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HomeMy WebLinkAboutWQ0004797_Monitoring (Report)_20170622hrA iaY _` sales Ch !IC .��n�h rrfi....r-\ri (¢ � •'�, �\ � •// /�! r � y %r�S��. �.� ` `:,•. ' Js. � . L, tl I'i'. �`�...� ;: � 1y . �.` . l Ir/ �''1 � � <[ • I '(��'�'1� 1 � i�i 1=• Mite; 1 t // �1 •'';;�: y� \.7 t\ th �;_ ..`'bt `ti� \�. �1\`, \jam ,- _•I [ ,C�; •\, ice. •� � ���. #f ����4� � r�' - , �• ••1 Lj��0• Lit •� � 'i_cl `7 � j �f a i-tr. ;c � .. � •• ._'. " . '' � . `:Z. / •c �i �M _ IN c ti��l r �i� �-�Piw,'�i;.y ,��. C%' n'.�i• �t�►i.1(the Cem ?��� Miie�a'Z�. 11j �', _ •,,� 1- R •• QO 6 4 " 1° 4,St, 1�' r"'• f '�• � , _ �t4 y-. t.'1_'t_�. •r' �� '4 S ~�� �'�'\rs}:_•,Il=',-�!�r�•�: _ sI•a '�/ r-t + 1 . 1 , i I,.�j r �, py�flll�`"'. ..', , • • �t I \.� y I •. • •' ` "yr�l' �7 lf�.l��: 4'••s�t.�� ;� ! 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Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Sample Name - Sample Date (mm/dd/yyyy) U c O F°.' (mg/L) 01 'o C (mg/L) E � ,� = (CFU per 100 ml.05/24/2006 Z (mg/L) 'S (mg/L) O 40 N C C a� (mg/Lj N . 2 o N O ,(mg/L) 7.2 9.7. < 1.1 2 19 d76 < 0.10 NA 11/09/2006 3.6 7.4 < 1.1 0.95 17 0.11 NA 05/18/2007 4.9 6.0 < 1.0 0.56 14 < 0.10 NA 11/13/2007 5.9 16.7 0.1 2.9 6.9 . 82.0 < 0.10 NA 05/27/2008 10.2 9.0 <1.1 0.80 21.3 140 < 0.10 NA 11/18/2008 4.7 10.7 0.1 1.9 8.5 32.0 < 0.10 NA 05/28/2009 14.4 1 7.1 < 4.0 0.46 . 24.2 104 < 0.10 NA 11/05/2009 13.5 5.9 < 2.0 0.31 23.5 80.0 < 0.10 NA MW-2R 05/13/2010 8.7 5.8 < 2.0 < 0.10 17.2 57.5 < 0.10 NA 11/08/2010 18.3 10.0 < 2.0 1.1 11.7 60.0 < 0.10 NA 05/17/2011 11.6 < 5.0 < 2.0 < 0.10 14.3 < 62.5 < 0.10 NA 11/15/2011 18.9 10.1 < 2.0 1.2 10.0 86.0 < 0.10 NA 05/17/2012 5.3 7.6 < 4.0 < 0.20 11.9 68.0 < 0.10 NA 11/07/2012 31.1 9.5 < 1.0 1.3 1 10.0 67.0 < 0.10 NA 05/16/2013 13:5 1.2 < 1.0 < 0.02 13.2 64.0 < 0.10 NA 11/20/2013 6.1 7.6 < 1.0 0.97 9.3 66.0 < 0.10 NA 05/22/2014 8.0 4.1 < 1.0 0.72 8.4 52.0 < 0.10 NA 05/15/2002 8.9 45 < 1.1 < 0.10 9.3 180 < 0.10 NA 11/05/2002 5.5 48 < 1.1 < 0.1 14 230 < 0.10 NA 05/13/2003 3.3 32 < 1.1 0.051 20 110 0.21 NA 11/04/2003 41 1 31 < 1.1 < 5.0 66 210 < 0.10 NA . 05/05/2004 6 29 < 1.1 < 5.0 45 240 0.11 NA 11/09/2004 8.4 13 3.6 < 0.10 52 200 < 0.10 NA 05/.17/2005 8.5 10 < 1.1 < 0.10 37 220 < 0.10 NA 11/03/2005 16 14 < 1.1 < 0.10 29 220 0.14 NA 05/24/2006 19 i 11 < 1.1 < 0.10 28 180 < 0.10 NA 11/09/2006 8.8 6.9 < 1.1 < 0.10 26 180 < 0.10 NA 05/18/2007 8.5 8.9 < 1.0 < 0.10 29 300 < 0.10 NA 11/13/2007 16.7 11.3 < 1.1 < 0.10 25.0 152 1 < 0.10 NA 05/27/2008 < 1.0 10.0 <-1.1 < 0.10 38.6 176 < 0.10 NA 11/18/2008 20.5 9.3 < 1.1 < 0.10 19.6 108 < 0.10 NA MW4 05/28/2009 8.6 13.6 < 4.0 < 0.10 35.5 156 < 0.10 NA 11/05/2009 31.0 13.6 < 2.0 .< 0.10 30.7 120 < 0.10 NA 05/13/2010 7.8 18.0 < 2.0 0.17 31.0 141 < 0.10 NA 11/08/2010 23.9 17.5 1 < 2.0 < 0.10. 34.4 144 < 0.10 NA 05/17/2011. 7.7 13.5 < 2.0' 0.82 25.6 137 < 0.10 NA 11/15/2011 7.3 14.4 < 2.0 < 0.20 27.8 157 < 0.10 NA 05/17/2012 6.7 12.1 2.0 . < 0.20 22.3 117 < 0.10 NA 11/07/2012 10.6 14.5 2.0 < 0.020 26.2 150 < 0.10 NA 05/16/2013 31.8 10.2 2.0 0.28 19.1 108 1 < 0.10 NA 11/20/2013 8.0 ' -14.7 < 1.0 0.026 22.1 157 1 < 0.10 NA 05/22/2014 8.7 10.8 1 < 2.0 0.14 1 22.5 146 < 0.10 NA 11/18/2014 28.7 12.1 < 2.0 < 0.020 21.9 c 161 < 0.10 NA % 05/13/2015 5.4 9.2 < 1.0 < 0.020 21.5 130 <, 0.10 NA 11/04/2015 6.6 6.2 <2.0 < 0.020 NA 139 < 0.10 0.10 05/04/2016 5.5 8.4 < 4.0 < 0.020 NA .119 < 0.10 0.095, 11/09/2016 4.3 12.2 < 4.0 < 0.020 NA 124 < 0.10 0.27 05/02/2017 1 3.9 7.0 <2.0 -0.40 NA 1 96.0 1 <0.10 1 0.072 Standards 1 10 1 250 1. 70 1 250 1 500 1 7.5 T NL Clement Pappas May 2017 Groundwater Monitoring Hendersonville, North Carolina Page 1 of 5 June 2017 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Sample Name .. - - Sample Date (mm/dd/yyyy) o; -E V F' (m9/L) (mg/L) .. (CFU per 100 mL) (Mg/L) '(mg/L) .O N F (mg/6 p a (.g/L) N 2 F (mg/L) 05/15/2002 2.9 15 < ,1.1 0.42 1.7 < 40 < 0.10 NA 11/05/2002 1.4 16 < 1.1 0.54 < U 83 1.3 NA " 05/13/2003 4.6 17 < 1.1 0.65 2 56 0.25 NA 11/04/2003 19 22 < 1.1 0.23 < 5.0 58 < 0.10 NA 05/05/2004 0.7 28 • < 1.1 0.57 < 5.0 80 0.15 NA 11/09/2004 1.2 34 < 1.1- 0.24 < 5.0 130 < 0.10 NA 05/17/2005 2.1 35 1 < 1.1 < 0.10 < 5.0- 110 < 0.10 NA 11/03/2005 8.1 34 1 < 1.1 0.11 < 5.0 82 < 0.10 NA 05/24/2006.' 7.8 34. < 1.1 < 0.10 < 5.0 120 < 2.5 NA 11/09/2006 1.3 37 < 1.1 0.20 < 5.0 90 < 0.1 NA 05/18/2007 1.7 42. < 1.0 0.16 < 5.0 130 < 0.10 NA 11/13/2007 4.2 41.3 < 1.1 0.25 < 5.0 112 < 0.10 NA 05/27/2008 6.7 14.3 < 1.1. 0.21 < 5.0 168 0,17 NA 11/18/2008 25.9 47.6 - < 1'A 0.17 < 5.0 80.0 < 0.10 NA 05/28/2009 16.1 29.0 4.0 0.11 ',< 5.0 188 < 0.10 NA MW-5 11/05/2009 4.7 39.1 2.0 0.15 < 5.0 112 < 0.10 NA 05/13/2010 3.2 43.0 23 0.17 < 5.0 147 < 0.10 " NA 11/08/2010 13.8 43.7 200 < 0.10 < 5.0 113 < 0.10 NA' 05/17/2011 4.0 32.3 < 4.0 < 0.10 < 5.0 < 167 < 0.10 NA 11/15/2011 3.0 52.6 120 < 0.20 < 5.0. 165 < 0.10 NA 05/17/2012 4.7 36.6 < 2.0 < 0.20 < 5.0 '110 < 0.10 NA 11/07/2012 ^ - 4.1 61.1 < 10.0 0.12 < 2.0 139 < 0.10 NA 05/16/2013 4.0 44.2 1.0 0.093 2.3 152 < 0.10 NA 11/20/2013 -, 4.2 64.6 1.0 0.19 < 2.0 162 < 0.10 NA 05/22/2014 5.8' , 6.6 < 10.0 0.099 < 2.0 110 < 0.10 NA 11/18/2014 16.0' 57.7 6.0 0.28 < 2.0 160 < 0.10 NA 05/13/201S 21.0 68A < 2.0 0.11 <. 2.0 176 < 0.10 NA 11/04/2015 7.3 20.3 7.0 < 0.0201 NA 68.0 < 0.10 0.21 05/04/2016 8,6 1 41.5 < 10.0 6.042 NA 90.0 < 0.10 0.12 11/09/2016 <1.0 45.0 < 4.0 0.42 NA 109 < 0.10 0.47 05/02/2017 8.1 29.0 3.0 <0.020 NA 134 <0.10 0.097 Standards 70- 250 1 10. 250 500 7.5 NL Clement Pappas May 2017 Groundwater Monitoring Page 2 of 5 Hendersonville, North Carolina June 2017 I Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry - Sample Name,- .,,Sample Date (mm/dd/yyyy) C O a u A!E C EI O A r (mg/L) CD o `o (mg/L) `o w u R' LL (CFU per 100 mL) r _ Z (mg/L) « _ v. (mg/L) 'O o v N N C A (mg/L) m o' E a (mg/Lj o a O a m (mg/L) MW-6 05/15/2002 6.8 9.9 SA < 0.10 11 2 40 < 0.10 NA 11/05/2002 3.9 4.6 < 1.1 0.49 9.8 51 2.5 NA 05/13/2003 .4.4 7.3 > 23.0 0.075 14 52 0.14 NA 11/04/2003 26 6.8 9.2 < 0.050 12 < 20 < 0.10 NA 05/05/2004 1.8 6.7 1.1 < 0.10 11 58 0.13 NA 11/09/2004 3.5 11 9.2 < 0.10 9.3 88 < 0.10 NA 05/17/2005 2.4 7.4 < 1.1 < 0.10 8.7 50 1 < 0.10 NA 11/03/2005 ` 6.3 9.6 < 1.1 < 0.10 9.6 66 0.17 NA 05/24/2006 7.4 10 < 1.1 < 0.10 9 54 '< 0.10 NA 11/09/2006 1.4 11 < 1.1 0.20 11 54 0.18 NA 05/18/2007 3.9 9.4 < 1.0 < 0.10 9.1 58 0.12 NA 11/13/2007 5.7 10.7 3.6 0.24 5.8 114 0.24 NA 05/27/2008 10.9 1 5.4 < 1.1 < 0.10 15.3 92.0 < 0.10 NA 11/18/2008 7.4. 7.6 > 23 < 0.10 < 5.0 36.0 <.0.10 NA 05/28/2009 6.4. 6.2 276 0.39 8.8 104 < 0.10 NA 11/05/2009- 6.4 < 5.0 30 0.10 9.3 52.0 < 0.10 NA ' 05/13/2010 14.3 5.8 < 2.0 < 0.10 8.1 44.0 < 0.10 NA 11/08/2010 16.5 5.0 7.0 1.5 9.3 48.0 < 0.10 NA 05/17/2011 6.2 9A < 2.0 < 0.10 6.8 60.0 < 0.10 NA 11/15/2011 4.6 5.2 5.0 < 0.20 7.5 82.0 < 0.10 NA 05/17/2012 21.6 8.1 28.0 1 < 0.20 8.8 52.0 < 0.10 NA 11/07/2012 6.4 6.8 3.1 < 0.020 7.5 46.0 < 0.10 NA 05/16/2013 7.5 5.4 12.1 0.048 9.4 62.0 < 0.10 NA 11/20/2013 4.4 7.3 < 1.0 < 0.020 8.6 56.0 < 0.10 NA 05/22/2014 4.6 4.5 1.0 < 0.020 10.1 32.0 < 0.10 NA 11/18/2014 16.3 6.9 13.0 0.078 9.8 49.0 < O.td NA 05/13/2015 2.1 6.2 < 1.0 < 0.020 10.1 46.0 < 0.10 NA 11/04/2015 2.2 9.5 136 1 2.9 NA 58.0 < 0.10 0.12 05/04/2016 2.1 9.4 < 2.0 0.41 NA 58.0 < 0.10 0.079 11/09/2016 7.1 9.0 < 10.0 < 0.020 NA 64.0 0.11 0.70 .05/02/2017 1.8 12.1 2.0 0.47 NA 93.0 <0.10 0.090 Standards 10 250 ] 70 250 500 7.5 NL Clement Pappas May 2017 Groundwater Monitoring Page 3 of 5 Hendersonville, North Carolina June 2017 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry . . _ -. Sample Name ' Simple Date .: (mm/dd/yyyy) C o ... "V.. O (m9/1.) 13 0 (m9/L) 0 10 , (CFU Per 100mL, - ad+ « (m9LL) .01 ..= (m9/1.) 9.. 'O M� -R (m9/L) E (m9/W .. .e .A (m9/L) MW-7 05/15/2002 20 6.5 < 1.1 5.2 26 < 40 < 0.10 NA ' 11/05/2002 16 3.3 < 1.1 1.3 1.1 68 1.4 NA 05/13/2003 9.7 3.6 2.2 1.8 9.3 44 0.72 NA 11/04/2003 19 6.1 < 1.1 0.72 < 5.0 < 2.0 < 0.10 NA. 05/05/2004 3.0 7.0 < 1.1 1.3 < 5.0 52 < 0.10 NA 11/09/2004 2.2 5.1 S.1 1.9 < 5.0 62 < 0.10 NA 05/17/2005 3.2 1 6.1 < 1.1 1.2 < 5.0 40 < 0.10 NA 11/03/2005 7.7 6.1 < 1.1 0.99 < 5.0 58 0.10 NA 05/24/2006 8.4 5.5 < 1.1 1.5 < 5.0 .48 <.0.10 NA 11/09/2006 1.9 7.0 < 1.1 1.1 6.7 38 < 0.10 NA 05/18/2007 3.6 8.6 < 1.0 2.2 5.9 70 < 0.10 NA 11/13/2007 4.2 6.8 < 1.1 1.7 < 5.0 42.0 < 0.10 NA 05/27/2008 7.6 11.5 < 1.1 2.2 6.9 88.0 < 0.10 NA 11/18/2008 7.5 7.7 < 1.1 1.7 < 5.0 30.0 < 0.10 NA 05/28/2009 23.4 9.8 1 < 4.0 2.3 < 5.0 336 < 0.10 NA 11/05/2009 5.3 10.7 2.0 2.3 11.2 70.0 < 0.10 NA 05/13/2010 4.6 11.0 < 2.0 2.5 < 5.0. 71.0 < 0.10 NA 11/08/2010 15.4 .8.9 < 2.0 2.3 . < 5.0 60.0 < 0.10 NA 05/17/2011 6.0 11.6 < 2.0 5.3 7.6 103 < 0.10' NA . 11/15/2011 2.2 9.9 < 2.0 3.5 < 5.0 89.0 < 0.10 NA 05/17/2012 4.4 10.9 < 2.0 . 3.8 < 5.0 67.0 < 0.10 NA MW-7R 11/07/2012 11.6 13.1 1 < 100 4.0 14.9 108.0 < 0.10 NA 05/16/2013 12.8 17.1 < 1.0 10.S 28.3 252 < 0.10 NA 11/20/2013 9.4 ' 14.0 < 1.0 5.5 3.5 < 250 < 0.10 NA 05/22/2014 8.9 13.1 < 10,000 5.7 4.0 93.0 < 0.10 NA 11/18/2014 19.1 16.0 < 20.0 7.1 4A 93.0 < 0.10 NA 05/13/2015 8.5 17.0 < 2.0 9.3 1 3.7 125 1 < 0.10 NA 11/04/2015 9.9 18.0 - < 2.0 8.3 NA 129 < 0.10 0.35 05/04/2016 13.5 27.7 1 < 10.0 11.2 NA 130 < 0.10 0.78 06/09/2016 - Pace NA NA NA 10.9 NA NA NA NA 06/09/2016 - Prism NA NA NA 10.0 NA NA NA NA 11/09/2016 13.0 22.7 < 20.0 12.5 NA 147 < 0.10 1.0 05/02/2017 6.7 17.9 <4.0 8.9 NA 169 <0.10 0.43 Standards 10 250 1 1 10 250 500 1 7.5 1 NL Clement Pappas May 2017 Groundwater Monitoring Page 4 of 5 Hendersonville, North Carolina June 2017 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Sample Name Sample Date (mm/dd/yyyy) V c io p t-O (mg/L) CD u (mg/L) E w V �i' (CFU per 100 mL) Y� Z (mg/L) , v (mg/L) N 9 N Y F .(mg/L) A - (mg/L) N G a O a. F (mg/L) 05/15/2002 6.8 8.7 < 1.1 < 0.10 9.1 64 < 0.10 NA 11/05/2002 4.8 9.8 < 1.1 ' 0.16 7 100 0.57 NA 05/13/2003 5.5 3.3 2.2 1.4 9.4 64 0.41 NA 11/04/2003 27 8.1 6.9 < 0.050 13 54 < 0.10 NA 05/05/2004 3.0 7.4 < 1.1 0.24 9.8 140 < 0.10 NA 11/09/2004 3.7 6.7 > 23 0.79 6.8 120 < 0.10 NA 05/17/2005 3.8 8.3 < 1.1 0.61 6.4 88 < 0.10 NA 11/03/2005 7.1 11 < 1.1 0.95 8.4 100 < 0.10 NA 05/24/2006 15 10 < 1.1 0.39 8.1 130 < 0.10 NA 11/09/2006 4.7 12 <'1.1 0.97 7.7 96 <0:10 NA 05/18/2007 5.0 15 < 1.0 3.0 13 290 < 0.10 NA 11/13/2007 8.3 19.6 < 11 .'0.97 26.6 154 < 0.10, NA 05/27/2008 12.4 20.0 < 1.1 0.55 35.8 184 < 0.10 NA 1.1/18/2008 14.4 17.2 2.2 < 0.10 21.5 118 < 0.10 NA 05/28/2009 6.2 24.9 240 0.74 24.9 192 < 0.10 NA MW-8 11/05/2009 - 10.8 15A 50 0.54 18.4 114 < 0.10 NA 05/13/2010 10.8 14.7 < 2.0 1.1 24.1 106 < 0.10 NA 11/08/2010 23.2 24.3 200 < 0.10 26.3 173 < 0.10 NA 05/17/2011 10 16.9 10.0 12.2 16.1 232 < 0.10 NA 11/15/2011 8.0 26.6 < 2.0 3.7 1 20.2 232 1 < 0.10 NA 05/17/2012 14.4 24.8 12.0 8.0 22.9 356 < 0.10 NA 11/07/2012 24.8 26.3 < 100 1.9 28.3. 324 < 0.10 NA 05/16/2013 15.8 8.8 10.9 6.8 13A 248 < 0.10 NA 11/20/2013 21.0 15.4 < 1.0 1.3 24.3 342 < 0.10 NA 05/22/2014 17.6 14.5 < 10.0 0.61 17.8 352 < 0.10 NA 11/18/2014 54.0 16.4. < 4.0 1.1 13.2 421 < 0.10 NA 05/13/2015 19.7 18.3 <.2.0 9.7 12.2 454 < 0.10 NA 11/04/2015 15.0 21.6 4.0 3.0 NA 396 < 0:10 0.82 .05/04/2016 15.0 24.5 < 10.0 19.1 NA 398 < 0.10 0.62 5/9/2016 - Pace NA NA NA 26.3 NA NA . NA NA 06/09/2016 - Prism NA NA NA 26.0 NA NA NA LNA 11/09/2016 9.7 12.0 < 4.0 14.3 NA 333 < 0.10 0.26 ' 05/02/2017 11.4 18.9 8.0 12.4 NA 497 <0.10 0.30 MW-9 05/13/2015 2.2 " 12A < 2.0 1.0 1 5.5 94.0 < 0.10 NA 11/04/2015 3.8 2.6 < 1.0 <' 0.020 NA 58.0 < 0.10 0.45 05/04/2016 15.0 5.3 < 10.0 0.64 NA . 51.0. < 0.10 0.095 11/09/2016 9.3 10.7 < 20.0 0.77 NA 69.0 < 0.10 0.76 05/02/2017 7.6 3.8 <4.0 0.17 NA 92.0 <0.10 0.61 Standards . 