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WQ0004797_Monitoring (Report)_20181212
Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry - - 7i o 0 m Y LL =Z w LA •0 fo F £ E Q - a H (CFUs.per Sample Name ! Sample Date, {mg/L) (mg/L) 100 mL); (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) Standards 10 250 1 10 250 500 7.5 NL 05/15/2002, 3.5 23 < 1.1 6.3 < 1.0 68 < 0.10 11/05/2002 1.2 24 2.2 6.7 1.3 130 < 0.10 05/13/2003 1.2 31 < 1.1 7.3 < 1.0 130 0.19 11/04/2003 24 32 1.1 7.3 < 5.0 96 < 0.10 MW 2 05/05/2004 2.1 32 < 1.1 7.2 < 5.0 120 < 0.10 11/09/2004 2.4 31 > 23 7.4 < 5.0 140 < 0.10 05/17/2005 2.2 30 < 1.1 9.4 < 5.0 150 < 0.10 11/03/2005 6.6 31 < 1.1 12 < 5.0 150 < 0.10 05/24/2006 7.2 9.7 < 1.1 2 19 82 < 0.10 NA 11/09/2006 3.6 7.4 < 1.1 0.95 17 76 0.11 NA 05/18/2007 4.9 6.0 < 1.0 0.56 14 62 < 0.10 NA 11/13/2007 5.9 16.7 <1.1 2.9 6.9 82.0 < 0.10 NA 05/27/2008 10.2 9.0 <1.1 " 0.80 21.3 140 < 0.10 NA 11/18/2008 4.7 10.7 <1.1 1.9 8.5 32.0 < 0.10 NA 05/28/2009 14.4 7.1 < 4.0 0.46 24.2 104 < 0.10 NA 11/05/2009 13.5 5.9 < 2.0 0.31 23.5 80.0 . < 0.10 NA 05/13/2010 8.7 5.8 < 2.0 < 0.10 17.2 57.5 <.0.10. NA MW-2R 11/08/2010 18.3 10.0 < 2.0 1.1 11.7 60.0 < 0.10 NA 05/17/2011 11.6 < 5.0 < 2.0 < 0.10 14.3 < 62.5 < 0.10 NA 11/15/2011 18.9 10.1 < 2.0 1.2 10.0 86.0 < 0.10 NA 05/17/2012 5.3 7.6 < 4.0 < 0.20 11.9 1 68.0 < 0.10 NA 11/07/M12 31.1 9.5 < 1.0 1.3 10.0 67.0 < 0.10 NA 05/16/2013 13.5 1.2 < 1.0 < 0.02 13.2 64.0 < 0.10 NA 11/20/2013 . 6.1 7.6 < 1.0 0.97 9.3 66.0 < 0.10 NA 05/22/2014 8.0 4.1 < 1.0 0.72 8.4 52.0 < 0.10 NA November 2018 Groundwater Sampling Event Page 1 of 7 Clement Pappas, Hendersonville, North Carolina December 2018 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry - •, .. Sample Name .. Sample,Date t O r a p �ti E Q ,� a LL Z `� V1 :2 - O a N . N Y F f6 o Q 0 n. N 0 a H (mg/q (mg/L) (CFUs per 100 mL) (mg/L) (mg/L) (mg/L) (mg/L): (mg/L) Standards 10 250 1 10 250 500 1.5 NL MW-4 05/15/2002 8.9 45 < 1.1 < 0.10 9.3 180 < 0.10 NA 11/05/2002 5.5 48 < 1.1 < 0.1 14 230 < 0.10 NA , 05?13/2003 3.3 32 < 1.1 0.051 20 110 0.21 NA 11/04/2003 41 31 < 1.1 < 5.0 66 210 < 0.10 1 NA 05/05/2004 6 29 < 1.1 < 5.0 45 240 0.11 NA 11/09/2004 8A 13 3.6 < 0.10 52 200 < 010 NA 05/17/2005 8.5 10 < 1.1 < 0.10 37 220 < 0.10 NA 11/03/2005 16 .14 < 1.1 < 0.10 29 220 0.14 NA 05/24/2006 19 11 < 1.1 < 0.10 28 180 < 0.10 NA 11/09/2006 8.8 .6.9 < 1.1 < 0.10 26 180 < 0.10 NA 05/18/2007 8.5 8.9 < 1.0 < 0.10 29 300 < 0.10 NA 11/13/2007 16.7 11.3 < 1.1 < 0.10 25.0 152 < 0.10 NA 05/27/2008 < 1.0 10.0 < 1.1 < 0.10 38.6 176 < 0.10 NA 11/18/2008 20.5 9.3 < 1.1 < 0.10 19.6 .108 < 0.10 NA 05/28/2009 8.6 13.6 < 4.0 < 0.10 35.5 156 < 0.10 NA 11/05/2009 31.0 13.6 < 2.0 < 0.10 30.7 120 < 0.10 NA 05/13/2010 7.8 18.0 < 2.0 0.17 - 31.0 . 141 < 0.10 NA 11/08/2010 23.9 17.5 < 2.0 < 0.10 34.4 144 < 0.10 NA 05/17/2011 7.7 13.5 < 2.0 0.82 , 25.6 137 < 0.10 NA 11/15/2011 7.3 14.4 < 2.0 < 0.20 27.8 157 < 0.10 NA 05/17/2012 6.7 12.1 2.0 < 0.20 22.3 117 < 0.10 NA 11/07/2012 " 10.6 14.5 2.0 < 0.020 26.2 150 < 0.10 NA 05/16/2013 31.8 10.2 2.0 0.28 19.1 108 < 0.10 NA 11/20/2013 8.0 14.7 < 1.0 0.026 22.1 157 < 0.10 NA 05/22/2014 817 10.8 < 2.0 0.14 22.5 146 < 0.10 NA 11/18/2014 28.7 -12.1 < 2.0 < 0.020 21.9 161 < 0.10 NA 05/13/2015 5.4 9.2 < 1.0 ' z 0.020 21.5. 130 < 0.10 NA 11/04/2015 6.6 6.2 <2.0 < 0.020 NA 139 < 0.10 0.10 05/04/2016 5.5 8.4 < 4.0 < 0.020 NA 119 < 0.10 0.095 11/09/2016 4.3 12.2 < 4.0 < 0.020 NA 124 < 0.10 0.27 05/02/2017 3.9 7.0 <2.0 OA NA 96 <0.10 0.072 11/08/2017 3.0 7.3 <2.0 1.2 NA 135 <0.10 0.070 05/02/2018 3.0 10.0 <1.0 2.1 NA 167 <0.020 0.11 11/02/2018 3.6 9.0 • <10.0 OA8 NA ' 137 <0.10 1 0.070 November 2018 Groundwater Sampling Event Page 2 of 7 Clement Pappas, Hendersonville, North Carolina December 2018 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Sample Name Sample Date 0 `m U c a� O r a v. 0 0 0 = u°' t0 u U :: i .. "z :: i° a 0 '0 _W N C a c E a .0 o n. ate+ (mg/L) (mg/L) (CFOs per 100 mL) (mg/L) (mg/L) (mg/L) .(mg/L) (mg/L) Standards 10 250 1 1 10 250 500 7.5 NL 05/15/2002 2.9 15 < 1.1 0.42 1.7 < 40 < 0.10 NA 11/05/2002 1.4 16 < 1.1 0.54 <.1.0 83 1.3 NA 05/13/2003 _ 4.6 17 < 1.1 0.65 2 56 0.25 NA 11/04/2003 19 22 < 1.1 0.23 < 5.0 58 < 0.10 NA 05/05/2004 0.7 28 < 1.1 0.57 < 5.0 80 0.15 NA 11/09/2004 1.2 34 < 1.1 0.24 < 5.0 130 < 0.10 NA 05/17/2005 2.1 35 < 1.1 < 0.10 < 5.0 110 < 0.10 NA 11/03/2005 8.1 34 < 1.1 0.11 < 5.0 82. < 0.10 NA 05/24/2006 7.8 34 < 1.1 < 0.10 < 5.0 120 < 2.5 NA 11/09/2006 1.3 37 < 1.1 0.20 < 5.0 90 < 0.1 NA 05/18/2007 1.7 42 < 1.0 0.16 < 5.0 130 < 0.10 NA 11/13/2007 4.2 41.3 < 1.1 0.25 < 5.0 112 < 0.10 NA 05/27/2008 6.7 14.3 < 1.1 0.21 < 5.0 168 0.17 NA 11/18/2008 25.9 47.6 < 1.1 0.17 < 5.0 80.0 < 0.10 NA 05/28/2009 16.1 29.0 4.0 0.11 < 5.0 188 < 0.10 NA MW-5 11/05/2009 4.7 39.1 2.0 0.15 < 5.0 112 < 0.10 NA 05/13/2010 3.2 43.0 23 0.17 < 5.0 147 < 0.10 NA 11/08/2010 13.8 43.7 200 < 0.10 < 5.0 113 < 0.10 NA 05/17/2011 4.0 32.3 < 4.0 < 0.10 < 5.0 < 167 < 0.10 NA 11/15/2011 3.0 52.6 120 < 0.20 < 5.0 165 < 0.10 NA 05/17/2012 4.7 36.6 < 2.0 < 0.20 <, 5.0 110 < 0.10 NA 11/07/2012 4.1 61.1 < 10.0 0.12 < 2.0 139 < 0:10 NA 05/16/2013 4.0 44.2 1.0. 0.093 2.3 152 < 0.10 NA 11/20/2013 4.2 64.6 1.0 0.19 < 2.0 162 < 0.10 NA 05/22/2014 5.8 6.6 < 10.0 0.099 < 2.0 110 < 0.10 NA 11/18/2014 16.0 57.7 6.0 0.28 < 2.0 160 < 0.10 NA 05/13/2015 21.0 68.4 < 2.0 0.11 < 2.0 176 < 0.10 NA 11/04/2015 7.3 20.3 7.0 < 0.020 NA 68.0 < 0.10 0.21 05/04/2016 8.6 41.5 < '10.0 0.042 NA 90.0 < 0.10 0.12 11/09/2016 <1.0 45.0 < 4.0 0.42 NA 109 < 0.10 0.47 05/02/2017 8.1 29.0 3.0 <0.026 NA 134 <0.10 0.097 11/08/2017 6.7 12.8 188 <0.020 NA 84.0 <0.10 0.086 05/02/2018 5.7 16.1 2.0 0.022 NA 90.0 <0.10 0.097 11/02/2018 5.1 23.9 <10.0 <0.020 NA 86.0 <0.10 0.085 November 2018 Groundwater Sampling Event Page 3 of 7 Clement Pappas, Hendersonville, North Carolina December 2018 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Sample Name Sample Date C O �L R c 61 O w a •O £ JS u f0 y :: L Z M H N 0 H �, N 0 R M H f0 o E G Q VI o a p ns 10 0 F (mg/L) (mg/L) (CFUs per 100 mL) •(mg/L) (mg/L) (mg/L) (mg/L) (mg/L) Standards 10 250 1 10 250 500 1.5 NL MW-6 05/15/2002 6.8 9.9 5.1 < 0.10 11 < 40. < 0.10 NA 11/05/2002 3.9 .4.6 < 1.1 OAY 9.8 51 2.5 NA 05/13/2003 4.4 7.3 > 23.0 0.075 14 52 0.14 NA 11/04/2003 26 6.8 9.2 < 0.050 12 < 20 < 0.10 NA 05/05/2004 1.8 6.7 1.1 < 0.10 11 58 0.13 NA 11/09/2004 3.5 11 9.2 < 0.10 9.3 88 < 0.10 NA 05/17/2005 2A 7_.4 < 1.1 < 0.10 8.7 50 < 0.10 NA 11/03/2005 6.3 9:6 < 1.1 < 0.10 9.6 66 0.17 NA 05/24/2006 7.4 10 < 1.1 < 0.10 9 54 < 0.10 NA 11/09/2006 1 A 11 < 1.1 0.20 11 54 0.18 NA 05/18/2007 3.9 9A < 1.0 < 0.10 9.1 58 0.12 NA 11/13/2007 5.7 10.7 3.6 0.24 5:8 114 0.24 NA 05/27/2008 10.9 5A < 1.1 < 0.10 15.3 92.0 < 0.10 NA 11/18/2008 7.4 7.6 > 23 < 0.10 < 5.0 36.0 < 0.10 NA 05/28/2009 6.4 6.2 276 0.39 8.8 104 < 0.10 NA 11/05/2009 6.4 < 5.0 30 0.10 9.3 1 52.0 < 0.10 NA 05/13/2010 4.3 5.8 < 2.0 < 0.10 8.1 44.0 < 0.10 NA 11/08/2010 16.5 5.0 7.0 1.5 9.3 48.0 < 0.10 NA 05/17/201.1 6.2 9.4 < 2.0 < 0.10 6.8 60.0 < 0.10 NA 11/15/2011 4.6 5.2 5.0 < 0.20 7.5 82.0 < 0.10 NA 05/17/2012 21.6 8.1 28.0 < 0.20 8.8 52.0 < 0.10 NA 11/07/2012 6.4 6.8 3.1 < 0.020 7.5 46.0 < 0.10 NA 05/16/2013 7.5 5.4 12.1 0.048 9.4 62.0 < 0.10 NA 11/20/2013 4.4 7.3 < 1.0 < 0.020 8.6 56.0 < 0.10 NA 05/22/2014 4.6 4.5 1.0 < 0.020 10.1 32.0 < 0.10 NA 11/18/2014 16.3 6.9 13.0 0.078 .9.8 49.0 < 0.10 NA 05/13/2015 2.1 6.2 < 1.0 < 0.020 10.1 46.0 < 0.10 NA 11/04/2015 2.2 9.5 136 2.9 NA 58.0 < 0.10 0.12 05/04/2016 2.1 9A < 2.0 0.41 NA 58.0 < 0.10 0.079 11/09/2016 7.1 9.0 < 10.0 (< 0.020 NA 64.0 0.11 0.70 05/02/2017 1.8 12.1 2.0 OA7 NA 93.0 - <0.10 1 0.09 11/08/2017 1.4 11.1 74.0 0.045 NA 66.0 <0.10 <0.050 05/02/2018 2.3 9.4 1.0 0.085 NA 81.0 -<0.10 0.097 11/02/2018 2.5 10.1 69.0 0.64 NA 88.0 <0.10 0.057 November 2018 Groundwater Sampling Event Page 4 of 7 Clement Pappas, Hendersonville, North Carolina December 2018 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Sample Name Sample Date o u e O .H V d U Li y I Z 41 {A 0 LA V. 3 N 0 Co 7 : `o C ii (mg/L) (mg/L) (CFOs per 100 mL) .(mg/L) (mg/L) (mg/L) (mg/L) (mg/L) Standards 10 250 1 10 250 500 1.5 NL MW-7 05/15/2002 20 6.5. < 1.1 5.2 26 < 40 < 0.10 NA 11/05/2002 16 3.3 < 1.1 1.3 1.1 68 1.4 NA 05/13/2003 9.7 3.6 2.2 1.8 -9.3 44 0.72 NA 11/04/2003 19 6.1 < 1.1 0.72 < 5.0 < 2.0 < 0.10 NA 05/05/2004 3.0 7.0 < 1.1 1.3 < 5.0 52 < 0.10 NA 11/09/2004 2.2 5.1 5.1 1.9 < 5.0 62 < 0.10 NA 05/17/2005 3.2 6.1 < 1.1 1.2 < 5.0 40 < 0.10 NA 11/03/2005 7.7 6.1 < 1.1 0.99 < 5.0 58 0.10 NA 05/24/2006 8A 5.5 < 1.1 1.5 < 5.0 48 < 0.10 NA 11/09/2006 1.9 7.0 < 1.1 1.1 6.7 38 < 0.10 NA 05/18/2007 3.6 8.6 < 1.0 2.2 5.9 70 < 0.10 NA 11/13/2007 4.2 6.8 < 1.1 1.7 < 5.0 42.0 < 0.10 NA 05/27/2008 7.6 11.5 < 1.1 2.2 6.9 88.0 < 0.10 NA 11/18/2008 7.5 7.7 < 1.1 1.7 < 5.0 30.0 < 0.10 NA 05/28/2009 23.4 1 9.8 < 4.0 2.3 < 5.0 '336 < 0.10 NA 11/05/2009 5.3 10.7 2.0 2.3 11.2 70.0 < 0.10 NA 05/13/2010 . 4.6 11.0 < 2.0 2.5 < 5.0 71.0 < 0.10 NA 11/08/2010 15.4 8.9 < 2.0 2.3 < 5.0 60.0 < 0.10 NA 05/17/2011 6.0 11.6 < 2.0 5.3 7.6 103 < 0.10 NA 11/15/2011 2.2 9.9 < 2.0 .3.5 < 5.0 89.0 < 0.10 NA 05/17/2012 4A 10.9 . < 2.0 3.8 < 5.0 67.0 < 0.10 NA MW-7R 11/07/2012 11.6 13.1 < 100 4.0 14.9 108.0 < 0.10 NA 05/16/2013 12.8 17.1 , < 1.0 10.5 28.3 .252 < 0.10 NA 11/20/2013 9.4 14.0 < 1.0 5.5 3.5 < 250 < 0.10 NA 05/22/2014 8.9 13.1 < 16,000 5.7 4.0 93.0 < 0.10 NA 11%18/2014 19.1 16.0. < 20.0 7.1 4A 93.0 < 0.10 NA 05/13/2015 8.5 17.0 < 2.0 9.3 3.7 125 < 0.10 NA 11/04/2015 9.9 18.0 < 2.0 8.3 NA 129 < 0.10 0.35 05/04/2016 13.5 27.7 < 10.0 11.2 NA 130 < 0.10 0.78' 06/09/2016 - Pace NA NA NA 10.9 NA NA NA NA 06/09/2016 - Prism NA NA NA 10.0 NA, NA NA NA 11/09/2016 13.0 22.7 < 20.0 12.5 NA 147 < 0.10 1.0 05/02/2017 6.7 17.9 <4.0 8.9 NA 169 <0.10 0.4 11/08/2017 3.9 17.9 19.0 36.8 NA 376 <0.10 0.14 05/02/2018 3.2 22.6 <2.0 15.5 1 NA 207 <0.10 0.32 11/02/2018 5.3 20.2 <10.0 15.7 1 NA 243 <0.10 0.17 November 2018 Groundwater Sampling Event Clement Pappas, Hendersonville, North Carolina fn bi1".s % 14 SOUr��'S Ater 2019 Page 5 of 7 December 2018 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry . Sample Name • -'Sample Date o C c El O m - I-- ' °10 `2 U £ = v V LLL ;; r Z ar,+ Ln L v > � 4AA p I- 2 c Q . C`o a O a F (mg/L) (mg/L) .(CFOs per 100 mL) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) Standards 10 250 1 10 250 500 7.5 NL MW 8 05/15/2002 6.8 8.7 < 1.1 < 0.10 b.1 64 < 0.16 NA 11/05/2002 4.8 9.8 < 1.1 0.16 7 100 0.57 NA 05/13/2003 5.5 3.3 2.2 1 A 9.4 64 0.41 NA 11/04/2003 27 8.1 6.9 < 0.050 13 54 < 0.10 NA 05/05/2004 3.0 7.4 < 1.1 0.24 9.8 140 < 0.10 NA 11/09/2004 3.7 6.7 > 23 0.79 6.8 120 < 0110 NA 05/17/2005 3.8 8.3 < 1.1 0.61 6A 88 < 0.10 NA 11/03/2005 7.1 11 < 1.1 0.95 8.4 100 < 0.10 NA 05/24/2006 15 10* < 1.1 0.39 8.1 130 < 0.10 NA 11/09/2006 4.7 12 < 1.1 0.97 7.7 96 < 0.10 NA 05/18/2007 5.0 15 < 1.0 3.0 13 290 < 0.10 NA 11/13/2007 8.3 19.6 < 1.1 0.97 1 26.6 154 < 0.10 NA 05/27/2008 . 12.4 20.0 < 1.1 0.55 35.8 184 < 0.10 NA 11/18/2008 14.4 17.2 2.2 < 0.10 21.5 118 < 0.10 NA 05/28/2009 6.2 1 24.9 240 0.74 24.9 192 < 0.10 NA 11/05/2009 10.8 15.4 50 0.54 18.4 114 < 0.10 NA 05/13/2010 10.8 14.7 < 2.0 1.1 24.1 106 < 0.10 NA 11/08/2010 23.2 24.3 200 < 0.10 26.3 173 < 0.10 NA 05/17/2011 10 16.9 10.0 12.2 . 16.1 232 < 0.10 NA 11/15/2011 8.0 26.6 < 2.0 3.7 20.2 232 < 0.10 NA 05/17/2012 14.4 24.8 12.0 8.0 22.9 356 < 0.10 NA 11/07/2012 24.8 26.3 < 100 1.9 28.3 324 < 0.10 NA 05/16/2013 15.8 8.8 10.9 6.8 13.4 248 < 0.10 NA 11/20/2013 21.0 15.4 < 1.0 1.3 24.3 342 < 0.10 NA 05/22/2014 17.6 14.5 < 10.0 0.61 17.8 352 - < 0.10 NA 11/18/2014 54.0 16A < 4.0 1.1 13.2 421 < 0.10 NA 05/13/2015 19.7 18.3 < 2.0 9.7 12.2 1 454 < 0.10 NA 11/04/2015 15.0 21.6 4.0 3.0 NA 396 < 0.10 0.82 , 05/04/2016 15.0 24.5 < 10.0 19.1 NA 398 < 0.10 0.62 6/9/2016 - Pace NA NA NA 26.3 NA NA NA NA 06/09/2016 - Prism NA NA NA _ 26.0 NA NA NA NA 11/09/2016 9.7 12.0 < 4.0 14.3 NA 333 < 0.10 0.26 05/02/2017 11.4 18.9 8.0 12.4 NA 497 <0.10 0.3 11/08/2017 8.1 9.7 <4.0 14.4 NA 390 <0.10 0.098 05/02/2018 10.8 12.9 <2.0 14.4 NA 548 <0.10 0.19 11/02/2018 9.5 8.0 19.0 6.8 "NA 351 <0.10 0.25 November 2018 Groundwater Sampling Event Page 6 of 7 Clement Pappas, Hendersonville, North Carolina December 2018 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry c V; 0 H N O .. N CL N. .. • 0 'O V•0 N_ R 4. 16 v .�+ E w • i .. F. .. W li r_ Z. N (CPUs per Sample'Name; Sample Date (mg%L) (mg/L) 100 nnL) ' (mg/L) (mg/L), (mg/L) (mg/L) ,(mg/L) Standards 10 250 1 10 250 500 1.5 NL 05/13/2015 2.2 12.4 < 2.0 1.0 5.5 94.0 < 0.10 NA 11/04/2015 3.8 2.6 < 1.0 < 0.020 NA 58.0 . < 0.10 0.45 05/04/2016 15.0 5.3 < 10.0 . 0.64 NA 51.0 < 0.10 0.095 11/09/2016 9.3 101 < 20.0 0.77 NA 69.0 < 0.10 0.76 MW-9 05/02/2017 7.6 3.8 <4.0 0.17 NA 92.0 <0.10 0.61 11/08/2017 7.0 8.9 10.0 0.95 NA 64.0 <0.10 1 0.53 05/02/2018 4.6 4.9 <2.0 0.58 NA , 69.0 <0.10 0.37 11/02/2018 8.4 5.8 <10.0 0.57 NA 88.0 <0.10 1 0.47 Notes: Standards are from North Carolina Administrative Code, Title 15A, Subchapter 2L (21- standards), April 1, 2013, except total organic carbon and fecal coliform. The total organic carbon standard is from Spray Irrigation Permit Number WQ0004797. The fecal coliform standard is the 2L standard for total coliform. 06-09-2016 - Pace/Prism: A resampling event was performed on June 9, 2016, to investigate nitrate exceedances in MW-7R and MW-8.One set of samples was analyzed by Pace Analytical Services, and a second set of samples was analyzed by Prism Laboratories. Sulfate was removed from the list of necessary analyses as of fall 2015 and replaced by total phosphorous. Bolded values indicate a concentration equal to or above the respective standard. < indicates that the constituent concentration was not detected above the laboratory reporting limit. CFU: coliform-forming unit mg/L• milligrams per liter mL: milliliter NA: not analyzed NL : No standard limit is set. November 2018 Groundwater Sampling Event Page 7 of 7 Clement Pappas, Hendersonville, North Carolina December 2018 1 Table 2 Current and Historical Groundwater Analytical Results for Volatile Organic Compounds ' t O C d C d O Y O N O > W O Sample Name Sample Date (pg/L)• (pg/L) (Ng/L) (Ng/L) (pg/L) (pg/L) 2L Standard 0.7 3 70 100 0.03 7 11/05/2002 < 0.50 0.83 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 0.94 0.62 < 0.50 < 0.50 < 0.50 MW 2 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 < 0.50 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW-211 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50. < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 < 0.50 < 0.50 . < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 . 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 6.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 < 0.50 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW 4 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2014 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/09/2016 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2017 < 0.50 < 0.50 < 0.50 < 0.50 < lb < 0.50 11/02/2018 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 November 2018 Groundwater Sampling Event Page 1 of 4 Clement Pappas, Hendersonville, North Carolina December 2018 Table 2 Current and Historical Groundwater Analytical Results for Volatile Organic Compounds . e s O S u r F aci a`i O O 2 F cry. a. y `o ;0 N U c o o r u 9 N ra I- d p L V 9 c a, CD O u Sample,Name Sample Date (pg/L) (Ng/L) (Ng/L) (Ng/L) (pg/L) (Ng/L) , '2L Standard 0.7 3 70 100 0.03 7 11/05/2002 4,700 980 820 13 24 1.9 11/04/2003 3,500 570 510 < 50 < 50 < 50 11/09/2004 580 62 38 < 10 < 10 < 10 11/03/2005 1,900 210 220 < 50 < 50 < 50 11/09/2006 350 74 67 0.61 1.2 < 0.50 05/18/2007 320 47 60 < 0.50 < 0.50 < 0.50 11/13/2007 1,150 217 209 2.0 3.4 1.0 11/18/2008 2,680 534 293 < 25.0 < 25.0 < 25.0 11/18/2008 11/05/2009 872 106 125 0.92 < 1.0 < 0.50 MW-5 11/08/2010 578 107 160 < 2.5 < 5.0 < 2.5 11/15/2011 1,450 124 141 < 2.5 < 5.0 < 2.5 11/07/2012 774 68.8 77.8 < 5.0 < 10.0 < 5.0 11/20/2013 332 65.1 80.5 < 1.2 < 2.5 < 1.2 11/18/2014 121 22.2 26A < 0.50 < 1.0 < 0.50 11/04/2015 26.1 2.6 2.9 < 0.50 < 1.0 < 0.50 11/09/2016 141.0 63.1 75.2 < 0.50 < 1.0 < 0.50 11/08/2017 35.9 4.6 4A < 0.50 < 1.0 < 0.50 11/02/2018 39.1 6.0 6.7 < 0.50 < 1.0 < 0.50 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 .11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 ' < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 3.0 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW-6 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2014 < 0.50 < 0.50 < 0.50 <,0.50 < 1.0 < 0.50 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/09/2016 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2017 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/02/2018 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 1 < 0.50 November 2018 Groundwater Sampling Event Page 2 of 4 Clement Pappas, Hendersonville, North Carolina December 2018 Table 2 Current and Historical Groundwater Analytical Results -for Volatile Organic Compounds c d O c o M O c a, i - O Sample Name Sample Date (pg/L) (Ng/L) (Ng/L) (pg/L) • (Ng/L) (pg/L) 2L Standard 0.7 3 70 700 0.03 7 11/05%2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0:50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 MW-7 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 0.79 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0' < 0.50 . 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2014 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 . 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW-7R 11/09/2016 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2017 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/02/2018 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 <-0.50 11/05/2002 < 0.50, < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 - < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.56 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.56 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 <•0.50 < 0.50 < 0.50 < 0.50 < 1.0 r0.50 11/18/2008 <,0.50 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW 8 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50. < 0.50 < 0.50 < 1.0 < 0.50 l 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2014 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/09/2016 < 0.50 < 0.50 - < 0.50 < 0.50 < 1.0 < 0.50 11/08/2017 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/02/2018 < 0.50 < 0.50 < 0.50 < 0.50 < 1.6 < 0.50 November 2018 Groundwater- Sampling Event Page 3 of 4 Clement Pappas, Hendersonville, North Carolina December 2018 Table 2 Current and Historical Groundwater Analytical Results for Volatile Organic Compounds c s d a w a o a ,e L C C r O r' O ' L v 'O W d . . O y. O u 'O N O t O t t O N N U u > Sample Name 1 Sample Date (pg/L) (pg/L) (pg/L) 1, (pg/L) (pg/L) (pg/L) 2L Standard 0.7 3 70 700 0.03 7 11/04/2015 < 0.50, < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/09/2016 < 0.50 < 0.50 <'0.50 < 0.50 < 1.0 < 0.50 MW-9 11/08/2017 < 0.50 . < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/02/2018 < 0:50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 Notes: This table only includes:compounds that were detected above the laboratory method detection limit since the sampling event in November 2002. The complete suite of compounds analyzed can be found in the individual an reports. Only samples collected during November sampling events were analyzed for volatile organic compounds, in accordance with Spray Irrigation Permit Number WQ0004797. 5/18/2007: In accordance with the Compliance Evaluation Inspection letter issued by Beverly Price of the North Carolina Department of Environment and Natural Resources, Division of Water Quality on April 27, 2007, volatile organic compounds and semivolatile organic compounds were sampled during the May 2007 sampling event Naphthalene was detected in MW-6'for the first time at a concentration of 2.2 pg/L (which is below the 2L standard of 6 pg/Q during the November 5, 2002 sampling event. 1,1,2-trichloroethane was detected in MW-5 for the first time on November 20, 2010, at a concentration of 8.0 pg/L, which exceeds the North Carolina Interim Maximum Allow able.Concentration of 0.6 pg/L. Chloroform was detected for the first time in MW-5 during the November 2011 sampling event at a concentration of 31.3 pg/L, which is below the 2L standard of 70 ug/L. Toluene was detected for the first time in MW-4 during the November 2015 sampling event at a concentration of 0.75 pg/L, which is below the 2L standard of 600 pg/L Bold values indicate an exceedance of the 2L standard. 2L Standard: North Carolina Administrative Code, Title 15A, Subchapter 2L, April 1, 2013 pg/L: micrograms per liter November 2018 Groundwater Sampling Event Page 4 of 4 . Clement Pappas, Hendersonville, North Carolina December 2018 Table 3 Current and Historical Groundwater Elevation Measurements Well Identification. Date Measured Depth to Groundwater ;(feet BTOC), Top-of=Casing Elevation ' (feet) Top -of -Casing Height Above'. Ground Surface (feet) Groundwater Elevation (feet) . MW-2R 05/24/2006 9.29 2063.00 3.77 2053.71 11/09/2006 6.49 2063.00 3.77 2056.51 05/18/2007 7.94 2063.00 3.77 2055.06 11/13/2007 8.46 2063.00 3.77 2054.54 05/27/2008 8.48 2063.00 3.77 2054.52 11/18/2008 8.50 2063.00 3.77 2054.50 05/28/2009 5.43 2063.00 3.77 2057.57 11/05/2009 6.72 2063.00 3.77 2056.28 05/13/2010 7.36 2063.00 3.77 2055.64 11/08/2010 9.60 2063.00 3.77 2053.40 05/17/2011 7.25 2063.00 3.77 2055.75 11/15/2011 7.86 2063.00 3.77 2055.14 05/17/2012 5.19 2063.00 3.77 2057.81 11/07/2012 7.74 2062.36 3.77 2054.62 05/16/2013 6.86 2062.36 3.77 2055.50 11/20/2013 7.92 2062.36 3.77 2054.44 05/22/2014 1 7.56 1 2062.36 1 3.77 1 2054.80 11/18/2014 8.89 1 2062.36 1 3.77 2053.47 Well abandoned, replaced by MW-9. J November 2018 Groundwater Sampling Event Page 1 of 7 Clement Pappas, Hendersonville, North Carolina December 2018 Table 3 Current and Historical Groundwater Elevation Measurements Well Identification Date Measured Depth to Groundwater (feet BTOC) Top -of -Casing Elevation (feet) Top -of -Casing Height Above Ground Surface (feet) Groundwater Elevation (feet) MW-4 05/15/2002 9.32 2064.60 2.43 2055.28 11/05/2002 9.49 2064.60 2.43 2055.11 05/13/2003 8.20 2064.60 2.43 2056.40 11/04/2003 9.23 2064.60 2.43 2055.37 05/05/2004 9.35 2064.60 2.43 2055.25 11/09/2004 8.61 2064.60 2.43 2055.99 05/17/2005 6.19 2064.60 2.43 2058.41 11/03/2005 9.57 2064.60 2.43 2055.03 05/24/2006 9.60 2064.60 2.43 2055.00 11/09/2006 8.41 2064.60 2.43 2056.19 05/18/2007 9.42 2064.60 2.43 2055.18 11/13/2007 9.89 2064.60 2.43 2054.71 05/27/2008 9.78 2064.60 2.43 2054.82 11/18/2008 9.76 2064.60 2.43 2054.84 05/28/2009 7.16 2064.60 2.43 2057.44 11/05/2009 8.53 2064.60 2.43. 