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WQ0004797_Monitoring (Report)_20180709
O 0" �+. V u �. ;' . Z ;; ; {A ul M O JA C... I.- o. Q:. 7 ; a G: (CFUs per Sample.Name.- Sample Date (mg/L) (mg/L) 100 mQ) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) 05/24/2006 . 7.2 . - -9.7 < 1.1• 2' '..'. 19- 82' < 0:10 NA .11/09/2006 . ' " 3:6 ..' 7.4. <.1;1 0.95 ' .: ,17 76 0.11- NA ' 05/18/2007 : 4:9 . 6.0 <. 1.0 0.56 . 14 62:- < 0.10 " NA 11/13/2007 . - 5.9 ' 16.7 : z.1.1 ' 2.9 6.9 82.0 < .0.10 NA. 101. - 9:0 1.3 140 <.0.10 NA .05/27/2008 1.1/18/2008 - - 4.7 : -10:7- .<1.1. 1.9 :. 8.5. 32.0 . <0.10. NA 05/28/2009 . ' 14A 7.1. <-4.0 0.46 •' : 24.2 _ . 104.. :< 0.10 NA 11/05/2009 115 - .5.91 <'2.0 0.31 . 23:5 .80.0 < 0.10 NA MW-2R.... 05/13/2010 8.7. "' .5.8 < 2.0.. .< 0.10 1.7.2' 57:5. ' < 0.10 NA:. .11/08/2010 . ' :.18.3 10:0. <:2:0 \ : ll 1.1.7. 60.0- < .0.10. NA' ' 05j17/2011. _ M6 ' < 5.0 .<.2:0 .. <.0.1D 14.3 < 62.5 < 0.10 NA - „ 11 /15/2011.. 18.9 . 10.1 ' - < 2.0 : - .1:2 ...10.0 - 86:0 < 0:10: NA ' - 05/17/2012 5:3 .. 7.6 r4:0' < 0.20 .' 11.9' ..68.0 < 0.10 'NA '.-11,/07/201'2 : 31:.1.- 9.5 '< 1.0 1.3 10.0 67A <.0.10 NA ,. 05/16/2013' U.'s 1:2 <.1.0 < 0.02 13:2' 64.0 < 0.10 .'' NA. 11/20/2013 61 ' . 76 <:1.0 _ 0.97. 9.3. b6.0. < 0.10 NA. - 05/22/2014 ' - ' 8.0 : 4.1 . < 1.0 : ' 0.72 . .. 8.4 1 52.0 - . <- 0.10. NA Standards :10 _ 256. 1' . 10 _ .' : 256 - .500 1.5 . ..NL Table 1 Current and Historical Groundwater Analytical Results for Microbiology and:Wet Chemistry Sample Name Sample Date O V r F o V. �° r Z vf0.. - IA o N,. +f0. FO - R E Q O O O H (mg/L) . (mg/L). (CFUsper , 100 mL) " (mg/L) : (mg/L) (mg/L) (mg/L) (mg/L) MW-4 05/15/2002 8.9 45 < 1.1 < 0.10 9.3 180 < 0.10 NA ' 11/05/2002 5.5 48 < 1.1 < 0.1 14 230 < 0.10 NA 05/13/2003 3.3 32 < 1.1 0.051 20 110 0.21 - NA 11/04/2003 41 31 < 1.1 < 5.0 66 210 < 0.10 NA 05/05/2004 6 29 < 1.1 < 5.0 45 240 0.11 NA 11/09/2004 8.4 13 3.6 < 0.10 52 200 c0.10 NA 05/17/2005 8.5 10 <.1.1 < 0.10 37 220 " . < 0.10 NA 11/03/2005 16 14 < 1.1 < 0.10 '29 220 0.14 NA 05/24/2006 19 11 < 1.1 < 0.10 28 ' 180 < 0.10 NA 11/09/2006 8.8 6.9 < 1.1 < 0.10 26 180 < 0.10 NA 05/18/2007 8.5 8.9 < 1.0 < 0.10 29 300 < 0.10 NA 11/13/2007 16.7 11.3 < 1.1 1 < 0.10 25.0 152 . <" 0.10 NA 05/27/2008 < 1.0 10.0 < 1.1 < 0.10 38.6 176 < 0.10 NA 11/18/2008 20.5 9.3 < 1.1 < 0.10 19.6 108 < 0.10 NA 05/28/2009 8.6 13.6 < 4.0 < 0.10 35.5 156 < 0.10 NA 11/05/2009 31.0 13.6 1 < 2.0 < 0.10 30.7 . - 120 < 0.10 NA 05/13/2010 7.8 18.0 < 2.0 0.17 31.0 141 < 0:10 NA 11/08/2010 23.9 17.5 < 2.0 < 0.10 34.4 144 < 0.10 NA 05/17/2011 7.7 13.5 < 2.0 0.82 25.6 137 < 0.10 NA 11/15/2011, 1.3 14.4 < 2.0 < 0.20 27.8 157 - < 0.10 NA 05/17/2012 6.7 12.1 2.0 < 0.20 22.3 117 < 0.10 NA 11/07/2012 10.6 14.5 2.0 < 0.0201 26.2 150 < 0.10 NA 05/16/2013 31.8 10.2 2.0 0.28 19.1 108 < 0.10 NA 11/20/2013 8.0- 14.7 < 1.0 0.026 22.1 157 < 0.10 NA 05/22/2014 8.7 10.8 < 2.0 0.14 22.5 146 < 0.10 NA 11/18/2014 28.7 12.1 < 2.0 . < 0.020 21.9' 161 < 0.10 NA 05/13/2015 5A 9.2 < 1.0 < 0.020 21.5 130 < 0.10 NA 11/04/2015 6.6 6.2 <2.0 < 0.0201 NA 139 1 < 0.10 0.10 05/04/2016 5.5 8.4 < 4.0 < 0.020 NA " 119 < 0.10 0.095 11/09/2016 4.3 12.2 < 4.0 < 0.020 NA 124 < 0.10 0.27 05/02/2017 3.9 7.0 <2.0 0.4 NA 96 <0.10 0.072, 11/08/2017 3.0 7.3 <2.0 1.2 NA 135 <0.10 0.070 05/02/2018 3.0 10.0 <1.0 2.1 NA 167 <0.10 0.11 Standards 10 250 1 10 250 500 1.5 NL Clement Pappas Groundwater Monitoring May 2018 Page 2 of 7 Hendersonville, North Carolina July 2018 ,Sample,Name. •-' Samp!OVaite- _ O C. - O Oi+ a L o u: _ H 'O O p c.. O _ E s a , (mg/L) (mg/L) (CPUs>per ..-100`mL) (mg/L) :(mg/L) (m9/4) (m9 L) (m9/W: MW-5 05/15/2002.. - 2.9 .' • 15. < 1.1- 0.42 ..' . 1.7 < 40 < 0:10: NA 11 /05/2002 . 1:4 . 16. . r.1;1 0:54 c 1.0 83 ' ' : 1.3. NA 05/13/200, 3 : 4.6 , 17 <. 1.1 0.65 2 56 0.25 " NA 11/04/2003 19. - -' 22 <.1.1: 0.28 <'5.0 58: < 0.10 :: NA. . 05/05/2004 0.7 . -28 < 1:1.' - 0.57. < 5.0 80.. 0:15 NA,. 1.1/09/2004 1'.2 : 34 . < 1:1 : 0.24 . < 5;0 130 .. < 0.10_ NA 05/17/2005 2:1 35 . < 1.1 < 0:10:: < 5.0. 110 < 0.10 . NA 11/03/2005 : 8:1. ` ' .34. " <-:1.1 _ 0.11 . <- 5.0 82 ` < 0.1.0 NA - 05/24/2006 7.8: - 34 < 1.1 < 0.10 <. 5.0 .120 . < 2.5 NA 11/09/2006' 1.3 : 37 ,' <:1:1 . 0:20-_ - 2.-5.0 90 <:0.1. NA 05j18/2007 .: - I.T. 42 <:1 D .. . 0.16 <' 5.0 . 130 < 0.10 NA' 11/13/2007 .' 4.2.". '41.3 < 1,1.: 0.25 .. < 5.0 112 < 0:10: "'NA'' 05/27/2008 6.7. 14.5 < .1;1 0:21 < 5.0 168 0.17. NA 11/18/2008, 25.9. 47.6 :. .' <. 1.1 0.17 - z:5.0 86.0 < 0.10 NA 05/28/2009. 16.1 : :•29.0 : 4.0 : 0.11 <.5.0 -188 - <.0:10 :. NA. 11/05/2009 4.7 ' . . 39.1 2.0 . - . ' 0.15 < 5.0 112 . < 0.10 NA' . . 0.5/13/2010 3.2 ; -43.'0. ' :.. 23.: 0.17 : , <-5.0 -W .: < 0.10. ' ' NA' 11 /08/2010 .: 13.8 43:7 200 '' . < 0:10' :. < 5.0. 113 . :< 0.10 NA 05/1.7/201.1:: 4:0.' ' 32.3 <'4.0 - -.'< 0.10 <_ 5.0_ ..< 167. < 0..10. NA 11/15/2011 :. 3.0.'' S2.6' ` 120 <0.20 <.5.0 .165. <'0.10 ,NA. 05/17/2012 4:7 `36.6 .' <: 2:0 , < 0.:20: < 5.0 - 110 ' < 0.'10- 'NA. ' 11/07/2012 .. : .4.1 61.1 < :10.0 . 0.12 c 2.0 . .139 < 0.10 --NA' 05/16/2013, .4.0 . 44.2 ' . 0.093 ... 2:3.: 152 < 0:10: NA ' 11/20/2013 .' 4:2,. -64.6' 1:0.' 0:19�' r2.0 162 ` :-< 0.10 NA' 05/22/2014: 5:8 . "6.6 < 10.0 ..' 0.099: <.2,0 110. <.0.10 11/18/2014' 16:0 : 'S7.7 . 6.0 : 0:28., <.2.0 160 - <.0.10 NA' 05/13/2015 21.0 - - 68.4 - . < 2.0. ' 0.1.1. < 2:0 -176 . < :0.10 NA. . 11/04/2015 - 7.3 : 20.3. ' - .. 7.0. < '0.020 . -NA' 68.0 .. <-0.10, 0.21 05/04/2016' . ::8:6, 4.1:5 < 10.0 . 0.042 NA - .90.0_ < 0.10 0;12 11/09/2016 : <1:0`' 45.0 <.4.0 . 0.42 - NA 109 < 0.10• .'0.47 05/02/2017 8.1. - L29.'0, : 3.0 <0.020 NA 134. <0'10' 0.097. 11/08/2017 _ 6:7 12:8. 188 . <0.020 NA., 84.0 <0:10 : 0.086 05/02/2018. - 5.7 16.1 10 0.022- :NA 90.0- .<0.10 0.097 "Standdrds- , = -: -- 70 250 - - 1 .".: 10 250 : 500 1.5 .: - -NL ' Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Sample Name Sample Date 0 U •� O r F M L 0 U C UO V LL ;+ r Z « W 4A o M d Vl i] Y H 10 0 Q L 0 t 0 a r .. H (mg/L) (mg/L) (CFUs per 100 mL) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) MW-6 05/15/2002 6.8 9.9 5.1 < 0.10 11 < 40 < 0.10 NA 11/05/2002 3.9 4.6 < 1.1 0.49 9.8 51 2.5 NA 05/13/2003 4.4 7.3 > 23.0 0.075 14 52 1 0.14 NA 11/04/2003 ' 26 6.8 9.2 < 0.050 12 < 20 < 0.10 NA 05/05/2004 1.8 6.7 1.1 < 0.10 1.1 58 0.13 NA 11/09/2004 3.5 11 9.2 < 0.10 9.3 88 < 0.10 NA 05/17/2005 2.4 7.4 < 1.1 < 0.10 8.7 50 < 0.10 NA 11/03/2005 6.3 9.6 < 1.1 < 0.10 9.6 66 0.17 NA 05/24/2006 7.4 10 < 1.1 < 0.10 " 9 54 !< 0.10 NA 11/09/2006 1.4 11 < 1.1 0.20 11 54 0.18 NA 05/18/2007 3.9 9.4 < 1.0 < 0.10 9.1 58 0.12 NA 11/13/2007 5.7 10.7 3.6 0.24. 5.8 114 0.24 NA. 05/27/2008 10.9 5.4 < 1.1 < 0.10 15.3 92.0 < 0.10 NA 11/18/2008 7.4' 7.6 > 23 < 0.10 < 5.0 36.0 < 0.10 NA 05/28/2009 6.4 6.2 276 0.39 8.8 .104 < 0.10 NA 11 /05/2009 6.4 < 5.0 30 0.10 9.3 52.0 < 0.10 NA 05/13/2010 4.3 5.8 < 2.0 < 0.10 8.1 44.0 < 0.10 NA 11/08/2010 16.5 5.0 7.0 1.5 9.3 48.0 < 0.10 NA 05/17/2011 6.2 9.4 < 2.0 < 0.10 6.8 60.0 < 0.10 NA 11/15/2011 4.6 5.2 5.0 < 0.20 7.5 82.0 < 0.10 NA 05/17/2012 21.6 8.1 28.0 < 0.20 8.8 52.0 < 0.10 NA 11/07/2012 6.4 6.8 3.1 < 0.020 7.5 46.0 < 0.10 NA 05/16/2013 7.5 5.4 12.1 0.048 9.4 62.0 < 0.10 NA 11/20/2013 4.4 7.3 < 1.0 < 0.020 8.6 56.0 < 0.10 NA 05/22/2014 4.6 4.5 1.0 < 0.020 10.1 32.0 < 0.10 NA 11/18/2014 16.3 6.9 13.0 0.078 1 9.8 49.0 < 0.10 NA 05/13/2015 2.1 6.2 < 1.0 < 0.020 10.1 46.0 < 0.10 NA 11/04/2015 2.2 9.5 136 2.9 NA 58.0 < 0.10 0.12 05/04/2016 2.1 9.4 < 2.0 0.41 NA 58.0 < 0.10 0.079 11/09/2016 7.1 9.0 < 10.0 < 0.020 NA 64.0 0.11 0.70 05/02/2017 1.8 12.1 2.0 0.47 NA 93.0 <0.10 0.09 11/08/2017 1.4 11.1 74.0 0.045 NA 66.0 <0.10 <0.050 05/02/2018 2.3 9.4 1.0 0.085 NA 81.0 <0.10 0.097 Standards 70 250 7 10 250 500 7.5 NL Clement Pappas Groundwater Monitoring May 2018 Page 4 of 7 Hendersonville, North Carolina July 2018 Sample Name Sample'Date •�' ' A V O , ia+ .0 u • u ;; aY+, w M V O. H C r E In L O IA O a r (mg/L) ,(mg/L) (CFUsL per ' 100•mL). (mg/L) (mg/L) (mg/L); .(mg/L) (mg/L) MW=7. -. : 05/15/2002.. .20 , 6.5 < 1.1•' 5.2 - - - 26 : < 40 < 0.10 NA _ :11/05/2002 16' 3.3 r 1.1 1:3 1:1. 68 1.4 NA 95/13/2003: 9:7.. 3.6 2.2 1.8 '. '9.3 44'' - 0.72 NA 11/04/2003 1.9 . 6.1 <.1.1 0.72 <.5.0 < 2.0. <.0.10 NA. 05/05/2004 3.0 7:0 <:•1:1 - 1.3. < 5.0 52- . < 0.10 NA . . 11/09/2004 2.2 ' 5.1 5:1:: 1.9 : < 5:0 62 .. < 0.10, NA 05/17j2005 3:2 6.1- c 1.1 : 1.2 :: < 5.0 . - 40 ; - < 0.10 NA 11/03/2005 7.7 6.1 <'.1:1. "0.99. <.5.0 58 D..10 NA 05/24/2006 8.4 5.5 < 1.1 1:5- <: 5:0 48:. < 0.10 NA :. 11 j09/2006 1:9 7.0 <:1:1 . 1.1 6:7 38' < 0.10 NA. 05/18/2007.... 3.6 8:6. - <:1:0.. 2.2 5.9 . 70- < 0.10 NA 11/13/2007.. 4.2 .. 6.8' < 1.1 : .1.7, ' < 5.0 42.0- ' < 0.10 NA 05/27/2008 7.6'.. 11.5- <-1:1 .. 2.2 6.9 88.0 < 0.10 NA `'. 11/18/200.8:- T..5. -7.7 <1.1 :1.7' . <:5.0 30.0. <0.10 NA:: 05/28/2009 23.4 ; 9.8 <.4.0 & ..2.3 < 5.0 336 ' < .0.10 NA.' • 11/05/2009 5.3 10.7 . 2.0-. 2.3 . - 11:2 - 70.0 - < 0.10 NAB 05/13/2010 . 4.6 ': 11:0 < 2.0 : 2.5 < -5.0. 71.0 .. < 0.1.Q NA 11/08/2010 : 15.4 8.9. c 2,0 . : 2.3;.:: < 5.0 60.0, < 0.10 .NA 05117/201.1. 6:0 11.6 < 2.0 5.3 . 7.6 . `103 < 0.10 NA - - 11/15/2011 2.2. 9.9 < 2.0. • 3:5. <. 5.0 89:0. <-0.10 NA :. 05/17/2012 ' 4.4 10.9 - <: 2:0 , 3.8 • . <. 5.0. 67.0 < 0.10. : NA MW=7R . 11/07/2012 . 11 X. & 13.1 < 100, ..4.0 14.9.. 108.0 < 0.10 NA - 05/16/2013 12.8 -17.1 < 1.0. 10.5 .28.3. 252 - < 0.10 -NA - 11/20/2013 9-4 .. 14.0 <.1.0 5:5 3:5 < 250 < 0.10 NA 05/22/2014 : 8:9 - 13:1 . c 1,0,000 5.7 4.0 93.0. • < 0.10 NA ;. 11/18/2014 - - 19.1 - :16,0 c 20.0 7.1 4.4 93.0 < 0.10 NA.' 05/13/2015 8.5 17.0 . <: 2.0. 9.3 . 3.7. 125 < 0.10 NA . . 11/04/2015 ..9.9 : 18:0. < 2.0: 8.3 - NA : 129 <-0.1.0. 0.35 05/04/2016 13.5 . 27:7 < 10.0 11:2 :: NA ..130;, :< 0.10 0.78 . 06/09/2016 ,'Pace - . NA.' NA NA' . ..10.9 . NA- . `NA NA 06/09/2016 = Prism. NA ' . NA NA, 10.0 NA NA f NA NA 11 j09/2016 13.0 22.7 < 20.0. U.5 _ NA - 147 < 0.10, 1.01 05/02/2017 . , .6.7' . . 17.9 <4.0 . 8.9 NA. -169 Am 0.4 : - 1'1/08j2017. 3.9 17.9 A9:0: 36.8.: NA•: 376 .<0.10 0.14 05/02/2018 3.2 .. - 22.6 <2.0 153 -NA 207 <0.10 0.32 Standdrds - . - 10. 250 1..• 10,. 250 500.. 1:5 NL :_ Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Sample Name Sample Date G M u � 0 •o w u a, a �° Q � G c E4. y ` �.. c a sa R (mg/L) (mg/L) (CFOs per 100 mL) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) MW-8 05/15/2002 6.8 8.7 < 1.1 < 0.10 9.1 '64 < 0.10 NA 11/05/2002 4.8 9.8 < 1.1 0.16 7 100 .0.57 NA 05/13/2003 5.5 3.3 2.2 1.4 9.4 64 0.41 - NA 11/04/2003 27 8.1 6.9 < 0.050 13 54 < 0.10 NA 05/05/2004 3.0 7.4 < 1.1 .0.24 9.8 140 < 0.10 NA 11/09/2004 3.7 6.7 > 23 0.79 6.8 120 < 0.10 NA 05/17/2005 3.8 8.3 < 1.1 0.61 , 6.4 88 < 0.10 NA 11/03/2005 7.1 11 < 1.1 0.95, 8.4 100 < 0.10 NA 05/24/2006 15 10 < 1.1 0.39 8.1 130 < 0.10 NA 11/09/2006 4.7 12 < 1.1 0.97 7.7 96 < 0.10 NA 05/18/2007 5.0 j 15 < 1.0 3.0 13 290 < 0.10 NA 11/13/2007 8.3 19.6 < 1.1 0.97 26.6 154 < 0.10 NA 05/27/2008 12.4 20.0 < 1.1 0.55 35.8. 184 < 0.10 NA 11/18/2008 14.4 17.2 2.2 < 0.10 21.5 118, < 0.10 NA 05/28/2009 6.2 24.9 240 0.74 24.9 192 < 0.10 NA 11/05/2009 10.8 15.4 50 0.54 18.4 114 < 0.10 NA 05/13/2010 10.8 14.7 < 2.0 1.1 24.1 106 < 0.10- NA 11/08/2010 23.2 24.3 200 < 0.10, 26.3 173 < 0.10 NA 05/17/2011 10 16.9 10.0 12.2 16.1 232 < 0.10 NA 11/15/2011 8.0 26.6 < 2.0 3.7 20.2 232 < 0.10 NA 05/17/2012 14.4 24.8, 12.0 8.0 22.9 356 < 0.10 NA 11/07/2012 24.8 26.3 < 100 1.9 28.3 324 < 0.10 NA 05/16/2013 15.8 8.8 10.9 6.8 13.4 248 < 0.10 NA 11/20/2013 21.0 15.4 < 1.0 1.3 24.3 342 < 0.10 NA 05/22/2014 17.6 14.5 < 10.0 0.61 17.8 352 < 0.10 NA 11/18/2014 54.0 16.4 < 4.0 1.1 13.2 421 < 0.10 NA 05/13/2015 19.7. 