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WQ0004298_2002 Residuals Annual Report (Revision)_20030606
L 4 --rp�&VCOU a� Amended Report WQ0004298 Town of Mars Hill Land Application' 2002 To Whom It May Concern: It was brought to my attention that mistakes were made on the original 2002 annual report regarding the metals . calculation. Metals were converted from mg/1 to mg/kg when the original report was filed. The results from the lab were already in mg/kg. This mistake made the metals loading figures incorrect.. The DENR forms RSSF, FSF, and MFLSF were modified to show the correct figures. If you have any questions regarding this amended report please call me at (828) 689-9850. Robert M. Sams Diof Public Works 5/29/03 j AAA u A l , LAM APPLICATION CERTIFICATION FORM Permit#: 10Qn00'a� County: Year: 'a 0 g Facility Name (as shown on permit): Land Application Operator 1 064@,1'� ri\1S',c,#.4Vl<, Phone: Land application of residual solids as allowed by the permit occurred during the past calen %year?9 RS 0 ❑ Yes ❑ No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A: Total number of application fields in permit: a Total number of fields land application occurred during the year: Total amount of dry tons applied during the year for all application sitesF�Z7� 7Total number of acres land application occurred during the yearI Part B: Facility was compliant during calendar year ` 00`� with allconditions of the land application permit (including but not limited to items 1-12 below) issued by the Division of Water Quality.. [6 Yes ❑ No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis were performed on each site receiving residuals during. the past calendar year and three (3) copies of laboratory results are attached. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 10. Vegetative cover as specified in the permit was maintained on this site and the _crops grown were removed in accordance with the crop management plan. 11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 12. All buffer requirements as specified on the permit were maintained during each. application of residuals. "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant. penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 4 y � 3 o pr✓e — %pN.v � �� <Z � 2 —/0— 03 ;rmittee Name and Title (type or print) Signatu er of Permittee Date /2,J zg��i�i d�" 0 Signature of Preparer* Date Signature of Land Applier Date (if different from Permittee) (if different from Permittee and Preparer) + Prensrar is ricfinnA ;- en `+-- - . -- - 11cAln----- "UAL DISTRIBUTION AND MARKETING/ SURFAC _ - 'ISPOSAL CERTIFICATION AND SUMMARY FOR.p . _. ERMIT #: � - �p�}aq � FACILITY NAME: (o,-z%, PHONE: c�a����g-a�s� COUNTY: OPERATOR1 �r 1`YL.m� L : ' FACILITY TYPE (please check one): Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C) 0 Distribution and Marketing (complete Parts A, B, and C) Vas the facility in operation during the past calendar year? Ej Yes [3No No If No skip parts A, B, C and certify for below Part A*: Part B*: Sources(s) (include NPDES # if Volume (dry tons) Recipient Information Month Admendment/ applicable) Residual In Product Out Name(s) Volume c(dry Bulking Agent tons) Intended use(s) anuary ebruary larch .pril lay ane aly r it 51 -NCeO sj , Q , .ugust eptember ictober ovember ecember otals: Annual (dry tons it more space than given is rrt C: 0 are attached icility was compliant during calendar year a®pQ with all conditions of the permit (including but not limited to items 1-3 below) issued by the [vision of Water Quality. Q( Yes [] No If No, please provide a written description why the facility was not co Mpliant. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the 'Division of Water Quality. - No contravention of Ground Water Quality Standards occurred at a monitoring well. certify, under penalty of law, that the above information is, to the best. of my knowledge and belief, true, accurate and complete. I am aware .at there are significant penalties for submitting false inff ormaiton, incl ing the possibility of fines and imprisonment for knowing.. violations. ;nature of Permittee Date 'Signature of Preparer** Date (if different from Permittee) * *Preparer is defined in 40 CFR Part 503.9(r) DENR FORM DMSDF (7/2002) Michael Ladd 75 Bison Lane Murphy, NC 28906 Robbinsville Lab (828) 479.6428 Madison County Lab (828) 649-9250 Residence (828) 837-9543 Name and Address of Facility: Date: 1/13/03 Town of Mars Hill WWTP Sample Collector: RS P.O. BOX 368 Date and Time Sample Received: 12/4103 11:35 AM MACS Hill, NC 28754 Date and Time Sample Collected: 1713 & 4/02 Aft: Robert Sams Date and Time Sample Analyzed: < MHT Land Application Analyses - Note: All results in mg/Kg Dry Basis unless otherwise noted. Test Aer. Dig Sludge Dry Bed Sludge Soil Site #1 Soil Site #2 Report Limit Method Units ACIDITY 0.1 meq/100g 0.9 meq/100g 2.0 SM5210B mg/L TOTAL SUSPENDED RESIDUE 1.6 SM2640D mg/L CATION EXCHANGE CAPACITY 9.2 meq/100g 8.8 meq/100g 1 SM9222D per 100ml PH 6.6 6.5 6.9 6.3 0-14 SM4500H+ units AMMONIA NITROGEN 52.6 18.7 0.5 SM4500NH3F mg/L NO2 + NO3-n < 1.00 < 1.00 1.0 SM5620B mg/L TOTAL KJELDAHL NITROGEN 703 5000 SCA mg/L TOTAL PHOSPHOROUS 199 916 174 51 SCA mglL PERCENT TOTAL RESIDUE 1.37% 5.11% 84.3% 83.7% 1.0 SM2540B mg/L %HUMIC MATTER 3.00/6 3.3% 1.0 SM2130B NTU % BASE SATURATION - K 3.7 28.8 1.0 SM2540C mg/L - H 1.4 10.6 - Mg - Ca 30:3 63.6 25.6 34.0 PLANT AVAILABLE (surface) 221.4 1503.8 10 SM2510B umhos/cm NITROGEN- PPM DRY WT (subsur0 247.7 1513.1 0.1 SM4500CIG mg/L TEMPERATURE SM2550B deg C MIXED LIQUOR SUPSPENDED SOLIDS 1.0 NIA mg/L MAGNESIUM 12200 5230 1390 2460 SCA mg/L ODIUM 11500 3030 < 58.1 < 56.9 SCA mg/L CADMIUM < 71.5 < 18.6 < 1.16 < 1.14 SCA mg/L CHROMIUM 86 37.4 51.8 39.5 SCA mg/L COPPER 1070 399 27.6 15.3 SCA mg/L LEAD 172 67.3 13.3 10.2 SCA mg/L NICKEL < 71.5 26.2 11.9 10.0 SCA mg/L ZINC 2350 822 61.2 43.7 SCA mg/L CALCIUM 52900 15900 2030 644 SCA mg/L POTASSIUM 12500 3600 738 3570 SCA mg/L ALUMINUM 52500 20700 SCA mg/L JARSENIC E 71.5 < 18.6 < 1.16 < 1.14 SCA mg/L SELENIUM < 143 < 37.4 < 2.33 < 2.27 SCA mg/L YBDENUM < 71.5 < 18.6 < 1.16 < 1.14 SCA mg/L MERCURY < 7.30 < 1.96 < 0.12 < 0.12 SCA mglL N.C. Laboratory ID# 352 Analyzed By: MB Lab Supervisor. Michael J. Ladd; EES-Robbinsville Certified By: I 7`l6 /-/ : 0.0 ��) I "Ar- 01 C . Plant Available Nitrogen (PAN) calculations and land application area requirements: CONSTITUENTS MR/Kg -DRY WEIGHT TIN Sly 6q AMMONIA-N . NO3-NO2-N .