2056.07 05/13/2010 8.83 2064.60 2.43 2055.77 11/08/2010 9.30 2064.60 2.43 2055.30 05/17/2011 8.97 2064.60 2.43 2055.63 11/15/2011 9.48 2064.60 2.43 2055.12 05/17/2012 7.62 2064.60 2.43 2056.98 11/07/2012 9.32 2063.77 2.43 2054A5 05/16/2013 7.93 2063.77 2.43 2055.84 11/20/2013 8.87 2063.77 2.43 2054.90 05/22/2014 8.70 2063.77 2.43 2055.07 11/18/2014 8.54 2063.77 2.43 2055.23 05/13/2015 9.18 2063.77 2.43 2054.59 11/4/2015 6.93 2063.77 2.43 2056.84 05/04/2016 8.43 2063.77 2.43 2055.34 11/09/2016 9.63 2063.77 2.43 2054.14 05/02/2017 7.82 2063.77 2.43 2055.95 11/08/2017 7.88 2063.77 2.43 2055.89 05/02/2018 1 8.44 1 2063.77 2.43 2055.33 11/02/2018 1 8.00 1 2063.77 2.43 2055.77 November 2018 Groundwater Sampling Event Page 2 of 7 Clement Pappas, Hendersonville, North Carolina December 2018 Table 3 Current and Historical Groundwater Elevation Measurements Well Identification Date Measured Depth to Groundwater (feet BTOC) Top -of -Casing Elevation (feet) Top -of -Casing . Height Above Ground Surface (feet) Ground'Water Elevation (feet) MW-5 05/15/2002 8.31 2086.40 3.00 2078.09 11/05/2002 10.20 2086.40 3.00 2076.20 05/13/2003 8.29 2086.40 3.00 2078.11 11 /04/2003 9.92 2086.40 3.00 . 2076.48 05/05/2004 8.75 2086.40 3.00 2077.65 11/09/2004 8.50 2086.40 3.00 2077.90 05/17/2005 8.87 2086.40 3.00 2077.53 11/03/2005 9.70 2086.40 3.00 2076.70 05/24/2006 9.34 2086.40 3.00 2077.06 11/09/2006 8.39 2086.40 3.00 2078.01 05/18/2007 9.16 2086.40 3.00 2077.24 11/13/2007 11.00 2086.40 3.00 2075.40 05/27/2008 9.84 2086.40 3.00 2076.56 11/18/2008 11.59 2086.40 3.00 2074.81 05/28/2009 7.95 2086.40 3.00 2078.45 11/05/2009 8.63 2086.40 3.00 2077.77 05/13/2010 8.87 2086.40 3.00 2077.53 11 /08/2010 10.24 2086.40 3.00 2076.16 05/17/2011 8.99 2086.40 3.00 2077.41 11/15/2011 10.58 2086.40 3.00 2075.82 05/17/2012 8.73 2086.40 3.00 2077.67 11/07/2012 9.65 2085.60 3.00 2075.95 05/16/2013 8.14 2085.60 3.00 2077A6 11/20/2013 9.33 2085.60 3.00 2076.27 05/22/2014 8.57 2085.60 3.00 2077.03 11/18/2014 9.04 2085.60 3.00 2076.56 05/13/2015 8.92 2085.60 3.00 2076.68 11/4/2015 8.12 2085.60 3.00 2077.48 05/04/2016 8.54 2085.60 3.00 2077.06 11/09/2016 11.25 2085.60 3.00 2074.35 05/02/2017 8.63 2085.60 3.00 2076.97 11/08/2017 8.23 2085.60 3.00 2077.37 05/02/2018 1 8.47 2085.60 3.00 2077.13 11/02/2018 1 8.23 2085.60 3.00 2077.37 November 2018 Groundwater Sampling Event Page 3 of 7 Clement Pappas, Hendersonville, North Carolina December 2018 Table 3 Current and Historical Groundwater Elevation Measurements Well Identification Date Measured Depth to Groundwater (feet BTOC) Top -of -Casing Elevation (feet) Top -of -Casing, Height Above Ground Surface (feet) Groundwater Elevation (feet) MW=6 05/15/2002 6.20 2061.90 3.00 2055.70 11/05/2002 6.15 2061.90 3.00 2055.75 05/13/2003 5.43 2061.90 3.00 2056.47 11/04/2003 5.85 2061.90 3.00 2056.05 05/05/2004 6.00 2061.90 3.00 2055.90 11/09/2004 5.32 2061.90 3.00. 2056.58 05/17/2005 6.10 2061.90 3.00 2055.80 11/03/2005 6.01 2061.90 3.00 2055.89 05/24/2006 6.48 2061.90 3.00 2055.42 11/09/2006 5.71 2061.90 3.00 2056.19 05/18/2007 6.50 2061.90 3.00 2055.40 . 11/13/2007 7.85 2061.90 3.00 2054.05 05/27/2008 7.01 2061.90 3.00 2054.89 11/18/2008 7.38 2061.90 3.00 2054.52 05/28/2009 5.63 2061.90 3.00 2056.27 11/05/2009 5.74 2061.90 3.00 2056.16 05/13/2010 5.90 2061.90 3.00 2056.00 11/08/2010 5.99 2061.90 3.00 -2055.91 05/17/2011 5.85 2061.90 3.00 2056.05 11/15/2011 6.14 2061.90 3.00 2055.76 05/17/2012 5.87 2061.90 3.00 2056.03 11/07/2012 . 6.05 2061.17 3.00 2055.12 05/16/2013 5.84 2061.17 3.00 2055.33 11/20/2013 5.96 2061.17 3.00 2055.21 05/22/2014 5.96 2061.17 3.00' 2055.21 11/18/2014 5.82, 2061.17 3.00 2055.35 05/13/2015 6.05 2061.17 3.00 2055.12 11/4/2015 5.18 2061.17 3.00 2055.99 05/04/2016 5.59 2061.17 3.00 2055.58 11/09/2016 7.42 2061.17 3.00 2053.75 05/02/2017 5.31 2061.17 3.00 2055.86 11/08/2017 4.80 2061.17 3.00 2056.37 05/02/2018 5.36 2061.17 1 3.00 1 2055.81 11/02/2018 5.03 2061.17 1 3.00 1 2056.14 November 2018 Groundwater Sampling Event Page 4 of 7 Clement Pappas, Hendersonville, North Carolina December 2018 B Table 3 Current and Historical Groundwater Elevation. Measurements Well Identification Date Measured Depth to Groundwater " (feet BTOC) Top -of -Casing Elevation: _(feet) Top -of -Casing . Height Above Ground Surface (feet) Groundwater Elevation (feet) MW-7 05/15/2002 10.90 2062.70 3.00 2051.80 11/05/2002 11.35 2062.70 3.00 2051.35 05/13/2003 8.87 2062.70 3.00 2053.83 11/04/2003 10.78 2062.70 3.00 2051.92 05/05/2004 10.80 2062.70 3.00 2051.90 11/09/2004 9.70 2062.70 3.00 2053.00 05/17/2005 10.60 2062.70 3.00 2052.10 11/03/2005 11;09 2062.70 3.00 2051.61 05/24/2006 11.27 2062.70 3.00 2051 A3 11/09/W06 9.71 - 2062.70 3.00 2052.99 05/18/2007 11.02 2062.70 3.00 2051.68 11/13/2007 11.76 2062.70 3.00 2050.94 05/27/2008. .11.55 2062.70 3.00 2051.15 11/18/2008 11.63 2062.70 3.00 2051.07 05/28/2009 8.21 2062.70 3.00 2054.49 11/05/2009 9.89 2062.70 3.00 2052.81 05/13/2010 10.44 2062.70 _ 3.00. 2052.26 11/08/2010 11.12 2062.70 3.00 " 2051.58 05/17/2011 10.80 2062.70 3.00 - 2051.90 11/15/2011 11.43 2062.70 3.00 2051.27 05/17/2012 8.91 2062.70 3.00 2053.79 MW-7R 11/07/2012 12.02 2062.86 3.00. 2050.84 05/16/2013 10.29 2062.86 3.00 2052.57 11/20/2013 11.69 2062.86 3.00 2051.17 05/22/2014 11.38 2062.86 3.00 2051.48 11/18/2014 1125 2062.86 3.00 2051.61 .05/13/2015 11.94 2062.86 3.00 2050.92 11/4/2015 8.43 2062.86 3.00 2054.43 05/04/2016 11.08. 2062.86 3.00 2051.78 11/09/2016 12.63 2062.86 3.00 2050.23 05/02/2017 10.13 2062.86 3.00 2052.73 11/08/2017 10.34 2062.86 3.Od 2052.52 05/02/2018 10.99 2062.86 3.00 2051.87 11/02/2018 10.33 2062.86 3.00 2052.53 November 2018 Groundwater Sampling Event Clement Pappas, Hendersonville, North Carolina i d. Page 5 of 7 December 2018 i Table 3 Current and Historical Groundwater Elevation Measurements Well Identification Date Measured Depth to Groundwater (feet BTO'C) Top of -Casing Elevation (feet) Top -of -Casing. Height Above Ground Surface (feet) Groundwater Elevation (feet) . MW-8 05/15/2002 10.25 2061.40 3.00 2051.15 11/05/2002 10.35 2061.40 3.00 2051.05 05/13/2003 8.16 2061.40 3.00 2053.24 11/04/2003 10.23 2061.40 3.00 2051.17 05/05/2004 10.30 2061.40 3.00 2051.10. 11/09/2004 8.90 2061.40 3.00 2052.50 05/17/2005 10.08 2061.40 3.00 2051.32 11/03/2005 10.61 2061.40 3.00 2050.79 05/24/2006 10.60 2061.40 3.00 2050.80 11/09/2006 9.40 2061.40 3.00 2052.00 05/18/2007 10.31 2061.40 3.00 2051.09 11/13/2007 11.09 2061.40 3.00 2050.31 05/27/2008 10.83 2061.40 3.00 2050.57 11/18/2008 11.11 2061AO 3.00 2050.29 05/28/2009 8.25 2061.40 3.00 2053.15 11/05/2009 9.22 2061.40` 3.00 2052.18 05/13/2010 9.88 2061.40 3.00 2051.52 11/08/2010 10.38 2061.40 3.00 2051.02 05/17/2011 10.27 2061.40 3.00 2051.13 11/15/2011 10.87 2061.40 3.00 2050.53 05/17/2012 8.03 2061.40 3.00 2053.37 11/07/2012 10.45 2060.80 3.00 2050.35 05/16/2013 8:58 2060.80 3.00 2052.22 11/20/2013 10.34 2060.80 3.00 2050.46 05/22/2014 9.79 2060.80 3.00 2051.01 11/18/2014 10.03 2060.80 3.00 2050.77 05/13/2015 10.34 2060.80 3.00 2050.46 11/4/2015 7.21 2060.80 3.00 2053.59 05/04/2016 9.84 2060.80 3.00 2050.96 11/09/2016 11.16 2060.80 3.00 2049.64 05/02/2017 8.48 2060.80 3.00 2052.32 11/08/2017 8.73 2060.80 3.00 2052.07 05/02/2018 9.39 2060.80 1 3.00 2051.41 11/02/2018 8.85 2060.80 1 3.00 2051.95 November 2018 Groundwater Sampling Event Page 6 of 7 Clement Pappas, Hendersonville, North Carolina December 2018 Table 3 Current and Historical Groundwater Elevation Measurements Well Identification Date Measured Depth.to Groundwater (feet BTOC) Top -of -Casing Elevation (feet) Top -of -Casing ': , Height Above Ground Surface (feet) Groundwater Elevation (feet) MW-9 05/13/2015 6.03 2060.23 1.44 2054.20. 11/4/2015 2.89 2060.23 1.44 2057.34 05/04/2016 5.53 2060.23 1.44 2054.70 11/09/2016 6.55 2060.23 1.44 2053.68 05/02/2017 3.99 2060.23 1.44 2056.24 11/08/2017 3.60 2060.23 1.44 2056.63 05/02/2018 5.07 2060.23 1.44 2055.16 11/02/2018 4.55 2060.23 1.44 2055.68 Notes: Top -of -casing elevations: MW-5 through MW-8 top -of -casing elevations are based upon a surrey by Hill and Associates Surveyors, dated January 10, 2002 through May 2012. MW-2R and MW-4 top -of -casing elevations are based upon differential level measurements made by Altamont Environmental, Inc., on June 26, 2006 through May 2012. The top -of -casing elevations for the monitoring wells were resurveyed on November 21, 2012, by Wes Cole Land Surveying. The top -of -casing elevations for MW-9 were surveyed on May 29, 2015, by Wes Cole Land Surveying. Groundwater elevations are top of casing minus depth to groundwater. BTOC: feet below top of well casing November 2018 Groundwater Sampling Event Page 7 of 7 Clement Pappas, Hendersonville, North Carolina December 2018 Table 4 Current and Historical Surface Water Analytical Results 0 u o o , •O`1 . . o a O 'o ;; C c H U U. Z F Q !- (CFUs per Sample Name. Sample Date (mg/L) . (mg/L) 100 mL)• (mg/L) . (mg/Q. (mg/L) {mg/L) Standards NL 230 < 200 NL NL NL NL 6/9/2016 (Prism) NA NA NA 0.74 NA NA NA 6/9/2016 (Pace) NA NA NA 0.85 NA NA NA 5/2/2017 2.7 4.7 580 0.64 64.0 <0.10 <0.050 SW-1 (Upstream) 11/8/2017 2.5 5.1 530 0.66 44.0 <0.10 0.091 5/2/2018 1.5 4.8 53.0 0.74 54.0 <0.10 0.0441 11/2/2018 2.9 5.1 780 0.72 54.0 <0.10 0.077 6/9/2016 (Prism) NA NA NA 0.78 NA NA NA 6/9/2016. (Pace) NA NA NA 0.86 NA NA NA 5/2/2017 2.7 4.7 935 0.63 41.0 <0.10 0.052 SW-2 (Downstream) 11/8/2017 2.8 4.8 860 0.61 54.0 <0.10 0.094 5/2/2018 1.4 4A 118 0.72 51.0 0.052 J 0.045 J 11 /2/2018 2.9 4.6 ' 940 0.75 53.0 0.099 J 0.076 Notes: 6/9/2016 (Prism/Pace): A sampling event was performed on June 9, 2016.One set of samples was analyzed by Prism Laboratories, and a second set of samples was analyzed by Pace Analytical Services. Standards are from North Carolina Administrative Code, Title 15A, Subchapter 2B. Bolded values indicate a concentration equal to or above the respective standard. < indicates that the constituent concentration was not detected above the laboratory reporting limit CFU: coliform-forming unit 1: The concentration is above the adjusted method detection limit and below the adjusted reporting limit, and is therefore considered an estimate. mg/L: milligrams per liter mL: milliliters NA: not analyzed NL: No standard limit is set. November 2018 Groundwater Sampling lEvent Page 1 of 1 Clement Pappas, Hendersonville, North Carolina December 2018 NAI f & EN 2trkeley ism Ba 11 Park.,, 1h• L 0' N LEGEND:- SOURCES: Basemap: USGS Topographic Maps, Fruitland and Hendersonville 0 2,000 Ej Site Location Quadrangles, 1997 Parcel: Henderson County GIS 2016 Feet Publish Date: 2018/05/30,11:36 AM I User: ecrute Filepath: P:',Clenient Pappas\Figures\GIS\Figure I - Site Location Map.nlxd ANCHOR Figure 1 Site Location Map November 2018 Groundwater Sampling Event Clement Pappas, Hendersonville North Carolina Pace Analytical Services, LLC • aceAnal rcal ®. Riverside Dr., , As2225 heville, NC 28804 . wwwpacelabs.com (828)25477176 CERTIFICATIONS Project: Lassonde. Pappas 18148201.01 -Pace Project No.:. 92405811 . Charlotte Certification Ms 9800 Kincey Ave. Ste.100, Huntersville; NC 28078 South Carolina Certification #: 9900.6001 _ Louisiana/NELAP Certification #.LA170028 Florida/NELAP Certification #: E87627 . North Carolina Drinking Water Certification M 37706. Kentucky.UST Certification M 84 North Carolina Field Services Certification M 5342 VirginiaNELAP.Certification M 46022T North Carolina .Wastewater Certification M 12 Asheville Certification IDs .2225 Riverside Drive; Asheville,.NC 28804. _' North Carolina Wastewater Certification M 40 Florida/NELAP Certification #: E87648 • . South Carolina.Certification #: 99030001 Massachusetts' Certification #`•M-NC030 . • VirginiaNELAF Certification #' 460222 North Carolina,Drinking.Water Certification M 37712 CD . O f9 t•. I. T171, .. oC!, 0. -REPORT-OF LABORATORY ANALYSIS This: report shall not be reproduced, except in full, without'the written consent of Pace Analytical Services, LLC. - Page„2 of _44 Pace Analytical Services, LLC �+Q QQ►7 ® .. 2228 Riverside Dr._ CZ��rinCZl��iiC3l Asheville, NC 28804 wmpacelabs.com (828)25477176 SAMPLE SUMMARY Project: Lassondle Pappas 18148201.01 , Pace Project No.: .92405811 Lab ID _ Sample ID.. Matrix 'Date Collected _ Date Received 92405811001 .. MW-4 . Water 11/02/18 12:13' 11/02/18 14:33 - 92405811002 MW-5 Water 11/02/18-10:19 11/02/18 14:33 -92405811003 . = 'MW-6 Water .. - 11/02/18 10:54. 11/02/18 14:33 . 92405811004. MW-7R_ : Water 11/02/18 09:37- 11/02/18 14:33 92405811005 - MW-8 Water 11/02/18 08:32 11/02/18 14:33 92405811006 `. MW-9 : Water 11/02/18 11:33 11%02/18 14:33 92405811007 - SW-1- . Water 11/02/18 12:28 11/02/18 14:33 92405811008 -- SW-2: Water . 11/02/18 08.57 11/62/18-14:33 92405811009 - Trip Blank. Water 11/02/18 00:00 11/02/18 14:33 REPORT ,OF LABORATORY ANALYSIS .. . This report shall not be reproduced, except in full, without written consent of Pace Analytical Services, LLC. _ Page of 44 - . Pace Arialytical,Service% LLC aceQ ►7 Ana�yiical 2225 Riverside Dn. .. • Asheville, NC 28804 www.pacelabs.com (828)254-M6 ;. SAMPLE ANALYTE COUNT' ' Project: - Lassonde Pappas 18148201.01 Pace. Project No.: '.92405811 Analytes .. Lab;ID Sample ID Method Analysts Reported . '.Laboratory 92405811001 MW-4. SM 6200E GAW 63 PASI-C SM 2540C-2011. CRV 1 PASI-A SM 9222D-2006 ECH _ 1 .. PASI-A EPA 350.1 Rev2:0 1993 NAL I'. PASI-A . EPA353.2 Rev2.0.1993 MFO 1 PASI-A EPA:365.1 Rev 2.0 1993: MDW.. 1 PASI-A SM 4500-CI-E-201;1 MVC 1 PASI-A . SM - 5310B 2011 ECH 1 - .. PAST A 92405811002 MW-S '-" SM 6200B GAW 63 . PASI-C " SM 2540C-2011 .CRV 1 PASI-A SM 9222D 2006 ECH 1 PASI A EPA350.1 Rev201993 NAL 1 'PASI-A . EPA 353:2 Rev 2.0:4993 MFO . 1 PASI_ A EPA 365.1 Rev 2:01993 MDW 1, . PASI-A.. - SM 4500 CIE 2011 MVC 1 _ .PASI A SM.53.1OB-2011 ECH.. 1 PASI-A 92405811003 : MW-6 .. SM 62006 GAW 63 PASI C . SM 2540G 2011..CRV 1 PASI A :. SM`9222D_ 2006;. ECH 1. PASI-A . EPA 350.1 Rev 2.0.1693 NAL 1 PASI-A EPA 353.2.Rev 2.0 1993: MFO.: 1 PASI-A' . EPA,365.1' Rev 2.0 1993. MDW ` 1 PASkA , - SM 4500=CI-E-2011 :. MVC 1 PASI-A SM 53106.2011 ; .. ECH 1 PASI- A . 92405811004 " MW-ZR .SM 6200B GAW .63 PASI-C SM 2540C- 2011 GRV:. T PASI_ A'; .. . SM 9222D 2006. ECH 1 PASkA EPA 350:1 Rev 2:0.1993 NAL 1 PASI-A EPA 353.2 Rev 2:0 1993 MFO' 1 PASI-A . . - EPA 365.1" Rev 2.0.1993 MDW 1 PASkA SM 4500-CI-E-2011 MVC: 1 PASI-A . . SM 531OB-2011 , ECH 1 PASkA 92405811005 MW-8 SM 62006 GAW 63 PASI-C SM2540C.- 2011 , . CRV 1 PAS] -A.. SM 9222D-2006 ECH 1 PASI=A • ' EPA:350.1 Rev 2.0 1993: NAL 1 ', PASI-A . . EPA.353.2 Rev 2.0 1993 MFO 1 PASI-A . REPORT OF LABORATORY ANALYSIS" . This report shall not be reproduced; except in full, without the written consent -of Pace Analytical Services, LLC. Page,4 of;44 ./+ Pace Analytical,Services; LLC . ®.. +.Q /�L7. ��rt+/'l/ I�I�Vf�l 2225 Riverside Dr. Asheville, NC 28804 www.pacelabs.com (828)254-7176 SAMPLE ANALYTE COUNT Project: Lassonde Pappas- 18148201.01 'Pace Project No.: ..92405811 Analytes Lab; ID Sample ID Method Analysts Reported :.Laboratory EPA:365.1 Rev 2.0 1993. MDW 1 " PASI-A SM 4500-CI-E=201.1 MVC " 1 PASI-A . SM 531OB-2011 ECH 1 PASI-A 92405811006 . MW-9 SM 6200E GAW 63. PASI-C . SM 2540C-2011 CRV 1 PASI-A SM 9222D=2006 ECH 1--- . PASI-A . . EPA 350.1 Rev.2.01993 NAL 1" PASI-A EPA 353.2 Rev 2.0,1993 MFO : 1 PASI-A EPA365.1 Re 2:01993 v- MDW 1 - PASI A . SM 4500-CI-E-2011 MVC 1 PASI=A SM 53.106-2011 ECH. 1 PASI-A 92405811007 - SW-1 SM 6200B GAW 63 PASI-C SM 2540C-2011 CRV 1 PASI-A J - SM'9222D 2006 ECH 1 - PASI A EPA 350.1 Rev 2.0 1993 NAL 1 PASI-A EPA-353.2.Rev 2.0 1993 _ MFO . 1' PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A . SM 4500-0-E-2011 `MVC . 1 ' PASI-A SM 531 OB-2011 :. ECH 1 PASI-A .. 92405811008 SW-2". SM 6200B GAW - 63 PASTC- SM 2540C 2011 CRV 1 A . PASI- . SM 9222D-2006. ECH 1 PASkA . " EPA 350.1 Rev 2.0 1993 NAL 1 PASI-A'. . :. EPA 353.2 R .2.0 1993 ev, MFO 1. - PASI A EPA 365.1 Rev 2.0. 1993' MDW 1" PASkA SM 4500-CI-E-2011 MVC: 1 PAS] -A , SM 5310B-2011 .- ECH. 1 PASI=A 92405811009 Trip Blank , SM 6200B ". GAW. 63' PASI-C REPORT OF LABORATORY ANALYSIS This; report shall not be reproduced, except in full, without'the written consentof. Pace Analytical Services, LLC. '. Page 5 of 44 I Pace Analytical Services, LLC 2225 Riverside .Asheville, NC 2880404 www.pacelabs.com. (828)25477176 ANALYTICAL RESULTS " Project: Lassonde Pappas 18148201.01 Pace Project No.:" .92405811 Sample Lab ID:.92405811001 Collected: 11/02/18 12:13 Received: 11/02/18 14:33 Matrix: Water Parameters' : Results Units .. PQL MDL : DF . Prepared Analyzed- CAS No... Qual . -6260B MSV; . Analytical Method:SM 62006 Benzene ND ug/L 0.50 0.25 1 . .11/09/1813:02 71743-2 Bromobenzene ND ug/L', 0.50 0.25 1; 11/09/18 13:02 108-86-1 _ Bromochloromethane ND . ug/L 0:50. 0.25 .. 1 11/09/18 13:02 .74-97-5 . Bromodichloromethane ND ug/L . _ 0.50 0.25 1 11/09/18 13:02: 75=27-4 Bromoform ND .. - ug/L: .0.60' 0.25 1. 11/09/18 13:02 .75-25-2 Bromomethane ND ug/L 5.0 2.5 _ 1. 11/09/18 13:02' 74783-9. n-Butylbenzene ND ug/L 0.50 0.25 1. 11/09/18 13:02 104-51-8 sec-Butylbenzene ND ug/L .. 0.50 0;25 : 1 11/09/18 13:02. 135-98-8. tart-6utylbenzene ND- ug/L '. ..0.50;. 0;25 .. 1 "1 •11/09/18 13:02 ..98-06=6 Carbon tetrachloride ND ug/L 0.50. _' 0.25 11/09/18 13:02 56-23-5 Chlorobenzene ' ND ug/L 0.50 0.25. 1 . 11/09/18 13:02 108-90-7 Chloroethane ND ug/L 1.0 0.50. 1- 11/09/18 13:02 75-00-3 Chloroform ND ug/L 0.50 0.25 1 11/09/18 13:02 .67-66-3 Chloromethane . ND.' ug/L -1.0 . 0.50 '. :1 . , 1.1/09/18 13:02. 74=87-3 -2=Chlorotoiuene ND ug/L. 0.50 0.25.' 1 . .11/09/18 13:02 .05-49-8 . 4-Chlorotoluene ND ug/L 0.50 0.25 . 1, 11/09/18 13:02 "106-43-4 1,2-Dibromo73-chl6ropropane ND ug/L. 1..0 0.50 1. .11/09/18 13:02 96-12-8. Dibromochloromethane ND ug/L- 0.50- 0.25 1 11/09/18 13:02 124-48-1 1,2-Dibromoethane(EDB) ND ug/L .0.50..'. 0.25 1 11/09/1818:02..106-93-4 Dibmmomethane ND ug/L 0.60 0.25 1 11/09/18 13:02 74-95-3 1;2-Dichlor6benzene ND ug/L: .0.50... 0.25. -..1 . .11/09/1813:02 95-50.4 . 1,3-Dichlorobenzene NO ug/L 0.50 0.25_ 1; 11/09/18 13:02 541-73-1 1,4-Dichlorobenzene. ND . ug/L 0.50 0.25 .. 1 11/09/18 13:02..106-46-7 Dichlorodifluoromethane ND ug/L 0.50 . 0.25 .1' 11/09118 13:02.' 75-71-8 1;1=Dichloroethane - ND .. ug/L • . 0.50 0.25 1. 11/09%1a 13:02 .75.34-3 1;2=Dichloroethane ND ug/L 0.50 0.25 1: 11/09/1813:02 107-06-2 1,1-Dichloroethene.'. ND ug/L.' 0..50 0.25 1. 11/09/1813:02 75735-4. cis-1,2-Dichloroethene. NO ug/L .. 0.50 .0.25-. 1 11/09/18 13:02. 156-59-2 .. trans--1,2-Dichloroethe ne ND ug/L .0.50::. 02 11/09/1613:02.156-6075 1,27Dichloropropane - . ND ug/L 0.50.. 0.2 1 11/09/18 13:02 '78-87-5 1,3-Dichloropropane ND uglL. 0.50 0.25 � . .11/09/18 13:02- 142-28-9 2,2-Di6hloropropane - ND ug/L 0.50 0.25 11/09/18 13:02 594-20-7 1.,1-Dichloro ro ene ND u /L 0:50 0.25 �� c0 11/09/18 13:02. .563-58-6 cis-1;3-Dichloropropane ND uglL 0.50 0.25 -, 1?.. z = .11/09/18 13:02 10061-01-5.. trans-1�,3=Dichloropropene ND . ugll 0.50 0:25 l'.:..1 .11/09%18. T3:02 .10061-02-6 Diisopropyl ether ND ug/L 0.50_ 0.25 . j `1a ) 11/09/18 13:02 108-20-3 _ Ethylb;enzene ND uglL. 0.50 0.25 =;10 <:11/09/18 13:02 100 41=4 Hexachloro-1,3-butadiene. : ND ug/L 2:0 1.0 .'=.;1' 11109/1813:02 • 87-68-3' Isopropylbenzene (Cumene) ND ug/L 0.50 . 0.25 l ;'� c o N11/09/18 13:02 . 98-82=8 Methylene Chloride ND ug/L _ 2.0 1.0 j 1 11/09/18 13:02 75-09-2 Methyl-tert-butyl ether ND ug/L: 0.50 '. 0.25 .0 11/09/18 13:02 1634-04-4 Naphthalene. ND ug/L 2.0 1.0 1.0 11109/1813:02 91=20-3 n-Propylbenzene ND ug/L 0.50. 0.25 1'_---11/09/18 13:02..103 65 1_ Styrene: ND.' ug/L 0.50 .0.25 '~ 11/09/18 13:02. 100-42-5 1;1;1,2-Tetrachloroethane ND ug/L- --0.50 0.25 1 11109118-13:02 ' 630-20-6. 1,1,2,2-Tetrachloroethane. _ ND' ug/L_ 0.50 0.25 1.. _ 11./0.9/1813:02 79-34-5. REPORT OF LABORATORY ANALYSIS This report: hall not be.reproduced; except in full, Date: 11/09/201.8 04:27 PM without the written consentof Pace Analytical Services, LLC. Page 6 of 44 Pace Analytical Services; LLC , ® aceMalytical. 2225 Riverside Dr. Asheville, NC 28804 WgW.Pa-140 com (828)25477176 ANALYTICAL RESULTS. Project: Laswride, Pappas 18148201.01 Pace Project No:: 92405811 Sample: MW-4 Lab ID: 92405811001. Collected:: 11/02/18 '12:.13 . Received: 11/02/18 14:33 'Matrix: Water Parameters Results Units .. PQL MDL OF Prepared Analyzed : CAS No. - . Qual 6200B MSV Analytical Method: SM 62008 Tetrachloroethene; NO ug/L: 0.60 0.25 1 . 11/09/18 13:02 127-184: Toluene NO ug/L -0.50 0.25. _ 1. 11/09/18 13:02 108-88-3 - 1,2,3-Trichlorobbnzene NO ug/L 2.0 1.0 1 11/09/18 13:02 87-61-6', 1,2,4Trichlorobenzene. :- NO ug/L ". .2.0.. .1.0 "1' 11./09/18'13:02: 120-82-1 1,1JJdchloroethane- NID ug/L. 0.50 0.25 .1 11/09118.13:02 .71-55=6: 1;1,2-Trichloroethane NO ug/L 0.50 0.25 - 1. 11/09/18 13:02 79-00-5. Trichloroethene NO ug/L 0.50 0.25 1, 11/09/1813:02 79-01-6 Th6hlorofluoromethane NO. ug/L' 1:0 0:50 : 1 11 /09/18 13:02"75-69-4 1,2;3-Trichloropropane ;. NO . - ug/L - ' 0.50.. 0:25 .. 1 11/09/18.43:02 ..96-18=4 . 1,2,4-Trimethylbehzene. - NO. ug/L . ., .. 0.50 .. 0.25 1 - 11/09/18.13:02 95-63-6 1;3,5=Trimethylbenzene NO ug/L 0.50 0.25• 1 . .11/0911813:02 108-67=8 Vinyl -.chloride NO ug/L 1..0 0.50 1; 11/09/1.8 13:02 75=01-4 m&p:Xylerie ND ug/L 1.0. . 0.50 1 :-11/09/18 13:02. "179601-23-1 o-Xylene ND. ug/L 0.50 . 0.25 ;' .1 1.1/09/1813:02. 9547-6 Surrogates . 1,2=Dichloroethane-d4 (S) ' 95 % .707130 1 11%09/18 13:02 -17066-07-0 4-Bromofluorobenzene (S) .95 % 70-130 1- 11/09/18 13:02 . 460-00-4 - Toluene=d8 (S) .. . 104 P/6 - 70-130 .. � � � �1 � ' � �11/09/18 13:02. 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011' Total Dissolved Solids 137 mg/L: 25.0 25.0 1 . 11/03/18 14:42 MBIO 9222D: Fecal Coliform AVIL • Analytical.Method.:.SM 9222D-2006 'Preparation Method: SM 9222D-2006 Fecal Coliforms ND' CFU/100 mL 10.0 10.0 : 10 11/02/18 16:46 11/03/18 14 47_ 350.1 Ammonia Analytical Method:,EPA350.1 Rev.2.0 1903 Nitrogen, Ammonia .. NO mg/L .. ' 0.10 0.050 .1 11/08/18 12:10: 7664-41-7" . 353.2 Nitrogen, N021NO3 unpres; Analytical Method' EPA353.2 Rev.2.0 1993 Nitrogen; Nitrate ... 0.48, ". mg/L 0.020 ".: 0:010 1 " 11/03/18 00;15. 1.4797-55-8 365.1 Phosphorus, Total Analytical Method: EPA365.1 Rev2.0 1993 Preparation Method', EPA 368.1 Rev 2.0-1993 Phosphorus . , . ".. 0:070 mg/L. . 0.050 :.6:025 1.' 11'/05/18.20t45 11/06/1820:23 7723-14-0 .: 4500.Chloride Analytical Method: SM 4500-CI-E=2011 Chloride, .9.0, mg/L - 1.0. 0.50 :. 1 11/05/18 20:09:. 16887-00-6 - 5310B TOG AhalyticaLMethod: SM 53106-2011- " Total Organic Carbon . "• 3.6 mg/L 1.0 0.50 .1 • : 11/09/18.13:02: 7440-44-0 REPORT OF LABORATORY ANALYSIS.'.. This reportshall not be reproduced; except in full, Date: 11/09/201.8 04:27 PM without the written consent of Pace Analytical Services, LLC. Page-7 of 44 Pace Analytical Services, LLC ® acQ �1 / eAIIaIICaI 22 25 Riverside Dr. Asheville, NC 28804 .. " w m.pacela6s.com. (828)254-7176 ANALYTICAL RESULTS : Project: Lassonde Pappas 18148201.01 Pace Project No.: -.92405811 Sample:'.MW-5 Lab ID: 9240.5811002 Collected: -11/02/1810:19 Received:' 11/02/1814:33 Matrix: Water Parameters Results Units PQL ' MDL DF . Prepared Analyzed- CAS No. : Qual 6200B MSV" Analytical Method: SM 6200B " Benzene ND" ug/L .0.50 0.25 1 11/09/1813:34 71-43-2. Bromobenzene ND ug/L 0.50 0.25 1 .11/09/18 13:34 -108-86-1 Bromochloromethane -ND . ug/L 0:50 0.25 1 11/09/18 13:34. 