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HomeMy WebLinkAboutNC0047597_Permit Modification_20130124ATA rENR North Carolina Department of Environment and Natural Resources Division of Water Quality Pat McCrory Charles Wakild, P. E. John E. Skvarla, III Governor Director Secretary January 24, 2013 Charles Cocker, Superintendent City of Durham Department of Water Management 101 City Hall Plaza Durham, North Carolina 27701 Subject: Modification of Permit NC0047597 South Durham WRF Class IV Facility Dear Mr. Cocker: Division of Water Quality (Division) personnel have reviewed and approved your request for a modification of the subject permit. Accordingly, we are forwarding the attached NPDES discharge permit. It is issued pursuant to the requirements of North Carolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the U.S. Environmental Protection Agency dated October 15, 2007. This permit modification grants your request for a reduction in the monitoring frequency for total mercury from monthly to quarterly. It also contains the following changes pursuant to the recently approved statewide TMDL for mercury: • Special condition A (10) has been added requiring a mercury minimization plan (MMP). • Limits for total mercury have been changed to an annual average limit of 12 ng/L. This permit is not transferable except after notifying the Division of Water Quality. The Division may modify and reissue or revoke this permit. Please note that this permit does not affect your legal obligation to obtain other permits required by the Division of Water Quality, the Division of Land Resources, the Division of Coastal Management, or other federal or local agencies. 1617 Mail Service Center, Raleigh, North Carolina 27699-1617 Location: 512 N. Salisbury St. Raleigh, North Carolina 27604 Phone: 919-807-63001 FAX: 919-807-6492 Internet www.ncwaterauality.orq Wone CaT01]T1S 7s7aturaI4i An Equal opportunity l Affirmative Action Employer If you have questions, or if we can be of further assistance, please contact Mr. Gil Vinzani at [gil.vinzani@ncdenr.gov] or at telephone number (919) 807-6395. Sincerely, Mtk �x Charles Wakild, P. E., Director Division of Water Quality Enclosure: NPDES Permit NC0047597 Cc: Raleigh Regional Office, Surface Water Protection Section* NPDES Files Central Files * E-mail copy Permit No. NC0047597 STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provisions of North Carolina General Statute 143-215.1, other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act, as amended, the City of Durham is hereby authorized to .discharge wastewater from a facility located at the South Durham Water Reclamation Facility 6605 Farrington Road Chapel Hill, NC Durham County to receiving waters designated as an unnamed tributary to New Hope Creek in the Cape Fear River Basin in accordance with effluent limitations, monitoring requirements, and other conditions set forth in Parts I, II, III, and IV hereof. This permit shall become effective February 1, 2013. This permit and authorization to discharge shall expire at midnight on April 30, 2016. Signed this day January 24, 2013: rles Wakild, P. E., Director Division of Water Quality By Authority of the Environmental Management Commission Permit No. NC0047597 SUPPLEMENT TO PERMIT COVER SHEET All previous NPDES Permits issued to this facility, whether for operation or discharge are hereby revoked. As of this permit issuance, any previously issued permit bearing this number is no longer effective. Therefore, the exclusive authority to operate and discharge from this facility arises under the permit conditions, requirements, terms, and provisions included herein. The City of Durham is hereby authorized to: 1. Continue to operate an existing 20.0 MGD wastewater treatment facility consisting of the following: • Mechanically