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WQ0004797_Monitoring (Report)_20171218
Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry o M 0 U �. o . - M .N _ N M C O r (CFUs per Sample Name Sample. Date (mg/L) (mg/L). 100 mL) (mg/L) (mg/L) (mg/L) . (mg/L) (mg/L) 05/24/2006 7.2, 9.7. < 1.1 2 19 82 < 0.10 NA 11/09/2006 3.6 7.4 < 1.1 0.95 17 76 0.11 NA 05/18/2007 . 4.9" 6.0 < 1.0 0.56' 14 62 < 0.10 NA 11/13/2007 5.9 16.7 <1.1 2.9 6.9 82.0 < 0.10 NA 05/27/2008 10.2 9.0 <1.1 0.80 21.3 140 < 0.10 NA 11/18/2008 4.7 10.7 <1.1 1.9 8.5 32.0 < 0.10 NA 05/28/2009 14.4 7.1 < 4.0 0.46 24.2 104 < 0.10 NA 11/05/2009 13.5 5.9 < 2.0 0.31 23.5 80.0 < 0.10 NA MW-2R 05/13/2010 8.7 5.8 <.2.0 < 0.10 17.2 57.5 < 0.10 NA 11/08/2010 18.3 10.0 < 2.0 .1.1 11.7 60.0 < 0.10 NA 05/17/2011 . 11.6 < 5.0 < 2.0 < 0.10 14.3 < 62.5 < 0.10 NA 11/15/2011 18.9 10.1 < 2.0 1.2 10.0 86.0 < 0.10 NA 05/17/2012 5.3 7.6 < 4.0 < 0.20 11.9 68.0 < 0.10 NA 11'/07/2012 31.1 9.5 < 1.0 1.3 10.0 67.0 < 0.10 NA 05/16/2013 13.5 1.2 < 1.0 < 0.02 13.2 64.0 <.0.10 NA 11/20/2013 6.1 7.6 < 1.0 0.97 9.3 66.0 < 0.10 NA 05/22/2014 8.0 4.1 < 1..0 0.72 8.4 52.0 < 0.10 NA Standards 10 250 1 10 250 500 1.5 NL Clement Pappas Groundwater Monitoring November 2017 Hendersonville, North Carolina, Pagel of 7 December 2017 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Sample Name . Sample Date O V 'C O 0 p 'E 0 W V V U. .°.' ro = Z(CFUsper :: R = -N � � N N - 0 2 0 C C L 0 s• 0 a . 4. /L)(mg/L) ;5.5 .100 m.L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) 05/15/2002 9 45 < 1.1 < 0.10 9.3 180 < 0.10 NA 11/05/2002 48 < 1.1 < 0.1 14 2.30 < 0.10 NA '05/13/2003 3.3 32 < 1.1 0.051 1 20 110 0.21 NA 11/04/2003 41 31 < 1.1 < 5.0 66 210 < 0.10 NA 05/05/2004 6 29 < 1.1 < 5.0. 45 240 0.11 NA 11/09/2004 8.4 13 3.6 < 0.10 52 200 < 0.10 NA 05/17/2005 8.5 10 < 1.1 < 0.10 37 220 < 0.10 NA 11/03/2005 16 . 14 < 1.1 < 0.10 29 220 0.14 NA 05/24/2006 19 11 < 1.1 < 0.10 28 180 <.0.10 NA 11/09/2006 8.8 6.9 < 1.1 < 0.10 .26 180 < 0.10 NA 05/18/2007 8.5 8.9 < 1.0 < 0.10 29 300 < 0.10 NA 11/13/2007. 16.7 11.3 < 1.1 < 0.10 25.0 152 < 0.10 NA 05/27/2008 < 1.0 10.0 < 1.1 < 0.10 38.6 176 < 0.10 NA 11/18/2008 20.5 . 9.3 < 1.1 < 0.10 19.6 108 < 0.10 NA 05/28/2009 8.6 - 13.6 < 4.0 < 0.10 35.5 156. < 0.10 NA MW-4 11/05/2009 31.0 13.6 < 2.0 < 0.10 30.7 120 < 0.10 NA 05/13/2010 7.8 18.0 < 2.0 0.17 31.0 141 < 0.10 NA 11/08/2010 23.9 17.5 < 2.0 < 0.10 34.4 144 < 0.10 NA 05/17/2011 7.7 13.5 < 2.0 0.82 25.6 137 < 0.10 NA 11/15/2011 7.3 14.4 < 2.0 < 0.20 27.8 157 < 0.10 NA 05/17/2012 6.7 12.1 2.0 < 0.20 1 22.3 117 < 0.10 NA. 11/07/2012 10.6 14.5 2.0 < 0.020 26.2 150 <,0.10 NA 05/16/2013 31.8 10.2 2.0 0.28 15.1 108 < 0.10 NA 11/20/2013 8.0 14.7 < 1.0 0.026 22.1 157 < 0.10 NA 05/22/2014 8.7 10.8 < 2.0 0.14 22.5 ' 146 < 0.10 NA 11/18/2014 28.7 12.1 < 2.0 < 0.020 21.9 161 < 0.10 NA 05/13/2015 5.4 9.2 < 1.0 < 0.020 21.5 130 < 0.10 NA 11/04/2015 6.6 6.2 <2.0 < 0.020 NA 139 < 0.10 0.10 ..05/04/2016 5.5 8.4 < 4.0 < 0.020 NA 119 < '0.10 0.095 11/09/2016 4.3 12.2 < 4.0 < 0.020 NA 124 < 0.10 0.27 05/02/2017 3.9 7.0 <2.0 0.4 NA 96 <0.10 0.072 11/08/2017 3.0 7.3 <2.0--r 1.2 NA 135 <0.10 0.070 Standards 10 250 1 10 250, 500 7.5 NL Clement Pappas Groundwater Monitoring November 2017 Page 2 of 7 Hendersonville, North Carolina December 2017 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry • Sample Name .. Sample Date 0 O Y 'o •O u U, . U. " LL. z H fl" O N c ¢ .0C a , (mg/L) (mg/L) =(CFOs per . 100 mL) (mg/L) (mg/L) (mg/L) (mg/L), (mg/L) 05/15/2002 2.9 15 < 1.1 0.42 1.7 < 40 < 0.10 NA 11/05/2002 1.4 16 < 1.1 0.54 < 1.0 83 1.3 NA 05/13/2003 4.6 17 < 1.1 0.65 2 " 56 0.25 NA 11/04/2003 19 22 < 1.1 0.23 < 5.0 58 < 0.10 NA 05/05/2004 0.7. 28 < 1.1 0.57 < 5.0 80 0.15 NA 11/09/2004 1.2 34 < 1.1 0.24 < 5.0 130 < 0.10 NA 05/17/2005 2.1 35 < 1.1 < 0.10 < 5.0. 110 < 0.10 NA 11/03/2005 8.1 34 < 1.1 0.11 < 5.0 82 < 0.10 NA 05/24/2006 7.8 34 < 1.1 < 0.10 .< 5.0 120 < 2.5 NA 11/09/2006 1.3 37 < 1.1 0.20- < 5.0 90 < 0.1 NA 05/18/2007 1.7 42 < 1.0 0.16 < 5.0 130 < 0.10 NA 11/13/2007 4.2 41.3 < 1.1 0.25 < 5.0 112 < 0.10 NA 05/27/2008 6.7 14.3 < 1.1 0.21 < 5.0 168 0.17 NA 11/18/2008 25.9 47.6 < 1.1 0.17 < 5.0 80.0 < 0.10 NA 05/28/2009 16.1 129.0 4.0 0.11. < 5.0 188 < 0.10 NA MW-5 11/05/2009 4.7 39.1 '2.0 0.15 < 5.0 112 < 0.10 NA 05/13/2010 3.2 43.0 23 0.17 < 5.0 147 < 0.10 NA 11/68/2010 13.8 43.7 200 < 0.10, < 5.0 113 < 0.10 NA 05/17/2011 4.0 32.3 < 4.0 < 0.10 < 5.0 < 167 < 0.10 NA 11/15/2011 3.0 52.6 120 < 0.20 < 5.0 165 < 0.10 NA 05/17/2012 4.7 36:6 < 2.0 < 0.20 < 5.0 110 < 0.10 NA 11/07/2012 4.1 61.1 < 10.0 0.12 <. 2.0 " 139 < 0.10 NA 05/16/2013 4.0 44.2 1.0 0.093 2.3 152 < 0.10 _ NA . 11/20/2013 4.2 64.6 1.0 0.19 < 2.0 162 < 0.10 NA 05/22/2014 5.8 6.6 < 10.0 0.099 < 2.0 110 < 0.10 NA 11/18/2014 16.0 57.7- 6.0 0.28 < 2.0 160 < 0.10 NA 05/13/2015 21.0 68.4 < 2.0' 0.11 < 2.0 176 < 0.10 NA 11/04/2015 7.3 20.3 7.0 < 0.020 NA 68.0 < 0.10. 0.21 05/04/2016 8.6 41.5 < 10.0 0.042 NA 90.0 < 0.10 0.12 11/09/2016 <1.0 45.0 - < 4.0 0.42 NA 109 < 0.10 0.47 05/02/2017 =. 8.1 29.0 3.0 <0.020 NA 134 <0.10 0.097 11/08/2017 6.7 12.8 188 <0.020 NA 84.0 <0.10 0.086 Standards 10 250 1 10 1 250 500 1.5 NL Clement Pappas Groundwater Monitoring -November 2017 Page 3 of 7 Hendersonville, North Carolina December 2017 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry ,Sample Name_ Sample Date O V 01 O 16' W 'o O . ~ v, f0 « i +; w O in °7 a Yl p 10 �o o E Lft O .c O a �0 (mg/L) ;(mg/L) (CFUsper 160 ml.) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) 05/15/2002 6.8 9.9 5.1 < 0.10 11 < 40 < 0.10 NA 11/05/2002 3.9 4.6 < 1.1 0.49 9.8 51 2.5 NA 05/13/2003 4.4 7.3 > 23.0 0.075 14 52 0.14 NA 11/04/2003 26 6.8 9.2 < 0.050 12 < 20 < 0.10 NA 05/05/2004 1.8 6.7 1.1 < 0.10 11 58 0.13 NA 11/09/2004 3.5 11 9.2 < 0.10 9.3 88 < 0.10 NA 05/17/2005 2.4 7.4 <.1.1 < 0.10 8.7 50 1 < 0.10 NA 11/03/2005 6.3 9.6 < 1.1 < 0.10 9.6 66 0.17 NA 05/24/2006 7.4 10 < 1.1 < 0.10 9 54 < 0.10 NA 11/09/2006 1.4 ' 11 < 1.1 0.20 11 54 0.18 NA 05/18/2007 3.9 9.4 < 1.0 <.0.10 9.1 58 0.12 NA 11/13/2007 5.7 10.7 3.6 0.24 5.8 114 0.24 NA 05/27/2008 . 10.9 5'4 < 1.1 < 0.10 15.3 92.0 < 0.10 NA 11/18/2008, 7.4 7.6 > 23 < 0.10 < 5.0 36.0 < 0.10 NA 05/28/2009 6.4 6.2 276 0.39 8.8 104 < 0.10` NA MW-6 11/05/2009 6.4 < 5.0 30 0.10 9.3 52.0 `<0.10 NA 05/13/2010 4.3 1 5.8 < 2.0 <' 0.10 8.1 44.0 < 6.10 NA 11/08/2610 -' 16.5 5.0 7.0 1.5 9.3 48.0 < 0.10 NA 05/17/2011 6.2 9.4 < 2.0 < 0.10 6.8 60.0 < 0.10 NA 11/15/2011 4.6 5.2 5.0 < 0.20 7.5 82.0 < 0.10 NA 05/17/2012 . 21.6 8.1 28.0 < 0.20 8.8 52.0 < 0.10 NA 11/07/2012 6.4F69� 3.1 < 0.020 7.5 46.0 < 0.10 NA 05/16/2013 7.5 12.1 . 0.048 9.4 62.0 < 0.10 NA 11/20/2013 4.4 < 1.0 < 0.020 -8.6 56.0 <0.10 NA 05/22/2014 4.6 1.0 < 0.020 10.1 32.0 < 0.10 NA 11/18/2014 16.3 13.0 0.078 9.8 49.0. < 0.10 NA 05/13/2015 2.1 6.2 < 1.0 < 0.020 10.1 46.0 < 0.10 NA 11/04/2015 2.2 9.5 136 2.9 NA 58.0 < 0.10 0.12 05/04/2016 2.1 9.4 < 2.0 0.41 NA 58.0 < 0.10 0.079 11/09/2016 7.1 9.0 < 10.0 < 0.020 NA 64.0 0.11 0.70 05/02/2017 1.8 12.1 2.0 0.47 NA 93.0 <0.10 0.09 11/08/2017 1.4 11.1 74.0 0.045 NA 66.0 / <0.10 <0.050 Standards 10 250 7 10. 250 500 7.5 NL Clement Pappas Groundwater Monitoring November 2017 Page 4 of 7 Hendersonville, North Carolina December 2017 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Sample Name Sample Date o 10 U c to O H 'o U E U U.. �a,+ Z ;� to 0 IA3 -a W o . 41. F o Q O s c a 1- (mg/L) (mg/L) (CFUs per 100 mL) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) 05/15/2002 20 6.5 < 1.1 5.2" 26 < 40 < 0.10 NA 11/05/2002 .16 3.3 < 1.1 1.3 1.1 68 1.4 NA 05/13/2003 9.7 3.6 1 2.2 1.8 9.3 44 0.72 NA 11/04/2003 19 6.1 < 1.1 0.72 < 5.0 < 2.0 < 0.10 NA 05/05/2004 3.0 7.0 <' 1.1 1.3 < 5.0 52 < 0.10 NA 11/09/2004 2.2 5.1 5.1 1.9 < 5.0 62 < 0.10 NA 05/17/2005 3.2 6.1 < 1.1 1.2 .< 5.0 40 < 0.10 NA 11/03/2005 7.7 6.1 < 1.1 0.99 < 5.0 58 0.10 NA 05/24/2006 8.4 5.5 < 1.1 1.5 < 5.0 - 48 < 0.10 NA 11/09/2006 1.9 7.0 < 1.1 1.1 1 6.7 38 < 0.10 NA MW-7 05/18/2007 3.6 8.6 < 1.0 2.2 5.9 70 < 0.10 NA 11/13/2007 4.2 6.8 < 1.1 1.7 < 5.0 42.0 < 0.10 NA 05/27/2008 7.6 11.5 < 1.1 2.2 6.9 88.0 < 0.10 NA 11/18/2008 7.5 7.7 < 1.1 1.7 < 5.0 30.0 < 0.10 NA 05/28/2009 23.4 9.8 < 4.0 2.3 < 5.0 336 < 0.10 NA 11/05/2009 5.3 10.7 2.0 2.3 11.2 70.0 < 0.10 NA 05/13/2010 4.6 11.0 < 2.0 2.5 < 5.0 71.0 < 0.10 NA 11/08/2010 15.4 8.9 . < 2.0 2.3 < 5.0 60.0 < 0.10 NA 05/17/2011 6.0 11.6 < 2.0 5.3 7.6 103 < 0.10 NA 11/15/2011 2.2 9.9 < 2.0 3.5 < 5.0 89.0 < 0.10 NA 05/17/2012 4.4 10.9 < 2.0 3.8 < 5.0 67.0 < 0.10 NA 11/07/2012 11.6 13.1 < 100 4.0 14.9 108.0 < 0.10 NA 05/16/2013 12.8 17.1 < 1.0 10.5 .28.3 252 < 0.10 NA 11/20/2013 9.4 14.0 < 1.0 5.5 3.5 < 250 < 0.10 NA 05/22/2014 8.9 13.1 < 16,000 5.7 4.0 93.0 < 0.10 NA 11/18/2014 19.1 16.0 < 20.0 7.1 4.4 93.0 < 0.10 NA 05/13/2015 8.5 17.0 < 2.0 9.3 3.7 125 < 0.10 NA MW-7R 11/04/2015 9.9 18.0 < 2.0 8.3 NA 129 < 0.10 0.35 05/04/2016 13.5 27.7 < 1.0.0 11.2 NA 130 < 0.10 ' 0.78 06/09/2016 - Pace NA NA NA 10.9 NA NA NA NA 06/09/2016 - Prism NA NA NA 10.0 NA NA NA NA 11/09/2016 13.0 22.7 < 20.0 12.5 NA 147 < 0.10 1.0 05/02/2017 6.7 17.9 <4.0 8.9 NA 169 <0.10 0.4 11/08/2017 3.9 17.9 19.0 36.8 NA. 376 <0.10 0.14 Standards 70 250 1 10 250 500 1.5 NL Clement Pappas Groundwater Monitoring November 2017 Page 5 of 7 Hendersonville, North Carolina December2017 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Sample Name • f Sample Date O A U c IM O 10 'o •O U p = U . f0 LLL �+ to Z :: Vl {A 'O h i] 10 FO- O p I_• Q 3 O a o a 10 ~ q4.8 (mg/L) (CFUs_per 100 mL) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) 05/15/2002 8.7 < 1.1 < 0.10 9.1 641 < 0.10 NA 11/05/2002 9.8 < 1'1 0.16 7 100 0.57 NA 05/13/2003 3.3 2.2 1.4 9.4 64 0.41 NA 11 /04/2003 27 8.1 6:9 < 0.0501 13 54 < 0.10 NA 05/05/2004 3.0 7.4 < 1.1 0.24 9.8 140 < 0.10 NA 11/09/2004 3.7 6.7 > 23 0.79 6.8 120 < 0.10 NA 05/17/2005 3.8 8.3 < 1.1 0.61 6.4 88 < 0.10 NA 11/03/2005 7.1 11 < 1.1 0.95 8.4 100 < 0.10 NA 05/24/2006 15 10 < 1.1 039 8.1 130 < 0.10 NA 11/09/2006 4.7 12 < 1.1 0.97 7.7 96 < 0.10 NA 05/18/2007 5.0 15 < 1.0 3.0 13 290 < 0.10 , NA' 11/13/2007 8.3 19.6 < 1.1 0.97 26.6 . 154 < 0.10 NA _ 05/27/2008 12.4 20.0 < 1.1 0.55 35.8 184 < 0.10 NA 11/18/2008 14.4 17.2 2.2 < 0.10 21.5 118 < 0.10 NA 05/28/2009 6.2 , 24.9 240 0.74 24.9 192 < 0.10 NA 11/05/2009 10.8 15.4 50 0.54 18.4 114 < 0.10 NA MW-8 05/13/2010 10.8 14.7 < 2.0 1.1 24.1 106 < 0.10 NA 11/08/2010 23.2 24.3 200 < 0.10 26.3 173 < 0.10 NA 05/17/2011 10 16.9 10.0 12.2 16.1 232 < 0.10 NA 11/15/2011 8.0 26.6 < 2.0 3.7 20.2 232 < 0.10 NA 05/17/2012 .14.4 24.8 12.0 8.0 22.9 356 < 010 NA 11/07/2012 24.8 26.3 < 100 1.9 28.3 324 < 0.10 NA 05/16/2013 15.8 8.8 10.9 6.8 13.4 248 < 0.10 NA 11/20/2013 21.0 .15.4 < 1.0 1.3 24.3 342 < 0.10 NA 05/22/2014 17.6 14.5 < 10.0 0.61 17.8 352 < 0.10 NA 11/18/2014 54.0 16A < 4.0 1.1 13.2 421 < 0.10 NA 05/13/2015 19.7 18.3 < 2.0 9.7 12.2 454 < 0.10 NA 11/04/2015 15.0 21.6 4.0 3.0 NA 396 < 0.10 0.82 05/04/2016 15.0 24.5 < 10.0 19.1 'NA 398- < 0.10 0.62 6/9/2016 - Pace NA NA NA. 26.3 NA NA NA NA 06/09/2016 - Prism NA NA NA 26.0 NA NA NA NA 11/09/2016 9.7 12.0 < 4.0- 14.3 NA 333 < 0.10 0.26. 05/02/2017 11.4 18.9 8.0 12.4 ' NA 497 <0.10 0.3 11/08/2017 8.1 9.7 <4.0 14.4 NA 390 <0.10 0.098 Standards 10 250 1 10 250 500 1.5 NL Clement Pappas Groundwater Monitoring November 2017 Page 6 of 7 Hendersonville, North Carolina December2017 Table.1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry 0 - 0!. �,." U N M, L s . O v +) A) C p a 0 R .o. m E .o . _ U- LL.. Z ,..,. LA H Q -H (CFUs per Sample Name Sample Date (mg/L) (mg/L) 100 mL) (mg/L) (mg/L) (mg/Lj (mg/L) (mg/L) 05/13/2015 2.2 12.4 < 2.0 1.0 1 5.5 94.0 < 0.10 NA 1.1/04/2015 3.8 2.6 <.1.0 < 0.020 NA 58.0 < 0.10 0.45 05/04/2016 15.0 5.3 < 10.0 0.64, NA 1 51.0 < 0.10 0.095 M W 9 -11 /09/2016 9.3 10.7 < 20.0 0.77 NA 69.0 < 0.10 0.76 05/02/2017 7.6 3.8 <4.0 0.17 NA 92.0 <0.10 0.61 11/08/2017 .7.0 8.9 10.0 0.95 NA 64.0 <0.10 0.53 Standards ' 10 250 1 10 1 250 500 1:5 NL . Notes: Standards From North Carolina Administrative Code, Title 15A, Subchapter 2L, April 1, 2013, except total organic carbon and fecal coliform. Total organic carbon standard from Spray Irrigation Permit Number W00004797. Fecal coliform standard is 2L standard for total coliform. 06-09-2016 - Pace A resampling event was performed on June 9, 2016, to investigate nitrate exceedances in MW-7R and MW-8.One set of samples was analyzed by Pace Analytical Services, and a second set of samples was anahnarl by Pricm 1 ahnratnriac Sulfate Removed from list of necessary analyses as of fall 2015 and replaced by total phosphorous 15.0 Bold indicates concentration equal to or above the respective standard. < 4.0 Indicates constituent concentration was not detected above the laboratory reporting limit mg/L milligrams per liter CFU coliform-forming unit mL milliliters NA not analyzed NL No standard limit is set. Clement Pappas Groundwater Monitoring November 2017 Page 7 of 7 Hendersonville, North Carolina December 2017 Table 2 Current and Historical Groundwater Analytical Results for'Volatile Organic Compounds Sample Name Sample Date s' .. L O C y I- (pg/L) e y, a+ O H (pg/L) - O O u 9 N U (pg/L) e d N C F- (Ng/L) O C U ..T (pg/L) ._., O Q.., (pg/L) 11/09/2006 < 0.50 < 0.50 < 0.50 '< 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 < 0.50 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 MW-2R 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0..50 11/08/2010 < 0.50 . < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50. < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 < 0.50 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 MW-4 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2014 < 0.50 < 030 < 0.50 < 0.50 < 1.0• < 0.50 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/09/2016 < 0.50 < 0:50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2017 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/05/2002 4,700 980 820 13 24 1.9 11/04/2003, 3,500 570 510 < 50 < 50 < 50 11/09/2004 580 62 38 < 10 <-10 < 10 11/03/2005 1;900 210 220 < 50 < 50 < 50 11/09/2006 350 . 74 67 0.61 1.2 < 0.50 05/18/2007 320 47 60 < 0.50 < 0.50 < 0.50 11/13/2007 1,150 217 209 2.0 3.4 1.0 11/18/2008 2,680. 534 293 < 25.0 < 25.0 < 25.0 MW-5 11/05/2009 872 106 125 0.92 < 1.0 < 0.50 11/08/2010 578 107 160 < 2.5 < 5.0 < 2.5 11/15/2011 1,450. 124 141 < 2.5 < 5.0 < 2.5 11/07/2012 774 68.8 77.8 < 5.0 < 10.0 < 5.0 11/20/2013 332 65.1 80.5 < 1.2 < 2.5 < 1.2 11/18/2014 121 22.2 26.4 < 0.50 < 1.0 < 0.50 11/04/2015 26.1 2.6 2.9 < 0.50 < 1.0 < 0.50 11/09/2016 141.0 63.1 75.2 < 0.50 < 1.0 < 0.50 11/08/2017 35.9 4.6 4.4 < 0.50 < 1.0 < 0.50 2L Standard a7 3 70 100 0.03 7 Clement Pappas Groundwater Monitoring November 2017 Page 1 of 3 Hendersonville, North Carolina December 2017 Table 2 Current and Historical Groundwater Analytical Results for Volatile Organic Compounds (D C d r d o e 07e e ° o G7 O u W d d u N O O = u N ^ L V u � �O •= e T C H Fes- In VV A H C > •= Sample Name Sample Date (pg/L) (pg/L) (pg/L) W/O (pg/L) W/O 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 . < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 . 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50- < 0.50 " < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 3.0 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 MW-6 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2014 < 0.50 < 0.50 <0.50 < 0.50 < 1.0 < 0.50 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/09/2016 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2017 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW-7 05/18/2007_ < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 0.79 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 . < 1.0 < 0.50 11/07/2012. < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW-7R 11/18/2014 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/04/2015 < 0.50 <0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/09/2016 < 0.50 < 0.50 < 0.50 < 0.50 • < 1.0 < 0.50 11/08/2017 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 2L Standard 0.7 3 70 100 0.03 7 Clement Pappas Groundwater Monitoring November 2017 Page 2 of 3 Hendersonville, North Carolina December 2017 Table 2 Current and Historical Groundwater Analytical Results for Volatile Organic Compounds a w c "o C' _ o o . •• d o u d v d o S u O N . V u. H M N L C > Sample Name Sample Date. (pg/L) OWL). (pg/L) . (pg/L) (pg/L) (pg/L) 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 . < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 • < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50. 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 a 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 <'0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 < 0.50 < 0.50 < 0.50 < 0:50 <-0.5 < 0.50 MW-8 11/05/2009' .< 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 <"0.50 < 0.50 < 0.50 < 0.50 <.1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 ' < 0.50 <"0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013. < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2014 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/09/2016 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 <.0.50 11/08/2017 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/04/2015 < 0.50 < 0.50 < 0.50 '. < 0.50 < 1.0 < 0.50 MW-9 11/09/2016 < 0.50 < 0.50, < 0.50 < 0.50 < 1.0 < 0.50 11/08/2017 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 2L Standard 0.7 3 70 100 0.03 7 Notes: Detections This table only includes compounds that were detected above the laboratory method detection limit since the sampling event in November 2002. The complete suite of compounds analyzed can be found in the individual analytical reports. Only samples collected during November sampling events were analyzed for volatile organic compounds, in accordance with Spray Irrigation Permit Number WQ0004797. 4,700 Bold indicates an exceedance of the 2L standard. 5/18/2007 In accordance with the Compliance Evaluation Inspection letter issued by Beverly Price of the Department of Environmental and Natural Resources, Division of Water Quality, on April 27, 2007, volatile organic compounds and semivolatile organic compounds were sampled during the May 2007 sampling event. Naphthalene Detected in MW-6 for the first time at a concentration of 2.2 ug/L (which is below the 2L standard of 6 pg/L) during the November 5, 2002 sampling event 1,1,2-trichloroethane Detected in MW-5 for the first time on November 20, 2010, at a concentration of 8.0 pg/L; which exceeds the North Carolina Interim Maximum Allowable Concentration of 0.6 ug/L Chloroform Detected for the first time in MW-5 during the November 2011'sampling event at a concentration of 31.3 pg/L, which is below the 2L standard of 70 Ug/L Toluene Detected for the first time in MW-4 during the November 2015 sampling event at a concentration of 0.75.ug/L, which is below the 2L standard of 600 ug/L 2L Standard North Carolina Administrative Code, Title 15A, Subchapter 2L, April 1, 20.13 ug/L micrograms per liter Clement Pappas Groundwater Monitoring November 2017. Page 3 of 3 Hendersonville, North Carolina December 2017 Table 3 Current and Historical Geoundwater'Elevation Measurements r Well Identification. Date Measured Depth to Groundwater (ft-BTOC) Top -of -Casing Elevation (feet) Top -of -Casing Height Above Ground Surface (feet) Groundwater Elevation (feet) 05/24/2006 9.29 2063.00 3.77 2053.71 11/09/2006 6.49 2063.00 3.77 2056.51 05/18/2007 7.94 2063.00 3.77 2055.06, 11/13/2007 8A6 2063.00 3.77 2054.54 05/27/2008 8A8 2063.00. 