74-97-5 Bromodichloromethane ND ug/L .. 0.50 .0.25 1 11/09/1813:34: 75-27-4 Brornoform ND . ug/L: 0.50 0.25 .1 . 11109/18 13:34 .75-25-2 Bromomethane ND ug/L 5.0 2.5 1 11109/1813:34 74,83-9 n-Butylbenzene ND ug/L; 0.50 0.25 1 11/09/18 13:34 104-51=8. sec-Butylbenzene NO " ug/L :. 0'.50 " " _ 0:25" . " 1 11/09/18.13:34: 135-98-8 tert-Butylbenzene ND.". ug/L --0.50.. 0:25 1 : 11/09/18.13:34.98-06=6 Carbon tetrachloride .. ND ug/L 0.50. 0.25 .1 11/09/18 13:34 '56-23-5 .. Chlorobenzene ND ug/L. M0 0.25. 1. 11/09/1813:34. 108-90-7. Chloroethane 'ND ug/L 1.0 0.50 _ 1 11/09/18 13:34 75=00-3 -Chloroform ND . ug/L 0:50:" 0.25 .. 1 11/09/1813:34..67-66-3 . Chlorornethane ND ug/L 1.0 0.50 .1 11/09/18 13:34', 74-87-3 " 2=Chlorotoluene ND ". ug/L 0.50 0.25 "..1 11109%18 13:3.4.05-49=8 4-Chlorotoluene . • ND ug/L 0.50 0.25 1 11/09/18 13:34 106-43 4. 1,2-Dibromo,3-chloropropane _ ND. ug/L:. :. 1.0 0.50 1. 11109/1813:34.. 96712-8. Dibromochloromethane NO ug/L 0'.50 0:25 1 11/09/18 13:34 124-48-1 1;2-Dibromoethane (EDB) ND.. ug/L .. 0.50; '. 0.25 • • 1 11/09/18 13:34 ..106-93-4 Dibromomethane ND ug/L 0.50. 0.25 1 11/09/18:13:34 74-95-3 :.1,2-Di6hlorobenzene ND ug/L: 0.50 :: 0.25 .1 . 11/09/18 13:34 95-504 . _ 1,3-Dichlorobenzene ND ug/L _ 0.50 0.25 1: 11/09/18 13:34 541-73-1 1.,4-Dichlorobenzene. - ND ug/L 0.50 .0.25 .. 1 11/09./18 13:34. .106-46-7 Dichlorodifluoromethane : ND ug/L .. 0.50 .. 0.25 -1 .' ." .. 11/09/18 13:34. 75-71-8 . 1;1=Dichlbroethane, ND ug/L- 0.50 0.25 1 " 11709/18,13:34 75-34-3 1;2-Di6hloroethane ND ug/L 0.50 0.25 _ " 1. 11/09/18 13:34 107-06-2" 1,1-Dichloroethene ND ug/L 0.50 0.25 1 . ' 11/09/18 13:34 75-35-4 cis-1,2-Dichloroethene. 6.7 ug/L 0.50 0:25 -1 li/619/18.13:34. 156759-2 .. trans=1,2-Dichloroethene ND. ug/L 0.50.'. 0:25 •1 11/09/18.13:34."156-60-5 1-,2-Dichloropropane ND ug/L . 0.50 . • 0.25 1 11/008.13:34 78-87-5 1,3-Dichloropropane ND ug/L: .0.50 0.25. -1 . 11/09/18 13:34* 142-2&9 2,2-D1chloropropane ND ug/L- _ 0.50 0:25 1: 11/09/1.81.3:34 594-20-7 1.,1-Dichloropropene . " ND ug/L' 0.50, 0.25'.. 1- 11/09/18 13:34..563-58-6' cis- 1,3-Dichloropropene ND ug/L 0.50 - .0.25 .1" 11/09/1813:34: 10061-01-5 trans- 1,3=Dichloropropene ND ug/L. 0.50 0.25 1 11/00118,13:34.10061-02-6. Diisopropyl ether . ND ug/L 0.50 0.25 1 11/09118-13:34 108-20-3 Ethylbenzene ND ug/L 0.50 ' _ 0.25 1.* 11/09/18 13:34 100-41=4 . Hexachl6ro=1,3-butadiene' ND ug/L 2.0 1.0 1 11/0.9/1813:34: 87-68-3 Isopropylbenzerie (Cumene) ND ug/L .. .0.50 0.25 1 11/09/18 13:34 ..98-82-8 Methylene.Chloride ND ug/L 2.0 . 1.0 .1 • ' 11109/18.13:34 -75-09-2 Methyl-tert-butyl ether _ ND' ug/L 0.50 0.25 . 1 . 11/09118 13:34 1634-04-4 Naphthalene. NO ug/L - 2.0 1.0 1 11/09/18 13:34 9.1-20-3 . n.Propylbenzene ND ug/L 0:50 .0.25 -1 11/09/18 13:34, 103-65-1 Styrene, ND• ug/L 0.50 . -,0.25 1 11/09/18 13:34 100-42-5 - 1,111,2-Tetrachloroethane ND ug/L. 0.50 0.25 1: 11/09/18.13:34.630-20-6 1,1,2,2-Tetrachloroethane. ND ug/L 0.50 0.25 1: 11/09/18 13:34, 79-34-5 REPORT OF LABORATORY ANALYSIS . This: report shall not be reproduced, except in full, Dater 11/09/2018 04:27 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 44 Pace Analytical Services, LLC ® - lane Analytical. .: 2225 Riverside, Dr. Asheville, NC 28804 wwwpacela6s.com (828)254-7176 ANALYTICAL RESULTS. Project: Lassonde Pappas 18148201.01. 'Face .Project No.:. .92405811 .. - Sample:.MW-5 Lab ID: 9240,5811062 Collected: 11/02/1810:19 Received: 11/02/1814:35. Matrix: Water Parameters Results Units PQL MDL DF . Prepared- Analyzed CAS No:.. Qual - 6200B MSV Analytical Method: SM 6200B :Tetrachloroethene; 39.1' ug/L' 0.50.1. 0.25. 1 . .11/09/18 13:34, 127-18-4 Toluene - NO ug/L 0.50 0.25 1 11/09/18 13:34 1.08-88-3 . 1.,2,3-Trichlorobenzene ND ug/L 2.0 1.0 1 11/09/18 13:34 .87-61-6 1,2.kTrichlorobenzen. ND ug/L 2.0 .. 1.0 1" . 11'/09/1813:34 120-82-1 1 ,Vrrichloroethane . ND ug/L. 0.50 0.25 1 . .11109/18 13:34 .71755-6 1;1,2-Trichloroethane ' ND ug/L 0.50 0:25 1: 11/09/18 13:34 79700-5. Trichloroethene 6.0 ug/L 0.50 0.25 1. .11/09/1813:34 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0:50 1 ' 11/09/18 13:34 75-69-4 1;2,3Jrichloropropane ND ug/L ;. 0.50 0:25 1 11/09/1843:34..96-18-4 4,2,4-Trimethylbenzene ND '. ug/L . ., . .0.50. 0.25 1 11/09/18 13:34- 95-6376 1,3,5-Trim ethyl benzene- ND ug/L. 0.50 ': 0.25 1. 11/09/1813:34 108-67-8. Vinyl'chloride ND . ug/L 1.0 0.50 1. 11/09/1813:34 75-01-4 m&p-Xylene ND . " ug/L" 1.0. 0.50 1 11/09/18 13:34. 179601-23-1 o-Xylene ND" ug/L 0.50 .. 0.25 "1- 11109/18 13:34. 95=47-6 Surrogates 1,2-DichloroethaneA4 (S) 94 % .707130 - .1 11/09/18 13:34 17060-07-0 4-Bromofluorobenzene (S) 94. % 70-130. 1. 11109/1.8 13:34 460-00-4 Toluene=d8 (S) 98 % 70-130 1 11/09/18 13:34'. 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 254OC-2011 Total Dissolved Solids 86.0 mg/L 25.0 ,',' 25.0. 1 . 11/06/18 19:23 MBIO 9222D: Fecal Coliform AVL Analytical -Method:.SM 9222D-2006 Preparation Method: SIN 9222D-2006 Fecal Coliforms ' ' . - ND CFU/100 mL 10.0 10.0 10 - 11/02/18 16:26 11/03/18 14:30 350.1 Ammonia Analytical Method: EPA 350.1 .Rev 2.0 1993 Nitrogen;Ammonia '. ND' mg/L 0.10 . 0.050 1 11108/1812:11:: 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method`. EPA 353.2 Rev 2.0 1993 Nitrogen, Nitrate _. ND. rrig(L. 0,020 , .. 0:010 1 11%03L18 0007, 1.4797-55-8 365:1 Phosphorus, .Total . Analytical Method:-EPA365.1 Rev 2.0 1993 Preparation,Method:• EPA 365:1 Rev 2.0 1993 Phosphorus 0.085 mg/L. . -0.050 .0.025 1. 11/05/18.20:45 . 11/06418 20:25 7723-14-0. 4500.Chloride Analytical Method:'SM 4500-CI-E-2011 Chloride. 23.9 .' mg/L 1.0 0.50 .-1 11/05/18 20:14: 16887-00-6 531013 TOC Analytical Method: SM 531 OB-2011 ' Total Organic Carbon 5.1 mg/L 1.0.. • 0.50 ..1 11/09/18.13:33 7440744-0 ' REPORT OF LABORATORY ANALYSIS . This report shall not be reproduced', except in full. Dater 11/69/2018 04:27 PM without the written consent of Pace Analytical Services, LLC. - Page,9 of 44 Pace Analytical.Service% LLC �+Q p / �+. ® weAnalyhcal 2225 Riverside Dr._ . Asheville, NC 28804 www.pacelab.i.com (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas 18148201.01 Pace Project No.:. 92405811 Sample:.MW-6 Lab ID: 9240,5811003 Collected:: 11/02/18 10:54 Received:.11/02/18 14:33.- Matrix: Water -Parameters Results Units .. PQL MDL : DF . Prepared -Analyzed CAS No. : Qua] 6200B MSV Analytical Method: SM. 62006 : - Benzene ND .' ug/L. 0.50 0.25 -1 11/09/18 12:46- 71-43-2 Bromobenzene ND ug/L 0.50 0.25 .1 .11/09/18 12:46 108-86-1 Bromochloromethane ND ug/L 0.50. 0.25 1 11/09/18 12:46 .74-97-5 BromodichloroMethane ND ug/L • . '0.50 0.25 1 - 11/09/18 12:46.. 75-274 Bromoform ND ug/L 0.50 0.25 1 11109/1812:46 .75-25-2 Bromomethane ND, ug/L 5.0 2.5 1 11/0911812:46 74-83-9 - n-Butylbenzene ND • ug%L 0..50 0.25 1. 11/09/18 12:46 104-51=8 . sec-Butylbenzene - NO ug/L .. 0.50 0.25 1 11/091/18 12:46. 135-98-8 test-Butylbenzene ND. ug/L 0.50 , . 0.25 1 11/09/18 42:46 ..98-06.=6 Carbon tetrachloride ND _ ug/L . 0:50 0.25 .1 11/09/18.12:46 56-2375 Chlorobenzene, :: ND ug/L: 0.50 0.25 1 . 11/09/18 12:46 108-90-7. Chloroethane ND ug/L 1.0 0.50- 1 11/09/18 12:46 75-00-3 Chloroform ND ug/L .. 0.50.' . 0.25 1 11/09/18 12:46..67-66-3 Chloromethane ND.' ug/L - 1.0 0.50 1 11/09/18 12:46 74=87-3 2-Chlorotoluene ND ug/L - 0.50 0:25 1 . 11/00/1a 12:46 '•05-49-8 4-Chlorotoluene ND ug/L 0.50 0.25 1: 11/09/1812:46 '106-43-4 1,2-Dibromo73-chl6ropropane ND ug/L, 1.0 0.50 1 11/09/1812:46.96712-8 Dibromochloromethane ND ug/L .. 0:50 0.25 1 11/09/18 12:46. 124-48-1 1,2-Dibromoethane (EDB) ND. ug/L ; 0.50.;. 0:25 " - 1 11/09/18.12:46 _106-93-4 .. Dibromomethane ND ug/L . ' .... 0-.50 0.25 1 11/09/18.12:46 74-95-3 1;2-Dichlorobenzene ND • . ug/L. 0.50 ''.. -0.25. '1 . 11/09/1812:46 95.50-1. . - 1,3-Dichlorobenzene - ND ug/L 0.50 - 0.25 . 1 ; 11/09/18 12:46 541-73-1 1,4-Dichlorobenzene. ND . ug/L 0.5G 0.25 .. 1 11I09/1812:46..106-46-7 Dichlorodifluoromethane : ND. ug/L _ " 0.50 ..- 0.25 ". .1 - .11/09/18.12:46.- 75=71-8 1,1-Dichloroethane ND ug/L. 0.50 •0.25 1. 11/09/1a 12:46 .75-34-3 1;2-Dichloroethane- ND ug/L '0.50 0.25 1_. 11/09/18 12:46 107-06-2 1,1-Dichloroethene ND ug/L 0.50 0.25 1. .11/09/18 12:46 75-35-4 cis- 1,2=Dichloroethene. ND ug/L' :. 0:50 0.25' . 1 - 11/09/18.12:46. 156-59-2 .. trans=1,27Dichlorroethene ND ug/L .'0.50. 0.25 ." 1 11/09/18,12:46 .156-60-5 1,27Dichlor6propane ND ug/L • .0150 0.25 .1 _ 11/09/18 12:46 78-87-5 1;37Dichlor6propane ND ug/L A.50 0.25 1. 11/0911812:46 142-28=9 2;27Dichloropropane, ND- ug/L:.. 0.50. 0.25, -1: '11/09/18 12:46 594-20-7 1,1-Dichloropropene ND ug/L 0.50 0:25 1 11)09/1812:46..563-58-6 6571,3-Dichloropropene ND.. ug/L 0.50 0.25 1 - • 11/09/18 12:46, 10061-01-5 . . trans-113-Dichloropropene " . , ND ug/L• 0.50 0.25 ..1- 11/09/18 12:46 10061-02-6 Diisopropyl ether . - ND ug/L 0.50 0.25 1: 11/09/18 12:46 108-20=3 Ethylloenzene ND ug/L.. 0.50 0.25 1 .11/09/18 12:46 100-41-4 Hexachloro-113-butadiene ND ug/L 2.0 1.0 1 11/09/18 12:46. 87-68-3 Isopropylbe'nzene (Cumene) ND ug/L b.50 0.25 1 11/09/18 12:46 . 98-82=8 Methylene Chloride ND ug/L 2.0 1..0 .1 11/00/18 12:46 75-09-2 Methyl tert butyfetffer ND ug/L: 0.50 _ 0.25 1 . .11/09118 12:46 1634-04-4 'Naphthalene, 'ND ug/L -2.0 1.0- .1 11/00/1812:46 9.1-20-3 n-Propylbenzene "" ND . ug/L 050 0.25 1 - 11/09/1812:46..103-65-1. Styrene; ND. ug/L '.. 0.50 . 0.25 1 .. 11/09/18 12:46 100-42-5 1,1,1,2-Tetrachl6roethane ND .. ug/L• 0.50 0:25 _1 . 11709%1812:46 630-20-6 1;1_,2,2-Tetrachloroethane . _ ND ug/L 0.50 -0.25 1. 11/09/18 12:46 79734-5 REPORT OF LABORATORY ANALYSIS This; report shall not be reproduced; except in full, Date: 11/09/2018 04:27 PM without the written consent of Pace Analytical Services, LLC. _ Page.10 of:44 Pace Analytical Services, LLC Q r1I2225 I� Riverside Dr. �All�l .IC0L' J' Asheville, NC 28804 ,�Ian www.pacelabs.com (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas 18148201.01 Pace Project No.: 9240581'1 • Sample: MW-6 Lab ID: 92405811063 Collected:: 11/02/18 '10:54. Received: 11/02/18 14:33 -Matrix: Water Parameters Results Units .. PQL MDL DF . Prepared Analyzed CAS No.. Qual 6200B MSV:. Analytical Method: SM 6200B - Tetrachloroethene ND ug/L. 0.50 0.25 1 11/09/18 12:46 127-18-4 Toluene ND ug/L 0.50 0.25 1: 11/09/18 12:46 1.08-88-3 1.,2,3-Tric6lorobenzene ND ug/L 2.0 1.0 1 11/091/18 12:46 .87-61-6 1,2,4Trichlorobenzene ND ug/L 2.0.. .1.0 1 11/09/1812:461. 120-82-1 :.1;1,1-Trichloroethane:. ND . ug/L. - .. 0.50 0.25 1. 11/0911812:46 .71-55-6 :• 1;1,2 Trichloroethane '_ ND' - ug/L "0.50 0.25 _ 1 : 11/09/18 12:46 79=00-5 Trichloroethene ND ug/L 0.50 0.25 1. 11/09/1812:46 79-01-6 . Trichlorofluoromethane • NO ug/L .. 1.0 .0:50 1 11/09/18.1-2:46, 75-69-4 1,2,3=Trichloropropane ND ug/L 0.50.'. 0:25 1 11/09/1912:46.96-18=4 1,2,4-Trimethylbenzene. ND Og/L . 0.50' 0.25 1 11/09/18 12:46 95-63-6 .1,3,5-Trimethylbenzene ND ug/L. 0.50 0.25 1 . 11/09/18 12:46 108-67=8' Vinyl chloride ND ug/L' 1.0 0.50 1 _ 11/09/1.8 12:46 75-01-4 m&p-Xylene ND . ug/L 1.0, 0.50 1 11/09/18 12:46..179601-23 1 o-Xylene ND,.' ug/L 0.50. 0.25 .1 11/09/1812:46.. 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 94 :. % 707130 1 11/09/18 12:46 17060-07-0 4-Bromofluorobenzene (S) .. 94, % 70-130. 1 11/09/18 12:46 . 460-00-4 Toluene-d8 (S) 104 % 70-130 1 11/09/18 12A6.. 2037-26-5 2540C Total Dissolved'Solids Analytical Method: SM 2540C-2611 Total Dissolved Solids 88.0 mg/L. 26.0 25.0 .1 . 11/06/18 19:23 .' MBIO 9222D, Fecal Coliform AVL Analytical Method.: SM 9222D-2006 Preparation Method: SM 9222D-2006 Fecal Coliforms 69.0 CFU/100 ml- 1.t) 1.0 1 _ 11/02/18 16:46 11/03/18 14:47• 350.1 Ammonia - Analytical Method:,EPA 350.1 Rev.2.0 1993 " Nitrogen, Ammonia ND mg/L 0.10 0.050 1 .. 11'/08/18 12:13' 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Nitrogen, Nitrate. 0,64. mg1L 0.020 . 0.01.0 1 11103/18 00;09: 14797-55-8 36.5.1 Phosphorus, Total Analytical Method:'EPA 365.1 Rev-2.0 1993 Preparation,Method: EPA 365.1 Rev 2.0 1993 . 'Phosphorus 0:057 mg/L 0.050 .0.025 1 11/05/18.20.45 .11/06/18 20:26 7723-14-0. 4500 Chloride Analytical -Method: SM 4500-CI-E-2011 Chloride. - 10.1 - mg/L 1.0, 0.50 :.. 1 11/05/18 20:15.. 16887-00-6. 5310B TOC Analytical Method: SM 531OB-2011 . = Total Organic Carbon .. 2.5 mg/L 1.0 0.50 1 11/09/18 13:44 7440-44-0 .. REPORT OF LABORATORY ANALYSIS .. This; report shall not be reproduced, except in full, Date:11/09/2018 04:27 PM without the written consent of Pace Analytical Services, LLC. Page.11 of44 . Pace Analytical Services; LLC ' //++Qq //��//��tggJJ //.++gg ® aV{�/'IIIGl�1VO 2225 Riverside.Dr. Asheville, NC 28804 . . www.pacela6s.ecm• (828)25477176 ANALYTICAL" RESULTS Project; Lassonde Pappas 18148201.01 Pace Project No:: ,' .92405811 Sample:. MW-7R : Lab ID:. 92405811064 Collected:: • 11/02/18 09:37. Received: 11/02/18 14:33. Matrix: Water Parameters' • Results Units .. PQL MDL DF . Prepared Analyzed :: CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L. 0.50 0.25. .1 . 11/09/181214- 71-43-2 Bromobenzene ND ug/L _ - -0.50 0.25. _ -1 11/09/18 12:14 108-86-1 Bromochloromethane ND ., ug/L 0'.50. • . 0.25 1 11/09/18 12:14..74.97 5 Bromodichloromethane ND. ug/L 0.50 0.25 1 11/09/18 12:14', 75-2774 Bromoform ND ug/L. 0.50 0:25 ' ...1 11/09/18. 12:14 ,75 25 2 Bromomethane ND ug/L 5.0 2.5 1. 11/09/1812:14 74-83-9 n-Butylbenzene ND uglC 0.50 0.25 1 11/09/18 12:14 104-51=8 . sec-Butylbenzene NO ug/L .. 0:50 0:25 1 11/09/18.12:14. 135-98-8 .. tent-Butylbenzene ND ug/L 0.50:.. 0:25 ...1 11/09/18.12:14..98-06=6 Carbon tetrachloride ND .: ug/L . .. 0.50' . 0.25 1'. 11/09/18 12:14 56-23-5 Chlorobenzene. . . ND ug/L' .0.50 0.25 .1 . 11/09/18 12:14'. 108-90-7 Chloroethane ND ug/L _. 1.0 0.50 1 11/09/1812:1.4 75=00-3 . Chloroform ND'. ug/L 0:50 0.25 1 11/09/18 12:14..67-66-3 Chloromethane . ND .. ug%L 1.0 .. 0.50 1 .. 1,1/09/18 12:14:. 74-8773 2-Chlorotoluene ND ug/L • 0.50 ' 0:25 1 . 11709%18,-12:14 .95-49-8 4-Chlorotoluene ND ug/L 0.50 0.25. 1 11/09/18 12:14 106-43-4 1,2-Dibromo-3-chl6ropropane ND ug/L; 1..0 0.50 1. 11/09/18 12:14 96-12-8 -, Dibromochloromethane ND ug/L 6.50 - 0:25 : -1 11/09/18 12:14 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50..'. 0:25 . 4 11/09/18.12:14 .106-93 4 .. Ditiromomethane ND ug/L 0:50. 0..25 1 11/09/18 12:14 74-95-3 12-0chlorobenzene ND' ug/L 0.50 ': 0.25. ..1 .11/09/1812:14 95-50.l . 1,3-D.ichlorobenzehq ND _ ug/L 0.50 0.25 1 ; 11/09/18 12:14 541=73-1 " 1,4-Dichlorobenzene. ND '' ug/L 0'.56. .'0.25 .. 1 11/09/1812:14..106-46-7 Dichlorodifluoromethane : ND. ug/L 0.50 .. 0.25 .1 11/09/1812:14, 15-71-8 1 J-'Dichloroethahe - ND ". _ ug/L. 0.50 0.25 .1 11/09/18 12:14 .75-34-3 1;2-Dichloroethane ND ug/L 0.50_ 0:25 . 1.: 11109/1a J2:14 1'07-06-2 1,1-Dichloroethene:. ND uq/L- 0.50 0.25 1. .11/09/18 12:14 75735-4 cis-1,2=Dichloroethene. ND ug/L :. 0:50 0:25 1 11/09/18.12:14. 156-59-2- ;. trans-1,2-Dichloroethene ND - ug/L .0.50:, 0:25 1 11/09/18:12:14..156-60-5 :. 1,2-Dichloropropane ND !ug/L 0.50. 0.25 1 11/00/1812:14 78-87-5 1;3 Dichloropropane ND ug/L. 0.50 ,' : 0.25 '1 . 11/09/1812:14- 142-28-9. 2,27Di6hloropropane. ND ug/L', 0.50 6.25. 1 11/09/1812:14 594-20-7 . 1,1-Dichloropropene . ND ug/L 0:50. 0.25 1' 11709/18 12:14..563 58 6 cis-1,3-Dichloropropene ND" ug/L , _ 0.50 .. 0:25 1 11/09/18 12:14;' 10061-01-5. traris-1,3-.Dichloropropehe ND .. ug/L. 0.50 0.25 1 . 11109/18 12:14 .10061-02-6 Diisolampyl ether _ . ND ug/L 0,50 0.25 1. 11/09/18 12:14 108-20-3 Ethylbenzene -.. -. ND- ug/L 0.50 0.25 1. .11/09/18&12:14 • 100-414 Hexachloro-1,3-butadiene . ND ug/L - 2.0 • . .. 1.0 1 11/09/18 12:14. 87-68-3 Isopropylbenzene (Cumene) ND ug/L _. 0.50: -0.25 .. 1 11/09/18 12:14 98-82=8 Methylene Chloride ND ug/L 2.0' _ ..1.0 _ .1 11/09/18 12:14 75-09-2 Methyl-tert-butyl, ether ND ug/L .0.50 0,25. 1 . 11/09/18 12:1.4 1634-04-4 Naphthalene ND ug/L _ 2.0 . . 1.0. 1 , ;11/09/18 12:14 91=20-3 " n-Propylbenzene ND ug/L" 0.50 .0.25 1 11709/1812:14..103-65-1 Styrene; ND. ug/L 0.50 . • 0.25 1 11/09/18 12:14 100742-5 :.1,1,1,2-Tetrachloroethane ND ug/L '.' 0.50 0.25 .1 11/09/18 12:14 '.630-20-6 1;1,2,2-Tetra6hloroethane. ND ug/L_ 0.50 0.25 1 .11/09/1812:14 79734-5 REPORT OF LABORATORY ANALYSIS . ". This reportshall not be reproduced; except in full, Date: .11109/2018 04:27 PM without the written consent of Pace Analytical Services, LLC. Page.1.2 of'44 Pace Analytical.Services; LLC ® aceAnaliftal 2225 Riverside_Dr. Asheville, NC 28804 - www.pacelabs.com (828)254-7176 ANALYTICAL RESULTS. Project: Lassonde Pappas 18148201.01 Pace Project No::...92405811 .' Sample:'.MW-7R : Lab 0:.92405811004 Collected:: 11/02/18 09:37. _ Received:. 11/02/18 14:33. Matrix: Water Parameters _ Results Units ' .. PQL MDL' :. DF . Prepared Analyzed _ CAS No.. Qual 6200B MSV . .' Analytical. Method: SM 6200B Tetrachloroethene ND . " ug/L: .0.50 ' 0,25 1 . 11/09/18 12:1.4 127-184 'Toluene ND ug/L _ -0.50 0.25. 1 : 11/09/18 12:14 108-88=3 1,2,3-Trichlorobenzene ND . ug/L 2.0 1.0 1 11/09/18 12:14 .87-61-6 1,2,4Trichlorobenzene. ND ug/L - " 2.0 .1.0 1 11/09/18 12:14; 120-82-1 1;1,1-Trichloroethane" ND _ .. ug/L 0.50 0:25 .1 11/09/18 12:14 ".71755-6 1;1,2-Trichloroethane ND- ug/L 0.50- 0.25 1: 11/09/18 12:14 79-00-5. Trichloroethene ND ug/L _ 0.50 0.25 1 . .11/09/18 12:14 79-01-6 Trichlorofluoromethane NO ug/L .. 1.0.1 .0:50 :- 1 11/09,/18.12:14. 75-69-4. 1;2;3-Trichloropropane ND.. ug/L ..0.50::.1 0:25 1 11/09/1812:14..96-184 1,2,4-Trimethylbenzene... ND ug/L . ," ,0.50 . 0.25 1 11/09/18 12:14 95-63-6 1;3,5?rimethylben2ene ND' _ . ug/L: 0.50 0.25. 1 . ' ' 11/09/18 12:14' 108-67=8. Vinyl chloride ND ug/L 1.0 - 0.50 1 .11/09/18 12:14 75=01-4 m&p-Xylene ND ug/L 1.0. 0.50 1 11/090812:14..179601-2371 o-Xylene " . - ND.- ug/L 0.50 0.25 .1 11/09/18 12:14. 95=4776 Surrogates 1,2=Dichloroethane-d4 (S) 92" %_ .' .70-130 - 1' 11/09/18 12:14 17060-0770 4-Bromofluorobenzerie(S) :. 97: % 70-130. 1 11/09/18-12:14:.460-00-4 Toluene-d8 (S) .. - " '.. 98. % 70-130 .. 1 " .. " 11/09/18"12:14:. 2037-26-5 . 2540C Total Dissolved Solids : Analytical Method:.SM 2540C-2011 Total Dissolved Solids 243'_ . . mg/L. 25.0 , , `.: 25.0 1 . " _ .: 11106/18 19:23 . " MBIO 9222D Fecal Coliform AVL Analytical -Method:.SM 9222D-2006 Preparation Method: SM•9222D-2006 Fecal Coliforms ND CFU'/100 mL 10.0 10.0 10 _ 11/02/18 16:26' 11/03/18 14 30 ' 350.1 Ammonia Analytical Method:.EPA 350.1 Rev 2.0 1993 Nitrogen; Ammonia - ' ND. mg/L. 0.10 0.050 1- 11/08/18 12:17.. 7664-41-7 . . 353.2 Nitrogen, NO2/NO3-unpres Analytical Method: EPA353.2 Rev'2.0 1993 - Nitrogen, Nitrate.... 1:5.7,' ', . nig/L 0.10 " " - 0.'050 5 /1703/18 00 32.- 1.4797-55-8 365:1 Phosphorus,.Total . .' :. Analytical'Method: EPA365.1 Rev"2.01993' Preparation Method' EPA365:1 Rev 2.0`1993'. Phosphorus . .0.17 mglL'. 0.050 .0:025 1 11/05/18,20:45, .11/06/1820:27" 7723-14-0. ' 4500'.Chloride. Analytical"Method? SM 4500-CI-E-2011 Chloride. 20.2 mglL 1.0 0.50 1 11/05/1820:16:. 16887-00-6 5310B TOC Analytical -Method: 53108-2011 Total Organic Carbon .. _ 5.3 _' mg/L . .. 1.0 0.50 .. 1 11/09/18.13:56; . 7440-44-0 REPORT OF LABORATORY ANALYSIS'. This; report shall not'be reproduced, except in full, Dater 11/091201.8 04:27 PM - l witiioufthe written consent of Pace Analytical Services,"LLC. Page.13 of'44 - - Pace Analytical.Services, LLC . �• cical ® e aAnal 2225 Riverside Dr. Asheville, NC 28804 . . -pacelabs.eom _ (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas 18148201.01 Pace Project No.:, , .92405811 Sample.:. MW-8 Lab ID:. 92405811065 - 'Collected:: 11/02/18 08:32 Recei4ed:.' 11/02/18 14:33 Matrix.. Water Parameters Results Units .. PQL MDL DF . Prepared Analyzed • CAS No:.. Qual 6200B MSV: Analytical Method:SM 6200B Benzene ND ug/L 0.50 0.25. 1'. .11/09/18 12:30 71-43-2. Bromobenzene ND ug/L 0.50 0.25 1 11/09/1812:30 108-86-1 Bromochloromethane ND . ' ug/L 0:50 0.25 1 11/09/1812:30. -74-97-5 Bromodichloromethane NO ug/L 0.50 0.25 1 .. 11/09/18 12:30: 75=27-4 Brornoform NO . ,.. ug/L. 0.50 0.25 1 1110011812:30 .75-25-2 . Bromomethahe ND ug/L 5.0 2.5 1 11/09/18 12:30 '74-83-9. - n-Butylbenzene ND- - ug/L 0'.50 0.25 1.' • 11/09/1812:30 104-51-8. sec-Butylbenzene , .. ND . ug/L 0.50 0.25 1 11/09/18.12:30. 135-98-8 test-Butylbenzene ND.. ug/L `. 0.50,. 0:25 ..1 11/09/1812:30..98-06=6 Carbon tetrachloride ... NO ug/L _ .. - _ 0'.50 0.25 .1 11/09/18.12:30 56-23-5 Chlorobenzene NO ug/L, 0.50 0.25 .1. .11/09/18 12:30 108-90-7 Chloroethane - ND ug/L 1.0 0.50 - 1 -11/09/1812:30 75-00-3 Chloroform ND ug/L 0:50 ' 0.25 .. 1 11/09/18 12:30..67 66 3 C.liloromefhane .. ND. ug/L 1.0 0.50 '. .1 11/09/18 12:30. 74=8773 .2=Chlorotoluene ND ug/L 0.50 0:25 .1- 11/09/1812:30 .9549-8 4-Chlorotoluene ND ug/L 0.50 0.25 1 11/09/18 12:30 106-43-4 1,2-Dibromo-3-chl6ropropane NO ug/L_ . 1.0 0.50 1. .11/09/18 12:30 96712-8 Dibromochloromethane NO ug/L 0.50 0:25 1 11/09/18 12:30 124-48-1. 1;2-Dibromoethane (EDB) . .. NO ug/L `. 0.50: 0:25 .. 1 11/00/19.12:30 ..106-93-4 . Dibromomethane ND ' ug/L . .... 0.50. 0.25 1 . ` 11/09/18 12:30 74-95-3 1;2-Dichlorobenzene NO. ug/L 0.50 .' :: 0.25. .. 1 . :: 11/09/18 12:30 95-50=1 1,3-Dichlorobenzene NO ug/L 0.50 0.25. 1 _ 11/09/18 12:30 541-73-1 1.,4-Dichlorobenzene. ND . ug/L' 0.50 0.25 1 11/09/1812:30, .106-46-7 Dichlorodifluoromethane ND' ug/L .. 0.50. 0.25 .1 11/09/.1812:30. 75=71-8 1; 1 -Dichloroethane ND .. - ug/L 0.50 0:25 1. 11/09118-12:30 75-34-3 1;2-Dichloroethane ND ug/L 0.50 0.25 1.. .11/09/1812:30 107-06-2 1,1-Dichloroethene '. NO ug/L 0.50 0.25 .1. 11/09/1812:30 75735-4 cis-1,2 Dichloroethene NO ug/L : 0.50... 0:25 1 11/09/18.12:30 156-59-2 trans=1,2-Dichloroethene ND ug/L 0.50:. 0:25 .. 1 • ;,' -11/09/18 12:30 .156-60-5 1,2-Dichloropropane .. ND ug/L 0.50. 0.25 1 11/09/18.UM 78-87-5 1,3-Dichloropropane ND ug/L 0.50 0.25• 1. ..11/09/18 12:30 142-28-9: 2,27Dichloropropane. NO ug/L' 0.50 0:25 1' 11/09/1812:30 5.94-20-7 1,1-Dichloropropene . NO ug/L' 0'.50 0.25 '.. '1 11/09/18 12:30..563-58-6 cis-1,3-Dichloropropene NO ug/L : 0.50 0.25 1 11/09/1812:30. 10061-01-5 trans-1,3-Dichlol-opropene ..ND ug/L 0.50 0:25 1 11709/18 12:30 10061-02-6 Diisopropyl ether- _ NO - ug/L 0.50 0.25 '' 1: 11/09/18 12:30 1'08-20-3 Ethylbenzene ND ug/L 0..50 0.25 1 11/09/1812:30 100-414 Hexachloro=1,3-butadiene, NO ug/L : 2.0 1.0 : 1 11/09/1812:30 87-68-3 Isopropylbenzene (Cu.mene) . ND ug/L 0.50 . 0.25 1 11/09/19,12:30 . 98-82-8 MethyleneChloride. NO ug/L 2.0 1.0 .1 11/09/1812:30 75-09-2. Methyl-tert-butyl ether NO ug/L: 0.50 0.25 1 .11/09/18 12:30'. 1634-04-4 Naphthalene. ND ug/L-. 2.0 1.0_ 1; 11/09/1812:30 -9.1=20-3 - n-Propylbenzene NO ug/ 0.50 0.25 '1 11/09/1812:30.103-65-1, Styrene ND ug/L 0.50 . 0.25 ;.' .1 ... .11/09/18 12:30' 100-42-5 1;1,1,2-Tetrachloroethane NO ug/L 0.50 .• 0.25 1 _ 11/09/18.12:30 .630-20-6 1;1,2,2-Tetrachloroethane. NO, ug/L 0.50. 0.25 " 1.. .. 