cleaned bar screens • Long channel grit chambers • Primary clarifiers • Aeration basins • Final clarifiers • Flocculation basins • Traveling bridge effluent sand filters • UV disinfection • Anaerobic digesters • Aerobic digesters • Gravity belt thickener • Clarifier • Sand drying beds • Belt filter press Facility is located at 6605 Farrington Road, Chapel Hill, NC, in Durham County, and 2. Discharge from said treatment works at the location specified on the attached map into an unnamed tributary to New Hope Creek, classified WS-IV NSW waters in the Cape Fear River Basin. ' \ _,-----nilP . j >lr - SA � *lI �.�1i N. �_ ' is QC 'T r O Val ` _--__ _ = _'• sx ShSch / phi-1�, 1 .�� - 1 s. IIP- .t ) (r • I: a sz.-- =ate _ --N /_ _ _ __ \s1 F-=--i:--- cf.'- Iff," < f 4110,1 s _ � _., r= 1 5r, O • If 1,\' �tfl I N s - 0 11.... _ 3_- i�- . Q y �� 4= . = _ " _= Gr ' - f d- -` _ 47%4 _- _- "� 11, ► f :� _� =_ =7 z. i lap7or•.. l'oA..A-p-b-.- • ipv <1:+_ =; « ice== == ,.� ' /d r � s . 7.1r,- �%_ r) 1I ! �r - _ tn—_ _ -= _ _ ,.,. ' = J_ , _ _ --t--_.- -=- ="___ = ,r'�= _«=_,�1 �_ v _�-'. — . ^ �u. =•:�" 's !e 1 __ _ ;-r' �'1. -� _ _ ,• _ _— _ _. ,I� %ice') I t?i i ,, N. - � •- �lr , �:� ��� ;� �.; --- _= µme. j�. ,,T. - ,% ___ '''l , 1.S..-- / YA Ilk M. 1 i \ t �:�k•}�r,A�r� -It `���Tr ' �k"' 1_ -r 1 _- - = =-: s sue Outfall 001 0``Y __s / 5- sts = i rJs /> `I �:, ( o r _ r ;1y l 1 �5 •T!=_ _- -rL_ (J it fit- -- _- --- - -= _ _7 ry // 7 r• e. il 4.0111r ice:.: _ _ _ ; _a� , \ ,.. _ `s' -MI . r-_ -- a- a-- Lie • r�N' e y 1 • _ S it " - -_- -- =_ � ems.' �..f,' i _ _ ��Q�� f i I x �� South Durham WRF - NC0047597 Facility :` • USGS Quad Name: Southwest Durham Receiving Stream: New Hope Creek Lat.: 35°58'18" Long.: 78°58'28" Location • ' Stream Class: WS-IV NSW Subbasin: Cape Fear - 030605 HUC: 03020101 North SCALE 1:24,000 Permit No. NC0047597 A (1) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS Beginning upon the effective date of this permit and lasting until expiration, the Permittee is authorized to discharge treated wastewater from Outfall 001. Such discharges shall be limited and monitored by the Permittee as specified below: r ; ;. ; EFFLUENT CHARACTERISTICS_ ';� �' . . EFFL-UENTLI{IITAATIO?NS , : MONfTQRING REUIREMENTS_ Monthly Average' ' Weekly '' Average• ' Daily Max rlio t 4 Measurement' Frequency Sam !eT"-el.. P ' 'Sampte1 f Locafioh Flow 20.0 MGD Continuous Recording I or E Total Monthly Flow (MG) Monitor & Report Monthly Recorded or Calculated I or E BOD, 5-day, (20°C) 2 (April 1 — October 31) 5.0 mg/L 7.5 mg/L Daily Composite I & E BOD, 5-day, (20°C) 2 (November 1 — March 31) 7.0 mg/L 10.5 mg/L Daily Composite I & E Total Suspended Solids2 30.0 mg/L 45.0 mg/L Daily Composite I & E NH3 as N (April 1-October 31) 1.0 mg/L 3.0 mg/L Daily Composite E NH3 as N (November 1-March 31) 2.0 mg/L 6.0 mg/L Daily Composite E Dissolved Oxygen3 Daily Grab E pH 4 Daily Grab E Total Residual Chlorines 17.0 pg/L Daily Grab E Temperature (°C) Daily Grab E Fecal Coliform (geometric mean) 200/100 mi 400/100 ml Daily Grab E TKN Monitor & Report (mg/L) Weekly Composite E NO3-N + NO2-N Monitor & Report (mg/L) Weekly Composite E Total Nitrogen, TN 6 Monitor & Report (mg/L) Weekly Composite - E TN Load 7'8 Monitor & Report (Ib/mo) 334,705 lb/yr (until 12/31/2015) 185,345 lb/yr (effective 1/1/2016) Monthly Annually Annually Calculated E Total Phosphorus, TP Monitor & Report (mg/L) Weekly Composite E TP Load 7'8 Monitor & Report (Ib/mo) 14,053 lb/yr Monthly Annually Calculated E Total Mercury 9 Annual Average: 12 ng/L Quarterly Grab E Total Zinc Quarterly Composite E Chronic Toxicity 1° Quarterly Composite E Annual Pollutant Scan11 Annually See A (5) E Footnotes are shown on the next page. Permit No. NC0047597 Footnotes to Table A (1) on the previous page: 1 I = Influent; E = Effluent. See Condition A (2) for instream monitoring requirements. 