WQ0004797_Monitoring (Report)_20161216

• ��INFUM
E NGINEERING 8G H YDR0GEOLOGY
231 HAYWOOD STREET.-ASHEVILLE, NC 28801
TEL.[phone] FAC.828.281. 351 RECEP
.. WWW.ALTAMONTENVIRONMENTAL.0 M Division of Water
December 16, 2016 I JAN - 3 2017
Mr. Blake Kehoe
Water oualitv'Reaional Operations
Plant EngineerL Asheville Rn•nnal Office
Lassonde Pappas and Company, Inc.
125 Industrial Park Road
'Hendersonville, North Carolina 28792
Subject:. November 2016 Groundwater Sampling Event �
Clement Pappas & Co., Inc. (Clement Pappas) � IIj� L
125 Industrial Park Road �;✓�JJ,�
Hendersonville, North Carolina
40P
Dear Mr. Kehoe:
Altamont Environmental, Inc. (Altamont) performed a groundwater sampling event -at the subject facility on
November 9, 2016. A site location map is included as Figure 1. Altamont performed the groundwater
sampling.event in accordance with the North Carolina Department of Environmental Quality (DEQ), formerly
known as the Department of Environment and Natural Resources (DENR), spray irrigation system permit
number WQ0004797 (permit most recently reissued on September 3, 2015). Altamont collected
groundwater samples from six monitoring wells: MW-4, MW-5,-MW-6, MW-7R, MW-8, and MW-9. Monitoring
well MW-9 was installed on April 14, 2015 to replace the previously damaged monitoring well MW-2R. The
locations of.the monitoring wells are shown -on Figure 2 (attached). Altamont submitted the groundwater
samples to Pace Analytical Services, Inc. (Pace), a North Carolina -certified laboratory, for analysis of the
parameters specified in the permit.
Table 1 summarizes the current and historical laboratory analytical results for microbiology and wet
chemistry. All parameters analyzed, except total organic carbon (TOC) and nitrate, were below the permit
limits and North Carolina Administrative Code, Title 15A, Subcliapter 2L.0202 Standards (2L standards).
The TOC concentrations can be summarized as follows:
• The permit limit for TOC is 10 milligrams per liter (mg/L).
• Similar to previous sampling events, the TOC concentration in the MW-7R sample collected during
this event (November 2016) was in excess of the.permit limit.
• TOC concentrations in samples MW-4, MW-6, MW-8, and MW-9 collected during this event
(November 2016) were below the permit limit. TOC was not detected in the sample collected from
MW-5.
Nitrate concentrations can be summarized as follows:
• The permit limit for nitrate is 10 mg/L.
Similar to the previous sampling event (May 2016), nitrate concentrations exceeded the permit limit
in the samples collected from monitoring wells MW-7R and MW-8.
• Nitrate was not detected in samples from monitoring wells MW-4 and MW-6. Nitrate concentrations
detected in samples from monitoring wells MW75 and MW-9 were reported below the permit limit.
P:\Clement Pappas\Reports\2016 2081.01\November\Cover Letter —November 2016.Doc

Blake Kehoe
-December 16, 2016
Page 2 of 3
Following the May 2016 sampling event, Clement Pappas requested that Altamont analyze the overall
effluent application rates for the irrigation system in an effort to determine if the effluent may have been
influencing groundwater results, specifically in regards to nitrate concentrations. As conveyed to the DEQ,
Altamont's analysis found that it was highly unlikely that nitrogen concentrations in the effluent were
influencing nitrate concentrations in groundwater. The more likely source of nitrate exceedances in
floodplain monitoring wells (monitoring wells MW-7R and MW-8), as identified by DEQ and Altamont, was the
continuous flooding of Mud Creek and its nutrient loading associated with runoff from agricultural fields
upstream of the facility.
In -order to be proactive, Clement Pappas contracted Nutter and Associates to analyze the overall health and
performance of the land application system. This analysis resulted in a report that included
recommendations to improve the longevity of the system, while reducing the likelihood of impacts to
groundwater. Recommendations that have been implemented by Clement Pappas include the following.
• In order to avoid introducing additional nitrogen to soils at the subject facility, Clement Pappas has
implemented the practice of bailing harvested fescue and removing it from the irrigation fields,
instead of mowing it and allowing it to decompose. Removing the harvested fescue should result in
improved vegetative growth, which will allow the fescue to uptake additional available nitrogen.
Additionally, it is expected that removal of the harvested fescue will result in greater assimilation of
nitrogen into facility soils and reduce the potential for nitrogen leaching.
• In an effort to correct calcium deficiencies in the irrigation fields, gypsum is applied. Gypsum was
applied to the irrigation fields at a rate of approximately 5 tons per acre during 2016. Correcting
calcium deficiencies allows the fescue to better uptake nutrients, thus reducing the available
nutrients in soils that could potentially leach to groundwater. Clement Pappas also applied foliar
manganese chelate to the fescue in an effort to increase nutrient uptake and further limit the
amount of nutrients available in soils that could potentially leach to groundwater.
Table 2 summarizes the current and historical laboratory analytical results for volatile organic compounds
(VOCs) analyzed by EPA Standard Method 6200. In accordance with permit requirements, samples are
analyzed for VOCs once annually, during the month of November. All VOCs analyzed, except
tetrachloroethene, trichloroethene, and cis-1,2-dichloroethene, were detected below the permit limits or 2L
standards.
VOC concentrations can be summarized as follows:
• Three VOCs (tetrachloroethene, trichloroethene, and cis-1,2-dichloroethene) were detected in the
sample collected from monitoring well MW-5. All three of these VOCs were detected at
concentrations above their 2L standards. These VOCs have been consistently detected at high
concentrations in samples collected from this monitoring well since 2002. Concentrations are
generally trending downward, with occasional spikes in the data.
• No VOCs were detected in the samples collected from monitoring wells MW-4, MW-6, MW-7R, MW-8,
and MW-9.
Table 3 summarizes the current and historical groundwater elevations. With the exception of monitoring well
MW-9, all of the monitoring well concrete pads and top -of -well casing elevations were surveyed by Wes Cole
Land Surveying, PA on November 21, 2012. Monitoring well MW-9 was surveyed by Wes Cole Land
Surveying, PA on May 29, 2015. The surveyed elevations are indicated on Table 3 and on Figure 2.
In accordance with the spray irrigation permit, Clement Pappas is required to submit the following by
December 31, 2016. (on or before the last working day of the month following the sampling month) to the
DEQ:
• Laboratory analytical report and chain -of -custody form (Attachment A); the well sampling logs and
equipment documentation and instrument calibration data sheet are also included (Attachment B)
P:\Clement Pappas\Reports\2016 2081.01\November\Cover Letter —November 2016.Doc

Blake Kehoe
December 16, 2016
Page 3 of 3 :
• DEQ GW-59A—Compliance Report Form (Attachment C)
• DEQ GW-59—Groundwater Quality Monitoring Compliance Report Form for each monitoring well
(Attachment D)
Aitamont proposes to complete the next scheduled'groundwater sampling event in May 2017.
If you have any questions or would like additional information, please do. not hesitate to contact the
undersigned at 828.281:3350.
Sincerely,
ALTAMONT ENVIRONMENTAL, INC.
Brian Gant
Attachments:
Figure 1-Site Location Map
Figure 2-Site Plan Map
Table 1—Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry
Table 2—Current and Historical Groundwater Analytical Results for Volatile Organic Compounds
Table 3—Current and Historical Groundwater Elevation Measurements
Attachment A: Laboratory Analytical Report and Chain -of -Custody Form
Attachment _B: Well Sampling Logs and, Equipment Documentation and Instrument Calibration Data Sheet
Attachment C: DEQ GW-59A=Compliance Report. Form
Attachment D: DEQ GW-59—Groundwater Quality Monitoring: Compliance Report.Forms -
P:\Clement Pappas\Reports\2016 2081.01\November\Cover Letter_November 20.16.Doc

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BASEMAP - USGS 1:24,000 ToPo MAPS, ::��� n i�nl ,�� ' 1 r/��! ,c • %:�`=` o A��'�' .,�- d �j
HENDERSONVILLE AND FRUITLAND QUADRANGLES �• I, ,f �`.l�'j{' \� ' \r, 1 `�-�� lspo•
PARCELS — HENDERSON COUNTY GIS, 2015 `r�•C'! ,. `,ii :�. 'J�Bai ✓F� 1 ;��_.� ` ;�;
\\ �^"'� 111'�,.?.-
` • • SITE LOCATION MAP FIGURE
E NGI N EERIIIIG & H Y D R a G E O L O G Y
231 HA-0Q3 S7PCE1. ASHEVILLE, NC 28801
-e1. 820.201.3350 rAC.820.201.3351 CLEMENT PAPPAS
W WW.ALTA„p„rE„„I.e„„ErarnL.ccn 125 INDUSTRIAL PARK ROAD
DRAWN BY: ALLESCALE HENDERSONVILLE, NORTH CAROLINA
PROJECT MANAGER: BRIAN RIAN GANT 0 1,000 2,000
CLIENT: CLEMENT PAPPAS
DATE: 11/10/2016 FEET PACLEMENT PAPPAS\FIGURES\GIS\FIGURE I - SITE LOCATION MAP.MXD

,: r, a' '^,:•t ' COMPLIANCE
{BOUNDARY
C:
Field #5
z 6
Field # 4 i
MW-8
2060.80�'
PZ-1y:
MW-7R - -
`: 2062.86)
=1
PROPERTY
i �: t * _ • "j B_OUNDARY
—4,
i ' a
or
i 4 t
8 J, ! . / . ?'!��`%�`ji \ Ae� � t :WIV�
a
a �9 LEGEND �� - ' a � �;�� � p,�tu � ,�► �,
,fit € ^A:jt-`-•,� \ `.t 1 1 ' f jt:f t. i` t k r f w 2i�
MONITORING WELL
! (IN USE) ,::�" : �• � w , �✓ +� � ; ,. - t '. .
� �• wA • Irv: �+1 k 1 ,;t;`C.'�� i� i'! \J '� / `�t' .t
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® MONITORING WELL
O PIEZOMETER 1yr ry'1`ia
TOP -OF -CASING I"Ye`
/•
(2060.64) ELEVATION [ ..t
SOURCE: _
1. AGRI—WASTE TECHNOLOGY, INC. (AWT) MAY 4, 2001 IRRIGATION PLAN.
2. EARTH SYSTEMS ASSOCIATES, LTD. FIGURE 3 LAND TREATMENT SYSTEMS, UNDATED.
3. HENDERSON COUNTY GIS WEBSITEACCESSED JANUARY 30, 2006.
4. AERIAL PHOTOGRAPHY DATED 2015 OBTAINED BY NC ONE MAP.
NOTES:
1. PROPERTY BOUNDARY LINES (PINK LINES) AND 2' CONTOUR LINES FROM HENDERSON COUNTY GIS.
2. IRRIGATION FIELDS FROMAWT IRRIGATION PLAN (BLUE LINES).
3. COMPLIANCE BOUNDARY DETERMINED PER 15A NCAC 02L .0107 (YELLOW LINES).
4, MONITORING WELL TOP -OF -CASING ELEVATIONS SURVEYED BY WES COLE LAND SURVEYING ON
NOVEMBER 21, 2C 12.
5. MONITORING WELL TOP —OF —CASING ELEVATION FOR MW-9 SURVEYED BY WES COLE ON MAY29, 2016. REV. DATE DESCRIPTION BY

Table 1
Current and Historical Groundwater Analytical Results
for Microbiology and Wet Chemistry
Clement Pappas
Hendersonville, North Carolina
Sample. Name
.
Sample Date
.0
�
N
U
O
F
D
0
o
U
U
z
U)
y
cn
m
CooC
a
W
`,
o
am
(mm/dd/yyyy)'
(mg/L)
(mg/L)
I (CFU per 100 mL)'
(mg/L)
.(mg/L)
(mg/L)
(mg/L)
(mg/L)
05/24/2006
7.2
9.7
< 1.1
2
19
82
< 0.10
NA
11/09/2006
3.6
7.4
< 1.1
0.95
17
76
0.11
NA
05/18/2007
4.9
6.0
< 1.0
0.56
14
62
< 0.10
NA
11/13/2007
5.9
16.7
<1.1
2.9
6.9
82.0
< 0.10
NA
05/27/2008
10.2
9.0
<1.1
0.80
21.3
140.
< 0.10
NA
11/18/2008
4.7
10.7.
<1.1
1.9
8.5
32.0
< 0.10
NA
05/28/2009
14.4
7.1
< 4.0
0.46
24.2
104 .
< 0.10
NA
11/05/2009
13.5
5.9
< 2.0 -
0.31
1 23.5
80.0
< 0.10
NA
MW-2R
05/13/2010
8.7
5.8
< 2.0
< 0.10
17.2.
57.5
< 0.10
NA
11/08/2010
18.3
10.0
< 2.0
1.1
11.7
60.0
< 0.10
NA
05/17/2011
11.'6
< 5.0.
< 2.0
< 0.10
14.3
< 62.5
< 0.10
NA
11/15/2011
18.9
10.1
< 2.0
1.2.
10.0
86.0
< 0.10
NA
05/17/2012
5.3
7.6
< 4.0
< 0.20
11.9
68.6
< 0.10
NA
11/07/2012
31.1
9.5
< 1.0
1.3
10.0 _
67.0
< 0.10
NA
05/16/2013
13.5
1.2
< 1.0
< 0.02
13.2
64.0
< 0.10
NA
11/20/2013
6.1
7.6
< 1.0
0.97
9.3
66.0
< 0.10
NA
05/22/2014
8.0
4.1
< 1.0
0.72
8.4
52.0
< 0.10
NA
05/15/2002
8.9
45
< 1.1
< 0.10
9.3
180
< 0.10
NA
11/05/2002 ;
5.5
48
< 1.1
< 0.1
14
230
< 0.10
NA
05/13/2003
3.3
32
< 1.1
0.051
20
110
0.21
NA
11/04/2003
41
31
< 1.1
< 5.0
66
210
< 0.10
NA
05/05/2004
6
29
< 1.1
< 5.0
45
240
0.11
NA
11/09/2004
8.4
13
3.6
< 0.10
52
200
< 0.10
NA
05/17/2005
8.5
.10
< 1.1
< 0.10
37
220
< 0.10
NA
11/03/2005
16
14
< 1.1
< 0.10
29
220
1 0.14
NA
05/24/2006
19
11
< 1.1
< 0.10
28
180
< 0.10
NA
11/09/2006
8.8
6.9
< 1.1
<0.10
26
180
< 0.10
NA
05/18/2007
8.5
8:9
< 1.0
< 0.10
29
300
< 0.10
1 NA
11/13/2007
16.7
11.3
< 1.1
< 0.10
25.0
152
< 0.10
NA
05/27/2008
< 1.0
10.0
< 1.1
< 0.10
38.6
176
< 0.10
NA
11/18/2008
20.5
9.3
< 1.1
<-0.10
19.6
108
< 0.10
NA
05/28/2009
8.6
13.6
< 4.0
<' 0.10
35.5
156
< 0.10
NA
MW 4
11/05/2009
31.0
13.6
< 2.0
< 0.10
30.7
120
< 0.10
NA
05/13/2010
7.8
18.0
< 2.0
0.17
31.0
141
< 0.10
NA.
11/08/2010
23.9
17.5
< 2.0
< 0.10
34.4
144
< 0.10
NA
05/17/2011
7.7
13.5
< 2.0
0.82
25.6
' 137
< 0.10
NA
11/15/2011
7.3
14.4
< 2.0
< 0.20
27.8
157
1 < 0.10
NA
05/17/2012
6.7
12.1
2.0
< 0.20
22.3
117
I < 0.10
NA
11/07/2012
10.6
14.5
2.0
< 0.020
26.2
150
< 0.10
NA
05/16/2013
31.8.
1 10.2
2.0
0.28
19.1
108
< 0.10
NA
11/20/2013
8.0
14.7
< 1.0
0.026
22.1'
157
< 0.10
NA
05/22/2014
8.7
10.8
< 2.0
0.14
22.5
146
< 0.10
NA
11/18/2014
28.7
12.1
< 2.0
< 0.020
21.9
161
< 0.10
NA
05/13/2015
5.4
9.2
< 1.0
<0.020
21.5
130
< 0.10
NA
11/04/2015
6.6
6.2
<2.0
< 0.020
NA
139
< 0.10
0.10
05/04/2016
5.5
8.4
< 4.0
< 0.020
NA
119
< 0.10
0.095
11/09/2016
4.3
12.2
< 4.0
1 < 0.02011
NA
124
< 0.10
0.27
Standards
- 10
250
1
1 10
1 250
500
1.5
NL
P:\Clement Pappas\Reports\2016 2081.01\November\November 2016_Historic Analytical Results Page 1 of 5

Table 1
Current and Historical Groundwater Analytical Results
for Microbiology and Wet Chemistry
Clement Pappas
Hendersonville, North Carolina
Sample Name
_
Sample Date "
a
fI
.0
b�0
Q
F
O
,°�'
z
tNq
V
U)
N
E
Q
N
�
O
F
(mm/dd/yyyy)' _
(mg/L)
(mg/L)
(CFU per 100.ml-)
(mg/L)
(mg/L)
(mg/L)
'(mg/L)
(mg/L)
05/15/2002
2.9
15
< 1.1
0.42
1.7
< 40
< 0.10
NA
11/05/2002
1.4
16 -
< 1.1
0.54
< 1.0
83
1.3
NA
05/13/2003
4.6
17
< 1.1
0.65
2
56
0.25
NA
11/04/2003
19
22
< 1.1
0.23
< 5.0
58
< 0.10
NA
05/05/2004
0.7
28
< 1.1
0.57
< 5.0
80
0.15
NA
11/09/2004
1.2
34
< 1.1
0.24
< 5.0
130
< 0.10
NA
05/17/2005
2.1
35
< 1.1
< 0.10
< 5.0
110
< 0.10
NA
11/03/2005
8.1
34
< 1.1
0.11
< 5.0
82
< O.AO
NA
05/24/2006
7.8
34
< 1.1
< 0.10
< 5.0
120
< 2.5
NA
11/09/2006
1.3
37
< 1.1
0.20
< 5.0
90
.< 0.1
NA
05/18/2007
1.7
42
< 1.0
0.16
< 5.0
130
< 0.10
NA
11/13/2007
4.2
41.3
< 1.1
0.25
< 5.0
112
< 0.10
NA
05/27/2008
6.7
14.3
< 1.1
0.21
< 5.0
168
0.17
NA
11/18/2008
25.9
47.6
< 1.1
0.17
< 5.0
80.0
< 0.10
NA
MW-5
05/28/2009
16.1
29.0
4.0
0.11
< 5.0
188
< 0.10
NA
11/05/2009
4.7
39.1
1 2.0
0.15
< 5.0
112
< 0.10
NA
05/13/2010
3.2
43.0
23
0.17
< 5.0
147
< 0.10
NA
11/08/2010
13.8
43.7
200
< 0.10
< 5.0
113
< 0.10
NA
05/17/2011
4.0
32.3
< 4.0
< 0.10
< 5.0
< 167
< 0.10
NA
11/15/2011
3.0
52.6
120
< 0.20
< 5.0
165
< 0.10
NA
05/17/2012
4.7
36.6
< 2.0
< 0.20
< 5.0
110
< 0.10
NA
11/07/2012
4.1
61.1
< 10:0
0.12
< 2.0
139
< 0.10
NA
05/16/2013
4.0
44.2
1.0
0.093
2.3
152
< 0.10
NA
11/20/2013
4.2
64.6 1
1.0
0.19
< 2.0
162
< 0.10
NA
05/22/2014
5.8
6.6
< 10.0
0.099
< 2.0
110
< 0.10
NA
11/18/2014
16.0
57.7
6.0
0.28
< 2.0
160
< 0.10
NA
05/13/2015
21.0
68.4
< 2.0
0.11
< 2.0
176
< 0.10
NA
11/04/2015
7.3
20.3
7.0
< 0.020
NA
68.0
< 0.10
0.21
05/04/2016
8.6
41:5
< 10.0
0.042
NA
90.0
< 0.10
0.12
11/09/2016
<1.0
45.0
< 4.0
0.42
NA
109
< 0.10
0.47
Standards
10 1
250 1
1
10
250
500
1.5
NL
P:\Clement Pappas\Reports\2016 2081.01\November\November 2016_Historic Analytical Results Page 2 of 5