11 /09/18 12:30 79=34-5. REPORT OF LABORATORY ANALYSIS- '_ This report shall not be reproduced, except in full, Date: 11/09l2018 04:27 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 44 Pace Analytical Services, LLC J® r1g nali /+ a 2225 Riverside Dr. . . lie/'�J . Asheville, NC 28804 . . wrnv pacelabs com. (828)254-7176 ANALYTICAL RESULTS . . Project: Lassonde Pappas 18148201.01 Pace Project No.:. .92405811 Sample:. MW-8 Lab ID: 92405811005 Collected:. 11/02/18 08:32 Received: " 11/02/18 14:33 Matrix: Water Parameters Results Units .. PQL MDL DF . Prepared Analyzed CAS No: " . Qual 6200E MSV - Analytical Method: SM 620013 Tetrachloroethene: ND ug/L: 0.50 0.25 1. 11/09/18 12:30 127-18=4 Toluene ND ug/L 0.50 0:25, 1 11/09/18 12:30 108 88 3 1,2,3-Trichlorobenzene ND . ug/L 2.0. 1.0 .. 1 11109/18 12:30. 87-61-6 1,2,4=Trichlorobenzene ND ug/L .. 2.0 . 1.0 .' .1 .11/09/18 12:30,- 120-82-1 1,1,1-Trichloroethane'. ND . _. ug/L. 0.50 0.25 1 11/09/18-12:30 ',71-55-6 1;1,2-Trichloroethane ND"'..' ug/L 0.50 0.28 " 1' .11/09/1812:30''79-00-5 Trichloroethene ND ug/.L " 0.50 0.25 1. 11/09/1812:30 79-01-6_ Trichlorofluoromethane ND ug/L 1.0 0:50 . 1 11/09/18.12:30. 75-69-4 1,2,3=Trichloropropane ND. ug/L 0.50 0:25 .. 1 11/09/18.12:30 ..96-18 4 1,2,4-Trimethylbenzene... ND ug/L 0.50. 0..25 1 11/09/18 12:30 95-63-6 1;3,5-Trimethylbenzene ND ug/L 0.50 0.25 1 11/09/18 12:30 108-67=8: Vinyl chloride ND ug/L _ _ 1.0 0.50. 1 11/09/18 12:30 75=01-4, m&p-Xylene ND ug/L 1.0: .0.50 1 11/09/1812:30.179601-23-1 o-Xylene ND. ug/L 0.50 0.25 .. .1 1.1/09/1812:30: 9&47-6 Surrogates- 1,2-Dichloroethane-44 (S) 93 % 70-130 1 11/09/18 12:30 17060-07-0 4-Brom6fluorobenzehe (S) :. 94, % 70-130 1 11/09/18 12:30'. 460-00-4 Toluene=d8 (S) 103 % - 70-130 1 11/09/18 12:30. 2037-26-5 2540C Total. Dissolved Solids . Analytical Method: SM 2540C-2011 .. Total Dissolved Solids 351. mg/L: 25.0 .' :. 25.0. .1 11/06/18 19:23 MBIO 9222D; Fecal Coliform AVL Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Fecal Coliforms 19.6 CFU1100 mL 1.0 1.0 1 11/02/18 16:26 . 11/03/18 14'.30 .350.1 Ammonia Analytical Method: -EPA 350.1 Rev 2.0 1993 Nitrogen, Ammonia ND mg/L 0.10 0.050 - 1 .. 11/08/18 12:18. 7664-41-7 . 353.2 Nitrogen, NO2/NO3 unpres _' . Analytical Method: EPA 353.2 Rev.2.0 1993 Nitrogen; Nitrate... 6.8 .. mg/L. 0,040 ", .. 0.020 '. ,2 11/03/18-00 22. 1.4797r55-8 365:1 Phosphorus, .Total . Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation, Method`. EPA 365.1 Rev 2.0 1993 Phosphorus . 0.25 mg/L.. 0.050 .0:025 1 11/05/18 20:45 .11/06/18-20:28 7723-14-0 M1 4500.Chloride Analytical Method: SM 4500-CI-E-2011' Chloride', 8.0 mg/L 1.0: 0.50 .. 1 11/05/1820:181. 16887-00-6 531OB TOG Analytical- Method: SM 5310E-2011 Total Organic Carbon 9.5.., mg/L 1.0 0.50 1 11/09/18.14:27' _-7440-44-0 REPORT OF LABORATORY ANALYSIS. . This reportshall not,be reproduced, except in full, " Date: 11/09/201.8 04:27 PM without the written consent of Pace Analytical Services, LLC. Page.15 of 44 Pace Analytical.Services, LLC ® g �1g dceAlla0001 2225 Riverside Dr., . Asheville, NC 28804 wwwpacelabe.com (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas 18148201.01 Pace Project No.:, .92405811 Sample: . MW-9. Lab ID: 92405811006 Collected: 11/02/18 11:33 ' Received: 11/02/18 14:33 Matrix: Water Parameters Results Units PQL MDL- DF . - Prepared Analyzed : CAS No. Qual " 6260B MSV . Analytical Method: SM 6200B Benzene ND .' ug/L. 0.50 0.25. 1 11/09/.18 13:18 _ 71-43=7 Bromobenzene ND ug/L 0.50 0.25 1: 11/09/18 13:18 108-86-1 . Bromochloromethane ND . = ug/L 0.50 0.25 " 1 11/091/18 13:18 74-97-5 Bromodichloromethane ND. ug/L 0.50 0.25 : 1 11/09/1813:18. 75-27-4 " Bromoform - .. ND' - ug/L. 0.50 0:25 .1. 11/09/1813:1875-252 Bromomethane ND ug/L 5.0 2.5 - " 1. 11/09/18 13:18 74-83-9 n-Butylbenzene ND ug/L 0.50 0.25 1. - 11/09/18 13:18- 104-51-8 sec-Butylbenzene . :. NO ug/L 0.50 0:25- : 1 11/09/18 13:18 135-98-8 tert-Butylbenzene ND. ug/L .0.50 0.25 ..1 11/09/18.13:18 98-06=6 Carbon tetrachloride - . ND ug/L 0.50 0.26 1 11/09/18.13:18 56-23-5 Chlorobenzene .: ND ug/L: 0.50 0.25 -1 . .11/0911813:18 108-90=7: Chloroethane ND ug/L ' _ 1.0 0.50 1: 11/09/18 13:18 75700-3 Chloroform ND . ug/L' 0.50 . 0.25 1 11/09/18 13:18. .67-66-3. Chloromethane .. ND," ug/L 1.0 0.50 1 11/09/18 13:18 " 74=87-3 2=Chlorotoluene ND " .. -ug/L. 0.50 - .. '0.25 1 11/09%18.13:18 .9549-8 . 4-Chlorotoluene ND- ug/L 0.50 0.25 1: .11/09/18 13:18 106-43-4 .1,2-D.ibromo73-chloropropane ND ug/L, . 1.0 0.50 1. 11/09/1813:18 96-12-8 Dibromochloromethane NO ug/L 0.50 0:25 1 11/09/1813:18 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 0.25 .. 1 11/09/18 13:18 ..106-93-4 Dibeomomethane ND ug/L - .. - 0.50 .. Q.25 1 11/09/18.13:18 74-95-3 .. . 1;2-Dichlorobenzene ND. - . ug/L 0.50 _ :: 0.25 '.:1 , 11/09/.18 13:18 9575071' -1,3-Dichlorobenzene ND ug/G 0.50 0.25 1; 11/09/18 13:18 541-73-1 1,4-Dichlorobenzene. ND ug/L 0'.50, 0.25 1 11/09/4813:18 106-46-7 Dichlorodifluoromethan.e : ND - ug/L 0.50 .. 0.25 .1 .. 1.1/09/18 13:18 75-71.8 1;1-Dichloroethane.. ND - - ug/L. 0.50 0:25 1. 11/09/18,13:18 .75-34-3': 1;2-Dichlor6ethane_ ND ug/L 0.50 0.25 " 1" ..11/09/1813:18' 107-06-2 1,1-Dichloroethene:. ND ug/L_ . 0.50 0.25 1. 11/09/18 13:18 75-35-4 cis- 1,2=Dichloroethene. ND uglL 0:50 , . .0:25 : 1 11/0.9/18.13:18 156-59-2 trans=1,2-Dichloroethene ND ug/L ;. .-0.50. 0:25 ..1 11/09/1813:18..156-60-5 .. 1,2-Dichloropropane ..: • ND ug/L .0.50. 0.25 1 11/09/18,13:18 78-87r5 Ii3-Dichloropropane ND_ -. ug/L: .0.50 0.25 1 . 11/09/1813:18 142-28=9' 2,2-Dichloropropane • _ ND ug/L 0.50 0.25. 1: 11/09/1813:18 594-20-7 1,1-Dichloropropene . ND ug/L 0:50. 0.25 1 11/09/18 13:18, 563-58-6 cis-1,3-Dichloropropene ND. ug/L 0.50 .0.25 1 . 11/09/1813:18. 10061-01-5 . trans-1,3=Dichloropropene "'. ND' ug/L. 0.60 0:25 1. 11/09/18.13:18 10061-02-6. Diisopeopyl ether ND - :: ug/L _, 0,50 0:25 1. 11/09/18 13:18 108-20-3 Ethylbenzene ND ug/L. 0..50 0.25 1 11/09/18 13:18 100-41-4 Hexachloro=1,3-butadiene ND ug/L 2:0 1.0 . 1 - . 11/09/18.13:18. 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50. 0.25 1 -11/09/18 13:18 98-82-8 Methylene, Chloride ND ug/L . 2.0.' 1.0 1 11/09/18 13:18.1 75-09-2 Methyl-tert-butyl ether ND ug/L. 0.50 :. 0.25 _ . 1 .11/09/18 13:18 1634-04-4 - Naphthalene. ND ug/L' 2.0 1.0. '1 : 11/00/18 13:18 -9.1-20-3 - n-Propylbenzene ND ug/L 0:50. 0.25 1 11/09/18 13:18. .103-65-1 Styrene:.. ND. ug/L 0.50 .. .0.25 1 11/09/18 13:18 100-42-5 1;1,1,2-Tetrachl6roethane ND ug/L• '.' 0.50 0.25 1. 11/09/18.13:18 630-20-6 1,1,,2,2-Tetrachloroethane ND ug/L 0.50, 0.25 1_ 11/09/18 13:18 79-34-5 REPORT OF LABORATORY ANALYSIS. This. report shall not be reproduced; except in full, Dater 11109/201.8 04:27 PM withouf'the written consent of Pace Analytical Services,'LLC. - . Page.16 of 44 Pace Analytical,Services, LLC +Q qI7 r+ /® �lreAhil�ico 2225 Riverside Dr. . Asheville, NC 28804 - WvMpacelabs.com (828)254-7176 ANALYTICAL RESULTS. Project: Lassonde Pappas 18148201.01 Pace Project No.:- 92405811 Sampler MW-9_ Lab lO:.92405811006 Collected: 11/02/18'11:33 Received: 11/02/18 14:33.- Matrix: Water Parameters Results Units .. PQL MDL DF . Prepared Analyzed CAS No... Qua] 6200E MSV Analytical Method:SM 6200E Tetrachloroethene ND ug/L .0.50 0.25. 1. 11/09/1813:1$ 127-18-4' Toluene ND ug/L 0.50 0.25- 1 11/09/18 13:18 108-88-3 1.,2,3-Trichlorobenzene ND ug/L.' 2.0. 1.0 .. 1 11/09/18 13:18. .87-61-6 1,2,4=Trichlorobenzene. ND ug/L . 2.0 1.0 .1 .11/09/18 13:18. 120-82-1 1;1,1-Tridhloroethane ND _ ug/L 0.50 0:25 1. 11/09/18.13:18 .71-55-6 1,1,2-Trichloroethane ... ND ug/L 0,50 0.25 1 11/0911813:18 79-00-5 Trichloroethene - ND ug/L 0.50- 0.25 1. " 11/09/18 13:18 79-01-6 Trichlorofluoromethane ND - ug/L :. 1.0 _' .0:50 1 11/09/18 13:18 " 75-69-4 , 1,2;3-Trichloropropane ND ug/L 0.50... 0;25 -1 11/09/1813:18..9618.4 1,2,4-Trimethy]benzene ND ug/L . 0.50. 0.25 1 - 11/09/18 13:18 -95-63-6 1,3,5-Trimethylbenzene ND ug/L. 0.50 0.25 1 11/0911813:18 108-67=8 Vinyf.chloride ' ND ug /L 1.0 0.50 1 11/09/18 13:18 75-01-4 m&p-Xylene ND . ug/L 1.0, '0.50 1 11/09/18 13:18 179601-23-1 o-Xylene ND ug/L 0.50. 0.25 1 11/0911813:18 95-47-6 Surrogates . 1,2=Dich]oroethane-d4 (S) ' 95 % .70-130 1 11/09/18 13:18 17060-07-0 4-Bromofluorobenzene (S) .. 95 % 70-130 1 _ 11/09/18 13:18: 460-00-4 Toluene. (S) .. 104 % ZO 130.. 1 11/09/18 13:18: 2037-26-5 2540C Total.Dissolved Solids . Analytical Method: SM 2540C-2011 Total Dissolved Solids 88.0 mg/L 2E0 . ' 25.0 1'. .11/06/18 19:23 . MB10.9222D: Fecal Coliform AVL -Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Fecal Coliforms ND CFU/100 niL 10.0 10.0 10 11/02/18 16:46 . 11/03/`18 14A 350A Ammonia -Analytical Method: EPA350.1 Rev2.0 1993 Nitrogen, Ammonia ND mg/L 0.10 0.050 1 11I08/18 12:23:." 7664-41-7 - 353.2 Nitrogen, NO2/NO3 unpres Analytical Method`. EPA 353.2 Rev'2.0 1993 Nitrogen; Nitrate. ,. 0.57. -. mg/L. 0,020 . _. 0:010 1 11/03/18 00:10,' 14797-55-8 365:1 Phoephorus,.Total Analytical Method: EPA365.1 Rev2.01993 Preparation. Method:. EPA365.1 Rev 2.01993 Phosphorus . 0.47. mg/L 0.050 .0.025 1- 11/05/18.20:45..11/06/18 26:30 7723-14-0. 4500.Chloride• Analytical Method: SM 4500-CI-E-2011 Chloride - 5.8 mg/L 1.0 0.50 . _ 1 _ 11/05/18 20:19 . 16887-00-6 531 OB TOC Analytical Method: SM 5310B-2011, Total Organic Carbon 8.4 mg/L 1.0 0.50 1 - : 11/09/18 14:37 7440744-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/09/2018 04:27 PM without the written consent of Pace Analytical Services, LLC. Page, 1.7 of 44' Pace Analytical Services, LLC �+ ® aceAna! rcal. 2225 Riverside Dr. Asheville, _ NC 28804 . . www.pacelabs.cora (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas 18148201.01 Pace Project No.: 92405811 Sample: SW-1 Lab ID:-92405811007 Collected:: 11/02/18'12:28 Received: 11/02/18 14:33. Matrix: Water '. . Parameters Results units .. PQL MDL _ DF . Prepared Analyzed CAS No. Qual 6200B MSV" Analytical Method:SM 6200B Benzene NO ug/L; 0.50.-.- 0.25 1 11/09/1811:41 71-43-2: Bromobenzene NO ug/L 0.50 0.25 1. 11/09/1.811:41 108-86-1 Bromochloromethane: - NO ug/L 0:50. 0.25 1 11/09/18 11:41. .74-97-5. Bromodichloromethane ND' - ug/L 0.50.. .0.25 .1 11/09/18 11:41. 15-274 Bromoform ND . ug/L. _ .- 0.50 025 1 11/09/18 11:41 75-25-2 Bromometfiane NO ug/L. 5.0 2.5. 1: 11/0911811;41 -74-83-9 n-Butylbenzene ND ug/L 0.50 0.25 1 11/09/1811:41 104-51-8 sec-Butylbenzene ND ug/L 0.50 025 1 11/09/18.11:41. 135-98-8 • tert-Butylbenzene NO ug/L 0.50.:. 0:25 1. 11/00/1911:41 ..98-06=6 Carbon tetrachloride NO ug/L. .. 0.50. 0.25 1 11/09/18 11:41 56-23-5 Chlorobenzene NO ug/L 0.50 0.25 1 .11/0911811:41 108-90=7: 'Chloroethane'. -ND ug/L 1.0 0.50 11 11/09/18 11:41 75=00-3 Chloroform NO . " ug/L 0.50. 0.25 1 -11/09/18 11:41, -67-66-3 Chlororrrethane .. NO ug/L , " 1.0 . 0.50 1 11/09/18 11:41". 14=87-3 M1 2=Chlorotoluene NO ".. ug/L 0.50 0:25 1 11/09/18 11:41 95-49-8 .4-Chlorotoluene ND- - ug/L 0.50 0:25 1 11/09/1811:41 106-43-4 1,2-D.ibromo73-chl6ropropane - _ ND- _ ug/.L 1..0 0.50 1. .11/09/1811:41, 96712-8- Dibrom6chlorome.thane ND -ug/L .. 0.50 _ 0:25 1 _ - 11/091/18 11:41 - 124-48-1 1,2-Dibromoethane (EDB) NO ug/L -0.50: . 025 .. 1 11/09/18 11:41 .106-93-4 Ditiromomethane" - ." : NO dg/L . 0:50 .. 0.25 1 11/09/18 11:41 74-95-3 1;2-Dichlorobenzene NO ug/L 0.50 0.25. 1. ..: 41/0911811:41 95-50.1" 1,3-Dichlorobenzene NO ug/L _ 0.50 0.25, 1. 11/09/18 11:41 -541-73-1 . 1,4-Dichlorobenzene NO ug/L' 0:50 0.25 1- 11/09/18 11:41..106-46-7 Dichloro.difluoromethane : ND. .• ug/L• 0.50 .. 0.25 '. 1 ... 11/09/1811:41:. 75-71-8 1;1=Dichloroethane . NO ug/L. 0.50 0.25 .1 . 11/00/18 11:41: -75-34-3 - 1,2-Dichlor6ethane. ND .. ug/L 0.50 0.25 1. ..11/09/18 11:41 107-06-2- 1,1-Dichloroethene, . NO ug/L. 0.50 0.25 1.' .11109/1811:41 75.35-4 cis-1,2-Dichloroethene. - NO ug/L 0.50 025 1 11/09/18.11:41 - 156-59-2 transA,2-Dichloroethene NO ug/L - .. .0.50.' . 025 1 .11/09/18 11:41 . 156-60-5 1,27Dichloropropane - NO ug/L . 0:50 .' 0.25 1 - 11/09/18:11:41 78-87-5 1;3-Dichloropropane ND- ug/L .0.50 0,25. 1 . 11/0911811:41 142-28=9: 2;2-Di6hloropropane. -ND ug/L _ 0.50 025. 1 ; 11/09/18 11:41 594-20-7 1,1-Dichloropropene : NO ug/L 0.50. 0.25 .. 1 11/09/18 11:41 .563-58-6 ci5-1,3-Dichlor6propene NO. ug/L 0.50 0.25 1 11/09/1811:41 10061-01-5. trans-113=Dichloropropene ND -ug/L. 0.50 0:25 -.'1 11/09%18.11:41 .10061-02-6. Diisopeopyl'ether .. NO ug/L 0.50 0.25- 1.. .11/09/18 11:41 108-20-3_ Ethylbenzene NO ug/L _ . 0.50 0.25 .1.* .11/09/18 11:41 - 100-41-4 Hexachloro-1,3-butacliene NO ug/L 2:0 1.0 1 _ 11/09/18.11:41: 87-68-3 Isopropylbenzene (Cumene) NO ug/L 0.50 0.25 .. 1 11/09/18 11:41 .08-8278 Methylene Chloride ND ug/L 2.0 1.0 1 11/09/18 11:41 75-0972 Methyl-tert=butyl ether NO _ . ug/L. 0.50.'.'. 0.25 .1 . 1//019118 11:41 1634-04-4 Naphthalene: _ ND ug/L _ -; 2.0 1.0 1 : 11/09/16 11:41 91-20-3 n-Propylbenzene- NO ug/L 0.50 0.25 1 11/09/18 11:41 .103-65-1 Styrene : NO ug/L - 0.50 0.25 1 11/09/18 11:41: 100-42-5 1;1,1,2-Tetrachloroethane NO ug/L 0.50 0.25 1 11/09/18 11:41 .630-20-6. 1;1,2,2-Tetrachloroethane NO ug/L• 0.50 0'25 1.. 11/09/18-11:41 -79-34-5 REPORT OF LABORATORY ANALYSIS. . This; report shall not be reproduced; except in full, Date; 11/09/201.8 04:27 PM without the written consent of Pace Analytical Services, LLC. Page 18 of _44 - Pace Analytical.Service% LLC . • - aceAnal 2225 Riverside Dr. i'ca!® Asheville, NC 28804 - www.pacelabs.com ': (828)254-7176 ANA LYTICAL RESULTS Project: Lassoride Pappas 18148201.01 Pace .Project No::. 92405811 . Sample: SW-1 Lab ID: 92405811067 Collected:: 11/02/18'12:28.. Received: :11/02/1814:38. Matrix: Water Parameters Results Units PQL .. MDL DF Prepared Analyzed CAS No:.. Qual 620013 MSV:. Analytical Method: SM 6200B Tetrachloroethene ND ug/L 0.50 0.25 1 . 11/09/18 11:41 127-184 Toluene ND ug/L 0.50 025_ - 1 11/09/18 11:4.1 108-88-3 1,2,3-Trichlorobenzene ND ug/L . 2.0 1.0 1 11/090811:41 .87-61-6. : 1,2,4Trichlorobenzene ND ug/L 2.0 . .1.0 1 11/09/18 11:41, 120-82-1 111,1-Trichloroethane . .. ND' ug/L 0.50 0.25 1. .11109118'11:41 .71-55-6 1,1,2-Trichloroethane ND._ ug/L 0.50 0:25 1 11/09/18-11:41 79=00-5. Trichloroethene _ ND ug/L 0.50 0.25 1. .11/09/18-11:41 79701-6- Trichlorofluoromethane - ND ug/L : 1:0 0.50 - 1 11/09/18 11:41 75-69-4- 1,2;3-Trichloropropane ND ug/L :. ..0.50; 0:25 1- -11109/19.11:41 ..96-18=4 1,2,4-Trimethylbenzene.:: ND rig/L . 0150. 0.25 1 11/09/18,11:41 95-63-6 1,3,5=Trimethylbenzene ND ug/L .0.50 0.25 1 . 11/09/18 11:41 108-67=8 Vinyl chloride - 'ND ug/L1.0 0.50_ 1 11/09/18 11:41 75=01-4 rn&p-Xylene ND . ug/L 1.0 . 0.50 . - 1 11/09/18 11:41 .179601-2371 o-Xylene ND. ug/L 0.50 .. 0.25 ." .1 .: 11/09/18 11:41: 95-47-6- Surrogates 1,2=Dichloroethane-d4 (S) ' 92 .. % .70A30 . 1 11/09/18 11Al 17060-07-0 ' 4-Bromofluorobenzene (8,) 100 % 70-130 1 - : 11/09/18-11;41:. 460-00-4 99. % 70-130 .. - 1 - -11/09/18 11:41- 2037-26-5 . 2540CTotal Dissolved Solids :. Analytical -Method: SM 2540C-2011 . Total Dissolved Solids 54.0 . mg/L: .25.0 25.0. _ 1 . .. 11/06/18 19:23 MBIO 9222D Fecal.Coliform AVIL Analytical Method:.SM 9222D-2006 Preparation Method: SM 9222D-2006 Fecal Coliforms ' 780 CFU/100 mL -1.0 1.0 1 11/02/18 16:46 . 11/03/18 14:47- 350.1 Ammonia Analytical, Method:. EPA350.1 .Rev.2:01993 .. Nitrogen, Ammonia ND mg/L 0.10 0.050 : 1 ... 11/08/18 12:27 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres:.. Analytical Method`. EPA353.2 Rev:2.0'1993 Nitrogen, -Nitrate- .. - 6.72 -. mgjL. 0.020 .... 0.010 -1 11103/18 00.21 14797-55-8 365.1 Phosphorus, Total . Analytical"Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 . . Phosphorus. 0:077- .. mgjL. 0.050-.0:025 1. 11/05/1820:45..11/06/1820:31 7723-14-0- 4500.Chloride Analytical Method: SM 4500-CI-E-2011 - Chloride: 5.1: mglL 1.0: 0.50 1 11/05/1820:20: 16887-00-6 - 5310B TOC Analytical Method: SM 53106-2011 Total Organic Carbon 2.9. mg/L 1.0 0.50 1 11106/1814:48 7440-44-0 REPORT OF LABORATORY ANALYSIS This. report shall not be reproduced, except,in full, Date: 11/69/2018 04:27 PM without the written consent of Pace Analytical Services, LLC. Page.19 of 44 Pace Analytical Services, LLC �.an QQQd��}} lJ //++2225"RiversideDr. eAnaOcaI. Asheville, NC 28804 www.pacei-abs.com" _ (828)254-7176 ANALYTICAL RESULTS. Project: Lassonde Pappas 18148201.01 Pace Project No.:. .92405811 Sample: SW-2 Lab ID: 92405811068 Collected:: 11/02/18 08:57 Received: 11/02/18 14:33 Matrix: Water Parameters Results Units PQL MDL OF . Prepared - Analyzed : CAS No.. Qual 6200B MSV: Analytical Method:SM 6200B :. Benzene ND ug/L 0.50 0.25. - 1 11/09/1811:58 71-43-2; Bromobenzene NO ug/L -0.50 0.25 .1 11/09/18 11:5.8 108-86-1 Bromochlororrethane NO . ug/L' 0.50- 0.25 -1 11/091/1811:58..74-97-5 Bromodichloromethane NO ug/L 0.50 - . 0.25 1 11/09/18 11:58,: 75-27-4 Bromoform ND'. ug/L. 0.50 0.25 1 11/00/1811:58 75-25-2 Bromomethane- NO . _ ug/L" 5.0 2.5 1: 11/09/18 11:58 74-83-9. n-Butylbenzene _ NO ug/L, 0.50 0.25 1. 11 /09/1.8 11:58 - 104-51-8,. sec-Butylbenzene _ .- NO ug/L .. 0.50 0.25 :" 1 " 11/09/1811:58.- 135-98-8 :. tort-Butylbenze a NO ug/L ..0.50... 0.25 .. 1" 11/09/1811:58 A8-06=6 Carbon tetrachloride ..: NO ug/L . 0.50. 0.25 1 " 11/09/18.11:58 56-2375 Chlorobenzene ND . ug/L .0.50 0.25, 1 . 11/09/1811:58 108-90.7 Chloroethane NO ug/L 1.0 0.50 1 : " -11/09/18 11:58 75=00-3 Chloroform ND .. ug/L 0:50, 0.25 1 11/09/18 11:58 .67-66-3 Chloromethane . NO. ug/L 1.0 .. 0.50 1 1,1/09/18 11:58. 74-87-3 2=Chlorotoluene NO ,.. "ug/L 0.50 0.25 ..1 " 11/09/18 11:58 '95749-8: 4-Chlorotoluene ND uglL 0.50 0.25 1 11/09/18 11:58 - 106-43-4 1,2-Dibromo,3-chloropropane NO ug/L_ . 1.0 0.50 1. .11/09/18 11:58 96-12-8 Dibromochlorom ethane NO ug/L .50. .0.25 --1 11/09/18 11:58 124-48-1 1,2-Dibromoethane(EDB) ND ug/L 0.50: _0.25 1 11/09/18.11:58.106-93-4 Dibromomethahe NO ug/L . 0.50'.. 0.25 1 11/09/18 11:58 74-95-3 1;2-Dichlorobenzene NO. . . ug/L. mo ":: 0.25. 1 . 11/09/18 11:58.. 95750.1: 1,3-Di6hlorobenzene NO ug/L'" 0.50 " 0.25. - 1; - 11/09/18 11:58 541-73-1 ", 1,4-Dichlorobenzene . " " NO . ug/L 0:50 0.25 .. 1 11/09/18 11:58. 106-46-7 Dichlorodifluorometha.n.e : ND. ug/L 0.50 .0.25 .1 11/09/18 11:58. 7&7.1-8 M-Dichloroethane ND . ,. ug/L. .. 0.50 0.25 _ .:1. 11/09/1811:58 75-34-3 " 1i2-Di6hlor6ethane NO ug/L. 0.50 0.25 1; ... .11/09/1811:58 107-06-2 1,1-Dichloroethene NO ug/L,' 0.50- ' 0.25 - .1 11/09/18 11:58 75-35-4 ' c'is-1,2-Dichloroethene. NO ug/L" 0.50 .. .0:25 1 11/09/18.11:58. 156-59-2" trans=1,27Dichloroethene NO. ug/L 0.50; .. 0.25 "1 • 11/09/18 11:58 . 156-60-5 '. 1,27Dichloropropane .. NO ug/L . .0.60. 0.25 1 " 11/00/18,11:58 78-87-5 1;3-Dichloropropane NO ug/L. 0.50 ':. 0,25. - 1 . 11/09/1811:58 142-28=9: 2,2-Di6h1oropr6p6ne. ND ug/L" 0.50 0.25, " 1 ; 11/09/18 11:58 5.94-20 7 1,1-Dichloropropene . NO ug/L " 0[50:" .'0.25 .. 1 " .11/09/18 11:58..563-58 6 - cis- 1,3-Dichloropropene ND- ug/L 0.50 .. 0.25 1 11/09/1811:58; 10061-01-5.. trans-1,3=Dichloropropene NO .. _ ug/L 0.50'. " : 0.25 .1 11109/18 11:58 .10061=02-6. . Diisopropyl ether . ND ug/L 0,50- " . 025 1 11/09/18 11:58 108-20-3" Ethylb;enzene NO ug/L_ 0.50 0.25 1." " - 11/09/1811:58 100-41=4 Hexachloro=1,3-butadiene : NO ug/L ". • 2.0. .."1.0" ." 1 •, 11/09/18.11:58: 87-68-3 " .. Isopropylbenzene (Cumene) NO ug/L -0.50: '0.25 1 11/09/18 11:58 ..98-82=8 Methylene. Chloride NO ug/L 2.0_ 1.0 1 11/09/1811:58 75-09-2 Methyl-tert-butyl ether NO ug/L 0.50 0.25 '1 11/09/18 11:58 1634-04-4 Naphthalene. NO ug/L 2.0 1:0. 1. 11/09/1811:58 "91-20-3 n-Propylbenzene NO ug/L 0.50. 0.25 .. 1 11/09/18 11:58. 10376571 Styrene NO ug/L- 0.50 0.25 _1 .11/09/18 11:58, 100-42-5 , 1,1,1,2-Tetrachloroethane -ND ug/L 0.50 0.25 1. 11/09/18 11:58 630-20-6 1,1-,2,2-Teteachloroethahe ND ug/L 0.50 0.25 1. 11/09/18 11:58 79-34-5 REPORT OF LABORATORY ANALYSIS, This report shall not be reproduced, except in full, Date: 11/09/2018 04:27 PM without the written consentof Pace Analytical Services, LLC. Page 20 of 44 Pace Analytical Services, LLC . g dQ►7 !/ 1/® efli�6�l 2225 Riverside.Dr., C itiiCZt Asheville, NC 28804 . . wWwpacelabs.com q(828)25477176 ANALYTICAL RESULTS.-.. Project: - Lassonde Pappas 18148201.01 Pace Project No.:. 92405811 Sample,:.SW-2 Lab ID: 92405811008 'Collected:: • 11/02/18 08:57 Received: 11/02/1.8 14:33 Matrix: Water Parameters' : Results Units PQL MDL DF Prepared Analyzed -CAS No:.. _ Qual 6260B MSV.. .. Analytical Method: SM 6200B Tetrachloroethene: ND ug/L: 0.50 0.25. 1', .11/09/18'11:58 127-18-4 Toluene ND ug/L . 0.50 0.25 - 1: 11/09/18 11:58 108-88-3 1,2,3-Trichlorobenzene ND . ug/L 2.0 1.0 1 11/09/1811:58..87-61-6 1,2,4=Trichlorobenzene ND ug/L " 2.0 1.0 " .1 11/09/18 11:58:. 120-82-1 - .1;1,1-Trichloroethane . .. ND . -ug/L. 0.50 0.25 1. 11/091/18-11:58-•71755-6 :. 1;1,2-Trichloroethane ND ug/L-- 0.50 0:25 .1 11/09/18 11:58 79700-5 Trichloroethene 'ND ug/.L. 0.50 .'. 0.25 1.. 11/09/18 11:58 79701-6 .' Trichlorofluoromethane ND ug/L .. 1:0 0:50 1 11/09/18.11:58. 75-69-4 • 1;2,3-Trichloropropane ND.. ug/L -0.50 '0:25 .. -1 11/00/18.11:58 . 96-18-4 .1,2,4-Trimethylbenzene. ND ug/L 0.50.: 0.25 1 11/09/18.11:58 95-63-6' . 1;3,54rimethylbenzene ND ... ug/L. 0.50 0.25 .1 .11/0911811:58 . 108-67-8 Vinyl chloride ND ug/L' _ 1.0 ' 0.50- - 1 11/09/18 11:58 75-01-4 m&p-Xylene ND . ug/L 1.c ' 0.50 .. 1 11/09/18 11:58 .179601-23-1 o-Xylene - ND ug/L- 0.50 0.25 :: .1 ... .11/09/18 11:58. 9547-6 -'.'Surrogates 1,2-Dicliloroethane,d4 (S),'. 89 % 70-130 1 11/09/1811:58 17060-07-0 4-Bromofluorobenzene (S) .. . 96. % 70-130 1 11/09/18 11:58:. 460-00-4 Toluene=d8 (S) . • 105 : - ' % 70-130 1 11/09/18 1.1:581. 2037-26-5 . " . 2540C Total Dissolved Solids • .. Analytical Method: SM 2540C-2011 Total Dissolved Solids 53.0 mg/L: 25.0 25.0. ' :1 . _ 11/06/18 19:23' . MBIO 9222R Fecal_Coliform AVL Analytical Method: SM 9222D 2006 Preparation Method: SM 9222D-2006 Fecal Coliforms 946 CFU/100 mL 1.0 1.0 -1 11/02/18 1626 . 11/03/18 14 30 350.1 Ammonia Analytical.Method: EPA 350.1 Rev 2.0 1903 Nitrogen, Ammonia 0.099J. mg/L. 0.10 0.050 1 11/08/18 12:28. 7664-41-7 . 363.2 Nitrogen, N021NO3 unpres. Analytical Method: EPA353.2 Rev.2.0 1993 Nitrogen, Nitrate. _.. 0.75. .. mg/L. 0.020 '. 0.0110 1 - 11/03/18 00.04. 1.4797755-8 365:1 Phosphorus, Total . .' ' : Analytical Method: EPA-365.1. Rev2.0 1993 Preparation Method> EPA 365:1 Rev 2.0 1993 . Phosphorus 0.076 mg/L 0.050 0:025 - 1- 11/05/18.20:45. 11/06/1820:31 7723-14-0 .. 4500.Chloride- Analytical Method: SM 4500-CI-E=2011 Chloride.. 4.6 -mg/L _ 1..0 0.50 -1 11/05/1820:21:. 16887-00-6 531013 TOC Analytical Method: SM 531OB-2011 Total Organic Carbon .. 2.9 mg/L 1.0- 0.50 1 - 11/09/18 14:58 7440-44-0 REPORT PORT OF LABORATORY ANALYSIS This:reportshall not be reproduced, except in full, ' - Dater 11/09/2018 04:27 PM without'the written consent of Pace Analytical Services,:LLC. Page.21 of 44 - Pace Analytical Services; LLC ytiVo1 CZI✓Pi/intZ' -. - 2225 Riverside Dr. Asheville, NC 28804 ". www..pacelabs.com (828)25477176 ANALYTICAL RESULTS Project: Laswnde. Pappas 18148201.01 Pace Project No.: ' 92405811 Sample:.Trip Blank . Lab ID: 92405811009 Collected: 11/02/18 00:00_ Received: 11/02/1,8 14:33 Matrix: Water , Parameters' Results Units .. PQL - MDL DF . Prepared -Analyzed CAS No:.. Qual 6200B MSV: Analytical Method: SM. 6200B - '. Benzene ND ug/L: 0.50 0.25. 