WQ0004298_2004 Residuals Annual Report_20050214

:T
ANNUAL LAND APPLICATION CERTIFICATION FORM �� �° 106'
ljermit#: County: Ind (� adn►-E "�'! ty: _ o.c�; r, Year:
Facility Name as shown on permit): lowN �r �� i I
Land Application Operator �ob e M. 1 { -
Land application of residual solids as allowed by the permit occurred during the past calendar 6 �q + 9 `� �C�
[� Yes 0 No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were
generated but not land applied, please attach an explanation on how the residuals were h
Part A:
Total number of app
Total number of fields land application of
Total amount of dry tons applied during the year
Total number of acres land annlica+in„ „,,
Part B:
fields in p
reu uurmg the year: L all application sites:
red during the year:
r-----------
Facility was compliant duringcalendar "
year
Y � (gyp y with all conditions of the land a0yeation pert
(including but not limited to items 1-12 below) issued by the Division of Water Quality. i"
. Irq Yes ,..__ ❑:
If no please, provide a written description why the facility was not compliant, the dates, and explain_
corrective action taken. ~-~
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at
least 6.0 or the limit specified in the permit.
3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three
(3) copies of laboratory results are attached.
Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached.
All other monitoring was performed in accordance with the permit and reported during the year as required
and three (3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements in 40 CFR Part 503.12'and management practices in 40 CFR Part 503.14 were
complied with (applicable to 40 CFR Part 503.regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Quality.
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed
in accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as specified on the permit were maintained during each application of residuals.
"I certify, under penalty of Jaw, that the above information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and ifflp violations."
i �'%�� (iand" ef-FEB - 7 2005
mitte Name and Title (type or prin WATER QUALITY SECTIONSigna e of Permittee
Non -Discharge � T
Ent
S' tur f
Date
igna e o Preparer Date Signiture of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part rin.q a t,% DENR FORM ACF (7/2002)

ANNUAL DISTRIBUTION AND MARKETING/ SURFA DISPOSAL CERTIFICATION AND SUMMA
PERMIT #: ( SOU() `f �q � FACILITY NAME: RY FOl
PHONE: C�d2 i�F,�°I-q$r� COUNTY: ow �� rR,rs F� LA
FACILITY TYPE (please check one):
��� So OPERATOR:
'rR, Sovr,
0 Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only;
I7 Distribution and Marketing (complete Parts A, B, and C)
Was the facility in operation during the past calendar year? Yes
Part A*: ONO No If No skip parts A, B, C and certify for
Month Sources(s) (include NPDES # if
applicable)
ianuary
eb ur ary
March
�pri
Ray
une
ul-__
.ugu-- t
ept me ber
Ictober
ovember
ece ber
SIN�� Ncoo 5 7 1 51
olume
Bulking Agent I Residual In I Product Out I Name(s)
LON
tons)
v • .
and Part C)
below
e
Intended
* If more space than q p 15UMng Agents use
P given is required, lease attach additional information sheets . Part C: () [] I Check box if additional sheets) are attached
Facility was compliant during calendar year O04 with all conditions of the permit (including but not limited
Division of Water Quality. j� Yes to items 1-3 below) issued by the
[] No If No, please provide a written description why the facility was not compliant.
All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified
'. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorizatio laboratory results are attached.
Quality. n was received from the Division of Water
No contravention of Ground Water Quality Standards occurred at a monitoring well.
I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true accurate
:hat there are signif nt penalties for submitting false informaiton, includ' the ossibility fines and imprisonment
complete. I am aware
P nt for knOwing,violations."
ignature Permittee Date qDe
Signature ofPrepare
(if different from Permittee) * *PTeparer is defined in 40 CFR Part'503.9(r)
DENR FORM DMSDF (7/9nng)

r
cad Envonmenfal Se is
Michael Ladd
75 Bison Lane
Murphy, NC 28906
Robbinsville Lab [phone]
Madison County Lab [phone]
Residence [phone]
plzvp Q
FEe � 7 2005
NWATER QUAL17-Y
on,.N a , SECTION
°w'im►c ,6,f
Name and Address of Facility.
Date: 9/13/2004
Town of Mars Hill WWTP
Sample Collector: RS
P.O. Box 368
Data and Time Sample Received: 7/20/2004 11.30 AM
Mars Hill, NC 28754
Date and Time Sample Collected: 7/15 & 20/04
Aft: Robert Sams
Date and Time Sample Analyzed: < MHT
Land Application Analyses - Note: All results in
mg/Kg Dry Basis unless otherwise noted.
Test
Dry Bed Sludge
Soil Site #1
Sal Sfte #2
Report Limit
Method
Units
ACIDITY
0.0 meq/100g
0.0 me /10%
2.0
SM5210B
mg/L
TOTAL SUSPENDED RESIDUE
M2540D
mg/L
CATION EXCHANGE CAPACITY
10.1 meq/100g
10.3 meq/100g
1
SM9222D
per 100ml
PH
7.3
7.0
7.0
0-14
SM4500H+
units
AMMONIA NITROGEN
903
0.5
SM4500NH3F
m
NO2 + NO3-n
< 1.0
1.0
SM55208
mg/L
TOTAL KJELDAHL NITROGEN
3340
SCA
mg/L
TAL PHOSPHOROUS
1710
1 30
81
SCA
mg/L
PERCENT TOTAL RESIDUE
9.36%
86.0%
84.1%
1.0
SM2540B
mg/L
HUMIC MATTER
3.2°k-
3.6%
1.0
SM2130B
NTU
% BASE SATURATION - K
5.9%
6.7%
1.0
SM2540C
mg/L
- H
0.0%
0.0%
.Mg
27.1%
24.2%
-Ca
66.7%
68.9%
-Na
0.3%
0.3%
k Arvr AVAILABLE (surface)
1182.6
10
SM2510B
umhos/cm
NITROGEN- PPM DRY WT (subsurf)
1634.1
0.1
SM4500CIG
mg/L
TEMPERATURE
SM2550B
deg C
MIXED LIQUOR SUPSPENDED SOLIDS
1.0
NIA
mg/L
MAGNESIUM
3710
329
299
SCA
mg/L
SODIUM
< 633
185
< 58.0
SCA
mg/L
CADMIUM
410.7
< 1.14
< 1.17
SCA
m
CHROMIUM
18.2
44.1
39.0
WA
mg/L
COPPER
298
33.6
52.1
SCA
mg/L
LEAD
36.2
15.7
10.7
SCA
mg/L
NICKEL
19.2
14.5
< 1.17
SCA
mg/L
ZINC
734
71.7
65.3
SCA
mg/L
CALCIUM
12400
3570
6240
SCA
mg/L
POTASSIUM
2830
3670
719
SCA
mg/L
ALUMINUM
24.6
N/A
N/A
SCA
mg/L
ARSENIC
< 10.7
3.17
2.32
SCA
mg/L
SELENIUM
< 21.4
2.72
< 2.32
SCA
mg/L
MOLYBDENUM
< 10.7
< 1.14
41.17
SCA
m91L
MERCURY
2.90
< 0.113
< 0.118
SCA
mg/L
N.C. Laboratory ID# 352 Analyzed By: IA
Lab Supervisor: Michael J. Ladd; EES-Robbinsville Certified W.