Table 1
Current and Historical Groundwater Analytical Results
for Microbiology and -Wet Chemistry
Clement Pappas
Hendersonville, North Carolina
Sample Name
Sample Date
0
a
F
1=
uQ7
z
r':.
y
CO
El -
, a
2.::;
L "
O
�. .
(mm/dd/yyyy)
(mg/L)'
(mg/L)
I (GFU per 100 mL)
I „(mg/L)
.(me,L)
(mg/L)
05/15/2002
6.8
9.9 -
5.1
< 0.10
11
540
< 0.10
NA
11/05/2002
3.9
4.6 :
< 1.1
• 0.49
9.8
51
2.5
NA
05/13/2003
4.4
7.3
> 23.0
0.075
14
52'
0.14
NA
11/04/2003 '
26
6.8
9.2
< 0.050
12
< 20
< 0.10
NA
05/05/2004
1.8
6.7
1.1
< 0.10
11"
58
0.13
NA
11/09/2004
3.5
11 -
9.2
< 0.10
9.3
88
< 0.10
NA
05/17/2005
2.4
7.4
< 1.1
< 0.10
8.7
50
< 0.10
NA
11/03/2005
6.3
9.6
< 1.1'
<0.10
9.6
66
0.17
NA
05/24/2006
7.4
..10
< 1.1
< 0.10 .
9
54
< 0:10
NA
11/09/2006
1.4.
1 11
< 1.1
0.20
- 11
54
.0.18
NA
05/18/2007
3.9
9.4-.
< 1.0
< 0.10
9.1
58
0.12
NA
11/13/2007
5.7
10.7
3.6
0.24
5.8
114
0.24
NA
05/27/2008 .
10.9
5:4
< 1.1
< 0.10
15.3
- 92.0
< 0.10
NA
11/18/2008
704:
7.6
> 23
2 0.10
< 5.0
36.0.
< 0.10
NA"
MW
05/28/2009 -
6.4
6.2
276
0.39
8.8
104
< 0.10
NA
6
11/05/2009
6.4
< 5.0
30
0.10 1
9.3
52.0
< 0.10
NA
05/13/2010
4.3
5:8
< 2.0
< 0.10
8.1
- 44.0
< 0.10
NA
11/08/2010
16.5
5.0
7.0
1.5
9.3
48.0
< 0.10
NA
05/17/2011
6.2.
9.4
< 2.0
< 0.10
6.8
60.0
< 0.10
NA
11/15/2011
4:6 "
5.2
5.0
-< 0.20
7.5 .
82.0 "
< 0.10
NA
05/17/2012
21.6
8.1
28.0
< 0.20
8.8
52.0
< 0.10
NA
11/07/2012
6.4
6:8
3.1
< 0.020
7.5
-46.0
1 < 0.10
NA
05/16/2013
7.5
5A
12.1
0.048 -
9.4
62.0
< 0.10
NA
11/20/2013
4.4
7.3
< 1.0
< 0.020
8.6
56.0
< 0.10
NA
05/22/2014
4.6 ,
4.5
1.0
< 0.020
10.1
32.0
< 0.10
NA
11/18/2014
16.3
6.9
13.0
0.078
9.8
49.0
< 0.10
NA
05/13/2015
2.1
6.2
< 1.0
< 0.020
10.1
46.0
< 0.10-
NA
11/04/2015
2.2
9:5
136' `
2.9'
NA
58.0.
< 0.10
0.12
05/04/2016
2.1
9.4
< 2.0
0.41
NA
58.0
< 0.10
0.079
11/09/2016 _
7.1
9.0
z 10.0
< 0.0201
NA
64.0
011
0.70
Standards
10
250,
. 1
10
250
500
t5
NL
P:\Cleinent Pappas\Reports\2016 2081.01\N6ember\November 2016_His�oric Analytical Results

Table 1
Current and Historical Groundwater.Analytical Results
for Microbiology and Wet Chemistry
Clement Pappas
Hendersonville, North Carolina
Sample Name
Sample Date'
.. . O
F
N
LL
z
CO'�..
U)
�
N
Q
O
(mm/dd/yyyy) ",
(mg/L)
(mg/L)
.(CFU per 100 mL)'
(mg/L)
(MVL)
(mg/L)
;(mg/L)
(mg/L)
05/15/2002
20
6.5
< 1.1
5.2
26
< 40
< 0.10
NA
11/05/2002
16
3.3
< 1.1 '
1.3
1.1
68
1.4
NA
05/13/2003
9.7
3.6
2.2
1.8
9.3
44
0.72
NA
11/04/2003
19
6.1
< 1.1
0.72
< 5.0:
< 2.0
< 0.10
NA
05/05/2004 :
3.0
7.0
< 1.1
1.3
< 5.0
52
< 0.10
NA
11/09/2004
2.2
5.1
5.1
1.9
< 5.0
62
< 0.10
NA
05/17/2005
3.2
6.1
< 1.1
1.2
< 5.0
40
< 0.10
NA
11/03/2005
7.7
6.1
< 1.1
0.99
< 5.0
58
0.10
NA
05/24/2006
8.4
•5.5
< 1.1
1.5
< 5.0
48 :
< 0.10
NA
11/09/2006
1.9
7.0
< 1.1
1.1
6:7
38
< 0.10
NA
MW-7
05/18/2007
3.6
8.6
< 1.0
2.2
5.9
.70
< 0.10
NA
11/13/2007
4.2
6.8
< 1.1
1.7
< 5.0
42.0
< 0.10
NA
05/27/2008
7.6
11.5
< 1.1
2.2
6.9
88.0
< 0.10
NA
11/18/2008 ' , . '
7.5
7.7
< 1.1
1.7
< 5.0.
30.0
< 0.10
NA
05/28/2009 :.
23.4
9.8
< 4.0
2.3
< 5.0
336
< 0.10
NA.
11/05/2009
.5.3
10.7
2.0.
2.3
11.2
70.0
< 0.10
NA
05/13/2010
4.6
11.0
< 2.0
2.5
< 5.0
71.0
< 0.10
NA
11/08/2010
15.4
8:9
< 2.0
2.3
< 5.0
60.0
< 0.10
- NA.
05/17/2011
6.0
11.6
< 2.0
5.3
7.6
103
< 0.10
NA
11/15/2011
2.2
9.9
< 2.0
3.5
< 5.0
89.0
< 0.10
NA
05/17/2012
4.4
10.9
< 2.0
3.8
< 5.0
67.0
< 0.10
NA
11/07/2012
11.6
13.1
< 100
4.0
14.9
108.0
< 0.10
NA
05/16/2013
12.8
17.1
< 1.0
10.5
28.3
252
< 0.10
NA
11/20/2013
9.4
14.0
< 1.0
5.5
3.5
< 250
< 0.10
NA
05/22/2014 -
8.9
13.1
< 10,000
5.7
4.0
93.0
< 0.10
NA
11/18/2014
19.1
16.0
< 20.0
7.1
4.4
93.0
< 0.10
NA
MW-7R
05/13/2015
8.5
17.0
< 2.0
9.3 .
3.7
125
< 0.10'
NA
11/04/2015
9.9
18.0
< 2.0
8.3
NA
129
< 0.10.
0.35
05/04/2016
13.5
27.7.
< 10.0
11.2
NA
130
< 0.10
0.78
06/09/2016 - Pace
NA
NA
NA
10.9
NA
NA
NA
NA
06/09/2016 - Prism
NA
NA
NA _
10.0
NA
NA
NA
NA
11/09/2016
13.0
22.7
< 20.0
12.5
NA
147
< 0.10
1.0
Standards
10
250
1
10
250
500 1
1.5 .
NL
P:\Clement P6ppas\Reports\2016 2081.01\November\November 2016_Historic Analytical Results
Page 4 of 5

Table 1
Current and Historical Groundwater Analytical Results
for Microbiology and Wet Chemistry
Clement Pappas
Hendersonville, North Carolina
Sample, Name
Sample Date
U
O
ro
LL
m
z
w
co
v
o
E
aE
o
(mm/dd/yyyy)
(mg/L)
(mg/L)
(CFU per 100 ml-) '
(mg/L)
(mg/L)
(mg/L)
'(mg/L)
I (mg/L)
05/15/2002
6.8
8.7
< 1.1
< 0.10
9.1
64
< 0.10
NA
11/05/2002
4.8
9.8
< 1.1
0.16
7
100
0.57
NA
05/13/2003
5.5
3.3
2.2
1.4
9.4
64
0.41
NA
11/04/2003
27
8.1
6.9
< 0.050
13
54
< 0.10
NA
05/05/2004
3.0
7.4
< 1.1
0.24
9.8
140
< 0.10
NA
11/09/2004
3.7
6.7.
> 23
0.79
6.8
120
< 0.10
NA
05/17/2005
3.8
8.3
< 1.1
0.61
1 6.4
88
< 0.10
NA
11/03/2005
7.1
11
< 1.1
0.95
1 8.4
100
< 0.10
NA
05/24/2006
15
10
< 1.1
0.39
8.1
130
< 0.10
NA
11/09/2006
4.7
12
< 1.1
0.97
7.7
96
.< 0.10
NA
05/18/2007
5.0
15
< 1.0
3.0
13
290
< 0.10
NA
11/13/2007
8.3
19.6
< 1.1
0.97
26.6
154
< 0.10
NA
05/27/2008
12.4
20.0
< 1.1
0.55
35.8
184
< 0.10
NA
11/18/2008
14.4
17.2
2.2
< 0.10
21.5
118.
<0.10
NA
05/28/2009
6.2
24.9
240
0.74
24.9
192
< 0.10
NA
MW-8
11/05/2009
10:8
15.4
50
0.54
18.4
114
< 0.10
NA
05/13/2010
10.8
14.7
< 2.0
1.1
24.1
106
< 0.10
NA
11/08/2010
23.2
24.3
200
< 0.10
26.3
173
< 0.10
NA
05/17/2011
10
16.9
10.0
12.2
16.1
232
<0.10
NA
11/15/2011
8.0
26.6
< 2.0
3.7
.20.2
232
< 0.10
NA
05/17/2012
14.4
1 24.8
12.0
8.0
22.9
356
< 0.10
NA
11/07/2012
24.8
26.3
< 100
1.9
28.3
324
< 0.10
NA
05/16/2013
15.8
..8.8
10.9
6.8
13.4
248
< 0.10
NA
11/20/2013
21.0
15.4
< 1.0
1.3
24.3
342
< 0.10
NA
05/22/2014
1.7.6
14.5
< 10.0
0.61
17.8
352
< 0.10
NA
11/18/2014
54.0
16.4
< 4.0
1.1
13.2
421
< 0.10
NA
05/13/2015
19-.7
18.3
< 2.0
9.7
12.2
454
< 0.10
NA
11/04/2015
15.0
21.6
4.0
3.0
NA
396
< 0.10
0.82
05/04/2016
' 15.0
24.5
< 10.0
19.1
NA
398
< 0.10
0.62
6/9/2016 - Pace
NA
NA
NA
26.3
NA
NA
NA
NA
06/09/2016 - Prism
NA
NA
NA
26.0.
NA
NA
NA
NA
11/09/2016
9.7
12.0
< 4.0
14.3
NA
333
< 0.10
0.26
05/13/2015
2.2
12.4
< 2.0
1.0
5.5
94.0
< 0.10
NA
MW
11/04/2015
3.8
2.6
< 1.0
< 0.020
NA
58.0
< 0.10
0.45
9
05/04/2016
15.0
5.3
< 10.0
0.64
NA
51.0
< 0.10
0.095
11/09/2016
9.3
10.7
< 20.0
0.77
NA
69.0
< 0.10
0.76
Standards
10
250
1
10
250
1 500
1.5
NL
Notes:
mg/L Milligrams per liter
CFU Coliform forming units
mL Milliliters
15.0 Indicates concentration equal to or above the respective standard.
< 4.0 Indicates constituent concentration was not detected above the laboratory reporting limit
Standards From North Carolina Administrative Code, Title 15A, Subchapter 2L April 1, 2013, except total organic carbon and fecal coliform.
Total organic carbon standard from Spray Irrigation Permit Number W00004797. Fecal coliform standard is 2L standard for total
coliform.
Sulfate Removed from list of necessary analyses as of fall, 2015 and replaced by total phosphorous.
NA Not analyzed
NL Indicates no standard limit is set.
06-09-2016 - Pace A re -sampling event was performed on June 9, 2016 to investigate nitrate exceedances.in MW-7R and MW-8.One set of samples
was analyzed by Pace Analytical Services, and a second set of samples was analyzed by Prism Laboratories.
P:\Clement Pappas\Reports\2016 2081.01\November\November 2016_Historic Analytical Results Page 5 of 5

Table 2
Current and Historical Groundwater Analytical Results
for Volatile Organic Compounds
Clement Pappas
Hendersonville, North Carolina
l
Sample Name'
Sample Date
(mm/dd/riYy)
.�
C
N
o
F
(pg/L)
N
t
(D
U
F
(pg/L)
d
C
)
O
t
N
(pg/L)
y
O
0,
N
cI
W/L)
N'..
.:2 ..
p
t
U
(pg/L)
C
t
N
U
O
L
U
(pg/L) .
MW-213
11/09/2006
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/18/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/13/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2008
< 0.50 _
< 0.50
< 0.50
< 0.50 ,
< 0.5
< 0.50
11/05/2009
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/08/2010
< 0.50
< 0.50
< 0.50.
< 0.50
< 1.0
< 0.50
11/15/2011
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/07/2012
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/20/2013
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
MW-4-
11/05/2002
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/04/2003
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2004
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/03/2005
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2006
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/18/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/13/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2008
< 0.50
< 0.50
< 0.50
< 0.50
< 0.5
< 0.50
11/05/2009
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/08/2010
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/15/2011
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/07/2012
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/20/2013
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2014
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/04/2015
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/09/2016
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
MW-5
11/05/2002
4,700
980
820 -
13
24
1.9
11/04/2003
3,500
570
510
< 50
< 50
< 50
11/09/2004
580
62
38
< 10
< 10
< 10
11/03/2005
1,900
210
220
< 50
< 50
< 50
11/09/2006
350
74 _
67
0.61
1.2
< 0.50
05/18/2007
320
47
60
< 0.50
< 0.50
< 0.50
11/13/2007
1,150
217
209
2.0
3.4
1.0
11/18/2008
2,680
534
293
< 25.0
< 25.0
< 25.0
11/05/2009
872
106
125
0.92
< 1.0
< 0.50
11/08/2010
578
107
160
< 2.5
< 5.0
< 2.5
11/15/2011
1,450
124
141
< 2.5
< 5.0
< 2.5
11/07/2012
774
68.8
77.8
< 5.0
< 10.0
< 5.0
11/20/2013
332
65.1
80.5
< 1.2
< 2.5
< 1.2
11/18/2014
121
22.2
26.4
< 0.50
< 1.0
< 0.50
11/04/2015
26.1
2.6
2.9
< 0.50
< 1.0
< 0.50
11/09/2016
141
63.1
75.2
< 0.50
< 1.0
< 0.50
A Standard
0.7
3
70
100
0.03
7 HI
P:\Clement Pappas\Analytical Data\Water\November 2016_Historic Analytical Results Page 1 of 3

Table 2
Current and Historical Groundwater Analytical Results
for Volatile Organic Compounds
Clement Pappas
Hendersonville, North Carolina
1
C
a.
2.:
CD
W
-✓
'
O
O
.y
V
N
O
,0 .
Sample Date
"
F
>
.
Sample Name
(mm/dd/yyyy)
(pg/1) '
.(Pg/I)
(119/1)
(P9/I)
(P9/I)
(ug/1)
MW-6
11/05/2002
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/04/2003
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2004
< 0.50
< 0.50 -
< 0.50
< 0.50
< 0.50
< 0.50
11/03/2005
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2006
< 0.50.
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/18/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/13/2007 "
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2008
3.0
< 0.50
< 0.50
< 0.50
< 0.5
< 0.50.
11/05/2009
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/08/2010
< 0.50.
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/15/2011
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/07/2012
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/20/2013
< 0.50
< 0.50
< 0.50
< 0:50
< 1.0
< 0.50.
11/18/2014
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/04/2015
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/09/2016
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
MW-7
11/05/2002
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/04/2003
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2004
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/03/2005
< 0.50
< 0.50
< 0.50 -
< 0.50
< 0.50
< 0.50
11/09/2006
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/18/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/13/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2008 _
0.79
< 0.50
< 0.50
< 0.50
< 0.5
< 0.50
11/05/2009
< 0.50.
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/08/2010
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/15/2011
< 0.50
< 0.50
< 0:50
< 0.50
< 1.0
< 0.50
MW-7R
11/07/2012
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/20/2013
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2014 .
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/04/2015
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/09/2016
< 0.50
< 0.50
< 0'50
< 0.50
< 1.0
< 0.50
2L'Standard '
0.7
3
70
-100
0.03
7.
P:\Clement Pappas\Analytical Data\Water\November 2016 Historic Analytical Results Page 2 of 3

Table 2
Current and Historical Groundwater Analytical Results
for Volatile Organic Compounds
Clement Pappas
Hendersonville, North Carolina
a)
..
_ d)
C
L
(13
%2
o.
a)r
O
2
2
L
TU_
T
O
�
'
.
L
o'
O
N
�.'I
L
U ..
U
�.�
.. ..
.. .
O ..
c-I
C
7.
Sample Date
F
U
F
j .
Sample Name
(mm/dd/yyyy)
(P9/1)
W/O
(pg/,)
(pg/p
(pg/I) '
W/O
MW-8
11/05/2002
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/04/2003
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2004
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/03/2005
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2006
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50'
05/18/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/13/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2008
< 0.50
< 0.50
< 0.50
< 0.50
< 0.5
< 0.50
11/05/2009
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/08/2010
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/15/2011
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/07/2012
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/20/2013
< 0.50
< 0.50
<.0.50
< 0.50
< 1.0
< 0.50
11/18/2014
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/04/2015
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/09/2016
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
MW-9
11/04/2015
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0 .
< 0.50
11/09/2016
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
A Standard
0.7
3
70
106
0.03
7
Notes:
Detections
This table only includes compounds thatwere detected above the laboratory method detection limit since the
sampling event in November 2002. The complete suite of compounds analyzed can be found in the individual
analytical reports. Only samples collected during November sampling events were analyzed for volatile organic
compounds, in accordance with Spray Irrigation Permit Number WQ0004797.
pg/L
Micrograms per liter
2L Standard
From North Carolina Administrative Code, Title 15A, Subchapter 2L, April 1, 2013.
4,700
Indicates an exceedance of the 2L standard.
5/18/2007
In accordance with the Compliance Evaluation Inspection letter issued by Beverly Price of the DENR, Division
of Water Quality (DWQ) on April 27, 2007, volatile organic compounds and semivolatile organic compounds
were sampled duringthe May 2007 sampling event.
Naphthalene
Detected in MW-6 for the first time at a concentration of 2.2 pg/L (which is below the 2L standard of 6 pg/L)
duringthe November 5, 2002 sampling event.
1,1,2-trichloroethane
Detected in MW-5 for the first time on November 20, 2010 at a concentration of 8.0 pg/L, which exceeds the
North Carolina Interim Maximum Allowable Concentration of 0.6 pg/L.
Chloroform
Detected for the first time in MW-5 during the November 2011 sampling event at a concentration of 31.3
pg/L, which is below the 2L standard of 70 pg/L.
Toluene
Detected for the first time in MW-4 during the November 2015 sampling event at a concentration of 0.75
pg/L, which is below the 2L standard of 600 pg/L.
P:\Clement Pappas\Analytical Data\Water\November 2016_Historic Analytical Results Page 3 of 3

Table 3
Current and Historical Groundwater Elevation Measurements
Clement Pappas
Hendersonville, -North Carolina
Well Identification
Date Measured
Depth'to
Groundwater
Top -of -Casing
.. Elevation
Top -of -Casing ..
-.HeightAbove
Ground Surface
Groundwater
Elevation
(mm/dd/yyyy)
(ft-BTOC) - _
(feet)
(feet)
{feet)
MW-213
05/24/2006
9.29
2063.00
3.7.7
2053.71
11/09/2006
6.49
2063.00
3.77
2056.51
05/18/2007
7.94
2063.00
3.77
2055.06
11/13/2007
8.46
2063.00
3.77
2054.54
05/27/2008
8.48
2063.00
3.77
2054.52
11/18/2008
8.50
2063.00
3.77
2054.50
05/28/2009
5.43
2063.00
3.77
2057.57
11/05/2009
6.72
2063.00
3.77
2056.28
05/13/2010
7.36
2063.00
3.77
2055.64
11/08/2010
9.60
2063.00
3.77
2053.40
05/17/2011
7.25
2063.00
3.77
2055.75
11/15/2011
7.86
2063.00
3.77
12055.14
05/17/2012
5.19
2063.00
3.77
2057.81
11/07/2012
7.74
2062.36
3.77
2054.62
05/16/2013
6.86
2062.36
3.77
2055.50
11/20/2013
7.92
2062.36-
3.77
2054.44
05/22/2014
7.56
2062.36
3.77
2054.80
11/18/2014
8.89
2062.36
3.77
2053.47
Well abandoned, replaced by MW-9
MW-4
05/15/2002
9.32
2064.60
2.43
2055.28
11/05/2002
9.49
2064.60.
2.43
2055.11
05/13/2003
8.20
2064.60
2.43
2056.40
11/04/2003
9.23
2064.60
2.43
2055.37
05/05/2004
9.35
2064.60
2.43
2055.25
11/09/2004
8.61
2064.60
2.43
2055.99
05/17/2005
6.19
.2064.60
2.43
2058.41
11/03/2005
9.57
2064.60
2.43
2055.03
05/24/2006
9.60
2064.60
2.43
2055.00
11/09/2006
8.41
2064.60
2.43
2056.19
05/18/2007
9.42
2064.60
2.43
2055.18
11/13/2007
9.89
2064.60
2.43
2054:71
05/27/2008
9.78
2064.60
2.43
2054.82
11/18/2008
9.76
2064.60
2.43
2054.84
05/28/2009
7.16
2064.60
2.43
2057.44
11/05/2009
8.53
2064.60
2.43
2056.07
05/13/2010
8.83 .
2064.60
2.43
2055.77
11/08/2010
9.30
2064.60
2.43
2055.30
05/17/2011
8.97
2064.60
2.43
2055.63
11/15/2011
9.48
2064.60
2.43
2055.12
05/17/2012
7:62
2064.60
2.43
2056.98
11/07/2012
9.32
2063.77
2.43
2054.45
05/16/2013
7.93
2063.77
2.43
2055.84
11/20/2013
8.87
2063.77
2.43
2054.90
05/22/2014
8.70
2063.77
2.43
2055.07
11/18/2014
8.54
2063.77
2.43
2055.23
05/13/2015
9.18
2063.77
2.43
2054.59
11/4/2015
6.93
2063.77
2.43
2056.84
05/04/2016 -
8.43
2063.77
2.43
2055.34
11/09/2016 1
9.63
2063.77
2.43
2054.14
P:\Clement Pappas\Reports\2016 2081.01\November\Table 2 Historic GW Elev Pagel of 5