1 11/09/18 11:25 71-434 . . Bromobenzene ND ug/L , 0.50 0.25. 1 11/09/1.8 11:25 108-86-1 Bromochloromethane ND . ug/L 0.50 0.25 1 11/09/18 11:25 .74-97-5 Bromodichloromethane ND ug/L '; . 0.50 . 0.25 .1' .. 1.1109/18 11:25: 75-2774 BroMoform.. ND . _ ug/L 0.60 0.25 1. 11109118.11:25' 15-25=2 . Bromomethane ND ug/L. 5.0 ' . 2.5 1 : 11/09/18 11:25 74-83-9 n-Butylbenzene ND ug/L_ . 0.50 0.25 1. 11/09/18 11:25. 104-51-8. sec-Butylbenzene- NO ugIL .'. 0'.50 0:25 1 11/09/18,11:251 135-98-8 tent-Butylbenzene ND.. - ug/L :. .0.50 .. 0:25 .. 1 11/09/18 11:25 ..98-06=6 Carbon tetrachloride .. `. ND ug/L . .. 0.50 0.25 1 11/09/18.11:25- -56-237-5 .. ' Chlorobenzene ND_ ug/L: 0.50 0.25 1 11/09/18 11:25 108-90=7 Chloroethane - 'ND ug/L 1.0 0.50_ _ 1 11/09/18 11:25 75=00-3 Chloroform ND ug/L 0150 6.25 .. 1 11/091/1811:25..67-66-3. Chloromethane .. ND uglL , ' : 1.0 .. 0.50 1' 11109/18 11:25. 1448773 2=Chlorotoluene' ND ug/L - _ 0.50- : - ' 0.25 1. 11109/18 11:25 '. 95-494. 4-Chlorotoluene ND ug/L 0.50. 0.25 1 11/09/1811:25 106-43.4 '1,2-Dibromo-3-chloropropane _ . ND ug/L, . 1.0 0.50 - 1 . 11/09/1.8 11:25 96-12-8_ " Dibromochloromethane• ND- .ug/L .. 0.50 .0.25 - 1 11/09/18.11:25. 124-48-1 1,2-Dibromoethane (EDB) ND ug/L :. 0.50 , 0.25 -1 11/09/18 11:25 ..106-93-4 Dibromomethahe ND ug/L ". ' .. 0:50 - 0.26 .1 - 11/09/18 11:25 -74-95-3 1,2-Dichlorobenzene ND ug/L: 0.50 0,25. 1 . _ 11/09/18 11:25. 95-50=1: 1,37Dichlorobenzene ND ug/L', 0.50 0.25, -1: 11/09/18 11:25 541-73-1 1,4-Dichlorobenzene. ND . ug/L' - 0.50- . 0.25 .. 1 11109/1811:25..106-46-7 Dichlorodifluoromethane ND. ug/L .. 0.50 .. 0.25 -1 11/09/18 11:25:.' 1541-8 1;1-Dichloroethane• ND .. ug/L: 0.50 0.25 1 . 11/09/18 11:25''.75-34-3 1;2-Dichloroethane ND' ug/L 0.50 0:25 1. 11/09/1811:25 107-06.2• .'1,1-Dichloroethene.. ND ug/L,. 0.50 '. 0.25 1.' .'. _ 11109/1.8-11:25- 75-35-4- cis-1,2-Dichloroethene. ND ug/L .. 0.50 0:25 : 1 11/09/18.11:25. 156-59-2 :. trans=1,2Dichloroethene ND: ug/L 0.50.. 025 ...1:." 11/00/1811:25..156-60-5 1',27Dichloropropane ND ug/L - -.0:50 .. 0.25 1 11/09/18.11:25 78-87-5 1;3-Dichloropropane ND ug/L 0.50 0.25 1 .11/09/18 11:25 142-28=9: 2,2-Dichloropropane, _ ND uglL 0.50 0.25. 1 : 11/09/1811:25 594-20-7 - 1,1-Dichloropropene . ND . ug/L 0;50, 0.25 1 11/09/18 11:25..563-58 6 cis71,3-Dichloropropene ND ug/L 0.50 .. 0.25 .' .1 - 1.1/09/18 11:251.' 10061-01-5- . trans-1,3=Dichloropropene ND - ug/L: 0.50 0.25 1 . 11709/18 11:25, .10061-02-6. Diisopropyl ether ND ug/L ' 0.50 0.25 . 11/09/18 11:25 108-20-3. Ethylbenzene ND ug/L - '0.50 - . 0.25 .1. .11/09/18 11:25 100-41-4. Hexachloro=1-,3-butadiene. ND ug/L .. 2:0 -' ..1.0. 1 '. 11/09/18-11:25. 87-68-3 Isopropylbenzene (Cumene) - ND ug/L 0.50:.. 0:25 .. 1 11/09/18 11:25 .98-82=8 Methylene.Chloride : -ND ug/L. 2.0.. 1.0 .1 _ 11/09/18.11:25 75-09r2 Methyl-tert-butyl ether ND.. . ug/L. .0.50 0,25. '.. 1 . .. ' : 11/09118 11:25'_ 1634-04-4 Naphthalene, ND ug/L 2..0 1.0- 1 11/09/1811:25 91=20-3 n-Propylbenzene ND ug/L 0:50 0.25 1- 11/09/18 11:25 .103-65-1. Styrene: ND ug/L 0.50 - : 0.25 1- 11-/09/18 11:25-. 10042-5 •1,1,1,2-Tetrachloroethane ND . • ug/L: 0.50 0.25 .1 1110911 a 11:25 630-20-6• 1,1,2,2-Tetrachloroethane . ND = ug/L • 0.50 ',. 0:25 1: 11/09/18 11:25 '79=34-5 REPORT OF LABORATORY ANALYSIS, . This; report shall not be reproduced, except in full, Dater 11/091201.8 04:27 PM without'the written consent of Pace Analytical Services, LLC. - . " Page.22 of 44 Pace Analytical.Services, LLC. �VG/`'lllahXYVJl - .. As2hevmi Riverside .11e, NC 2880404 wrnupacelabaxorn (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas 18148201.01 Pace Project No.: 92405811 Sample:"..Trip Blank ." " Lab -lb: 92405811009 Collected:: 11/02/18 00:00, Received: 11/02/18 14:33. Matrix: Water Parameters Results Units .. PQL MDL DF Prepared - Analyzed CAS No.. Qua] -6200B MSV:. Analytical Method:SM 6200B Tetrachloroethene: • ND" ' ug/L. 0.50 " ` , -0.25 1 . 11/09/18 11:25 127-184 Toluene ND ug/L _ 0.50 0.25 1 11/09/1811:25 108-88-3 " 1,2,3-Trich]orobenzene ND ug/L 2.0, 1.0 1 11709/1811:25 .87-61-6 1,2,4Trichlorobenzene, ND. ug/L 2.0 1.0 " 1 111/09/18 11:25' 120-82-1 1;1;1-Trichloroethane . ND ug/L 0.50 " : 0.25 ,.1 11/09/18:11:25 .71-55 6 1,1,2-Trichloroethane ' ND ug/L_ 0.50_ 0.25 1, 11/09/18 11:25 79-00-5, Trichloroethene ND ug/L _ . 0.50 0.25 1 11/09/18 11:25 79-01-6 Trichlorofluoromethane - ND - ug/L " :. 1.0. _ 0:50 1 _" 11/09/18 11:25. 75-69-4 - :. 1;2,3-Trichloropropane ND.." ug/L 0.50 0.25 .. 1 • 11/09/1811:25 . 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.60 0.25 1 11/00/18.11:25 95-63-6 1,3,5=Trimethylbenzene ND ug/L. 0.50 ' , .0.25. 1 11/09/.1811:25, 108-67=8: " Vinyl.chloride ND ug/L` 1.0 0.50 " 1. " . 11/09/18 11:25 75=01-4 m&p-Xylene ND .. ug/L 1.0" . 0.50 1 11/09/18 11:25..179601-2371 o Xylene ND ug/L 0.50 . 0.25 :. .1 11/09/18 11:25:. 95-47-6 Surrogates 1,2-Dich]oroethane-d4 (S) 89 % 70-130 1 11/09C18 11:25 17060-07.0. 4-13rom6fluorotienzene (S) :. 95 % 70-130. 1 " 11/09/18 11:25'. 460-00-4 Toluene=d8 (S) 102 % 70-130. 1 11/09/18.1.1:25:. 2037-26-5 QUALITY CONTROL DATA Project: Lassonde Pappas 18148201.01 Pace Project No.:. .92405611 QC Batch:` 441361 AnalysisMethod: SM 62008 QC Batch Method`.. SM.62006 - Analysis, Description::, : 6200B MSV, Associated Lab. Samples' 92405811001; 9240581100.21.92405811003; 924.05811004, 924058110051_ 92405811006, 92405811007, .92405811008,92405811009 METHOD -BLANK:. 2423744 " ' Matrix: -Water Associated Lab'Samples: 92405811001', 92405811002; 92405811003,.92405811004, 92405811005;.92405811006 92405811007,. . 92405811008,92405811009 _. .. .• Blank-'- Reporting Parameter - ;. Units Result • Limit MDL _ Analyzed ... :'Qualifiers 1,1;1,2-Tetrachloroethane, - ug/L ND - 0.50 .: 0.25,.11/09/1805:23 1,1,1-Trichloroethane ,'. :. vg/L ND' 0.50 0.25 .11/09/1805:23. 1;1,2,2-Teirachloroethane :. :; , Ud/L ND .. 0.50 0.25 :11/09/18.'05:23. 1;1,2-Trichloroeth6ne . - ug/L ND 0.50. . 0.25 - 11109/18.05:23- 10-Dichloroethane. ug/L ND. 0.50 0:25. 11/09/1805:23 1,1-Dichloroethene. ug/L ND 0.50 . '0:25 11109/18 05:23 1.;1-Dichloropropene : ug/L ND • _ 0.50 0.25 _ .11/09/18 05:23 1,2,3-Trichloropenzene ug/L ND 2.0 1.0 '.11/09/18-05:23. 1 2;3-Trichloropropane' ug/L - ND .. 0.50 . 0.25 '11/09/18 05:23 1,2;4-Trichlorobenzene ug/L. ND 2.0 : : 1.0 11/09/18 05:23 1,2,4-Trimethylbenzene ug/L. _ ND 0.50.. 0.25'..11/09/1805:23 . 1,2-Dibromo737chl6ropropane- ug/L ND 1.0 0.50 11/09/18 05:23. 1,2-Dibromoethane (EDB) ug%L ND ' .. 0.50 0.25 -11/09/18 05:23. .1,2-Dichlorobenzene'. - ' ug/L ND 0.50. 0.25- 11109118.05:23 1,2-Dichloroethane. ug/L ND. _ 0.50 0.25: 11/09/18-05:23 1,2-Dichloropr0pane aug/L ND 0.50 ' 0:25 - 11/09/18 05:23 1;3;5-Trimethylberizene '. ug/L ND .. 0.50 0.25' .11109/18 05:23 1,3-Dichiorobenzene..... • ug/L ND : 0.50. 0.25 -.11/09/18.05:23., 1,3-D'ichloropropane ug/L ND 0.50 . 0.25 -11/09/18 05:23 1 A-Dichlorobenzene - ug/L. NO .0.50 , , 0.25 11/09/18 05:23 2,2-Dichloropropane : ug/L .. ND .0..50 ... 0.25, . 11/09/18 05:23' 2-Chlorotoluene ug/L ND' . � - 0.50 0.25 '11/09/18 05:23 4-Chlorotoluene. ub/L ND .. 0.50 - 0:25 :11/09/18 05:23 Benzene. _ ug/L' ..ND 0.50.. 0.25- 11/09/18 05:23. Bromobenzene ug/L. ND. .0.50 0:25: -11/09/18.05:23 Brornochloromethane ug/L ' ND 0.56 . 0:25-. 11/09/18 05:23 Bromodichloromethane ug/L ND .. 0.50 0.25 -11/09/18 05:23 . Bromoform: .. ug/L ND 0.5Q 0.25 .11/09/18.05:23. Bromomethane ug/L ND 5.0 2:5 -11/09/18 05:23 Carbon tetrachloride _ ug/L ND, .0.50 0.25 11/09/18 05:23 , Chlorobenzene ug/L . • 1JD 0.50 :.' 0.25, . 11/09/18 05:23 Chloroethane . vg/L ND 1.0 .0.50 .11/09/1805:23 Chloroform ug/L ND 0.50 , 0:25 :11/09/18 05:23. Chloromethane . ug/L ND 1.0, 0.50 11109/18.05:23 cis- 1,2-Dichloroethene' . ug/L ND. 0.50 0:25. 11/09/18 05:23 cis-1;3-Dichloropropene ug/L ND 0.50. 0125 . 11/09/18 05:23 D'ibromochloromethane ug/L ND 0.50 0.25 11/09/18 05:23 D'ibromomethane ug/L ND 0.50. .0.25 .11/09/18 05:23 Dichlorodifluoromethane : ug/L ND 0.50 0.25 11/09/18.05:23 Diisopropyl ether--:' ug/L.. NO .0.50. 0.25 11109/18 05:2.3 Results presented on this page' are in the units indicated by the "Units" column except where'an alternate unit is presented to the right of the result: REPORT OF LABORATORY ANALYSIS. This: report shall not be reproduced, except in full, Date: 11/09/2018 04:27 PM without the written consent of Pace Analytical Services, LLC. Page.24 of 44 Pace Analytical Services, LLC. acEAf g ® CIe?/yIICe?�. 2225 Riverside Dr. Asheville, NC 28804 www.pacelabs.com- - (828)254-7176 '. QUALITY CONTROL DATA Project: - Lassonde Pappas 18148201.01 ,Pace Project No.: . 92405811 METHOD BLANK: .2423744. Matrix: Water' - Associated Lab. Samples:. 92405811001,.92405811002, 92405811003' 92405811004, 924058.11005, 92405811006, 92405811007, 92405811008;92405811009.; Blank Reporting . Parameter Units Result Limit MDL. Analyzed Qualifiers Ethyllienzene ug/L' ND 0.50. 0:25 . 11/09/18 05:23 Hexachloro-1,3-butadiene, ug/L: ND 2:0 :: 1 0. 11/09/18 05:23. Isopropylbenzene (Cumene) . ug/L" ND 0.50 -0.25- .1.1/09/18 05:23 m&p Xylene u9/L ND .. , ..... 1:0 . 0.50 11/09/.18 05:23 '. Methyl-tert-butylethe[ ug/L ND 0.50. , 0.25 1.1/09/18 05:23 Methylene Chloride ug/L::. ND 2.0 ;. 1.0: 11/09/18 05:23 _. . n-Butylbenzene ug/L ND 0.50- 0.25' 11/09/18 05:23 . n-Propylbenzene :. ug/L ND. 0.50 0.25. .11/09/18 05:23 Naphthalene : ug/L ND :.. 2.0 ': .1.0 11/09/18 05:23 o-Xylene .. ug/L ND '. 0.50. 0.25• '11/09/18 05:23, sec-Butylbenzene ug/L ND 0.50. • . 0:25 . 11/09/18 05:23 Styrene .. ug/L ND 0.50 ` 0.25. -11/09/18 '05:23 tert-Butylbenzene . ug/L ND . 0.50 0:25 1.1/09/18 05:23 Tefrachloroethene ug/L ND .: 0.50 - -0.25 .11/09118A5:23 Toluene ... ug/L- _ ND- 0.50.. 0.25 11/09/1805:23 . trans-.1,2=Dichloroethene . ug/L : ND 0.50' :: 0.25. 11/09/18 0523 :trans=1,3-Dichloropropene; .'. ug/L • ND .:. 0.50 ." .0.25 11/09/18 05:23- Tr'ichloroethene .. ug/L ND 0.50 0.25. :11/09/18.05:23 TrichlorofluorohJethane ug/L ND ; : 1:0 0.50 11'/09/18 05:23 Vinyl chloride ug/L ND ' . 1.0 0:50 11/09/18 05:23 1,2-Dichloroethane-d4 (S) . % : 89 ` : 70-130 . 11109/18 05:23 .. 4-Bromofiuorobenze.ne ,(S) % 99 70-130 . 11/09/18 05:23. Toluene-d8 (S) % . - .102 . 70-130 11109/18 05:23 .. . . LABORATORY CONTROL SAMPLE:. 2423745 ...Spike CCS• ..- LCS , ... % Rec. .Parameter Units Conc. Result -- ' -% Rec .. Limits Qualifiers' ' 1,1,1,2-Tetrachloroethane .. ug/L :- 50 -45.9 92.' .: 60-140 . 1,1 jJrichloroethane ug/C 50. - 45.4 91 60-140 1,1,2,2-Tetrachloroethane ug/L 50 .. 43.7 87 60-140 1,1,2-Trichloroethane ug/L .- 50 .45.9 92 60-140 . . 1,1-D1chloroethane'. ug/L 50. - -44.8 90 .60-140' ' T 1-Dichloroethane ;- . ug/L 50 46.7 93 ... 60-140 - 1,1=Dichloropr9pene ug/L" 50 : 44.7 89 `- . .60-.140 1,2;3-Trichlorobenzene : ug/L 50 40:0:: 80 60-140. 1,2,3 Trichlo�opropane . ug/L 50 44,9 90 60-140 . . 1:;2,4-Trichlorobenzene Ug/L 50 - 41.2 82. 60-140 = 1,2,4-Trimethylbenzene: ug/L• 50 _ 42.0 84, 60-140 1,2-0'1brorno-3 chloropropane ug/C.. $0. 46:0 92 60 140 . . 1,2-Dibromoethan6.(EDB) ug/L. 50 45.8, 92 66-140 .'1,2-Dichlorobenzene ' u9 /L . 50 .43.1 86 6.0-140 1,2-Dichloroethane vg/L 50. 42A. 84 60-140 1;2-Dictiloropropane ;_. ug/L 50- . • 45.4 91 _ .60-140. . . - Results presented on this.page'are in the units indicated by the "Unite" columnexcept where* an alternate unit is presented to the right of the result:' REPORT .OF LABORATORY ANALYSIS... . This report shall not be reproduced. except in full, Dater 11/09/201.8 04:27 PM without the written consentof Pace Analytical Services, LLC. Page.25 of.44 Pace Analytical.Services, LLC ® aceAnalyt 01 2225 Riverside Dr.. . S A heville, NC 28804 -.pacefabs_com (828)254-7176 QUALITY CONTROL DATA Project: Lassonde Pappas 18148201.01 Pace Project No.: 92405811 LABORATORY CONTROL SAMPLE:. 2423745 Spike . LCS LC.S , Rec . Parameter " _ Units .. Cond.. Result - % Rec - Limits. Qualifiers . . 1;3,5-Trimethylbenzene ug/L 50. 41.2 82 .60-140 1,3=Dichlorobenzene ... ug/L 50 42.1:: .84 60-140. 1,3-Dichloropropane ug/L 50 46:7 '93 60-140. ' 1+Dichlorobenzene . " ug/L'; .50 42.4 85 60-140 2,2-Dichloropropane ug/L 50. 39.7 79. 60-140" 2-Chlortitoluerie . ug/L 50 41,7 .83 - . 60-140 . 4-Chloroto.luene ug/L. 50, . .42.5 -85 60-140 .. - Benzene ug/L 50 46.5. 93 .. 60-140 Bromobenzene ug/L _ . -..50 44.3 -89. 60-140" Bromochlorornethane . - " ' uglL 50 46.7 _ : 93 60-140 Bromodichlorometharie ug/L 50- 45.3 .91 ; 60-140. . " . Bromoform " - - ug/L 50 43,4 `. _ 87 .. 60-140.. . Bromomethane ug/L . 50 39.7 '79 60-140 :. • Carbon_ tetrachloride ug/L 50- 45.5 91 60-140 Chlorobenzene ug/L : 50 . ' : 44:7 89 60-140 Chloroethane "` .. ug/L :50. 53.4 : .. .107 .60-140 . Chloroform . - ug/L .60 ...... :.47.4 -95 .. 60-140 -Chloromethane ug/L .' 50 32.3. 65 60-140 . cis-1,2-Dichloroethene .. ug/L .50 44.3 89. 60-140 cis-1,3-Dichloropropene ug/L 50 46.2 92 60140 " Dibromochloro:methane ug/L -50.. 46.2 92 , . 60-140- Dibromomethane -. ug/L 50'. 47.1':• 94' ... 60-140- Dichlorodifluoromethane_ ug/L 50 _ 38:1 76 . '' 60-140 Diisopropyl ether : ug/L_ - -.50 50 41.0 82 60-140 .. Ethylbenzene :"" ug/L 50 414 87. 60-140 Hexachloro-1,3-but6diene ug/L :50" 31.5 .75.. - 60-140. Isopro pylbenzene (Cuniene) -" ug/L. 50 . 43.9, 88 60-140 m&p-Xylene. ug/L .. .. 100 .. . _ 87.3.. .87 607140 Methyl-tert.butyl ether ug/L . ":. 50 44:1' 88. 60-140 Methylene Chloride :. ug/L 50 48.3 87 .. 60-140 n-Butylbenzene . ug/L- 50 38.2 16 : 60-140 n-Propylbenzene ug/L 50 42.3 85 60-140. Naphthalene. ... ug(L " 50 .4018 81 60 140 o-Xylene :: : . "ug/L '.50 44.9 90 60-140 ." sec-Butylbenzene. ug/L 50 . 40:9 82 60-140 Styrene . uglL. : 50 44.6 89' .. 60 140 .. . tert-Butylbenzerie ug/L. 50 , . 36.6 .. 73 60-140 Tetrachloroethene ug/L _ 50 " :. 41.3. 83 _ .. 60-140' . Toluene . ' ug/L 50 41.9 ' 60-140 trans-1,2-Dichloroethene ug/L 50 45.0 _84. 90 60-140.-- .. trans-1,3-Dichloropropene" .. ug/L 50.. 46.8 94 -60-140. Trichloroethene: ug/L 50'. 45A _ 90 60-140. " Trichlorofluoromethane " ug/L 50 498 .99 -_60-140 - . Vinyl.chloride .. ug/L 50 47.3' 95 60-140 . 1,2-Dichloroethane=d4 (S) %" 92. 70-130 4-Bromofluorobenzene (S) :. % 99 - 70-130 Toluene-d8 (S) % . 102 70-130 . Results presented on this page are in the units indicated by the "Units" column except where -in alternate unit is presented to the right of the result: REPORT OF LABORATORY ANALYSIS. This report -shall not be reproduced; except in full, Date: 11/09/2018 04:27 PM without the written consent of Pace Analytical Services, LLC. Page.26 of:44 Pace Analytical Services; LLC /+Q /{!� / /+ I ® 2225 Riverside Dr. ' f l�G/'111alWa1 .Asheville, NC 28804 .. www.pacelabs.com (828)254717 6 QUALITY CONTROLDATA Project: Lassonde Pappas 18148201.01 Pace Project No.: 92405811 MATRIX SPIKE& MATRIX SPIKE DUPLICATE:- _ 2423764 . .. 2423765. MS': MSD _. 9240581100T Spike Spike ; MS MSD: MS MSD % Rec Max Parameter: -Units . Result Conc. Conc.. Result Result % Rec % Rec . Limits RPD RPD "Qua[ ". 1,1,1,2-Tetrachloroethane: ub/L ND. 20 : 20 „ :18.7 19.3 93 97 .60-140 .3 30- 1,1,1=Trich[oroethane ug/L ND :. 20. '. 20 19.7 . 19.2 99 96 60-140 . 3 : 30 1,1,2,2-Tetrachloroethane ug/L. ND 20 20 18.2 18.0, 91 90 60-140. 1 30. 111,2-Trich[oroethane ug/L . ND ,' -20 . -20 19.8 .20,2 .99 101 607140 .'2 30 1,1-Dichloroetiiane ug/L ND . 20 :. 20 19.2 19.1 96 95. 60=140 0 30 111-Dichl'oroethene ug/L ND' 20 20:. 21.7 22.1 100 111: 60=140. 2 : 30 1,1=Dichloropropene ug/L ND 20, 20 20.7 19.8 103 99. 60-140 . 4 3.0 1,2,3-Trichlorobenzene : ug/L. ND 20, 20 .: 16.5 17.2. 82 .' '86 . 60-140 4 30.'.' 1,2;3-Trichloropropane ug/L :. ND . 20 20. 18.1 18.3 .. .90 91. 60-:140 1 30 1;2;4-Trichlorobenzene ug/L :. ND_ 20- .. 20 16.7. 17.0 :. 83 85. 60-140 . 2 30 1,2,4-Trimethylbenzene : `ug/L ., .: ND. 20 20 -18.1 18:1 91 91, .60=140 0 30 1,2-Dibromo-3 ug/L ND 20. 20 17.1 17.9 86 . 89 60-140 4 30 '. chloropropane :. 1,2-Dibromoethane (EDB) ug/L ND 20 "' 20. 19.2 18.4 96 : 92 . 60-140 . 4 30. . .12-Dichlorobenzene ug/L . ND 20 20. .17.9 17.7, 90. . 88 60-140 . 1 .' . 30 . - 1,2-Dich[oroethane .. ug/L -. ND .. 20 . 20, 17.5 17.4 .. 88 87.' 60-.140 1 30 1',2-Dich[oropropane : ug%L .. ND 20 .. .20 19.3:. 18.8 96 94 60 140 2 30 1,3,5-Trimethylbenzene ug/L .. ND 20 _ 20 18.0 -18.1 90 " 90 60-140 0 30 1,3-Dichlorobenzene ug/L „ ND 20. 20 : 18.5.. 17.8 93 89 60-140 . . 4 30 1,37Dichloropropene. ug/L ND 20 20 ' . 19.3 18.8. 9T. 94 . '60-140 ' 3 30 . 1,4-Dichlorobenzene: ug/L . -ND ." 20 - 20. 18:2 18:2 91 91 60 1.40 0 30 2,2-Dichioropropane ug/L - ND . 20 - 20 19.4 '19.0 .97 95. 60-.140 2 .30 . 2,Chlorotoluene,' ug/L ND :: .20. 20: 18.1 ._ 17.8 91 89. 60440 2 30. 4-Chlorotoluene '.. - " . ug/L .::: ND'.. - 20 20 17.9 18.0 " . - 89 :. 90"_ .60-140.: 1 30 Benzene ug/L. ND .20 20 20.4 20.0. 102- 100- 60-140 2 .-30".' Bromobenzene ug/L ND 20 20 19.0 18.9 :- 95 94 60-.140 _ 1. 30 Bromochloromethane - ug/L .. ND. 20 20 19.8:. 19.4 99 97 60-140 .2 30 Bromodichloromethane. ug/L ND 20 '. 20 18.3 . 17.7 92 " 89:. 60=140 - . 3 '30 - Bromoform ug/L ND ':. 20. 20 : 15.8 16.2 79' 81 60-140 3 : 30 ' Bromgmetha.ne i ug/L. ND,, 20 20 21.4 - 20.7 107, 104 60-140 - 3 " 30 Carbon tetrachloride ugjL . ND 20 20. 19.9" -%5 .99 98 60-.140 2 " .30- Chlorobenzene ug/L,, , : ND 20 _ 20 19.5 18.9 98 95 60;140. 3 30 Ch[oroethane . ug/L " ND 20 .' . , 20:- .23.1-.. 22.8 115 _ _ _ 114. 60.140 -'1 : 30 Chloroform :. ug/L _.. ..ND, 20 20, - 19.3 19.0 "" .: 96 :: 95 .. 60-140 ' 1. -30. . Chloromethane ... ug/L. ND ". .20 _ 20. AO.A .. 13.4. 54 67 . 6..0-140 .' 21... 30.-M1- cis-1,2=Dichloroethene ug/L .. ND . 20 . 20. 18.4 18.2 92 91" 60-140 2.. 30 . ;. cis- 1,3-Diich[oropropene ug/L :_ ND _ 20' 20 19.4 20.7 97 104 60-140 7 30 Dibromochloromethane ug/L ':: ND 20 20 18.2 . 18.2 91 91 60-140 0 30: Dibromomethane.. ug/L ND :: 20. ,.. 20 - 19.6 19.8 98 99 - 60-1.40 . 1 30 Dichlorodifluoromethane ug/L ND 20 20:- 17.5 16.4 88:: 82 60-140 ; 7 30 ' '. Diisopropyl ether '. -ug/L . ND 20 .20-1 16.7 16:3 84 81 60-.140 3 30 Ethylbenzene . ug/L .. ND 20 20 18.8 18.6 94 93 . 60-140 1 30 Hezachloro-1,3-bu6cliene ug/L .. ND 20... 20:_ 16.1. 17.1 86 :86" .60-1.4.0 6. 30. " Isopropylbenzene.(Cumene)' ug/L ', . • ND 20 .. 20. .18:5 18.9' _ .. 93' : 95 .60-140 2. 30. . m&p-Xylene ug/L. ND .40 40... .37.5 37.1. 94 93 .60-140. 1. 30..: : MethylAert-butyl ether. ug/L .. ND 20 . 20. 19.0 18.6 95 93 6.0-140 2- 30 ." . : .'Results presented on this.page'are in the units indicated by the "Units" column except where an alternate unit its presented to the right of the result: REPORT OF LABORATORY ANALYSIS -. . This reportshall not be reproduced, except in full, Dater 11/09/2018 04:27 PM without the written consent of Pace Analytical Services, LLC. Page.27 of 44 PaceArialytical Services, LLC' q,, ® �CE/ 2225 Riverside Dr. tll�IIC�I Asheville, NC 28804 www.pacelabs.com (828)25477176 QUALITY CONTROL DATA Project: - Lassonde Pappas 18148201.01 Pace Project No.: 92405811 QC. -Batch: 440180 " Analysis Method:. SM 2540C-2011 QC Batch Method. SM:2540C-2011 . _' Analysis Description: . 2540C Total Dissolved Solids, Associated Lab Samples'. 924058.11001 METHOD BLANK: 2418298 Matrix: Water Associated Lab Samples: 92405811001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Dissolved.Solids, . mg/L ND 25.0 25.0 11/03l18 14:41 . LABORATORY CONTROL SAMPLE:' 2418299 Spike LCS LCS _ Rec Parameter Units Conc. Result %:Rec . Limits Qualifiers Total Dissolved Solids mg/L 251 250 100 90-110 SAMPLE DUPLICATE: 2418300 .92,405725010 -Dup. Max Parameter Units . - " "" Result Result RPD RPD _ Qualifiers Total'Dissolved Solids mg/L 67.0 . 61.0 9 5 D6 SAMPLE DUPLICATE: :2418305 924.05753003 Dup Max Parameter, .. Units Result Result RPD RPD Qualifiers Total: Dissolved Solids . mg/L 86.0 _ . 87.0 . 1 5 Results' presented on this page are in the units indicated by the "Units" column except wherein alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This, report shall not be reproduced, except in full, Date: 11/09/201.8 04:27 PM without the written consent of Pace Analytical Services, LLC. Page 29 of44 Pace Analytical Services, LLC ® aceAlai/Xical ' 2225 Riverside Dr. ', Asheville, NC 28804 . . .. twnvpacelabacom (828)25477176 QUALITY CONTROL DATA . . Project: Lassonde, Pappas .1814820 1.01 Pace Project No.: _ 92405811 QC Batch:: 440708 :: -Analysis Method:.. ." SM 2540C-2011' - QC Batch Method: SM2540C-2011 Analysis Description: - .. 2540C Total Dissolved Solids. ' Associated Lab Samples' .92405811002; 924Q5811003; 92405811004; 92405811005, 92405811006,.92405811007.92405811008 METHOD BLANK:, 2420669 Matrix: Water: Associated -Lab Samples:. '92405811002; 92405811003;:92405811004, 92405811005, 92405811006; 92405811007; 92405811008: Blank Reporting Parameter Units 1 Result. Limit MDL Analyzed Qualifiers. Total Dissolved -Solids . mg/L ND 25.0 25.0 .11/06/18 19:23. LABORATORY CONTROL SAMPLE:..2420670 Spike - LCS : LCS . %. Rec . . Parameter Units Conc: - . Result . %`Rec . Limits Qualifiers Total Dissolved Solids mg/L 251 .' : 246 98 90-110 SAMPLE DUPLICATE: ' 2420671 . 92405976001 , . DU p - Max. ".. Parameter Units .. Result Result . RPD ' _ _ RPD ." Qualifier's'.' Tota[ Dissolved Solids . mg%L'. 47.0 - 51.0 - . 8 " 5 D6 SAMPLE DUPLICATE`: :2420672 . . 9 2404937013. .Du Max Max Parameter , Units . -Result Result RPD RPD Qualifiers Total.Dissolved Solids q mg/L 387 .. :305 1 5 Results presented on this -page are in the units'indicated by the "Units" column except where an alternate unit is presented to the right of the result:' REPORT OF LABORATORY ANALYSIS This reportshall not be reproduced; except in full, , Date: 11/09/201,8 04:27 PM without the written consent of.. Pace Analytical Services,-LLC. '_ - P.age.30 of 44 Pace Analytical Services; LLC ® a AI In n LIc al ICI. 2225-Riverside Dr.- Asheville, NC 28804 www.pacelabs.com (828)25477176 QUALITY CONTROL DATA Project: Lassonde Pappas 18148201.01 Pace Project No.: 92405811 QC Batch:' 440609 Analysis Method: EPA 350.1-Rev 2.0.1993: QC Batch Method-.. 350.1 Rev 2.0 1993 Analysis Description: .: 350.1.Ammonia' Associated Lab. Samples' 92405811001, 92405811002;.92405811003, 92465811004, 92405811005 - METHOD BLANK: 2420112 Matrix: Watec Associated Lab Samples: 92405811001, 92405811002,.92405811003, 92405811004, 92405811005 Blank - Reporting . Parameter Units Result Limit -MDL Analyzed Qualifiers Nitrogen, Ammonia :. mg/L ND 0.10 0.050 _ ..11/08/1 S 11:3.4 . LABORATORY CONTROL. SAMPLE_ : ' .2420113 Spike -LCSLCS .%.Rec . Parameter Units Conc: Result, %:Rec Limits Qualifiers Nitrogen, Ammonia: frig/L 5 5.1 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2420114 2420115- MS . MSD 92405648002 . Spike Spike '_ MS MSD_. MS ;. MSD % Rec . Max.. . Parameter Units Result Conc: Conc. Result Result • " % Rec % Rec Limits . RPD. RPD -:Qual . Nitrogen, Ammonia mg/L :_ ND. 5 5: 5.0. 5.0 100 100 " 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE -DUPLICATE`. 