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Home My WebLink AboutWQ0032016_Monitoring - 07-2022_20220831Monitoring Report Submittal Permit Number #* Name of Facility:* WQ0032016 Rose Hill Plantation Month: * July Year: * 2022 Report Information Type* Upload Document* GW-59 Rose Hill (WQ0032016) 2.12MB GW59 with lab results 8-31- 22.pdf PDF Only Please upload one PDF containing all applicable monitoring reports (i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59). Confirmation Email Address:* kreese@rpbsystems.com Name of Submitter: * Kimber Reese Signature: Date of submittal: 8/31/2022 This will be filled in automatically Initial Review Reviewer: Gerald, Wanda Is the project number correct?* WQ0032016 Is the monitoring report accepted?* Yes NO Regional Office* Asheville Reviewer: _anonymous Review Date: 9/26/2022 COMPLIANCE REN-M]" FORM Pe i i r n i # -, Of �, -:3 2. CVednyfii aire each ppyonhioripl�r ptnloef with 614-59 fin-Pim) Enter date monitoring results were due. ( 81 Will this monitoring report (GIN-59 and GW-59A) YES NO'', be submitted after the established due date? � 2 Was any required information missing on the GW-59 report forms? YES, NO,, IF the answer to question I or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information, 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? if floe answer is "Yes ", contact the Regional Of .ficejbj, guidance. 4 Are any monitored constituents equal to or above the established standards? YES NO If the answer to question 4 is "NO", skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below: 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? If the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES" list in the space provided below, each well with constituent(s) exceeding standards, concentration (s) reported, and sample collection date for each occurrence (for the last two years), 15- 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES 1*10 If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE, If the answer is 'WO", monitoring wells may be improperly located; contact the Regional Office, 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Re Tonal Office within 90 days: an evaluation may b Mquired to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subLect the permittee to a Notice of Violation, fines, andlor penalties. 8 The person completing this portion (GW-59A) of the monitoring report should sign below and submit this form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form. I hereby acknowledge that the above information was evaluated and the information submitted in this report (Compliance Report GW-59A) is true and complete to the best of my knowledge. Signature of Permittee (or Authorized Agent) Date GW-59A 12/8/2003 SUBMIT FORM ON YELLOW PAPER ONLY 9 DEPARTMENT OF ENVIRONMENTAL QUALITY -DIY. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: � INFORMTION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENMR, RALEIGH, NC 27SWI617 FACILITY INFORMATION Please Pnnt clearly or Type PERMIT Number: Expiration Date: 613012028 Facility Name: Rose Hill Plantation Development, LLC Non -Discharge UIC NPDES Other W00032016 Permit Name (if different): Facility Address: 3041 New Leicester Highway TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediaton: Infiltration (gallery Leicester INC 28748 County Buncombe ❑ Spray Field ❑ Remediation: Contact Person: Bob Barr Telephone#: (828) 251-1900 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Well # 1(MW A on GW-1b) No. of wells to be sampled: 3 ❑ Water Source Heat Pump X Other: Surface Irrigation