NC0004987_EPA Form 1 2014 - Application_20141015

EPA Form 1
RECEIVED/DENR/DWR
OCT 1 5 2014
Water Quality
Permitting Section

Please print or type In the unshaded areas only Form Approved OMB No 20400086
FORM US ENVIRONMENTAL PROTECTION AGENCY I.EPA I.D.NUMBER
1 ��EPA GENERAL INFORMATION s cox
Cansokfated Palmus,Program F NC 0 0 0 4 9 8 7 D
GENERAL (NraJihr n�rrrrruf:,Hrrurr:.,..r"brfivr,mnn�)
LABEL fTEMS GENERAL INSTRUCTIONS
If a prepnnuid feat has been pinked, arra 11 in ftdesignated span.Review ate inforrnstlon carefully;If any of h
I EPA I.0 NUMBER is tr,covect,ansa Tdouph i1 and enter are coma data in M
apprvpnate hWn area below Also,it any of the pnpdnbd data
h absent (me use to the tel!of Me Is"space Fats the
III FACILITY NAME PLEASE PLACE LABEL IN THIS SPACE 7nrtsr6aFon roar saoub appeal,phase provke a N the proper
na-in arw(s)below t me Iabel Is complete and con you
V FACILITY MAILING need not complete nems I,Ill,V and N(emepf K$wfiicA
ADDRESS mustbe coli bled regawess).Corroeb as Items of no W*
has been provided.Refer to rhe Inatnrcnons for detalhd sem
VI FACILITY LOCATION dnolpeons and for line WoauthonZations under wtd:h ata
NY Y Collected.
II POLLUTANT CHARACTERISTICS
INSTRUCTIONS Complete A through J to determine whether you need to submit any pemut application rams to the EPA.If you answer yes'to any questions,you must
submit this form and the supplemental form listed In the parenthesis fallowing the question Mark'X'In the box In the third column H the supplemental form is attached If
you answier'ne to each question.you need not submit any of these forms.You may anawer'no'r1 your activity Is excluded from permit requirements,see Section C of the
instnrctiens.See also,Section D of the instructions for definitions of bold-faced terms.
sin•x•
SPECIFIC QUESTIONS YES HoA FDAM SPEGFtC QUESTIONS YEs No FoAm
ATTACHM
A Is this facility a publicly owned treatment works which 8 Does or will this facility (either exis6rg or proposed)
results In a discharge to waters of the U.S.?(FORM 2A) X Include a concentrated animal feeding operation or X
aquatic animal production facility which results In e
N discharge to waters of the U.S.?(FORM 28) Is a „
C Is this a facility which currently results in discharges to 0 Is fhs a proposed facHity(other then those described in A
waters of the U.S.other than those described in A or B X X or B above)which will result in a discharge to waters of X
above?(FORM 2C) r—H.— ,. the U.S.?(FORM 2D) a is „
E Does or wit this facility treat store a dispose of F Do you or will you inject at this facility industrial or
hazardous wastes?(FORM 3) X muNelpal emuare beow the lowermost stratum X
containing within one quarter mile of the wellbore,
„ n underground sources of dnnking water?(FORM 4) ,+ m a
G Do you or will you Inject at this facility any produced water H Do you or will you inject at this facility fluids for special
or other fluids which aro brought to the surface in processes such as mining of sulfur by the Fresch process,
connection with conventianal oil or natural gas production. X solution m ring of minerals,In sdu combustion of fossil X
Inject fluids used for enhanced recovery d of or natural fuel,a recovery of geothermal energy?(FORM 4)
gas or inject fluids for storage of liquid hydrocarbons?
(FORM 4) y w M sr is a
1 Is this facility a proposed stationary source which Is one J Is this facility a proposed statlonary source which Is
of the 28 industrial categories listed In the Insiructioro and NOT one of the 28 Industrial categories listed in the X
which will potentially emd 100 tons per year of any air /� instructions and which will potentially emit 250 tons per
pollutant regulated under the Clean Air Act and may aft ed year of any air pollutant regulated under the Crean Air Act
or be located in an attainment area?(FORM 5) r a and may erred or be located in an attainment areali o N
(FORM 5)
III NAME OF FACILITY
c
1 Sx1p Marshall Steam Station
IV FACILITY CONTACT
A.NAME 6 TITLE(larr,frnr, tide) B PHONE(and rule k not)
c
2 S owe, 1 en Lea nAr'ironmenta 16rofetasional ( 0 ) 3 2-4 0
n I N r r r I r s,14} n
V FACILTY MAILING ADDRESS
A STREET OR P O BOX
e
3 P.O. Ox 1006, Will 1& E 1 K
8 CITY OR TOWN C STATE D ZIP CODE
c
4 Charlotte dc 12J241
e N o ., a .r n
VI FACILITY LOCATION
A STREET,ROUTE NO OR OTHER SPECIFIC IDENTIFIER
e
5 8 z est Hig way 15
is N r
B COUNTY NAME
Catawba
C CITY OR TOWN D STATE E Z)P CODE F COUNTY CODE(Ifb..w)
W-c
T r e l dc 2116142
N
EPA Form 3510.1(8.90) CONTINUE ON REVERSE

CONTINUED FROM THE FRONT
VII.SIC CODES(4-dgk in order of ori
A FIRST B SECOND
7 4911 [le fsiic Services 7 (rF'rrh)
C.THIRD 0 FOURTH
(YwCif-J 7 6p oW
?
VIII.OPERATOR INFORMATION
A.NAME 8 Is the name listed In Item
a Duke Energy Carolinas, LLC (Attention: Allen Stowe) AYES ONO 7
aI's jai"
C.STATUS OF OPERATOR(Fntrr tlr a torr tear,un r rhr annx n btu_r "Ocher."f crfh) D PHONE(area c•oale&rut.)
,r,
F-FEDERAL M•PUBLIC utherthan ederal ortrare
S=STATE ( I ) pr-r.- ult:y (704) 382-4309
P-PRIVATE O OTHER(tprcrJt)
10 M 11 M T '•] T
E STREET OR P.O.BOX
P.O. ox 1 0 Mai Code C 3
a e
F CITY OR TOvvN G.STATE H.ZIP CODE IX INDIAN LAND
�pCharlotte Is the fad dy located on Indian lands?
NC 28201 OYES ONO
m
X.EXISTING ENVIRONMENTAL PER
A.IV:fOES PihTj h, oc Hf,er D PSO .Irr£mtttknu rtue l tfed.Vourcer
C f r i
9 N NC0004987 g p
Npq 12
B UIC r%mk roundIn enicm ofFruktr E.OTHER r cr!'
e ♦ t * (rprrlrfv)
9 U 9 0 6 6 50 18-12 Jir i4r+rnit i+nau:: rr.ut
N / n
C RCRA Nacoal p a'atru E OTHER x N
I I r*p
9 R NCD043678879 g SWP 18-09 WQO000452 tit rr ltd Pocw:/Dls:rlbu:lcn of Ana:S l
SoLidta Permit
XI.MAP
Attach to
this application a topographic map of the area extending to at least one mile beyond property boundaries.The mop must show the outline of the facility the
location of each of its mxdsting and proposed Intake and discharge structures each of its hazardous waste treatment,storage,or disposal fact(lies,and each well where it
k*'ds fluids underground Include all springs,rivers,and other surface water bodies In the reap area.See instructions for precise requirements.
XI NATURE OF BUSINESS(provide a briNdescn bon
Coal fired electric generation
RECEIVEDIDENRIDWR
PICT 1 5 2014
Water Quality
Permitting
XIII CERTIFICATION(see Instnxb'ons)
I cattily under penafty oflaw fhef I have person0y examined and am Aw0ar with the inidm>abon submided Irl tltts apokabon end M sUodynords and M.basad on my
inquiry o/those persons immedslely responsible for obtaining the In/orm ttion contained in the application,f below prat the Information is erre,eccurafe,and complete I
am ewere that there we sigrtit wf penalties for submitting false inkirmai r'on,induc&tq the possibility of#ne and impifsortment.
A.NAME 8 OFFICIAL TITLE(typo or print) B SIGNATURE C DATE SIGNED
Brian Weiske - General Manager III,
Regulated Fossil Stations
COMMENTS FOR OFFICIAL USE ONLY
e
C
N M
EPA Forth 3510.1(8-90)

Outfall Locations

•;Y��f' '� i� -f+a:'rti%1, y, f.'•.�'• .� �j F4•t �. Y `.r �•l JJ '•'',1: �Y }• •Rwt.
�(-!Yi y e,�•s Mfr t �*TiL':�'LL �l' t 3:Rt�il, it �. ! ! .�'t�`�if� til.
•� J T ,i1�3t}}•• _�i• '.= . r�,A►1�II,... i �...AI•y,»` •��••ii . .�:� ZS�Y�/♦.�� :'l�l.' ,lS�y+ ��.
+•'I,aYt it•,��'11Ls��•��:.� a yY.••,.1''r••'. �'-✓'� t:�'r r ~
t '1� �'' .,_. jr ._ 'J ��� •� '.-, ` I a }^A �,J�K
Y.. 'tYi '..•.41
V.X1 K/i 'ff tiLIR f [ir,•,
Y.
t,,((�+-�'L�� f�• w:.t li ' •.J`j��ff-�1�.:j� {',{,.,,,'��" y� •i} ♦ , � `i �• .r 4�a7
+� ti;. ^�j'}.�:•1;y�`•�',x s:jw'4�•':!,;?:•-rs.�•t� �' _ r.^ r� r f '✓.lta"5`'
a,J,y;.1L'''� r• .S`' 1 r �, ' : N�� JryfLt
?� ''` ;.� ��, i• 1, ��,� �+Y: � � Tr+ `.#. C•' fr' :'� !.',. .,';,r `l r •t ,
y-•`� ,,rw�r t.:t �� t+rjn'� i +�r�1�� �36,rk �,'�jr'CK'�,.'",�i9'M ; ; y �•,` s• '� ';�'
"sVZ `• , rj`�,j • ��j.�r,,� _ .1"T
'.� F . �• yt',•�.✓',�,n 1� Z 11. � rL�1i`^ l t, ,M•�"f•Y, � O�„
'�•t•': I�.,A+ t;�;• .`� ;� RC1;' xt. � .a• c r ; +�:' ' •�•
.„rt J., tt t1 -�r It.�.b•��'.F■+•tea'.�'�• t� � f ''��- .•t ,, _ r,•��><t' 4�`'� �i���0
rt- ►• j1' '� " T � ri .-„�. -r� ,may? !1 '�
�•--� _ n r till �;•h: rY �_ r 4,c• .r+d' "� �1jw �'� �,�
� ,I
•I{.�� r j�c? •�w� ��•. aJ Ali. ,`�� Ki.L ��i i •�,• f`(�{1 ,�'y+jS.^ .. 1•Nj �.iLs�
; � f Ys r ' `�•�•�s a., tr'jtj. LFL.; , -1i
, ••..'tsr s� ' i•''� � a� I"1:•i�a� a1•.'� -'"wrL 'M i=►'�k� t t• � .�5� {�L
.Y:rte.•,,:i, /� �7r ant. V;•.'i+ 1�y �••~.(�,�1 .: ;�.,•,i��'jJ'�e' _N'.r�•• .~'dti •-t. 'L.
te L f�i :J •• ��•♦ .-•',fie 1 •'-�,... -!z f �. . J t• :' •r^� 1tif
Alt
Illy
�'••,� `Y�'d ,� 004 ,T•FT's� .y{L,: _yahL�; �2�� :,�.r•:• ;� `- ,,.�, .
iw
,'•r''1 �.. �},cL'� .-•. Tc16 ':•��.•S s'-:.s „r ;t�w..<.:,�.'y; .�1, •; ' S;'t
Y %1rY, jam- 44t._ ”♦x `�. R 3��, �(�7•_�� S.
71
`'��r •' ~�r ` a� '� ��. ,' "" �' ••C :✓ tE� .♦ � }t.
"4a4la"'+`l-'��FjT f�3it. :{\t•_''i�-•.y-••.•••$�,•.�t 11..+1 '���..�``T"•.1 l iQ♦77•`(^y4{�•yZ',�y♦ry'vff.f-r�'+�r.`.t�Y!•:+.'-�'v.�hri����-rJ-J�{_r1 •j r�r4��C� �.��a+�'`•��•.',•L~af.s't «':P'�;...Cr�a�Fy.!„q�i►"l-S1.•��r �l,•)��iI.
♦ WZ—i-
j
'toN1Ctb�
�y
•?,
,Ei �.rK✓. •{ Jy
Q •r�` ){fir" .•.-,•y., ;' 1.•L{ .'t r {. rr1•.•.
Y; ..t • . << r r.,rti � 00 - , d '`txat� t'L;1
4e. t� •;r::.' Caal a ti•- �,_�'�v 1,�j�Jl� r , ^ �• j. i ` ` c..
%� �• 'fit , �'a .,•« X••�-.t-
�• i _ . jft�..7 •�•1L• 1►x Ir r
� -�;��;� r�,v' �.�Mat'ahall. .•�,'r'�001 .: '�. t -���,t �; __� �t. .Lt' �. 7
� . �h,,%ia: *�.� ;�Steam'Statllinf;&'ti„r-!,,
1L 4 +Y�G r� :��;.!t�'�•T t..n �� t "I:t�;-•, V^ eta�/O
,t�tv )1�' i�S.n �y�4!+ '�s::. -•. •♦r•�t.%. ♦ 1 : ±�'':` •r •61
•r * ►'.
��: i' a IICr r �l•t•• li• - r /
`� 7 •KF• •
..:� y1Zi.• ,��r;i�,;�.'�.i� �'7•• •a' ,�. -' .'T 4.. �f f �c ��"' .,�•� .�1 •�
ci •-.✓-. =�^�`« r1) f�• Y��.+T :�i L.Y J - ti-, i' f•�',i:l;`- -'•�'�r.};'���'r.. -+'.•'=f�'.
`w,: '; r'aT :`” �r{ y, r�*�i.' /�.. "i'• t,_� aP !.•jr r r.r: t��lr:l1
."�!.,;► �,.. �^+1`• h, L v' Legend ?i•
"r•I1'�:` �Yi _ ,i+ �,f + j►
U, MPQESOrN1ACLomfict1
C�' t�.. �' , ..,���L ��i,�:�:�• "''" j`?. ;,�+.i ,/. ..r. Mar •
•,�, .• �+ • �j., ;.t.• wok ® NPOE5 putt
3� :L,�Y�M A' 'i+ i�* �r .its. 4.`, DAC Enarpy Property Boundary
REFEAEMCE: 1/"
0 015 1
6ALROROImDATA.115osTOI'OOnAmmouA0 WAS 00TAINEDFRUUN000TC•E00PARINCAL ICilOmelt:fs
INFORMATION(001WEMTF.THE MWERTY DATA W kS 06TALWn FWU TT(CATAWBA r.01NFTY L
AMMTHCA110LWAGOCEPAMMEM REASENOYETMS DATA 16FOR o4rogw*NAI_Pt1ProSE5CNLY 0 0.5 1
Miles �
SCALA AS SHAWN LOCATION MAP DUKE ENERGY RGURE
NO
PATE 10-15-2009 Duke MARSHALL STEAM STATION
CRAWN BY RDP NPDES# NC0004987
PRCUECT NO Energy® MARSHALL STEAM STATION
1411-06.140 CATAWBA COUNTY,NORTH CAROLINA