2420116' 2420117 MSMSD.* 92405708001 Spike. .. Spike M.S. MSD MS. MSD %Rec Max Parameter:.. Units :. Result Conc. Conc.. Result .. Result .% Rec % Rec : Limits RPD RPD . Qual Nitrogen; Ammonia mg/L 79.2 5 5. 87.1 87.1 A59 :: 159 _. 90-110 : 0 _ 10.. M6 - . - Results'presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result: REPORT OF LABORATORY ANALYSIS.. . This reportshall not be reproduced; except in full, Date: 11/09/2018 04:27 PM without the written consent of Pace Analytical Services, LLC. Page.32 of 44 Pace A alytical Services; LLC ® aceAnalytical 2225 Riverside Dr. 28804 www.pacelab.s1c nl. Asheville, NC .. . (828)254-7176 QUALITY CONTROL DATA. - Project: Lassonde Pappas 18148201.01 Pace Project No.: ' 92405811 QC Batch :: 440610 :: Analysis Method:' EPA 350.1 Rev 2.Q 1993 QC'Batch Method` . .EPA350.1 Rev 2.01993 Analysis. Description: 350;1.Ammonia Associated Lab Samples: 92405811006, 92405811007; 92405811008 METHOD BLANK: 2420121. Matrix: Water Associated Lab Samples:. -92405811006; 92405811007; 92405811008. . - Blank Reporting Parameter Units Result_ Limit MDL Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 0.050 _11/08/18 12:20 LABORATORY CONTROL, SAMPLE: ,2420122 - Spike LCS LCS . - %.Rec Parameter Units : Cone; . ° Result : WRec Limits,Qualifiers Nitrogen, Ammonia. .. mg/L _ .5 5.2 104 90-110 MATRIX -SPIKE & MATRIX SPIKE DUPLICATE::. 2420123 .. '2420124 MS. MSD . 12405811.006:.. Spike Spike MS: MSD, MS MSD % Red :. Max.. . Parameter '. Units Result Cone.. Coric: '.. Result Result:- .% Rec % Rec Limits . •RPD. RPD .:Qua]. Nitrogen,. Ammonia mg/L ND. 5 5 • 5.0 5.0 := . 99 100 • 90-110 - ..1. 10 MATRIX -SPIKE & MATRIX SPIKE DUPLICATE: 2420125 :2420126 .: MS MSD 9240579900.1 Spike. .. Spike MS- MSD MS.: MSD . %Rec Max. -.- Parameter'- . Units .. Result Code. Cone. Result :. Result .% Rec % Rec . Limits RPD RPD Qua[ - Nitrogen, Ammonia- '. mg/L :ND - , . 5 . 5. - 5.1 ' :_ 5.1 .102.. 102 90-110 : 0 10_. - - Results'presented on this.page'are in the units indicated by the "Units-" column except wherein alternate unit is presented to the right of the result; . REPORT OF LABORATORY ANALYSIS'.'. . This report not be reproduced; except in full, Dater 11/09/2018 04:27 PM withoutthe written consent of Pace Analytical Serdices, LLC. Page.33 of 44 Pace Arialytical.Services, LLC ® ace_ Analyiical 2225 Riverside Dr. Asheville, NC 28804 www.pacelabs.com .. (828)2544176 QUALITY CONTROL DATA Project: Lassonde Pappas 18'148201.01 Pace Project No.: 92405811 ' .. QC Batch:` 440144 Analysis Method: -EPA 353.2 Rev 2:0 1993 QC Batch Method`.. EPA 353.2 Rev 2.0 1993 Analysis_ Description: .: 353:2. Nitrate + Nitrite; Unpres. . Associated Lab.Samples: • :92405811002; 9240581100.3, 92405811004i 92405811-005, 92405811006, 92405811008.-. METHOD BLANK: 2418200 Matrix: 1Nater Associated Lab Samples: . -92405811002; 92405811003;:92405811004, 92405811005, 92405811006, 92405811008" - Blank Reporting Parameter Units Result Limit MDL- Analyzed. -Qualifiers. Nitrogen, Nitrate - mg/L ND .. o.020 0.010 :11/02/18 23:37 LABORATORY CONTROL SAMPLE: '2418201 Spike • l LCS LCS . %. Rec Parameter Units Conc. .. Result . %:Red . Limits Qualifiers Nitrogen, Nitrate :: rng/L - 1.5 116 1.07 90-110 . MATRIX SPIKE & MATRIX SPIKE DUPLICATE:. 241.8202 2418203 - "- _ .. MS. MSD 92405850001 . Spike Spike MS ;MSD_ MS " ;.' MSD % Rod Max. Parameter Units Result 'Conc. Conc: ..Result Result . %Rec .. %Rec Limits .RPD RPD..;Qual. . Nitrogen, Nitrate = mg/L ND. : 1.5. 1.5: -0:87 0.88 .58 59 90=110- ..2: 10 MATRIX SPIKE &_MATRIX SPIKE DUPLICATE:-2418204 2418205 . . - MS "MSD 92405850011 Spike. Spike MSMSD MS.. MSD' %Rec Max' -Parameter... Units . - -Result Conc. Conc. _ Result :. Result % Red % Rec : Limits RPD RPD Qual Nitrogen; Nitrate mglL '. _ .' ND •1.5 1.5. 1.6 - _: 1.5 905 _; 103 90-110: 3. 10.. - _ 'Results presented on this.page'are in the units' indicated by the "Units" column except where'an alternate unit is presented to the right of the result: REPORT'OF LABORATORY ANALYSIS '. This, reportshall not be reproduced; except in full, Date: 11/09/201.8 04:27 PM a without the writteri consent of Pace Analytical Services, LLC. Page.34 of 44 Pace Analytical Services, LLC ® aceAnalwical 2225 Riverside Dr. Asheville, NC 28804 www.pacelab.s..com (828)254-M6 QUALITY CONTROL DATA . Project: Lassonde Pappas 18148201.01 Pace Project No.: .92405811 :'.QC Batch: 446145 Analysis Method: EPA 353.2 Rev 2.0.1993 QC Batch_Method: EPA 353.2 Rev 2.0 1993 Analysis. Description; 35.12. Nitrate + Nitrite, Unpres. Associated Lab.Samples: 92405811001, 92405811007 . METHOD BLANK:- 2418206 Matrix: Water Associated -Lab Samples: 92405811001, 92405811007 . Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.02.0 0.010 11/03/18 00:11 LABORATORY CONTROL SAMPLE:: ,2418207 Spike.. ' LCS LCS . % Rec Parameter Units . Conc: - . Result %_Rec . Limits Qualifiers Nitrogen, Nitrate :: mg/L 1.5 1.6 108 90-110 . MATRIX SPIKE & MATRIX SPIKE DUPLICATE:: 2418208 2418209 MS MSD 92405811001 Spike Spike MS MSD MS MSD % Rec - Max Parameter Units Result Conc. Conc. Result Result % Rec %Rec .Limits RPD RPD Qual. - Nitrogen, Nitrate mg/L : 0.48 1.5 1.5 2.1 - 2.0 - 106 103 90-110 ..2 10 Results presented on this page'are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This: report shall not be reproduced; except in full, Date: 11/09/201.8 04:27 PM without the written consent of Pace Analytical Services, LLC. _ Page 35 of:44 Pace Analytical Services, LLC ® aceMalidic0l 2225 Riverside Dr.. Asheville, NC 28804 . . wwwpacelabs.corn (828)254-7176 QUALITY CONTROL DATA . Project: Lassonde Pappas 18148201.01 Pace Project No.:_-92405811 QC Batch: 440423 ` Analysis Method:. EPA 365.1 Rev 2.Q 1993 QC Batch Method-. . EPA 365.1 Rev 2.0 1993 Analysis_ Description:' 365.1. Phosphorus; Total Associated Lab Samples' 92405811001, 92405811002, 92405811003; 92405811004, 92405811005, 92405811006,,9240581100.7; ".. . 92405811008 METHOD BLANK: ' 2419261 Matrix: Water Associated Lab Samples: 92405811001, 924058.11002; 92405811003,.92405811004, 92405811005;.92405811006, 92405811007, 92405811008 Blank Reporting Parameter Units Result Limit - MDL _ . Analyzed _- . :Qualifiers Phosphorus" mg/L . ND-0.050"..: 0.025. 11/06/18 20:15 LABORATORY CONTROL SAMPLE: 24.19262.. Spike LCS. LCS. %'Rec . Parameter Units Cone., Result % Rec ':: Limits . Qualifiers. Phosphorus :. mg/L 2.5 2.7 106: 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: . 24192133. 2419264: MS': MSD . 92406686006 Spike' Spike . MS MSD MS . MSD .. % Rec . Max ' Parameter: Units - Result , . Cone. -Cone.. _" R'esult, -" Result % Rec %Rec Limits" ROD: RPD " :Qual "Phosphorus .: mg/L 0.69: _ 2.5 2.5 • . 3.3". 3:3 104 - .' 104_ . 90-110 . '. 0 10' MATRIX SPIKE &-MATRIX SPIKE DUPLICATE:.. 2419265 2419266. MS :. MSD 9240581.1005 Spike - Spike ' : MS MSD MS- .. MSD % Rec. Max. " Parameter .. Units Result Cone. Cone. ' ._'Result Result % Rec :: % Rec _'.Limits .RPD. RPD..-Qua] . Phosphorus' mg/L 0.25 . 2.5 2.5 0:27 0.27 1 1 90=110 - 2 10 M1: Results presented on thispage are fn the unitsindicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS.. . This report shall not be reproduced, except in full, Date: 11/09/201.8 04:27 PM without the written consent of. Pace Analytical Services, LLC. Page.36 of44 Pace A alyticaLServices, LLC , g�++QQ �/{{I/7�e� �{++gg//® G!V{r/'lI1QIttItJRI ... 2225 Riverside Dr. Asheville NC28804 .. . wwmpacelabs.com .. _ (828)254 7176 QUALITY CONTROL DATA' Project: Lassonde Pappas 18148201.01 Pace Project No.: 92405811 QC Batch :: 440291 ' Analysis Method: SM 4500-CI-E-20.11 QC Batch Method; SM:4500 CI -CI _'" : Analysis. Description:. 4500 Chloride Associated Lab Samples' '92405811001, 924058110021:92405811003; 924.05811004, 92405811005, 92405811006;.92405811007; 92405811008 METHOD BLANK: .2418582' . Matrix`. Water "- Associated Lab Samples: 924058110011 924058.11002, 92405811003, 92405811004, 92405811005192405811006, 92405811001, 92405811008 . Blank Reporting Parameter _ Units Result Limit MDL Analyzed : Qualifiers Chloride... mg/L .: --ND 1..0 .. 0.50:. 11/05/18 19:51 LABORATORY CONTROL SAMPLE: 24.18583. Spike LCS CCS. % Red Parameter Units Conc:. Result % Rec Limits . Qualifiers. Chloride mg/L _ 20-- 19.8 . • 99 : 90-110. MATRIX SPIKE& MATRIX SPIKE DUPLICATE: _. 2418584 '. - 241a585,, . .. S MSD .... M 92405702001 Spike Spike MS MSD MS MSD % Rec . Max Parameter:_ Units. Result'.. _Cone. Conc.. Result. _ Result%Rec %.Rec Limits RPD.RPD Qual Chloride mg/L 7.5 . 10 10 _ . 17.1 1.7.2 96 97 : 90-116 1 10' .: MATRIX SPIKE &MATRIX SPIKE DUPLICATE:. . 2418586 2418587. = ` MS•: MSD.. 92405562001' :Spike. Spike MS MSD : MS MSD .% Rec. .. ; Max... Parameter Units •' Result Conc.. Conc. 'Result- Result %Rec'_ . %Rec Limits :RPD. RPD..Qual . Chloride: mg/L 75.6 . 10 : 10 80.2 81.1 46 . ... 55. 90-110, 1 .10 M1. ' Results` presented on this.page are in the units indicated by the "Units" colummexcept where' an alternate unit is presented to the right of the result; - REPORT OF LABORATORY ANALYSIS.' This reportshall not be reproduced, except in full, Date: 11/09/201.8 04:27 PM b without the written consent of Pace Analytical Services, LLC. - . ` Page,37 of 44 Pace Analytical Services; LLC . , ® �• aceAnal 2225 Riverside Dr. .rcal: Asheville, NC 28804 wwwpacelabs.com (828)25477176 QUALITY .CONTROL DATA:CROSS. REFERENCE TABLE Project: _ Lassonde. Pappas ,18148201.01. 'Pace ProjectNo.: •-.92405811 .. .. ,. Analytical Lab; ID Sainple 16: '.. QC Batch. Method •. QC Batch' : Analytical Method Batch 92405814001. : MW-4 SM6200B .. -441361`:. " . 92405811002 : MW-5_- .:. -SM.6200B.. 441361: -92405811003` '.'MW-6 SM6200B-. 441361.. 92406811004 MW=711 SM 620013 1• '. .441361 . 92405.8110.05 • MW.8 :. SM 6200E 441361 ' -. 92405811006 MW-9 SM 6200B- 441361 92405811007..: 'SW=1 SM-fi2006:.. 441361.. :. .' : - 92405811008 _ ,SW=2 . 'SM 6200B -92405811009 Trip Blank .. • SM 6200E . ';. 441,361 . . 92465811001 MW-4 ". SM 2540C-2011 - 440180 92405811002... MW-5 SM 2540C-2011 : 440708. 92405811003 MW-6 SM 2540C=2011 ' .. 440708 .-. 92406811004 MW-714 SM 254OC-2011 : 440708 92405811005 -MW-8 -. SM-2540C-2011 ` ; 440708 62405811006 ' MW-9 SM 2540C-2011 : ' 440708 92405811007. -SW _ SM 2540Cr2011 .. 440708.. ' 92405811008 -. .SW=2 . " SM 2540C-2011 ." 440708: -92405811001 . .' - . " 'MW-4 . ' ' - - : ': SM 9222D-2006 440083 _ : SM'9222672006 , 440098 ' - 92465811002 • MW5. ". SM 9222D-2006 - '. 440083 SM 9222D;-2006 440098 . 92405811003- MW-6 SM 9222D-2006 . 440083. SM 9222D-2006_ 440098 92405817004 ; MW-711: SM 9222D=2006 .' 440083 .: SM 9222D-2006 440098 9240.5811005 MW78. SM 9222D-2006 440083 '.SM 9222D-2006 - .._440098. 92405811006 ' MW-9 .. - SM 9222D-2006 ' 440083 SM 9222D-2006 - 440098 92465811007 SW-4.". SM.9222D-2006 - 440083 ", SM.9222D-2006 .". 440090 . -92405811008 . SW-2 : SM 0M,D-2006 .. 440083 ' .. . SM 9222D-2006, 446098.' - : - 92405811001 MW-4, EPA 350:1 Rev 2.0 1993 ... 440609'.' . - - 92405811002 - .. MW=S :. EPA 350.1 Rev 2.0 1993 440609 92405811003 MW-6 - . EPA 350.1 Rey 2'01993 -440609 -- 92405811004. MW-7R - .. •` EPA 350.1. Rev 2.0 190. 440609 92405911005 -. MW-8 EPA 350:1 Rev 2.0 1993 440609. - " 92405811006 MW79. EPA.350:1 Rev 2.0 1993': 440610 . 92405811007 'SW-1 EPA 356.1 Rev 2.0 1993 440610 4246561100.8 SW-2 .' . EPA 350:1 Rev 2.0..1993 ° .' .. 440610• 92405811001. MW4 EPA353.2.Rev2.0.1993: 440145:. 92465811002 : ' MW,5 EPA 353.2 Rev 2.01993 . - • 440144`- ' .92405811003 , .' MW-6 EPA353.2 Rev 2:01993 440144 92405811004 ' ' MW=711. EPA353.2 Rev 2.0 1993 440144 62405811005 - :" MW-8 EPA 353:2 Rev 2.0 1993 440144. -' 92405811006 : MW-9' : EPA 353:2 Rev 2.6.1993- : ' : 440144 . - . .92405811007 :... SW=1 " EPA 353.2-Rev 2.0 1993 .. . 440-145 92405811008 SW-2 -" . -EPA 353.2 Rev 2.0 1993 . -' 440144 92405811001. MW4_ .1Rev20 4404541 92405811002 MW-5. EPA 365A Rev 2.0 1993 .. 440423', . • EPA 365.1 Rev.2:0 1993 440454 92405811003 .. =• .MW-6 ;- - 'EPA Rev2.0,1993 440423 .... EPA 365.1 Rey-2.01993 .' .440454. RE PORT OF LABORATORY ANALYSIS'... . This report shall not be reproduced; except in full, Date: 11/09l201.8 04:27 PM • - : without the written consent of. Pace Analytical Services,UC. Page.40 of_44, Pace Analytical Services, UC g ® 2225 Riverside Dr.. - Asheville, [lceAnalytical _ NC 28804 wwwpa-10S.90m (828)25477176 '. QUALITY.CONTROL DATA CROSS. REFERENCE TABLE Project: Lassonde.Pappas 18148201.01. Pace Project No.:. _ .92405811 .: Analytical. Lab, ID Sample ID QC Batch Method QC Batch, Analytical.Method Batch• 92405811004 MW-7R EPA 365.1, Rev 2.0 1993 440423 EPA 365.1-Rev 2.0 1993 440454 92405811005 :. MW-8 EPA 365.1 Rev 2.0 1993 440423 EPA 3B5.1 Rev 2.0 1993 ." 440454 92405811006 MW-9 EPA365.1 Rev 2.0 1993 440423 .. EPA365.1 Rev 2.0 1993 440454 92405811007 SW-1 EPA'365.1 Rev 2.0 1993 . 440423 EPA 365.1. Rev 2.0 1.993 .440454 92405811008 SW-2 ".: EPA 365:1 Rev 2.0 1993 440423" EPA 365.1 Rev 2.01993 440454 . 02405811001. MW-4. SM 4500-CI-E-2011 440291 9246581.1602 MW-5 SM 4500-CI-E-2011. 440291.. . 92405811003 MW-6: SM4500-CI-E-2011 44029.1` .92405811004 MW-7R SM 4500-CI-E-2011 440291 92405811005 MW-8 SM 4500-CI-E-2011 440291 62405811006 .' MW-9" SM 4500-CkE-2011 440291. 92405811007 SW-1 SM 4500-CI=E-2011 440291 - 92405811008 .. SW-2." SM 4500-CI=E-2011 :• 440291 92405811001 MW-4 SM 531OB-2011 441352 §2405811002 , MW-5" SM 531013-2011 441352 92405811003.E MW-6 SM 5310E-2011 441352 . 92405811004 MW-7R SM 53106-201.1 ." 441352. .. 92405811005 "" MW-8 SM 5310E-2011 441352 .92405811006 MW-9 .• SM 5310E-2011'. 441352 92405811007 SW-1 SM 5310E-201.1 441352• " 92405811008:. SW-2 SM 5310E-2011 .• 441352: REPORT OF LABORATORY ANALYSIS" This report shall not be reproduced, except in full, Date: 11/09/201.8 04:27 PM without the written consent of Pace Analytical Services, LLC. Page.41 of 44 ` j ;-alcleAnalyfta, l ; Document Name: Sample Condition:Upon Receipt(SCUR): Document Revised: February 7, 2018 Page 1 of 2 : Document.No.: F-CAR=CS-033-Rev.06 Issuing Authority: Pace Carolinas Quality Office Document Name: Document Revised'. February7, 2018 Y aceAnalyticai Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority .. ,. F-CAR-CS-033-ReV.06 Pace Carolinas Quality Office v, - vim.. N _`.Z m� ...> ` •� .V .. N .V V -vc .. xc "� 0Lxn05 "yvmwc =°1 z ¢"SW . . ZO_2_" C MW Ny, x Q Q "ZaY� OO c c c- _ O C U. A E a a o+ N .d'.Z .y?y i" D. a . E x Z 7 i Y OJ E 'o ¢ ¢" Q. Q �_ v m E c .n. E. a a: a a a 0.An E E. ¢ E Q r O O O a a' in a ¢ n d- E a a J a J > '> N E E �. E. v .E.. a�" E E" - E E E m. o o. °Ln- E p E" E �_ w. c : of M E E. .E E �. .' Ln c o E. N 6.N-Ij N N• N p pQ' Oa M N N ry . R• `Ni - 7 .7 N . Z . eN-i .N 'Ni U. W �-I .� a -I 2�. ri dl " .. v�• Q 'x G. .�� �' . OL F= a O O=i 0. A. _ m Co rc Co Co Ca '.Ca m .'3 .a. .a 'a a. a .¢ c '>. >. .a >" > (n m ¢ > o 1 I N\ a :6:- I ) ti� 3 8 x \N : 10 11.. 12 Out of hold; Incorrectpreservative, out of temp, incorrect containers:.' Page.43 of 44 CHAIN OF -CUSTODY / Analytical Request Document o " 1-4 ce Ica The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. �. tM . .Section A. . Section B. .Section C : m Required Client Information: Required: Project Information: Invoice Information:. Pa a :' ' 1 �f 1 Company:. ANCHOR QEA'of NORTH CAROLINA Report To:: Brian Gen( Attention: . Address: • - :321"Haywood Street Copy To: Company Name: 7 Ti, ; ' Asheville. NC 28801 Address: - . Regulat6ryr-A 'enc Email: bganI@bncnergea.coin' ' Purchase Order #: Pace Quote: Phone: -NONE Fax', Project Name;Lassondo Pappas - Pace Project Manager. ', - lorri.patton@pacelabs.com. State 1 Location' Requested Due Dale', <<1_ qr / ' Project M 5 ' 7- a': _ e)'' Pace Profile #:: . Requested Anal sis Filtered /N ' - 'tnniatx CODE. COLLECTED" �_ Preservatives- - Drin ingW ter Dw a .0 O 'Water Wi Wa2to Wato - :ww a a j .O _ - SAMPLE ID P,oaod oalUSoGe _ P of i _ C� S ,START, END u to 1� c_ .} One Character per box.' wPa. wa w w s w z v m d. a p o ..IA-7..0-91,-t Aar Dha, AR,} OT 1- r k. Z _ a U Sample Ids must be unique 7rsua Ts ,U X W W () N N .t= .A CO U ' W -r ° :,tt y y O Z- Z5.1 O to N. _ m L C 'Q U O' E...vi. E O m W '(, d .tt '.� _. _ ._._. .z O: r ¢ r. z LL. >. t`. •z . ::.� N>�h t► }Its i�i:3 X :X: :X .. Id1M1r-0 wr� 1i .. X X..X L ." t'U lt� �t "G� '!.`. 'X .2.:-', MV11-5. WT !� - Iv X' X' X X X' V�. ., MW-7R �i �L, J �\ .�) ( X X '.X. X :x: X V�: :. .. Q�24a' I1 1 .5.'. MW-8 W7G /J� %�'C1' i11'� X. X X. X X X'. WT X' X X X X,X' 7•„ .Sw-1 1�0V t /L+ X X 'X X X X �61: a 1XV..X X X x X X ��5 . 9 . . Trip Blank WT . '.. 'X •. �� - " 10:. . 11s." . 12'., -'•}.'ADDITONAL'COMMENT3"s ,2 7'•. ... ELI NOUISHED BYIAFFILIATION - I .. •-'DATE> "' ,TIME, _ - ,ACCEPTED BY I'AFFILWTION6, .. DATE,'" TIME: SAMPLE CONDmONS` RUSHTATIII - .1 ` I,�l, -.. V` 77-1 SAMPLER NAME AND SIGNATURE . ' - PRINT Name of SAMPLER: j. . . . . ^ 0V0fMil-d:Q'V1 . - a 0 -o m d/Y SIGNATUREpf SAMPLER, IJ .A DATESigned:.' tu" 0 z m o z M a z, _ tNeIl,Casing Volumes defined in Table 2 of the Region 4.Environmental Pro tection Agency (EPA) Science and Ecosystem Support Division (SESD}document titled Operating Procedure - groundwater Sampling last revised Apri126, 2617: Samples are analyzed immediately upon collectlen. Minimumwolume purged: 3 well volumes. Sample time determined by parameter stabilization, °C: degrees Celsius . . mV: millwlY pS/cm:micro-Siemenpar rcentimeter NTU:nephelometricturbidity units , mg/L• milligrams per liter S.Ut Standard Units Method Reference: Specific eonductiviiy. EPA Method 120:1, Rev. 1982_ Temperatu re: SM 2550 B-2010 - pH: SM 4500-H' B-2011 DO: SM'4500 O t3-2011 Project _Name; ��l . Date: (: Project NumberfmA Weather•.. J 4oQS. N` Sampling Personnel; Sample Name: S.�( w Comments:. `fio.�v►cic Semple Method: Grab Syringe Pump ,Bailer-Disp., . Other. S .,:r .,�y,�.:�*..<. '.1 S z-.K}' iya•` 6r+ }' 4" r r.�i y . � , x . [,,, a'`aF� � '�.:� � .� � } :�^ � . •'z�' .�. � .�v �}r•.g�� � k a s ' �t � ..Qj(jdatiClt'� r�s �` s >.'� �{ `� r`' � '�,�r ":..., ��,'.�F �,d' ,. Hit �. �- 5 ,^.r;e:. •:'. 5pecifi�c C41td � ,e�H•[s11.��.:, .. _'�ftedl:ctio�n, Turbid �f !` :Tirtie •Temp (°t); ��Y9er! (ma/LjT. {li5%m) <report ro a r u Potential'(n11�� :F J e ,,'� Comments -Sam ;li P 56 niL:Plastic 250 mL.Plastic - - - 125 mL Plastic 40 mL Glass C..y 1 LGlass --- Other c Vegetation:.. U Access: !� 'U., U(. :t . nnel Signature: Date.Sam lin Perso ANCHOR QEA ':� Surface Watet Sampling Log Anchor QEA of North Carolina, PLLC B1 Haywood Street Asheville; North Carolina 28801 Project Name: t d Panda Date: Project.Number. Weather: _ Sampling Personnel:- Sample.Name:. Comments:j�J`, - �rAL.J (_CACIL :1 ._c_�ti't dil Sample Method:.' . Grab Syringe Pump Bailer-Disp. Other r� � ,r �- � � , �` $ � ri ,� � . "•� • ' x �' .� t as �. � . •' .ire � � t'x �' � �' s: G r _ -4 �� [Sissolved � .•f'r `I`F. T"e. 5pe�dflcCond : J ''41 ; pH (S V a .Lrty+ .. .+� �, Iteduetiori � - TuFbidi •'� i . ?7:,j � :� r �, 'r'�` :�''}. 4 ;'' 4' ` : ~ • 1� `° � • y; F�`. � "'.Times `} Temp {°C) Gx�►gen (mg/1) : L ,.•# {ItSlcm� ' repor# fo 0 ar SU'' : P,oterttial {rli1� :;.�, ° A..r� n (NTU)'_d(^ . .. � 1 �'" 'r e z :_ , a' : Comr>lterits., Sarr+piln Container; sh. '` _ - _ ,Nuiiiber of n ` v► _ � t%tamers j�j : a. `� 1 ., • 500 mL Plastic J � llj�. 250 mL Plastic _ L ' - 125•ml.Plastic .. .. -40 mL Glass'--- ._ vi OL 1 L Glass — Other' Vegetation: Access: b Sampling Peonnel Si nature: mite: I ' .t�1,NACHOR Anchor. QEA.of North Carolina, PLLG ;;D V[ 1 t1 231 Haywood Street Asheville, North Carolina 28801 Equipment Documentation and Instrument Calibration Data sh"ppt. Equipment or meters used to take meastirerrients (e.g.;_water level meters,,survey.equipment)i i_ . l�Sr!l'1;�y,'i3� � ef.� J9��= '' et. .i . _�!g1�lR+,, S' 'i"• .�9 �• � 150-ft Water Level -26154 " "V Solinist. 150-ft Water. Level 22754 Solinist 150-ff Water Level 150 Test'well_ 150-ft Diawdown 1MP30-1327 QED Select Turbidinreter. ✓ . Hach 2100Q (s/n 151006045207) .. . .. HP Sderttific Mlc[oTPW.(s/n 200601045). lnsfasllnejJlI�i �y °Ratlr3ll r x tFD •`i1 7lcpirrilbfit (5 a�'1 l�l..•�C , ?,i:.--"<=;i' i Cal: r CaF Cal:. at ' . .. "IMP— :ti- "l � �' Cat, l .3 Time( Tim Time Time: Time Time . i '• Verification (10 NTU)• 3 Veriflcatiom Verification: Verification: Y. AOF .Time(( .11 %%' 10 NIlJ CalhhExp Von Date- Date• .. Time Time Ttrrte . *�, ..!c#.L�ty� "y' sic •�+,� 43t _aa.Xi t �VSi IOft551,D71a� f�5'JVf�t�l1•ent121<lr��l�(+L'1;5��Ig8B10#�A>��xa � '�.rG a +"• rf �.;: . � .+yet: t �� }'�-..' �sl-b� � .. _.'a.� 1 �r�tNmfvnl, :.. �Lgs _;.• "' . +e>"`�. . _.. � ` _ �_ w .' x ;;CbNlit�ic{n�rpiia�4n.p�tg: " Dissolved O�rygen Initial: jj II I/�� Cal //�� mmH9 Temperature (°C). Time +, NA r. PH7S.U..".. report to0.1SU. Initial: . �y _ C pHmV:- -�( �: �� Cal; <av:... pHmV:.... - Time:• e of.::. (� .75.' . report to 01PH 4 t S.U. Initf�l _. (� v PHmV: / . Cal�:1"�, pH v .' . ( Time . pH 10 S•U. .. • repprttoais.0 - Initial: . " . (�_i3 pHmV: - Cal: " . pHmV: Time . . W pH 7 S.U. " report to Q. I S U. AM Ti e: f �1"" Meas p Mid Day Time: Check PM Time Check SpecCond..' Initial: Ca: Timhe: pS/cm"' 1�U�' ln�u OUG - /��U t� 0'I A000 AM:Time: Was: :: Mid Day Time Check PM Time: ' Check ORP.. �1:SmV Initial: Cal: j " Temperature (°C): Time O�1. .' q p Signature: /: J / j f O Date• _ Notes:. 1: Electronic equipment calibrated according to the manufacturer's operation:manual. 2. Specific Conductivity should be calibrated according to values representative of historic range, 3.Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH :10, DO; ORP, QC, checks. 'Al. QC Acceptable Ranges: pH +/- 0.1 "S.U. and Specific Coriductivity 10% of the true value, If QC readings are out -of range, the instrument needs to.be rec librated. S. • Indicates that a QC check must be performed in the morning; aftemoon, and the end of the day, four hours. or every _ 6. •' Indicates to"choose a Specific Conductivity buffer of 1413, 447,'84 or 23 mS which Is closest to historical readings from the project location. " Method Reference Temperature SM 2550 B-2010 IS conductiyfty; EPA:Method 120.1, Rev. 1982 I DO: SM 4500 O G-10i i I pH: SM 4500 N+ 8-2011 . Page 1 f 1 o i Enter date monitoring results were due. (iz/3i%26re) Will this monitoring-report(GW-59.and.GW-59A) YES NO be submitted after the established due date? X. 2' Was any requircd;information missing on the GW-59 reportforms? YES NO IF the" answer to .guestion 1 or 2 is °YES , list in the spaceprovided below the. weliidentification number(s) and explain the problems encountered in obtaining the required information: . 3 Are.any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown; etc.)? If the diuu er is " 3 es'; cwitdcl the Regional Office for giridrnrce. X 4 Are any monitored constituents equal to or above the established standards? YES NO Iff the answer to question 4 is "NO", skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) ' . exceeding standards in the space provided below: , Nitrate (2L = 10. mg/L): MW-7R®15:7 mg/L' .. Fecal Coliform ,(Total Coliform 2L standard =. 