Select
Crop 1 or Crop
P P
2
*
*
Gal.
CuNd.
Report
Totals
in Gal.
Crop 1
Crop 2
7/13/06
6000
1578.9
19.2
1.264168421
Drying Bed Sludge
Dry
0
S
0.5
30%
19100
3910
373
17.4076
#######
fescue
1
7/17/06
13,500
3552.6
19.2
2.844378947
Drying Bed Sludge
Dry
0
S
0.5
30%
19100
3910
373
39.1671
#######
fescue
2
0
0
0
0
3
0
0
0
0
4
0
0
1
1 0
0
5
0
0
0
0
6
0
0
0
0
7
0
0
0
0
8
0
0
0
0
9
0
0
0
0
10
0
0
0
0
11
0
0
0
0
1
12
TOTALS:
5132
::""`*:: "
As
Cd
Cr
Cu
Pb
H
Mo
Ni
Se
Zn
P
PAN 1
PAN 2
Lime Applied
Annuallbs/acre
0.138808
0.15881
0.5304
7.02
0.77688
0.06583
0.47736
0.50856
0.33072
21.3096
377.52 156.5747
0
Date
Ibs/ac
Current Cumulative lbs/ac
0.380808 0.43831 1.5206 32.602 3.80088 0.13833 1.98586 1.66506 0.97762 37.0316 ::::::::::::::::::::::::::::
0.222 0.2795 0.9902 25.582 3.024 0.0725 1.5085 1.1565 0.6469 15.722
36 34 nl 1338 267 15 nl 374 89 2498
Prior Years Cumulative Ibs/ac
Permitted C. P. L. R.***
,Permit
mrt PAN Limit 't lst/2nd Crop
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant ppen�lties fo submitting f Ise inform tion, including the possibility of fines and imprisonment for knowing violations."
_Z 211 _-�/ 7 - *Application Method: S - Surface, IN - Injection, INC - Incorporation
Signature of Land Vpplier Date **Volatilization Rate: Surface - 0.5, Iniection/Incorvoration - 1.0
***C.P.L.R.: Cumulative Pollutant Loading Rate
* * * * The RSSF Data and the Dry Tons Per Acre are to be entered on the MFLSF Form. The FSF and MFLSF are mathematically linked so this information needs to be entered into
the same numbered column on the MFLSF as is entered on the identically numbered FSF row to properly complete the metals equations. ie. FSF row # 1 to MFLSF column # 1.
DENR FORM FSF (5/2003)

ANN UAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM
Facility Name: Town of Mars Hill Land Application Permit Number: WQ0004298
WWTP Name: Town of Mars Hill WWTP NPDES Number: NCO057151
Monitoring Period: From January 12006 To December 312006
Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed:
Class A:
Alternative 1 ❑
Alternative 2 ❑
Alternative 3 ❑
Alternative 40
Alternative 5 ❑
Alternative 6 ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost [3J
Heat Drying [3Heat
Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
Alternative 10
Alternative 2 T-F-7
Alternative 3 ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens'
Lime Stabilization ❑
Air Drying ❑
1 Composting ❑
Aerobic Digestion 0
Anaerobic Di g estion
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g tY
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
Analytical
Tech-nique
Minimum
Geo. Mean
Maximurr
Units
Fecal Coliform
2 x 10 to the 6th
power NTN per
gram of total
solids or 2 x 10 to
the 6th power
CFU per gram of
21,000
25,000
31,000
col./gram
0
1/year
grab
9222d
1000 mpn per
gram of total solid
(dry weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 NTN per 4
grams total solid
(dry weight)
Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed:
Option 1 ❑ Option 2 ❑ 1 Option 3 ❑ j0ption 4 0 Option 5 ❑
Option 6 ❑ Option 7 ❑Option 8 ❑ Option 9 ❑ Option 10 ❑
No vector attraction reduction options were performed
P p ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
0 "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
❑ " I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the
system designed to ensure that qualified personnel properly gather and evaluate the information
used to determine that the pathogen and vector attraction reduction requirements have been met. I
am aware that there are significant penalties for false certification including fine and imprisonment."
Robert M. Sams- Public Works Dir.
Prep e d Title (type r print)
Signature of Preparer to
Land Applier Name and Title (if applicable)(type or print)
Signature of Land Applier (if applicable) Date
DENR FORM RF (5/2003)