- < lvo :� 1- Mineralization Rate (MR) 30 %d -�d (These values, can be established for the specific residual or default values can be used for domestic wastewater treatment residuals, .If actual value's are establlsbed, attach the documentation, The default values are as follows): Unstabilized Primary and Secondary Residuals 40% Aerobically Digested Residuals 30% Anwobwiy Digested Residuals 20% Composted Residuals 10% (If the default values are used, attach an explanation as to why the specific chosen default value is appropriate.) 2. Complete the following calculations for the application method proposed (Please note, the Mineralization Rate [MR] should be utilized in the following calculations as a.decirnal): PAN for Surface Application PAN = l(MR) x (TKN - NH3)) + ,S x (NH3) + (NO3-NO2-N) PAN=` +,sx( 123#-7 PAN = PPM Dry Weight PAN for Subsurface Application. PAN = [(MR)x(TKN - NH3)] + (NH3) + (NO3-NO2-N) PANS[ m30 x(- PAN = Sd3 ` PPM Dry Weight 3. Total PAN to be land applied per year Tnrnl dry inn%of rrcidnal fn hr. land ae.nVM nw woo-- TestLmerica ANALYTICAL REPORT ' 1 TESTAMERICA-ASHEVILLE 5781 1 Lab Number: 02-A199987 DINAH TRAMMEL ��"� Sample ID-. EES #120224 122 LYMAN STREET% Sample Type: Soil ASHEVILLE, NC 28801 Q Site ID: r Date Collected: 12/ 3/02 Project: -2;' '�Cl �Q Time Collected: 7 : 45 Project Name: �� � Date Received: 12/ 6/02 Sampler: 4 Time Received: 9:00 A Page: 1 Report Dil Analyse Result Units Limit Factor Date Time Analyst Method Batch *METALS* Aluminum 52500 mg/kg 717. 1 12/13/02 1:23 C.Johnson 6010E 700 Arsenic NO mg/kg 71.5 1 12/13/02 1:23 C.Johnson 6010E 700 Cadmium ND mg/kg 71.5 1 , 12/13/02 1:23 C.Johnson 6010B• 700 Calcium 52900 mg/kg 717. 1 12/13/02 1:23 C.Johnson 6010B 700 Chromium 86. mg/kg 71.5 1 12/13/02 1:23 C.Johnson 6010B 700 Copper 1070 mg/kg 71.5 1 12/13/02 1:23 C.Johnson 6010B 700 Lead 172. mg/kg 71.5 1 12/13/02 1:23 C.Johnson 60109 700 Magnesium 12200 mg/kg 717. 1 12/13/02 1:23 C.Johnson 6010B 700 Mercury ND - mg/kg 7.30 1 12/11/02 25:04 R.Hatchett 7471A 2053 Molybdenum ND' mg/kg 71.5 1 12/13/02 1:23 C.Johnson 6010B 700 Nickel ND mg/kg 71.5 1 12/13/02 1:23 C.Johnson 6010E 700 Potassium 12500• mg/kg 3580 1 12/13/02 1:23 C.Johnson 6010B 700 Selenium ND mg/kg 143. 1 12/13/02 1:23 C.Johnson 6010B 700 Sodium 11500 mg/kg 3580 1 12/13/02 1:23 C.Johnson 6010E 700 Zinc 235a mg/kg 717.- 1 12/13/02 1:23 C.Johnson 60102 700 *GENERAL CHEMISTRY PARAMETERS* pH 6.60 pH units 12/ 7/02 21:15 S. Self 9045 9357 & Dry Weight 1.37 Jk 12/11/02 0:00 X. Keller CLP 9,�39 Nitrite-N as N ND mg/kg 1.0 1 12/ 9/02 23:31 S. Overton 9056 1287 Nitrate-N as N ND mg/kg 1.00 1 12/ 9/02 23:31 S. Overton 9056 1287 Ammonia Nitrogen as N 52.6 mg/kg 1.00 1 12/13/02 23e00 • S. Prayter 350.1M 5391 Phosphorus as P 199. mg/kg 10.0 1 12/15/02 23:00 G. Baun 365.4 M 5477 Sjeldahl. Nitrogen as N 703. mg/kg 10.0 1 12/ 9/02 13:00 S. Prayter SM4500NC 1963 Sample report continued . . . OnRn P.......•.•., n................ M'..... / A1............ TIU 071MA / Q1C 71)1-' 1%177 / V . r:1 : 70G nn^.A / Onn 7arz nnon Tes. t merica- I N C O R P O R AT E D ANALYTICAL REPORT TESTAMERICA-ASHEVILLE DINAH TRAMMEL 122 LYMAN STREET ASHEVILLE, NC 28801 Proj ect : Project Name: Sampler: 5781 Lab Number: 02-A199988 Sample ID: EES #120225 Sample Type: Soil Site ID: Date Collected: 12/ 4/02 Time Collected: 7:45 Date Received: 12/ 6/02 Time Received: -9:00 Page: 1 Report Dil Analyte Result Units Limit Factor Date Time Analyst Method Batch ------------------------ -------- -- ------ ------ -------- --------------- --------- ----- *METALS* Aluminum 20700 mg/kg 187. 