3.77 2054.52 11/18/2008 8.50, 2063.00 3.77 2054.50 05/28/2009 5A3 2063.00 3.77 2057.57 11/05/2009 6.72 2063.00 3.77 2056.28 05/13/2010 7.36 2063.00 3.77 2055.64 MW-211 11/08/2010 9.60 2063.00 3.77 2053.40 05/17/2011 7.25 2063.00 3.77 2055.75 11/15/2011 7686 2063.00 3.77 2055.14 05/17/2012 5.19 2063.00 3.77 2057.81 11/07/2012 7.74 2062.36 3.77 2054.62 05/16/2013 6.86 2062.36 3.77 2055.50 11/20/2013. 7.92 2062.36 3.77 2054.44 05/22/2014 7.56 2062.36 3.77 2054.80 11/18/2014 8.89 2062.36 3.77 2053.47 Well abandoned, replaced by MW-9. 05/15/2002 9.32 2064.60 2.43 2055.28 11/05/2002 9A9 2064.60 2A3 2055.11 05/13/2003 8.20 2064.60 2A3 2056.40 11/04/2003 9.23 2064.60 2A3 2055.37 05/05/2004 9.35 2064.66 2.43 2055.25 11/09/2004 8.61 2064.60 2.43 2055.99 05/17/2005 6.19 2064.60 2.43 2058.41 11/03/2005 9.57 2064:60 2.43 2055.03 05/24/2006 9.60 2064.60 2.43 2055.00 11/09/2006 8.41 2064.60 2.43 2056.19 05/18/2007 9.42 2664.60 2.43 2055.18 11/13/2007 9.89 2064.60 2A3 2054.71 05/27/2008 9.78 2064.60 2A3 2054.82 11/18/2008 9.76 2064.60 2A3 2054.84 05/28/2009 7.16 2064.60 2A3 2057.44 MW-4 11/05/2009 8.53 2064.60 2A3, 2056.07 05/13/2010 8.83 2064.60 2A3 2055.77 11/08/2010 9.30 2064.60 2.43 2055.30 05/17/2011 8.97 2064.60 2.43 2055.63 11/15/2011 9.48 2064.60 2.43 2055.12 05/17/2012 7.62 2064.60 2.43 2056.98 11/07/2012 9.32 2063.77 2.43 2054.45 05/16/2013 7.93 2063.77 2.43 2055.84 11/20/2013 8.87 2063.77 2.43 2054.90 05/22/2014 8.70 2063.77 2A3 2055.07 11/18/2014 8.54 2063.77 2A3 2055.23 05/13/2015 - 9.18 2063.77 2A3 2054.59 11/4/2015 6.93 2063.77 2.43 2056.84 05/04/2016 8.43 2063.77 2.43 2055.34 11/09/2016 9.63 2063.77- 2.43 2054.14 05/02/2017 7.82 2063.77 2.43 2055.95 11/08/2017 1 7.88 2063.77 2.43 . 2055.89 Clement Pappas November 2017 Groundwater Monitoring Page 1 of 5 Hendersonville, North Carolina December2017 Table 3 Current and Historical Groundwater Elevation Measurements Well Identification Date Measured Depth to Groundwater (ft-BTOC) Top -of -Casing Elevation (feet) Top -of -Casing Height Above Ground Surface (feet) _ Groundwater Elevation (feet) 05/15/2002 8.31 2086.40 3.00 2078.09 11/05/2002 10.20 2086.40 3.00 2076.20 05/13/2003 8.29 2086.40 3.00 2078.11 11/04/2003 9.92 2086.40 3.00 2076.48 05/05/2004 8.75 2086AO 3.00 2077.65 11/09/2004 8.50 2086.40 3.00 2077.90 05/17/2005 8.87 2086.40 3.00 2077.53 11/03/2005 9.70 2086.40 3.00 2076.70 05/24/2006 9.34 2086.40 3.00 2077.06 11/09/2006 8.39 2086.40 3.00 2078.01 05/18/2007 9.16 2086.40 3.00 2077.24 11/13/2007 11.00 2086.40 3.00 2075.40 05/27/2008 9.84 2086.40 3.00 2076.56 11/18/2008 11.59 2086.40 3.00 2074.81 05/28/2009 7.95 2086.40 3.00 2078.45 11/05/2009 8.63 2086.40 3.00 2077.77 MW 5 05/13/2010 8.87 2086.40 3.00 2077.53 11/08/2010 10.24 2086.40 3.00 2076.16 05/17/2011 8.99 2086.40 3.00 2077.41 11/15/2011 10.58 2086.40 3.00 2075.82 05/17/2012 8.73 2086.40 3.00 2077.67 11/07/2012 •9.65 2085.60 3.00 2075.95 05/16/2013 8.14 2085.60 3.00. 2077.46 11/20/2013 9.33 2085.60 3.00 2076.27 05/22/2014 8.57 2085.60 3.00 2077.03 11/18/2014 9.04 2085.60 3.00 2076.56 05/13/2015 8.92 2085.60 3.00 2076.68 11/4/2015 8.12 2085.60 3.00 2077.48 05/04/2016 8.54 2085.60 3.00 2077.06' 11/09/2016 11.25 2085.60 3.00 2074.35 05/02/2017 8.63 2085.60 3.00 2076.97 11/08/2017 1 8.23 1 2085.60. 3.00 2077.37 Clement Pappas November 2017 Groundwater Monitoring Page 2 of 5 Hendersonville, North Carolina December 2017 Table 3 Current and Historical Groundwater Elevation Measurements Well Identification, Date Measured Depth to Groundwater (ft-BTOC) Top -of -Casing Elevation (feet) Top -of -Casing Height Above Ground Surface (feet) Groundwater' Elevation (feet) 05/15/2002 6.20 2061.90 3.00 '2055.70 11/05/2002 6.15 2061.90 3.00 2055.75 05/13/2003 5A3 2061.90 3.00 2056.47 11/04/2003 5.85 2061.90 3.00 2056.05 05/05/2004 6.00 2061.90 3.00 2055.90 11/09/2004 5.32 2061.90 3.00. 2056.58 05/17/2005 6.10 2061.90 3.00 2055.80 11/03/2005 6.01 2061.90 3.00 2055.89 05/24/2006 6A8 2061.90 3.00 2055.42 11/09/2006 5.71 2061.90 3.00 2056.19 05/18/2007 ' 6.50 2061.90 3.00 2055AO 11/13/2007 7.85 2061.90 3.00 2054.05 05/27/2008 7.01 2061.90 3.00 2054.89 11/18/2008 7.38 2061.90 3.00 2054.52 05/28/2009 5.63 2061.90 3.00 2056.27 MW-6 11/05/2009 5.74 2061.90 3.00 2056.16 05/13/2010 5.90 2061.90 3.00 2056.00 11/08/2010 5.99 2061.90 3.00 2055.91 05/17/2011 5.85 2061.90 3.00 2056.05 11/15/2011 6.14. 2061.90 3.00 2055.76. 05/17/2012 5.87 2061.90 3.00 2056.03 11/07/2012 6.05 2061.17 3.00 2055.12 05/16/2013 5.84 2061.17 3.00 2055.33 11/20/2013 5.96 2061.17 3.00 2055.21 05/22/2014 5.96 2061.17 3.00 2055.21 11/18/2014 5.82 2061.17 3.00 2055.35 05/13/2015 6.05 2061.17 3.00 2055.12 11/4/2015 5.18 2061.17 3.00 2055.99 05/04/2016 5.59 2061.17 3.00 2055.58 11/09/2016 7A2 2061.17 3.00 2053.75 05/02/2017 5.31 2061.17 3.00 2055.86 11/08/2017 4.80 2061.17 3.00 2056.37 Clement Pappas November 2017 Groundwater Monitoring Page 3 of 5 Hendersonville, North Carolina December 2017 Table 3 Current and Historical Groundwater Elevation Measurements ' Well Identification ` -Date Measured Depth to Groundwater. (ft-BTOC) Top -of -Casing Elevation (feet) . Top -of -Casing Height Above Ground Surface (feet) Groundwater Elevation (feet) 05/15/2002 10.90 2062.70 3.00 2051.80 11/05/2002 11.35 2062.70 3.00- 2051.35 05/13/2003 8.87 2062.70 3.00 2053.83 11/04/2003 10.78 2062.70 3.00 2051.92 05/05/2004 10.80 2062.70 3.00 2051.90 11/09/2004 9.70 2062.70 3.00 2053.00 05/17/2005 10.60 2062.70. 3.00 2052.10 11/03/2005 11.09 2062.70 3.00 2051.61 05/24/2006 11.27 2062.70 3.00 2051.43 11/09/2006 9.71 2062.70 3.00 2052.99 MW-7 05/18/2007 11.02 2062.70 3.00 2051.68 11/13/2007 11.76 2062.70 3.00 2050.94 05/27/2008 11.55 2062.70 3.00 2051.15 11/18/2008 11.63 2062.70 3.00 2051.07 05/28/2009 8.21. 2062.70 3.00 2054.49 11/05/2009 9.89 2062.70 3.00 t 2052.81 05/13/2010 10.44 2062.70 3.0& 2052.26 11/08/2010 11.12 2062.70 3.00 2051.58 05/17/2011 10.80 2062.70 3.00 '2051.90 11/15/2011 11.43 2062.70 3.00 2051.27 05/17/2012 8.91 2062.70 3.00 2053.79 11/07/2012 12.02 2062.86 3.00 2050.84 05/16/2013 10.29 2062.86 3.00 2052.57 11/20/2013 11.69. 2062.86 3.00 2051.17 05/22/2014 11.38 2062.86 3.00 2051.48 11/18/2014 11.25 2062.86 3.00 2051.61 MW-7R 05/13/2015 11.94 2062.86 3.00 2050.92 11/4/2015. 8.43 2062.86 3.00 2054.43 05/04/2016 11.08 2062.86 3.00. 2051.78 11/09/2016 12.63. 2062.86 3.00 2050.23 05/02/2017 10.13 2062.86 3.00 2052.73 11/08/2017 10.34 2062.86 3.00 2052.52 Clement Pappas November 2017 Groundwater Monitoring Page 4 of 5 Hendersonville, North Carolina December'2017 Table 3 Current and Historical Groundwater Elevation Measurements Well Identification Date Measured Depth to Groundwater (ft-BTOC) Top -of -Casing Elevation (feet) Top -of -Casing Height Above Ground Surface (feet) Groundwater Elevation (feet) 05/15/2002. 10.25 2061.40 3.00 2051.15 11/05/2002 10.35 2061.40 3.00 2051.05 05/13/2003 8.16 2061.40 3.00 2053.24 11/04/2003 10.23 2061.40 3.00 2051.17 05/05/2004 10.30 2061.40 3.00 2051.10 11/09/2004 8.90 2061AO 3.00 2052.50 05/17/2005 10.08 2061.40 3.00 2051.32 11/03/2005 10.61 2061.40 3.00 2050.79 05/24/2006 10.60 2061.40 3.00 2050.80 11/09/2006 9.40 2061.40 3.00 2052.00 05/18/2007 10.31 2061 AO 3.00 2051.09 11/13/2007 11.09 2061.40 3.00 2050.31 05/27/2008 10.83 2061.40 3.00 2050.57 11/18/2008 11.11 2061.40 3.00 2050.29 05/28/2009 8.25- 2061.40 3.00 2053.15 11/05/2009 9.22 2061.40 3.00 2052.18 MW-8 05/13/2010 9.88 2061.40 3.00 2051.52 11/08/2010 10.38 2061.40 3.00 2051.02 05/17/2011 10.27 2061.40 3.00 2651.13 11/15/2011 - 10.87 2061.40 3.00 2050.53 05/17/2012 8.03 2061.40 3.00 2053.37 11/07/2012 10.45 2060.80 3.00 2050.35 05/16/2013 8.58 2060.80 3.00 2052.22 11/20/2013 10.34 2060.80 3.00 2050.46 05/22/2014 9.79 2060.80 3.00 2051.01 11/18/2014 10.03 2060.80 3.00 2050.77 05/13/2015 10.34 2060.80 3.00 2050.46 11/4/2015 7.21 2060.80 3.00 2053.59 05/04/2016 9.84 2060.80 3.00 _ 2050.96 11/09/2016 11.16 2060.80 3.00 2049.64 05/02/2017 8.48 2060.80 3.00 2052.32 11/08/2017 8.73 2060.80 3.00 2052.07 05/13/2015 6.03 2060.23 1.44 2054.20 11/4/2015 2.89 2060.23 1.44 2057.34 MW 9 05/04/2016 5.53 2060.23 1.44 2054.70 11/09/2016 6.55 2060.23 1.44 2053.68 05/02/2017 3.99 2060.23 1.44 2056.24 11/08/2017 3.60 2060.23 1.44 2056.63 Notes: ft-BTOC feet below top -of -well casing Top -of -casing MW-5 through MW-8 top -of -casing elevations based upon a survey by Hill and Associates Surveyors, elevations. dated January 10, 2002, through May 2012. MW-2R and MW-4 top -of -casing elevations based upon differential level measurements made by Altamont Environmental, Inc., on June 26, 2006, through May 2012. The top -of -casing elevations for the monitoring wells were resurveyed on November 21, 2012, by Wes Cole Land Surveying. The top -of -casing elevations for MW-9 were surveyed on May 29, 2015, by Wes Cole Land Surveying. Groundwater Top of casing minus depth to groundwater elevations Clement Pappas November 2017 Groundwater Monitoring Page 5 of 5 Hendersonville, North Carolina December 2017 Table 4 Current and Historical Surface Water Analytical Results 0 WI `o E 0 oVI a y O 'o u° ;; C O a. _ ._ .. .O .0' E R . 12 6 L z. a r° (CFUs per Sample Name Sample Date (mg/L) (mg/L) 100 mL) (mg/L) (mg/L) (mg/L) (mg/L) 6/9/2016 (Prism) NA NA NA 0.74 NA NA NA SW71 6/9/2016 (Pace) NAL NA NA . .0.85 . NA NA NA (Upstream) 5/2/2017 2.7 4.7 580 0.64 64.0 <0.10 <0.050 11/8/2017 2.5 5.1 530 0.66 44.0 <0.10 0.091 6/9/2016 (Prism) NA NA NA 0.78 NA NA NA 6/9/2016 (Pace) NA NA NA 0.86 NA NA NA SW-2 (Downstream) L 5/2/2017 2.7 4.7 935 0.63 41.0 <0.10 0.052 11/8/2017 2.8 4.8 860 0.61 54.0 <0.10 0.094 Standards NL .230 < 200 NL NL NL NL Notes: 6/9/2016 (Prism) A sampling event was performed on June 9, 2016.One set of samples was analyzed by Prism Laboratories, and a second set of samples was analyzed by Pace Analytical Services. Standards From North Carolina Administrative Code, Title 15A, Subchapter 2B 15.0 Bold indicates concentration equal to or above the respective standard. <4.0 < indicates constituent concentration was not detected above the laboratory reporting limit mg/L milligrams per liter CFU coliform-forming unit mL milliliters NA not analyzed_ NL indicates no standard limit is set Clement Pappas Surface Water Monitoring November 2017 Page 1 of 1 Hendersonville, North Carolina -December 2017 �Ir�le'p �;�`iti!f ,—� 1^��': •,\� �"�, •'(,� % � :I _ it l a• •fit /• ,' ', / ~ A �, '�xly'�'. �a = : •� 11pi fain' e. \•. '' C rr 12 A, '--u Nir 4WO 41 � • 0 1 l � � ..� '.`�.� . y��� r�• `bra, � � ,—�' � � � l\ � .✓ d � '�� rut �t �- �`�f��_ r • , � �� R.. > > �•, �;,, ,� ' ,,f. �� ,�� ` ,1C1z4 '' ,pry t��.f 7��,r�-� 1ti �y ('`�i •r��`r'C F�_� � j���ti ;��. .. 80'rketey LEGEND: SOURCE(S): Basemap: USGS Topographic Maps, Fruitland and Hendersonville 0 2,000 ® Site Location Quadrangles, 1997 Parcel: Henderson County GIS 2016 Feet Publish Date: 2017/11/22, 11:54 AM I User: alesueur Filepath: \\ashevillet\asheville\Projects\Clement Pappas\Figures\GIS\Figure 1 - Site Location Map.mxd ANCHOR Figure 1 QEAC`�'" Site Location Map November 2017 Groundwater Monitoring Report Lassonde Pappas and Company, Inc. Pace Arialytical Services; LLC _ .. / . /.+.. ® �/+ Ve!'ll lN0001 2225 Riverside Dr. - Asheville, NC 28804 wwwpacelabs.com (828)254-7176 CERTIFICATIONS:. Project: Clement Pappas 11/8 Pace Project No.:. ,' .92362594 Charlotte Certification IDs. 9800 Kincey Ave. Ste.100, Huntersville; NC 28078 . South Carolina.Certification #: 9900..6001 Lomisiana/NELAP Certification # LA170028 Florida/NE LAP. Certification M, E87627 North, Carolina Drinking Water Certification #: 37706: Kentucky,UST Certification #: 84. North Carolina Field. -Services Certification M 5342 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #:.12 Asheville Certification IDs 2225 Riverside Drive; Asheville,. NC 28804.. .. -North Carolina Wastewater Certifcation #: 40 . Florida/NELAP'Certification M E87648 ::. South Carolina -Certification :M 99030001 . Massachusetts Certification M M-NC030 - Virg inia/VELAP:: Certification'#i 460222 North Carolina Drinking: Water Certification M .37712 REPORT OF LABORATORY ANALYSIS.. - l This report shall not be reproduced, except in full, _ without the written consent of.Pace Analytical Services, LLC. Page-2 of'44 Pace Analytical Services;.LLC . aceAn.. ®' . n al q1 2225 Riverside Dr. ..: . _ ..• Asheville, NC 28804 wwwpacela6s:com (828)254-7176 .. -.'. SAMPLE ANALYTE COUNT` Project: -Clement Pappas 11/8 . . Pace Project No:: .. .92362594 Analytes Lab.ID Sample ID - Method Analysts. Reported Laboratory 92362594001 MW-4. SM 62006 - , .GAW: .63' PASI-G SM 2540C MJP 1 PASI-A SM 9222D.. - KDF1 1 PASLA. . EPA 350.1 1993 Rev 2.0 AES2 1 - PASI A - - EPA353.2 CJH1 - 1_ . PASTA EPA365.1 CJH1 1, PASI-A' SM 4500. CI-E : MDW 1 PASI-A . SM 53106 _ . KDF1 1 • ,PASIA .'' 92362594002 ;, . MW-S SM 62006 GAW 63'. PASI-C ... ;, SM 2540C . MJP 1 PASI=A SM 9222D KDF1: 1 PASI-A ... . " EPA350:41993 Rev:2.0 AES2 1 PASI-A EPA 353.2. CJH1 1 ' PASI A _.. EPA 365.1 CJH1 1.. PASI-A .. SM4500-CI-E. MDW 1 '.PASI-A- .. " SM 53108 KDF1 . 1 PASI-A . . 92362594003 MW-6 .. SM 6200E GAW " . 63 PAS[-C. . SM 2540C MJP. 1 ' PASTA' . °. SM 9222D KDF1 1 PA$I A .. EPA 350.1 1993 Rev-2.0 AES2 1 PASI-A EPA353..2 CJH1 1" :. PASIA , .. EPA365.1 :• ". CJH1 1 PASTA . ` SM 4500=C.I-E. MDW : 1 .PASI-A SM 53108 KDF1 1 PASI-A .. 92362594004 MW-7R SM 6200E GAW .' .63 PASI=C SM 2540C MJP- 1 PASI_A SM 9222D KDF1 1 PASI-A . .:. .. EPA 350:1 1993-Rev 2.0 : AES2 1 PASI-A EPA353.2 CJH1 1 -PASI-A . EPA365.1 .: CJH1 .1 PASILA SM 4500=CI-E MDW: 1 PASI-A ... • SM 5310B KDF1. 4 PASIA . 92362594005 MW-6 SM 6200E GAW : 63 PASI C SM 2540C MJP 1. PASI-A . SM 9222D .' KDF1 1 PAS] -A, EPA:350.1 1993 Rev 2.0: • ,AES2.. T PASI-A - EPA353.2:- CJH1 1. .' PASIA - "REPORT OF LABORATORY ANALYSIS. . This'reportshall not be reproduced; except in full, without the written c i L onsenfof. Pace Analytical $erv'ces, L C. Page 3 of 44 Pace Analytical Services; LLC . j ® �CCAI �1 alWical 2225 Riverside Dr._ . . Asheville, NC 28804 . . wwwpacelabs.com• (828)25477176 SAMPLE-ANALYTE COUNT. Project: Clement Pappas 11/8 Pace Project No::. 92362594 - Analytes -. Lab:ID 'Sample ID Method Analysts, Reported ..Laboratory EPA365.1 CJH1:. 1 PASI A . . SM 4500-CI-E MDW, - 1 PASI-A SM 53106 .. KDF1 : 1 :. PASI A .. 92362594006 MW-9 . .... SM 6200B GAW 63. PASI-C .. SM 2540C.. MJP 1 PASI=A SM 9222D . KDF1:: 1 PASI-A ... . EPA 350.1 1993 Rev 2.0 AES2 - 1 PASI-A EPA : CJH1 1 PASI A : • EPA 365.1 CJH1 1. " PASI- A .. SM 4500_ CI-E MDW .. 1 PASI=A • , .' . SM 53108 '� KDF1:: 1" :. PASI A .. 92362594007 . ' SW-1 SM 6200E GAW 63 PASI-C SM 2540C SLB: 1 PASI A" . SM 9222D KDF.1 1 _ PASI-A . EPA 350.1 1,993 Rev 2:0 .. AES2 _ . 1 PASI A EPA353.2 CJH1: 1 - _: PASI A . : EPA365.1: :CJH1- - 4 PASI-A . SM 4500-0=E. • MDW' 1 :.PASI A' - $M 5310E ' .. KDF1 1.. _ PASI-A ._ 923625§4008 SW-2 ' . SM 6200B GAW .63 ..PASI=C SM 2540C -SLB :. 1.. PASI-A . ". SM 9222D KDF-1 1 PASI=A EPA 350.1 1993.Rev 2.0 AES2 1 - PASI A _ . EPA 353.2 CJH1 1. PASI-A .. EPA365.1 _ CJHl' 1 PASI=A SM 45007CI-E MDW : " 1 PASI-A SM 531OB KDF1 1 PASI-A . :- 92362594009 :Trip Blank . SM 620013 ` GAW 63 PASI-C REPORT OF LABORATORY ANALYSIS . . This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services,Ut. -" .. Page 4 of 44 Pace Analyticil,Servicesi L.LC dAnjOcal' 2225 Riverside -Dr.. -Asheville, NC 28804 wwwpacqlabs.FOM (828)254-7176 ANALYTICAL RESULTS. Project: Clement Pappas 11/8 Pace Project No.:. .92362594. Sample: AWW-4 Lab ID: M36.2564001 Collected: 11/08/17 13:45. ater Received: A 1/08/17 15:16 Matrix:. Parameters Results. Units Report Limit DF Prepared_'. Analyzed CAS. No. Qual 620.0B. MSV Analytical Method:'SM .6200B Benzene -ND . ug/L,. .0.50 1 11/15/17 13:48 .71743-2 Br6mobenzene ND -ug/L 0.50 1 11.115/1718:48 .108-96-1 Bromochbirometh4ne'. N. D ug/L 01.50. 1 11/15/17.13:48' 74-.97'5. Bromodichlbrorhethane. -ND ug/L 0.50 11/115M 1148 75-2T"4. Brom6form ND 0;50 1-- .11/15/1.713:48, 75-25-2 Brofn6fnethan6 -ND ug/L,. 5;0 1' 11/15/17 13:48 74-83-9 'n-Butylbenzene' ND: ug/L .0;50 1 :11/15/17.13:48 104-51-8. sec-Butylbenzene ND uglL 0.50 1 11/15/17 13:48 135=98T8 tert*Butylbenzene ND ug/L. 0.50 11/15117 13:48 98-06-6 Carbon tetrachloride ND." bgl. 0.50. 1 11/1511713:48, 56,23-.5.. Chlorobenzene ND . ug/L -0.50 1 11/15/1.7 13:48 - 108 90-7. -Chloroethane �ND' ug/L -1.0 1 11/15/1718:48 '75-013-3. Chloroform, ND ud/L 0.50 1 11/15/17 13:48 67-66 73 Chlo'ro'methane'- - -ND' ug1L .1-.0 1 11/15/1713-48 74-8773 .2-ChlorotQluene ND ug/L 0150 11/1511.713:4a -95-49-8, 4'Chl6rotoluene -ND :'ug/L 0.50 1 11/15/1713:48.10643-4:* 1,2-Dibromo-3-6hloropropane. ND: ,ud/L- Igo A 11/15/17.1348 i96-1279 Dibromoch lorom ethane i ND -uglL.11./15/47 13:48 -124w48-1 1,2-Dibrdmoethane (EDB) - ND ug/L 0.50- 11/15/1-7 13:48 106-93-4: DibromomEithane ND. ug/L. -0.50. .'.11/.15/17113.:48 74-95-31., 1,2-Dichlorobenzene- ND. ug/L,., 1 11115/1.7,13:48 -95-50-1 .1 8-bichlorobenzene ND -ud/L 0.50 11/15/17 13:48 -541m73-1- 1,4-Dichlorobenzene ND ug/L .0.50 1. 11/15/17 13:48 106-46-7 Didhlorodifluoromethane - ND' ug/L 0:60 1 -1 -48 '11/15/17 .3. 75-71-8 lil-Dichloroethane ND ug/L' 0:50 V 11 /15/1� 13.48.75- 34-3 1 Mibhloroethari6 ND ug/L. . 0.50 1 11 /15/17 43:48 - 10M6-2: M-Dichloroethene.' ND: udil- a 0.50 1 75-3574 - -ciS.-1,2-Dichlorb6thene ND, ug/L -0.50 1 .11/15/17 13:48 '156=59T2 -trans-1,2-Qichlorbethen6 ND ug/L 0.50 1 11/15/1-7 13:48 156-60-5: 1;27pidhloropropane' ND ugl. 0.50- 1 ''..11/15/17 13:48. 78-87-5 .1,3-Dichloropropp6q. ND . ug/L . 0.50 11 11/1511.7 13:48..142728-9 2,2-Dichloropr6pqrje 'ND' ug/L 0.50 1' 11/15/1713:48 .594-90-7- 1 1-Dichloropropene ND ud/L .0.50 1 11/15/17 13:48- 563 -58-6 CiS71,3-Dichlorqpropene ND* ug/L. 0.50. 1 IIMJ17-1148 10061--01-5 trans-1,3-Dichloropropene ND ...... ug/L 0.50 1 .11/15/17 13:48 100611-02-6 Dilsopropyl ether' ug/L 0.50 1- -1 11/15/17 13:48 10&-20-3: Ethylbenzene ND: -ug/L -0;50 .1 111.1 5/1T 13:48'.. 1 004f-4 Hexachibro-1,3-butadi.e.ne ND ugl 2:0. 1 11/15/17 13:48 .87-6$-3. ls,opropylbenzqn.e (6umene) ND :'ug/L, 0.50 .1 11/15/17 13:48 '98-82-9 Methylene Chloride ND.. OWL 2.0. 1 .11/15/17 13:48- 75-09-2 Methyl-tert-butyl ether ND. -.ug/L .0.50. 1. . 11/15/1713:48 -163.4-04-4 .-Naphthalene ND -ug/L 2.0 1 '11/15/1.7 18:48 91-20-3 n-Propyl6enzene ND ug/L 0.60 1. 11/15/17 13:48 -103-65-1 Styrene ND ug/L. 0.50 1 11/15117 13:48 100-42-5 1,1,1,:2-Tetmchlor6ethane ND ug/L 0:50 1 .11/15/17 13:48 '630-20-6. 1,1,2,2-Tetrachloroethane ND :'ug/L' 0.50 1. 11 /15/17 .13:48 79-34-5 TetrachloroOthene ND: ug/L 0.50 1 -48 11/15/17 13. -127m18 4, Date: 11 M 7/201.7 01:59 OM REPORT OF LABORATORY ANALYSIS* This report:shall not be reproduced; except . in full, without the written consent of Pace Analytic al Services, :L LC. Page 5 of 44 „ Pace AnalyticaLServices; LLC . /+Q /�►7 / /"+: ®' dCi$/'111�f�V01 2225 Riverside Dr.' " " Asheville, NC 28804 . . vAmpacelabs.com" (828)254-7176 ANALYTICAL RESULTS Project; .. Clement Pappas 11/8 Pace Project No.:.' - .92362594 Sample; .MW-4 " : Lab ID:.92362594001" :Collected:::11/08/1713:45 Received: ,11/08/1715:10 -Matrix: Water " Parameters .:.. Results'. Units - Report Limit DF Prepared-:. Analyzed CAS No.-' .. Qual 6200B.MSV : Analytical Method: SM 0200B Toluene . ND ug/L' .. ... ..0.50, .:1. • `. "' ... 