18.3 < 2.0 9.7 12.2 454 < 0.10 NA 11/04/2015 15.0 _ 21.6 4.0 3.0 NA 396 < 0.10 0.82 - 05/04/2016 15.0 24.5-, < 10.0 19.1 NA 398 < 0.10 0.62 6/9/2016 - Pace NA NA NA 26.3 NA NA NA NA 06/09/2016 - Prism NA NA NA 26.0 NA NA NA NA 11/09/2016 9.7 12.0 < 4.0 14.3 NA 333 < 0.10 0.26 05/02/2017 11.4 18.9 8.0• 12.4 NA 497 <0.10 0.3 11/08/2017 8.1 9.7 <4.0 -14.4 NA 390 <0.10 0.098 05/02/2018 10.8 12.9 <2.0 14.4 NA 548 , <0.10 0.19 standards 10 250 1 10 250 500 1.5 NL Clement Pappas Groundwater Monitoring May 2018 Page 6 of 7 Hendersonville, North Carolina July 2018 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry .0 V V N 3 C . >- 0 s w O H ' O 'a v N ,0 O. O .0 (CFUs per Sample Name . Sample Date (mg/L) '(mg/L) 100' mL) (mg/L) (mg/L) (mg/L) (mg/L) (mg/.Q 05/13/2015 2.2 12.4 < 2.0 11.0 5.5 94.0 < 0.10 NA 11/04/2015 3.8 2.6 < 1.0 < 0.020 NA 58.0 < 0.10 0.45 05/04/2016 15.0 5.3 < 10.0 0.64 NA 51.0 < 0.10 0.095 MW-9 11/09/2016 9.3 10.7 < 20.0 0.77 NA 69.0 < 0.10 0.76 05/02/2017 7.6 3.8 <4.0 0.17 NA 92.0 1 <0.10 0.61 11/d8/2017 7.0 8.9 10.0 0.95 NA 64.0 <0.10 0.53 05/02/2018 4.6 4.9 <2.0 I-07-F NA 69.0 <0.10 0.37 Standards 10 250 1 1 10 250 500 1.5 NL Notes: Standards are from North Carolina Administrative Code, Title 15A, Subchapter 2L (21- standards), April 1, 2013, except total organic carbon and fecal coliform. The total organic carbon standard is from Spray Irrigation Permit Number WQ0004797. The fecal coliform standard is the 2L standard for total coliform. 06-09-2016 - Pace/Prism: A resampling event was performed on June 9, 2016, to investigate nitrate exceedances in MW-7R and MW-8.One set of samples was analyzed by Pace Analytical Services, and a second set of samples was analyzed by Prism Laboratories. Sulfate was removed from the list of necessary analyses as of fall 2015 and replaced by total phosphorous. Bolded values indicate a concentration equal to or above the respective standard. < indicates that the constituent concentration was not detected above the laboratory reporting limit. CFU: coliform-forming unit mg/L: milligrams per liter mL: milliliter NA: not analyzed NL : No standard limit is set. Clement Pappas Groundwater Monitoring May 2018 Page 7 of 7 Hendersonville, North Carolina July 2018 Table 2 Current and Historical Groundwater Elevation Measurements Well Identification. Date Measured Depth to, Groundwater (feet BTOC), Top:: -of -Casing Elevation (feet) 'Top -of -Casing ,Height Above- . Ground Surface (feet) Groundwater' Elevation. (feet)- MW-2R 05/24/2006 9.29 2063.00 3.77 2053.71 11/09/2006 6.49 2063.00 3.77 2056.51 05/18/2007 7.94 2063.00 3.77 2055.06 11/13/2007 8.46 2063.00 3.77 2054.54 05/27/2008 8.48 2063.00 3.77 2054.52 11/18/2008 8.50 2063.00 3.77 2054.50 05/28/2009 5.43 2063.00 3.77. 2057.57 11/05/2009 6.72 2063.00 3.77 2056.28 05/13/2010 7.36 2063.00 3.77 2055.64 11/08/2010 9.60 2063.00 3.77 2053.40 05/17/2011 7.25 2063.00- 3.77 2055.75 11/15/2011 7.86 2063.00 3.77 2055.14 05/17/2012 5.19 2063.00 3.77 2057.81 11/07/2012 7.74 2062.36 3.77 2054.62 05/16/2013 6.86 2062.36 3.77 2055.50 11/20/2013 7.92 2062.36 3.77 2054.44 05/22/2014 7.56 2062.36 3.77 2054.80 11/18/2014 8.89 2062.36 3.77 2053.47 Well abandoned, replaced by MW-9. Clement Pappas May 2018 Groundwater Monitoring Page 1 of 7 Hendersonville, North Carolina July 2018 Table 2 Current and Historical Groundwater Elevation Measurements Well 'Identification Date Measured Depth to Groundwater (feet BTOC) Top -of -Casing Elevation (feet) Top -of -Casing ' . Height Above Ground Surface (feet) Groundwater Elevation - (feet) MW-4 05/15/2002 9.32 2064.60 2.43 2055.28 11/05/2002 9.49 2064.60 2.43 2055.11 05/13/2003 8.20 2064.60 2.43 2056.40 11/04/2003 9.23 2064.60 2.43 2055.37 05/05/2004 9.35 2064.60 2.43 2055.25 11/09/2004 8.61 2064.60 2.43 2055.99 05/17/2005 6.19 2064.60 2.43 2058.41 11/03/2005 9.57 2064.60 2.43 2055.03 05/24/2006 9.60 2064.60 2.43 2055.00 11/09/2006 8.41 2064.60 2.43 2056.19 05/18/2007 9.42 2064.60 2.43 2055.18 11/13/2007 9.89 2064.60 2.43 2054.71 05/27/2008 9.78 2064.60 2.43 2054.82 11/18/2008 9.76 2064.60 2.43 2054.84 05/28/2009 7.16 2064.60 2.43 2057.44 11/05/2009 8.53 2064.60 2.43 2056.07 05/13/2010 8.83 2064.60 2.43 2055.77 11/08/2010 9.30 2064.60 2.43 2055.30 05/17/2011 8.97 2064.60 2.43 2055.63 11/15/2011 9.48 2064.60 2.43 2055.12 05/17/2012 7.62 2064.60 2.43 2056.98 11/07/2012 9.32 2063.77 2.43 2054.45 05/16/2013 7.93 2063.77 2.43 2055.84 11/20/2013 8.87 2063.77 2.43 2054.90 05/22/2014 8.70 2063.77 2.43 2055.07 11/18/2014 8.54 2063.77 2.43 2055.23 05/13/2015 9.18 2063.77 2.43 2054.59 11/4/2015 6.93 2063.77 2.43 2056.84 05/04/2016 8.43 2063.77 2.43 2055.34 11/09/2016 9.63 2063.77 2.43 2054.14 05/02/2017 7.82 2063.77 2.43 2055.95 11/08/2017, 7.88 2063.77 2.43 2055.89 05/02/2018 8.44 2063.77 2.43 2055.33 Clement Pappas May 2018 Groundwater Monitoring Page 2 of 7 Hendersonville, North Carolina July 2018 Table 2 Current and Historical Groundwater Elevation Measurements Well - - Identifications Date Measured Depth to Groundwater (feet BTOC) Top -of -Casing Elevation (feet). Top -of Casing Height Above' j Ground Surface "(feet) -Groundwater Elevation (feet) MW-5 05/15/2002 8.31 2086.40 3.00 2078.09 11/05/2002 10.20 2086.40 3.00 2076.20 05/13/2003 8.29 ' 2086.40 3.00 2078.11 11/04/2003 9.92 2086.40 3.00 2076.48 05/05/2004 8.75 2086.40 .3.00 2077.65 11/09/2004 8.50 2086AO 3.00 2077.90 05/17/2005 8.87 2086.40. -3.00 2077.53 11/03/2005 9.70 2086AO 3.00 2076.70 05/24/2006 9.34 2086.40 3.00 2077.06 11/09/2006 8.39 2086.40 3.00 2078.01 05/18/2007 9.16 -2086.40 3.00 2077.24 11/13/2007 11.00 2086.40 - 3.00 2075.40 05/27/2008 9.84 2086.40 3.00 2076.56 11/18/2008 11.59 2086.40 3.00 2074.81 05/28/2009 7.95 2086.40 3.00 2078.45 11/05/2009 8.63 2086.40 3.00 2077.77 05/13/2010 8.87 2086AO 3.00 2077.53 11/08/201.0 10.24 2086AO 3.00 2076.16. 05/17/2011 8.99 2086AO 3.00 2077A1 11/15/2611 10.58 2086.40 3.00 2075.82 05/17/2012 8.73 2086.40 3.00 2077.67 11/07/2012 . 9.65 2085.60 3.00 2075.95 05/16/2013 8.14 2085.60 3.00 2077.46 11/20/2013 9.33 2095.60 3.00 2076.27 05/22/2014 8.57 2085.60 3.00 2077.03 11/18/2014 9.04- 2085.60 3.00 2076.56 05/13/2015 8.92 2085.60 3.00 2076.68 11 /4/2015 8.12 2085.60 3.00 2077.48 05/04/2016 8.54 2085.60 3.00 2077.06 .11/09/2016 11.25 2085.60 3.00 2074.35 05/02/2017 8.63 2085.60 3.00 2076.97 11/08/2017 8.23 2085.60 3.00 2077.37 05/02/2018 8.47 ,2085.60 3.00 2077.13 Clement Pappas May 2018 Groundwater Monitoring Page 3 of 7 Hendersonville, North Carolina July 2018 Table 2 Current and Historical Groundwater Elevation Measurements Well " Identification ; .Date Measured Depth to Groundwater (feet BTOC) Top=of-Casing ' : Elevation (feet) Top =of -Casing' Height Above Ground Surface (feet) .Groundwater -Elevatioh - (feet) . MW-6 05/15/2002 6.20 2061.90 3.00 2055.70 11/05/2002 6.15 2061.90 3.00 2055.75 05/13/2003 5.43 2061.90 3.00 2056.47 11/04/2003 5.85 2061.90 3.00 2056.05 05/05/2004 6.00 2061.90 3.00 2055.90 11/09/2004 5.32 2061.90 3.00 2056.58 05/17/2005 6.10 2061.90 3.00 2055.80 11/03/2005 6.01 2061.90 3.00 2055.89 05/24/2006 6.48 2061.90 3.00 2055.42 11/09/2006 5.71 2061.90 3.00 2056.19 05/18/2007 6.50 2061.90 3.00 2055.40 11/13/2007 7.85 2061.90 -3.00 2054.05 05/27/2008 7.01 2061.90 3.00 2054.89 11/18/2008 7.38 2061.90 3.00 2054.52 05/28/2009 5.63 2061.90 100 2056.27 11/05/2009 5.74 2061.90 3.00 2056.16 05/13/2010 5.90 2061.90 3.00 2056.00 11/08/2010 5.99 2061.90. 3.00 .2055.91 05/17/2011 5.85 2061.90 3.00 2056.05 1.1/15/2011 6.14 2061.90 3.00 2055.76 05/17/2012 5.87 2061.90 3.00 2056.03 11/07/2012 6.05 2061.17 3.00 2055.12 . 05/16/2013 5.84 2061.17 3.00 2055.33 11/20/2013 5.96 2061.17 3.00 2055.21 05/22/2014 5.96. 2061.17 3.00 2055.21 11/18/2014 5.82 2061.17 3.00 2055.35 05/13/2015 6.05. 2061.17 3.00 2055.12 11/4/2015 5.18 2061.17 3.00 2055.99 05/04/2016 5.59 2061.17 3.00 2055.58 11/09/2016 7.42 2061.17 3.00 2053.75 . 05/02/2017 5.31 2061.17 3.00 2055.86 11/08/2017 4.80 - 2061.17 3.00 2056.37 05/02/2018 5.36 2061.17 3.00 2055.81 Clement Pappas May 2018 Groundwater Monitoring Page 4 of 7 Hendersonville, North Carolina July 2018 Table 2 Current and Historical Groundwater Elevation Measurements Well. " Identification. Date Measured Depth to Groundwater (feet BTOC) Top -of -Casing Elevation (feet). Top=of-Casing Height Above Ground Surface , (feet) Groundwater Elevation (feet), MW-7 05/15/2002 10.90 2062.70 3.00 2051.80 11/05/2002 11.35 2062.70 3.00 2051.35 05/13/2003 8.87 2062.70 3.00 2053.83 11/04/2003 10.78 2062.70 3.00 2051.92 05/05/2004 10.80 2062.70 3.00 2051.90 11/09/2004 9.70 2062.70 3.00 2053.00 05/17/2005 10.60 2062.70 3.00 2052.10 - 11/03/2005 11.09 2062.70 3.00 2051.61 05/24/2006 11.27 2062.70 3.00 2051.43 11/09/2006 9.71 2062.70 .3.00 2052.99 05/18/2007 11.02 2062.70 3.00 2051.68 11/13/2007 11.76 2062.70 3.00 2050.94 05/27/2008 11.55 2062.70 3.00 2051.15 11/18/2008 11.63 2062.70 3.00 2051.07 05/28/2009 .8.21 2062.70 3.00 2054.49 11/05/2009 9.89 2062.70 3.00 2052.81 05/13/2010 10.44 2062.70 3.00 2052.26 11/08/2010 11.12 2062.70 3.00 2051.58 05/17/2011 10.80 2062.70 3.00 2051.90 11/15/2011 11A3 2062.70 3.00 2051.27 05/17/2012 8.91 2062.70 3.00 2053.79 MW-7R 11/07/2012 12.02 2062.86 3.00 2050.84 05/16/2013 10.29 2062.86 3.00 2052.57 11/20/2013 11.69 2062.86 3.00 2051.17 05/22/2014 11.38 2062.86 3.00 2051.48 11/18/2014 11.25 2062.86 3.00 2051.61 05/13/2015 11.94 2062.86 3.00. 2050.92 11/4/2015 8.43 2062.86 3.00 2054A3 05/04/2016 11.08 2062.86 3.00 2051.78 11/09/2016 12.63 .2062.86 3.00 2050.23 05/02/2017 . 10.13 ' 2062.86 3.00 2052.73 11/08/2017 10.34 2062.86 3.00 2052.52 05/02/2018 10.99 2062.86 3.00 2051.87 Clement Pappas May 2018 Groundwater Monitoring Page 5 of 7 Hendersonville, North Carolina July 2018 Table 2 Current and Historical Groundwater Elevation Measurements Wel4 Identification, Date Measured Depth to Groundwater (feet BTOC) Top -of -Casing .. Elevation- (feet) , Top -of -Casing Height Above `. Ground, Surface': „ (feet) • Groundwater Elevation (feet) MW_8 05/15/2002 10.25 2061.40 3.00 2051.15 11/05/2002 10.35 2061.40 3.00 2051.05 05/13/2003 8.16 2061.40 3.00 2053.24 11/04/2003 10.23 2061.40 3.00 2051.17 05/05/2004 10.30 2061.40 3.00 2051.10 11/09/2004 8.90 2061.40 3.00 2052.50 05/17/2005 10.08 2061.40 3.00 2051.32 11/03/2005 10.61 2061.40 3.00 2050.79 05/24/2006 10.60 2061.40 3.00 2050.80 11/09/2006 9.40 2061.40 3.00 2052.00 05/18/2007 10.31 2061.40 3.00 2051.09 11/13/2007 11.09 2061.40 3.00 2050.31 05/27/2008 10.83 2061.40 3.00 2050.57 11/18/2008 11.11 2061.40 3.00 2050.29 05/28/2009 8.25 2061.40 3.00 2053.15 11/05/2009 9.22 2061.40 3.00 2052.18 05/13/2010 9.88. 2061.40 3.00 2051.52 11/08/2010 10.38 2061.40 3.00 2051.02 05/17/2011 10.27 2061.40 3.00 2051.13 11/15/2011 10.87 2061.40 3.00 2050.53 05/17/2012 8.03 2061.40 3.00 2053.37 11/07/2012 10.45 2060.80 3.00 2050.35 05/16/2013 8.58 2060.80 3.00 2052.22 11/20/2013 10.34 2060.80 3.00 2050.46 05/22/2014 9.79 2060.80 3.00 2051.01 11/18/2014 10.03 2060.80 3.00 2050.77 05/13/2015 10.34 2060.80 3.00 2050.46 11/4/2015 7.21 2060.80 3.00 2053.59 05/04/2016 9.84 2060.80 3.00 2050.96 11/09/2016 11.16 2060.80 3.00 2049.64 05/02/2017 8.48 2060.80 3.00 2052.32 11/08/2017 8.73 2060.80 3.00 2052.07 05/02/2018 9.39 2060.80 3.00 2051.41 Clement Pappas May 2018 Groundwater Monitoring Page 6 of 7 Hendersonville, North Carolina July 2018 Table 2 Current and Historical Groundwater Elevation Measurements Well Identification Date Measured Depth to Groundwater (feet BTOC) Top -of -Casing Elevation (feet) Top -of -Casing Height Above Ground Surface (feet) Groundwater Elevation (feet) MW-9 05/13/2015 6.03 2060.23 1.44 2054.20 11/4/2015 2.89 2060.23 1.44 2057.34 05/04/2016 5.53 2060.23 1.44 2054.70 11/09/2016 6.55 2060.23 1.44 2053.68 05/02/2017 3.99 2060.23 1.44 2056.24 11/08/2017 3.60 2060.23 1.44 2056.63 05/02/2018 5.07 2060.23 1.44 2055.16 Notes: BTOC: feet below top of well casing Groundwater elevations: top of casing minus depth to groundwater Top -of -casing elevations: MW-5 through MW-8 top -of -casing elevations are based upon a survey by Hill and Associates Surveyors, dated January 10, 2002, through May 2012. MW-2R and MW-4 top -of -casing elevations are based upon differential level measurements made by Altamont Environmental, Inc., on June 26, 2006, through May 2012. The top -of -casing elevations for the monitoring wells were resurveyed on November 21, 2012, by Wes Cole Land Surveying. The top -of -casing elevations for MW-9 were surveyed on May 29, 2015, by Wes Cole Land Surveying. Clement Pappas May 2018 Groundwater Monitoring Page 7 of 7 Hendersonville, North Carolina July 2018 Table 3 Current and Historical Surface Water Analytical Results m. � U. E M c . c�CL = in m Im O' v N C _ o o a M O o A To 8 To F= L u Li Z �°— ¢ H (CFOs per Sample Name Sample Date (mg/L) (mg/L) 100 mL) (mg/L) (mg/L) (mg/L) (mg/L) 6/9/2016 (Prism) NA NA NA 0.74 NA NA NA (Pace) NA NA NA 0.85 NA NA NA SW--16/9/2016 5/2/2017 2.7 4.7 580 0.64 64.0 <0.10 <0.050 (Upstream) 11/8/2017 2.5 5.1 530 0.66 44.0 <0.10 0.091 5/2/2018 1.5 4.8 53.0 0.74 54.0 <0.10. 