EPA Form 2C
RECEIVEDIDENR/DWR
OCT 1 5 2014
vvater ouality
Permitting Section

EPA 10 NUMBER(C"yn jmmn tram 1 djl•rrn!) Form Approved.
rxC0004987 OMB No.2040.0086.
Please print or type fn the unshaded areas only. Approval expires 3-31.98
FORM US ENVIRONMENTAL PROTECTION AGENCY
APPLICATION FOR TO2C �/EPA EXISTING MANUFACTURING,COMMERCI AL,MINI GRGE AND SILVICUWASTEWATLTURE URE OPERATIONS
NPDES Consohdafed Permits Program
I OUTFALL LOCATION
For each outfall,list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water.
A.OUTFALL NUMBER B.LATITUDE C LONGITUDE
(+1 Q) I DEG 2 WN, 3.SEC t DEG 2 ON 3 SEC D.RECEIVING WATER(name)
01 35 35 42 80 57 49 Lake Norman
02 35 36 22 80 57 40 Lake Norman
02A/0028 1 35/35 35/35 55/54 80/80 57/57 52/52 Lake Norman (Intermittent)
03 35 35 51 80 57 45 Lake Norman
04 35 36 38 80 58 04 Internal Outfall to 002 to Lake Norman
If FLOWS.SOURCES OF POLLUTION,AND TREATMENT TECHNOLOGIES
A Attach a line drawing slowing the water flow through the facility Indicate sources of intake water operations contributing wastewater to the of luent,and treatment units
labeled to correspond to the more detailed descriptions in Item B Construct a water balance on the line drawing by showing average flows between Intakes,operations.
treatment units,and outfalls If a water balance cannot be determined(e g for cerfain miring aUrvi✓res) protide a pictorial description of the nature and amount of any
sources of water and any collection or treatment measures.
8 For each o1Afall,provide a description of (1)All operations contributing wastewater to the effluent inducting process wastewater,sanitary wastewater coaling water,
and storm water runoff (2)The average flow contributed by each operation and(3)The treatment received by the wastewater. Continue on additional sheets if
necessary
I.OUT- 2 OPERATION(S)CONTRIBUTING FLOW 3.TREATMENT
FALL b.AVERAGE FLOW b.LIST CODES FROM
NO.(list) a OPERATION(fur) (rmlude unas) a DESCRIPTION TABLE 2C-1
Condenaer Cooling rater ?15.9 MCI) s:roea dlacha73• tv sur
T-
ool r 1T
(once through don-contsct!
9A
Include# intake screcn backrasn
Jus basin ala�.bat3n ■anitarr
oat l !CD cnamlul caaguUtlan, sealing. ncuccalL-atton, JC it
■ystem ■ffluen: and ac rm rater ion exchange, surface racer dlsc.•urge
7.
eA
Gergsncy 0vorflor of yard drain Intarmlccent surface rater dLscharge aA
002A
0 02 B sump 11 (001AI and aunp a (00231
See aupplemantal lrfor.atlor.
003 Induced draft fan control 0.2 rG0 surface racer discharge aA
Iouse cooling rrer
(once through non-coauctl
Constructed treateenc retl—le sed uaanceclon
oda 1.17 � i-
reducclon
2L
OFFICIAL USE ONLY(efJlurntgvid drier sub-tnrep riei)
EPA Form 3510.2C(8.90) PAGE 1 of 4 CONTINUE ON REVERSE

CONTINUED FROM THE FRONT
C Except for storm runoff leab,or spas,are any of the discharges described in Items 11-A or g intermit(erd or seasonal?
m YES(C—ffa k I&Jrtl::N mg taNr) ❑NO(lm to 4roon Ili)
3 FREQUENCY 4 FLOW
a DAYS PER B TOTAL VOLLME
2 OPERATION(s) WEEK b MONTHS a FLOW RATE(lawsall -t,
I OUTFALL CONTR18UTINGFLOW (4+t)' PER YEAR t LONGTERM 2 MAXIMUM I LONGTERM 2 MAXIMUM = DURATIONNUMBER(kit) (lift) arsmxe) N-6 s xv) AVERAGE DAILY AVERAGE DAILY
002A Emergency overflow of yard drain sump See See See See
01 see supplmental information) Supple Supple Supple Supple
mental mental mental mental
InLcrmat Informat Informat Informat
Ion Son Lon -ion
0028 Emergency overflow of yard drain sump See See See See
42 tsee supplmental informati=) Supple Supple Supple Supple-
mental mental mental mental
inf:,rmat- Informat- Informat- Informat
ion ion ion -ion
III PRODUCTION
A.Does an effluent guideWhe limitation promulgaled by EPA under Section 304 of the Clean Water Act apply to your taolity?
®YES komyi,tr/I'm 111.8) ❑NO(.,m 1a Secthw ll)
B.Are the limitations in the applicable effluent guideline expressed in terms of production(or other measure of opembon)?
❑YES{cotarJi tr it, ln�o ®NO(Am to 14-cls—11)
C If you answered'yes'to Item III-g,fist the quantity which represents an edual measurement of your level of production expressed in the terms and unds used in the
applicable effluent guideline.and indicate the affected outfalls.
1 AVERAGE DAILY PRODUCTION 2 AFFECTED OUTFALLS
a.QUANTITY PER DAY b UNITS OF MEASURE c.OPERATION PRODUCT.MATERIAL,ETC (lilt outfalf numban)
(area,jh')
NA NA HA NA
IV IMPROVEMENTS
A Are you now required by any Federal, Sole or local authortty to n)"any Implementation schedule for the construction, upgradshg or operations W wastewater
treatment equipment on practices or any other onvirorwnental programs which Piny axed the discharges desenbed in this application?This includes,iota la rM lImited to.
pemdt conditions,admiruslrative or enforcement orders,enforeemnnt con once schedule letters,stipulations,court orders and grant or loan conditions.
❑YES(a»ntplete the fitlkrvitrx mNe) NO(yin tv lnem it-In
1 IDENTIFICATION OF CONDITION, 2 AFFECTED OUTFALLS BRIEF DESCRIPTION OF PROJECT 4 FINAL COMPLIANCE DATE
AGREEMENT,ETC
a NO D SOURCE OF OtSCaaARGE a.REAL REQ D PROJECTED
B OPTIONAL You may ahach additional sheets describing any additional water pollution Control programs(or other environmental projects whch may ailed your
discharpes)you now have underway or which you plan Irdicale whether each program is now underway or planned and indicate your actual or planned sc hedu'es for
construction
❑MARK'X'IF DESCRIPTION OF ADDITIONAL CONTROL PROGRAMS IS ATTACHED
EPA Form 3510.2C(8-90) PAGE 2 of 4 CONTINUE ON PAGE 3

LD NUMBER(oryfmm Item I ifi-orm 1)
CONTINUED FROM PAGE 2 FEPA
0004987
V INTAKE AND EFFLUENT CHARACTERISTICS
A,B.S C: See instructions before proceeding—Complete one set of tables for each outfan—Annotate the outfall number in the space provided
NOTE:Tables V-A,V-B,and V-C aro included on separate sheets numbered V-1 throgh V-9
D Use the space below to list any of the pollutants listed In Table 2c-3 of the instructions,which you know or have reason to believe is discharged or may be discharged
from any outfall.For every pollutant you list,briefly describe the reasons you believe it to be present and report any analytical data In your possession
1 POLLUTANT 2.SOURCE 1 POLLUTANT 2 SOURCE
See Supplemental Information,
Table 5.1 lattached) for
complete list
VI POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS
Is any pollutant listed in Item V-C a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct?
YES(lar all.0 ch firllotmis hehhw) m NO(luno to Item 1 I v)
EPA Form 3510-2C(8.90) PAGE 3 of A CONTINUE ON REVERSE

CONTINUED FROM THE FRONT
VII BIOLOGICAL TOXICITY TESTING DATA
Do you have any knowledge or reason to believe that any bidogkW test for acute or chronic toxicity has been made on any of your disdarpes or one rete ting water in
relation to your discharge within the,last 3 yeWS7
QYES(Wear,-A,lair.1 oral A.urthe their purprees behn,) NO(}m ru tiecm,n V111)
Quarterly analysis of Cericdaphn:a Dubia chronic testing per current permit requirements on Outfall 002
Vlil.CONTRACT ANALYSIS INFORMATION
Were any of Ute analyses reported In item V performed by a cmntroci laboratory or consulting rrrm7
®YES Val the name addict.,sal nelepin,ne number r f am!pallmanrt pro11_eJ1) E]NO(go h tic,rho,1.11
ern*such Witnutav arfirrd below)
A.NAME B ADDRESS C TELEPHONE D.POLLUTANTS ANALYZED
(arra:rile,f n,,.) (HSI)
Shealy Environmental 136 Vantage Fzint Drive 6);-791 97):' BCD,color,sulfide,sulfite,
Services,Ine. West Calumbia, S' 2917: fecal coliform,surfactants,
cyanide,phanol,volatiles,
semi-volatile,scid
eompoundo,PCBa,peaticides,
mercury
SGS Environmental Services, Inc. 5500 Business Dr. 910-3501901 Dioxin
Wilmington, NC 2840S
GEL Laboratories LLC 2040 Savage Road 841.556 9171 Radiological
Charleston, SC 29417
Duke Energy Analytical 11119 Nagers Ferry Road 980-875 5375 Metals,COD,TKN.oil L
Laboratory Nuntersville, NC 28070 gresse,total
phosphorous,TSS,TOC,
bromide.sulfate,fluoride,
nitrate-nitrite
IX CERTIFICATION
I certify under penally ollaw that ttis doarmerd and alt eacMre1113 were prepared under my rfrecfion or supervision in accordance with a system designsd to Assure that
qua0ed personnel property gather and evaluate the kJorrnsbon submitted Based on my kWry of the person or persons who manage the system or(hose persons
dreary responsible lar gathering the infonnabon,the inlonnabon submitted is.to the best of my knowledge and betel,hue,accurate,and complete.I am aware Mat utas
ars sigmficant penatbes for subtnitong false information,bWu6ag itte poswbrbfy of lane and impitsonment for knowing vWsbons.
A NAME&OFFICIAL TITLE()pr wjl tni) B PHONE NO (arra tate i rn,.)
Brian Heisker, General Manager III, Regulated Fossil Stations [phone]
C S TORE D DATE SIGNED
EPA Form 351(•=(8.90) PAGE 4 of 4

PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D.NUMBER(copy from Item I of Farm I
this information on separate sheets(use the same formal)Instead of completing these pages. EPA Facility Name:
SEE INSTRUCTIONS NCO004987 Marshall Steam Station
OUTFALL NO.
IFINTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 009
PART A-You must provide the results of at least one analysis for every pollutant m this table. Complete one table for each outfall. See instructions for additional details.
2.EFFLUENT 3.UNITS 4.INTAKE(opWnal)
1 POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE
04we&eb+e) IaarNabM) d.NO.OF a.Comm- b.Mass b.NO.OF
(1) 121 Masa 1)C.WKe1eabW (2)Mass (1lcacentrnron 2)Mtts ANALYSES trawn o)Concebmwn (2)Mass ANALYSES
rc-'
wn"O.Ow < 2 < 244175 1 mgA IND" < 2 1
(0001
20 < 2441747 1 mgA IbiDay < 20(COO)
rww 24 29WI0 1 m9A Iboay 24 1
-ad ,(TOc)
TeW swpenaea < b < 610437 1 -0 bNDay < 5 1
(15SI
AamnYa(aa N) 0.070 9279 1 nw INDay 0.009 1
Plow VALUE VALUE VALUE VALUE
14417 141111.111 94501 730 MGD WA
Twrww xe VALUE VALUE VALUE VALUE
,,,yam) ISO DEGREES CELSIUS
Taipeebse VALUE VALUE VALUE VALUE
mel 160 DEGREES CELSIUS
PN MMNMUM MAXIMUM MINIMUM MAXIMUM
1 STANDARD UNITS 7 1
ART B-Mark'X'in column 2a for each pollutant you know or have reason to believe is present.Mark'X'in column 2b for each pollulanl you believe to be absent.If you mark column 2a for any
pollutant which is limited either directly or Indirectly but expressly in an effluent limitations guldefine,you must provide the results of at least one analysis for that pollutant.For o61er pollutants
for which you mark column 2a,you must provide quantitative data or an explanation of their presence In your discharge.Complete one table for each outfall.See the inslrucbons
for additional details and requirements.
1-POLLUTANT 2-MARK x 1 3.EFFLUENT 4.UNITS 5.INTAKE(optional)
ND CAS NO. aaMved a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM F
•pe (a a•aaaela) fa arasaMa) d.NO.OF e.Careen- b.Mass b.NO.OF
seri 11)con.dw.twr (21 Mau IIIcareenvabm 12)Mass (IlCancenastim (2)Mab ANALYSES iration 1)Cerwntratla ANALYSE
eranoa X <' 0.10 < t220.9 1 mgA w wy =e. 0.10 1
249�Ab7.9) - f
chi ey . X s 0.05 < 610.4 1 m9A h0ay < 0.05 1
oW PAmhd W
Cite X < • 25.0 WA WA NIA 1 Sid.Units WA < 25.0 NIA
F" X 10.0 WA WA NIA 1 Colonies NIA woo WA 1
Data'+ f 1(70 ml
Alorba X 0.10 < 12209 1 RW 1brDay K. 0.10 1
169544")
.Nroate X ZI 0.32 38580 1 mgA Ibmay - 0.3t 1
ae(aaNl
FPA Fan 351420IRw.2-65) PAGE V•1 CONTINUE ON PAGE V 2