11/15/17 13:48 108-88-3.. " 1,43-Trichlorobenzene ND ug/L 2.0 . • 1 1Ill 5/17 :13:48 : 87-61-6 . 1;2kTrichlorobenzene " : ND ug/L 2.0 " ..1 `. 11/15/1713:48 .1.20-82.'1 1,1,1-Trichloroethane" :'... `, : ND ug/C• . 0:50. 1 ". 11/15%1T13` -71-55.-6: ..: 1,1,2=Trichloroethane ." ND :ug/L 0.50 . 1 "". `' 11/15/1.713.48. 79-60-5 Trichloroethene ND : ug/L _ 0.50 1 11/15/1713:48 79-01-6' Trichlorofluoromethane ND ug/L 1.0 ..1 11115/17.13:48'.75-69-4 1,2,3-Trichloropropane. ND .":.:" uglL : 0.50" 1 _ 11,/15/17 13:48 .96--6183--6 1;2,4-Trimethylbenzene` . 7 13:48 1/1_/1 954. 1;3,5-Trimethylbenzene' ND:' ug/L.: 0.50 1 -: 11/15/17 13:48- 108=67-8. Vinyl chloride ND.- ug/L-., 1.0 1.. 11/15/17 13:48 75-01-4 m&p-Xylene ND ,"ug/L - 1.0 ." 1 11/15/17:13:48 :179601-234 o-Xylene. ND ug/L _ 0.50 1 . ' 11/15/17 13:48 " 95-47-6. Surrogates' . 1 2-Dichloroethane d4 (S) 103• % "' 70-130 1 "- : 11/15/17.13`.48 .17060-07-0 . 4=Brom6fluorobenzene (S) _ 97 % - ". 707130 1 .. 11/15/17.13:48. 460-0074 Toluene708 (S);.; 101" ;. % . 70.130- ..1 " .:. ". 11/.15/17.13:48 2037-2675 254.00 Total Dissolved.Solids "" ' .. _ Analytical Method: SM 2540C." " . .. Total Dissolved,Solids 135: mg/L.. 25.0. 1 :: :. 11/10/1711:21 MB10 9222D.Fecal:Coliform AVL Analytical,"Method::SM 9222D.. . Fecal Coliforms" ND., : CFU/100 ML .: • • "2.0 "-. 2 . ." .11/08/1.716:33 350:1 Ammonia Analytical Method: EPA"35011 1993 Rev 2.0' Nitrogen, Ammonia ND mg/L : ," 0.10 1" 11115/1712:23' 7664-41.-7 353:2 Nitrogen,.N021NO3 unpres... " Analytical.Method: EPA 353;2 ., Nitrogen,. Nitrate " " . ', . " . ".::. 1.2 . mg/C"" . ." .. 0.020. ,.1:: 11/09/17 02:37 ' .365.1 Phosphorus, Total_' Analytical Method:.EPA365.1' Phosphorus : 0:070 : mg/L.'. 0:050 . "1 11/14/17 03:10 7723-14-0 4500.Chloride" Analytical Method: SM 4500-CI-E' Chloride " " .73 .. mg/L "_ 1:0 1" 11/69/17 23:03 : 16887-00-6 5310B TOC Analytical Method: SM.5310B. Total -Organic Carbon'. :. , 3.0 " mg/L 1.0 1 """ 11/16/1700:36. 7440-44-0• .._ REPORT OF LABORATORY ANALYSIS.. This report shall not be reproduced; except in full, Date:"11/17/201.7.01:58 PM without "the writtenconsent of.Pace Analytical Services,LLC. " "" Page,6 of:44 " Pace Analytical Services; LLC �CQ r1 ® 2225 Riverside Dr. GAI alift0I Asheville, NC 28804 wwmpace/abs.pom (828)254-7176 ANALYTICAL RESULTS Project: Clement Pappas 11/8 Pace Project No.: 92362594 Sample: MW-5 Lab ID: 92362594002 Collected: 11/0811711:47 Received: 11/08/17 15:10 Matrix: Water Parameters Results Units - Report Limit DF - _ Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene ND, - - ug/L 0.50 1 11/15/17 19:16 71-43-2 Bromobenzene ND ug/L 0.50 1 11/15/17 19:16 .-108-86-1 Bromochloromethane-. ND ug/L 0.50 1 11/15/1719:16 74-97-5 Bromodichloromethane ND ug/L 0:50 1 1.1115/171.9:16 75-27=4 Bromoform ND' ug/L 0.50 1 11/15/1.719:16 75-25-2 Bromomethane ND ug/L - 5:0 1 11/15/17 19:16 74-83-9 n-Butylbenzene ND ug/L 0.50 .1 11/15/17 19:16 104-51-8, " see -Butyl benzene ND ug/L 0.50 1 11/15/17 19:16 -135=98-8 .tert-Butylbenzene ND ug/L 0.50 1 11/15/17 19:16 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 . 11/15/17 19:16 56-23-5' Chlorobenzene ND ug/L . 0.50 1- - _ . 11/15/17. 19:16 108-90-7 Chloroethane . ND ug/L .1.0 1 11/15/17 19:16 .75-00-3 , Chloroform, -,ND ug/L 0.60 .1 11/15/1719:16 67-66=3. " Chloromethane. ND ug/L.. 1:0 1 11/15/1719`16 74-87-3. 2-Chlorotoluene ND ug/L 0.50 1 • 11/15/1.719:16 95-49-8 4-Chl6rotoluene ND ug/L _ 0.50'_ 1 11/15/17 19:16 106-43-4 1,2-Dibr6mo-3-chloropropane ND' ug/L 1.0 .1 11/15/1719:16 96-12-8 Dibromochloromethane ND ug/L . 0.50 1 11 /15/17 19:16 .124-48-1 1;2-Dibromoethane (EDB) ND ug/L . • 0.50 1 - 11/15/1•7 19:16 106-93-4 _ Dibromomethane . ND ug/L 0.5.0 1 11/15/17 19:16 . 74-95-3 1,2-Dichlorobenzene ND . ug/L 0.50 1 11/15/17 19:16 •95-50-1 " 1,3-Dichlorobenzene . ND ug/L 0.50 1 11/15/17 '19:16 541-73-1 . 1;4-Dichlorobenzene ND ug/L 0.50 1 11/15/17 19:16' .106-4677 Didhiorodifluoromethane ND ug/L.. '0.50 1 ' 11/15/17 19:16 75=71=8 1;1-Di6hlor6ethane ND. ug/L 0:50 1 11/15/17 19:16 75-34-3. 1,2-Dichloroethane _ ND ug/L . 0.50 1 11/15/17 19:16 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/15/.17.19:16.75=35-4 cis-1,2-Dichloroethene 4.4 uglL : 0.50 1 11/15/17 19:16 156-59-2 traris-1,2-Dichloroethene ND ug/L 0.50 1 11/15/17 19:16 156-60-5. 1;2-Dichloropropane ND ug/L 0.50 1 11/15/17 19:16. 78-87-5 1,3-Dichloropropane ND ug/L .. 0.50 1 11/15/17 19:16 142-28-9 "_ 2,2-Dichloropr6pane . ND ug/L 0.50 1 11/15/17 19:16 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/15/17 19:16 563-58-6 cis;1_,3-Dichloropropene ND ug/L- 0.50 1 11/15/17 19:16 10061-01-5 trans=1,37Dichloropropene . ND ug/L 0.50 1 11/15/17 19:16 10061-02-6 • - Diisopropyl;ether ND ug/L _ 0.50 1.. 11/15/17 19:16 108-20-3 Ethylbenzene NDr ug/L 0:50 1 11/15/17.19:16-.100-4.1-4 Hexachloro-1,3-butadiene ND uglL . 2.0 1" 11/15/1710:16 87-68-3 Isopropylbenzene (Cumene) ND uglL 0.50 1 11/15/17 19:16 98-82-8 - . Methylene Chloride ND. ug/L 2.0 1 11/15/17 19:16 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1. 11/15/17 19:16 1634-04 4 Naphthalene ND ug/L 2.0. 1 11/15/17 19:16 .91-20-3 -' n-Propylbenzene ND ug/L 0.50 1 11/15/17 19:16 103-65-1 Styrene ND ug/L 0.50 1 11/15/17 19:16 100-42-5 1;1,1,27Tetrachloroethane ND ug/L 0.50 1 11/15/17 19:16 '630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/15/17 19:16 79-34-5 Tetrachloroethene 35.9 ug/L 0.50 1 11/15/17 19:16 . 127-18 4 Date: 11/i7/2017 01:58 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 44 Pace Analytical Services; LLC . ® aceAnalXieal. _ 2225 Riverside Dr. Asheville, NC 28804 wwwpacelabs.com (828)25477176 ANALYTICAL -RESULTS Project: -Clement Pappas 11/8 Pace. Project No.:. 92362594 Sample:.MW-S- '. '.Lab 10:.92362594002 Collected::-11/08/1711:47. Received:. 11/08/1715:10. Matrix: Water Parameters Results:. Units Report Limit DF Prepared,, . Analyzed CAS No. .. Qual .:: 6200B.MSV . Analytical Method:'SM 62006' Toluene ND ug/L. .. 0.50. .1 .. 11/15/1.719:16 108-88-3.'.'. ,. 1,2,3-Tri6hlorobenzene NDug/L 2.0 : 1 ' 11/15/17:19:16 .87-61-6 , 1,2,4=Trichlorobenzene ND ug/L ' 2.0 ..1 11/15/17,19:16 .120-82=1 1,1,1-Trich1oroethane ."' ND ug/L.. 0:50 1 '1.1/1511719:16 71-55=6. '. 1;1,2-Trichloroethane ND , `_ :ug/L 0:50 . 1 11/15/1719:16 .79=00-5 Trichloroethene 4.6 ug 0.5.0 1` 11/15/1719:16 79-01-6 Trichlorofluororhethane ND ug/L 1.0 ..1 ' 11/15/17.19:16 .75-69-4 1,2,3-Trichloropropane. ND ug%L : 0.50 1 11/15/17 19:16 :.96-18=4 1;2 4-Trimethylbenzene ..a ND . ug/C . 0.50 1- .' 11/1b)17 19:16 95-63-6 :. 1;3,5-Trimethylbenzene ND. : ' ug/L, . 0.50 1 11/15/1719:16. 108=67-8- Vinyl chloride ND,- - ug/L -: 1.0 - 1 _ . 11/15/17 19:16 75701-4 rn&p-Xylene _ _ ND - ug/L .1.0 : 1 11/15/17;19:16 . 179601-23-1 o=Xylene.. ND ug/L :. 0.50 1 11/15/1719:16.95-47=6 Sgrrogates 1,2-Dichloroethane-d4 (S) 103. % 70-130 1 11%15/17.19`.16 : 17060-07-0 . . 4=Brom6fluorobenzene (S) 96 % : 70;130. 1 11/15/17 :19:16 ' 460-00-4 Toluene-d8 (S):. 95: % : 70-130 1 : 11/15/17,19-16 .2037-26-5 2540C Total Dissolved.Solids Analytical Method::SM 2540C: .. - Total Dissolved Solids 84.0_ ` mg/L 25.0 , 1: :: 11/10/1711:21 MBib 9222D.Fecal Coliform AVL Analytical., Method: SM 9222D. Fecal Coliforms. 188.'-CFU/l00 mL 1.0- .1 .11/08/17 15:54. u1 - 350.1 Ammonia Analytical Method: EPA 350:1 1993 Rev 2.0 Nitrogen,.Ammonia ;. /L ND m g 0.10 1 �` 11/15/1712:24' 7664-41-7 :. 35$:2 NitYogen,.N021NO3 unpres.. Analytical. Method: EPA 353:2'. Nitrogen,, Nitrate ND. m9/C .... 0:020 . 1 11/09/17 02`.34 .365.1, Phosphorus, Total.: AnalyticalMethod:.EPA 365.1 . Phosphorus : 0.086, mg/L . _ 0:050 . 1; 11/14/17 03:19. 7723-14-0'.: . 4500.Chloride Analytical Method: SM 4500-Cl-E . .. Chloride - 12.8 '.. :mg/L : 3.0' 3 11/09/1723:04, 16887-00=6 5310B TOC . ', . ..: Analytical Method: SM.5310B. Total Organic Cairbon : 6.7 mg/L 1.0 1_ 11/1b/17 07:22 7440-44-0- _. E R PORT"OF LABORATORY ANALYSIS This report shall not be reproduced; except in full, Date: 1Ill 7/201.7. 01:58 PM without the written consent of Pace Analytical Services, LLC. . Page.8 of 44 Pace Analytical Services, LLC . aV�/'L�ia1 �V�1, 2225"Riverside " Asheville, NC 2880404 . . mW.pacelabs com" (828)25477176 ANALYTICAL RESULTS, Project:. '" Clement Pappas 11/8 Pace, Project No.: _ 92362594 Sample:.MW-6 " : Lab 10: 92362594003 ` Collected:: "11/08/1712:30 -" Received:. 11/08/17 15:10 • Matrix: Water Parameters 'Results Units ' Report Limit DF Prepared Analyzed CAS No. Qual. 6200B.MSV : Analytical Method:"SM 6200B Benzene ND ug/L,." :. 0.50' ..1 11/15/1714:05 71-43-2 Bromobenzene " ND . "ug/L . 0.50 , .: • 1 ' 11/15/17 14:05 :108-86-1 . Bromochloromethane: NO ug/L - 0:50 1 " 11/15/17 14:05 74-97-5. Bromodichloromethane• .: ND , .' ug/L.. 0.50. 1 - - 11115/17 14:05 75-27'4. Bromoform .. ND ug/L 0:50 . '" 1'.. " . 11/15/17 14:05 " 75-25-2 Bromomethane ND 'ug/L . 5:0 1; 11/15/17 14:05: 74-83-9 n-Butylbenzene ND ug/L 0:50.".1 11/15/1714:05.104-51-8, sec Butylbenzene ND " , ".: ug/L : 0.50 ; 1 11/15/17 14:05 ;.135=9878 tert-Butylbenzerie :_ NO ug/L v., 0.50" 1. 11/15/17 14:05 -98-06-6 Carbon tetrachloride "'_ ND. ug/L" ." 0.50 1':; "" 1105/1714:05 56-23-5'. Chlorobenzene NO ." " ug/L'.; -: 0.50 1 _ _ " " 11/15/17 14:05 108-90-7 " Chloroethane . ND _ _ ug/L _ 1.0 " . 1 11/15/17.14:05 .75=00-3 - . .. Chloroform NO ug/L 0.60 " ..1 11/15/17 14:05 67-66=3 Chloromethane.: NO ug/L- - 1:0. 1 ' 1.1/15/17 14:05 74-87=3.-: . 2-Chlorotoluene' ` ND :ug/L 0:50 '" 1 ,; :: 11/15/1714:65 '95-49-8 4-Chl6rotoluene NO ug/L" . _ "_ 6.50 1 11/15/17 14:05 10643-4 ropropne. g 11/15/17.14:05.9612-81,2-Dibromo-3-chlo Dibromochloromethane ND - , .: ug/L : - -0.50 :. 1 11/15/17 14:05 ;124=4871 : 1,2-Dibromoethane (EDB) NO - " ug/L.. " .. 0.50- J. 11/15/17 14:05 Dibrornomethane- . " NO. ug/L:. " 050. 1 :: 11/15/17 14:05. 74-95-3" . 1,2-Dichlorobenzene. ND. ug/L." 0.50 1,. 11/15/1714:05.95-50-1 1;3-Dichlorobenzene :. ND ug/L 0.50 .• 1 " ." " 11/15/17,14:05 :541=73-1 _ .. 1,4-Dichlorobenzene :. " NO ug/L - 0.60 ..1 11/15/17.14:05 .106-46.-7 Dichlorodifluoromethane.. ND' ug/L. 0.50. 1 " " ' 1.1/15/17-14`.05 75-71-8 1;1-Dichlor6ethane : NO ug/L _ 0:50 1 . " 11/15/1.7 14:05 '75-34-3 ":. " 1,2-Dichloroethane _ = NO ug/L'. 0.50 1 11/15/17 14:05= 107-06-2 1,1-Dichloroethene. - ND ug/L 0.50 ..1 11%15/17.14:05.75=35-4 cis-1,2-Dichloroethene ND -ug/L : 0.50 1 11./15/1714:05 :.15&5.9-2 -trans-1,2-Dichloroethene. " ".". - ND ug/L.. " 0.50 1_ 11/15/17 14:05 156-60-5 1;2,Dichloropropane "' . _ _ -: ND.: .ug/L 0.50. T:; 11/15/1714:05' 78-87-5 - 1,3-Dichloropropane.. ND ug/L'." 0.50 1.. 11/15/17 14:05 142-28-9 2,2-Dichloropropane ... " : ND ug/L 0.50 : 1 11/15/17.14:05 :594-20-7 . I J-Dichloropropene :. ND ug/L 0.50 " ..1 11/15/17 14:05 663-58.-6 cis- 1,3-Dichloropropene • ND' ug/L:. 0:50_ 1 '11/15/17 14:05 10061-01-5 :trans=1,3-Dichloropropene ND , ug/L 0:50 . -1 . " 11%15/17"14:05 -10061-02-6 'Diisopropyl'ether ND ug/L'.. • 0.50 . " 1; 11/15/17-14:05 108-20-3 Ethylbenzene ND .. " •'ug/L 0:50 ."-1 11/15/17 14:05 .10041-4" Hexachloro-1,3-butadiene ND ugl- : 2.0 :: 1 11/15/17.14:05 :.87-68=3 - .Isopropylbenzene"(Cumene)' ND D. ug/L " 0.50 1 _ 11/15/17 14:05 " 98-82-8 " Methylene Chloride" NO. ug/L,". "' _ ,: 2.0. • ' 1'; 11/15/17 14:05 75-09-2" . -Methyl-tert-butyl ether .'.: ND. ug/L.'.; 0.50' - 1 • . 11/15/17 14:05 1634-04-4_ - Naphthalene ND' "- ug/L 2.0. 1 11/15/17.14:05 " 91-20-3 _ . .. n-Propylbenzene. - ND,. -:. ug/L -. 0:50 -1 11/15/17 14:05 .103-65-1 Styrene;- . NO . ug/L:. .. 0.50. 1 ;, .. 1.1/15/1714.05 100-42-5 . " •,': 1;1,1,2-Tetrachlor6ethane' .. "", : NO ug/L 0:50 1 "11%15/1714:05 630-20=6: 1;1,2,2-Tetrachloroethane NO. .ug/L'. . "; 0:50. 1 ; 11/15/17.14:05 79-34-5 Tetrachloroethene ND ug/L .. 0:50 1 11115/17.14:05.127-184. REPORT OF LABORATORY ANALYSIS'.- - This* report not be reproduced; except in full, Date:11/17/2017 01:58 PM without'the written consent'of.Pace Analytical Services, L.I.C. Page.9 of 44 Pace Analytical Servicesi LLC . 2225 Riverside Dr. GIVGAIl�I�Vt��, Asheville NC28804 wwwpace186s.com .. (828)254-7176 ANALYTICAL RESULTS.. , . ' . Project: Clement Pappas 11/8 Pace Project No.,: ..92362594- Sample:.MW-6. .• .' '.Lab ID:.92362594003 Collected::•11/08/1712:30, Received:. 11/08/1715:10. -Matrix! Water Parameters Results : Units • 'Report Limit DF Prepared_ .. Analyzed . CAS. No. .. Qual 620.0B. MSV : Analytical Method: 'SM 6200B " Toluene ND ug/L 0.50: 1 11/15/17 14:05 :1 08r88-3 12,3-Tri6hlorobenzene , ND A& 2.0. . -1 ' 11/15/17.14:05 ' 87-61-6 . 1,2,4=Trichlorobenzene ND ug/L ' 2.0 1 11/15/17.14:05' .120-82=1 1,1,1-Trichloroethane :.. ND ug/L:. 0.:50.. '1 '1.1/15/1714.05 71 55-6: 1,1,2=Trichloroethane ND . ."ug/L ". 0:50. 1.. .11/15/1714.05 79D0-5 Trichloroetherie ND Ug/L . '• r 0.50' 1; 11/1511`7.14:05 79-01-6 Trichlorofluoromethane ; -.ND:- ug/L '. 1:0 .:1 11/15/17:14:05:75=69 4 - . 1,2,3Jrichloropropane. ND ;' ug/L' : 0.50 ". 1• 11./15/1714:05 ;96-1$=4. 12,4-Tiimethylbenzene ND . ,ug/L.. 0.50 ,1 11/15/17 14:05 -95-63-6 1;3,5-Trimethylbenzene ND:' ug/L, . - "' 0.50: T. ,11/15/1714:05. 108=67--8. Vinyl chloride ND ug/L .; - 1.0 1 .' 11%15/17, 14:05 _75 01-4 m&p-Xylem ND' vg/L 4.0. 1 -11/15/17.14:05.179601-231 o=Xylene. ND ug/L ' . 0.50 1 11/15/17 14:05 95 47=6. Sgriogates . 1 2-Dichloroethane-d4 (S) 104 % 70-130 1 " 11%15/17 -14:05 17060-07-0 4=Bromofluorobenzene (S,) 97 % 70-130 : 1 11/15/17,14:05. 460-0674 Toluene-d8 (S); ; 100 % : 70=130 1 11L15/1 ' 14:05 _2037-2675 -2540C Total Dissolved. Solids Analytical Method: SM 2540C Total Dissolved Solids 66.0 mg/L.: - 25,0. 1 11/10/17 11:22 : MBIO 9222D.Fecal Coliform AVL Analytical. Method::SM-9222D Fecal'C.oliforms .744, CFU/100 ML -1.0 9 11?68/1.7 15:54. 350:1 Ammonia Analytical Method:'EPA 350.1 .1993 Rev 2.0 Nitrogen, Ammonia ND mg/L - 0.10 1 11%15/17:12:26. 7664-41-7 353.2 Nitrogen„N021NO3 unpres." .. Analytical. Method: EPA 353:2 Nitrogen,. Nitrate - - 0:045 mg/L ' ' 0.-020 1 11/09/17 02.35• 365:1; Phosphorus, Total AnalyticaLMethod: EPA 365:1 'Phosphorus ` ND' ing/L . - • 0:050 -: -1; 11/14/1703:20 7723-1-4-0 4500.Chloride. Analytical Method: SM 4506 CI E' Chloride 11,1 mg/L 1:0 1 11/09/1723:06 16887-00=6 5316B TOC Analytical Method: SM 5310B Total Organic Carbon ;. 1.4 mg/L - T 0 1 11/15/.17 07:57 7440-44-0 E R PORT OF LABORATORY ANALYSIS".. Ttiis'report shall not be reproduced; except in full, Date: 11/17/201.7 01:58 PM without the written consent of. Pace Analytical Services, LLC. : Page-10 of 44 Pace Analytical Services; LLC aceAQ.,, ® nalXii✓a!_ 2225 Riverside Dr. Asheville, NC 28804 . . www.pacelab&com (828)254-7176 ANALYTICAL RESULTS'. Project: Clement Pappas 11/8 Pace _Project No.:. " ,92362594 -Sample: .MW-7R : ..Lab I0:.92362 *64 Collected:: 11/08/17 11:12. ,` Received:. 11/08/1715:1t) Matrix: Water Parameters :. Results . Units Report Limit DF Prepared. _' . Analyzed CAS. No.- Qual 62006'-MSV : Analytical Method: SM 6200B '. Benzene ND . ,ug/L'.; 0.50 1 .' 11/15/1714:22 71-43-2' Bromobenzene ND ug/L ,; 0.'50 : 1 -11115/17:14:22 .108-86-1 _ .. Bromochloromethane:. ND ug/L 0.50 4 11/15/1714.22 74-97=5. Bromodichloromethane. :. ND' uglL.. 01.50 -1 1//15117 1422 75 27=4. Bromoform ' '.: ND :.ug/L 0:50 1'-': 11/15/17 14:22 75-25-2 Bromomethane - ND : ug/L. 5:0 . 1:. .. 11/15/17.14:22. 74-83-9 : .. n-Butylbenzene ND:-. ug/L: .0.50 ..1 11/15/.17.14:22'.104-51-8. sec-Butylbenzene ND _ .: ug%L : 0.50 1 11/15/17.14:22 ;.135=98.8 tert-Butylbenzene :. ND .ug/L.. 0.50 1. 11/16/1714;22 -98-66-6 .:. Carbon tetrachloride ND : ug/L- . 0.50 1 11/15[1714:22 56-23-5- . Chlorobenzene ND ug/L . .0.50 1 11/15/1.714:22 - 108-90=7 Chloroethane ND ug/L A.0 1 11/15/17.14:22 .75-00-3 Chloroform • ' ND ug/L 0.50 '.1 11/15/17 14.22 67-66-3. Chloromethane :, .. ND uglL` 1:0 1 1,1/15/17 14:22 74-87-3. 2-Chlorotoluene '. ND ug/L.- 0;50'. 1 11/15/1114:22 `95-49-8 4-Ch1orotoluene ND ug/L .. 6.50 1- _' 11/15/17 14:22 106-43-4 1,2-Dibromo-3-:6hloropropane. ND u61- 1:0 1 -" :11/15/17.14.22 .96-127'8 Ditiromochlorofnethane ND ug/L : • 0.50 1" : 11/15/17 14:22 :.12448A 1 2-Dibromoethane (EDB) -ND . ug/L.. 0.50 1.. 11/15/17 14:22 106-93-4 : Dibrornomethane . ND : ug/L.. 0.50 9' 1105/1714.22 74-95-3' . 1,2-Dichlorobenzene: ND ug/L.'.: 0.50 1 .' 11/15/17 14:22 .95750-1 1,3-Dichlorobenzene :. ND' ug/L 0.50 1 11/15/17:14:22 :541-73 1, M-Dichlorobenzene ;. ND ug/L 0.50 '1 . ,: 11115/1714:22 .1.06-46.-7 Dichlorodifluorome'thane. -ND' uglL.. 0.:50- 1' 11/15/1714`22 7571=8. 1;1-Dichloroethane : ND . ug/L 0:50 . 1 11/15717 14:22 75 34-3_ 1,2-Di6h1oroetha6e' _ "' ND ug/L . _ - 6.50 1 - 11/15/17 14:22 107-06-2 1,1-Dichloroethene, : `.ND 'ug/L 0:50 1 11115/17:14.22.75-3574 cis-1,2-Dichloroethene. ND ug/L = 0.50 1 11/15/17 14:22 ,.156-5.9-2 trans-12-Dichloroethene ND . ug/L.. 0.50 1 .: 11/15/1.7 14:22 ' 156.60-5 : ND . 11/15117 14:22 78-87-51;2-Dichloropropane ..' 1,3-Dichloropropane. ND ug/L .: .0.50 .1 .' 11/15/17,14:22 142-28-9' -2,2-Dichloropropane .. ND ug/L 0.50 1 11/15/17.14:22 .59440-7. 1-1-Dichloropropene :. ND ug/L 0.50 1 11115/1714:22 563-58=6 cis71.,3-Dichloropropene ND ug/L 0:50. 1 .: 11/15%1T14`22 ' 10061'01-5 ` trans-1,37Dichloropropene. ..' ND :-` :ug/L ' 0:50 1 .'.:. 11/1.5/1.714:22 '10061-02-6 Diisopropyl:ether ND ; ug/L ' . 0.50 1 : '" 11/15/17 14:22 108-20-3 'Ethylbenzene : ND:- -ug/L" 0:50 1 11115/17-14:22'.100.41-4- Hexachloro-1,3-butadiene ND .: ug/L . '.' 2:0 1 ..11/15/17 14:22 ;87-68;=3 Isopropylbenzene (Cumene) ND . _ : ug/L - 0.50 1 : 11/15/17 14:22 98-62-8 Methylene Chloride ND ug/L, 2.0 _ ''1 :: 11/15/1.714;22 75-09-2 Methyl-tert-butyl ether ND. _ ,ug/L . 0.50 1 _ . 11/15/17 14:22. 1634-04-4 Naphthalene : ND'.. ug/L 2.0 1 ' '11/15/17:14:22 :91-20.3 n-Propylbenzene. ND ug/L 0.50 1 11/15/17 14:22 103-65-1 Styrene ND ug/L- 0:50- 1 '1.1/15/17-1422 100-42-5 1,1,1,27Tetrachloroethane' ND_ . ug/L 0:50 1' 11/15/17 14:22 630-20=6 Iil,2,2-Tetrachloroethane ND : ug/L . 0.50 1: 11/1511714:22 79-34-5 Tetrachloroethane ND ug/L 0:50 ..1 11/15/17.14:22 .127-18-4 - REPORT OF LABORATORY ANALYSIS. . This.reportshall not be reproduced; except in full, Date: 11/17/201.7 01:58 PM without the written consent of Pace Analytical Serdices, LLC. Page,11 of 44 - .'..Pace Analytical Services; LLC . •' q % ® �CV AnalXica 2225 Riverside.Dr.. ' Asheville, NC 28804 .:wwwPacelascom- .. (828)25477176 .. t ANALYTICAL RESULTS.." . Project: Clement Pappas 11/8 Pace .Project No.: 92362594 Sample:�.MW-7R : '." Lab la: 946.2594004 Collected'.: 11/08/1714:12_ ,Received:, 11/08/1715:10.- Matrix: Water Parameters -Results'. Units Report Limit - ; DF Prepared..'. Analyzed CAS. No, .`.'" Qual 6200B. MSV : Analytical Method: SM 6200B Toluene ND ug/L . 0.50 1 11/15/17 14:22 108-88-3 ." 1,2,3-Trichlorobenzene ND -ug/L 2.0 1, •-:. 11/15/17 14:22 .87-61-6 1,2,4Trichlorobenzene ND ug/L 2.0 1 11/15/1T14:22 120-82=1 1,1,1,Trichloroethane ., ND ug/L. 0:50 1' "11/15/1714-.22 `71=55-6: 1;1,2=Trichl6roethane : - . ND : ug%L 0:50 1 11/1571:7 14:22 '79 00-5 Trichloroethene ND ug/L 0.50 1.. 11/15/17 14:22 79701-6 -Trichlorofluoromefhane ND", ug/G : 1:0 ..1':... 11/15/17A422 .75 69-4 .1,2,3=Trichloropropane ND ug/L ; 0.50 1 11/15/17 14:22 '.96 18.4,. 1;2,4-Trimethylbenzene' ND ug/L,- 0.50 1.. 11/15/17 14:22 95 63 6 ND. ug/L.1,3,5 _ 0.50 1-Tmethylbenzn5/17 ' 7-8.2 Vinyl.chloride ND ' ug/L .: 1.0 . 1 •. 11/15/17 14:22 75-01-4 ni&p-Xylene ND _ vg/L A.0 1 11/15/1714:22 A79601-23-1 0-Xylene ND • ug/L " 0.50 1 11/15/17 :14:22 95 47 6. Surrogates 12-Dichlorcethane-d4 (S) 105. % 70-130 1." _" 11/15/17 14:22 17060-07-0 4-Brom6fluorobenzene (S) : 97 % ': 70-130 : 1 11/15/17 14:22. 