1.0 CFU/100mL): MW-6069.0'CFU/iOOML, KW-8®19.O :CFU/100ML Tetrachloroethene (2L = 0.7 pg%L) C MF7-5®39.1 pg/L " Trichloroethene'(21,= 3 pg/L) MW-506.0 pg/L - 5 For'the constituents Identified In question 4-above, have standardsbeen exceeded, previously for the . YE NO. same constituent(s) in the same well(s) in the last two years? _ If the answer to ggestion 5 is NO , skip to section 8. If the answer to question 5 is "YES'; list in the. space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence((or the last two years). Nitrate_- Fecal Coliform - Tetrachloroethene Trichloroethene MW-7R. . KW-6 MW 5' MW-S. . . 11109116; 12.5 mg/L 11/08/17: 74.0 CFU/100ML., ll/09/l6:'l41.0.pg/L 11/09/16:, 63.1 pg/L 11/08/17: 36.8 mg/L. 05/02/18: 1.0 CFU/100mL,' 11J08/17: 35.9 pg/L 11/06/17:,4.6 pg/L 05/02/18 a 15.5 mg/L. - MW-B _ . - .. .. .. .. .. 05/02/17: 8.0-CFU/100mL -. . Are the monitoring wells listed in section 6 located at or beyond. the review boundary?- YES NO MW-5.,'MW-M, and MW-e.are.at'or beyond,the.review boundary... X . If the ansiver fs "YES". a groundwater quality problem may be occurring: CONTACT THE REGIONAL . OFFICE IMMEDIATELY FOR GUIDANCE -.If the answer Is "NO" monitoring wells maybe improperly located; contact the Regional Office.. . is the permittee implementing previously approved actions required by the Division involving this YES NO: groundwater quality problem? X: If the answer to. question 7 is 'YES", describe those actions in the space providedbelow. If the answer to question 7, is "NO'; contact the Regional Office within 90 days; an evaluation maybe required to determine the imm ict the.waste 'disbosal system is having at the review and compliance' boundaries surrounding'this facility.- Failure to do so may subject the perrnittee to a Notice of Violation, fines: and/orpenalties. . Fecal.coliform should not.be attributable_to site operations'. Historical z(onitoring.of anon -.site tributary of mud, Creek has found -high levels of fecal'coliform'. Nitrate' concentrations exceeded the groundwater standard in MW-7R and MW-8 for.the first'time in -May 2016. The high -concentrations of nitrate. are likely attributable to the frequent, flooding of Mud Creek. .. g The person completing this portion (GW-59A) of the monitoring report should sign below and submit this form with GW 59 forms for required wells to the address provided at the top of the current GW--59 form:' . �I hereby acknowledge that the above information -was evaluated andAhe information submitted in this 1 �reporf"(Compliance Re ort -59A) is tr e'and com -lete to.the best of my knowledge. 1 .Signature of Permitt (de Authorized Agent) ate . SUBMIT FORM ON YELLOW PAPER ONLY IGROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM FACILITY INFORMATION Please Print Clearly or Type Facility Name: Clement Pappas Permit Name (if different): Facility Address: 125 Industrial Park Hendersonville (street) NC 28792 County Henderson act Person: Mrs. Tracy Wolfe Telephone#: 8 2 8- 3 2 9- 6 6 4 7 Location/Site Name: Irrigation Area No. of wells to be sampled: 6 OF MAIL JRCES` tOCESSING UNIT 17 Phone:919407:-6306 PERMIT Number: Expiration Date: 8 / 31 / 2 0 2 C Non -Discharge WQ 0 0 0 4 7 9 7 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: 'Infiltration Gallery IN Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: WELL ID NUMBER (from Permit): MW- 4 Date sample collected: l l /'02 / 2 018 FIELD ANALYSES: Well Depth: 18 _ 2 Q ft. Well Diameter: 2 in. pH 00400: 5 •47 units Temp. 0001o: 17.6 °C Depth to Water Level 82546: 8 . 0 0 ft. below measuring point Screened Interval: 8 *ft. t016_1*ft. Spec. Cond. 00094: 206.1 µMhos Measuring Point is 2 . 43 ft. above land surface Relative M.P. Elevation: 2063.77 ft. Odor 00085: none *screened interval is relative to land surface Volume of water pumped/bailed before sampling: 5.0 gallons Appearance Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified`. El YES ❑ NO WAS DRY at time ofsampling, check here:❑ LABORATORY INFORMATION Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.; COD 00335 mg/L Nitrite (NOZ) as N 00615 mg/L Pb - Lead o1o51 ug/C"� q5s oacl� Coliform: MF Fecal 31616 <10 0/100mL Nitrate NO as N 00620 Zn - Zinc 01092 Coliform: MF Total 31504 .. /100mL. phorus: Total as P o0665 0 . 0 7 0 Phosphorus: mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Co pounds and Concentratio%4ts) issolved Solids:Total 70300 137 mg/L Al - Aluminum of im mg/L pH (Lab) 00403 units Ba- Barium 01007 ug/L 4 TOC 00680 3 .6 mg/L Ca - Calcium 00916 mg/L Chloride 00940 9.0 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils oo552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, Gbk§, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ® Yes (1)' ❑ No (0) pecific Conductance 00095 µMhos K - Potassium 00937 mg/L method # Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; N113 as.N; Ammonia Nitrogen, Total) Mn. - Manganese oio55 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs; mg/L VOC Removal% SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: , .. ; DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM ,. • 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 8 / 31 / 2 0 2 0 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville (Street) NC 28792 Count Henderson y ❑Lagoon El Remediation: Infiltration Gallery (City) (state) (zip) ER Spray Field ❑ Remediation: Contact Person: Mrs. Tracy Wolfe Telephone#: 82 8 - 3 2 9 - 6 64 7 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: _ from Permit SAMPLING INFORMATION MW- 5 If WELL WELL ID NUMBER (from Permit). Date sample collected: 11 / 0 2 / 2 018 FIELD ANALYSES: WAS Well Depth: 18 _ r,L ft. Well Diameter: 2 in. pH 00400: 5 .53 units Temp. 000lo: 16 • 8 °C DRY at Depth to Water Level 82546: 8 .2 3 ft. below measuring point Screened Interval: 9 * ft. to 19 * ft. Spec. Cond. 00094: 115.5 µMhos time of Measuring Point is 3 . D 0 ft. above land surface Relative M.P. Elevation: 2085.60 ft. Odor 00085: none sampling, check Volume of water pumped/bailed before sampling; 5.0 gallons screened interval is relative to land surface Appearance here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION --" Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services CertlflcatlorrNo''3771?� PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N oo615 mg/L Pb - Lead oleos a so00 `' � ug/L 4 Col'Iform: MF Fecal31616 <10 . 0 /100mL Nitrate (NO3) as N 00620 <0 . 020mg/L Zn -Zinc 01092 �. Coliform: MF Total 315o4 /100ml- Phosphorus: Total as P 00665 0 . 0 8 5 mg/L (Note: Use MPNmethodforhighly turbid samples) Orthophosphate 70507 mg/L Other (SpecifyCompoundsand Concentration Units): issolved Solids:Total 70300 86.0 mg/L All -Aluminum of im rr Zf� mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 5.1 mg/L Ca - Calcium 00916 mg/L Chloride 00940 23.9 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ® Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L method # Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L ; method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Permittee (or Authorized Agent) Name and Title- Please pr&for type GW-59 Rev.8/2013 Authorized (Date) SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM a 1617 MAIL SERVICE CENTER, RALEIGH, NC27699.1617 Phone: 919.807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 8 / 31 / 2 02 0 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different);_ NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville (Sreet) NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery (City) (State) (zip) IN Spray Field ❑ Remediation: Contact Person: Mrs. Tracy Wolfe Telephone#: 8 2 8 - 3 2 9 - 6 6 4 7 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: from Perrnit - SAMPLING INFORMATION MW- 6 If WELL WELL ID NUMBER (from Permit): Date sample collected: 11 / 0 2 / 2 018 FIELD ANALYSES: WAS Well Depth: 11. 58 ft. Well Diameter: 2 in. pH 00400: 5 .02 units Temp. oo010: 16 -9 eC DRY at Depth to Water Level 82546: 5 . 0 3 ft. below measuring point Screened Interval: 5* ft. to 10 * ft. Spec. Cond. 00094: 150.8 µMhos time of sampling, Measuring Point is 3 . 00 ft. above land surface Relative M.P. Elevation:. 2061.17 ft. Odor 00085: none check Volume of water pumped/bailed before sampling: 3.25 *screened interval is relative to land gallons surface - Appearance here: ❑ Samples for metals were collected unfiltered: El YES El NO and field acidified: ❑ YES El NO LABORATORY INFORMATION Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 69.0 /100mL Nitrate (NO3) as N 00620 0.64 mg/L Zn - Zinc 01092 mg/L., -@ Co_ liform: MF Total 31504 /100mL, Phosphorus: Total as P 00665 0 . 0 5 7 m_ g/L- (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds,an0 6hcentration Units): issolved Solids:Total 70300 88.0 mg/L Al -Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L 1 TOC 00680 2.5 mg/L Ca - Calcium 00916 mg/L b� Chloride 00940 10.1 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLG Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test' and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ® Yes (1) ❑ No (0) Specific Conductance o0095 µMhos K - Potassium 00937 mg/L method # Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen,' Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.8/2013 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT& NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 8 / 31 / 2 02 0 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED' Hendersonville (streeq NC 28792 County Henderson El Lagoon El Remediation: Infiltration Gallery (City) (state) (zip) ® Spray Field ❑ Remediation: Contact Person: Mrs. Tracy Wolfe Telephone#: 8 2 8 — 3 2 9 — 6 6 4 7 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION MW- 7R If WELL WELL ID NUMBER (from Permit): Date sample collected: 11 / 0 2 / 2 018 FIELD ANALYSES: WAS Well Depth: 173 7ft. Well Diameter: 2 in. pH 00400: 5.48 units Temp. cool 0: 17.4 eC DRY at Depth to Water Level 82546: l C " 3 eft. below measuring point Screened Interval: 5 ft.* to 15ft.* Spec. Cond. 00094: 363.4 µMhos time of sampling, Measuring Point is 3 . 00 ft. above land surface Relative M.P. Elevation: 2062.86 ft. Odor 00085: none check Volume of water pumped/bailed before sampling: 3.5 *screened interval is relative to land surface gallons Appearance here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sampleanalyzed:varies; see analytical report LaboratoryName: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead olo51 ug/L Coliform: MF Fecal 31616 <10 . 0 /100mL Nitrate (NO3) as N 00620 15.7 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100ml- Phosphorus: Total as P 00665 0.17 mg L � (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 # -';P' a p' ,.i,mound `i mg Ot�1er (Specify Compounds and Co centration Units): issolved Solids:Total 70300 243 mg/L Al -Aluminum 01105 mg/ t ) pH (Lab) 00403 units Ba - Barium 01007 ug/ �� — 7 201 ; TOC 00680 5.3 mg/L Ca - Calcium 00916 mg/ +, Chloride 00940 20.2 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 u IL Chromium: Total 01034 u /L WSJ'r Qurs . = 77 Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L RGANICS (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #.ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ® Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L method # Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.8/2013 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 8 / 31 / 2 0 2 0 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville (Street) NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery (City) (state) (zip) ® Spray Field ❑ Remediation: Contact Person: Mrs. Tracy Wolfe Telephone#: 8 2 8 - 3 2 9 - 6 6 4 7 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION MW- 8 If WELL WELL ID NUMBER (from Permit): Date sample collected: 11 / 0 2 / 2 018 FIELD ANALYSES: WAS Well Depth: 13 _ 9 a ft. Well Diameter: 2 in. pH 00400: 6.52 units Temp. 00010: 17. 9 °C DRY at Depth to Water Level 82546: 8 . 85 ft. below measuring point Screened Interval: 3 ft* to 13 ft* Spec. Cond. 0009a: 586 µMhos time of sampling, Measuring Point is 3 . 00 ft. above land surface Relative M.P. Elevation: 2060.80 ft. Odor00085: none check Volume of water pumped/bailed before sampling: 2.5 gallonSscreened interval is relative to land surface Appearance here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: varies; see analytical report LaboratoryName: Pace .Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. \ COD 00335 mg/L Nitrite (NOZ) as N 00615 mg/L Pb - Lead o1051 ug/L Coliform: MF Fecal 31616 19.0 /100mL Nitrate (NO3) as N 00620 6.8 mg/L Zn - Zinc o1092 -` ' ; mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P o0665 0.25 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify�Compounds and Concentration Units): issolved Solids:Total 70300 351 mg/L All -Aluminum o1105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L ,a TOC 00680 9.5 mg/L Ca - Calcium 00916 mg/L Chloride 00940 8.0 mg/L. Cd - Cadmium 01027 ug/L 1 Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS `(by,GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ® Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L method # Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L �, method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.8/2013 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1017 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 8 / 31 / 2 0 2 0 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville "treat) NC 28792 Count Henderson y ❑Lagoon El Remediation: Infiltration Gallery (city) (State) (zip) ® Spray Field ❑ Remediation: Contact Person: Mrs. Tracy Wolfe Telephone#: 8 2 8 - 3 2 9 - 6 6 4 7 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW- 9 Date sample collected: 11 / 0 2 / 2 018 FIELD ANALYSES: WAS Well Depth: 18 _ 12 ft. Well Diameter: 2 in. pH 00400: 5 .11 units Temp. 00010: 17.9 °C DRY at Depth to Water Level 82546: 4 . 5 5 ft. below measuring point Screened Interval: 6 *ft. to 16 * ft. Spec. Cond. 00094: 77.4 µMhos time of Measuring Point is 1 . 44 ft. above land surface Relative M.P. Elevation: 2060.23 ft. Odor 00085: none sampling, check Volume of water pumped/bailed before sampling: 6.75 *screened interval is relative to land surface gallons Appearance here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO _. LABORATORY INFORMATION --' Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services cation No. 07712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.'' ___C6i ` COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Bb=lead o1o5P ug/L Coliform: MF Fecal 31616 <10 . 0 /100mL Nitrate.(NO3) as N 00620 0.57 mg/L Zn -Zinc 61092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0 . 4 7 mg/L '� J (Note: Use MPN.method for highly turbid samples) Orthophosphate 70507 mg/L Other (Spe 'I4tompounds and Concentration Units): issolved Solids:Total 70300 88.0 mg/L Al - Aluminum oil o5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 8.4 mg/L Ca - Calcium 00916 mg/L Chloride 00940 5.8 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ® Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L method # Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.8/2013 PO Box 7565 yyyWWW 28802 Asheville,'NC Phone:. (828) 350-9364 Fax: (828) 350-9368 '�^vlronmental Testing $olutlons, lnt Ce)C111 1CatC Of 1�I1413'S1S Project.narrie.: City of Marion _ j ProJect number: 181.1M500 Collection date: - .12=Nov-18 . . Date received: 12 Noy`48 - Sample identification: MW # 1 •Grab . . Sample number: 163966 Parameter Method Result RL q. Units .... Date - Analyst Footnotes Analyzed " Solids, Total Suspended SM'25400 6.0. 5.0 mg 14-i4v-i8 .' KEK Solids; Total -Dissolved. SM 2540 C.' <20 20• mg/L 15-riot/-18 KEK Ammonia Nitrogen. SM450ONH3ID <0.10 0:_10 mg/L 15=rrov-18 KEK .:Nitrate as N ': 300 0 <Oc25 0.25 mg/L _ 13-No,18 ' . LBW 1 'Phenolics 420:1 <0.005 0:005 rn 15-Nova8 CM 1 Arsenic_ 200.8: <0.010 0.010 m S� ... 27-Nov-1 a' ... MLR 1 Cadmium .200.8 . . ` <0.001 0.001 Jng/L 17-Nov718 MLR 1 on. 200.7 0.7.0. 0.050 mWL .. ,3o-Nov=1 s LMC 1 Lead 200., 8.. <0:005. .0.005 m �. z�-Novas .. MLR 1 . Manganese 200.7 0.01.1 0:010. mg/L 30Nav 1s, LMC 1 Total Organic Carbon ' SM 5310 B -: <1.00 100 WWI,..zo-Novels JRM 1 8260 B :` 8260;B See,attached.sheets zt-Noy-la, STM 2 Sample identification MW # 2 = Grab Sample,nurillier: 163967 Parameter' " Method Result RL Units Date A d .'Analyst Footnotes nalyze Solids, Total'Suspended _• `" S&12540'1). ;. 45' 5.0 mg/L' -14-Novis '` KEK _ Solids, Dissolved SM, 540 C - 120 - . 20 rng/L is -Nov 1$ KEK .Total Ammonia Nitrogen" SM4500NH3D_-. '6.2. 0:10 mg�i is -Noels KEK Nitrate as N' '. ' 300:0 Q.71 0:25 m ' 13-Nov-Is - LBW 1 . Phenolics 420.1' <0:605 0.005 mg/L ..is -Novas . ; CEW 1 Arsenic 200.8. .. <0.010 0.010,mWL ., V-Nov-1a .. MLR 1 Cadmiurii :.. 200i8. <0'001 0:001 mg/L ,zi-Nov la MLR 1 Iron 200*3 32 : 1.0 mg/L 30-Nov 1 s LMC 1 Lead 200.8�<0.005 0.005 mg/L 27-No1is :MLR 1 1Vlanganese .200.7 *3 0 O10 " mg/L 3o-rtov 1s LMC 1 Total Organic Carbon SMS310 4.�1�1:00 -mg/L : zaxov is : JR1VI 1 8260 B. /t 8260.B C attach( edssh ets, zt=Nov-is STM 2 t Uy 0�8 A�iJ b ] tl Resources alaier Resources201 2 7 8 L oFiopia?al Operations Astis This"report should not lie reproduced exepGin ttsetitiri y-without;the writteti:tonsentof Environmental:TestingSoiutions, Inc. The results in, this report relate only fo'the samples submitted for analysis. , . PO Box 7565 "Asheville N.C. 28802 _ TRIM Phone: (828) .0 9364�Fax: (828) 350-9368x Out ON Environmental Testing Solutions; lnc Certircate ofAnalysls ; Project name City of Nlar�tin Project number: 181112.500 Collection date.. 12-Nov-18 Date received 12=Ngi,48`_, Sample identification MW.#3 = -Grab Sample;number:. - 163968 Parameter Method Result RL "Units 'Date Anal' d Analyst .. YZ e ` .Footnotes Solids, Total Suspended SM 2540 U 29<: . 5:0 mg/L 4 Nov is KEK Solids, Total Dissolved ' _ ": SM 2540 C':' 200 20 ilig/L i3=rtav is :' :KEK: AmmonldNitrogen sM45ootJH3D <010 010. mg/L i5-rtovis ' -KEK Nitrate as N 3000 346 250 . mg/L 3-Nov-1"8 LBW 1 Phenolics' 420:1 <0.005 0.005 mg/L : is-rro� is :.'CEW 1 Arsenic:: 200.8 - <0:010 , 0.010 MLR 1 Cadmium.. 200.8 0.002 0.001 mg/ 2� Nov 1 s MLR 1 Iron 200;7 0 62 0:050 mg/L, 3o-xo� is " . 1 Lead . 200:8 <0.005 .0005 " mg7L "zi-xo�as _LMC MLR .. 1 Manganese: 200:7 0.36 0:010 ing1L. 3o=xo.as ;LMC i :_Total.Organic-Carbon : _ . SM' 5310 C .:" 1.41 . , t 6 : mg/L _. 2o-Nod-18 JRM 1 8266 j3. _ ` 8260.13 ttachedsheets See a , ,., :. 21=Nov-18. ST1V1 2 Sample identification MW # 4 - Grab .. , :. Sample number: - 163969 Parameter, Method Result iL Units T Date Analyst Analyzed :.: .. Footnotes Solids; TotaBdspended -: SM:2540 D :; 200 5'.0 _. mg/L ia-Now-is ' KEK Solids, Total Dissolved Sm.2540 C 30 20'-KEK ,._ Ammonia Nitrogen SM. 450oNH3 D " <0 10 0 10 mglL is iJo� i s KEK : Nitra�e asN . - 300 0' 1.99 0.25 nig/L t3-Nov-i8 - "LBW 1: 'Phenolics 420.1. <0:005 0005 :mg/I is -Nov is . CEW. 1; Arsenic '.: 200.8 <0.010 0.0110 mg%L ii-Noy 18 ` MLR 1 Cadmium 200.& <0.001 0.001 mg lL 2�-Nov-ia MLR . 1 " Iron 200.1 ` . 5.1 0:050 , nig/L " 3o=1vo� 1 s _ L MC' 1 Lead 200.8 <.0.005 0 005 , mg%L z�-riav i s ' `MLR 1 ..,.-,Manganese-, 200.7. 0.13 0.010 irig/L `3o-rtoV-ts `LMC i Total Organic Carbon SM 5310 C " 1.43 100,' rnglL 26,Nov is JRM ��1� 8260 B 8260.8 See atfached sheets • zl-tyo -is .: ST1VI_ 'l a23 TFc:'tUfC s. f VV- . Footnotes: DEC 2 20�a RL Reporting Limrt Values arelreported_down to.the Reporting Limrt only: -'l. Sample analyzed by Rogers &:Callcott Environmental'. ' r, "SUBMIT FORM ON YELLOW PAPER ONLY (GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Facility Name: City of Marion Permit Name (if different): _ Facility Address: Marion Marlon (c,tr) Please Print Clearly or Type NC 28752 (Street) NC 28752 County McDowell act Person: Lary Carver Location/Site Name: Monitoring Well # I Telephone#: 828-652-8843 No, of wells to be sampled: 4 PERMIT Number: Expiration Date: 7-3 /— 20 zZ Non -Discharge WQ0003698 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: (from Pemu SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Monitoring Well IR Date sample collected: 11/11/2018 FIELD ANALYSES: WAS Well Depth: 65 ft. Well Diameter: 2 in. pH 00000: 5.9 units Temp. 000lo: H, % °C DRY at Depth to Water Level szsas: 28 ft ft. below measuring point Screened Interval: 55 ft. to 65 ft. Spec. Cond. 000sa: µMhos time ofsampling, Measuring Point is 1.5 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: n/a check Volume of water pumped/bailed before sampling: 18 gallons Appearance low turbidity here: ❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 11/12/18- 11/127/18 Laboratory Name: Environmental Testing Solutions Certification No. 600 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb -Lead 01051 <5 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 <0.25 mg/L Zn - Zinc 01092 Coliform: MF Total 31504 /100mL Phosphorus: Total as P oo665 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compc unds and Concentration Units): issolved Solids:Total 70300 <20 mg/L AI -Aluminum ol1o5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TSS 6.0 mgP UEU TOC oo68o <1.00 mg/L Ca - Calcium 00916 mg/L Chloride 00940 mg/L Cd - Cadmium 01027 <1 ug/L Arsenic 01002 <10 ug/L Chromium: Total 01034 ug/L ^-� .r.,.., i' :- l t'• '� Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 <0.005 ug1L Fe - Iron 01045 200 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg -Mercury 71900 - ug/L Lab Report Attached? K Yes (1) ❑ No (0) Specific Conductance 0009s µMhos K - Potassium 00937 mg/L VOC 7873 method # 6230D Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese olo55 11 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOG Removal /o Larry Carver WWTP Superintendant Permittee (or Authorized Agent) Name and Tide - Please print or type GW-59 Rev.3-1-2016 z -i3 -r9 CASAfialytldal Parameter` Number;=; Method Result , _Q LGQ Units Benz,ene" 71 432, J- 7 N �ug/l_ B e b,nzene romo - 826 013- 0.�o ug/L f: mochlaromethane 74-07--5 _"82603" Kb' 050 ug/ L d than Brdmo ichlorome e.,, -75 :2.7 4 826013*m 0.50 ug/L Br6mofornf. kb 'A50 A/L th i .Bromome an e (Methyl bromid6).' D" 0 50 ug/L n-Buty benze n, 7. 1'8 5 0.- 0i ug/L 135�98-8 -:�"826013 J �ND, 0.50 ug/L �.l 4, t6rtI361:yIbeni0ne, 98-06-6._. '8 E ... 260 0.50 ug iL 1 'Carbon h , - :4, tetrachloride 56 -23 -5 826013, ND .0.510 ug/L ne Ch orob enziiefi ?lb�-004,� 8,20013-D 0.5 ug/L Chlbedetharib _j �3 8 d60B 0750 . ug/L hloroforrh '�826013; ND 0 .50 I ug/L A;- .:.Chioromethane (Meiigi ND 0:56'. ug/L 2-CM[orotolupne,:. D .0.5 0 ug/L A�Chlorotoluene 10 4' 82 0& 0.50 ug/L I 2-Dibtb-rii(5-3-chlorbpropano (DBda).-, _M ND 0.50 ug/L _.Dfbrornochlorornethaine_ A 24 26013i M 0 ug/L T�2-[Dibrornbbtfiane_(EDb) 6� S260B� N ..050 ug/L -82'603`� ND 0.50 ug/L I I2-Dichlorobefizene "Z 95bi :826d3 _ ND 0.50 ug/L 1 , 3-1) it . III I dtobenze ne 541-73;m1 82 OB-"- 'N .0 50 .ug/L 1 4bibhl6robenzene 0646 7 8260B 0.50 ug/L Dichloro diIiUbrometha-ne,- .75:Ti'8' 82608, ND 0.50 ug/L. , et fl-pidhlorohane.: ' - 343 826 OB ND 0.50 ud/L , 1,2Dichlorbbthane. 