1 12/13/02 1:23 C.Johnson 6010B 700 Arsenic ND mg/kg 18.6 1 12/13/02 1:23 C.Johnson 6010E 700 Cadmium ND mg/kg 18.6 1 12/13/02 1:23 C.Johnson 6010B 700 Calcium IS900 mg/kg 187. 1 12/13/02 1:23 C.Johnson 6010E 700 Chromium 37.4 mg/kg 18.6 1 12/13/02 1:23 C.Johnson 6010E 700 Copper 399. mg/kg 18.6 1 12/13/02 1:23 C.Johnson 6010E 700 Lead 67.3 mg/kg 18.6 1 12/13/02 1:23 C.Johnson 6010B 700 Magnesium 5230 mg/kg 187. 1 12/13/02 1:23 C.Jobnson 6010B 700 Mercury ND mg/kg 1.96 1 12/11/02 15:04 K.Hatchett 7471A 2053 Molybdenum ND mg/kg 18.6 1 12/13/02 1:23 C.Johnson 6010E 700 Nickel 26.2 mg/kg 18.6 1 12/13/02 1:23 C.Johnson 6010B 700 Potassium 3600 mg/kg 933. 1 12/13/02 1:23 C.Johnson 6010E 700 Selenium ND mg/kg 37.4 1 12/13/02 1:23 C.Johnson 6010B 700 Silver 59.7 mg/kg 18.6 1 12/13/02 1:23 C.Johnson 6010E 700 Sodium 3030 mg/kg 933. 1 12/13/02 1:23 C.Johnson 6D10B 700 Zinc 822. mg/kg 187. 1 12/13/02 1:23 C.Johnson 6010E 700 *GENERAL CHEMISTRY PARAMETERS* PH 6.50 pH units 12/ 7102 21:20 S. Self 9045 9357 W Dry weight 5.11 tr 12/11/02 0:00 K. Keller CLP 9339 Nitrite-N as N ND mg/kg 1.0 1 12/ 9/02 23:31 S. Overton 9056 1287 Nitrate-N as N ND mg/kg 1.00 1 12/ 9/02 23:31 S. Overton 9056 1287 Ammonia Nitrogen as N 187. mg/kg 10.0 10 22/12/02 8:45 S. Prayter 350.1M 1954 Phosphorus as P 916. mg/kg 20.0 2 12/15/02 23:00 G. Baun 365.4 M 5477 Sample report continued . . . 9UR11 Fnwrvv f'vvrr.urnrc Tlvnry / Ill:+cnn'niv TA1 379(ld / R1r-79R-11177 / R.%%• AIR-79F-f)QF;4 / Rflfl_7fir,-(1pRfl TesU. merica I N C O R P O R A T E D ANALYTICAL REPORT ! Laboratory Number: 02-A199988 Sample.ID: EES #120225 Project: Page 2 Report Dil Analyse ------------------------ Result Units ----------- ------ Limit ------ Factor Date Time ------ -------- ----- Analyst Method Batch ---------- --------- ----- Ajeldahl Nitrogen as N 5000 mg/kg 200. 20 12/ 9/02 13:00 S. Prayter SM4500NC 1963 LABORATORY COMMENTS: ND = Not detected at -the report limit. H = Analyte was detected in the method blank. J = Estimated Value below Report Limit.., E = Estimated Value above the calibration limit of the instrument, # - Recovery outside Laboratory historical or method prescribed limits. All reported results for metals or Organic analyses have been corrected for dry weight. End of Sample Report. 9Qn(1 PrIwI:u Ruuu:urnm nV111V I N.112111:111L` TN R79nA / n1.r,-799-0177 / R.tti• 915_79A-O0.,d / Rnn-7n.r,-(1QRO Testli merica I N C 0 R P 0 R A T E D ANALYTICAL REPORT TESTAMERICA-ASHEVILLE 5781 1 .S DINAH TRAMMEL X+ 122 LYMAN STREET o �j V ASHEVILLE, NC 28801 Proj ect : Project Name: Sampler: LabNumberi 02-A199989 Sample ID: EES.