N17/22/1996 14:57
�f
7042516452
PAGE 01s f
WATER QUAU7YSECTION I/ �� C � �.
Non=Discharge compliance Enf, °J3
C . plant Available Nitrogen (PAN) calculations and land application area requirements:
CONS7PY'i TENTS
M . DRY WEIGHT
TKN
FN
3 2
ONiA-N
@ 3
03-NO2-N
C 1,
1. Mineralization Rate (MR)
(These values -can be established for the specific residual or default values can be used for dotncsdc wastewater treatment
residuals. if actual value's are established, attach the docua=Won. 7U default values are as follows):
Unstabilized Primary and Secondary Residuals 40%
Ambically Digested Residuals 30%
Atu mbically Digested Residuals 20%
Composted Residuals 10%
(If the default values are used, attach an explanation as to why the specific chosen default value is appropriate.)
2. Complete the following calculations for the application method proposed (Please dote, the lldineralization
Rate [MR] should be utilized in the following calculations as a.decimal):
PAN for Surface Application
PAN = [(MR) x (MN - NH3)] + .5 x (NH3) + (1403-NO2-N)
PAN=( t 3t x( 3 - 923 )1+.5x( 0 )+ /,I.fz
PAN = PPM Dry Weight
PAN for Subsurface Application
PAN - ((MR)x(TKN - NH3)l + (NH3) + (NO3-NO2-N)
PAN=l 13 83 �+ 41,0
i
PAN - b; 4, PPM Dry Weight
3. Total PAN to be land mlied Der veer

Total PAN in pounds (PAN in mg/ky,1hv Weightl x 2= Pounds / In
per dry tun 1,000,O00 _
r;,.1. .• Syr,.. ..y . Y.i �.. "� � "^N" - -�
_ Poundwth7 Tow-ftar
Total PAN in pounds = (PAN in founds / Dry Ton) x Total tons of residual to be land applied
0 x
Pounds/Yew
- 1
Due to the fact that organic nitrogen is mineralized slowly over time. the amount of nitrogen that comes availabletyem.,
following the initial application;must be taken into consideration when calculating application rates for the subsequent
)fears. This being the case, please attach an evaluation of this factor and its impact on loading rates. ShWt6j'usted pan
for at least five years.
The maximum adjusted annual PAN is Pounds/Year.
FORM: LA,RS 06194
Page 12 ,of 19
IREEFI V®
FEB - 7 Coos
WATER CUAM SECTnON
*n-Discharge Comb IAce Enf.

07/22/1996 14:57 7042516452
4. Crop information on nitrogen uptake per year .,
PAGE 02
(Division
Crop(s) PAN
Recommendations) (Provide for the Crops. Specified)
(lbs.Jacre/year) PAN (lbsdacre/year)
Alfalfa :
200
Bermuda Crass (Hay, Pasture)
220
Blue Grass
120 3
Corn (Grant)
160 —
Corti (Silage)
200
Cotton
70
Fescue
250
Forest (Hardwood & Softwood)
75
Milo
too RECEIVED
Small Grain (Wheat, barley, oats)
too FEE91-
Sorghum, Sudex (Pasture)
180 005
Sorghum, Sudex (Silage)
220 WATER QUA1ja RirsT;QAj
Soybeans
200 1vOn-u1scharge Compicnce Enf.
Timothy, Orchard, & Rye Grass
200
Please provide the basis for the uptake rates used U different than Division Recommendations:
5. Total acres needed to land apply the pounds of available nitrogen calculated above
Total am nceded: s Maxinum-wULpaunds gf pbot Uailable aiM n (PAS
Pounds of nitrogen needed for crop*
Minimum acres needed based on most restrictive PAN acres
o This value must be the value for the crop to be -grown that has the lowest nitrogen uptake rate per acre.
If there are various crops that will only be utilized for certain sites, please attach the calculations for each site and dew AWne
the total nee4ed acres wing the fog outlined above.
ID Calculate the Sodium Adsorption Ratio (SAR)
('"*This section must be completed in mg/1, to convert: mg/kg x % solids [as a decimal] = mg/l**)
SAR = Na Milli Equivalent + [0.5 (Ca Milli Equivalent + Mg Milli Equivalent)) 0.5
CONCENTRATION (mg/l) + Equivalent Weight = Milli Equivalents of Ion
SODIUM (Na) - (mgA) + 23
CALCIUM (Ca) (mg/1) + 20
MAGNESIUM (Mg) (mg/Q + 12
SAR =
FORM: LARS 0"4 Page 13 of 18

