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HomeMy WebLinkAboutWI0100230_Regional Office Physical File Scan Up To 9/23/2022NCDENR North Carolina Department of Environment and Natural Resources Division of Waste Management Beverly Eaves Perdue Dexter R. Matthews Dee Freeman Governor Director Secretary September 25, 2012 Mr. Thomas Slusser UIC Program Manager Aquifer Protection Program 1636 Mail Service Center Raleigh, NC 27699-1636 Reference: Chemtronics, Inc Site Swannanoa, NC Dear Mr. Slusser: This letter is to certify that.the clean up being conducted at the Chemtronics, Inc site in Swannanoa is being conducted under the CERCLA program. Per N.C.G.S. 130A.310 (e) "For any removal or remedial action conducted entirely on -site under this Part, to the extent that a permit would not be required under 42 U.S.C. § 9621(e) for a removal or remedial action conducted entirely on -site under CERCLA/SARA, the Secretary may grant a waiver from any State law or rule that requires that an environmental permit be obtained from the Department." Per this statute, the Chemtronics, Inc. site would like to obtain a Letter of Consent for this clean up rather than a Class 5I UIC Permit. The completed application for the Chemtronics, Inc. site should arrive in your office in the next two weeks. If you have any questions or need any additional information contact me at (919) 707-8335. Sincerely, Elizabeth A. Hartzell Environmental Engineer _ NC Superfund Section cc: Stu Ryman, Altamont Environmental, Inc. 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 One NOl"e11C3i011I1a Phone/Fax: 919-707-82001 Internet: http://portal.ncdenr,org/web/wm/ roh An Equal Opportunity lAffrmativeActlon Employer Natur171lY -.--.- ►,.�4� 0 2vi2 I ��t� i NCDEN North Carolina Department of Environment and Natural Resources., Division of Water Quality Beverly Eaves Perdue Charles Wakild, P. E. Dee Freeman Governor Director Secretary November 1, 2012 Todd Hagemeyer, P.G. Geosyntec Consultants 1255 Roberts Boulevard,,Suite 200 Kennesaw, GA 30144 . RE: Chemtronics, Inc. CERCLA Site Swannanoa, Buncombe County, NC Dear Mr. Hagemeyer: The Underground Injection Control Program has reviewed the enhanced bioremediation pilot test workplan for the subject site, which was received on October'17, 2012. The proposed injection project as presented in the workplan meets relevant state regulatory requirements (15A NCAC 2C.0200) for construction and operation of injection wells. Due to the site's coverage under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), the state's administrative permitting requirements have been waived for this project: However, to ensure continued compliance with applicable injection well regulations, please submit well construction and injection event records as well as a technical report summarizing the project -and monitoring data upon completion of the injection project. Please contact me at 919-807-6412 or thomas.slusser@ncdenr.gov if you have any questions. Best Regards, lf5573� Thomas Slusser, L.G. Underground Injection Control Program Manager cc: Elizabeth Hartzell, Superfund Section - Division of Waste Management Landon -Davidson; Aquifer Protection Section= -Asheville -Regional Office_� WIR00230 Permit"File AQUIFER PROTECTION SECTION 1636 Mail Service Center, Raleigh, North Carolina 27699-1617 Location: 512 N. Salisbury SL Raleigh, North Carolina 27604 Phone: 919-807-64641 FAX: 919-807-6496 Internet: www.ncwaterauality.orglweblwg/aps An Equal Opportunity 1 Affirmative Action Employer One NorthCarolina �a&Olf Geosyntec® consultants 1255 Roberts Boulevard, Suite 200 Kennesaw, Georgia 30144 PH, 678.202.9500 FAX 678.202.9501 www.geosyntec.com 28 September 2012 ECEI EDIDE fD Mr. Thomas Slusser 0 C T 1 ;? UIC Program Manager t Division of Water Quality — Aquifer Protection Program Apifef ProfeCtiop, Section North Carolina Department of Environmental and Natural Resources 1636 Mail Service Center Raleigh, NC 27699-1636 Subject: Underground Injection Control (UIC) Permit Application for Enhanced In Situ Bioremediation (EISB) Pilot Testing Chemtronics Site, Swannanoa, Buncombe County, North Carolina Dear Mr. Slusser: Geosyntec` Consultants of NC, P.C. (Geosyntec) has prepared the attached Underground Injection Control (UIC) permit application for the Chemtronics Site located in Swannanoa, Buncombe County, North Carolina (the Site). Geosyntec has prepared this application on behalf of Chemtronics, Inc., Northrop Grumman Systems Corporation (Northrop Grumman), and CNA Holdings LLC (CNA) (together the Companies). Enhanced In Situ Bioremediation (EISB) pilot tests, as described in.this permit application, .are planned at the Site in support of the Remedial Investigation/Feasibility Study (RI/FS) currently being completed under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) program (EPA CERCLIS ID: NCD095459392). Ms. Elizabeth A. Hartzell of the Superfund Section, Division of Waste Management (DWM) in the North Carolina Department of Environmental and Natural Resources (NCDENR) has provided a letter under separate cover to certify that cleanup activities at the Site are being conducted under the CERCLA program. As summarized by Ms. Hartzell, the Companies request a Letter of Consent, as opposed to a Class 51UIC Permit, for the proposed pilot tests per N.C.G.S. 130A.310 (e). Groundwater compounds of potential concern (COPCs) at the Site include volatile organic compounds (VOCs), nitroaromatics, and energetics (perchlorate). EISB was identified during feasibility screening of candidate technologies as a promising remedial technology given Site conditions (i.e., COPC mixtures and distribution, groundwater geochemistry, hydrogeology, GR4943/2012 0928_Chemtronics_0_Cover Letter UIC Application. docx engineers I scientists I innovators_ Mr. Thomas Slusser 28 September 2012 Page 2 etc.). Three EISB pilot tests, which are the subject of this UIC permit application, are proposed to generate design and performance data to support the eventual selection of appropriate technologies for source mass reduction and/or plume migration control within key areas of the Site. EISB is accomplished by stimulating microbial degradation through the injection of a biodegradable organic carbon source. (electron donor) and/or amendment of a bioaugmentation culture. The EISB pilot tests will consist of injecting a biodegradable emulsified vegetable oil (EVO) (Newman Zone®, an EVO product that also includes 4% sodiumlactate) solution into a total of 36 permanent injection wells. For two of the pilot tests, a bioaugmentation culture (KB- 1® Plus, which is a mixture of KB-1® and WBC-2 bioaugmentation cultures) and buffer will also be injected. Potable water will be used to provide additional water for dilution and injection of the EVO solution. Another electron donor, EHCO, will be used to generate anaerobic conditions in the injection fluid prior to injection. Implementation of EISB utilizing EVO as a carbon source/electron donor and a bioaugmentation culture is a safe and environmentally sound remediation technology that is widely practiced. The planned injectants are on the UIC Program's list of approved injectants. Specific details of the injection fluid composition, injection rationale and procedure, and proposed monitoring plan are provided in the attached UIC application. The pilot tests are evaluating an in situ remedy; as such, contaminated groundwater will not be extracted, treated ex situ, and then re -injected into the aquifer. Geosyntec looks forward to working with the Division of Water Quality during their review of the UIC permit application. If you have any questions regarding the Site, the proposed EISB pilot tests, or the attached application, please do not hesitate to contact the undersigned. 0 C T R. 7 2012 Aquifer Protp�ctirrn Section Attachment: UIC Application GR4943/2012_0928_Chemtronics_0_Cover Letter_UIC Application. docx Sincerely, Leah MacKinnon, M.A.Sc. Senior Scientist R. Todd Hagemeyer, P.G. Associate engineers I scientists I innovators OCT 7 ta�1 Aquifer Protection Section UNDERGROUND INJECTION CONTROL (UIC) PERMIT. APPLICATION FOR ENHANCED IN SITU BIOREMEDIATION PILOT TESTING CHEMTRONICS SITE, SWANNANOA, BUNCOMBE COUNTY, NORTH CAROLINA EPA CERCLIS ID: NCD095459392 Prepared by Geq$. consultants - engineers ] scientists I innovators 125:5 Roberts Boulevard, Suite 200 Kennesaw, Georgia 30144 Project Number GR4943 September 2012 CEGEIVEDIDENDW oc� X. 7 2U12 Aquifer P�oi��tion �eGtiQn PERMIT APPLICATION North Carolina Department of Environment and Natural Resources APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION In Situ Groundwater Remediation I Tracer Injection Do not use this form for the following: • in situ remediation, tracer, or aquifer test injection wells permitted by rule (ref. 15A NCAC 02C .0217) • remediation systems that reinject treated contaminated groundwater (ref. 15A NCAC 02T .1600 Application Number (to be completed by DWQ): OCT x 7,20112 I. APPLICATION INFORMATION Aquifer Protection Section 1. Project is: [X] New [ ] Modification [ ] Renewal without modification [ ] Renewal with modification 2. If this application is being submitted for renewal or modification to an existing permit, provide: existing permit number and the issuance date For renewal without modifications, fill out sections I & II only, sign the certification on the last page of this form, and obtain the property owner's signature to indicate consent (rf the applicant is not the owner). For all renewals,. submit a status report including monitoring results of all injection activities to date. H. WELL OWNER (generally the responsible party) 1. Name: Chemtronics.Inc. 2. Signing Official's Name*: Charles Lynn Miller Title: Vice President * Signing Official must be in accordance with instructions in part IX on page 5.. 3. Mailing address of applicant: c/o Rebecca Moring, Halliburton Energy Services, Inc. 2107 CityWest Blvd. City:- Houston State: Texas Zip: 77042-3051 4. Telephone number: 713.839.2179 Email: rebecca.moring@halliburton.com 5. Status (choose one): Individual X Business/Org. Federal State County Municipality III. PROPERTY OWNER (if different than well owner) 1. Name: SAME AS ABOVE' 2. Physical address:. . City:_ 3. Mailing City: 4. Telephone number: State: Zip: State: Zip: HH. PROJECT CONTACT — Person who can answer technical questions about the proposed injection project. 1. Name: Todd Hagemeyer .C.. P.G. #1703) Title: Associate 2. Company: Geosyntec Consultants of NC. PC 3. Address: 1255 Roberts Boulevard, Suite 200 4. City: Kennesaw State: GA Zip: 30144 5. Telephone number: 678.202.9509 Email: THagemeyer@Geoantee.com Revised 5/l/2012 UIC-5I/5T Page 1 of 5 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION . In Situ Groundwater Remediation I Tracer Injection V. FACILITY INFORMATION 1. Facility name: Chemtronics, Inc. Ph#: 281.575.4425 2. Mailing address: 180 Old Bee Tree Road City: Swannanoa County: Buncombe State:NC Zip: 28778 3. Geographic Coordinates: Latitude: 350 37' 10.3" N Longitude: 82 ° 26' 4.08" W Reference Datum: NAD 83 Accuracy: Approximate Method of Collection: Estimated coordinates of site entrance using ArcMap GIS software 4. Brief description of business: former manufacturing plant VI. INCIDENT DESCRIPTION 1. Source and date of contamination: The Site was used for industrial purposes from the early 1950s until 1994. The primary products manufactured at the Site were explosives. incapacitating aaents. and chemical intermediates. Chemicals of Potential Concern (COPCs) have been identified in groundwater, surface water, sediment, and soil in association with various manufacturing and waste disposal areas at the Site. 2. List all contaminants present in soils or groundwater at the site (contaminants maybe listed in groups, e.g., gasoline, diesel, jet fuel, fuel oil, chlorinated ethenes, chlorinated ethanes, metals, pesticides/herbicides, etc): COPCs include trichloroethene (TCE), tetrachloroethene (PCE), 1,2-dichloroethane (1,2-DCA), chloroform (CFI vinyl chloride (VC), research department explosive (RDX), high melting explosive (HMX), 2,4,6-trinitrotoluene (2,4,6-TNT), and perchlorate. 3. Has LNAPL or DNAPL ever been observed at the site (even if outside the injection zone)? [ ] Yes If yes, list maximum measured separate phase thickness: feet [X] No If no, list maximum concentration of total VOCs observed at site: 380,000 ppb 4. Agency managing the contamination incident: [ ] UST Section [X ] Superfund Section (including REC Program and DSCA sites) [ ] DWQ Aquifer Protection Section [ ] Solid Waste Section [ ] Hazardous Waste Section [ X] Other: EPA Region IV Superfiind 5. Incident manager's name: Ms. Elizabeth A. Hartzell, NC Superfund Section Ph#: 919.707.8335 Mr. John Bornholm, EPA Region IV Superfund Ph#: 404.562.8820 6. Incident number or other incident mgmt. agency tracking number: EPA CERCLIS ID: NCD095459392 VII. PERMITS List all applicable permits or construction approvals issued for the facility or incident: 1. Hazardous Waste Management program permits under 2. DWQ Non -Discharge or NPDES permits: 3. County or DEH subsurface wastewater disposal permits: 4. Other environmental permits required by state or federal law: MSD NSIU Permit No. G-006-08: Conditionally Exempt Small Quantity Generators Permit No. NCD095459392 Revised 5/1/2012 UIC-5I/5T Page 2 of 5 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION In Situ Groundwater Remediation I Tracer Injection VIM - ATTACH TENTS — provide the following information in separate attachments. The attachments should be clearly identified and presented in the order below to expedite review of the permit application package. 1. INJECTION ZONE — Specify the horizontal and vertical portion of the subsurface within which the proposed injection activity will take place and beyond which no violations of groundwater quality standards shall result from the injection as determined by an approved monitoring plan. The determination shall be based on the hydraulic properties of the specified zone. Provide any supporting documentation in a separate attachment. 2. HYDROGEOLOGIC EVALUATION — Provide a hydrogeologic evaluation of the injection zone that includes all of the following: (A) Regional and local geology and hydrology; (B) Changes in lithology underlying the facility; (C), Depth to bedrock; (D) Depth to the mean seasonal high water table; (E) Hydraulic conductivity, transmissivity, and storativity, of the injection zone based on tests of site -specific material, including a description of the test(s) used to determine these parameters; (F) Rate and direction of groundwater flow as determined by predictive calculations or computer modeling; and (G) Lithostratigraphic and hydrostratigraphic logs of any existing test and injection wells. 3. INJECTANT INFORMATION — List each injectant in the space below and provide the following information for each injectant. NOTE. Approved injectants can be found online at http://portal.ncdenr.o/web%wg/aps/gwpro. All other substances must be reviewed by the Division of Public Health, Department of Health and Human Services. Contact the UIC Program for more information (Ph# 919-807-6496). Each of the proposed injectants are on the approved list: (i) Newman Zone® an emulsified vegetable oil (EVO)with 4% sodium lactate; (ii) KB-10 Plus, which is a mixture of KB-18 and WBC-2 bioaugmentation cultures (iii1 buffer and/or base (sodium bicarbonate_ calcium carbonate_ magnesium hvdroxicle)- and (ivl F.HC® (A) MSDS, concentration at the point of injection, and percentage if present in a mixture with other injectants; (B) The source of fluids used to dilute, carry, or otherwise distribute the injectant throughout the injection zone. If any well within the area of review of the injection facility is to be used as the fluid source, then the following information shall be submitted: location/ID number, depth of source, formation, rock/sediment type, and a chemical analysis of the water from the source well, including analyses for all contaminants suspected or historically recognized in soil or groundwater on the site; (C) A description of the rationale for selecting the injectants and concentrations proposed for injection, including an explanation or calculations of how the proposed injectant volumes and concentrations were determined; (D) A description of the reactions between the injectants and the contaminants present including specific breakdown products or intermediate compounds that may be formed by the injection; (E) A summary of results if modeling or testing was performed to investigate the injectant's potential or susceptibility for biological, chemical, or physical change in the subsurface; and (F) An evaluation concerning the development of byproducts of the injection process, including increases in the concentrations of naturally occurring substances. Such an evaluation shall include the identification of the specific byproducts of the injection process, projected concentrations of byproducts, and areas of migration as determined through modeling or other predictive calculations. 4. INJECTION PROCEDURE — Submit a table with a detailed description of the proposed injection procedure that includes the following: (A) The proposed average and maximum daily rate and quantity of injectant; (B) The average maximum injection pressure expressed in units of pounds per square inch (psi); and (C) The total or estimated total volume to be injected. Revised 5/1/2012 UIC-5I/5T Page 3 of 5 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION In Situ Groundwater Remediation I Tracer Injection 5. FRACTURING PLAN (if applicable) — Submit a detailed description of the fracturing plan that includes the following: (A) Material Safety Data Sheets of fracturing media including information on any proppants used; (B) a map of fracturing well locations relative to the known extent of groundwater contamination plus all buildings, wells, septic systems, underground storage tanks, and underground utilities located within the Area of Review; (C) a demonstration that buildings, wells, septic systems, underground storage tanks, and underground utilities will not be adversely affected by the fracturing process; (D) injection rate and volume; (E) orientation of bedding planes, joints, and fracture sets of the fracture zone; (F) performance monitoring plan for determining the fracture well radius of influence; and (G) if conducted, the results of geophysical testing or pilot test of fracture behavior conducted in an uncontaminated area of the site. 6. WELL CONSTRUCTION DETAILS — Submit the following information in tabular or schematic form as appropriate for each item: (A) number and depth of injection wells; (B) number and depth of borings if using multi -level or "nested" well systems; (C) indication whether the injection wells are existing or proposed; (D) depth and type of casing; (E) depth and type of screen material; (F) depth and type of grout; (G) indication whether the injection wells are permanent or temporary "direct push" points; and (IT) plans and specifications of the surface and subsurface construction details. 7. MONITORING PLAN - Submit a monitoring plan that includes the following: (A) target contaminants plus secondary or intermediate contaminants that may result from the injection; (B) other parameters that may serve to indicate the progress of the intended reactions; (C) a list of existing and proposed monitoring wells to be used; and (D) a sampling schedule to monitor the proposed injection. Monitoring wells shall be of sufficient quantity and location to detect any movement of injection fluids, injection process byproducts, or formation fluids outside the injection zone. The monitoring schedule shall be consistent with the proposed injection schedule, pace of the anticipated reactions, and rate of transport of the injectants and contaminants. 8. WELL DATA TABULATION —Provide a tabulation of data on all existing or abandoned wells within the area of review of the injection well(s) that penetrate the proposed injection zone, including monitoring wells and wells proposed for use as injection wells. Such data shall include a description of each well's type, depth, and record of construction or abandonment. 9. MAPS AND CROSS -SECTIONS — Provide scaled, site -specific site plans or maps depicting the location, orientation, and relationship of facility components including the following: (A) area map based on the most recent USGS 7.5' topographic. map of the area, at a scale of 1:24,000 and showing the location of the proposed injection site; (B) topographic contour intervals showing all facility related structures, property boundaries, streams, springs, lakes, ponds, and other surface drainage features; (C) all existing or abandoned wells within the area of review of the wells listed in the well data tabulation that penetrate the proposed injection zone; (D) potentiometric surface map(s) that show the direction of groundwater movement, existing and proposed wells; (E) contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the contaminant plume in soil and groundwater, and existing and proposed wells; (F) cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, major changes in lithology, and existing and proposed wells; and (G) any existing sources of potential or known groundwater contamination, including waste storage, treatment, or disposal systems within the area of review of the injection well or well system. Revised 5/1/2012 UIC-5I/5T Page 4 of 5 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION In Situ Groundwater Remediation i Tracer Injection IX. CERTIFICATION* (to be signed as required below or by that person's authorized agent*) NCAC 15A 02C .021'1(e) requires that all permit applications shall be signed as follows: 1. for a corporation: by a responsible corporate officer 2. for a partnership or sole proprietorship: by a general partner or the proprietor, respectively 3. for a municipality or a state, federal, or other public agency: by either a principal executive officer or ranking publicly elected official 4. for all others: by the well owner. *If an authorized agent is signing on behalf of the applicant, then supply a letter signed by the applicant that names and authorizes their agent. "I hereby certify under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments therein, and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is trite, accurate, and complete. I am aware that there are penalties, including the possibility offines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well(s) and all related appurtenances in accordance with the approved specifications and conditions of the Permit. " Printed N Signature Date: 1% a-%�Zo/,?