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HomeMy WebLinkAboutNC0072575_Response to Notice_20221018pligrinnt. October 18, 2022 Vanessa Manuel, Assistant Regional Supervisor NC DEQ- Division of Water Resources Raleigh Regional Office 3800 Barrett Drive Raleigh, NC 27609 Re: Pilgrim's Pride, Sanford Processing Plan NOV Tracking No. NOV-2022-LV-0672 NPDES Permit No. NCO072575 Lee County Dear Ms. Manuel: Pilgrim's Sanford Plant is in receipt of the Notice of Violation & Intent to Assess Civil Penalty dated September 23, 2022. Pilgrim's personnel have taken significant effort to understand or uncover the reason for the elevated BOD value on July 1, 2022. This Pilgrim's facility has not had a BOD permit exceedance for over 6 years, so this elevated number is certainly unusual for the site. In addition, the BOD data for the Monthly average for July was 0.74 (including the 15.5 mg/I exceedance). Pilgrim's requested the laboratory provide copies of the Quality Control (QC) data, see attached letter from the lab. All QC met analytical standards with the blank being the only QC that was close to exceeding test standards at 0.19 with the limit being 0.20. As quickly as possible after the results of this sample were found to be elevated, the sample was re -ran out of hold time. The results of that test was <2.4 mg/l. Pilgrim's staff also performs Root Cause Analysis (RCA) any time a value exceeds permit limits. Please find attached Pilgrim's accompanying RCA for the BOD anomaly. aa8eueyq xaldwoD aa8eueyq leluawuoilnu3 xaldwo:) me45 laluep �Aalpad eu1 'AlajaaulS 'LSVE-S68-616 le aw peluo:) slew noA suoilsanb glue 9ne4 nog( pino4S '.,Ajjouorlualuj to Ajjnjjjrm papwwoa lou som„ uo13eloln a41 pue „uorloinp foujw„ la Alulelpa:) sem uolleloin 843 uorllppe ui yljoaij orjgnd to luawuojjnua ay1 of w.roy ou o; apig ur paljnsal loyl uorlajojn .rourw o sluasaldaf„ Alule:pa3 uolleloln s141 •uol3elolA i gall 5141 aol panssl aq Aouapgacl to aMON a wnl ul pue aouelldwo3 }o tiols14 2uol a41 uo paseq papuPsW aq AON ayl 1e41 isanbai Allewaol of qq pinom s,wIJBIId •sasuea 8ullejado lewjou ul u1431m ajam Aep 1e43 aol sanlen loiluo:) ssaaad poi a41 •qel pRUpJaa a41411m aldwes lllds a seop qel loiluo:) ssa3oid asno4-ul mo'uolllppe ul '1IwIl alge:wodai a41 uey3 ssal wam Alnf aol saldwes ja43o Ile pue llwll alge:podai a43 ue41 ssal Ile ajam aunt'to 41uow 941 aol s141 ajolaq saldwes lld •awll uollualap Suol a41 uo paseq „luanl}la anal„ ino sloagai elep lsal aldwes auo s143 anallaq l,uop am •llnsai s141 jal}e jo aaolaq 8ulseanap jo 8ulseanu1 sllnsai to puail ou mo4s am sAep 8•£z si walsAs aillua a41 uI A4l:)ede:) :)llneipA4 ino uo paseq awll uollualap ino •sllwll llwjad u143im Ilam ajam uollellwll xeyy Alley a41 papaa3xa 1e41 aldwes ay1 jal}e pue aaolaq Alalelpawwl saldwes •41moa8 le8le loilum of sainseaw Suljel sI A41113el a41 pale:)lpul V38 a41 se pue jeaA to aw11 sI41 anssl ue sl aeSIV •Oog a41 Pasl@J aney slew 1e41 aldwes s141 ul pajnlde� uaaq ane4 pinoa ae8le jo Ssl 10 lunowe hews a leyl lepalod a sl aaa41'Voij lewalul ino pue liodai qej a4143oq ul'aas ue:) noA sd October 5, 2022 Ms. Tina Pedley Pilgrim's Pride 494 Zimmerman Road Sanford, NC 27330 Dear Ms. Pedley: On July 1, 2022, Cameron Testing Services received an Effluent sample from Pilgrim's Pride for BOD analysis. Samples from Pilgrim's final effluent and anaerobic digester were into a 5 day BOD analysis setup according to Standard Methods 521013-2016. The result of the BOD analysis