tAmerica
ANALYTICAL TESTING CORPORATION
2960 FOSTER CREIOHTON DRIVE * NASHVILLE, TENNESSEE 37204
800-765-0980 *'615-726-3404 FAX
ANALYTICAL REPORT
TESTAMERICA-ASHEVILLE
DINAH TRAMMEL
122 LYMAN STREET -
ASHEVILLE, NC 28801
5781 p.11%C0
�J ALab Number: 04-A112342 C Sample ID: EES# 0X0430 7/15/04
g( Sample Type: Soil
5 Site ID:
Date Collected: 7/15/04
Project:
Project Name: EARTH ENVIRONMENTAL SVCS
Sampler:
Time Collected: -
Date Received: 7/22/04
Time Received: 8:10
Page: 1
Report
Dil
Analyte
--------------------------
Result
-----------
Units
------
Limit
------
Factor
------
Date
--------
Time
-----
Analyst
----------
Method
---------
Batch
-----
*METALS*
Arsenic
ND
mg/kg
10.7
1
7/26/04
10:06
C.Johnson
6010E
2969
Cadmium
NO
mg/kg
10.7
1
7/26/04
1Q:06
C.Johnson
6010B
2969
Calcium
12400
mg/kg
533.
1
7/26/04
10:06
C.Johnson
6010B
2969
Chromium
18.2
mg/kg
10.7
1
7/26/04
10:06
C.Johnson
6010E
2969
Copper
298.
mg/kg
10.7
1
7/26/04
10:06
C.Johnson
6010B
2969
Lead
36.2
mg/kg
10.7
1
7/26/04
10:06
C.Johnson
6010E
2969
Magnesium
3720
mg/kg
533.
1
7/26/04
10:06
C.Johnson
6010E
2969
Mercury
2.90
mg/kg
1.05
1
7/23/04
14:06
K. Keller
7471A
2913
Molybdenum
ND
mg/kg
10.7
1
7/26/04
10.06
C.Johnson
6010E
2969
Nickel
19.2
mg/kg
10.7
1
7/26/04
10:06
C.Johnson
6010E
2969
Potassium
2630
mg/kg
533.
1
7/26/04
10:06.
C.Johnson
6010B
2969
Selenium
ND
mg/kg
21.4
1
7/26/04
10:06
C.Johnson
6010B.
2969
Silver
24.6
mg/kg
10.7
1
7/26/04
10:06
C.Johnson
6010B
2969
Sodium
ND
mg./kg
533.
1
7/26/04
10:06
C.Johnson
6010B
2969
Zinc
734.
mg/kg
107.
1
7/26/04
10.06
C.Johnson
6010B
2969
*GENERAL CHEMISTRY
PARAMETERS*
PR
7.30
pH units
7/23/04
11:20
B.Minor
9045
2137
o Dry Weight
9.36
7/22/04
12:14
B.Plett
CLP
2193
Nitrite-N as N
ND
mg/kg
1.0
1
7/26/04.
11500
S. Overton
9056
4798
Nitrate-N as N
ND
mg/kg
1.00
1
7/26/04
11:00
S. Overton
9056
4798
Ammonia Nitrogen as
N 903.
mg/kg
10.0
10
7/28/04
14:27
K.Saiyasak
350.1M
3777
Phosphorus as P
1710
mg/kg
50.0
5
7/27/04
9:47
K.Saiyasak
365.4'M
2992
Kjeldahl Nitrogen as N 3340
mg/kg
100.
10
7/26/04
14:53
K.Saiyasak
SM450ONC
2994
Sample report continued . . .
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e
Test merlca
ANALYTICAL TESTING CORPORATION
2960 FOSTER CREIGHTON DRIVE NASHVILLE, 7'ENNESSEC 37264
800-765-0980 • 615-726-3404 FAx
ANALYTICAL REPORT
Laboratory Number: 04-A112342 V-
Sample ID: .EES#-020430'7%1-'FtO-4
Project:
Page 2
LABORATORY COMMENTS:
ND .= Not detected at the report limit.
B = Analyte was detected in the method blank.
J = Estimated Value below Report Limit.
E = Estimated Value above the calibration limit of the instrument.
# = Recovery outside Laboratory historical or method prescribed limits.
All reported results for metals or Organic analyses have been corrected for dry weight.
�,u of Sample Report.
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TestAmerica
ANALYTICAL TESTING CORPORATION
2960 FOSTER CREIGHTON DRIVE • NASHVILLE, TENNESSEE 37204
800-765-0980 615-726-3404
FAx
ANALYTICAL REPORT
TESTAMERICA-ASHEVILLE 5781Lab
Number:
04-A112344
DINAH TRAMMEL
(�, L'
Sample ID: EES#-0X0432
7/20/04
122 LYMAN STREET
�-�a ;';�Q Z
Sample Type:
Soi17
ASHEVILLE, NC 28801
51�!
Site ID:
�1
Date Collected:
7/20/04
Project:
Time Collected:
Project Name: EARTH ENVIRONMENTAL SVCS
Date Received:
7/22/04
Sampler:
Time Received:
-8:10
Page: 1
Report Dil
Analyte Result
Units Limit Factor Date Time
Analyst Method
Batch
*METALS*
Arsenic 2.32
mg/kg 1.17 1
7/26/04 10:06
C.Johnson 6010B
2969
Cadmium ND
mg/kg 1.17 i
7/26/04 10:06
C.Johnson .6010E
2969
Calcium 6240
mg/kg 58.0 1
7/25/04 10:06
C.Johnson 6010B
2969
Chromium 39.0
mg/kg 1.17 1
7/26/04 10:06
C.Johnson 6010E
2969
Copper 52.1
mg/kg 1.17 1
7/26/04 10:06
C.Johnson 6010B
2969
Lead 10.7
mg/kg 1.17 1.
7/26/04 10:06
C.Johnson 6010E
2969