JTom Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Well # 1 Upgradient Date sample collected: 7/22/2022 FIELD ANALYSES: WAS Well Depth: 69 ft, Well Diameter: 2 in. pH 00400: 5.6 units Temp. 000la: 20.8 °C DRY at Depth to Water Level 82546: 34.24 ft. below measuring point Screened Interval: 49 ft. to 69 ft. Spec. Cond, 00094: 61.9 ffMhos time of sampling, Measuring Point is 2.5 ft. above land surface Relative M.P. Elevation: ft, Odor o0085: None check Volume of water pumped/bailed before sampling: gallons Appearance Clear here:❑ Samples for metals were collected unfiltered: ® YES ❑ NO and field acidified: ❑■ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 81812022 Laboratory Name: Pace Analytical Certification No. 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 0of15 <0,040 mg/L Pb -Lead Ot051 <5.0 ug/L Coliform: MF Fecal 31616 <1 1100mL Nitrate (NO3) as N 00620 <0,040 mg/L Zn - Zinc 01092 <10.0 mg{L Coliform: MF Total 31504 /10()mL Phosphorus: Total as P o0c65 0.067 mg/L (Note:. Use r> PN method for highly turbid sampled Orthophosphate 70507 mg1L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 67.0 mgiL Al - Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 20.1 ug/L TOG o0s8o <1.0 mg/L Ca - Calcium oosls mg/L Chloride 00940 <1.0 mgfL Cd - Cadmium 01027 ug/L Arsenic 01002 <10.0 ug/L Chromium: Total 01034 8.6 ug/L Grease and Oils 00552 mg1L Cu -Copper 01042 <5.0 mgfL ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug[L Fe - Iron 01045 474 ug/L (Specify test and method #, ATTACH LAB REPORT.) Sulfate 00945 mgfL Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ■❑ No (0) Specific Conductance o0095 ttMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia o0610 <0.10 mg1L Mg - Magnesium 00927 mg/L method # (Ammonia NitrogenNH, as N. Ammonia Nitrogen, Tataf) Mn - Manganese 01055 9•3 ug/L ,. method # TKN as N 00625 mg1L Ni - Nickel 01067 ug/L method For Remedlation Systems Only (Attach Lab Reports). Influent Total VOCs: I mg/L Effluent Total VOCs: mg/L VOC Removal% Robert P. Barr I Authorized Agent Perrnittee (or Authorized Agent) Narne and Title - Please print or type vv Signature of Permittee (or Authorized Agent) 3 (Date) GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENTAL QUALITY - DI V. OF WATER RESOURCES GROUNDWATER (QUALITY MONITORING. f .. INPORMA71ON PROCESSINGUNIT- COMPLIANCE REPORT FORM 1617 MAtL SERVICECENTER, RALEIIGH,NC2769 1617 FACILITY INFORMATION Please Print Clearly orType PERMIT Number: Expiration Date: 6/30/2028 Facility Name: Rose Hill Plantation Development, LLC Non -Discharge UIC NPDES tither WQ0032016 Permit Name (if different): Facility Address: 3041 New Leicester Highway TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Leicester NC 28748 County Buncombe ❑' Spray Field ❑ Remediation: Contact Person: Bob Bart Telephone#: (828) 251-1900 ❑ Rotary Distributor ❑ Land Application of Sludge. Well LocationlSite Name: Well # 2(MW B on G -1b) No. of yells to be sampled: 3 ❑ Water Source Heat Pump N Other: Surface Irrigation (front Perm,I). SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit). Well # 2 downgradient Date sample collected: 712212022 FIELD ANALYSES: WAS Well Depth: 30 ft. Well Diameter: 2 in. pH 00400: 5.3 units Temp. 000la: 17.8 °C DRY at Depth to Water Level 82546: 12.29 ft. below measuring point Screened Interval: 10 ft. to 30 ft, Spec. Cond. 00094; 40.0 ftMhos -- time of sampling, Measuring Point is 2.5 ft, above land surface Relative M.P. Elevation: ft. Odor 000m: None check Volume of water pumped/bailed before sampling: gallons Appearance clear here: Samples for metals were collected unfiltered: X YES ❑ NO and field acidified: ❑■ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 8/812022 Laboratory Name: Pace Analytical Certification No. 