Table 3
Current and Historical Groundwater Elevation Measurements
Clement Pappas
Hendersonville, North Carolina
Well Identification
Date Measured
Depth to
Groundwater.
Top -of -Casing
Elevation
Top=of-Casing
,
Height Above
Ground Surface
Groundwater
Elevation
-
(mm/dd/yyyy) .
(ft-BTOC)
(feet)
(feet)
- (feet)
MW-5
05/15/2002
8.31
2086.40
3.00
2078.09
11/05/2002
10.20
2086.40
3.00
2076.20
05/13/2003
8.29
2086.40
3.00
2078.11
11/04/2003
9.92
2086.40
.3.00
2076.48
05/05/2004
8.75
2086.40
3.00
2077.65
11/09/2004
8.50
2086.40
3.00
2077.90
05/17/2005
8.87
2086.40
3.00
2077.53
11/03/2005
9.70
2086.40
3.00
2076.70
05/24/2006
9.34
2086.40
3.00
2077.06
11/09/2006
8.39
2086.40
3.-00
2078.01
05/18/2007
9.16
2086.40
3.00
2077.24
11/13/2007
11.00
2086.40
3.00
2075.40
05/27/2008
9.84
2086.40
3.00
2076.56
11/18/2008
11.59
2086.40
3.00
2074.81
05/28/2009,
7.95
2086.40
3.00
2078.45
11/05/2009
8.63
2086.40
3.00
2077.77
05/13/2010
8.87
2086.40
3.00
2077.53
11/08/2010
10.24,
2086.40
3.00
2076.16
05/17/2011
8.99
2086.40
3.00
2077.41
11/15/2011
10.58
2086.40
3.00
2075.82
05/17/2012
8.73
2086.40
3.00
2077.67
11/07/2012
9.65
2085.60
3.00
2075.95
05/16/2013
8.14
2085.60
3.00
2077.46
11/20/2013
9.33
2085.60
3.00
2076.27
05/22/2014
8.57
2085.60
3.00
2077.03
11/18/2014
9.04
2085.60
3.00
2076.56
05/13/2015
8.92
2085.60
3.00
2076.68
11/4/2015
8.12
2085.60
3.00
2077.48
05/04/2016
8.54
2085.60
3.00
2077.06
11/09/2016
11.25
2085.60
3.00
2074.35
P:\Clement Pappas\Reports\2016 2081.01\November\Table 2 Historic GW Elev
Page 2 of 5
r

Table 3
Current and Historical Groundwater Elevation Measurements
Clement Pappas
Hendersonville, North Carolina
Well Identification
Date Measured
Depth to
Groundwater
Top=of-Casing
Elevation
Top -of -Casing
Height Above.
Ground Surface
Groundwater
Elevation
(mm/dd/yy)y)
(ft-BTOC)
(feet)
(feet)
(feet)
MW-6
05/15/2002
6.20
2061.90
3.00
2055.70
11/05/2002
6.15
2061.90
3.00
2055.75
05/13/2003.
5.43
2061.90
3.00
2056.47
11/04/2003
5.85
2061.90
3.00
2056.05
05/05/2004
6.00
2061.90
3.00
2055.90
11/09/2004
5.32
2061.90
3.00
2056.58
05/17/2005
6.10
2061.90
3.00
2055.80
11/03/2005
6.01
2061.90
3.00
2055.89
05/24/2006
6.48
2061.90
3.00
2055.42
11/09/2006
5.71
2061.90
3.00
2056.19
05/18/2007
6.50
2061.90
3.00
2055.40
11/13/2007
7.85
2061.90
3.00
2054.05
05/27/2008
7.01
2061.90
3.00
2054.89
11/18/2008
7.38
2061.90
3.00
2054.52
05/28/2009
5.63
2061.90
3:00
2056.27
11/05/2009
5.74
2061.90
3.00
2056.16
05/13/2010
5.90
2061.90
3.00
2056.00
11/08/2010
5.99
2061.90
3.00
2055.91
05/17/2011
5.85
2061.90
3.00
2056.05
11/15/2011
6.14
2061.90
3.00
2055.76
05/17/2012
5.87.
2061.90
3.00
2056.03
11/07/2012
6.05
2061.17
3.00
2055.12
05/16/2013
5.84
2061.17
3.00
2055.33
11/20/2013
5.96
2061.17
3.00
2055.21
05/22/2014
5.96
2061.17
3.00
2055.21
11/18/2014
5.82
2061.17
3.00
2055.35
05/13/2015
6.05
2061.17
3.00
2055.12
11/4/2015
5.18
2061.17
3.00
2055.99
05/04/2016
5.59
2061.17
3.00
2055.58
11/09/2016
7.42
2061.17
3.00
2053.75
P:\Clement Pappas\Reports\2016 2081.01\November\Table 2 Historic GW Elev Page 3 of 5

Table 3
Current and Historical Groundwater Elevation Measurements
Clement Pappas
Hendersonville, North Carolina
Well Identification
Date Measured
Depth to
Groundwater
Top -of Casing
Elevation
Top of Casing
Height Above
Ground Surface
Groundwater
Elevation
(mm/dd/yyyy)
(ft-BTOC)
(feet)
(feet)
(feet)
MW-7
05/15/2002
10.90
2062.70
3.00
2051.80
11/05/2002
11.35
2062.70
3.00
2051.35
05/13/2003
8.87
2062.70
3.00
2053.83
11/04/2003
10.78
2062.70
3.00
2051.92
05/05/2004
10.80
2062.70
3.00
2051.90
11/09/2004
9.70
2062.70
3.00
2053.00
05/17/2005
10.60
2062.70
3.00
2052.10
11/03/2005
11.09
2062.70
3.00
2051.61
05/24/2006
11.27
2062.70
3.00
2051.43
11/09/2006
9.71
2062.70
3.00
2052.99
05/18/2007
11.02
2062.70
3.00
2051.68
11/13/2007
11.76
2062.70
3.00
2050.94
05/27/2008
11.55
2062.70
3.00
2051.15
11/18/2008
11.63
2062.70
3.00
2051.07
05/28/2009
8.21
2062.70
3.00
2054.49
11/05/2009
9.89
2062.70
3.00
2052.81
05/13/2010
10.44
2062.70
3.00
2052.26
11/08/2010
11.12
2062.70
3.00
2051.58
05/17/2011
10.80
2062.70
3.00
2051.90
11/15/2011
11.43
2062.70
3.00
2051.27
05/17/2012
8.91
2062.70
3.00
2053.79
MW-7R
11/07/2012
12.02
2062.86
3.00
2050.84
05/16/2013
10.29
2062.86
3.00
2052.57
11/20/2013
11.69
2062.86
3.00
2051.17
05/22/2014
11.38
2062.86
3.00
2051.48
11/18/2014
11.25
2062.86
3.00
2051.61
05/13/2015
11.94
2062.86
3.00
2050.92
11/4/2015
8.43
2062.86
3.00
2054.43
05/04/2016
11.08
2062.86
3.00
2051.78
11/09/2016
12.63
2062.86
3.00
2050.23
P:\Clement Pappas\Reports\2016 2081.01\November\Table 2 Historic GW Elev Page 4 of 5

Table 3
Current and Historical Groundwater Elevation Measurements
Clement Pappas
Hendersonville, North Carolina
Well Identification
=Date Measured
Depth to
Groundwater
Top=of-Casing
.
-. Elevation ..
" Top=of-Casing
Height Above
Ground Surface
Groundwater
"
Elevation
(mm/dd/yyyy)
(ft-BTOC), -
(feet)
(feet)
'(feet)
MW-8
05/15/2002
10.25
2061.40
3.00
2051.15
11/05/2002
10.35
2061.40
3.00
2051.05
05/13/2003
8.16
2061.40
3:00
2053.24
11/04/2003
10.23
2061.40
3.00
2051.17
05/05/2004
10.30
2061.40
&00
2051.10
11/09/2004
8.90
2061.40
3.00
2052.50
05/17/2005
10.08
2061.40
3.00
2051.32
11/03/2005
10.61
2061.40
3.00
2050.79
05/24/2006
10.60
2061.40
3.00
2050.80
11/09/2006
9.40
2061.40
3.00
2052.00
05/18/2007
10.31
2061.40
3.00
2051:09
11/13/2007
11.09
2061.40
3.00
2050.31
05/27/2008
10.83
2061.40
3.00
2050.57
11/18/2008
11.11
2061.40
3.00
2050.29
05/28/2009.
8.25
2061.40
3.00
2053.15
11/05/2009
9.22
2061.40
.3.00
2052.18
05/13/2010
9.88
2061.40
3.00
2051.52
11/08/2010
10.38
2061.40
3.00
2051.02
05/17/2011
10.27
2061.40
3.00
2051.13
11/15/2011
10.87
2061.40
3.00
2050.53
05/17/2012
8.03
2061.40
3.00
2053.37
11/07/2012
10.45
2060.80
3.00
2050.35
05/16/2013
8.58
2060.80
3.00
2052.22
11/20/2013
10.34
2060.80
3.00
2050.46
05/22/2014
9.79
2060.80
3.00
2051.01
11/18/2014
10.03
2060.80
3.00
2050.77
.05/18/2015-
10.34
2060.80
3.00
2050.46
11/4/2015
7.21
2060.80
3.00
2053.59
05/04/2016
9.84
2060.80
3.00
2050.96
11/09/2016
11.16
2060.80
3.00
2049.64
MW-9
05/13/2015
6.03.
2060.23
1.44
.2054.20
11/4/2015
2.89
2060.23
1.44
2057.34
05/04/2016
5.53
2060.23
1.44
2054.70
11/09/2016
6.55
2060.23
1.44
2053.68
Notes: -
ft-BTOC Feet below top -of -well casing ,
Top -of -casing MW-5 through MW-8 top -of -casing elevations based upon a survey,by Hill and Associates Surveyors dated
elevations January 10, 2002 through May 2012. MW-2R and MW-4 top -of -casing elevations based upon differential level
measurements made by,Altamont Environmental, Inc. on June 26, 2006 through May 2012. The top -of -casing
elevations for the monitoring wells were resurveyed on November 21, 2012 by Wes Cole Land Surveying. The
top -of -casing elevations for MW-9 were surveyed on May 29, 2015 by Wes Cole Land Surveying.
Groundwater Top of casing minus depth to groundwater.
elevations
P:\Clement Pappas\Reports\2016 2081.01\November\Table 2 Historic GW Elev Page 5 of 5

acmnalytical
wmpacelabs.com
November 18, 2016
Brian Gant
Altamont Environmental
231 Haywood Street
Asheville, NC 28804
RE: Project: Clement Pappas
Pace Project No.: 92319070
Dear Brian Gant:
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on November 09, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lord Patton
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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Pace Analytical Services, LLC..
m 2225 Riverside Dr.
71wemalXical Asheville, NC 28804
www.pacelabs.com [phone]
CERTIFICATIONS
Project: . Clement Pappas
Pace Project No.: 92319070
Charlotte Certification IDs
9800•KinceyAve. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification.*: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 46,0221
Asheville Certification lDs
2225 Riverside Drive, Asheville, NC 28804
North Carolina Wastewater Certification #: 40
Florida/NELAP Certification #: E87648
South Carolina Certification #: 99030001
Massachusetts Certification #: M-NC030
Virginia/VELAP Certification #: 460222
North Carolina Drinking Water Certification #: 37712
t
REPORT OF LABORATORY ANALYSIS
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acmnalytical
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SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project:
Clement Pappas
Pace Project No.:
92319070
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92319070001
MW-4
SM 6200B
CAH
63
PASI-C
SM 2540C
MJS1
1
PASI-A
SM 9222D
KDF1
1
PASI-A
EPA 350.1 1993 Rev 2.0
BRJ
1
PASI-A
EPA 353.2
WRC
1
PASI-A
EPA 365.1
MDW
1
PASI-A
SM 4500-CI-E
WRC
1
PASI-A
SM 5310E
AES2
1
PASI-A
92319070002
MW-5
SM 62006
CAH
63
PASI-C
SM 2540C
MJS1
1
PASI-A
SM 9222D
KDF1
1
PASI-A
EPA 350.1 1993 Rev 2.0
BRJ
1
PASI-A
EPA 353.2
WRC
1
PASI-A
EPA 365.1,
MDW
1
PASI-A
SM 4500-CI-E
WRC
1
PASI-A
SM 5310B
AES2 `.
1
PASI-A
92319070003
MW-6
SM 6200B
CAH
63
PASI-C
SM 2540C
MJS1
1
PASI-A
SM 9222D
KDF1
1
PASI-A
EPA 350.1.1993 Rev 2.0
BRJ
1
PASI-A
EPA 353.2
WRC
1
PASI-A
EPA 365.1
MDW
1
PASI-A
SM 4500-CI-E
WRC
1
PASI-A
SW531013
AES2
1
PASI-A
92319070004
MW-7R
SM 6200B
CAH
63
PASI-C
SM 2540C
MJS1
1
PASI-A
SM 9222D
KDF1
1
PASI-A
EPA 350.1 1993 Rev 2.0
BRJ
1
PASI-A
EPA 353.2
WRC
1
PASI-A
EPA365.1
MDW
1
PASI-A
SM 4500-CI-E
WRC
1
PASI-A
SM 5310B
AES2
1
PASI-A
92316070005
MW-8
SM 6200B
CAH
63
PASI-C
SM 2540C
MJS1
1
PASI-A
SM 9222D
KDF1
1
PASI-A
EPA 350.1 1993 Rev 2.0
BRJ
1
PASI-A
EPA 353.2
WRC
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 37

aceAna1Xica1
www.pacefabsxom
SAMPLE ANALYTE COUNT
Project: Clement Pappas
Pace Project No.: 92319070
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
EPA 365.1
MDW
1
PASIA
SM 4500-CI-E
WRC
1
PASI-A
SM 5310B
AES2
1
PASI-A
92319070006, . ' : MW-9
SM 6200B
CAH
63
PASI-C
SM 2540C
MJS1
1
PASI-A
SM 9222D
KDF1
1
PASI-A'
EPA 350.1 1993 Rev 2.0
BRJ
1
PASI-A
EPA 353.2
WRC
1
PASI-A
EPA 365.1
MDW
1
PASI-A
SM 4500-CI-E
WRC
1
PASI-A
SM 5310E
AES2
1
PASI-A
92319670007 Trip Blank
SM 6200B
CAH "
63
PASI-C -
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 37

Pace Analytical Services, LLC
ane fl a I, ,yrnal 2225 Riverside 04
Vlr�! lY(Ilr Asheville, NC 28804
www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project: Clement Pappas
Pace Project No.: 92319070
Sample: MW-4 Lab ID: 92319070001 Collected: 11/09/16 13:00 Received: 11/09/16 14:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
6200B MSV Analytical Method: SM 6200B
Benzene
ND
ug/L
0.50
1
11/12/16 10:08
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/12/16 10:08
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/12/16 10:08
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/12/16 10:08
75-27-4
Bromoform
ND
ug/L
0.50
1
11/12/16 10:08
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/12/16 10:08
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/12/16 10:08
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/12/16 10:08
135-98-8
tert=Butylbenzene
ND
ug/L
0.50
1
11/12/16 10:08
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/12/16 10:08
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/12/1610:08.108-90-7
Chloroethane
ND
ug/L
1.0
1
11/1211610:08
75-00-3
Chloroform
ND
ug/L
0.50
1
11/12/16 10:08
67-66-3
Chloromethane
ND
ug/L
1.0
1-
11/12/16 10:08
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/1211610:08
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/12/16 10:08
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/12/16 10:08
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/1211610:08
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/12/16 10:08
1p6-93-4
Dibromomethane
ND
ug/L
0.50
1
11/12/16 10:08
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/12/16 10:08
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/12/16 10:08
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/12/16 10:08
106-46-7
Diehl orodifluoromethane
ND
ug/L
0.50
1
11/12/16 10:08
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/12/16 10:08
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/12/16 10:08
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/12/16 10:08
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/1211610:08
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/12/16 10:08
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/12/16 10:08
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/12/16 10:08
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/12/16 10:08
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/12/16 10:08
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/12/16 10:08
10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
0.50
1
11/12/16 10:08
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/12/16 10:08
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/12/16 10:08
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/12/16 10:08
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/12/16 10:08
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/12/16 10:08
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/12/16 10:08
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/12/16 10:08
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/12/16 10:08
103-65-1
Styrene
ND
ug/L
0.50
1
11/12/16 10:08
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/1211610:08
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/12/16 10:08
79-34-5
Tetrachloroethene
ND
ug/L
0.50
1
11/12/16 10:08
127-18-4
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/18/2016 10:59 AM
without
the written consent of Pace Analytical Services, LLC.
Page 5 of 37

aceAnalXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: Clement Pappas
Pace Project No.: 92319070
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-4.
Lab ID: 92319070001 Collected:
11/09/16 13:00
Received: 11/09/16 14:30 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No.. Qual
6200B MSV
Analytical Method: SM 6200B
Toluene
ND ug/L
0.50
1
11/12/16 10:08
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/1211610:08
.87-61-6-
1,2,4-Trichlorobenzene
ND ug/L
2.0.
1
11/12/1610-08.120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/12/16 10:08
71-55-6
1,1,2-Trichloroethane_
ND ug/L
0.50
1
11/12/16 10:08
79-00-5.
Trichloroethene
ND ug/L
0.50.
1
11/12/1610:08:79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/12/16 10:08
75-69-4
1,2,3-Trichloropropane .
ND - ug/L
0.50
1
11/12/16 10:08
96-18-4
1,2,4-Trimethylbenze6e.
ND ug/L
0.50
1
11/12/16 10:08
95763-6
1,3,5-Trimethylbenzene
ND ug/L
6.50
1
11/12/16 10:08
•108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/12/16 10:08
75-01-4
m&p-Xylene
ND ug/L
1.0-
1
11/12/16 10:08
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/12/16.10:08
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
93 %
70-130
1
11/12/16 10:08
17060-07-0
4-Bromofluorobenzene (S)
96 %
70-130
1
.11/12116 10:08
460-00-4
Toluene-d8 (S)
100 %
70-130
1
11/12/16 10:08
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C
i
Total Dissolved Solids
124 mg/L
25.0
1
11/11/16 14:53
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D
Fecal Coliforms
ND CFU/1.00 mL
4.0
4
11/09/16 15:39
350.1 Ammonia
Analytical Method: EPA 350.1 1993 Rev 2.0
Nitrogen, Ammonia
ND mg/L
0.10
1
11/17/16 07:39
7664-41-7
353.2 Nitrogen, N021NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
ND mg/L
0.020
1
11/11/16 moo
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
0.27 mg/L
10.050
1
11/11/16 23:05
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E
Chloride
12.2 mg/L
1.0
1
11/17/1617:01
16887-00-6
5310B TOC
Analytical Method: SM 5310B
Total Organic Carbon
4.3 mg/L
1.0
1
11/17/16 11:05
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC.
Page 6 of 37

aceAnalytical
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Clement Pappas
Pace Project No.: 92319070
Sample: MW-5 Lab ID: 92319070002 Collected: 11/09/16 11:15 Received: 11/09/16 14:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
6200B MSV Analytical Method: SM 6200B
Benzene
ND
ug/L
0.50
1
11/12/16 10:25
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/12/16 10:25
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/12/16 10:25
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/12/16 10:25
75-27-4
Bromoform
ND.
ug/L
0.50
1
11/12/16 10:25
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/12/16 10:25
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/12/16 10:25
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/12/16 10:25
135-98-8
tert-Butylbenzene
ND
ug/L
0.50
1
11/12/16 10:25
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/12/16 10:25
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/1211610:25
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/12/16 10:25
75-00-3
Chloroform
ND
ug/L
0.50
1
11/12/16 10:25
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/1211610:25
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/12/16 10:25
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/12/16 10:25
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
1111211610:25
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
1111211610:25
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/12/16 10:25
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/12/16 10:25
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/12/16 10:25
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11112/1610:25
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/12/16 10:25
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/12/16 10:25
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/12/16 10:25
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/1211610:25
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/12/16 10:25
75-35-4
cis-1,2-Dichloroethene
75.2
ug/L
0.50
1
11/12/16 10:25
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/12/16 10:25
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/12/16 10:25
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/12/16 10:25
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/12/16 10:25
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/12/16 10:25
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/12/16 10:25
10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
0.50
1
11/12/16 10:25
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/12/16 10:25
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/12/16 10:25
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/12/16 10:25
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/12/16 10:25
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/12/16 10:25
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/12/16 10:25
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/12/16 10:25
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/12/16 10:25
103-65-1
Styrene
ND
ug/L
0.50
1
11/12/16 10:25
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/12/1610:25
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/12/16 10:25
79-34-5
Tetrachloroethene
141
ug/L
0.50
1
11/12/16 10:25
127-18-4
REPORT
OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/18/2016 10:59 AM
without the written consent
of Pace Analytical Services, LLC.
Page 7 of 37