7 6-2: 260B N D 0.50 ug/L .1 I-Di6h!6roethe�i e ne,.:- �;:75�3 '4, 8 2 0.50 ug/L ciO -,213 ichl Oro . etfi � 5 69- 6 Qb13' 2 0.50 ug/L 1 6 trans zt�-.-bichloro '64 15 - �666 -_;, % . " "'NID .050 ug/L 1 nG�N"N 1,2 -D -roprppane M ichte? :82608 ND .0.50 ug/L 0(6prboane 00 14246 - 4' ND 0.50 ug/L 1 2 2-Dichlbrop: ropane ug/L A ILDichl^06plropene 5 M&6. `�,'826013 NO, 0.50. ug/L. Diis'opropy ethe050 108-20-3_� ... WD, ug/L 1 Ethylbbrizenb 260B ND 0.5.0 ug/L. -'Hbxddh_lof&b.Uta6iene 87 68 3, 826013- ND 0.50_. U41L . 1. Isopropylben . z : 6 n- 66-62-6 7 60B ND OM ug /L p4sopropy to uene: 8260131.1 ND 0.50 ug/L l` 'ether (M Methyl tertiary bdtyl TBiE).i 8260B i,:ND 0. .50 ug/L V: cki o i e� 60 t4D 0.50 ug/L .Methylene -8260B ND0- .50 ug! L ri-ftpylbenzene.' 03-65- -.826 0&: 0.50 1, ug/L Styrene 1004.2 �5,` 826013 ND ' 6.60 ug/L oethane .630.-26-6 0.50 ug/L LOQ bmit&Qu6ritita6ri hod b6 Q` d' 66f66h�.�un&&cee-�e r. blank ,.E= uah tation: djhe'c'ql!6raU ahge -W = Not oetect6dat or above the.LOQ=.Recovery is o6fbf chteria -P .=The RPUbetwberitwo GC to umns exceeds r wet H =:Ou't 6 mgr,tweight is time _qrted onV r Shi§aly,':Envi,t6nmehtal,tervices,, nc.', 106 Va4acbiumbi�,..St�_'.29172 -791 797 (803)79491111, www s r healylab.com wk 4., 4: e 5 of 21 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: R COMPLIANCE REPORT FORM y p FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: Zv 22. Facility Name: City of Marion Non -Discharge W00003698 UIC Permit Name (if different): NPDES Other Facility Address: Marion NC 28752 TYPE OF PERMITTED OPERATION BEING MONITORED Marion (Street) NC 28752 County McDowell El Lagoon ❑Remediation: Infiltration Gallery (0ty) (Stale) (ZIP) ❑ Spray Field ❑Remediation: Contact Person: Larry Carver Telephone#: 828-652-8843 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Monitoring Well 2 No. of wells to be sampled: 4 ❑ Water Source Heat Pump ❑ Other: from Pam" SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Monitoring Well 2 Date sample collected: 11-11-2018 FIELD ANALYSES: WAS Well Depth: 40 ft. Well Diameter. 2 in. pH ooaoo: 6.3 units Temp. 00010:/ , � °C DRY at Depth to Water Level 82546: 19 ft. below measuring point Screened Interval: 30 ft. to 40 fL Spec. Cond. 00094: µMhos time ofsampling, Measuring Point is •22 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: N/A check Volume of water pumped/bailed before sampling: 10.2 gallons Appearance LowTurbidity r---. here: Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO + LABORATORY INFORMATION Date sample analyzed: 11-12-11-27-18 Laboratory Name: Environmental Testing Solutions Certification No. 600 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. U , cn COD 00335 mg/L Nitrite (NO2) as N oo615 mg/L Pb -Lead olo51 <5 ug/L I ? o Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 0.71 mg/L Zn - Zinc 01092 mg/L , `- cv Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 mg/L CV (Note: Use MPN method for rnghly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentrati `n.Urfits): issolved Solids:Total 70300 120 mg/L Al -Aluminum o11os mg/L f r _, '' ' - pH (Lab) 00403 units Ba - Barium 01007 ug/L TSS 45 mgfl p E TOC 0066o 4.14 mg/L Ca - Calcium 00916 mg/L R S Chloride 00940 mg/L Cd - Cadmium 01027 <1 ug/L Arsenic 01002 <10 ug/L Chromium: Total o1o34 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 <5 ug1L Fe - Iron 01045 32000 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? X Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # 6230D Total Ammonia 00610 6.2 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 1300 g ug/L ,method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Larry Carver WWTP Superintendant / !//t— 1,2-13-115 Permittee (or Authorized Agent) Name and Title - Please print or type SI rat f P e r Authorized Agent) (Date) GW-59 Rev.3-1-2016 SM 6230D Ltst +';ICE MTBE Client Environmental Testing solutions, Inc.; Laboratory ID; TfC13004=002, Description MW #2 Matrix: Aqueous Date Sampled 11/1212018 0902 - Date Received .11/1.3/2018 Run Prep;:Method Analytical Method_ Dilution Analysis Date Analyst Prep Date Batch 11/21/2018;1214 STM '90260. _. CAS = Analytical Parameter N3umber,'; Methotl Result Q .; LOQ units :Run 1'F 22=Tetrachloroethane 5 82606 :` ND Oi50 .. ug/L =1 Tetrachloroethene:. 127 18 4 : 8260E i=. .:ND 0.50 ug/L Toluene 108 88 3: 8260E ND MID ug/L 1 � 1, 2-i37,Tnchlotobenzene 87 61 li .:- 82606 ND 0.50 iig/L 1��1 1.;2 4 t, hlorobenzene 1 920 82 : 8260B _ : ND 0,50 ug/L 1t ,. TnciiloroethaneND 0.50 ug/L 9k� Tnchloroethane 79 00 5-;."; 82606 tvp 0.50 ug/L 1" ` „. l richloroethene ,:. 79 01 6 _ . 82606 - ND 0.50 ug/L 1 i Trichlorofluoromethane ,. 75 lib 4 8260E >:' ND 0 50 tig/L 1 1,2 3 Tnchloroprtipane ' 96 18 4 ::: 82606 - ND 0..50 . ug/L : 1 12 4 Trimethylbe.nzene 95 63 6 8260E ND 0.50 _ ug/L 1 z 1`;3 5 Trimethylbenzene 408 67-8. _ 8260B ND 0.50 ug/L 1 Yji Vinyl chloride, it 75 01 4 . 82606 ::_ ND 0':50 ug/L A m+p Xylenes 179601231 ;, 82FOB .: ND 0:50 ug7L 1 o. - Xylenes, �'95 47 6 '; : 82606 '' N.D 0.50 ug/L 1 Run 1 Acceptance Surrogate; _.Limits j2 Dichloroethane-'d4 Bromofluorobenzene 105' ` 70=130 Toluene`d8' 105 , ' 10=130 `! Ur 77 I]ivi is or �Nbicr Resources t 5, DEC 2 7 201 i \Na+ar t?i:mil+tir i��n moral Operations ,. ... - LOQ = L,mI[ of Quant,[aUon .' B Detected m the.method blank E .QtiantdaLoh.o) compound exceededihe calibration range ND =Not detected at or abbve the LOQ[' N Recovery is out of cntena P — The RPD between.two GC oolumnsexceeds 40I H —_Out of holding hme - ;?'_ W Reported on wet weight tiasis , Shealy E9 nrohmental Services Inc 106°Vantage Point Dd West Columbia .SG 29172. (803) 791 9700 rFox (863 791 9111 :., www shealylab coin wl Page 8 of 21 . SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM FACILITY INFORMATION Please Print Cleatly or Type Facility Name: City of Marion Permit Name (if different): Facility Address: Marion NC 28752 Marion {street) NC 28752 County McDowell (city) (State) IZip) act Person: Larry Carver Telephone#: 828-652-8843 Location/Site Name: Monitoring Well # 3 No. of wells to be sampled: 4 PERMIT Number: Expiration Date: 7- ? t— Z07- Non-Discharge WO0003698 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Purnp ❑ Other. WELL ID NUMBER (from Permit): Monitoring Well 3 Date sample collected: 11-11 - 14' Well Depth: 52 fL Well Diameter: 2 in. Depth to Water Level 82546: 35 ft. below measuring point Screened Interval: 30 ft. to 40 ft. Measuring Point is 1.09 ft. above land surface Relative M.P. Elevation: ft. Volume of water pumped/bailed before sampling: 8.1 gallons SamDles for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO FIELD ANALYSES: pH 00400: units Spec. Cond. 00094: Odor 00085: n/a Appearance Moderately High Turbidity Date sample analyzed: Laboratory Name: Environmental Testing Solutions Certification No. 600 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. - COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead o1os1 <5 _ ug/L.-_ .- Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 34.6 mg/L Zn - Zinc o1o92t `- mg1L Coliform: MF Total 31504 (Nola: Use MPN method for highly turbid samples) /100mL Phosphorus: Total as P 00665 mg/L ' nn� Orthophosphate 7os07 mg/L Other (Specify mpounds ap�oncnrati�eYi Units): , issolved Solids:Total 703oo 200 mg/L AI - Aluminum oil o5 mg/L U l` pH (Lab) 00403 units Be - Barium 01007 ug/L TSS 29 mg/l TOC 00680 1.47 mg/L Ca - Calcium 00916 mg/L Chloride 00940 mg/L Cd - Cadmium 01027 2 ug/L - Arsenic 01002 <10 ug/L Chromium: Total olo34 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 <5 ug/L Fe - Iron 0104s 620 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # 6230D Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 0.36 mg/L method # (P,mmonla Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese olo55 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediatlon Systems Only (Attach lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Temp. 000lo: /j .? °C DRY at uMhos time of N GW-59 Rev.3-1-2016 ,. - ;SM.6230D List +.IPE &`_IUITQE Client Environmental Testing Solutions, Inc, Description Date Sampled 11/1212018 0846" boratory_ID: TK13004-003. Matrix: Aqueous ,Date Recbivbd 111l3.20, 8. ` Run Prep;lUethod. dnalytical Method" Dilution Analysis Date Analyst Prep Date ° Batch 1 50.306` ;; 8260B' 1'=,, 11/21/20181:2,36 STM 90260 CAS Analytical Parameter - - Number Method Result Q ._. " LOQ- Units Run benzene 71 43 2 ,_: 8260B ;: ND 0:50 ug1L 1 Bromoben2'ene 1:08861,_: 8260E : ND 0.50 ug/L 1 Bromochloromethane 74 97 5 8260E • '-" NO 0.50- ug/L 1 Bromodichfor omethane 75 27-4 -: 82606 i' NO 0.50 ug/L 1 Bromoform` 75 25-2 8260E `. NO, 0.50 : ug/L 1 7 _' BromornetFane (Methyl bromitle) =- 74 83 9 82606 ND 0:50 ug/L 1 ncBut' Ibenzene " ' 104 51 8 : 8260E - NO - 0.50 ug/L 1 sec Butylbenzene : : 135 98 8 8260E ND • _ 0.50 ug/L 1 _ -tert Butylbenzene . 98-06-6 8260E ND 0.50 ug/L 1 Carbon tetrachloride 56 23-5: 8260E ND 0.50 ug/L 1 x, Chlorobeniene 108 90 7 8260E ; NO, . 0.50 ug/L 1 z Chloroethane 75 00 3 82606 ND 0.50 ug/L 1r ;: , Chloroform 67 66-3 8260E ND 0.50 ug/L Chloromethane• (Methyl chloride) .74 87 3. 826013 NO 0.50 ug/L 1 2'6hlorotoluene " "" 96498 -'. 8260E ._;, ND 0.50 ug/L 1 4-Chlorotol'uene 106 43 4,: 8260E ND 0:50 ug/L 1 12 Dibromo 3 chloropropane (DBCP) 96 12=8 8260B `. NO 0.50 ug/L 1 ,?1 Dibromochlorom 'thane 124-48,1 ' ; 8260E ND 0.50 ug/L 1 ` 12 Dibromoethane (EDB) 1Q6 93 4.. ' 8260B °: ND 0.50 ug/L 1 Dbromomethane (Methylene bromide) 74 95 3;` 82606 ND 0.50 ug/L 1 12-Dichlorobenzene 95 50 1: ,` 82606- : ND. 0.50 ug/L 1 'L 3 Dichlorobenzehe 54,1 73 1 82606 ,.": ND 0:50 ug/L 1 - ,1;4 Dichlorobenzene 1064 7 8260E •`- ND = 0.50 ug/L Dichlorodifluoromethane 75 7.1-8 82606 ND 0.50 ug/L 1;1 Dichloroethane'.: 75 34-3 ". 82606 ,_. Nb" 0.50 ug/L 1 Dichloroethane " 10ti'2 860 D 0.50 ug/L 1 t Dichloroetherie 75 35 4 ` : 8260E ' ND. 0.50 ug/L 1 cis 2 Dictloroethene 156 59 2.. 82606 ND 0'.50 ug/L 1 1 trans 2 Dichloroethene 156 60 5':,: 82608 ND 0.50 ug/L 1 s 12 Dichloropropane . 78 87 5 :' i8260B ND 0.50 ug/L 1 13 DicMoor' propane _ 142 28 9": 8260B , . ND' 0.50 ug/L 1 22 Dichloropropane 594 20 7 82606 ; NO 0.50 - ug/L 1 1, :1 Dichloropropene F-9-- 563 58-6 8260E :: NO 0.50 uglL Sr r CD Diisopropy'k br {IPE) -v " 108 20 3' $2606 ND 0.50 ug/L Ethytbenzene : 2 100-414' 82606', ND 0:50 ug/LVtA Hexachlorobutadiehe , ? n i 87 68 3 "` 8260B ND 0.50 ug/L =1"/ # Ins Isopropyl benzene., rv� 98 82 8"' 8260B '- ND 0.50 ug/L 1 i a p.1topropyltoluene a ly "1 99 87 6 0.50 ug/L �. 1 ' Methyl tertiary butyl (MT ) � ' N �xr ti� " 4 04 4 826013 ND 0 50 ug/L 1 urd' ,ether Methylene:chlonde. .-; 75709 2 ... ; C, cg 82606 ND 0.50 u /L 1 Naphthalene o �; Co 0 91 20 3 -: 8260E ND 0.50 uglL 1 n-Pro Ibenzene 4 PY 103 65 1- 8260B .• ND 0:50 ug/L 1 Styrene y .", 100 42 5 - $260B - NO `0.50- ug/L 1 1;1,1 2-Tetrachlo[oettiane 63 0 20-6.' f 8260E .. N.D. 0.50 ' ug/L °4 LO0 =Limit of (luanlitat on. ; B -Detected m tfie"nethod'blank E QuaRGtahontof compound e$t 6e cled.the calibration range'-.:' - 'ND:= Notrletected at or above the LOQ N Recovery is out of criteria:; P = Ti RPD between two GC columns exceeds 400o H ,Out of hoidin time W Reported on wet weight basis Shealy EnwronmentalServices;.lnc ._- SM 6230D Ltst`+ IPE & MTBE - - Client Environmental Testm_g Solutions, Inc Laboratory 0a. Description MW43 :Matrix: Aqueous . Date Sampletl 11/1f2/2018 0846 Date Received 1111312018 - Run Pe6p Method? Ahalyticat..Method: Dilution Analysis Date Analyst Prep Date ' Batch ': .. l ,;` 50301i °' . 8260B 1 ;;" 1172]/20181236 STM 90210'II -CAS Analytical , .7.-..- -,0 Parameter, .. .. r. .. ethbd Result Q Number. <. M,:. . , _ ,. , . . '�., -: LOQ° , 1 1 2 2 1 I chloroethane �79 34 5 :: 82606 -'ND --- -I:a ,:r� 0 50 Tetrachloroethene: . ; 127 18 4 82606 ND .�-.' .W.1'- ,-. I-' �.. 0.50. . . Toluene : w 1. :. 108 88 3 82606 ND ,-' ` ,.--I:�;.�I 1I` l".�- ..t :�-; �.�... 0:50 . 1 2 3 Tnchlorobenzene .,. 87 ti1 6 - 8I ., ND . �:-w�.- -..:r 0 50 •. T;2 4 Tnchlorobenzene 120 82 4 82606 ND .�,',,.I.I 0;50, 1 1 1 Tndiloroethane W -. :71 55 6 8260B .- ND 'r� ;� �I ::.W-:�.�,: 0 50 . 1 1 2 TncHloroethane 79 00 5 8260E `- . ND -- 0.50 ::, Trichl*' hene : ,=. " 79 6 .° 8260E `. ND .. . 0.50 Trichlorofluoromethane ':.. .:. w .-, -- `'. ;: 75 69 4 _ 82606 ND - � ,,-:,":� --. : 0.50 ..: 12 3 Trichioropropahe ;9,6 18 4 ; ` 8260B N,D : .. 0.50' :... 1-2 4 Tnmethylbeniene , . 95 63 6 :.: 8260B ND � ,.- ..�: a": 4L� .'� a.. .,. 0:50 _. I. 1;,3 5 Trimethylbenzene 108 67 8 i 8260$ ND _, :-. -I'�.I,,-,- . "0 50 Vinyl chloride ,., 78 01 4 .; : „ 8260E ND .-..,.--,: .-..- ,�... 0'.50 .: m+p Xylenes ,. - 179601 23 1 - 82606 ND 0 50 .. o -'Xylenes; 95 47 6' 82606 Np .....�-�, -0.50 .. ,. . ..'Run 1 Acceptance a�. - . I. Surrogate .. .. - a . Q _. % Recovery. • .Lim. its .. ,... ` , "-w�,-� i::w1- I. 1;2 Dichlooethane=tl4 ' ' , " .. 95. :. 70-130 ". . Bromofluorobenzene ,.w.W—� ...:.: ; ; 10Z.. s; .. �70=130 , .. �- ,w� ..I .. Toluene d8:. .... 109 -` 70=130 :, . � -�,.. - , . ' : . .W � ..,�:,.W �. " I .� . � .w,;. : *:I— ... -�-'�-, -.'�., W�:,�, .W�: ,� ..a-.IAt .. .-1 wI,. . ��1 ..l�L —I.� II,'..w. . !,, .;.. .. ;" ". -w4 . :,,,1 � ....-1I ��� - ,. : w:.:-1I�� : -� ;,.1a. �,, - �:,-I. � :. .. .* .. w, . .. .-- :,:.,; ,.'�I,,�. I: "I�1 - , :-� 1.; a . - .I,�... -�r t to cqes �- �-..- .:. �- .".� �� -- :.�.� w. waI !a_, tl .� . ,I-\�I; �1 - .. . . '.• Uy�'.J:�-f '.� — , '1A 1- ;.'1,� ._ —.:�'a ,�..�.�.-� �.�-'-,:'� . , ,.I, '. .....ii�. . - " -1w. I.. . ..�i- . � . �-:-,I�-�'!�I-.::. ', . . - 1(�nera}to[�S i . . -: X,-. �,--. I. . .1. *.'... .',"-,I �,::.- ,:...:.1 . . , " - a 1 F, n ('e - _. - - - ,".w -'-, -.,I1. ,. .,— I'�. .'w :: ..,. :.�,,..: -:I: � -w: , : - �-¢',ram- . � 11 - - LOQ = Limit of (luanhtaLoh : B Detected m ihe:inethod blank E Quantitadon of compound exceeded the cahbrat on range ND =Not detectei a(orabove the L0f1.1: N Repovery Is out of criteria P the RPD between two GC' columns exceeds 40°/a' H :Out of holding time, ,' ` 1 W Reported on wet weight basis . Shealy Environmental:.Service"s'lnc. 10, Vantage POlnt Dnve. West Columbia SC 29172'.; ( 3) 79.1 9700 Fax t803)-Z 9111 WWW shealylab com . .. ,. Page1.0. of 21 tig/L 1 1. ug/L ..1 ug/L -:1 ug/L '1 ug/L r: '1 . ug/L �, ug/,L 1 ug/L 1 ug/L . 1 ug/L I1 ug/L , .I ug/L _ -..1 ug/L .1 g/L .1 u ug/L A GROUNDWATER QUALITY MONIT, COMPLIANCE REPORT FORM ``" t SUBMIT FORM ON YELLOW PAPER ,RING:, Please Print Cleady or Facility Name: City of Marion Permit Name (if different): Facility Address: Marion NC 28752 County Marion (street) NG 28752 McDowell Contact Person: Larry Carver Telephone#: 828-652-8843 Well Location/Site Name: Monitoring Well # 4 No. of Wells to be sampled: 4 ONLY l-''rF vinl'il�/ r..4rt'GiPwill:?a��1.Tr1J v.,."il.�.io.7't:uito.�,ru;n�� ?(�iiuli•IIII' ..�. �_ ..�.,,... ...� PERMIT Number: Expiration Date: 7-3 t -Ze 22 Non -Discharge W00003698 UIC NPDES Other TYPE OF PERMITTED OPERATION. BEING MONITORED 'El Lagoon " ❑`Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑,Other: SAMPLING INFORMATION ; WELL ID NUMBER (from Permit): Monitoring Well 4 Date sample collected: 11-12-2018 FIELD ANALYSES: Well Depth: 33 ft. Well Diameter: 2 in. pH o0400: 4.9 units Temp. 00010:/ °C' Depth to Water Level 82546: 22 ft, below measuring point Screened Interval: 18.5 ft: to 33 ft.. Spec: Cond. 000'94: µMhos . Measuring Point is . 1.09 ft. above land surface Relative M.P. Elevation: ft. ; Odor 000s5: n/a Volume'of,Waterpumped/bailed before sampling..":5A gallons - Appearance Moderate tur bidity' , Sam les for metals were collected unfiltered: ❑ YES' ❑ NO- .'and field acidified:. ❑ YES- ❑ NO - LABORATORY INFORMATION " Date sample'analyed: i1=12- 11-2i=2018 " ' Laboratory Names Environmental Testing"Solutions -.Certification No:'600 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations, , COD oo3s5 mg/L Nitrtef(NOZ),as N 00615 mgLL -Pb Leatl olul <5, ug/L - `.Coliform MF Fecal 31s1s /1 OOmL Nitrate (NO3) as N: 00620 1.90- mglL 2n - Zinc olosi, , " ... Emg/ f rc" Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 mg/L U. (Note: Use MPN method for mgny turbid samples) Orthophosphate 705107 mg/L. Other: (Specify Comptun s and'Concentration Units�j: � ssolved ,Solids:Total 703o0 30 mg/L Al - Aluminum ol105 mg/L PH (Lab) 00403. units Ba -Barium 0007 uglL TSS 200 mg/I; _t ; TOC 00660 1.43 mg/L Ca- Calcium 00916 mg/L Chloride 00840 mg/L Cd - Cadmium o1027 <1 ug/L 'ut"r O ` ' ' t .. Arsenic 61oo2 <l0 " ` '' ug/L Chromium: Total 01034 _.uglL Grease and. Oils 00552 mg{L Cu,- Copper 01042 . - :. mg/L ORGANICS: (by:GC, GC/MS, HPLC) Phenol 3213o <5 ug/L Fe; -,Iron 01045 5100-- ug/L (Speci'fytest and method #.,ATTACH I-AB'REPORT.) Sulfate 0945 mg/L Hg - Mercury 71900 " ug/L Lab Report Attached? 0 Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K = Potassium 00937 mg/L VOC 7873 method #. 6230D Total Ammonia o0s10 <0.10 mg/L Mg - Magnesium 00927 rhg/L method # (Ammonia Nitrogen NH3as N; Ammonia Nitrogen; Total) Mn - Manganese°o1o55 _130 ug/L method # TKN as N o0625 mg/L Ni -' Nickel 01067 : `uglL method # For Remediation Systems Only (Attach Lab Reports):. Influent Total.VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%. DRY at time of sampling, check here: Run Prep'';Method` -" Analyticat.Method Dilutioq Analysts Date Analyst PYep Date, Batch 1" • 5030B,. 82601, 1- °. 11/21l20181:259 STM 90260- :. CAS Analytical Parameter Number Method Result Q LOQ, .- Units Run Benzene- : ` a 71 43 2 ,f: 8260B ND 0.50: ug/L "1 Bromobenzene:: .. 108 86 1 8260E � ND 050 . ug/L 1 Bromochloromethane ': 7,4 97 5" 8260E _ ND Z.50 ug/L .1 Womodichloromethane 75 27 4 :_ 8260B ND ..0.50 ug/L 1 Bromoformi 75 25 2 ::. 8260B ND 0.50 ug/L 1 Bromomethane (Methyl bromide) 74 83 9 , 8260B N.D 0.50 ug/L 1� n'Bufyibenzene - 104 51 8 _ 8260B ug/L tit sec Butylbenzene 1.35 98 8 :" '.82606 :. ND 0:80. ug/L }x 7 Buyee 98066 0.50 ug ?ibnntent Carbon tetrachloride 56 23 5 :: 82606 ND 0:50 ug/L Chlorobenzene 108 90 7 :_= �8260B ND 0.50 ug/L ,a s Chloroethane 75 00 3 J_ 82606 ND 0.50 ug/L �.'1 Chmoroformj 67 6673 :_ -"82606 '_ ND 0.50 ug/L s. 1 kt Ctiloromethane (Methyl chloride) 74 87 3 - 82606 ND 0.50 ug/L . 1 2=Chlorotoluene;;` 95-498 °; 8260E '."` ND 0.50 ug/L 1 4,Chlorotbidene 106 43 4 8260B =: ND 0.50 ug/L 1 ,,.. 1,2 Dlbcomo 3 chioropropane (DBCP). ::: 96 12 8 > 8260E ND MO ug/L 1 Dibron' &H6r6meth6ne 124 48 1 8260E ND 0.50 ug/L '1 '1;2 Dibrornoethane: EDB) (, " :, ;`, ` _: : 1,06 93-4 .:, _. 8260E .:" N" D 050: ug/L , 1 ; Dibromoniethane.'(Methylene bromide) - 74 95 3 82606 ND 0.50 ug/L 1 4: '1,2 Dichlorobenzene " 95 50 1; = 8260B _:. Nb 0:50 ug/L 1 i 1,3 Dichlo.robenzene 54173 1 '8266B ', .ND ug/L 1 ,' 1;4 Dichlorobenzene. 1D6 46 7 82606 _ - ND 0.50 "" ug/L 1 Dichiorodifluoromethane 75 71 8 826013 _ ND 0;50 ug/L :1 lm, 1 0ichioroethane 8260B ` ND 0.50 ug/L 1 _. 1;2 Dichloroethane-_`. .. 407 06 2 8260E ND 0:50. ug/C 1 1;.1 Dichloroethene 75 35 4 _ 8260B ND ug/L 1 cis'I 2 Dichloroet bhei 5(i 59 2 ,8260E ?ND 0.50 ug/L 1 trans 1 2 Dichloroethene 4 O 56 60 5 `: 8260B - ND 0:50_ ug/L ;`1 ' 1;2 Dichloropropane °'� �'+78 87.5 _ 8260E ND ;'0.50 ug/L 1' 13 Dichloropropane N p Er r 42 28 9 :" 82606 Np 0.50: ug/L 1 2 2 Dichloropropane �' ro n 694 20 7 `= 82606 ND 0 50; tig/L 1rLTs 1,4 Dichloropropene 5 ry x 563 58 6 8260E _ ND 0.50 ug/L Diisopropyi ether (IPE) jj t 108 20 3 8260B ND 0.50 ug/L Eftiylbenzene r.� 51 14 _ 8260B ND 0:50 ug/L 1 Hexachlorobutadien '3 82606 ND 0.50 ug/L Istipropylbenzene .". o ; rro 98 82 8 8260E Nq 0.50 .. ug/L xT ° p lsopropyitoluene : 99 87r6 $260B ND MO : ug/L 1 rybu;' et Methyl tertiatyl _her (MTBE) N 1634 04 4 8260B ND.0.50 uglL 1 Methylene chlonde" s 75 09 2 _, 82606 ND 0.50 ug/L 1 = 'Naphthalene 91 20=3: 8260B _`: ND 0.50 ug1L `1 n=Propylbenzene- .: 103 65 - - k606 ND 0:50 ug/L 1 Styrene 100 42 5 8' ND 0.50 ug/L 1 1,1 1 2 Tetrachloroethane 630 20 6 , . 82606 ND 0:50 _ ug/L 1 LOQ=Limit o.Q d E naionof hobirat onangeb ND - Not detected at or above the LOQ `' N Recovery, is oubof cntena P The RPD between two GC columns exceeds 40%` i H .- Out of holding time W Reported on wet weigfit basis Shealy'Envi�onmental`Services;:Jnc ' ` ' ' "" 106';Vantage Pomt Drive' West CoUnbla;.SC 29172` {803) 791 9700; Fax (803)' 791 911 T wyvw shealylab corn , Page l 1. of 21 {js. .,. o >.. - ., , _ . , ,:. „ . _. SM 6230D Ltst + IPE & MTBE Client Environmental Testing Solutl9ns, Inc. :. Laboratory ID:TK13004=1 .,,. Desgnption MW.`#4 . - . Matrix: Aqueous„. Date Sampled 11/12/2018 0824 - II - Date Receivetl 11/13/2018 . ;, - �.., .i,.....::;�,.� ;. Run Prep'Method_; .,, -; . Analytical Method Dilution Analysts Date Analyst Prep Date Batch . . 1 = ,50306` ,_ 8260B: 1 111 1/20181259 STM 90260. 1 CAS :. Analytllcai , _*.b. .�-;i .!.,+-�-.-..II - Rprameter Number Method,,. Result Q LOQ Units Rung 1:1 2,2 TeiFachloroethane 79 34 5 .': $260B Nbs 0.50 ; : ug/L 1 Tetrachloroethene-.,, 127 16-4 8260B _ ; ND ., ,.._,-, 0,50 ug/L "1 Toluene .' 1O8 88 3. '.. 8260E ..: ND .; 0.50 ug/L :L 1,2 3 Tnghloroben ene . _ .8 61 6 -'- -8260B `. NE :.1:i"_" 0:50- . uglL � :1 1;2 4 Tnchlorobenzene 120 82 1 8260E ND 0 50 -ug/L -.1 1.,1 1;Trichlo I ethane `r 7:1 55 6 :; 8260E ND 0 50 , I ug/L :.1 1;1 2 Tncnloroethane 79 00 5 .: , . .>- ND .... ..' 0.50 t g/L 1 Trichloroettene 79 01 6 :8260B ND ! _: 0 50 . ug/L 1 Trichlorofluoromethane', � % 75 69 4 8260E ND �_."-I.�.-.," 0 50= ug/L 1 42 3 Tnchloropropane - 96 18 4 _ 82606 ND .+.1 0 50 _` ug/L 1 1:2 4.Trpethylbenzene . 96763 6 8260B ND .�: -;.I..� 0 50 ug/L 1 13 5 Tnmethylben e e 108-67 8 62' 66B ND 0 50 " uglL ;i j Vinyl chloride 75- 01-4 8260B ND l—..�;...4 ..4.-,." 0.50 ug/L "1= gi=' h rn+p Xylenes 179601 23 T :: 8260B ND 0.50. ug/L t ky i . -- Xylenes - -95 47 6;. 8260E ':. ND 0.50 ug/L 4' . . Run 1 Acceptance .'_,� 1,I., 1. Surrogate_ . Q %:'Recovery ' Ltmtts _ „, 1;2 Dtchloroethane-d4 _. ., - _ 96, 70-130 jI Bromofluoobenzene 1-,.,." : 106 70-130 Toluerie-d8 106 :'; -7 =1 - ,.�" ..:._ _ _,; � :' ... 1. :..�.�...- . " l :-,.. , +,..: . I.. . . . ,,L�4,�._W�I,:l�., - - ." �, �. .,1I,i l .�.,,.._ ." ..,..�:II .1.: i . 1 .;� N C7� . �Ty .. .�.,1.� Zo ' m ?u -'. :..� ,. �, to - .. .. `'t r s , :;t t r JFa < i rid . ,5, .� I..V1 , . �4.,, '. I� ':.,._:.-I.,,_ Y .:.,-. .,-��,.+'._ (Q� x. l,� f, - .,I�+ _ ...'-�. t Ste. �: _ _ F f'. - ��� Cy ' '... - -. ,. ...:. ... -. .. LO.t] Lund of QuantdaUon, B Detected m the melhotl blapk E :Quantitat�on;of compound exceeded the cahbraCion range- . ' N , Not detected at or above the L66 N Recovery is out, of cntena . P The RPD between two GC columns exceeds 40% H =Out ofholding time W Reported op wet weight tiasis .. .,. 'r. s ' �_. Shealyl Enmronmental $ernces .Inc __ . 106.. Vantage Pomt Dnye West Columbia, SC ,29172 :, (803) 791 9700 'fax (803)'791 911 t www shealylab com J ;