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD €10335 mg/L Nitrite (NO2) as N 0051b <0.040 rng/L Pb -Lead o1051 <5,0 ug/L Coliform: MF Fecal 31616 <1 11OOmL Nitrate (NO3) as N 00620 0.52 rng/L Zn - Zinc 01092 <10.0 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <0.050 mg/L (Norte- Use MPN method for highly turbid samples)-....._... Orthophosphate 70507 mgiL Other (Specify Compounds and Concentration Units): issolved Solids:Total 20300 <25 mg/L Al - Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 29.7 ug/L TOC 0o6m <1.0 mg/L Ca - Calcium 0091& mg/L Chloride 00940 2-3 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 <10.0 ug/L Chromium: Total 01034 <5.0 ug/L Grease and Oils a0552 mgiL Cu - Copper 01042 <5.0 mg/L ORGANICS: (by GC, GCIMS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 398 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Fig - Mercury 71900 ugfL Late Report Attached? ❑ Yes (1) X No (0) pecific Conductance 00095 uMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia rlmio <0.10 mg/L Mg - Magnesium 00927 mg/L method (Ammonia Nitrogen. NH, as N, Ammonia Nitrogen, Total) Mn - Manganese o1055 7.7 ug/L ,. method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mgiL VOC Removal% Permittee (or Authorized Agent) Name and Title - Please print or type Signature of Permittee (or Author€zed Agent) (Crate) GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENTAL QUALITY ITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNI'T COMPLIANCE REPORT FORM 1617MAIL SERVICE CENTER,RAL IGH,NC 27699.1617 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date; 6/30/2028 Facility Name: Rase Hill Plantation Development, LLC Non -Discharge UIC Permit Name (if different): NPDES Other VVQ0032016 Facility Address: 3041 New Leicester Highway TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Leicester NC 28748 County Buncombe ❑ Spray Field' ❑ Remediation: Contact Person: Bob Barr Telephone#: (828) 251-1900 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Well # 3 No, of wells to be sampled: 3 ❑ Water Source Heat Pump ®❑ Other: Surface Irrigation (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Well # 3 Date sample collected: 7/2212022 FIELD ANALYSES: WAS Well Depth: 14 ft. Well Diameter: 2 in. pH 00400: 6,6 units Temp. 00010: 27.0 oC DRY at Depth to Water Level 82546:4.81 ft. below measuring point Screened Interval: 4 ft. to 14 ft. Spec. Cond. 00094: 129.9 µMhos time of sampling, Measuring Point is 0 ft. above land surface Relative M.P. Elevation: ft. Odor o0085: None check Volume of water pumped/bailed before sampling: gallons Appearance Murky here: Samples for metals were collected unfiltered: ® YES ❑ NO and field acidified: ® YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 818/2022 Laboratory Name: Pace Analytical Certification No. 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0.040 mg/L Pb - Lead o1051 10.8 ug/L Coliform: MF Fecal slats 2.0 _ /100mL Nitrate (NO,) as N 00620 <0.062 mg/L Zn -Zinc 01092 71.1 mg/L Colifbrm: MF Total 31504 /100mL Phosphorus: Total as P 0o66s 2,3 mg/L (Note_ Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 70. mg/L Al -Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 294 ug1L TOC omm <1.0 mg/L Ca - Calcium 00916 mgiL Chloride 00940 3-8 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 <10-0 ug/L Chromium: Total 01034 44.1 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 11.3 mglL ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 