r,eQ I U( U(iAJI+ C4jr'br1 CIIVLI V11111�11Vvx a ——- — — — I-. -
EARTH ENVIRONMENTAL SERVICES
75 Bison Lane
Murphy, NC 28906
Residence — [phone]
Robbinsvillc Lab — [phone]
Marshall Lab [phone]
Shelby Lab — (704) 4492-5227'
E-Mail c_Irthcmscr!ri;�►cb�yorlcx_ccml\
February 12.2007
NC 1D#474, #352
Mr. Robot Sams
Town of Mars Hill
P.O. Box 368
Mars Hill; NC 28754
Dear Mr. Sams;
Following is a report of L•ubornory analyses for digMar sludge satnplcs,rceeived 7126/06.
ColonX founts
_1 n 1 ..a 0-0I m1
u
1
.$aln uc MIt
7/19106
Colri0ifil U°nsruc° wtwlly� ....•
25,000 Cdonies/Gw
,• ..- .. -
1.08°k
-
TNTC
27
3
2
720/06
27,000 Coltsnies/Grem
1.06%
TNTC
29
5
3
7111106
29,000 ColoniedGram
1'08%
TNTC
31
3
4
5
6
7=6
724106
7R5106
21,000 Cdonies/Gram
311 -- C*NedGram
22,000 Cdonies/Gtam
1.0796
1.06%
1.09%
TNTC
TNTC
TNTC
33
24
1
6
3.
7
7/,4M
25,000 Cokwdes/Gram
1.05%
TNTC
26
4
Geometric mean for all seven samples: 25.000 colonies/gram. 'Thank you for your
business. If you have any question or need additional sample analyses performed. please
can.
Respectfully submitted,
Michael J. Ladd
Laboratory Director
.o

ROBBINSVILLE LABORATORY EARTH ENVIRONMENTAL SERVICES
(828) 479,6428
PAAOISON COUNTY LA ORATORY AVCHAEL LADD-OWNER
(M) 649-9250 rNmawl
P.O, BOX 1177 75 BISON LANE
RESMENCE [phone] MARSHALL, NC 28753 NURPHY. NC2M
Address: !3 9
1r—Ct
Phone. c.��ti � � / L
Re rod To: (' �' z `�.e Y)
8ill To: r Lf-yi It
P.O.'J BiJng Relwarce_
Project Name 1 ND: —
CHAIN -OF -CUSTODY RECORD
Analocal Request
EES Cie:nt No.:
E ES Project Idarager: —. .
Et:S Proect No.
'Requestd Du=• Date:
Samp'e {p'rt}: yin PRESERVATIVES
ANALYSES �
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IrA Lab Temp:
Rec Lab Tenip:
SEE REVERSE SIDE FOR INSTRUCTIONS

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Time
(minutes)
0
1
2
3
4
5
6
7
a
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name:
Blosolids Permit Number.
Date:
Digester Temperature:
Sampling Dale/Time-
Sampled By:
Analysis Date/Time:
Analyzed By:
Sample Volume:
Total Solids:
Beginning Temperature:
End Temperature:
Dissolved Oxygen Level
5.121
1
13:3
Dry Solids
grees Celsius
ones Celsius
Slope: 0.1
Intercept: 6.3
Correlation Coefficient: 1.0
Oxygen Uptake Rate: 5.01 mg Oxygen/hr
Ambient Specific Oxygen Uptake Rate: 0.96 mg Oxygen/g/hr
Average Temperature: 14 degrees Celsius
Temperature Correction Factor. 1.500730352
Temperature Corrected Specific Oxygen Uptake Rate: 1.43 mg Oxygen/g/hr
Instructions: Enter Data in the Blue .Boxes. The Calculation and the Spreadsheet execute automatically.