46000-4 = Toluene d8 (S). _ 102 %.. 70.=130 1 :, 11L15/17.14;22 .2037-26-5 2540C Total Dissolved.Solids' Analytical Method: SM 2540C _ Total Dissolved Solids ... 376. mg/L.: - " :. 25.0. ' 1 ;: <11/10117 11:22 MBIO 9222D.Fecal.Coliform AVL Analytical Method: :SM"9222D . Fecal Coliforms : : 19.0 CFU/100 ML 1.0 " 1 . 11/08/1.7.15:54 u1' " - - -350A Ammonia Analytical•Method: EPA 350A 1993 Rev 2.0 Nitrogen, :Ammonia, :. - ND mg/L 0.10 1' 11/15/1712:27' 7664-41-7 353:2 Nitrogen, N021NO3 unpres. - : Arialytical.Method: EPA 3512. . Nitrogen,:Nitrate . 36:8 . -!mg/L - 0:020 1. 11/09/17 02:32 .365.1. Phosphorus, Total , Analytical.Method:.EPA 365.1 ". Phosphorus'; 0.14 , mg/L 0:050 A: ' 11/14/17 03:21 7723-14-0 4500.Chloride Analytical Method`..SM4500-CI-E :-Chloridee 17.9 mg/L , 1:0' 1 11/09/17 23:07. 16887-00 6 5310B TOC Analytical Method: SM.5310B Total Organic Carbon . -3.9 . " _ : mg/L- " 1.0 1 11/15/17 08:12 7446-44-0 t- 'REPORT OF LABORATORY ANALYSIS..- TFiis reportshall not be reproduced; except in full, . - - : Date: 11 /17/201.7 01:58 PM .' without the written consent of. Pace Analytical Services,:LLG. Page.12 of 44' Pace Analytical Services; LLC. " ® �• aceAnal 2225 Riverside Dr. -ica1- _ Asheville, NC 28804 wwwpacefabs.com (828)254-. .' ANALYTICAL RESULTS Project. Clement Pappas 11/8 Pace Project No::. _ .92362594 Sample.:'.MW-S- :- .Lab ID:.92362594065. .'Collected::.11/08/1710:13 Received:, 11/08/.1715:10. Matrix; Water Parameters Results.'.. Units Report Limit OF Prepared" .. Analyzed CAS. No.- Qual 6200B. MSV : Analytical Method: SM .6200E Benzene. NO. ug/L'.: .. -_0.50 ... 1, . :.' - 11/15/17 14:39 71-43-2: Bromobenzene •" . _ ND ug/L 0.50 1 11/15/17 14:39 A08 86-1 B:romochloromethane`. ND ug/L 0.50 .1 11/15/17 14:39 74 97=5. Bromodichloromethane 'ND ug/L.. -0.50 1 " : ' A1/15h7 14:39 75-27=4 Bromoforin _ • ND : ug/L 0:50 1' 11/1.511.7 14:39. 75 25-2 -. Bromomethane NO ug/L'.. " -&0 1 11/15/17 14:39 74-83-9 n Butylbenzene ND: . ,'ug/L- 0:50 1 ' :11115/17.14.39 .104-51-8 . sec-Butylbenzene ND ug/L : 0,50 -'1- 11/15/17 14:39 ::135-9878 tert=Butylbenzene ND ug/L.. 0.50 1. 11/1547 14:39 ' 98-06-6 Carbon.tetrachloride ND ug/L.. 0.50 1. 11/1511714:39- 56-23-5- - Chlorobenzene NO., ug/L ._ - 0.50 1 .' 11/15/17 14:39 •108-90-7 Chloroethane ND ug/L 1.0_ 1 11/15/17.14:39 75-00-3 Chloroform ND ug/L. 0.5�0 1 11/15/1714:39 . 67-66=3 Chloromethane..' :: -ND .: ug/L 1:0. ..1 .11/15/17'14`39 74-87-3. . 2-Chlorotoluene ND ` .ug/L 0:50 1 11/1571.7 14.39. '95=49-8 . 4-Chlorotoluene NO , Ug/L . 0.50 _ 1 11/15/1714:39 106=43-4 1,2-Dibromo-3-chloropropane. - `,ND ug/L- 1:0 '..1 ' 11/15/17.14r39`.96=12-8 Dibromochloromethane 'ND ug/L : 0,50 1 11/15/17 14:39 ;124=48-1 1;2-Dibromoethane (EDB)- ND . ug/t . 0.50 1. 11/15/1 7 14:39 106-93-4 ;. Dib�omometFiane . ND_: ug/L... _ 0.50 1 :: • :11/15/1714.:39 74-95-3 . 1,2-Dichlorobenzene. ND ug/L :' .0.50 1 11/15/17 14:39 95-50-1 " 1,3-Dichlorobenzene:. ND ug/L 0:50 1 11/15/17.14:39.54143-1.'. 1;4-Dichlorobenzene :. ND ug/L 0.50 1 11/15/17 -14:39 106-46-7 Dichlorodifluoromethane. `.. ND ug/L. 0.50 1 11/15/1714:39 75-71-8 1;1-Dichloroethane ND , ug/L 0:50 1 -11115/1714:39. 75-34-3 . . 1;27Di6hloroethane ND ug/L 0.50 1 11/15/17 14:39 107=06-2 1,1-Dichloroethene.' ND ug/L 0:50 1 11/15/17.14:39 .75-35-4 . cis-1,2-Dichloroethene, 'ND . Lugk, : 0.50 1 11/15/17 14:39 15&5.9-2 trans-1,2-Dichloroethene NO ug/C 0.50 1. 11/15?1.714:39 156-60-5 1,2-Dichloropropane ND' ug/L.. " 0.50. 1. .-11/15/17 14:39- 78-87-5 . 1,3 Dichloroproparie. ND ug/L'.: 0.50; 1.. 11/15/1714:39 142-28 9. 2,2-Dichloropropane .. ND _ - :. ug/L 0.50 : 1 ' " _ 11%15/17 14:39 : 59420-7 . .. 1;1-Dichloropropene :: NO - :.: ug/L 0.50 1 11/15/17 1439 563-58. 6 cis-1,3-Dichloropropene .: ', ND ug/L: 0.50. 1 . '.. ;.. 11/15%17'14`39 10061;01-5 _-; trans=1,37Dichloropropene . ND .' ug/L 0:50 1 .. 1111511.714:39. 10061-02-6 Diisopropyl:ether ND ug/L'.. 0.50 1; ' 11/15/17 14:39 108=20-3 ND g/L0;50 39 -4Ethylbenzehe 4 Hexachloro-1,3-butadie.ne ;ND .' . • ug%L : 2:0 1 11/15/1714:39 :.87-68-3. Isopropylbenzene (Cumene) ... NO . ug/L 0.50 1 11/15/1.7 14;39 ,' 98-82-8 - Methylene Chloride NO. ug/L,. 2.0. 1 :: :11/15/1714:39 75-09-2 . Methyl-tert-butyl ether ND ug/L'., .0.50, -1 11/15/17 14:39 163.4--04-4, Naphthalene ND' '. ug/L 2.0 1 11/15/17:14:39 :91-20-3 n-Propylbenzene NO ug/L 0.50 1 11/15/17 14:39 103-65-1 Styrene NO ug/L 0'.50 1 11/15h7'14:39:100-42-5 1;1,1;27Tetrachloroethane ND ug/L 0:50 . 1 11115/1714:39 '630-20=6: 1;1,2,2-Tetrachloroethane . NO ug/L 0.50 1 11/15/17 14:39 7994-5 Tetrachloroethene ND ug/L 0:50' :.1 11%15/17.14:39 .127=18-4 REPORT OF LABORATORY ANALYSIS This, report shall not be reproduced, except in full, Date: 11/17/201.7 01:58 PM without the written consent of Pace Analytical Services, LLC. Page.13 of 44 . Pace Analytical Services; LLC 2226 Riverside Dr. .Ash'eville', NC 28804 wwwpacelabs com (828)254-7176 ANALYTICAL RESULTS.' Project: Clement Pappas 11/8 Pace Project No.:. .92362594 Sample: MW-ii_ Lab ID: 92362594005 Collected:: 11/08/1710:13 Received: ' 11/08/1715:10 Matrix: Water. . Parameters Results . Units Report Limit DF Prepared„ . `Analyzed CAS. No. Qual 6200B. MSV : : _ - :: Analytical Method:'SM 6200B Toluene- ND . ug/L .: :: .0.50 1 .' 11/15/1714:39 108-88-3 :. 1,2,3-Trichlorobenzene . • NDug/L 2.0 1 11/15/17:14:39 : 87=61-6 4;2,4=Trichlorobenzene : ND ug/L 2.0 . 1 11/15117 14:39 120-82-1 1,1,1 Trichloroethane .... ND ug/L` : 0.50. 1 11/15il7 14`39 71-55-6. 1;1,2=Trichloroethane ND . ug/L 0:50 1 11/15/1714:39. 79-60-5 .: Trichloroethene ND : ug/L .. 0.50 . 1- 11/15/17 14:39 79-01-6 Trichlorofluoromethane - ND' - ug/L 1:0 1 = 11/15/17.14:39'.75=69 4 .1,2,37Trichloropropane. ND ug/L : -0.50 1 11/15/1714:39 ;96-187-4. " "12,4-Trimethylbenzene".. ND . ug/C_. 0.5.0 .1 11/15/1'7 14:39 95-63-6 1;3;5-Trimettiylbenzene . - ND,. ug/L, : - 0:50. 1 :: 11/15/1714:39. 108-67-8. " Vinyl chloride ND ug/L ,: 1.0 1 .' 11/15/1714:39 _75-01-4 Ap-Xylene ND ug/L to 1 11/15/1714:39 -179601-23-1 . o-Xylene " ND ug/L 0.50 1 1Ill5/17 14:39 95-47-6. Surrogates: 1 2-Dichloroethane d4 (S) 102, % 70-130 - 1 . " .11/15/17 14`.39 .17060-07-0 47Brom6fluorobenzene (S) : - 97 % - . : 70=130' 1 Ill 15/1714:39. 460-00-4 Toluene-d8 (S)". 102 % . . 70-130 1 : :11/15/17.14:39 .2037-2675 .2540C Total Dissolved Solids Analytical -Method: SM 2540C ' Total Dissolved Solids 390, mg/L : 50,0 1 ;. 11/10/17 11:22 M1310 9222D.Fecal:Coliform AVL Analytical Method: SM 9222D. . Fecal Coliforms ND. CFU/l00 inL :.' - - 4.0 4, 11/08/1715:54 350:1 Ammonia Analytical Method: EPA 350:1 1993 Rev 2.0 Nitrogen,. Ammonia :" ND ::. mg/L : 0.10 1 11115/1712:32 7664-41.-7 353:2 Nitrogen,.N021td03 unpres... Analytical Method: EPA 353.2 . Nitrogen,, Nitrate . ..14.4 mg/L :. - - 0:020 . 1.. 11/09/17 02:30 .365.1;Phosphorus,Total ,: Analytical Method:.EPA365.1'. Phosphorus 1098 : mg/L 0:050 .. 1: ; ' .. 11/14/17 03:21 7723-14-0 . -' .' • . 4500 Chloride Analytical Method: SM 4500-C1-E Chloride 9.7 mg/L.' - = 1.0' 1 11/09/17 23:08 : 16887-00-6 5316B TOC Analytical Method: SM-6310B- Total Organic Carbon .' 8..1 _ mg/L- :.: _ 1.0 1 11/15/1.7 13:28 7440-44-0 RE •. , _ PORT OF LABORATORY ANALYSIS . This: report' shall not be reproduced; except in full; Date: 11/17/201.7. 01;58 PM - without the written consent of Pace Analytical Services, LLC. 'Page.1.4 of 44 Pace Analytical,Services, LLC ® acMnalXical. 2225 Riverside Dr. ..: Asheville, NC 28804 www.pacwah.s.com (828)254-7176 ;. ANALYTICAL RESULTS Project: Clement Pappas 11/8 Pace. Project No.:.. 92362594 Sample: MW-9 Lab 10: 92362594006 Collected: 11/08/1713:05. Received:. 11/08/1715:10 Matrix: Water Parameters Results , Units Report Limit DF Prepared_.. Analyzed CAS No. .. Qual 6200B. MSV : Analytical Method: SM 6200B : Benzene - . ND,' ug/L' .0.50; 1 _ . _ 11/15/1.7 14:57 -71.43-2 Bromobenzene. -.ND ug/L 0.50. : 1 11/15/17.14:57108-86-1 Bromochloromethane:. ND ug/L 0.50 1 11/15/17 14:57 74-97:.5 `. Bromodichloromethane, . ND ug/L: 0.:50- 1 - .: 11/15/1714:57 75=27=4. Bromoform - . ND.. ug/L 0:50 . 1' " 11/15/17 14:57 75-25-2 : Bromomethane ND ug/L'. 5:0" 1' 11/15/17 14:57 74-83-9 n-Butylbenzene ND ug/L 0:50.'. 1= :11/15/.17.14:57'-104-51-8, sec Butylbenzene ND ,' .. -ug%L : 0.50 1 11/15/17 14:57 :.135 9878 tert=Butylbenzene :. .. :. ',' .. ND :.ug/L . " 0.50 -1 11/15/17 14:57 98-06 6 Carbon tetrachloride ND ug/L... 0.50. 1 11/15/1714:57" 56-23-5 . Chlorobenzene ND . u9/L .: 0.50 1- , 11/15/17 14:57 - 108 90-7 Chloroetharie : ND _ ug/L 1,0 : 1 11/15/17.14:57 .75=00-3 . Chloroform ND ug/L 0.50 .1 11/15/17 14:57 67-66 3. Chloromethane.. ND .. ug/L. 1.0. 1 11/15/1714:57 74-87-3: .2-Chl6rotoluene :: ND.. ug/L 0.50 1 . 11/15/1.714:57 -95-49-8 4-Chlorotoluene ND : ug/L 6.50 _ 1: 11/15/17 14:57 10643-4 1.,2-Dibrorrio-3-6hloropropane. - ND' : ud/L 1:0 ..1 " 11/15/17.14:57 .96-1278 Dibromochloromethane. ND .: ug(L -0.50 1 11/15/17 14:57 ::12448-4 1;2-Dibromoethane (EDB) ND . ug/C,. 0.50 1.: 11115/1.7 14:57 106-93-4:. Dibroniometfiane ND :. ug/L 0.50 1 : 11/15/17 14:57 74-95-3 . 1,2-Dichlorobenzene. ND. ug/L.: 0.50 1 11/15/17 14:57 95-50-1 1,3-Dichlorobenzene .. ND' ug/L 0.50 -1 11/15/17.14:57 .541-73-1 . 1;4-Dichlorobenzene :. ND ug/L 0.50- -.1 11/15/17 14:57 .106-46=7 Dichlorodifluoro"methane.. ND .: ug/L 0.50 :1 : 11/15/17"14`51 ' 75=71=8. 1;1-Di6hloroethane: ND . ug/L '. 0:50 . 1 ,. 11/15/17 14:57 -75-34-3 . . 1;2-Dichloroethane ND; ug/L .. 0.50 1; 11/15/17 -14:57 107-06-2 1,1-Dichloroethene,' ND Ug/L 0:50 - 1 11115/17-14:57.75=354- cis-1,2-Dichloroethene. ND ug%L : 0.50 1 11/15/1714:57 :.156=59=2 trans-12=Dich1oroethene ND . ug/L 0.50 1 11/15/17 14:57 156-60-5 1;2-Dichlor6propane ', ., ND:. ug/L... 0.50, 1 11/15/17 14:57- 78-87-5 . 1,3-Dichloroproparie . ND . ug/L .: 0.50 1 - _ . 11/15/1,7 14:57 142 28 9 . 2,2-Dichloropropane ,. ND ug/L 0.50 1 11/15/17.14:57.594-20-7.' 1;1-Dichloropro.pene :. ND ug/L 0.50 " ..1 11/15/17 14:57 563-58.=6 cis;1,3-Dichloropropene. • ND' ug/L.. 0:50. 1 11/15/17 14i57 10061;01-5' .. . trans=1,37Dichloropropene . - . :: ND . ug/L 0:50 . 1 11/15/17 14:57 10061-02-6 Diisopropyl,ether ND ug%L 0.50 1 11/15/17 -14:57 - 108-20-3 " Ethylbenzerie ND " ug/L 0;50 1 11/15/17.14:57--100414." . Hexachloro-1,3-butadiene ND .. ug(L . . 2.0 1 11/15/1714:57 ..87-68.=3. Isopropylbenzene (Cumene) ND . ug/C . 0.50 1 11/15)17 14:57 98-82-8 Methylene Chloride ND., ug/L. 2.0. 1' 11/15/1714:57 75-09-2 Methyl-tert-butyl ether -ND ug/L .0.50 1.. 11/15/17 14:57 1634-04-4 Naphthalene ND ug/L 2.0 1 . 11/15/17.14:57 .91=20-3 n=Propylbenzene ND- :.. ug/L 0.50 .1 11/15/17 14:57 103-65=1 Styrene:.. ND ug/L 0..50 1 11/15/17 14:57 100-42-5 1;1,1,2-Tetrach1oroethane -ND ug/L 0:50 1 11/15/1714:57 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/15/17 14:57 79-34-5 Tetrachloroethene-_ ND' ug/L .0:50 1 :11/15/17 14:57 127=18-4 REPORT OF LABORATORY ANALYSIS This: report shall not be reproduced; except in full, Date: 11/17/201.7 01:58 PM without the written consent of. Pace Analytical Services, LLC. Page.15 of 44 Pace Arialytical Services; LLC Q /� ® aC@AI alXkal • .. 2225 Riverside Dr. Asheville. NC 28804 :. wwwpacelabs.com (828)254-7176 ANALYTICAL RESULTS. Project: Clement Pappas 1118 ,'Pace Project No.:. 92362594 Sample:.MW-9 Lab ID: 92362594006 Collected: 11/08/17 13:05 Received:," 11/08/17 15:10.- Matrix: Water Parameters Results . Units Report Limit DF Prepared..". 'Analyzed CAS No..' Qual 6200B.MSV : Analytical Method: SM 6200B Toluene . ND ug/L 0.50. .. 1 11/15/1.7.14:57 i08788-3.' ' 1,2,3-Trichlorobenzene ND ug/L .2.0 1 1.1/15/17.14:57.87-61-6 1,2kTrichlorobenzene ND ug/L .2.0 1 11115/1714:57 120-82-1 1',1,1-Trichloroethane' - ND ug/L.. 0.50 1 11/15/1714:57 71=55-6 1;1,2-Trichloroethane ND :ug/L 0:50 1 .11/15/17 14:57 79-00-5 Trichloroethene ND ugJL . 0.50 - 1, _ 11/15/17 14:57 79-01-6 Trichlorofluoromethane :.ND ug/L 1.0 1 11/15/17.14:57.75=69=4 . 1,2,3=Trichloropropane. ND ug(L . 0,50 1 11/15/17 14:57 .96-18=4 .1;2,4-Trirhethylbenzene -. ND ug/L . 0.50 ' .1.: 11/15/17 14:57 95-63-6 1,3,5-Trimetfiylbenzene . ND: ug/L...'- 0.50 1 _; 11/1511714:57 108767-8• Vinyl chloride ND. ug/L 1.0. 1 11/15/17 14:57 75701-4 m&p-Xylene ND ug/L 1.0 • 1 11/15/17.14:57 .179601-23-1 o=Xylene ND ug/L 0.50 .1 11/15/17-14:57' 95-47-6 Surrogates' . 1,2-Dichloroethane-d4 (S) 102 % 70-130' 1 , _ 11/15/17 14.57 .17060-07-0 4-Brom6fluorobenzene(S) 96 % • _ - 70-130' : 1 11/15/1714:57, 460-0074 Toluene-d8 (S)..' 99 % . 70=130 - 1: 11/15/17.14:57 ,2037-2675- 2540C Total Dissolved.Solids Analytical Method: SM 2540C: Total Dissolved Solids'... 64.0_. mg/L 25.0. 1 :. 11/10/17 11:22 MBIO 92221) Fecal:Coliform AVL Analytical_ Method::SM 9222D• . Fecal Coliforms: .10.0. . CFU/100 mL 1.0 1 ; 11/08/1715:54. u1 '. 350A Ammonia -Analytical Method: EPA350A 1993 Rev 2.0 Nitrogen, Ammonia ND mg/L 0.10 1 11/15/17 '12:33 7664-41-7 353:2 Nitrogen,.NO2/.NO3 unpres• .. Analytical. Method: EPA 353.2 . Nitrogen,. Nitrate- 0.96 mg/L 0:020. .1. 11/09/1702:36 :.. .365.1. Phosphorus, Total Analytical Method: EPA 365.1' . Phosphorus '6.53 ; " mg/L '- 0.050 1 11/14/17 03:24 - 7723-14-0 4500 Chloride _ Analytical Method: SM 4500-cl-E' Chloride 8.9 mg/L 1.0 1 - 11/09/17 23:09. 16887-00=6 5310E TOC Analytical Method: SM 6310B Total Organic Carbon'... ' 7.0 . mg/L I.Q.1 11/15/17 08:24 7440-44-0 REPORT OF LABORATORY ANALYSIS. • . This: report shall not be reproduced; except in full; Date: 11/17/2017 01:58 PM without the written consent of Pace Analytical Services, LLC. Page.1.6 of44 Pace Analytical Servicesi LLC , . / . /+.. ® /+ �ce aIXical.' 2225 Riverside Dr. .: Ash'eville, NC 28804 ..' wwwpacelabs.com. .. . . (828)254.7178 ANALYTICAL RESULTS. . Project: -Clement Pappas 11/8 Pace. Project No.:.'_ .92362594 Sample: .SW-1'. :- Lab ID: 92362594007 Collecteii:: 11/08/1714:10, Received: 11/08/1715:10. Matrix: Water - Parameters Results Units - . 'Report Limit' DF Prepared... 'Analyzed CAS. No. .. Qual. 6200B. MSV : Analytical Method: SM .6200B Benzene ND ug/L .; 0.50 1 11/15/17 15:14 71-43-2 Bromobenzene . _ :. ND uglL _ : 0.50 : ,1 11/15/17.15:14 .108-86-1 :. Bromochloromethane:. ND ug/L ' 0.50 1 11/15/17 1514 74-97=5. Bromodichloromethane.. ND : ug1L. 0:50 1 ' 1.1/15/17 15:14 ' 75-27=4. Bromoform .. : ' .. ND ug/L ' MO_ 1 11/15/1.715:14. '75 25 2 : • . Bromomethane • ND ug/L . 5.0 _ 1 11/15F17 15:14. 74-83-9 n-Butylbenzene ND ug/L .0:50 .1 11)15/17.15:14 104-51-8 sec Butylbenzene ND ug/L : 0,50 1 . 11/15/17 15:14 ,.135=9878 tert-Butylbenzehe :. N. D . ug/C.. 0.50 1- " 11/15/1715:14 98-06-6 Carbon tetrachloride _ , ND : ug/L.. • 0.50, • 1 -; 11/15/1715:14 56-23-5 . Chlorobenzene ND . ug/L'.; .0.50 1. 11/15/17 15:14 108-90-7 Chloroefhane ND --, ..ug/L .1.0. 1 -11/15/17:15:14 .75-00-3. :> Chloroform ND ug/L 0.50 :.1 11/15/17:15:14 67-66=3 Chloromethane : , :.: ND . ' .. ug/L. 1:0 . 1 1.1/15117' 15:14 74-87-3 2-Chlorotoluene' ND.. :ug/L 0M .: V.. ,.: 11/15/1715:14.. 95 49-8 4-Chl6rotoluene ; ND" ug%L .. 0.50 - 1 ; 11/15/17 15:14 10643-4 =' 1,2-Dibromo-3-6hloropropane ND ud/L' 10 ..1 11/15/17.15:14.96-12-8 Dibromochloromethane - ND ug/lL 0.50 1 11/15/17 16:14 ;.124=48-1 1,2-Dibromoethane.(EDB) ND. ug/L.. 0.50 1 11/15/17 15:14 -106-93-4 Dibromomethane . ND_. ug/L. 0.50 1'.. 11/1511715:14 74-95-3 . 1,2-Dichlorobenzene. ND. ug/L .; - .0.50- 1 11/15/17 15:14 95750-1 1,3-Dichlorobenzene :: ND' ', -ug/L 0.50 1 ' 11/15/.17.15:14 .541=73-1 .' 1,4-Dichloroben2ene :. ND ug/L . 0.50 1 11/15/17:15:14 106-46=7 Didhlorodifluoromethane. - ND . ' .- ug1L 0:50 1 11/15/171514 75-71-8. 1;1-Dichloroethene . ND ug/L 0:50 _ 1 : 11/15/1.7-15:14. 75 34-3 1;2-Dichloroethane _ ND ug/L 0.50 1 11/15/1T15:14 107-06-2 1,1-Dichloroethene. ND ug/L 0.50' - 1 11115/17.15:14'.75=354 : cis- 1,2-Dichloroethene. ND' ug%L' : 0.50 1 11/15/1716:14 :.156-59-2 trans-1,2-Dichloroe4hene ND .' ug/C,. 0.50 1 11/15/17 15:14 '156-60-5: 1;2-Dichlor6propane _ ND_: ug/L.. 0.50. 1.: 11/15/1715:14 78-87-5 1,3-Dichloropropane. ..; ND . ug/L .; .0.50 - 1.. 11/15/17 15:14 142-28-9_ . .-2,2-Dichloropropane :: ND ug/L 0.50.' : 1 11/15/17:15:14 .594-20-7 1 J-Dichloropropene '. ND ug/L ` 0.50 1 11/15/17 15:14 563-58=6 cis-.1,3-Dichloropropene` ND' .. ug/L -. 0.50. 1 '. 11/15/17,15:14 10061701-5 Grans=1,3-Dichloropropene . : - . ., :: ND . ,.'::ug/L 0.50'. . 1 ':: 11/15/17 15:14 10061-02-6 Diisopropyl.ether : .. ND, ug/L'. 0.50 1; ; 11/15/17 15:14 108-20-3 Ethylbenzene ND Ug/L' 0.50 1 '. 11%15/17.15:14 10041-4 Hexachldro-1,3-butadiene ND .. ug[L' . 2.0 1 ll/15/1715:14 :.87-68-3. .. - Isopropylbenzene (Cumene) ND ug/L. 0.50 1 11/15/17 15:14 98-82-8 - Methylene Chloride ND:: ug/L.:. 2.0 1 .. 11/15/17 15:14 75-09-2 _. Methyl-tert-butyl ether .. ND ug/L . 0.50 1.. 11/15/17 15:14 1634-04-4: . Naphthalene' ND A/L 2.0 1 11/15/1715:14.91=20-3.- n7Propylbenzene. ND ug/L 0.60 1 11115/1715:14 .103-65-1 . Styrene ND ug/L.: .. 0.50 1 :. ', .' 11/15/17-15`.14 -100-42-5 1;1,1,2-Tetrachloroethane ND . ug/L 0:50 . 1 ., .11/15/17 15:14 630-20 6 . 1;1,2,2-Tetrachlor6ethane . ND ; ug/L - . 6.50 1; 11/15/1715:14 79-34-5 Tetrachloroethene - : ND : ug/L 0:50 - -1 11/15/17,15:14 .127=18-4' REPORT OF LABORATORY ANALYSIS. . This; report shall not be reproduced, except in full, Date: 11/17/201.7 01:58 PM without the written consent'of.Pace Analytical Services, LLC. - Page.17 of 44 Pace Analytical.Services, LLC ® aC@AnaOCal. 2225 Riverside.Dr. .. Asheville, NC 28804 wwwp..labs com - 7176 (828)254 ANALYTICAL RESULTS _ Project: Clement Pappas 11/8 Pace Project No.:- _ .92362594 , . . Sample.: SW-1 Lab ID:.92362594067 Collected:: 11/08/1714:10 _ Received: ' 11/08/17 15:10. Matrix: Water Parameters Results.. Units Report Limit DF Prepared • Analyzed CAS. No. Qual 6200B.MSV : _ Analytical -Method: SM 62006' Toluene- -:.' ND ug/L'.; 0.50 1 11%15/1715:14 108-88-3 1,2,3-Trichlorobenzene ND vg/L 2.0 1' _ •., .. 11/1'W17.15:14.87=61-6 1,2kTrichlorobenzene ND ug/L 2.0 1 11/15/1715:14 120-82.=l 1,1,1-Trichloroethane -. : ND ug/L.. 0.50 .1 1.1115/17-15:14 -71-55=6 1;1,2=Trichl6roethane ND ug/L 0:50 1 11/15/1715:14 '79=00-5 ... ' Trichloroethene ND ug/L . _ - ` 0.50 1 11/15/1715:14- 79-01-6 Trichlorofluororriethane .ND ud/L. 1:0 1 11/15/17.15:14'.75=694 1,2,3-Trichloropropane. ND ug/L : 0.60 1 11/15/17 15:14 96-18=4 1;2,4-Trimethylbenzen.e. ND ug/C 0.50 1- - 11/15/:1715:14 95-63-6 1;3,5-Trimethylbenzene . ND. ug/L... 0.50 "1 11/15/1715:14. 108-67-8._ Vinyl chloride ND. ug/L1.0 1 11/15/1715:14 75-01-4 m&p-Xylene ND' _ : ug/L 1,0 : 1 11/15/17.15:14 -179601-23-1.. o=Xylene . ND - ... ug/L 0.50 .1 11/15/17 15:14 95-47=6. . 1,2-Dichloroethane-d4 (S) 106. % 70-130 1'.' .11/15/17.15:14 .17060-07-0 . -4-Brom6fluorobenzene (S) 97 % ' 70;130 1 11/15/17:15:14 : 460-00-4 Toluene=d8 (S).. 100 % . ' _ . 70=130 1 :11/15/17 15:14 .203T2fi-5 -2540C Total DissolvedSolids Analytical Method: SM 2540C. -Total Dissolved Solids _ ... 44.0• mg/L ' 25.0. • 1'.' 11/13/17 09:14- ` - . D6. MBIO 9222D.Fecal.Coliform AVL - .Analytical, Method: SM 9222D. • - Fecal Coliforms. 530 CFU/100 rnL 1.0 ' 1 . 11108/1716:33- 350:1 Ammonia Analytical Method: EPA'350.1 1993 Rev 2.0 :. Nitrogen, -Ammonia :- ND mg/L 0.10 1 11/15/17:12:34 7664-41-7.: -353.2 Nitrogen,.NO2/NO3 unpres..: Arialytical.MetFiod: EPA353.2 Nitrogen,. Nitrate . ..0.66 . mg/L 0.020 . 1.. 11/09/17 02.38 ,. ... 365.1 Phosphorus, Total. _ Analytical.Method:.EPA 365.1 Phosphorus : - . 0.091 mg/L . 0:050 1; 11/14/17 03:24 7723-14-0 . 