71300 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑■ No (0) Specific Conductance 00095 ftMhos K - Potassium 00937 mg1L VOC 7873 method # Total Ammonia o0610 <0.10 mgiL Mg - Magnesium 00927 mgiL method # (Ammonia Nitrogen 14H.,as N: Ammonia Nitrogen, Total) Mn - Manganese o1055 656 ug/L method # TKN as N 00625 mgfL Ni - Nickel 01067 ug/L method For Remediation Systems Only (Attach Lab Reports): influent Total VOCs: Robert P. Barr / Authorized Agent ittee (or Authorized Agent) Name and Title - Please print or type mg/L Effluent Total VOCs: Signature mg/L VOC Removal% (slate) G -59 Rev.06-07-2018 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW 7/22 Pace Project No.: 92616363 Sample: MWA Lab ID: 92616363001 Collected: 07/22/22 09:50 Received: 07/22/22 15:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 08/08/22 10:23 Collected By S.Warlick 1 08/08/22 10:23 Collected Date 7/22/22 1 08/08/22 10:23 Collected Time 09:50 1 08/08/22 10:23 pH 5.6 Std. Units 1 08/08/22 10:23 Temperature 20.8 deg C 1 08/08/22 10:23 Static Water Level 34.24 feet 1 08/08/22 10:23 Specific Conductance 61.9 umhos/cm 1 08/08/22 10:23 Oxygen, Dissolved 4.7 mg/L 1 08/08/22 10:23 7782-44-7 Total Well Depth 69.0 feet 1 08/08/22 10:23 REDOX 103.9 my 1 08/08/22 10:23 Turbidity 9.8 NTU 1 08/08/22 10:23 Odor None 1 08/08/22 10:23 Appearance Clear 1 08/08/22 10:23 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville Arsenic ND ug/L 10.0 1 08/02/2219:05 08/03/2218:13 7440-38-2 Barium 21.0 ug/L 5.0 1 08/02/2219:05 08/03/2218:13 7440-39-3 Chromium 8.6 ug/L 5.0 1 08/02/2219:05 08/03/2218:13 7440-47-3 Copper ND ug/L 5.0 1 08/02/2219:05 08/03/2218:13 7440-50-8 Iron 474 ug/L 50.0 1 08/02/2219:05 08/03/2218:13 7439-89-6 Lead ND ug/L 5.0 1 08/02/2219:05 08/03/2218:13 7439-92-1 BC Manganese 9.3 ug/L 5.0 1 08/02/2219:05 08/03/2218:13 7439-96-5 Zinc ND ug/L 10.0 1 08/02/2219:05 08/03/2218:13 7440-66-6 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services - Asheville Total Dissolved Solids 67.0 mg/L 25.0 1 07/27/22 13:08 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 07/22/22 16:30 07/23/22 16:58 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Ammonia ND mg/L 0.10 1 08/03/22 12:35 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Nitrate ND mg/L 0.040 1 07/23/22 03:30 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 1 07/23/22 03:30 14797-65-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/08/2022 10:28 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 24 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW 7/22 Pace Project No.: 92616363 Sample: MW-1 Lab ID: 92616363001 Collected: 07/22/22 09:50 Received: 07/22/22 15:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services - Asheville Phosphorus 0.067 mg/L 0.050 1 08/02/22 16:44 08/02/22 20:02 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services - Asheville Chloride ND mg/L 1.0 1 07/29/2214:31 16887-00-6 5310E TOC Analytical Method: SM 531OB-2014 Pace Analytical Services - Asheville Total Organic Carbon ND mg/L 1.0 1 07/26/22 16:52 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/08/2022 10:28 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 24 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW 7/22 Pace Project No.: 92616363 Sample: MW-2 Lab ID: 92616363002 Collected: 07/22/22 13:10 Received: 07/22/22 15:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 08/08/22 10:24 Collected By S.Warlick 1 08/08/22 10:24 Collected Date 7/22/22 1 08/08/22 10:24 Collected Time 13:10 1 08/08/22 10:24 pH 5.3 Std. Units 1 08/08/22 10:24 Temperature 17.6 deg C 