0.044 J 6/9/2016 (Prism) NA NA NA 0.78 NA NA NA 6/9/2016 (Pace) NA NA NA 0.86. NA NA NA SW-2 5/2/2017 2.7 4.7 93S 0.63 41.0 <0.10 0.052 (Downstream) 11/8/2017 2.8 4.8 860 0.(1 54.0 <0.10 0.094 5/2/2018 1 A 4A 118 0.72. 51.0 1 0.052 J 0.045 J Standards NL 230 - < 200 NL NL I NL NL Notes: 6/9/2016 (Prism/Pace): A sampling event was performed on June 9, 2016.One set of samples was analyzed by Prism Laboratories, and a second set of samples was analyzed by Pace Analytical Services. Standards are from North Carolina Administrative Code, Title 15A,.Subchapter 2B. Bolded values indicate a concentration equal to or above the respective standard. - < indicates that the constituent concentration.was not detected above the laboratory reporting limit. "1" flag indicates that the concentration is above the adjusted method detection limit and below the adjusted reporting limit, and is therefore considered an estimate. CFU: coliform-forming unit mg/L: milligrams per liter mL: milliliters f . NA: not analyzed NLr No standard limit is set. Clement Pappas Surface Water Monitoring May 2018 Page 1 of 1 Hendersonville, North Carolina July 2018 Pace Analytical,Services; LLC ® aceMalytical 2225 Riverside Dr. Asheville, NC 28804 www.pacelabs.com. (828)254-7176 . SAMPLE SUMMARY . Project: - CLEMENT PAPPAS Pace, Project No.: 92383249 Lab ID Sample ID ` . Matrix Date Collected Date. Received 92383249001 . , SW-1.: _ Water 05/02/18 14:35 . 05/02/18 15:30 . 92383249002 SW-2 Water 06/02/1810:30. 05/02/1815:30. 92383249003 MW=4:: Water . '..' .05/02/18 14:11 .' .05/02/18 15:30 . 92383249004 .. MW-5 Water 05/02/1812:04.. 05/02/1815:30 .92383249005 MW-6_ .' . Water . 05/02/18 12 49 05/02/1815:30 . . 92383249006 MW-7R Water 05/02/1811:15. 05/02/1815:30.. 92383249007.. M1N-8. Water' 05/0271810:10. 05/02/1.815:30. 92383249008 .. MW4 - Water 05/02/18 13:35, - .05/02/18 15' 30 .' REPORT OF LABORATORY ANALYSIS - This'report'shall not be reproduced; except in full, without the written consent of. Pace Analytical Services, LLC.. Page 3 of 27 . Pace Analytical Services; LLC Q p ® 2225 Riverside Dr. c?G@A11e?�y1�Gai Asheville, NC 28804 wwwpacelabs:com .. (828)254 7476 - SAMPLE ANALYTE COUNT Project: CLEMENT PAPPAS . . Pace Project No.: 92383249 � Analytes . . Lab -ID :. Sample ID Method Analysts Reported _ .Laboratory 9238324900.1. SW-1 . -. _ . SM 2540C .... CAM 1 PASI-A' ..... . SM-9222D: KDF1 :. 1 - PASI-A EPA 350.1 1993 Rev 2.0 : BRJ:. 1 ,PASI=A _ . EPA353.2 CJH1 1.. PASI-A.. ,. -.. EPA 365.1 BRJ. 1 - PASF A - SM 4500-CI-E - ' AES2-. 1 PAASI-A SM 531 OB : MDW ' 1 PASI-A 92383249002 SW-2 SM 2540C. CAM .1 PASI-A .. SM 9222D _ . KDF1' - - ' . 1.. PASI-A .. EPA'350:11993 Rev.2.0" -:' ' _ _ BRJ 1 PASI-A - .. EPA353.2 CJH1,. 1.. PASI-A .. . . EPA365..1 : BRJ 1 PASI-A . SM 4500 CIE AES2 1 PASI A' .' . SM 53106 '. MDW 1 - PASI- A . 02383249003: MW-4'.' .- SM-2540C .' CAM 1 - -.PASI-A. " SM 9222D . • KDF1;- 1 PASI A'. -. EPA 350.1 1993 Rev.2.0 BRJ 1 PASI-A . EPA 353.2. CJH1 : 1 ' :. PASf A EPi4365.4 BRJ 1'. - PAS I A_. ` SM 4500-CI-E` . AES7 1 PAS.I=A . SM 531QB MDW1. - 1 PASI-A . , 92383249004. - MW-5 SM 254OC: CAM 1 PASI-A SM 9222D.. KDF1 : 1 ' PASI=A' .. , EPA 350.1 1993 Rev,2.0 • '. BRJ 1.. PASI-A .. .EPA353.2 ,' CJH1 1 PAS.I'A. EPA 365.1 BRJ :. 1.. PASI A SM.45007CI-E AES2 1 PASI-A . - S M 5310B. MD1N : .. 1 PASI=A - 92383249005: °. MW-6 ... SM2540C . :. -CAM 1.. PASI-A... . SM 9222D .' KDF1 .. -" .: -1 PASI-A- EPA350.1.1993 Rev 2.0 : BRJ 1 PASI-A EPA353.2: CJH1 1 PASI-A " EPA' 365.1 . BRJ: 1 PASI=A' . - 4500 CI-E AES2 1 - PASI A " SM 5310B .' KDF1 I. PASf A 92383249006 MW-7R SM 26400 : CAM - 1 PASI-A SM 9222D: KDF9 1 PASI-A . REPORT OF LABORATORY ANALYSIS .. . This reportshall not be reproduced, except in full, without the written consent of. Pace Analytical Services, LLC. - Page 4 of 27 • Pace A n 'alytical Services; LLC . ® �+Q /� J /+ aV.eA.04100!/ 2225_Riverside Dr. ' Asheville, NC 28804 www.pai:ilabs.com , (828)254-7176 SAMPLE ANALYTE"COUNT: , . Project; -.. :. CLEMENT PAPPAS Pace Project No.: 92383249 Analytes 'Lab. • Sample ID Method Analysts • Reported _ '.Laboratory EPA,350.1 1993 Rev 2.0.. 'BRJ .. .1.. PASI-A _ EPA 353.2:.- CJH1 1 PASI-A EPA 365,1 . _ . BRJ. 1 - PASI=A' . - SM 4500 CI-E AES2- - 1_ - - . . PASI-A..'- $M'5310B "• KDF1 A, - PASTA 923,83249067 .. MW-8. _ SM2540C CAM-: 1.. :: PASI-A . SM 9222D: KDF1 1 PASI-A EPA 350:1 1993.Rev 2.0 : BRJ:PASI-A EPA353.2 - :.. CJH1 1.. PASI-A . - EP A365:1 .' BRJ 1, . .PASI:A. . SM 4560-CI-E AES2 _ -1 PASI-A SM 531OB: KDF1 1 PASI-A . . 92383249008_ .. MW-9 ' SM 2540C. .. CAM 1 '.. PASI-A SM 9222D KDF1'- `. 1.. PASI-A.' EPA'350.1 1993 Rev:2.0 BRJ ' 1 PASI-A . EPA353.2 ' . CJH1:. 1.. PASI-A - .. . EPA 365.1 BRJ 1 PASI-A . _ . SM 4500=CI=E AES2 " 1 PASI-A . SM 5310E KDF1' 1 PASI-A .. .. REPORT OF LABORATORY ANALYSIS This repoitshall not be reproduced; except in full, without the written consent of Pace Analytical Services :LLC. Page 5 of 27 Pace Analytical Services, LLC ' g�+Q Q17 /"+ J® tjcoI 2225 Riverside Dr. . Gtli.eA ljl Asheville. NC 28804 .. www.pacelabs.cori+ - (828)254 7176 .. ANALYTICAL Project: CLEMENT PAPPAS Pace Project No.: 92383249 Sample•:. SW-1 : '.Cab ID: 92383249001 Collectedi:.05/02618 74:35 Received: 05/02/18 15:30. _ Matrix: Water Parameters, : Results .' Units .. PQL MDL DF ... _Prepared Analyzed CAS No::. Qiial " 2540CTotalDissolved.Solids : AnalyticahMethod:SM25.40C -. Total Dissolved Solids 54,0' mg/L; 25.0 25.0 1 05/08/18 18:06 ' MB10.92221). FecalColiform_AVL AnafyticaLMethod:.SM 9222D..' " Fecal Coliforms - 53.0" CFU7100 mL = 1.0 ' 1.0 1 05/02/1816:55 350.1 Ammonia- Analytical Method: EPA350.1. 1993,Rev 2.0 Nitrogen; Ammonia ND.mg/L 0.10 `.: 0:050 :1 65/11/18 02:52. 7664-41-7 . 353:2 Nitrogen, N021NO3 unpres Analytical Method: EPA353.2 Nitrogen, Nitrate _ 0.74 mg/L 0.020 0.010 1 . 05/03/18 02:36 365:1 Phosphorus, Total' Analytical Method:".EPA-365.1 . - Phosphorus., 0.044J mg/C 0 050.. 0;025 1 06/11/18 08:27. 7723-14=0 -4500.Chloride. Analytical Method: SM 4500-CI-E . . Chloride.. 4.8, . mg/L 1.0: 0.50 ..1 . 05/09/18.17:16. 16881-00-6 . 5310B TOC . . " AnalyticaWei thod:"SM 5310B .- ' Total OrgaN6.Carbon .'- :: ...1.5 mg/L . - , , 1.0 .' . " 0.50 1 . ` 05/09M 8 20:29 7440-44-0 " - REPORT'OF LABORATORY ANALYSIS.... .• '. This'reportshall not be reproduced; except in full, Date: 06/21/2018 0229 PM : without the written consent of. Pace Analytical Services, 1-C. Page 6 of 27 - ' Pace Analytical.Services; LLC , ® aceAnal�/.�cal 2225.Riverside Dr. y � Asheville, NC 28804 wriwpacelabi.com (828)254-7176 - ANALYTICAL RESULTS Project: CLEMENT PAPPAS Pace Project No:: 92383249 Sample: SW-2 Lab ID:.92383249002 Collected:. 05/02/18 10:30 Received: 05/02/18 95:30, Matrix: Water Parameters Results Units PQL' MDL DF .. Prepared Analyzed CAS No.. Qual 2540C Total Dissolved Solids Analytical Method: _SM 2540C Total Dissolved Solids 51.0 mg/L. 25.0 25.0. 1 . 05/08/181&06 MBIO 9222D Fecal Coliform AVL Analytical.Method: SM 9222D Fecal Coliforms 118 CFUM00 mL 1.0' 1.0 1 ' 05/02/18 16:28 350.1 Ammonia Analytical Method: EPA 350.1 1993• Rev 2.0 Nitrogen, Ammonia - 0.052J mg/L 0.10 0.050 .1 05/11/18 02:53 7664-41-7 - - 353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA353.2 . Nitrogen, -Nitrate 0.72 mg/L. _ ' 0.020 . - - 0.010 1 . 05/03/18'02:30 365:1 Phosphorus, Total . Analytical Method: EPA 365.1 Phosphorus . 0:045J _ mg/L . 0.050 0:025 .. 1. .05/11/18 08:28 _ 7723-14-0. 4500 Chloride.. Analytical Method; SM 4500-CI-E Chloride_ 4.4. mg/L 1.0: 0.50 .1 05/09/1817:17. 16887-00-6 5310B TOC Analytical -Method: SM 5310B Total Organic Carbon 1.4 mg/L 1.0 0.50 1 05/09/18 20:39 7440-44-0 REPORT OF LABORATORY ANALYSIS .. . This report shall not be reproduced, except in full, Date: 06/21/2018 02:29 PM without the written consent of Pace Analytical Services,•LLC. Page 7 of 27 Pace Analytical Services, LLC _ n® �Ce) JI,�t7C�1 2225 Riverside Dr. . u!Qg .. Asheville,.NC 28804 : ' wwwpacelabscom. .. (828)25477176 .' ANALYTICAL RESULTS Project: ., CLEMENT PAPPAS . Pace Project No.: 02383249 Sarhple.: _MW-4 : : Lab�ID:.92383249003 Collected:: 05/02/1814:11 Received: 05/d2/1.815:30. Matrix: Water - Parameters Results .:. Units - - = PQLMDL: DF . .. Prepared Analyzed- CAS No... : Qual 2540CTotalbissolved Solids :: 'Analytical -Method: SM 2540C _. .'Total Dissolved Solids 16.7 mg/L- 25.0 ' ' 25.0 - 1 05/08/1'8 180.6 MBIO 9222D Fecal.Coliform AVL Analytical. Method: SM 9222D- . Fecal Coliforms - ND- CFU/100 mL 1.0 1.0 : 1 05/02/18.16t55 350.1 Ammonia Analytical Method: EPA 350.1.1993,Rev 2.0 Nitrogen;; Ammonia - . - ND.' mg/L. 0.10 '. , 0A50 .1 :..- 05/11/18 02:55., 7664-41-7 353:2 Nitrogen ,'N021NO3 unpres Analytical Method`. EPA353.2 Nitrogen, Nitrate .. 2.1 mg/L.' -0.020 -. -.. 0.010 1 05/03/18 02:35 365:4 Phosphorus; Total : Analytical 'Method: EPA 365.1 Phosphorus . : - 0..11 . mWL 0.050. - 0:025 • . 1 . ` : 05/11/18 08:30 . 7723-14=0 _ 4500 Chloride- . Analytical Methods SM 4500-CI-E . . Chloride; 10.0 , . -mg/L 1:0: 0.60 ; .' .1 05/09/18.17:18:. 16881-00-6 .. 53106 TOC a Analytical.Meth6d: SM 5310B .- Total Organic.Carbon' . 3.0 '. mg/L. - ;.:: 1.0, 0.50 ",1 . ', : - -. - - 05/09/18.20:50 7440-44-0 ..:. ' .. PORT OF LABORATORY ANALYSIS, ... -REPORT This, reportshall not be reproduced, except in full, Date: 06/21/2018 02:29 PM : without the written consent of Pace Analytical Services, LLC. - Page 8 of 27 - - `Pace ArialyticaLSer4)ces; LLC l® RC`g aIMiV/+ �I 2225 Riverside Dr. _. Asheville .NC 28804 1 w ..pacelabscom. .. (828)254-7176 ANALYTICALRESULTS Project. .. '. .. -CLEMENT PAPPAS : " Pace Project No.: " 92383249 Sample: .MW-5 :: Lab ID: 92383249004 Collected: 05/02/18 12:64 Received: 05/62/181"5:30. Matrix: Water •. .. Parameters : Results Units • . : PQL MDL DF Prepared Analyzed ". CAS No:.. : Qual 2540C Total Dissolved"Solids - Analytical Method:•SM 2540C" :: :Total Dissolved Solids " " 90.0" - mg/L' 25.0 25.0. 1 . 05/08/18 18:06" . ". MBIO 9222D- Fecal.Coliform AVL -Analytical. Method: "SM 9222D . Fecal Coliforms 2.0 CFU/100"mL 1.0 1.0 1 05/02/18.16:28 u1 350.1 Ammonia Analytical Method: EPA 350.1. 1993.Rev 2.0' Nitrogen, Ammonia- ND.' mg/L : • '. '0.10 . , 0.050 .1 .. 05/11/18 02:56.. 7664-41-7 353:2 Nitrogen, N021NO3.unpres Analytical Method` EPA353.2 . . Nitrogen, Nitrate ... 0:022 " . " mg/L. " 0.020 . -.: 0:010 1 05/03/18 02:32 " 365A Phosphorus; Total _ "' :: "" Analytical Method:'EPA 365.1 " Phosphorus . 0:097 - mg/L " . -0.050 0:025 • 1, . 05/11/18 08:31•. 