was 15.1 mg/L for the effluent and > 68.2 mg/L for the anaerobic. These were reported on July 20, 2022. At your request, we reviewed the data packet associated with that sample to verify the reported result. The GGA QC standards for the July 1 BOD were 195 mg/L which was exactly in the middle of the acceptance limits (168-229 mg/L). The seed correction was 0.71, also in the middle of the target range (0.60 - 1.40). The blank was the only parameter close to being out of acceptance limts with a A value of 0.19 (limit = 0.20) The QC bench sheets have been included for review along with the bench sheets showing analysis of Pilgrim's samples. In addition, since we run process samples weekly, we know what BOD values expect from samples. There were no anomalies in the other samples in the July 1 st run. Based upon the QCs and results of all other client samples, it is our judgement the July 1 BOD analysis was valid and the values reported to Pilgrim's are therefore also valid. Cameron Testing have been processing Pilgrim's BOD samples weekly for almost 2 years. Without doing a detailed record search, this is the first time Pilgrim's effluent has had a BOD value. Having run BODs for 13 years, seeing a 15 mg/L for an effluent BOD does not raise alarm bells. Such a result is almost always due to some TSS sneaking across from the settling tank. A past client regularly had BOD NOVs for effluent ultimately stemming from the fact his digester had never been cleaned and the TSS values were high. It is not due to chemicals or untreated water in the effluent. We have seldom if ever, seen a cleaner effluent than what we receive from Pilgrims Pride Sanford. Please feel free to contact me if you need any additional information. Sincerely CAM N TESTING SERVICES ris Cameron Cameron Testing Services Analyst CSC CARBOY 16-4 Initial Prep Reagents Dilution Water Nutrients (1 mg/L) Seed (time) BOD (5210 B - 2001) Start Date: 07/01/22 Start Time: 1730 Inc. Temp: 20.0 DO Calibration 8.41 DO Slope 87.4% NCDENR WWlGW Cert 0654 US EPA Lob Cart # NC0191 B Read Date: DW Cert # 37799 07/06/22 Read Time: 1700 Inc. Temp: 20.0 R RA Seed 312105 Nutrients Glutamic Vol (L) 19 FeC13 19 CaCh 19 M902 19 Na2HPos Dil. Water 1400 Aeration 1400 Decant 1730 19 Sample ID Bottle seed Vol (mL) DOI DOf ADO BOD Drift Check 8.0$ 7.88 Blank 58 0 8.47 8.27 0.20 High Blank 59 0 8.46 8.27 0.19 Good 0.20 1 37 9 8.39 6.39 2.00 0.67 2 38 12 8.45 5.42 3.03 0.76 3 39 15 8.43 4.90 3.53 0.71 Seed Correction (0.60 < target range a 1.40) CF = 0.71 The seed correct is subtracted from all final ADO values to get the BOD. Adjust as needed until GGA falls within target range. GGA #1, 6 mL 40 3 8.44 3.54 4.90 209.5 GGA #2, 6 mL 42 3 8.45 3.91 4.54 191.5 GGA #3, 6 mL 43 3 8.41 4.01 4.40 184.5 Glutamate/Glutamic Acid (GGA) target BOD =167.5 - 228.5 195116 Drift Check 8.02 7.81 Duplicates o m E mn° m a'% 0 nM. cc c. S a 0.00 0.0 0.00 0.0 Page 1 ameron Testing Services Analyst CARBOY 1b ` "+ Initial Prep Reagents Dilution Water utrients (1 mg1L) Seed (time) Sample ID Drift Check Blank BIank ��� BOD (5210 B - 2001) NCDENR WW1GW Cart #654 U$ EPA l.ab Cary # NCO1818 Start Date: o'7/oljzz Read Date: DWCOO #37799 ,?/ WZZ Start Time: 1,730 Read Time: 7 Inc. Temp: 10_0 Inc. Temp: D DO Calibration j{j -144 DO Slope Seed 31 Z 10S Nutrients Glutamic Vol (L) r — FeCI, 19 CaC6 ! e1 Mgch Z �} NaxtiPO. ! �[ DII.Water Aeration 1—�_ Decant��- Iti3a Bottle (mL) Sead-v°t%1- DOf eD0 BOD 0 ' n n o.IVto! 1 3.T 9 S.'3i b39 3T 12 $.is 5.4z 3 3g 15 8 43 +56 Seed -Correction (d.We.Ttarget range a 1s40) Gp = 11DIV/01 �e seed correct is.suhtracted front all f 21--fADO.