1 08/08/22 10:24 Static Water Level 12.29 feet 1 08/08/22 10:24 Specific Conductance 40.0 umhos/cm 1 08/08/22 10:24 Oxygen, Dissolved 1.7 mg/L 1 08/08/22 10:24 7782-44-7 Total Well Depth 30.0 feet 1 08/08/22 10:24 REDOX 121.1 my 1 08/08/22 10:24 Turbidity 8.7 NTU 1 08/08/22 10:24 Odor None 1 08/08/22 10:24 Appearance Clear 1 08/08/22 10:24 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville Arsenic ND ug/L 10.0 1 08/02/2219:05 08/03/2218:16 7440-38-2 Barium 29.7 ug/L 5.0 1 08/02/2219:05 08/03/2218:16 7440-39-3 Chromium ND ug/L 5.0 1 08/02/2219:05 08/03/2218:16 7440-47-3 Copper ND ug/L 5.0 1 08/02/2219:05 08/03/2218:16 7440-50-8 Iron 398 ug/L 50.0 1 08/02/2219:05 08/03/2218:16 7439-89-6 Lead ND ug/L 5.0 1 08/02/2219:05 08/03/2218:16 7439-92-1 BC Manganese 7.7 ug/L 5.0 1 08/02/2219:05 08/03/2218:16 7439-96-5 Zinc ND ug/L 10.0 1 08/02/2219:05 08/03/2218:16 7440-66-6 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services - Asheville Total Dissolved Solids ND mg/L 25.0 1 07/27/22 13:08 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 07/22/22 16:30 07/23/22 16:58 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Ammonia ND mg/L 0.10 1 08/03/22 12:37 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Nitrate 0.52 mg/L 0.040 1 07/23/22 03:34 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 1 07/23/22 03:34 14797-65-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/08/2022 10:28 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 24 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW 7/22 Pace Project No.: 92616363 Sample: MW-2 Lab ID: 92616363002 Collected: 07/22/22 13:10 Received: 07/22/22 15:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services - Asheville Phosphorus ND mg/L 0.050 1 08/02/22 16:44 08/02/22 20:19 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services - Asheville Chloride 2.3 mg/L 1.0 1 07/29/2214:00 16887-00-6 5310E TOC Analytical Method: SM 531OB-2014 Pace Analytical Services - Asheville Total Organic Carbon ND mg/L 1.0 1 07/26/22 17:09 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/08/2022 10:28 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 24 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW 7/22 Pace Project No.: 92616363 Sample: MW-3113 Lab ID: 92616363003 Collected: 07/22/22 14:50 Received: 07/22/22 15:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 08/08/22 10:25 Collected By S.Warlick 1 08/08/22 10:25 Collected Date 7/22/22 1 08/08/22 10:25 Collected Time 14:50 1 08/08/22 10:25 pH 6.6 Std. Units 1 08/08/22 10:25 Temperature 27.0 deg C 1 08/08/22 10:25 Static Water Level 4.81 feet 1 08/08/22 10:25 Specific Conductance 129.9 umhos/cm 1 08/08/22 10:25 Oxygen, Dissolved 1.1 mg/L 1 08/08/22 10:25 7782-44-7 Total Well Depth 13.52 feet 1 08/08/22 10:25 REDOX 47.7 my 1 08/08/22 10:25 Turbidity 90.5 NTU 1 08/08/22 10:25 Odor None 1 08/08/22 10:25 Appearance Murky 1 08/08/22 10:25 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville Arsenic ND ug/L 10.0 1 08/02/2219:05 08/03/2218:20 7440-38-2 Barium 294 ug/L 5.0 1 08/02/2219:05 08/03/2218:20 7440-39-3 Chromium 44.1 ug/L 5.0 1 08/02/2219:05 08/03/2218:20 7440-47-3 Copper 11.3 ug/L 5.0 1 08/02/2219:05 08/03/2218:20 7440-50-8 Iron 71300 ug/L 50.0 1 08/02/2219:05 08/03/2218:20 7439-89-6 Lead 10.8 ug/L 5.0 1 08/02/2219:05 08/03/2218:20 7439-92-1 BC Manganese 656 ug/L 5.0 1 08/02/2219:05 08/03/2218:20 7439-96-5 Zinc 71.1 ug/L 10.0 1 08/02/2219:05 08/03/2218:20 7440-66-6 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services - Asheville Total Dissolved Solids 70.0 mg/L 25.0 1 07/27/22 13:08 