4500.Chloride Analytical Method: SM 4500-CI-E Chloride' - 5.1 mg/L 1.0 1 11/09/4723:14. 16887-00=6 5310B TOC Analytical Method: SM.5310B. Total Organic Carbon : 2.5 mg/L 1.0 .' .1 - 11/15/17 08:35 7440-44-0- REPORT -OF _LABORATORY ANALYSIS Thisreport shall not be reproduced; except in full, Date: 11/17/201.7 01:58 PM without the written consent of.Pace AnalyBcal Serdices, LLC. '- -Page.1.8 of4 - Pace Analytical Servicesi LLC /�� I ® dCe IaIXical . 2226 Riverside Dr. Asheville, NC 28804 . . wwwpacela6s.com "' - : (828)254-7176 .. ANALYTICAL RESULTS Project: Clement Pappas 11/8 " Pace Project No:: 92362594 Sample:' SW-2 '.Lab ID:.92362594068 Collected: .11/08/17 10:35 - Received: "11/08/17 15:10 Matrix: Water Parameters Results,". Units Report Limit DF Prepared., Analyzed CAS No.- Qual 6200B. MSV : Analytical Method: SM 6200B Benzene- ND. _ ug/L - - .0.50 1 11/15/17 15:31 71-43-2 Bromobenzene" ND _ ug/L 0.50 : 1 11/15/17.15:311 .108-86-1-" .. Bromochloromethane:. ND ug/L 0.50 " .' 1" 11/15/17 15:31" 74-97-5. " Bromodichloromethane. : ND ug/L 01:50: 1 11/15/17 15:31 75-274 Brom6fbrm ND ug/L 0:50' 1 -11/15/1715:31 75-25-2 Bromomethane " ND ug/L .. " 5:0 . 1; .. 11/15/17 15:31 " 74-83-9 n-Butylbenzene ND: ug/L" .0:50 ..1 11/15/1Z15:31 .104-51-8 - sec-Butylbenzene ND " "ug/L " 0.50 :." 1 11/15/17 15:31 13579,8-8 tert-Butylbenzene . = ND . ug/L, - 0.50 1 11/15/1.7 15:31 - 98-06-6 _ -Carbon tetrachloride ND-: ug/L• " - '0.50-' 1 •: 11/15/17 15:31. 56-23-5 . Chlorobenzene ND - - _ .ug/L 0.50 1 11/15/17 15:3.1 •108790-7 -Chloroethane, " . .. ND ug/L ..1.0 1 11/150715:31 .75-00-3 " . Chloroform ND - - ug/L .0.50. . 1 11/15/17 1531 67-66-3. Chloromethane. _ ._ .. ND " ug/L. - • .1:0. 1 ", ", ' . " ,..: 1.1/15h7 1,5`.31 74-87-3 .. 2-Chlorotoluene .: ND ug/L 0:50 : 1 _ . 11/15/17 15:31. 95=49-8.. 4-Chlorotoluene ND : ug/L" . _ 0.50 . -1 11/15/17 15:31 10643-4 1;2-Dibromo-3-6hloropropane. ND" Ug/L 1:0 ..1 11/15/1715:31..96=127'8 Dibromochloromethane :" '. 'ND ... ugLL :" :." 0.50 1 -" 11/15/1715:31 :.1244971 1;2-Dibromoethane•(EDI3)" ND ug/L . 0.50" " .1_ _ " 11/16/1.7 15:31" 106-93-4 :. Dibromomethane - _ ND, ug/L, : " .'0.50. '1 11/15/171531 74-95-3 . 1,2-D.ichlorobenzene. ND. ug/L _ 0.50 1 11/15/17,15:31 95-50-1 -1,3-Dichlorobenzene :. ND ug/L 0.50" . 1 '11/15/17.15:31 :541-73-1 :. 1;4-Dichlorobenzene :, ND ug/L " " . 0.50 A 11/15/17 15:31 .106-46.=7 Dichlorodifluoromethane . ND .. ug/L` . 0..50. " "1 11/15/17 15`.31 "75-71=8- 1;1-Dichloroethane : ND. ". - _ ug/L 0:50 - " 1 . - 11/15/1715:31. 75=34-3 1;2-.Dichloroethane ND ug/L _ 0.50 1: _ 11/15/17 15:31 107-06-2 1,1-Dichloroethene," : ND .Ug/L .. 0.50 .1 =" 11/150715:31'.75-35-4 cis- 1,2-Dichloroethene ND " ," .. ug%L : • 0.50 1 11./15/17 15:31 _156-59-2 trans-1,2-Dichloroethene. ND . ; •ug/C . 0.50 -.1 1111547 15:31 ' 156-60-5 ; 1;2-Dichloropropane ND" ug/L. 0.50 - T : _ 11/1511715:31" 78-87-5 1,3-Dichloropropane. ND . ug/L.. .0.50 1 • .' 11/15/17 15:31 142-28-9 . 2,2-Dichloropr6pane "." ND ", ug/L 0.50 : 1 " 11115/17.15:31 .594-20-7 1,1-Dichloropropene :. ND ug/L -0.50 1 - - 11/15/17 15:31 " 563-58.=6 �. cis-1,3-Dichloropropene • ". ND ug/L• . 0..50• 1 1.1/15iW 15-31 10061=01-5 trans=1,37Dichloropropene . .: " . "- :. ND . _ ::ug/L 0:50 1" .: .:: 11/1511:7 15:31. A0061-02-6 Diisop�opyl-ether ND ug/L 0.50 1 - - 11/15/17 15:31 " 108-20-3 Ethylbenzene ND ug/L" 0:50 .1 =" 11115/17.15:31 .10041-4 Hexachloro-1,3-butadiene ND .. :ug/L 2.0 1 11115/17116:31 .81-68,-3. .. Isopropylbenzene (Cumene) .. - -ND • ug/L 0.50 1 -' 11/15/17 15:31 98-82-8 Methylene Chloride. ND:. ug/L.. 2.0. 1:: 1.11.1511715;31 75-09-2 Methyl-tert-butyl ether ND . ug/L.. _ .0.50 1, . 11/15/17 15:31 1634-04-4 . Naphthalene" ND ug/L 2.0. 1 " 11%15/1715:31 91-20-3 - n-Propylbenzene. ND ug/L 0.50 1" 1111511715:31 1.03-65-1 Styrene '. ND ug/L 0.50 1 11/15/1715`:31 -100-42-5 1,1,1;2-Tetrachloroethane ND . ug/L UT 1 11/15/17 15:31. 630-20=6 1;1,2,24etrachloroethane. ND ug/L 0.50 1 11/15/17 15:31. 7994-5 Tetrachloroethene ND7 ug/L 0:50 1 11/15/17 15:31 .127-18-4 REPORT OF LABORATORY ANALYSIS This. report shall not be reproduced, except in full, Date: 11/17/201.7 01:58 PM without the written consent of Pace Analytical Services, LLC. " Page 19 of'44 Pace Analytical Services; LLC - g�+ GICe it J�� ('V�l . 2225Riverside .Dr. Asheville. NC 28804 wwwpacelabs.com .. (828)254-7176 ANALYTICAL -RESULTS .:. . Project: Clement Pappas 11/8 Pace Project No.:. 92362594 Sample: .SW-2- Lab ID: 92362594068 Collected:: 11/08/17'10:35. _ Received: 11/08/1715:10. Matrix: Water :. Parameters 'Results'.: Units • : Report Limit DF Prepared. , . Analyzed CAS. No. Qual 6200B. MSV : Analytical Method: SM 6200E •Toluene ND ug/L ._ - 0.50. -. 1. _ : :. 11/15/1715:31 108-88-3 .. 1,2,3-Trichlorobenzene • NDug/L 2.0. : 1 11%15/17.15:31 :87-61-6 . . 12,4=Trichlorobenzene • ND ug/L 2.0 A 11/15/17 1531 .120-82=1 .1,1,1-Trichloroethane. :: ND' ug/L 0.'50: -1 11/15/17 15:31 71=55-6 1,12-Trichloroethane" ND ug/L 0:50 1 - . 11/15/1715:31 '79-00-5 Trichloroetherie '.' ND ug/L 0.50 .11 11/15/17 15:31 79-01-6 Trichlorofluoromethane - ND ug/L 1.0 1: 11/15/17.15:31 :75=69-4 . . 1,2,3-Trichloropropane_ ND ... ug%L : 0.50 1 11/15/17 16:31 :.96-18.=4. 1;2,4-Trimethyllienzene ND . : ug/L . 0.50 1.. 11/15/17 15:31 95-6376 1 A§-Trimethylbenzene .. _ ND.' ug/L,- : 0.50 ; 1 11/15/17 15:31 108767-8. Vinyl chloride' -NO ug/L'. 1.0.. 1 _ 11/15/17 15:31 75-01-4 . m&p Xylene ND ug/L _ 1.0_ 1 11%15/17:15:31 :179601-234: o=Xylene.. ND - ug/L 0.50 1 .11/15/17 15:31 ''95-47-6. Surrogates . 1,2-Dichlomethane-d4 (S) .104. % ` 70-130 - 1 - - _11%15/17.15`31 .17060-07-0 . 4-Brom6fluorobenzene (S) 98 % _ 707130 1 11/15/17 :15:31 : 460-00-4: Toluene-08 (S).. , - ; 98. % . 70=130 . ,1 : :11L15/17 15:31 :2037-26-5 .- . . .2540C Total Dissolved.Solids AnalyticafMethod- SM 2540C' ,Total Dissolved Solids .. 54.0:. mg/L 25.0 :1 : 11/13/17 09:14 ;MBib 92226 Fecal:Coliform AVIL Analytical Method: SM 9222D_ . -Fecal Coliforms -. 860. CFU/100 rnL 1.0 1 . 11/08/17 15:54. 350.1 Ammonia Analytical Method: EPA 350:1 1993 Rev 2.0 Nitrogen,. Ammonia :. ND mg/L 6.10 1 11/15/1712:36 7664-414 353:2 Nitrogen,.NO2IN03 unpres... Analytical.MetFiod: EPA353.2. " Nitrogen, Nitrate .0.61 mg/L ,.' : 0.020 1:: 11/09/1702:31 .365.1. Phosphorus, Total . Analytical.Method: EPA 365.1 - Phosphorus : 0.094 _ • mg/L . - -0.050 . 1; 11/14/17 03:25 7723-14-0 . 4500 Chloride Analytical Method: SM 4500-CI-E Chloride = 4.8 mg/L .' : " - 1:0 1 11/09/17 23:15 . 16887-60=6 5310B TOC Analytical Method: SM.531013. Total OrganicCalrbon.2.8 mg/L 1.0 - -1 11/15/1709:11 7446-44-0• _- _. 'REPORT OF LABORATORY ANALYSIS,.',. This reportshall not be reproduced; except in full, Date:.11/1.7/2017 01:58 PM without the written consent of Pace Analytical SerOices, LLC. Page.20 of:44 Pace Analytical -Services, LLC - CZ(iPi/`111G1 _�IVt�l . 2225 Riverside Dr. Asheville, NC 28804 www.pacelabs.com (828)25477176 ANALYTICALRESULTS. Project: Clement Pappas 11/8" Pace Project No.: 92362594 Sample.: Trip Plank.. Lab ID:.92362594009 Collected:: 11/08/17 00:00 •" Received: 11/08/1716:16 -Matrix: Water Parameters Results . Units Report Limit DF Prepared... Analyzed CAS. No. Qua[ 62008.MSV : Analytical Method: SM 620013': Benzene " .. ND ug/L .:.: 0.50 ., 1 11/15/17 15:49 71-43-2' Bromobenzene . _ ND vg/L 0.50. 1 11/15/17:15:49 -"168-86- oroane:. Bromochlmeth ND uglL .. 0.50 1. 11/15/1715:49 ' 74-97=5. Bromodichloromethane... ND ug/L:. 0:50. -1 " ", 11/15/17 15:49 -75-27-4 Bromoform .. ND.. "'. ` :ug/L b0:50 ' - ' 1 11/15/1115:49 75 25-2 Bromomethane .ND :'ug/L 5:0 .1 11/15/17 15:49 74-83-9 n-Butylbenzene ND ug/L" " ".. 0:50 ". 1 :11115/17.15:49".104-51-8" sec-Buty[benzene" ND ug/L : -0.50 :" 1" 11/15/1715:49 :.135-9.8-8 -tert=Butylbenzerie :. ND . ug/L.,. 0.50 1 " 11/15%17 15:49 98-06-6 :. ' -Carbon-tetrachloride ..: ND_: ug/L.: - 0.50 1 -,: 11/15/17 15:49 56-23-5 . Chlorobenzene ND . _ ug/L ._ • -.0.50- • "1_ . 11/15/17 15:49 108790-7 '. Chloroetharfe ND" _ -ug/L : 1.0 1 11115/1715:49:75-00-3 Chloroform ND ug/L 0.60 1 11/15/1715`:49 " 61-66=3. Chloromethane.. :.- -ND ug/L- .1.0 1 11/15/17'15149 74=87=3. .2-Chloroto[uene - ND " -' '::ug/L .0.50 1 - 11/15/17 15:49" '95=49-8.: 4-Ch[6roto[uerie ND . ug/L . 0.50 " " 1: 11/15/17 15:49 - 106-43-4' 1,2-Dibromo-3-chloropropane. - ." ND:ug/L 1:0" .1 11/15/17."15:49 96=12-8 Dibromochloromethane a 'ND ug1L : -0.50 ". 1 11/15/17 15:49 :-124484 .1;2-Dibromoethane"(EDB) " ND_ " ug/L . 0.50 .1. 11/15/17 15:49 '106-93=4: -Dibromomethane " . ND:: _ . "ug/L 0.50- -`1 _: :11/15/17 15:49 74-95-3 .1,2-Dichlorobenzene. ND.- - ug/L . _ _ 0.50: 1.. "" ."_ . ::_ 11/15/17 15:49 -95-50-1' 1,3-Dichlorobenzene :. ND" _ ug/L 0.50. : 1 11'/15/17:15:49 .541-73-1 . 1;4-Dichloroben7ene :. ND " :. ug/L " " "- - 0.50 " - - 4 11/15/17 15:49 106-46-7 Dichilorodifluoromethane• ND ug/L- 0:50. -1 _ ` 11/15/1715A9 -75-71-8 1;1-Di6hloroethane : ND ug/L 0:50". 1 -". 11/15/1715:49 75-34 3 . 1,2-Dichloroethane _ ND ' - ug/L • 6.50 , 1; 11/15/17 15:49 107=06-2 1,1-Dichloroettiene_" ND ug/L 0:50 1 '11/15/17-15:49 -75-35-4 cis-1,2-Dichloroethene. - ND .' - ugl : 0.50 1 .' . 11/15/17 16:49 :.156-59-2 trans-12=Dichloroethene. " "ND . ug/L 0.50 " ' 1.. 11/1511.7 15:49 ' 156-60-5 : 1;2-Dichloropropane - _. ND : ug/L. 0.50- 1 :: " ';11/15117 15:49 78-87-5 . 1,3-Dichloropropane. : ND ug/L--: "- 0.50- 1 -"- 11/15/1715:49-142-28-9,'_. 2,2-Dichloropr6.pane .- -, -. ND ug/L 0.50 : 1 ' - . -" :." 11115/17:15:49 .59420-7" :. 1;1-Dichloropropene :. ND ug/L ' 0.50 1 11115/1715:49' 563-58-6" " cis-,1•,3-Dichloropropene ND ug/L• • _ 0:50 1 11/15/17-15`49 '10061-01-5' .. trans=1,37Dichloropropene . - . '. ND. . " .'. ` .ug/L 0:50 1 11/15/17 15:49. '10061-.02-6 Diisopropyl;ether ND :ug/L . 0.50 1:: 11/15/17 15:49 - 108-20-3. Ethylbenzene : ND ug/L 0:50". .1 '11/"15/17.15:49-.100-41-4:," Hexachloro-1,3-butadiene ND _ " ug%L . 2:0 1 11/15/17 15:49 .-87-68.-3 Isopropylbenzene"(Cumene) ND ug/C 0.50 ' -1" - 11/15/1715:49 .98-82-8 " Methylene Chloride ND:. - ug/L 2.0. 1 -: 11/15/1.715:49 75-09-2 Methyl-tert-butyl ether ND . ug/L 0.50' 1 - 11/15/17 15:49 1634-04-4 Naphthalene _ ND" -ug%L - - 2.0 1 11/15/1716:49 -91-20-3 n=Propylbenzene ND ug/L 0.50 .1 11/1511715:49 .103-65-1 Styrene ND ug/L 0.50 1 11/15M 15:49 _100-42-5 - 1,1,1;2-Tetrachloroethane ND ...ug/L 0:50 .1 11/15/17 15:49 '630-20=6 1,1,2,2-Tetrachloroethane. ND ug/L 6.50 1. _ 11/15/17 15:49 79-34-5 Tetrachloroethene ND Ug/L 0:50 1 11%15/1715.49 127=18-4 REPORT".OF LABORATORY ANALYSIS This -report shall not be reproduced; except in full, Date: 11/1.7/2017 01:58 PM without the written consent'of Pace Analytical Services, LLC. Page 21 of 44 . Pace An alytical Servicesy LLC QD aceAnalical:As 2225 Riverside Dr heville, NC 28804 www.pacela6s.cam - (828)254-7176 ANALYTICAL RESULTS Project; Clement Pappas 11/8 Pace Project No.:. _ .92362594 Sample_:.Trip Blank . .. Lab 0: 92362594009 " 'Collected: 11/08/17 00:00 'Received: 11/08/17 15:10. -Matrix: Water Parameters Results:. Units Report Limit " DF Prepared, Analyzed CAS No. .. Qual 6200B.MSV . Analytical Method: -SM 62006 Toluene- ND ug/L ; 0.50. 1 11/15/1715:49.108-88-3 1,2,3-Tri6h1oroberizene ND -ug/L 2,0_ : 1 11/15/17.15:49:87=61-6 1,2kTrichlorobenzene ND ug/L 2.0 .1 _ :. 11/15/17 15:49' 120-82-1 1,1,1-Trichloroethane ND ug/L- 0.50 1 " '11/15/1715:49 71-65-6 1;1,2-Trichl6roethane ND ug/L 0.50 . 1 ". 11/15/1.715:49. 79-60-5 " Trichloroethene" ND ug/L 6,50 1 11/15/1715:49" 79701-6 " Trichlorofluoromethane" -° ND Ug%L 1.0 1 : :11/15/17.15:49 75=69-4 1,2,3-Trichloropropane_ ND ug/L : ". 0.50 1 .11/15/17 15:49 ;.96-18-4. 1;2,4-Trimethylbe'nzene'.. ND- ug/L - • 0.50 1. - 11/15/17 15:49 -95-63-6 1;3,5-Trimethylbenzene . ND. ug/L. 0.50. T.: 11/15117.15:49 108.67-8. Vinyl chloride ND ug/L .; - 1.0 -1 11/15/17 15:49 "75-01-4 m&p-Xylene _ ND ug/L AO 1 11715/1715:49:1-79601-231:, o-Xylene.... .. ND • ;.". uglL 0.50 " . 1 - ." 11/15/17 15:49 95-4775 Surrogates. 1,2-Dich1oroethane-d4 (S) 102 % 70-130 1 -.11/15/17 -15:49 17060-07-0 4-Brom6fluorobenzene (S) - 97 W , . - ' 70-130 1 11/15/17 15:49 ' 460-00-4 Toluene-08 (S);. .. 98: % 76=130 " _1 . 11/15/17 15:49 ,2037-2875 REPORT'OF LABORATORY ANALYSIS... . This'reportshall not be reproduced, except in full, Dater 11/17/2017 01:58 PM without the written consent of Pace Analytical Services, Ll-C.' Page.22 of 44 Pace Analytical Services; LLC ® aceAnalytical 2225 Riverside.Dr. Asheville, NC 28804 wwwpacelabs.com (828)25477176 '. QUALITY CONTROL DATA Project: Clement Pappas 11/8 Pace. Project No.:. 92362594. QC -Batch:, 386189 AnalysisMethod-` SM 6200B ..QC BatchMethod; . SM 6200E Analysis Description;. 6200B MSV. Associated Lab_ Samples' 92362594001; 92362594002; 92362594003, 92362594004, 92362594005, 92362594006, 92362594007, .92362594008,92362594009 METHOD -BLANK:" 2145266 Matrix: Water " Associated Lab Samples: 92362594001, 92362594002, 92362594003,.92362594004, 92362594005; 92362594006;"92362594007, . 92362594008,92362594009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers: _ 1•,1;1;27Tetrac6l0roet6ane ug/L ND 0:50" .11/15/1711:47 . " ..: 1,1,1-Trichloroethane ug/L ND ." 0.50 1.1/.15/1711:47 1',1,22-Tetrachloroethane :. ug/L ' "... ND .. 0.50 11/15/17 11:47- 1,12-Trichloroethane`. ug/L• ND .. 0.50'.' 11/15/17 11:47 .1,1-Dichloroethane ug/L ND. .. 0.50 11 /15/17 11:47 1,1-Dichloroethene: ug/L W. 0.50 - .11/15/17 11:47- 1,1-Dichloropropene :"" ug/L ND ... 0.5'0 " 11'/15/17 11:47 .. . 1.",2,3-Triohlorobenzerie . ug/L ND :. ." 2,0, .11/15/17 11:47 .. " 1,2,3-lrichloropropane ug/L. ND 0.60.11/15/17-11:47 12;4-Trichlorobenzene ug/L., ND 2.0 .11/15/17 11:47 1,2;4-Trimethylbenzene ug/L. ND 0.50 .' .1,1/15/17 11:47 . . 1,2-1ib�omo-3-chloroproparie ug/L ND' : -1.0 11/.15/17.11:47 1,2-Dibromoethane (EDB) ' ' ug/L ND .. 0.50 11/15/17 1"1:47 .1 2-Dichloeobenzene ug/L -ND 0.50 11/15/17.11:47 1 2-Dichloroethane . . _ :: ug/L ND " . :.:0.50 11/15/1711;47 1,2-Dichloropropane qug/L " .. ND, 0.50 .11/15/17 11:47 " 1,3,5-Trimethyiberizene ug/L- ND' 0.50 11/15/17 11:47 " 1,3-Dichlorobenzene..: ug/L ND 0.50, 11/15/17 11:47 .. 1,3 Dichlo�opropane ug/L ND '.. 0.50 . 11/15/1711:47 1,4=Dich1orotienzene _ _.: ug/L. ND : 0.50_ ..11/15/1711:47 '. 2,2=Dichloropropane - ug/L - ND 0:50 11/15/17 11:47, . 2-Chlorotoluene ' ug/L ND : 0.50 11115/17.11:47 .. 47.Chlorotoluene. ug/L ND .. 0.5o 11/15%17 11:47 Benzene.. ug/L.. ND 0.50.".11/15/1711:47 Bromobenzene.. ug/L ND. '.. 0.50 11/15/1Z 11:47 Bromochloromethane ug%L ND, 0.50 .41/15/17 11;47. - Bromodichloromethane ug/L' ' ND .. 0.50 ' 11/.15/17 11:47 . " Bromoform: ug%L :• ND ".' " ... 0.50. 11/15/17 11:47 -.. Bromomethane., ug/L ND 5.0 ,11/15117"11':47 Carbon tetrachloride ug/L ND 0.50. ,. 11/15/17 11:47 . Chlorobenzene ug/L .; - ND 0.50 .-11/15/17 11:47 Chloroethane , ug/L ND 1.0 1-1/15/17.14;47 ,. Chloroform ,.. .. ug/L " ND 0.50 11/15/17 11:47 Chloromethane ug/L ND 1.0 11/15/17 11:47 .'. cis-1,2-Dichloroethene. u9 /L ND 0.50 11/15/1711:47 6is-1;3-Dichl6ro ro ene P . P. u /L g. ND 0.50 .11/15/17 11:47. . Dibromochloromethane ug/L ND .. 0.50 111.15/1711:47 Dibromomethane ug/L _ ND 0.50. 11/.15/1711:47 Dichlorodifluoromethane ug/L _ ND 0.50 . 11/15/17 11:47 Diisopropyl ether ug/L. NO. 0.50, .11/15/17 11:47 Results' presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result: REPORT :OF LABORATORY ANALYSIS.. . This; report shall not be reproduced; except in full, Date: 11/17/201.7.01:58 PM . without"the written consent of Pace Analytical Services, ILLC. -: Page.23 of 44 Pace Analytical.Services; LLC g//++QQ QQrl�1g // //++ggJJ® ICeAnal fica . 2225"Riverside,Dr. . . Asheville, NC 28804 . . :. wwwpacelabs.com (828)254-7176 . . QUALITY CONTROL DATA Project: Clement Pappas 11/8" Pace Project No.: " ,92362594 " " METHOD, BLANK: .2145266 :: Matrix: Water' Associated Lab.Samples: 92362594001.,.92362594002, 92362594003, 92362594004, 92362594005, 92362594006; 92362594007, 92362594008,92362594009'':" Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Ethylbenzene u9 /L ND . - 0.50 . 11/15/17 11:47. .. " .." Hexachloro-1,3-butadiene"" " . "ug/L_ ; - " ND 2:0 ;11115/17 11:47 Isopropylbenzene'(Cumene) . ug/L ND . 0.50. " 11/:15/17.11:47 . - rh&p;Xylene -." ... ug/L- - ND 1.0 - 11/15/17-11:47 .. Methyl-tert-butyl ether ug/L. .. ND 0.50.. 11/15/17 11 A7 _ ' Methylene Chloride ug/L. ND - 2.0" 11/15/17 11:47 n-Butylbenzene ug/L " ND "" 0..50 11/15/17.11:47 n-Propylbenzene-- . " :: ug/L ND. ": , " 0.50 11/15/17 11 A7 Naphthalene .: ug/L ..ND :.. 2.0. 11/15/17 11:47 o-Xylene ug/L ND. '.. .. 0.50. 11/15/17 11:47 sec-Butylbenzene : ug/L " ND. 0.50 ." 11/15/17 11:47. Styrene ug/L; ND'- 0.50' `11/15M711:47, . tert-Butylbehzene . .. ug/L ..ND 0.50. 11/.15/17 11:47 . . Tetrachloroethene .. : ug/L ND . 0.50 - 11115l17 11:47 : Toluene .. ug/L: ND 0.50.. 11/15/1711'.47 trans-1,2-Dichloroethene . " ug/L- ND "". 0.50 - _11/15/1111:4Z trans-1,3-Dichloropropene; ug/L . ND - - .". 0.50 " _11/15/17 11:47 Trichloroethene ":.' :: ug/L ND_ " .. 0..50 ' 11/15/17 11:47" Trichlorofluororrietharie ug/L ND :: 1:0 " 11/15/17 11:47. _- Vin' chloride '. ug/L ND ': 1.0 . 11/15117 11.:47 1,2=Dichlor6ethane-d4 (S) . . "" . .', ` ; % . ,'. 103 ,'.:. 70-130 .' 11/1"5/17 11:47. 4-Bromofiuor6benzene (S)• % ; 97 -_ " 70-1-30 ; 11/15%17 11:47- - Toluene-c18 (S) . " _ .. %. .. .. .101 70-130. :11/.15/17 .11:47 LABORATORY, CONTROL SAMPLE:. _ 2145267 Spike: LCS ,' LCS .. % Rec Parameter Units Conc. "" Result % Rec . Limits ". Qualifiers 1,1,.1,2-Tetrachloroethane ug/L" : 50 " : "." 51.2" 102 . 60-140 -" 1,1,1-Trichloroethane ug/L. 50. ". " 47.9 96 60-140 .. . 1,1;2,2-Tetrachloroethane "' - ug/C - 50 50.4. - 101 . - " 60-140 1,1;2-Trichloroethane " ug/L 50 49.7 99 6.0-140 1,1-Dichl6roethane - •. ug/L 50 - 48.8 98 :."60-140 1,1-Dichloroethene• ug/L 50. 49.2 98 .60-140. 1',1-Dichloro ro ene p p ug/L 50 40.7 93 .. 60- :140 1,2,34richl6robenzene" .: ug/L 50 50.3 101 " 66-140. 1,2,3-Trichloropropane ug/L '50 " 51.6 103 .. : 607140 1,2,4-Trichlorobenzene ug/L 50 50.9 " - - .102 60-140 1,2,4-Trimethylbenzene. ug/L 50 . 4.0.1 98 .: 60-140. " 12-D-ibrorno-3-chloropropane ug/L . :50. 56.7 : .113 .60-140 . 1,2=Dibromoethane:(EDB) ug/L. 50 52.1 104 60,140' 1,2-Dichlorobenzene ug/L 50" .49.3 99 60A40 1,2-Dichloroethane vg/L 50 52.3 105. _ "" :.60-140 1,2-Dictiloropropane .. - ug/L 50. .48.0 96 '.60-140 Results presented "on this.page are JIn the units 'Indic ated by the "Units" column except where in alternate unit is presented to the right of the result! " REPORT OF LABORATORY ANALYSIS- . i This; reportshall"not he reproduced; except in full, Date: 11/17/2017 01:58 PM without the written consent of. Pace Analytical Services, LLC. Page24 of 44 Pace Arialytical.Services, LLC ® aceAnal ical 2226 Riverside Dr., Asheville, NC 28804 wwwpacelabs.com 1 (828)254 7 76 QUALITY CONTROL DATA Project: "- . -. Clement Pappas 11/8 Pace Project No.: 92362594 LABORATORY CONTROL SAMPLE: '2145267 Spike LCS LC.S - . Re0 , Parameter `Units' Conc: Result % Rec Limits. Qualifiers 1,3,5=Trimethylbenzene" ug/L 50 49.2 98 ,. 66-140 1,3-Dichlorobenze.ne ., .. ug/L 50 48.2. .96 60-140. 1,3-Dichloropropane " ug/L .. .'.:: 50 51:6 103 60-140 1;47Dichlorobenzene - ug/L , 50 - 47.4.. ". " "95 60-140 2,2-Dichloropropane. ug/L 50 . -47:8 96. 60-140 2-Chlorotoluene . ug/L. 50. ". 41.6 95 60-140 4-Chlorotoluene'" .. ug/L, 50 . , 48.8 -98 .' .. -60-140 ..: Benzene .' . ug/L .. 50 46.8. 94 60-140 Bromobenzene ug/L .. .50 49.0 98, 60-140 Bromochloromethane : ju61L 56 49.6 ...99 60-140 " " Bromodichloromethane ug/L 50.. 