— X. CONSENT OF PROPERTY OWNER (if the property is not owned by the permit applicant) "Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing. "As owner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (Title 1 SA NCAC 02C.0200). " Printed Name and Signature: Date: Submit TWO copies of the completed application package, including all attachments, to: DWQ - Aquifer Protection Section 1636 Mail Service Center Raleigh, NC 27699-1636 REGEIVEM ENRIDW Telephone (919) 807-6464 OCT 17 Z012 Aquifer Protection Section Revised 5/1/2012 UIC-5I/5T Page 5 of 5 ATTACHMENT I INJECTION ZONE 1. INJECTION ZONE 1.1 Overview The Chemtronics Site (Site) is located in Swannanoa, Buncombe County, North Carolina and is divided into two geographic areas commonly referred to as the Front Valley and Back Valley (see. Figure 9-1 of Attachment 9). Enhanced In Situ Bioremediation (EISB) has been identified as the candidate technology with the broadest applicability to the Front Valley groundwater - Areas of Concern (ADCs), and the most likely to have remedial success given. the Front Valley conditions (i.e., Compounds of Potential Concern [COPC] mixtures and distribution, groundwater geochemistry, hydrogeology, etc.). Site COPCs include volatile organic compounds (VOCs), nitroaromatics, and energetics (perchlorate), whose concentrations in groundwater exceed applicable Federal and State standards. Pilot tests are planned in support of the Remedial Investigation/Feasibility Study (RI/FS) currently being completed under the Comprehensive Environmental Response, Compensation, and Liability Act (CERLCA) program (EPA CERCLIS ID: NCD095459392). The proposed injection activities will be evaluated per the monitoring plan described in Attachment 7. The pilot tests are intended to confirm the ability of EISB to effectively degrade the target COPCs to appropriate end products under actual field conditions. The pilot tests will also be used to generate design and performance data for potential scale -up of the EISB technology at these pilot test areas (PTAs). EISB pilot tests are planned at three areas within the Front Valley including: the Building 105- 139 Area (B105-139), Building 147 Area (B147) and Building 149 Area (B149). -The locations of these PTAs are shown in Figures 9-2 and 9-3 of Attachment 9. The pilot tests will be conducted to evaluate the efficacy of treating the following COPCs using EISB: • Groundwater Area B105-139 — Elevated concentrations of chlorinated volatile organic compounds (cVOCs), particularly trichloroethene (TCE; up to 23,000 micrograms per liter [µg/L]), in Zone AB1; • Groundwater Area B147 — Perchlorate (up to 480 µg/L); and • Groundwater. Area B149 = TCE (up to 350 µg/L) in the partially weathered rock in Zone C. The following subsections describe the horizontal and vertical portion of the subsurface within which the proposed injection activities will occur. 1 The surficial aquifer exists in unconsolidated material (referred to as Zones A and B) and partially weathered rock (PWR) (referred to as Zone Q, extending from the water table to the competent bedrock surface. The highly fractured upper portion of . the bedrock aquifer is referred to as Zone D. For further information, refer to Attachment 2. 1.2 Pilot Test Area B105-139 Target Treatment Area and Depth The target treatment area (TTA) for the B105-139 pilot test will measure approximately 70 feet (ft) by 70 ft (see Figure 9-4b of Attachment 9). The proposed target treatment depth (TTD), which is within Zone AB of the surficial aquifer, has been selected to extend from 13 to 28 ft below ground surface (bgs), as shown in Figure 9-6b of Attachment 9. The TTD was chosen to coincide with the screen interval of well MW-180-H38AB, where the highest concentrations of TCE in the B105-139 area have been detected. PTA Layout The PTA layout will consist of an array of 16 injection wells (IWs), as shown in Figure 9-4b of Attachment 9. This layout assumes an anticipated effective radius of influence (ROI) of 11 ft for each IW, so that wells would be spaced on 22 ft centers. The ROI was selected to create a reasonable distribution of emulsified vegetable oil (EVO) in the subsurface while maintaining reasonable target injection volumes.. The injection volume to achieve this ROI (injection volumes are discussed in Attachment 3) has been calculated based upon the TTD described above, an effective porosity of 0.2, and assumes that the injection fluid will replace about 40% of the effective pore volume. It is anticipated that the ROI will be achievable in the soil/saprolite of the Zone AB surficial aquifer. Two existing AB monitoring wells (MW231-1-138AB and MW180-1-138AB) and one existing CD monitoring well (MW200-H38CD) are present within the proposed PTA, while one existing AB monitoring well (MW230-H38AB) is present outside the PTA. These wells will be used for EISB performance monitoring as described in Attachment 7.' The monitoring network will be supplemented with two additional AB monitoring wells, one additional CD monitoring well, and two AB piezometers, as shown in Figure 9-4b of Attachment 9. The locations and number of proposed IWs as well as the locations of the proposed monitoring wells and piezometers may be adjusted based on spacing of existing Site features (i.e., trees) in the PTA. The refined layout and number of wells will not exceed the current design parameters as described above by more than 50%. 1.3 . Pilot Test Area B147 Target Treatment Area and Depth The TTA for the B147 PTA will measure approximately 70 ft by 70 ft (see Figure 9-4b of Attachment 9). The proposed TTD, which is within Zone AB of the surficial aquifer, has been selected to extend from 15 to 35 ft bgs (see Figure 9-6c of Attachment 9). The TTD was chosen to extend from the water table (at approximately 15 ft bgs) to the bottom of the MW-147- 1 screen interval (at 35 ft bgs). The proposed TTA and depth for the B147 PTA are based on currently available perchlorate data but may be refined in the field based on groundwater samples to be collected for COPC analysis following initial installation of the four corner PTA injection wells (see Attachment 7). PTA Layout The PTA layout consists of an array of 16 IWs (see Figure 9-4b of Attachment 9). The IWs were spaced approximately 22 ft apart, yielding an effective ROI of 11 ft. The rationale for this spacing is. the same as described for the well spacing at B105-139 PTA. One existing AB monitoring well (MW-147-1) is present within the proposed PTA, while one existing AB monitoring well (MW-147-2) is present outside the PTA. These wells will be used for EISB performance monitoring as described in Attachment 7. The monitoring network will be supplemented with two additional AB monitoring wells and two AB piezometers. The locations of the proposed piezometers were selected based on the regional groundwater flow, as shown in Figure 9-4b of Attachment .9. The locations and number of proposed IWs, as well as the locations of the proposed monitoring wells and piezometers, may be adjusted in the field based on spacing of existing Site features (i.e., trees, berm) in the PTA and after additional data collection, as described above. The refined layout and number of wells will not exceed the current design parameters as described above by more than 50%. 1.4 Pilot Test Area B149 Target Treatment Area and Depth The pilot test will target Zone C near well MW-149-1 (see Figure 9-4c of Attachment 9). The proposed TTA will measure approximately 60 ft by 60 ft. The pilot test is intended to target the PWR above the competent bedrock in the B149 area. The thickness of the soil and' saprolite above the PWR varies in the B149 PTA, and thus the proposed TTD is the 10 ft interval above the competent bedrock, with a total anticipated depth of between 20 and 50 ft bgs (see Figures 9- 6d/6e of Attachment 9). PTA Layout The layout will consist of 4 IWs (see Figure 9-4c of Attachment 9). The layout assumed an anticipated effective ROI of 19 ft for each IW, so that wells would be spaced on 38 ft centers. The design ROI for B149 PTA is greater than the design ROI for the B105-139 and B147 PTAs since the PWR of Zone C and the highly fractured upper portion of the bedrock aquifer (Zone D) are expected to have greater permeabilities than the Zone AB aquifer material, facilitating greater injection distribution. The injection volume to achieve this ROI (injection volumes are discussed in Attachment 3) has been calculated based upon the TTD described above, an effective porosity of 0.2, and assumes that the injection fluid will replace about 60% of the effective pore volume. Two existing Zone CD monitoring wells (MW-149-1 and MW183-O39CD) are present within the proposed PTA. These will be used for EISB performance monitoring as described in Attachment. 7. To supplement the monitoring network, two additional Zone CD monitoring wells are proposed (see Figure 9-4c of Attachment 9). One additional Zone C monitoring well is also proposed to characterize the shallow groundwater above the TTA. The locations and number of proposed IWs and the locations of the proposed monitoring wells may be adjusted based on spacing of existing Site features (i.e., trees) in the PTA. IN ATTACHMENT 2 HYDROGEOLOGIC EVALUATION 2. HYDROGEOLOGIC EVALUATION 2.1 Geology and Hydrogeology The Chemtronics Site lies within the Blue Ridge Physiographic Province (Horton and Zullo, 1991). The Blue Ridge Province is predominately composed of igneous and metamorphic rocks that have been complexly folded and faulted in a northeasterly direction, parallel to the regional trend of the mountains. These structural imprints are reflected in the topographic and drainage patterns within the region. The predominant rock type underlying in the area are high-grade metamorphic rock of the Ashe Metamorphic Suite. Y The geology of the Site is typical of that found in the Blue Ridge Province and consists of soil and saprolite overlying a partially weathered rock (MR) transition zone which grades into competent bedrock with depth (Altamont, 2010). A generalized depiction of the primary components of the hydrogeologic system is presented in Figure 2-1 (Harned and Daniel, 1992). Unconsolidated material overlying bedrock and extending to the surface is typically known as overburden. In western North Carolina and other parts of the southern Appalachians, most of the overburden is derived from in -place weathering of bedrock, although some is from deposition by streams and rivers (alluvium) or deposition from mass wasting (colluvium). As show in Figure 2-1, the Site is underlain by overburden consisting of soil, saprolite, and weathered rock overlying bedrock. Soil at the Site typically contains high percentages of clay, silt, and fine sized particles and thus is anticipated to have relatively low permeability of about 10-2 feet/day (ft/day), based on literature values for similar materials. The saprolite, which generally ranges from 2 to 65 ft thick, is highly weathered with variable permeability while the PWR layer (generally 5 to 10 ft thick) covers the bedrock and is anticipated to have moderate permeability of about 10-1 ft/day, based on literature values for similar materials. The permeability of the PWR can be locally variable depending on mineralogy and structure. The predominant bedrock underlying the Site is muscovite-biotite gneiss while garnet -muscovite schist has also been encountered (Altamont, 2010). Cross -sections depicting the thickness of the overburden and the depth to bedrock are shown in Figures 9-6a to Figure 9-6e of Attachment 9. The majority of the Site is situated within one of two local watersheds which are separated by a prominent ridge. These watersheds are the Unnamed Branch and Gregg Branch, which are commonly referred to as the Front Valley and Back Valley, respectively. Both of these watersheds are part of a larger watershed- (Bee Tree Creek) and a regional watershed (Swannanoa River; Figure 9-1 of Attachment 9). Two primary aquifer systems exist at the Site; the surficial aquifer and the bedrock aquifer. The aquifers are likely interconnected throughout the Site, but each has distinctly different characteristics that define the groundwater flow paths within them. The surficial aquifer exists in unconsolidated material (referred to as Zones A and B) and PWR (referred to as Zone C), extending from the water table to the competent bedrock surface. The highly fractured upper portion of the bedrock aquifer is referred to as Zone D. The deeper bedrock aquifer (referred to as Zones E and F) consists of sparsely interconnected joints and fractures within the competent bedrock. Potentiometric surface maps for Zone AB and Zone CD, including the locations of the pilot test areas (PTAs), are shown in Figure 9-4a through Figure 9-4c of Attachment 9. The potentiometric surface maps for Zone AB and Zone CD indicate that the predominant groundwater flow direction is generally down -valley towards the southeast. Average groundwater flow velocities of approximately 0.15 ft/day have been estimated for both the AB and CD zones of the Front Valley of the Chemtronics Site. This groundwater flow velocity has been estimated by dividing the specific discharge, calculated using Darcy's Law, by a literature derived estimate of the effective porosity of the system. These parameters are fairly similar for Zone AB and Zone CD. The specific discharge was calculated using a hydraulic conductivity value of 1.17 ft/day, which was estimated from a recent long-term pumping test in the Front Valley, and a hydraulic gradient of 0.025 ft/ft, which was calculated from groundwater levels measured in wells in the Front Valley of the Site for Zones AB and CD. A value of 0.21 was used for the effective porosity and was obtained from a published value for fine sand (Fetter, 1994). Groundwater elevations were measured within each PTA in April 2012. The recorded depths to water were: (i) 9.4 ft below ground surface (bgs) at MW180-H38AB in B105-139 PTA; (ii) 12.4 ft bgs at MW-147-1 in B147 PTA; and (iii) 7.75 ft bgs at MW-149-1 in B149 PTA. Review of historical groundwater level measurements indicates that, in general, the various aquifer zones respond to seasonal and annual changes in precipitation similarly (Altamont, 2010). Temporal changes in water -level vary across the Site with a range of a few feet in the Front Valley surficial aquifer to as much as 6 ft in the bedrock aquifer. 2.2 References Altamont, 2010. Remedial Investigation/Feasibility Study (RI/FS) Work Plan - Work Plan Overview. Chemtronics Site, Swannanoa, Buncombe County, North Carolina. January, 2010. Fetter, C.W., 1994. Applied Hydrogeology, 3rd edition, Prentice -Hall, New Jersey. Harried, D.A., and Daniel, C.C.; III, 1992. The transition zone between bedrock and regolith: Conduit for contamination?, in Daniel, C.C., III, White, R.K., and Stone, P. A., eds., Ground Water in the Piedmont, Proceedings of a Conference on Ground Water in the Piedmont of the Eastern United States, Charlotte, N.C., Oct. 16-18, 1989: Clemson, S.C., Clemson University, p. 336-348. Horton, J.W., Jr. and Zullo, V.A., 1991. The Geology of the Carolinas, Fiftieth Anniversary Volume, Carolina Geology Society, The University of Tennessee Press/Knoxville. ATTACHMENT 2 FIGURE Water l Zone A Zone B Zone C Zone D Zones E and F Note: Modified from Harned and Daniel, 1992 Soil Zone Saprolite _ Partially Weathered Bedrock (Transition Zone) Competent Bedrock (Fractured Gneiss) Sheet Joint Bedrock Fabric (Foliation) Fracture ATTACHMENT 3 INJECTANT INFORMATION 3. INJECTANT INFORMATION This attachment provides information on- the proposed injectants for the Enhanced In Situ Bioremediation (EISB) pilot tests. The proposed injectants include: (i) Newman Zone®, an emulsified vegetable oil (EVO) which will serve as an electron donor; (ii) KB-10 Plus, which is a mixture of KB-10and WBC-2 bioaugmentation cultures; (iii) buffer. (sodium bicarbonate,. calcium carbonate) and/or base (magnesium hydroxide) for pH control; and (iv) EHC®, a slow release electron donor containing zero-valent iron. Each of the proposed injectants is on the North Carolina Department of Environment and Natural Resources (NCDENR), Division of Water Quality (DWQ.), Aquifer Protection Section (APS), Underground Injection Control (UIC) Program's list of approved injectants2. Material Safety Data Sheets (MSDSs) for each proposed injectant are provided in Attachment 3-A. 3.1 Pilot Test Design and Implementation Overview The EISB approach will be to inject a food -grade, slow -release electron donor (EVO that includes 4% sodium lactate [Newman Zone®]) into the target aquifer zone (either Zone AB or Zone C, as defined for each pilot test area [PTA] in Attachment 1) to establish a biologically active zone (BAZ) to promote in situ biodegradation of target compounds of potential concern (COPCs). For the B105-139 and B149 PTAs, a commercially available bioaugmentation culture (KB40 Plus) comprised of natural dehalorespiring bacteria, will also be injected to mediate the full biodegradation of trichloroethene (TCE) to ethene. Bioaugmentation will not be implemented at the B147 PTA since the microorganisms necessary for. complete biodegradation of perchlorate, the target COPC in this PTA, are anticipated to be already present in the subsurface (they are believed to be ubiquitous).. The target pH range for the B105-139 and B149 PTAs will be between 6.5 and 8.3. The pH in B105-139 and B149 PTA has been observed to be as low as 4.9 and 5.5, respectively (pH data provided in Figure 9-5a and Figure 9-5c in Attachment 9). Therefore, a buffer (i.e., sodium bicarbonate, calcium carbonate) and/or base (i.e., magnesium hydroxide) will also be injected into the B105-139 and B149 PTA groundwater along with the electron donor to establish and maintain suitable pH conditions during the pilot tests. In the B 147 PTA, the pH . has been observed to be as low as 6.1 (pH data provided in Figure 9-5b in Attachment 9). Since bacteria responsible for reduction of perchlorate, the target COPC in this PTA, remain active at lower pH levels (compared to the microorganisms responsible for transformation of TCE, the target COPC in the other PTAs) and the background pH is somewhat higher in this PTA, buffer will not be added to the B 147 area. 2 http://portal.nedenr.org/c/document library/get_file?uuid=foc4520b-a93d-4bOd-92ab- 098e5650fl 8e&groupId=38364 Injection of EVO, buffer and, as appropriate, the bioaugmentation culture, into the subsurface will be performed using a series of injection wells (IWs) distributed across each PTA. The layouts, target areas, and target depths for each PTA are discussed in Attachment 1. 3.2 Injectant Volumes and Concentrations This section describes injectant volumes and concentrations. The injectant volumes outlined below and in Table 3-1 are based on the proposed pilot test layouts, which may be adjusted in the field based on site conditions and/or additional data collection (see Attachment 1). Therefore, the injectant volumes may be less than outlined below or, if greater, will not exceed the outlined quantities by more than 50%. Electron Donor The total mass of EVO to be injected in each PTA is a function of. (i) the number of IWs per PTA (see Table 3-1); (ii) the target treatment volume; and (iii) the target EVO concentration. The target treatment volume for each injection point was estimated to be approximately 3,450 gallons (gal), 4,600 gal, and 10,600 gal -for the B 105-139, B 147, and B 149 PTAs, respectively. These estimates assumed design radii of influence (ROIs) and target treatment depths (TTDs) as specified in Table 3-1 and a porosity of 0.20. A target EVO concentration of 0.5% (volume/volume [v/v], as oil) was selected for the B147 and B149 PTAs. A target EVO concentration of 1.0% (v/v, as oil) was selected for B105-139, as this PTA contains higher COPC concentrations than the other PTAs. Based on performance at other sites, these EVO concentrations are sufficient to provide electron donor to treat Site COPCs but low enough to minimize methane production which can occur if the electron donor is over -dosed and if the resulting oxidation-reduction potential (ORP) is driven too low (i.e. methanogenesis). Based on the defined ROIs and target concentrations, approximately 260, 175, and 400 kilograms (kg) of EVO will be injected into each 1W in the B105-139, B147, and B149 PTAs, respectively, with a total of 8,500 kg of EVO planned to be injected during the pilot testing. In addition, up to 210 kg of a slow release electron donor (EHe) will be added to potable water that will be used as the injection fluid for bioaugmentation (the EHC® will help make the water anaerobic, to accommodate the anaerobic microorganisms in the bioaugmentation culture). Bioaugmentation Culture KB-10 Plus (which is a mixture of KB-10 and WBC-2 bioaugmentation cultures) is a commercially available remediation culture provided by SiREM, will be used as the bioaugmentation culture to promote TCE dechlorination. The total volume of KB-1® Plus culture recommended by SiREM to provide sufficient microbial mass to stimulate reductive dechlorination is 32 liters (L) each for the B105-139 and B149 PTAs (see Table 3-1). The volume of culture will be distributed equally between the IWs in each PTA. Buffer Groundwater pH measured in the B105-139 and B149 PTAs is typically below or on the low end of the range (pH 6.5 to 8.3) for effective biodegradation of chlorinated volatile organic compounds (cVOCs) (pH data provided in Figure 9-5a and Figure 9-5c in Attachment 9). A buffer (i.e., sodium bicarbonate, calcium carbonate) and/or base (i.e., magnesium hydroxide) will be amended to the injection fluid -to provide pH control in the B105-139 and B149 PTAs. A bench test with soil cuttings generated during well installation will be completed to confirm the appropriate dose of amendment(s) for pH control for the pilot tests, as the dose will be dependent on the Site geochemistry. Concentrations are anticipated to be up to 10 g/L for sodium bicarbonate; 20 g/L for magnesium hydroxide, and 80 g/L for calcium carbonate. It is expected that lower concentrations may actually be used, pending the results of the bench test. As discussed above, buffer addition in the 8147 PTA is not planned. Dilution Water The injection fluid will be prepared by diluting the EVO to the target concentration with potable water from the local municipality, with a total volume of up to 55,200, 73,600, and 42,400 gal to be injected into 13105-139, B147 and B149 PTAs, respectively, during the pilot test. 3.3 Anticipated COPC Transformations Laboratory and field demonstrations over the past decade have shown that microorganisms in subsurface environments (e.g., groundwater) can degrade cVOCs, perchlorate and research department explosive (RDX) to environmentally acceptable end products (DOD, 2004; Hawari et al., 2000, Crocker and Indest, 2006, Cox et al:, 2000). While these biodegradation reactions can occur under a range of environmental conditions, the dominant biodegradation mechanism employed in EISB applications for these COPCs is reduction, which occurs under anaerobic conditions (absence of oxygen). In each case, the COPCs serve as electron acceptors, and are reduced, while organic carbon substrates (e.g., EVO) serve as electron donors. For cVOCs, sue as TCE, the dominant biodegradation mechanism used in EISB applications is reductive dechlorination, which involves the sequential replacement -of chlorine atoms on the alkene molecule with hydrogen atoms. Under reducing conditions, TCE is dechlorinated to cis- 1,2-dichloroethene (cis-1,2-DCE) then to vinyl chloride (VC) and finally to ethene. Hydrogen, typically produced during the bacterial metabolism of simple organic carbon compounds such as alcohols, organic acids, sugars or edible oils, serves as the electron donor in the dechlorination reactions. Figure 3-1 shows the common biodegradation pathways for chlorinated ethenes, including TCE. Perchlorate biodegradation results from microbially-mediated redox reactions where perchlorate serves as the electron acceptor and is reduced to chlorate and then to chlorite (Figure 3-2). Chlorite then undergoes a biologically mediated dismutation reaction, producing chloride and oxygen. Anaerobic biodegradation of RDX can proceed through a number of pathways, which include two -electron reduction, single -electron reduction (or denitration), and direct enzymatic ring cleavage (Figure 3-3). Biological breakdown products of RDX include carbon dioxide (CO2), methane, nitrous oxide, hydrazine, and dimethyl hydrazines. 