�2tues to get the WD. AdJUSt as needed un61 � falls within target range GGA #i , 6 mL �10 3K,,,,GGA #2, 6 mL3GGA #3, 6 mL y3 3At..Di GiutamatelGltitamic AcW (GGA) target SOD = 16.7.6 - 22&5 #DIY/Oi Driff bhook '5 p2. T7 $1 r Duplkaies 0 °m 40.0 a 0.0.0 Page 1 Cameron Testing Services Analyst CSC BOD (5210 B - 2001) Start Date: 07/01/22 Read Date: Seed Time: 1830 Read Time: Inc. Temp: 20.0 Inc. Temp: NCDENR WWlGW Cert #654 US EPA Lab Cert # NC01918 DW Cert # 37799 p, m Q, E c�, �; c� EI J E� o f O O F a 45 0.00 3 8.39 7.02 1.37 66.0 46 7.03 5 8.36 6.71 1.65 56.4 47 10 8.44 7.55 0.89 5.40 48 6.03 0.00 1 25 8.38 7.26 1.12 5 49 100 8.13 6.34 1 1.79 3 50 250 8.07 4.67 3.40 3.23 52 1 6.54 0.00 3 8.32 4.06 4.26 355.0 53 5 8.15 2.25 5.90 311.4 54 5 8.19 3.30 4.89 251 35 1 1 1 10 7.89 0.99 6.90 186 Drift Inc @ 8.00 7.75 55 6.60 0.00 25 8.38 6.72 1.66 11 56 100 8.27 4.80 3.47 8.28 57 250 7.85 1.29 6.56 7.02 2207-0002-02 98 7.71 0.00 25 8.44 6.33 2.11 16.8 PP eff 99 100 8.52 3.38 5.14 13.3 100 250 8.75 0.99 7.76 1 8.46 AnA-03 101 6.79 0.00 20 25 8.43 7.22 1.21 300 102 1 20 100 8.40 6.90 1.50 118 103 20 200 8.36 6.74 1.62 68.2 Drift Inc @ 8.03 7.79 Seed Correction Factor 0.71 QC Notes Sample pH = 7.0 t 1.0, If not adjust to DOi > 7.5 OOf > 1.0 ADO > 2.0 PH = 7.1 * 0.1. Page 1 Cam ron Testing Services BOD (5210 B .2001) tnaiyst a Start Date: o7/OIJZ2 Read Date: Seed Time: 1,1-d.30 Read Time: Inc. Temp: Inc. Temp: O > dCL O. 9JE 3 g.39 'I.o .�■rs �'� 03 10 8-Afq '7. 8s �-� 411 too 9. + 3 6. !)4 50 2.S O 1.01 AQ;7 5Z G.5 3 .3Z 4.0f,, 1 S3 s I 54 S V.I`t 3 � 3 S < irc 1.7S tM 6_r7Z 5� roo $.21 -q.$O 5'7 e5o (. 2.9 Z 5 G.,3O i'i E3� � too � 5 3�3g goo $.75 < 1 lax Ida 531140 f 90 �03 Zao 1. 34. f 7.4 Ott .•� � ,Incs�.�. � ��"��=�'!�G���;,a� �� seed C rection Factor ;e r7; i i' pN �'7 ?3.1:Oe arbt adjust= Page I NCDENR WW/GW Cert #654 US EPA Lab Cart # NCO1918 DW Cert # 37799 #DIV/O! 40 *,; 7DQr: Jr:.-AW:y:Z NOMM6 RCA — Root Cause Analysis / RAA — Report of Analysis of Anomalies Date: Downtime Start: End: Total Downtime: 10-7-22 Department/Area: Equipment / PM #: Analysis Completed by: Wastewater Tina Pedley PROBLEM DESCRIPTION BOD daily max exceeded in effluent sample WHY & ROOT CAUSE WHY? Split sample results from in house lab had results within limits, so sample taken as required WHY? Possible algae in the sample bottle that went to the certified lab WHY? Sunlight caused algae growth WHY? Areas not covered/blocked from the sun in wastewater system WHY? ROOT CAUSE: Brainstorming with consulting engineer and one idea is possible algae in the sample CORRECTIVE MEASURE (How To FIX THE PROBLEM) Working with NCDEQ to try to get them to overturn based on one sample that is not representative of our effluent PREVENTATIVE MEASURE (To PREvENT rr FRoM HAPPENING AGAIN) ASSIGNED TO DUE DATE STATUS Tina Pedley 10/3/22 Closed Covered clarifier trough, getting quote to build walls around the flume where sample is collected, clean composite sampler bottle daily, clean contact chamber quarterly, move fuzzy filter cleaning from quarterly to monthly, purchase refrigerator for holding splits samples until results are received from certified lab Production Maintenance Date PM Modification Needed? ❑ SOP Modification Needed? ❑ SOP Training Needed? ❑ PM or SOP Title: Maintenance & Production Template