EPA I D NUMBER(copy from Item i of Form 1) OUTFALL NUMBER
I TCM V Ii CONTINUED FROM FRONT
z MARK x o frO^a
AND CAS NO se6e ad a.MAXIMUM DAILY VALUE b.MAXNAUM 30 DAY VALUE c.LONG TERM AVG-VALUE a.LONGTERM AVG VALUE
d arYaoef) a.pre- 0 atr (d ard+ael (d aradaetel d.NO.OF a CowAo- b.Mass b.NO.OF
,ane sem (t)Correntration 121 Maas (1)Corwww Dom (2)A1asa (1)Conca tt- (21m� ANALYSES"ion (IIComm"aban 121 mass ANALYSES
muga
toW OrgaNc A '"-� 0.52 82997 1 mgA IhrUay .� 0.54 7
n N)
A Tj 5.00 < 81044 7 1 rTw IbrDay '4', 5.O(1 l
a P).Tow A ? 0.033 4U2 9 1 rTW Wuay _�; 0.032 1
7721 I4-01
t
tow A 5.01 WA WA WA 1 p(;N WA -T 5,00 NIA 1
TOW A Ti 5.01 WA WA WA 1 P(:dt WA r- 5.00 WA 1
Beal A 1.00 WA WA WA 1 pco WA 1,00 WA 1
I
Rmy-
e,%,Tow A 1.00 WA WA WA i puin WA 1.00 WA 1
w
as 504) A 4.80 5w1.9 1 -W (Wuay - 3.80 1
t 4x067491
ass) A 1.00 < lZM.7 1 mgA lw0ay 4.10 1
a
n 503) A 2.00 < 14417.5 1 my (hrUay 2.OU 1
1425645.3)
A -W 0.05 < t11U4 1 rregA ICrDay O-M2 1
ow A 'sl 0.870 10021 ti 1 mgA IdDay - 0.890 1
142490-5)
TOW A - O.Ota 219.8 1 mgA luDay 0.017 1
7440-3331
ow A : 0.074 41(13.4 1 mgA lblOay , 0.050 1
7440.42-0)
ow A 0.001 < 12.2 1 mgA 1010ay 0.001 1
7440-1x-1)
oa
743989-e) A O.T79 9510-8 1 mgA IOA3ay 0.750 1
aw A ".� 1.03 21581.9 1 mgA tlNDay :J 1.54 1
743395.41
aw A 0.001 < 12.2 1 mgA lbfDay 0.001 1
1439967)
ywrs4
Tow A 0.037 4517 1 "W lbruay _- 0.028 1
7434965) ti
T-..
ToW
r440-31.5) A 0.010 < 171.1 1 mgA IbMay 1
0.010
aa�af.
0.027 324.0 1 mgA ItllOay _._ 0.02tl 1
lMLLSL-0)
EPA Poem 3510.2C(Hfv.2-85) PAGE V-2 CONTINUE ON PAGE V-3

L
A I D NUMBER(copy from Own 1 of Form 1) OUTFALL NUMBER
CONTINUED FROM PAGE 3 OF FORM 2-C NC0004987 001 1 Marshall Steam Station
ART C-If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GClMS traclK)ns you must test for.Mark"X'in
column 2-a for all such GUMS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary Industnes,
norprocess wastewater outfalls,and nonrequired GClMS fractions).mark W In column 2-b for each pollutant you know or have reason to bell eve is present.Mark W in column 2-c for each
pollutant you(relieve is absent.It you mark column 2a for any poButanl,you must provide the results of at least one analysis for that pollutant.It you mark column 2b for any pollutant,you
must provide the results of at least one analysis for that pollutant it you know or have reason to believe it will be discharged In concentrations of 10 ppb or greater If you mark column 2b for
aemlein,acrylonilrile,2,4 dinilrophenol,or 2-methyi4.6 dinitrophenol•you must provide the results of at least one analysis for each of these pollutants which you know or have reason to
believe thal you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the
reasons the pollutant is expected to be discharged.Note that there are 7 pages to this pan;please review each carefully.Complete one table(all 7 pales)for each outfall.See instructions
for additional details and reQuirements.
1 POLLUTANT 2_MARK W 3.EFFLUENT 4.UNITS 5.INTAKE(optional)
AND CAS NO. a, t3siered a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE e.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE
ra.arabts> pp• roe.- ca4D to&,Dd§ts) I (denalble) d.NO.OF a.Cancen- IS.Masa I d.NO.OF
as sew sant �1)cecerr50on (2)Mau (I)C.V-WsaoMM 2)Ma (1)Comaa'es5om 1121 Mass ANALYSES irauon (IICOr Wsam if2)Ms" JANALYSES
ALS,CYANIDE,AND TOTAL PHENOLS
r7440,38-21
rAWO". X -4; 1.0 < 12.21 1 WA IIrIDsy '< 1.0 1
7440360)
newc-ToW X 1.0 < 12.21 1 u9A IISDay t 1.0 1
f/.awykm X c 1.0 < t2.21 1 ugA IdDay l j 1.0 1
out(7440-41.7)
M.Caenwun. X -c" 1.0 < 12.21 1 ugA IM32y t 1.0 1
oW(7440-1}9)
.ChMffAan X 'c 1.0 < 12.21 1 u9A IbMay < 1.0 1
oql(7440.47-3)
Carpe.taut X owe 73.25 / mgA Imuy < 0.005 1
74465os)
IM,Load,Taal X 1 < 12.21 1 ugA lbrpay :42 1.0 1
r439.92•tl
Msmxsy.Taal X D"0018 002 1 ugA lboly 0.00153 1
74�97.e)
Mr NI TOW X 1.0 < 12.21 1 ugA IWay < 1.0 1
ra40-02-0)
1014 sewwn, X e". 1.0 < 12.21 1 u9A Iwoay ',e- 1.0 1
aW(7792.49.2)
ISM saw.ToW X 10 < 12.21 / u94 loony `41 1.0 t
1440224)
1214.ThaMu M, X <. 0.001 < 122 1 trt911 IOrDay < 0.001 1
ow J7440.21w)
13M.Zinc,TOW X 0.0048 59"33 1 mgll INDay 0.0024 1
x440.66.6)
1444.Cywft. X "c. 0-010 < 122.09 1 ttrgll INDay 0.010 1
TOW(57-12.5)
15M.PMala. X 00051 62.3 1 mgA Ibuay _ 0.02 1
tap
OIOXIN
-a,7,9 TWO OESCRiBE RESULTS
P X < 10 < 122087 4 1 PO IblDay <,, 10 1
Mn(tT640t�)
EPA Foran 351021c(0.&r.2.85J
PAGE V-3 CONTINUE ON PAGE V-4

EPA I D NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER
CONTINUED FROM PAGE V-3 NCO004987 001 Marshall Steam Station
1,POLLUTANT 2.114ARK W 3 EFFLUENT 4.UNITS 5.INTAKE opllonal)
O CAS NO .�. 6efe.ea a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE a LONGTERM AVG.VALUE a.LONG TERM AVG.VALUE
r erasable) a>,rr• b we- rob IN*,slaw) 1a a xikst e) d.NO.OF a.Correa b.Maas d,NO OF
et aenl sans It1)Caceanean (2)Maas IIICamerabon (2)U. (I)CWwwagom (21►tast ANALYSES tralion (1)Cortcentratlan t21►+ua ANALYSES
CIMS FRACTION-VOLATILE COMPOUNDS
IV AoviW X c. .0 < 6104 1 u914 b5ay < 0 1
r71-43-2)
X < 5.0 < 8104 1 u9A Ih1Day < 50x e, 2.0 < 2442 1 uy,4 ONy2.0 x
542-6&11
v&bnrrorm xa ug20
,52s2) bDt
ay
V Carbon
T eyadYPlOa X �? 20 < 24.42 1 t40 b0ay 2.0 1
•t.2151
CwaobWUerr X c y 20 < 24.42 1 u9A vDay _ 2.0 1
1069P7)
Cl lbroOr
X .e 20 < 24.42 1 UgA INDay 2.0 1
12-4.4&t)
fv
Cttiaowm x c .0 < 24.42 1 UgA bVay < 2.0 1
1?&1-0 31
10V 2-chko-
rfwM Else x %v so < 61 w 1 u9A Ib7Day r7l 5.0 1
UDtS-0)
I IV cAwdam X 2.0 < 24 42 1 ugA INDay 2.0 1
t2V OIdlbr
X <, 20 < 2442 1 ugA taDay 2.0 1
,627-4)
13V 13.20 o
,. X i 20 < 24.42 1 u9A Ib/Day 2,0 1
767141)
14V 1 I-O<liao x c . 0 < 24,42 1 u9A lb/Day 20 1
yr(7634-3)
15V 1?4JclYaas X 20 < 24.42 1 u9A Ib0ay S 20 1
11171-0621
16V t I4Nr7Ma X 20 < 24.42 1 u9A Ib1Day < 20 1
(75-35-4)
1tv t�0+ctfoo- x ti 20 < 24.42 1 u9A Ib1Dey 20
ne(7667.51
16V 11000r x c. 20 24.42 1 u9A lb/Day 20 1
(s.2.7se)
19V Etlrtlbw=m X c 20 < 24.42 1 u9A Ibmay 2.0 1
100-41-4)
xv►tettlyi X 20 24.42 1 u9A EbMay < 2.0(74.6}9)
IV Nevay) X < 20 < 24.42 1 ugA 2.0 1
-
EPA Fo m 151620(Rev.2-851 PA4�1 V-4 CONTINUE ON PAGE V-5

EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER
CONTINUED FROM PAGE V-0 NCO004987 001 Marshall Steam Station
1 POLLUTANT 2 RK'X' 3.EFFLUENT 4.UNITS 5.INTAKE(ophonaq
AND CAS NO. am I Believed e.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE
w ereeeDN) cur• b pr aaa (w 9v0"ble) (e eve4edel d.NO.OF a.Cancer* b Mess d.NO OF
.a 4an sou I1)Concenreron (2)Meu II)Coment ftn 42)Mefe 11)CwwaVr.nwr 121 Mase JANAIYSES tratbn (1>Cancentnoon (21Meaa ANALYSES
.CIMS FRACTION-VOLATILE COMPOUNDS(continued)
2v Melnyr w X c2.0 < 24,42 1 u9A INDay c 2.0 1
'r+uWe(75.0321
N 1.1.2.2-Tetra- 1
•+e X < 2.0 < 24.42 1 u9A IAIDay 20
222-)
IV Teradrwo- X _< 2.0 < 24.42 1 uw IWDay 2.0 1
It27•t9-i)
z5v Taber X t 2.0 < 24.42 1 ugA 16IDay 2.0 1
108.6&3)
.IN 12-T(so-
,,w-.».Mylerr Xc 2.0 < 2442 1 u%A Ib7Day 2.0 1
136-645)
n I t I.I.«w X <- 2.0 24.42 1 ugA IHDay :i32.0 1
11.36.6)
8V t.1.246-
x c 2. < 2442 1 u9A IbrDay 2.0 1
T9-045)
N Tnchi o- x -< 20 < 2442 1 u9A IbJDay f 20 1
(79-01{)
YN Tddiwu
x c 2.0 < 2442 1 ugA 4YDey 2.0 /
7}69.4)
tv V.,p x < < 2442 1 ugA IRDay 2 D
on1
hes 175-01-4)
GC/MS FRACTION-ACID COMPOUNDS
IA.2-C74wipAert x t, 10 < 122.09 1 ugA Ib1Day 10 1
9557-0)
'A 2.44Drlrwa x 1 < 122.09 1 u9A Ib/Day 10 1
x 2,44),Irarw x <4 10 < 122.09 1 ugA wroay 10 1
(105$7-9)
A 1,6.Orwu1130"y
O- X 1 < 12209 1 ugA I10 1
rosdI534.52-11
2.44NnK1 X 77 50 < 610.44 1 u9A b0ay 50 1
ISr•2e-5)
24arodhe4l x < 10 122.D9 t tv ro7Day < 1 t
66.75.5)
A 4 N a canard X c 1 < 122.09 1u9A 16/Day < 10 1
100-02.7)
P4eara64 X < 10 < 12209 1 u911 Off.y c 10 /
(59-50-7)
PenleHdwu X 't` 10 < 122.09 1 mp bDay < 10 7
(67.6&3)
1 W Ph&-" X + 10 < 122.09 1 ugA brDay <i 10 1
t0&9S2)
1 lA 2A.6-Tn-
X c 10 < 12209 1 ugA tdDay < 10 1
6&06.2)
EPA Fare 351420(Rev.2.851 PAUL V5 CONTINUE ON PAGE V6

EPA I.D.NUMBER(copy from uem t of Form 1) OUTFALL NUMBER
CONTINUED FROM PAGE V-5 NC0004987 001 Marshall Steam Station
1 POLLUTANT 2.MARK'X' 3.EFFLUENT 4.UNITS 5.INTAKE(optional)
ND CAS NO. .,s edo vd a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE 1c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE
4.wwble) a.- bpw c.a Id..■+,b1e) pard■w) d.NO.OF a.Corcert- b.Mau d.NO.OF
ed seem serc {+)Cdreena■sert 2)14aa■ It}Catcerar■twt 21u■as f+)C� {2ivaas ANALYSES
-ion fi)Catarttraw+ Iz1ua■+ ANALYSES
GCJMS;FRACTION-BASE NEUTRAL COMPOUNDS
1B.Acan.oh W.8 X <J to 122.09 1 ugA IwDay c 1
&3.32.9)
8 Acen.QeNne X < v 10 < 12208 1 u9A Ib(Day c 1
20696-e I � -
36
Ano acane X t 10 < 122.09 1 ugA IbJDay �_ 10
12412.7)
a Benddirts X < : 100 < 12M g 1 u9A brDay c 100
9247.5)
Brnmtal
X 10 < 122.09 1 WA IbIDay Z_ry 10
*&5&31
Benmta) x < 1 < 1220'9 1 ugA 1 ay �.� 1
150.32.9) _
rB 3,4-0enao
x F, 10 < 122.09 1 u9A Ib1Day < 10
205.99-2) ,ti
JS Benw(ah1 X < 10 122.09 1 ugA ay < 1
eN4nte(191.242}
rk-
11■nm is l
X - 10 < 12209 1 ugA IbfDay 10
207-0tF9)
toe ftp-Cndo
rory)ueawb X Z 10 < 12.209 1 u9A Ib1Day 10
ttt-91.1)
11 B.Bb Q-Chwu
.r1Ebw X Z' 10 < 122.09 1 u44 RYDay _y 10
ttl-4H)
129 Bb(2-CNorono-
wtvol Eaw X 10 < 122.09 1 ugA Ib/Day 1 10
106441)
138.Bb(2'Eb*
plPharwt. Xk-
pr-brIvi
10 < t:1t7<i 1 ugA IblDay - 10
117-041)
148. X Z' 10 < 122.09 1 U911 IC+Day 10
1tw I tOt-55-3) b
150.Bwyt Bew X <77 10 < 122.Q9 1 ugA Ib0ay < 1
ri1700&
7) X <7 10 < 12209 1 u9A Ib1)ay 10
X 10 < 122.09 1 UgA AYDay �' 10
l
ta0 Chmm X < In 122.00 1 UgA lWay c- 10
t 18-01.9)
198.00amota.h)
X < 10 < 12209 1 UgA IbMay c 10
53.743)
9B.12-OK"w X <_ 20 < 2442 1 ugA Ib1Dayc 2O 1
(95.541)
18.1 SOtnyoo X i 20 24 42 1 ugll 1 ay 20 1
ens(541-73.1)
EPA Fv 3510.2C(Pa 2.85) PAGE V-6 CONTINUE ON PAGE V-7