49.8 " " .. " 100 : .60-140, " Bromoform . ug/L 50 57.8 116 60-140. " Bromomethane : .. ug/L 50." " ... ' 50:0 100 60 140 Carbon tetrachloride ug/L :: 50 46.7. 93, 60-140 Chlorobenzene ug/L : "",: 50 . 48:9' 98. 60-140 Chloroethane ..... ug/L. " " 50. . " 44.6 .. .. .89 . " . , 60-140 Chloroform .... .. ug/L" 50 .. 46.2 92 60-140 Chloromethane ug/L.' .: 50- ." 45.1.: 90 ' 60-140 cis-1,2-Dichloroethene .'. u /L .. " .' .50" 49.5 99 60-140 cis-1,3-Dichloropropene ug/L - 50 50.5 101 ". 60-140 Dibromochloromethane ug/L 50 - 54.0 108.. 60-140- Dibromomethane ug/L 50 50.0 100 60-140. Dichlorodifluoromethane ug/L " . : _ : 50 " ., - . "','.:31:3 63 60-140 Diisopropyl ether ug/L". - 50 49.5 '99 60-140 Ethylbenzene ." ug/L : 50 . =' : - 49.1 98. 60-140 Hexachl6ro-1,3-butadiene ug/L 50.' - 512 . 102 " . . 60-140 Isopropylbenzerie (Curriene) . ug/L" 50'.: 48.8 98 - -'60-_140 m&p-Xylene "" ug/L .. 100 - . "98.3. 98 '60-140 "Methyl-tert-butyl ether'.' ug/L .50 -48.4 97 60-.140', : Methylene Chloride .. ug/L 56 50.6 _ 101 . "60-140. .. n=Butylbenzene' . • ' u9/L :." 50.. " 49.4 .. 99 60-140 . . n-Propylbehzehe " ug/L 50 .48.7- . 97 60-140 Naphthalene ug/L 50-- 51.6 1.03 60140 o-Xylene' .: ug/L- '.50 49.3 99 60-140 "sec-Butylbenzene ug/L :- .: 50 . -48:9 98. 60-140 - . .. S.tyrene:" - ug/L 50. 56.1 -. 100 .. 60-140 ... - tert-.Butylbenzehe : ug/L • 50 - 40.0 180 60-140 - Tetrachloroethene. ug/L ": 50 48.3 97 - 60.140 - - Toluene " ug/L 50- 47.5 95 60.140. trans-.1,2-Dichloroethene _' . ug/L ". 50 -48.1 96 ". 60-140 trans-1,3-Dichloropropene ug/L .50 -" 49.5 .99 ;. 60-140 Trichloroethene, ug/L 50 -. 46.8 94 60-140 Trichlorofluoromethane ug/L 50 _ . 42:7 .85 60-140 Vinyl.chloride" ug/L - .50 45.9 92: 60-140 1,2-Dichloroethane-d4 (S) .. % 99 70-130 " 47Brom6fluorobenzene (S) :_ % " 98 70-130 - Toluene=il8 (S) . •" %. 98 70-130 - - Results presented on this.page' are in the units indicated by the "Units" column except where'an alternate unit is presented to the right of the result: REPORT OF .LABORATORY ANALYSIS . This report shall not be reproduced, except in full, Date: 11/17/201,7 01:58 PM without the written consent of.Pace Analytical Services, LLC. - Page 25 of 44 Pace Analytical Services, LLC 2225 Riverside Dr._ Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2145268 2145269 MS MSD . 923625940.08 : Spike Spike '. MS MSD; I MS MSD: % Rep Parameter -Units :.-Result.. :Cone. -Conc.. Result. Result %'Rec % Rec : Limits 'RPD Qual 1,1,1,2-Tetrachloroethane. ug/L,... ND . '_ . 20 ', 20 20.5 . 19.8 ., :: 103 _ . 99.,'.60-140 . 4 ..:: 1,1,1=Teichloroethabe 41 ND' '; 20. 20 21.9 ,, .. 21.0 109'. :105 60-140 . 4: 1,1,2,2-Tetrachloroethane_ uglL ND. 20 20 , • . 19.8 _ 18.5, 99 '93 60-140 , 6 . 1,1,2-Trichloroethane ug/L ND .: 20 20 21.5 20.0 . 108 : -100 60-.140 7 1,1-Dichloroethane ug/L. : ND.: 20 : 20 21.5 21.0 .. 1,07 105. 60-140 . 2 1,1=Dichloroethene. ug/L ,- ND .-'.20 20.. _230.,.. 223 . 115.112, .60-140 3.. 1j-Dichlor6pr9pene ug/L, ... '. ND .. 20 20. 21.8 ..: 20.6 .109.1 103 .6.0-140: 5. 1,2,3-Trichlorobenzene.. ug/L . _: ND 20 20 19.2- 18.7. -96.. - 9.4 .60-140 3 .. 1,2;3-Trichlor6propane ;'ug/L • ND. 20 : 20_ 19.8 19.0 :. 99 -. 95. 60-140 4. 1,2;4=Teichlorobenzene ug/L - ND'. '20 .. 20 200 19.4 _: 100 97, 60.140 -3 1,2,4-Trimethylbenzene'. - ug/L., .. ND . 20 20 21.1 . `19.3 - - 105 96...60A40 . ` 9 . 1,2-Dibromo:3-chloropropane . ug/L ND :: 20, 20 18.8.: '18.5 94 _ . 92 60-1.40 . 2 1;2-Dibromoethane (EDB_), ug/L : ND. .20. 20 . • , 20.4 : _ 19.8 102' 99 60-140 _ - -3 1,2-Dichlorobenzene` ug/L .. :ND 20 20 20.2. :' : 18.8 . 101 94 60-.140 7, 1,2-Dichl6roethane . _ ug/L. - : ND 20 :. 20 21.4 20.8 1.07. 104 ,'' 60=140 3 1,2=Dichloropropene ;. . _ ug/L -- ND 20 ' ..._ 26:. . ' 21.2. 19.9 _ 106• 100, 60-140 . 6:. : 1,3,5-Trimethylbenzene.. ug/L ND - .. 20 20 '20.9 19.4 104 97 60-140 . 7. 1,3-Dichlorobenzene .ug/L :.. ND W. 20 20. d. .20.2 ..' 18.8 101 94 :60-140. - 7 1,3-Dichloropropane : ug/L ' ND- 20 . 20 _ 20.7 20.1 : - 103 •101. 60-140 3 1,4-Dichlorobeniene:. ' ug/L. ND : 20 20 19.8.... ' 18.4- '. 99 92. 60-140 . ..7 2,2-Diichlor6propane - .. „ ug/L. - - ND 20 20 .. 20.8 . 19.9 :. - . 104 ' 99..:60-140' , '. 5 2-Chl6rotoluene ' ug/L ND ': 20. .. 20.: : 20.1_ . ,. 19.1 :-.101' . 95 60-140 6: 4-Chl6rotoluene - ' ug/L :. ND. 20 20 20.6 19.2 - 103 96 .-60-140 7 _ Benzene. ug/L ND 20'.. 20." 20.4.' 19.4.... 102 97 60-.140 5. Bromobenzene .. ug/L ND. . 20 ; 20 20.9 19.3 - . 1.05 97 , 60-140 ." 8 Bromochloromethane. ".. ug/L -. ND :: 20 ... 20:. .21.8.. 20.7 .- 109.. 104.' .60.140 5; Bromodichloromethane _. ug/L : - ND .. 20 20. 21.2 19.6 -106 .: 98, 60-140.: 8 Bromoform, . ug/L- .: ND .20 20 -.20.1 18.8. 100- . 94 . 60-140 . 6- .. :. Bromomethane -, . ug/L - ,' ND 20 .: 20 13.7 '.. 16.3 .. 69 81. 66-:140 17 Carbon'tetrachloride.:. : ; ug/L ND' , .. 20 20 21.8 - . '20.1, '. 109 100. 60-140 8 Chlorobenzene- ug/L ND 20 '20 :.20.7 '19.7 103. 98. 60.140 5 Chloroethane ug/L ND- :: 20. '. 20 22.7 20.5 114' ,', `1:03 60-1.40 . 10 Chloroform ug/L . ND. 20 20:' 20.0 19.1 _100 96 . 60-140 ; 4 Chloromethane ug/L ND - 20 .. 20 22:7. ,21'.6 . 11.4 . 08 -60440` 5. cis-1;2-Dichloroethene, .: ug/L ND... 20 :. 20 21.7 21.2 .. 1.09•' ...106. 60-140 .3 cis=1,3-Dichloropropene. ug/L ND 20 .. 20: 21.3 _ - 19.6 107- 98. 60-140. 8: Dib'romochlaromethane... ug/L ND 20 20. . _20.T - :: 19.7 --103':: 99 _ 60-140_: Dibromomethane... ug/L ..: `• ND .20 - .. 20 .21.0 - .' 19.4. 105..' - 9.7 . 60-140 . -8 Dichlorodifluoromethane ug/L ND 20 - 20 . : 21.1 20,0. - 106 '. , 100 60-.140 5 Diisopropyl ether ug/L ND 20 . 20 21.2. 20.9 - 106 104. 60-140 1 Ethylbenzene ug/L . - ND 20 20 20.9 19.7 104 98 . 60-140' 6 - Hexachloro-1,3-butadiene 'ug%L ND''-; 20.- 20 19.6 19.6 98'_ . 9 .8 60-140 6 Isopropylbenzene (Cumerie) ug/L ND. 20 20' 21.3 : 19.9. - - ..107:. 99 60-140 -7 m&p-Xylene : ug/L ND 40 40 42.4. 39.7 . 106 99 60-.1.40 7 - Methyl -tart -butyl ether ug/L. NP.. 20 . 20 . -19.7 19.8 98 99 6o-140 1 Methylene. Chloride ug/L ND 20 20 21.6 20.0 108 100 60.140 8. Results' presented on this.page are In the units Indicated by the "Units" column exceptwhere'an alternate unit is presented to the right of the result: REPORT OF LABORATORY ANALYSIS This. report shall not be reproduced, except in full, Date: 11/17/201.7 01:59 PM without the written consent of Pace Analytical Services,-LLC. Page.26 of'44 Pace Analytical Services; LLC . aceAnalyticaf. 2225 Riverside Dr. Asheville, NC 28804 . . -pacelabs.com ;. (828)254-7176 QUALITY CONTROL DATA Project: Clement Pappas 11/8 Pace Project No:: 92362594 .' MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2145268 2145269 MS .. MSD_ . 92362594008 "Spike - Spike _ MS MSD; M$ MSD % Rec . Parameter Units Result.. :Conc.- Conc. Result. Result: % Rec %.Rec . Limits RPD Qual n-Butylbenzene . : ug/L" ., .' ND . 20 20 20.3 . 19.4 - 101 97 ..60-140 4 n-Prooylbenzene: ug/L ND : 20--- : . 20. 21.2 :. 19.8 .106 .. 99 60-1.40 . 7 Naphthalene .. ' ug/L ND. " 20 20:' .19.6 18:3 98 92 60-140 - .7 ' , 0-Xylene. ug/L ND . • 20 20 21.1. 19.6. .... 105 98 60--140 7 - : - sec-Butylbenze.ne ug/L. ND = 20 .. '20 21.0 19.9 _ _ ' : 1,05 99 60-140 6 Styrene . , : Ug/L ND ' 20 ' .. 20 :. 26.7.. 10.4 103. 97- . 60-140 :...6 :. .. tert-Butylbenzene ug7L - . ND 20 20. 17.2 16,1 86 81 60-140: - 7 Tetrachloroethene :. ug/L .. ND 20 20 20.6 _ . 19.8. 103 99 60-140 . 4. Toluene.- ug/L. ND . 20 20, :. 21.4 19.4 :: 107 97: 60-.140 10 trans-1,2-Dichloroethene .. ug/L. ND . 20 .. 20' :. 22.0.'. 2:1.2 :. 110 106- 60-14o . '.4 trans- 1,3-Dichloropropene ug/L.. ND. 20 ''_ 20 .. 20.6- 18.8 103 94. -60-140 -" 9 Trichloroettiene' '; ug/L ND 20 20 21.3 19.5 107 '_ 98 60-140 . 9. Trichlorofluoromethane ug/L . '. _ ND. 20 - 20: 21.8 21.2 109 _ - 106 60-140 ; 3 Vinyl chloride ug/L ND 20 .. 20. 23A. . "..22.2 . 117 111 60-140 5 1,2-Dichloroethane-d4.(S) '.' % ". 1.00 104. 70 130 ' 47Bromofluorobenzene (S) % ' " 99 99 .-70-130 Toluene-d8 (S) . "/0 103 99 ..70-130. , Results presented "on this page'are in the units Indicated by the "Units" column except where'an alternate unit is presented to the right of the result." REPORT OF LABORATORY ANALYSIS-.: . This: report shall not be reproduced; except in full, : - - Date: 11/17/201.7 01:59 PM without the written consent of. Pace Analytical SeniicesrLLC. ,. Page.27 of:44 Pace Analytical Services, LLC ®. aceAnalytical 2225 Riverside Dr. Asheville, NC 28804 wwwpacelabs.com (828)254-7176 QUALITY CONTROL DATA ' Project: Clement Pappas 11/8 Pace Project No.:. 92362594 QC Batch: 386203 ' Analysis Method: SM 2540C QC Batch. Method; . SM:2540C Analysis_ Description;, .. 2540C-Total Dissolved Solids. -. Associated Lab. Samples. .92362594001; 92362594002, 92362594003, 92362594004, 92362594005, 92362594006. ' METHOD BLANK:. 2141990 Matrix: Water Associated Lab Samples. _ 92362594001, 92362594002, 92362594003, 92362594004, 92362594005, 92362594006 Blank' :. Reporting Parameter Units - _ Result Limit Analyzed Qualifiers Total Dissolved.Solids- . mg/L NO 25.0 11/10/17 11:20 LABORATORY CONTROL SAMPLE: ,2141991 . Spike LCS LCS . %.Rec' Parameter .. - Units : Conc. .. Result . %:Reiff Limits Qualifiers, . ` = Total Dissolved Solids mg/L 250 252 1.01 90-110 SAMPLE DUPLICATE: 2141992 92362395012 .. :-Dup. " .. Parameter Units : Result :- Result RPD • , Qualifiers Total: Dissolved Solids . mg/L235 . 244 4 SAMPLE DUPLICATE`. 2141993 ... 92362542001. Dup_.. Parameter Units -Result . - Result RPD Qualifiers . Total: Dissolved Solids . ' : mg/L 700 .: :700 -". 0 p. - Results presented on this page -are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result:' -REPORT PORT OF LABORATORY ANALYSIS This reportshall not be reproduced- except in full, Date:11/17/2017 01:58 PM without the written consent of. Pace Analytical Services, LLC. Page.28 of 44 - .. n PaceA alyticaLServices,LLC ® aceAnalytical 2225-Riverside Dr.. . . Asheville; NC 28804 wwwpacela6s com : (828)25477176 .:. . . QUALITY CONTROL DATA Project: Clement Pappas 11/8 . Pace Project No.:-'. .92362594. . " QC: Batch:. 386448 ` Analysis Method:'. SM 2640C _QC Batch _Method:. SM 2540C . Analysis. Description; :. 2540CTotal.Dissolved Solids. Associated Lab.Samples: 92362594007; 92362594008 METHOD BLANK:- 2143338 1Matrix: _Water Associated Lab Samples: , 92362594007i 92362594008. ; • Blank: .. Reporting „ . Parameter Units Result- Limit Analyzed 'Qualifiers Total Disstilved.Solids.. mg/L ND 25.0 11/13/17 09:14 :. LABORATORY CONTROL. SAMPLE: ` :2143339 " . LCS LCS . % Rec Spike Parameter Units . Conc. Result %:Rec Limits , Qualifiers . Total Dissolved Solids mg/L 250 240 96 90_110 SAMPLE DUPLICATE: '2143340... .'... 92362594007 Dup Parameter Units Result Result RPD ... - Qualifiers Total Dissolved Solids . mg%L .' 44.0 51.0 T5 D6 SAMPLE DUPLICATE`. 2143341 92362624009. Dup.. Parameter .. . Units .: Result ..: Result RPD Qualifiers . Total: Dissolved Solids:mg/L. ND No . Results'presented on this page'are In the units Indicated by the "Units-" column except where an alternate unit Is presented to the right of the result:' - REPORT OF LABORATORY ANALYSIS .. This: report shall not be reproduced; except in full, Date: 11/1-7/201.7 01:59 PM without the written consent of Pace Analytical Services,'LLC. - Page.29 of 44 Pace Analytical Services, LLC . ® aceAnalytical 2225 Riverside Dr. . . Asheville, NC 28804 www.psce/abicom : (828)254; 7176 QUALITY CONTROL DATA• Project: Clement Pappas 11/8 Pace. Project No.: . 92362594 QC -Batch: 386064 '; Analysis Method:', ... SM. 9222D QC Batch_Method> . $M;9222D . Analysis_Description:., :: 9222D MBIO Fecal Coliform -.AVL . ,• Associated Lab.Samples' '92362594002; 92362594003, 92362594004, 92362594005, 92362594006,-92362594008 METHOD BLANK: 2141227. Matrix: Water Associated Lab Samples:'' 92362594002, 92362594003, 92362594004, 92362594005,.92362594006, 92362544008 . Blank Reporting Parameter Units Result. Limit Analyzed"_ Qualifiers Fecal Coliforms CFU/100 mL -. ND ... 1.0 11/08/17 15:54 SAMPLE DUPLICATE: 2141228• ... . 92362594005 .. Dup Parameter Units Result. Result �_RPD Qualifiers Fecal :: GFU/400 mL = ND ... 3.0 ; . u1 . I. - - - Results -presented on this page'are in the units Indicated by the "Units" column except where'an alternate unit is presented to the right of the result: . REPORT OF LABORATORY ANALYSIS'.. This. report shall note reproduced, except in full, Date: 11/17/201.7.01:58 PM ." without the written consent of Pace Analytical Services, LLC. Page.30 of:44 Pace Analytical Services, LLC fWt�!'111QL��VQI 2225 Riverside Dr. Asheville, NC 28804 wwwpacelabs.com (628)25477176 QUALITY CONTROL DATA Project: Clement Pappas 11/8 Pace Project No.:" . 92362594 QC Batch:. 386078 Analysis Method: . ' .' . SM W22D QC Batch Method: ' SM 9222D . Analysis, Description:,9222D MBIO Fecal Coliform -.AVL Associated Lab.Samples. . '92362594001; 92362594007- METHOD BLANK:. 2141307 Matrix: Water Associated'Lab Samples:' 92362594001; 92362594007' Blank,' :. Reporting Parameter Units Result_ '' Limit- Analyzed Qualifiers Fecal Coliforms'. • CFU/100 mL .. - ND 1.0 11/08/17 16:33 SAMPLE DUPLICATE:- 2141308 .. 92362596001' Dup - Parameter Units - Result. Result RPD .. Qualifiers Fecal Coliforrms -CFU/100 mL ` . ND . ND . Results'presented on this page are in the units indicated by the "Units" column except where'an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS.. " This report shall not be reproduced; except in full, Dater 11/171201.7 01:58 PM without the written consent of. Pace Analytical Services, LLC. ", Page.31 of'44 Pace Analytical Services; LLC . �Ve/'111Q1 2225Riverside Asheville, NC 2880404 ' .. wwwpacelabs.com (828)254-7176 QUALITY CONTROL DATA .' Project: Clement Pappas 11/8 Pace Project No.:, 92362594 QC Batch: 386861 ` Analysis Method: EPA 350.1 1993-Rev 2.0 QC Batch.Method> . EPA350.1 19.93 Rev.2.0 Analysis. Description:..' 35.0.1 Ammonia Associated Lab.Samples- `92362594001; 92362594002;.92362594003,.92362594004, 92362594005, 92362594006, 92362594007; . .. 92362594008 . METHOD BLANK:. 2145511. Matrix- Water Associated Lab Samples: 92362594001', 92362594002, 92362594003, '92362594004, 92362594005,-92362594006; 92362594007, - 92362594008 Blank. Reporting .. Parameter Units, Result Limit Analyzed Qualifiers Nitrogen; Ammonia. mg/L". ND 0,:10 .1;1/•15/1712:14'. _ LABORATORY CONTROL SAMPLE:. 2145512 . Spike . LCS ' :. LCS % Rec . Parameter Units ..::: Conc. - _ Result %Rec :: Limits . Qualiifiers ... Nitrogen, Ammonia, : _ mg/L 5 5.0 100 : 90-110: MATRIX SPIKE & MATRIX SPIKE DUPLICATE:- " 2145513, 2145514 MSMSD . 92362558003 Spike Spike MS' MSD MS: MSD .. %Rec'. Parameter -Units .Result.. Conc. Conc.. Result.' -Result %°-Rec %Rec Limits 'RPD Qua] -. Nitrogen, -Ammonia. rng/L.': 24.6 .''. • 5 5.. 29.0 28.8. 88 . '' 85' `90-110 '. '' 11 M1 MATRIX SPIKE & _MATRIX SPIKE.DUPLICATE:.. 2145515 2145516 . ' - MS MSD 92362644001' :Spike Spike MS' MSD : MS .. MSD .' % Rec Parameter .: - Units Result Conc.. Conc. Result 'Result. % Rec : %o' Rec '.Limits, :RPD. Qua[ Nitrogen, Ammonia mg/L. ' .• ND.: 5 :: 5 '5.1 - . 5.0 .. ' 99' 99 . 90=110 .. 0 . Results presented on this.page are In the units indicated by the "Units" column except where -in alternate unit is presented to the right of the result. - REPORT OF LABORATORY ANALYSIS. This; report shall not be reproduced, except in full, Date: 11/17/2017 01:58 PM without the written consent 'of.PaceAnalytical Services,'LLC. .. - Page.32 of';44 1 Pace Analytical Servicesi LLC ® aceAnal q1, 2226 Riverside Dr. Asheville, NC 28804 wwwpscelabs.com „ (828)25477176 QUALITY "CONTROL DATA Project: ".. Clement Pappas 11/8 Pace. Project No.: _ 92362594 " QC- Batch::: -385932 ' " " Analysis Method:' EPA 353.2 QC Batch _Method:. EPA 353.2. .:: _ " .' Analysis, Description: _ :. 353:2: Nitrate + Nitrite; Uripres. Associated "Lab.Samples' 92362594001; 92362594002; 92362594003, 92362594004, 92362594005,'92362594006.; 92362594007; . . 92362594008 " METHOD BLANK: 2140482 Matrix: Water . Associated Lab'Samples: '92362594001, 92362594002192362594003,.92362594004, 92362594005; 92362594006, 92362594007, 92362594008 „.. •Blank . Reporting Parameter `Units Result Limit - Analyzed Qualifiers Nitrogen; Nitrate ." " ", .. mg/L' . ND 0,020-:.11/09/1701:59. LABORATORY CONTROL SAMPLE:. 21.40483.. _Spike LCS . LCS . Rec . . Parameter Units Conc. Result % Rec Limits Qualifiers, Nitrogen,"Nitrate mg/L .. 2.5 2.4 96 . 90010• . MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2140484 . _ 2140485 •, :. . MS':. MSD 9236241Q001 Spike Spike MS MSD MS- MSD_ " % Rec Parameter Units Result.. Gone. ""Cone.. " : Result. Result' : % Rec _ %Rec . "Limits RPD Qual Nitrogen, Nitrate mg/L _ :: 0.18 - . - 2.5 2.5 ". 2.9 2.9 107 ' 107 ` 90-110 0 MATRIX SPIKE &MATRIX SPIKE DUPLICATE:.. 2140486 ." 2140487. MS- :" MSD"... . 92362424001 "' :Spike. Spike" " :. ".MS . ". MSD MS .. _ MSD. "' % Rec." Parameter Units .. Result - " . Conc, Conc. Result 'Result % Rec _ : % Rec Limits_ :RPD. Qual Nitrogen, Nitrate mg/L. 37,7. - 0.6 2 5 -" .2.5 4 42.2 146 177 90110 4 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result:' REPORT OF LABORATORY ANALYSIS'. This: reportshall not be reproduced; except in full, ' Date: 11/17/2017. 01:59 PM without the written consent of. Pace Analytical Services, LLC. - -Page.33 of 44 Pace Analytical Services, LLC ® aceAnal0001. 2226 Riverside Dr. .. - Asheville, NC 28804 www.pacelabs.com (828)25477176 QUALITY CONTROL DATA Project: Clement Pappas 11/8 Pace .Project No.: .92362594 .. QC. Batch:386579 ' Analysis Method: EPA 365.1 QC'Batch Methodi EPA 365.1 Analysis, Description:_ 365.1. Phosphorus, Total . Associated Lab. Samples' 92362594001, 92362594002, 92362594003, .92362594004, 92362594005, 92362594006., 92362594007; 92362594008 .-. METHOD 'BLANK: . 2144066 Matrix`. Water Associated Lab Samples: 92362594001, 92362594002; 92362594003,.92362594004, 92362594005, 92362594006, 92362594007, . 92362594008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phosphorus. .. .. mg/L . -- ND 0.050 .".11/14/1763:15 LABORATORY CONTROL SAMPLE: 2144067.. Spike . LCS. LCS.% Rec. Parameter Units Conc.. Result %-Rec Limits . Qualifiers. Phosphorus .. mg/L 2.5 2.5 101 . 90-110. :. MATRIX SPIKE-& MATRIX SPIKE DUPLICATE: 2144069 . .' _ 2144069.. `. MS:. MSD . 92362503001 Spike Spike MS MSD MS MSD % Red Parameter Units Result Conc. Conc.. Result Result %Rec %•Rec : Limits RPD Qual Phosphorus . ' mg/L.: 0.74 . '. 2.5 2.5 ` 3.3 3.3 :: 104 .' 103 90-110 0 - MATRIX SPIKE & MATRIX SPIKE DUPLICATE:.. '2144070 2144071 . -MS .. MSD. . 2 % Re 9 362375003 Spike Spike' MS MSD :. MS ... MSD. c.- - Parameter. .. Units .. Result Conc.. Conc. Result, Result % Rec •' •: %Rec Limits .RPD - Qual - Phosphorus mg/L. ND. - 2:5 : 2.5 2.6 2.6 102 103. 90 110 1 - Results' presented 'on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced; except in full, Date: 11/17/2017 01:58 PM without the written consent of Pace Analytical Services, LLC. Page.34 of 44 Pace Analytical Services; LLC . ®' �Ce/� IaI ICI .. 2225 Riverside Dr. - .. Asheville, NC 28804 ' - wrw.pacelabs.com _ (828)254-7176 QUALITY-CONTROL'DA A Project: Clement Pappas 11/8 Pace Project No:: 92362594 QC -Batch: 386135 Analysis Method: SM 4500-0I-E . . QC Batch,Method`.. SM:4500-CI-E: , _ .: Analysis Description: 45.00 Chloride Associated'Lab Samples'.'-92362594001, 92362594002, 92362594003, 92362594004, 92362594005,923625940061-92362594007; . 