#120226 Sample Type: Soil Site ID: Date Collected: 12/ 4/02 Time Collected: 14:00 Date Received: 12/ 6/02 Time Received: 9:00 Page: 1 Report Dil Analyte. Result Units Limit Factor Date Time Analyst Method Hatch ----------------------------------- ------ ------ -------------- --------------- --------- ----- +METALS+ Cadmium ND mg/kg 1.16 1 12/12/02 13:.31 G.McCord 6010E 2160 Calcium 2030 mg/kg 11.6 1 12/12/02 13:31 G.McCord 6010E 2160 Chromium 51.8 mg/kg 1.16 1 22/12/02 13:31 G.McCord 6010B 2160 Copper 27.6 mg/kg 1.16 1 12/12/02 13:31 G.McCord 6010B 2160 Lead 13.3 mg/kg 1.16 1 12/12/02 13:31 G.MCCord 6010E 2160 Magnesium 1390 mg/kg 11.6 1 12/12/02 13:31 G.McCord 6010E 2160 Mercury ND mg/kg 0.12 1 12/11/02 15:04 K.Hatchett 7471A 2053 Molybdenum ND mg/kg 1.16 1 12/12/02 13:31 G.McCord 6010B 2160 Nickel 11.9 mg/kg 1.16 1 22/12/02 13:31 G.McCord 6010B 2160 Potassium 738. mg/kg 58.1 1 12/12/02 13:31 G.McCord 6010E 2160 Selenium ND mg/kg 2.33 1 12/12/02 13:31 G.McCord 6010E 2160 Silver ND mg/kg 1.16 1 12/12/02 13:31 G.McCord 6010E 2160 Sodium ND mg/kg 58.1 1 12/12/02 13:31 G.McCord 6010E 2160 Zinc 61.2 mg/kg 11.6 1 12/12/02 13:31 G.McCord 6010B 2160 *GENERAL CHEMISTRY PARAMETERS* PH 7.20 pH units 12/ 7/02 11:20 S. Self 9045 9357 %r Dry Weight 84.3 12/11/02 15:00 K. Keller CLP 553 Sample report continued . . . 7AR0 Fncrb:u ('.vrru:n•1'(w (lunar / NAQ111•rl i w• TN R77(11d / R1r,-77R-(1177 / Wa%. RI _77R_n(Y.1 / Ann_7RF-noon Test-merica. I N C O R P O R A T E D ANALYTICAL REPORT TESTAMERICA-ASHEVILLE 5781 DINAH TRAMMEL R 122 LYMAN STREET v ASHEVILLE, NC 28801 �i Project: / Jx a Project Name: r4 Sampler: Lab Number: 02-A199990 Sample ID: EES #120227 Sample Type: Soil Site ID: Date Collected: 12/ 4/02 Time Collected: 14:10 Date Received: 12/ 6/02 Time Received: - 9:00, Page: 1 Report. Dil Analyte Result Units Limit Factor Date Time Analyst Method Batch ----------------------------------- ----- ------ ------ -------- ------------------------ ----- *METALS* Cadmium ND Calcium 644. Chromium 39.5 Copper 15.3 Lead 10.2 Magnesium 2460 Mercury ND Molybdenum ND' Nickel 10.0 Potassium 3570 Selenium ND Silver ND' Sodium ND Zinc 43.7 *GENERAL CHEMISTRY PARAMETERS* pH 6.20 g Dry weight 83.7 Sample report continued . mg/kg 1.14 1 12/12/02 23:31 G.McCord 6010B 2160 mg/kg 11.4 1 12/12/02 13:31 G.Mccord 6010E 2160 mg/kg 1.14 1 12/12/02 13:32 G.MCCord 6010E 2160 mg/kg 1.14 1 12/12/02 13:31 G.McCord 6010E 2160 mg/kg 1.14 1 12/12102 13:31 G.MCCord 6010E 2160 mg/kg 11.4 1 12/12/02 13:31 G.MCCord 601DB 2160 mg/kg 0.12 1 12/11/02 15:04 R.Hatchett 7471A 2053 mg/kg 1.14 1 12/12/02 13:31 G.McCord 6010B 2160 mg/kg. 1.14 1 12/12/02 13:31 G.McCord 60108 2160 mg/kg 56.9 1 12/12/02 13:31 G.McCord 6010E 2166 mg/kg 2.27 1 12/12/02 13:31 G.Mccord 6010E 2160 mg/kg 1.14 1 12/12/02 23:31 G.McCord 6010B 2260 mg/kg 56.9 1 12/12/02 13:31 G.McCord 6010E 2160 mg/kg 11.4 1 12/12/02 13:31 G.McCord 6010E 2160 PH units 12/ 7/02 11:25 S. Self 9045 9357 g 12/11/02 15:00 R. Xeller CLP 553 nnen P........... /, ................ T....... 1 ni............ mm-n�nnA / o+c "na ni"m / ID.._ vi= '7nn .nn^A / onn r7ae nnon ANNUAL RESIDUAL, -SAMPLING SU C IARY FORM Attach this form to the corresponding Annual Report Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: (1)06604 Q "� 9 Facility Name: / tl ,U) VI NPDES # or WQ#:, WC 00 6 '7 15 I WWffP Name: jnwh d ! , Il t ) j P Residual Analysis Data Laboratory: 1), Eo-,4 F-V)V r,0V1VYle,Y1 ,ZxI l hr-, 3) 4) 5) Sample • Date .—I�m -I..........