EPA I.D NUMBER(coMfrom Item 1 of Fam 1) OUTFALL NUMBER
CONTINUED FROM PAGE V-6 NC0004987 001 Marshall Steam Station
1 POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional)
AND CAS N0. •.rsM
a. c. a.
w•..a•el•) LONG TERM AVC..VALUE
w• (w•vw•m•) (4-Ad ale) d.NO.OF a.Cocer- b.Mass d.NO.OF
•a (1)Ca Wsucn mm"s (1)co-Atrs* 2)1w4 JIICo enwatcrr (2)Ml ANALYSES Uat10a (1)Canc•rr77ua 2)h4•aa ANALYSES
CIMS FRACTION-BASEINEUTRAL COMPOUNDS(continued)
� 1,404hicr& - -�] 20 < 24 42 1 upA IbfDey T 2.0 1
(10646.71 -
31a 3.3-0-cr4a
X K 10 < 122.09 1 u9A IWDay 10
a 1.94-1)
4!i Dwryl
r."'M X _<..y� 10 < 122.09 1 u9A PoIDay 10
B4f,62)
1S D~VY
nn•la4e X < 10 < 122.09 1 u9A INDay r' 10
11s•u4)
du.Or•N-Butyn
7+fswsa x "< 10 < 122.08 1 ugA IblDay 10
54.74-2)
M.2.443rW X s 10 < 122.08 1 U00 IWDay <-
ok. (121.14.2)
M 2.64DMWro x <� 10 < 122.08 1 U911 IbfDay c 1
d�(60620.2)
DM-Octyt
n►.•+.• X 10 < 122.09 1 U90 IbA)ay 10
is 74")
Im t2-D,p,sryti
.ydebm(as Am- X - 10 < 122.09 1 ugA tWDay 10
ar)(122f6.7)
IQ
iB Flronnitwl• x < 10 < 122.09 1 ugA Ibcay <
20&.44.0) J
-B FkKa x <_ 10 < 12209 1 ugA t ay t10
W T3.7)
tw.nwo o x < 10 122.09 1 ugA may c
p..4(11&141)
8.Ila•-
M+uww,.w4-- x 10 < 12209 1 u0A ItvDay 10
e7-6&3)
.A N•Marlw
yr.l�aw•uar x 10 < 122.09 1 ugA kvuay <l 10
7747-4)
Ibe.Fi•a•crwwtr x t 10 < 122.09 1 1.gA lWay c. 7
'r4(67-72.1)
7B w4ww
12.1aa1Pyro X < 10 iZ2 09 1 u9A Ib0ay 10
193.39.31
tsepnorv> x < 1 < 12209 1 ugA RAMP <y 10
71-50-1) -
i8 N•pM7Wai• X < 1 < 122.09 1 u9A IblDay < - 0
91.20-3)
00.N*Vbff tme x t 1 < 122.09 1 ugA I y < 1
95-95.3) J
18.N-NAro-
e x 10 < 12209 1 ugA IbDay < 10
62.75.9}
0.N-Ntrmotl-
,n.ysrnne x 10 < 12209 1 uo IWDay ;<� 10
621ba-7) .
EPA Form 351 NX(R•r 2-55, PAVE V-1 CONTINUE ON PAGE V-5

EPA I D.NUMBER(copy from item 1 at Form t) OUTFALL NUMBER
CONTINUED FROM PAGE V-7 NC0004987 001 Marshall Steam Station
1 POLLUTANT 2.MARK'X' 3.EFFLUENT 4.UNITS 5 INTAKE(optional)
CAS NO. ..r ae...ed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE
1 T-
11..N.be) vwr• b.prs cot• 1.1..M.bM1 rrl...i.ble) d.NO.OF a.Concen- b.Mau d.NO.OF
ed sera sera t)foncerrtr..on 121me (11Carrvwuen t71M.ss ;11Concern7.bor, 1(21 Moss ANALYSES bation ;I)C..cw&da, 12)MZ ANALYSES
'CIMS FRACTION-BASE/NEUTRAL COMPOUNDS(continued)
,e N•N&o-
X c a 10 < 122.09 1 U911 bmay < 10
063o4i)
p11e,memw X < 10 < 122.09 1 u9A Ib(Day <' 10
SS-01-0)
Se.Pre+. X < 10 < 122.09 1 U911 lb/Day < 10
129-0401
t,7.a7rr
FFFF
2 0 < 24 42 1 WA lWay E 2.0 1
120.62•q
GCIMS FRACTION-PESTICIDES
IP Aldm x
3D9.042)
p e4eHc x
3,984•G1
W bet"HC x
315-awn
P 9vm www x
58-09-91
+e dela-BHC X
319-08-0)
C14prom. x
57.74-9)
7►4.4'-DDT x
5429-3)
P 4 4'-CM x
72-55.9)
,,4'•000 x
n-54-0)
IOP D.1dM x
x457.1)
I1p..en..Fj o"w x
t,o-29-7)
12P bW.+,d."— X
L
IV EAdommism
x
1L x
l x
1rtim x
FPA Fmn 351420(Re..2-05) PAGE v-0 CONTINUE ON PAGE V.9

EPA I.O.NUMBER(copy tram Item 1 of Form 1) OUTFALL NUMBER
CONTINUED FROM PAGE V-8 NC0004987 001 Marshall Steam Station
1 POLLUTANT 2.MARK*X' 3.EFFLUENT 4.UNITS 5.INTAKE(optional)
CAS NO. am Baaavaa a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE
x avaia6k)
I-plwl a Pr► c.ab (w avaYaDb) IN araaatila) d.NO.OF a.Concert h.Mass Id.NO.OF
w iml tent I I I concolusbm 1(2)MMS 11)CaKenVttm i2)Masa 11)calcanlrabcn L(2)man ANALYSES baton (1)C WAW**%W 2)Man ANALYSES
CJMS FRACTION-PESTICIDES(continued)
17P M�pla[111a
w>.wa X
11024-57-31
15P PCB-1242 X <J 0.28 < 1 u9A < , 0 55 1
53169.21.9)
19P PCB-1254 X '- 0 28 < 1 u9A S . 0.25 1
11097-69.1)
,v PCB-1221 X 018 < 1 ugA c 0.25 l
11101.2621
IP PCB-1232 X e 0.26 < 1 u9A < 015 1
11141-16.5)
P PC13-1218 X 7 0.26 < 1 ugA �.,� 0.25 1
12672.29.6)
-'►P PCB-1260 X <t 0.26 < 1 ugA 0.25 1
11096-8251
PC&1DI6 X < 028 < 1
0.25 1
1267411.2)
"I' Tmaplwr X
0001.352{
EPA Fam 3510-2C(tie+.2-85) PAGE V-9

PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA 1.D.NUMBER(copy from Item 1 of Form 1)
this information on separate sheets(use the same format)instead of completing these pages. EPA Facility Nama
SEE INSTRUCTIONS NC0004987 Marshall Steam Station
OUTFALL NO.
V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 002
PART A-You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details.
2.EFFLUENT 3.UNITS 4. INTAKE(optional)
1.POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE
(if available) (if available) d.NO.OF a.Concert- b.Mass b.NO.OF
(1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration 12)Klass ANALYSES tration (1)Concentration (2)Mass ANALYSES
.Biochemical Oxygen ". 2 < 287.1 0 0.0 0 0.0 1 mg/l Ib/Day 0
Demand(Boo)
b.Chemical Oxygen $ 20 < 2870.7 U 00 0 o u 1 mgll Ib/Day U
rand(COD)
0 2727 U UU U DD 1 UTotal Organic 1.9
arbon(TOC)
J.Total Suspended 11 0 1578.9 11 U 15789 6 1 U 392.0 25 mg/l lDay J U
solids(TSS)
Ammonia las N 1 0.26 0 37.2 0 00 0 0.0 1 mgll Ib/Day 0
Flow VALUE VALUE VALUE VALUE
17.2 17.2 7.7 24 MGD N/A
Temperature VALUE VALUE VALUE VALUE
winter) 1 DEGREES CELSIUS
Temperature VALUE VALUE VALUE VALUE
summer) DEGREES CELSIUS
pH MINIMUM MAXIMUM MINIMUM MAXIMUM
24 STANDARD UNITS
PART B-Mark"X"in column 2a for each pollutant you know or have reason to believe is present.Mark"X"In column 2b for each pollutant you believe to be absent.If you mark column 2a for any
pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline,you must provide the results of at least one analysis for that pollutant.For other pollutants
for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions
for additional details and requirements.
1.POLLUTANT 2 MARK'x` 3.EFFLUENT 4.UNITS 5.INTAKE(optional)
AND CAS NO Believed a. MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE
if available) a.pre- b ab- (if available) (d available) d.NO.OF a.Conceit- b Mass b. NO.OF
sent sent 11)Concentration (2)Klass (1)Concenlraton 1(2)mass (1)Concentration (2)Mass ANALYSES tratlon (1)Concentration (2)Mass ANALYSES
a.Bromide X 7, 3.80 U 545.4 0 0.0 U 00 1 mg/l Ib/Day ..J 0
24959-67-9)
.Chlonne, X 777 0.05 < 7.2 0 0.0 0 0.0 1 mg/I Ib/Day 0
Total Residual
Color X -;p 25.0 N/A N/A NIA 1 Std.Units N/A N/A
.Fecal X 1.00 N/A NIA NIA 1 Colonies N/A _ NIA
pldorm /100 ml e.
Fluonde X 0.97 D 1392 0 0,0 0 UA 1 mg/I lb/Day ) 0
16984-4&8)
Nitrate- X 0.60 0 86.7 0 0,0 0 0.0 1 mg/I Ib/Day U
ltrite(as N)
EPA Form 3510-2C(Rev 2-85) PAGE V-1 CONTINUE ON PAGE V-2

EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER
ITEM V-B CONTINUED FROM FRONT Marethall Steam Station
2.MARK"X" 4 ITS 5.IRTAIT-Fo-ptional)
AND CAS NO. Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE e.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE
tl avatlable) 9.pre- b ab- (if available) (if available) d.NO.OF a.Concert- b.Mass b.NO.OF
sent sent (1)Concentrabon (2)Mass (1)Concenuauon (2)mass (1)Concerwabwr 1(2)mass ANALYSES tration (1)Concenbabon (2)Mass ANALYSES
g.Nitrogen,
Total Organic X 8.60 U 1134.4 8.6 U 12;14.4 2.9 U 186.3 25 mg/l IWUay U
as N)
r. i an
rease X 5.W < 717.1 < 5 < 117.7 < 5 < 311.3 8 mg/I lb/Day U
osp orous
as P),Total X - U.6UU U 86.1 U.U6 U 8.6 U.03 U 1.9 9 mg/I IbJDay U
7723-14-0)
II
Alpha,
Total X - y 5.W N/A N/A N/A 1 pCVI N/A N/A
eta.
otal X 5.W NIA N/A N/A 1 pCVI N/A - NJA
Radium,
Total X FM
1.00 N/A N/A N/A 1 pCVI N/A N/A
Radium
26.Total X ". 0.58 NIA N/A N/A 1 pCUI N/A N/A
Sulfate
as 504) X _ 170 U 2441JU.8 U U.0 U 00 1 mg/1 Ib/Uay 0
14808.79.8)
Suffide
ass) X 1.W < 1415 U U.0 U UA 1 mgll IWUay U
sullite
as 503) X 2.00 < 287.1 U U.0 U 00 1 mg11 lb/Day U
14265-45-3)
Surfactants
X 0.05U < /.2 U U.0 U U U 1 mgll lb/Day U
Aluminum.
Total X 0.227 U 32.6 U U.0 U 00 1 mgll IWUay U
7429.91-5)
num.
Total X O.U76 U 1U.9 U U.0 U 00
1 mgll IWUay - U
7440.39-3)
4.Boron.
Total X 7.750 U 1112.4 U 0.0 U U.0 1 mg/I IWUay U
744(}42.8)
cobalt,
Total X 0.0044 U 0.6 U U U U UA 1 mg/1 IWUay _ U
7441-48-0)
ion, ote
7439.89.6) X - 0.4W U 66.0 U 48 0 bb,o U.41 U 28.3 2 mg/1 IWUay U
Magnesium
Diel X +ye, 87.8 U 91318 U 00 U 0.0 1 mg/1 IWUay U
7431-95-4)
olytodenuni,
Total X U.0184 0 2.6 0 U.0 U U.0 1 mgJl lb/Day 0
7439-98-7)
Manganese.
Total X - U.828 U 118.8 U U.0 U U.0 1 mg/l Ib/Day 7-1 U
7439-96.5)
N.Tin.Total
744o-31-5) X - 0.010 < 1.4 U U.0 U U.0 1 mg/1 IWUay U
it itamum.
Diel X 0.W5 c Q7 U U.0 U U.0 1 mgJl IblUay U
i44tru-u)
EPA Form 3510.2C(Rev.2-85) PAGE V-2 CONTINUE ON PAGE V-3

EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER
CONTINUED FROM PAGE 3 OF FORM 2-C N00004987 002 Marshall Steam Station
PART C-If you are a primary Industry and this outfall contains process wastewater,refer to Table 2c-2 1n the instructions to determine which of the GC/MS fractions you must test for.Mark"X"In
column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary industries,
nonprocess wastewater outfalls,and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each
pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant,you
must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for
acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to
believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the
reasons the pollutant is expected to be discharged.Note that there are 7 pages to this part;please review each carefully.Complete one table(all 7 pages)for each outfall.See instructions
for additional details and requirements.
1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5. INTAKE(optional)
AND CAS NO. a, Believed a.MAXIMUM DAILY VALUE jbMAX.11MUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE
if available) quer- b.pre- c.ab- vailable) (il available) d.NO.OF a.Concert- b.Mass d.NO.OF
ed sent sent (1)Concentration (2)mass (1)Concnntration (2)Mass (1)Concentraborr (2)Mess ANALYSES lratlOn (1)Concentrauon I2)hlass NO.
METALS,CYANIDE,AND TOTAL PHENOLS
1M,Antimony. X 1.0 < 0.14 0 U 00 0 U 00 1 ugh Ib/Day 000
Total(7440-36-0)
M.Arsenic.Total X f 14.7 0 2.11 14.7 U 2 11 789 0 0.51 10 Ug/I Ib/Day 000
7440-38-2)
310.Beryllium. X 7r, 1.0 < 014 U 0.00 0 0.00 1 ugll INDay 000
Total(7440-41-7)
M.Cadmium, x 1.0 < 0.14 U 000 0 0 0U 1 ug/l Ib/Day 0.00
Total(74411.1-4.1-9)
1,1.Chromium. X 1.0 < U 14 0 000 U 000 1 ug/l Ib/Day 000
Total(7440-47-3)
'M.Coppet.Total X 0.005 < 0.72 < 0.005 < 0.72 < 0 005 < 032 3 mg/I IWDay 71 U 00
7440-5(l-8)
M.Lead,Total X 1 < 0.14 0 0 00 0 000 1 ug/I Ib/Day 000
7439192-1) -
M.Mercury.Total X _6 1.28 0 018 1.28 0 018 0 73 U 0.05 10 ngll Ib/Day 0.00
7439197-6)
9M Nickel,Total X r- 10.8 U 1.55 10.8 U 1 55 7.4 0 0.48 10 ugli lb/Day 0.00
7440-02-0)
10M.Selemurn. X 6.04 0 0.87 57 0 082 3 19 U 0.20 103 ug71 Ib/Day 000
Total(7782-49-2)
11M.Silver.Total X -_3 1.0 < U 14 0 Vou 0 000 1 ug/l Ib/Day 0.00
7440.22-4)
12M.Thallium. X 0.001 < 0.1 0 00 U 0.0 1 mg/l Ib/Day 000
Total(7440.28-0)
I:iM.Zinc.Total X .LLs 17.300 0 2483.14 17.3 0 2483.14 7.687 U 493.94 26 ug/1 VDay 000
7440-666)
14M.Cyanide. X 2 0.010 < 1.44 U 0.00 U 000 1 1119/1 Ib/Day 000
Total(57-12-5)
15M.Phenols. X - 0.0054 0 0.8 0 00 0 00 1 mg/l Ib/Day 0.U0
Total
DIOXIN
,3.7,8 Tetra DESCRIBE RESULTS
hlorodibenzo P X - 9.95 < 1428.2 U 0 0 U 0.0 1 pgll lb/Day -
io-(1764-01-t{)
EPA Funn 3510-2C(Rev 2-1151 PAGE V-3 CONTINUE ON PAGE V-4

EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER
CONTINUED FROM PAGE V-3 NC0004987 002 Marshall Steam Station
1.POLLUTANT 2 MARK"X" 3.EFFLUENT 4.UNITS 5. INTAKE(optional)
AND CAS NO. a.re Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE C.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE
d available) qua- b.pre- c.aa (if available) (if available) d.NO.OF a.Concert- b.Mass ]d.NO.OF
ed sent sent (1)Concentration 1(2)Mass [(I)Concentration 1(2)mass Ili)Concentration (2)Mass ANALYSES tralion (1)Concentrahon 1(2)Mass ANALYSES
GC/MS FRACTION-VOLATILE COMPOUNDS
IV Acrolein X 5.0 < 072 0 0.00 0 000 1 Ug/l Ib/Day 000
107-02-8)
V.Acrylonitrile X 79Z7_ 5.0 < 0.72 D 0.00 0 0.00 1 Ug/1 lb/Day 0.00
107-13-1)
V.Benzene X OWT-r 2.0 < 0.29 0 0M 0 U 00 1 ug/1 IWDay0 00
71-43.2)
V Bis(Chloro-
ethyl)Ether X 0 0 0 0
542.88-1)
W.Brornoform X 2.0 < 0.29 0 U.OU 0 0-00 1 Ug/I IWDay r 0.00
75-2!5.2)
V.Carbon
etrachlonde X 2.0 < 0.29 0 000 0 0.00 1 Ug/I Ib/Day 0.00
5Ei•L'J-5)
V.Chlorobenzene X i 2.0 < 029 0 000 0 000 1 ug/1 lb/Day 0.00
108-90.7)
V.Chloroma
romomethane X 2.0 < 0.29 0 0.00 0 0.00 1 ug/1 IWDay 0.00
12448-1)
v.Chloroethane X 2.0 < 029 0 000 0 000 1 ugh IWDay 000
75-00-3)
tUV.2-Chloro-
thy vinyl Ether X J 5.0 < 0.72 0 000 0 000 1 Ug/I lb/Day 0.00
11475-8)
1IV.Chloroform X 2.0 < 0.29 0 0.00 0 000 1 Ug/1 Ib/Day 000
87.68.3)
12V.Dlchloro-
romomethane X ;;. 2.0 < 0.29 0 0.00 U 0.00 1 Ug/l lb/Day 0-00
75-27-4)
13V.D¢hlwo-
8uoromethane X 2.0 < 0.29 0 000 0 000 1 ug/l lb/Day 000
75-71-8)
14V.1.1-Dlchloro- X 2.0 < 029 0 0.00 0 0 UU 1 Ug/1 lb/Day 0.00
thane(75-34-3)
15V.1.2-Dichlo- X •:� 2.0 < 0.29 0 0.00 0 000 1 Ug/I Ib/Day - 000
thane(107-06-2)
16V 1.1-Dichlor0- X 2.0 < 0.29 0 0.00 0 0.00 1 Ugh Ib/Day ! 000
thylene(M,35-4)
17v.1,2-Dichloro- X 2.0 < 0.29 0 0.00 0 000 1 Uy/l Ib/Day 0.00
ropane(78.87-5)
18V 1.3-Dlchl010- X 2.0 < 0.29 U 0.00 0 0.00 1 ug/1 lb/Day 0.00
ropylene(542-75-8)
19v.Ethylbenzene X 2.0 < 0.29 0 U 00 0 0.00 1 Ug/1 Ib/Day 0,01)
100-41.4)
OV Methy X 2.0 < 0.29 0 000 0 0.00 1 ug/1 IWDay 0 00
romide(74-83-9)
1V.Methyl X 2.0 < 0.29 0 0.00 0 coo 1 ug/I lb/Day 000
hloode(74-81.3)
EPA Form 3510-2C(Rev.2.85) PAGE V-4 CONTINUE ON PAGE V-5

EPA I.D.NUMBER(copy from Item lot Form 1) OUTFALL NUMBER
CONTINUED FROM PAGE V-4 NC0004987 002 Marshall Steam Station
1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional)
AND CAS NO. .,re- Believed a.MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE
'if available) quir- b.pre- c atr (d available) (If available) d.NO.OF a.Conten- b.Mass d.NO.OF
ed is sent (1)Concentration (2)Mass o)Concenlrabon (2)Mass (t)Concentrahon (2)Mass ANALYSES tratlon ll)Concentrahon (2)hlass ANALYSES
GC/MS FRACTION-VOLATILE COMPOUNDS(continued)
2V.Methylene X 2.0 < 029 0 0.00 0 000 1 ug/1 lb/Day -; 000
nlonde(7509-2)
3V.1,1,2,2-Tetra-
nioroelhane X 2.0 < 0.29 0 000 0 000 1 ug/I Ib/Day 000
79334-5)
24V,Tetrachloro- X 2.0 < 0.29 0 0.00 0 0.00 1 ug/1 lb/Day 000
Ihylene(127-18-4)
5V.Toluene X 2.0 < 0.29 0 0.00 0 0.00 1 ug/l lb/Day _ 000
108-88-31
tiV.1,2-lrans-
ichloroethylene X _ + 2.0 < 0.29 0 0.00 0 000 1 ug/I Ib/Day 0.00
15660.5) y
7V.1.1,1-Tn-
moroetnane X -y 2.0 < 0.29 0 0.00 0 0.00 1 Ug/I Ib/Day 000
71-55-6)
tlV 1.1,2-Tn-
hloroethane X ,_. 2.0 < 0.29 0 0.00 0 0.00 1 ug/l lb/Day 000
799-00-5)
9V.Tnchbru- X 2.0 < 0.29 0 0.00 0 000 1 Ug/l lb/Day 000
ethylene(79-01.6)
V.Trlchloro-
luorwnethane X 2.0 < 0.29 0 0.00 0 0.00 1 Ug/l Ib/Day 000
7569-41
1V.Vinyl X Y 5.0 < 0.72 0 000 0 &00 1 ugll b/Day 000
nlonde(75-Ut-41
GC/MS FRACTION-ACID COMPOUNDS
1A.2-Chlwopnenul X 10 < 1.44 0 0.00 0 0.00 2 u9/1 l
b/Day0.00
99557-8)
A 44•Dichluro- X 10 < 1 44 U 000 0 0.00 2 ug/1 0.00
nenol(120-83-2)
SA 2,4-Danemyl- X 10 < 1.44 0 U U0 0 0.00 2 Ug/1 000
hend(105-67.9)
A.4.6D nitro-U- X 10 < 1.44 0 000 0 0.00 2 ug/I 0.00
resol(534.52-1j2+0,niho- X50 < 718 0 000 0 000 2 ug/l 000
hend(51-28-5)
A.2-Ndrophenol X �.. 10 < 1.44 0 0.00 0 0.00 2 ug/l lb/Day ,_ 000
8&755)
A.4-n8trophenol X 10 < 1.44 0 0.00 0 0.00 2 ugll Ib/Day 0 OU
100-02-7)
A.P-Chlwo-M- X 10 < 1.44 0 0.00 0 0.00 2 ug/1 lb/Day U 00
resol(59-50-7)
9A.Pentachlwo- X _ 10 < 1.44 0 0.00 0 0.00 2 ug/1 IWDay 0-00
hand(67-8b-5)
T11A.Pnenul X -<,-� 10 < 1.44 0 0.00 0 0.00 2 ug/1 IWDay 000
108-95-2) '
11A.2,4,GTn-
mwophemol X 10 < 1.44 0 0.00 0 0.00 2 U9/1 lb/Dayi°9 000
8ft•UO-"2)
EPA Fwm 3511!-2C(Rev.2-85) PAGE V-5 CONTINUE ON PAGE V-6

EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER
CONTINUED FROM PAGE V-5 NC0004987 002 Marshall Steam Station
1.POLLUTANT 2. MARK"X" 3.EFFLUENT 4.UNITS 5. INTAKE(optional)
AND CAS NO are- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE
if available) yun- O.P.- c.ab- (d available) (if available) d.NO.OF a Conceo- b.Mass d.NO.OF
ad sent sent (1)Concentratiwi 2)Mass (1)Concentration (2)Mass (1)Concentra[1ai (2)Mass ANALYSES tratton (1)Concentrauon 2)Mass ANALYSES
GC/MS FRACTION-BASE NEUTRAL COMPOUNDS
1B AcenaphVrene X -
10 1.44 0 000 0 000 1 ug/1 Ib/Day 000
as3z-9)
B Acenaphtylene X 10 1 44 0 0 W U 0.00 1 ugil Ib/Day _ 0 W
20e--6.8)
'3B.Anthracene X 10 < 1 44 0 0.00 0 000 1 ugll Ib/Day
000
120-12-7)
6 Benzidine X 100 14 35 0 000 0 000 1 ug/I Ib/Day
000
B.Benzu(a)
nthracene X .g` 10 < 1.44 U 000 0 000 1 ug/I Ib/Day 000
56-55-3)
'B.Benzo(a) X < 10 1 44 0 000 0 0.00 1 ug/I Ib/Day 000
yrene(50-32-8)
B.3 4-Benzo-
luorantheneX 10 < 1 44 0 0 W 0 0.W 1 ug/I Ib/Day r7 0.00
205-9y-2) I I
-
6.Benzo I9m1 X 10 < 144 0 0 W U 000 1 ugil lb/Day _ 000
erylene(141-24-2)
JB.Benzo(k)
Fluoranthene X s 10 < 1 44 0 000 U 000 1 ug/l lb/Day _ 000
207-08-91
10B.&s([-Chloro-
thoxylI Methane X j 10 < 1 44 0 O W 0 0 00 1 ug/I Ib/Day _ 000
111.41-11 -
11B.Bis(2-Chloro-
ethyl)Ether X 10 < 1.44 0 000 0 000 1 ugll b/Day 000
(111-444)
12B.Bis(2-Chlorwso-
propyl)Ether X ..`,,.. 10 < 1 44 0 000
0 U W 1 ugll Ib/Day � O W
tUd•60-1) -
13B.Bis(2-Elhyl-
exyl)Phthalate X < 10 < 1 44 0 0.00 0 000 1 ug/I Ib/Day 000
17-81-7)
148-4-8ronw- ,�
ner Phenyl X 10 < 1 44 U U 00 U 0 W 1 ug/l Ib/Day U W
Ethel 001-b5-:i)
I 6.Butyl Benzyl X 10 1 1 44 0 0 00 0 0.00 1 ug/l lb/Day 0 00
hthalale(85-68-7)
16B.2-Chlor,
naphthalene X f'`1` 10 < 1.44 0 0 UO 0 0.00 1 ug/ lb/Day 000
91.58-7)
17B 4-Chloro-
amyl Phenyl X 10 < 1 44 0 0 00 0 000 1 ug/I IblDay 000
Ether(7M,72-3) E
1135 Ch-pene X 10 1 44 0 0 00 0 0 00 1 uy/1 Ib/Day _a 000
218-01.9)
19B.Dibenzu(a,h)
kritnracene X :` 10 < 1 44 0 000 0 0.00 1 ugll Ib/Day _,r 000
53-70.31
08.1.2-Dichloro- X 11711 7 2.0 < 0.29 0 0.00 0 000 1 ugh Ib/Day --1 000
nzene(95-50-11
i B.1,3-Dichloru X -•, 2.0 < 029 0 000 0 0Tay 1 ugil Ib/D _S 0.00
nzene(541-7:1.1)
EPA Fwm'351U-2C(Rev 2-851 PAGE V-6 CONTINUE ON PAGE V-7

EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER
CONTINUED FROM PAGE V-6 NC0004987 002 Marshall Steam Station
1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional)
AND CAS NO aro- AIL IMUM 30 LONG RM AVG.VALUEa.LONG VALUE
bIT
available)aaiable) ilta--able) d.NO.OF aColcer- bMass
(itd.NO,OF
ed sensent t1) onenatlw
(Y)Mass 0)Goncentraaun (2)Mass t1)concenirat- (2)Mass ANALYSES tration (1)cwwentrabon J121 Mass ANALYSES
GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued)
2B.1,4-Dlchlwo- X 2-0 < 029 0 000 0 000 1 ugil Ib/Day 0.00
nzene(106-46-7)
38.3,1Dlchlwo-
amidine X -"C 10 < 1.44 0 0.00 0 000 1 ug/1 lb/Day j 000
91-94-i)
48 Diethyl
hlhalate X 10 < 1 44 U 000 0 000 1 ug/I Ib/Day 000
'5B Dimethyl
hthalale X 10 < 1 44 0 0.00 0 000 1 ug/l Ib/Day �7 0.00
131-11-aJ -
66 Di-N-Butyl
hthalale X _ 10 < 1 44 0 000 0 000 1 ug/l Ib/Day 000
84-74-2)
78.2A-Dlnd X 10 < 1 44 0 000 0 000 1 Ug/l Ib/Day 000
duene(121-14-2)
tlB.46-Duutro- X =,^ 10 < 1 44 0 0.00 0 000 1 u9/1 lb/Day 7 000
auene(6U6-21J-2)
98.Dr-N-octyl
hthalale X 10 < 144 U 0.00 0 0.00 1 ug/I lb/Day _� 000
117-H4-UI
SUB 1,6Diphenyl-
ydrazme(as Azo- X j 10 < 1 44 0 000 0 000 1 ug/I lb/Day P7 0.00
enzene)(122-tib-7)
31B Fluoranthene X 10 1 44 0 000 0 000 1 ug/I Ib/Day 0 OD
2Ub-44-OJ
32B Fluwene X 10 1.44 0 000 0 000 1 ug/I lb/Day 77 000
H6-73-7)
33B.Hexachtwo- X 10 < 1 44 0 0.00 U 000 1 Ug/I lb/Day -I 000
enzene(11 H-74.1) --
B Hexa-
nlwobutadlene X ..ra 10 < 1 44 0 0 00 0 0 00 1 ug/l IWDay,! 000
tl 7-Ktl-:4)
356.Hexachloro-
yclopentadiene X '-T 10 < 144 0 0.00 0 0.00 1 ug/l Ib/Day 0.00
(77-474)
3613 Hexachlwo- X 19e 10 < 1 44 0 000 0 000 1 Ug/I Ib/Day 000
ethane(b7-72-1)
37B Indene
1.2,1cd)Pyrene X ir, 10 < 1.44 0 0.00 0 000 1 ug/l Ib/Day 71000
18139-5) -
3813 Isuphorone X _a 10 < 1 44 0 0.00 0 000 1 uy/I Ib1Day _ 000
78-58-1)
398 NaphthaleneX 10 144 0 000 0 000 1 uy/l IWDay 000
91-20-3J
UB.Nitrobenzene X 10 < 1.44 0 0.00 0 000 1 ug/I Ib/Day 000
98-95-3)
iB.N-Ntro-
odimethylarnme X 10 < 1.44 0 0.00 0 000 1 ug/l IWDay 000
62-75.9)
2B.N-Ndrosotli-
-Propylamme X 2" 10 < 1.44 0 0.00 0 000 1 ug/I Ib/Day r7j 000
621.64-7)
EPA Forrn 3510-2C(Rev 2-85) PAGE V-7 CONTINUE ON PAGF V-n

EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER
CONTINUED FROM PAGE V-7 NC0004987 002 Marshall Steam Station
1,POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5. INTAKE(optional)
AND CAS NO. a r, Beoeved a.MAXIMUM DAILY VALUE ]!bf[MUM 30 DAY VALUE C.LONGTERM AVG.VALUE a.LONG TERM AVG.VALUE
d available) awr- b.pc vadable) (if available) d.NO.OF a.Concen- b.Mass d.NO,OF
ed sent sent (1)Concentratlon 1(2)Mass (1)Concentration 1(2)mass tl)Concentrabon (2)hlass ANALYSES tratlon (1)Concentration (")Mass JANALYSES
GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued)
3B.N-Nd -
-odiphenylamme X '- 10 < 1.44 0 000 0 0.00 1 ug/I Ib/Day '-'' 0 00
H6-30-6) _
4B.Phenanthrene X 10 < 1.44 U 000 U 0.00 1 ugll Ib/Day a U U0
H5 Ut-tl)
56 Pyrene X 10 1.44 0 0 00 0 0 00 1 ugd IWDay _. 000
129-UU-U)
Ge.1.2.4-Tu-
nlorobenzene X 2.0 < 0.29 0 000 U 0 D 1 ugll Ib/Day j R00
120 H2-1)
GC/MS FRACTION-PESTICIDES
1P Aldnn X 0
309-W-11
P.alpha-BHC X 0
319-H4-6)
3P beta-BM(, X 0
,i15-H671
P gamma-BHC X 0
5H-89-9)
5P delta-BHU X 0
319-86-H)
'P Chlordane X 0
57-74-9)
P 4.4'-DD1 X U
5U-29-3)
P.4,4'-DDE X 0
72-569)
uP.4,4'-00D X 0
72-54-a)
10P Dieldrin X 0
60-57-11
11P.alpha-EndosultanX 0
11629-71
t2P.beta-Endosultan X 0
115-29.7)
13P Endosultan
SuNate X 0
1031-U7-H)
14P.Endnn X U
72-20-H)
15P Endnn
Aldehyde X 0
(7421-93-4)
1tiP HeptachlorX 0
76-04-H1
EPA Fom1 35111-2C(Rev "-H5) PAGE V-H CONTINUE ON PAGE V-9

EPA I.D.NUMBER(copy from Item lot Form 1) OUTFALL NUMBER
CONTINUED FROM PAGE V-ti NC0004987 002 Marshall Steam Station
1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional)
AND CAS NO. Ta— behe,ed a.MAXIMUM DAILY VALUE b.MAXIMUM 3U DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE
if available) c.ab- (if available) Qf available) d.NO.OF a.Conten- b.Mass d. NO.OF
sent (1)Concentration (2)Mass 0)Concentraaon 1(2)mass (1)Concentrabon 1[2)Mass ANALYSES tration (1)Concentrabon (2)Mass ANALYSES
GC/MS FRACTION-PESTICIDES(continued)
17P Heptachlor
Epoxide X 0
1024-57-31
18P.PCB-1242 X `E'". 0.30 < 1 ug/I
53465-21-5) ._'
111P PCB-1zS4 X F 030 < 1 ug/I
11057-b4-1)
UP.PCB-1221 X < ) 0.30 1 ug/l
11104-28.2) ,
1P PCB-1232 X 0.30 < 1 ug/1
11141-16-5) -Yf
2P PCB-124b X • c 0.30 1 ug/I
12672-25-61
;iP.PCB-ilebu X0.30 < 1 ug/1
11 VJ6.82.5) -__
4P PCB-1016 X 0.30 < 1 ug/1
12.674-11-2)
SP.Toxaphene X 0
tlUut-35.21
EPA Fon-3510-2C IR— 2-8.`>i PAGE V-1r

Water Flow Diagram

Marshall Steam Station Water Schematic
NPDES Permit#NC0004987
Unit 4 ID Fan Control Catawba County
House Coding Water Outfall 003
0.2 MGD
Intake Screen Backwash
Condenser Coding Outfall 001 Lake
Water 1093 MGD Norman
Ash Sluice 3.21 MG
Lake
Norman
—♦ Evap.1.7 MGD
Flue Gas FGD Wetland Wastewater
Desulfurization Treatment System NPDES Internal 1.2 MGD
(FGD)Blowdown Outfall 004
Drinking Water Sanitary Storm Water
(groundwater)
1.45 MGD
i
isc.Equipment 0.53 MG
Coding
0.01 MGD Seeps
Water Treatment
iler and Turbine Yard Drain Su Ash Basin Outfall 002_ Lake
1 9 MG Sumps 2 43 MG 8.3 MGD Norman
ji
Room Sumps (2)
Outfalls 002a and 002b
Emergency overflow onLake
(no flow expected) Norman

S ♦ } � r� 1117
� Tr•
• a r � t-- 1 t 3' r - a ..q
5 �� T { {:_• tis s
��''r��1 }� ��r• � .,5� J , � .7"+r�F'�R,.. .;f � J t� t`� _'d' � { •f•� 'T .�� P'�Z�
,� �ic''�''}r_ r• .t' '� r.�� S' 6ti. • <f ♦�. ..ate ,� �„�•� ,r�-%-i
Vr - ,' � '� ` ` . -r. y ' /♦ ,�t'_'r-r,r, �a 1�Z lr. J:y'
+f¢K.:�j D� �'!1 r1 rr� r � •f p ♦ ty 1 '�•' t`f '� �
1-4
im
40
,i
s + w r I
{�� .. .ty f r lrr „ - - - rJ.• r. ° � I Il 1�l1/Z r � ' ��
;Z
a,e cif, /_♦♦ 7��f � - .!- • ,. •�• F,�§J:vL.' ter 1 •�
AT
_ -�,1',F� S J` "S.y r t-�, fi..L ,' I`Y ��1 �•;7"' D att�•Y L'I�i.�
1 � r •.1a - �,is -I•. '�'' .t s�-a' • '• +• '4%;. ,
D - � - .. �� 1 `_ I'• yr � '^� �'
• '', � i :_ lira r. x
I
Lit yT } ls, re + I
• -i, . r,r{: � � d +` .amu
?I A-2i
.,i. 1 r rot, ` •� , '� �-`�' k�. 4�,, i`a '••�?
1 Tia. p. - v' ^'• _ a .0 �'--lJ'
�t,• �• , ` , 1-1 ' ,, _ '` ' 1". tfS 1 'J•'2 f.,:�•. 'r ''S d.� 1 ..r f �iry
p J•?l, �` _ '''y, I•. -S ,w•.. .,_'1 r�`..•�F11�l.� •J � a y S�9r r, •�
;•� �_ •.�� t ', � a'• ♦1- -� �'�ll ,�J�7 _ �'+7y ,.. �- TM I`l_h.ir.Y - �I .tv �t".�li ({ i.i ;. .. {i
a ' 1_ry r - :S r5 s' '�. !'i a • e •'q'i to 1�„}` - ` ,.. t,�.t aia ' _ , 3
���`.•`�. 7L.a'.7a.� �JS�.JS. ��-rlEr�.'.�.■.�'� _... 1i�� LiYY.1-ira. �_�.>�lJ .li':¢�L�r�... n''w�eY.�''—.'- �-_.. �:�.'l 'rti)�

NPDES
Supplemental Information
For
Marshall Steam Station
NPDES Permit No. NC0004987
October 2014

1.0 General Information
Marshall Steam Station (MSS) is located on NC Highway 150, six miles west of 1-77 in Catawba
County on Lake Norman near Terrell, North Carolina. MSS consists of four coal-fired steam electric
generating units. Units 1 and 2 can generate 380,000 kilowatts (net) of electricity each and units 3
and 4 have the capacity to generate 660,000 kilowatts (net) of electricity each.
A brief discussion of the individual waste streams follows.
2.0 Outfall Information
2.1 Outfall 001 - Condenser Cooling Water(CCW) Units 1-4
The CCW system is a once through non-contact cooling water system, which condenses
steam from the condensers and other selected heat exchangers. When MSS is operating at
full power, it has a design capacity to pump 1463 MGD (1,016,000 GPM) of cooling water
through a network of tubes that runs through the condenser and selected heat exchangers.
The raw cooling water is returned to the lake. No biocides or other chemicals are used in the
condenser cooling water.
Units 1 and 2 have two CCW pumps per unit and Units 3 and 4 have three CCW pumps per
unit with the following maximum flow capacities:
Unit No. 1-Pump 2-Pump 3-Pump
GPM GPM GPM
1 126,000 190,000 -
2 126,000 190,000 -
3 150,000 253,000 318,000
4 150,000 253,000 318,000
The operational schedule for these pumps is dependent on the intake water temperature and
on the unit loads. Depending on the electrical demand, pumps are operated to maximize MSS
efficiency and to assure balanced and indigenous populations are maintained in Lake Norman.
Each unit is on an independent system to avoid a system trip that would suddenly reduce the
discharge flow at outfall 001. This practice leads to a higher reliability factor for the units and
protection of aquatic life taking refuge in the discharge canal during cold weather. Flow
recorded on the monthly Discharge Monitoring Reports is based on CCW pump run times.
The condensers are mechanically cleaned. Normally, amertap balls are cleaning the tubes on
a continuous basis while the plant is operating. Periodically, after the condenser is drained,
metal scrapers, plastic scrapers or rubber plugs are forced through the tubes to rid them of
scale or other deposits. The condenser tubes may also be tested for leaks, as needed. A leak
test can be conducted in approximately two to three hours per unit with usually no more than
six injections of tracer gas (i.e., sulfur hexaflouride, helium, etc) each within approximately a 30
second period and/or checked with fluorescent dye. The dye is added to the condensate water
and put on the outside of the condenser tubes. During the test, if fluorescent water does leak
into the tubes, this discharge indicates a leak does exist in the condenser tubing. The levels of
gas or dye that might be discharged would be well below any levels of aquatic biological
toxicity concerns. If leaks are detected, then one method used to temporarily stop small leaks
is to add sawdust to the CCW system, as previously approved by NCDENR. The sawdust is