Mercury ND
mg/kg 0.118 1
7/26/04 8:46
K. Keller 7471A
4098
Molybdenum ND
mg/kg 1.17 1
7/26/04 10:06
C.Johnson _ 6010B
2969
Nickel 9.52
mg/kg 1.17 1
7/26/04 10:06
C.Johnson 6010E
-2969
Potassium 719.
mg/kg 58.0 1
7/26/04 10:06
C.Johnson 6010B
2969
Selenium ND
mg/kg 2.32 1
7/26/04 10:06
C.Johnsan 6010B
2969
Silver ND
mg/kg 1.17 1
7/26/04 10:06
C.Johnson 6010B
2969
Sodium ND
mg/kg 58.0 1
7/26/04 10:06
C.Johnson 6010B
2969
Zinc 65.3
mg/kg 11.6 1
7/26/04 10:06
C.Johnson 60loB
2969
*GENERAL CHEMISTRY PARAMETERS*
PH 7.00
pH units
7/23/04 11:20
B.Minor 9045
2137
k Dry weight 84.1
1
7/22/04 12:14
B.Plett CLP
2193
Sample report continued . .
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TinstAmerica
ANALYTICAL TESTING CORPORATION
2960 FOSTER CREIOHTON DRIVE • NASIMUE, TENNESSEE 37204
800-765-0980 615-726-3404 FAX
MALYTTCAL REPORT
Laboratory Number: 04-A112344
Sample ID: EES#-020432 7204
Project:
Page 2
LABORATORY COMMENTS-
ND = Not detected at the report limit.
B = Analyte was detected in the method blank.
J = Estimated Value below Report Limit.
E = Estimated Value"above the calibration limit of the instrument.
# = Recovery outside Laboratory historical or method prescribed limits.
All reported results for metals or Organic analyses have been corrected for dry weight.
znd of Sample Report.
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bstAmerica
ANALYTICAL TESTING CORPORATION
2960 POSTER CREIGHTON DRIVE • NASHVILLE, TENNESSEE 37204
800-765-0980 615-726-3404 FAX
ANALYTICAL REPORT
TESTAMERICA-ASHEVILLE 5781 S • Lab Number- 04-A112344
DINAR TRAMMEL L'� Sample ID:EES#-0X0432 7/20/04
122 LYMAN STREET -�a "'�l p2 Sample Type: Soil7
ASHEVILLE, NC 28801 S� Site ID:
Date Collected: 7/20/04
Project: Time Collected:
Project Name: EARTH ENVIRONMENTAL SVCS Date Received: 7/22/04
Sampler: Time Received: -8:10
Page: 1
Report
Dil
Analyte
-------------------------
Result
-----------
Units
-----^
Limit
------
Factor
------
Date
--------
Time
-----
Analyst
-----------
Method
---------
Batch
-----
+METALS•
Arsenic
2.32
mg/kg
1.17
1
7/26/04
10:06
C.Johnson
6010B
2969
Cadmium
ND
mg/kg
1.17
1
7/26/04
10:06
C.Johnson
.6010B
2969
Calcium
6240
mg/kg
58.0
1
7/26/04
10:06
C.Johnson
6010E
2969
Chromium
39.0
mg/kg
1.17
1
7/26/04
10:06
C.Johnson
6030E
2969
Copper
52.1
mg/kg
1.17
1
7/26/04
10:06
C.Johnson
6030B
2969
Lead
10.7
mg/kg
1.17
1
7/26/04
10:06
C.Johnson
6010E
2969
Mercury
ND
mg/kg
0.118
1
7/26/04
8:46
K. Keller
7471A
4098
Molybdenum
ND
mg/kg
1.17
1
7/26/04
10:06
C.Johnson
6010B
2969
Nickel
9.52
mg/kg
1.17
1
7/26/04
10:06
C.Johnson
6010E
2969
Potassium
719.
mg/kg
58.0
1
7/26/04
10:06
C.Johnson
6010B
'2969
Selenium
ND
mg/kg
2.32
1
7/26/04
10:06
C.Johnson
6010E
2969
Silver
ND
mg/kg
1.17
1
7/26/04
10:06
C.Johnson
6010E
2969
Sodium
ND
mg/kg
58.0
1
7/26/04
10:06
C.Johnson
601'OB
2969
Zinc
65.3
mg/kg
11.6
1
7/26/04
10:06
C.Johnson
60108
2969
*GENERAL CHEMISTRY
PARAMETERS*
'
PH
7.00
pH units
7/23/04
11:20
B.Minor
9045
2137
k Dry Weight
84.1
'
7/22/04
12:14
. B.Plett
CLP
2193
Sample report continued . . .
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TestAmerica
ANALYTICAL TESTING CORPORATION
2960 FOSTER CREWNTON DRin • NASHVILLS, TENNFSSEE 37204
800-765-0980 615'-726-3404 FAX
.ANALYTICAL REPORT
Laboratory Number: 04-A112344 j
Sample ID: EES#-020432 T/,20iq&"
Project:
Page 2
LABORATORY COMMENTS:
ND = Not detected at the report limit.
B = Analyte was detected in the method blank.
J = Estimated Value below Report Limit.
E = Estimated Value above the calibration limit of the instrument.
# = Recovery outside Laboratory historical or method prescribed limits.
All reported results for metals or Organic analyses have been corrected for dry weight.
End of Sample Report.
www.lestamericainc.com
T..-.A—....__ n-_I...e__.1 T.