2. The monthly average effluent BOD5 and Total Suspended Solids concentrations shall not exceed 15% of the respective influent value (85% removal). 3. The daily average dissolved oxygen effluent concentration shall not be less than 6.0 mg/L. 4. The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units. . 5. Monitoring requirement and limit applies only if chlorine is added.for.disinfection. The Division shall consider all effluent TRC values reported below 50 pg/L to be in compliance with the permit. However, the Permittee shall continue to record and submit all values reported by a North Carolina certified laboratory (including field certified), even if these values fall below 50 pg/L. 6. TN = TKN + NO3-N + NO2-N, where TN is total nitrogen, TKN is Total Kjeldahl Nitrogen, and NO3-N and NO2- N are Nitrate and Nitrite Nitrogen, respectively. 7. TN or TP Load is the mass quantity of Total Nitrogen and Total Phosphorus discharged in a given period of time. See Special Condition A (8) Calculations of Total Nitrogen or Total Phosphorus Loads. 8. Compliance with mass limits shall be determined in accordance with Special Condition A (7), Annual Limits for Total Nitrogen or Total Phosphorus. 9. Total mercury shall be limited to an annual average of 12 nglL. All sampling must be done using low-level Method 1631 E. 10. Chronic Toxicity (Ceriodaphnia) P/F @ 90%; January, April, July, and October (See A (4) Special Conditions of the Supplement to Effluent Limitations). 11. See Special Condition A (5) Effluent Pollutant Scan. There shall be no discharge of floating solids or foam in other than trace amounts. A (2) INSTREAM MONITORING REQUIREMENTS Monitoring Locations: Upstream - New Hope Creek at 1-40 Downstream - At NCSR 1107 Parameter Frequency Sample Type Dissolved Oxygen 3/week, June 1 — September 30; 1/week, October 1 — May 31 . Grab' Fecal Coliform 3/week, June 1 — September 30; 1/week, October 1— May 31 Grab Temperature 3/week, June 1— September 30; 1/week, October 1 — May 31 Grab Conductivity 3/week, June 1 — September 30; 1/week, October 1 — May 31 Grab pH 3/week, June 1— September 30; 1/week, October 1— May 31 Grab Total Phosphorus 1/week, June 1— September 30 Grab NO3-N + NO2-N 1/week, June 1— September 30 Grab TKN 1/week, June 1— September 30 Grab PO4 1/week, June 1— September 30 Grab A (3) PROVISIONAL WAIVER OF INSTREAM MONITORING REQUIREMENTS Instream monitoring requirements in A (2) above shall be provisionally waived so long as the Permittee remains a member of the Upper Cape Fear River Basin Association and the Association continues to function as approved by the Division and Environmental Management Commission. If the Permittee does not participate in the Association or if the Association ceases to function, the instream monitoring requirements in this permit become effective immediately; and the Division may reopen this permit by administrative letter to establish additional instream monitoring requirements it deems necessary to adequately characterize the effects of the discharges on water quality in the receiving stream. Permit No. NC0047597 A (4) CHRONIC TOXICITY PASS/FAIL PERMIT LIMIT The effluent discharge shall at no time exhibit observable inhibition of reproduction or significant mortality to Ceriodaphnia dubia at an effluent concentration of 90%. The permit holder shall perform at a minimum, quarterly monitoring using test procedures outlined in the "North Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure," Revised February 1998, or subsequent versions or "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised -February 1998) or subsequent versions. The tests will be performed during the months of January, April, July, and October. Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. If the test procedure performed as the first test of any single quarter results in a failure or ChV below the permit limit, then multiple -concentration testing shall be performed at a minimum, in each of the two following months as described in "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised -February 1998) or subsequent versions. The chronic value for multiple concentration tests will be determined using the geometric mean of the highest concentration having no detectable impairment of reproduction or survival and the lowest concentration that does have a detectable impairment of reproduction or survival. The definition of "detectable impairment," collection methods, exposure regimes, and further statistical methods are specified in the "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised - February 1998) or subsequent versions. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the months in which tests were performed, using the parameter code TGP3B for the pass/fail results and THP3B for the Chronic Value. Additionally, DWQ Form AT-3 (original) is to be sent to the following address: NCDENR/ DWQ/ Environmental Sciences Section 1621 Mail Service Center Raleigh, North Carolina 27699-1621 Completed Aquatic Toxicity Test Forms shall be filed with the Environmental Sciences Section no later than 30 days after the end of the reporting period for which the report is made. Test data shall be complete, accurate, include all supporting chemical/physical measurements and all concentration/response data, and be certified by laboratory supervisor and ORC or approved designate signature. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required, the permittee will complete the information located at the top of the aquatic toxicity (AT) test form indicating the facility name, permit number, pipe number, county, and the month/year of the report with the notation of "No Flow" in the comment area of the form. The report shall be submitted to the Environmental Sciences Section at the address cited above. Should the permittee fail to monitor during a month in which toxicity monitoring is required, monitoring will be required during the following month. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Water Quality indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival, minimum control organism reproduction, and appropriate environmental controls, shall constitute an invalid test and will require immediate follow-up testing to be completed no later than the last day of the month following the month of the initial monitoring. Permit No. NC0047597 A (5) EFFLUENT POLLUTANT SCAN The Permittee shall perform an annual Effluent Pollutant Scan for all parameters listed in the attached table. The analytical methods shall be in accordance with 40 CFR Part 136 and shall be sufficiently sensitive to determine whether parameters are present in concentrations greater than applicable standards and criteria. Samples shall represent seasonal variations. Unless otherwise indicated, metals shall be analyzed as "total recoverable." Ammonia (as N) Trans-1,2-dichloroethylene Bis (2-chloroethyl) ether Chlorine (total residual, TRC) 1,1-dichloroethylene Bis (2-chlbroisopropyl) ether Dissolved oxygen 1,2-dichloropropane Bis (2-ethylhexyl) phthalate Nitrate/Nitrite 1,3-dichloropropylene 4-bromophenyl phenyl ether Kjeldahl nitrogen Ethylbenzene Butyl benzyl phthalate Oil and grease Methyl bromide 2-chloronaphthalene Phosphorus Methyl chloride 4-chlorophenyl phenyl ether Total dissolved solids Methylene chloride Chrysene Hardness 1,1,2,2-tetrachloroethane Di-n-butyl phthalate Antimony Tetrachloroethylene Di-n-octyl phthalate Arsenic Toluene Dibenzo(a,h)anthracene Beryllium 1,1,1-trichloroethane 1,2-dichlorobenzene Cadmium 1,1,2-trichloroethane 1,3-dichlorobenzene Chromium Trichloroethylene 