added at amounts that will plug the leaks and not result in an environmental impact. This is a
temporary measure until the unit can come off-line so the leaks can be permanently repaired.
2.1.1 Intake Screen Washing Manually by Removing Screens
The intake screens (32 total) are washed on an as needed basis. Normally, the screens
require washing once a month for a period of approximately 5 minutes per screen. The
screens (10 ft x 20 ft) are stationary type and are removed for cleaning. A low-pressure
pump supplies the raw water required for washing with a design capacity of 300 gpm.
Therefore, the average flow of water used to backwash the screens is 0.002 MGD.
Should it become necessary to backwash the screens on a continuous basis the
maximum flow would be 0.43 MGD per screen. The debris collected on the screens
consists of twigs, leaves, and other material indigenous to Lake Norman and is removed
and properly disposed. The intake screen backwash water drains back to the station
intake cove without any adverse environmental impact.
2.2 Outfall 002 - Ash Basin
The ash basin at MSS accommodates flows from two yard-drain sumps, an ash removal
system, low volume wastes and non-point source storm water. Low volume waste sources
include, but are not limited to: wastewater from wet scrubber air pollution control systems, ion
exchange water treatment system, water treatment evaporator blowdown, laboratory and
sampling streams, boiler blowdown, floor drains, and recirculating house service water
systems. Total average influent from these sources combined is approximately 8.3 MGD. At
times, due to unit loads, rainfall, evaporation and seepage of ash basin ponds, the amount of
effluent may be different than influent volumes.
2.2.1 Yard-Drain Sumps
The yard-drain sumps are concrete structures having four level controlled pumps each
that direct wastewater from the powerhouse area to the ash basin. These pumps are
operated on a rotating basis. Usually two pumps are set so that one pump is primary
and the other is backup. After a selected period the controls are changed so that
different pumps are utilized.
The yard-drain sumps collect wastewater from many sources, such as, the filtered water
system, turbine and boiler room sumps, miscellaneous equipment cooling water,
foundation drainage, low volume wastes, and tunnel unwatering. The yard-drain sumps
also collect some storm water runoff from the coal pile, rail access, and powerhouse
roofs and pavement. Ground water from a foundation drainage system under the track
hopper is also intermittently discharged to the yard-drain sumps. The combined
average flow from all sources tied to the yard-drain sumps is approximately 2.43 MGD,
which is pumped to the ash basin for physical and biological treatment.
2.2.2 Turbine Room Sumps
The turbine room sumps collect approximately 0.35 MGD of wastewater. This
wastewater comes from non-contact cooling water (from Units 1 & 2 boiler feedpump
turbine lube oil coolers) and floor drains. Floor drains contain boiler blowdown, leakage
from seals, equipment cooling water, condensate from the feedwater system, low
volume wastewater, boiler room sump overflow, emergency fire fighting water, general
mechanical maintenance activities, miscellaneous plant wastes and area washdown
water.

2.2.3 Boiler Room Sumps
The average flow pumped from the boiler room sumps directly to the ash basin is
approximately 1.55 MGD. The sources of input to the boiler room sumps include the
following:
2.2.3.1 Water Treatment System
The MSS make-up water treatment system is comprised of a clarifier, three
gravity filters, two sets of activated carbon filters, a reverse osmosis system and
two sets of demineralizers. The water treatment wastes consist of floc and
sedimentation, filter backwash, reverse osmosis concentrate reject and cleaning
wastes, and demineralizer regeneration wastes. Water processed through this
system is supplied to the boilers to generate steam to tum the turbines. On
occasion a vendor may be used with a mobile water treatment unit to augment
the facility water treatment capacity. Any vendor will use traditional water
treatment methods, chemicals, and disposal methods generally described below.
This wastewater is drained to the boiler room sump, which ultimately discharges
to the ash basin.
Clarifier.-
The
larifier.The clarifier utilizes typical water treatment chemicals such as, Ferric sulfate (),
sodium hydroxide, and calcium hypochlorite for the primary treatment of raw
water. The sedimentation wastes collected in the clarifier consists of solids that
were suspended in the service water plus Ferric precipitate formed as a result of
adding Ferric sulfate () and sodium hydroxide. The quantity of Ferric Sulfate
used per year is approximately 14,000 gallons. The total amount of caustic is
roughly one quarter the amount of Ferric Sulfate The average volume of water
required for desludging the clarifier is approximately 0.008 MGD. These
sedimentation wastes along with dilute water treatment chemicals and by-
products are piped to a floor drain which flows to the boiler room sumps where
they are pumped to the ash basin via the yard-drain sump.
Gravity Filters:
There are three gravity filters composed of anthracite (coal) which follow the
clarifier in the water treatment process. They are used for removal of colloidal
material and are backwashed as necessary, dependent upon the level of solids
in the water. Normally, one of these filters is backwashed each day.
Approximately 0.007 MGD of backwash water is required for each filter. This
flow is discharged to the floor drains to the boiler room sump, which pumps to the
yard-drain sump. The gravity filter medium is changed out on an as-needed
basis with the spent filter media being landfilled.
Activated Carbon Filters:
Two activated carbon filters remove organics and the chlorine that is injected into
the clarifier. These filters are typically backwashed approximately once a week.
The flow of water required to backwash one of these filters is 20,000 gallons per
day. The wash water flows to the boiler room sump and is pumped to the yard-
drain sump. Activated carbon is replaced on an as needed basis with the spent
carbon sluiced to the ash basin.

Reverse Osmosis System
There is a two stage Reverse Osmosis (RO) system which processes
approximately 535 gallons per minute of filtered water. Approximately 400 gpm
of permeate water is produced and flows to the permeate water storage tank.
Approximately 135 gpm of concentrate water is produced which flows to the
boiler room sump and ultimately the ash basin via the yard drain sump. Water
from the permeate tank is pumped to the demineralizers as supply water.
The RO system is cleaned approximately twice per year using a dilute low pH
cleaner(sulfonic acid/citric acid), biocide (Trisep Tristat 110), and a high pH
cleaner(sodium hydroxide/sodium lauryl sulfate).
Demineralizers:
Demineralizers at MSS consist of two sets of mixed-bed cells which supply
make-up water to the boilers and other closed systems. Normal plant operation
requires that only one cell of each demineralizer set operate at any one time.
Each cell has a capacity of 225 gpm.
Each cell is regenerated approximately every four weeks. Each year MSS will
use an estimated 8,000 gallons of 50% caustic and 2,500 gallons 93% sulfuric
acid for demineralizer regenerations. The dilute acid and caustic are discharged
from the cell simultaneously through the same header for neutralization
purposes. The regeneration wastes flow to the boiler room sumps where it is
pumped to the ash basin via the yard-drain sump. The useful life of the resin
varies and when replaced spent resin is sluiced to the ash basin.
2.2.3.2 Miscellaneous Waste Streams
• Closed system drainage, cleanings, testing containing corrosion inhibitors
(Calgon CS), biocides (Calgon H-550 and H 7330), cleanings'! (small heat
exchangers), dispersant (polyacrylamide), wetting agent (sodium lauryl
sulfate), detergent (tri-sodium phosphate), and leak testing (disodium
fluorescing dye).
• Turbine room sump overflow
• Boiler seal water(trace oil and grease)
• Miscellaneous system leakages (small leaks from pump packings and seals,
valve seals, pipe connections)
• Moisture separators on air compressor precipitators
• Floor wash water
• Emergency fire fighting water
• Pyrite (ash) removal system overflow
• Low Volume Wastewater.
2.2.3.3 Chemical makeup tanks and drums rinsate
Intermittent rinse water containing small amounts of Ferric sulfate, sodium
hydroxide, hydrazine, ammonium hydroxide.
2.2.3.4 Boiler blowdown
To date small closed system cleanings (e.g. heat exchangers) have not used these chemicals, reserved for
future use.

Primarily when units 1 & 2 startup and until water chemistry stabilizes the
blowdown from these boilers is allowed to flash in a blowdown tank. During
startup a significant portion of this blowdown steam is vented to the atmosphere.
After water chemistry has stabilized, blowdown venting is minimal and
condensate flow is small. Trace amounts of hydrazine, ammonia, and silica
oxide may be present in the condensate. The combined condensate flow from
blowdown amounts to an average of approximately 0.002 MGD. This flow is
routed to the boiler room sump and then to the ash basin.
2.2.3.5 Boiler Cleaning
Boilers #1, #2, #3 and #4 at MSS are chemically cleaned on an as needed basis.
Tube inspections are performed during outages, which indicate when cleaning
needs scheduling. Boilers #1 and #2 are controlled circulation boilers and boilers
#3 and #4 are supercritical boilers. The wastes produced from a boiler chemical
cleaning are pumped to the ash basin.
Boilers #1 and #2 each have a water-side volume of 51,600 gallons. The volume
of #3 and #4 boilers is 35,300 gallons each. The total volume of dilute waste
chemicals, including rinses, discharged from #1 or #2 boilers during a chemical
cleaning is 580,000 gallons. The total volume of dilute waste chemicals drained
from #3 or #4 amounts to 320,000 gallons. This dilute wastewater is drained
through temporary piping to permanent ash removal piping where flow goes to
the ash basin. The chemicals and approximate amounts for each cleaning are
listed below.
CLEANING CHEMICALS AMOUNT USED PER UNIT
Alkaline Boilouts —(only after major boiler tube work)
Boiler#1 or#2 Boiler#3 or#4
Soda Ash 4400 Ib NA
Trisodium Phosphate NA 3000 Ib
Triton X-100* Detergent (0.05%) 25 gal 18 gal
Antifoam Agent (0.025%) 13 gal 9 gal
* or equivalent detergent
EDTA Boiler Chemical Cleaning
Boiler#1 or#2 Boiler#3 or#4
Tetra-ammonium EDTA (38%) 11000 gal NA
Antifoam Agent 15 gal 10 gal
Ammonium Hydroxide (260Be') NA 1,400 gal
Di-ammonium EDTA (44.5%) NA 6,000 gal
Rodine 2002 (corrosion inhibitor) 300 gal 240 gal
Regardless of the method used for cleaning, no waste water will be discharged to
the ash basin, rather all cleaning waste waters will either be evaporated in the
boiler or collected and transported off-site for proper treatment and disposal.

2.2.4 Stormwater Runoff
The ash basin collects/receives flows from the yard drainage basins, ash removal lines
and rainfall run-off from the basin watershed area. Some of the flows pumped into the
ash basin from the yard drains include roof runoff, stormwater discharge from
transformer containments, stormwater discharge fom fuel oil containments, stormwater
from the FGD facility, rail lines, coal handling facilities, chemical storage and
miscellaneous plant equipment. Details of storm water the runoff that flows into the ash
basin via gravity are described in section 2.2.15.
2.2.5 Induced Draft Fan Motor Bearing Cooling Water
Once through non-contact cooling water is supplied to eight induced draft (ID)fan motor
bearings to remove excess heat. No chemicals are added to the once through raw lake
water. The rate of flow through the ID fan heat exchangers that discharges to the yard-
drain sumps is approximately 0.08 MGD, which is pumped to the ash basin.
2.2.6 Track Hopper Sump
The track hopper sump collects ground water from a foundation drain system
underneath the track hopper. The flow is usually intermittent; however, the pump
capacity is 100 gpm. On a daily basis it is estimated that the run time is only 50% which
would correspond to a flow of 0.07 MGD to the yard-drain sumps, which is pumped to
the ash basin.
2.2.7 CCW Tunnel-Unwatering Sump
In the event that maintenance activities are needed in the intake or discharge tunnels an
unwatering sump is provided to remove water from the tunnels. Raw water in the
tunnels can be pumped to the yard-drain sumps that ultimately discharge to the ash
basin.
2.2.8 Turbine Non-Destructive Testing
Bore sonic testing of turbine rotors is infrequent, once every 5 years. Demineralized
water is mixed with a corrosion inhibitor, e.g. Immunol 1228, at a ratio of 100 parts
water to 1 part inhibitor. The mixture is applied to the turbine rotors. The excess is
drained and mixed with low volume wastewater and discharged to the ash basin via the
yard-drain sumps.
2.2.9 Ash Sluice
MSS utilizes electrostatic precipitators as its air pollution control devices. Under normal
plant operations, the dry fly ash captured in these precipitators is collected in temporary
storage silos for subsequent disposal in a permitted on-site structural fill or for recycling
in off-site ash utilization projects. If the system that collects the dry fly ash is not
operating, the fly ash can be sluiced to the ash basin. Bottom ash from the boilers is
usually sluiced with water to a holding cell for recycling activities. Pyrites from the mills
are sluiced with water to an ash basin settling-cell. Approximately 3.21 MGD of
fly/bottom ash and pyrite sluice is pumped through large steel pipes (ash lines) directly
to the ash basin settling-cell. Once through non-contact cooling water from the coal
pulverizing mill is discharged to the bottom ash hopper and pumped to the ash basin.
Electrostatic precipitators at MSS are normally cleaned by mechanically vibrating the
wires and rapping the plates inside the precipitator. Before major precipitator work is
performed they are cleaned by a wash down. The wash water is pumped to the ash
basin from the yard-drain sump.

2.2.10 Sanitary Waste
A sanitary waste treatment system is operational and consists of an aerated basin that
provides treatment with a 30-day retention time and has a total volume of 587,000
gallons. Effluent from the aerated basin is polished further through additional residence
time in the ash basin. The system is designed for 6100 gpd (normal) and 13,500 gpd
(outage).
The powerhouse lift station was installed as a central collection point to receive all the
sanitary waste from MSS and pump it to the aerated basin.
The sanitary system accommodates wastewater flow from the following sources:
• General plant sanitary wastewater
• Vendor facilities sanitary wastewater
• Laboratory drains (Small amounts of laboratory chemicals used to test
wastewater effluents and high purity boiler water, see the following table for
non-hazardous substance).
Substance Quantity Location
2-Propanol 4 gal. Lab/Warehouse
Glycerin 4 gal. Lab/Warehouse
Indigo carmine 0.3 Ib Lab
Dimeth laminobenzaldeh de 0.22 lbs Lab
Table values represents typical quantities on-site at any given time and do not
necessarily reflect quantities discharged.
2.2.11 Ash Silo Storm Water Sump
A ash silo system has been constructed for dry handling of the ash. This system
includes a sump for collection of rainfall runoff and washdown of the silo area, which is
pumped to the ash basin. This sump's drainage area is approximately 1 acre. Overall,
this will be a minimal input to the ash basin.
2.2.12 Wastewater from Plant Additions
2.2.12.1 Selective Non-Catalytic Reduction (SNCR)
As part of the compliance with the North Carolina Clean Air Initiative (NCCAIR),
Marshall installed urea based "trim" Selective Non-Catalytic Reduction (SNCR)
systems on units 1, 2, and 4. The trim SNCR systems are expected to reduce
NOx emissions by approximately 20%. SNCR systems operate by injecting urea
liquor into the upper section of the boiler where a chemical reaction occurs to
reduce the NOx to water and nitrogen. Some residual ammonia will be collected
in the fly ash from the electrostatic precipitators. The majority of this ammonia will
stay with the ash as it is handled dry but a small amount may be carried to the
ash basin. However, the operation of the SNCR system is not expected to
require additional treatment capabilities to ensure compliance with NPDES
permit limits. Marshall units 1, 2, and 4 currently are using this technology to
reduce NOx whereas unit 3 operates a Selective Catalytic Reduction (SCR)
system.