7723-14-0 -4500 Chloride. - Analytical Method: "SM 4500-CI-E . ". .Chloride.." 16.1 ". mg/L 1.01. "" 0.50 __1 05/69/18 17:20. ,' 16887-00-6 ". -5310B TOC - .. Analytical.Met.hod:.SM 531013, Total Organic.Carbon" -_ . 5.7 mg/L . . _' 1.0"- ." . 0.50 1 ". `, . "• . " " :: 05/09/18 21:00 7440-44-0 REPORT OF LABORATORY ANALYSIS' This report shall not be reproduced, except in full, Date: 06/21/2018 02:20 PM" . withoutthe written consentof.Pace Analytical Serwces,:LLC. Page 9 of27 - Pace Arialytical.Services; LLC " - �++QQ //��►►77 // ���++g ® � •. 2225 Riverside Dr f ti.G/'l1l�l�4Q� .. Asheville, NC 28804 . . wwwpacela6s.com- (828)25477176 . . ANALYTICAL- RESULTS :. Project:. .. CLEMENT PAPPAS Pace. Project No.: 92383249 Sample.:.MW-6 .Lab ID: , 92383249005 .Collected:: 05/02/18 12:49 Received: ';05/02/18 15:30 Mat[ix: Water ....... Parameters Results ;. Units" :. - PQL mcu DF .. Prepared .Analyzed CAS No:.. : Qual 2540C"Total :Dissolved Solids - Analytical Method: SM 2540C Total Dissolved Solids "- 81,0- : mg/L' 25.0 ": 25.0 1 05/08/18 18:0.6 .MBIO 9222D. Fecal.Coliform AVL ' Analytical.Method:.SM 9222D. ' Fecal Coliforms 1.0 CFU7100 mL : 1.0 .1.0 .. 1 05/02/18.16:55 u1 := 350.1 Ammonia Analytical Method: EPA 350.1.1993. Rev 2.d' Nitrogen., Ammonia ND. rig/L. 0.10 .. 0'.050 1 05/11/18 02:58.' 7664-41-7 353:2 Nitrogen, N021NO3 uripres " Analytical -Method` EPA 353.2 . . Nitrogen Nitrate 0:085 mg/L. 0.020 0:010 1 05/0.3/18 02.33 365.1 Phosphorus; Total„ Analytical .Methodi'EPA365.1 Phosphorus ' . 0.097 . mg/L' 0 050 0:025 1, 05/11Y16 08:32. 7723-14=0 '4500 Chloride Analytical Method: SM 4500-CI E ' . . '. Chloride `. 9.4 n4L 1.0:.. ": 0.50 .".1 05/09/18 17:21',• 16887-00-6 .. .53108 TOC Analytical -Method: SM 5310B Total Organic Carbon .'.': 2.3 - mg/L. : ' 1 0 .'. ' 0..5.0 1 . ' 05/10/18 22:49 7440=44-0 _. REPORT :OF LABORATORY ANALYSIS . This repoit:shall not be reproduced; except in full, ' Date: 06/21/201.8 02.29 PM .. without the written consent'of Pace Analytical Services,:LLC. " ,Page.10 of 27 . Pace Analytical Services, LLC ® ace Ana Xjcol 2225 Riverside Dr. . Asheville, NC 28804 www.pacelabs.caro (828)254-7176 ANALYTICAL RESULTS Project: CLEMENT PAPPAS Pace Project No:: 92383249 Sample:MW-7R : Lab ID: _92383249006 Collected: 05/02/18 11:15 Received: 05/62/18 15:30 Matrix: Water Parameters Results Units .. PQL MDL DF . Prepared Analyzed CAS No: : Qual -2540C Total Dissolved .Solids Analytical Method: SM 2540C Total Dissolved Solids 207 mg/L. 25.0 25.0. 1 05/0.8/181806 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D . Fecal Coliforms NO CFU7100 mL 2.0 2.0 2 ` . 05/02/18 16:28 .350.1 Ammonia _ Analytical Method: EPA 350.1 1993. Rev 2.0 - Nitrogen, Ammonia ND. mg/L 0.10 0.050 1 05/11/18 02:59 7664-41-7 353:2 Nitrogen, NOWN03.unpres Analytical Method: EPA 353.2. . -Nitrogen, Nitrate, 15.5 ' . mg/L. - 0.020 ', " 0.0110 1 05/03/18 02:31 365:1 Phosphorus, Total . Analytical Method: EPA 365.1 Phosphorus . 0.32 mg/L 0.050: 0.025 1 05/11/18 08:32. 7723-14-0 . 4500 Chloride Analytical Method' SM 4500-CI-E' .. Chloride: 22.6..: -mg/L 2.0` 1.0 .2 05/09/18 18:01,, 16887-00-6 5310B TOC Analytical. Method: SM 5310B . Total Organic Carbon 3.2 mg/L. 1.0 0.50 1 05/10/18.23:00 7440=44-0 'REPORT OF LABORATORY ANALYSIS This repot shall not be reproduced' except in full, Date: 06/21/2018 02:29 PM , without the written consent of. Pace Analytical Services, LLC. Page 11 of 27 Pace Analytical Services; LLC - Q ,. /+gr® �V�i/'lllt�I ifco 2225 Riverside Dr -Asheville, NC 28804 ' wmpacelabs.com ..: .. (828)254-,71176 ANALYTICAL'RESULTS " Project: CLEMENT PAPPAS :- Pace Project No.: 92383249 SamW ple: ". M-9 Lab ID: ,92383249008 Colle: 0 cted:5/02/18 13:35 Received: 05/02/18 15:30. - Matrix: Water Parameters Results Units ' PQL MDL DF Prepared '._ : -Analyzed CAS No... : Qual ' -2540C Total Dissolved Solids Analytical Method:SM 25.40C `Total Dissolved Solids „ ' _ 69.0mg/L' 25.0 25.0 1 . 05/08/18 18:06 MBIO 9222Q Fecal,Coliform AVL Analytical Method::SM 9222D '. Fecal Coliforms ND CFU/100'mL ' : 2.0 2.0 :.' -2 .. '.. 05/02/18.1655 350.1 Ammonia • _' : -Analytical Method: EPA 350.1. 1993. Rev 2.0 Nitrogen.; Ammonia . ND.' .. mg/L _ . 0.10 '.: 0:050 _. :1 05/11/18 03:05.` Z664'-41-7' 353:2 Nitrogen,NO2/NO3-unpres '. Analytical Method: EPA853.2 . Nitrogen,. Nitrate 0.58 rngtC 0.020 - 0.010 1 • 05/03/18 02:34 '365..1 Phosphorus; Total . Analytical Method; EPA-365.1 ' - Phosphorus . 0.37. mg/L 0.050 0.025 1 .05/11/18 08:35 :7723-14-0 4500 Chloride.. ' Analytical -Method: SM 4500 CI-E' .. Chloride.: 4.9.' m , . gJL: 1.0; . 0.50 .1 05/09/18 17:28.. 1688.7-00 6 .. • . - : 5310E TOC : AnalyficaLMetfiod: SM 5310B .• Total Organic Carboni . _' 4.6 mg/L.1.0', . 0.50 1 05/10/18 23:21' 7440=44=0 : REPORT OF LABORATORY ANALYSIS'... Thissreportshall not be reproduced, except in full, ' Date: 06/21/2018 02:29 PM . - without the written consent of Pace Analytical .Services, LLC. • Page.13 of 27: Pace Analytical,Services; LLC ® aceMaIXieal 2225_Riverside Dr. Asheville, NC 28804 www.pacelabs.com (828)254-7176 ANALYTICAL RESULTS Project: CLEMENT,PAPPAS Pace, Project No.: 02383249 Sample: MW-8 Lab ID: 92383249007 Collected:; 05/02/18 10:10 Received: 05/02/18 15:30 Matrix: Water Parameters Results Units PQL MDL DF :.. Prepared Analyzed CAS No... . Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C " Total Dissolved Solids " 548 mg/.L 50.0 50.0 1 05/08/18 1806 M1310 9222D Fecal Coliform AVL Analytical, Method:.SM 9222D . . Fecal Coliforms NO CFU/100"mL 2.0'. 2.0 : 2 05/02/18 16:28 350.1 Ammonia " Analytical Method: EPA 350.1 1993 Rev 2.0 Nitrogen, Ammonia ND. mg/L 0.10 " 0.050 1- 0.5111118 03:01. 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method`. EPA 353.2 Nitrogen, Nitrate- _ 14.4 mg/L- 0.020 ' 0:010 1 05/03L18 02:21 M6 365.1 Phosphorus, Total , Analytical Method: EPA 365.1 - Phosphorus . 0.19 mg/L . 0.050 0:025 -1. 05/1.108 08:33 7723-14-'0 4500 Chloride.. Analytical -Method: SM 4500-CI-E .. Chloride; "". 12.9 - mg/L 1.0 0.60 :. 1 05/09/18 17:23 16887-00-6 - 5310B TOC - _ . :. Analytical. Method: SM 531013. ". Total Organic.Carbon -, . ..10.8 - mg/L 1.0. 0.50 .1 05/10/18123:10 7440-44-0 REPORT'OF LABORATORY ANALYSIS .. This; report shall not be reproduced; except in full, Date:. OW 1 /2018 02:29 PM . without the written consent of Pace Analytical Services, LLC. Page 12 of 27 Pace ArialyticaLServlces; LLC aceAn/i /� ® alytical : 2225.Riverside Dr. Asheville, NC 28804 www.pacelabacorn (828)254-7176 ;. QUALITY CONTROL DATA Project: CLEMENT PAPPAS Pace Project No.: 92383249 QC- Batch:.: 409813 Analysis Method: SM 254OC " QC Batch Method` . SM:2540C . Analysis Description; 2540C Total. Dissolved Solids.. . Associated Lab, Samples' " - 92383249001, 92383249002, 92383249003, 92383249004, 92383249005, 92383249006, .92383249007, 92383249008 .. METHOD BLANK: 2273461 " " " Matrix: Water -" Associated Lab Samples: 92383249001, 92383249002, 92383249003,'92383249004, 92383249005; 92383249006,_92383249007, . 92383249008 • Blank.'. Reporting Parameter - Units Result Limit MDL Analyzed Qualifiers . Total"Dissolved Solids mg/L .: _ ND. 25.0 - . 25.0 05/08/18 18:06 LABORATORY CONTROL SAMPLE:. ' 2273462." Spike . LCS LCS % Rec Parameter Units .. ' :: Conc. " " Result %.Rec Limits . Qualifiers. ' Total Dissolved.Solids- mg%L 250.. " 248 99 : 90-11.0. SAMPLE DUPLICATE:., 2273463 .92383233004"_ Dup:: Max Parameter Uriits Result Result RPD".. " RPD Qualifiers • " - Total Dissolved Solids.. m /L. 162 " 162.:: 0 - ..:: 5 9 SAMPLE DUPLICATE: 2273464. ." 92383206001" Dup Maz . Parameter: Units Result Result:- RPD- RPD . Qualifiers' . Total.Dissolved Solids mg/L: 957 1070 11. " 5 D6 , Results presented on this.page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS ". . This repoitshall not be reproduced; except in full, Date: 06/21/2018 02:29 PM : _ . without the written consent of Pace Analytical Services, LLC. Page.14 of 27 • Pace Analytical Services, LLC " ® aceAnaly CO. 2225.Riverside Dr. Asheville, •NC 26804 www.pacelabi.com (828)254-7176 QUALITY CONTROL DATA Project: CLEMENT PAPPAS Pace Project No.: 92383249 QC, Batch:' 410231 ' Analysis Method: EPA 350.1 1993 Rev 2.0 QC Batch Method:. EPA 350.1 199.3.Rev 2.0 Analysis Description;' : 350.1.Am.monia Associated Lab. Samples: . '92383249001; 92383249002, 92383249003;"92383249004, 92363249005, 92383249006, 92383249007, . .'.. . 92383249008 METHOD BLANK.: = 22.75910 Matrix,. Water Associated Lab -Samples: - 92383249001, 92383249002, 92383249003,.92383249004, 92383249005; 92383249006, 92383249007, . 92383249008 Blank,Reporting . Parameter' Units Result Limit MDL Analyzed Qualifiers . Nitrogen; Ammonia.' mg/L ND 0.10 - 0.05.0 " 05/11/18 02:11 LABORATORY CONTROL SAMPLE:. 2275911 .. .. LCS LCS.. :. % Rec . Spike Parameter Units .. : Conc:. Result %o.Rec Limits Qualifiers:. . Nitrogen, Ammonia '. mg/L 5 ". 5.2 103 . 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2275912 - 2275913' MS- MSD .92383197001 . Spike: : Spike MS MSD MS MSD .. %Rec Max' Parameter; Units Result ..' :Cone. Conc.. Result... Result: %Rec.. %Rec ; .Limits. RPD:RPD. -Qual Nitrogen, Ammonia . mg/L ND . 5 5 5.3 5.3 105 105 : 90 140 ' 0 7. . MATRIX SPIKE &MATRIX SPIKE DUPLICATE:. , 2275914 2275915 MS 92383237003 :Spike. Spike .MS MSD .. MS .... MSD. %Rec, Max . Parameter- Units Result Conc.. - Conc. .. Result Result - % Rec :.. % Rec Limits.'-:RPD. RPD..Qual.: Nitrogen, -Ammonia " _ : mg/L' ND :5 : .5 5.2.. .5.2 105 - - 105 . 90-110 0 7' Results.' presented on this.page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, D6te:•06/21/2018 02:29 PM , without the written consent of Pace Analytical Services,:LLC. Page.16of 27 Pace Analytical Services; LLc - Q r1 ® /Wico!I 2225 Riverside Dr. Asheville, NC 28804 (�5a'aGAf www.pacelabs.com (828)254-7176 QUALITY CONTROL DATA Project: CLEMENT PAPPAS Pace Project No.: 92383249 QC Batch:" 409030 - Analysis Method: EPA353.2 QC Batch Method: - EPA 353.2 . Analysis Description:.: 353.2 Nitrate + Nitrite; Unpres.. - Associated Lab. Samples: 92383249001; 92383249002; 92383249003, 92383249004, 92383249005, 92383249006,.92383249007, 92383249008 METHOD BLANK:. 2269301 Matrix: Water Associated Lab Samples: 92383249001, 92383249002, 92383249003, 92383249004, 92383249005; 92383249006, 92383249007,. 92383249008 Blank.. Reporting :. Parameter Units Result Limit MDL Analyzed " Qualifiers Nitrogen, Nitrate mg/L ND 0.020 0.010 . 05/03/18 01:59 LABORATORY CONTROL SAMPLE:. 2269302 . Spike LCS LCS % Rec " Parameter Units _ Conc. Result %.Rec Limits - Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2269303 .. 2269304 MS MSD 92383042001. Spike Spike MS MSD MS: MSD %Rec Max Parameter, Units - Result. _ :Conc. Conc.. Reesuit Result: . % Rec %.Rec •. ".Limits. RPD :RPD. Qual Nitrogen, Nitrate.. mg/L, 2.8 2.8. 1 . .10' MATRIX SPIKE &MATRIX SPIKE DUPLICATE:.. 2269305 2269306 _ MS MSD . 92383249007 Spike. Spike' -MS MSD MS MSD. %Rec. Max_ Parameter Units - 'Result Conc. Conc: Result. " -Result % Rec " " %Rec Limits+ .:RPD. RPD..Qual.. Nitrogen; Nitrate _ mg/L 14.4 2.5 : 2.5 16.6 17.2 90 112 90-110 3 10 M6 ' - Results presented on this Rage are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. - REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/21/2018 02:29 PM without the written consent of Pace Analytical Services,:LLC. -Page-17 of 27 Pace Analytical Services, LLC /+ n l /+g ®.. �V.e/' nJlXicgf 2225 Riverside Dr. . . . Asheville, NC 28804 www.pacela6s.coro (828)254-7176 " QUALITY CONTROL DATA " Project: CLEMENT PAPPAS Pace. Project No.: 92383249 QC Batch:: 410208 ' Analysis Method: ' , EPA 365.1 QC'Batch Method`' EPA365.1' Analysis Description:" 365. 