1,4-dichlorobenzene Copper Vinyl chloride 3,3-dichlorobenzidine Lead Acid -extractable compounds: Diethyl phthalate Mercury* P-chloro-m-cresol Dimethyl phthalate Nickel 2-chlorophenol 2,4-dinitrotoluene Selenium 2,4-dichlorophenol 2,6-dinitrotoluene Silver 2,4-dimethylphenol 1,2-diphenylhydrazine Thallium 4,6-dinitro-o-cresol Fluoranthene Zinc 2,4-dinitrophenol Fluorene Cyanide 2-nitrophenol Hexachlorobenzene Total phenolic compounds 4-nitrophenol Hexachlorobutadiene Volatile organic compounds: Pentachlorophenol Hexachlorocyclo-pentadiene Acrolein Phenol Hexachloroethane Acrylonitrile 2,4,6-trichlorophenol Indeno(1,2,3-cd)pyrene Benzene Base -neutral compounds: Isophorone Bromoform Acenaphthene Naphthalene Carbon tetrachloride Acenaphthylene Nitrobenzene Chlorobenzene Anthracene N-nitrosodi-n-propylamine Chlorodibromomethane Benzidine N-nitrosodimethylamine Chloroethane Benzo(a)anthracene N-nitrosodiphenylamine 2-chloroethylvinyl ether Benzo(a)pyrene Phenanthrene Chloroform 3,4 benzofluoranthene Pyrene Dichlorobromomethane Benzo(ghi)perylene 1,2,4-trichlorobenzene 1,1-dichloroethane Benzo(k)fluoranthene 1,2-dichloroethane Bis (2-chloroethoxy) methane Test results shall be reported to the Division in DWQ Form- DMR-PPA1 or in a form approved by the Director within 90 days of sampling. The report shall be submitted to the following address: NCDENR/ DWQ/ Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 * Mercury samples shall be analyzed using EPA Method 1631. Permit No. NC0047597 A (6) NUTRIENT ALLOCATIONS (a) The following table lists the Total Nitrogen (TN) and Total Phosphorus (TP) allocations assigned to, acquired by, or transferred to the Permittee in accordance with the Jordan Lake nutrient management rule (T15A NCAC 02B .0270) and the status of each as of permit issuance. For compliance purposes, this table does not supersede any TN or TP limit established elsewhere in this permit or in the NPDES permit of a compliance association of which the Permittee is a Co-Permittee Member. Total Nitrogen Allocation ALLOCATION TYPE . `SOU_ RCE "DATE ALLOCATION AMOUNT (1) '. .. ' ' ... ''' STATUS ° ' ! " �`. Delivered (Ib/yr) r Discharge (Ib/yr) . Base Assigned by Rule (T15A NCAC 02B .0270) 8/11/09 139,009 185,345 Active TOTAL 139,009 185,345 Active Footnote: (1) Nitrogen Transport Factor = 75% Total Phosphorus Allocation t �. ii•�f }: :,-1 :T' P . TYPE . j ' + .:' } ::, ` SOURCE .i:i ACT, DA 'EY :� ALLOCATION' AIIIIOUNT. (') �r r - r •. • STATUs r.. j Delivered (Iblyr) • r Discharge (Iblyrj Base Assigned by Rule (T15A NCAC 02B .0270) 8/11/09 9,415 14,053 Active TOTAL 9,415 14,053 Active Footnote: (1) Phosphorus Transport Factor = 67% (b) Any addition, deletion, or modification of the listed allocation(s) (other than to correct typographical errors) or any change in status of any of the listed allocations shall be considered a major modification of this permit and shall be subject to the public review process afforded such modifications under state and federal rules. Permit No. NC0047597 • A (7) ANNUAL LIMITS FOR TOTAL NITROGEN OR TOTAL PHOSPHORUS (a) Total Nitrogen (TN) and Total Phosphorus (TP) allocations and Toad limits for NPDES dischargers in the.Jordan Lake watershed are annual limits and apply on a calendar year basis. (b) For any given calendar year, the Permittee shall be in compliance with the annual TN (or TP) Load limit in this Permit if: (i) the Permittee's annual TN (or TP) Load is less than or equal to the effective limit, or (ii) the Permittee is a Co-Permittee Member of a compliance association. The TN (or TP) Load limit in this Permit may be modified as the result of allowable changes in the Permittee's allocations. (i) Allowable changes include those resulting from purchase of TN (or TP) allocation from an authorized mitigation banker, the Ecosystem