2.2.12.2 Selective Catalytic Reduction (SCR)
As part of the compliance with the North Carolina Clean Air Initiative (NCCAIR),
Marshall has replaced unit 3's SNCR with a more efficient Selective Catalytic
Reduction (SCR) system, capable of reducing NOx by approximately 90%. This
SCR utilizes a urea to ammonia (U2A) which converts the urea liquor into an
ammonia gas, external to the boiler in a hydrolyzer. The hydrolyzer contains
approximately 1000 gallons of urea while in operation and periodic blowdowns
occur to flush out sediment in the bottom of each hydrolzer. Small quantities of
urea will be discharged into the ash basin from the blowdown process. Roughly,
10 gallons a week is discarded during the blowdown process and is collected in
the ash basin. Similar to the SNCR, the SCR will also result in small traces of
ammonia in the fly ash that is collected from the electrostatic precipitators. The
majority of this ammonia will remain with the ash as it is handled dry but a small
amount may be carried to the ash basin. However, the operation of the SCR
system is not expected to require additional treatment capabilities to ensure
compliance with NPDES permit limits.
2.2.12.3 Flue Gas Desulfurization (FGD)
The installation of a Wet Flue Gas Desulfurization (FGD) system was completed
in 2006 at Marshall for Unit 4. The remaining units FGD systems were
completed in 2007. The FGD is an air pollution control system that removes SO2
from the flue gas system. In a Wet Scrubber system the SO2 component of the
flue gas produced from the coal combustion process is removed by reaction with
limestone-water slurry. The particular system used at Marshall will collect the
flue gas after it passes through the electrostatic precipitator and route the gas
into the lower end of a vertical tank. As the gas rises through the tank to the
outlet at the top, the gas passes through a spray header. An atomized slung of
water and limestone droplets is continually sprayed through this header into the
stream of flue gas. The SO2 in the flue gas reacts with the calcium in the
limestone and produces SO3. The SO3 slurry falls to the bottom of the tank
where a stream of air is injected to oxidize the slung to form gypsum
(CaSO4•H2O). The gypsum slurry is drawn off the tank to a hydrocyclone and
subsequently routed to a vacuum belt filter. The liquid waste from this process
will be treated as wastewater in the constructed treatment wetlands. The effluent
from the CTW discharges to the ash basin (via NPDES Intemal Outfall 004).
The FGD system requires a material handling system that supplies limestone to
the scrubber and a gypsum storage area for the gypsum removed from the
process. The limestone comes into the site by rail and is stored in an area near
the coal pile. It is then transferred to the FGD site via a covered conveyor.
Runoff from the storage area is routed to the ash basin. The gypsum is routed
from the FGD tank via a covered conveyor belt that carries it to a storage pile.
The runoff from this area is also routed to the ash basin.
The FGD system also requires a gypsum landfill. The FGD landfill is located
west of the Marshall Ash Basin. The runoff and leachate from this landfill is
routed to the ash basin. FGD residue material that is not suitable for beneficial
use as wallboard will be placed in the landfill. In addition to this material, material
is periodically removed from the clarifier stage of the wastewater treatment

system and placed in the landfill. The landfill footprint contains approximately
20.64 acres. The landfill is permitted to receive asbestos from Duke Genergy
Carolinas, facilities, generated gypsum from the Allen, Marshall and Cliffside
Stations, generated clarifier sludge from the Allen, Marshall and Cliffside Sations
as well as the following wastes generated soly from the Marshall Station: fly and
bottom ash, C&D debris, pyrites, waste limestone material, land clearing and
inert debris, boiler slag, mill regects, sand blast material and coal waste.
The FGD residue is conveyed to the landfill site by truck, where the material is
spread and compacted. The landfill began receiving FGD residue in the fall of
2006. The volumetric capacity of the landfill is 2.19 million yd3- Duke Energy is
exploring other beneficial uses for the FGD residue (gypsum). If these options
are determined to be viable, the FGD residue meeting the material requirements
for the beneficial uses will not be disposed in the landfill.
2.2.13 Seepage
MSS has identified two seeps in the vicinity of the of the ash basin dam. These
seeps contribute a small amount of water to Lake Norman.
2.2.14 Industrial Waste landfill Leachate
Construction of an industrial waste landfill is scheduled to begin in early 2010.
Landfill operation is slated for late 2010. Fly ash, FGD gypsum and clarifier
sludge will be disposed in this landfill. Landfill runoff and leachate will be routed
to the ash basin for treatment.
2.2.15 Stormwater Gravity Drains to the Ash Basin
Marshall Steam Station has several non-stormwater discharge drainage areas
that drain via gravity flow into the ash settling basin, or discharge into station
sumps that subsequently pump to the ash settling basin. These aere addressed
were addressed in Section 2.2.4. All of the areas north of the primary coal
delivery rail lines gravity drain to the ash settling basin. The following is a
summary of the stormwater that gavity drains to the ash basin:
2.2.15.1 FGD Gypsum Radial Stacker
This drainage area includes the FGD gypsum radial stacker operation and
portions of an adjacent soil borrow area. Stormwater runoff from this area
enters a detention basin before discharging into a tributary of the ash
settling basin to the north.
2.2.15.2 Soil Borrow Area
This drainage area includes the remaining portions of the soil borrow area.
Stormwater runoff from this area enters a detention basin on the west side
of the drainage area before discharging into a small creek that flows to the
ash settling basin.
2.2.15.3 Drainage Area 15— FGD Landfill
This drainage area includes the FGD residue landfill. Stormwater runoff
from this area enters a detention basin at the southeastern edge of the
landfill and is subsequently piped via gravity flow to the ash settling basin.

This landfill also includes FGD wastewater treatment sludge, asbestos,
flyash, bottom ash, mill rejects, and construction and demolition debris.
2.2.15.4 Coal Pile
This drainage area is comprised entirely of the station coal storage pile.
Stormwater runoff from this area enters perimeter ditches that discharge
into the ash basin.
2.2.15.5 Sanitary Wastewater Lagoon
This drainage area is comprised of the sanitary wastewater treatment
lagoon and surrounding area. Stormwater runoff discharges into the ash
basin to the north.
2.2.15.6 FGD Constructed Wetland Treatment System
This drainage area is comprised of the constructed wetland treatment
system (CWTS) designed to treat wastewater from the FGD solid removal
wastewater treatment system. Stormwater runoff from the CWTS area
flows into the adjacent ash settling basin.
2.2.15.7 Bottom Ash Operation and Pyrite Operation
This drainage area includes the bottom ash operation and recovery of coal
from pyrites. All stormwater runoff from this area is routed via ditches into
the ash settling basin.
2.2.15.8 Closed Ash Landfill
This drainage area includes the closed and capped ash landfill. All
stormwater runoff from this area is routed via ditches into the ash settling
basin.
2.2.15.9 Beneficial Structural Fill
This drainage area includes the active beneficial ash structural fill. All
stormwater runoff from this area is routed via ditches into the ash settling
basin.
2.3 Outfalls 002A and 002B - Yard-Drain Sump Emergency Overflow
An overflow pipe that could direct flow from the sump to Lake Norman was included in the
construction of the two yard sumps. This modification was performed to prevent submergence
and damage of the pump motors within the sumps in the event that all pumps failed or
redundant power supply lines could not be restored in a timely manner. Outfall 002A has
overflowed five times between April 2007 and March 2009. Outfall 002B has overflowed two
times between April 2007 and March 2009. Observations and monitoring of effluent during
these events have indicated no noticeable impact to water quality. No sanitary waste is routed
through the yard-drain sumps.
2.4 Outfall 003 - Unit 4 ID Fan Control House Cooling Water
Once through non-contact cooling water is supplied to the Unit 4 induced draft (ID) fan motor
control-house equipment to remove excess heat. No chemicals are added to the once through
raw lake water. The flow rate through the control equipment that discharges to Lake Norman
is approximately 0.2 MGD.

2.5 Internal Outfall 004— Treated FGD Wet Scrubber Wastewater
The wastewater from the FGD system is conveyed to the wastewater solids removal system,
which discharges into the mixed equalization tank. The wastewater contained in the
equalization tank is conveyed to the flocculating clarifier which is utilized as the liquid/solids
separation device. Polymer may be injected to aid in the settling process. Clarified effluent is
conveyed to the Constructed Treatment Wetlands (CTW) supply tank.
Settled solids are removed from the clarifier by the operating sludge transfer pump and
conveyed to the mixed sludge holding tank and dewatered by the filter presses. Dewatered
cake from the filter presses is ultimately landfilled. Filtrate from the dewatering process is
conveyed to the equalization tank for reprocessing.
The CTW system receives wastewater from the clarifier unit where it enters two equalization
basins, each with a 24-hour hydraulic retention time (HRT) for cooling, mixing, concentration
equalization, and settling of solids. Water from the equalization basins is normally split into 6
flows then to three equal flows, each entering a treatment train consisting of two 1.28 acre
wetland cells (36 hour HRT), a 0.24 acre rock filter and a 1.67 acre final wetland cell (64 hour
HRT). Total area of treatment is approximately 15 acres with a normal HRT of 8 days based
on average projected flows. The CTW system will treat an average flow of 1.2 and a peak flow
of 1.4 MGD.
3.0 Additional Information
FUEL AND OIL STORAGE TANKS
The following above ground fuel and oil storage tanks are located at MSS:
e two 500 gallon,
e three 1,000 gallon,
e 2,000 gallon,
e 5,000 gallon
e two 500,000 gallon fuel-oil tanks;
1000 gallon gasoline tank;
e four 750 gallon lubricating-oil tanks;
e 500 gallon hydraulic-oil tank;
e 900 gallon used-oil tank;
e 8000 gallon used-oil tank (inside the powerhouse).
At the time of this application, only one of the 500,000 gallon fuel-oil tanks is in service. All above
ground tanks at MSS have secondary containment provided that is capable of containing the entire
contents of the tank.
All oil storage facilities and oil filled equipment are presently covered under Spill Prevention Control
and Countermeasure Plans (SPCC)2.
5.0 Hazardous and Toxic Substances
5.1 Hazardous and Toxic Substances Table 2c-3
2 SPCC Plan required by 40 CFR 112.

At MSS, the potential for toxic and hazardous substances being discharged is very low. In reference
to item V-D of Form 2-C, the substances identified under Table 2c-3 that may be in the discharge are
as follows:
Marshall Steam Station Hazardous and Toxic Substances
Table 5.1
Acetaldehyde Dodecylbenzenesulfonic Nitric Acid Sodium Hydroxide
Acid
Acetic Acid Ethylbenzene Phenol Sodium Hypochlorite
Adipic Acid Ferrous Sulfate Phosphoric Acid Sodium Phosphate
Diabasic
Aluminum sulfate Formaldehyde Phosphorus Sodium Phosphate
Tribasic
Ammonia Hydrochloric Acid Potassium Bichromate Styrene
Ammonium Hydrofluoric Acid Potassium Hydroxide Sulfuric acid
Chloride
Ammonium Hydrogen Sulfide Potassium Permanganate Toluene
Hydroxide
Antimony Trioxide Maleic Acid Propionic Acid Vanadium Pentoxide
Asbestos Mercuric Nitrate Pyrethrins Vinyl Acetate
Benzene Monoethylamine Sodium Xylene (Mixed Isomers)
Dodec Ibenzenesulfonate
Chlorine Na hthenic Acidalene Sodium Fluoride Zinc Chloride
�_Cupric Nitrate Cyclohexane Nickel Hydroxide
During the course of the year products such as commercial cleaners and laboratory reagents may be
purchased that can contain very low levels of a substance found in Table 2C-3. It is not anticipated
that these products will impact the ash basin's capacity to comply with its toxicity limits, since their
concentrations are extremely low.
5.2 40 CFR 117 and CERCLA Hazardous Substances
The table below identifies hazardous substances located on-site that may be released to the ash
basin during a spill. Substances listed are present in quantities equal to or greater than the
reportable quantity (RQ) levels as referenced in 40 CFR 117, 302 and 355. This list is being provided
in order to qualify for the spill reportability exemption provided in 40 CFR 117 and the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA).
Marshall Steam Station Hazardous Substances in Excess of RQ
Table 5.2
SUBSTANCE QUANTITY SOURCE
Aluminum sulfate 40,987 lbs Powerhouse/Water Treatment
Ammonium hydroxide 3,317 lbs Powerhouse
Benzene 167 lbs Gasoline Tank
Hydrazine* 2,145 lbs Powerhouse/Warehouse
Methyl Tert-But I Ether 1,334 lbs Gasoline Tank
Naphthalene 41,700 lbs Fuel Oil Tanks

Sodium hydroxide 50,040 lbs Powerhouse
Sulfuric acid 6,738 lbs Powerhouse
Xylene Mixed Isomers 42,992 lbs Fuel Oil Tanks
Ferric Sulfate 116,620 lbs Water Treatment
Values in Table 5.2 represent maximum quantities usually on-site at any given time and do not necessarily reflect
quantities discharged. Various amounts of these substances may go to the ash basin for treatment due to use in site
laboratories, small leaks, spills, or drainage from closed loop systems. Treatment of these substances and their by-
products is achieved by physical and biological activity in the ash basin.
*Listed in 40 CFR 302.4-Table 302.4 List of Hazardous Substances and Reportable Quantities.
6.0 Marshall Steam Station 316 Determination
6.1 316(a) Determination
During the term of this permit Duke Energy has continued to monitor the receiving waters
of Lake Norman in an attempt to determine if the Lake still supports a balanced and
indigenous population. The attached Balanced and Indigenous Population Report (BIP)
continues to indicate that Lake Norman continues to support a balanced and indigenous
population of fish and macro-invertebrates. Therefore, Duke energy request that the
thermal variance for the Marshall Steam Station be continued for the next permit cycle.
6.2 Marshall Steam Station 316(b) Determination
Please see the attached alternate schedule request.