10 250) 7 - 70 250 500 7.5 NL Notes: mg/L Milligrams per liter CFU Coliform forming units mL Milliliters 15.0 Indicates concentration equal to or above the respective standard. < 4.0 Indicates constituent concentration was not detected above the laboratory reporting limit. Standards From North Carolina Administrative Code, Title 15A, Subchapter 2L April 1, 2013, except total organic carbon and fecal coliform. Total organic carbon standard from Spray Irrigation Permit Number W00004797. Fecal coliform standard is 2L standard for total coliform. Sulfate Removed from list of necessary analyses as of fall 2015 and replaced by total phosphorous. NA Not analyzed NL Indicates no standard limit is set. 06-09-2016 - Pace A re -sampling event was performed on June 9, 2016 to investigate nitrate exceedances in MW-711 and MW-8.One set of samples was analyzed by Pace Analytical Services, and a second set of samples was analyzed by Prism Laboratories. - Clement Pappas May 2017 Groundwater Monitoring. Page 5 of 5 Hendersonville, North Carolina . June 2017 Table 2 Current and Historical Groundwater Elevation Measurements Well Date Measured Depth to Groundwater . Top -of- Casing Elevation Top -of -Casing Height Above Ground Surface Groundwater Elevation' Identification (mm/dd/yyyy) (ft-BTOC) _ (feet) (feet) (feet) MW-2R 05/24/2006 9.29 2063.00 3.77 2053.71 11/09/2006 6.49 2063.00 3.77 2056.51 05/18/2007 7.94 2063.00 3.77 2055.06 11/13/2007 8.46 2063.00 3.77 2054.54 05/27/2008 8A8 2063.00 3.77 2054.52 11/18/2008 8.50 2063.00 3.77 2054.50 05/28/2009 5.43 2063.00 3.77 2057.57 11/05/2009 6.72 2063.00 3.77 2056.28 05/13/2010 7.36 2063.00 3.77 2055.64 11/08/2010 9.60 2063.00 3.77 2053AO 05/17/2011 7.25 2063.00 3.77 2055.75 11/15/2011 7.86 2063.00 3.77 2055.14 05/17/2012 5.19 2063.00 3.77 2057.81 11/07/2012 7.74 2062.36 3.77 2054.62 05/16/2013 6.86 2062.36 3.77 2055.50 11/20/2013 7.92 2062.36 3.77 2054.44 05/22/2014 7.56 2062.36 3.77 2054.80 11/18/2014 8.89 2062.36 3.71 2053.47 Well abandoned, replaced by MW-9 MW-4 05/15/2002 9.32 2064.60 2A3 2055.28 11/05/2002 9.49 2064.60 2A3 2055.11 05/13/2003 8.20 2064.60 2.43 2056.40 11/04/2003 9.23 2064.60 2.43 2055.37 OS/05/2004 9.35 2064.60 2.43 2055.25 11/09/2004 8.61 2064.60 2.43 2055.99 05/17/2005 6.19 2064.60 2:43 2058A1 11/03/2005 9.57 2064.60 2.43 2055.03 05/24/2006 9.60 2064.60 2.43 2055.00 11/09/2006 8A1 2064.60 2.43 2056.19 05/18/2007 9A2 2064.60 2.43 2055.18. 11/13/2007 9.89 2064.60 2.43 2054.71 05/27/2008 9.78 2064.60 2.43 2054.82 11/18/2006 9.76 2064.60 2.43 2054.94 05/28/2009 7.16 2064.60 2.43 2057.44 11/05/2009 8.53 2064.60 2.43 2056.07 05/13/2010 8.83 2064.60 2A3 2055.77 11/08/2010 9.30 2064.60 2A3 2055.30 05/17/2011 8.97 2064.60' 2A3 2055.63 11/15/2011 9.48 2064.60 2A3 2055.12 05/17/2012 7.62 2064.60 2A3 2056.98 11/07/2012 9.32 2063.77 2.43 2054.45 05/16/2013 7.93 2063.77 2.43 2055.84 11/20/2013 8.87 2063.77 2.43 2054.90 05/22/2014 8.70 2063.77' 2.43 2055.07 11/18/2014 8.54 2063.77 2.43 2055.23 05/13/2015 9.18 2063.77 2.43 2054.59 11/4/2015 6.93 2063:77 2.43 2056.94 05/04/2016 8A3 2063.77 2.43 2055.34 11/09/2016 9.63 2063.77 2.43 2054.14 05/02/2017 7.82 2063.77 2.43 2055.95 Clement Pappas May 2017 Groundwater Monitoring Hendersonville, North Carolina Page 1 of 5 June 2017 Table 2 Current and Historical Groundwater Elevation Measurements Well . Date Measured Depth to Groundwater Top -of- Casing Elevation Top-of,Casing Height, Above Ground Surface Groundwater Elevation Identification (mm/dd/yyyy) (ft=BTOC) (feet) (feet) (feet) Mw-5 • 05/15/2002 8.31 2086AO 3.00 2078.09 11/05/2002 10.20 2086AO 3.00 2076.20 05/13/2003 8.29 2086.40 3.00 2078.11 1.1/04/2003 .9.92 2086AO 3.00 2076.48 05/05/2004 8.75 2086.40 3.00 2077.65 11/09/2004 8.50 2086.40 3.00 2077.90 05/17/2005 8.87 2086.40 3.00 2077.53 11/03/2005 9.70 2086.40 3.00 2076.70 05/24/2006 9.34 2086.40 3.00 2077.06 11/09/2006 8.39 2086.40 3.00. 2078.01 05/18/2007. 9.16 2086.40 3.00 2077.24 11/13/2007 11.00 2086.40 3.00 207SAO 05/27/2008 9.84 2086.40. 3.00 207656 11/18/2008 11.59 2086.40 3.00 2074.81 05/28/2009 7.95 2086.40 3.00 2078A5 11/05/2009 8.63 2086AO 3.00 2077.77 05/13/2010 8.87 2086AO 3.00 2077.53 11/08/2010 10.24 2086AO 3.00 2076.16.. 05/17/2011 8.99 2086AO 3.00 2077.41 11/15/2011 10.58 2086AO 3.00 2075.82 05/17/2012 8.73 2086AO 3.00 2077.67 11/07/2012 9.65 2085.60 3.00 2075.95 . 05/16/2013 8.14 2085.60 3.00 2077.46 11/20/2013 9.33 2085.60 3.00 2076.27 05/22/2014 8.57 2085.60 3.00 2077.03 11/18/2014 9.04 2085.60 3.00 2076.56 05/13/2015 8.92 2085.60 3.00 2076.68 11/4/2015 8.12 2085.60 3.00 2077.48 05/04/2016 8.54 2085.60 3.00 2077.06 11/09/2016 11.25 2085.60 3.00 2074.35 05/02/2017 8.63 2085.60 3.00 2076.97 Clement Pappas May 2017 Groundwater Monitoring Page 2 of.5 Hendersonville, North Carolina June 2017 Table 2 Current and Historical Groundwater Elevation Measurements Well Date Measured Depth to • Groundwater, Top. -of- Casing Elevation Top -of -Casing , Height Above Ground Surface Groundwater Elevation Identification (mm/dd/yyyy) (ft-BTOC) ' (feet) (feet) (feet), MW-6 05/15/2002 6.20 2061.90 3.00 2055.70 11/05/2002'. 6.15 2061.90 3.00 2055.75 05/13/2003 5A3 2061.90 3.00 2056.47 11/04/2003 5.85 2061.90 3.00 2056.05 05/05/2004 6.00 2061.90 3.00 2055.90 11/09/2004 5.32 2061.90 3.00 2056.58 05/17/2005 6.10 2061.90 3.00 2055.80 11/03/2005 6.01 2061.90 3.00 2055.89 05/24/2006 6A8 2061.90 3.00 205SA2, 11/09/2006 5.71 2061.90 3.00 2056.19 05/18/2007 6.50 2061.90 3.00 205SAO 11/13/2007 7.85 2061.90. 3.00 2054.05 05/27/2008 7.01 2061.90 3.00 2054.89 11/18/2008 7.38 2061.90 3.00 2054.52 05/28/2009 5.63 2061.90 3.00 2056.27 11/05/2009 5.74 . 2061.90 3.00 2056.16 05/13/2010 . 5.90 _ 2061.90 3.00 2056.00 11/08/2010 5.99 2061.90 3.00- 2055.91 05/17/2011 5.85 2061.90 3.00 2056.05 11/15/2011 6.14 2061.90 3.00 2055.76 05/17/2012 5.87 2061.90 3.00 2056.03 11/07/2012 6.05 2061.17 . 3.00 2055.12 05/16/2013 5.84 2061.17 3.00 2055.33 11/20/2013 5.96 2061.17 3.00 2055.21 05/22/2014 5.96 2061.17 3.00 2055.21 11/18/2014 5.82 2061.17 3.00 2055.35 05/13/2015 6.05 2061.17 3.00 2055.12 11/4/2015 5.18 2061.17. 3.00 2055.99 05/04/2016 5.59 2061.17 3.00 2055.58 11/09/2016 7A2 2061.17 3.00 2053.75 05/02/2017 5.31 2061.17 3.00 . 2055.86 0 Clement Pappas May 2017 Groundwater Monitoring Page 3 of 5 Hendersonville, North Carolina June 2017 Table 2 Current and Historical Groundwater Elevation Measurements Well Date Measured Depth to Groundwater Top -of- Casing Elevation Top -of -Casing Height Above Ground Surface 'Groundwater - Elevation Identification (mm/dd/yyyy) (ft-BTOC) (feet) (feet) .(feet) MW-7 05/15/2002 10.90 2062.70 3.00 2051.80 11/05/2002 11.35 2062.70 3.00 2051.35 05/13/2003 8.87 2062.70 3.00. 2053.83 11/04/2003 10.78 2062.70 3.0.0 2051.92 05/05/2004 10.80 2062.70 3.00 2051.90 11/09/2004 9.70 2062.70 3.00 2053.00, 05/17/2005 10.60 2062.70 3.00 2052.10 11/03/2005 11.09 2062.70 3.00 2051.61 05/24/2006 11.27 2062.70 3.00 2051 A3 11/09/2006 9.71 2062.70 3.00 2052.99 05/18/2007 11.02 2062.70 3.00 2051.68 11/13/2007 11.76 2062.70 3.00 2050.94 05/27/2008 11.55 2062.70 3.00 2051.15 11/18/2008 11.63 2062.70 3.00 2051.07 05/28/2009 8.21 2062.70 3.00 2054.49 11/05/2009 9.89 2062.70 3.00 2052.81 05/13/2010 10.44 2062.70 3.00 2052.26 11/08/2010 11.12 2062.70 3.00 2051.58 05/17/2011 10.80 2062.70 3.00 2051.90 11/15/2011 11.43 2062.70 3.00 2051.27 05/17/2012 8.91 .2062.70 3.00 2053.79 MW-7R. 11/07/2012 12.02 2062.86 3.00 2050.84 05/16/2013 10.29 2062.86 3.00 2052.57. 11/20/2013 11.69 2062.86 3.00 2051.17 05/22/2014 11.38 2062.86 3.00 2051A8 11/18/2014 11.25 2062.86 3.00 2051.61 05/13/2015 11.94 2062.86 3.00 2050.92 11/4/2015 8.43 2062.86 3.00 2054A3 05/04/2016 11.08 _ 2062.86 3.00 2051.78 11/09/2016 12.63 2062.86 3.00 2050.23 05/02/2017 10.13 2062.86 3.00 2052.73 Clement Pappas May 2017 Groundwater Monitoring Page 4 of 5 Hendersonville, North Carolina June 2017 Table 2 Current and Historical Groundwater Elevation Measurements Well Date Measured Depth to Groundwater Top -of- Casing Elevation Top -of -Casing Height Above Ground Surface Groundwater Elevation Identification (mm/dd/yyyy) (ft-BTOC) (feet)' (feet) ' (feet) MW-8 05/15/2002 10.25 2061AO 3.00 2051.15 11/05/2002 10.35 2061AO 3.00 .. 2051.05 05/13/2003 8.16 2061AO -3.00 2053.24 11/04/2003 10.23 2061.40 3.00 2051.17 05/05/2004 10.30 2061AO 3.00 2051.10 11/09/2004 8.90 2061.40. 3.00 2052.50 05/17/2005 10.08 2061AO 3.00 2051.32 11/03/2005 10.61 2061.40 3.00 2050.79 05/24/2006 10.60 2061.40 3.00 2050.80 11/09/2006 9.40 2061.40 3.00 2052.00 05/18/2007 10.31 2061.40 3.00 2051.09 11/13/2007 11.09 2061.40 3.00 2050.31 05/27/2008 10.83 2061.40, 3.00 2050.57 11/18/2008 11.11 2061.40 3.00 2050.29 05/28/2009 8.25 2061.40 3.00 2053.15 11/05/2009 9.22. 2061.40 3.00 2052.18 '05/13/2010 9.88 2061.40 .3.00 2051.52 11/08/2010 10.38 2061AO 3.00 2051.02 05/17/2011 10.27 2061.40 3.00 2051.13 11/15/2011 10.87 2061AO 3.00 2050.53 05/17/2012 8.03 2061.40 3.00 2053.37 11/07/2012 10AS 2060.80 .3.00 2050.35 05/16/2013 8.58 2060.80 3.00 2052.22 r 11/20/2013 10.34 2060.80 3.00 2050.46 05/22/2014 9.79 2060.80 3.00 2051.01 11/18/2014 10.03 2060.80 3.00 2050.77 05/13/2015 10.34 2060.80 3.00 2050.46 11/4/2015 7.21 2060.80 3.00 2053.59 05/04/2016 9.84 2060.80 3.00 2050.96 11/09/2016 11.16 2,060.80 3.00 2049.64 05/02/2017 8AB, 2060.80 3.00 2052.32 MW-9 05/13/2015 6.03 2060.23 1.44 2054.20 11/4/2015 2.89 2060.23 1.44 2057.34 05/04/2016 .5.53 2060.23 1.44 2054.70 11/09/2016 6.55 2060.23 1.44 2053.68 05/02/2017 3.99 2060.23 1.44 2056.24 Notes: ft-BTOC Feet below top -of -well casing Top -of -casing MW-5 through MW-8 top -of -casing elevations based upon a survey by Hill and Associates Surveyors, dated January 10, elevations 2002 through May 2012. MW-2R and MW-4 top -of -casing elevations based upon differential level measurements made by Altamont Environmental, Inc. on June 26, 2006 through May 2012. The top -of -casing elevations for the monitoring wells were resurveyed on November 21, 2012 by Wes Cole Land Surveying. The top -of -casing elevations for MW-9 were surveyed on May 29, 2015 by Wes Cole Land Surveying. Groundwater Top of casing minus depth to groundwater. - elevations Clement Pappas May 2017 Groundwater Monitoring Page 5 of 5 Hendersonville, North Carolina June 2017 Pace Analytical Services, LLC aCe IJ lalXica ' 2225 Riverside Asheville, NC 2880404 mn wpacelabs.com. (828)254-7176 . SAMPLE ANALYTE COUNT Project: Clement Pappas 5/2: Pace. Project No.: 92339086 - Analytes Lab.ID Sample. ID Method Analysts. Reported ..Laboratory " 92339086001 MW4. SM 2540C CJH1: 1 PASI-A' . SM 9222D KDF1 1 PASI-A . EPA 350.1 1993:Rev 2.0 AES2 1" PASI=A EPA 353.2 DMN 1 PASI A . EPA365.1 AES2 1 _'.PASTA SM 4500 CI_E MLS 1 PASI-A .. . SM 5310B MJS1 1 PASTA 02339086002 MW-5 SM 2540C CJH1 1 PASI=A SM 92220 KDF1 1 PASI A .. EPA 350 1 1993 Rev•2.0' _ AES2 _ . 1 PASTA EPA 353.2 DMN : 1 PASI-A' EPA 365.1 : AES2 1 PASI-A SM 4500-CI-E. MLS.. 1 :.PASI=A' SM 5310B MJS1 - 1 _ . PASI A 92339086003 - MW-6 .' SM 2540C - MJP 1 PASTA SM 9222D KDF1 : 1.. PASI-A" . „• . .EPA350:1 1993 Rev:2.0 " . AES2 " 1 PASTA . EPA'353.2 DMN 1 PASI A EPA 365.1 AES2 1 - PASI A. . 'SM 4500 CI-E -MLS .. 'I PASI.A SM 5310E MJS1.. 1 PASI-A . 92339086004 . MW-7R SM1 2540C `-MJP- PASI-A . SM 9222D' '. ', . KDF1 1 - PASI A EPA 350.1 1993 Rev 2.0 AES2 1, PASI-A .. - EPA 353.2 DMN 1 _ PASI;A • EPA365.1.. AES2.- '. 1 PASI-A " _ SM4500 CIE MLS 1 _ PASI A SM 5310B MJS1 1 :. PASI=A- . 92339086005 . MW-8 SM 2540C MJP 1 PASI-A . SM R222D KDF1 1 PASI=A EPA:350.1 1993 Rev 2:0" AES2: 1 PASI A EPA 353.2 - DMN 1 PAST -A EPA 365.1 - AES2 1 PASI-A SM 4500 CI-E MLS 1 PASI A .. - SM 5310B MJS1 1 PASTA .92339086006 MW=9 SM 2540C MJP 1 PASI-A SM 9222D: .. KDF1 1 PASI=A . REPORT OF LABORATORY ANALYSIS This report shall not be reproduced; except in full, .' without the written consent of. Pace Analytical Services, LLC. Page.3 of 26 Pace Analytical Services, LLC . ® - weAna�j0pl ' 2225 Riverside Dr. '. . . Asheville, NC 28804 _ .. www.pacelabs.com (828)25477176 '. SAMPLE ANALYTE COUNT. Project: Clement Pappas 5/2 Pace Project No.: 92339086 Analytes ... . LabJD Samplo ID Method Analysts. Reported Laboratory EPA 350.1 .1993 Rev 2:0. DMN.. 1 PASI-A EPA 353.2 =. DMN 1 PASI-A . ' EPA 365.1 .. . AES2 : 1 ' PASI=A' _. _ SM 4500 CI_E ... MLS _ 1 PASI A $M 53106 .' MJS1 - 1 PAS.fA . REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 26 Pace Analytical Services; LLC . , �l�eA al�illia! 2225 Riverside Dr.Asheville, . : NC 28804 www.pacelabs.com (828)25477176 ANALYTICAL RESULTS Project: Clement Pappas 5/2 Pace Project No.: 62339086 Sample; MW4. - : - Lab ID: 92339086001 Collected:: 05/02/17 12:50 . Received: 05/02/17 15:10 Matrix: Water Parameters Results . Units Report Limit DF - . Prepared... Analyzed CAS No. dual. 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved, Solids. 96:0 mg/L 25.0 • 1 05/03 ..7 05:3.6 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms ND CFU/100 mL'.. 2.0 2 05/02/17 16.56 350.1 Ammonia. Analytical Method: EPA 350.1 1993 Rev 2.0. Nitrogen, Ammonia ND mg/,L 0.10 1 05/04/17 14:40 7664-417 . 353.2 Nitrogen; NO2/NO3 unpres Analytical_Method .EPA353:2 .- Nitrogen, Nitrate . 0.40 mg/L' q0.020: 1 _ 05l03/.1711;54 -365A Phosphorus; Total. Analytical Method: EPA 365.1 Phosphorus 0.072 mg/L 0.050 1: 05/03/.17.12:10.7723-14-0 : 4500 Chloride' Analytical Method: SM 4500--CI-E Chloride 7.0 mg/L 1.0 _ _1 . 