Enhancement Program, or other source allowed under applicable regulations; purchase, sale, trade, or lease of allocation between the Permittee and other dischargers; regionalization; and other transactions approved by the Division. (ii) The Permittee may request a modification of the TN (or TP) Load limit in this Permit to reflect allowable changes in its allocation(s). (A) Upon receipt of timely and proper application, the Division will modify the permit as appropriate and in accordance with state and federal program requirements. (B) Changes in TN (or TP) limits become effective on January 1 of the year following permit modification. The Division must receive application no later than August 31 for changes proposed for the following calendar year. (iii) Any requests for modification should be sent to: NCDENR/ DWQ/ NPDES Programs Attn: Jordan Lake Watershed Coordinator 1617 Mail Service Center Raleigh, NC 27699-1617 (d) If the Permittee is a member and co-permittee of an approved compliance association on January 1 of a given year, its TN and TP discharges during that year are governed by that association's group NPDES permit and the limits therein. (i) The Permittee shall be considered a Co-Permittee Member for any given calendar year in which it is identified as such in Appendix A of the association's group NPDES permit. (ii) Association roster(s) and members' TN and TP allocations will be updated annually and in accordance with state and federal program requirements. (iii) If the Permittee intends to join or leave a compliance association, the Division must be notified of the proposed action in accordance with the procedures defined in the association's NPDES permit. (A) Upon receipt of timely and proper notification, the Division will modify the permit as appropriate and in accordance with state and federal program requirements. (B) Membership changes in a compliance association become effective on January 1 of the year following modification of the association's permit. (e) The TN and TP monitoring and reporting requirements in this Permit remain in effect throughout the term of the Permit and are not affected by the Permittee's membership in a compliance • association. Permit No. NC0047597 A (8) CALCULATION OF TOTAL NITROGEN OR TOTAL PHOSPHORUS LOADS (a) The Permittee shall calculate monthly and annual TN Loads as follows: (i) Monthly TN (or TP) Load (Ib/mo) = TN (or TP) x TMF x 8.34 where: TN or TP = the average Total Nitrogen or Total Phosphorus concentration (mg/L) of the composite samples collected during the month TMF = the Total Monthly Flow of wastewater discharged during the month (MG/mo) 8.34 = conversion factor, from (mg/L x MG) to pounds (ii) Annual TN (or TP) Load (Ib/yr) = Sum of the 12 Monthly TN (or TP) Loads for the calendar year (b) The Permittee shall report monthly Total Nitrogen and Total Phosphorus results (mg/L and Ib/mo) in the appropriate discharge monitoring report for each month and shall report each calendar year's results (Ib/yr) with the December report for that year. A (9) NUTRIENT MONITORING REOPENER Pursuant to N.C. General Statute Section 143-215.1 and the implementing rules found in Title 15A of the North Carolina Administrative Code, Subchapter 2H, specifically, 15A NCAC 2H.0112(b) (1) and 2H.0114(a), and Part II, Sections B-12 and B-13 of this permit, the Director of DWQ may reopen this permit to require supplemental nutrient monitoring of the discharge. The additional monitoring will be to support water quality modeling efforts within the Cape Fear River Basin, and shall be consistent with a monitoring plan developed jointly by the Division and affected stakeholders. A (10) MERCURY MINIMIZATION PLAN (MMP) The permittee shall develop and implement a mercury minimization plan during this permit term. Guidelines for MMP development will be placed on the Division website following a stakeholder review process. The MMP should place emphasis on identification of mercury contributors and goals for mercury reduction. Results shall be summarized and submitted with the next permit renewal application. The MMP must be kept available for inspection on -site. REASONABLE POTENTIAL ANALYSIS Mercury Date Data BDL=1/2DL Results 1 3/5/2008 0.801 0.801 Std Dev. 4.0816 2 4/22/2009 0.679 0.679 Mean 3.4770 3 4/14/2010 1.29 1.29 C.V. 1.1739 4 n 20 5 1/15/2007 1.25 6 4/16/2007 1.72 7 7/16/2007 1 8 1/2/2008 . 