3.4 Anticipated Injectant Transformations The following subsections describe the injectants' potential for or susceptibility to transformation in the subsurface. Electron Donor Newman Zone® is a biodegradable EVO product that contains both fast- and slow -release electron donors. In the subsurface, Newman Zone° is anticipated to undergo microbial biodegradation, producing volatile fatty acids (VFAs) (e.g., lactate, acetate) and dissolved hydrogen. VFAs and dissolved hydrogen are necessary to stimulate microbial reductive dechlorination of chlorinated organic compounds; VFAs and dissolved hydrogen get consumed during the process. Total organic carbon (TOC) analysis, as discussed in Attachment 7, will be used as an indication of changes in EVO and VFA concentrations. Following injection, it is expected that the EVO will remain essentially stationary in the subsurface, and will serve as a long-term source of electron donor to promote biodegradation of the COPCs in these areas. Similar transformations are anticipated for EHC®; the zero-valent iron in EHC®, which is not anticipated to be injected itself, is anticipated to react with dissolved oxygen in dilution fluids to produce anaerobic water. Bioaugmentation Culture In the subsurface, the microbial populations within KB-18 Plus are anticipated to grow as they consume the electron donor/carbon source (Newman Zone°) and transform the chlorinated organics via reductive dechlorination. Once the chlorinated solvents are degraded, the microbes no longer have the necessary energy source to continue growing, resulting in the death of the microbial populations. KB-1® Plus is not expected to undergo chemical or physical transformation in the subsurface. Buffer/Base The addition of a buffer (i.e., sodium bicarbonate, calcium carbonate) or base (i.e., magnesium hydroxide) are anticipated to neutralize pre-existing acidic groundwater conditions and the influence of VFA production on groundwater pH. 3.5 Potential Byproduct Formation In addition to the anticipated transformations of COPCs and injectants discussed in Sections 3.3 and 3.4, respectively, EISB may result in the formation of additional byproducts. For example, anaerobic conditions established during EISB can enhance the mobility of naturally occurring iron and manganese. Additionally, EISB can result in the formation of methane. As discussed above, the proposed EVO concentrations are anticipated to be sufficient to provide electron donor to treat Site COPCs but low enough to minimize methane production. Dissolved metals and methane are included in the monitoring program as discussed in Section 7. 3.5 References Cox EE, Edwards E, Neville S. 2000. In situ bioremediation of perchlorate in groundwater. In.. Urbansky ET, eds, Perchlorate in the environment. Kluwer Academic, New York, NY. Crocker and Indest, 2006, Biodegradation of the cyclic nitramine explosives RDX, HMX, and CL-20, Appl. Microbiol. Biotechnol. 73:274. DOD, 2004. Principles and Practices of Enhanced Anaerobic Bioremediation of Chlorinated Solvents. August, 2004. Hawari; J., A. Halasz, T. Sheremata, S. Beaudet, C. Groom, L. Paquet, C. Rhofir, G. Ampleman, and S. Thiboutot. 2000. Characterization of metabolites during biodegradation of hexahydro- 1,3,5-trinitro-1,3,5-triazine (RDX) with municipal anaerobic sludge. Appl. Environ. Microbiol. 66:2652-2657. ATTACHMENT 3 TABLE TABLE 3-1: EISB PILOT TEST INJECTION DETAILS Chemtronics Site, Swannanoa, NC Geosyntec Consultants PTA #1 B105-139 PTA #2 B147 PTA #3 B149 Totalst Target COPC WE Perchlorate WE na Zone AB AB C na New AB Zone Monitoring Wells 2 2 0 4 New C/CD Zone Monitoring Wells 1 0 3 4 Estimated Number of EVO Injection Wells 16 16 4 .36 Porosity 0.20 0.20 0.20 na Target Average Biobarrier Thickness [ft] 15 20 10 na Theoretical Radius of EVO Injection [ft] 7 7 15 na Anticipated Effective Radius of EVO Injection [ft] 11 11 19 na Target % oil 1.0% 0.5% 0.5% na Mass of Slow Release Electron Donor per well [kg] 259 172 397 8,500 Volume of Slow Release Electron Donor (EVO) per well [gal] 69 46 106 2,300 Target Injection Volume per well [gal] 3,450 4,600 10,600 171,200 Estimated Injection Rate per well [gpm] 1.5 1.0 1.5 na Minimum Estimated Time to Inject Per well (assumes 6 hr/day injection time) [days] 6.4 12.8 19.6 na Bioaugmentation volume per well [L] 2 0 8 64 EHC mass per well [kg] 4 1 6 12 210 Notes: COPC - compound of potential concern TCE - trichloroethene EVO - emulsified vegetable oil ft - feet kg - kilogram gal - gallons gpm - gallons per minute PTA - pilot test area L - liters na - not applicable 1 - Totals represent the sum for all three pilot tests. Totals were calculated by first multiplying the per -well quantities by the number of wells. PTA quantities are estimates based on the pilot test conceptual design and may be refined based on baseline characterization results and/or performance during injections. 2 - This radius of influence assumes that 100% of the pore volume will be replaced by the injection fluids. 3 - Based on experience at other sites, it is anticipated that the effective radius of influence will be greater than the theoretical radius of influence because replacement of the pore volume will be less than 100%. 2012 0928 Chemtronics 6b Attachment 3 Table 3-1.xlsx 09.28.2012 ATTACHMENT 3 FIGURES Aerobic Conditions Anaerobic Conditions Tetrachloroethene (PCE).. reductive dechlorination CO2 cometabolism Trichloroethene (methanotrophs) (TCE) -(toluene oxidizers) (propane oxidizers) reductive (ammonia oxidizers) dechlorination (phenol oxidizers) (ethene oxidizers) CO2 cometaborism (as forTCE) cis-1,2-Dichloroethene (cls-1,2=DCE) anaerobic oxidation (manganese reducers) CO2 or oxidation reductive dechlorination CO2 cometabolism (as for TCE) Vinyl Chloride anaerobic oxidation . or oxidation VC (_ ) (iron reducers) C 02 reductive dechlorination CO2 oxidation Ethene Ethane CIO" (Perchlorate) Electron Donor (reduction) CO2, H2O, Biomass 6103 (Chlorate) Electron Donor (reduction) CO2, H2O, Biomass CI03 (Chlorite) (chlorite dismutation) Electron Donor CI- +-02 \ CO2, H2O. Biomass I 2e reduction 1 e- reduction , � Cleavage _ ----- - Cleavage I l; Ring Ring g g , i 2e- reduction i DNX, TNX ; Hydroxylamino RDX Derivative Ring Cleavage if McOH + HCHO + Dimethyl + Hydrazine i �I MDNA BHNA I! Spontaneous decomposition Hydrolysis in water I. I I HMNA i i I Nitramines + Formaldehyde I i a; Abiotic Biotransformation Hydrazines i ,j Biotransformation Carbon Dioxide Nitrous Carbon + j Oxide Dioxide Methane + Methan Two -Electron Reduction Legend DNX - dinitroso compound derivative MNX - mononitroso compound derivative TNX-trinitroso compound derivative e- - electron RDX-1,3,5-trinitro-1,3,5-triazine (Research Department Explosive) MDNA - methylenedinitramine BHNA - bis(hydroxylmethyl)nitramine HMNA - hydroxymethylnitramine HCHO-formaldehyde McOH- methanol Source: 1. Howari er aL, 2000, AppL Environ. MicrobioL 66:2652. 2. Crocker and Indest 2006, AppL Microbial. Biorechnol. 73.274. Enzymatic Cleavage NO2 RDX MDNA Unknowns Spontaneous decomposition. in water HMNA Nitramines + HCHO Abiotic Biotransformation Nitrous Carbon Oxide Dioxide e Methane Single -Electron Red uction/Denitrition ATTACHMENT 3 -A MATERIAL SAFETY DATA SHEETS MODIFIED MATERIAL SAFETY DATA SHEET: USA Page 1 of 3 Remediation,and Natural Attenuation Services Incorporated 6712 West River Road Brooklyn Center, MN 55430 Product Information: 763-585-6191 Issue Date: February 5, 2010 Section 1� ,E IDENThFICATION. , ;- , � ,`,.� 1.1 Product Name: Newman Zone -Standard Formulation 190-6722 1.2 Product Type: Edible Industrial Nutrient for Microbial Organisms 1.3 Hazard Rating: Health: 1 Fire: 1 Reactivity: 1 1.4 Formula: Proprietary -------------------------------------------------------- m Subject to SARA 313 Reporting Are Indicated by 4" -------------------------------------------------------------------------- It is our opinion that the above named product does not meet the definition of "hazardous Chemical" as defined in the OSHA "Hazard Communication Standard" regulation 29 CFR 1910.1200. This material Safety Data Sheet is provided as general information for health and safety guidelines. ,Section 2_ �INGREDhENTS�COMPOSITION (mg /m3 ) CAS No. o PEL TWA Soybean Oil (food grade) 8001-22-7 46 15(Mist) 10(Mist) Sodium-L-Lactate 867-56-1 4 Food Additives/Emulsifiers/Preservatives (Proprietary) <10 Water <45 EMERGENCY ONLY, 24-HOUR SERVICE: CHEMTREC: 1-800-424-9300 ;Section 3 m PHYSICAL AND CHEMICAIL CHARACTERISTICS This section completed per formulation ingredient data unless stated. • Solubility: Dispersible in water (product) • PH: 7.0 (product) • Specific Gravity: 0.99 (product) • Boiling Point: NA • Vapor Pressure: NA • Vapor Density: NA • Percent Volatile By Volume (o): NA • Evaporation Rate: NA • Viscosity: 23.6 cps @ 68°F (Brookfield)(product) • Product Appearance and Odor: White -colored liquid, vegetable oil odor. I Page 2 of 3 Section 4: FIRE AND EXPLOSION HAZARDS This section completed per formulation ingredient data unless stated. 4.1 Special Fire Hazards: Product - none, does not support combustion. Flash Point: >540 degrees F (Pure Soybean Oil Closed Cup). Flammable Limits LEL ND UEL ND 4.2 Fire Fighting Methods: Use method appropriate for surrounding fire. 4.3 Extinguishing Media: Dry Chemical or CO2 Preferable; water may cause spattering or -spreading. _...._.-- ..... _._ :- 'Section 5: HEALTH HAZARD DATA 5.1 THIS PRODUCT IS USED FOR SOIL AND GROUND WATER REMEDIATION BUT IS FORMULATED USING FOOD AND FOOD GRADE ADDITIVES. PROCESSING, PACKAGING, SANITATION AND STORAGE OF THE PRODUCT FOLLOWS THE BEST PRACTICES USED FOR FOOD PRODUCTS. 5.2 Effects of Overexposure: NA 5.3 Emergency and First Aid Procedures: If inhaled, remove from contaminated atmosphere. For eye contact immediately flush eyes with large amounts of water. Ensure rinsing entire surface of eye & under lid. For skin contact wash affected areas thoroughly with soap and water. Seek medical help for persistent irritation. 5.4 Hydrolyzed soy protein has been identified by the United States Food and Drug Administration as a food allergen. Symptoms include swelling of the lips, stomach cramps, vomiting, diarrhea, skin hives, rashes, eczema and breathing problems. 5.5 Occupational Exposure Limits [8-hour time weighted averages (TWA)]: mg /m3 CAS No. OSHA PEL/ACGIH TLV Soybean Oil (food grade). 8001-22-7 15(Mist)/10(Mist) :Section 6,: REACTIVITY DATA This section completed per formulation ingredient data unless stated. 6.1 Stability: Stable under normal conditions. 6.2 Conditions to Avoid: NA 6.3 Incompatibilities: None known 6.4 Hazardous Decomposition Products: Product - None identified. Ingredients -,Carbon oxides. Biological decomposition (spoilage) may result in offensive odors. 6.5 Hazardous Polymerization; None known Page 3 of 3 Section 7:< SPILL OR LEAK -PROCEDURES This section completed per formulation ingredient data unless stated. 7.1 Spill Response: Water dispersible. Same as for vegetable oil spills: isolate spill, prevent from entering waterways, and sewer systems. Sorb or remove spilled materials as soon as possible. Oils and specific quantities of oils may be reportable under federal, state, or local regulations. 7.2 Waste Disposal Method: This product is not hazardous, however, wastes must be disposed in accordance with local, state or federal .regulations. Consult with local sewer authority, or solid waste facility prior to disposition... 'Section 8r SPECIAL PRECAUTIONS No protectiveequipment is necessary under normal use conditions. 8.1 Eyes: If splashing may occur, eye protection recommended. 8.3 Skin: Wear impervious gloves for prolonged or repeated exposure. 8.4 Respiratory: Avoid breathing mists of this product 'Section 9. TRANSPORTATION PRECAUTIONS. i This section completed per formulation ingredient data unless stated. 9.1 Transportation Considerations: This product is not classified as dangerous in the meaning of transport regulations. Shippers and transporters may need to meet packaging and transportation requirements for certain oils and respective quantities under CFR 49 Part 130. The above information is believed to be correct with respect to -the formula used to manufacture .the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. "REM Sfe Reiovery&Management 130 Research Lane, Suite 2 Guelph•Ontario • N1G 5G3 • Canada • Tel: (519) 822-2265 • Fax: (519) 822-3151 KB-10 Plus Material Safety Data Sheet Section 1: Material Identification Trade Name: KB-10 Plus Chemical Family: bacterial mixture Chemical name: No IUC name for mixture is known to exist Manufacturer/Supplier: SiREM 130 Research Lane, Suite 2, Guelph, Ontario, Canada-N1G 5G3 For Information call: 519-822-2265 / 1-866-251-17.47 x236 Emergency Number: 519-822-2265 Description: Microbial inoculum (non-pathogenic, non -hazardous) Trade Name: KB-16Plus Product Use: Bioremediation of contaminated groundwater. Date Prepared: 23 October 2008 Section 2: Composition, Information on Ingredients KB-10 Plus is a microbial culture grown in a dilute aqueous mineral salt solution -media containing no hazardous ingredients. The microbial composition of KB-10 Plus is listed in Table 1. Table 1. Major Microbial Groups Identified in KB-1®Plus Microbial lnoculum Acetobacterium Acidaminococcaceae Dehalobacter sp. Dehalococcoides sp. Desulfovibrio sp. Methanomethylovorans sp. 1 Section 3: Hazards Identification: A review of the available data does not indicate any known health effects related to normal use of this product. Section 4: First Aid Measures: Avoid direct contact with skin and eyes. In any case of any exposure which elicits a response, a physician should be consulted immediately. Eye Contact: Flush eyes with water for at least 15 minutes, occasionally lift upper and lower eyelids, if undue irritation or redness occurs seek medical attention. RTRASIREMU-tealth and SafetyWSM13ioaugmentation CuHure MSDSs\KB-1 PLUS MSDS .doc CRecovery& Management 130 Research Lane, Suite 2 Guelph •Ontario • N I G 5G3 • Canada • Tel: (519) 822-2265 • Fax: (519) 822-3151 Skin Contact: Remove contaminated clothing and wash skin thoroughly with water and antibacterial soap. Seek medical attention if irritation develops or open wounds are present. Ingestion: Do not induce vomiting, drink several cups of water, seek medical attention. Inhalation: Remove to fresh air. If not breathing give artificial respiration. In case of labored breathing give oxygen. Call a physician. Section 5 - Fire Fighting Measures: Non-flammable Flash Point: not applicable Upper flammable limit: not applicable Lower flammable limit: not applicable Section 6 — Accidental Release Procedures Spilled KB-10 Plus should be soaked up with sorbant and saturated with a 10% bleach solution (prepared by making a one in ten dilution of diluted standard bleach [normally sold at a strength of 5.25% sodium hypochlorite] to disinfect affected surfaces. Sorbant should be double bagged and disposed of as indicated in section 12. After removal of sorbant, area should be washed with 10% bleach solution to disinfect. If liquid from the culture vessel is present on the fittings, non -designated tubing or exterior of the stainless steel pressure vessel liquid should be wiped off and the area washed with 10% bleach solution. Section 7 - Handling and Storage KB-10 Plus is shipped in stainless steel pressure vessels in a protective over pack. KB- 1® Plus should be handled with care to avoid any spillage. Vessels are shipped with 1 pound per square inch (psi) pressure; valves should not be opened until connections to appropriate lines for subsurface injection are in place. Storage Requirements: Avoid exposing stainless steel pressure vessels to undue temperature extremes (i.e., temperatures less than 0°C or greater than 300C may result in harm to the microbial cultures and damage to the vessels). All valves should be in the closed position when the vessel is not pressurized or not in use to prevent the escape of gases and to maintain anaerobic conditions in the vessel. Avoid exposure of the culture to air as the presence of oxygen will kill dechlorinating microorganisms. Section 8 - Exposure Controls/Personal Protection Personal protective equipment: Skin: Protective gloves (latex, vinyl or nitrile) should be worn. Eye Protection: Wear appropriate protective eyeglasses or goggles when opening pressure vessels, valves, .or when pressurizing vessels to inject contents into the subsurface. Respiratory: No respiratory protection is required. Engineering Controls: Good general room ventilation is expected to be adequate. RTRASiREMNealth and Safely4MSDSViioaugmentation Culture MSDSsVB-1 PLUS MSDS .doc SE E Site Recovery&Management 130 Research Lane, Suite 2 Guelph•Ontario • N1G 5G3 -Canada • Tel: (519) 822-2265 • Fax: (519) 822-3151 Section 9: Physical and Chemical Properties: Physical State: liquid Odour: skunky odour Appearance: dark grey, slightly turbid liquid. under anaerobic conditions, pink if exposed to air (oxygen). Specific gravity: 1 Vapor pressure: not applicable Vapor density: not applicable Evaporation rate: not determined Boiling point: —100' C Freezing point/melting point: — 0°C pH: 6.5-7.5 Solubility: fully soluble in water Section 10 — Stability and Reactivity Data Stable and non -reactive. Maintain under anaerobic conditions to preserve product integrity. Materials to avoid: none known. Section 11 -Toxicological Information Potential for Pathogenicity: KB-10 Plus has tested negative (i.e., the organisms are not present) for a variety of pathogenic organisms listed in Table 2. While there is no evidence that virulent pathogenic organisms are present in KB-1® Plus, there is potential that certain organisms in KB-10 Plus may have the potential to act as opportunistic (mild) pathogens, particularly in individuals with open wounds and/or compromised immune systems. For this reason standard hygienic procedures such as hand washing after use should be observed. Table 2, Results of Human Pathogen Screening of KB-1® Plus. Organism - Disease(s) Caused Test result Salmonella sp. Typhoid fever, gastroenteritis Not Detected Listeria monocytogenes Listerioses Not Detected Vibrio sp., Cholera, gastroenteritis Not Detected Campylobactersp., Bacterial diarrhea Not Detected Clostridia sp., Food poisoning, Botulism, tetanus, gas gangrene Not Detected Bacillus anthracis Anthrax Not Detected Pseudomonas aeruginosa Wound infection Not Detected Yersinia sp., Bubonic Plague, intestinal infection Not Detected Yeast and Mold Candidiasis, Yeast infection etc. Not Detected Fecal coliforms Indicator organisms for many human pathogens diarrhea, urinary tract infections Not Detected Enterococci Various opportunistic infections Not Detected P.TMISiREMWealth and SafetyWSDS1Bioaugmenlation CuHure MSDSMKB-1 PLUS MSDS.doc SIREM Site Recovery&Management 130 Research Lane, Suite 2 Guelph•Ontario • N1G 5G3 • Canada • Tel: (519) 822-2265 • Fax: (519) 822-3151 Section 12. Disposal Considerations Material must be disinfected or sterilized prior to disposal. Consult local regulations prior to disposal. Section 13 — Transport Information Non -hazardous, non-pathogenic microbial inoculum Chemicals, Not Otherwise Indexed (NOI), Non -hazardous Not subject to TDG or DOT guidelines. Disclaimer: The information provided on this MSDS sheet is based on current data and represents our opinion based on the current standard of practice as to the proper use and handling of this product under normal, reasonably foreseeable conditions. Last revised: 21 May 2010 P:tPRJ\SiREMUiealth and SafetyUSDS0oaugmentation Culture MSDSsXB-1 PLUS MSDS.doe Material Safety Data Sheet 'EHC® +MC MSDS #: EHC-C Revision Date: 2012-04-30 Version 1 This MSDS has been prepared to meet U.S.-.OSHA Hazard Communication Standard 29 CFR 1910.1200 and Canada's Workplace Hazardous Materials Information System (WHMIS) requirements. 1.` ERODUGT AND COMPANV IDENTIFICATION Product name Recommended use Manufacturer FMC CORPORATION ` FMC Peroxygens 1735 Market Street Philadelphia, PA 19103 Phone: +1 215/ 299-6000 (General Information) E-Mail: msdsinfo@fmc.com EHC® Bioremediation product for the remediation of contaminated soil and groundwater only. Not for use in potable drinking water. Emergency telephone number For leak, fire, spill or accident emergencies, call: +1 703-527-3887 (CHEMTREC) +1 303 / 595 9048 (Medical - Call Collect) :'Haa`rds;ident><ficat><ori: " A._, r. s Emergency Overview CONTAINMENT HAZARD: Any vessel that contains wet EHC must be vented due to potential pressure build up from fermentation gases Potential health effects Acute Toxicity No significant health effects anticipated Eyes Product dust may cause mechanical eye irritation. Skin None known Inhalation Inhalation of dust in high concentration may cause irritation of respiratory system. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Chronic Toxicity No known chronic effects of components present at greater than 1%. '6M ositio dinf(if iononingred ents Ingredients Chemical Name CAS -No Weight % Iron 7439-89-6 18-48 Organic Amendment Proprietary 52-82 Page 1/6 EHC® MSDS #: EHC-C Revision Date: 2012-04-30 Version 1 1.Firsta>idmeas1 a =' Eye contact In case of contact, immediately flush skin with plenty of water. Get medical attention if irritation develops and persists. Skin contact Wash off with soap and water. Inhalation Remove person to fresh air. If signs/symptoms continue, get medical attention. Ingestion Rinse mouth with water and afterwards drink plenty of water or milk. Call a poison control center or doctor immediately for treatment advice. �: Fire-fighting'measures Flammable properties Combustible material. Suitable extinguishing media Dry chemical, CO2, sand, earth, water spray or regular foam. Explosion Data Sensitivity to Mechanical Impact not applicable Sensitivity to Static Discharge not applicable Specific hazards arising from the Dry or powdered ingredients are combustible. Dispersal of finely divided dust from products into chemical air may form mixtures that are ignitable and explosive. Minimize airborne dust generation and eliminate sources of ignition. NFPA I Health Hazard 1 I Flammability 1 I Stability 0 1 Special Hazards - NFPA/HMIS Ratings Legend Severe = 4; Serious = 3; Moderate = 2; Slight = 1; Minimal = 0 6. Accidental• release measures = Personal precautions Avoid dust formation. For personal protection see section 8. Methods for containment Cover powder spill with plastic sheet or tarp to minimize spreading and keep powder dry. Methods for cleaning up Sweep or vacuum up spillage and return to container. MHandling•and storage Handling Minimize dust generation and accumulation. Keep away from open flames, hot surfaces and sources of ignition. Refer to Section 8. Storage Keep tightly closed in a dry and cool place. Keep away from open flames, hot surfaces and sources of ignition. Any vessel that contains .? must be vented due to potential pressure build up from fermentation gases. '8. Ex protection Exposure guidelines Occupational exposure controls Local nuisance dust standards apply. Page 2 / 6 EHC® MSDS #: EHC-C Revision Date: 2012-04-30 Version 1 Engineering measures None under normal use conditions. Provide appropriate exhaust ventilation at places where dust is formed. Personal Protective Equipment General Information If the product is used in mixtures, it is recommended that you contact the appropriate protective equipment suppliers, These recommendations apply to the product as supplied Respiratory protection Whenever dust in the worker's breathing zone cannot be controlled with ventilation or other engineering means, workers should wear respirators or dust masks approved by NIOSH/MSHA, EU CEN or comparable organization to protect against airborne dust. Eye/face'protection Safety glasses with side -shields Skin and body protection No special precautions required. Hand protection No special precautions required Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and immediately after handling the product. �9`'Pliyscal and chemical properties. Appearance Light -tan powder Physical state solid Odor, odorless pH 5.6 (as aqueous solution) Melting Point/Range No information available. Freezing point No information available Boiling Point/Range not applicable Flash Point not applicable Evaporation rate not applicable Autoignition Temperature No information available. Flammable properties Combustible material Vapor pressure No information available Vapor density No information available Density 0.80 g/mL Water solubility practically insoluble Percent volatile No information available Partition coefficient: not applicable Viscosity No information available Oxidizing properties not applicable Page 3 / 6 EHC® MSDS #: EHC-C Revision Date: 2012-04-30 _ Version 1 10: Stability -•and reactivity Stability Conditions to avoid Materials to avoid Hazardous decomposition products Hazardous polymerization Stable. Heat, flames and sparks Oxidizing agents Strong acids None known Hazardous polymerization does not occur 11. Toxicological information_ Acute effects Remarks The product has not been tested. Data is based on component. Eye irritation No data available for the formulation. Non -irritating (rabbit) (based on components) Skin irritation No data available for the formulation. Non -irritating (rabbit) (based on components) LD50 Oral Iron: 98.6 g/kg (rat) LD50 Dermal No information available LC50 Inhalation: Iron: > 100 mg/m3.6 hr (rat) Chronic Toxicity Chronic Toxicity No known chronic effects of components present at greater than 1%. Carcinogenicity Contains no ingredient listed as a carcinogen. Ecotoxicity The environmental impact of this product has not been fully investigated Chemical Name Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphnia and other aquatic invertebrates Iron LC50= 13.6 mg/L Morone saxatilis 96 h LC50= 0.56 mg/L Cyprinus carpio 96 h Page 4 / 6 EHC® MSDS M EHC-C Revision Date: 2012-04-30 Version 1 13 Dis osalconside`ratios fi' ,x..t „ Waste disposal methods This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements Contaminated packaging Dispose of in accordance with local regulations 14 Transportinformation . .. DOT not regulated TDG not regulated ICAO/IATA not regulated IMDG/IMO not regulated International Inventories TSCA Inventory (United States of America) DSL (Canada) Complies NDSL (Canada) Complies EINECS/ELINCS (Europe) Complies ENCS (Japan) - IECSC (China) Complies KECL (Korea) - PICCS (Philippines) Complies AICS (Australia) Complies NZIoC (New Zealand) Complies U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard no Chronic Health Hazard no Fire Hazard no Sudden Release of Pressure Hazard no Reactive Hazard no CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. Page 5 / 6 EHC® International Regulations Mexico - Grade No information available MSDS #: EHC-C Revision Date: 2012-04-36 Version 1 Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class not determined 6: Other information HMIS Health Hazard 1 I Flammability 1 I Stability 0 1 Special precautions - NFPA/HMIS Ratings Legend Severe = 4; Serious = 3; Moderate = 2; Slight = 1; Minimal = 0 Revision Date: 2012-04-30 Reason for revision: No information available. Disclaimer FMC Corporation believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specified product designated and may not be applicable where such product is used in combination with any other materials or in any process. , Further, since the conditions and methods of use are beyond the control of FMC Corporation, FMC corporation expressly disclaims any and all liability as to any results obtained or arising from any use of the products or reliance on such information. Prepared By FMC Corporation FMC Logo and EHC - Trademarks of FMC Corporation © 2012 FMC Corporation. All Rights Reserved End of Material Safety Data Sheet Page 6 / 6 ASTRO PRODUCT CODE # 15046 J This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication Standard, 29 CPR 1910.1200; the Canada's Workplace Hazardous Materials Information System (WHMIS) and, the EC Directive, 2001/58/EC. 