05/07/17'14:46 .16887-00-6. . 5310B TOC Analytical Method:.SM 5310B. Total Organic Carbon 3.9. mg/L, 1.0 1 05/09/17 15:41 7440-44-0 REPORT OF, LABORATORY ANALYSIS This, report shall not be reproduced, except in full, Date: 05/10/201 Z 11:57 AM without the written consent of Pace Analytical Services, LLC. Page,5 of 26 . Pace Analytical Services, LLC /+Q 2225 Riverside Dr. f�VG/'111QI�UC11 ; Ash'eville, NC 28804 . . viwww.pacelabs.com (828)254-7176 ANALYTICAL RESULTS . Project: Clement Pappas 5/2 Pace. Project No.: . 92339086 : Sampie: •.MW-5 Lab ID: 92339086002 Collected: 05/02/1711:14. Received: 05/02/17 15:10. Matrix: Water Parameters Results' Units Report Limit . DF : _ Prepared.. . Analyzed CAS. No. Qual. 2540C.Total Dissolved.Solids _ Analytical Method: SM 2540C Total Dissolved Solids ..' 134 . mg/L .: - .25.0. - 1 05/03/1.7 05:37 MBIO 9222D Fecal Coliform AVIL . Analytical Method: SM 9222D Fecal Coliforms. 3.0 CFU/100 mL. 1.0 1 05%02/17 16.25 :. _ u1 : 350.1 Ammonia. :' Analytical Method: EPA.350.1 1993 Rev 2.0 Nitrogen, Ammonia . NDmg/L: 0.10 1 '05/04/1T14:42 7664-41-7. 353:2 Nitrogen; N021NO3 unp,res AnalyticaI Method EPA 353:2 -. Nitrogen, Nitrate . _ - ND mg/L: 0.020: 1 0.5/03/17 11 52 ..365.1 Phosphorus; Total. Analytical Method: EPA 365,1 -. "Phosphorus= 0.097 - mg/L- 0.050 ..1 05/03/17 12:10 .7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E .. Chloride . 29.0: mg/L 5.0 5 : 05107/17 1.4:56 16887 00-6 . . 5310B TOC Analytical Method: SM 531013 Total Organic Carbon 8.1_: mg/L.. -1.0. 1 05/09/1715:84 7440-44-0 -'REPORT OF LABORATORY ANALYSIS r This: report shall not be reproduced, except in full, Date: 0.5/10/2017 11:57 AM without the written consent of.Pace Analytical Services, LLC. Page 6 of .26 2 Pace Analytical.Servicesi LLC . " Wg Ana0cal 2225 Riverside Dr. ,' . Asheville, NC 28804 wwwpacefabs.com (828)254-7176 ANALYTICAL RESULTS, Project: - Clement Pappas 5/2 Pace Project No.:. 92339086 -Sample: MW-fi Lab ID: 92339086003 Collected: 05/02/17 "11:50. Received: " 05/02/17 15:10 -Matrix: Water Parameters Results". Units Report Limit DF Prepared, Analyzed CAS.No. Qual 2540C Total Dissolved, Solids Analytical Method: SM 2540C . Total Dissolved Solids " •" 93.0 mg/L - "" ; .25.0 - 1 05/05/17 11:14 D6 MMO 9222D Fecal boliform AVL . Analytical Method: SM 9222D Fecal Coliforms .2.0 :CFU/100 mL-. - 1.0 :. 1 05/02/17 16:25 -350.1 Ammonia :" Analytical Method: EPA356.1 .1993'Rev 2:d Nitrogen, Ammonia . ... ND mg/L. 0.10 1 05/04/-17-14:43 766441-7 - 353.2 Nitrogen; NO2/NO3 unpres Analytical "Method: EPA•353.2 : Nitrogen, Nitrate... 0.47 _ mg/L. 0.020. 1 - " " 05/03/.1711;53"" ".-;365:1 Phosphorus, Total . Analytical Method: EPA365.1 Phosphorus 0.090 mg/L 0.6501 05/03/1712:11 7723-14-0 4500 Chloride _ Analytical Method: SM 4500-CI-E "Chloride, _ 12.1: mg/L 1.0 . 1: ". b5/07/17 14:57- 16887700-6 5310B.TOC Analytical Method: SM 531013.' Total Organic Carbon" 1.8: mg/L, .. 1'.0 1' .05/09/17'16_:12 7440-44-0 REPORT OF LABORATORY ANALYSIS. - This reportshall not be reproduced; ,except in full, Date: 05/10/2017 11:57 AM without the written consent of.Pace Analytical Services, LLC. - Page 7 of 26 - Pace Analytical Services; LLC �CGn nalXi^a� Ht 2225 Riverside Dr. . V�i I V Asheville, NC 28804 . . vnywpacelabs.com (828)254-7176 ANALYTICAL RESULTS Project: Clement Pappas 5/2 Pace Project No.: .' 92339086 Sample: MW-7R - Lab ID: 923.39086004 Collected:: 05/02/17 10:34 Received: 05/62/1.7 15:10 Matrix: Water Parameters Results_ Units- - ;.. Report Limit DF Prepared,, . Analyzed CAS No. Qua[ 2540C Total Dissolved Solids" - Analytical Method: SM 2540C . Total Dissolved Solids 169 mg/L 25.0. _ 1 05/05/17 11:15 . MBI08222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms ND CFU/100 mL;- - 4.0 -. 4 05/02/17 16.25 350.1 Ammonia, Analytical Method: EPA.3501 1993 Rev 2.0. Nitrogen, Ammonia . ND mg/L 0.10 1 05/04/17 14:45 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 8.9 mg/L 0.060 3 05/03/17 12417 365.1 Phosphorus; TOM. Analytical Method: EPA 365.1 Phosphbrus 0.43 mg/L 0.050 ..1 05/03/1 T 12:12 .7723=14-0 4500 Chloride Analytical Method: SM 4500-CI-E Chloride, ". 17.9 mg/L - _ _ 1.0 1 : 05/07/17 14:58 16887-00-6 . . 5310B .TOG Analytical Method: SM 5310E Total Organic Carbon 6.7 mg/L. 1.0 1. 05/09/17 16-47 7440-44-0 • 1. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/10/2017 11:57 AM without the written consent of Pace Analytical Services, LLC. Page ,8 of 26 - Pace Analytical Services; LLC ®" aceAnalytical 2226 Riverside_Dr.. Asheville, NC 28804 www.pacelabs,com (828)254-7176 ; ANALYTICAL RESULTS Project: Clement Pappas 5/2 Pace Project No.: 92339086 Sample:.MW-8 "" Lab ID:.92339086005 " :Collected:. 05/02/17 10:00_ Received: 05/02/17 15:10. "Matrix: Water Parameters 'Results. Units :" . Report Limit DF Prepared;.. - ;Analyzed CAS. No. Qual. '254.0C Total Dissolved. Solids Analytical Method: SM 2540C Total Dissolved Solids " 497 . mg/L ..25.0 1 05/0511"7 11:16 " MBIO 9222D Fecal Coliform AVL " Analytical Method'; SM 9222D Fecal Coliforms 8.0 CFU/100 mL: ' 1.0 1 05/02/17 16:25 :. D6,ul - 350:1 Ammonia, Analytical Method: EPA.350.1 .1 993Rev 2.0. Nitrogen, Ammonia ND mg/L. 0.10. 1 05/04/17 14:46, 7664-41-7 .353',2 Nitrogen, NOWN03 unpres Analytical Method: EPA_353:2 ,. . Nitrogen, Nitrate .. . g 12.4 ' mg/L: 0.020 1 05/03/1711;30 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Phosphorus- :: 0.30 " mg/L 0.'050 1 05/03/17.12.12 .7723-14-0' 4500 Chloride : Analytical Method: SM 4500-CI-E Chloride_ 18a mg/L _ .. .' 1.0 1 : 05/07/17 1.4:59 ,16887700-6 53106 TOC Analytical Method: SM 5310B." ,.. Total Organic Carbon 11.4 mg/L... 1.0 1 05/09/17 16:58 7440-44-0 " REPORT"OF LABORATORYANALYSIS.: This, report shall not be reproduced, except in full, Date: 05/10/201.7 11:57 AM without the written consentof Pace Analytical Services, LLC. Page 9 of,26 Pace Analytical Services, LLC ® _ aceAnalytical 2225 Riverside Dr. Asheville, NC 28804 www.pace/abs.Farn (828)254-7176 ;. ANALYTICAL RESULTS _ Project: Clement Pappas 5/2 Pace Project No.: 92339086 Sample_:.MW-9 Lab ID: 92339086006 Collected: 05/02/17 13:10 _ Received: 05/02/17 15:10 Matrix: Water Parameters Results- Units Report Limit DF Prepared; Analyzed - .. CAS No.- Qual 2540C Total Dissolved Solids.. Analytical Method: SM 2540C Total Dissolved Solids 92:0 mg/L. 25.0 1 05/05/1711:16 - MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms 'ND CFU/100 mL.. 4.0 : 4 05/02/17 16:56 :. . 350.1 Ammonia, ". Analytical.Method: EPA 350A 1993 Rev 2.0 Nitrogen, Ammonia . " ND mg/L.. 0'.1.0 1 05/08/17 12:28 7664-41-7 . 353',2 Nitrogen; NOWN03 unpres Analytical Method:. EPA,353.2 . Nitrogen, Nitrate 0.17 "- mg/L. 0.020 1 ' 05103/.17 11:59 . 365.1 Phosphorus, Total . Analytical Method: EPA 365.1 Phosphorus 0.61 mg/L 0.050 .1 05/03/1712:13.7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E .. Chloride, . 3.8. m.g/L 1.0 1 05/07/17 15:00 .16887700-6 5310B.TOG Analytical Method: .SM 5310B- Total Organic Carbon 7.6 " mg/L 1.0 1 05/09/17 18:14 7440-44-0 REPORT OF LABORATORY ANALYSIS This'report shall not be reproduced, except in full, Date: 05/10/201.7 11:57 AM without the written consent of Pace Analytical Services, LLC. Page.10 of 26 Pace Analytical.Services, LLC .2 n ( ® aCt+Q AI 2225-Riverside Dr. l�IIC0!/ Asheville, NC 28804 www.pacelabs.com (828)25477176 QUALITY CONTROL DATA Project: Clement Pappas 5/2 Pace Project No.: 92339086 . QC. Batch:- 358018 Analysis Method: SM 2540C QC Batch Method: SM 2540C . Analysis. Description: 2540C Total Dissolved Solids, . . Associated Lab Samples: 92339086601; 92339086002 METHOD BLANK: 1990491 Matrix: .Water Associated•Lab Samples: 92339086001; 92339086002: Blank `: Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L ND 2.5 05/03/17 05:20 " LABORATORY CONTROL SAMPLE: 1990492 Spike LCS LCSRec Parameter- Units Conc. . _ Result . %:Re.c " LimitsQualifiers Total Dissolved Solids mg/L 250 270 108 90-110 . SAMPLE DUPLICATE: 1990493: -" 92338734002 Dup Parameter.." Units Result Result RPD Qualifiers Total'Dissolved Solids . mg/L ""191 186 1 SAMPLE DUPLICATE: :1990494 92338823001' Dup. Parameter _ . Units . Result :.: Result ,' . RP0" Qualifiers . Total.Dissolved Solids , mg/L 284 ". :296 . 4 - Results'presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result: - REPORT OF LABORATORY ANALYSIS This:reportshall not be reproduced, except in full, Date: 05/10/2017 11:57 AM without'the written consent of Pace Analytical Services, LLC. Page.11 of 26 Pace AnalyticaLServicesi LLC ® aceAnalyiical 2225"Riverside Dr. " Asheville, NC 28804 rAmpacelabs.crom (828)254 717 6 QUALITY CONTROL -DATA Project: Clement Pappas 5/2 Pace Project No.:. 92339086 QC. Batch:" 359352 Analysis Method- SM 2640C' QC Batch Method' SM 2540C Analysis, Description:. 2540C Total Dissolved Solid_ s Associated Lab Samples:' _ 92339086003; 92339086004, 92339086005, 92339086006 " METHOD BLANK:. 1992948 Matrix: Water Associated Lab Samples: 92339086003i 92339086004, 92339086005, 92339086006 " Blank Reporting P 9 Parameter Units " Result. Limit Analyzed Qualifiers Total Dissolved Solids.. mg/L ; :: ND • - 25.0 " 05/05/17 11:13 :. LABORATORY CONTROL,SAMPLE:'. 1992949 . Spike %.Rec LCS LCS Parameter Units ; Conc. Result . - %:Red ." Limits:" Qualifiers. Total Dissolved Solids mg/L 250 246 98 90-110 SAMPLE DUPLICATE; 1992950 . . - :92339086003 ...: Dup. Parameter. Units Result .Result RPID Qualifiers .Total Dissolved Solids .' mg/L " ... 93..0 . .. 101 8''D6 . SAMPLE DUPLICATE`. :1992951 . . 92339123006. :'Dup ". Parameter Units Result'.". Result RPD: Qualifiers Total:Di$solved Solids ". mg/L .. -1.07 111 ". 4: .. Resultspresented on this' page are In the unitsindicatedby the "Units" column except where an alternate unit is presented to the right of the result:' " REPORT OF, LABORATORY ANALYSIS This report -shall not be reproduced, except in full, Date: 05/10/201.7 11:57 AM without the written consent of Pace Analytical Services, CLC. Page 1.2 of 26 Pace Analytical Services, LLC : ®_ r1 aCeAnallytical, 2225 Riverside Dr. . . Asheville, NC 28804 www.pacelabs.com.(1328)25477176 :. QUALITY CONTROL DATA Project: Clement Pappas 5/2 Pace Project No.: 92339086 QC Batch: - 358088 Analysis Method: SM 9222D QC'Batch Method: SM.9222D Analysis_Description: 9222D MBIO Fecal Coliform---AVL Associated Lab.Samples: .'92339086002; 92339086003',92339086004, 92339086005 METHOD BLANK:- 1990935 Matrix: :Water- Associated tab Samples: 92339086002i 92339086003', 92339086004, 923391)86005. .. Blank ` . Reporting .. . Parameter Units Result Limit Analyzed. 'Qualifiers Fecal Coliforms - ° CFU/100 mL .. ND .. - 1.0 05/02/17 16:25 SAMPLE DUPLICATE: 1990936 92339086005 Dup Parameter Units - Result. Result RPD _ _ Qualifiers Fecal Coliforms .. CFU/100'mL ' ' 8.0 ... ND D6 • Results'presented on this page 'are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result: REPORT OF LABORATORY ANALYSIS - This report shall not be reproduced, except in full, Date: 05/10/2017 11:57 AM without the written consentof Pace Analytical Services; LLC. Page.13 of 26 Pace Analytical Services; LLC aCeAI ® nalj cad, 2225.Riverside Dr. Asheville, NC 28804 www.pacelabs.com (828)25477176 QUALITY CONTROL:DATA Project: Clement Pappas 5/2. Pace Project No.: 92339086 QC Batch: 358989 '. Analysis Method: SM 9222D QC Batch Method:. W.9'222D . Analysis. Description:..:: 9222D MBIO Fecal Coliform -.AVL Associated Lab Samples: .92339086001; 92339086006 METHOD BLANK:. 1990937 Matrix: Water Associated Lab Samples: 92339086061; 92339086006: Blank.' Reporting Parameter .. Units Result. Limit Analyzed Qualifiers Fecal Coliforms . CFU/100 mL .. _ ND .. 