92362594008 METHOD BLANK: 2141724 Matrix: Water Associated Lab Samples: 92362594001;92362594002;923.62594003,92362594004,92362594005,92362594006,92362594007,. 92362594008 .•Blank, Reporting Parameter Units .. - Result . Limit Analyzed Qualifiers_. . mg -; -ND - 1.0 .11/09/1722:36 .. Chloride .: m L'ABORATORY.CONTROL SAMPLE:. 2141725.' .Spike LCS LCS .. % Red . Parameter Units - . Conc.. Result % Rec :: Limits . Qualifiers Chloride - mg/L . .. • 20 _ , 21.4 107 90 110 : - . MATRIX SPIKE & MATRIX SPIKE DUPLICATE: ,, 2141726 214.1727,, : : MS :. MSD- 92362700001 Spike Spike MS MSD MS MSD% Rec Parameter Units Result. Conc. Conc.. Result. Result %Rea : %Rec : Limits: -RPD Qua[ Chloride _ mg/L, ; 38.4 .. ';10 '10 ,', 56.1 3 57.:. 177 189: :90-110 2 M1 " MATRIX SPIKE &MATRIX SPIKE DUPLICATE:' .. 2141728 2141729. MS MSD .. 92362421001_ ;Spike Spike MS MSD : MS MSD - '% Rec.. . Parameter' Units Result Conc.. Cobc: Result Result % Rec •'%-Rec Limits .RPD Qual Chloride mg/L. - 144 : 10 : 10 .. -154 153 90 83 90;11�0. 0 M6 " . Results' presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.' REPORT -OF LABORATORY ANALYSIS This report'shall not,be reproduced, except in full, Date: 11/17/201.7. 01:58 PM without the written consent of Pace Analytical Semites, LLC. Page.35 of:44 'Pace Analytical Services; LLC . ® a CeAllc7��/tIGB�.' 2225 Riverside_Dr.- Asheville, NC 28804 ".. :. wwwpace(abs.com. .. (828)25477176 . . QUALITY CONTROL DATA Project: " Clement Pappas 11/8 Pace Project No.: _ 92362594 QC. Batch::: 386596 : Analysis Method:. SM 53109 QC-Baich.Mbthcd:. SM :53108 . .. Analysis, Description:. :. 5310E TOC. Associated Lab.Samples: _ 92362594005. . METHOD BLANK:." 2144127." Matdx:.Water Associated'Lab Samples: ", "92362594065" Blank :. Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon.., :::. .. mg/L - .. ":. ND 1.0 : 11/14/17 23:52 . _ " LABORATORY CONTROL SAMPLE:2144128" .. Pike LCS LCS,.. S . %.Rec .". Parameter Units : Conc. ... Result :.. %:Rec Limits: Qualifier's. Total Organic Carbon " mg/L • 25'. ; . _ `.. 2&6 - .95 90-110 -: MATRIX SPIKE:& MATRIX SPIKE DUPLICATE:: 214.4129 2144130" MSD"." ;. .. 92362393015 ' : Spike Spike MS MSD, . MS MSD " %:Rec. Parameter - .. ; Units ..: Result: . Conc. .: Conc. .'Result .Result . % Rec ' .. %Rec Limits' - -RPD. Qual Total.OrganicCarbon;' 'mg/L 0.60J. :" :." 25 . 25 23.1"" .24.6 ." 90 ... " 96 90=110 "' .6 MATRIXSPIKE& MATRIX"SPIKE DUPLICATE`. .'2144131: _ .. 2144.132 MS' , , ..MSD . . 92362393016 Spike Spike " M.S " .. " MSD "." MS :: " MSD ".%'Rec Parameter. Units. Result .. Conc. Conc.. "" Result °. Result .% Rec., %.Rec :.. Limits RPD :. dual - Total Organic Carbon - mg/L. ND 25• " 25, •' 23.4 ;-: 23.9' 92-.: 94'.90-110. - 2 " .'Results presented on this page are in the units Indicated by the "Units" column except where'an alternate unit is presented to the right of the result: " P RE ORT OF LABORATORY ANALYSIS This report shall not be reproduced; jexcept.in full, Date:" 11/1-7/201.7 01:58 PM ." -without the written consent of. Pace Analytical Services, LLC. Page.36 of44 - - Pace Analytical Services; LLC 2225 Riverside Dr._ Asheville, NC 28804 wwwpacela6s.com (828)25477176 -QUALITY CONTROL DATA Project: Clement Pappas 11/8 Pace Project No.: 92362594 QC Batch:386697 : ' Analysis Method: SM 53106 QC Batch Method:. SM.5310B Analysis Description: :. 5310B TOC Associated Lab.Samples- ' 92362594002; 92362594003, 92362594004, 92362594006, 92362594007, 92362594008 METHOD BLANK:. 2144133 Matrix:.Water Associated Lab Samples: 92362594002; 92362594003, 92362594004, 92362594006, 92362594007, 92362594008 Blank Reporting Parameter _ Units Result. Limit Analyzed Qualifiers Total'Organic Carbon mg/L ND 1.0 : 11/15117 06:45 LABORATORY CONTROL, SAMPLE:. ;2144134 Spike ... LCS LCS . -' %.Rec Parameter Units Conc.. ' Result .. %:Rec . Limits Qualifier's Total Organic Carbon Mg/L ' '.: 25' .'' 23:9 96 90-110 - MATRIX'SPIKE & MATRIX SPIKE DUPLICATE:. 214,4135 ".. 2144136: - -MS MSD. 92362594002 . Spike "Spike MS MSD, MS :- MSD. %.Rec Parameter' :.: Units' Result- . Conc. .: Conc: .. Result Result :. %Rec ' .. %'Rec .Limits ..RPD... Qual" Total Organic Carbon. mg/L 6.7 .25. .25 29.5- = - -.29.4 :" 91 91 90-110 0 MATRIX SPIKE & MATRIX SPIKE -DUPLICATE: ' 214413Z 2144.138' "_ MS' MSD,. 92362594003 - 'Spike ' .. Spike MS .. MSD MS.. MSD %Rec _ Parameter.. Units Result .. Conc. Conc. . Result .. Result % Rec % Rec :. Limits RPD Qua[ . Total Organic Carbon 'mg/L.' 1.4 25 25. 23.9 , - - : 23.8 '" .. - 90 90 _. 90-110, : - 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. . REPORT OF LABORATORY ANALYSIS . This. report shall not be reproduced, except in full, _ Dater 11/17/2017 01:58 PM without the written consent of Pace Analytical Services, LLC. Page.37 of 44 Pace Analytical Services; LLC" " ® aceAhj1Xjc01 2225 Riverside Dr. .. Ash'evillej NC 28804 wwwpacelabs.com . ... . (828)254.7176 QUALITY CONTROL DATA = Project: Clement Pappas 11/8 -Pace Project No.: 92362594 QC. Batch:: 386151 ': Analysis Method: ". SM 5310B ". QC'Batch.Method:_ . SM:531013 . '..' .. ,'.:: Analysis Description:..5310B TOC Associated Lab•Samples' 92362594001. . METHOD BLANK:, 2145118, Matrix:. Water. Associated Lab Samples:'', 92362594001 " Blank :. Reporting Parameter Units Result, Limit' Analyzed.: Qualifiers Total'OrganicCarbon.:. ,'. mg/L ND .':: :.. 1..0 11/15/1718:19 LABORATORY CONTROL SAMPLE:-2145119 L .Rec' Spike LCS CS %.; , Parameter :. Units : Conc: ' .. Result ... . %=ROc . Limits: - -Qualifiers ' Total Organic Carbon mg/L ' 25 ' . 23:7 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: ;• .2145120 ".. - 2145121 MS., MSD 92362624.015 .. Spike Spike .. MS MSD. MS :. MSD % Rec .: Parameter'' ..: Units' • .: Result - Conc:.: Conc: .. Result Result .. '% Rec ' . - %' Red Limits _RPID ''Qual ` . . Total Organic Carbon:_ - .. mg/C ND..' : 25 . 25 : 23.0 _ 24.9 92 96 90=110 ..4 MATRIX SPIKE' & MATRIX SPIKE_ DUPLICATE`. 2145122 " . 2145123 .. MS MSD 92362630010 'Spike. Spike MS" :. MSD MS.. MSD %Rec Parameter.. Units Result Codc. Conc.. Result Result % Red, % Rec. Limits RPD Quay N Total Organic Carbon mg/L D ..' 25_ 25. 23.3' 23.9 93:: . 96'_ .90-110; 3. Resuits'presented on this page -are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result; ' REPORT OF LABORATORY ANALYSIS " This report shall not be reproduced; except in full, Date: 11/17/2017.01:513 PM without the written consent of Pace Analytical Services, LLC. Page.38 of 44 aCeAnaIXical www.pacelabs.com -QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC . 2225 Riverside Dr.. Asheville, NC 28804 (828)254-7176 Project: Clement Pappas 11/8 Pace. Project No.:. - 92362594 _ . Analytical Lab"ll) Sample ID QC Batch Method- - QC Batch. _ AnalyticaLMethod• Batch; 92362594001, MW-4 SM 6200B 386789. 92362594002 . MW-5, . SM 6200B. 386789. 92362594003,; MW-6 SM 6200B .. 386789 92362594004 MW-7R . :. SM 62006 ... .. . 386789 92362594005 . .. _ MW-8 SM 6200B :. 386789 92362594006 MW-9 SM'6200B 386789 92362594007. SW-1 . SM 6200E 386789.. '- 92362594008 . .. SW=2 SM 6200E :. _ 386789:. . 92362594609 -. Trip Blank- SM 6200B ...386780 . 92362594001 MW-4.. - SM 2540E ..386203 923625§4002.. MW-5 SM 2540C. 386203: 92362594003 .' MW-6 :: . , SM 2540C;• 386203" ... 92362594004 .. .. MW-7R SM 2540E , 386203 92362594005 MW-8.. SM 2540E 386203 92362594006 MW-9 .: SM 2540E 386203 92362594007 SW-1 SM 2540C 386448.. = 92362594008 ... SW=2 : :. SM 2540E. _ _.. 388448' 92362594061 MW-4 SM 92221) 386078 92362594002. MW-5 'SM 9222D 386064 92362594003-.- MW-6 SM 9222D:. 386064 92362594004. MW77R SM 9222D 3.86064 .. .92362594005 .. MW:8 .. '.. SM9222D .... •. .386064 92362594006 MW-9. SM 9222D 386064 923.62594007 - .SW-1 SM 0222D 386078 .. :. 92362594008 SW=2 SM W22D 1. .386064: . 92362594661 MW-4 EPA350.11993.Rev.2.0 .386861 92362594002 11V!W=5, .. EPA 350.1 1993 Rev 2.0 • ..3868.61 92362594003 . MW-6 EPA 350.1 1993 Rev 2.0 ` 386861. 92362594004 : MW-7R_ EPA 350.1 1993 Rev 2.0.. 386861- . . 92362594005 .. MW78-. EPA:350:1 1693 Rev 2.0: 386861 92362594006 MW-9 .. EPA-350.1 1993 Rev 2.0 .386861 92362594007 'SW-1 .. EPA 350.1 1693 Rev 2.0 .' . 386861 923.62594008 _ SW-2 EPA 350.1 1993 Rev 2.0 . 386861 92362594001 MW-4. EPA353.2 .385932. - 92362594002 : - MW-5 . • EPA 353.2 385932 92362594003 MW-6 . EPA 353.2 385932 92362594004. - MW-71Z_ EPA 353.2 '385932 92362594005 MW-8 EPA 353.2 385932 - 92362594006 MW.9 EPA.358.2 385932.. 92362594007 SW-1 EPA 353.2 385932 92362594008 SW-2 EPA 353.2 385932" ." 92362594001 MW-4 EPAW5.1 386579 92362504602 MW-5 EPA 365.1 386579:. 92362594003 MW-6 - EPA 365.1 386579 REPORT OF LABORATORY ANALYSIS - This report shall not be reproduced, except in full, Date: 11h7/201.7 01:58 PM without the written consent of Pace Analytical Services, LLC. Page.40 of 44 Pace Analytical Services; LLC ® aceAnal .ical O,. 2225 Riverside Dr.. Asheville, NC 28804 www.pacela6scom (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE . Project: Clement Pappas 11/8 Pace Project No.:.. 92362594 . Analytical Lab -ID Sample ID . - • QC Batch Method' :. QC -Batch:: • Analytical Method - Batch. 92362594004 MW-7R .. EPA365.1. ..._ 386579 92362594005:. MW-8 EPA365.1: 386579. 92362594006 . MW-9. EPA365.1 386579 92362594007 _ ..: SW=1 .- EPA 365.1' ..:: .. 386579 92362594008 SW-2 EPA365.1 386579' 92362594001: MW4 SM 4500-CI-E 386135 92362594002 .. MW-5 SM 4500-CI-E 386135.. . 92362594003, -MW-6 SM 4500-CI=E .' 386135' 92362594004 MW-7R SM 4500-CI-E 38M5 92362594005- •j MW-8-' SM 4500-CI-E:: .386135 92362594006 MW-9...... S.M 4500-CI-E: 386135: 92362594007 ;: SW-1 SM 4500-CI=E 386135 - 92362594008 SW-2 . SM 4500-ClE - 386135 92362594001 MW-4 :: .. SM 5310E :. .. 386751 92362594002. M 6 SM 5310E. 386597 .. .92362594003 .. MW-6 SM 5310B 92362594004 '. MW-711 - SM 5310E 386597`- . 92362594005 MW-8 . SM 53106 '386596 - 92362594006.. MW-9 SM 5310B .' 386597 92362594007 :: SW7.1 : SM 5310B .. 386597. 92362594008 .... SW-2 SM 53106 386597 REPORT'OF LABORATORY ANALYSIS. • . This:reportshall not be reproduced, except in full, Date: 11/17/2017 01:58 PM without the written consent of Pace Analytical Services, LLC. Page,41 of 44 - Document Name: Document Revised: July.25; 2011 e Sample Condition Upon Re'ceipt(SCUR) Page 1 of 2 Document No.: Issuing Authority:: . aCEAnarryhCa�." F-CAR-CS-033-ReV.03 Pace Quality Office' s , Laboratory, receiving saTpi Asheville Q Eden❑ . 'Greenwood ❑ Huntersville❑ Raleigh❑ -Mechanicsville❑. W ®;" ' .923G.. . • Client Name; " Upon Receipt oject ( II I III II L I Ii l llllll 111 Courier:. ❑Fed Ex ..: - "❑lJPS"" EILISPS ❑Cl en 9236259�4 ❑ Commercial ❑Pace ❑Other: Custody Seal Present? ❑Yes ❑o N Seals Intact? ❑Yes . ❑ No . Date/Ipttials Person Examining Contents 'Packing Mate►ial: ❑Bubble Wrap ❑Bubble Bags ❑None ❑ "Other Biological Tissue Fr n3� Thermometer . EWet // .. ❑Blue Dyes . ❑No, ❑ /A. ❑iJone... ` .. ❑ IIR Gun ID: Type of Ice: Correction Factor: ", /i Cooler Temp Corrected (°C): ".. G Temp-should'be above freezing to'6°C. " . - ❑Samplesout of temp criterta. Samples on Ice, cooling process . .. � has begun. . '. Soil (❑,N/A.watersemplg) . us ample) Did samples" originate in a�quarantine zone -Within the United States: CA, NY, or SC (check maps)? . Did samples originate;from a forelgn.source (internatior�al(y, Hawaii and Puerto Rico)? ❑Yes No ❑Yes ' ❑No '. . including Comments/Discrepancy: Chain of CustodyPresent? ... ❑ es❑No ❑N/A 1. Samples Arrived within Hold Time? 0 es .: ❑No... ❑N/A .2. Short Hold Time Analysis (42 hr:)?s�❑No . ❑N/A . 3; ' C_c•I Rush Turn Around Time Requested? ':. El es ❑N/A 4. Sufficient Volume? b s ❑No ❑N/A". 5-' . Correct Containers Used? ❑Yes ❑No,' .. ❑N/A 6.:. .-Pace Containers Used? El eY/'❑No' ❑N/A Containers Intact?_ ❑ .es []No❑N/A.% 7'• Dissolved analysis: Samples Field Filtered? ❑Yes .[`JNd ❑N/ : Sample Labels Match"COC? ❑YZ..❑No,', ": ❑N/A 9:.. -Includes Date/Time/ID/Analysis Matrix: ) n / . 10• Headspace in VOA Vials (>S-6mm)? ❑ s/ I�No • ❑N/A Trip Blank Present? .. [], er ❑No []N/A 11. Trip Blank Custody -seals -Present? 2Yes ❑No '. ❑N/A " :Field Data Required?''❑Yes- o CLIENT NOTIFICATION/RESOLUTION Person Contacted:' Date/Time:" .. : . Comments/Sample Discrepancy: (" vj I Project Manager SCURF Review:. Dater 1 . Project Manager.SRF Review: Date Nate: Whenever there Is'a discrepancy affecting North Carolina compliance samples, a copy of this form will. be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect-preservative, out of temp, incorrectcontalners) Page.42of_44" ZZ zzzzzzzzz mL Plastic Unpreserved (N/A) (CI-) G C M. n' :2BkU=125 w'. 03 " 'Q-..m SP3U-250 mL Plastic Unpreserved (N/A) . — — — —_ BP2U-500 mL Plastic Unpreserved (N/A) -.. '.y = •G c 3 � SP1U-1 liter Plastic Unpreserved (N/A)•. C' ? p < BMS-125 mL Plastic H2SO4 (pH 2) (Cl-)Oh . YD.�. a BP3N-250 mL plastic HNO3 (pH < 2) : O. — . 'X .Ly. . `s cam' 8P3Z-250 inL PlasticZN Acetate & NaOH (>9). -Z// , c y _ 21� BP3C-250 mL Plastic NaOH (pH > 12) (CI-) ' E WGFU-.Wide-mouthed Glass•jar Unpreserved . 0 O AGiU-i liter. Amber' Unpeeserved'(N/A)'(CI-) tS ti G d AGiH-1 liter Amber HCI,(pH < 2) m �. CD A61LI-250.mLAmber.Unpreserved(N/A)(CI-) O. v �. o AG35=1 liter Amber H2504 (pH < 2) . 3 'c o c m C AG3S-250mLAmber H2504.(pH,<2) : w h o z Z AG3A(DG3A)-250mLAmber.NH4Cl(N/A)(CI-) m' o s 1D m wM. M y 5w DG9H40.mL VOA HCI. (N/A) o n VG9T-40 mL V0 A.Na2S203,(N/A) >t' V69U-40 mL VOA Unp (N/A) n v .DG9P-40 mL VOA H3004(N/A); m- Q VOAK-,(6 vials per kit)-5035.kit (N/A) . V/GK (3 vials per kit)-VPH/Gas kit (N/A)' . Ca,^ n y c •obi mGQ SPST-125mLSterilePlastic (NIA -lab) ' r Al S en0q SPZT-25.0 mL Sterile Plastic (N/A -lab) 3. ®' ' 0 o 0 p .0 N �. g ... BP3.A-250 mL Plastic (NH2)2504 (9.3-9.7) Cubitainer VSGU-20mLScintillatimvials (N/A) Z j. N . D+ v CHAIN -OF -CUSTODY 1.AnalVAcal 'Aequest.Document o The Chain -of -Custody is.a'LEGAL DOCUMENT. All relevant fields must be completed accurately. • v Section A' Sectlao B Section C rn . to . Il Required Client Information: Required Protect Information: Invoice Information: Fa e L 1 Ot 1 , •Company .: ANCHOR OEA ofNORTH CAROLINA: Reporl'To: AlexLeSueur. Attention: -. - Address: 231 Haywood Steel Copy. TO. Company Name: - Asheville, NC 288D1 Address:.•. - _ _R Mato 'A •en ", - Email: Purchase OrderM Pace Quote: - Phone: ' ' (7- Z Qj t- 3 �%•70 Fax .. Project Name: Clement Pappas Pace Project Manager. . lorri. atton gparelabs.com, _ _ State LLocation' Requested Due Date:, Project M. Pace Profile g: - '-.Ra uesitc-d AdalysfsFlltored 1N - . . 'MATRIX, -CODE , m o .0 • COLLECTED _ PreservatiVBS - ', - � "o . .. - DOng Water. OVJ. Mi v �• O . ' - Water Wr. '. 'u v_ V '� n' ZL SAMPLE.ID . Waster Water Pladu SOS.hd WN P : .SL ''> U' ' a c1 START - END O N m F' . O t n LL m. od . aL a 5 . ' One Characterper.box. Wpe : _ We m w a ._ .�: o ~ y. E. o # (A-Z, D-91, -) � Nr M. '. AR . OT ' o . a r w m m .. _ . �; z U . . Sample Ids must be unique .rrsaua , Ts - U x m� T TDATETIME m < = N m C O O m U 9 Q. C "�. N O. z U O dl N N r m t . Q fJ O E E .o` L w m .p m '1� —i . ~ N - N a x x x z . z .� O. r ¢ o Z a > . > x. T •'..1•- •MW-0 . '. : WT t t l�13. '. ..it x X X :X'. �X. 2. MW-5 wi' It li t1 Il X. X X I.X. .X .X�, - 3 Ntw s ,nri << , 17,3 1 X..x z X x ..X MwaR liar x" x x x x .z. EJii. rr MW-8 .. wr I1(31t i'o(3' fi X x x x x x �. 6- MW_9: -VJT -h (I� '17: .. ll x X. X . x . x ..x. . " WT it �b ).1 . '1�419 {� x X X X. •. . .X • .: 601. ' & sIX w_z ` ,,1 1'ie�� l� x x. x x 9 :..Trip Blank Wr k f$D Q, U 10., •: ,... ;ADDITIONALCOMMENTS: .". 'REONQUISHEDBYJAFFILUITION :' DATE -.71ME ACCEPTED.BYIAFflLIATON,;.. DATE•'- `TIME SAMPLECONDITIONS f . .. _ SAMPLER NAME ANQSIGNATURE�'.' PRINT Name of SAMPLER: j O QL:n. SIGNATURE of SAMPLER: DATE Signed: a UJ w _ o m E u m z� m $ ? �_ m ? rn-2 Well S.amplingi Log Anchor QEA of North Carolina; PLLC 231 Haywood -.Street . -Asheville, North Carolina 28801 Project Name: C,LAJ�nD .. h�1C-S Date:. . . Project;Number C�-1hI-�1 — Weather.-�J�S Sampling Personnel: (� Sample Time: 12 Well. Number f i/1 ni— (o --°" Well Depth in Feet (WD): Well Diameter., .Z•�. WaterLevel in Feet.(WL): Type of Casing:"I Length -of Water: Column:, 7 'feet 'rtO4 MeasuriZS�O�k�- (►ND) - (WL).=.(LWC7 — -- — Flush Mount. One Casing Volume: S gallons Comments:... (LW C) x (WM 'three Casing Volumes• �, ��, .� gallons Actual Volume.Purged:: 'gallons_ WeliCasing ,Volumes (WCV) 1 °.= 0.04.1 GaV .t 2" - .0.17;Ga1/Ft .. •3" •=.0.38 QVFt ..4" =:0.66 Gal%Ft 6`' = 1.5. Gal/Ft 8".= 2.6 Gal/Ft' 12". = 5.8.Gal%Ft: Purge'Method: , . , Bailer' is'- 'Bailer -Teflon'. `.Ded'icated.Pump: .Whale Pump Grundfos Other. Sample Method; $viler-Disp : Bailer -Teflon. Dedicifed Purrip Whale Pump , Grundfos Other. — . .Iux1aallon., Gallons Temp Specific Cond. Dissolved �pki(S:U.). ! Reduction Turbldity Readin g .. Time Purged ("C) (pS/cm) . O xY9 (. g A) en m re p o oit tMY S.U. Potential:(m1) (NTU)- Comments . . 1 iZzv ! two. r _z:26 3 ? 79.. 2,51 6 9 i � �_l:. I_ _ i -- r - ' 0 Sampling Container `'Number of Containers' !'Requested Analysis.. 500 mL Plastic ' hC, 250 mL Plastic' 125 mL Plastic — --Z — .Ap r \ 40 mL•Glass � r�— — 11 Glass Protective Casing: �i' _ Pad: Lock: "off:. Vegetation: Access: .' t. Sampling personnel Signature:• �� Date:, j J r..� 4--O.ANCHOR'.. -A 7, QEM-C-C-1 well' sampling Log Anchor QEA of North Carolina; PLLC. 81 Hay'wood Street AsheVille, North Carolina 28801- Anc.h6r QEA'of North Carolina, PLLC 231.Hayw6od Street MheYmej North Carolina 20801 WWI Sampling. Lb Anchor QFA of North.Carolina; PLLC. 231 Haywood Street Asheville, North Carolina 28801 wen samprng cog Adch6r-QEA of North Carolina, PLLC 231. Hbywo6d, Street AshdVille, -North.Carolina 28801 .burra.ce wa-ter bamping, Log Project.Name. ci bate:. %kli lc� Prqject-Wrrlber. Weather: OVRJ C4 Sampling Personnel:.. A �-Sarnple Name: Comments: Sample Method: F-A b w ump Syrin 1 9 e 'Dfsp� Other' Bailer b no x ant RI O Specific Cand. Dismolved. pH (S.U.). Reduction Turbidity rime Tqm Q p (psldh). OXY9 en (mg/L). report to 0. 1. S. U. Potential (NTU) Comments Ii� �3-� 3 `� j ��y3.. ��3 J.. g 1�} simplifig,contalner Number 6f C6ntiineirs Requested Analysis. 500.6iL Plistie. 250 mL Plastic 125 ML Plastic 4 mL Glass' 6- J.6c 3. 1 LGlass Other. Vegetation, Access, Sampling P rsonnel Sign. turv. K -ourirace water zPamping Lag Project Name: Date[ LD- J ProjProjectNuMbier.,• Weather:� g� -Sarilpfing Personnel: - --i 'S Sample Narne, comments: 06,. - �'I CA 7 ----7-' :Sample Method: :e�ob SYdjjg- PUMP. B-qHer7D-isp' Other. - O)ddotign Spe�IfIFCopcl.. Dissolved. 0" (S uQ, . Reduction Tutbidlty Mm em Temp'(OC)-: CPS/Cffi) 0. -n Cing'/L vaL rep9l'to 0. 1 s. U. Potential Pa. tia - (mV) (NtU).' Commens I. Sampling Containar Number of tontainers Requested Adriilyds.' 500 rhCPlastic 256 M-L Plastic ---- -OIL N vv- 125 ML PIaAic V14e_ 40 mLGlass : f _ -L Glass . — Wgetition: Date: nnel Si n 7-h mpling Pgrio 9. ature: 50 CALIBRATION DOCUMENTATION Project Name: 5..i�Qf7tY�(1�5 .`. Person Conducting Calib:retion:. -C . Project Number. Date of: Calibration Project Location: {; y r-Oft ✓1 J, i`p L11 L Date of Feld Measurements. ( ' _. l'1. EQUIPMENT DOCUMENTATION Equipment or meters used to take measurements (e g; Waterleve[meters, survey equipmentye Equipment Type. I Serial Number. Brand' Date of Use 150-ft Water Level 26154. - � Solinist. 1507ft lWater Level.