RT NUMBER -
A&L EASTERN AGRICULTURAL LABORATORIES, INC.
R217-040 7621 Whitepine Road • Richmond, Virginia 23237 a [phone]
ACCT * 4622o Fax No. [phone] • Email: [e-mail] -, M1031 LA
SEND
TO: EARTH ENVIRONMENTAL SVCS
75 BISON LN
MURPHY NC 28906
GROWER: SAMPLES
EARTH ENV SVCS SUBMITTED EARTH ENVIRONMENTAL SVCS
BY:
SOIL ANALYSIS REPORT ANALYTICAL METHOD:
1 08/03/2004 08/04/2004 08/05/2004 AMMONIUM ACETATE, BRAY-P
PAGE DATE RECEIVED DATE OF ANALYSIS DATE OF REPORT
ORGANIC MATTER
PHOSPHORUS
POTASSIUM
MAGNESIUM
CALCIUM
SODIUM
PH
ACIDITY
C.E.C.
SAMPLE
NUMBER
LAB
NUMBER
%ENR
AVAILABLE
RESERVE
K
MG
CA
NA
SOIL
BUFFER
H
Ibs/A
ppm RATE
ppm RATE
ppm RATE.
ppm
RATE
ppm RATE
ppm RATE
pH
INDEX
meq/100g
meq/100g
070A31.
06704
3.2 100M
30H
61VH
232VH
329VH
1350M
8VL
7.2
0.0
10.1
070A32
06705
3.6 107M
70VH
112VH
269VH
299VH
1420H
6VL
7.0
0.0
10.3
PERCENT BASE SATURATION
NITRATE
SULFUR
ZINC
MANGANESE
IRON
- COPPER
BORON
SOLUBLE
CHLORIDE
ALUMINUM
SAMPLE
K
Mg
Ca
Na
H
NO, N
SO4-S
ZN
MN
FE
CU
B
SALTS
CL
AL
ms/cm RATE
NUMBER
/,
%
%
%
%
ppm RATE
:ppm RATE
ppm RATE
ppm RATE
ppm RATE
ppm RATE
ppm RATE
ppm RATE
ppm RATE
070A31
5.9
27.1
66.7
0.3
0.0
070A32
6.7
24.2
68.9
0.3
0.0
Values on this report represent the plant available nutrients in the soil.
Rating after each value: VL (Very Low), L (Low), M (Medium), H (High), VH (Very High).
ENR - Estimated Nitrogen Release. C.E.C. - Cation Exchange Capacity.
Explanation of symbols: % (percent), ppm (parts per million), Ibs/A (pounds per acre),
ms/cm (milli -mhos per centimeter), meq/100g (milli -equivalent per 100 grams).
(.nnvorcinnc• nnm v 9 — the/A qnh ihIP ..qgItz me/r m y Adn - nnm Spp the hark of thic rpnnrt fnr mnrp datailerl infnrmatinn_
This report applies to the sample(s) tested. Samples are retained a
maximum of thirty days after testing. Soil Analysis prepared by:
A & L EASTERN AGRICULTURAL LABORATORIES, INC. _
/7
i
by
Ll I\Inrmnn .Innpc