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Sodium Bicarbonate SYNONYMS: Baking Soda, Bicarbonate of Soda GENERAL USE: Leavening agent, cleaner ingredient, bath salt ingredient, water softener, diaper rinse ingredient, feed additive. This chemical is certified to ANSI/NSF Standard 60, Drinking Water Chemicals -Health Effects (as packaged in the original, unopened container). The maximum dosage level for this chemical is 100 mg/L MANUFACTURER EMERGENCY TELEPHONE NUMBERS FMC Wyoming Corporation (800) 424-9300 (CHEMTREC - U.S.) Alkali Chemicals Division (303) 595-9048 (Medical - Call Collect) 1735 Market Street Philadelphia, PA 19103 (307) 872-2452 (Plant - Green River, WY) (215) 299-6000 (General Information) 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: • White, odorless, granular solid. • Product is non-combustible. • Reacts with acids to release carbon dioxide gas and beat. POTENTIAL HEALTH EFFECTS: No significant health effects anticipated. Pagel of 9 ASTRO PRODUCT CODE # 15046 Sodium Bicarbonate (144-55-8) Date: 01/26/2004 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS# WL% EC No. EC Class Sodium Bicarbonate 144-55-8 1C0 205-633-8 Not classified as hazardous 4. FIRST AID MEASURES +'YES: Flush with plenty of water. Get medical attention if irritation occurs and persists. SKIN: Wash with plenty of soap and water. Get medical attention if irritation occurs and persists. INGESTION: Drink plenty of water. Never give anything by mouth to an unconscious person. If any discomfort persists, obtain medical attention. INHALATION: Remove to fresh air. If breathing difficulty or. discomfort occurs and persists, obtain medical attention. NOTES TO MEDICAL DOCTOR: Internal toxicity is low. Treatment is symptomatic and supportive. 5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Water, water fog, carbon dioxide (CO2), dry chemical FIRE / EXPLOSION HAZARDS: None FIRE FIGHTING PROC +'DUPES: None FLAMMABLE LIMITS: Not applicable HAZARDOUS COMBUSTION PRODUCTS: None SENSITIVITY TO IMPACT: None SENSITIVITY TO STATIC DISCHARGE: None Page 2 of 9 ASTRO PRODUCT CODE # 15046 Sodium Bicarbonate (144-55-8) Date: 01/26/2004 6. ACCIDENTAL RELEASE MEASURES COMMENTS: PERSONAL PRECAUTIONS: Refer to Section 8 "Exposure Controls / Personal Protection". CLEAN-UP: This product, if spilled, can be recovered and re -used if contamination does not present a problem. Vacuum or sweep up the material. If the spilled product is unusable due to contamination, consult state or federal environmental agencies for acceptable disposal procedures and locations. See Section 13 "Disposal Considerations". NOTIFICATION REQUIREMENTS: Federal_ regulations do not require notification for spills of this product. State and local regulations may contain different requirements; consult local authorities. 7. HANDLING AND STORAGE HANDLING: Use air conveying/mechanical systems for bulk transfer to storage. For manual handling of bulk transfer use mechanical ventilation to remove airborne dust from railcar, ship or truck. Use approved respiratory protection when ventilation systems are not available. Selection of respirators is based on the dust cloud generated. STORAGE: Store in a cool dry area, away from acids. COMMENTS.: Use general room dilution or local exhaust ventilation when excessive dust is expected in the work environment. S. EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS: Where possible, provide general mechanical and/or local exhaust ventilation to prevent release of airborne dust into the work environment. PERSONAL PROTECTIVE EQUIPMENT EYES Alai .FACE: Appropriate eye and face protection equipment (ANSI Z87 approved) should be selected for the particular use intended for this material. Safety glasses with side shields are recommended. RESPIRATORY: Whenever dust in the worker's breathing zone cannot be controlled with ventilation or other engineering means, workers should wear respirators or dust masks approved by NIOSH/MSHA, EU CEN or comparable certification organization to protect them against airborne dust. PROTECTIVE CLOTHING: Dry product is generally non -irritating to intact skin. However, this product can be irritating where skin has been damaged and can create skin irritation Page 3 of 9 ASTRO PRODUCT CODE # 15046 Sodium Bicarbonate (144-55-8) Date: 01/26/2004 after long exposures when moisture is present. Under such conditions, gloves and long-sleeved clothing are recommended to minimize skin contact. COMMENTS: ADDITIONAL EXPOSURE GUIDELINES: Federal guidelines treat the ingredient(s) in this product as a nuisance dust, as no product -specific guidelines have been issued for exposure. As with all nuisance dusts, worker breating zone concentrations should be measured by validated sampling and analytical methods. The following limits (OSHA and MSHA) apply to this material: Particulates Not Otherwise Regulated: OSHA (PEL / TWA):15 mg/m3 (total dust); 5 mg/m3 (resp fraction) MSHA (PEL / TWA): 10 mg/m3 (total dust) The information noted above provides general guidance for handling this product. Specific work environments and material handling practices will dictate the selection and use of personal protection equipment (PPE). 9. PHYSICAL AND CHEMICAL PROPERTIES ODOR: Odorless APPEARANCE: White, granular solid, AUTOIGNITION TEMPERATURE: Not applicable BOILING POINT: Not applicable COEFFICIENT OF OIL/ WATER: Not available DENSITY / WEIGHT PER VOLUME: 0.88 g/mL EVAPORATION RATE: Not applicable (Butyl Acetate = 1) FLASH POINT: Non-combustible MELTING POINT: Decomposes ODOR THRESHOLD: Not applicable OXIDIZING PROPERTIES: Not applicable . PERCENT VOLATILE: Not available PH: 8.3 (1 % solution) SOLUBILITY IN WATER: % by wt. @ 20°C (68°I): 9.0 SPECIFIC GRAVITY: (H2O =1) 2.20 VAPOR DENSITY: Not applicable (Air =1) Page 4 of 9 ASTRO PRODUCT CODE # 15046 Sodium Bicarbonate (144-55-8) Date: 01/26/2004 VAPOR PRESSURE: Not available 10. STABILITY AND REACTIVITY CONDITIONS TO AVOID: Contact with acids except under controlled conditions. STABILITY: Stable POLYMERIZATION: Will not occur INCOMPATIBLE MATERIUS: Reacts with acids to release carbon dioxide gas and heat. HAZARDOUS DECOMPOSITION PRODUCTS: None 11. TOXICOLOGICAL INFORMATION EYE EFFECTS: Non -irritating (rabbit) J. Amer. Coll. Toxicol. 1987 SKIN EFFECTS: Non -irritating (rabbit) J..Amer. Coll. Toxicol. 1987 DERMAL LDso: No data available for the product. ORAL LDS0: 20% slurry: 4,300 mg/kg (rat) 50 %n slurry. 6,000 mg/kg (rat) Gosselin, Smith & Hodge, Clinical Tox. of Comm. Products,1994 INHALATION LC50: No data available for the product. TARGET ORGANS: None ACUTE EFFECTS FROM OVEREXPOSURE: This product, when dry, is generally non -irritating to intact skin. However, when moisture is present, -it can be irritating to damaged skin and can create irritation after long exposures. This product is approved for use as a food ingredient and is Generally Recognized As Safe (GRAS). No significant acute toxicological effects expected. CHRONIC EFFECTS FROM OVEREXPOSURE: Administration of large doses of sodium bicarbonate to patients with renal insufficiency can produce systemic alkalosis.. Page 5 of 9 ASTRO PRODUCT CODE # 15046 Sodium Bicarbonate (144-55-8) CARCINOGENICITY: NTP: Not listed IARC: Not listed OSHA: Not listed OTHER: (ACGIH) Not listed 12. ECOLOGICAL INFORMATION Date: 01/26/2004 ECOTOXICOLOGICAL INFORMATION: 48 hr LC50 = 2000 mg/L (Culex sp. larvae or mosquito) CHEMICAL FATE INFORMATION: No data available for the product. 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: When this product is discarded or disposed of, as purchased, is is neither a characteristic nor a listed hazardous waste according to US Federal RCRA regulations (40 CFR 261). As a non -hazardous waste the material may be disposed of in a landfill in accordance with government regulations; check local or state regulations for applicable requirements prior to disposal. Any processing, usage, alteration, chemical additions to, or contamination of, the product may alter the disposal requirements. Under Federal regulations, it is the generator's responsibility to determine if a waste is a hazardous waste. 14. TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION (DOT) PROPER SHIPPIAN r NAME: PRIMARY HAZARD CLASS / DIVISION: UNINA NUMBER: LABEL(S): PLACARD(S): MARKINGS): ADDITIONAL INFORMATION: Not regulated Not applicable None Not applicable Not applicable Not applicable Hazardous Substance/RQ: Not applicable 49 STCC Number: Not applicable Page 6 of 9 ASTRO PRODUCT CODE # 15046 Sodium Bicarbonate (144-55-8) Date: 01/2512004 INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG) ADDITIONAL INFORMATION: Not regulated ADR - EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD ADDITIONAL INFORMATION: . Not regulated 15. REGULATORY INFORMATION UNITED STATES SARA TITLE IH (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 11 SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355, APPENDIX A): Not listed SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370): The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,0001bs; however, this product contains the following ingredients with a TPQ of less than 10,000 lbs.: No TPQ for this product SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372): Not listed CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND LIABILITY ACT) CERCLA DESIGNATION & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4). Not applicable TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA INVENTORY STATUS (40 CFR 710): Listed ; RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) RCRA IDENTIFICATION OF HAZARDOUS WASTE (40 CFR 261): Waste Number: Refer to Section 13 "Disposal Considerations" for RCRA status. Page 7 of 9 ASTRO PRODUCT CODE # 15046 Sodium Bicarbonate (144-55-9) Date: 01/26/2004 CANADA WHMIS (WORKPLACE HAZARnOUS MATERIALS INFORMATION SYSTEM): Product Identification Number: None Hazard Classification / Division: None Ingredient Disclosure List: Not listed COMMENTS: CLEAN WATER ACT (CWA) - SECTION 307 / 311 Not listed as a hazardous pollutant (40 CFR 116), nor as a toxic pollutant (40 CFR 401.15) CLEAN AIR ACT (CAA) - SECTION 112 Not regulated under the chemical accident prevention provisoins (40 CFR 68) 16.OTHER INFORMATION 11MIS Health 0 Flammability 0 Physical Hazard 0 Personal Protection PPE B Protection = B (Safety glasses and gloves) HMIS = Hazardous Materials Identification System Degree of Hazard Code: 4 = Severe 3 = Serious 2 =?Moderate 1 = Slight 0 = Minimal NFPA Health 0 Flammability 0 Reactivity 0 Special' None No special requirements NFPA = National Fire Protection Association Degree of Hazard Code: 4 = Extreme 3 = High 2 = Moderate 1= Slight 0 = Insignificant Page 9 of 9 ASTRO PRODUCT CODE # 15046 REVISION SUMMARY: Changes in information are as follows: New Format, as well as text changes and/or updates to one or more Sections of this MSDS. FMC Logo - FMC Corporation Trademark © 2004 FMC Corporation. All Rights Reserved. FMC Corporation believes that the information and recommendations contained herein (including data and statements) are accurate ss of the date hereof. NO WARRANTY OF FTINESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED IiEREIN. The information provided herein relates only to the specific product designated and may not be applicable where such product is used in combination with any other materials or :n any process. It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of FMC Corporation, FMC Corporation expressly disclaims any and all liability as. to any results obtained or arising from any use of the product or reliance on such information. Page 9 of 9 Material Safety Data Sheet Calcium carbonate MSDS Section 1.: Chemical Product and Company Identification Product Name: Calcium carbonate Catalog Codes: SLC1141, SLC4720, SLC4438, SLC1645 CAS#: 471-34-1 RTECS: FF9335000 TSCA: TSCA 8(b) inventory: Calcium carbonate CI#: Not available. Synonym: Chemical Name: Calcium Carbonate Chemical Formula: CaCO3 Composition: Name Calcium carbonate Contact Information: Sciencelab.com, Inc. 14025 Smith Rd. Houston, Texas 77396 US Sales: 1-800-901-7247 International Sales: 1-281-441-4400 Order Online: ScienceLab.com CHEMTREC (24HR Emergency Telephone), call: 1-800-424-9300 International CHEMTREC, call: 1-703-527-3887 For non -emergency assistance, call: 1-281-441-4400 Section 2`, C.ompositio.n; and Information on Ingredients. CAS # % by Weight 471-34-1 100 Toxicological Data on Ingredients: Calcium carbonate: ORAL (LD50): Acute: 6450 mg/kg [Rat]. Section 3: Hazards Identification Potential Acute Health Effects: Hazardous in case of eye contact (irritant). Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation: Potential Chronic Health Effects: CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys. Repeated or prolonged exposure to the substance can produce target organs damage. Section 4: First Aid Measures Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush -eyes with plenty of water for at least 15 minutes. Cold water may be used. WARM water MUST be used. Get medical attention. Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Serious Skin Contact: Not available. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Serious Inhalation: Not available. Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie„ belt or waistband. Get medical attention if symptoms appear. Serious Ingestion: Not available. Section 5 Fire an d Explosion'Data; Flammability of the Product: Non-flammable. Auto -Ignition Temperature: Not applicable. Flash Points: Not applicable. Flammable Limits: Not applicable. Products of Combustion: Not available. Fire Hazards in Presence of Various Substances: Not applicable. Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Fire Fighting Media and Instructions: Not applicable. Special Remarks on Fire Hazards: Will ignite and burn fiercely in contact with fluorine Special Remarks on Explosion Hazards: When a mixture of calcium carbonate and magnesium is heated in a current of hydrogen, a violent explosion occurs. Section 6: Accidental, Releaser Measures ` Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and -dispose of according to local and regional authority requirements. Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. Section 7:, Handling and Storage Precautions: Do not ingest. Do not breathe dust. Avoid contact with eyes. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing agents, acids. Storage: Keep container tightly closed. Keep container in a cool, well -ventilated area. Hygroscopic Section 8: Exposure-Controls/Personal- Protection p. 2 Engineering Controls: . Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne. contaminants below the exposure limit. Personal Protection: Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure .Limits: TWA: 10 (mg/m3) from ACGIH (TLV) [United States] Inhalation Total. TWA: 10 STEL: 20 (mg/m3) [Canada] Inhalation Total. TWA: 5_ (mg/m3) from OSHA (PEL) [United States] Inhalation Respirable. TWA: 15 from OSHA (PEL) [United States] Inhalation Total.Consult local authorities for acceptable exposure limits. Section 9:. Physical , and Chemical. Properties. Physical state and appearance: Solid. (Powdered solid.) Odor: Odorless. Taste: Chalky Molecular Weight: 100.09 g/mole Color: White. pH (1% soln/water): Not available. Boiling Point: Not available. Melting Point: 8250C (1517°F) Critical Temperature: Not available. Specific Gravity: 2.8 (Water= 1) r' Vapor Pressure: Not applicable. Vapor Density: Not available. Volatility: Not available. Odor Threshold: Not available. Water/Oil Dist. Coeff.: Not available. lonicity (in Water): Not available. Dispersion Properties: Not available. Solubility: Very slightly soluble in cold water. Soluble in dilute acid. Insoluble in alcohol. . i Section 1:0: Stability and Reactivity Data Stability: The product is stable. Instability Temperature: Not available. Conditions of Instability: Incompatible Materials p. 3 Incompatibility.with various substances: Reactive with oxidizing agents, acids. Corrosivity: Non -corrosive in presence of glass. Special Remarks on Reactivity: Hygroscopic. Will ignite and burn fiercely in contact with fluorine. Incompatible with acids, alum, ammonium salts, mercury + hydrogen, aluminum and magnesium Special Remarks on Corrosivity: Not available. Polymerization: Will not occur. Section 1.1: Toxicological Information Routes of Entry: Inhalation. Ingestion. Toxicity to Animals: Acute oral toxicity (LD50): 6450 mg/kg [Rat]. Chronic Effects on Humans: May cause damage to the following organs: kidneys. Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation. Special Remarks on Toxicity to Animals: Not available. Special Remarks on Chronic Effects on Humans: Not available. Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects: Skin: Causes skin irritation. Eyes: Dust causes eye irritation. Inhalation: Excessive inhalation causes respiratory tract and mucous membrane irritation. Low hazard for usual industrial handling. Ingestion: Ingestion of large amounts may cause gastrointestional tract disturbances with nausea and possibly constipation. Expected to be a low hazard for usual industrial handling. Chronic Potential Health Effects: Chronic ingestion may affect kidneys, and may cause hypercalcemia with alkalosis. Section 12:. Eco.lo°gical Information Ecotoxicity: Not available. BOD5 and COD: Not available. Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However,.long term degradation products may arise. Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic. Special Remarks on the Products of Biodegradation: Not available. Section 13: Disposal Considerations E Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 14: Trans or# Information P DOT Classification: Not a DOT controlled material (United States). Identification: Not applicable. Special Provisions for Transport: Not applicable. p. 4 Section 15:'OtherRegulatory Information Federal and State Regulations: TSCA 8(b) inventory: Calcium carbonate Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances. Other Classifications: .WHMIS (Canada): Not controlled under WHMIS (Canada). DSCL (EEC): R36- Irritating to eyes. S2- Keep out of the reach of children. S46- If swallowed, seek medical advice immediately and show this container or label. HMIS (U.S.A.): Health Hazard: 2 Fire Hazard: 0 Reactivity: 0 Personal Protection: E National fire Protection Association (U.S.A.): Health: 1 Flammability: 0 Reactivity: 0 Specific hazard: Protective Equipment: Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles. Section 16: Other Information i References: Not available. Other Special Considerations: Not available. Created: 10/10/2005.08:15 PM Last Updated: 06/09/2012 12:00 PM The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations ,to determine the suitability of the information for their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab. com has.been advised of the possibility of such damages. p. 5 Material Safety Data Sheet Magnesium hydroxide MSDS Section 1: Chemical Product'and Company Identification Product Name: Magnesium hydroxide Catalog Codes: SLM2437, SLM3811, SLM1663 CAS#: 1309-42-8 RTECS: OM3570000 TSCA: TSCA 8(b) inventory: Magnesium hydroxide CI#: Not available. Synonym: Chemical Name: Not available. Chemical Formula: Mg(OH)2 Composition: Contact Information: Sciencelab.com, Inc. 14025 Smith Rd. Houston, Texas 77396 US Sales: 1-800-901-7247 International Sales: 1-281-441-4400 Order Online: ScienceLab.com CHEMTREC (24HR Emergency Telephone), call: 1-800-424-9300 International CHEMTREC, call: 1-703-527-3887 For non -emergency assistance, call: 1-281-441-4400 Section 2: Composition., and .Information on Ingredients j Name CAS # Magnesium hydroxide 1309-42-8 Toxicological Data on Ingredients: Not applicable. Section 3: Hazards Identification % by Weight 100 Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Potential Chronic Health Effects: CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition. Section 4: First Aid Measures Eye Contact: Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Skin Contact: After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover the irritated skin with an emollient. If irritation persists, seek medical attention. P. 1 Serious Skin Contact: Not available. Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention. Serious Inhalation: Not available. Ingestion: Do not induce vomiting. Loosen tight clothing such as a collar, fie, belt or waistband. If the victim is not.breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention. Serious Ingestion: Not available. Section 5: Fire and 'Explosion Data Flammability of the Product: Non-flammable. Auto -Ignition Temperature: Not applicable. Flash Points: Not applicable. Flammable Limits: Not applicable. Products of. Combustion: Not available. Fire Hazards in Presence of Various Substances: Not applicable. Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Fire Fighting Media and Instructions: Not applicable. - Special Remarks on Fire Hazards: Not available. Special Remarks on Explosion Hazards: Not available. Section 6 Accidental. Release Measures Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Section 7: Handling and Storage -Precautions: Nonspecific safety phrase has been found applicable for this product. Storage: No specific storage is required. Use shelves or cabinets sturdy enough to bear the weight of the chemicals. Be sure that it is not necessary to strain to reach materials, and that shelves are not overloaded. I Section 8: Exposure Controls/Personal Protection Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. p. 2 Personal Protection: Safety glasses. Lab coat.. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure Limits: Not available. Spec#ion 9: Physici l and Chemicals Properties, ' Physical state and appearance: Solid. Odor: Not available. Taste: Not available. Molecular Weight: 58.32 g/mole Color: Not available. pH (1% soln/water): Not available. Boiling Point: Not available. Melting Point: Decomposes. Critical Temperature: Not available. Specific Gravity: 2.36 (Water = 1) Vapor Pressure: Not applicable. Vapor Density: Not available. Volatility: Not available. Odor Threshold: Not available. Water/Oil Dist. Coeff.: Not available. lonicity.-(in Water): Not available. Dispersion Properties: Not available. Solubility: Very slightly soluble in cold water. Section .10: Stability a'nd Reactivity Data Stability: The product is stable. Instability Temperature: Not available. Conditions of Instability: Not available. Incompatibility with various substances: Not available. Corrosivity: Non -corrosive in presence of glass. Special Remarks on Reactivity: Not available. Special Remarks on Corrosivity: Not available. Polymerization: No. ' `S.ectioftll Toxicol0gica1Information p. 3 Routes of Entry: Not available. Toxicity to Animals: LD50: Not available. LC50: Not available. Chronic Effects on Humans: Not available. Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation. Special Remarks on Toxicity to Animals: Not available. Special Remarks on Chronic Effects on Humans: Not available. Special Remarks on other Toxic Effects on Humans: Not available. Section 12 Ecological Information Ecotoxicity: Not available. BOD5 and COD: Not available. Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation: The products of degradation are as toxic as the original product. Special Remarks on the Products of Biodegradation: Not available. Section 13: Disposal Considerations. Waste Disposal: Section 14: Transport Information DOT Classification: Not a DOT controlled material (United States). Identification: Not applicable. Special Provisions for Transport: Not applicable. a _ Section 15: Other Reg ulatory Information: i Federal and State Regulations: TSCA 8(b) inventory: Magnesium hydroxide Other Regulations: Not available.. Other Classifications: WHMIS (Canada): Not controlled under WHMIS (Canada). DSCL (EEC): This product is not classified according to the EU regulations. HMIS (U.S.A.): Health Hazard: 1 Fire Hazard: 0 Reactivity: 0 p. 4 Personal Protection: E National Fire Protection Association (U.S.A.): Health: 1 Flammability: 0 Reactivity: 0 Specific hazard: Protective Equipment: Gloves. Lab coat. Dust respirator. Be.sure to use an approved/certified respirator or equivalent. Safety glasses. Sectib".16:;Other Information'; References: Not available. Other Special Considerations: Not'available. Created: 10/10/2005 08:22 PM Last Updated: 06/09/2012 12:00 PM The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its.use. Users should make their own investigations to determine -the suitability of the information for their particular purposes. In no event shall ScienceLab. com be. liable- for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab: com has been advised of the possibility of such damages. . p. 5 ATTACHMENT 4 INJECTION PROCEDURE 4. INJECTION PROCEDURE 4.1 Injection Approach For the B105-139 and B147 pilot test areas (PTAs), the injection approach will consist of a two - stage process, whereby one set of injection wells will be injected with amendments, while the remaining set of injection wells (IWs) will be used to monitor the radius of influence (ROI) of the injections within the PTA.. As target injection volumes are met at the first set of IWs, injection will transition to the remaining IWs. The' number of IWs simultaneously receiving amendments will be adjusted to accommodate field -conditions and will balance data needs (i.e., assessment of ROI) with observed field conditions (e.g., injection rates and pressures) and equipment (e.g., number of channels on the injection manifold). For the B149 PTA, where there are fewer IWs, the proposed injection strategy is to simultaneously inject into all 4 IWs. The injection quantities into individual IWs in each PTA may be adjusted based on the results from additional data collection activities during and subsequent to well installation., 4.2 Injection Procedure and Equipment During injections, one set of injection equipment (storage tanks, transfer pumps, manifold and hosing) will be used in each PTA to allow simultaneous injection into multiple IWs. A typical schematic of the injection equipment to be used is presented in Figure 4-1. At each IW the order of injection will be: 1) several hundred. gallons (gal) of emulsified vegetable oil (EVO) solution, 2) a small volume of anaerobic water, 3) the bioaugmentation culture KB-10 Plus, 4) a second volume of anaerobic water, and 5) the remainder of the EVO volume for the injection well. The anaerobic water is used to protect the KB-10 Plus from oxygen exposure. Anticipated injectant volumes and concentrations, as detailed in Attachment 3, include approximately 3,450 gal, 4,600 gal, and 10,600 gal of a 1-2% (volume/volume [v/v]) EVO solution (0.5 to 1%v/v as oil) per injection well for the B105-139, B147, and B149 PTAs, respectively. The total injection volume for all three PTAs is approximately 171,000 gal. The total volume of KB-10 Plus proposed is.32 liters (L) each for the B105-139 and B149 PTAs distributed equally between the IWs in each PTA. Further details regarding the bioaugmentation 'procedures are provided in Attachment 4-A. An anticipated average injection rate of 1.5, 1.0 and 1.5 gallons per minute (gpm) per injection well has been assumed for the EVO injections at the B105-139, B147 and B149.PTAs, respectively, based on the anticipated geology and target thickness of the treatment zones. At these injection rates and assuming injection for 6 hours per day to account for daily setup/takedown of equipment and to switch between injection fluids (EVO solution, KB-10 Plus, 3 Proposed injectant volumes, which were detailed in Attachment 3, are based on the proposed pilot test layouts, which may be adjusted in the field based on site conditions and/or additional data collection (see Attachment 1). Therefore, the injectant volumes may be less than outlined in the attachment or, if greater, will not exceed the outlined quantities by more than 50%. anaerobic -water), the anticipated average daily injection rate per IW is anticipated to be approximately 540 gal, 360 gal, and 540 gal for the B 105-139, B147, and B149 PTAs, respectively. At this average daily injection rate and assuming that injection occurs in approximately 50%, 50%, and 100% of the 16, 16, and 4_ IWs in B105-139, B147, and B149 PTAs; respectively, the average daily injectant rate per PTA is anticipated to be approximately 4,300, 2,900, and 2,200 gallons per day. At the average daily injection rate for the EVO solution volumes listed above, it is anticipated that injection event will be approximately 6, 13, and 20 days for the B105-139, B147 and B149 PTAs, respectively. Delays due to weather and limitations in injection rates are possible. It is expected that at least 4-6 weeks of field work will be required to inject the full volume for the PTAs at these rates. The average maximum injection pressure is anticipated to be maintained at or below 20 pounds per square inch (psi). Higher injection rates, and correspondingly higher daily injection rates and lower injection durations, may be used if it is found to be practical at this average maximum pressure. 4.3 Injection Monitoring One of the objectives of the pilot testing is to evaluate ROI. An estimate of ROI and the variability of ROI between IWs may be used to refine well spacing for potential technology scale -up. During EVO injection, ROI monitoring will consist of collecting grab samples from surrounding locations not receiving injections. These grab samples will be visually inspected for EVO, which has a milky white color, and field tested for conductivity. and turbidity, which increase when EVO is present. During injection, the. injection rate, cumulative volume and injection pressure will be monitored for each IW. Monitoring will also include measurement of water levels in and around the IWs and visual observation for short-circuiting/daylighting to ground surface. The operational data Will be used to support any adjustments in injection rates or pressures, and to confirm that overall injection targets are met. Should the monitoring data indicate that short-circuiting and/or daylighting at the ground surface is occurring, the injections will be temporarily stopped and injection rates/pressures will be decreased and/or injection re -configured. ATTACHMENT 4 FIGURE FROM PUMP/ POTABLE y WATER. 12" MANWAY STORAGE TANK TRANSFER PUMP CONVEYANCE SYSTEM LEGEND FLEXIBLE HOSE ,FLOW METER WITH TOTALIZER DDI VALVE l ') PRESSURE GAUGE FILTRATION SYSTEM (10 mm) (AS NEEDED) PROPORTIONAL FEED PUMP TYPICAL INJECTIONWELLHEAD FITTING VENT VALVE MULTI -CHANNEL INJECTION MANIFOLD -- - - - - -.- - - - - I F© I I FM f COMPRESSION FITTING I FM PVC CASING t SLOTTED PVC DISPOSABLE TOTE SCREEN EMULSIFIED VEGETABLE OIL INJECTION WELL ATTACHMENT 4-A KB-l.° PLUS INJECTION PROCEDURE ;Sfte 8emvery &Management TO: FROM: DATE: SUBJECT: Ben Amos, 'Geosyntec Consultants Sandra Dworatzek, SiREM (sdwoaatzek@siremlab.com) 17 February 2011 Injection Procedure for KB-1®/ KBA Plus List of Equipment Pressurized cylinder of compressed gas (argon or nitrogen) — locally sourced I kResek6 Lane; Suite 2 Guelph Ontario N1GSO: Phone (519) 822=2265 fax: (519) 822-3151. The injection field kit provided by SiREM containing equipment and materials required for injection: • Stainless steel vessel containing KB-1® or KBA Plus • Appropriate regulator for compressed inert gas • Tubing with appropriate fittings for transfer of gas to vessel and inoculum from vessel to well. •. Tubing to inject culture into subsurface. • Digital scale (to measure injection volumes ) Summary of Method SiREM ships all required equipment and materials to the site prior to the scheduled injection date. The bioaugmentation technician inspects the vessel integrity upon arrival at the field site and confirms that all valves are closed and all connections are secure. The pressure in the vessel and vessel weight are checked to ensure that they have not changed since leaving the laboratory. The vessel is shipped under slight positive pressure (1 pound per square'inch [psi]). The injection technician proceeds with the injection by placing the injection tubing in the well/drive point to the desired injection depth and purges the well/drive point with argon or nitrogen gas to displace oxygen from the well column and maintain an inert gas blanket in the well above the water table. A 5 minute purge is recommended. The culture is then injected into well/drive point using compressed gas. There are four stainless steel stems on SiREM vessels: the pressure relief and pressure gauge 'port (to monitor pressure and pressure relief for safety); the purge port (for purging or venting the vessel); the inoculation port (culture line into subsurface); and the pressurization port (connected to compressed gas to pressurize vessel and push culture into the ground) shown in Figure 1. The bioaugmentation technician connects the tubing so that the compressed gas is used to pressurize the vessel (typical maximum pressure required is up to 30 psi for injection depths up to 30 feet below ground surface) and push the culture into the injection tubing and into the well/drive point at the desired wwwsiremlati.com SiteRemvery&Management _ 130 Research Lane, Suite 2 Guelph;Ontario N1G50 Phone: (519) 822-2265 Fax. (519) 822-3151 www.siremlab.com depth interval. The required volume is metered into the ground and the injection equipment moved to the next injection as required until all locations are completed. The bioaugmentation technician facilitates the return of all materials and equipment to SiREM following completion of the bioaugmentation. Health and Safety Considerations: Appropriate protective eyeglasses or goggles are to be worn when opening vessels valves or pressurizing vessels when injecting contents in to groundwater. Disposable latex or nitrile gloves should be worn when handling and disposed of after use. Spilled liquid should be soaked up with a sorbant and saturated with a 10% bleach solution (1/10 diluted standard bleach). Sorbant should be double bagged and disposed of in garbage. After removal of sorbant, area should be washed with 10% bleach solution to disinfect. If liquid from the culture vessel is present on the fittings, non- designated.tubing or exterior of the culture vessel liquid should be wiped off and the area washed with 10% bleach solution. KB-1® Vessel KB-1® Vessel. Shipping Case Empty Weight = 27 Ibs . Empty Weight = 28 Ibs Full Weight = 77 lbs. Full Weight with KB-1 Vessel = 105 Ibs MM 24 �i-3tf'' -�dl � Y 9� `any 6 j a ,�� � l,t�t I +""•,� � � _` ¢� ' ItB�128., 44,. j CJK� ' ,:A L.• u . i - 9.3" 16" Fr #' fit c4 r 4t. y'p. ? Yp 5t it P FB ro f-J �,p t Ste) xf 't 4 A Inoculation Pressurization Port (Red) 1`r= Port (yellow) Purge Port (Green) Pressure Relief and Pressure Gauge Port KB-:1® Vessel and Shipping Case Feb.2009 Figum:I - �S ryEM Y Site Ra ATTACHMENT 5 FRACTURING PLAN 5. FRACTURING PLAN Fracturing is not planned for the Enhanced In Situ Bioremediation (EISB) pilot tests. ATTACHMENT 6 INJECTION WELL CONSTRUCTION DETAILS ATTACHMENT 6 TABLE TABL] INJECTION WELL CON Chemtronics Site, Number of Total Depth Total Depth of Total Depth of Permanent/ Well Pilot Test Injection Injection "Injection Injection Well Borings for multi- Status Temporary Diameter Type of Area Well ID Wells Wells Borings „ level or nested„ Direct Push (inches) Casing (ft BLS) (ft BLS) well systems Points B105-139 IP105-1 Schedule to 16 28 29 NA Proposed Permanent 2 40 PVC IP105-16 B147 IP147-1 Schedule to 16 35 36 NA Proposed Permanent 2 40 PVC IP147-16 B149 IP149-1 Schedule to 4 TBD1 TBD1 NA Proposed Permanent 2 40 PVC IP 149-4 Notes: Refer to Figure 6-1 (B 105-139 and B 147 Pilot Test Areas) and Figure 6-2 (B 149 Pilot Test Area) for typical subsurface injection well construction de BLS = below land surface. PVC = Polyvinyl chloride. NA = Not applicable. TBD = To be determined. ft = feet. 1= Surface of bedrock is variable and is estimated to be between 20 and 50 ft BLS. Wells will be installed so that the total depth is coincident with th 2 = Neat cement grout to contain up to 5 percent (%) bentonite. 2012 0928 Chemtronics 9 Attachment 6 Well Construction Details Table 6-1.xlsx Geosyntec Consultants UCTION DETAILS ananoa, NC -pth of Casing Type of Screen Screen Interval Type of Depth of Depth of Depth of Sand- Surface (ft BLS) Screen Length (ft BLS) Grout z Grout Bentonite Seal Above Screen Completion P (ft) (ft BLS) (ft BLS) (ft BLS) Locking steel 0 - 13 0.010 inch 15 13 - 28 Neat cement 0-9 9 - 11 11- 13 protective slot PVC grout casing Locking steel 0 - 15 0.010 inch 20 15 - 35 Neat cement 0 - 11 11 - 13 13 - 15 protective slot PVC grout casing Locking steel I TBD 0.010 inch 10 1 TBD Neat cement 1 TBD 1 TBD TBD protective slot PVC grout casing ipetent bedrock surface 09.28.2012 ATTACHMENT 6 FIGURES 6-inch boring �i' ' "''i a 2-inch PVC riser Thickness A rN 2- inch PVC riser Neat Cement Grout __lt , between Riser and ;• Boring 6-inch boring —►�` 2-foot minimum (bentonite seal) 2-3 foot maximum riffs .i (sand above screen) 5:1 FSr+ t:t +:1a 25-foot maximum C•:t f}151 ;:iJ LSl+J I+t� i Ftt�t it tt� 1� \! Thickness B +' r+p+ I% r t, 2- inch PVC screen o-`•:i t:t '.riff t;t [1:-t• hi.� i t: t J t� tiJ AN, 1-foot minimum (sand below screen) Legend. Neat Cement Grout Bentonite Chips t; it fit+ �'•�_+' Sand Pack Typical Well Construction Details Zone AB Wells NOT TO SCALE Chemtronics Site Swannanoa North Carolina Geosynte& Figure consultants 6 Kennesaw September-2012-1 PTA# 1 B 105-139 PTA#2 8-inch boring ;, ,' , i'j'•��``� .• 24nch PVC riser j.: • j Thickness A 2- inch PVC riser 8-inch boring -0.1-. 2-foot minimum (bentonite seal) T2-3 foot maximum �L;:; i1;1 :',•i (sand above screen) S�t� 25-foot N` t•L k{: `dry maximum t:t Thickness B •1�-5 Lt�t� 2- inch PVC nt:: screen .y C • Competent bedrock surface Neat Cement Grout in overdril led borehole - - - = "-! Legend Neat Cement Grout LLLJ Bentonite Chips t- �:L' LL Sand Pack Typical Well Construction Details Zone C Wells NOT TO SCALE Chemtronics Site Swannanoa North Carolina Geosynrec Figure consultants 6-2 Kennesaw September-2012 PTA# 1 B105-139 PTA#3 B149. Thickness A (feet) 53 6 to 36 Thickness B (feet) 15 10 ATTACHMENT 7 MONITORING PLAN 7. MONITORING PLAN This attachment provides information on the proposed monitoring plan. Baseline, injection, and performance monitoring of groundwater will be performed over time and analyzed to measure biodegradation of target compounds of potential concern (COPCs), consumption of amendments, changes in geochemical conditions, and emergence/disappearance of degradation intermediates and end products (see Attachment 3 for additional details regarding degradation intermediates and end products).. The results from these tests will be used to evaluate the field implementation of enhanced in situ bioremediation (EISB). Lancaster Laboratories, Inc. (LLI) will analyze groundwater samples for target COPCs (i.e., volatile organic compounds [VOCs], perchlorate), Research Department Explosive (RDX), dissolved hydrocarbon gases (DHGs; i.e., methane, ethane and ethene), anions (chloride, sulfate, sulfide, nitrate, nitrite), total organic carbon (TOC), and dissolved metals (iron, manganese), as presented in Tables 7-1 and 7-2. In addition, select samples will be submitted to SiREM, for microbial analysis. The proposed baseline, injection, and performance monitoring schedules are described in Sections 7.1, 7.2 and 7.3, respectively. 7.1 Baseline Monitoring Baseline groundwater sampling will be conducted at the monitoring wells and injection wells (IWs) to characterize the groundwater chemistry prior to implementation of the injection activities in each pilot test area (PTA). The baseline characterization program is presented in Table 7-1 and the sample handling and analytical details are presented in Table 7-2. Baseline groundwater sampling will be completed using low -flow purging and sampling techniques. Field measurement of pH, dissolved oxygen (DO), oxidation reduction potential (ORP), specific conductance, turbidity and temperature will be completed during well purging and groundwater sample collection. Water levels.will be measured to evaluate groundwater flow directions. The analytical suite for each PTA is described in the following sections. Pilot Test Area B105-139 Groundwater samples will be collected for baseline VOC analysis from the 16 IWs and the newly installed Zone AB and Zone CD wells (MW238-H38AB, MW239-H38AB, MW240- H38CD), to gain a better understanding of the distribution of VOCs in the PTA groundwater. Groundwater samples will also be collected for VOCs, DHGs, anions, TOC, Perchlorate, RDX from each of the existing wells (MW1 8 0-H3 8AB,,MW230-H38AB, MW231-H38AB; MW200- H38CD), and the three newly installed monitoring wells. Samples for microbial molecular analysis (i.e., vinyl chloride reductase gene) and dissolved metals analysis will be collected from the one new Zone AB well (MW239-H38AB) and MW180-H38AB. Dissolved metals have been. included in the analytical suite because the anaerobic conditions established during EISB can enhance iron and manganese mobility. Pilot Test Area B147 The four corner IWs will be sampled for baseline analysis of VOCs, perchlorate and RDX. Based on the results of the additional baseline perchlorate data from the four corner IWs, the number, depth, and layout of injection and monitoring locations may be refined in B147 PTA, as discussed in Attachment 3. Additional IWs, which will be installed after refinement of the PTA layout, will be sampled for perchlorate alone. Groundwater samples will also be collected for VOCs, anions, TOC, and perchlorate from each of the existing monitoring wells (MW-147-1, MW-147-2), and from the newly -installed Zone AB wells (MW241-G38AB and MW242- G38AB). Dissolved metals samples will be collected from well MW-147-1 and one of the newly installed Zone AB wells. Pilot Test Area B149 Groundwater samples for baseline VOC analysis will be collected from the 4 IWs as well as the new Zone C monitoring well (MW245.-039C). Groundwater samples will also be collected for VOCs, DHGs, anions, TOC, perchlorate and RDX from each of the existing monitoring wells (MW-149-1, MW183-039CD), and newly -installed transgradient and downgradient Zone CD monitoring wells (MW243-P39CD and MW244-P39CD). Samples for microbial molecular and dissolved metals analysis will be collected from wells MW-149-1 and MW183-039CD. 7.2 Injection Monitoring One of the objectives of the pilot testing is to evaluate radius of influence (ROI). An estimate of ROI and the variability of ROI between IWs may be used to refine well spacing for potential technology scale -up. During emulsified vegetable oil (EVO) injection, ROI monitoring will consist of collecting grab samples from surrounding locations not receiving injections (i.e., inactive IWs, monitoring wells, and/or piezometers). These grab samples will be visually inspected for EVO, which has a milky white color, and field tested for conductivity and turbidity, which increase when EVO is present. During injection, the injection rate, cumulative volume and injection pressure will be monitored for each IW. Monitoring will also include measurement of water levels in and around the IWs and visual observation for short-circuiting/daylighting to ground surface. The operational data will be used to support any adjustments in injection rates or pressures, and to confirm that overall injection targets are met. Should the monitoring data indicate that short-circuiting and/or daylighting at the ground surface is occurring, the injections will be temporarily stopped and injection rates/pressures will be decreased and/or injection re -configured. 