�._.._........._.. a n 9 lot cei , under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure.that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Preparer Date DENR FORM RSSF (7/2009) 1 . ANNUAL LAND APPLICATIC.f_'',� FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD PLACE A N/A IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Town Q H , Permit #: (,Jqdpp4Q yZ Annual Dry Tons Applied: -7 , O Owner: ct�r+V CoAOperator: } �1 g Capacity ) .�p Me�, jioo i o @v- Cation Exchange Ca aci non 503 .� Field #: d Acres Utilized: ILI, d Acres Permitted: j —%— Specify 70 Gal. Totals Solids Dry. Inches Appli- Voli- Miner- Ammo Must Select Cond. Cu Yd. Tons Residual Ni-trate q Cu Repod. Per Per As Sources Dry KN Precip. cation tila- ala- T nia- Crop 1 or Crop ' Past 24 Meth- zation zation Ni- PAN 1 PAN 2 Totals Acre Deci- (Summarize) Wet in Gal. mal Acre Hrs. od* * Rate* Rate tro Ni_ en trogen Moist g Crop 1 Crop 2 nnIn 0.71) l L� I/ �LL I IN n 1'a q3 5. it I O, EMUND U1ALN: Ia .5-75, l 1. 1 As 1 Cd—T Cr nnual lbs/acre Zn P PAN i PAN 2 Lime, Cu Pb Hg Mo NiF/,,2 0. 03716,399 :uiTent Cumulative lbs/acre Q, <'0' 79 1, 3 ! S 0.0 6 i <0.00a <�,v 186 v. (gaO;Yaa 0, 9 i 6 ; I � Date 3 '% $ (} D, 0 �g►{ a a 5I a, bG %$, 33i riot Years Cumulative lbs/acre Q,'+6l 1; e � 0a7cq <);`ic1S �.6L(?,5� mnitted C. P. L. R. * * * �.�15. 9 -rmit PAN Limit 1 st/2nd Crop f certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system -signed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are ;nifica penalties for submittin false information, including the possibility of fines and imprisonment for knowing violations." C ' -� ' 01 JLQ.� *Application Method: S - Surface, IN - Injection, INC - Incorp oration Signature of Land Applier Date **Volitilization Rate• Surf 0 5 I ace - . , njection/Incorporation -1 0 ***C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (7/2002) ANNUAL METALS FIELD LOADING SUMMARY FORM Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: j.. (RA.I-5 P A I Total Dry Tons Applied (Annual): -7_ Q :-rmit #: (A 9 Cation Exchange Capacity (non 503 only): -operator: �- Owner: r► r V Acres Used: r �Ac�resPerxnitted: Site #: Field Residual Analysis Data (Heavy Metals and Total Phosphorus use mu/ku--% Rnlvla nap. Raw Paw-ava+4A posite Date or Annual Heavy Metal Field Loadings (Calculated in lbs/acre): MEN certily, under penalty of law, that this document was prepared under my direction or supervision in )rdance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, inclu4iW the possibility of fines and imprisonment for knowing violations" 5- �Q DENR FORM MFLSF (7/200, Signature of Land Applier Date ANNUAL LAND APPLICATION ;,LD SUMMARY FORM PLEASE h ss(E A COPY OF THIS BLANK FORM TO BE COMPLr ED AND SUBMITTED FOR EACH APPLICATION PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. acility Name: To umg �s ; Permit #: (k-)Q0 04 '� <) Annual Dry Tons Applied: wner: L.I,, V Coc'�y Operator ;e #: : 2o��r--� Cation Exchange Capacity (non 503):e ion � i Field #: � � Acres Utilized: �� �rr Specify o T • Acres Permitted: 3 a a Totals in Gal. Totals Solids Dry Residual Cond. Inches Appli- Voli- Miner - Ammo Per As Tons Sources Dry, Precip. cation tila- ala- ma - Ni-trab Acre Deci- Per (Summarize) Wet - Past 24 Meth- zaon tiMoist zation TKN Ni- Ni- mal Acre Hrs. od**' Rate* Rate trogen I . - . — trogen J �. 