�-JceAhalyficql
wwwp-labs,com
ANALYTICAL RESULTS
Project: Clement Pappas
Pace Project No.: 92319070
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-5
Lab ID: 92319070002 Collected:
11/09/16 11:15
Received: 11/09/16 14:30 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
6200E MSV
Analytical Method: SM 6200B
Toluene
'ND ug/L
0.50
1
11/1211610:25
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/12/16 10:25
87-61-6
112,4-Trichlorobenzene
ND ug/L
2.0
1
11/12/16 10:25
120-82-1
1,1,1-Trichloroethane:
ND ug/L
0.50
1
11/12/16 10:25
71-55-6 `
1,1,2-Trichloroethane.
ND ug/L
0.50
1
11/12/16 10:25
79-00-5
Trichloroethene
-63.1 ug/L
0.50
1
11/12/16 10:25
79-01-6
Trichlorofluoromethane
ND ug/L
1:0
1
11/12/16 10:25
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1 _
11/12/16 10:25
96-18-4
1,2,4-Trimethylbenzene
ND ug/L.
0.50
1
11/12/16 10:25
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/12/16 10:25
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11'/12/16 10:25.
75-01-4
m&p-Xylene
ND :ug/L
1.0;
1
11/12/1610:25
179601-23-1.
o-Xylene
ND. ug/L
0.50
..1
11/12/16 10:25
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
89 %
70-130
1
11/12/16 10:25
:17060-07-0
4-Bromofluorobenzene (S)
95 %
70-130
1
11/12/16 10:25
460-00-4 .
.Toluene-d8 (S)
99 %
70-130
1
11/12/16 10:25
2037-26-5
2540C.Total Dissolved. Solids
Analytical Method: SM 2540C
Total Dissolved Solids
109 mg/L
25.0.
1
11/11/16 14:54.
MBIO 9222D. Fecal Coliform AVL
Analytical Method: SM 9222D
Fecal Coliforms
ND CFU/100 mL
4.0
'4 -
11/09/16 15:39
350.1 Ammonia
Analytical Method: EPA 350.1 1993 Rev 2.0
Nitrogen, Ammonia
ND mg/L
0.10
1
11/17/16 07:41
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
0.42 mg/L
0.020
1
11/10/16 23:5.5
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
0.47 mg/L
0.050
1
11/11/16 23:06
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E
Chloride
45.0 mg/L
4.0
4..
11/1711617:36
16887-00-6
5310B TOC
Analytical Method: SM 5310B
-
Total Organic Carbon
ND mg/L
1.0
1
11/17/16 11:36
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC.
Page 8 of 37

aceAnalytical
www.pacelabs.com
ANALYTICAL RESULTS
Project: Clement Pappas
Pace Project No.: 92319070
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-6 Lab ID: 92319070003 Collected: 11/09/16 12:00 Received: 11/09/16 14:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
6200B MSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2=Dichlorobenzene
1,3-Dichlorobenzene
1,47Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Date: 11/18/2016 10:59 AM
Analytical Method: SM 6200B
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
0.50
0.50
0.50
0.50
0.50
5.0
0.50
0.50
0.50
0.50
0.50
1.0
0.50
1.0
0.50
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
0.50
2.0
0.50
2.0
0.50
0.50
0.50
0.50
0.50
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
11/12/1610:42
71-43-2
11 /12/16 10:42
108-86-1
11/12/1610:42
74-97-5
11/12/1610:42
75-27-4
11 /12/16 10:42
75-25-2
11/12/1610:42
74-83-9
11 /12/16 10:42
104-51-8
11 /12/16 10:42
135-98-8
11/12/1610:42
98-06-6
11/12/1610:42
56-23-5
11 /12/16 10:42
108-90-7
11/12/1610:42
75-00-3
11/12/16:10:42
67-66-3
11 /12/16 10:42
74-87-3
11/12/1610:42
95-49-8
11112/16 10:42
106-43-4
11/12/1610:42
96-12-8
11 /12/16 10:42
124-48-1
11 /12/16 10:42
106-93-4
11/12/1610:42
74-95-3
11 /12/16 10:42
95-50-1
11/12/1610:42
541-73-1
11 /12/16 10:42
106-46-7
11/12/1610:42
75-71-8
11/12/1610:42
75-34-3
11/12/16 10:42
107-06-2
11/12/1610:42
75-35-4
11112/16 10:42
156-59-2
11 /12/16 10:42
156-60-5
11/1211610:42
78-87-5
11 /12/16 10:42,
142-28-9
11 /12/16 10:42
594-20-7
11/12/1610:42
563-58-6
11 /12/16 10:42
10061-01-5
11 /12/16 10:42
10061-02-6
11 /12/16 10:42
108-20-3
11 /12/16 10:42
100-41-4
11/12/1610:42
87-68-3
11/12/1610:42
98-82-8
11 /12/16 10:42
75-09-2
11 /12/16 10:42
1634-04-4
11/12/1610:42
91-20-3
11 /12/16 10:42
103-65-1
11 /12/16 10:42
100-42-5
11/12/1610:42
630-20-6
11/1211610:42
79-34-5
11 /12/16 10:42
127-18-4
Page 9 of 37

i
2aceftlj6cal
c—pacelabsxam
ANALYTICAL RESULTS
Project: Clement Pappas
Pace Project No.: 92319070
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-6
- Lab ID: 92319070003 Collected:
11/09/16 12:00
Received: 11/09/16 14:30 Matrix: Water
1 Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No.
. 6200B MSV
Analytical Method: SM 6200B
Toluene
ND ug/L
0.50
1
11/12/16 10:42
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/12/16 10:42
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0:
1
11/12/1610`.42
120-82-1
1,1,1-Trichloroethane
ND.' ug/L
0.50
1
11/12/16 10:42
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/12/16 10:42
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/12/1610:42
_79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/12/16 10:42
75-69-4
1,2,3-Trichloropropane
ND ,. ug/L. -
0.50
1
11/1211610:42
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/12/16 10:42
95-63=6
i 1,3,5-Trimethylbenzene
ND-, ug/L
0.50
1
11/12/16 10:42
108-67-8
Vinyl chloride .
ND ug/L
1.0..
1
11-/12/16 10:42
75-01-4
F m&p-Xylene ...
ND ug/L
1.0
1
11/12/16 10:42
-179601723-1
o-Xylene
ND.. ug/L
0.50
..1
11/12/16 10:42
95-47-6
i Surrogates
1,2-Dichloroethane-d4 (S)
92 %
70-130
1
11/12/16 10:42
.17060-07-0
4-Bromofluorobenzene (S)
97 %
70-130
1
11l12/16 10:42
460-00-4.
' Toluene-d8 (S)-
100 %
70-130
1
11/12/16 10:42
2037-26-5 "
2540C Total Dissolved, Solids
Analytical Method: SM 2540C
Total Dissolved Solids
64.0 mg/L
25.0.
1
11/11/16 14:55
.
P MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D
ph Fecal Coliforms
ND. CFU/100 mL
10.0
10
11/09/16 15:39
j 350A Ammonia,
Analytical Method: EPA 350.1 1993 Rev 2.0
Nitrogen, Ammonia
0.11 - mg/L
0.10
1
11/17/16 07:42
7664-41-7
E 353.2 Nitrogen, N021NO3 unpres.
Analytical Method: EPA 353.2
Nitrogen, Nitrate
ND mg/L
0.020 -
1
11/10/16 23:59
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
0.70 mg/L
0.050
1
11/11/16 23:06
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E
Chloride
9.0 mg/L
1.0
1
11/17/1617:08
16887-00-6
531OB TOC
Analytical Method: SM 5310B
TotalOrganic.Carbon
7.1 mg/L
1.0
1
11/17/1611:49
7440-44-0
Date: 11 /18/2016 10:59 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Qua[
Page 10 of 37

Pace Analytical Services, LLC
/+ //���n o 2225 Riverside Dr.
ace (alXi /+a%Asheville, NC 28804
www..pacelabs.com
[phone]
ANALYTICAL RESULTS
Project: Clement Pappas
Pace Project No.: 92319070
Sample: MW-7R Lab ID: 92319070004 Collected: 11/09/16 10:25 Received: 11/09/16 14:30 Matrix: Water
Parameters
6200B MSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3=chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,17Dichloropropene
cis-1,3-Dichloropropene
trans-1, 3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Date: 11/18/2016 10:59 AM
Results Units
Analytical Method: SM 6200B
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
Report Limit DF Prepared
Analyzed CAS No. Qua[
0.50
1
11112/1610:59
71-43-2
0.50
1
11/12/16 10:59
108-86-1
0.50
1
11/12/16 10:59
74-97-5
0.50
1
11/.1211610:59
75-27-4
0.50
1
11/1211610:59
75-25-2
5.0
1
11/1211610:59
'74-83-9
0.50
1
11/12/16 10:59
104-51-8
0.50
1
11/12/16 10:59
135-98-8
0.50
1
11/12/16 10:59
98-06-6
0.50
1
11/12/16 10:59
.56-23-5
0.50
1
11/12/16 10:59
108-90-7
1.0
1
11/12/16 10:59
75-00-3
0.50
1
11/12/16 10:59
67-66-3
1.0
1
11/12/16 10:59
74-87-3
0.50
1
11/12/16 10:59
96-49-8
0.50
1
11/12/16 10:59
106-43-4
1.0
1
11/12/16 10:59
96-12-8
0.50
1
11/12/16 10:59
124-48-1
0.50
1
11 /12/16 10:59
106-93-4
0.50
1
11/12/16 10:59
74-95-3
0.50
1
11/1211610:59
95-50-1
0.50
1
11/12/16 10:59
541-73-1
0.50
1
11/12/16 10:59
106-46-7
0.50
1
11/1211610:59
75-71-8
0.50
1
11/12/16 10:59
75-34-3
0.50
1
11/12/16 10:59
107-06-2
0.50
1
11/12/16 10:59
75-35-4
0.50
1
11/12/16 10:59
156-59-2
0.50
1
11/12/16 10:59
156-60-5
0.50
1
11/12/16 10:59
78-87-5
0.50
1
11/12/16 10:59
142-28-9
0.50
1
11/12/16 10:59
594-20-7
0.50
1
11112/1610:59
563-58-6
0.50
1
11/12/16 10:59
10061-01-5
0.50
1
11/12/16 10:59
10061-02-6
0.50
1 _
11/12/16 10:59
108-20-3
0.50
1
11/12/16 10:59
100-41-4
2.0
1
11112/1610:59
87-68-3
0.50
1
11/12/16 10:59
98-82-8
2.0
1
11/12/16 10:59
75-09-2
0.50
1
11/12/16 10:59
1634-04-4
2.0
1
11/12/16 10:59
91-20-3
0.50
1
11/12/16 10:59
103-65-1
0.50
1
11/12/16 10:59
100-42-5
0.50
1
11/12/16 10:59
630-20-6
0.50
1
11/1211610:59
79-34-5
0.50
1
11/12/16 10:59
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 37

aceAnalytical
wmpacelalis.cam
ANALYTICAL RESULTS
Project: Clement Pappas
Pace Project No.: 92319070
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-7R
Lab ID: 92319070004 Collected:
11/09/16 10:25
Received: 11/09/16 14:30 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Toluene
ND ug/L
0.50
1'
11/12/16 10:59
.108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/12/16 10:59
87-61-6
1;2;4-Trichlorobenzene
ND ug/L
2.0.
. 1
11/12/1610:59.120-82-1
1,1,1-Trichl4oethane
ND ug/L
0.50
1
11/12/16:10:59
71-55-6
1,1,2-Trichloroethane
ND. ug/L:
0.50
1
11/12/16 10:59
79-00-5
Trchloroethene
ND ug/L
0.50
1
11/12/16 10:59
79-01-6.
Trichlorofluoromethane
ND ug/L
1:0
1
11/12/16 10:59
75-69-4.
1,2,3-Trichloropropane
ND ug/L.
:6.56
1
11/12/1610:59
96-18-4
1,2,4-Trimethylbenzene .
ND ug/L
0.50
1
11/12/16 10:59
95-63-6
1,3,5-Trimethylbenzene
ND ..ug/L, "
0.50
1
11/12/1610:59
106-67-8
Vinyl chloride :
ND :ug/L
:1.0
1
- 11/12/16 10:59
75-01-4.
m&p-Xylene
-. ND uglL
1.0:,
1
11/12/16 10:59
179601-23-1
o-Xylene
ND. ug/L
_0.50
1
11/12/16 10:59
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
93' :%
70-130
1
11/12/16 10:59
17060-07-0
4-Bromofluorobenzene (S)
96 %
70-130
1
11/12/16 10:59
460-00-4 -
Toluene-d8 (S)
101 %
70-130
1
11/12/16 10:59
2037-26=5
2640C.Total Dissolved Solids
Analytical Method: SM 2540C
Total Dissolved Solids
147 mg/L
25.0
1
11/11/16 14:55
MBIO 9222D. Fecal Coliform AVL
Analytical,Method: SM 9222D
Fecal Coliforms
ND CFU/100 mL -
20.0
20
11/09/16 15:39
350.1 Ammonia .
Analytical Method: EPA 350.1 1993 Rev 2.0 "
Nitrogen, Ammonia
ND mg/L
0.10
1-
11/17/16 07:44
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
AnalyticafMethod: EPA353.2
Nitrogen, Nitrate,"
12.5 mg/L
0.10
5
11/11/16 00:42
365.1 Phosphorus, Total `
Analytical Method: EPA 365.1
Phosphorus
-1.0 mg/L•'
0.050.
1'
11/11/1623:08
7723-14=0
4506 Chloride
Analytical Method: SM 4500-CI-E
Chloride
.22.7. mg/L..
1.0
1 ..
11/17/16:17 09
16887-00-6
5310E TOC
Analytical Method: SM 53106
Total Organic Carbon
13.0 mg/L
1.0
1
11/17/16 12:05
7440-44-0
r
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC: Page 12 of 37

aceAnalytical
vnvwpacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Clement Pappas
Pace Project No.: 92319070
Sample: MW-8 Lab ID: 92319070005 Collected: 11/09/16 09:45 Received: 11/09/16 14:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
6200E MSV Analytical Method: SM 6200B
Benzene
ND
ug/L
0.50
1
11/12/16 11:15
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/12/16 11:15
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/12/16 11:15
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/12/16 11:15
75-27-4
Bromoform
ND
ug/L
0.50
1
11/12/16 11:15
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/12/16 11:15
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/12/16 11:15
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/12/16 11:15
135-98-8
tert-Butylbenzene
ND
ug/L
0.50
1
11112/1611:15
9&06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/12/16 11:15
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/12/16 11:15
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/12/16 11:15
75-00-3
Chloroform
ND
ug/L
0.50
1
11/12/16 11:15
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/12/16 11:15
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/12/16 11:15
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
.11/12/16 11:15
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/12/16 11:15
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/12/16 11:15
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/12/16 11:15
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/12/16 11:15
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/12/16 11:15
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
.1
11112/1611:15
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/12/16 11:15
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/1211611:15
75-71-8
1,1-Dichloroethane
ND
ug/L
.0.50
1
11/12/16 11:15
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/12/16 11:15
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/12/16 11:15
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/12/16 11:15
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/12/16 11:15
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/12/16 11:15
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/12/16 11:15
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/12/16 11:15
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/12/16 11:15
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/12/16 11:15
10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
0.50
1
11/12/16 11:15
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/12/16 11:15
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/12/16 11:15
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/12/16 11:15
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/12/16 11:15
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/12/16 11:15
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/12/16 11:15
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/12/16 11:15
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/12/16 11:15
103-65-1
Styrene
ND
ug/L
0.50
1
11/12/16 11:15
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/12/16 11:15
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/12/16 11:15
79-34-5
Tetrachloroethene
ND
ug/L
0.50
1
11/12/16 11:15
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC.
Page 13 of 37

laceAnalyfical
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ANALYTICAL RESULTS
Project: Clement Pappas
Pace Project No.: 92319070
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-8
Lab lD: 92319070005 Collected:
11/09/16 09:45
Received: 11/09/16 14:30 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qua[
6200B MSV
Analytical Method: SM 6200B
Toluene
ND ug/L
0.50.
1
11/12/16 11:15
108-88-3
1,2,3-Trich[orobenzene
ND ug/L
2.0
1
11/12/16 11:15
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/12/16 11:15
120-82-1
1,1,1-Trich[oroethane:
ND: ug/L
0.50
1
11/12/16 11:15
71-55-6
1,1,2-Trichloroethane.
ND ug/L ,
0.50
1
11/12/16 11:15
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/12/16 11:15
79-01-6
TricMorofluoromethane
ND ug/L
1.0
1
11/12/16 11:15
75-69-4
1,2,3-Trich[oropropane .
ND ug/L,
6.50
1
11/12/16 11:15
96-18-4
1,2,4-Trimethylbenzene.
ND ug/L
0.50
1
11/12/16 11:15
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/12/16 11:15
108-67-8
Vinyl chloride .
ND ..ug/L
.1.0
1
11/12/16 11:15-
75-01-4.
m4-Xylene (
ND ug/L
1.0 _
1
11/12/16 11:15
179601-23-1
o-Xylene
ND ug/L
0.50
1 ..
11/12/16 11:15
95-47-6
Surrogates
1,2-Dichloroethane-d4(S)
91 %
70-130.
1
11112/1611:15
17060-07-0
4-Bromofluorobenzene (S)
97 %
70-130
1
11/12/16 11:15
460-00-4
Toluene-d8 (S)
96 - %
70-130
1
11/12/16 11:15
2037-26-5
2540C Total DissolvedSolids
Analytical Method: SM 2540C
Total -Dissolved Solids
333 mg/L q
25.0. .
1'
11/11/16 14:55
MBIO 9222D Fecal Coliform AVL
Analytical Method:,SM 9222D
Fecal Coliforms
ND CFU/100 mL
4.0
4
11/09/16 15:39
350.1 Ammonia
Analytical Method: EPA 350A 1993 Rev 2.0 .
Nitrogen, Ammonia
ND mg/L
0.10
1.
11 /17/16 07:45
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate,
14.3 mg/L
0.02a
1
11/10/16 23:48
M6
365.1' Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
0.26 mg/L
0.050
1
11/11/1623:11
7723-14-0
4506 Chloride
Analytical Method: SM 4500-CI-E
Chloride
12.0 mg/L
1.0
1
11/17/1617:10
16887-00-6
5310B TOC
Analytical Method: SM 531 OB
Total Organic Carbon
9.7 mg/L
1.0
1
11/17/16 12:36
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/18/201610:59 AM . without the written consent of Pace Analytical Services, LLC.
Page 14 of 37

aceAnalytical
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ANALYTICAL RESULTS
Project: Clement Pappas
Pace Project No.: 92319070
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-9
Parameters
Lab ID: 92319070006 Collected: 11/09/16 13:20 Received:
Results Units Report Limit DF Prepared
11109/16 14:30 Matrix: Water
Analyzed CAS No. Qua[
6200B MSV
Analytical Method: SM 6200B
Benzene
NO
ug/L
0.50
1
11/12/16 11:32
71-43-2
Bromobenzene
ND
ug/L
.0.50
1
11/12/16 11:32
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/12/16 11:32
74-97-5
Bromodichloromethane
NO
ug/L
0.50
1
11/12/16 11:32
75-27-4
Bromoform
NO
ug/L
0.50
1
11/12/16 11:32
75-25-2
Bromomethane
NO
ug/L
5.0
1
11/12/16 11:32
74-83-9
n-Butylbenzene
NO
ug/L
0.50
1
11/12/16 11:32
104-51-8
sec-Butylbenzene
NO
ug/L
0.50
1
11/12/16 11:32
135-98-8
tert-Butyl benzene
NO
ug/L
0.50
1
11/12/16 11:32
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/12/16 11:32
56-23-5
Chlorobenzene
NO
ug/L
0.50
1
11/12/16 11:32
108-90-7
Chloroethane
NO
ug/L
1.0
1
11/12/16 11:32
75-00-3
Chloroform
NO
ug/L
0.50
1
11/12/16 11:32
67-66-3
Chloromethane
NO
ug/L
1.0
1
11/12/16 11:32
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/12/16 11:32
.95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/12/16 11:32
106-43-4
1,2-Dibromo-3-ch[oropropane
ND
ug/L
1.0
1
11/12/16 11:32
96-12-8
Dibromochloromethane
NO
ug/L
0.50
1.
11/12/16 11:32
124-48-1
1,2-Dibromoethane (EDB)
NO
ug/L
0.50
11
11/12/16 11:32
106-93-4
Dibromomethane '
NO
ug/L
0.50
1
11/12/16 11:32
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/12/16 11:32
95-50-1
1,3-Dichlorobenzene
NO
ug/L
0.50
1
11/12/16 11:32
541-73-1
1,4-Dichlorobenzene
NO
ug/L
0.50
1
11/12/16 11:32
106-46-7
Dichlorodifluoromethane
NO
ug/L
0.50
1
11/12/1611:32
75-71-8 M1
1,1-Dichloroethane
NO
ug/L
0.50
1
11/12/16 11:32
75-34-3
1,2-Dichloroethane
NO
ug/L
0.50
1
11/1211611:32
107-06-2
1,1-Dichloroethene
NO
ug/L
0.50
1
11/12/16 11:32
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/12/16 11:32
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11112/1611:32
156-60-5
1,2-Dichloropropane
NO
ug/L
0.50
1
11/12/16 11:32
78-87-5
1,3-Dichloropropane
NO
ug/L
0.50
1
11/12/16 11:32
142-28-9
2,2-Dichloropropane
NO
ug/L
0.50
1
11/12/16 11:32
594-20-7
1,1-Dichloropropene
NO
ug/L
0.50
1
11/12/16 11:32
563-58-6
cis-1,3-Dichloropropene
NO
ug/L
0.50
1
11/12/16 11:32
10061-01-5
trans-1,3-Dichloropropene
NO
ug/L
0.50
1
11/12/16 11:32
10061-02-6
Diisopropyl ether
NO
ug/L
0.50
1
11/12/16 11:32
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/12/16 11:32
100-41-4
Hexachloro-1,3-butadiene
NO
ug/L
2.0
1
11/12/16 11:32
87-68-3
Isopropylbenzene (Cumene)
NO
ug/L
0.50
1
11/12/16 11:32
98-82-8
Methylene Chloride
NO
ug/L
2.0
1
11/12/16 11:32
75-09-2
Methyl-tert-butyl ether
NO
ug/L
0.50
1
11/12/16 11:32
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/12/16 11:32
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/12/16 11:32
103-65-1
Styrene
NO
ug/L
0.50
1
11/12/16 11:32
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/12/16 11:32
630-20-6'
1,1,2,2-Tetrachloroethane
NO
ug/L
0.50
1
11/12/16 11:32
79-34-5
Tetrachloroethene
ND
ug/L
0.50
1
11/12/16 11:32
127-18-4
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/18/2016 10:50 AM
without
the written consent of Pace Analytical Services, LLC.
Page 15 of 37