1.0 05/02/17 16:56 '. SAMPLE DUPLICATE- :1990938 92339086001 .. - Dup. parameter Units : Result Result RPD ... Qualifiers Fecal Coliforms '; CFU/100 mL " ; NO Np Results presented on this -page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result:' REPORT 'OF LABORATORY ANALYSIS . This report shall not be reproduced, except in full, Date: 05/1012017 11:57 AM without the written consent of.Pace Analytical Services, LLC. Page 14 of 26 Pace Analytical Services, LLC . ® aceMaRical 2225 Riverside Dr. .Asheville, NC 28804 . . .pacelabs.com (828)254 7176 QUALITY CONTROL DATA Project: Clement Pappas 5/2 i Pace Project No.: 92339086 QC Batch: 359006 : Analysis Method: EPA 350.1 1993 Rev 2.0 QC Batch Method: EPA 350.1-1993 Rev 2.0 Analysis Description: 350A.Ammonia Associated Lab Samples: 92339086001, 92339086002 92339086003, 92339086004, 92339086005 . METHOD BLANK:" 1991040 Matrix: Water. '. Associated tab Samples: 92339086001; 92339086002;.92339086003, 92339086004, 92339086005 Blank Reporting . _ Parameter. Units Result. Limit Analyzed` Qualifiers Nitrogen, Ammonia mg/L ND 0.10 05/04/17 14:00 :. LABORATORY CONTROL SAMPLE: '1991041 - _ %. Spike LCS LCS Rec Parameter Units Conc. Result .. "/.:Rec Limits: Qualifiers. Nitrogen, Ammonia niglL 5 5:0 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE:: 1991042 1991043 MS MSD , 9 233887 1001 - . Spike Spike ', MS " ;MSD MS MSD %.Rec. Parameter - . ; Units Result Conc. Conc. .. Result Result . % Rec .. % Rec Limits . RPD.. Qual Nitrogen, Ammonia- ," mg/L ND 5 .5 ,.. 4.9 4.9 98 98 -90-110 0 MATRIX SPIKE & MATRIX SPIKE. DUPLICATE: 1991044 1991045 MS --MSD 92339003006 'Spike. Spike MS MSD MS. MSD %° Rec Parameter.. Units . Result Conc. Conc. Result Result % Rec % Rec : . Limits RPD Qual; Nitrogen, Ammonia mg/L ND 5 5. 4.8 '. 4.8 96 : 96 .90-110 : 0. Results presented'on this page'are in the units indicated by the"Units" column except where an alternate unit is presented to the right of the result:' - - REPORT OF LABORATORY ANALYSIS_ . This'reportshall not be reproduced, except in full, Date: 05/10/2017 11:57 AM without the written consent of Pace Analytical Services, LLC. Page -15 of 26 . QUALITY CONTROL DATA Project:, Clement Pappas 5/2 . Pace Project No.: 92339086 QC Batch:359540 ' Analysis Method: EPA 360.1 1993 Rev 2.0 QC Batch Method: EPA 350.1 1993 Rev 2.0 Analysis Description:, ' 356:1.Ammonia Associated Lab.Samples: 92339086006 . METHOD BLANK: 1993987 Matrix: 1Nater Associated Lab Samples: 92339086006 Blank :. Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia- mg/L ND 0.10 05/08/17 12:21 LABORATORY CONTROL "SAMPLE: .1993988 Spike LCS LCS Rec . Parameter Units : Conc: Result .. % Rec Limits Qualifies Nitrogen, Ammonia mg/L ' 5 4:9 98 90-110 MATRIX=SPIK& MATRIX SPIKE DUPLICATE: 1993989 1993990 E- „ . MS MSD, 92339606001. Spike Spike' MS MSD,, MS MSD % Red , Parameter Units Result Conc:.: Conc. Result Result % Rec % Red. Limits ..RPD" Qual Nitrogen, Ammonia mg/L ND. 5 ..5 5.1 .5.1 99 100 9021.10 -.0 Results presented on this page'are In the units indicated by the "Units." column except where an.altemate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS. This;reportshall not be reproduced; except in full, Date: 05/10/2017 11:57 AM without the written consent of, Pace Analytical Services, LLC. Page.16 of 26 Pace Analytical Services; LLC, aeeAnalytical 2225 Riverside Dr.. Asheville, NC 28804 —.pacelabs.cam (828)254-7176 QUALITY "CONTROL DATA Project: Clement Pappas 5/2 Pace Project No.: _ 92339086 QC.Batch: 358953 Analysis Method:' EPA 353.2 QC Batch Method:. EPA353.2 . Analysis"Description:. 353:2.Nitrate+Nitrite; Unpres. Associated Lab.Samples: 92339086605 . METHOD BLANK:- 1990645 Matrix: Water - Associated tab Samples: ' . 92339086005 Blank ". Reporting . Parameter- Units Result Limit Analyzed ' Qualifiers Nitrogen, Nitrate mg/L ND 0.020 05/03/17 10:47: . LABORATORY CONTROL.SAMPLE: .1990646 Spike LCS LCS %Rec .. Parameter Units Conc. - . Result , %:Rec . Limits. Qualifiers. Nitrogen, Nitrate - - mg/L 2.5- : 2:5 " 101 90-110 MATRIXSPIKE & MATRIX SPIKE DUPLICATE: 1990647 1990648 MS MSD" 92338932003 " Spike SpikeMS MSD, MS MSD %Rec Parameter' " .. Units . Result Conc. Conc: " " Result Result % Rec . % Rec Limits' RPD. Qua] Nitrogen, Nitrate : mg/L ND"" ;: 2.5 2.5 2.5- 2.5 101_ 100 90=110 —"1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: " 1990649 1990650 MS MSD 92338932005 Spike Spike MS " MSD ...Ms. MSD % Rec Parameter. Units - Result Conc. Conc.. " Result Result % Rec % Rec : " Limits' RPD Qual Nitrogen, Nitrate mg/L_ _ ND - .' 2.5 2.5 0.98 0.98'39' 39' .90-110 . " 1 M1 " - Results' presented onthis page'are In the units indicated by the "Units" column except where an alternate unit is presented to the rightof the result: REPORT OF LABORATORY ANALYSIS.. This, report shall not be reproduced, except in full, Date: 05/10/2017 11:57 AM without the written consent of. Pace Analytical Services, LLC. Page.17 of 26 Pace Arialytical Services; LLC 0 aCeAnaI060l 2225 Riverside Dr. ' Asheville, NC 28804 www.pacelabs.com (828)254-7176 QUALITY CONTROL DATA Project: Clement Pappas 5/2 Pace Project No.: . 92339086 QC Batch: 858972 Analysis Method: : EPA 363.2 QC Batch Method: EPA 353.2 Analysis.Description; 353.2.Nitrate + Nitrite, Unpres. Associated Lab Samples: '92339086001, 92339086002, 92339086003,_92339086004, 92339086006 METHOD BLANK:- 1990809 Matrix: -Water Associated Lab Samples: 92339086061, 92339086002, 92339086003, 92339086004, 92339086006 Blank.-, ` Reporting Parameter - Units Result- Limit Analyzed. Qualifiers Nitrogen, Nitrate. mg/L ND .. 0.020 05/03/17 11:31 LABORATORY CONTROL SAMPLE: 1990810 Spike 'LCS LCS %-Rec ,.. Parameter Units Conc: -- Result %:Rec Limits: Qualifiers . Nitrogen, Nitrate mg/L 2.5- 2:5 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1990811 -1990812' MS MSD . 92339019002 . Spike ' Spike MS . MSD MS MSD % Rec :. . Parameter Units Result Conc:.. Conc. .. Result Result % Rec .. % Rec Limits . •RPD. Quail Nitrogen, Nitrate mg/L' ND_ 2.5. 2.5 2.5 2.5 98 99 90=110 .0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1990813 1990844 MS MSD 92339084001 'Spike,' Spike "' M.S.' MSD MS MSD %Rec Parameter. Units _ Result _ Conc. Conc.. Result : Result % Rec % Rec :, Limits: RPD Qua[ . Nitrogen; Nitrate mg/L_ .: . 34.3 2.5 2.5 - 37.7" 37.7 .135 137 90-110 . 0 M6 - Results presented an this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result: . REPORT OF LABORATORY ANALYSIS This report shall not be reproduced; except in full; Date: 05/10/2017 11:57 AM - without the written consent'of Pace Analytical Services, LLC. Page.1.8 of 26 ' Pace Analytical Services, L.I.C. • aceAnal�jfical ® 2225 Riverside Dr. }r� " .Asheville, NC 28804 . . rnvw.pacelabs.com. 828)254-7176 QUALITY CONTROL DATA Project: Clement Pappas 5/2 Pace. Project No.: 92339086 QC Batch:358856 Analysis Method: . ' EPA365.1 QC'Batch Method:. EPA 365.1 .' - Analysis, Description: 365A Phosphorus, Total Associated Lab Samples: '92339086001; 92339086002, 92339086003, 92339086004, 92339086005, 92339086006 METHOD BLANK:. 1990212. Matrix: Water Associated Lab Samples: 92339086061; 92339086002', 92339086003, 92339086004, 92339086005, 92339086006 Blank Reporting Parameter Units - Result Limit Analyzed Qualifiers Phosphorus mg/L '. ND ' ..'• . 0.050 05/03/17 12:02 LABORATORY CONTROL SAMPLE: _ 199021.3 Spike ... LCS' LCS . % Rec Parameter Units Conc. Result . %Rec . Limits: Qualifiers Phosphorus mg/L 2.5- 2:6 -106 90-110 'MATRIX SPIKE & MATRIX SPIKE DUPLICATE: ; 199.0214 .. 1990215 MS. MSD. :. 92338788..001 Spike . Spike MS MSD MS MSD % Red . Parameter- , .: Units'..: Result- Conc:.. Coric. Result Result %Rec %-Rec Limits ..RPD -Qual Phosphorus mg/L .0.78 2.5 2.5 3.3. 3.3 102 102 90-110 0 MATRIX SPIKE &MATRIX SPIKE DUPLICATE: 1990439: 1990440 MS. ' " ..MSD- . . 92339091001 ' 'Spike. Spike MS MSD MS : MSD % Rec Parameter. Units . Result _ Conc. Conc. Result : Result % Red %.Rec :. Limits RPD Qual' Phosphorus.. mg/L ND -.2.5- 2.5 - 2.5 2.7 98 108 90-110 9. - - Results' presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.' - REPORT OF LABORATORY ANALYSIS This, report shall not be reproduced; except in full, Date: 05/10/201.7 11:57 AM without the written consent of Pace Analytical Services, LLC. Page.19 of 26 Pace Analytical Services; LLC 2225 Riverside Dr._ Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Clement Pappas 5/2 Pace. Project No.: 62339086 QC Batch:` 359135 Analysis Method: SM.4500-CI-E QC Batch Method'. SM 4500-CI-E Analysis. Description: 4500 Chloride Associated Lab Samples: 92339086001, 92339086002, 92339086003, 92339086004, 92339086005,,92339086006 METHOD BLANK:. 1991706 Matrix:.Water Associated'Lab Samples: 92339086001; 92339086002; 92339086003, 92339086004, 92339086005, 92339086006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND .. 1.0 05/071-1714:44. LABORATORY CONTROL SAMPLE:1991707 Spike LCS : LCS . %.Rec . Parameter Units : Conc. .. Result . %:Rec Limits Qualifiers Chloride mg/L 20 19:3 96 .. 90-110 MATRIX SPIKE &' MATRIX SPIKE DUPLICATE:. 1991708 1991.709 MS MSD 92339086,001 Spike Spike' MS MSD MS MSD % Rec Parameter Units Result Conc:.. Conc., Result Result - % Rec % Rec Limits .RPD.: - 'Qual Chloride :. mg/L - -0. 10 10 17.7..• .17.6 107. 106 90-110 ..0 MATRIX SPIKE& MATRIX'SPIKE DUP_LICATE`. 9991710: 1991711 MS' MSD 92338624001 Spike. Spike MS MSD MS:. MSD %Rec Parameter Units - Result Conc. Conc. Result Result % Rec % Rec : . Limits RPID Qual. Chloride • : " mg/L 4900 10 _ 10 15.0 14.9 ' .. 101_ :, 100 .90-110 0. ug/L Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result, REPORT OF LABORATORY ANALYSIS This. report shall not be reproduced, except in full, Date: 05/10/2017 11:57 AM without the written consentof. Pace Analytical Services, LLC. Page.20 of 26 Pace A_ nalytical Services, LLC ® aceAMidical.. 2225 Riverside Dr._ -Asheville, NC 28804 www.pacefabs.cam (828)254-7176 QUALITY CONTROL DATA Project: Clement Pappas 5/2 Pace Project No.: : 92339086 QC Batch:: 358933 Analysis Method: SM, 5.310E QC Batch Method' SM.5310B Analysis Description:: 5310E TOC Associated Lab Samples' _92339086001, 92339086002, 92339086003; 92339086004, 92339086005, 92339086006 METHOD BLANK: 1990538 Matrix: Water Associated'Lab Samples: 92339086001; 92339086002; 92339086003, 92339086004, 92339086005, 92339Q86006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L ND 1.0 05/09/17 12:47 LABORATORY CONTROL SAMPLE: 1990539 Spike LCS LCS . %.Rec' Parameter Units . Cone. - . Result . %.Rec . Limits Qualifiers . Total Organic Carbon mg/L 25 24:2 97 90-110 -: MATRIX SPIKE & MATRIX SPIKE DUPLICATE:: _1990540 1990541 MS- MSD .._ 92338929001 .. Spike Spike' MS MSD. MS MSD % Roe Parameter' Units Result Cone:.: Cone. .. Result Result . % Rec :. %Rec Limits ..RPD .. "Qual , Total Organic Carbon: mg/C ND :: 25--- 25 _ 26.4 26.6 104 105 90-110 —1. MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1990542 1990543' : MS' MSD 92339086004 Spike. Spike MS MSD MS . MSD % Rec Parameter.' Units,. Result .- Cone. Conc... Result Result %Rec %Rec : Limits RPD Qual.. Total Organic Carbon .. mg/L .. . 6.7 , .' 25 25 25.8 24.5 76 71 90-110 . 5. .,Results presented on this page 'are in the units Indicated by the"Units" column except where an alternate unit is presented to the right of the result. : REPORT OF LABORATORY ANALYSIS This. report shall not be reproduced, except in full, Date: 05/10/201,711:57 AM without the written consent of.Pace Analytical Services, LLC. Page 21• of-26 . Pace Analytical Services, LLC ® 2225 Riverside Dr. .. aceAnalyticol Asheville, NC 28804 wwwpacelabs.com (828)25477176 QUALIFIERS Project: Clement Pappas 5/2 Pace. Project No.: ' 92339086 DEFINITIONS DF -'Dilution Factor, if reported, represents the factor applied to the reported data.due to dilution of the sample aliquot. ND : Not Detected at or above adjusted reporting limit. J - Estimated. concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL-Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL Reporting Limit. S'- Surrogate 1,2-Diphenylhydrazine. decomposes to and. cannot be separated, from.Azobenzene using Method 8270. The result for each analyte is a combined.concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate %recovery and RPD values. LCS(D) - Laboratory. Control Sample (Duplicate) MS(D) --Matrix Spike (Duplicate) DUP - Sample Duplicate . . RPD -. RelativePercent Difference NC.- Not. Calculable.... SG - Silica Gel;= Clean -Up U -.Indicates the compound was analyzed for, but.hot detected... ....Acid preservation may.not.beappropriate for 2 Chloroethylvinyl.ether: AseparateMal:preserved to a pH of.4-5 is recommended in SW846 Chapter 4.f6rthe analysis ofAcrolein and Acrylonitril'e by EPA Method 8260... N-Nitrosodiphenylamine decomposes.and cannot be separated from Diphenylamine.using Method 8270.. The.result reported for " each analyte."is a combined concentration: " Pace Analytical is TNI accredited. Contact your Pace. PM for.the current.list of accredited.analytes. TN I.- The NELAC Institute: LABORATORIES .- -PAST-A:. Pace Analytical.Services-Asheville ANALYTE QUALIFIERS. D6- The'precision:between the sample and sample duplicate exceeded laboratory -control limits: M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory, control sample (LCS).recovery.. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution: . ul Results based upon colony.counts outside acceptable range. " • I REPORT OF LABORATORY ANALYSIS . This;report'shall not be reproduced, except in full, Date: 05/10/2017 11:57 AM without the written consent'of.Pace Analytical Services,. LLC. Page 22 of _26 lac,CeAnalytic0l Pace Analytical Services, LLC o - 2226 Riverside Dr. Asheville, NC 28804 ww. wpacelabs.com , (828)25477176 QUALITY CONTROL, DATA CROSS REFERENCE TABLE Project: Clement Pappas 5/2 Pace Project No:: _ 92339086 Analytical Lab.ID - Sample ID : ". - " QC Batch Method QCBatch' Analytical Method Batch. 92339086001 MW-4 SM 2540C 358918 92339086002 MW-5 SM 2540C 358918 92339086003 - MW-6. SM 2540C 359352 " 92339086004 MW-7R SM 2540C 359352 " 92339086005 MW-8 SM.2540C 359352- 92339086006 MW.-9 SM 2540C 359352 92339086001 MW-4 SM 9222D 358989 92339086002 MW-5 SM 9222D _ 358988 92339086003 MW-6 - SM 9222D 358988-- 9233.9086004.. MW-7R SM 9222D. 358988 92339086005 .. MW-8 SM W22D 358988 . 92339086006 MW=9, SM 9222D ., .358989 . 92339086001 MW-4 EPA 350.1 1993 Rev 2:0 ".. 359006 02339096002. MW-5 EPA850.1 1993 Rev- 2.0"." 359006 92339086003 MW-6 EPA 350.1 1993 Rev 2.0.. 350006: . 92339086004 MW-7R EPA350.1 1993 Rev 2.0 •. • 359006`. 92339086005 'MW-8 EPA-350.11993.Rev.2.0 359006 92339086006 MW-9 EPA 350.1 1993 Rev 2.0• 359540- 92339086001 MW-4' . • EPA 353.2 . 358972 92339086002 MW-5 . EPA 3532 .. 358972 92339086003" MW-6 . EPA 353.2 358972,.- 92339086604 MW-7R EPA 353.2 358972 92339086005 MW.-8 " EPA 353.2 358953. . 92339086006 " MW-9 • • EPA 353.2 358972 92339086001 MW-4' . EPA-365.1 358856 92339086002 MW-5 EPA 365.1 358856 92339086003 MW-6 EPA 365:1 . - 358856 92339086004 MW-711 EPA365.1 358856 92339086005- MW-8" EPA'365.1' .358856 92339086006 MW-9 : EPA 365.1 358856 92339086001 . MW-4 SM 46007CI-E 359135 " 92339086002 MW-5 !SM 4500-CI-E 359135 " 92339086003 MW-6 - „. GSM 4500-CI-E 359135 .92339086004 MW-711' SM 4500-CI-E .359135 92339086005 MW-8 SM 4500-C1-E:: 359135 033.9096006. MW-9 - SM 4500=CkE 359135. 92339086001 MW.-4 SM 53.1013_ 3.58933 92330086002' MW-5 SM 53.1OB 358933 ' 92339086003 MW-6 : SM 531013 358933 _ 92339086004 MW-7R SM 5310B 358933 92339096005 MW.-8 SM 5310B 358933. 92339086006' ,'. MW-9 SM 5310B 358933; REPORT OF LABORATORY ANALYSIS - - This. report shall not be reproduced; except in full, Date' 05/10/2017 11:57 AM without the written consent of.Pace Analytical Services, LLC. Page 23 of26 Document Name; Document Revised: Sept. 21, 2016 o q6' AnalX' kal Sample Condition Upon ,Receipt(SCUR) Page 1 ofI�A2 Document No.: Issuing Authority: �•' F-CAR-CS=033-Rev.01 Pace'Ctuality Office. Laboratory receiving sampl s: Asheville ] . Eden❑-. Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsirille❑. .. Client Name:. WO# 9�33908. ry I Projec Courier: ❑Fed Ex ❑UPS ❑USPS QClient IIIIII II I III'IIIIII_�II ❑ Commercial. ❑Pace ❑Other; 023380f36 ff- Custody5eal Present? ❑Yes ❑No Seals Intact?, ❑Yes ❑No Date/Inftlals Person Examining Contents: 'I'l�l Packing Material: Bub61e Wra Bubble Ba s r None Other. l g El p ❑ g ❑ 0 Thermometer: et []Blue ❑None ❑Samples an.ice, cooling process has begun, ❑ IR:6un ID: Type of Ice: Correction Factor. L' Cooler Temp Corrected ('C): ,) . i< Biological Tissue Frozen? ❑Yes ❑No ❑ti/A Temp.should be above freezing,/,6 .. USDA Regulated Soil (❑ N/Atwater sample) Did samples originate -in a quarantine zone wifhinthe United. States: CA, NY, or SC (check maps)?' Did samples originate from a foreign source (internationally; ❑Yes' ❑No Including Hawaii and Puerto Rico)? []Yes �-QNo . . Comments/Discrepancy:.. Chain of Custody Present? ❑Yes ❑No ❑N/A 1.. Samples Arrived %within Hold Time? .. P Y s j❑No. . ❑/ ❑N/A'.2 Short Hold -Titre Analysis (02 hr.)? . ❑Yes . DN.. _ ]N/A 3:_ Rush Turn Around Time'Requested? . ❑Yes. ' Oil o ❑N/A . 4.. .Sufficient Volume? ❑yes - ❑No ❑N/A 5; Correct Containers Used? I]Ye/_: ❑No. . -❑N/A ' 6. -Pace Containers Used? []Yes, ❑No ❑N/A Containers intact?. ❑Yes Samples Field Filtered? []Yes..., - []No, 1)]N/A .9; Note ifsediment is -visible in the dissolved container Sample Labels Match COC? ❑Yes: ❑No ❑N/A -Includes Date/lime/iu/Analysis aviatrix: - Hdadspace in v0A Vials (>5-6nim)? ❑yes / ❑No, :❑N/A 10: Trip Blank Present? ❑Yes; '❑i No [I N/A 11, Trip Blank Custody Seals Present? ❑Yes ❑No ❑N%A - CLIENT NOTIFICATION/RESOLUTION - Required? ❑Yes ❑No Field Data d . Person Contacted: : Date/Timec.. Comments/Sample Discrepancy: Project Manager SCURF Review: Date:. Project Manager SRF Review: Note: Whenever there Is a discrepancy affecting North Carolina compliance samples-,.5 copy of.this form will be sent to the North Carolina D,EHNR Certification Office (i.e. Out of hold,. incorrect preservative; out of temp, incorrect containers)' r Pag,e.24 of 26 . Ni o m v+ 'a 'w N Item iF -fn. .N.• n M< ZZZZ--7ZZ `BP41.1-125 mL Plastic'Unpreserved (N/A) (CI-) K M -�—t'. Pr is BP3U-250 mL,Plastic -Unpreserved (N/A) '': —' — SP2U-500 mL-Plastic Unpreserved (N/A) =w y a- rr 0 fy '� O v SP1U-1 liter Plastic Unpreserved (N/A) cr 'O •\ t BP3S-250 mL Plastic.H2504 (pH <2)-(CI-) M s O fD O fS sv f3P3N-250 mL plastic HNO3 (pH <2)' — ',X rt (D �; n BP3Z-250 mL Plastic ZN Acetate &.NaOH (>9) a . zzz 8P3C 250 mL Plastic NaOH (pH,>12) (CI-) '• a n 3 . M M. CL WGM-Wide-mouthed Glass jar Unpreserved � t � O� AGSU-1 liter Amber. Unpreserved (N/A).(CI-)' a' ffDD , Or+ .rt O _ 3 zzzzz zzzzzz AGSH-1 liter Amber HCI (PH < 2), :v! O �' A63U-250 mLAmber. Unpreserved (N/A)(CI-) . Su -n .. .^'. n D O 0'• t n C AG1S-1 liter Amber H2SO4 (pH t 2) O 7 y' c 0 n C C AMS-250 mLAmber H2SO4 (pH <2) c Z AG3A(DG3A)-250 mLAmber NH4CI (N/A)(CI-) o !Z -- n 0 0 'DG9H-40 mL VOA HCI (N/A) V69T-40 mLVOANa2 ,S203 (N/A) C% r•r n. VG9U-40 mL VOA Unp (N/A) j . DG9P 40mL VOA H3Pg4 (N/A) ft VOAK (6 "vials per kit)=5035'kit (N/A) t _ V/GK (3 vials per kit)-VPH/Gas.kit (N/A) W O1 rD .C.. r �'p o •9 Cu SPST-125 r il-Sterile Plastic (N/A -lab) —4 as M •- �• C r 3 N, C —. SPZT-250 mL Sterile Plastic_ (N/A -.lab) Z M O o N r C w ZZZX. BP3A-250 mL Plastic (NH2)2504 (9.3-9.7) . . 5 Cubitainer Co r c M p� -VSGU-20 mLScintillation'vials (N/A) GN V �-YaCE/1117IyfiG7! CHAIWOF-CUSTODY / Analytical, Request,Document The Chain -of -Custody is a"CEGAL DOCUMENT: All relevant fields must be completed accurately. 'Section A - Section B, Section C' _ Required Client Information: Required Project Information:. Invoice.lnformation: Pa e : 1 . Of 1 Company.*. ANCHOR QEA of NORTH CAROCINA . - Report To: AIez.LeSueur Ci n Attention:/I"r Address:' 231 Ha ocd Sleet Copy .To: ;; I! Y, Cempany Name: /Jn Asheville, NC 28801 . - Address: '7 �L .Hc. i' �i �a�" :F'°iT3%dr' ��� .7 k•,f�� Re utato � AV enc EmaiL•' Ganl�.JcinCGc� 2<5_Gur+ - : Purchase.Order#: Pace Quote: Phone;..K 1�j-);h/=33SG Fax Project Name: Clement Pappas."'" Pace Project Manager.. IDrri.patton .pacelabs.com, State/Location Requested Due Dale: i TU r 1 r.� . Project #: Pace Profile 'Requested Analysis Filtered Y)N IMTRix cone o. '� COLLECTED a Preservatives - • p . DunWn9 Wninr DW O . �' W.W. VAT tv*1 . w Wum w .V . a ..z SAMPLED somsoua su 04 , aL. �_ START END u r �• am r t a � c One Character per box. ' W. WP' o v € o "(A-Z,0-9.Ir) on« oi.0 w, Sample Ids must be unique - T- .Ts x �++' •`o 'v' '" O c .'.�� 'o c>• m:.0 ". y i LL ,.a, y O.. Z. U .O. N r m °� t ,a U "E di a 7° v . — _ yTDATETIME ."DATE TIME G N' O = C O N = _ _' z' ,0 z' O _' - '� ¢ .P S�izl�•. j'J N. �� �Q4^-iC� 1 nnw� wr,' z z z z z '.Mw-s 2 . wr'x 3' ` "Wows . WT. I j lam' x x X'. x + �.3, 'x 4' MW-7R. Wi X X' X. X 6_' Mw� wT X x X X X -B MIN-9 WT' t�IG V ." X X X. X' X L` r T : x x X 10_... ', .. ADDITIONAL COMMENTS .. •REUNDUISHEDBYIAFFILIATION '. DATE. •TIME.' - - . ACCEPTEDBYIAFFILIATION: _ DATE . .TIME .SAMP,LECONDITIONS , wa�I�,-saw-r;t�5 ,�i7 �-��l �.�"r`�nr'i,;•�r� s!.=/�� I S i �. , I�''--=� < l�ll� � i {� I� �� � ? : ,�-' - - - SAMPLER NAME AND SIGNATURE - c a m PRINT Name of SAMPLER: m } , } SIGNATURE,Of$AMPCER:� -DATE Signed.. % % `•71. K 'MU rn c} aceAnalytical' wwwpecelabs:som, May 10, 2017 Brian Gant Altamont Environmental 231 Haywood Street Asheville, NC 28804 RE: Project: Clement Pappas 5/2 Pace Project No.: 92339091 Dear Brian Gant: Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Enclosed are the analytical results for sample(s) received by the laboratory on May 02, 2017. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions. concerning this report, please feel free to contact me. Sincerely, Lord Patton lorri.patton@pacelabs.com 1(828)254-7176 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 17 aceAnalyfical wwww0lebs wrn Project: Clement Pappas 5/2 Pace Project No.: 92339091 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 17 Pace Analytical Services, LLC g p g � aCeAR. a�ytiCal 2225 Riverside Dr. Asheville, NC 28804 vn»rpacelebs_cori (828)254-7176 SAMPLE ANALYTE COUNT Project: Clement Pappas 5/2 Pace Project No.: 92339091 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92339091001 SWA SM 2540C MJP 1 PASI-A SM 9222D KDF1 1 PASI-A EPA 350.1 1993 Rev 2.0 DMN 1 PASI-A EPA 353.2 DMN 1 PASI-A EPA 365.1 AES2 1 PASI-A SM 4500-CI-E MLS 1 PASI-A SM 5310B MJS1 1 PASI-A 92339091002 SW-2 SM 2540C MJP 1 PASI-A SM 9222D KDF1 1 PASI-A EPA 350.1 1993 Rev 2.0 DMN 1 PASI-A EPA353.2 DMN 1 PASI-A EPA 365.1 AES2 1 PASI-A SM 4500-CI-E MLS 1 PASI-A SM 5310B MJS1 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 17 aceAnal , tical -Pacelaba_com ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Clement Pappas 5/2 Pace Project No.: 92339091 Sample: SW-1 Lab lD: 92339091001 Collected: 05/02/17 14:10 Received: 05/02/17 15:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 64.0 mg/L 25.0 1 05/05/17 11:17 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms 580 CFU/100 mL 1.0 1 05/02/17 16:56 350.1 Ammonia Analytical Method: EPA 350.1 1993 Rev 2.0 Nitrogen, Ammonia ND mg/L 0.10 1 05/08/17 12:30 7664-41-7 363.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 0.64 mg/L 0.020 1 05/03/17 12:01 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Phosphorus ND mg/L 0.050 1 05/03/1712:14 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 4.7 mg/L 1.0 1 05/07/1715:07 16887-00-6 5310B TOC Analytical Method: SM 5310B Total Organic Carbon 2.7 mg/L 1.0 1 05/09/17 18:24 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/10/2017 11:58 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 17 e -.7 aceAnalytical WWW0q.ela6ssnm ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Clement Pappas 5/2 Pace Project No.: 92339091 Sample: SW-2 Lab ID: 92339091002 Collected: 05/02/17 13:40 Received: 05/02/17 15:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CASNo. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 41.0 mg/L 25.0 1 05/05/17 11:17 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms 935 CFU/100 mL 1.0 1 05/02/17 16:56 350.1 Ammonia Analytical Method: EPA 350.1 1993 Rev 2.0 Nitrogen, Ammonia ND mg/L 0.10 1 05/08/17 12:31 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 0.63 mg/L 0.020 1 05/03/17 12:00 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Phosphorus 0.052 mg/L 0.050 1 05/03/1712:16 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 4.7 mg/L 1.0 1 05/07/1715:08 16887-00-6 5310B TOC Analytical Method: SM 5310B Total Organic Carbon 2.7 mg/L 1.0 1 05/09/17 18:59 7440-44-0 4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/10/2017 11:58 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 17 an Analytical w}vw:pacelebs;irorn QUALITY CONTROL DATA Project: Clement Pappas 512 Pace Project No.: 92339091 QC Batch: 359352 Analysis Method: SM 2540C QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids Associated Lab Samples: 92339091001, 92339091002 METHOD. BLANK: 1992948 Matrix: Water Associated Lab Samples: 92339091001, 92339091002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 05/05/17 11:13 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 1992949 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Dissolved Solids mg/L 250 246 98 90-110 SAMPLE DUPLICATE: 1992950 92339086003 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 93.0 101 8 D6 SAMPLE DUPLICATE: 1992951 92339123006 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 107 111 4 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/10/2017 11:58 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 17 aceAnalytical, wwwpaiielsbs:com Project: Clement Pappas 5/2 Pace Project No.: 92339091 QC Batch: 358989 QC Batch Method: SM 9222D Associated Lab Samples: 92339091001, 92339091002 METHOD BLANK: 1990937 Associated Lab Samples: 92339091001, 92339091002 Parameter Units Fecal Coliforms CFU/100 mL SAMPLE DUPLICATE: 1990938 Parameter Units Fecal Coliforms CFU/100 mL QUALITY CONTROL DATA Analysis Method: SM 9222D Analysis Description: 9222D MBIO Fecal Coliform -AVL Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 1.0 05/02/1716:56 . 