1 I p� 0 10-7 h ® U! V�`Jln ��l `I l -7i..... I%i 17 _ P ^ < `a T 0/ A I P_' IALa: Ila$ J'A ival lbs/acre rent Cumulative lbs/, ,r Years Cumulative ] nitted C. P. L. R. * * * st O I "'o 10. 5 36'Im I L. G 5 1.60 0 �r <0 .009 0.015� (),Q79s 6,990 5, 5 30alf Iony 5 1115 96 (09,644 915,-7a U,5 7 0,9s a 5, l 191t3 6.6201 6ai JV A %9 I, PAN I I PAN 2 o(.I 1, uiL rnlN L,uruz isulna crop erhfy, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system geed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are 6 ificant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.'.' 5 a7 Crop 1 or Crop 2 Crop III Crop 2 es/ac 0 1U.0 *Application Method: S - Surface, IN - Injection, INC - Incorporation Signature of Land Applier Date **Volitilization Rat • S rf . u a ece - 0.5, Iniection/Incorporation -1.0 ***C.P.L.R.: Cumulative Pollutant Loading Rate Author Daryl D. Merritt DENR FORM FSF (7/2002) ANNUAL METALS FIELD LOADING SUACKARY FORM Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report chitty Name: ,� if rjQ r5 �i; �� (li ��i`� �1 Total Dry Tons Applied (Annual): `d . 3 rmit #: bA a yip y �9 y C n i S ' Cation -Exchange Capacity (non 503 only): `� 1 one � � �V � L � / 1 did ,. Operator: Owner: LcAr r� coy v Acres Used: d,] - � f�ajn:s 7— Acres Permitted: Site #• Field M Residual Analysis Data (Heavy Metals and Total Phosphorus use mz/km Solids use Raw Percent M: Id 1:MEN1 Annual Heavy Metal held Loadings (Calculated in lbslaere): 31 , ���o����� Total t OMEN ernty, under penalty of law, that this document was prepared under my direction or supervision in irdance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, includAg the possibility of fines and imprisonment for knowing violations" DENR FORM MFLSF (7/2 Cis �9yr� of .anti App plierTiatt� .. _.-�__���•�•-•�'i• ruy •L�-ivnt�l ttct�t.Y1111V K1511UC:' ION FORM Facility Name: o�:n 1) M"V- �� I, Permit Numb NVWTP Name: o ��� Number: (�d�i °I U�� NPDES Number: � f C qy s -7 1 � 1 Monitoring Period: From ,, n►►na�ry e) d _ To c- Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed: Class A: Alternative 1 ❑ Alternative 2 ❑ Alternative 3 ❑ Alternative 4E—T-1 rnative 5 ❑ Alt 11 applicable to alternative Compost ❑ Heat Beta Ray - ❑ Gam Class B: Al If applicable to alternative Lime Stabilization. 4naerobic Digestiono] [f applicable to alternative i Parameter I Level in ernative 6 U. rmed (Class A only) indicate "Process to Further Reduce Pathog Ig ❑ Heat Treatment ❑ Thennophilic ❑ . !Y❑ Pasteurization l Alternative 2 ❑ Alternative 3 ❑ -med (Class B only) indicate "Process to Significantly Reduce Pa Air Drying❑ Composting ❑ Aerobic Digestion erformed (Class A or Class B) complete the follow Pathogen Density nm er menu Geo. Mean aximu Units Excee- d L x lU to' -Me 6 power DON per SOO 36, 000 35Colon es gram of total F ��� solids or 2 x 10 to Fecal Coliform the 6th power ences CFU per gram of 1000 mpn per gram of total solid (dry weight) Salmonella bacteria 3 MPN per 4 (in lieu of fecal grams total solid coliform) (dry weight) Vector Attraction Reduction (40 CFR 5*03.33) - Please indicate option performed: onitoring data: [uency Sample a c of Tech- afamie TYPe Vye(xrl Gra� CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Scam iG OLIrk blrec+or Prep er N e and Title type or print) o?