1. Phosphorus, Total Associated Lab. Samples: . `92383249001, 92383249002, 92383249003, 92383249004, 92383249005, 92383249006,.92383249007; . .92383249008 METHOD BLANK: 2275707 Matrix: Water " Associated Lab -Samples: 92383249001, 92383249002; 92383249003,.92383249004, 92383249005; 92383249006, 92383249007, ." 92383249008 Blank.. Reporting Parameter Units Result . "..Limit MDL Analyzed Qualifies Phosphorus mg/L . ND ." 0:050 . .0.025 05/11/18 08:17 LABORATORY CONTROL SAMPLE:. 2275708. Spike LCS . .. ` LCS . % Rec . . Parameter Units . _ Conc:. Result %-Rec Limits Qualifiers. . Phosphorus : mg/L 2.5.. • 2.3 .... 92 ". .90-110. ". MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2275709. 2275710 MS MSD . 92383206001 Spike Spike MS MSD MS , MSD %Rec - Max Parameter;: Units '. Result', :Conc. Cone._ Result ..Result. % Rec.. " %.Rec .: Limits. •RPD RPD. Qual Phosphorus " mg/L 42.3. -2.5 2.5'.. 43.9 42.8 64 . • .. 21 .90-110 2 - 10 M6 MATRIX SPIKE &MATRIX SPIKE DUPLICATE: . 2275711 2275712 . MS MSD., 92383249002":;Spike Spike"::. MS MSD - MS MSD: %Rec. . Max_ Parameter Units Result Conc... Conc. .. Result. Result . ; %. Rec % Rec Limits.".:RPD RPD. -Qual " Phosphorus ." .. mg/L 0.045J 2.5 ; .2.5 :2.6 - 2.6 103 104 , 90-110 " 1 10 - - - Results' presented on this,page are in the units indicated by the "Units' column except where an alternate unit Is presented to the right of the result. - REPORT OF LABORATORY ANALYSIS . This reportshall not be reproduced, except in full, Date: 06/21/2016 02:29 0M without the written consent of Pace Analytical Services, LLC. Page 18 of 27 Pace Analytical Services, LLC ® 222 ang ►�1 5 Riverside Dr. Analy Ca!/ Asheville, NC 28804 www.pacelabs.com (828)254-7176 QUALITY CONTROL DATA Project: CLEMENT PAPPAS Pace, Project No.: 92383249 QC Batch:" 409912 ' Analysis Method:SM 4500-CI-E QC Batch Method: " SM 4500-CI-E - .. Analysis Description: 4500 Chloride Associated Lab Samples: 92383249001, 92383249002, 92383249003, 92383249004, 92383249005, 92383249006, 92383249007, 92383249008 • METHOD BLANK: 2273979 Matrix: Water Associated Lab Samples: 92383249001, 92383249002; 92383249003, 92383249004, 923832490.05, 92383249006, 92383249007, 92383244008 Blank.. Reporting Parameter Units Result Limit MDL Analyzed Qualifiers . Chloride .. mg/L ND 1.0 0.50 05/09/1817:04 LABORATORY CONTROL SAMPLE:. 2273980. Spike LCS LCS" % Rec Parameter Units . Conc. Result %.Rec Limits - Qualifiers Chloride " mg/L 20 " 20.2 101 90-110. " MATRIX SPIKE& MATRIX SPIKE DUPLICATE: 2273981 2273982 MS MSD 92383460002 Spike Spike MS MSD MS " MSD % Rec Max Parameter. Units _ Result" -Conc. Conc.. Result. : Result: % Rec % Rec . Limits RPD .RPD. Qual Chloride mg/L 87.9 , 10 10 98.3 96.1. 104 82 90-110 2 10 M1 MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 2273983 2273984 MS MSD. . 92383249008 Spike. . Spike MS MSD MS .. MSD % Rec,. Max Parameter Units " ", " Result Conc. Conc: Result Result % Rec % Rec " Limits . RPD RPD ,Qual . Chloride mg/L 4.9 10 10 14.4 14.5 95 96 90 110 0 10 = - "Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. " REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/21/2018 02:29 PM without the written consent of. Pace Analytical Services, LLC. Page-19 of 27 . Pace Analytical Services, LLC , t�CCAI IniIICoI _ .. 2225 Riverside Dr. Asheville, NC 28804 ' wwwpacefabs.com. (828)254-7176 QUALITY CONTROL DATA Project: CLEMENT PAPPAS Pace Project No:: 92383249 QC, Batch: 409758 Analysis Method:'. SM 5310B QC Batch Method:. SM.5310B . Analysis Description: . 5310B TOC, Associated Lab -Samples: 92383249001; 92383249002, 92383249003, 92383249004 '. . METHOD BLANK:.' 2273163 Matrix: 'Water. Associated Lab Samples`92383249001; 92383249002, 92383249003, 92383.249004. - . . " B . lank Reporting Parameter ' - - Units Result. Limit MDL Analyzed . : Qualifiers Total'OrganicCarbon mg/C '. ND' 1.0: .. : 0:50 05/09/1815:16- LABORATORY CONTROL SAMPLE: . 2273164 Spike :.. LCS LCS .... %.Rec .. - :. Parameter Units : Conc., .. Result ,: - . ,'kOC . Limits: Qualifiers' • Total Organic Carbon mg/L . ... -25 24.6: 98 .. 90-110.. .. . MATRIX SPIKE.& MATRIX SPIKE DUPLICATE:.' .2273165 .. 2273166: - MS." MSD - 92383610002 Spike . 'Spike MS. "- .MSD-. MS :: MSD' % Rec ;: Max. . Parameter Units. Result " Conc:. ; Conc. Result - _Result '% Rec . % Rec. Limits _ .RPD. RPD.', Qual. . Total Organic Carbon'. . _ mg/L . ND. : .25 .. 25: 24.6 . ". . 24.7 .97 97 . 90-1.10 . , 0 : - 10. MATRIX SPIKE & MATRIX SPIKE DUPLICATE` 2273167 2273168 • . MS MSD :. 92383373001 Spike, Spike MS :. MSD MS::. _ MSD, 0/ Rec _ Max_ Parameter , . Units :', Result :. Conc. Conc..- " Result ; . Result % Rec % Rec • . Limits RPD RPD Qua[ -Total Organic Carbone'. _ . mg/L_ 1.2 -.` 25: •25.. 25.5 31.6 - 97.: 122 .90-110.: 21, 10.M1,R1.: Results'peesented bn this.page'are in the units 'indicated by the " Units" column except where an alternate unit Is preserited to the right of the result: REPORT OF LABORATORY ANALYSIS. . This reportshall not be reproduced; except in full, :Pate: 06/21/201.8 02:29 PM . _ - . without the written consent of Pace Analytical Services,:LLC. v Page.20 of 27 Pace Analytical,Services, LLC Q /® j/jC0 2225 Riverside Dr. CZr,Pi/`ii% Asheville, NC 28804 www.pacelabs.com (828)254-7176 QUALITY CONTROL DATA Project: CLEMENT PAPPAS Pace Project No.: .92383249 QC Batch: 409932 Analysis Method: SM 5310B QC Batch Method:. SM'53106 - Analysis Description: .. 5310B TOC, Associated Lab. Samples: 92383249005, 92383249006, 92383249007, 92383249008 METHOD BLANK: 2274084 ' Matrix..1Nater Associated Lab Samples: 92383249005; 92383249006, 92383249007, 92383249008 Blank Reporting Parameter Units Result Limit MDL Analyzed. Qualifiers ' Total Organic Carbon mg/L ND 1.0 0.50 05/10/1.8 17:56. LABORATORY CONTROL SAMPLE: 2274085 Spike LCS LCS Sp % Rec Parameter Units Conc. Result %:Rec Limits Qualifiers Total Organic Carbon mg/L 25 24.5 98 90-110 MATRIX SPIKE.& MATRIX SPIKE DUPLICATE: " .2274086-2274087 MS MSD 92383722001 Spike Spike MS MSD MS MSD %Rec Max. . - Parameter Units. Result Conc. Conc. 'Result Result % Rec %'Rec. Limits .RPD RPD.. Qual . Total Organic Carbon. mg/L ND. 25 .. .25. 24.0 24.0 .- 95 95 --90- 10 0: 10. MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2274088 2274089 .. . MS MSD. 92383723014 Spike. Spike MS MSD MS . • MSD % Rec Max - Parameter., . Units ,. Result' Conc. Conc Result -. Result %Rec %Rec .Limits RPD RPD Qual Total Organic Carbon mg/L ND 25 25 24.0 24.0 96 96 .90-110 : 0 10 . . . Results presented on this page ate In the units indicated by the "Units" column exceptwhere'an alternate unit Is presented to the right of the result: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dater 06/21/2018 02:29 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 27 Pace Analytical Services, LLC . ® 2225 Riverside Dr. aCeArla�y�ICal Asheville, NC 28804 www.pacelab*com .. 828)254.71 6 - QUALIFIERS. Project: -CLEMENT PAPPAS Pace Project No:: 92383249 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot: ND Not Detected.at or above adjusted reporting limit.. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limitand below the.adjusted reporting limit. MDL-Adjusted.Method Detection. Limit. PQL - Practical .Quantitation Limit: RL - Reporting Limit.- The lowest concentration value that meets project requirements for quantitative data with, known precision and. bias for a specific analyte in a. specific matrix: $ Surrogate 1',2=Dipheny1hydrazine decomposes -to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is. a combiried.concentration. - Consistent with EPA guidelines, unrourided data are displayed and have been used'to calculate, % recovery and RPD values... .. LCS(D) - Laboratory Control.Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP-. Sample Duplicate RPD. - Relative Percent Difference NC:- Not Calculable. SG -:Silica Gel -. Cleari-Up U. Indicates the compound was analyzed for, but not detected: Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. . A separate vialpreserved to.a pH of 4-5 is recommended in SW846 Chapter 41orthe analysis ofAcroleln and:Acrylonitrile by EPA; Method 8260.. N,Nitrosodiphenylamihe decomposes and cannot be separated from Dipheriylamine using Method.8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace. PM forthe current"list of accredited analytes. TNI,=.The NELAC Institute. LABORATORIES PASI-A - Pace Analytical Services -Asheville.' ANALYTE QUALIFIERS D6 The precision between the sample and;sample duplicate exceeded laboratory control limits. M1 Matrix spike recovery. exceeded'_QC limits. Batch accepted based on laboratory control•sample (LCS) recovery. M6 Matrix spike and. Matrix.' spike duplicate recovery not evaluated against control limits due.to sample dilution.* R1 RPD value was outside control limits.'. u1 Results based upon colony counts outside acceptable range. REPORT OF LAB ORATORY ANALYSIS". This report shall not be reproduced, except in full, Date: 06/21/2018 02:29 FM without the written consent of Pace Analytical Services, LLC. Page22 of 27 . aceAnalj&al www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: CLEMENT PAPPAS Pace Project No.: 92383249 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Analytical Lab ID Sample ID - QC Batch Method QC Batch. _ Analytical Method Batch 92383249001 SW-1 SM 2540C 409813 92383249002 " SW-2 SM 2540C:.. 409813 92383249003 MW-4 SM 2540C 409813 92383249004 MW-5 SM 2540C 409813 92383249005 MW-6 SM 2540C 409813- 92383249006 MW-7R SM 2540C= 409813 92383249007• MW-8 SM 2540C 409813 . 92383249008 MW-9 - SM 2540C 409813 92383249001 SW-1 SM 92221D 409123 92383249002. SW-2 SM 9222D 409123 92383249003 . MW-4 SM 9222D.. 409123 92383249004 " MW-5 SM 9222D' 409123 92383249005 VW-6 SM 9222D 409123 92383249006 MW-711 SM 9222D 409123 92383249007 MW-8 'SM.9222D 409123 92383249008 " MW.-9 SM 9222D: 409123 92383249001 SW4 EPA 350.1 1993 Rev 2.0 410231 92383249002 SW-2 EPA 350.1 1993 Rev 2.0 410231 92383249003 MW-4 . EPA 350.1 1993 Rev 2.0 410231 - 92383249004 MW-5 EPA 350.1 1993 Rev 2.0 410231- 92383249005 . MW-6 EPA 350.1 :1993 Rev 2.0 410231. 92383249006 _ MW-7R EPA 350.1 1993 Rev 2.0 410231 92383249007 MWm8 EPA 350.1 1993 Rev 2.0 " . 410231 923832490018 MW-9 EPA 350.11993,Rev2.0 410231 92383249001 SW-1 - EPA 353.2 , 409030 92383249002 SW-2 EPA 353.2 .. 409030' 92383249603 MW-4 EPA 353.2 409030 92383249004 . MW-5 EPA 353.2 .' .: 409030 92383249005 MW-6, EPA 353.2 - 409030 92383249006. MW-7R EPA 353.2. 409030 92383249007 MW-8 EPA 353.2 409030" - 92383249008 MW-9 EPA 353:2 409030- :-92383249001 SW-1 EPA 365.1 410208 92383249002 SW-2 EPA 365.1 . 410208 92383249003. MW-4 EPA 365.1 410208 92383249004 MW-5. EPA 365.1 410208. 92383249005 MW-6 EPA 365.1 410208 92383249006 -.MW-711 . EPA 365.1 ..410208 62383249007. MW-8 EPA 365.1 410208 92383249008 MW-9 EPA 365:1 410208 " 92383249001 $W-1 SM 4500-CI-E 409912 92383249002 SW-2 SM 4500-CI-E 409912. 92383249003 MW-4 SM.4500-CI-E 409912 92383249004. MW-5 SM 4500-CI-E 409912 92383249005 MW-6 SM 4500-CI-E 409912 92383249006 MW-7R SM 4500-CI-E 409912 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/21/2018 02:29 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 27 Pace Analytical Services, LLC 2225 Riverside Asheville, NC 2880404 wvmpacelabs.crom. . . 17 (828)254-7 6 •" QUALITY CONTROL DATA:CROSS REFERENCE TABLE. . Project: CLEMENT PAPPAS Pace Project No.: 92383249 Analytical ' Lab ID Sample 10 QC Batch Method QC Batch Analytical Method Batch 92383249007 MW-8 SM 4500=CI-E 409912. 92383249008:: MW-9 SM 4500-CI-E 409912:. 92391249001 - SW4 .. SM 531013' . - 409758 92383249062. ' .: .. SW-7... SM 5310B 409758- 92383249003 .. MW-4.. SM, 5310B .. .. .. 409758 . 92383249004: MW-5 SM 5310B; - 409758 92383249005 .. MW=6. SM 5310B 409932,. " 92383249006 ` MW-711• SM 5310B 409932 '92383249007 MW-8 SM 5310E .409932 . 