reu.lc ur u r i JcP Gar Ln mnvlrunmenrei ovo5 1-aca-aOr-aaRJ
Time
(minutes)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name:
Siosolids Permit Number:
Date:
Digester Temperature:
Sampling Date/Time:
Sampled By:
Analysis Date/Time:
Analyzed By:
Sample Volume:
Total Solids:
Beginning Temperature:
End Temperature:
Dissolved Oxygen Level
5.511
5.131
4.82
4.75
4.3
4.09
14
12:25
12:25
1
1000 milliliters
0.59 % Dry Solids
14.1 [degrees Celsius
141degrees Celsius
Slope: 0.1
Intercept: 5.8
Correlation Coefficient: 1.0
Oxygen Uptake Rate: 6.85 mg Oxygen/hr
Ambient Specific Oxygen Uptake Rate: 1.16 mg Oxygen/g/hr
Average Temperature: 14 degrees Celsius
Temperature Correction Factor. 1.500730352
Temperature Corrected Specific Oxygen Uptake Rate::; 1.74-mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

Time
rminuites►
0
1
2
3
4
5
B
T
i3
9
10
11
12
13
14
15
specific Oxygen Uptake Rate
SOUR
Facility Nnmc:
Biosoiids Permit Number,
Date
Digester Temperature:
Sampling Daterrime:
Sampled By.
Analysis Date/Time
Analyzed By
Sample Volume
Total Solids
Beginning Temperature
End Temperature
Dissolved Oxygen Level
7.
4.
4.
MArF. Hill
W0004298
14-Dec
11.9
12/14/2006 11:40
Michael Ladd
12/14/2006 11:40
Michael Ladd
1000
0.6
11.9
11.4
nilliliters
!6 Dry Solids
degrees Celsius
degrees Celsius
Slope: 0.2
IMercept: 7.4
Correlation Coefficient: 1.0
Oxygen Uptake Rate: 13.74 mg oxygen/hr
Ambient Spec Oxygen Uptake Rate: 2.29 mg Oxygen/g/hr
Average Temperature: 12 degrees Celsius
Temperature Correction Factor: 1.71818618
Temperature Corrected Specific Oxygen Uptake Elate:: 3.94 :mg Oxygen/g/hr
Instructions: Enter Oata in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

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F.'t
Time
(minutes)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name:
Siosolids Permit Number.
Date:
Digester Temperature:
Sampling Datetrime:
Sampled By:
Analysis Date/Time:
Analyzed By:
Sample Volume:
Total Solids:
Beginning Temperature:
End Temperature:
Dissolved Oxygen Level
7
6.181
1
Dry Solids
Arees Celsius
arees Celsius
Slope: 0.2
Intercept: 7.6
Correlation Coefficient: 1.0
Oxygen Uptake Rate: 11.15 mg Oxygen/hr
Ambient Specific Oxygen Uptake Rate: 1.86 mg Oxygen/g/hr
Average Temperature: 11 degrees Celsius
Temperature Correction Factor. 1.838459212
Temperature Corrected Specific Oxygen Uptake Rate: ; 3.42;'mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

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Time
(minutes(
0
1
2
3
4
5
6
7
a
9
10
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name:
Siosolids Permit Number:
Date:
Digester Temperature.
Sampling Date/Time:
Sampled By:!
Analysis Date/Time:
Analyzed By:
Sample Volume:
Total Solids:
Beginning Temperature:
End Temperature:
Dissolved Oxygen Level
7.391
Dry Solids
grees Celsius
(frees Celsius
Slope: 0.1
Intercept: 8.5
Correlation CoeffiCier±t: 1.0
Oxygen Uptake Rate: 6.25 mg Oxygen/hr
Ambient Specific Oxygen Uptake Rate: 1.12 mg Oxygen/g/hr
Average Temperature: 14 degrees Celsius
Temperature Correction Factor. 1.500730352
Temperature Corrected Specific Oxygen uptake Ra?e:i 9�5�. mg oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