92339086001 Dup Result Result ND ND RPD Qualifiers Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/10/2017 11:58 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 17 ac6Mai yt cal www.pacelebs;irom Project: Clement Pappas 5/2 Pace Project No.: 92339091 QC Batch: 359540 QC Batch Method: EPA 350.1 1993 Rev 2.0 Associated Lab Samples: 92339091001, 92339091002 METHOD BLANK: 1993987 Associated Lab Samples: 92339091001, 92339091002 Parameter Units Nitrogen, Ammonia mg/L LABORATORY CONTROL SAMPLE: 1993988 Parameter Units Nitrogen, Ammonia mg/L Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Analysis Method: EPA 350.1 1993 Rev 2.0 Analysis Description: 350.1 Ammonia Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.10 05/08/1712:21 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 5 4.9 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1993989 1993990 MS MSD 92339606001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.1 5.1 99 100 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05110/2017 11:58 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 17 aceAnalytical W.W.Pacefabs com QUALITY CONTROL DATA Project: Clement Pappas 5/2 Pace Project No.: 92339091 QC Batch: 358972 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92339091001, 92339091002 METHOD BLANK: 1990809 Matrix: Water Associated Lab Samples: 92339091001, 92339091002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.020 05/03/17 11:31 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 1990810 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1990811 1990812 MS MSD 92339019002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L ND 2.5 2.5 2.5 2.5 98 99 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1990813 1990814 MS MSD 92339084001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 34.3 2.5 2.5 37.7 37.7 135 137 90-110 0 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/10/2017 11:58 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 17 aceAnalytical www.pace/eb5:oorri QUALITY CONTROL DATA Project: Clement Pappas 5/2 Pace Project No.: 92339091 QC Batch: 358856 Analysis Method: EPA 365.1 QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total Associated Lab Samples: 92339091001, 92339091002 METHOD BLANK: 1990212 Matrix: Water Associated Lab Samples: 92339091001, 92339091002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phosphorus mg/L ND 0.050 05/03/1712:02 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 1990213 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg/L 2.5 2.6 106 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1990214 1990215 MS MSD 92338788001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua] Phosphorus mg/L 0.78 2.5 2.5 3.3 3.3 102 102 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1990439 1990440 MS MSD 92339091001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua[ Phosphorus mg/L ND 2.5 2.5 2.5 2.7 98 108 90-110 9 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/10/2017 11:58 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 17 aceARol ytical wwwpacelebs:coi». QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Clement Pappas 5/2 Pace Project No.: 92339091 QC Batch: 359135 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92339091001, 92339091002 METHOD BLANK: 1991706 Matrix: Water Associated Lab Samples: 92339091001, 92339091002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 05/07/1714:44 LABORATORY CONTROL SAMPLE: 1991707 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 19.3 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1991708 1991709 MS MSD 92339086001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 7.0 10 10 17.7 17.6 107 106 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1991710 1991711 MS MSD 92338524001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 4900 10 10 15.0 14.9 101 100 90-110 0 ug/L Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/10/2017 11:58 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 17 aceAnalyfical WnW.p8ce1gbs earn Project: Clement Pappas 5/2 Pace Project No.: 92339091 QC Batch: 358933 QC Batch Method: SM 5310B Associated Lab Samples: 92339091001, 92339091002 METHOD BLANK: 1990538 Associated Lab Samples: 92339091001, 92339091002 Parameter Units Total Organic Carbon mg/L LABORATORY CONTROL SAMPLE: 1990539 Parameter Units Total Organic Carbon mg/L Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Analysis Method: SM 5310B Analysis Description: 5310B TOC Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 1.0 05/09/1712:47 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 25 24.2 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1990540 1990541 MS MSD 92338929001 Spike Spike MS MSQ MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L ND 25 25 26.4 26.6 104 105 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1990542 1990543 MS MSD 92339086004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L 6.7 25 25 25.8 24.5 76 71 90-110 5 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/10/2017 11:58 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 17 aceAnalytical wivwpacelabsiom QUALIFIERS Project: Clement Pappas 5/2 Pace Project No.: 92339091 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services -Asheville ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/10/2017 11:58 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 17 aC Anal i -al . y6 www.p gc910s:com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Clement Pappas 5/2 Pace Project No.: 92339091 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92339091001 SWA SM 2540C 359352 92339091002 SW-2 SM 2540C 359352 92339091001 SWA SM 9222D 358989 92339091002 SW-2 SM 9222D 358989 92339091001 SWA EPA 350.1 1993 Rev 2.0 359540 92339091002 SW-2 EPA 350.1 1993 Rev 2.0 359540 92339091001 SWA EPA 353.2 358972 92339091002 SW-2 EPA 353.2 358972 92339091001 SWA EPA 365.1 358856 92339091002 SW-2 EPA 365.1 358856 92339091001 SWA SM 4500-CI-E 359135 92339091002 SW-2 SM 4500-CI-E 359135 92339091001 SW-1 SM 5310E 358933 92339091002 SW-2 SM 5310E 358933 ' Date: 05/10/2017 11:58 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch Page 14 of 17 G, Document` -Name: i Document Revised: tepti._24'4 . Ulb IM V60e:i of 2' Laboratory receivii-nE t-,MhOville less Eden[]. Green -wood F. 1 Huntersville. �,.Mkhan'1csvi11e[],.,. Sample Condition Upon Client Name: r WQ#':- 923890 Receipt 'Prolect.,, : Courier: E] Fed Ei E]VPS" DOSPS ❑Merc!6[ Ekadd' Elothery 9233909, Custody Seal Present?; Yes ENo Seals, Intact? Ely6s EIN6. Dat4initiais'Person tx6ailhirig Contents: Pac'king"Materlb-1. [:jE4bWe Wrap, [1pubble-,Bags []96he MOther: Thermometer[jti: []5amples odicq, coolifig p�r&ess. as begun- ' _O( []'blue. [Ken I D; Type of Ice: W !Correction Factor' 0 Cobler-Tetrip-Correct6d(! Blblb gical Tissue Frozen? Mybs. No EIN/A , Temp,shoujd bq,a4oVe-freezing. C USDA Regulated Soil NjA�Yater sample) Old samples orleinate,in-a quarantine zonevithin the United:StJtes'.:CA, NY; or SC (check Maps)?! Did samplesorlginatefrbm a f0qjgn source (internationally;, l Ico)?,FlYes, '-MNO Lj Gp: Uvw • Comments/Discrepancy;,____ Chain of Custody#reseni? es []N6 EIN/A' li. Samb , ies Arrived Wlihin Hold Time? QN/A 2:.,• Short 'H -old Time Analysis (02'Iff.)? ELI W E]N/4' Rush Turn Around Time Requested? []Yes o, EINIA 4, Sufficient Volume? E]Yes El NIA .5. C6rre6t'Co6t5iners.'Used? .1-EIN... ONI -6. -Pac6C.6ritailrids Used?s❑ No E]NiA Containers - Intact? nNd' EIN/A, 'Samples Field 0,fIfere0'; []Y6i E]N6 ._E5N Note if sediment is Osi6l% in t6'8Jssp(ved container Sarnple Labels Match -COG?' Yes, E❑IN b EINIA. He'a&Oace_ In VOAM5N:(>5 -66im)? Elyes: FIN'O',, UN/A 10. TrlpBlahk Present? Trip Blank CustodYSeals present? Elyes i No E]N/A ..CtiE,Nt-NdTitItAtION/FtES'OLUTION p'&9bh,'Cd' Contacted:: . Comments/Sample' Discr6 I pgicy" lirojedManager '_ SCURF .,SC RFR'qview: .Project :M . ainager:SRF ReView'.. Date/Time: . Date. Date: Fte10vataKeqweuS Ljiys. h Note:,,Whenever- there is.a discrepancy -affecting North'tarolina,6ornpfiance s4trpi §,z oo yd&s form.will b.e.sen1tt.6t, e North Catolina,QEHNKCertifkation Off_ (Le: lNfffhold, lifedreettoteseNativia,but.oftemp, Incorrect containers) Page 15 of 17 in 3 -o 0 1 Ko o, E N S: m -b c o' n M o d L rt -M m o :r 3 C�0 N y '0 M a M. Uf d .;CL p 9 tA C � � Ca m N a 0 ,o c. ' � v aw M a N 0 40 'oo -4 a, 4n a 4u N ZZZZZZZZZX7;;< 9P4U-125 mL Plastic,..Unpreserved (N/A) (Cl-) . R G ;r ,BP3U-250 o mL Plastic Unpreserved (N/A) 0 — 6P2U-500 ml Plastic Unpreserved (N/A) -% yr = rr o BP1U-i liter Plastic..Unpresdrved (N/A) Cr 'C 's s 0 M— w _. . . BP3S-250 mL Plastic H2SO4 (pW<:2! (CI-) u 04 a n .X rn n rr 0 �, 1 P3W.250 mL piasticHNO3 (pH <2) BP3Z 250 mL PlastitZ N Acetate &NaOH 0 Z ZZZ..,,"'ZZZZ/ x BR3C-250 mL.P.lastic NaOH (pH > 12) (01-) Cr m 3 fD WGFU-Wide-mouthed Glass jar Unpreserved O. 3 AG1U-1 IiterAmber UnpreseNed (N/A) (CI*) 0 ,: zzzz H 111ter Amber HCl AGM- pH<2) AG3U-250 m_ LAmber Unpreserved (N/A) (Cl-) O " AG1S-1 liferArnb`er H2SO4 (OH <2). ? AMS-250.m1'Amber H2SO4•(pH - 2) Z-7zzzz2rzz AG3A(DG3A)-23t5 mL Amber, NH40 (N/A)(CI-) OG9H-40_mL VOA HCI (N/A), Q VG9,T40 mL V0A Na2S203 (N/A) VG9U-40.mLVOA Unp (N/A) "0 \J�) OG9Pc40mL VOA H3PO4 (N/A) Z r yy0.�, ra VOAK,(6 vials per kit)-S035 kit (N/A) V/GK-(3 vials "per-kit)cVPH/Gas kit (N/A) a r' N SPST-125mLSterilePlastic (N/A —lab) -- SP2T 250 mLSterile Plastic (N/A -.tab) z M v; ,C BP3A,250mLPlastic:(NH2)2504(9:3-9.7) o. QD Cubitalner VSGU-20:mLScintillation vials (N/A) N !. GN CHAIWOF'=CUSTODY I Analytical Request Document �ArralytrG?f, The Chain=of-Custody is a LEGAL DOGUME-.'-' All relevant 8eltls must be;compieted'accu6fely„ ... m Section A Secdoo.Section Ci - to • .. ... .. .., ..:.. w. EL Required ClientinforMatioRequired Pro:6,jeeti..nfonrtation: invoice'Intorrnattohr ..... Page;: 1 Of" 1 Attentlgn: Comparryf )'ANCHOR'OEA'of.NORTH:CAROLINA Report To? ;Aldk LeSueur, •'/3 . ? rt`F"w" -. - - , Address'231'Ha :good Steef Copy To:-.�^ ` ' ', Com an Name,-- _ KV19V / .G;ti rav t r P Y 1ri As he�ille.;NC28801 _ � Address. • ", ..:;��{•-. � , ': r o " Erriait;J PurcFiase` Omer #t P,ace.Quo*,:, Phone. , a. 3; ' .lax _. ProjecfName Clement Pappas _ Pece'ProjectManager. lorri, non oel9bs com, • _ I Requesled,.Due Date;: j i-GrYt. ('t�' - - _- Projed #:. _ ,.. .. .. Pace Profile'#d..,. ' R uestodrAoat is,Tiltered ' . - c v q ..Dnnkirg COLECTEDurnq. OS1 : ,., . ,cooE Wninr O,W Wastb WalOr 1VW W" . ... ` .... Pm ud S`aiV5ol6dS4 SAMPLED mC � START END, U r v++ ' m: h; o 't a LL �. on ol, One Ctiaractor per boar:. wipn.�. we w„� a': z � o m- E o� (A 2 0 9/ •j` ! c ail :: Other. OT o r; Z a m Sample;lds must bo,unlq up Tiu .. ._ '2 w E't c . '� tom.. .. Q Q O C N; Z U N to •O E .0:, GATE" TIMEt `DATE 'TIME x .x.�z; z a dF. Z.., u; MUVB' T. .5 ,x 6 : ; -y , _ xv, ADOmONALCOMMENTS:., - ,.. '-• a. ..i n, +... -- „., fiEL1N0U1SHEQBYlAFflLIATiON .. t: _�.., x: bATE TIME • ` 'µz ACCEPTED BY1AFf,1LIATiON e .L. -,eQATE ..dux "TIME n .r _. `iSAMPLECO" QNS .J .., P Ie 839Y. Line tldm S i d - .. � i= lam �1 If Y:. '.� � (. v � r ..•+-'_"'.. ✓ � t tJ. . l'f .. ,/ .( SAMPLER NAME AND SIGNATURE PRINT Name,Of'SAMPLER; SIGNATURE,O€SAMPLERS; '" DATE4Signed. z "n-. ._ x...vee'+*'>ww ..-...: xK+M w•!wa re x•09z' _LL-4w=:'. .sw:..::mm-^r•s.,:-:...^-^^,-... .mm-a. ..-z,nrn.�."-....,+.x _ m-:ar•C.. -w ,•._ .r+ ANCHOR :QEA . Project Name: q{j D k Project Number'i�l^ Weather ` dew . . Sampling Personnel j',�.c,.�4 Sample .Time: l•� r�� Well Number. Well Depth in Feet (WD):_ ��---1 - . C_----------- ------ - Well Diameter. ;e10 -- Water Level in Feet (WL): " 'f e.of Casin : Yp. 9 �i�c Leri th of Water -Column: g " r 3r .. -feet Measuring Point:. `j-O(✓ SUck-Up - - (WD) = (WL) _ (LWCj T l Flush Mount / . One Casing Volume: i gallons" Comments. (LWC) x (W(;V) - Three Casing Volumes:. S 2 q gallons'. .. Actual Volume Purged: gallons Well Casing Volumes (WCI) . 