-d6-03 Signature of Preparer Date Land Applier Name and Title (if applicable)(type or print) Signature of Land Applier (if applicable) Date L EARTH ENVIRONMENTAL SERVICES 75 Bison Lane Murphy, NC 28906 Residence — (828) 837-9543 Robbinsville Lab — (828) 479-6428 Marshall Lab — (828) 649-9250 Shelby Lab — (704) 482-5227' E-Mail — earthenvser(&,,webworkz.com\ December, 14, 2002 NC 1139474, #352 Mr. Robert Sams Town of Mars Hill P_Q_ Box 368 Mars Hill, NC 28754 Dear Mr_ Sams_ Following is a report of laboratory analyses for digester sludge samples received 12/4/02. Colony Counts Sample Date Coliform Densities (colonies/mam) o Tnta1 Snlids t rot n i —1 n n, 1 11/25102 31,000 Colonies/Gram 0.83% TNTC 26 _ V 4 2 11/26/02 28,000 Colonies/Gram 0.82% TNTC 23 1 3 11/27/02 33,000 Colonies/Gram 0.81% TNTC 27 4 4 11/30/02 25,000 Colonies/Gram 0.83% TNTC 20 6 5 12/2/02 35,000 Colonies/Gram 0.84% TNTC 29 3 6 12/3/02 25,000 Colonies/Gram 0.82% TNTC 20 5 7 1214/02 35,000 Colonies/Gram 0.84% TNTC 29 3 Geometric mean for all seven samples: 30,000 colonies/gram. Thank you for your business. If you have any question or need additional sample analyses performed, please call. Respectfully submitted, xL"�—v Michael J. Ladd Laboratory Director Specific Oxygen Uptake Rate SOUR Time (minutes) 0 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Facility Name Biosolids Permit Numbei Date Digester Temperature Sampling Date/Time Sampled By Analysis Date/Time Analyzed By Sample Volume Total Solids Beginning Temperature End Temperature Dissolved Oxvaen Level Slope: Intercept: Correlation Coefficient: T Wn all00O 0 4 9 I /)a YA ;ke, I " Mike- 600 f f Wn nilliliters /o Dry Solids legrees Celsius legrees Celsius Oxygen Uptake Rate: mg Oxygen/hr Ambient Specific Oxygen Uptake Rate: mg Oxygen/g/hr Average Temperature: a ► '7 degrees Celsius Temperature Correction Factor: Temperature Corrected Specific Oxygen Uptake Rate: mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Specific Oxygen Uptake Rate (SOUR) 1. SOUR mg 02 /hr/g — OUR mg 02 /Uhr % Total Solids * 1000 g/L ti1p Note: enter total solids are as a decimal, see S.M. 2540 G 3 SOUR =_ Mg 02 /Uhr mg 02 /h_ r/ _ % Total Solids *1000 g/L � �,E.©lam � = � � z 64E-7,n�2i��.15. �0XCq 2. SOUR mg 02 /hr/g — OUR ma 02/Uhr Total Solids g/L �' Note: S.M. 2540D, except use evaporating dish instead of fiber filter. SOUR = mg 02 /Uhr = Frig 02 /hr/ <g/L Total Solids g/L =Total Solids ma/L Vco 1000 m9/9 i 1. l 9 cl d �ng � /,•� �i ems . Ce rre�C� r?��eti�t Temperature Adjustment SOUR = 0 20 °C = SOUR @ Average Temp * Adjustment, or correction factor Mg 02 /hr/g -mg 02 /hr/g 0 20 °C oC Note: See Adjustment formula and correct -lot, factors 0011 the next page. Specific Oxygen Uptake Rate Temperature Adjustment SOUR is determined at the digester's ambient temperature and then adjusted as follows. SOUR = 0 20 °C = SOUR ® Average Temp " Adjustment, or correction factor Where A =1.05 above 200 =1.07 below 200 These facters are good between 100 C and 300 Simplfed SOUR = ® 20° C = SOUR 0 Average Temp ` Correction Correction A (20= Ambient Tempe) Temp °C Correction - 10 1.97 11 ' 1.84 12 1.72 13 1.69 14 1.56 15 1.40 16 1.31 17 1.22 18 1.14 19 1.07 20 1.00 21 0.95 ..22._ . _. 0.90 23 0.86 24 0.82 25 0.78 26 0.75 27 0.71 28 0.68 29 0.64 30 0.61