Pace Analytical Services, LLC
aceMalXical ® 2225 Riverside
Asheville, NC 2880404
www.pacelabs.com [phone]
ANALYTICAL' RESULTS
Project: Clement Pappas
Pace Project No.: 92319070
Sample: MW-9
Lab ID: 92319070006 Collected:
11/09/16 13:20
Received: 11/09/16 14:30 Matrix: Water
Parameters
Results Units Report
Limit
DF
Prepared Analyzed
CAS No. Qua]
6206B MSV
Analytical Method: SM 6200B
Toluene
ND ug/L
0.50
1
11/12/16 11:32
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/12/16 11:32
87-61-6'
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/12/9611:32
120-82-1
1,1,1-Trichloroethane
ND ug/L ;
0.50
1
11/12/16 11:32
71-55=6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/12/16 11:32
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/12/1611:32
79-01-6
Trich]orofluoromethane
ND ug/L
1.0
1
11/12/16 11:32
75-69-4
1,2,3-Trichloropropane
ND ug/L. _.
0.50
1
11/12/16 11:32
96-18-4
1,2,4-Trimethy]benzene .
ND'- ug/L .
0.50
1
11/12/16 11:32
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/12/16 11:32
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/12/16 11:32
75-01-4
m&p-Xylene -
ND ug/L
1.0
1
11/12/16 11:32
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/12/16 11:32
95-47-6
Surrogates
1,2-Dichloroethane-d4(S)
91 %
70-130
1
11/12/16"11:32
17060-07-0
4-Bromofluorobenzene (S)
96 %
70-130
1
11/12/16 11:32
460-00-4
Toluene-d8 (S)
102 %
707130
1
11/12/16 11:32
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C
Total Dissolved Solids
69.0 mg/L
25.0
1
11/11/16 14:56
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D
Fecal Co]iforms _
ND CFU/100 mL
20.0
.20
11/09/16 15:39
350.1 Ammonia
Analytical Method: EPA 350.1 1993 Rev 2:0
Nitrogen, Ammonia
ND mg/L
0.10
1
11/17/16 07:50
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres .
Analytical Method: EPA353.2
Nitrogen, Nitrate
0.77 mg/L
0.020
1
11/11/16 00:01
366.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
0.76 rrig/L
0.050
1
11/11/16 23:13
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E
Chloride
10.7 mg/L
1.0
1
11/17/1617:11
16887-00-6
5310E TOC
Analytical Method: SM 5310B
Total Organic Carbon
9.3 mg/L
1.0
1
11/17/16 12:48
7440-44-0
Date: 11 /18/2016 10:59 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 16 of 37

aceAnalytical
www.pacelabs,com
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804 ✓
[phone]
Project: Clement Pappas
Pace Project No.: 92319070
Sample: Trip Blank
Lab ID: 92319070007 Collected: 11/09/16 00:00 Received:
11/09/16 14:30 Matrix: Water
Parameters
Results
Units
Report Limit
DF Prepared
Analyzed
CAS No. Qual
6200B MS.V
Analytical Method: SM 62006
Benzene
ND-
ug/L -
0.50
.1
11/12/16 11:49
.71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/12/16 11:49
108-86-1
Bromochloromethane
ND
-ug/L
0.50
1
11/12/16 11:49
74-97-5:
Bromodichloromethane -
ND
ug/L
'0.50
1
11/12/16 11:49
75-274
Bromoform-
ND.
ug/L- .
0.50
1;
11/12/16 11:49
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/12/16 11:49
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/12/16 11:49
104-51-8
sec-Butylbenzene
ND _
ug/L
0.50
1
11112/1611:49
135-98-8
tert-Butylbenzene
ND
ug/L.:
0.50
1.
11/12/1611:49
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/12/16 11:49
•56-23-5
Chlorobenzene
pND
ug/L
0.50
1
11112/1611:49
108-90-7
Chloroethane
ND
-,ug/L
1.0.
1
11/12/1611:49,
75-00-3.
Chloroform
ND
ug/L
0.50
1 .'
11/12/16 11:49
67-66-3
Chloromethane
ND.
ug/L;'
1.0
1---
11/1.2/1611:49
74-8.7-3
2-Chlorotoluene .
ND
ug/L
0.50
1
.11/12/16 11:49
95-49-8
4-Chlorotoluene ;
ND
ug/L
0.50
1
11/12/16 11:49
106-43-4
1,2-Dibromo-3=chloropropane
ND
ug/L
1.0
1
11/1211611:49
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/12/16 11:49
124-48-1
1,2-Dibromoethane (EDB).
ND
ug/L
0.50
1
11/12/16 11:49
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11112/1611:49
74-95-3,
1,2-Dichlorobenzene
ND
-ug/L
0.50
1
11/12/16 11:49.
95-50-1
1,3-Dichlorobenzene
ND
ug/L
.0.50
1
11/12/16 11:49
541-73-1
1,4-Dichlorobenzene -
ND
ug/L.
0.50
1
11/12/16 11:49
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/12/16 11:49
75-71-8
1,17Dichloroethane
ND
ug/L
0.50
1
11/12/16 11:49
75-34-3
1,2-Dichloroethane -
ND
ug/L
0.50
1
11112/1611:49
107-06-2
1,1-Dichlor0ethene
ND
ug/L
0.50
1
11/12/1611:49
75-35-4
cis-1,2-Dichloroethene
ND
ug/L .
.0.50
1
11/12/16 11:49
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11 j12/16 11:49
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/12/16 11:49
78-87-5
1,3-Dichloropropane ,
ND
ug/L
.'0.50
1
11/1.2/16 11:49
142-28-9
2,2-Dichloropropane
ND
ug/L-
0.50
1
11/12/16 11:49
594720-7
1,17Dichloropropene
ND
ug/L
0.50
1
11/12/16 11:49
-563-58-6
cis-1;3-Dichloropropene
ND
ug/L
0.50
1
11/12/16 11:49
10061-01-5
trans-1,3-Dichloropropene
ND
-ug/L
0.50
1
11/12/16 11:49
10061-02-6'
Diisopropyl ether
ND'
ug/L
'0.50
1
11/12/16 11:49
108-20-3
Ethylbenzene d
AD
ug/L
0.50
1
11/12/16 11:49
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/12/16 11:49
87-68-3
Isopropyl benzene (Cumene)
ND
ug/L
0.50
1
11/12/16 11:49
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/12/16 11:49
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/12/16 11:49
1634-04-4
Naphthalene
-ND
ug/L
2.0
1
11/12/16 11:49
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/12/16 11:49
103-65-1
Styrene
ND
ug/L
0.50
1
11/12/16 11:49
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/12/16 11:49
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11112/1611:49
79-34-5
Tetrachloroethene
ND
ug/L
0.50
1
11/12/16 11:49
127-18-4
REPORT
OF LABORATORY ANALYSIS
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Date: 11 /18/2016 10:59 AM
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of Pace Analytical Services, LLC.
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2225 Riverside Dr.
Asheville, NC.28804
[phone]
Project: Clement Pappas
Pace Project No.: 92319070
Sample: Trip Blank
Lab ID: 9231.9070007 Collected: 11/09/16 00:00
Received: 11/09/16 14:30 Matrix: Water
Parameters
Results
Units
Report Limit
DF
Prepared Analyzed
CAS No. Qual
6200B MSV
Analytical Method:
SM 6200B
Toluene
ND
ug/L
0.50
1
11/12/16 11:49
108-88-3
1,2,3-Trichlorobenzene
ND
ug/L
2.0
1
11/12/16 11:49
87-61-6
1,2,47Trichlorobenzene
ND
.ug/L
2.0
1
11/12/16 11:49
120-82-1
1,1,1-Trichloroethane
ND
ug/L
0.50
1
11/12/16 11:49
71-55-6
1,1,2-Trichloroethane
ND
ug/L
0.50
1
11/12/16 11:49
79-00-5
Trichloroethene
ND
ug/L
0..50
1
11/12/16 11:49
- 79-01-6.
Trichlorofluoromethane
ND
ug/L
1.0
1
11/12/16 11:49'
75-69-4
1,2,3-Trichloropropane
ND
ug/L
0.50
1
11/12/16 11:49
96-18-4 .
1,2,4-Trimethylbenzene
ND
ug/L
0.50
1
11/12/16 11:49
95-63-6
1,3,5-Trimethylbenzene
ND
ug/L
0.50
1
11/12/1611:49
108-67-8
Vinyl chloride
ND
ug/L
1.0-
1
11/12/16 11:49
75-01-4
m&p-Xylene
ND
ug/L
1.0
1
11/12/16 11:49
179601-23-1
o-Xylene
ND -
ug/L .:
0.50
1 ..
11/12/16 11:49
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
90
%
70-130
1
11/12/16 11:49
17060-07-0
4-Bromofluorobenzene (S)
94
%
70-130
1
11/12/16 11:49
460-00-4
Toluene-d8 (S)
1010
%
707130
1
11/12/16 11:40
2037-26-5
REPORT OF LABORATORY ANALYSIS
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Project: Clement Pappas
Pace Project No.: 92319070
QC Batch: 336667
QC Batch Method: SM 6200B
QUALITY CONTROL DATA
Analysis Method: SM 6200B
Analysis Description: 6200B MSV
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006, 92319070007
METHOD BLANK: 1866910
Matrix: Water
Associated Lab Samples: . 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006, 92319070007
Parameter
Units
Blank
Result
Reporting
Limit
Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
0.50
11/12/16 09:34
1,1,1-Trichloroethane
ug/L
ND
0.50
11/12/16 09:34
1,1,2,2-Tetrachloroethane
ug/L
ND
0.50
11/12/16 09:34
1,1,2-Trichloroethane
ug/L.
ND
0.50
11/12/16 09:34
1,1-Dichloroethane
ug/L
ND
0.50
11/12/16 09:34
1,1-Dichloroethene
ug/L
ND
0.50
11/12/16 09:34
1,1-Dichloropropene
ug/L
ND
0.50
11/12/16 09:34
1,2,3-Trichlorobenzene
ug/L
ND
2.0
11/12/16 09:34
1,2,3-Tdchloropropane
ug/L
ND
0.50
11/12/16 09:34
1,2,4-Trichlorobenzene
ug/L
ND
2.0
11/12/16 09:34
1,2,4-Trimethylbenzene
ug/L
ND
0.50
11/12/16 09:34
1,2-Dibromo-3-chloropropane
ug/L
ND
1.0
11/12/16 09:34
1,2-Dibromoethane (EDB)
ug/L
ND
0-50
11/12/16 09:34
1,2-Dichlorobenzene
ug/L
ND
0.50
11/12/16 09:34
1,2-Dichloroethane
ug/L
ND
0.50
11/12/16 09:34
1,2-Dichloropropane
ug/L
ND
0.50
11/12/16 09:34
1,3,5-Trimethylbenzene
ug/L
ND
0.50
11/12/16 09:34
1,3-Dichlorobenzene
ug/L
ND
0.50
11/12/16 09:34
1,3-Dichloropropane
ug/L
ND
0.50
11/12/16 09:34
1,4-Dichlorobenzene
ug/L
ND
0.50
11/12/16 09:34
2,2-Dichloropropane
ug/L
ND
0.50
11/12/16 09:34
2-Chlorotoluene
ug/L
ND
0.50
11/12/16 09:34
4-Chlorotoluene
ug/L
ND
0.50
11/12/16 09:34
Benzene
ug/L
ND
0.50
11/12/16 09:34
Bromobenzene
ug/L
ND
0.50
11/12/16 09:34
Bromochloromethane
ug/L
ND
0.50
11/12/16 09:34
Bromodichloromethane
ug/L
ND
0.50
11/12/16 09:34
Bromoform
ug/L
ND
0.50
11/12/16 09:34
Bromomethane
ug/L
ND
5:0
11/12/16 09:34
Carbon tetrachloride
ug/L
ND
0.50
11/12/16 09:34
Chlorobenzene
ug/L
ND
0.50
11/12/16 09:34
Chloroethane
ug/L
ND
1.0
11/12/16 09:34
Chloroform
ug/L
ND
0.50
11/12/16 09:34
Chloromethane
ug/L
ND
1.0
11/12/16 09:34
cis-1,2-Dichloroethene
ug/L
ND
0.50
11/12/16 09:34
cis-1,3-Dichloropropene
ug/L
ND
0.50
11/12/16 09:34
Dibromochloromethane
ug/L
ND
0.50
11/12/16 09:34
Dibromomethane
ug/L
ND
0.50
11/12/16 09:34
Dichlorodifluoromethane
ug/L
ND
0.50
11/12/16 09:34
Diisopropyl ether
ug/L
ND
0.50
11/12/16 09:34
Ethylbenzene
ug/L
ND
0.50
11/12/16 09:34
Results presented on this page are in the units_ indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 37

�?ceAnaiyficq(
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i
QUALITY CONTROL DATA
Project: Clement Pappas
Pace Project No.: 92319070
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
METHOD BLANK: 1866910
Matrix: Water
Associated Lab Samples: 92319070001, 92319070002, 92319070003,
92319070004, 92319070005, 92319070006, 92319070007
Blank
Reporting
Parameter:
Units
Result
Limit
Analyzed
Qualifiers
Hexachloro-1,3-butadiene
ug/L
ND.
2.0
"11112/16 09:34
Isopropylbenzene (Cumene)
ug/L
ND"
0.50
11/12/16 09:34
m&p-Xylene
ug/L
ND
-1.0
11/12/16 09:34
Methyl -tent -butyl ether
ug/L
ND
0.50
11/12/16 09:34
Methylene Chloride
ug/L
ND
.
2.0
:11/12/16 09:34
n-Butylbenzene
ug/L
ND,
0.50
11/12/16 09:34
n-Propylbenzene
ug/L
ND
0.50
11/12/16 09:34
Naphthalene
ug/L
ND
2.0
11L12/16 09:34
o-Xylene
ug/L •
ND
0.50
.11/12/16 09:34
sec-Butylbenzene
ug/L
ND.
-
0.50
11/12/16 09:34
Styrene
ug/L
ND:
0.50
11/12/16 09:34
tert-Butylbenzene .
ug/L
ND
0150
11/12/16 09:34
Tetrachloroethene
ug/L
ND
0.50
11/12/16 09:34 .
Toluene
ug/L: ' .
ND
0.50
" 11/12/16 09:34
trans-1,2-Dichloroethene
ug%L
ND
0.50
11/12/16 09:34
trans-1,3-Dichlor6propene
ug/L
ND
0.50
11%12/16 09:34
Trichloroethene
ug/L
ND
0.50
11/12/16 09:34
Trichlorofluoromethane.
ug/L
ND
1.0
11/12/16 09:34
Vinyl chloride
ug/L
ND
1.0
11/12/16 09:34
1,27Diichloroethane d4 (S) -
%
89`
70-130
11/12/16 09:34
4-Bromofluorobenzene (S)
%
96
70-130
11/12/16 09:34
Toluene-d8 (S)
%
99
70-130
11/12/16 09:34
f
LABORATORY CONTROL SAMPLE:
1866911
Spike "
LCS
LCS ' % Rec "
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
47.8
96
60-140
1,1,1-Trichloroethane
ug/L
50
46.5
93
60-140
1,1,2,2-Tetrachloroethane .
ug/L
50
46.0
92
60-140
1,1,2-Trichloroethane
ug/L
50
44.5
89
60-140
1,1-Dichloroethane
ug/L
50
47.2
94
60-140
1,1-Dichloroethene_"
ug/L
50
53.4.
107"
60-140
1,1-Dichloropropene
:Ug/L
50
47.5
95
60-140
1,2,3-Trichoorobenzene
ug/L
50
56.4
113
60-140
1,2,3-Trichloropropane
ug/L
50
43.3
87
60-146
1,2,4-:Trichlorobenzene
ug/L
50
54.1
108
60-140
1,2,4Trimethylbenzene
ug/L
50
49.4
99
60A40
1,2-Dibromo-3-chloropropane
ug/L
50
45.4
91
60-140
13-Dibromoethane (EDB).
ug/L
50
47.3
95
60-140
1,2-Dichlorobenzene ,
ug/L
50
51.2
102
60-140
1,2-Dichloroethane
ug/L
50.
40.1
80
60-140
1,2-Dichloropropane
ug/L
50
45.5
91
60-140
1,3,5-Trimethylbenzene
ug/L
50
48.5
97
60-140
1,3-Dichlorobenzene
ug/L
50
49.7
99
60-140
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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te: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services,. LLC.
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QUALITY CONTROL DATA
Project: Clement Pappas
Pace Project No.: 92319070
LABORATORY CONTROL SAMPLE:
1866911
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
1,3-Dichloropropane
ug/L
50
44.8
90
60-140
1,4-Dichlorobenzene
ug/L
50
48.1
96 ..
60-140
2,2-Dichloropropane
ug/L
50
38.3
77
60-140
2-Chlorotoluene
ug/L
50.
47.2
94
60-140
4-Chlorotoluene
ug/L
50
46.6
93
60-140
Benzene
ug/L
50
49.5
99
60-140
Bromobenzene
ug/L
50
46.8
94.
60-140
Bromochloromethane
ug/L
50
46.7
93
60-140
Bromodichloromethane
ug/L
50
46.6
93
60-140
Bromoform-
ug/L
50
45.5
91
60-140
Bromomethane
ug/L
50
40.0
80
60-140
Carbon tetrachloride
ug/L
50.
49.5
99-
.60-140
Chlorobenzene
ug/L
50
46.4
93
60-140
Chloroethane
ug/L
50
45.4
91
60-140
Chloroform
ug/L
50
44.9
90
60-140
Chloromethane
ug/L
50
52.2
104
60140
cis-1,2-Dichloroethene
ug/L
50
46.4
93
60-140
cisA,3-Dichloropropene
ug/L
50
44.2
88
60-140
Dibromochloromethane
ug/L
50
47.9
96
60-140
Dibromomethane
ug/L.
50
44.9
90
60-140
Dichlorodifluoromethane
ug/L
50
53.1
106
60-140
Diisopropyl ether
ug/L
50
- 50.9
-102
60-140
Ethylbenzene
ug/L
50
48.2
96
60-140
Hexachloro-1,3-butadiene
ug/L
50
51.2
102
60-140
Isopropylbenzene (Cumene)
ug/L
50
48.9
98
60-140'
m&p-Xylene
ug/L
100
95.6
96
60-140
Methyl-tert-butyl ether
ug/L
50
48.6'
.97
60-140
Methylene Chloride
ug/L
50
53.3
107
60-140
n-Butylbenzene
ug/L
50
50.0
100
60-140
n-Propylbenzene
ug/L
50
48.9 . ;
98.
60-140
Naphthalene
ug/L
50
53.0
106
60-140
o-Xylene
ug/L
50
46.9
94
60-140
sec-Butylbenzene
ug/L
50
50.6
101
60-140
Styrene
ug/L
50
48.4
97
60-140
tert-Butyl benzene
ug/L
50
43.0
86
.60-140
Tetrachloroethene
ug/L
50
41.2
82
60-140
Toluene
ug/L
50
45.7
91
60-140
trans-1,2-Dichloroethene
ug/L
50
50.2
100
60-140
trans-1,3-Dichloropropene
ug/L
50
43.2
86
60-140
Trichloroethene
ug/L
50
46.3
93
60-140
Trichlorofluoromethane
ug/L
50
48.0
96
60-140
Vinyl chloride
ug/L
50
45.7
91
60-140
1,2-Dichloroethane-d4 (S)
%
89
70-130
4-Bromofluorobenzene (S)
%
98
70-130
Toluene-d8 (S)
%
96
70-130
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right 'of the result.
Date: 11 /1812016 10:59 AM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Clement Pappas
Pace Project No.: 92319070
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1866912
1866913
MS
MSD
92319070006
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units .
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual:'
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
20.2
19.9
101
100
60-140•
1
1,1,1-Trichloroetharie
ug/L
ND
20
20
19.9
19.7
99
98
60-140
1
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
19.5
19.6
98
98
60-140
0
1,1,2-Trichloroethane
ug/L
ND
20
20
19.6
19.3
98
97
60-140
1
1,1-Dichloroethane
ug/L
ND
20
20
20.0
19.9
100
100
60-140
0
1,1-Dichloroethene
ug/L
ND
20
20
21.4
21.8
107
109
60-140
2
1,1-Dichloropropene
ug/L
ND
20
20
20.2
20.7
101
103
60-140
2
1,2,3-Trichlorobenzene
ug/L
ND.
20
20
21.8
20.8
109
104
60-140
5
1,2,3-Trichloropropane
ug/L
ND
20
20
18.6
18.1
93
90
60-140
3
1,2,4-Trichlorobenzene',
ug/L
ND
20
20
20.9
20.4
104
102
60-140
2
1,2,4-Trimethylbenzene
ug/L
ND
20
20
20.5
20.8
103
104
60-140
1
1,2=Dibromo-3-chloropropane
ug/L
ND
20
20
18.7
18.7
94:
94
60-140
-0
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
19.9
19.3
100
97
60-140
3
1,2-Dichlorobenzene
ug/L
ND
20
20
21.1
21.2
105
106
60-140
1
1,2-Dichl6roethane
ug/L
ND
20
20
17.0
17.1
84
85
60-140
0
1,2-Dichloropropane
ug/L
ND
20
- 20
19.6
19.5
98.
98
60-140
0
1,3,5-Trimethylbenzene
ug/L
ND '
20
20
20.7
20.7
104
104
60-140
0
1,3-Dichlorobenzene
ug/L
ND
20
20
20.6
20.7
103
103
60-140
0
1,3-Dichloropropane
ug/L
ND
20
20
19.0
18.9
95
95
60-140
0
1,4-Dichlorobenzene
ug/L
ND
20
20
20.0
20.0
100
100
60-140
0
2,2-Dichloropropane
ug/L :
ND
20
20
16.2
15.8
81
79
60-140
2
2-Chlorotoluene
ug/L
ND
20.
20
20.5
20.7
103
104
60-140
1
4-Chlorotoluene
ug/L
ND
20
20
19.8
20.0
99
100
60-140
1
Benzene
ug/L
ND
20
20
20.8
20.7
104
103
60-140
1
Bromobenzene
ug/L
ND
20
20
20.2
20.1
101
100
60-140
0
Bromochloromethane
ug/L
ND
20
20
19.9
20.1
100
101
60-140
1
Bromodichloromethane
ug/L
ND
20
20
20.0
19.7
100
98
60-140
1
Bromoform.
ug/L
ND
20
20
18.5
18.0
93
90
60-140
3
Bromomethane
ug/L
ND
20
20
15.8
14.8
79
74
60-140
6
Carbon tetrachloride
ug/L
ND
20
20
21.2
21.5
106 .
107
60-140
1
Chlorobenzene
ug/L
ND
20
20
19.8
19.7
99
98
60-140
1
Chloroethane
ug/L
ND
20
20
15.8
16.5
79
82
60-140
4
Chloroform
ug/L
ND
20
20
19.4
19.3
97
97
60-140
0
Chloromethane
ug/L
ND
20
20
14.3
13.7
71
69
60A40
4
cis-1,2-Dichloroethene
ug/L
ND
20
20
19.6
19:8
98
99
60-140
1
cis-1,3-Dichloropropene
ug/L
ND
20
20
18.5
18.7
93
94
60-140
1
Dibromochloromethane
ug/L
ND
20
20
20.1
19.6
100
98
60-140
2
Dibromomethane
ug/L
ND
20
20
18.9
19.1
95
96
60-140
1 .
Diclfiorodifluoromethane
ug/L
ND
20
20
8.3
7.9
41
40
60-140
5 M1
Diisopropyl ether
ug/L
ND
20
20
21.2
21.3
106
107
60-140
0
E'.hylbenzene
ug/L
ND
20
20
20.8
20.6
104
103
60-140
1
Flexachloro-1,3-butadiene
ug/L
ND
20
20
19.6
18.7
98
94
60-140
4
isopropylbenzene (Cumene)
ug/L
ND
20
20
21.1
20.9
105
104
60-140
1
m&p-Xylene
ug/L
ND
40
40
41.1
40.8
103
102
60-140
1
M4thyl-tert-butyl ether
ug/L
ND
20
20
19.8
19.9
99
99
60-140
0
Methylene Chloride
ug/L
ND
20
20
20.5
20.7
103
104
60-140
1
Results presented on this
page are in
the units indicated
by the
"Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
ate: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, L-C. Page 22 of 37