1 0.041 Gal F Z" '0.17 Gal/Ft - 3" =•0.38 Gal/Ft • 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft, _8" = 2.6 Gal%Ft 12" = 5.8 Gal/Ft Purge Method: aile`r Dis .. Bailer -Teflon Dedicated Pump- Whale_Pump.., Grundfos .Other.; Sample Method: ailer-Disp B Bailer-?eflon Dedicated.Pump Whale Pump. Giundfos . Other w a ron :. Giinons Temp Specific Cond.. ( ' Dissolved . pH (S.U.) i Reduction Turbidity Reading. Time 4;. Purged (°C) . _ .'(p5/crn) j Oxygeri.(m9/I-) : i .. report toU.1 S.U. Potential.(MV) :: (NTU) .. 4 . Comments .. . z 3ti 1.2.��;� ,ce G7� 3,11 S:q6 L O��,r-- -Il t2.3: .. . _. _.��G. - 5 ' — l 7 I �9- I: - --- 10 Sampling Container. h Number of Containers .. �- Requested Analysis 500 mL Plastic- 250 mL Plastic + j 125 mL Plastic 40 mL Glass, j 1 L Glass -- - - - - -- - — - — - - - Other Protective Casing: v 'i Pad: Lock: Q Vegetation: Ur: Access: Pate: Sampling Personnel Signature: f lj�! Notes:. Samples are analyzed immediately upon collection, "C: degrees Celsius 0S/cm: micro -Siemer. or centimeter mg/L• milligrams per liter. Anchor. QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name:a> gin �iPPLf-. �GiQ,Oas .G r'tvft►I�rn Date: _@aR$MY7 y Project Number. 90iI t Weather.. Sampling Pers6nnel:el-1-CLjt/�. Sample Time! Well Number. Well Depth in Feet (WD): -1(✓'_� Well Diameter. j Water Level in Feet (WL): (3 . Type of Casing: .PVC _ --- Length of Water Column: ? L - - - feet Measucing P (WL) _ (LWC) ; _ Flush Mount Stick -UP One Casing Volume: - gallons Comments; (LWQ x (WCV) . . Three Casing Volumes: 3i G 3 gallons. J - - Actual Volume Purged:.'S -...- --. .. � . gallons Well Casing Volumes (W 1". = 0.041=:D. 7 Gal/Ft 3" =.0.38 Gal/Ft. 4" _ 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2:6 Gal/Ft ..12" =_5;8 GaljFt Purge Method:: - mailer-Disp._: Bailer-Teflori.' Dedicated Pump:. Whale Pump, Grundfos Method: Bailer=Disp 'Bailer ' Other. : .Sample - -Teflon Dedicated Pump .',.Whale Pump. Grundfos :.Other. ux1aalion f f Gallons 1 Temp Specific.Cond:- Dissolved pH (S.U.) Reduction Turbidity Reading- I Time ; 9.., .. P ! urges CC) ,.. I (pS/cm) .. ; O . e(m . /L) xY9n .. 9 report to 0. f S.U. Po Poterrtial . m TU ( � (N. � ) :Comments . 2 _ _ Flo 1,75 .i3.tr r6�-j;Qk S;74- 3 t i It S { �• I��' `i -"I 3 ,� $� :_. S• 6G:: : Z7H I S4__�. — -.- 4 . ` (((c� S. 2s: I�_Lf3�? - — 6 7 Us Sampling Container Number of Containers Requested Analysis 500 m.L: Plastic .. . 250 mL Plastic - 125 mL Plastic- 40 mL Glass - 1 L Glass Other. - -- Protective Casing: � Pad: Lock: / . Vegetation: Accesst Sam lin Personnel Si nature: P 9 9 f :. .✓ C -- , - Date. J /Z / Notes: .Samples are analyzed Immediately upon' collection.. " °C: degrees.' Celsius r PS/cm:. micro -Siemer per centimeter ;mg/L milligrams per liter mv: millivolt NTU: nephelometric turbidity units S.U.: Standard Units Rnchor.QEA of North Carolina, PLLC 231. Haywood Street Asheville, North Carolina 28801 Sampling Personnel Signature: Project Nam e:PAbN l- �tul �t1i t�Gll l3�'�Hi7lli(onIq Date 51.2li� Project Number 0} Weather 0S.Gt$P�. Sampling Personnel: S' . Sample Time: Well Number M L�/ -. ' (� Well Depth in Feet (WD):Will Diameter.. Water. Level in Feet (WL): .� . Type of Casing: 1911C Length of Water Column: feet Measuring Point.:. (WD) - (WL) _ (LWC) Flush Mount /Stick=��Up One Casing Volume: '). 3 gallons Comments:. i. K.l3n (LWC).x.(WCV) Three Casing Volumes: . 3 GG gallons Actual Volume Purged: +r '�"�_$� • ^gallons .. Weff Casing Volumes (WCV) 1 ". = 0.041, GalAt. 2" = 0.11 Gal/Ft 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal%Ft 8" = 2.6 Gal/Ft 12" = 5.8 Gal/Ft Purge Method: bailer-D•isp Bailer Teflon Dedicated Pump.. Whale Pump, Grundfos Other l Sample Method: er-Disp. /"Bailer -Teflon . Dedreated.Pump .Whale Pump . Grundfos .Other ORMation Gallons f Temp Spedfic Cond. Dissolved PH (S.11.) Reduction Turbidity Reading . Time . Purged " (� VC) (pS/cm) Oxygen (mg/Q:. report to 0..1 S.U. Potential .(MV)- .. (NTU) Comments .. . 1 II � jG 63 ; p ( 3 ZZas 573 f 2. ... _ IaZ6' i � S ��i 5� ZZ3 . G. Z3� s r��� -, �t, z (fir LL s s• zt.a : s gv . - 4 i(a3�! '..1 7.�Y7,G?:'.'23.`1_- 6 _ i - — -- 8- _- - - - Sampling container. Number of Containers - - :: �. Requested.Analysis 500.ML Plastic i 250 mL Plastic .. . . 125 rriL Plastic 40 mL Glass- -- 1 L Glass Other _ —=- - "---- -- • .- = .. --.— - -- _ _ - .. -.: _ - - = - Protective Casin " Pad: 0 ♦! Lock: ?M(C8" g:, �_ f ( K .. Veg etation: Access: G t. Sampling Personnel Signature: �/ i - Datee 51 . well 5amprng Log Page 1 of 1. . Anchor.QEA of North Carolina, PLLC 231.'Haywood Street . Asheville, North Carolina 28801 Project Name:. Date: - Project Number8?P - 1 Weather. - Sampling Personnel sample Time: 13 i0 - . Well Number. �.M : Well Depth in Feet (VIED) Well Diameter. Z,� Water Level in Feet (WL) _ - :. ( -.- — Type of Casing: Length -of WaterColumn: feet . . Measuring Point: (WD) - (WL) =.(LWC) -- - - Flush Mount / Stick-U One Casing Volume: L r gallons Comments:_ (V (L1/vCj.x (WCV) - — V,/pli jW �(j(,''(�$ Three Casing Volumes —t -_ gallons: d' [✓O([�(;�'plh1 . �� . Actual Volume Purged: ') e:/. gallons p (: Well'Casing Volumes(WCV) .1. 0.041.13al/Ft 0.17 Gal/Ft 3" =.0.38 Gal/Ft : 4 =.0.66 Gal/Ft 6" = 1.5 Gal/Ft e' 2.6 GaVFt 12" = 5.8 Gal/Ft Purge Method: Bailer-Dlsj)� : Bailer -Teflon:.' Dedicated Pump:. Whale Pump. Grundfos Other. Sample Method: .. Bailer-Dis Bailer -Teflon Dedicated Pump --;Whale Pump.. Grundfos :.Other i xi a to -Gallons .I TernSpecific p Spec Cond. Dissolved PH (S.U.) l . Reduction Turbidity_ Reading Time - .Purged (Y) (p6/cm) Oxygen (ing/y . report to 0.1 S U.. Potential (MV) (NTU - - .. . . - . .. - ) - Comments - I 3.. I. C1_(: -8 9. Sampling Container Number of Containers, Requested Analysis 500 MI-Tiast:ic - 250 mL Plastic....- 125. mL Plastic- 4D mL Glass-- i. 1 L Glass Other - Protective tasing:Pad: if-. Lock: O(G Vegetation: 0 Access: .7 Sampling Personnel Signature: Date: sampleswd.analyzed immediately upon collection. °C: degrees Celsius mV: mlllw' It pS/cmr.micro-Siemen per centimeter N7U; nephelometrlc turbidity units ' mg/L rnMigwns per liter. S.U.: Standard Units Page 10 f 1. Anchor,QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801. CALIBRATION DOCUMENTATION Project Name: GIcw1-61,. Person Conducting.Calibration:GkSf�v/. Project Number. - Date of.Calibration: .7 " Project Location �f'Y�21��{r "/1ir. Date of Field Measurements EQUIPMENT DOCUMENTATION Equipment or meters used to take measurements (e.g., water level meters, survey equipment): Equipment Type I Serial Number .1 Brand .� Date of Use _150-ft:Water Level- 1' 26154 150-fiWater, Level "j 22754" 150-ft Water Level .. 150. --- . 150-ft Drawdown MP30-1527 S01in.ist Sblinist 5/Z / -� _- -- Testwell QED — Select Turbidimeter Hach 2100Q (s/n 151006045207) HF Scientific MicroTPW (s/rr200601045) Calibration Instrument Reading i Instrument Reading Standards : (Hach 2100Q) I (HF Scientific MicroUffl. Explratlon Date', 20 NTU 100 NTU �~ 806,NTU ":� . 0.02 NTU f ;:10.0 NTU I. 1000 NTU Cal: Cal 1Cal: Cal: Cal: Cal: - Time: Time:. Time: — tme:. �Trme: Timer Verificatlon (10 NTU): ^ Verification: (Verifications Vercation: r ",Time: /-- q ' _ -- n �T77 me I1irw Time: fj� YSI SS6 Multiparameter Meter (s7n 12001057) — --- — — Instrument -Readings Calibration Expiration Date Dissolved oxygen. Initial ` {Cal: mmHg: (Time NA pH 7 S.U. Initi%a ` — pHmV: Cal pHmV: — Time: report to 0.1 S U. Vr • _ -,Go07/tr �pH 4 SAL: . Initial:" pHmV Cal: f /�� pHmV: , " Time: ieportio0.15U I `/.f/� l ."v St pH 10 S.U. Initial pHmV[ Cal: pHmV iTime: P report to 0.1 S.U. /; 3 I S p (J"��.� �G.O QC* pH 7 S.U. AM Time: , Mea- : Mid Day Time: Check: j PM Time Check report to 01 S.U. SZ Z 7>OZ%i Spec. Cond. A initial: Cal: iTime: - T QC*: AM Time: Meas iMid Day. Time: Check • PM.Time: Check NS/cn, to/� Initial: Cel Time: -- //7 ORP 1 Signature: �� 9 � Date: Notes: 1. Electronic equipment calibrated according to the manufacturer's operation manual. 2. Specific Conductivity.shoUld be calibrated"according to values representative of historic range. 3.Order of Calibration is as follows: SpecificCondudivity pH 7; pH q, pH 10, DO,.ORP, QC checks: 4. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true.balue. If QC reading's are out of range, the instrument needs to be iecalibrated. 5.' indicates that a QC "check must be performed in the morning, afternoon, and the end of the day, or every four hours. 6. •' Indicates to choose a "Specific Conductibity buffer of 14.13, 447, 84, or 23 mS which is closest to historical' readings from the project location. Page 1 of 1 " Enter date: monftorincg results were.due. ( 6/30/20i7) Will this:rnonitorlhg report (GW-59 and GW-59A) YIDS- NO be'submitteif after thc-establishedA -date? _ - X. 2 rilissiilg an (hc GR'-59 report forms?' Yi?S. NO. iF the aMwor to .question .1 cr 21s `YES'; fist in !ha space provided bofoidr, the. iveli identifieatiot7 rlumber(s), and erplainlhe problems. encounfered in obtaining the roquired information; Are an}, orthe inn ni(ariYClI% in rated of l'epair ur'maitiwniki (damaged cashigi Vhlaekcd or missing'cap,-missing .. YES - NO ' idpatirCatton P at RCC:1 evel rOwllr CIC.?� IJIitc Qf!¢II'Cr !S ���'P�ti ", Co11lr1Cl the llCPiatj ff U1rC f0)' j,ndd4itte-.X . Are any monitored constituentsequal to orabove Cite established -standards? : YES NO If the answerto.question 4 is "NO"; skip'to section 8 .. If the answer to question 4, is "YES" list the affected wells individually tRjtlj'constiluent(s) and.concef►tration(s) . exceeding standords in tho space provided bolmw- .' - Total Organic Carbon .(Limit '= 10 -mg/L)-= MW-.8:•. 11,4 mg/L; Nitrate (Limit= 10. mg/L) - MW-8:'12.4 mg/L .. Fecal:Coliform (Total,Coliform.2L standard_= 1-.0.CFU/100mL)=,MW-5: 3.0•CFU/100mL; MW=6:.2.0'CFO/100mL; - Por the constituents Identified In question 4-above, have standardsbeen exceeded' previously for the YES' . NO. same constituents) In the.same wells) In the last two'years?:. X if 0 ahstver fo questiori.5 is WO -skip to-seclion 8. - 7f the answer to ques[lori 5 fs "YES list in -the. space provided tielaw; each ii%z(!- vrr7h constituen(s) exceeding slandards, cORCGntration(S) re. p6ridd Arid sanypla colleotfon date for each occurrarice (for the last two years). . . TOC: - - Nitrate• . . - . . . . - _ 5/4/2016:. KW-8 = 15.0,mg/L 11/9/2016: MW78 _ 14.3 mg/L ;.-- .- 11/04/15: MW-8,= 15:O,mg/L - --.6/9/2016: MW-8 = 26.3 mg/L 5/13/15: MW-8 = 19.7.mg/L' .. - --' -- 5/4/2016,: MW-8 19.1:mg/L Fecal coliform: 11/4/2015:. MW-5 = 74. CFU/100mL" MW-6 = i36 CFU/100mL, MW-8_-.4.0 CF6/1001nL; 6 ' .Arethe'monitoring wells listed -in sectloh 5 located ut or Beyond.the reviewtiaunda,ry?- . 1'ES' NO. MW-5,'Mw.M; and MW-8,aid, beyond the review.boundary.. ,.- - " X. If the answerls. ".YES', a'groundwatergtiali.ty prohlem may be occuriingr CONTACT THEREGiONAt ,.. : OFFICE 114 MEDIATELYFOR GUIDANCE. If the answerls "NO monitoring wells maybe inrpropeiiy- locate'dl contact the Regional Offlce.* . - - ' . 7 Is the permittee implementing previously approved actions required by the Division involving this. YES NO gr4ndwatergi4lity0.r6blem7 " X . .Iff the answer to 4ueWon'7 is "YES , describe those actions !n the space provided belot% INN answerto question 11s "NO'; corit5ctIft RecrIona! Office wlfhlri.90 daysran evaluatlon'rnay be-, lac alred to deteanine the Impact the.was;fei. posal system !s hadlna at the revleiv and'corriplfarice'; boundaries surrounding this facility.' •falfure to do so may sublect the'nerrhittee to a Notice of Violation: fines; and/orpenafties.. :. 'Fecal. coliform was detected in MW-5 during the November.2015, November 2014,, and the November 2013 sampling " .events.. Fecal. coliform Was, last detected in MW-6 'and MW-O"during the November 2015'sampling event: Total Organic .. - 'Carbon Moc),yoci and_.SVOC analyse s.were completed for all'samples.during the May..2007 groundwater'sampling event.' The TOC. is not attributable. to VOCs' or SVOCs' and, is 'possibly naturally occurring: .. ', .. The person completing this portion {G W-59A) of the }nonitorin report should sign below and subinitthis form:wilh GW 59'fbgnsi for_iequfred wells to theaddress provided at.tlie fop of the curren. GW-59 form:' Thereby.acknowledge thatthe ab"ove Information was evaluated'and fie information swim" ltted iri dge.:. , ?report (Compliance Report GW 59A),is true and eompleEe to the:besf of.my knowle71, d. Signat0r6 of Permittee (de Authorized Agents SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: . DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617`MAIL SERVICE CENTER, RALEIGH, NC 276MI617 Phone: 919-607-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 8 31 2020 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville (Street) NC 28792 County Henderson ❑ Lagoon ❑Remediation:Infiltration Gallery (City) (State) (Zip) IN Spray Field ❑ Remediation: Contact Person: Mr. Blake Kehoe Telephone#: 8 2 8 — 6 9 3 — 0 711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump 0 Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW— 4 Date sample collected: 5 / 2 / 2 017 FIELD ANALYSES: WAS Well Depth: 18 _ 2 a ft. Well Diameter: 2 in. pH 00400: 5.96 units Temp. 000lo: 17.41 °C DRY at Depth to Water Level 82546: 7 . 