7.3 Performance Monitoring The purpose of the performance monitoring program is to track and document the progress of EISB in each PTA. The groundwater monitoring program for the pilot test will include four quarterly monitoring events following the injections, with a pilot test duration of 1 year. The performance monitoring schedule is presented in Table 7-1. The sample handling and analytical details are presented in Table 7-2. The following subsections present the approach; methods and schedule to complete performance monitoring for the pilot tests. The approach and methods to collect and analyze groundwater samples for the performance monitoring program will be similar to that described for the baseline sample event (Section 7.1). Field measurement of pH, DO, ORP, specific conductance, turbidity and temperature will be completed during well purging and groundwater sample collection. Water levels will be measured during each monitoring event to evaluate flow directions. The analytical suite and schedule for analysis for each PTA is described in the following subsections. Pilot Test Area BI05-139 Groundwater samples will be collected on a quarterly basis for the one year pilot test duration for analysis of VOCs, DHGs, anions, and TOC from each of the existing monitoring wells (MW180- H38AB, MW230-H38AB, MW231-H38AB, MW200-H38CD), and the newly -installed Zone AB and CD monitoring wells (MW238-H38AB, MW239-H38AB, MW240-H38CD). Samples for microbial molecular analysis will be collected on a quarterly basis from well MW180- H38AB only. Samples for analysis of dissolved metals will be collected during the fourth quarter monitoring event, from well MW180-H38AB and one new Zone AB monitoring well (MW239-H38AB). Pilot Test Area B147 Groundwater samples will be collected on a quarterly basis for the one year pilot test duration for analysis of perchlorate, anions and TOC from each of the existing monitoring"wells (MW-147-1, MW-147-2), and the newly -installed Zone AB monitoring wells (MW241-G38AB and MW242- G38AB). Samples for analysis of dissolved metals will be collected from well MW-147-1 and one of the new Zone AB wells during the fourth quarter monitoring event. Pilot Test Area B149 Groundwater samples will be collected on a quarterly basis for the one year pilot test duration for analysis of VOCs, DHGs, anions, and TOC from each of the existing monitoring wells (MW- 149-1, MW183-O39CD), and the two newly -installed Zone CD monitoring wells (MW243- P39CD and MW244-P39CD). A sample for microbial molecular analysis will be collected from well MW-183-O39CD during each of the quarterly monitoring events. Samples for analysis of dissolved metals will be collected from MW-149-1 and MW183-039CD during the fourth quarter monitoring event. ATTACHMENT 7 TABLES TAl PROPOSED PERFORMAN Chemtronics Si Event Baseline Pilot Test Area (PTA) Well ID i. 3 w v1 U > U Q v r o ¢� U w b a: U a�i •> v] O B105-139 MW180-1-138AB ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ Pilot Test Area ff 1 MW230-1138AB ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ MW200-1-138CD ✓ ✓ _ ✓ ✓ ✓ ✓ ✓ ✓ MW231-1-138AB ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ Proposed ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ MW239-H38AB inside PTA Proposed ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ MW238-H38AB outside PTA Proposed ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ MW-240-H38CD Injection Wellss B147 MW-147-1 ✓ ✓ ✓ ✓ ✓ ✓ ✓ Pilot Test Area 92 MW-147-2 ✓ ✓ ✓ ✓ ✓ ✓ Proposed ✓ ✓ ✓ ✓ ✓ ✓ ✓17 MW241-G38AB Proposed ✓ ✓ ✓ ✓ ✓ ✓ ✓12 MW242-G38AB Injection Wells `� ✓ B149 MW-149-1 ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ Pilot Test Area#3 MW183-039CD ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ Proposed ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ MW243-P39CD (transgradient) Proposed ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ MW244-P39CD (downgradient) Proposed ✓ ✓ ✓ MW245-039C Injection Wells7o Notes: All samples are groundwater except where specifically indicated 1 Field Parameters (FP) are pH, dissolved oxygen, oxidation-reduction potential, specific conductance, turbidit 2 VOCs are Volatile Organic Compounds 3 DHGs are Dissolved Hydrocarbon Gases and include methane, ethane, ethene 4 Anions include chloride, sulfate, sulfite, nitrate, nitrite 5 TOC is Total Organic 6 Research Department Explosive 7 Dissolved metals are manganese and iron 8 16 Injection wells will be installed and sampled 9 16 Injection wells will be installed. The 4 corner injection wells will be sampled for VOCs, perchlorate and 1 10 4 Injection wells will be installed and sampled for baseline parameters 11 PTA is Pilot Test Area 12 One of MW241-G38AB or MW242-G38AB will be sampled for dissolved metals according to the schedul( 2012 0928 Chemtronics 10b Attachment 7 Table 7-1.x1sx 7-1 Geosyntec Consultants MONITORING SCHEDULE wannanoa, NC Quarterly Final (Quarter 4) w Nn > En Q C. ¢�' N _ O a c4 =3 O > Q E 3 w Nn Q > mn 1' Ca . ¢ O a e X c;i b /> N ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓iz ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓iz ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ l temperature , other injection wells will only be sampled for VOCs. icated. 2012.09.28 TABLE 7-2: SUMMARY OF GROUNDWATER SAMPLE HANDLING AND ANALYTICAL DETAILS &osyntm Consultants Chemtronics Site, Swannanoa, NC Sample Method Practical Holding Matrix Parameter - Analytical Method Numbers r> Quantitation Sample Container Preservative Time Limit Volatile Organic Gas Chromatography SW-846, 8260B 5 to 20 µg/L . 3 x 40 mL VOA HCI, cool to 4°C 14 days Compounds /Mass Spectrometry Anions (chloride, nitrate, 28 days (48 nitrite, sulfate) Ion Chromatography EPA 300.1 0.5 - 5 mg/L 2x 40 mL VOA cool to 4°C hours for nitrite) Dissolved Hydrocarbon Gas 15 µg/L Gases (ethene, ethane, Chromatography/ RSK-175 or EPA (methane), 5 3 x 40 mL VOA HCI, cool [0 4°C 14 days methane) Flame Ionizing 8015B µg/L (ethene and Detector ethane) 4 da 3 a Perchlorate Ion Chromatography EPA 314.0 2 µg/L 250 mL plastic cool to 4°C 28 days = High Performance Nitroaromatics and Liquid EPA 8830 0.6-18 µg/L 2 x I L amber glass cool to 4°C 7 days Amines Chromatography with UV detection Inductively Coupled Dissolved Manganese and Plasma/Atomic 6010B 0.05-0.15 in 500 mL plastic nitric acid to 60 days Iron"' Emission pH<2 Spectrometry Total Organic Carbon Combustion or EPA 415.1 EPA 1 mg/L 500 mL plastic H3P cool to 28 days Oxidation Vin 1 Chloride Reductase y Pol erase chain ym N/A 3.9 x 103 gene 1000 mL plastic Sterile technique, no 24 hours (vcrA) reaction copieslL or field filter c of to 4ace cool to 4°C Notes: mg/L - milligrams per liter µg/L. - micrograms per liter mL - milliliters HCL - hydrochloric acid H3PO4 - phosphoric acid t�1 United States Environmental Protection Agency Method Number (2) Groundwater samples will be field filtered prior to preservation 2012 0928 Chemtronics 10c Anachment7 Table 7-2.xlsx 2012.09.28 ATTACHMENT 8 WELL DATA TABULATION 8. WELL DATA TABULATION A tabulation of well data is included in this attachment, including: (i) proposed injection wells, monitoring wells; and piezometers (Table 8-1), (ii) existing monitoring wells (Table 8-2); and (iii) abandoned wells (Table 8-3). Table 8-2 lists existing wells within the B 105-139, B 147, and B149 Target Evaluation Areas, as defined in Figure 9-3 of Attachment 9. Table 8-3 lists abandoned wells within the B105-139, B147, and B149 Target Evaluation Areas, as defined in Figure 9-3 of Attachment 9. Additionally, Table 8-3 lists select abandoned wells outside of B 149 Target Evaluation Area but between Pilot Test Area. B 149 and Pond 2 (see Figure 9-3 of Attachment 9). Well construction records for the existing wells listed in Table 8-2 are provided in Attachment 8-A, while available well abandonment records are provided in Attachment 8-B. ATTACHMENT 8 TABLES TAI PROPOSED INJECTION WELL, MONITORING W Chemtronics Si PTA Well ID Type Status Date Installed Easting (ft NADI B105-139 MW238-1-138AB Monitoring Proposed TBD 978449.: MW239-1-138AB Monitoring Proposed TBD 978458.1 MW240-H38CD Monitoring Proposed TBD 978440 IP105-1 Injection Proposed TBD 978417.: IP105-2 Injection Proposed TBD 978437.' IP105-3 Injection Proposed TBD 978458.1 IP105-4 Injection Proposed TBD 978478., IP105-5 Injection Proposed TBD 978412. IP105-6 Injection Proposed TBD 978432.: IP105-7 Injection Proposed TBD 978452.1 IP105-8 Injection Proposed TBD 978472.1. IP105-9 Injection Proposed TBD 978405, IP105-10 Injection . Proposed TBD 978425.1 IP105-11 Injection Proposed TBD 978445.'1 IP105-12 Injection Proposed TBD 978466.: IP105-13 Injection Proposed TBD 979400.1 IP105-14 Injection Proposed TBD 978420.: IP105-15 Injection Proposed TBD 978440., IP105-16 Injection Proposed TBD 978460. P105-IAB Piezometer Proposed TBD 978393.: PI05-2AB Piezometer Proposed TBD 978423.: B147 MW241-G38AB Monitoring Proposed TBD 978313.. MW242-G38AB Monitoring Proposed TBD 978296.'. IP147-1 Injection Proposed TBD 978280. IP147-2 Injection Proposed TBD 978301.. IP147-3 Injection Proposed TBD 978322: IP147-4 Injection Proposed TBD 978343. IP147-5 Injection Proposed TBD 978282.'. IP147-6 Injection Proposed TBD 978303. IP147-7 Injection Proposed TBD 978324. IP147-8 Injection Proposed TBD 978345. IP147-9 Injection Proposed TBD 978284.'. IP147-10 Injection Proposed TBD 978305. IP147-11 Injection Proposed TBD 978326. IP147-12 Injection Proposed TBD 978347. IP147-13 Injection Proposed TBD 978286. IP147-14 Injection Proposed TBD 978307. IP147-15 Injection Proposed TBD 978328. IP147-16 Injection Proposed TBD 978349. P147-IAB Piezometer Proposed TBD 978297. P147-2AB Piezometer Proposed TBD 978268. B149 MW243-P39CD Monitoring Proposed TBD -980347. MW244-P39CD Monitoring Proposed TBD 980329.. MW245-039C Monitoring Proposed TBD 980295.. IP149-1 Injection Proposed TBD 980276. IP149-2 Injection Propose TBD 980312.: IP149-3 Injection I Proposed TBD 980291.' IP149-4 Injection I Proposed TBD 980327. Notes: PTA = Pilot Test Area. *= Coordinates provided are approximate. ft = feet. NAD83 =North American Datum (1983). NAVD88 =North American Vertical Datum (1988). BLS = below land surface. TBD = To be determined. 1= Surface of bedrock is variable and is estimated to be between 20 and 50 ft BLS. Wells will be installed so 2 = Well screen will be installed to intercept the water table. Construction details (e.g., total depth, screen interval, and screen length) for the proposed injection wells, mo: 2012_0928_Chemtronics_I la Attachment 8_Proposed Well Data Tabulation -Table 8-l.xlsx 84 AND PIEZOMETER CONSTRUCTION DETAILS wannanoa, NC Northing* (ft NAD83) Top -of Casing Elevation (ft NAVD88) Ground Elevation (ft NAVD88) Well Diameter (inches) Total Depth (ft BLS) Screened Interval (ft BLS) Screen length (ft) 700280.45 TBD TBD 2 29 13 to 28 15 700197.79 TBD TBD 2 29 13 to 28 15 700242.68 TBD TBD 2 72 57 to 72 15 700262.35 TBD TBD 2 29 13 to 28 15 700255.00 TBD TBD 2 29 13 to 28 15 700249.01 TBD ' TBD 2 29 13 to 28 _ 15 700243.58 TBD TBD 2 29 13 to 28 15 700243.87 TBD TBD 2 29 13 to 28 15 700236.52 TBD TBD 2 29 13 to 28 15 700230.53 TBD TBD 2 29 13 to 28 15 700225.10 TBD TBD 2 29 13 to 28 15 700222.85 TBD TBD 2 29 13 to 28 15 700215.50 TBD TBD 2 29 13 to 28 15 700209.51 TBD TBD 2 29 13 to 28 15 700204.08 TBD TBD 2 29 13 to 28 15 700204.37 TBD TBD 2 29 13 to 28 15 700197.02 TBD TBD 2 29 13 to 28 15 700191.03 TBD TBD 2 29 13 to 28 15 700185.60 TBD TBD 2 29 13 to 28 15 700252.32 TBD TBD 2 29 13 to 28 15 700172.67 TBD TBD 2 29 13 to 28 15 700161.34 TBD TBD 2 36 15 to 35 20 700119.17 TBD TBD 2 36 15 to 35 20 700167.68 TBD TBD 2 36 15 to 35 20 700168.70 TBD TBD 2 36 15 to 35 20 700170.97 TBD TBD 2 36 15 to 35 20. 700173.80 TBD TBD 2 36 15 to 35 20 700148.51 TBD TBD 2 36 15 to 35. 20 700149.52 TBD TBD 2 36 15 to 35 20 700151.79 TBD TBD 2 36 15 to 35 20 700154.62 TBD TBD 2 36 15 to 35 20 700126.52 TBD TBD 2 36 15 to 35 20 700127.54 TBD TBD 2 36 15 to 35 20 700129.81 TBD TBD 2 36 15 to 35 20 700132.64 TBD TBD 2 36 15 to 35 20 700107.35 TBD TBD 2 36 15 to 35 20 700108.36 TBD TBD 2 36 15 to 35 20 700110.63 TBD TBD 2 36 15 to 35 20 700113.46 TBD TBD 2 36 15 to 35 20 700189.58 TBD TBD 2 36 15 to 35 20 700100.11 TBD TBD 2 36 15 to 35 20 690946.95 TBD TBD 2 20 to 50' TBD' 10 699896.40 TBD TBD 2 20 to 50' TBD' 10 699955.64 TBD TBD 2 TBD' TBD' 10 699948.33 TBD TBD 2 20 to 50' TBD' 10 699962.46 TBD TBD 2 20 to 501 TBD' 10 699910.57 TBD TBD 2 20 to 50' TBD' 10 699924.71 TBD TBD 2 20 to 50' TBD' 10 he total depth is coincident with the competent bedrock surface. ng wells, and piezometers are subject to change based on field conditions. Geosyntec Consultants 09.28.2012 TAB EXISTING MONITORING WF Chemtronies Sit PTA WellID Type Status Date Installed Easting (ft NAD83) Noi (ft N B105-139 BW-5 Monitoring Existing 3/18/1986 978686.74 700: DW-139 Monitoring Existing. 3/26/2002 978781.19 700: MW180-H38AB Monitoring Existing 1/7/2000 978454.22 700' MW181-I37AB Monitoring Existing 1/27/2010 978698.79 7W MW200-H38CD Monitoring Existing 1/27/2010 978416.28 700: MW218-J38CD Monitoring Existing 1/25/2011 978863.27 700 MW230-H38AB Monitoring Existing 12/6/2011 978501.93 700: MW231-1138AB Monitoring Existing 12/6/2011 978414.06 700'. B147 MW-147-1 Monitoring Existing 8/3/2005 978333.31 700 MW-147-2 Monitoring Existing 4/25/2000 978243.77 700 MW-147-3 Monitoring Existing 4/25/2000 978173.64 700 B149 MW-149-1 Monitoring Existing 7/31/2000 980302.81 699: MW183-039CD Monitoring Existing -1/29/2010 980301.19 699: MW184-N38AB Monitoring Existing 1/8/2010 980093.58 700 MW219-039CD Monitoring Existing 2/1/2011 980134.20 699' MW235-P39CD Monitoring Existing 12/9/2011 980454.14 700, SW-149 Monitoring Existing 3/19/2002 980212.75 700 Notes: PTA = Pilot Test Area. ft = feet. NAD83 =North American Datum (1983). NAVD88 = North American Vertical Datum (1988). BGS = below ground surface. 1='Ibis deep bedrock well contains an open 3 in. (nominal) borehole from 79.5 to 122.7 ft BLS (open `. 2012 0928 Chemtronics 1 lb Attachment 8 Existing Monitoring Well Data Tabulation_ Table 8-2.xlsx 8-2 CONSTRUCTION DETAILS 3wannanoa, NC ng 83) Top of Casing Elevation (ft NAVD88) Ground Elevation (ft NAVD88) Well Diameter (inches) Total Depth (ft BGS) Screened Interval (ft BLS) Screen length (ft) .87 2271.20 2271.60 3 122.7 79.5 to 122.7 1 43.5 1 .70 2273.56 2270.71, 2 44.0 39.0 to 44.0 5 .42 2291.65 2288.78 2 28.0 13.0 to 28.0 15 .93 2274.27 2271.52 2 23.4 7.8 to 23.4 15.6 .97 2291.58 2288.71 2 73.0 57.8 to 72.5 14.7 .02 2276.71 2274.72 2 24.0 14.0 to 24.0 10 .80 2291.13 2288.12 2 25.0 10.0 to 25.0 15 .63 2291.61 2288.88 2 25.0 10.0 to 25.0 15 .36 2302.14 2299.04 2 35.0 25.0 to 35.0 10 .38 2296.17 2296.29 2 20.0 10.0 to 20.0 10 .44 2300.01 2300.34 2 20.0 10.0 to 20.0 10 .52 2234.42 2232.62 2 21.8 10 to 20 10 32 2233.44 2230.81 2 42.5 27.8 to 42.1 14.7 .29 2271.30 2268.24 2 49.0 34.0 to 49.0 15 .95 2254.51 2251.68 2 84.0 69.0 to 84.0 15 .04 2234.38 2231.58 2 30.0 20.0 to 30.0 10' .11 2262.81 2259.96 2 43.0 33.0 to 43.0 10 rehole length of 43.5 ft). Geosyntec Consultants. 09.28.2012 M: ABANDONED WELI Chemtronies Sit PTA Well ID Type Status Date Installe 13105-139/B147 TW-3 Monitoring Abandoned (date unknown) 12/17/2001 B105-139 TW-147D Monitoring Abandoned (date unknown) 2/25/2002 TW-14 Monitoring Abandoned (date unknown) 12/18/2001 SW-5 Monitoring Abandoned (11/27/2009) 4/26/1986 B149 TW717 Monitoring Abandoned (date unknown) 12/19/2001 TW-18 Monitoring Abandoned (date unknown) 12/19/2001 TW-16 Monitoring Abandoned (date unknown) 12/19/2001 Notes: PTA = Pilot Test Area. ft = feet. NAD27 = North American Datum (1927). NAVD88 = North American Vertical Datum (1988). BLS = below land surface. NA = not available. 2012 0928 Chemtronics 1 lc Attachment 8 Abandoned Well Data Tabulation Table 8-3.xlsx 8-3 ATA TABULATION iwannanoa, NC. Easting (ft NAD27) Northing (ft NAD27) Top of Casing Elevation (ft NAVD88) Well Diameter (inches) Total Depth (ft BLS) Screened Interval (ft BLS) 978331.72 700187.73 2289.63 1 NA 5 to 15 978433.99 700227.53 2285.40 1 NA 30 to 40 978477.73 700255.71 2284.03 1 19.9 8 to 18 978635.64 700281.90 2271.96 1 51.3 13.8 to 48.8 980292.44 699900.51 2229.23 1 15.6 5 to 15 980244.57 699826.81 2229.05 1 15.3 5 to 15 980286.31 699854.09 2227.23 1 NA 5 to 15 Geosyntec Consultants 9.28.2012 ATTACHMENT 8-A RECORDS OF CONSTRUCTION FOR EXISTING MONITORING WELLS Project Abbrev. Date Project No. /3,� f Logged by C.. •. �o T J i LOG OF ROCK CORE Boring No. .8 to- .5 Location ^•��r ar�_�� • n f — /CY: z c� j Depth of Boring f tea• 7 Boring Elev, Size of Core--_ /UQ l �e in, Elev. Top of Bedrock "' 94- per,,r•_ - Type of Core Barrel gLrwA/o `Er, b[ Elev. Groundwater [troth Run No, Recovery % RQD % Graphic Lag Fractures 'Lithology maLA Top o 1 Bor�vm off' ¢ "ss ca,Siri O 79. Z , 80 COnhUnirr:, c Ln bZrd:S t Caar3e ;,; r • ' anum of cu ktt 1'316e �r , rnatt✓f:c�.l?, 9�� � �rous , we.E'� r 3 - -0 , 92nepU6y ¢a 45 r � Ye IS itR-t.t�� 1L�1.w�C.2�cGcC: t . • r, r 87�5 N ` �'• klm Form No. 350 6 Z 0 0 W Project Abbrev. 0I1ot11'fyor1 i [S Date Project No.--- 1 o? I Logged by C. Scvv� f LDG OF ROCK CORE Boring No. JB U)" 5 Location - Uo wrn r e!6 sa t — Anu Z Depth of Bonn I dg"� , / 9 . � Boring Elev. r .Oa71. 3 e 0r0!»,ri ,Sur�cG Size of Core— NQ- 17/B rn. Elev. Too of Bedrock ^' 74 �f fi'P�o��r ar 17u Type of Core Barrel -c bUlnle 4U60 Elev. Groundwater Depth Run No. Recovery % RQD % Graphic ' Log Fractures Lithology Q • r, • Corqauum, QLun huzrzts t Coar:sz q0p • .,' . 1��1 �{ uLtr�3t�ic �A1C�SS a; 9 gg. g' qZ. Zr �3•�r'� ancC 94.7S'- •. .[/9 .50 °— 7'o ° Core is 12Clre-l" -�b veld A" in $.cu! c�3IIhG r.• a4rac,urn ev-up- fur du!Cnj ' � � • breaks. . q5 •!". r• r• 97-55 N• l o o r .r' • r Inn IrT Fenrm Nn -Isn L49TI-Al v a -- ProjectAbbrev._ Vnom•h-oni .S Date G lzlsc Project No. 1 311 Logged by LOG OF ROCK CORE Boring No. ��'Jr Location D01.01oraatc2n4- Ar,�4 a 3 Depth of Boring-1 �a.7 �---- Boring Elev. -6. Size of Core_ NO -.I M Elev. Top of Bedrockc-;*1nL7_prooa� Type of Core Barrel _rhUhle limp_ Elev. Groundwater Depth Run No. Recovery X RQD % Graphic Log Fractures Lithology �•�.' I bi 6& 8*io-hk C,vtlss • ; •. • • Cor+iau" dun b nd s y coax , 105 R-3 100% loot • d e ',�'erous, I - • r ; N�,�./5-5� a�' 1�3104.95' (i.G'� �. Q3�5 . r �ti r2c� a.►1C� 101.7 '7 •r, .r 10 -4 100% 100Z '�; •r Form No. 350 _ _ _ METCALF & EDDY Z } Q Q W Ca U. :J a LU u M Project Abbrev, Date --�A2 Project No. I ha! Logged by Swgo_ l, LOG OF ROCK CORE Boring No. 5 Location [10 ?2no2.3 Depth of Boring- /a.0. % Boring Elev. ���7/.:.(, .Or�icna Su�vice Size of Core h/n- 1 y9 +�• ' Elev. Top of Bedrock 7d E `'%a./ Oi» g2 irr� Type of Core Barrel .,Igzr. hbe Elev. Groundwater Depth- Run No. Recovery % ROD d• Graphic Log Fractures Lithology v N.^'rJGyp. (cJlu�e B�a�;�e �rrVclSs �LGKL grLux nL t�/5 ti • /`� In P.�atG�S� OCClL59LLi6Y1Q�r_YR>n�5 u. /Zo P1-5 /00% 100% ti. N .¢'� ^6.N ,�cLLnZai�2ra7.cS� die ;� 30 =¢oo •.v •: 2 iu.n�ra:ur2� t Co 5 1 .N VI,y� N &44om Form No. 350 iuFrrel F A cnnv r METCALF -a EDDY - ENGINE=lS BE6 Lc .t! �. zN3P�c73M -_ 5.9•uYct7Z WEATHcR Mce 1214, .y w ul .501 L' %-ik�. h A II Q 7 !I T]p,tiJ i . 1 1 d'L.r-tic �Gt LU j tom/--'Lk�.�.-�• ,..�` ,r, mac` v 3 1 6, c<rPovND >rL E ✓ Tj,�l L D L- PTij c�/lGu.v o &J, T �. 'PA7e � 1 METCALF & EDDY WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources - Division of Water Quality WELL CONTRACTOR (INDllWMVAL) NAME (print) MARK GETTYS CEYRMFICATION 4 2345 WELL CONTRACTOR COMPANY NA 1B GEOLOGIC EXPLORATION, INC. PHONE # (704)872-7686 STATE WELL CONSTRUCTION PER MIT4 ASSCCIATED WQ PERA41W (if applicable) (if applicable) 1. WELL USE (Check Applicable Box): Residential 0 Municipa.Mblic C3 Industrial[] Apicuiturai Ibionitoring M Recovery ® Heat ?%imp Water Injection 13 Other® If Other, List Use 2. WELL LOCATION: Nearest Town: SWANNONOA County BUNCOMBE 180 OLD BEE TREE ROAD (Street -Nam, Numbers, Community, Subdivision, Lot No., Zip Cods) -3. OWNER: CHEMTRONICS; INC. Address 180 OLD BEE TREE ROAD (St ect or Route No.) SWANNONOA NC 28778 City or Town State Zip Cale Area code- Phone number 4. DATE DRILLED o8mxm 5. TOTAL DEPTH: 35.0 FEET 6. DOES WELL REPLACE EXISTING WELL? YES ❑ NO El 7. STATIC WATER LEVEL Below Top of Casing: 10.0 FT. (Use "41" if Above Top of Cuing) 8. TOP OF CASING IS 2.5 FT. Above Land Surfwe* *Top oftsing terwinated at/or below had merface requires a vnrbxa to accordance with 15A NCAC 2C .81I& 9. Y 1LL'U (gpm): N/A N i HOD OF ! EES i N/A 10. WATER ZONES (depth): N/A IL DISINFECTTON: Type NIA Amount 12. CASING: Wall Thickness Depth Diameter or Weight/Ft- Material From 0.0 To 25.0 FL 2 INCH SCH. 40 PVC From To Ft From To Ft. - 13. GROUT: Depth Material Method From 0.0 To 19.0 Ft. PORTLAND BENTONITE SLURRY From To Ft. 14. SCREEN. ' Depth Diautcter SIot Size Material From 25.0 To 35.0 Ft2.0 is .010 in. PVC From To Ft in. M. 15. SAND/GRAVEL PACK: Depth Size Material From 23.0 To 35.0 Ft. 20-40 FINE SILICA SAND From To Ft- • Topographic/Land setting ❑Ridge ❑Slope ©Valley ®Flat (check appropriate box) LatitudeAonn tude of well location (de#C-/MkUL s/secoi d&) Latitude/longitude source:❑GPSOTopographic map (chock box) DEPTII DRILLING LOG From To Formation Description 0.0 10.0 BROWN SILTY CLAY • 10.0 18.0 18.0 35.0 RED/BROWN SILTY CLAY BROWN CLAYEY SILT LOCATION SKETCH Show direi tion and distance in mules from at least two State Roads or County Roads. Include the road numbers and common road names.11 d� re 16. REMARKS: MW-147-1 REP BENTONITE SEAL FROM 19.0 TO 23.0 FEET. I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15A NCAC 2C, WELL CONSTRUCTION STANDARDS ANDJ7ATA�.COPY OF THIS RECORD HAS BEEN PROVIDED TO THE WELL OWNER SIGNATURE OF PERSON CONSTRUCTING -THE WELL Submit the original to the Division of Water Quality, At. -a: Information Management, I617 Mail Service Center - Meign, NC 27699-1617, Phoae No. (919) 733-7015, within 30 dal;s. MONITORING WELL COMPLETION DIAGRAM DATE INSTALLED: 8/03/2005 CLIENT: Chemtronics Inc PROJECT NO: 2085.10 WELUBORING NO: MW-147-IREP PLANE COORDINATES: NORTH PROJECT NAME: Chemtronics Inc. EAST ADDRESS: Swannanoa, NC TOP OF SLAB ELEVATION: WELL CONTRACTOR: Geologic Exploration Inc. TOP OF CASING ELEVATION: WELL SCHEMATIC TOP OF CASING PROTECTIVE CASING I TOP OF CONCRETE PAD LENGTH OF STICKUP 3.0 FT. GROUND SURFACE CEMENT/BENTONITE GROUT DEPTH r0 BASE OF ' GROUT SEAL 1s.0 FT. TOTAL BOREHOLE BOREHOLE DIAMETER DEPTH 8.0 IN. LENGTH FROM OF GRADE RISER •35.0 FT. 25.0 FT 13ENTONITE SEA 4.0 FT. TOTAL WELL DEPTH FROM GRADE 35.0 FT. CONSTRUCTION DATA CASING INFORMATION ' MATERIAL: ® PVC ❑ STAINLESS Cl CARBON ❑ OTHER DIAMETER: ®2" ❑ 4" ❑ 8" ❑ OTHER IN. JOINTS: ®THREADED ❑ WELDED ❑ SCREWED ❑ COUPLED ❑ OTHER SCHEDULE: SCREEN INFORMATION MATERIAL: ® PVC ❑ STAINLESS ❑ TEFLON ❑ OTHER DIAMETER: ® 2" ❑ 4" ❑ s" ❑ OTHER IN SLOT: ® 0.010 ❑ 0.020 ❑ OTHER IN CENTRALIZER: ❑ YES ® NO SHOW LOCATION OF CENTRALIZERS) ON SCHEMATIC FILTER PACK MATERIAL 20/40 SAND OTHER ❑ SECONDARY FILTER PACK MATERIAL SUGAR SAND ❑ OTHER ❑ BENTONITE WELL SEAL, LENGTH ®1/24NCH PELLETS OF ❑ 1/4-INCH PELLETS SCREEN ❑ CHIPS 10.0 FT. ❑ OTHER SURFACE PROTECTION CONCRETE PAD:®2'X2' ❑ 4'X4' ❑OTHER FT WELL SUMP/CAP WELL SUMP/CAP ® YES ❑ NO LENGTH 0.17 FT. ALL ELEVATIONS ARE IN FEET NGVD ENGINEERING & HYDROGEOLOGY 50 COLLEGE STREET,ASHEVILLE, NC 28801 TEL.8282813350 FAC.828.281.3351 w wr.altamonlereiaonmentaLcom Prepared By: PJCh=tm.les-H&VftIo=wI of MW-113.1 147-11,all ddails Checked By: Norh Carolina - Degartinertt.of Enviratl ;rent -and -Natural Resources - Division of W3:er Quati:y - Grcundv.wer Sacticn 1636 N161 Service Center - Raleigh. N.C. 27699.1636-Phone (919) 733.3221 WELL CONSTRUCTION RECORD - WELL•CONTRACTOR: WELL CONTRACTOR CERTIFICATION ,,ter`-(`, %f I (� STATE WELL CONSTRUCTION PERMITR: 1. WELL USE (CtieckAcplicab;e Box): Residentia; ❑ Municipal ❑ Industrial ❑ Agicultlral ❑ �L!oni:or;ng Recovery ❑ Heat Pump Water injection ❑ Other ❑ If Other, List Use: 2. WELL LOCnTISW4;,W�C .A1location)belo.v) N Nearest � cunt Ccun;;: or SubC:Visicn aid Lct No.) Address 06J) _-i"Ice e_ /Qjj , U ^ 2 O OR�fNG� -"/L City or Town S:a,.e Zip Cede -".. DA T F. DRILLED Ok �� S. TOT AL DEPTH 6. CUTTINGS COLLECTED YE3 ❑ r," 7. DOES WELL REPLACE EXISTING WELL? YES NOX 6. STATIC Y` A7ER LEVEL Selcw Tcp of Cash',;: f FT. (Use'- if A:ova Ta? cf S. TOP OF CASING IS + r i . Above Land Surface -Top of cas:ng terminated al*r below land surface requL.as a variance in accor- dance wit'l 15A NCAC 2C .C113 10. YIE -D'(gpm): M, Fr'^0 OF TEST 11. VIA TER ZONES (depth): 12. C: HLORINIAT[ON: Type Amnount. If a=di.., -a- -a - :S na=d d U S s =_:< c: ;0.:n 13. CASING: Wall Th.c:cess I OCrTOBI Sri=-C= D��. tii to %'A2 - i.: `e!ial S� dire-.:_r an:! r4 ..:=--e I �.•:: �� Diame r Cr �r..,,r�' =t 2 (...G�/ ....... ..:o'... a:. aa:..... J:B:� FrCm�Tc s'Q =.._�— �c�fYO From To FI. From —To— 1A. GROUT: Depth aterlai Method From 0 To =:. 10—AAAND 15. SCREEN: CJ�/ Depth v Di=_��.eter Slot Size 'aterial es r 1 From fQ_ ToFt 2+ f__f in. Q.L, in. From To Ft. in. in.. From To FL in. in. 16. SAIND(GRAVEL PACK: Dept99 Size Material From To,, FL From To Ft. 17. REMARKS: 100 HEREBY CERTIFY THAT THIS WELL WAS CONSTWR IN,�ICCORDANCE WITH I SA NCAC 2C, WELL CONSTRUCTION STANDARDS, AND THAT A CO,PYQq E RD H�4S BEEN_FROVIDED TO THE WELL OWNER. FOR OFFICE USE ONLY Quad No: Sarial No. Cl�7 r. 1 0- . 