ANNUAL RESIDUAL S_%:-,,JLING SUMMARY FORM -
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: (,� Q, Q 0 rJ 4 '� 9 Laboratory: 1) V
Facility Name: w. � �� �o.� 5 ��� � 2) A Yyve r ; co,.
NPDES # or 3)
WQ#: NC0o571Si
4)
WWTP Name: I puJw1 1���-s 1� l 5)
Recirinnl Annlvcic Data
Sample• Composite Date
--
Percent Solids
IVA
_All®�_---_S--_
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer Da e
_ DENR FORM RSSF (7/2002)

ANNUAL LAND APPLICATIOf .___ ELD SUMMARY FORM _
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: c) W y) 0�, H ; Permit #: G)a 000 4 a9 � Annual Dry Tons Applied:
Owner: LA,,-y �o�v Operator: ob ��-� ;(,� 50.r� Cation Exchange Capacity (non 503):
m,e_t
Site #: 01 Field #: l Acres Utilized: Acres Permitted: I Lj. n
�,
Q
7 9 o
1 ra0`i
�/30
Uq
l f b
Specify
Totals
Per
Acre
500
7
Pogo
7 14
ily
70
Solids
As
Deci-
oral
9. 6
01. 36
,36
/,�
.3(-
Dry
Tons
Per
Acre
(0, -a b
0, i
0,3
0,
6,25
Residual
Sources
(Summarize)
�, ,n 3e��s1
�� s
, :. >_S1
;, 5i
Cored.
D
Wet,
Moist
�
��-
ro,
'Dh
Inches
Pre p
Past 24
Hrs.
d
o
0
Appli-
cation
Meth-
od**
s
S
Voli-
tila-
zation
Rate*
O, 5
015
0,5
Miner-
ala-
zation
Rate
30%
dlo
3o°a
30
:3 0 %r
TKN
1. 3
a��
a,6
I ,9
1,
Ammo
ma-
Ni-
trogen
3 5
0, 5
01-7
0,50
U,50
Ni-trate
Ni-
trogen
O
O
(0
d
PAN 1
O,
0Q 3
_
PAN 2
Must Select
Crop 1 or Crop
p
2
Gal.
:-
Cu.Yd.
e s
in Gal.
7,000
�� (2U9
r�,
10 0o0
(JQOt�
Cro 1
Crop 2
FCZC 1A
F'e�
O, 9 a
o..,(,6
Fes u.
rOTALS: 371 `f [,6916
knnual lbs/acre
�urrent Cumulative lbs/acre
. rior Years Cumulative lbs/acre
'ermitted C. P. L. R.* **
'ermit PAN Limit lst/2nd Crop
IT cerHfv_ render nPnalfv of law
As Cd I Cr Cu Pb Hg Mo Ni Se Zn P PAN 1 PAN 2 Lime Applied
40,0309 U,03 0.05a 0,$633 (),i 0'+9 d.00$`� <4,030 d,v s5bed ova a, la7 95 3.�t 3 Date
0;15g - U0 3 a3'f 1, � 1 l9 , 5, D% �f,q� 5 p, 0�ga to 5 5$ rd,1 53 371 `l a l,` 61 f D't
,'7a7 `f9� 1, 359 14q.Q6lq,1V0 0 ®`dU$ <a, 507 ' .09'7 0094 19.334
6 AiA 1.1.33VI Del15 1 NA 3 -7 J4 '89 a 4 9 2
+ho+ +h:o .a.,..,,..,o„t _tee___ _
lbs/ac
5 3 i9
—__ . J , t.......�., — A"—, waa . •aaao uVa UJLu�ui "ao bra VYai Gu under illy direction or supervision in accordance with a system
lesigned to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
.ignifica t penaltiesforsubmitting false information, including the possibility of fines and imprisonment for knowing violations."
)il �zyu Lo 5 *Application Method: S - Surface, IN - Injection, INC - Incorporation
Signature of Land Applier Date **Volitilization Rate: Surface - 0.5, InjectionJncorporation -1.0
***C.P.L.R.: Cumulative Pollutant Loading Rate
Author Daryl D. Merritt DENR FORM FSF (7/2002)

ANNUAL METALS FIELD LOADING SUAMARY FORM
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
eility Name: AvlTotal Dry Tons Applied (Annual):
#: 600H 3 96 Cation Exchange Capacity (non 503 only): (� ( m�4� �1Z
Operator: ` "_� M, 5�VV s Owner: �.,c�r fiv Co
. Acres Used: i d Acres Permitted: ( Site #: Q j Field
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
posite
Date
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
MOM
i Total
Phos-
phorus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in
)rdance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information,
incWing possibility of fines and imprisonment for knowing violations"
i 31 DENR FORM MFLSF (7/20(
Signature of Land Appher Date

ANNUAL LAND APPLICATIM." 'LLD SUMMARY FORM
PLEASE'c inKE A COPY OF THIS BLANK FORM TO BE COMP: _- ;' �'ED AND SUBMITTED FOR EACH APPLICATION
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: J oW f\
Owner:`r�1 C.oc�,y Operator:
;ite #: ()j Field #: ()'D
Permit
A m, axoy,
Acres Utilized: C7
Annual Dry Tons Applied: O
Cation Exchange Capacity (non 503):
Acres Permitted: 1/
Q
Specify
Totals
Per
Acre
7,0
Solids
As
Deci-
mal
Dry
Tons
Per
Acre
Residual
Sources
(Summarize)
Cond.
Dry,
Wet,
Moist
Inches.
Precip.
Past 24
Hrs.
Appli-
cation
Meth-
od *
Voli-
tila-
zation
Rate *
Miner-
ala-
zation
Rate
TKN
Ammo
ma-
Ni-
trogen
Ni-trate
Ni-
trogen
PAN 1
PAN 2
Must Select
Crop 1 C
p orro p
2
Gal.
Cu.Yd.
Report
Totals
in Gal.
Crop 1
Crop 2
COTALS:
As
Cd
Cr
Cu
Pb
Hg
Mo
Ni
Se
Zn
P
PAN 1
PAN 2
Lime App
ie
knnuallbs/acre
Date
lbs/ac
�urrent Cumulative lbs/acre
< 0.�7°1� 0,�96� a55 3;Oa�+ 6,c� 7� �5c>8S 1, J � �, ©,6 � } �,7� i1 ys v'
3(, N A A 2�19
5319
?rior Years Cumulative
?ermitted C. P. L. R.***
?ermit PAN Limit 1 st/2nd Crop
`I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
lesigned to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
agnific t penal °es for submitting false information, including the possibility of fines and imprisonment for knowing violations."
1131105 *Application Method: S - Surface, IN Injection, INC - Incorporation
Signature of Land Applier Date **Volitilization Rate: Surface - 0.5, Injection/Incorporation -1.0
***C.P.L.R.: Cumulative Pollutant Loading Rate
Author Daryl D. Merritt DENR FORM FSF (7/2002)

W
ANNUAL METALS FIELD LOADING SUMMARY FORM
Attach this form to the Vcorresponding Field Loading Summary Form to be submitted in Annual Report
ility Name: l nuw 6� 1 c r s " i I) Total Dry Tons Applied (Annual):
Permit #: Cation Exchange Capacity (non 503 only): to, 3 �� f 1 0a
Operator: r S mS Owner: CA
Acres Used: Acres Permitted: , Site #: 1 Field #: o a
-D—M.,al Analvcic na+a rueaw Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent ft
Non
0
MEE
,.,i ,u —, wrp+.i Fipm T .narlin¢c Walculated in lbs/acre):
o
�
y
CD d
�r n
Arsenic
Cadmium
hromiu
Copper
Lead
Mercury
Mo y -
denum
Nickel
Selenium
Zinc
Total
Phos-
phorus
certify, under penalty of law, that this document was prepared under my direction or supervision in
.. ,-ordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information,
includling the ossibility of Pr es and' risonment for knowing violations"
/i
JUL
„K. I AA _ n I 1 /0Jr DENR FORM MFLSF (7/20
Signature of Land Applier