18.3 9 4/1/2008 2.97 10 7/1/2008 < 1 11 10/1/2008 1.11 12 1/1/2009 . 4.38 13 4/1/2009 4.21 14 7/1/2009 8.15 15 10/1/2009 4.88 16 1/1/2010 6.19 17 4/1/2010 . 4.82 18 7/1/2010 2.39 19 10/1/2010 2.7 20 1/1/2011 1.7 21 4/1/2011 < 1 22 24 25 26 27 28 29 30 V / I e ('() 31 32 33 34 35 36 37 38 39 40 41 42 USE ONLY "PASTE SPECIAL - Values" WITH "COPY" 1.25 1.72 Mult Factor = 1 Max. Value 18.3 Max. Pred Cw 2.97 0.5 1.11 4.38 4.21 8.15 4.88 6.19 4.82 2.39 2.7 1.7 0.5 4.06 18.3 ng/L 74.3 ng/L 1 2 3 4 5 Molybdenum Date Data BDL=1/2DL 3/5/2008 6.7 6.7 4/22/2009 1.3 1.3 4/14/2010 >43 3.13 3/13/2011 2.5, 2.5 Results Std Dev. Mean C.V. n USE ONLY "PASTE SPECIAL - Values" WITH "COPY" 2.3262 3.1929 0.7285 24 6 1/15/2007 < 5 \ 2.5 Mult Factor = 2.48 7 4/16/2007 < 5 2.5 Max. Value 13.0 ug/L 8 7/16/2007 < 5 '2 5 Max. Pred Cw 32.2 ug/L 9 10 1/15/2007 13 13 11 4/16/2007 5 5 12 7/16/2007 < 5 2.5 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 A (t0 W4i b k r13 CenCen-11-476, oh - 1 /1 /2008 < 5 2.5 4/1/2008 < 5 2.5 7/1/2008 < 5 2.5 10/1/2008 < 5 2.5 1/1/2009 < 5 2.5 4/1/2009 < 5 2.5 7/1/2009 < 5 2.5 10/1/2009 : < 5 2.5 1/1/2010 < 5 2.5 4/1/2010 < 5 2.5 7/1/2010 < 5 2.5 10/1/2010 < 5 2.5 1/1/2011 < 5 2.5 4/1/2011 < 5 2.5 Peten4 DGA_ 6 0- 20/1-- cu t/. 20)2 Aki5a�►fn . vat 'S4wpie re.fv1i 1• 67 vI/L r4&-x (wcvN( S4 p(e %2e.v ( = 3-68 log fL (o cr c ) No T13EL. opiatr b(e- (#& l- ? [7 n5/L M I�i urahm New RPA, data 1 7/20/2011 c(ed-,� a eve 14J /L DURHAM 1869 CITY OF MEDICINE * * ** CITY OF DURHAM DEPARTMENT OF WATER MANAGEMENT 101 CITY HALL PLAZA • DURHAM, NC 27701 919-560-4381 • FAX 919-560-4479 November 5, 2012 Gil Vinzani NPDES Program 1617 Mail Service Center Raleigh, North Carolina 27699-1617 Administration 919-560-4381 Customer Billing Services 919-560-4412 Laboratory Services 919-560-4386 Plant Maintenance 919-560-4388 Regulatory Compliance 919-560-4381 Utility Engineering 919-560-4381 Wastewater Treatment North - 919- 560-4384 South - 919-560-4386 Water Supply & Treatment WiI!iamc - Q1Q-SFr1-434R -.3 r - —'U NOV 7 2012 DENR ✓ATE POINT SOURCE BRANCH BRAi JCH The City of Durham wishes to petition for a reduction of monitoring for effluent total mercury at the South Durham Water Reclamation Facility, NC0047597. Monitoring frequency is currently once per month and this request is for a reduction to quarterly monitoring. This request is allowed by the terms in our permit. Laboratory results for 13 consecutive months of sampling are attached. All of the results are under the water quality standard of 12 ng/L. If you have any questions, please call me at 919- 560-4386. Sincerely, Charles Cocker Superintendent Attachment 1/0 3 (7; - m, f t/il 0 4 Ate s4-tehl 11' Mot./ /K""() Annaofr. l o a „th, AMP re vtrsl+t'.4 14.1 n } rf1 Durham — Where Great Things Happen South Durham Water Reclamation Facility NC0047597 Effluent Low Level Mercury Sample date Result October 10, 2011 November 1, 2011 December 1, 2011 January 9, 2012 February 2, 2012 March 5, 2012 April 16, 2012 May 7, 2012 May 22, 2012 June 5, 2012 July 9, 2012 August 6, 2012 September 4, 2012 October 8, 2012 poi-131 i v Z 3.88 ng/L <1.00 ng/L <1.00 ng/L <1.00 ng/L <1.00 ng/L 1.80 ng/L <1.00 ng/L 1.16 ng/L <1.00 ng/L 1.37 ng/L 2.09 ng/L 1.72 ng/L <1.00 ng/L <1.00 ng/I !.5