82 ft. below measuring point Screened Interval: 8*ft. to16_1*ft. Spec. Cond. 00094: 183 µMhos time of Measuring Point is 2 . 43 ft. above land surface Relative M.P. Elevation: 2063.77 ft. Odor o0085: none sampling, check Volume of water pumped/bailed before sampling: 6.0 *screened interval is relative to land surface gallons Appearance here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead o1o51 ug/L Coliform: MF Fecal 31616 <2 . 0 /100mL Nitrate (NO3) as N 00620 0.40 mg/L Zn - Zinc 01092 mg/L Coliform: MP Total 31504 /10OmL Phosphorus: Total as P 00665 0.072 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 96.0 mg/L Al - Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium olo07 ug/L TOC oo68o 3 . 9 mg/L Ca - Calcium 00916 mg/L Chloride 00940 7,0 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper o1o42 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 719oo ug/L Lab Report Attached? ❑ Yes (1) ® No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L. VOC 7873 , method # Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total) Mn'- Manganese wom ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% ennittee (or Authorized Agent Name and Title - Please print or type GW-59 Rev.8/2013 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: • • DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM • • • 1.617 MAIL SERVICE CENTER, RALEIGH, NC27699.1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Dater 8 1 O2O Facility Name: Clement Pappas Non -Discharge WQ 0 0 04 7 9 7 UIC - Permit Name (if different): NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville Is"Oet) NC 28792 County Henderson ❑Lagoon El Remediation: Infiltration Gallery (city) (state) (zip) 1 Spray Field ❑ Remediation: Contact Person: Mr. Blake Kehoe Telephone#: 8 2 8 - 6 9 3 - 0 711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION MW— 5 If WELL WELL ID NUMBER (from Permit): Date sample collected: 5 /2 /2.017 FIELD ANALYSES: WAS Well Depth: 18_ 5p ft. Well Diameter: 2 in. pH 00400: 5 .50 units Temp. 000lo: 15.43 °C DRY at Depth to Water Level 82546: 8 . 6 3 ft. below measuring point Screened Interval: 9 * ft. to 19 * ft. Spec. Cond. 00094: 76 µMhos time of MeasuringPoint is 3 . 0 0 ft. above land surface Relative M.P. Elevation: 2085.6o none ft. Odor o0065: sampling, check Volume of water pumped/bailed before sampling: 5.25 gallons screened interval is relative to land surfaceAppearance here: Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services CertificationNo. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NOZ) as N oo615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 3.0 /100mL Nitrate (NO3) as N 00620 < 0 . 02 0mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0 . 0 97 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 134 mg/L Al - Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00660 8.1 mg/L Ca - Calcium oo916 mg/L Chloride 00940 29 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 . mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ® No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N: Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.8/2013 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: • • DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM • • • • 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone; 919-807.6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 8 1 2C2C Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville cstreet) NC 28792 Count Henderson y El Lagoon El Remediation: Infiltration Gallery (City) (state) (zip) ® Spray Field ❑ Remediation: Contact Person: Mr. Blake Kehoe Telephone#: 828 - 693 - 0 711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: from Permit) SAMPLING INFORMATION 6 If WELL WELL ID NUMBER (from Permit):- Date sample collected: 5 /2 /2 017 FIELD ANALYSES: WAS Well Depth. 11 '_EE ft. Well Diameter: 2 in. pH 00400: 5 . 15 units Temp. 00010: 20 . 84 °C DRY at Depth to Water Level 82546: 5 . 31 ft. below measuring point Screened Interval: 5 * ft. to 10 * ft. Spec. Cond. 00094: 118 µMhos time Measuring Point is 3 . 0 0 ft. above land surface Relative M.P. Elevation: 2061.17 ft. Odor 0008s: none sampling, check Volume of water pumped/bailed before sampling: 3.75 *screened interval is relative gallons to land surface Appearance here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services Certification No. _37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 rng/L Pb - Lead o1o51 ug/L Coliform: MF Fecal 31616 2.0 /100mL Nitrate (NO3) as N 0062o 0.47 m /L Zn - Zinc 01092 g mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0 . 090 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300- 93.0 mg/L Al - Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium olooi ug/L TOC 00680 1. 8 mg/L Ca - Calcium 00916 mg/L Chloride 00940 12 . 1 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ® No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # -# Total Ammonia 00610 < 0 . 1.0 mg/L Mg - Magnesium 00927 mg/L method (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen; Total) Mn -Manganese 01055 ug/L ,method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Permittee (or'AAu onzed Agent) Name and Title - Please print or type GW-59 Rev.8/2013 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: MIR • . DEPARTMENT, OF ENVIRONMENT:& NATURAL RESOURCES DIVISION OF WATER RESOURCES' -INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM • • • • 1617 MAIL SERVICE CENTER, RAI EIGH, NG Z7699-1617 Phone: 919-807.6306 FACILITY INFORMATION Please Print Clear)yorType PERMIT Number: Expiration Date:. g 31 2020 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville (sueet) NC 28792 Count Henderson y ❑Lagoon El Remediation: Infiltration Gallery (city) (state) (Zip) ® Spray Field ❑ Remediation: Contact Person: Mr. Blake Kehoe Telephone#: 8 2 8 - 6 9 3 - 0 71.1 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION _ MW 7R If WELL WELL ID NUMBER (from Permit): Date sample collected: 5 /2 /2 017 FIELD ANALYSES: WAS Well Depth: 17--.Uft. Well Diameter: 2 in. . pH 00400: 5 . 56 units Temp. ocolo: 17. 07 °C DRY at Depth to Water Level 82546: 1 0 _ l -4ft. below measuring point Screened Interval: 5 ft.* to 15 ft* Spec. Cond. 00094: 239 µMhos time of Measuring Point is 3 . 0 0 ft. above land surface Relative M.P. Elevation: 2062.86 ft. Odor 00085: none sampling,check Volume of water pumped/bailed before sampling: 3 . 75 *screened interval is relative to land surface gallons Appearance here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES: ❑ NO LABORATORY INFORMATION Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2),as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <4 . 0 /100mL Nitrate (NO3) as N 00620 8.9 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0 . 43 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration. Units): issolved Solids:Total 70300 7 6 2 mg/L Al - Aluminum o11o5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 6.7 mg/L Ca - Calcium 00916 mg/L Chloride 00940 17.9 mg/L Cd - Cadmium olo27 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945mg/L Hg - Mercury 71900 ug/L, Lab Report Attached? ❑ Yes (1) ® No (0) Specific Conductance o0095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L , method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% ittee (or Authorized Agent) Name and Title - Please print or type r Signature or Permittee (or GW-59 Rev, 8/2013 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: • DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES DIVISION OF WATER RESOURCES- INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM • • • • 1617 MAIL SERVICE CENTER, RALEIGH, NC27699-1611 Phone: 919407-6306 FACILITY INFORMATION Please PrintClearly orType PERMIT Number: Expiration Date: 8 3l 2020 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville (st(m) NC 28792 County Henderson El Lagoon El Remediation: Infiltration Gallery (City) . (Stair.) (zip) IN Spray Field El Remediation: Contact Person: Mr. Blake Kehoe Telephone#: 8 2 8 — 693 — 0 711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: (from Permit SAMPLING INFORMATION MW— 8 If WELL WELL ID NUMBER (from Permit): Date sample collected: 5/2 /2017 FIELD ANALYSES: WAS Well Depth: 13 _ 93 ft. Well Diameter: 2 in. pH 00400: 6 .56 units Temp. 0oolo: 15 .35 °C DRY at Depth to Water Level 82546: 8 • 4 8 ft. below measuring point Screened Interval; 3 ft* to 13 ft* Spec. Cond. 000sa: 714 µMhos time of Measuring Point is 3 . 0 0 ft. above land surface Relative M.P. Elevation: 2060.80 ft. Odor 00085: none sampling, check Volume of water pumped/bailed before sampling: 3.00 gallons -screened interval is relative to land surf ac'Appearance here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: varies; see analytical report Laboratoryidame: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 8.0 /100mL Nitrate (NO3) as N 00620 12.4 mg/L Zn - Zinc 01092 m 9lL Coliform: MF Total 31504/100mL Phosphorus: Total as P 00665 0.30 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 497 mg/L All - Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00660 11.4 mg/L Ca - Calcium 00916 mg/L Chloride 00940 18.9 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper01042 mg/L ORGANICS: (by GC, GUMS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ® No (0) Specific Conductance o0095 µMhos K - Potassium 00937 mg/L VOC 7B73 method # Total Ammonia oo6lo < 0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn -Manganese 01055 Ug/L method # TKN as N 00625 mg/L Ni - Nickel o1067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.8/2013 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: • • DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES DIVISION OF'WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM • • • • 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699.11617 Phone: 919 807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 8 31 2020 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES . Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville (street) NC 28792 Count Henderson y El Lagoon El Remediation: Infiltration Gallery (city) (state) (zip) ® Spray Field ❑ Remediation: Contact Person: Mr. Blake Kehoe Telephone#: 828 - 693 - 0 711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW- 9 Date sample collected: 5 /2 / 2 017 FIELD ANALYSES: WAS Well Depth: 18 _ 1 2,ft. Wellbiameter: 2 in. pH 00400: 5 .40units Temp. 000lo: 21 .61°C DRY at Depth to Water Level 82546: 3 . 9 9 ft. below measuring point Screened Interval: 6 *ft. to 16 * ft. Spec. Cond. 00094: 91 µMhos time of Measuring Point is 1.44 ft. above land surface Relative M.P. Elevation: 2ft. Odor 00085: none sampling,.060.23 check Volume of water pumped/bailed before sampling: 2.4 *screened interval is relative to land surface gallons, Appearance here: Samples for metals were collected unfiltered: ❑ YES El NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NOO as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <4 . 0 /100mL Nitrate (NO3) as N 00620 0.17 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.61 mg/L (Note: Use MPN method for highly turbid samples) - Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units_): issolved Solids:Total 70300 92.0 mg/L Al - Aluminum.ollo5 mg/L pH (Lab) 00403 _ units Ba - Barium 01007 ug/L TOC ooiiBo 7.6 mg/L Ca - Calcium 00916 mg/L Chloride 00940 3.8 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese o1055 ug1L ,method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L . method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.812013