rAt tIMA-Y A AIND VEC'MR ATTRACTION REDUCTION FORM
i y
Facility Name: �� . �1(' AA �_A Permit Number: Coa0004a9 CA
WWTP Name: o n cp NPDES Number: &00 5 7 1 5 I
Monitoring Period: From ��ti t aooq To ��ce�nbe� 3 i a00
Pathogen Reduction (40 CFR 503.32) -'Please indicate level achieved and alternative performed:
Class A:
Alternative 1 ❑
Alternative 2 ❑
Alternative 3 ❑
Alternative 4❑ Alternative 5 ❑
Alternative 6 ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑ Heat Drying ❑ 1 Heat Treatment ❑ Thezmophilic
Beta Ray ❑
Gamma Ray [3
Pasteurization [j
Class B:
Alternative ig
Alternative 2 ❑
Alternative 3 ❑ .
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization. ❑ Air Drying❑ Composting ❑ Aerobic Digestion
Anaerobic Digestion❑
If applicable to alte ativ erformed (Class A or Class B) complete the following monitoring data:
Parameter
Level in
Pathogen Density
AM= Ot
Excee-
Precla—ency
Sam le
p
a ca
inimu
Geo. Mean
aximu
Units
deuces
of
Analysis
Type
Tech-
ni ue
x o e
power WN per
total
�0, �®©
°�g�00O
���0U0
Celor+;e
O
I
Gy-
gram of
Gfm"
(`/L°qr
b
solids or 2 x 10 to
Fecal Coliform
the 6th power
CFU per gram of
1000 mpn per
gram of total solid
(dry weight)
Salmonella bacteria
. 3 MPN per 4
(in lieu of fecal
grams total solid
coliform)
(dry weight)
Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed:
Option 1 ❑ Option 2 ❑ Option 3 ❑ Option 4 Option 5 ❑
Option 6 ❑ Option 7 ❑ Option 8 ❑ Option 9 ❑ Option 10
No vector attraction reduction options were performed
!'/TT TTTIT lY
�ivmn 1 (piease check the appropriate statement)
E2( "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
u "-i cernry, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the
system designed to ensure that qualified personnel properly gather and evaluate the information
used to determine that the pathogen and vector attraction reduction requirements have been met. I
am aware that there are significant penalties for false certification including fine and imprisonment."
�y r i��b�ici�Orils 17„ree'�'c�r
Pr arer ame and Titl (type or print)
Signature of Preparer Date
Land Applier Name and Title (if applicable)(type or print)
Signature of Land Applier (if applicable) Date
nFNR FORM RF f7tmm)

EARTH ENVIRONMENTAL SERVICES
75 Bison Lane
Murphy, NC 28906
Residence — [phone]
Robbinsville Lab — [phone]
Marshall Lab — [phone]
Shelby Lab — [phone]'
E-Mail — earthenvsergwebworkz. coml
August 10, 2004
NC ID#474, 4352
Mr. Robert Sams
Town of Mars Hill
P.O. Box 368
Mars Hill, NC 28754
Dear Mr. Sams:
Following is a report of laboratory analyses for digester sludge samples received 7/28/04.
Colony Counts
Sample Date Coliform Densities (colones! % Total Solids 10 ml 01 ml 0 01 m!
1
7/19/04
27,000 Colonies/Gram
0.91%
TNTC
24
5
2
7/20104
34,000 Colonies/Gram
0.91%
TNTC
31
5
3
7/21/04
28,000 Colonies/Gram
0.93%
TNTC
26
5
4
7/22104
20,000 Colonies/Gram
0.91%
TNTC
17
3
5
7126/04
33,000 Colonies/Gram
0.91%
TNTC
30
6
5
7/27/04
28,000 Colonies/Gram
0.89%
TNTC
25
5
0
7/28/04
27,000 Colonies/Gram
0.89%
TNTC
24
4
Geometric mean for all seven samples: 28,000 colonies/gram. Thank you for your
business. If you have any question or need additional sample analyses performed, please
call.
Respectfully submitted,
Michael J. Ladd
Laboratory Director

M 1
Specific Oxygen Uptake Rate
SOUR
Time
(minutes)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
Facility Name
Biosolids Permit Number
Date
Digester Temperature
Sampling Date/Time
Sampled By
Analysis Date/Time
Analyzed By
Sample Volume
Total Solids
Beginning Temperature
End Temperature
Dissolved Oxygen Level
n
Slope:
Intercept:
Correlation Coefficient:
milliliters
Dry Solids
legrees Celsius
legrees Celsius
Oxygen Uptake Rate: mg Oxygen/hr
Ambient Specific Oxygen Uptake Rate: mg Oxygen/g/hr
Average Temperature: 15. a degrees Celsius
Temperature Correction Factor: d
Temperature Corrected Specific Oxygen Uptake Rate: Q, mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

-,. Jaw,,31 05 01:03p Earth E[nviron�m+ental Svcs 1-828-837-9543 p.1
Specific Oxygen Uptake Rate
SOUR
date 1 2 C Sample Location sec-�h-G I�ryc�^ Temperature
Time -2
c� BIg in T emp i ' 3 Average Temp / 5 Z End Temp s'
), or( Oxygen Uptake Rate (OUR) (SM 2710B)
— I;07-
- 1c0�
1, C OUR mg O2 A thr = Begin Dissolved © gen End J2issa ' xynen ' 60
p IG Elapsed Time
Y`
OUR = -- mg /L - mg A ' 60 = Minutes mg 02 /Uhr
, '7
�,�ti P,,VIL