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QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Clement Pappas
Pace Project No.: 92319070
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1866912
1866913
MS
MSD
92319070006
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
n-Butylbenzene
ug/L
ND
20
20
20.1
19.8
101
99
60-140
2
n-Propylbenzene
ug/L
ND
20
20
21.1
21.3.
106
106
60-140
1
Naphthalene
ug/L
ND
20
20
21.2
20.5
106
103
60-140
3
o-Xylene
ug/L
ND
20
20
20.0
20.2
100
101
60-140
1
sec-Butylbenzene
ug/L
ND
20
20
20.9
20.8
104
104
60-140
0
Styrene
ug/L
ND
20
20
20.2
20.0
101
100
60-140
1
tert-Butyl benzene
ug/L
ND
20
20
18.5
18.2
92
91
60-140
1
Tetrachloroethene
ug/L
ND
20
20
17.3
17.4
86
87
60-140
1
Toluene
ug/L
ND
20
20
20.0
20.0
100
100
60-140
0
trans-1,2-Dichloroethene
ug/L
ND
20
20
21.1
20.8
106
104
60-140
2
trans-1,3-Dichloropropene
ug/L
ND
20
20
18.3
17.8
92
89
60-140
3
Trichloroethene
ug/L
ND
20
20
19.6
19.8
98
99
60-140
1
Trichlorofluoromethane
ug/L
ND
20
20
19.0
19.4
95
97
60-140
2
Vinyl chloride
ug/L
ND
20
20
13.8
13.8
69
69
60-140
0
1,2-Dichloroethane-d4 (S)
%
91
91
70-130
4-Bromofluorobenzene (S)
%
101
99
70-130
Toluene-d8 (S)
%
99
100
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Clement Pappas
Pace Project No.: 92319070
QC Batch: 336499 Analysis Method: SM 2540C
QC Batch Method:. SM 2540C Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006
METHOD BLANK: 1865998 Matrix: Water
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids. mg/L ND 25.0 11/11/16 14:32
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 1865999
Spike LCS LCS % Rec
Parameter. Units Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 264 106 90-110
SAMPLE DUPLICATE: 1866000
92318780051 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 183 191 4
SAMPLE DUPLICATE: 1866001
92319148004 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids rrig/L 1950 1460 29 D6.
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Clement Pappas
Pace Project No.: 92319070
QC Batch: 336424 Analysis Method: SM 9222D
QC Batch Method: SM 9222D Analysis Description: 9222D MBIO Fecal Coliform -AVL
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006
METHOD BLANK: 1865520 Matrix: Water
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Coliforms CFU/100 mL ND 1.0 11/09/16 15:39
SAMPLE DUPLICATE: 1865521
Parameter Units
Fecal Coliforms CFU/100 mL
92319070005 Dup
Result Result
ND ND
RPD . Qualifiers
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC.
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Z�;a'ceftlXicalo
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Clement Pappas
Pace Project No.: 92319070
QC Batch: 337277
Analysis Method: EPA 350.1 1993 Rev 2.0
QC Batch Method: EPA 350.1 1993 Rev 2.0
Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92319070001, 92319070002,
92319070003, 92319070004, 92319070005, 92319070006
METHOD BLANK: 1870478
Matrix: Water
Associated Lab Samples: 92399070001, 92319070002,
92319070003, 92319070004, 92319070005, 92319070006
Blank Reporting
Parameter Units
Result Limit Analyzed. Qualifiers
Nitrogen, Ammonia mg/L
ND 0.10, 11/17/16 07:32
.LABORATORY CONTROL SAMPLE:-1870479
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/L -
5 4.9 99 90-1.10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1870480 1870481
MS MSD
92319652001
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec
Limits RPD Qual:
Nitrogen, Ammonia mg/L ND
5 5 5.2 5.2 103 104
90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1870482 1870483
MS MSD
92318818002
Spike Spike MS MSD MS MSD
% Rec
Parameter Units . Result
Conc. Conc. Result Result % Rec % Rec
Limits RPD Qual
Nitrogen, Ammonia mg/L 13.1
5 5 19.7 19.2 132 121
90-110 3 M1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
.[phone]
Project:' Clement Pappas
Pace Project No.: 92319070
QC Batch: 336471
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92319070001, 92319070002,
92319070003, 92319070004, 92319070005, 92319070006
METHOD BLANK: 1865760
Matrix: Water
Associated Lab Samples: . 92319070001, 92319070002,
9231907Q003, 92319070004; 92319070005, 92319070006
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L
ND 0.020 11/10/16 23:45
LABORATORY CONTROL SAMPLE: 1865761
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
2.5 2.6 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1865762 1865763
MS MSD
92319070005
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec
Limits RPD Qua]
Nitrogen, Nitrate mg/L 14.3
2.5 2.5 17.3 17.5 120 126
90-110 1 M6
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1866056 1866057
MS MSD
92319338008
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec
Limits RPD Qua[
Nitrogen, Nitrate mg/L ND
2.5 2.5 2.3 2.3 91 91
90-110 1
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Page 27 of 37

Pace Analytical Services, LLC
�;a'cemayical' 2225 Riverside 0
Asheville, NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Clement Pappas
Pace Project No.: 92319070
QC Batch: 336486 Analysis Method: EPA 365.1
QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004
METHOD, BLANK: 1865898 Matrix: Water
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004
Blank Reporting
Parameter Units Result Limit Analyzed qQualifiers,
Phosphorus mg/L ND 0.050 11/11/16 22:46
LABORATORY CONTROL SAMPLE:
1865899
'
Spike
LCS
LCS
% Rec
Parameter
Units '
Conc.
Result
% Rec
Limits'
Qualifiers
Phosphorus
mg/L
2.5
2.5
99
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1865900.
1865901
MS
MSD
92318583001_
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter ..
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
Phosphorus
mg/L 20.6
2.5
2.5
24.5
23.9
155
132
90-110
2 M1
MATRIX SPIKE & MATRIX SPIKE -DUPLICATE: 1865902
1865903
MS
MSD
.92318901001
Spike
Spike
. MS
MSD
MS
MSD
% Rec
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
Phosphorus
mg/L 0.72
2.5
2.5
3.3
3.3
103
103
90-110
0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Qual
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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Project: Clement Pappas
Pace Project No.: 92319070
QC Batch: 336488
QC Batch Method: EPA 365.1
Associated Lab Samples: 92319070005, 92319070006
METHOD BLANK: 1865913
Associated Lab Samples: 92319070005, 92319070006
Parameter Units
Phosphorus mg/L
QUALITY CONTROL DATA
Analysis Method:
Analysis Description
EPA 365.1
365.1 Phosphorus, Total
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.050 11/11/16 23:09
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 1865914
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.5 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1865915 1865916
MS MSD
92319070005 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua]
Phosphorus mg/L 0.26 2.5 2.5 2.8 2.8 103 103 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1865917 1865918
MS MSD
92319199003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua]
Phosphorus mg/L .1.8 2.5 2.5 4.3 4.4 103 103 90-110 0
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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;aceArialXicaI
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QUALITY CONTROL DATA
Project: Clement Pappas
Pace Project No.: 92319070
QC Batch: 337161 Analysis Method: SM 4500-CI-E
QC Batch Method:. SM 4500-CI-E Analysis Description: 4500 Chloride
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006
METHOD BLANK: 1869588 Matrix: Water
Associated Lab Samples: 92319070001, 92319070002; 92319070003, 92319070004, 92319070005, 92319070006
Blank Reporting.
Parameter Units _ Result Limit . Analyzed Qualifiers
Chloride mg/IL ND 1.0 11/17/1616:59
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 1869589
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chloride mg/L 20 20.9 104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1869590 • 1869591
MS MSD
92319070001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 12.2 '10 .10 22.9 22.9 107 107 90-110 . 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1869592 1869593
MS MSD _
92318783003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua]
Chloride mg/L 1.1 10 10 12.3 12.3 112 112 90-110 0 M1
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC .
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Clement Pappas
Pace Project No.: 92319070
QC Batch: 337165 Analysis Method: SM 5310B
QC Batch Method: SM 5310B Analysis Description: 5310E TOC
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006
METHOD BLANK: 1869646 Matrix: Water
Associated Lab Samples: 92319070001, 92319070002, 92319070003, 92319070004, 92319070005, 92319070006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 11/17/16 10:29
LABORATORY CONTROL SAMPLE: 1869647
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Organic Carbon mg/L 25 23.1 92 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1869648 1869649
MS MSD
92319070001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 4.3 25 25 27.3 27.6 92 93 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1869650 1869651
MS MSD
92319496009 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 0.56J 25 25 24.7 24.7 96 96 90-110 , 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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. QUALIFIERS
Project: Clement Pappas
Pace Project No.: 92319070
DEFINITIONS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND -.Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to, and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have.been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP -,Sample Duplicate, .
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica GeV- Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the .analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes. and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for.the current list of accredited analytes.
TNI -The NELAC Institute. .
LABORATORIES .
PASI-A Pace Analytical Services - Asheville
PASI-C Pace,Analytical Services - Charlotte
ANALYTE QUALIFIERS
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Clement Pappas
Pace Project No.: 92319070
Lab ID Sample ID QC Batch Method QC Batch
92319070001
MW-4
SM 6200B
336667
92319070002
MW-5
SM 6200B
336667
92319070003
MW-6
SM 6200B
336667
92319070004
MW-7R
SM 6200B
336667
92319070005
MW-8
SM 6200B
336667
92319070006
MW-9
SM 6200B
336667
92319070007
Trip Blank
SM 6200B
336667
92319070001
MW-4
SM 2540C
336499
92319070002
MW-5
SM 2540C
336499
92319070003
MW-6
SM 2540C
336499
92319070004
MW-7R
SM 2540C
336499
92319070005
MW-8
SM 2540C
336499
92319070006
MW-9
SM 2540C
336499
92319070001
MW-4
SM 9222D
336424
92319070002
MW-5
SM 9222D
336424
92319070003
MW-6
SM 9222D
336424
92319070004
MW-7R
SM 9222D
336424
92319070005
MW-8
SM 9222D
336424
92319070006
MW-9
SM 9222D
336424
92319070001
MW-4
EPA 350.1 1993
Rev 2.0
337277
92319070002
MW-5
EPA 350.1 1993
Rev 2.0
337277
92319070003
MW-6
EPA 350.1 1993
Rev 2.0
337277
92319070004
MW-7R
EPA 350.1 1993
Rev 2.0
337277
92319070006
MW-8
EPA 350.1 1993
Rev 2.0
337277
92319070006
MW-9
EPA 350.1 1993
Rev 2.0
337277
92319070001
MW-4
EPA 353.2
336471
92319070002
MW-5
EPA 353.2
336471
92319070003
MW-6
EPA 353.2
336471
92319070004
MW-7R
EPA 353.2
336471
92319070005
MW-8
EPA 353.2
336471
92319070006
MW-9
EPA 353.2
336471
92319070001
MW-4
EPA 365.1
336486
92319070002
MW-5
EPA 365.1
336486
92319070003
MW-6
EPA 365.1
336486
92319070004
MW-7R
EPA 365.1
336486
92319070005
MW-8
EPA 365.1
336488
92319070006
MW-9
EPA 365.1
336488
92319070001
MW-4
SM 4500-CI-E
337161
92319070002
MW-5
SM 4500-CI-E
337161
92319070003
MW-6
SM 4500-CI-E
337161
92319070004
MW-7R
SM 4500-CI-E
337161
92319070005
MW-8
SM 4500-CI-E
337161
92319070006
MW-9
SM 4500-CI-E
337161
92319070001
MW-4
SM 53106
337165
92319070002
MW-5
SM 5310B
337165
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/18/2016 10:59 AM without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Analytical Method
Analytical
Batch
Page 33 of 37

aceAnalytical
www.pacelabs.com
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project:
Clement Pappas
Pace Project No.:
92319070
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method Batch
92319070003
MW-6
SM 5310B
337165
92319070004
MW-7R -
SM 5310B
337165
92319070005
MW-8
SM 5310B
337165
92319070006
MW-9
SM 5310B
337165
Date: 11 /18/2016 10:59 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, I.I.C.
Page 34 of 37

Document Name:
Document Revised: Sept. 21, 2016
o
aceAnalytical
Sample Condition Upon Receipt(SCUR) -
Page 1 of 2
Authority:
___,,
Document No.:
Issuing
/
F-CAR-CS-033-Rev.01
Pace Quality Office
Laboratory receiving sa > es:
Asheville4r Eden[—] Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑
Samlild 6 Client Name: Projec WO# : 92319070
i(ocelpt d 1�44— �
Courier: [-]Fed Ex ❑UPS ❑USPS [Client IIIII' II II'III I'III'II
❑ Commercial ❑Pace ❑Other: 92319070
Custody Seal Present? []Yes No Seals Intact? ❑Yes []No
Date/Initials Person Examining Contents:
Packing Material-. ❑Bubble Wrap ❑B le Bags ❑None ❑Other:
Thermometer•
IR Gun ID: Type of Ice: Wet [-]Blue❑None ❑Samples on ice, cooling process has begun
Correction Factor: Q 59oler Temp Corrected (°C): j. Q Biological Tissue Frozen? []Yes ❑No ❑N/A
Temp should be above free ng to 6°C
USDA Regulated Soil ( /A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (inte�ti n6 ally,
f-Ivo. r-lni., inrludine Hawaii and Puerto Ricol? MYes RNo
Comments/Discrepancy:
Chain of Custody Present?
Ye
[]No
❑N/A
1.
Samples Arrived within Hold Time?
+Ye;l
❑No
❑N/A
2.
Short Hold Time Analysis (02 hr.)?
0es
❑No
,❑N/A
3. (
T�ECC
Rush Turn Around Time Requested?
❑Yes , ❑ o
❑N/A
4.
Sufficient Volume?
es -
❑No
El N/A
5.
Correct Containers Used?
-Pace Containers Used?
21y.
Yes
[-]No❑N/A
[:]No
❑N/A
6.
Containers Intact?
es
❑No
❑ /A
7.
Samples Field Filtered?
[]Yes
[:]No
-❑N/A
8. Note if sediment is visible in the dissolved container
Sample Labels Match COC?
-includes Date/Time/ID/Analysis Matrix:
'' ••\\ es
[]No
❑N/A
9.
Headspace in VOA Vials (>5-6mm)?
❑Yes/
No
[]N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
�s
([Yes
❑No
[]No
❑N/A
El N/A
11.
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Sample
Discrepancy:
Project Manager SCURF Review:
Project Manager SRF Review:
Date/Time:
Date:
Date:
Field Data Required? UYes ,LJNo
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers)
Page 35 of 37