0, f— SIGNATUHE 0 PERSON CONsTjucTING THE WELL Submit original to Division of Water Quality, Grow dwater Section within 30 days r 7� ? 0() ATE GW-1 REV. 12/99 ___-. _ 1636 Mz1 Service Center - Rakish. N.C. 27699-1636-Phone (919) 733-3221 WELL CONSTRUCTION RECORD WELL CONTRACTOR: tiY ` _ / I ��ELL CONTRACTOR CERTIFICATION K:_ MYy 3 STATE WELL CONSTRUCTION PERh11TR: 1. WELL USE (Check Applicable 9ox): Residential ❑ Municipal ❑ Industrial ❑ Agricultural ❑ Micr'kitorng4 . Recovery ❑ . Neat Pump Water Injec:icn ❑ Other ❑ If Other, List Use: 2. WELL LOCATION: (Sho i ske c� of the Icca.._- 0W) z � N_sr_s: TOv. Cvt% 4 �tJ fir; ii/ Q � Cc :.y: 1�L� r/ (r:ead Na.-e a r Z Pit:-ber3, Ca,—r.._.:ry.'or Sa:t Lit Nc.) DRILLING LOG 3. OV.11NISM. To Address CJC.C) t.'� �f'E �. ���%� a 210' O*t* /G' SAT.. y (Jtr" tic. City or Town Si to Z:p :cC: 4. DA T c DRILLED 4/Z S/ QO 5. TOTAL DEPTH e5r 6. CU TINGS COLLECTED YES M P:Q-4 '" t,I 7. DOES WELL REPLACE EXISTING WELL? YES N0',-8 B. STATIC WATER LEVEL Below Top of Caslrs: F7. (::sa 'r' if A,'-cve 7c; c.1 Cas:e;) 6. TOP OF CASING IS 0 FT. Aaove Lan Surface, 'Top of casing terminated atjor below land sur:aca rein: as 3 var lance in 3c=o:- dance with 15A NCAC 2C.0118 10. YIELD (gprr:): MEtt HOD Or= TES- 11. W.XERZONES (depth): ^u�t12. CHLORINATION: Type y s^e:daduse L_=< C:I addilana* spa ; .... 13. CASING: D=ot�. r Ciaretar From Q—To _ Ft. 2�r Frorz To Ft. From To F.. 14. GROUT-: Wa:; -..cxness LOCATION SKETCH :t�a:eda; Depth, lat�ria! Method From 4 To —SI — r"t. Lt�AIQ From _ , To Ft. 15. SCREEN: Depth����,,,�r Diameter Slat Size Materal From 0" To � Ft " in. D/O in. 241AI90 From To Ft. in. in. From To Ft. in. in. 16. SAiNOIGRAVEL PACK: Depth, f Size, Material From k To _ Ft, From To Ft. 17. REMARKS: 100 HEREBY CERTIFY THAT THIS WELL WAS CONSTR IN CCOROANCE WITH 15A NCAC 2C, WELL CONSTRUCTION STANDARDS, AND THAT A COPY E RD H S BEEN PROVIDED TO THE WELL OWNER. FOR OFFICE USE ONLY Quad No: SIGNATURE OP PERSON CONSTIUCTING THE WELL Submit oritinal to Division of Water Quality, Groutdwater Section Within 30 days Serial No. -Z, W od GW-1 REV. t2'99 J W — Ar 1 WELL CONSTRUCTION RECORD North Carolina = Department of Environment and Natural Resources - Division of Water Quality - Groundwater Section WELL CONTRACTOR (INDIVIDUAL) NANIE (print;21�4_ L "e IY-e, CERTIFICATION§_X123 ' WELL CONTR\CTOItCOMPANY NAME _ SA.�fJAGC.O PHONE It aqS .Sa4-9IqS STATE WELL CONSTRUCTION PER.tiIITR ASSOCIATED WQ PM%IIT$ lifapplicable) (if applicable) 1. WELL USE (Check licable Box): Residential ❑ Municipal/Public ❑ Industrial ❑ Agricultural ❑ Monitoring recovery ❑ Heat Pump Water Injection ❑ Other ❑ If Other, List Use 3.. WELL LOCATION: Topographic/Land setting Nearest Town:stvcxmrxoJKao` Count y_8LAnCak2blz ❑Ridge ❑Slope ❑Valley_ bfaitr—_� ,zpd O "�� (check appropriate box) (Street Name. Numbers, Community, Subdivision, Lot No., Zip Code) Latitude/longitude of well location 3. OWNER: 1 Rd - f C ;$ ' - (degcees'mirtutes/seconds) Address o G Latitude/longitude source:❑GPS❑Topographic map (Street or Route No.) (check box) Yi2a; 'mcyioa_ /(J(� DEPTH DRILLING LOG City or Town • state Zip Code From To Formation Dy ription � jrJ Area code- Phone number 30 _� s D 4. DATE DRILLED 5. TOTAL DEPTH:_ 6. DOES WELL REPLACE EXISTING WELL? YES ❑ NO 7. STATIC WATER LEVEL Below Top of Casino: FT. (Use "+" if Above Top of Casing) 3.. TOP OF CASING IS t 3 FT, Above Land Surface* 'Tup of casing terminated ardor below land surface requires a variance in accordance wlth 15A NCAC 2C .0118. 9. YIELD Wm): METHOD OF.TEST 10. WATER ZONES (depth): 11. DISINFECTION: Type Amount 12. CASING: Wall Thickness • Depth Diameter or Weight/Ft. Material - Fro m_C_ To 33 Ft._ a',' S�vp iV C, From To Ft. LOCATION SKETCH Show direction and distance in miles from at least . two State Roads or County Roads. Include the road numbers and common road names. From To . Ft. :13. GROUT: Depth Mat ri 1 Method From To �9 FL Of QR � , v, • 1 P—M hn I-2i From To Ft. 14. SCREEN: Depth Diameter Slot Size Material From-33—To 4.3 Ft. A 'in. e) (8 in. PIC From To Ft. in. in. 15. SAND/GRAVEL PACK: Depth Size Material From 3 I To (4 3 Ft, t=L- Z "SF) }J From To Ft. 16. REMARKS: 1 DO HEREBY CERTIFY -THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH ISANCAC 2C, WELL CONSTRUCTION STA D T7T A COPY OF HIS CORD HAS BEEN PROVIDED TO THE WELL OWNER SIGNA LA-Q_. 3 1( NG THE WELL DATE Submit the original to the Division of Water Quality, Groundwater Section, 1636 i4lail Service Center - Raleigh, NC 27699-I636 Phone No. (919) 733-3221, within 30 days. GW-1 REV. 07/2001 1636 Mail Service Center - Raleigh, N.C. 27699-1636-Phone (919) 733.3221 WELL CONSTRUCTION RECORD WELL CONTRACTOR: PApgA-rT- VJMFF IMC• l `1C _ MW _ I WELL CONTRACTOR CERTIFICATION #: ZS`47- ` STATE WELL CONSTRUCTION PERMIT#: 1. WELL USE (Check Applicable sox): Residential ❑ Municipal [] Industrial ❑ Agricultural ❑ Monitoring Recovery ❑ Heat Pump Water Injection ❑ Other ❑ If Other, List Use: 2. WELL LOCATION: (Show sketch of the location below) Nearest Town:50A0WAt\30A County: (Road Name and Numbers. Community, or Subdivision and, Lot No.) DRILLING LOG DEPTH 3. OWNER F.rom To Formation Description Address 17C) O�,p gEE '(12EE 90,g) 5VIZ4-ACSE5 - 3.0r 6F-o"-7N aVD N0IS-r1DLJ treet or outs o. Sn 1k F / t..)A2t7 SILT I C LAt� SWANNAi\t�?A NC -- City or Town State Zip Code 4. DATE DRILLED -1zlr_ I� C BQowN DQ� WET r1� 5. TOTAL DEPTH t7,0 4JEATlac P� Y-�/G� 6. CUTTINGS COLLECTED YES d NO❑ 7. DOES WELL REPLACE EXISTING WELL? YES ❑ NOE, 8. STATIC WATER LEVEL Below Top of Casing: FT. (Use '+' It Above Top of Casing) 9. TOP OF CASING IS 2 FT. Above Land Surface' 'Top of casing terminated at/or below land surface requires a variance In accor- dance with 15A NCAC 2C .0118 10. YIELD (gpm): METHOD OF TEST 11. WATER ZONES (depth): 12. CHLORINATION: Type Amount If additional space is needed use back of form 13. CASING: t LOCATION SKETCH j Wall Thickness Depth Diameter or Weight/Ft. Material (Show direction and distance from at least two State From 7'o To 5"'r A's Ft 2' scu uo Pic Roads, or other map reference points) From To Ft, From To Ft. 14. GROUT: Depth Material Method From 3•0 To Ft. POLAQ_ From To Ft. 15. SCREEN: Depth Diameter Slot Size Material From t7•0' To 7, o Ft I- in. . 010 in. 9'1 e. From To Ft. in. In. From To Ft. In. In. 16. SAND/GRAVEL PACK: Depth Size Material From t-t.o To S, D Ft. 1' S �t`1Q From S•S� To 3,2Ft. 91-T, c�11P5 - 17. REMARKS: SEE SITS- ,riAP F-Q12 LJC/STioW, I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15A NCAC 2C, WELL CONSTRUCTION STANDARDS, AND THAT A CiPPY OF THIS1REORD HAS BEEN PROVIDED TO THE WELL] OWNER. FOR OFFICE USE ONLY v"i^-� 1 3 I -zo { Quad No: SIGNATURE OF PERSON CONSTRUCTING THE WELL DATE r Submit on inal to Division of Water Quality, Groundwater Section within 30 days Serial No. GWi REV. 12/99 NVELL CONSTRUCTION RECORD Noah Carolina -Department of Environment and Na esources -Division of Water Quality -Groundwater Section WELL CONTRACTOR (IlYDIY1DUAL) NAiHE (print) 0tJ�=++C• I � Ii� �C�� :CERTiFIC.lT10N �_ d�y7� WELL CONTRACTORCOMPANY NAM STATE WELL CONSTRUCTION PERb= ASSOCIATED WQ PERMITA (if applicable) (if'olicsble) 1. WELL USE (Check Applicable Box): Residential ❑ Municipal/Public C3. Industrial•❑ Agricultural ❑ Manitoring E "'Recovery ❑ Heat Pump Water Injection ❑ Other ❑ If Other, List Use 2: WELL LOCATIQN: •NearestTowa:' WCLhilg t Coua(Jc �'B& M2 O&D &P-,7k8,0, (Saw Name, Numbea, Conunaairy, Subdivision. Lpt No, Zip Code) -3. OWNER ,�'Is'lC?K" tlo'Ly TrOJlfCS AddressslFPiT,�i (Sant ar Rauce No. City oeTown Sty Zip Code Acca cedr,bone aua:;-- 4. DATEDUMED w�`e2(o—G� 5. TOTAL DEPTH: • L141 . 6. DOES WELL REPLACE EXISTING WELL? YES ❑ NO 0-*` 7. STATIC WATER LEVEL Below Top of Casing: FT. I (Usc "+" if Above Top of Cuing) 8. TOP OF CASING IS aW FT. Above Land Surface' `Top of easing terminated actor below land surface requires a tailanee in accordance with ISA IQCAC 2C .0118. 9, YIELD (gpm): METHOD OF TEST 10. WATER ZONES (depth): it. DISINFECTION:Type Amount 12. CASING: Wall Thickness Topoggzayhic/L.and setting - ME 'dge Mope ❑Valley ❑Flat (check appropriate box) Latitudellongitude of well location • (degr:almImstes/saroads) Latitudellongitude source:❑GPS❑Topographic map (check_ box) DEPTH DRILLING LOG From To ()fit ytion l 'pion LOCATION SKETCH. Show direction and distance in miles from at least two State Roads or County Roads. Include the road Depth Diameter orWeight/Ft atonal numbers and common road names. �J Cam- From To Ft From _ To Ft 13. GROUT: Depth Material Method From_ To Ft �'ta9_ From To Ft 14. SCRE Depth Diameter . Slot Size Material From To_V:R!_ FL_22 uL' 0. 0 t in. ,9I l eS From To Ft in. in. IS. SAND/GRAVEL PACK -- Depth - Size Material From_ To��FL ZX Sa d•Cz' �A WJI From —To —Ft. 16. REMARKS: _ I� F NTON d e-- d as _�?,' Ta Yl l I DO HEREBY CERTIFY THAT WAS CONSTRUCTED IN ACCORDANCE WnH 15A NCAC 2C, WELL CONSTRUCTION STAND T A CC?w 0- THIS RECORD HAS BztN PROVIDED TO THE WELL -OWNER SIGNATURE OF PE ON CONSTRUCTING THE WELL DATE Submit the original to the Division of Water Quality, Groundwater Section, Mail Service Center - Raleig NC 27699-1636 Phone No. (919) 733-3221, within 30 days. GW-1 REV. 07/2001 MONITORING WELL CONSTRUCTION DATA DATE INSTALLED: 1/7/2010 CLIENT: Chemtronics, Inc. PROJECT NO: 2115.117 WELL/BORING NO: MW180-H38AB PLANE COORDINATES: NORTH 700176.63 PROJECT NAME: Chemtronics, Inc. EAST 978383.00 ADDRESS: Swannanoa. NC TOP OF SLAB ELEVATION: 2288.78 WELL CONTRACTOR: AE Drilling Services TOP OF CASING ELEVATION: 2291.65 CONSTRUCTION DATA WELL SCHEMATIC TOP OF CASING PROTECTIVE CASING TOP OF CONCRETE PAD LENGTH OF STICKUP 2.87 FT. GROUND SURFACE CEMENT/BENTONITE GROUT DEPTH TO BASE OF GROUT SEAL 9.0 FT. TOTAL BOREHOLE BOREHOLE DIAMETER DEPTH 8.0 IN. LENGTH FROM OF GRADE RISER 28.0 FT. 13.0 FT, SEAL 2.0 FT. FILTER PACK 17.0 FT. TOTAL WELL DEPTH FROM GRADE 28.0 FT. CASING INFORMATION MATERIAL: ❑X PVC ❑STAINLESS ❑CARBON ❑ OTHER DIAMETER: ® 2" ❑4" 06" ❑ OTHER IN. JOINTS: © THREADED ❑ WELDED ❑ SCREWED ❑ COUPLED ❑ OTHER SCHEDULE: 40 MATERIAL: © PVC ❑ STAINLESS ❑ TEFLON ❑ OTHER DIAMETER: ❑x 2" ❑ 4" ❑ 6" ❑ OTHER IN SLOT: ® 0.010 ❑ 0.020 ❑ OTHER IN CENTRALIZER: EYES ® NO SHOW LOCATION OF CENTRALIZERS) ON SCHEMATIC FILTER PACK MATERIAL 20/40 SAND OTHER ® GP #1 SECONDARY FILTER PACK MATERIAL SUGAR SAND ❑ , OTHER ❑ BENTONITE WELL SEAL LENGTH ❑1/2-INCH PELLETS OF ❑ 1/4-INCH PELLETS SCREEN ❑X CHIPS 15.0. FT. ❑OTHER SURFACE PROTECTION CONCRETE PAD:© 3'X3' ❑ 4'X4' ❑ OTHER FT WELL SUMP/CAP WELL SUMP/CAP ® YES ❑ NO LENGTH 0.40 FT. 231 "Aywoob-.s T. [C T; 49H[Vltl C. NC'2beb1 ' "Tf l.62 e.281.3350 f�b�62 B,201.3391 rrr.w�ewwoen......... wi.eow PAChemtronics-211MTask 140-154 RIFS Phl Tech MemolAppend'oc C- Boring logs and well detals\ Well Construction Diagram MW780-H38ABAs MONITORING WELL CONSTRUCTION DATA DATE INSTALLED: 1/27/2010 CLIENT: Chemtronics, Inc. PROJECT NO: 2115.117 WELL/BORING NO: MW181-137AB PLANE COORDINATES: NORTH 700284.18 PROJECT NAME: Chemtronics, Inc. EAST 978627.56 ADDRESS: Swannanoa, NC TOP OF SLAB ELEVATION: 2271.518 WELL CONTRACTOR: AE Drilling Services TOP OF CASING ELEVATION: 2274.27 CONSTRUCTION DATA WELL SCHEMATIC CASING INFORMATION TOP OF CASING MATERIAL: ❑X PVC ❑STAINLESS ❑CARBON PROTECTIVE CASING4— ❑ OTHER TOP OF CONCRETE PAD LENGTH OF STICKUP DIAMETER: ® 2" ❑4" 06" ❑ OTHER IN. 2.75 FT. JOINTS: © THREADED ❑ WELDED GROUND SURFACE ❑ SCREWED ❑ COUPLED ^Pc :L.x< ❑ OTHER SCHEDULE: 40 SCREEN INFORMATION MATERIAL: © PVC CEMENT/BENTONITE ❑ STAINLESS GROUT DEPTH TO ❑ TEFLON BASE OF ❑ OTHER GROUTSEAL DIAMETER: ❑x 2" 3.0 FT. ❑ 4" TOTAL BOREHOLE ❑ 6" ❑ OTHER IN BOREHOLE DIAMETER SLOT: ® 0.010 DEPTH 8.0 IN. LENGTH ❑ 0.020 FROM OF ❑ OTHER IN GRADE RISER 23.4 FT. 7.8. FT. CENTRALIZER: El YES ® NO SHOW LOCATION OF CENTRALIZER(S) ON SCHEMATIC SEAL 2.2 FT. FILTER PACK MATERIAL 20140 SAND OTHER ❑X GP #1 TOTAL WELL SECONDARY FILTER PACK MATERIAL DEPTH SUGAR SAND ❑ FROM OTHER ❑ GRADE 23.4 FT. BENTONITE WELL SEAL FILTER LENGTH ❑1/2-INCH PELLETS PACK OF El 1/4-INCH PELLETS 18.2 FT. SCREEN OCHIPS 15.6 FT. ❑OTHER SURFACE PROTECTION CONCRETE PAD:© 3'X3' ❑ 4'X4' ❑ OTHER FT WELL SUMP/CAP WELL SUMP/CAP © YES ❑ NO LENGTH 0.60 FT. ALL ELEVATIONS ARE IN FEET NGVD E1ti.01�N'C'GR1;h'G �' N T4RO GE0106;�Y -231 HAYT.'OOfl STe�CCi; A911CVIcl [. li C.�2fl00t 'iTt:92 e.76/.335fl --Fw G,92 B,7.91.A351 .•Lt11110M�[I�v111GF�16M7r11t.CYM ' P:\Chemtronics - 21151Task 140-154 RIFS Phi Tech MemoWppendix C- Boring logs and well details\ Well Construction Diagram MW181-137AB.1ds MONITORING WELL CONSTRUCTION DATA DATE INSTALLED: 1/29/2010 CLIENT: Chemtronics, Inc. PROJECT NO: 2115.116 WELL/BORING NO: MW183-039CD PLANE COORDINATES: NORTH 699857.75 PROJECT NAME: Chemtronics, Inc. EAST 980230.01 ADDRESS: Swannanoa, NC TOP OF SLAB ELEVATION: 2230.81 WELL CONTRACTOR: AE Drilling Services TOP OF CASING ELEVATION: 2233.44 CONSTRUCTION DATA WELL SCHEMATIC TOP OF CASING PROTECTIVE CASING TOP OF CONCRETE PAD LENGTH OF STICKUP 2.63 FT. GROUND SURFACE CEMENT/BENTONITE GROUT DEPTH TO BASE OF GROUTSEAL 22.8 FT. TOTAL BOREHOLE BOREHOLE DIAMETER DEPTH 10 8T 5 IN. FROM GRADE 43.6 FT SEAL 2.2 FT. FILTER PACK 18.6 FT. ALL ELEVATIONS ARE IN FEET NGVD LENGTH' OF RISER 27.4 FT CASING INFORMATION MATERIAL: ❑X PVC ❑STAINLESS ❑CARBON ❑ OTHER DIAMETER: ® 2" ❑4" ❑6" ❑ OTHER IN. JOINTS: ❑X THREADED ❑ WELDED ❑ SCREWED ❑ COUPLED ❑ OTHER SCHEDULE: 40 SCREEN INFORMATION MATERIAL: ❑x PVC ❑ STAINLESS ❑ TEFLON ❑ OTHER DIAMETER: ❑X 2" ❑ 4" ❑ 6" ❑ OTHER IN SLOT: ® 0.010 ❑ 0.020 ❑ OTHER IN CENTRALIZER: DYES ® NO SHOW LOCATION OF CENTRALIZER(S) ON SCHEMATIC FILTER PACK MATERIAL 20/40 SAND OTHER ® GP #1 TOTAL WELL SECONDARY FILTER PACK MATERIAL DEPTH SUGAR SAND ❑ FROM OTHER ❑ GRADE 42.5 FT. BENTONITE WELL SEAL LENGTH ❑1/2-INCH PELLETS OF 01/4-INCH PELLETS SCREEN MCHIPS 14.7 FT. ❑ OTHER SURFACE PROTECTION CONCRETE PAD:❑X 3'X3' ❑ \ ❑ OTHER FT WELL SUMP/CAP WELL SUMP/CAP © YES ❑ NO LENGTH 0.47 FT. f f EffOiNE:t,a (;HO $ FI YO HOOtO CO.G'Y -131:/IAVM000 STIILCT. �h9N[VILL C, NC 28901 - '' T[.L:836.R81.3350 'f'I:c:B29.2 a,1:3351 Ta.wL3 owian•Iwori�[w:wC.cow' P:\Chemtronics- 2115\Task 140.154 RIFS Phi Tech MemoV\ppendix C- Boring logs and well details\ Well Construction Diagram MW783.039CDAsx MONITORING WELL CONSTRUCTION DATA DATE INSTALLED: 1/8/2010 CLIENT: Chemtronics, Inc PROJECT NO: 2115.117 WELL/BORING NO: MW184-N38AB PLANE COORDINATES: NORTH 700073.70 PROJECT NAME: Chemtronics, Inc. EAST 980022.37 ADDRESS: Swannarioa, NC TOP OF SLAB ELEVATION: 2268.24 WELL CONTRACTOR: AE Drilling Services TOP OF CASING ELEVATION: 2271.30 CONSTRUCTION DATA WELL SCHEMATIC CASING INFORMATION TOP OF CASING MATERIAL: ❑X PVC [!]STAINLESS ❑CARBON PROTECTIVE CASING ❑ OTHER LENGTH OF STICKUP 3.06 FT. DIAMETER: ® 2" ❑4" 06" ❑ OTHER IN. JOINTS: ® THREADED ❑ WELDED TOP OF CONCRETE PAD GROUND SURFACE ❑ SCREWED ❑ COUPLED .^; w: ^. ,. ❑ OTHER SCHEDULE: 40 t t CEMENT/BENTONITE GROUT DEPTH TO • BASE OF GROUT SEAL 28.0 FT. BOREHOLE DEPTH FROM GRADE 49.0 FT. BOREHOLE DIAMETER 8.0 IN. SEAL 2.5 FT. FILTER PACK 18.5 FT. ALL ELEVATIONS ARE IN FEET NGVD LENGTH OF RISER 34.0 FT. TOTAL WELL DEPTH FROM GRADE 49.0 FT. LENGTH OF SCREEN 15.0 FT. WELL SUMP/CAP MATERIAL: © PVC ❑ STAINLESS ❑ TEFLON ❑ OTHER DIAMETER: ❑X 2" ❑ 4" ❑ 6" ❑ OTHER IN SLOT: ® 0.010 ❑ 0.020 ❑ OTHER IN CENTRALIZER: DYES ® NO SHOW LOCATION OF CENTRALRER(S) ON SCHEMATIC FILTER PACK MATERIAL 20/40 SAND OTHER ❑X GP #1 SECONDARY FILTER PACK MATERIAL SUGAR SAND ❑ OTHER ❑ BENTONITE WELL SEAL ❑1/2-INCH PELLETS ❑ 1/4-INCH PELLETS ❑X CHIPS ❑OTHER SURFACE PROTECTION CONCRETE PAD:® 3'X3' ❑ 4'X4' ❑ OTHER WELL SUMP/CAP ❑X YES ❑ NO LENGTH 0.40 FT. 'G-A,6 1 N C!CR1'N C Et H,r 4R O 6 L D'LO G '2]1 /1 AYW OOC.STp IM A9H¢V{ :, NC 2aapi , ie.291.3356 `rA C:629;291.37a1 ' .wlewwowi{wY1wYa�pwrwi.cow FT P;\Chemtronics- 2115\Task 140-154 RIFS Phi Tech Memo\4ppendbc C- Boring logs and well detals\ Well Construction Diagram MW184-N38ABAs MONITORING WELL CONSTRUCTION DATA DATE INSTALLED: 1/28/2010 CLIENT: Chemtronics, Inc. PROJECT NO: 2115.116 WELUBORING NO: MW200-H38CD PLANE COORDINATES: NORTH 700143.18 PROJECT NAME: Chemtronics, Inc. EAST 978345.06 ADDRESS: Swannanoa, NC TOP OF SLAB ELEVATION: 2288.7 WELL CONTRACTOR: AE Drilling Services TOP OF CASING ELEVATION: 2291.58 CONSTRUCTION DATA WELL SCHEMATIC TOP OF CASING PROTECTIVE CASING TOP OF CONCRETEALENGTH OF STICKUP 2.88 FT. ROUND SURFACE CEMENT/BENTONITE GROUT DEPTH TO BASE OF GROUT SEAL '51.8 FT. TOTAL BOREHOLE BOREHOLE DIAMETER DEPTH 10 & 5 IN. LENGTH FROM OF GRADE RISER 74.0 FT. 57.8 FT. SEAL 2.2 FT. F FROM GRADE 73.0 FT FILTER LENGTH PACK OF 20.0 FT. SCREEN E 14.7 FT. ALL ELEVATIONS ARE IN FEET NGVD WELL SUMP/CAP CASING INFORMATION MATERIAL: PVC ❑STAINLESS ❑CARBON ❑ OTHER DIAMETER: ® 2" ❑4" ❑6" ❑ OTHER IN. JOINTS: © THREADED ❑ WELDED ❑ SCREWED ❑ COUPLED ❑ OTHER SCHEDULE: . 40 SCREEN INFORMATION MATERIAL: ❑X PVC ❑ STAINLESS ❑ TEFLON ❑ OTHER DIAMETER: ❑X 2" ❑ 4„ ❑ 6" ❑ OTHER IN SLOT: ® 0.010 ❑ 0.020 ❑ OTHER IN CENTRALIZER: ❑ YES ® NO SHOW LOCATION OF CENTRALIZER(S) ON SCHEMATIC FILTER PACK MATERIAL 20/40 SAND OTHER GP #1 SECONDARY FILTER PACK MATERIAL SUGAR SAND ❑ OTHER ❑ BENTONITE WELL SEAL q1/24NCH PELLETS _ Ell/4-INCH PELLETS ❑X CHIPS ❑ OTHER SURFACE PROTECTION CONCRETE PAD:© &XV ❑ 4'X4' ❑ OTHER FT WELL SUMP/CAP ® YES ❑ NO LENGTH 0.48 FT. E. 0Q.t;N,C^.C'y1N G & H Y❑ Rp G C 0 L,p,G_Y 2]f NAYYJOOO ST wCiT, 'Ae N¢VILLi. NC. 2a001 .' TLL.e 2e.?B1.3350 few c.B28,2B1.33B1 t¢w�1�oMwcw�wa.cow P1Chemtronics - 2115\Task 140-154 RIFS Phi Tech MemoWppendix C- Boring logs and well detals\ Well Construction Diagram MW200-H38CD.Asx MONITORING WELL CONSTRUCTION DATA DATE INSTALLED: 01-25-11 CLIENT: Chemtronics Inc PROJECT NO: 2115.161 WELL/BORING NO: MW218-J38CD PLANE COORDINATES: NORTH 700054.28 PROJECT NAME: Chemtronics Inc. EAST 978792.07 ADDRESS: Swannanoa, NC TOP OF SLAB ELEVATION: 2274.716 WELL CONTRACTOR: AE Drilling Services TOP OF CASING ELEVATION: 2276.71 CONSTRUCTION DATA WELL SCHEMATIC CASING INFORMATION TOP OF CASING MATERIAL: ❑X PVC ❑STAINLESS ❑CARBON PROTECTIVE CASING ❑ OTHER TOP OF CONCRETE PAD LENGTH OF STICKUP DIAMETER: ® 2" ❑ 4" ❑ 6" ❑ OTHER IN. 3 FT. JOINTS: ® THREADED ❑ WELDED GROUND SURFACE ❑ SCREWED ❑ COUPLED ❑ OTHER SCHEDULE: 40 SCREEN INFORMATION MATERIAL: © PVC CEMENT/BENTONITE ❑ STAINLESS GROUT DEPTH TO ❑ TEFLON BASE OF ❑ OTHER GROUT SEAL DIAMETER: ❑X 2" 9.0 FT. ❑ 4" ❑ 6" TOTAL BOREHOLE ❑ -OTHER IN BOREHOLE DIAMETER SLOT: ® 0.010 DEPTH, 10.0 IN. LENGTH ❑ 0.020 FROM OF ❑ OTHER IN GRADE RISER 24.7 FT. v 14.0 FT. CENTRALIZER: ❑YES ® NO SHOW LOCATION OF CENTRALIZER(S) ON SCHEMATIC SEAL 3.0 FT. FILTER PACK MATERIAL 20/40 SAND OTHER © GP #1 TOTAL WELL SECONDARY FILTER PACK MATERIAL DEPTH SUGAR SAND ❑ FROM OTHER ❑ GRADE 24.0 FT. BENTONITE WELL SEAL FILTER LENGTH Ell/2-INCH PELLETS PACKFiOF ❑1/4-INCH PELLETS 12.7 FT. SCREEN ❑X CHIPS 10.0 FT. ❑OTHER SURFACE PROTECTION CONCRETE PAD:® 3'X3' ❑ 4'X4' OTHER FT WELL SUMP/CAP WELL SUMP/CAP ® YES ❑ NO LENGTH 0.30 FT. ALL ELEVATIONS ARE IN FEET NGVD G ;au4N,c, R,iN,c A fi T o a,Loyc•c-o,t o s 231 490CY-.[, NC.-20001 T[L.B20.2B1..3350''!'M1C, B28,2B 1.3301' A ./1lT/�AOi1TCAY1RO.........ON ' P:1Chemtronics Data E-Library120101Fielditase II1Well Construction\MW21BJ38CD.xls MONITORING WELL CONSTRUCTION DATA DATE INSTALLED: 02-01-11 CLIENT: Chemtronics Inc PROJECT NO: 2115.161 WELL/BORING NO: MW219-039CD _ PLANE COORDINATES: NORTH 699900.36 PROJECT NAME: Chemtronics Inc. EAST 980063.01 ADDRESS: Swannanoa, NC TOP OF SLAB ELEVATION: 2251.681 WELL CONTRACTOR: AE Drilling Services TOP OF CASING ELEVATION: 2254.51 CONSTRUCTION DATA WELL SCHEMATIC TOP OF CASING PROTECTIVE CASING:::k-r TOP OF CONCRETE PAD [LENGTH OF STICKUP 3 FT. GROUND SURFACE CEMENT/BENTONITE GROUT DEPTH TO 11 BASE OF GROUT SEAL 63.0 FT. TOTAL BOREHOLE BOREHOLE DIAMETER DEPTH 10.0 IN. FROM GRADE 86.0 FT. SEAL 3.0 FT. FILTER PACK 20.0 FT. ARE IN FEET NGVD LENGTH OF RISER 69.0 FT TOTAL WELL DEPTH FROM GRADE 84.0 FT. LENGTH OF SCREEN 15.0 FT. WELL SUMP/CAP CASING INFORMATION MATERIAL: ❑X PVC [—]STAINLESS ❑CARBON ❑ OTHER DIAMETER: ® 2" ❑4" 06" ❑ OTHER IN. JOINTS: ® THREADED ❑ WELDED ❑ SCREWED ❑ COUPLED ❑ OTHER SCHEDULE: 40 SCREEN INFORMATION MATERIAL: ❑x PVC ❑ STAINLESS ❑ TEFLON ❑ OTHER DIAMETER: ❑x 2" ❑ 4" ❑ 6" ❑ OTHER IN SLOT: ❑x 0.010' ❑ 0.020 ❑ OTHER IN CENTRALIZER: El YES ® NO SHOW LOCATION OF CENTRALV.ER(S) ON SCHEMATIC FILTER PACK MATERIAL 20/40 SAND OTHER ® GP #1 SECONDARY FILTER PACK MATERIAL SUGAR SAND ❑ OTHER ❑ BENTONITE WELL SEAL ❑1/2-INCH PELLETS ❑1/4-INCH PELLETS X❑CHIPS ❑ OTHER SURFACE PROTECTION CONCRETE PAD:© 3'X3' ❑ 4'X4' ❑ OTHER FT WELL SUMP/CAP ❑X YES ❑ NO LENGTH 0.30 FT. • • 3].1 NAvao oo 51e[C1; NC 2eeef 7[6:e7e.7e1.,3� so -`f,'aC:83t3.7e1.3]Sf r.rrv:Airwwdei2nr��owwewi...... P:\Chemtronics Data E-Library12010\Field\Phase IhWeil COnstructionXMW219039CD.XiS MONITORING WELL CONSTRUCTION DATA DATE INSTALLED: 12/6/2011 CLIENT: Chemtronics Inc PROJECT NO: 2115.207 WELL/BORING NO: MW230-H38AB- PLANE COORDINATES: NORTH 700156.02 PROJECT NAME: Chemtronics Inc. EAST 978430.71 ADDRESS: Swannanoa, NC TOP OF SLAB ELEVATION: 2288.12 WELL CONTRACTOR: AE Drilling Services TOP OF CASING ELEVATION: 2291.13 CONSTRUCTION DATA WELL SCHEMATIC TOP OF CASING PROTECTIVE CASING TOP OF CONCRETE PAD [7 LENGTH OF STICKUP 3 FT. GROUND SURFACE ALL LENGTH OF RISER 10.0 FT TOTAL WELL DEPTH FROM GRADE 25.0 FT. WELL SUMP/CAP CASING INFORMATION MATERIAL: ❑X PVC ❑STAINLESS ❑CARBON ❑ OTHER DIAMETER: ® 2" ❑4" ❑6" ❑ OTHER IN. JOINTS: ® THREADED ❑ WELDED ❑ SCREWED ❑ COUPLED ❑ OTHER SCHEDULE: 40 SCREEN INFORMATION MATERIAL: ❑X PVC ❑ STAINLESS ❑ TEFLON ❑ OTHER DIAMETER: ❑X 2" ❑ 4" ❑ 6" ❑ OTHER IN SLOT: ® 0.010 ❑ 0.020 ❑ OTHER IN CENTRALIZER: ❑YES ® NO SHOW LOCATION OF CENTRALIZER(S) ON SCHEMATIC FILTER PACK MATERIAL 20/40 SAND OTHER ❑X GP #1 SECONDARY FILTER PACK MATERIAL SUGAR SAND ❑ OTHER ❑ BENTONITE WELL SEAL 71/2-INCH PELLETS ❑1/4-INCH PELLETS ❑ CHIPS ❑ OTHER 3/8-inch holeplug SURFACE PROTECTION CONCRETE PAD:® 3'X3' ❑ 4'X4' ❑ OTHER FT WELL SUMP/CAP © YES ❑ NO LENGTH 0.40 FT. E NG.I,N C�LRtNG A H ♦D ROGC O"L OiG`Y 231.HAYM000"ST w ttT. A9.tY L:c. NC, 2nob T[4.626.261.3]50 [AC.626,261.9391- wwowtewrlwatiwcw�wc.cow PAChemtronics Data E-Library\2011\Field\Phase III RIFS\Well Construction Logs\MW230H38AB.xls MONITORING WELL CONSTRUCTION DATA DATE INSTALLED: 12/6/2011 CLIENT: Chemtronics Inc PROJECT NO: 2115.207 WELL/BORING NO: MW231-H38AB PLANE COORDINATES: NORTH 700164.84 PROJECT NAME: Chemtronics Inc. EAST 978342.84 ADDRESS: Swannanoa, NC TOP OF SLAB ELEVATION: 2288.88 WELL CONTRACTOR: AE Drilling Services TOP OF CASING ELEVATION: 2291.61 JPROTECTIVECASING r TOP OF CONCRETE PAD GROUND SURFACE CEMENT/BENTONITE GROUT BOREHOLE DEPTH FROM GRADE 25.0 FT. ALL ELEVA DIAMETER 8.0 IN. SEAL 3.0 FT. FILTER PACK 17.0 FT. WELL SCHEMATIC TOP OF CASING LENGTH OF STICKUP 3 FT. DEPTH TO BASE OF GROUT SEAL 5.0 FT. i LENGTH OF RISER 10.0 FT. TOTAL WELL DEPTH FROM GRADE 25.0 FT. LENGTH OF SCREEN .15.0 FT. WELL SUMP/CAP CONSTRUCTION DATA CASING INFORMATION MATERIAL: ❑X PVC ❑STAINLESS ❑CARBON ❑ OTHER DIAMETER: ® 2" ❑ 4" ❑ 6" ❑ OTHER IN. JOINTS: © THREADED ❑ WELDED ❑ SCREWED ❑ COUPLED ❑ OTHER SCHEDULE: 40 SCREEN INFORMATION MATERIAL: ❑X PVC ❑ STAINLESS ❑ TEFLON ❑ OTHER DIAMETER: ❑X 2" ❑ 4" ❑ 6" ❑ OTHER IN SLOT: ❑x 0.010 ❑ 0.020 ❑ OTHER IN CENTRALIZER: ❑YES ® NO SHOW LOCATION OF CENTRALIZER(S) ON SCHEMATIC FILTER PACK MATERIAL 20/40 SAND OTHER ❑R GP #1 SECONDARY FILTER PACK MATERIAL SUGAR SAND ❑ OTHER ❑ BENTONITE WELL SEAL 71/2-INCH PELLETS 01/4-INCH PELLETS ❑ CHIPS ❑OTHER 3/8-inchholeplug SURFACE PROTECTION CONCRETE PAD:© 3'X3' ❑ 4'X4' ❑ OTHER FT WELL SUMP/CAP ❑X YES ❑ NO LENGTH 0.40 FT. • Q�.♦�q�t ..elJC'L!R�f>Ni0 ♦�C. •➢N "t O R,0-6� O 1.Q ;G'If';�:: :: 291 H�vW GOD STp C[T Ae NCf ILi[„NC 2a801 . 