JaF— 31 05 01 : 04p Earth Environmental Svcs
Speck Oxygen Uptake Rate (SOUR)
1-828-837-9543 p,2
a� 1.SSOUR mg 02 /hr/g = OUR m O AL1hr �I
r1 t' v % Total Solids • 1oo© g/L I
Note: enter total solids are as a decimal, see S.M. 254o
'-V'� SOUR = 02 lUhr
J = niq 02 /hr/q
% Total Solids'100o g/L
Z 1i7Z
-
Q e W-a 0 Y /, t1 G "T'�=?.sq p, c a�.
2. SOUR mg 02 /hr/g — OUR mg 02AJhr
Total Solids g/L
Note: S.M. 2540D, except use evaporating dish instead of fber filter. /
SOUR = mg 02 /Uhr = M9 02 /hr!
g/L
Total Solids g/L =Total Solids ma/L / '� Z y / Ja
1000 mg/g —Mynjo'
Temperature Adjustment��
SOUR = @ 20 °C = SOUR. ® Average TempAdjustment, or correction factor
mg 02 /hr/g = mg 02 /hr/g `
20 °C eaC
H`vfc: See i djiWG; era form la at'd correct-10ir rectors oon the hem page.

Jan ,y?1 05 01 a 04p
Earth Environmental Svcs 1-828-837-9543
p.3
Specific Oxygen Uptake Rate
Temperature Adjustment
SOUR is determined at the digester's ambient temperature and then adjusted as follows..-.
SOUR 0 20 °C = SCOUR @ Average Temp ` Adjustment, or correction factor
Where A­-I-OSve 20°
= 1.07 belo*,;!0 °
These Fartoro arm L_,et, can 1r10 f` 2nrt!{[i0
Simplified
SOUR = ® 206 C = SOUR @
Average Temp ` Correction
Correction : A (20= Ambient Tempe)
Temp °C
Correction
10
1.97
11
1.84
12
1.72
13
1.60
14
1.50
15
1.40
16
1.31
17
1.22
18
1.14
19
1.07
20
1.00
21
0.95
.22 .
0.90
23
0.86
24
0.82
25
0.78
26
0.75
27
0.71
28
0.68
29
0.64
30
0.61

-rtl wn O*f 9415 1-1,11
Annual Report Review SOP DWq
1. Annual Land Application Certification Form
• Was a certification form submitted?VZ5'
• Was land application conducted during the reported year? ye S
• How many dry tons and dry tons per acre were applied? a©> Q
• Were the applications within the permitted amount?y,eS
• Verify PAN. if more than 10 tons/acre
• Did it indicate compliance? Yt3'
• Was it signed by the appropriate people?yZ-3
2. Monitoring
• Were the analyses conducted at the required frequency? JZ5
• Were the metals analyses reported on the Residual Sampling Summary Form? yey
• Were the results reported in mg/kg? rs
• . Were the heavy metals within ceiling concentration permit limits?�,e,S
• If no, were the lab analyses attached?
• Were all the required parameters tested?sb,0
analysis conducted. ��cadd Was TCLP anal r2 j y F
y ,mot F y c_1e ,_ �zcte
3. Field Summary
• Were the land application events recorded on the Field Summary Forms?�1e3
• Was a Field Summary Form submitted for each field?
• Were all the residuals applied to permitted land?.ye5
• Were all the residuals applied from permitted sources?yts
• Were the field loading rates for each metal and PAN calculated (year to date)? .7
• Were the cumulative pollutant loading rates calculated? V
• Were the calculations correct? Y4e5'
• Were the PAN loading rates within permit limits?j..5
• Were the heavy metal cumulative pollutant loading rates within permit limits? y Y-S
• Were the residuals applied on a suitable crop?je
• Were the applications conducted during the crop's growing season? j,�
• Were the Field Summary Forms complete?y,,c
4. Pathogen and Vector Attraction Reduction
• Was a signed copy of the Pathogen and Vector Attraction Reduction Form submitted?yes
• Did the form indicate the period of coverage, the residual class, and.the pathogen reduction alternative and the
vector attraction reduction option used? y&S
• Was the appropriate documentation to show pathogen and vector attraction reduction included in the report? i-e- 5
• Was pathogen and vector attraction reduction demonstrated according to 40 CFR Part 503? v a �d 4-t,
5. Soil Tests
• Was a Standard Soil Fertility Analysis conducted for each application field?+zs o'-)-e.
• Were the soil pH's 6.0 or greater for each application field?
• Were the copper and zinc indexes in the soil less than 3000 for each application field? jJc+ 4,, 1P j1 A, 1
6. General
• Was the report in the proper format? * e-5
• Were any parts of the annual report missing?
• Was the report submitted on time? I-eS
* Any violations of ceiling concentrations should be reported to Pretreatment for municipalities only.

�3/,6 �152- P41u=1l8-Z..��I 00�-= a. - iA%v7-
ao,ag x 9,365- 16%7 ^ 4/7 9&(p/A 04N
JAI AC
K i"S l y j ij "—
�N
616sol�cl l
;3,
rog3(,o
/0.01Lfvl�PZJo' Z
T
o 7 7 07 lAc- �
Co-X ,6OZ_ o,38gE'b�o,3=o.�z®�a'�
39 -' 0.
1. �l 0• /0jq lb
DT
rT i
yr,
D.,g©x ,Ooa=cS.�oss Ib j�T
c�
Ac-
00
,0a1�
a 1, � k , 0 C) = 0. 6 L/ 2-�-
0 , b q &--� ) l . `i -- ch , 0 (a aq