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Asheville Fecal Coliforms 2.0 CFU/100 mL 1.0 1 07/22/22 16:45 07/23/22 16:58 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Ammonia ND mg/L 0.10 1 08/03/22 12:41 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Nitrate ND mg/L 0.040 1 07/23/22 03:35 14797-55-8 Nitrogen, Nitrite 0.062 mg/L 0.040 1 07/23/22 03:35 14797-65-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/08/2022 10:28 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 24 aceAnalytical wurmpacallabs.cmim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW 7/22 Pace Project No.: 92616363 Sample: MW-313 Lab ID: 92616363003 Collected: 07/22/22 14:50 Received: 07/22/22 15:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services - Asheville Phosphorus 2.3 mg/L 0.050 1 08/02/22 16:44 08/02/22 20:25 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services - Asheville Chloride 3.8 mg/L 1.0 1 07/29/2214:01 16887-00-6 5310E TOC Analytical Method: SM 531OB-2014 Pace Analytical Services - Asheville Total Organic Carbon ND mg/L 1.0 1 07/26/22 17:58 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/08/2022 10:28 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 24 Pace Analytical Services, LLC ceAnal, yical Asheville, Riverside 04 Jq/'� Asheville, NC 28804 wurmpacallab3.cmim (828)254-7176 QUALIFIERS Project: Rose Hill MW 7/22 Pace Project No.: 92616363 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS BC The same analyte was detected in an associated blank at a concentration above 1/2 the reporting limit but below the laboratory reporting limit. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/08/2022 10:28 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 24 77 77 -a - :PB's 3-Lvo :H3'1.dViVS J0-3HnN!D IVIS 0 v :U3ldWVS 10 OWEN ININd CN co CL aunIVNW MV 3MM H3ldWVS 42 =zz-7, 7 - SNOUION0391dum gnu zvc, 0314moov 3wa Siva N0LLVnU4V IW U3KSlMmn3u z t 0I 6 9 79 X x x x x x F Im AL- (24g x x x x x x x s Im -MV4 z x x x x x x x Im L-M L --4 Z > 0 --1 0 K z z m m c 3Mll 31VCI 3V411 aivd o 0 cn io 3 3 0 C-) > EF a w w 0 C Z 0 cn > m o cn 0 3 o z anbuin aq jsnw spl aldweS JO .410 (-'/ 6-O'Z-V) mm m bv xoq Jail joloejeq:) ouo 10 (11 3ldWVS G 3 iHvj-s z I > 0 AAC --AA BUN-C xwxvn SaAfleAJOSal,d GLEZ 'A D190-ld 83ed :#;oafo-,d :ajeo an(] palsenbaH U04"01 1 GIBIS 'waa Sqejooed�uojjed-!jjol JOBEueN PaID'd @3ed MVq TPH usc)a :BLUeN POWd xud 00BL-LoUZO :auO4d :ajonc) 93ed :# JBPJO 8S?q3Jnd wco-swajsAsqdj� uoqj :I!ew3 :Ssajppv Z099Z 0N'9jj!AaLjSrV :BweN Auedwoo :o-L Adoo SZE 4 X08 'O'd :SSqjppv :U01jualivi wed ljaqc8 ;oj ljoda8l -oul stualsAs ed'd :Aueduu-il :uul4uwJO]ml 133!OJd pajlnna?j :uopeLLuojul lua!lo pailnoalj 3 U01pus g Uolloas y U0113as 'IP='Swjal-pjepuels-sedlS;qnqlwoo�sqetaDed-oluill:sdilLI le punoj suoii!puoo pue stwai 00e3 al4l to aousidame pue juawBpajmou� oe S@jnj!jSuoo Apoisno Jo upp S!L41 e!A aldwes e butRwqnS -Aleleinooe pajajd=3 aq isnw SPIOU JUCAalai IIV --LN3vinz)oci -IVO31 e si Apojsno-Jo-ui8q0 a'41 luouinooa IsenboU leoijAlcuV / kuo.Lsn3-:J0-NIVH3 I eAnalytical wurmpacallaba.caim Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 August 08, 2022 Kimber Reese RPB Systems Inc. P.O. Box 1325 Asheville, NC 28802 RE: Project: Rose Hill MW 7/22 Pace Project No.: 92616363 Dear Kimber Reese: Enclosed are the analytical results for sample(s) received by the laboratory on July 22, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Lorri Patton lorri.patton@pacelabs.com 1(828)254-7176 Project Manager Enclosures cc: Mr. Robert Barr, RPB Systems Inc. Ms. Liz Barr, RPB Systems Inc. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 24