2BB1 3 pa ;F' cs82Bj2®I.39$I; ' WM.Nlf11�1Y1�1CIM1,2Y 14VM1A¢Ff1�L.CCA ' P:\Chemtronics Data E-Library\2011\Field\Phase III RIFS\Well Construction Logs\MW231H38AB.xls MONITORING WELL CONSTRUCTION DATA DATE INSTALLED: 12/912011 CLIENT: Chemtronics Inc PROJECT NO: 2115.206 WELUBORING NO: MW235-P39CD PLANE COORDINATES: NORTH 700040.49 PROJECT NAME: Chemtronics Inc. EAST 980382.94 ADDRESS: Swannanoa, NC TOP OF SLAB ELEVATION: 2231.58 WELL CONTRACTOR: AE Drilling Services TOP OF CASING ELEVATION: 2234.38 CONSTRUCTION DATA WELL SCHEMATIC CASING INFORMATION TOP OF CASING MATERIAL: [91 PVC El STAINLESS El CARBON PROTECTIVE CASING ❑ OTHER TOP OF CONCRETE PAD LENGTH OF STICKUP DIAMETER: ® 2" ❑ 4" ❑ 6" ❑ OTHER IN. 3 FT. JOINTS: © THREADED ❑ WELDED GROUND SURFACE ❑ SCREWED ❑ COUPLED b e� ❑ OTHER SCHEDULE: 40 SCREEN INFORMATION MATERIAL: © PVC CEMENT/BENTONITE ❑ STAINLESS GROUT DEPTH TO ❑ TEFLON BASE OF ❑ OTHER GROUT SEAL DIAMETER: ❑x 2" 16.1 FT. ❑ 4" ❑ 6" TOTAL BOREHOLE ❑ OTHER IN BOREHOLE DIAMETER SLOT: ® 0.010 DEPTH 10.0 IN. LENGTH ❑ 0.020 FROM OF ❑ OTHER IN GRADE RISER 31.5 FT. v 20.0 FT. CENTRALIZER: ❑ YES ® NO SHOW LOCATION OF CENTRALIZER(S) ON SCHEMATIC SEAL 1.9 FT. FILTER PACK MATERIAL 20/40 SAND OTHER ® GP #1 TOTAL WELL SECONDARY FILTER PACK MATERIAL DEPTH SUGAR SAND ❑ FROM OTHER ❑' GRADE 30.0 FT. BENTONITE WELL SEAL FILTER LENGTH ❑1/2-INCH PELLETS PACK OF ❑1!4-INCH PELLETS 13.5 FT. SCREEN ❑CHIPS 10.0 FT. ❑OTHER 3/8-inchholeplug SURFACE PROTECTION CONCRETE PAD:® 3'X3' ❑ 4'X4' ❑ OTHER FT WELL SUMP/CAP WELL SUMP/CAP © YES Backfill 31.5-30.0 with #1 sand ❑ NO LENGTH 0.40 FT. ALL ELEVATIONS ARE IN FEET NGVD G xe 1. c�aa eN e& H r OR o c r as 2]1 MAYWOoO STa GC 1, A9NLVILLL, Ne ?Goof l Lt.520.281.3390 . rwc.028,281.3351 www.waT •cw�laoriw[wiwi.cow P:\Chemtronics Data E-Library\2011\Field\Phase III RIFS\Well Construction Logs\MW235P39CD.xls ATTACHMENT 8 -B WELL ABANDONMENT RECORDS North Carolina Department of Environment and Natural Resources - Division of Water Quality WELL ABANDONMENT RECORD WELL CONTRACTOR Abel McGuire Well ID M SW-5 WELL CONTRACTOR CERTIFICATION # 3571 1. WELL USE (Check Applicable Box): Residential 0 Municipal ❑ Industrial ❑ Agricultural ❑ Monitoring El Recovery ❑ Heat Pump Water Injection ❑ Other ❑ If Other, List Use: 2. WELL LOCATION: (Show a sketch of the location on back of form.) Nearest Town: swannanoa County Buncombe 180 Old Bee Tree Road (Road Name and Number, Community, Subdivision, Lot No.) 3.OWNER: Chemtronics 4. ADDRESS: same.as above; 5. TOPOGRAPHY: draw, slope, hilltop, valley, a (circle one) 6. TOTAL DEPTH: 88.6' DIAMETER 2". 7. CASING REMOVED: feet diameter 12/14/M09 8. DISINFECTION: (Amount of 70% hypochlorite used:) 9. SEALING MATERIAL: Neat Cement Sand Cement bags of cement 4: bags of cement gallons of water 14 gallons of water. Other Type material Amount 10. EXPLAIN METHOD EMPLACEMENT OF MATERIAL. Trerriie Method 11. DATE WELL ABANDONED 11-27-09 Quadrangle No. WELL V AUKAM: Draw a aetatlea sKetcn or me well showing total depth, depth and diameter of screens remaining in the well, gravel interval, intervals of casing perforations, and depths and types of fill materials used. I do hereby certify that this well was abandoned in accordance with 15A NCAC 2C, well construction standards, and that a copy of the record has been provided to the well owner. Signature of person abandoning the Date 12/14/2009_ WELL LOCATION: Draw a location sketch on the reverse of this sheet, showing the direction and distance of the well to at least two (2) nearby reference points such as roads, intersections and streams. Identify roads with State Highway road identification numbers. Submit original to the Division of Rater Quality, Attn: Information Management-1617 Mail Service Center - Raleigh, NC 2769971617, Phone No. (919) 733-7015, and one copy to the owner within 30 days from completion of abandonment. GW 30 Revised 09/2004 ATTACHMENT 9 MAPS AND CROSS -SECTIONS Location of Buncombe County N in North Carolina 1101 Buncombe County Y - . ` Chemtronics, Inc. , Asheville Black Mountain 0 2.5 5 TTSiiii Miles Chemtronics Property Boundary p Hydrogeologic Area (HGA) Q County Boundary Primary Roads Secondary Roads Notes: 1. PTA -Pilot Test Area 2. County boundaries and roads obtained from NC Department of Transportation. 3. Topograph map for USGS Craggy Pinacle and Oteen 1:24,000 topographic quadrangle (dated 2011 and 2010, respectively) obtained from USGS National Map (2012). Chemtronics, Inc. �,0 "JJf;,B105-139 PTA !>>i i -_ %s �B147 PTA f/ l l l 0 1,000 2,000 ` Feet .+` �✓�, Area Map Chemtronics Site Swannanoa, North Carolina Geosynte& Figure consultants 9-1 Kennesaw I 27-Sep-2012 aMW21f6 C37i W2?6-61,8' �o 14 titi � w MW-23' 47-E N H - 8AE i t �� �NI � — 1 47-3 ilh1111 �4,7 r . !o' iH3' N� §� -411 O a 1j47 Fa 8147 Pilot est Area - 147- • „. 17-C oO 0 -B B147.Area.. 147-A a E B147 PTA Monitoring Locations: 3 Inside PTA: Perchlorate (uglL) MW-147-1 480 0- proposed new AB well NA proposed new AB well NA Outside PTA: kMW-147-2 69 proposed piezometers NA 0 Proposed Pilot Test Piezometer 19 Monitoring Well - Detection Limit Exceeds Screening Value(s) O Target Evaluation Area 3 O Proposed Pilot Test Injection Well (9 Monitoring Well - Exceeds Screening Value(s) Stream • Proposed C/D Pilot Test Monitoring Well (9 Monitoring Well - Data Not Available • . Proposed A/B Pilot Test Monitoring Well Groundwater Contour Interval (5 ft Contour: e ® Former Building Area Pilot Test Area (PTA) �� Approximate Groundwater Flow Direction N TA ocations: t7nsi - - TCE (ug/L) 8AB 23,000 ` 8AB 6,600 MW200-H38CD 160 proposed new AB well NA ` proposed new CD well NA '-�� '�'�' " "• �gW_'. a• ��• L OF Outside PTA: MW230-H38AB 15 ` proposed new AB Well NA proposed piezometers NA DW 1`3f9 139 µ B105-13 Pilot Test A ea r �M1�V 0-H.38 MW-, SO-H38AB } �o l _ Q MW218-J3-8"C'D s - ` 1 105 N R105-139 Area 60 30 0 60 Feet Notes: ne 1. TCENA- B105-139 and B147 Pilot Test Area Layouts and Potentiometric Surface Ma Zone AB p - Not 2. NA -Not Applicable 3. pg/L- micrograms/liter Chemtronics Site, Swannanoa, North Carolina 4. PTA - Pilot Test Area s. Regional groundwater contours based June 1-2, 2011 sitewide monitoring event (Altamont, 2011). ). Geosyntec ® Figure 6. Groundwater elevations in feet above mean sea level (ft msl). consultants 9-4b Kennesaw 27-Sep-2012 t N 37 037 P37 QP7 1_00 _g Ilk At ng 4 41, ti 'A A I V-1 42 k 'K. 38 038 P38.1 ME n A A R A� R �Ar 9 1 41 �v J -P3WO AM35 D' AV Ak ' lelop 000,� 4 K6, N39 A O 39 W M, j C CID B149`Pilot Test Pond f 100 50 0 100 Feet Well -Data Not Available Monitoring Well - Detection Limit Exceeds Screening Value(! 09 Monitoring Well - Exceeds Screening Value(s) Target Evaluation Area — Stream TCE Plume in CD Aquifer RDX Plume in CD Aquifer Perchlorate Plume in CD Aquifer 1,2 DCA Plume in CD Aquifer _J Pond r_1 Pilot Test Area (PTA) 0 Proposed Pilot Test Injection Well Data Table Notes: JKey Ma 4f Groundwater results in pg/l. 100 Result does not exceed screening criteria 100 Analyte not detected but detection limit exceeds screening criteria * 4 k 100 Result exceeds screening criteria SLs (Screening Levels) for groundwater based on NC 2L Standards. Roads Note: C'Aquifer u :,ferr-ontour 1) Groundwater plume contours reflect the North Carolina property eny Boundary 2L standards. Latest Groundwater Data Around Area B149 Con 1,2- Chloro 2,4,6- Perch - Sample GW duct DCA form PCE TCE VC TNT HMX RDX lorate Location Zone Date pH i4ity ORP DO SLs:0.4 70 0.7- _ 3 0.03 1.2 350 0.32 2 MW-149-1 D 08/2008 6.22 0.075 84.3 0.93 0.1 U 15 0.2 J 350 0.1 U 0.2 U 0.65 U 2.4 U 0.61 J MW183-039CD CD 03/2010 5.5 0.063 155.2 5.45 1 U 1.1 J 15 360 1 U 0.2 U 0.7 U 5.2 67 MW184-N38AB AB 03/2010 5.29 0.048 149.8 4.5 0.1 U 0.2. J 0.2 J 2.5 0.1 U 0.2 U 2.4 7.2 0.91 J MW219-O39CD CD 02/2011 0.1 U 0.3 J 0.5 J 15 0.1 U 0.2 U 0.65 U 4.6 2.8 SW-149 B 07/2007 0.1 U 0.1 U 0.3 J 0.1 U 0.1 U 0.2 U 0.65 U 0.2 U 0.8 J Groundwater Plume Contours in Subject Are N t, • W179-H35�MW-115 r�135BA 1. A I 1kk a is . o123 n o W215 G36 0-J36A81,''� Pon d,3 (Nkural.Pond), ; . -j y i_ �,`./_.�:. MW- 6 P_13 IV W212-K36AB \/ .. 4 lop 0-'H38AQ ` '�- r,}` �•' ' ' W230-FF38Q8; d -3 -0 9 " eur g W_14�(-2 Bt6' 3a -_ I Q j B123 �� �j {�S MW1 -N38AB$ 49 r �. .. I MK -14 ,`. eu Q; . tag I ' W _ Bin k r r Etaswm u�,ar DA 10/11 .._.........._�-' MW2 9-13 39 9 91 1 82�KA s �` - -- .. .. - _==---- •,i - �, SW-152- Pond 2 SW-1,` ---- '- W19 K40AB ; :, �1512:I -- � T�4IW'151-2` ` stsz I r' IW-151-1 al. is .; ,.,..4Y SW-15� -- Roads EU Areas i M95L 14 �`-_------. • '-.- 8148 - DW-152-3SW!/23`, ash ° �.v tt o Stream Monitoring and Extraction Wells t =Pond 1 ? , Disposal Area - TCE Plume in CD Aquifer - RDX Plume in CD Aquifer., - Perchlorate Plume in CD Aquifer7 s3 9 i ° .,-•'M)67-04 ': �, lz• WW158-NAA °eJaV�a 6-P44A j P••�••�••-• tim.•�.`P .. "• I + / ' L - 1,2 DCA Plume in CD Aquifer ll • f ' 0 250 ' 500 1,000 Area B149 Contaminant Plume Map - Zone CD Chemtronics Site Feet Swannanoa, North Carolina Geosyntec° Figure consultants 9-5c Kennesaw 27-Sep-2012 I _..._.._,.._.. I _ I ! —t MW177-M44D t�� ��..._..._... i I ' MW177-M44F I I MW204-1_45EF' ` � MW160-M44C t t a + St 1 i � t S I f t t i i f I I I f I i I $ I 3 i I i j f I s zone Amonitoring Well Pilot Test Area (PTA) Cross -Section Line Soo 250 0 500 X' Zone B Monitoring Well w.� Stream Note: Feet Zone AB, Monitoring Well Pond 1. PTA - Pilot Test Area m ® Zone C Monitoring Well ;Roads Plan View of Cross -Section Locations Chemtronics Site ry S Zone D Monitoring Well ® Disposal Area (DA) SWannanoa, North Carolina S Zone CD, Monitoring Well HydrogeologicArea (HGA) Q Zone E Monitoring Well Chemtronics Property Boundary GeOsynteC ® Figure S . Zone F Monitoring Well = Former Building Location S Zane EF Monitoring Well Still standing COIISl]It<1T1tS S Extraction Well 250-ft by 250-ft Reference Grid 9-6a Kennesaw 27-Sep-2012 Northeast A ELEVATI❑N Ueet) 2500 3 (U ro 1 W 2400 hd 2300 ND )K ND/ 2200 ozJ 2100 2000 Southwest A' 105-139 Proposed Injection Zone / I 3 - / I / I o I 33 td 333 3 J FI I I FOR 0D Wo FI C7 /' 00 I D tdtd oCA O / I bd I ~ S= I I / I W W W W co 00 3 td td tj Q Inset A 1W B105-139 ' / Q Proposed - - - - - - -f n Injection s Zone / ND ND ND 12.3 /ND /ND 0 500 o'o 77 XJ 70 V) V) U-U-Q/d,d OOO mrlm W,td tititd 3 3 D C7D/O.0 Z Z OOO m m zzz/r,r- rr mmm/r�1 r-r-I r F- F- / DISTANCE Ueet) i B147 Proposed Injection (:...::'.:::'....•..,:.:.::•..:. Zone70 J J ---------------------------, 147 , Proposed Injection Zone 3 I , ro 0 p I o I J I w , OD Inset A Lithologic Codes s Water level Contaminant Color Codes TICE 1,2-DCA PCE CMorof orm Notes L Vertical Exaggeration = 2,5x 2, xIndicates 2011 sampling data where available 3. Concentrations are in micrograms per liter (fag/L) 4. Cross-section developed by Altamont (2011) 5, Locations of proposed monitoring wells and injection zones are approximate and may be adjusted to accommodate field conditions CROSS-SECTION A -A' VOLATILE ORGANIC COMPOUNDS CHEMTRONICS SITE SWANNANOA, NORTH CAROLINA Geosyntec® Figure: consultants 9-6b Kennesaw, GA I 05-Sept-2012 V1 Q� -p O 0 I'I W LJ1 I I VI"11J 1 P. I Q I C I i0 c, 0 MW180-H38AB I In 0. o O 0 ,a) I n C I -0c ri) 0. In :p O 0C aan_ N 147 Complex � r Q MW-147-1 MW200-H38CD I I MW231-H38AB MW180-H38AB v O m BW-5 o =� 0 ul o c .-I L 0 �. pqa- iN Unnamed Branch- MW-1BD MW-1BI MW212-K36AB 0 0 0 0 Ln d- (),j C�-j 0 0 oll o PROPOSED AB M❑N WELL \ � �PROP�ROPOSED � �MbN � � ,\ AB M❑N WELL PR❑P❑SED CD M❑N WELL PR❑P❑SED AB M❑N WELL zz 0 0 0 o a-i 0 0 Lo 0 Z-NDU33S-X,V-V\S3af101-J\SDINOalW3H0\0\OOVD\:l ---------------------------, 147 i Proposed I Injection Zone 3 3 I £ I I , I N o � J I o , I I � , OD tj . o..:.:;:;;:'.:::.:::::::::::..:.:.:.� td :rT,'::`:::;'::;':;'::::::::;' ram'-: Inset A Litholooic Codes s Water level Contaminant Color Codes HMX RDX Perchlorate NI-4 1, Vertical Exaggeration = 2,5x 2, xIndicates 2011 sampling data where available 3. Concentrations are in micrograms per liter (pg/L) 4.. Cross-section developed by Altamont (2011) 5, . Locations of proposed monitoring wells and injection zones are approximate and may be adjusted to accommodate field conditions CROSS-SECTION A -A' HMX, RDX, AND PERCHLORATE CHEMTRONICS SITE SWANNANOA, NORTH CAROLINA Geosynte& Figure: consultants 9-6c Kennesaw, GA I 05-Sept-2012 --------------------------------- I Imo\ ' B 149 I I 3 z Proposed £ Injection Zone in Co w Zone C I `D I (Transition Zone) I - �• W I I C) I ti I l 3 -U O �7 zo � O f'l (4 rF9 F-d Inset cl t� A Northeast B 3 3 3 CO w I �.D I 0 1 = W - W 00\ �,D tj d 0 ro I j I I I � I � I i 0 Lithologic Codes Contaminant Color Codes Overburden TCE material Bedrock PCE Chlc s Water level 3 ro ro I O 41 0 tJ Bi Pr In 70 76/7V 25 = = = 240 -0/-U _ _ M /'l tj U Z/ C7 /Cl ty =/3 z = /z � / r- r F- / 1SH Notes 1, Vertical Exc 2, xIndicates available 3, Concentrati (pg/L) 4. Cross-secti 5, Locations o injection zoi adjusted to J Southwest B' 1000 1500 2000 2500 DISTANCE Ueet) )geration = 2,5x )11 sampling data where ns are in micrograms per liter n developed by Altamont (2011) proposed monitoring wells and --s are approximate and may be accommodate field conditions 2500 2300 F � D 2200`J o z 2100 2000 CROSS-SECTION B-B' VOLATILE ORGANIC COMPOUNDS CHEMTRONICS SITE SWANNANOA, NORTH CAROLINA Geosyntec consultants Figure: Kennesaw, GA I 05-Sept-2012 - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - B149 \ I 3 3 Proposed Injection Zone in co -N w Zone C I 1,0 I (Transition Zone) I w I I 1 I. - d I I I � o EY � o I � 0/m/m tj I d n/ t= 3 I E-1 / I �/Z I z F- / I r /r :K_U O �U Z O �o Fr l f '' I/ I r d I c� I ti I Inset A Lithologic Codes Overburden material Bedrock s Water level Northeast B. 3 3 3 co 4 _P� w w\ �,D C) C) tj t) o rU 0 Contaminant Color Codes HMX RDX Perchlorate z /z r£ < M r/M r— I- I— r/ P- 500 3 P0 ry i 0 -P 0 n U B: Pi Ir Notes 1, . Vertical Ex( 2, xIndicates available 3, Concentrati (pg/L) 4. Cross -sect! 5, Locations c injection zo adjusted tc mw Southwest B' 1000 1500 2000 2500 DISTANCE (-Feet) )geration = 2,5x )11 sampUng data where -)s are in micrograms per liter developed by Altamont (2011) proposed monitoring wells and --s are approximate and may be accommodate field conditions 2500 2400 2300 F_ � D r0 2200`J o z 2100 2000 CROSS-SECTION B-B' HMX, RDX, AND PERCHLORATE CHEMTRONICS SITE SWANNANOA, NORTH CAROLINA Geosyntec consultants Figure: 9-6e Kennesaw, GA I 05-Sept-2012 Potentiometric Surface Map - Zone AB W213,MAB MW-11A3-�Wj3'1 ? 1 W-113-3. 23p i W21 5A 229p� MW 9- ` 23`22a5• W ��'`• ' ®W20 .13 ZZr © M 21 G3 AB, P-1 M 15 ` � h O M W212-K36�6 o cy - a B105-139 PTA 1 .G r '.?', ti6h_� 1s ,Lyp, MW- 4 -M 1 \ bp/ 131149 PTA Pond i - ® -152-2 _ r i �p S. "152-3," -152-3 M W 167-PP44A t�' h+[W156+P44A Mi6:N4� ® Zone A Monitoring Well (Water Table) Groundwater Contour Interval (5 ft Contours)Q Pilot t9 Zone B Monitoring Well (Intermediate Saprolite) Approximate Groundwater Flow Direction ® Dispc Zone AB Monitoring Well Existing or Former Building Location 0 Hydri Zone C Monitoring Well (Transition Zone) Stream Chen Zone D Monitoring Well (Upper Bedrock) Pond USG Zone CD Monitoring Well N i Potentiometric Surface Map -Zone CD HG42 MW 73- 34D, � ''� ryr,�ti •,,ry'h ti� ti rl`3 f04,. - �ryp�0 _3....® M 01- D 23 h 2 000 f � 4 B105-139 PTA 2 , 7 - = J` A _ -JV-139 M 20- [� HGA1 ,. 0 -H3 CD t 4 ® 'M 218,-J3 D B147 PTA +� Wl 0 o W H DW-10 B -6 � � a- cam.► 0l v� t 11 BW-1`f'N�`"N HGA 3 c! c� W 17J OCD r a D 7 51r W-15 ' ® it fy30 • _ IfAW1�6-L41D5 ,LZ�„ 4a W�� M . MW W1 IVI `4 3® M.4' MW 48-L43 i 57- 44C r I r M 177- D ry' M 59-L45C r IMW1 1- 6C i 0 150 300 600 Feet Area (PTA) Area (DA) )logic Area (HGA) -lics Property Boundary arface Elevation Contour Notes: 1. Regional groundwater contours based on June 1-2, 2011 sitewide monitoring event (Altamont, 2011). 2. Groundwater elevations in feet above mean sea level (ft � B149 PTA I e Q W221-040bD 7/ dL21 Wt193- 40C Q_M 192-P41C tiff �j M 4-N42CD _M 47-N42C f G-M43C rs' 1Pondl111 W155-P43C �2205t, MW1�4�' 44C`' 4Cf% i � r Potentiometric Surface Maps Chemtronics Site Swannanoa, North Carolina Geosynte& Figure . consultants Kennesaw I 27-Sep-2012 9-4a 4 i B110-111 °O B109-137 O B® O 10 DA23 m\ \ B114 DA23 \� B 115` 0 5 IB105-139 PTA B 143 ® B155 -128 �,, M111/181-137AB �. ~ \ TW-1A BW-5 � ', S>W-5—rB14V DW MW231-H38AB MfN180-H38AB v MW-147-3 . 4 Q o MW-147-2 MW-147-1 DA 1 DA 10/11 G Zone A Monitoring Well e Abandoned Well 9 Zone B Monitoring Well = PilotTestArea (PTA) ® Zone AB Monitoring Well _® Disposal Area (DA) ®- Zone C Monitoring Well Target Evaluation Area ® Zone D Monitoring Well Evaluation Unit (EU) Area O Zone CD Monitoring Well Nnr, Pond ® Zone E Monitoring Well — ® Stream O Zone F Monitoring Well Roads . 5) Zone EF Monitoring Well Existing or Former Building Area 9 Extraction Well M.0herntronics Property Boundary E= 77,1937-0, r 12 3 17 19-12 Bunker- Bi�4-3 B154 ,N 135 _t If 1 II ,, , o`nd 3 ; (Nn atural Pond) , �® 0� s� Of i �B1 B123 MW1,84-N38' B v� MW235-P39CD 3,-J38CD Q 814,E B122 MW-149�1 0 jZ7 TE 7 m MW21,9-039CD '"A I/ I 16 Q) , 61 3 / M1N183-Q39CD TW-16 TW-18 ® and 2 :� B,'52 o B149 PTA B 150-151 , O \\ 0 PSO 300 150 0 300 Feet B148 E tl ' J Proposed Phase I Front Valley Pilot Test Areas Chemtronics Site Swannanoa, North Carolina Geosyrite& Figure consultants Kennesaw I 27-Sep-2012 9-3 1 r uPilot Test Area (PTA) L,.jChemtronicsProperty Boundary t� ( Stream Former Building Location Pond WIStill standing Roads USGS Surface Elevation Contour Pond��{l" ®. Disposal Area (DA) Hydrogeologic Area (HGA) + Note: 1. PTA - Pilot Test Area. 2. Topographic contours are on 25 ft intervals. 780 .390 0 780 Feet Site Map Chemtronics Site Swannanoa, North Carolina Geosyntec consultants Figure 9-2 Kennesaw 27-Sep-2012 1 Pond Notes: 1.TGE-Trichloroethylene 2. NA- Not Applicable 3. pg/L- micrograms/liter 4. PTA - Pilot Test Area 5. Regional groundwater contours based on June 1-2, 2011 sitewide monitoring event (Altamont, 2011). 6. Groundwater elevations in feet above mean sea level (ft msl). 60 30 0 60 Feet B149 Pilot Test Area Layout and Potentiometric Surface Map - Zone CD Chemtronics Site, Swannanoa, North Carolina Geosyntec"" Figure consultants 9-4c Kennesaw I 27-Sep-2012 koi ` I/}Wr237=137C7 8 4s W=�1 .D� n. Y sW-$ �' t. A ,y MW _M � G37 H37 ' 137 ., - N J37 x- -e Ti�I11II81, �`B 139 Pilot Tes 9 1 ea x . 105-13t Area " 3 Fi38A6 MW280'f'138 B x, - � 8 138 m B147 Pilot l� st Area „ 11 T r 105 y G39, H39. F4 1390, J39 .; a 100 50 0 .100 Feet Well -Data Not Available Monitoring Well - Detection Limit Exceeds Screening Value(s) 09 Monitoring Well - Exceeds Screening Value(s) Target Evaluation Area Stream TCE Plume in AB Aquifer RDX Plume in AB Aquifer Perchlorate Plume in AB Aquifer 1,2 DCA Plume in AB Aquifer Pilot Test Area (PTA) Q Proposed Pilot Test Injection Well Data Table Notes: Groundwater results in pg/I. 100 Result does not exceed screening criteria 100 Analyte not detected but detection limit exceeds screening criteria 100 Result exceeds screening criteria SLs: SLs (Screening Levels) for groundwater based on NC 2L Standards. Note: 1) Groundwater plume contours reflect the North Carolina Ke Ma �l Roads'- '- .•� - AB Pot-Surface-5' Contours �. � � Property Boundary r. N Latest Groundwater Data Around Area B105-139 Con 1,2- Chloro 2,4,6- Perch - Sample GW duct DCA form PCE TCE VC TNT HMX RDX lorate Location Zone Date pH ivity ORP DO 8Ls:0.4 70, 0.7 3 0.03 1.2 350 " ' 0.32 2 K BW-5 E 09/2008 7.26 0.234 7.1 3.26 1,300 1 U 1 U 2.4 J 1.7 J 0.2 U 0.65 U 0.2 U 0.2 U DW-139 C 09/2008 5.36 0.066 102 2.14 5,100 10 11 9.4 1.3 0.2 U 0.65 U 2.5 0.72 J MW-147-1 B 08/2008 6.15 0.038 79.3 2.05 1.6 0.2 J 0.1 U 23 0.1 U 0.2 U 8.7 16 480 MW180-H38AB AB 03/2010 4.87 0 065 192.2 0.67 17 6.6 J 2 U 36,000 12 0.2 U 2.1 NJ 29 47 MW181-137AB AB 02/2010 5.37 0.079 204 1.97 0.1 U 0.1 U 0.1 U 0.2 J 0.3 J 0.2 U 0.65 U 6.9 8.3 MV1/-1 BD E 08/7008 0.1 U 13 U 0.21_J MWA BD E 10/2010 0.3 J 0.1 U 0.1 U 0.1 U 0.2 U 0.2 U MWAB1 D 08/2008 0.1 U 13 U 0.2 U MWAB1 D 10/2010 0.6 0.1 U 0.1 U 0.1 U 0.2 U 0.2 U MWAS A 09/2008 0.4 J 5 U 0.2 U MWAc n 10/2010 0.1 U 0.1 U 0.1 U 0.1 U 0.2 U 0.2 U MW200-H38CD CD 03/2010 5.99 0.062 72.7 2.95 0.2 U 0.2 U 0.2 U 160 0.2 U 0.2 U 16 J 2.9 J 2.1 MW218-J38CD CD 03/2011 0.1 U 3.8 0.3 J 1 0.1 U 0.2 U 0.65 U 0.2 U 0.21 J MW227-J39EF EF 01/2012 540 31:000 69 161 10 U 4 J 0.65 U 0.2 U 0.2 U 4K38 ' Groundwater Plume Contours in Subject Are ;; o �� >, N Bunker ESM-Rubble enaln-nz B,os-13i -i' 13-J33AB 4JL"v i'' " y 8113•'M M - 13-3 ' ,o z1 .w 6 K39 17-14 i 3'9GF y 1; ` W g) e MW-11 A 7 ,. O i `MW215 G36AB -J36AB"\' I i i B142 8143 I-M 15 B l �ss 8 1 S 212-K36AB 1 ti:- - 61191zo 8154 O M 216763 Df Wjl 1T9B+ f. MW1 0 38AB` i MW�23 -rt38 . J Q W-14 - 8105-139._ ' 6147 A -14 -2 _- `"-",Q -14 1\ 61z1 6123 ' W1 4-N3 Q3; 9 " _BSA.` -49 ,0" 49 0 O I. Ii l QRoads 4 B N%!/ 82-K39AB, Eli Areas A70' DA 10/11 �- � � B7 r Sw-15 -1 ` Pond 2 ® stream '` Monitoring and Extraction Wells 3w_1 - 1,2 DCA Plume in AB Aquifer t1V.E3�ts _.;M 91-K40AB Bi - Perchlorate Plume in AB Aquifer g 61' S 151- - - Rill Plume In AB Aquifer IW 1 ' - TCE Plume inAB Aquifer 61so 1 (r SW-1 -2 Disposal Area FM Pso 0 250 500 1,000 Area 13105-139 Contaminant Plume Map -Zone AB Chemtronics Site Feet Swannanoa, North Carolina GeosynteC® Figure consultants 9-5a Kennesaw 27-Sep-2012 .� Ate,- fA—V r E3 F37, G3713W216A S MW226'c tir H37 3 - f ' t s Ar .......... h - 9`PilotTes i L _. ' 5>w7 E W-2:V `H38 B J t -t rrMW'`74 rF A 1744;1`3381F ,€ _J Ulm 4w IMW-1 73 J��i1W'il! 17�2 ' LO04H =6 rf i E38= A F38 G38 H38 `) r r r V1/A 47 7-B ,' >TM B; 47ffiilot Test area, 7A �. w° xi.E39 F39939!s e _ 41 3 ti . K s t A 100 50 0 100 Feet Q Well -Data Not Available Monitoring Well - Detection Limit Exceeds Screening Value(s) 19 Monitoring Well - Exceeds Screening Value(s) OTarget Evaluation Area Stream TCE Plume in AB Aquifer RDX Plume in AB Aquifer Perchlorate Plume in AB Aquifer 1,2 DCA Plume in AB Aquifer O Pilot Test Area (PTA) 0 Proposed Pilot Test Injection Well lKey Ma Data Table Notes: Groundwater results in pg/I. 100 Result does not exceed screening criteria 100 Analyte not detected but detection limit exceeds screening criteria 100 Result exceeds screening criteria SLs: SLs (Screening Levels) for groundwater based on NC 2L Standards. ; Y Roads )f �t• Note: - AB Pot-Surface-6 Contours r ■ 1) Groundwater plume contours reflect the North Carolina 2Lstandards. C ;PropertyBoundary l N Latest Groundwater Data Around Area B147 Con 1,2- Chloro 2,4,6- Perch - Sample GW duct DCA form PCE .TCE VC TNT HMX RDX lorate . Location Zone Date pH ivity ORP DO SLs:0.4 70 0.7 3 0.03 1.2 350 0.32 2 MW-147-1 B 08/2008 6.15 0.038 79.3 2.05 1.6 0.2 J 0:1 U 23 0.1 U 0.2 U 8.7 16 480 MW-147-2 B 08/2008 4.4 0.017 81 1.72 0.1 U 0.1 U 0.1 U 0.6 0.1 U 0.2 U 0.65 U 3.4 69 MW-147-3 B 07/2007 0.1 U 0.1 U 0.1 U 0.2 J 0.1 U 0.2 U 0.65 U 0.2 U 79 MW174-F38E E 08/2008 4.97 0.053 187.9 4.29 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.2 U 0.65 U 0.2 U 1 ' MW174-F38F F 09/2008 7.5 0.091 -46 1.4 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.2 U 0.95 UJ 0.2 UJ 0.27 J MW180-H38ABB AB 03/2010 4.87 0.065 192.2 0.67 17 6.6 J 2 U 36,000 12 0.2 U 2.1 NJ 29 47 Y MW200-H38CD CD 03/2010 5.99 0.062 72.7 2.95 0.2 U 0.2 U 0.2 U 160 0.2 U 0.2 U 16 J 2.9 J 2.1 MW216-G37AB AB 03/2011 0.1 U 0.1 U 0.1 U 0.1 U 0.1 U 0.2 U 0.65 U 0.2 U 2 U ACea MW226-G37CD CD 03/2011 0.1 U 0.7 0.1 U 0.1 U 0.1 U 0.2 U 0.66 U 0.38 U 2 U 8AB H 8AB � Groundwater Plume Contours in Sub'ect Area Buller E§M11 RuFbla N ; ttaltl-1tz I. B109137 1',' 13-J33AB i 13113 M 2� M - 13-3 41 tostos W-6 14 ' `\ \ W , MW-11 A B11 p 4 AT i Or r MW215 G36RB� p(I 8143 7 I iM -15 e 1S 212-K36AB 6154 `1`�Ass 8 L �� 8119tza (. i O M' 216 G3 A MYV_1 1 BBB '._ �- � s - i 38ABM MW1 0 W230�Fh38 \ -N3 PS' r 49,` 0 W-14�� ¢ `_ Bros at4T _7 _2`_.., e123 WIN 0 O $ -14 �I 612t. Cit.iO �� Y 149 __ 104-14 B �t�,1aa- 1 b z; AhW/ 9 4, A DA tcr, C3 NI 82-K39AB - DA 10/11 i sto ORoads ` SW-15 -1 Pond 2 p .. i I! �._ +r' 0 EU Areas W 1 i M 9 1 -K40AB l\ -,s,-` B, Stream Y Monitoring and Extraction Wells1 '151-2 IW 1 - 1,2 DCA Plume In AB Aquifer Bt5a1: i� a SW-15 -2 - Perchlorate Plume in AB Aquifer--- - RDX Plume in AB Aquifer -- -' - TCE Plume In AB Aquifer` B14.1 so SW-15 Disposal Area e148 M85L 1 DW- 0 250 500 1,000 Area B147 Contaminant Plume Map - Zone AB Chemtronics Feet Swannanoa, North Carolina Geosyntec® Figure consultants 9-5b Kennesaw 27-Sep-2012