92383249008,.. M.1N-9 - SM 5310B .. :_ 409932.. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dater 001/2018 02:29 PM . without the written consent of Pace Analytical Services,_LLC. Page.24 of 27 Document Name: Document Revised:. February 7, 2018 Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: h Issuing Autority: 'h aceAnal Kcal" - . .Y`. F-CAR-CS.033-Rev.06 Pace Carolinas Quality Office Laboratory receiving"samor: Asheville []' Eden❑ Greenwood ❑ Huntersville ❑ Raleigh] Mechanicsville] Client Name:.: 0# : 9332 ,, • Protect �i (lea ` Courier:. ❑Fed,E) . ❑UPS ❑USPS.. ]client IIIIII I I ILIIII.OI ICI III ❑ Commercial ❑Pace []other: 92383249... i Custody Seal Present?. [-]Yes ❑Ne Seals Intact? ❑Yes ❑No Date/Initials Person ExaminingContents Packing.Material:. ❑Bubble Wrap ❑Bubble e.ags Q96ne ❑ Other. Biological Froze ? Thermometer: ❑yes ONO [] �'. Type oflce:et ❑Blue ❑None ❑I Gun ID: Cooler Temp ('C) ,�Q 5' Correction Factor: Add/Subtract ('.C) Ylo Temp should be above freezing to VC. Cooler Temp Corrected.('C): ❑Samples out of temp criteria. Samples on ice, codling process has begun USDA Regulated Soil ( �JA,ater sample) Did samples originate in a quarantine. zone Within the United State_ s: CA, NY, or SC (check maps)? Did samples originate from a foreign source.(internationally, ❑Yes ❑No including Hawaii and Puerto Rico)? Dies []No Comments/Discrepancy: Chain of Custody Present? es ❑No ❑N/A J. Samples Arrived within Hold Time? s ❑No' ❑N/A 2.. Short Hold Time Analysis (<72 hr.)? s .. ❑No , ❑N/A - 3. A (+%je, CC Rush Turn Around Time Requested? ' . ❑Yes o ❑N/A ` 4. Sufficient Volume? ❑Y ❑No ❑N/A 5: Correcf Containers Used? -Pace Containers Used? a ( es ❑No ' ❑No . ❑N/A []N/A' Containers Intact?' es .- ❑No ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑No ".❑N 8. 'Sample Labels Match COC? -Includes Date/Time/ID/Analysis, Matrix: Des []No - ❑N/A 9, Headspace in VOA Vials (>_576mm)? - ❑Yes. bNo r1oxItc t . Trip Blank Present? Trip Blank Custody Seals. Present? ❑Yes Oyes.. " 12 o No ❑ I/A 1. Document Name: Document Revised: February, 7; 2018' c7C8Analj�ICc?I Sampie Condition Upon 'Receipt(SCUR)' Pagel of 2 Document No.: Issuing Authority: 177CAR-CS-033-Rev.06 ,' . Pace Carolinas Quality Office *Check mark top half of. box if pH and/or dechlorination is Project# WO 92.38324:/: . verified and within the accepionce range for -preservation samples. PM:- UP. Due Date: 05/16/18 Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg . CLIENT 93-ALTAMONT **Bottom half of box is to list number of bottle . E . m '� as w .c u' �. E In N 14 'V a m .O. v ,.c L _ .,E o i+l �N "7.�" A a m .9 v awi. '.c V �_ E o O. .Y7 A A. m Z v �. R '�. D. N. a: W. _ �1 7 rl- -o._ m N x L 2 J E m .N-1 HZ. '�r . a m N = a m, O .� a E o V1 � N � M�' a to di.. m �. .0 ¢' 'z� N a J E .N .N er. a co _ a r. x ''O 19 . Z a J E. V� ry. � e-1 �' V .a . m z ._ ry M .� .� "E v �j LLB, �.. .3 V. Z.. w 2' .y.: v' .a cu. �, a . E ¢ = � e9.. l7 a. N. .v n _. E''¢ ¢ _ � .2 .rl� l7 a + ? _ w n c �: ... J E o INn N M. l7 a .N x. c 0 ..N T E . ¢ .. = � .-1. .� � ei t7 a .� _ v. ..v. O _.N 2� ,. E ¢' ..:.1 E o � N Jf M. a - u. Z U _ z ..v .a .E ¢ J O N. . m O �� .Q M a Q...m Z.. -... U ¢ O E- O C S 01_ e � Z .y Q' p' - > _ p ''.T � >. <'. .� Z d c . Q O � `� n Or. > ¢ 'z v ii� m Q O E..A O If 6. '0 .t9 o `. in m o. . ,:, �.. ..� > v Y a O >' Z .` x a: y, s N % ; V Y (� > :a: N z -u .� .a.a'Z 'y `m �- J E L_ N 'i ���. m' t 'z' d iu E O :N .f.. N � n rn r. O .ry x u. E o vI N a. ,P9 m a. z N m ..n c �. CU E �' E. o. 7 --0. a> c, �. V m¢ J E . o '� (� Q z = �. a m .�. E J . E 0 Q. 7 Ol c � 3 L 2 ... . 3 , IN 4: S L I. � .. 9' Apr S� 10 . 12 pH Adjustment Log for Preserved Sampies :. . Sample ID Type of Preservative pH upon receipt Datepreservation adjusted Time preservation Amount of Preservative tot If adjusted . ' added Note: Whenever there is a discreoancv affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office,(i.e. Out of hold, incorrect preservative; out of temp, incorrect containers.. ; Page.26 of 27 ��"dCC11112IyilC31 i CHAIN -OF -CUSTODY-! Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section A Section B Section C - Required Client Information: Required Project Information: Invoice Information: r Pa e : 1 Of 1 Company: ANCHOR QF11 of NORTH CAROLINA Report To: Brian Gant. Attention: S cr ivi { G Address:. 231 Haywood Street Copy To. Company Name,: Asheville, NC 28801 - - Address: _RdquIatorv.Aqen Email: bgant@a6chorqea.com Purchase Order#: Pace Ouete; Phone: (82B)2813350 Fax Project Name: CLEMENT PAPPA `I§" Pace Project Manager. loni.patton pacetabs.com_ State I Location Requested Due Dale: Project M - Pace Profile #: R= uested Anal Is Filtered (YIN)'_ - - WATRM CODE. m ti a . . COLLECTED o Preservatives • Z. •>'_ 06.109 Watar Dw o ci Wular .WT ~ . Waste Wo., W W J z SAMPLE ID Product P SafUSaiid SL od oL j u = o t? START END O .� +N } - One Character per box. wtp. WP w w CL m - (AZ 0.9 1, .) AL AR o a m w ¢ k`o m N o m r Sample Ids must be uNquo Th TS j . m o o ,� •P z • •E .� W. ~ r a '- t�i 'n y .O O w r Q rri m E .� o. DATE TIME DATE' TIME y _ =.. z z Ala/r,Y iW;� % XXXXX .. SW-2' WT' I { iGJ�t I I X X X X. X rrG,�i (� (� s.. �,,� ,✓_ (;. I. ; ! NCI WQ a :.9 " _12.. '• '-` AD6I710NALCOMMENT3 - RELINOUISFiED BY/AFFILIATION - DATE TIME - ACCFI+TED6YlAFFILIATIONATE . 'TIME SAMPLE •CON0ITIONS SAMPLER NAME AND'SIGNATURE•, r v PRINT Name of SAMPLER: r� " .�2 w • 8 z m m > o m• 0 2 > 5i o •� E Z m, m SIGNATURE of SAMPLER: - 7 's DATE Signed: - N 0 N' N c . d 1 Well Sampling log Anchor QFA of North'Carolina, PLLC 231, Haywood Street Asheville, North Carolina 28861 Project Name:'Oevitm? (?Gt/P?i .UV /00VI1 witj Date. 7�_Z_/� f -. Project Number. C( �f �7�-.U1; 01 T{jl Weather, v �p -- - .Sampling Personnel: .1 S Sample Time: Well Number. `i ��+f-'i `". - -- -- Well Depth in Feet MD): Well Diameter Z' - - —�. Water Level in Feet (WL): --- �— Type of Casing: V� Length of WaterColumn: - - _ feet � MeasuringPoint A TOG (11UD) -_M►L) _ (LWC): —[-7 Flush Mount /. t�lck U��` f' One Casing Volume 1 gallons C-6mments:. MC) x (WCV) - --- . -_ - --- Three Casino Volumes:. j " ��. gallons Actual Volume Purged: gallons } Well Casing Volumes (WCV) 1. _ 0.04 Gam 0.16 Gal/Ft .. 3° = 0.31 Gal/Ft. . 4" = 0.65 Gal/Ff -6" = 1:5 Gal/Ft, . 8" ' 2.6 Gal%Ft .12' = 5.9 Gal/Ft Purge Method: Bailer-Dispori . ? Baifer-TeflDedicated"Pump Whale.Purhp,.. Grifndfos .. Other. .. Sample.Method tBailer=D)sp� " Bailer Teflon Dedicated'Pump Whale Pump Grundfos. Other I Gallons Tempt Dissolved Specific Cond:. pH (S.li.) uJuclation " ' Reduction 1 Turbidity �(y _a _ —1ia� � iv`l. l�cir� _ 26f,� ------------ S,-Srg - '_16i_ _�(5,�--.- 3 r I.�Rc CJ. ' l 3: ff L.t G � 2 ?=j J rtl O' ;uI q,7, - — — 4 .T._`(G`�,�_'��1rtS>,a — _ 6 71 Sampling Container.. �. Number.of Containers Requested Analysis 500 mL'Plastic - -- - 250 mL Plastic - — 125mLPlastic- 40.mL Glass:': - -- - 1.03lass - - — - - - Other Protective.Casing: (Toa Pad:-� Lock: Vegetation:. GroJ Access--Cyoe�l Sampling Personnel Signature: ��/7 �// Datie: J /J% Well Casing Volumes defined in Table 2 of the Region 4 Environmental Protection Agency (EPA) Science and.Ecosystem Support Division (SESD) document titled Operofing Procedure - GroundwaterSbmPling .last revised April 26, 2017. " Samples are analyzed immediately upon collection. Minimum volume purged:3 well volumes: Sample time determined.by parameter stabilization: 9 mVi millivolt °C de tees Celsius pS/cm:.micro-Siernen per centimeter NTU: nephelomefricturbidityunits mg)tmilligrams per liter S.U-- Standard Units Method Reference; Specific conductivity. EPA'Method 120.1, Rev.1982 Temperature: SM 2550 B-2000 pH: SM 4506-H' B-2000 DO: SM 4500 O &2001 Page 1 of 1 wen b mpung.Log Project Name: W l�fJi1�� In � ifN'I y Project Number: C u[Y �.=C/1�0� TC�( �( - --- - - -- Weather.. �0°lF C/ZPn Sampling Personnel G S- - Sample Time: ( 2. y - — - - Well.Numlier: L/' tiv Well Depth in Feet (WD):Well, Diameter: 2 �1- - _ -- -- -- - . Water Level in beet (WL): , Type of Casing: (' VC Length of Water Column; ," Z feet Measuring Point:. (WD)' - (WL) _ (LWQ - -- Flush Mount /Ag�iyckKUU One Casing Volume: U,gallons Comments: � t%n S: n r . inn sr'�C .... (LWn. k (WCV) ----- -- - ��ti tG_LiY� La S;n r��r1 f��cq.'Q p Three Casing Volumes: gallons �r�.v f plrQ wl(r, 'vllG(( i°Gtl WAp fir hl �( r Actual Volume Purged: .� a gallons SiCV0rir.'Ya1. : Well Casing Volumes "CV) ". 0.04 3' 1 =. 0.16 Gal/Ft .. = 0:37 Gal/Ft 4' = 0:65 Gal/Ft . 6' =.1.5 Gal/Ft 8" _. 2.6 Gal/Ft 12" = 0 Gal/Ft Purge Method: iBailer-Diso. Bailer -Teflon Dedicated'Punip Whale.Pumo Grundfos ..Other. Simple.Method: Bader -Dish% Bailer -Teflon Dedicated'Pump. .Whale Pump Grundfos Other " xr a ion - l Gallons I Temp Dissolved Specific Cond: t pH (S.U.) I Reduction Turbidity ' Reading ; Time Purged . ('C). Oxygen (mg/L) (pS/cm) report to 0.7 SM. i 'Potential (m1� (NTU) I Comments . . L(,d5 2 ZLI _ I ka�� ^_ i 3 - -�` .. _ _ ;[ 6 T_ - - 9 I. i Sampling Container. Numberof Containers :' 'Requested Analysts . . Soo mL Plastic 1 / ) S// i J 250 mL Plastic- 125. mL Plastic- 40. mL Glass, - 1 L:Glass -I -- --_ - Other Protective Casing: � . Pad: & Lock L vie . Vegetation: 6L>r +� . Access: frc r Sampling Personnel Signature: / Date:G Zi / Notes: Well Casing Volumes defined in Table 2 of the Region 4 Environmental Protection Agency (EPA) Science and Ecosystem. Support Division (SESD) documenttitled Operating Procedure Groundwater Sampl nq last revised April 26, 2017. Samples are analyzed immediately upon collection:. Minimum volume purged: 3 Well volumes. Sample time determined b parameter stabilization. - `C: degrees Celsius mv: millivolt PS/cm micro-Siemen per centimeter NTU: nephelometric turbidity units mgjL milligrams per liter S.U.: Standard Units Method Reference:Specifloconductivity: EPA Method 120.1, Rew 1982 Temperature: SM 2550 B72000 pH: SM 4500-H' B-2000 DO: SM 4500 O G-2001 Page 1 of 1 Project.Name:'.(•Z►'e{� F 1��i�I f'/1S :Gt^/./�dolri'I� Date: Project Number. y Weather. : s Sampling Personnel: �[ Q �'✓G1/ .: Sample Time: Well Number. /v1 hr— fZ T Wb1I Depth in Feet (WD):— Well Diameter. 2'i _ _. Water Level "in Feet (WL): Type of Lasing:UG --- __ Length of Water , 3 feet " Measuring Point" 7-0l; - .. .. (WP) - (WL) = (LWC7.:- Flush Mount /: Stick,Up. . One Casing Volume: - 0 gallons: . AN HOR Well Sampling Log Anchor. QEA of North Carolina, PLLC 231 Haywood Street " Asheville, North Carolina 28801 Project Name: ��/ rc��l�rh�ilf I�� iiDate: r- ,�.i " -iiiAliDil/i� Project Number: �: ir �� %-( (GI -� `7 i �% I Weather q o f. " sampling Personnel: E Q?.J'.U� Sample Time: j 0 Well Number: Well Depth in Feet (WD): Well Diameter:: Z" Water Level in Feet (WL): r - 'Type of Casing:l - feet -" length of Water Column: ' I ( ��/_-- -- -�-VG - - Measuring P-Di. t •'"1 OC - -- - - (Wp) - M►L) = (LWL7 " Flush Mount Stick -Up One Casing Volume: �) 1 6 gallons / _ Comments: (LWC) x (WCV) ' Thee Casing Volumes: j gallons 4. Actual "Volume Purged: - v` 3. GU, _gallons 1N asing Volumes (WCV) ell C u . Q16fidflFt k. = 0.37 Gal/Ft . ' 4°.= 0.65 Gal/Ft 6".= 1.5 Gal/Ft 8" = 2:6_Gal/Ft_ - 12' = 5.9.GaVFt ; Purge Method: Bailer-Disp -Dedicated Pump Whale Pump' Grundfos Other Sample;Method: Bailer-Disp�'Barr { orb Dedicated Pump: Whale Pump . Gnindfos .Other. " 'Gall i Tem Dissolved p S edfic Cond:.. H.(S:U.) P P. w a ton . Reduction Turbid' I Reading." Tlme Purged CC), • ` Oxygen (mg/L)-' .p?/cm) " report to 0.1 S:U potential (mV), (NTU) ' k• " . comments. hs—+ _ oc __' iz.s: (�.GyC" •.. I sa$'3 Z��,v_ •_" . '" " . - ""7(7 2 f rc�c� "iCl 7� .- 12:s I , S� . 