�, 22754 - - Soliinist -_- - - -- 150-ft Water Level' -' 150 . - Testweli- 150-ft Drawdown' I MP30-152T .I QED - Other Select Turbidimeter... Hach 2100Q (s/n 151006045207j. . HP Scientific:MicroTPW,(s/n 200601045), Calibration' Instriment Reading Instrument Reading, Standards (Hach 21000).. (HF Scientific Micro TPIAI) ; 'Expiration Date : '20 NTU 100 NTU r 800:NTU 0.02 NTU . 10.0-NTU . I: 9000 NTU . lCel:. ICal: �'j �y ;Cal: ' Cal: Cal:. {Cal ej ;Time: In1e: Time: Time: Time:. Timer^ Verification (10: NTU)- Verification: ? Verification: Verification: .10 '�.. _ Time: -- :-Time:'..-_— ITnte:. Time: -- VSI 556 Multiparameter Meter (s/n 11211.101057) : Instrument'Readings --�f-Calibration Expiration ,Date. Dissolved O eo- InitiOal: 3Cal: mmHg Time; N pH 7 S.U. Initial: 'pHmV ICaI: _ pHmV: Time report to07SU .'. � �V v %� f(P ^7jJ �. sir, I pH 4 5 U Initial' . pHm22V:)) J Cal ipHmV: Time: report to07SU pH 10 S.U. Initial. p-may pHm'V:. Cal:. — ipHmV: Titrie: reportto0.7S.U. ��: QC* pH 7 S.U. AM Time: Meas::� ([ Mid Day.Time: Check:,_ PM Timer Check: �reportto.O.TSU.-OBI . f - - -- Spec Cond. 1Initial: Cal: Time: - pS/cm•• QC*: AM Time: 'Meas: .'Midbay Time: Check. - - PM Time: (Check. -- --- il ORP 240 mV . InttiaL• `Cal 1-m �f. . Signature:.. U � � Date I Notes: 1, Electronic equipment calibrated according,to the manufacturers operation manual.. 2,6 2 Specific Conductivity should. be calibrated according to values.representatiive of historic range... . 3, Order of Callbiation is a's follow's ::Specific Conductivity,' pH 7, pH 4; pH 1.0, DO, ORP, QC checks: 4. QC Acceptable Ranges>pH +1- 0:1 S.U. and Specific Conductivity 10% of the true value,.lf QC readings are out. of. 'range, the instrument needs to be recalibrated. S. *Indicates that a U check must be performed in the morning, afternoon, and the end of the day, or;every four hours._' ' 6. " Indicates to choose a Specific Conductivity buffer of 1413,'447, 84, oir 23 m5 which is dosest to historical readings from the project location.. Page 1 of 1 " 1 Enter date monitoring results were.due: ( 1z/3i/26it Wili this_monitoring report:(GW-59.and.GW-59A) YES'. NO be -submitted after theestablished due date.? _ X: 2.- Was.any required information missing on the'GW-59 report -forms? YES NO. IF the" answer to question 1. or 2 is "YES ; list in the space:provided below the, well identification number(s) and explain the'problei s,'encountered In obtaining the_required information; '. . 3. Are•any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, niissing .. YES - NO identification piste,! area overgt ow.n; etc.)? If the answer i.s ".3'es ., caitacl the Regio�ial Office for guidance.. X 4 - ' Are any monitored constituents equal to orabove.the established'standards? :. YES NO If the answer_to.questton 41s NO';.skip-to section 8.. If the answer to question, 4 is `WS" list the affected wells individually with constituents) and.concentration(s) exceeding standards in the space provided below: ' Nitrate (2L = 10'mg/L); .MW-7R036.8 mg/L,.MW-8@14.4 mg/l;;- - - Fecal Coliiorm (Total Coliform. 2L standard—.1,0 CFU/100mL): MW-5®188 CFU/160mL; MW,-6®74. 0. CFU/100mL;' 14W-7R®19.0 CFU/10 mL;. MW-9M10.0. CFU/100mL; !Tetrachloraethene (2L = 0.7, pg/L)6.MW-5®35.9 pg/L; 'Trichlorcefhene _(2L -= 3.,pg/L)i MW-5®4..6 jig/L. 5 Forthe constituents identified in question 4 above, have standards. been exceeded_prevlouslyforthe . _ YES..NO. same constituents) - in the same well(s) in the last two'years? . g . If the answer to question.5 is "NO", skip to "section 8.. ' If the answer to question :5 is "YES" list in. the: space provided below,,- each well with constituents) exceeding. standards, concentrations) reported, and=sample collection date for each"occurrence (for the last two years). Nitrate- Nitrate- Fecal Coliform (reported in-CFU/100mL) MN-7R - MW-8 MW-5. .. MW-7R'ana MW-9, no: exeedances in 2 yea a , . _ 05/04/16: 11•. 2. mg/L 5/4/2016: 19.1 'mg/L- -11/04/15: 7.0 -... ' 06/09/16:, 16.9/10:0 mg/l; 06/09/16.: 26,.3/26.0 mg/L. MW-6 MW-5 for Tetrachloroethene 11/69/16:'12.5 mg/4-11/09'/16:. 14.3 .mg/L" 11/04/15:"136 -" 11/64/15:'26A. jig/L;. 11/09/16i 14L.0 p /L .. .05/02/17:, 12.4 mg/L. : MW--5 for Trichloroethene 6 Arethe-monitoring wells listed in sections located at or beyond. the review boundary?.YES . .NO. . MW-5,•'MW.-7R,,'MW-.8, .and MW-9 are at'ar beyond the review boundary. - X. If theanswer fs: "YES" a-groundtvater quality problem may be occurring.. CONTACT THE REGIONAL . ' OFFICE IMMEDIATELY FOR GUIDANCE if the answer. is "NO ; monitoring wells maybe improperly located; contact the Regional Office.,'' is the permittee implementing previously approved actions required by the. Division involving this YES NO : groundwater qualityproblem? " " X. If the to.question 7 is'YES', describe those actions in the space provided below. If fhe ansvierfo question 7.is."NO11 contact the Regional Office within_90 dads: an evaldation may'be reduired to determine the impact the.waste disbosal system is having at the review and compliance boundaries surrounding this facility.. Failure to do so may sublect the�permltfee to a Nofice:of. Violation; -fines. and/or penalties..... . Fecal. coliform'should not. be 'attributable to site operat ions: .Monitoring of, an on -site tributary.of.Mud'.Creek.has. found'high. 'levels' of fecal coliform: .. .. - .. The vOCs T are. only,in, the, background monitoring well .(MW-5):.and appear, to. be from'an. upgradient source. -. 'Nitrate concentrations exceeded the.groundwater standard.in'MW-7R and MW-B, for the first-time in May,..2016. .. The .high concentrations,of nitrate are likely.attributable to the frequent` flooding of Mud Creek, -.The'person completing this portion (GW-59A) of the monitoring report shobld sign below and submit this form: with GW-59 forms for required wells fo fhe. address provided at the top of the current G W-59 form:: �I`hereby acknowledge that the above information was evaluated and the information subm_ itted In this report (Compliance Report G A)_is true and complete to the best of my knowledge ._ _ W — _ :. ..Signature of Permitt •(or thorized Agent) Date SUBMIT FORM ON YELLOW PAPER ONLY ROUNDWATER QUALITY MONITORING: OMPLIANCE REPORT FORM FACILITY INFORMATION Please Print Cleary or Type Facility.Name: Clement Pappas Permit Name (if different): Facility Address: 125 Industrial Park Hendersonville (Street) NC 28792 County Henderson (City) (State) (Zip) Contact Person: Mr. Blake Keho a Telephone#: 8 2 8 - 6 9 3 - 0 711 Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 !from Permit) WELL ID NUMBER (from Permit): MW- 4 Well Depth: 1 18 _ 2 nft. Depth to Water Level 82546: 7 . 8 8 ft. below measuring point Measuring Point is 2 .4 3 ft. above land surface Volume of water pumped/bailed before sampling: 5.5 Samples for metals were collected unfiltered: ❑ YES ❑ !RMIT Niumber: Expiration Date: 8 / 31 / 2 0 2 0 n-Discharge WQ0004797 UIC 'DES Other PE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ® Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: Date sample collected: 11 / 8 / 2 017 FIELD ANALYSES: WAS Well Diameter: 2 in. pH 00400: 6 .50 units Temp. 000lo: 15.400C DRY at Screened Interval: 8*ft. to16. 1*ft. Spec. Cond. 00094: 215 µMhos time of sampling, Relative M.P. Elevation: 2063.77 ft. Odor 00085: none check *screened interval is relative to land surface gallons Appearance here: ❑ NO and field acidified: El YES ❑ NO (Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD oo335 mg/L Nitrite (NO2) as N 00615 mg/L Coliform: MF Fecal 31616 <2 . 0 /100ml- Nitrate (NO3) as N 00620 1.20 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0 - 0 7 Qng/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L issolved Solids:Total 70300 135 mg/L Al - Aluminum oil o5 mg/L pH (Lab) 06403 units Ba - Barium 01007 ug/L TOC 00680 3.0 mg/L Ca - Calcium 00916 mg/L Chloride oog4o 7,3 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L du - Copper 01042 mg/L Phenol 32730 ug/L Fe - Iron 01045 ug/L Sulfate 00946 mg/L Hg - Mercury 71900 ug/L pecific Conductance 00095 µMhos K - Potassium 00937 mg/L Total Ammonia 00610 < 0 _ 1 0 mg/L Mg - Magnesium 00927 mg/L. (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen. Total) Mn - Manganese 01055 ug/L TKN as N 00625 mg/L Ni - Nickel 01067 ug/L Pb - Lead 01051 ug/L Zn - Zinc 01092 mg/L Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? ® Yes (1) ❑ No (0) VOC 7873 , method # 6200 method # method # method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.8/2013 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM FACILITY INFORMATION Please Print Clearly or Type ntvisioowwape Esau cr:�iRi irlocsilG�ri(in RsF4M�:rc1-cesyWtARM os,seoub PERMIT Number: Expiration Date: 8 / 31 / 2 0 2 0 Facility Name: Clement Pappas Non -Discharge WQ0004791 UIC Permit Name (if different): NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville (Street) NC 28792 CountyHenderson ❑Lagoon ❑Remediation: Infiltration Gallery (City) (State) (Zip) 1 Spray Field ❑ Remediation: Contact Person: Mr. Blake Kehoe Telephone#: 8 2 8 - 6 9 3 - 0 711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION MW- 5 If WELL WELL ID NUMBER (from Permit): Date sample collected: 11 / 8 / 2 017 FIELD ANALYSES: WAS Well Depth: 18 _ 5 p ft. Well Diameter: 2 in. pH omoo: 5 - 85 units Temp. 00010: '14 .61 °C DRY at Depth to Water Level 82546. 8 , 2 3 ft. below measuring point Screened Interval: 9 * ft. to 19 * ft. Spec. Cond. 000k: 68 µMhos time of sampling, Measuring Point is 3 . 00 ft. above land surface . Relative M.P. Elevation: 2085.60 ft. Odor 000m: none check Volume of water pumped/bailed before sampling: 5 .2 5 *screened interval is relative to land surface gallons Appearance. here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L. Nitrite (NO2) as N owi5 mg/L Pb - Lead o1051 ug/L Coliform: MF Fecal 31616 188 /100mL Nitrate (NO3) as N 00620 < 0 . 0 2 0 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0. 086 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 84 . 0 .mg/L Al - Aluminum o11o5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 6.7 mg/L Ca - Calcium 00916 mg/L Chloride 00940 12 , 8 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ® Yes (1) 0 No (0) ecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 , method # 6 2 0 0 Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NHaas N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.8/2013 SUBMIT FORM ON YELLOW PAPER ONLY UNDWATER QUALITY MONITORING: PLIANCE REPORT FORM FACILITY INFORMATION r-tease runt weany or iype Facility Name: Clement Pappas Permit Name (if different): Facility Address: 125 Industrial Park Hendersonville (street) NC 28792 County Henderson act Person: Mr. Blake Kehoe Telephone#: 8 2 8- 6 9 3- 0 711 Location/Site Name: Irrigation Area No. of wells to be sampled: 6 PERMIT Number: Expiration Date: 8 / 31 / 2 0 2 0 Non -Discharge WQ 0 0 0 4 7 9 7 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ® Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: L ID NUMBER (from Permit): MW - 6 Date sample collected: 11 / 8 / 2 017 FIELD ANALYSES: Depth:. 11. 58 ft. Well Diameter:. 2 in. pH o040o: 5 .24 units i to Water Level 82546: 4 . 8 0 ft. below measuring point Screened Interval: 5 * ft. to 10 * ft. Spec. Cond. 00094: - wring Point is 3 . 0 0 ft. above land surface Relative M.P. Elevation: 2061.17 ft. Odor 00085: none ne of water pumped/bailed before sampling: 3.75 gallonSscreenea interval is relative to land surfac'Appearance )les for metals were collected unfiltered: ❑ YES ❑ NO . and field acidified: ❑ YES ❑ NO ite sample analyzed: varies; see analytical report. Laboratory Name: Pace Analytical Services kRAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 Coliform: MF Fecal 31616 74.0 /100mL Nitrate.(NO3) as N 00620 0.045 mg/L Zn -Zinc 01092' Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 < 0 . 050 mg/L 'Note: Use MPN method for hi hl turbid sa m les) If WELL Temp. 000lo: 12 .70 °C DRY at 85 µMhos time of -- Certification No. 3 7 712 ug/L mg/L . g y a Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): ,solved Solids:Total 70300 66 . 0 mg/L Al -Aluminum o1105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L " TOC oo68o 1. 4 mg/L Ca - Calcium 00916 mg/L Chloride 00940 11 . 1 mg/L Cd - Cadmium 01027 -ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L _ (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? H Yes (1) ❑ No (0) ecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # 6200 Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total) Mn - Manganese olo55 ug/L method # TKN as N 00625 mg/L Ni - Nickel o1087 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% here:0 GW-59 Rev.8/2013 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Please Print Clearly or Type Facility Name: Clement Pappas Permit Name (if different): Facility Address: 125 Industrial Park Hendersonville (street) NC 28752 County Henderson (city) (state) (zip) Contact Person: Mr. Blake Kehoe Telephone#: 8 2 8- 6 9 3- 0 711 Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 from Permit L ID NUMBER (from Permit): MW- 7R Depth: 17 _ U ft. i to Water Level 82546: 10 _ 34ft. below measuring point luring Point is 3 . 0 0 ft. above land surface ne of water pumped/bailed before sampling: 3.75 Iles for metals were collected unfiltered: ❑ YES ❑ !RMIT Number: Expiration Date: 8 / 31 / 2 0 2 0 n-Discharge WQ0004797 UIC 'DES Other 'PE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon . ❑ Remediation: Infiltration Gallery ® Spray Field ❑ Remediation: . ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: Date sample collected: 11 / 8 / 2 017 FIELD ANALYSES: Well Diameter: 2 in. pH 00400: 5 -74 units Temp. 000lo: 14 . 08 °C Screened Interval: 5 ft.* to :L5ft* Spec. Cond. 00094: 472 µMhos Relative M.P. Elevation: 2062.86 ft. Odor 00085: none *screened interval is relative to land surface gallons Appearance and field acidified: ❑ YES ❑ NO ate sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services Certification No. 37712 kRAMETERS NOTE: Values should reflect,dissolved and colloidal concentrations. COD 00335mg/L Nitrite (NO2) as N.00615 mglL Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 19.0 /100mL Nitrate (NO3) as N 00620 36.8 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00885 0. 14 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): ;solved Solids:Total 70300 376 mg/L Al - Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00580 3.9 mg/L Ca - Calcium 00916 mg/L Chloride 00940 17.9 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS; HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ® . Yes (1) ❑ No (0) ecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # 6200 Total Ammonia 000lo <0 . 10 mg/L Mg - Magnesium 00927 mg/L . method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn -.Manganese o1055 uglL method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: ing/L Effluent Total VOCs: mg/L VOC Removal% If WELI WAS DRY at time of check here: 11 GW-59 Rev.8/2013 SUBMIT FORM ON YELLOW PAPER ONLY ROUNDWATER QUALITY MONITORING: OMPLIANCE REPORT FORM 1CILITY INFORMATION Please Print Clearly or Facility Name: Clement Pappas Permit Name (if different): Facility Address: 125 Industrial Park Hendersonville (Street) NC 28792 County Henderson (City) (State) (Zip) Contact Person: Mr. Blake Kehoe Telephone#: 8 2 8 - 6 9 3 - 0 711 Well Location/Site Name: Irrigation area No. of wells to be sampled: 6 PERMIT Number: Expiration Date: 8 /31 / 2 0 2 C Non -Discharge WQ 0 0 04 7 9 7 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED. ❑ Lagoon ❑ Remediation: Infiltration Gallery IN Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: MW-8 WELL ID NUMBER (from Permit): Date sample collected: 11 / 8 / 2 017 FIELD ANALYSES: WAS Well Depth: 13 - 9 a ft. Well Diameter: 2 in. pH 00400: 6. 63 units Temp. 000lo: 13 - 2 7 °C DRY at Depth to Water Level 82546: 8 . 73 ft. below measuring point Screened Interval: 3 ft* to 13 ft'r Spec. Cond. 000sa: 468 µMhos time of MeasuringPoint is 3 . 00 ft. above land surface Relative M.P. Elevation: 2060. 8o ft. Odor o0085: none sampling, check Volume of water um ed/bailed before sampling: 3 . 00 *screened interval is relative to land surface p p p g gallons Appearance here: ❑ Samples for metals were collected unfiltered: ❑ YES El NO and field acidified: ❑ YES El NO Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Coliform: MF Fecal 31616 <4 . 0 /100mL Nitrate (NO3) as N 00620 14.4 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.098 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L issolved Solids:Total 70300 390 mg/L Al - Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 8 . 1 mg/L Ca - Calcium 00916 mg/L Chloride 00940 9.7 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L Phenol 32730 ug/L Fe - Iron.01045 ug/L Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Specific Conductance o0095 µMhos K - Potassium 00§37 mg/L Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L (Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total) Mn - Manganese 01085 ug/L TKN as N oo625 mg/L Ni - Nickel 01067 ug/L Certification No. 3 7 712 Pb - Lead olo51 ug/L Zn - Zinc 01092 mg/L Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? ® Yes (1) ❑ No (0) VOC 7873 method # 6200 method # method # . method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% - GW-59 Rev.8/2013 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Please Print Clearly or Type acility Name: Clement Pappas ermit Name (if different): acilityAddress: 125 Industrial Park Hendersonville (,`ras) NC 28792 County Henderson act Person: Mr. Blake Kehoe Telephone#: 82 8 - 6 9 3 - 0 711 Location/Site Name: Irrigation Area No. of wells to -be sampled: 6 PERMIT Number: Expiration Date: 8 / 31 / 2 0 2 C Non -Discharge WQ0004797 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ® Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: WELL ID NUMBER (from Permit): MW - 9 Date sample collected: 11 / 8 / 2 017 FIELD ANALYSES: Well Depth: 18 _ 'I 2 ft. Well Diameter: 2 in. pH 00400: 5 .44 units Temp. 000lo: 13 . 90 °C Depth to Water Level 82546: 3 . 6 0 ft. below measuring point Screened Interval: 6 *ft. to 16 * ft. Spec. Cond. 00094: 88 µMhos Measuring Point is 1 . 44 ft. above land surface Relative M.P. Elevation: 2060.23 ft. Odor 00085: none Volume of water um ed/bailed before sampling: 7 . 5 *screened interval is relative .to land surface p p p g gallons Appearance Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO WAS DRY at time of sampling, check here:❑ LABORATORY INFORMATION Date sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00336 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 3161.6 10 . 0 /100mL Nitrate (NO3) as N 00620 0.95 m9/L Zn -Zinc 01092 mg/L Coliform: MF Total 31504 /100ml- Phosphorus: Total as P 00665 0.53 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 64 . 0 mg/L Al -Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 7.0 mg/L Ca - Calcium 00916 mg/L Chloride 00940 8.9 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 3273o ug/L Fe - Iron 01045 ug/L (Specify test, and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ® Yes (1) ❑ No (0) Specific Conductance 06095 µMhos K - Potassium oo937 mg/L VOC 7873 method # 62 0 0 Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH,as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total'VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Permittee (or GW-59 Rev. 8/2013