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Specific Oxygen Uptake Rate
SOUR
Facility Name:
Mars h
Biosolids Permit Number;
000
Date:
Digester Temperature:
Sampling DateMme:
12/21
Sampled By:
Mich8l
Analysis Datefrime:
12/21
Analyzed By:
Michas
Sample Volume:
Total Solids:
Beginning Temperature:
End Temperature:
Time
Dissolved Oxygen Level
(minuses)
mall)
0
7.56
1
7.4
2
7.35
3
71
MEIN
4
7.11
5
7.02
6
6.80
7
6.'6
$
6.7
g
6,58
10
11
1 v.
:2
- 27
14
v®.131
0.071
5,50
1
q
ilnnters
Dry Solids
egrees Celsius
e0rees Celsius
-9 y
loryg6r! '-irga€e Rate: 0 q? I ;gig f`WYga,,/IIr
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Average Ter, perature: 13 degrees r:Ielanus
r3rnpo at° ri;' iy e. Cme.fbp- 1 6057s3"76
e =� -
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Specific Oxygen Uptake Rate
$OUR
Facility Name:
Biowlids Permit Number:
Date:
Digester Temperature:
Sampling Date/Time:
Sampled By:
Analysis OatelTime
Analyzed BY
Sample Valuate
ict�,l SelldS
{:=_lili:iii43=a Tioiaq iuie:
E4M01
98
28-Dec
12.3
12/28/2005 12:15
Michael Ladd
12/28/200612:15
Michael Ladd
1000 milliliters
0.59 % Dry Solids
12.3 egrees Celsius
C. ; ;;ape atcre: 12.1 degrees Celsius
_ 4 .
�py ee CY74 OYe C'CS9're-ii Fr' tor:
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_;;n.auai Report Revietiv SLAY
1'.. Annual Land Application Ceriiiication Form
• Was a certification form submitted? '` e')
• Was land application conducted during the reported year? —kt'5
• How many dry tons and dry tons per acre were applied? 3• ®'
• Were the applications within the permitted mount? `�e`�
• Verify PAN if more than 10 tons/acre JAI
• Did it indicate compliance? -V5
• Was it signed by the appropriate people?
1a.Qto
2. Monitoring .
• Were the analyses conducted at the requiredfrequency?P`�
• Were the metals analyses reportedton the Residual Sampling Summary Form? '�t9
• Were the results reported in mg/kg? yes
•: Were the heavy metals within ceiling concentrationpermit limits?* ' O
• If no, were the lab analyses attached? Nkj(A
• Were all the required parameters tested? $5
• Was TCLP analysis conducted? V46 , w�.s . e, �ti,� irn
3. Field Summary
• Were the land applicationevents recorded on the Field Summary Forms? `le.>
• Was a Field SummaryForm submitted for each field?
• Were all the residuals applied to permitted land? vg S
• Were all the residuals applied from permitted sources?
• Were the field loading rates for each metal and PAN calculated (year to date)? � eS
• Were the cumulative pollutant loading rates calculated? idS
• Were the calculations correct? �C5 _
• Were the PAN Ioading rates. within permit limits? `DES
• Were the heavy metal cumulative pollutant loading rates within permit limits? pit 5
• Were the residuals applied on a suitable crop? Ile S
• Were the applications conducted during the cro 's growing season? pit s
• Were the Field Summary Forms complete? �t )
4. Pathogen and Vector Attraction Reduction
• Was a signed copy of the Pathogen and Vector Attraction Reduction Form submitted? y CS
• Did the form indicate the period of coverage, the residual class, and the pathogen reduction alternative and the
vector attraction reduction option used? `l 6
.
Was the appropriate documentation to show pathogen and vector attraction reduction included in the report?
• Was pathogen and vector attraction reduction demonstrated according to 40 CFR Part 503'? L3�
5. Soil 'Tests
•. 'Was a Standard Soil Fertility Analysis conducted for each application field? N 0
• Were the soil pH's 6.0 or greater for each application field?
• Were the copper and zinc indexes in the soil less than 3000 for each application field?
6. General
• Was the report in the proper format? Acs
• Were any parts of the annual report missing?
• Was the report submitted on time? Ae5
* Any violations of ceiling concentrations should be reported to Pretreatment for municipalities only.