5 lavr',!,T t3; ( H,51, G Alba �..75" 6 ilC1jU :13 O(i------ 7" 1 — - - - - -- — 9. I _� 10- Sampling Container- . �. Number of Containers ." �" Requested Analysis 500 riff Plastic 4. 250 mL Plastic- 125 mL Plastic 40: rnL Glass' 3 1 L.Glass Other" ProtectiveCasing: 6"K Pad: 17�4 Lock:! K Vegetatio�%� " ". Access: of% Sampling Personnel Signature: :: r Date: Z /1 Notes Well Casing Volumes defined. in Table 2 of the. Region 4 Environmental Protection Agency (EPA) Science and Ecosystem Support Division-(SESD).document titled Operating Procedure = GroundwaterSomplinq last revised April 26, 2017. Samples are analyzed immediately upon collection. Minimum'volume purged: 3 %vell volumes. Sample time deteemined'by parameter stabilization. °C: degrees Celsius mV: millivolt pS/cm: micro-Siemen per centimeter NTU: nephelometnc turbidity units mg/L• milligrams per -liter S.U_ Standard Units Method Reference: Spec conductivity: EPA Method 120.1, Rev. 1982 Temperature: SM 2550'872000 pH: SM 4500-1-1`13-2000 " M. S.M 4500 0 G-2001 Page 1 of 1. well sampiing Log III lass, Other Protective Casing: (>�r;l ." .Pad: �DN /. -Lock: Vegetation: —,4? Access: r � " Sampling Personnel Signature:; y/� Date.* Well Cas)ng Volumes defined in Table 2 of the:Region 4 Environmental" Protection Agency (EPA) Science and•Ecosystem Support Division (SESD).docuinent titled Q*oting Procedure.-.. Groundwater 5omphaq. last revised April 26, 2017r Samples aie analyzed imrnediately.upon collection. "• Minimum.volume purged: 3.well volumes. Sample time determined by parameter stabilization: `C: degrees Celsius. _ mV: millivolt p5/cm: micro-Siemen per centimeter NTU: nephelometricturbid'rty units mg/L• milligrams par.liter S.U.: StmWaid Urgts' Method Reference Specific coridudivity. EPA•Method. 120:1, Rev.'1982 Temperature: Stul 2550'B-2000 pl-'SM 4500-If -B-2000 DO: SM 4500.0 G-2001 Page-11 of 1 ANCHOR Surface Water: Sampling Log; Anchor QEA of North Carolina, PLLC 231 Heywood, Street Asheville, North Carolina 28801 Project Name: Date: r S�_lZ J L Project Number. _ Weather. Sampling Personnel: S Sample.Name; .. Si'►' _ Comments:. U�`S;�-f_wtt�t __ Sample Method: Grab / Syringe . Pump Bailer-Disp. Other. Dissolved. Sperrfi'c Cond. I pH (S U) Oxidation Reduction Turbidity. - Time Temp (°C) . Oxygen (mg/L). .. (PS/cm) report to.0.1 S.U. Potential (m1n {NTU)' Comments. Sampiing Container Number of Containers : 1 Requested Analysis 5001*mL Plastic 250 mL PlasticFe — C41 125 mL Plastic `` --- ►V _�CL1f,�^� i�'lOj�?�i�1'r�VS - — 40 mL Glass ---_ _ -- 1 I: Glass J. Other.' : -- Vegetation: ' M �!/!1 t ' C eV Access: Sanipling Personnel Signature: i �` Date• v1ssvzvL apm!im Duna. pn to v.i Reaucaon i urplalry Time Ter Oxygen (mg/L) (NS/cm) ! report W 01 S.U.. Potential (mV) f (NTU) Comments Sampling Container. Numlierof.Containers . Requested Analysis 500 rnL Plastic 7777777 T 250 ML Plastic . .. � :125 mL Plastic 40 mL Glass 1 L Glass Other Vegetation: �/ 1 ' Access: �'t PrVwr. Sampling Personnel Signature r Date Equipment or meters used to.take nieasurements(e:g., water level meters, survey equipment):' . Equipment Type_„ SerfatNumher 'k . Brand �_`, Date of Use 150=ft Water: Level .1.. .. 26.154 Solinist .150-ft Water.'Level- 22754 Solinist — -� 150 ff.Waterl-evel _: .150. Testwell 150-ft Drawdown .'. MP30-1527 . QED Cither.: Select Turbidimeter Hach 21000 (s/n 151006045207) " HF Scientific MicroTPW (s/n 20 060104 5) 616ratlon ` _ Instrument Reading Instrument Reading ac Standards :: (Hh 2100� EHF Scieetific MPcroTPVIO Expiration Date 20 NTU i • 10. ,NTU �`. 800 NT{l • 0 02 NTU : I 10 ll NTIi " I" ' 1D00 NTU Cal Cal Cal:. ICal: Ca[: Cal Ur �I �r r� Time:,, - Time:. Tirrie. Time. Time:' .. Time:,Verification (10 NTU). 1 evgf, (bA &7 Verification: Ver&atiort Verification: ". hwsFed,:_ Tit-he: d l Time: Time:. Time: !!! — _ YSI.556 MuiV ammeter Meier (s/n 12L1O1057) - :. Inst rument Rvadtngs .� _ Calibration Explratwn Date, DissolvedOzygen fInitial- r Cal: mmHg (Time: '' NA pH 7.S U Initial iPHmV T Cal: pHmV. Time: i O /—r, -- re ort to 015 U PH 4 S U.Initial: _ pHmV: Cal:. ; pHmV: `T ' 11.! Time: — - -- i ieportroorsu 'Al f/, G1 �:r� pH 10 Sm. Initial: ". pHmV:. ICal: pHmV }Time: J report to 01 S. U. .i: 1(�,v I j' QC* pH 7 S U �AM Time: - Mgas Mid Day Time ' Check - ' PM"Time 1Check'" f reporhto 0.1 S.U. : ( is 3.6 , i. i, 0� 0l/�'/ Spec. Cond. Initial Cal Time t - r QC•r' ;AM Time: �.Meas Mid Day Time: " Check `PM Time Che I- — i lnttial Cal:Time; ORP 240 mil / -- Signatute:'%.' ��..`. Date Ndtes: :. 1. Electronic equipment calibrated acco:dingtoahe manufacturers operation manual: 2: Specific Conductivity should be calibrated according to values representative of historic range. 3, Order of Calibration is as follows, SPeaficCon&ctivity pH 7,:pH 4,;PH) o, Do, ORP, QC checks... " 4. QC Acceptable Ranges: PH +/= 0.1 SA and Specific Conductivity 1 b% of the true value. If QC readings are out of range,,the instrument needs to be recalibrated. 5. * indicates' QC.check must be"performed in the:moming, afternodn, end the end of the day, or everyfour hours 6- " Indicates to choose a'Specific Conductivity buffer of 1473, 447, 84, or 23. mS which is cloeest to historical readings from the project location: _ Page 1 of f� CHAIN-OF=CUSTODY /Analytical Request Document fir. .... The Chain -of -Custody Is a LEGAL DOCUMENT. Ali,reledant fields must he completed accurately. Section A Sect ion 8 Section C. . Required Client trdarmatiori: Rragdired'ProJect lidormation:' Invoice IMormatian: Pa e : 1 Of . 7 COMWY: ANCHOR QEAof NORTH CAROLINA RePoftTo: . Brian Gant '' AKentlon: 5c yyi d qS :1Z e i10-1i'msr Address: 231 Hapv>ood Street . . _ Copy To: ' . . Company Name: Asheville; NC'28801. ` _ - Address: " Email. bgari'o anchonjea.com Purchase Order#. ". ' '. '. Pace Quote: - Phone: '. (828)281.335Q Fax Project Name: CLEMENT PAPPAS q Pace Project Manager.. " . .loni. alien acetaba.00m, . _ - Slate HLooaho$' Requested Due'Date: Project 0. Pace Profile M. f - .. - _-�-•R._uealodAiiiil IaiFllteiodYlN: °'2' �•c"` �',' k 'i^'=� .' " � o COLLECTED Preservatives . K r KI%�� CODEs ortnx fig taker . ow - a z • water wr W.UW.W. WW 8 M. �. m �'. .. .. 0 3. 2 . SAMPLE' 1) P.&a a�a P a e �' '' START END " . One Character per boy (A-Z,"1;') wb Arne. NP m Ids must he . � �a .� m Sample unique Tssue Ta w um x IJJ "" m y DATE TIME DATE TIME. o �- -, it&Irk fir,' �.�)' 7. WT. X X X X X. T SW 2 I X " X 'X X. X !'+c'.A ; �! %X k N1 W �. _ i Z&►`i z. AV— �S Ici0 � .�c IQJ: " - �.. '_AUUITIOtdAL'COMMFM3 -. RELINQtifBHED.8Yf/M1ATIGN: i DATA' TIME'. 1ACCF3Ra�9YlAF,FWTrtHlt r0 TL ', " �ME.� '� BAHPt�.COhDITlOtJ9`�,' 5�z NO -- ti ? :�`,�r 1 - ^ » c ' 50.MititERNAME/1NDSIGNATt1R6. �- - PRINT Memo of SAMPLER �PSJv,' f -''' e o m _ 3g�_ - - - SIGNATURE of SAMPLER. DATE Signed:. S.r/� ff` �} r�. m $ Y E r� GW-59A COMPLIANCE REPORT FORM Permit # wQ0004797 (SuGndl pine each moldloringPeriod with GIN-59 fiirms.). 1 Enter date monitoring results'weee due. (oe/31/2oi's) Will this monitoring report (GW-59 and GW-59A) YE NO be submitted after the established due date? X 2 Was any required information missing on the'GW=59 report forms? YES NO lF the answerto'question .1 or2 is 'YES", Mist in the space provided below the well identification number(s) and - explain the problems encountered in obtaining the required information: 3 Are any of the monitor wells in need of repair of maintenance (damaged casing, unlocked or missing -cap, missing. YES NO identification plate, area overgrown, ete.)? If the answer is "i es ", contact the Regional 0 rce for g+ridance. X 4- Are any monitored constituents -equal to or.above the established"standards? YES NO If the answerto.question 4 is NO", skip to section. 8: If the answer to question 4 is "YES"list the affected wells individually with constituent(s) and concentrations) exceeding standards in thespace provided below:' " Nitrate (2L = 10 mg/L): MW-7R015.5 mg/L, MW78914.4 mg/L; TOC (2L - 10 mg/L): MW-8®10.8 mg/L; Fecal Coliform (Total Coliform 2L standard = 1. 0:CFU/1P0mL)': MW-.5®2.0 CFU/100mL, . MW-6®1..0 CFU/100mL; TDS,(2L - 500 mg/L): MW-60548_ mg/L 5 For the constituents identified In question 4 above, have standardsbeen exceeded previously for the _ YES NO same constituent(s).in the same Wells) In the last two years? X If the answer to question 5 Is'"NO , skip to section 8. .If the. answer to question 5 is "YES- list in the. space provided below, each well with constituent(s) exceeding standards, concentration(s) repotted "and.sample collection date for each- occurrence (for the last two years). Nitrate Nitrate TOC _ Fecal Coliform" MW-7R MW-8 - .. KW-8 MW-5- . 05/04/16: 11.2, mg/L 5/4/2016: f9.1 'mg/L - 05/04/16: 15.0 mg/L 11/08/17: 1.88 CFU/100mL _ 06/09/16:. lo-.9/10.0 mg/l; 06/09/16: 26.3/26.0 mg/L 05/02/17: 11.4 mg/L MW-6. 11/09/16: 12.5 mg/L 11/09/16: 14:3 .mg/L' TDS 11/08/17: 79.0 CFU/100mY, ll/' 108/17: 36.8 mg/L .05/02/17:, 12.4 mg/L MW-8 - no exceedIances in two years .. 1' 11 08 T:. 14.4 ' 6 Are the monitoring wells listed. in section 5 located at beyond. the review boundary.? YES NO - MW-5, MW77R;'and MW'-8.are. at or beyond.the.review boundary.. X If the answwer ls: "YES ;"a'groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIA TELY FOR GUIDANCE_ , If the answer is "NO" monitoring wells may be improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem?' X If the answer to question 7 is TFS , describe those actions in the space provided below. If the answer to question 7 is "NO';, contact the Regional Office within 90 days: an evaluation may be required to determine the impact the.waste'disposal system Is having at the review and compliance boundaries surrounding this facility failure to do so may sublect the"permittee to a Notice of. Violation: - fines, and/or penalties. . Fecal col'iform'should not be attributable to site operations. Historical monitoring of an on -site tributary of Mud Creek has found high levels.of fecal coliform.. Nitrate concentrations exceeded the groundwater standard in MW-7R and MW-8 for.the first time -in May '2016. . -The high concentrations of nitrate are likely attributable to the frequent flooding of Mud Creek. g The person co►npleting this portion (G W-59A) of the monitoring report should sign below and submit this form.with GW 59 forms. for required wells to the. address provided at the top of the current GW-59 form. I hereby. acknowledge that th -above information was evaluated and the Information submitted in th)s j . Ireport (Comp , nce Rep W-59A)_ls'tr a and complete to the best of my knowledge.'_, gnature ofP.ermittee (or Authorized Age t) " Date Attachment 4 DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Forms SUBMIT FORM ON YELLOW PAPER ONLY 102E• • DEPARTMENT OF ENVIRONMENT 3 NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 8 / 31 / 2 0 2 0 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville (StfCe') NC 28792 County Henderson ❑ Lagoon' ❑ Remediation: Infiltration Gallery (cay) (stall) (zip) ® Spray Field ❑ Remediation: Contact Person: Mrs. Tracy Wolfe Telephone#: 8 2 8 - 3 2 9 - 6 6 4 7 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW - 4 Date sample collected: 0 5 / 0 2 / 2 018 FIELD ANALYSES: WAS Well Depth: 18 _ 2 0. Well Diameter: 2 in. pH ooaoo: 5. 86 units Temp. 000lo: 12 .8 °C DRY at Depth to Water Level 82546: 8 , 44 ft. below measuring point Screened Interval: 8*ft. to16_1*ft. Spec. Cond. 00094: 257.4 µMhos time of sampling, MeasuringPoint is 2 .43 ft. above land surface Relative M.P. Elevation: 2063 .77 ft. Odor o0065: none check Volume of water pumped/bailed before sampling: 5.0 -screened interval is relative to land surface gallons Appearance here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead o1051 ug/L Coliform: MF Fecal 31616 < 1 . 