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CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
.............
Page:
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DATE
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SAMPLECONDITIONS
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ORIGINAL
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Well Sampling Log
PROJECT NAPJ,E:' r : . lyj .1?r fJr r I /'aGrli ', r� DATE: I I %s'r 6
.PROJECT NUMBER:, WEATHER:Sri; .11d�1^ �ff:rr;'
SAMPLING PERSONNEL: . tlsue r' SAMPLETIME:
WELL NUMBER; jr� llt�t �t
WELL DIAMETE R:
TYPE OF CASING: 19 f/c.
MEASURING P01
FLUSH MOUNT/ TICK U
COMMENTS.(L4VC)
WELL DEPTH IN FEET (L41D):_(ri 60
WATER LEVELIN FEyf (WL):
LENGTH OF WATER COLUPAN : �/ FEE;
(WD) -(WL) c Plic)
ONE CASING VOLUME: 1. S z GALLONS
x (WCV)
THREECASING V'OLUMEs:: GALLONS
ACTUAL VOLUME PURGED:GALLONS
WELL CASING VOLUMES (WCV)
f ® 0.041;Go t : 2- = 0 1> Gal/Ft 3' - 0.38 Gal/Ft V = ©.66 GOVIP. 6" - 1.5 Gal/Ft 8' a 2.6 GaVFt
12" a 5.8 Gal/Ft
PURGE METHOD: AILER-DIV:
BAILER-TEFLON DEDICATED
PUMP INHALE PUMP GRUNDFOS OTHER:
SAMPLE METHOC' PAILER- (SP. ,BAILER-TEFLON DEDICATED
PUMP WHALE PUMP•
GRUNDFOS OTHER:
READING
TIME
ONS
PURGED
TEMP
('C)
SPECIFIC
COND,
(IDS/cm)
DISSOLVED
OXYGEN
(mg/0
pH
IS.U,)
report to
O'l S.U.
OXIDATION
REDUCTION
POTENTIAL
(Mv)
TURBIDITY
(NTUy
G4MMENTS
1iz�t�
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5
7
8,
a
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SAMPLING CONTAINER
NUMBER OF CONTAINERS
REQUESTED ANALYSIS
500 mL PLASTIC
250 mL PLASTIC
125 inL PLASTIC
40 mL GLASS .
1 L GLASS
OTHER
PROTECTIVECASIh1G: ��f PAD; G/ff LOCK:
VEGETATIOt`fi ACCESS: �lr_
Sampling Personnel Slgnature:
, it -
--- Dater. + �V19
Notes: 'C- degree&Celsius
VS/,cm m q-�cioSiemen Per centimeter
rng/L rnliiijrams per IAA
S:U_ = S;eric(ara Uriits
M%f - rnillhroIt
NTU = ii©Pliefoinetric turb:dity_units .
Samples or* analyzeJ immedlat-ply upon collectlon',
`XcmpiatcskGvv 6411169 Forrns',Well Sampling Lag-xls Page 1 of 9
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PROJECT NAME:_,rM04n - {-r »rs , L rv+;+ur,`n.
PROJECT NUMBER: (
SAMPLING PERSONNEL:. z7lgr . i
DATE: {�
W€ATF(ER:
S.AMPLETIME: I l 15
WELL NUMBER; �� i.tr _ �-
WELL DIAMETER:
TYPE OF CASI NG: (>(/C
.MEASURING POINT: ._'700
FLUSH MOUNT / CK-
COMMENTS:
WELL DEPTH IN FEET (W7 �" O
WATER LEVEL;N FEET tWL): I'..
LENGTH OF WINTER COLUMN: 1:5
(WD) - (WI-) = (L'dVC) t _
ONE CASING VOLUME: ! •5
(LWC) K (WCV) —7
THREE CASING VOLUMES: }. ! �
ACTUAL VOLUME PURGED: r "3. 7 5"—
FEEL•
GALLONS
GALLONS
GALLONS
WELL CASING VOLUMES (WCV)
3" - 0.33 (3ar/F t 4• - 0,a6 GaVFt o" - 1.5 GalVFt 8" = 2.6 GaljFt .
12" = 5.8 val/ft
PURGE METHOD: AILER-Dl P: I SAILER TEFLON DEDICATED PUMP YNHALE.PUMP GRUNDFOS OTHER:
SANIPLEn METHOD: ILER•D SAILER-TEFLDN DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER:
READING
TIME
GALLONS
PURGED
TEMP
(°.C)
SPECIFIC
COND.
(IaS/cm)
DISSOLVED
OXYGEN
(mg/L)
pH
is.U.)
report to
0.1S.U.
OXIDATION'
REDUCTION
POTENTIAL
(rnv)
TURBIDITY
;NTUI
COMMENTS
1
-
VI
,
4
.50
k-I 7��
5
6
1
8
9
10
SAMPLING CONTAINER
NUMBER OF CONTAINERS
REQUESTED AN LYSIS.
.500 mL PLASTIC
250 mL PLASTIC
125 mL PLASTIC '
4O mL GLASS
I
:1. L GLASS
_
OTHER
PROTECTIVE CASING: f) }� PAD;- Pir' LOCK: G'Irt VEGETATION: T k ACCESS: _
Sampling Personnel Signature: ff>1 L�L-
Date:
IVetes: °C=deEreesCelsius
PS/cm = mivrc-Sismen por centimeter
mg/L= rmlllgrams per IILer
S.U. = St;mdaid Units_
rnV = millivolt
NTLI nephelometrla Ulrbldi-,y units
Samples are analyzed Immediately t pon collection,
P:1,TemPlatcs1,GW Drilling F0rmisl4`Iell Sampling Log -As Page 1 of 1

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Well Sampling Log
PROJECT NAME: Cj2M?6 r" tM., S
PROJECT NUMBER: ? cfl C/
SAMPLING PERSONNEL; . ;1 Su . ..
DATE:
WEATHER: '5, Ulii r
SAMPLE TIME: 1 72OCI
WELL NUMBER: y✓-
WELL DIAMETER:
TYPE OF CASING: r1/C
MEASURING POINT—'- rti,
FLUSH FOUNT/ P`ICK"�UP i
COMMENTS: `—� >�ryj ei j dt,/
Q-Gtl(frs . t ufR'fr tir�Cll lci
Cul.{Oc*r,J I
oNer-
L9CI+wruc� 41n
WELL DEPTH IN FEET (WDY U_
WATER LEVEL I N FEET (VJL): J, Lf ':Z
LENGTH OF WATER COLUMN: L/, f 3 FEET
(WD)-- (WL) = (LYJC)
ONE CASING VOLUME;—( . �GT ' Z GALLONS
(LWC) x (WCV)
-THREECASINGVOLUMES: �()L GALLONS
ACTUALVOLUME'PURGED: ^^ ( C) GALLONS
WELL CASING VOLUMES (WCV)
1"=.0.041 GaUFt/ 2" ='0 1._] ,3aVFt 3' - C.33 Gal/Ft 4' = 0.66 GsVFt 6' = 1.5 GaVFt 3' = 2.6.Ga(/Ft
12" 6 5.8 GaVrt
PURGE METHOD; AILER•DISP BAILER TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER:
SAMPLE METHOD:
BAILER-DBAILER-TEFLON DEDICATED
PUMP WHALE PUMP GRUNDFOS OTHER:
READING
TIME
BALL-t6NS
PURGED
TEMP
(°C)
SPECIFIC
COND.
(PS/cm)
DISSOLVED
OXYGEN
(rng/L)
pH
(S.U.)
report to
0.1S.U.
OXIDATION
REDUCTION
POTENTIAL
(mV)
TURBIDITY
(NTU)
COMMENTS
Ir��o
17rcLr
17
^,s
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i�1.7�,
2
1I'�'f5—
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17. yr
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33.6
105.7
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e.
DUI%1�C�'i(r /Ip
5
7
8
9
-
10
SAMPLING CONTAINER
NUMBER OF CONTAINERS
REQUESTED ANALYSIS
500. mL PLASTIC
250 mL PLASTIC
125 mL PLASTIC
40 mL GLASS
1 LGLASS
OTHER
PROTECTIVE CASING: _ PAD: !'C
LOCK: K� VEGETATION; r a ACCESS: C
SamPIingPersonnel Signature:f'/fJ��\\ fF -''
Date:
.rJ
Notes: - 10=degia6s0;;l8lu5
Ns/cm = mr croSiernen per.centimeler
rnWL milligrams per liter
S,U. Stan-Jald Units
.mV F millivolt
NTU - nephelomet6c turbidity snits
San-jp:es,are aralyzed immediately upon collection.
P:tTcmpiatesi,GWI Drilling Formwall Sampling Leg,xis Pago 1 0l t

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Well Sampling Log
LPRGJECT NAME: N."11 vn.L I �? 'GuS / �! 1� �+��!' ` `�7 DP,TE: I
PROJECT NUIIIBER: — WEATHER: GJCT s . - r✓ T W;.� V
SAMPLING PERSONKEL: ? Sip.. SAMPLETIME: �w
WELL NUMBER: _
WELL DIAMETER: '�'�
TYPE OF C+r+SING: i? U• c
MEASURING POINT: -r rj'C
FLUSH MOUNT STI(f K.-GS
COMMENTS:
�i WELL DEPTH IN FEET (WD): I h'G
WATER LEVEL I1-1 FEET (wQ: I . d
LENGTH OF WATER COLUMN 7 7 FEET
(WD) - (N.rL) = (LWC)
ONE CASING VOLUME: 0, GALLONS
(LWC) x (WCV)
THREE CASING VOLUMES: , Li Y� GALLONS
ACTUAL VOLUME PURGED: " 5 GALLONS
WELL CASING VOLUMES (WCV)
1° - 0.041 Gal,�F . 2' = 0: 7 GaVI-'t 3" = 0.38 Gal/Ft 4" - 0.66 Gal/Ft 6' - 1.E Gal/FI 8" = 2.6 Gal/Ft
•
12" = 5,8 Gal/Ft
PURGE METHOD: BIER-DISP, BAILER-TEFLON DEDICATED PUMP WHALE•PUMP GRUNDFOS OTHER:
SAM?LE
JETHOD: AILED- SP. BAILER-TEFLON DEDICATED
PUMP WHALE PUMP GRUNDFOS OTHER:
READING
TIME
LONS'
PURGED
TEMP
{°C)
SPECIFIC
COND.
(NS/c►n)
DISSOLVED
OXYGEN
(mg/L)
PH
;S.U.)
reporr to
0..1 S. U.
OXIDATION
REDUCTION
POTENTIAL
(mV)
TURBIDITY
(NTU)
COMMENTS
(fit?
j ����'�r
5
SDI'
�•w
f%r �`
�13�r
2
iCJ
9. G
iG,PY
3=
�, ,�
5-&u
ISCr,
;�IfGO
K),
=' ?
` ,
. 2r
15k,
153 q�
7,
r.
B
9
10
SAIAPLJNG CONTAINER
NU [OBER OF CONTAINERS
REQUESTED ANALYSIS
500 mL PLASTIC
250 mL PLASTIC
125 rril, PLASTIC
40 mL GLASS
I L GLASS
OTHER
PROT=CTIVECASING: Q't PAD-- )' LOCK:-0 VEGETATION:Cl1' ACCESS: —C)r, s
Sampling Personnel Signature:
Date.,/ !`f
Natae: °C= degrees '_ISius
US/cm - IrL�eoSlemen per camlmet0
mg/L - milligrams per liter
S,J. = Sanderd Units
my = millivolt
NTU - nephalometdc turbidity ;nits
Samples are anaiyied Im7,edietely upon collaciian.
P:ITemplalos`)GIN brilling Formsh'Voll Sa6lpling Lag,xls Paget 1 of 1 ,

z $- -, ; It r ��G'+1� t ' M I i s' �''i Y �'"`r-14
. . rk. � .. .. .,� _.. . . . , _
23i,•H./Y'?JP't%.'TRFG"1',, 1/SFIEVILLE:.;N'G'.tiB.E.O1,-• .
'TL L�..e'a.$; •f9(t3?5¢, •F,AC: �2{3.20, 1. ::-3�¢�j'
• w yviv?gnj Trry y,191? tj ra r rk TAU, go A7.•,•,
Well Sampling Log
PROJECT NAME ,o , rr� ` A
PROJECT NUMBER; R-1
SAMPLING PER50N,NEL , AL p5kqj<BAMPLETIME;
DATE: I f t
WEATHER: Sd g ( ( e4 r
4 Y4,;•
WELL NUMBER: ��,/
WELL DIAMETER:
TYPE OF CASING; PV0
MEASURING-P4I
FLUSH MOUNT STILES -'UP
COMMENTS:
WELL DEPTH IN FEET (4UD)t E � • iIJ _
WATER LEVEL I N FEET {lNL): � I ! L�
LENGTH OF WATER COLUMN: FEET
(WO)- (WL) _ (00ve)
ONE CASING VOLUME: �. �JC � GALLONS
(L1lJC) x (iNCV)
THREE CASING VOLUMES; i 3�� GALLONS
ACTUALVOLUME PURGED: 1. s GALLONS
WELL CASING VOLUMES (vvcv)
Ge r t �" = G: ± GaII/rt 3' - 0.38.GaVI t d 4.66 Ga I/Ft 6' _ a Ga!/rt 8' = 2.G Gal/Ft
. i2" - 5,8 GaVFt
PURGEMEt'HOD; BAILER-DISP. B LE"R-TEFLON 'DEDICATED
PUMP 'AHALE.PUMP GRUNDFOS OTHER:
SAMPLE METHOD:
SAILER-DISP. LER-TEFLON DEDICATED
PUMP INHALEPUh-1P GRUNDFOS OTHER:
READING
TIME
-GALLGN9
PURGED
TEMP
('C)
SPECIFIC
COND,
(PS/cm)
DISSOLVED
OXYGEN
(md/L)
PH
is.U.)
report to
01: S u
OXIDATION
REDUCTION
POTENTIAL
(MV)
TURBIDITY
(N*
COMMENTS
2
; 3
Cl,.
itt 5
s
ZA5-
ft;,6
5`
5
6
7
8 .
9
10
SAMPLINGCONTAINERNUMBER
OF CONTAINERS
REQUESTED ANALYSIS
5CO mL PLASTIC.
J
250 mL PLASTIC
125 mL ELASTIC
40 mL GLASS
1 L GLASS �
OTHER
PROTECTIVECASING; Qh PAD; b(
LOCK: C% VEGETATION: jt ACCESS;
Samplrng Personnel Signature: �f'----'""
Date: � f Vf`��
Noes; °C = degrees .peWus
pslcm a micr"iemen par canUmeter
mg/L- milligrams per liter
5.0. = standard Un_ its
.n1v = nilliV61t.
NTU m lieyilelometria turbldky units
�Tples are aina . e� immedi toly,u do collactlon.
4'islGW Drilling rcdmswuall SsmP:ing Log.xls Page 1 of 1

e
—17
§Cr:.....i')F.:Ir$'t3',I.L.3 Fx
23! 11AYV-bPM STREET, AS'liILE. NI, 2E891
T ELSZES�. L 8-1.9.3 b FA c'r828.2E 1�a z UI
WWW.6 LTt{Cllory Tl'.NVINONFIENT Af.-CO><t
Well Sampling Log
PROJECTNAME: (4,s dA c
PROJECT NUMBER: Cie I
SAMPLING PERSONNEL
DATE: I�lf
WEATHER:
SAMPLETIME:
VJELLNUMBER: /VkL'/' —
WELL DIAMETER: `,"
TYPE OF CASING: PSG
MEASURING POINT _ (
FLUSH IVIOUNT�STICK-GP>
COMMENTS: '�` l��i�G t� �l?r It" ✓+Z.rll.
I
WELL DEPTH IN FEET(WD}:_
WATER LEVEL IN FEET (WLI:_C; S s
LENGTH OF WATER COLUMN ; It SS FEET
MID) -(WL) = (Chip)
ONECASING VOLUME: y GALLONS
(LWGI x (WCV)
THREE CASING VOLUMES: I GALLONS
ACTUAL VOLUME PURGED: `'� 125 GALLONS
ti WELL CASING VOLUMES (WCV)
1' = 0.04i Gal// '2' - O.i7 al/Ft 3' = 0.38 Gal/Ft d" - 0,66 GaI%Fc 6" - 1.5 Gal/Ft 8" ©2.6: a I/Ft
<_2' m 5.8 G0 t
PURGE METHOD: BAILER -DI S . EAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER:
SAMPLE METHOD: IL . ISP. EAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER:
READING
TIME
GALLONS
PURGED
TEMP
(°C)
SPECIFIC
COND.
(Ia8/cm)
DISSOLVED
OXYGEN
(mg/'_)
PH
(S.U.)
report to
0.1 S,U.
OXIDATION,
REDUCTION
POTENTIAL
(mV)
TURBIDITY
(NTU)
COMMENTS
3
f
4
5
6
f
.10
SAMP ING CONTAINER
NUMBER OF CONTAINERS
REQUESTED ANALYSIS
500 mL PLASTIC
250 mL PLASTIC
125 mL PLASTIC
40 mL GLASS
1 L GLASS
OTHER
PROTECTIVE CAS(NG: / 1 PAD: LOCI{:C11� VEGETAT(01d: 11- ACC[SS:
$srrrpling Personnel Signature: • '�~
Date:
Notes: °C = degrees Celsius
uS/crn = mlaro.Siemen per centimeter
rnWL - millig-arns per liter
S.U. - Ste nda rd Units
ml' = millivolt
RTU = nephelometrio turUidi y Units
5amplea are Firs*aed immediately upor. ccuecior.
PffernplsteslGW Drilling Formsl',,'d❑II Sampling Log.xis Page 1 of 1

• "tell
E KGIK q—"M, - &Wli QRa cE.O LOGY
.^_3r Hr,Ywooa S—r.c T, l..IIc VILic, NC 2e301
T tt4,@'r. P.a@1,33'.R rd r,P2P28t,3�pl
W W W."T4N ONTFAVI R4NN�NTI4 L.COM
Equipment'bacumentation & Instrument Calibration Data Sheet
Calibration Documentation
aqufpment Doctimentatlon
Equipment or motets used to take measuremana (@. water ie'/el meters, surveyequipmenl, etc.):
11EquIpmentType' I Sera! Number Brand I Date of Use
115C-ft ww", Level 1 25154 Sclinist
1 0505 t-'waterixwel
2275.9 Sol!nlst
=
150•ftWater Leact
150
Testwell
150•it DraWdot'n
y MP3()•1527
QED
I
Other.____._...�..
Select Turbldimeter. Hach 2100Q (sJn 151006045207)
HF Srlantlfic h1icrDTPNr {s/n 200601046)
Calibration Standards
Instrument Heading
Instvment Reading
D piratfon bete
(Hach 2100Q)
(HF' Scientific i,71onoTM)
20 NTU ! 100 NTU 1 8D0 NTU
0.02 NTU
. 10.0 N 71.1 1000 NTU
Cal: Cal: Cal:
�
Cal:
Cal: 'Cal:
Yme: Time: iTime:
Tlmt:
rTlmo: r� � Time: �
_�
Verification (10 NTU):
verification:
Verification: Verification.:
Time:
Time:
Time: u Timo:,0�
YSI 556 Multlparameter Meter (s/n 121-101657)
Instrument Readings
3 .•rr s rn tr
Calibration
Expiration Date
Dissolved bxygenInitial; c.r� Cal:; , + Imrnllq 7C Time: �S �f�
{
I A
ipH7S•U.repo;!to0.2
S.U.
H4S.U.re. 'to4,2
F S, !`a.
Initial:
Initial: �. G ��pHmV:
_2_._.12
pHtriV:
i
Cal:
Cal: �
pHmV:
pHmV:
Tame:
'J--
T'me:��r
1 Vrl ?01
�t Try
pH 10 SAreport ld
initial.
pHmV:
Cal:
pHmV:
Time:
i
� c =3!
QC* ptl 7 S.U. report
toci:tS:b.
MA Time:
Was:
7'G�
Itvlid Orc+Timo:
I
(Check:
-
PM Time:
Chock:
Spec.Cond.
Initial:
_F
Cal: j ime: f
�u -7 S
i,y V�17
J�c�usJem*
QC*: ^AXITime:
PrlldDsyTirno:
I
Dhabi'. P.'vlTim e:
ORP 240 MV
Initial: G 3 Cal: G� Time: �7 u
Date:
Notes:
1- Electronic oquipmahl caft'rated according tc,ihe mainufecturer's oubmilon monueL
2,Spec DConducti-dtyshouldbe'caiibratodaccer'L111%tovaiuesrepresentatiVeofhistorierange-
3.Order of Caf.badon Is as follows: Spouific'Canduptivity, pf-I 7, pl14, pl1 10, 00, ORP, QC checks.
tl, QCAecep;nbie Ranges: pH -/-0J S.U. arid SPecilla Cohducilvlto i0M of the true.vcluo. If qC ipadlrgs Wru 0,01 of 6111fra, the lis4wnent needs
tD be recallbrated,
5. = IhdlcaWS VIDE a QC check must be peffprmed In the morning, afternoon, and the end of the day, or every rcur h-ours.
S. Indica-asto chacso a SpeOlfir Cgnducdvitp buffor/f 1.413
/. 447, 844,, or 23 mS vililchh is closest to histurical readluo from the project iboafldn.
% j����.Lj�tnir ZQ f`�✓�V1'! • Cr
C�:\T@:cDla:Ps�Grou^d1q'ptu&S�IIIInE;Fortrs\Gimintlw.r�orscriacuwatorWailtralionuetnsnectysl55a•nev3 Pafc4ofi

CVV-5)A COMPLi/�,N.CE R- EP,nIZT F'OR,M Pcrniit! It Wg0004797
`(yubirf/l. nfe'e lc# inrim oring period n illr rU`-..4Q jurins,)
X
Enter date monitoring results were duo. (12/31/2016) Will this monitoring report (GW-69 and GW-59A)
YES
NO
be submitted after the established due date?
X
2
Vas any required information missing on the GW-59 report forms?
YI:S
NO
IF the answer to question 1 or 2 is "YES , fist in the.space provided below the well identification number(s) and
explain the problems encountered in obtaining the required Information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, ni locked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)?Ijtheanswer-ic "Fes", con/acl the Regional Ofcejorguidance.
X
4
Are any monitored constituents equal to or above the established standards?
-Y. S
NO
If the answer to question 4 is "NO". skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with conslituont(s) and concentrations)
exceeding standards in the space provided below.*
MW-8: Nitrate - 14.3 mg/L; MW-5: Tetrachlorethene = 141 ug/L, Trichloroethene - 63.1 pg/L, Cis-1,2-dichloroethene - 75.2 pg/L;
MW-7R: Total Organic Carbon = 13.0 mg/L, Nitrate = 12.5 mg/L _
Total Organic Carbon Limit - 10 mg/L; Nitrate Limit = 10 mg/L; Tetrachloroethene limit = 0.7 ug/L; Trichloroethene limit = 3 pg/L; Cis-1,2-dichloroethene limit = 70 pg/
.
5
For the constituents identified In question 4 above, have standards been exceeded previously for the:
YES.
NO
same constituent(s) In the same well(s) In the last two years?
X
If the answer to question 5 is "No", sldp to section 8.
If the.anstver to question 5 Is "YES". list in the space provided below, each well with constituents) exceeding
standards, concentrations) reported, and sample collection date for each occurrence (for the last two years):
Total Organic Carbon (limit = 10 mg/L) - 5/13/2015: MW-8 - 19.7 mg/L, 11/l8/2014: MW-8-54.0 mg/L; 5/22/2014: MW-8=17.6 mg/L;
5/4/2016: MW-7R=13.5 mg/L 11/18/14: MW-7R=19.1 mg/L
Tetrachloroethene (limit = 0.7 ug/L)-11/18/2014: MW-5 = 121 ug/L; 11/4/2015: MW-5 - 26.1 ug/L
Trichloroethene (limit-3 pg/L)-11/18/2014: MW-5 = 22.2 pg/L
Nitrate (limit= 10 mg/L) - 5/4/2016: MW-7R = 11.2 mg/L, MW-8 = 19.1 mg/L; 6/9/2016: MW-7R = 10.9 mg/L, MW-8 = 26.3 mg/L
6
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
X
if the answer Is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the a►rsweris "NO", monitoring wells may be improperly
located; contact the Regional Office.
MW-5 is upgradient and outside of the review boundary. MW-713 and MW-8 are beyond and downgradient
of the review boundary.
7
Is the permittee implementing previously approved actions required by the Division involving this
YFS
NO
groundwater quality problem?
X
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO" contact the Regional Office within 90 days; an evaluation may be
required to determine the Imnact the waste disposal system is having at the review and cornplience,
boundaries surrounding this facility. Failure to do so may subject the nermlttee to a Notice of Violation
flnes,:and/or Penalties.
Tetrachloroethene, trichloroethene, and cis-1,2-dichloroethene have been detected In MW-5 during almost every November sampling event since November 2002.
The concentrations ofthese VOCs have been trending downward since the initial detection In 2002, with occasional minor spikes in data.
Total Organic Carbon (170C), VOC, and SVOC analyses were completed for all samples during the May 2007 groundwater sampling event TOC concentrations are not
attributable to VOCs orSVOCs and are possibly naturally occurring.
Nitrate concentrations exceeded the groundwater standard in MW-7R and MW-8 for the first time in May, 2016. The high concentrations of nitrate are likely
attributable to occasional flooding from the stream adjacentto these monitoring wells and/or to an adjacent property.
g
The person completing this portion (G W--59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required'wells to the address provided at the top of the current G W-59 form.
�I hereby aclmowle Ghat ie awov Inform n was evaluated and the information submitted in4WIS i
reporttSCompli_ . ce R i_ -59 Istru nit. 'mpleteto the best ofrrny knowledge:-. !
signature Permltt ( Au horizod Agent) D to
G'1VY.9A 1218/200D

IGROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
Please Print Clearly or Type
Facility Name: Clement Pappas
Permit Name (if different):
Facility Address: 125 Industrial Park
Hendersonville tstreet) NC 28792 County Henderson
(City) (S*3te) (rip)
Contact Person: Mr. Blake Kehoe Telephone#: 82 8 - 6 93 -- 0 711
Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
1617 MAIL SERVICE CENTER, RALEIGH, NG 27699.1617 Phone: [phone]
PERMIT Number: Expiration Date: 8 31 202C
Non -Discharge WQ 0 0 0 4 7 9 7 UIC
NPDES Other
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
1Z Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other:
WELL ID NUMBER (from PermMW-4
Date sample collected: 11 / 9 / 2 016
FIELD ANALYSES:
IT VVtLLit):
WAS
Well Depth: 18 _ 2 5 ft.
Well Diameter: 2 in.
pH oo400; 5 • 76 units Temp. 000io: 16 .72 °C
DRY at
Depth to Water Level 62546: g . 63 ft. below measuring point
Screened Interval: 8*ft. to16_1*ft.
Spec. Cond. 00094: 1B6 µMhos
time of
Measuring Point is 2 . 4 3 ft. above land surface
Relative M.P. Elevation: 2063 .77 ft.
Odor 000m: none
sampling,
Volume of water pumped/bailed before sampling: 4.75 gallonsocreened
interval is relative to land ourface
Appearance
check
here:
Sam les for metals were collected unfiltered: ❑ YES ❑ NO
1 ADnn ATf�-11 .-.-
and field acidified: ❑ YES ❑ NO
El
Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite. (NO2) as N oo615
mg/L
Coliform: MF Fecal 31616
<4 0 /100mL
Nitrate (NO3) as N 00620
<0 . 020 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P ooss5
0.27 mg/L
(Note: use MPN method for h;ghly turbid
samples)
Orthophosphate 70507
mg/L
Dissolved Solids:Total 70300
124 mg/L
AI -Aluminum oil o5
mgiL
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC oosao
4.3 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940
2 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total olo34
ug/L
Grease and Oils oo552
mg/L
Cu - Copper 01042
mgiL
Phenol 32730
ug/L
Fe - Iron olo45
ug/L
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Specific Conductance 000e5
µMhos
K - Potassium 00937
mg/L
Total Ammonia oo610
< 0 . 10 mg/L
Mg - Magnesium 00927
mgiL
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese o1o55
ug/L
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
Pb - Lead olo51
Zn - Zinc 01092
Certification No. 37712
ug/L
mg/L
Other (Specify Compounds and Concentration Units):
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? ® Yes (1) ❑ No (0)
VOC 7673 method # 6200
method #
method #
method #
-• •-�-••••-•-••����•• �,�+...:....� v..•y %n MwI "au RC[jU[L.1). iiinuenL I mal vuus; mg/L Effluent Total VOCs: mg/L VOC Removal%
V vv-Du

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
FACILITY INFORMATION Please Print Clearly or Type
Facility Name: Clement Pappas
Permit Name (if different):
Facility Address: 1.25 Industrial Park
Hendersonville (steel' NC 28792 County Henderson
(city) (state) (ZO)
act Person: Mr. Blake Kehoe Telephone#/: 8 2 8- 6 9 3- 0 7.11
Location/Site Name: Irrigation Area. No. of wells to be sampled: 6
EPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
IVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
617 MAIL SERVICE CENTER. RALDGH, NC 27699.1517 Phones 919-807-6306
'ERMIT Number: Expiration Date: 8731=
Jon -Discharge WQ 0 0 0 4 7 9 7 UIC `
JPDES Other
"YPE OF PERMITTED OPERATION BEING MONITORED
Lagoon ❑ Remediation, Infiltration Gallery
ER Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other:
WELL ID NUMBER (from Permit): Mw- 5
Date sample collected: 11 / 9 / 2 016
FIELD ANALYSES:
If WELL
WAS
Well Depth: 18..-5Lft•
Well Diameter: 2 in.
pH 00400: 4 • 79 units Temp. 000lo: 15, 72'C
DRY at
Depth to Water Level 82546: 11 . 2 5ft. below measuring point
Screened Interval: 9 * ft, to 19 * ft.
Spec, Cond. 00094: 185 µMhos
time of
Measuring Point is 3 . 00 ft. above land surface
Relative M.P. Elevation: 2085.6p ft.
Odor OODss: none
sampling,
Volume of water um ed/bailed before sampling: 3 . 75 gallons
P P P 9� g
znterval is relatiue �o larva �urtace
Appearance
check
here,❑
,Samples for metals were collected unfiltered: ❑ YES ❑ NO
and field acidified: ❑ YES ❑ NO
t ARnPATnpv IN1Ff IDnnATlnh1
—
Date sample analyzed; -varies; see analytical report Laboratory Name: Pace Pmalytical Services
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N oo615
mg/L
Coliform: MF Fecal 31616
<4 , 0 /100mL
Nitrate (NO3) as N 00620
0.42 mg/L
Coliform: MF Total 31504
1100ml-
Phosphorus: Total as P oo665
0.47 mg/L
(Note: Use MPN method for highly turbid
sampres)
Orthophosphate 70507
mg/L
issolved Solids:Total 70aD
109 mg/L
Al -Aluminum oilos
mg/L
pH (Lab) OD403
units
Ba - Barium 01007
ug/L
TOC oo6ito
<1 . 0 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940
45.0 mg/L
Cd - Cadmium 01027
ug/L
Arsenic o1oo2
ug/L
Chromium: Total 01034
ug/L
Grease and Oils oo552
mg/L
Cu - Copper 01042
mg/L
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
Sulfate G0945
mg/L
Hg - Mercury 71900
ug/L
Specific Conductance 000gs
µMhos
K - Potassium oo937
mg/L
Total Ammonia oo610
< 0 . 10 mg/L
Mg - Magnesium 00927
mg1L
(Ammonia Nitrogen, NH. as N; Ammonia Nitrogen, Total)
Mn -Manganese o1055
ug/L
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
Pb - Lead oio51
Zn - Zinc olo92
Certification No. 37712
ug/L
mg/L
Other (Specify Compounds and Concentration Units):
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? ® Yes (1) ❑ No (0)
VOC 7873 method # F; a r, r,
method #
method #
method #
- - �. . yam. .•. 11 y tn«.1 .. tUPUl la;. IIIIItaU111 1 Utal vUl_.s: MOIL I-ttluAnt Tntat xinrc, —11 vnr^ n.,..,,..,.,lof
--- IZV, ofLV I

GROUNDWATER QUALITY MONITORING:
r
• ,
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
DIVISION OF WATER RESOURCES � INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
. r
.
1617 MAIL SERVICE CENTER, RA.LEIGH, NC27699-1617 Phone:[phone]o6
FACILITY INFORMATION Please Print CleadyorType
PERMIT Number: Expiration Date: 8 31 2020
Facility Name: dement Pappas
Non -Discharge WQ0004797 UiC
Permit Name (if different):
NPDES Other
Facility Address: 125 Industrial Park
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Hendersonville ""cot) NC 28792 County Henderson
X-Tty) (sine) (ZIP)
IN Spray Field ❑ Remediation:
Contact Person:. Mr. .Blake Kehoe
Telephone#: 82 8 ` 6 93 - 0 71.1
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION MW- 6
If WELL
WELL ID NUMBER (from Permit):
Date sample collected: 1.1 / 9 /2 016 FIELD ANALYSES:.
WAS
Well Depth: 11 _ , r, ft.
Well Diameter:. 2 in,
pH 00400: 5 .31- units Temp. cool 0: 17. 05 °C
DRY at
Depth to Water Level 82546: 7 . 4 2 ft. below measuring point Screened Interval; 5 * ft. to
1 o * ft. Spec, Cond. 00094: 88 µMhos
time of
Measuring Point is 3 . 0 0 ft. above land surface
Relative M.P. Elevation: 20sz.17 ft.
Odor o0085: none
sampling,
cheek.
Volume of water pumped/bailed before sampling: 1.0
*screened interval is relative to
gallons
land surtncE
Appearance
here:
Samples for metals were collected unfiltered:: ❑YES
❑ NO and field acidified: El YES ❑ NO
'
x
❑
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report Laboratory Name:. Pace Analytical Services Certification No. 37712
PARAMETERS NOTE: Values should reflect dissolved
and colloidal concentrations.
COD oo335 mg/L
Nitrite (NOO as N oo615
mg/L Pb - Lead olo51 u IL
Coliform: MF Fecal 3mi6 � 10 , 0 /100mL
Nitrate (NO3)(NQ) as N oos2a � 0 . 020 mg/L Zn -Zinc 01092 mglL
Coliform: MF Total 31504 1100mL
Phosphorus: Total as P 00665 0.70
mg/L
(Note: Use)NPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration _Units):
issolved Solids.,Total 70300 64.0 mg/L
Al - Aluminum oil o5
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 7.1 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 9.0 mg/L
Cd - Cadmium 01027
ug/L
Arsenic oloo2 ug/L
Chromium: Total 01034
ug/L
Grease and Oils oo55z mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GCIMS, HPLC)
Phenol 32730 ug/L
Fe - iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L Lab Report. Attached? H Yes (1) ❑ No (0)
Specific Conductance coo95 µMhos
K - Potassium 00937
mg/L VOC 7873 method # 6200
Total Ammonia 00610 0.11 mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH, as N, Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mq/L Effluent Total VOCs: ma/L VOC. RPmnvalet
GW-59 Rev.8/2013

ovotvui FUMM vIV 7CLLVVV YYHYCK VIVLY
(GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
FACILITY INFORMATION PtEasf £Prritweartyorlype
Facility Name: Clement Pappas
Permit Name (if different):
Facility Address: 125 Industrial Park
Hendersonville NC 28792 County Henderson
(Contact Person: Mr • Blake Kehoe Telephone#/: 8 2 8 - 6 9 3 - 0 711
Well Location/Site Name: Irrigation .Area No. of wells to be sampled; 6
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
DIVISION OF WATER RESOURCES,- INFORMATION PROCESSING UNIT
1617 MAIL SERVICE CENTER, RALEIGH, NC 27690-1617 phone; 919-807-5306
17
PERMIT Number. Expiration Date: > 7 1 202C
Non -Discharge WQ O O D 4 7 9 7 UIC
NPDES Other
TYPE OF PERMITTED OPERATION BEING MONITOREDEl '
Lagoon ❑ Remediation: Infiltration Gallery
D� Spray Field ❑ Remediation:
El Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other:
- - - MW- 7R
WELL ID NUMBER (from Permit):
Date sample collected: _ 11 / 9 / 2 016
FIELD ANALYSES:
It WF-LL
WAS
Well Depth: 17?Qft.
Well Diameter: 2 in,
H 00400: 5 . 03 1, ,
p units Temp. Doo1o: �� 34 G
DRY at
Depth to Water Level 62546: 1 2 . �� ft, below measuring point
Screened Interval: 5 ft.* to 25 ft*
Spec. Cond. 00094: 239 pMhos
time of
MeasuringPoint is 3 . 0 0 ft. above land surface
Relative M.P. Elevation: 2062 . s6 {f,
OdorooDeS: none
sampling,
check
Volume of water um ed/bailed before sampling: 2 ., 5 allonsecraened
P P p g� g
intezvsi is relative to rand surtaee
Appearance
here:❑
,Samples for metals were collected unfiltered: ❑ YES ❑ NO
and field acidified: ❑ YES ❑ NO
Date sample analyzed: varies see analytical report Laboratory Name: Pace Analytical Services
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N oo615
mg/L
Coliform: MF'Fecal 31616
<20 _ 0
/100mL
Nitrate (NO3) as N oo62o
12.5 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P OD665
-1 . 0 mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 7D507
rng/L
Dissolved Solids:Total 70300
-1 4 7
mg/L
Al - Aluminum oi1D5
mg/L.
pH (Lab) 00403
units
Ba - Barium oloo7
ug/L
TOC oo6so
13.0
mg/L
Ca - Calcium Do916
mg/L
Chloride 00940
22.7
mg/L
Cd- Cadmium olon
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00562
mg/L
Cu - Copper 01042
mg/L
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L
Total Ammonia oo610
<0 . 10 rrg/L
Mg - Magnesium 00927
mg/L
(Ammonia Nitrogen; NHa as N; Ammonia Nitrogen, Total)
Mn - Manganese 01D55
ug/L
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
Certification No. 3 7 712
Pb - Lead o1o51 ug/L
Zn - Zinc 01092 mg/L
Other (Specify Compounds and Concentration Units):
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? ❑ Yes (1) Ij No (0)
VOC 7873 method 6200
method #
method #
method #
�VIISVUtLiltttti Oy,Lerils Vnly t/ALLaGn LaD Keports): mnuent Iotai virus: mQ/L Effluent Total. VOCs: rnn/I 1/nr P? mnvnia/
I WV u'J. KCV, 01/u 13

AUowu 1 rUKIVI UIV T r-LLUVV f Al r-K UNLY
GROUNDWATER QUALITY MONITORING:
. • r
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27599-1617 Phone; 919-607.6306
FACILITY INFORMATION P/easePriatCteartyorType
PERMIT Number: Expiration Date: 31 2020
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 125 IriduStrlal Park
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville ('``eC" INC 28792 County Henderson
❑ Lagoon 9 ❑Remediation: Infiltration Gallery
(city) (state) (ZIP)
® Spray Field ❑ Remediation:
Contact Person: Mr. Blake Kehoe
Telephone#: 8 2 8 - 6 9 3 - 0 711
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION MW- 8
If WELL
WELL ID NUMBER (from Permit):
Date sample collected: 11 / 9 / 2 016 FIELD ANALYSES:
WAS
Well Depth: 13 , ]?zft.
Well Diameter: 2 in.
pH 00400: 6 • 12 units Temp. 000lo: 14 . 66°C
DRY at
Depth to Water Level s2546: a.1 . 3, ft. below measuring point Screened Interval: 3 fe to
13 e Spec. Cond. 00094: 626 µMhos
time of
Measuring Point is 3 • 0 0 ft. above land surface
Relative M.P. Elevation: 2060 , So ft.
Odor eoo85: none
sampling,
Volume of water um ed/bailed before sampling: 1 .5 0
P p P 9�
gallons interval is relative to land
9
surface
Appearance
check
here:❑
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: Varies; see analytical report Laboratory Name: pace Analytical
Services Certification No. 37712
PARAMETERS NOTE: Values should reflect dissolved
and colloidal concentrations.
COD 00335 mg/L
Nitrite (ND� as N oo615
mg/L Pb - Lead o1o51 ug/L
Coliform: MF Fecal 31616 <4 . 0 1100mL
Nitrate (NO3) as N ooGn 14.3
mg/L Zn - Zinc olon mg/L
Coliform: MF Total 31504 /100mL
Phosphorus: Total as P 00665 0.26
mg/L
(Note: Use MPN method for highly nubid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 333 mg/L
Al - Aluminum of lo5
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00660 9 . 7 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 12 . 0 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ® Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos
K - Potassium 00937
mg/L VOC 7073 method # 6200
Total Ammonia oomo < 0 . 10 mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3 cis N; Ammonia Nitrogen, Total)
Mn - Manganese 01o55
ug/L method #
TKN as N co625 mg/L
Ni - Nickel 01067
ug/L method #
r UI MV]I1aUl(1uUrl Z)ySLern5 Unly tHtiacn LaD Reports): Intluent Total VOCs: mq/L Effluent Total VOCs: mall 11017 Rnmrnralol
UW-by Rev.81Z013

i 1 v11 1. VIA 1 Lt_- - I-rlf% VIYL I
(GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
FACILITY INFORMATION PieasePrinz weanyorrype
Facility Name: Clement Pappas
Permit Name (if different):
Facility Address: 125 Industrial park
Henderso vi.11e isiff00 NC 28792 County Henderson
)ntact Person: Mr. Blake Kehoe Telephone#: [phone]
ell Location/Site Name: Irrigation Area No. of wells to be sampled: 6
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
1617 MAIL SERVICE CENTER, RAL.EIGH., NC 27699-1617 Phone: [phone]
PERMIT Number: Expiration Date: 8 3 I 2C2C
Non -Discharge WQ O O 0 4 7 9 7 U1C
NPDES Other
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
DO Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other:
_ _.._ - ... �.
WELL . ID NUMBE.. MW- 9 R (from Permit):
Date sample collected. 11 / 9 /2016
FIELD ANALYSES:
If WELL
WAS
Well Depth; 18 .1 Oft.
Well Diameter: 2 in,
pH 00400: 4 4 units Temp. 0oo1o: 16, 75OC
DRY at
Depth to Water Level 82546: 6 . 5 5 ft. below measuring point
Screened Interval: 6 * ft, to 16 *' ft.
,
Spec. Cond, 00094: 9 n µMhos
time of
Measuring Point is 1.44 ft. above land surface
Relative M.P. Elevation: 2060.23 ft.
Odor aoanode
sampling,e5:
check.
Volume of Water um ed/bailed before sampling: 2 . 25 gallons
P P P g� g
interval as relative to Sand surface
Appearance
here:
Sam Ies for metals were collected unfiltered: ❑ YES ❑ NO
and field acidified: El YES ❑ NO
Date sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NOO as N oos15
mg/L
Coliform: MF Fecal 31616
<2 D . 0 1100mL
Nitrate (NO3) as N 00620
0.77 mg/L
Coliform: MF Total 31504
1100mL
Phosphorus: Total as P oo665
0 .76 mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
issolved Solids:Total 70300
69.0 mg/L
AI - Aluminum otio5
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC ooino
9-3 mg/L
Ca - Calcium oo916
mg1L
Chloride 00940
10.7 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug1L
Grease and Oils oo552
mg/L
Cu - Copper 01042
mg/L
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L
Total Ammonia ooslo
< 0 • 10 mg/L
Mg - Magnesium 00927
mg/L
(Ammonla Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese o1055
ug/L
TKN as N oosn
mg/L
Ni - Nickel 01067
ug/L
Certification No. 3 7 712
Pb - Lead olo51 ug/L
Zn - Zinc 01092 mg/L
Other (Specify Compounds and Concentration Units).:
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
L-ab Report Attached? ❑ Yes (1) ❑ No (0)
VOC 7873 method #k
method #
method,#
method #
1 v1 MC 111Cu1OL1L)1 t JySLU1F1b Unly kmiLacn L3D Keports): Innuent I-otal VOcs: mo/L Effluent Total VOCs: rnn/I 11rlr Ramnv�l�A
vw-aij Kev. b14U16