0 /100mL Nitrate (NO3) as N 00620 2.1 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.11 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 167 mg/L All - Aluminum o11os mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 3.0 mg/L Ca - Calcium 00916 mg/L Chloride 00940 10 . 0 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate oo945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ® Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L method # Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese o1o55 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.8/2013 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-607.6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 8 / 31 / 2 0 2 0 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville (stc'3t) NC 28792 County Henderson El Lagoon El Remediation: Infiltration Gallery (city) state) (zip) [R Spray Field ❑ Remediation: Contact Person: Mrs. Tracy Wolfe Telephone#: 8 2 8 - 3 2 9 - 6 6 4 7 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: from Permh SAMPLING INFORMATION MW- 5 If WELL WELL ID NUMBER (from Permit): Date sample collected: 0 5 / 0 2 / 2 018 FIELD ANALYSES: WAS Well Depth: 18 _ s n ft. Well Diameter: 2 in. pH 00400: 5.69 units Temp. 000lo: 12 • 9 IC DRY at Depth to Water Level 82546: 8 • 4 7 ft. below measuring point Screened Interval: 9 * ft. to 19 * ft. Spec. Cond, 00094: 110.7 µMhos time of Measuring Point is 3 . 0 0 ft. above land surface Relative M.P. Elevation: 2085.60 ft. Odor 00085: none sampling, check Volume of water um ed/bailed before sampling. 5 . 25 p p p ga *screened interval is relative to land surface gallons Appearance here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead olo51 ug/L Coliform: MF Fecal 31616 2 . 0 /100ml- Nitrate (NO3) as N 00620 <0 . 022mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0. 0 9 7 mg/L . (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 90 - 0 mg/L AI - Aluminum oil o5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00660 5.7 mg/L Ca - Calcium oo916 mg/L Chloride 00940 16 . 1 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ® Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L , method # Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese olo55 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remedlation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM I c A d-n rry rti rncur AT1f%1J Please Print Clearly or Facility Name: Clement Pappas Permit Name (if different): Facility Address: 125 Industrial Park Hendersonville (Street) NC 28792 County Henderson IContact Person: Mrs. Tracy Wolfe Telephone#: 8 2 8- 3 2 9- 6 6 4 7 Well Location/Site Name: Irrigat ion Area No. of wells to be sampled: 6 DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 PERMIT Number: Expiration Date: 8 / 31 / 2 0 2 0 Non -Discharge WQ 0 0 0 4 7 9 7 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ® Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: ,,...,...�...,.. MW- 6 L ID NUMBER (from Permit): Date sample collected: 0 5 / 02 / 2 018 FIELD ANALYSES: Depth: 11 . 58 ft. Well Diameter: 2 in. pH 00400: 5 •28 units i to Water Level 82546: 5 . 3 6 ft. below measuring point Screened Interval: 5* ft. to 10 * ft. Spec. Cond. 00094: luring Point is 3 . 0 0 ft. above land surface Relative M.P. Elevation: 2061.17 ft. Odor 00085: none ne of water pumped/bailed before sampling: 3.25 gallonSBcreened interval is relative to land surface Appearance )les for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO Temp. 00010: 13 . 3 eC 123.4 µMhos ite sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services Certification No. 37712 \RAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Coliform: MF Fecal 31616 1.0 /100mL Nitrate (NO3) as N 00620 0 . 085 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0. 0 9 7 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L solved Solids:Total 70300 81.0 mg/L AI - Aluminum oil o5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC oo66o 2.3 mg/L Ca - Calcium 00916 mg/L Chloride 00940 9.4 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L Phenol 32730 ug/L Fe - Iron 01045 ug/L Sulfate 00945 mg/L Hg - Mercury 71900 ug/L ecific Conductance 00095 µMhos K - Potassium 00937 mg/L Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L (Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L TKN as N 00625 mg/L Ni - Nickel 01067 ug/L Pb - Lead o1o51 Zn - Zinc 01092 ug/L mg/L Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT-.) Lab Report Attached? ® Yes (1) ❑ No (0) method # method #/ method # method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% UVV-0W Rev. 01/v la DRY at time of sampling, check here:❑ SUBMIT FORM ON YELLOW PAPER ONLY • • DEPARTMENT OF ENVIRONMENT & NATURAL. RESOURCES GROUNDWATER QUALITY MONITORING: • � � DIVISION OF'WATER RESOURCES - INFORMATION `PROCESSING UNIT COMPLIANCE REPORT FORM � 1617, MAIL SERVICE CENTER, RALEIGM, NC 27699.1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 8 / 31 / 2 02 0 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other" Facility Address: 125 Industrial Park. TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville (street) NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery (aty) (state) (zip) N Spray Field ❑ Remediation: Contact Person. Mrs. Tracy Wolfe Telephone#: 8 2 8' - 3 2 9 - 6 6 4 7 El Rotary Distributor El Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION MW - 7R If WELL WELL ID NUMBER (from Permit): Date sample collected: 0 5 / 0 2 / 2 018 FIELD ANALYSES: WAS Well Depth: 17 _ 3 7ft. Well Diameter: 2 in. pH 00400: 5 .41 units . Temp. 0oolo: 13.6 eC DRY at Depth to Water Level 82546: 1 n _ 9gft. below measuring point Screened Interval: 5 ft.* to 15 ft* Spec. Cond. 00094: 281.4 µMhos time li sampling, MeasuringPoint is 3 . 00 ft. above land surface Relative M.P. Elevation: 2062.86 ft. Odor 000a5i none check Volume of water pumped/bailed before sampling: 3.75 *screened interval is relative to land gallons surface Appearance here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES' ❑ NO LABORATORY INFORMATION Date sample analyzed: varies; ,see analytical report LaboratoryName: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 . mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead o1o51 ug/L Coliform: MF Fecal 31616 <2 . 0 /100mL Nitrate (NO,) as N 00620 15.5 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.32 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 7o3oo 207 mg/L AI - Aluminum 61105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 3.2 mg/L Ca -Calcium 00916 mg/L Chloride oo94o 2 2 . 6 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? R1 Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L method # Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NHy as,N;.Ammonia Nitrogen, Total) Mn -.Manganese olo55 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L, method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM FACILITY INFORMATION Please Print Clearly or Type Facility Name: Clement Pappas Permit Name (if different): Facility Address: 125 Industrial Park Hendersonville (street) NC 28792 County Henderson Contact Person: Mrs. Tracy Wolfe Telephone#: 8 2 8- 3 2 9- 6 6 4 7 Well Location/Site Name: Irrigation area No. of wells to be sampled: 6- DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES DIVISION OF WATER RESOURCES • INFORMATION PROCESSING UNIT 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-907-6306 PERMIT Number: Expiration Date: 8 / 31 / 2 0 2 0 Non -Discharge WQ 0 0 0 4 7 9 7 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ® Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: WELL L ID NUMBER (from Permit): MW - 8 Date sample collected: 0 5 / 0 2 / 2 018 FIELD ANALYSES: WAS Depth: 13 9 a ft. Well Diameter: 2 in. pH 000lo: 6 .74 units Temp. 000lo: 12 •1 °C DRY at _ to Water Level 82546: 9 •3 9 ft. below measuring point Screened Interval: 3 ft* to 13 ft" Spec. Cond. 000sa: 871 µMhos time of sampling, luring Point is 3 . 00 ft. above land surface Relative M.P. Elevation: 2060.80 ft. Odor doom: none check screened interval is relative to land surface Tie of water pumped/bailed before sampling: 3.00 gallons Appearance here: ❑ ales for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO de sample analyzed• varies; see analytical report Laboratory Name: Pace Analytical Services 1RAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Coliform: MF Fecal 31616 <2 . 0 /100mL Nitrate (NO3) as N 00620 14.4 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.19 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L (solved Solids:Total 70300 5 4 8 mg/L All - Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC oosao 10.8 mg/L Ca - Calcium 00916 mg/L Chloride 00940 12 . 9 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L Phenol 32730 ug/L Fe - Iron 01045 ug/L Sulfate 00945 mg/L Hg - Mercury 71900 ug/L iecific Conductance 00095 µMhos K - Potassium 00937 mg/L Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese wo55 ug/L TKN as N 00625 mg/L Ni - Nickel 01067 ug/L Certification No. 3 7 712 Pb - Lead o1o51 ug/L Zn - Zinc 01092 mg/L Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method A ATTACH LAB REPORT.) Lab Report Attached? ® Yes (1) ❑ No (0) method # method # method # method # Fer Remediation Svstems Only (Attach Lab Resorts): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% vvv-5y Kev. is/zuis SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: • . � • � � DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617'MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 8 31 / 2 0 2 0 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED {Street) Hendersonville NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery (city) (State) (lip) ® Spray Field ❑ Remediation: Contact Person: Mrs . -Tracy Wolfe Telephonet 82 8 - 3 2 9 - 6647 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irri2ati.on Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW- 9 Date sample collected: 0 5 / 02 / 2 018 FIELD ANALYSES: WAS Well Depth: 18 .1 ?ft- Well Diameter: 2 in. pH 00400: 5.52 units Temp. 000lo: 13 .3 eC DRY at Depth to Water Level 82546: 5. • 0 7 ft. below measuring point Screened Interval: 6 *ft. to 16 * ft. Spec. Cond. 00094: g l . 0 µMhos time of sampling,. Measuring Point is 1 . 44 ft. above land surface Relative M.P. Elevation: 2060.23 ft. Odor 00085: none check Volume of water pumped/bailed before sampling: 6.75 *screened inte_rval'is relative to land surface gallons Appearance here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: varies; see analytical report Laboratory'Name: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb'- Lead 01051 ug/L Coliform: MF Fecal 31616 <2 . 0 /100mL Nitrate (NOO as N oo62o 0.58 rng/L Zn - Zinc 01092 mg/L Coliform: MFTotal 31504 /100mL Phosphorus: Total as P 00665 0.37 mg/L .(Note: Use MPN method for highly turbid Samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 69.0 mg/L Al -Aluminum 01105 mg/L pH (Lab) 00403 units Be - Barium 01007 ug[L TOC 00680. 4.6 mg/L Ca - Calcium 00916 mg/L Chloride 00940 4.9 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS', HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ® Yes (1) ❑ No (0) pecific Conductance 00095 µMhos K - Potassium 00937 mg/L method # Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia. Nitrogen; NH3 as N; Ammonia Nitrogen, Total: Mn - Manganese o1o55 ug/L ; method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent. Total VOCs: mg/L VOC Removal% Permittee (or Authorized Agent) Name find Title -Please print or type` Signature GW-59 Rev.8/2013