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WQ0004797_Monitoring (Report)_20151207
E NGINEERING 8c H YDROG OLOGY 231 HAYWOOD STREET, ASHEVILLE, NC 28801 $ 281-3r350 sFA-C.828�.2g81.3351 WW:A-LT.A�MON.T�ENYI R.O_19Jh,E NTf►'L.CO Mt'k •;; - December 7, 2015 Mr. Blake Kehoe,. Plant Engineer Clement Pappas & Co., Inc. 125 Industrial Park Road Hendersonville, North Carolina November 2015roundvy'tX S-atplmEvent p Zfl�S Clement Pappas & Co.; Eric. (C1&bnt-Pappasj - yk � RMAj'/ pROCION 125 Industrial Park Road 'SSINGUNIT Hendersonville, North Carolina Subject: Dear Mr. Kehoe: JAN m 4 2016 161' a nr-- Altamont Environmental, Inc. (Altamont) performed a groundwater sampling event at your facility on November 4, 2015. A site location map is included as Figure 1. Altamont performed the groundwater - sampling event in accordance with the North Carolina Department of Environmental Quality (DEQ), formerly known as the Department of Environment and, -Natural Resources (DENR), spray irrigation system permit number WQ0004797 (permit most recently reissued on September 3, 2015). Altamont collected groundwater samples from six. monitoring wells: MW-4, MW-5, MW-6, MW-7R, MW-8, and MW-9. Monitoring well MW-9 was installed on April 14, 2015 to replace the previously damaged monitoring well MW-2R. The locations of the monitoring wells are shown on Figure 2 (attached). Altamont submitted the groundwater samples to Pace Analytical Services, Inc. (Pace), a North Carolina certified laboratory, for analysis of the parameters specified in the permit. Table 1 summarizes the current and historical laboratory analytical results for microbiology and wet chemistry. All parameters analyzed, except total organic carbon (TOC) and fecal coliform, were below the permit limits and North Carolina Administrative Code, Title 15A, Subchapter 2L.0202 Standards (21L standards). The TOC concentrations can be summarized as follows: • The permit limit for TOC is 10 milligrams per liter. • -Similar to previous sampling events, the TOC concentration in the MW-8 sample collected during this event (November 2015) was in excess of the permit limit. • ,TOC concentrations in samples MW-4, MW-5, MW-6, MW-7R, and MW-9 collected during this event (November 2015) were below the permit limit. Fecal coliform concentrations can be summarized as follows: • The 2L standard for total coliform is 1 colony -forming unit (CFU) per 100 milligrams. There is not a specific permit limit or 2L standard for fecal coliform; however, total coliform includes fecal coliform. Fecal coliform concentrations exceeded the 2L standard for total coliform in monitoring wells MW-5, MW-6, and MW-8. • Fecal coliform was not detected in monitoring wells MW-4, MW-7R, and MW-9. P:\Clement Pappas\Reports\2015\November\Cover Letter -November 2015.Doc Mr. Blake Kehoe December 7, 2015 Page 2 of 3 Table 2 summarizes the current and historical laboratory analytical. results for volatile organic compounds (VOCs), analyzed by EPA Standard Method 6200. In accordance.with permit requirements samples are analyzed for VOCs once annually, during the month of November.. All VOCs analyzed, except tetrachloroethene, were below permit limits and 2L standards. VOC concentrations can be summarized as follows: • Three VOCs (tetrachloroethene, trichloroethene, and cis-1, 2-dichloroethene) were detected in . monitoring well MW-5. Of these VOCs, only tetrachloroethene was detected above its 2L standard of 0.7 micrograms per liter (pg/L). • Toluene was detected for the first time in monitoring well MW-4 at a concentration of 0.75 pg/L. This detection is well below the 2L standard of 600 pg/L. Table 3 summarizes the current and historical groundwater elevations. With the exception of monitoring well MW-9, all of the'monitoring well concrete pads and top -of -well casing elevations were surveyed by Wes Cole Land Surveying, PA on November 21, 2012. Monitoring well MW-9 was surveyed by Wes Cole Land Surveying, PA on May 29, 2015. The surveyed elevations are indicated on Table 3 and on Figure 2. In accordance with the spray irrigation permit, Clement Pappas is 'required to submit the following by December 31, 2015 (on or before the last working day of the month following the sampling month) to the DEQ: • Laboratory analytical report and chain -of -custody form (Attachment A); the well sampling logs and equipment documentation and instrument calibration data sheet is also included (Attachment B) • DEQ GW-59A—Compliance Report Form (Attachment C) • DEQ GW-59—Groundwater Quality Monitoring Compliance Report Form. for each monitoring well (Attachment D) Altamont proposes to complete the next scheduled groundwater sampling event in May 2016. R\Clement Pappas\Reports\2015\November\Cover Letter_November 2015.Doc Mr. Blake Kehoe December 7, 2015 Page 3 of 3 If you have any questions or would like additional information, please do not hesitate to contact the undersigned at 828.281.3350. Sincerely, ALTAMONT ENVIRONMENTAL, INC. Alex LeSueur, on behalf of Brian Gant Attachments: Figure 1-Site Location Map Figure 2—Site Plan Map Table 1—Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Table 2=Current and Historical Groundwater Analytical Results for Volatile Organic Compounds Table 3—Current and Historical Groundwater Elevation Measurements Attachment A: Laboratory Analytical Report and Chain -of -Custody Form Attachment B: Well Sampling Logs and Equipment Documentation and Instrument Calibration Data Sheet Attachment C: DEQ GVV-59A—Compliance Report Form Attachment D: DEQ GW-59—Groundwater Quality Monitoring: Compliance Report Forms P:\Clement Pappas\Reports\2015\November\Cover Letter —November 2015.Doc -FIGURES COMPLIANCE ,. �`.. r ' 1'` BQUNDARY `` •�'�4 ', f ��i .mow i rah \\��»\��. + T . Al ALTAMONT ENVIRONMENTAL, INC. TABLES Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Clement Pappas Hendersonville, North Carolina Sample Name. Sample Date (mm/dd/yyyy) C o � Ca U V O 0 (mg/L) o (mg/L) U U (CFU per 100 mL) Y m Z (mg/L) Y w U (mg/L) - O N a j N 000 F (mg/L) (0 E, < (mg/L) N O O L O a. F (mg/L) , 05/24/2006 7.2 9.7 < 1.1 2 19 82 < 0.10 NA 11/09/2006 3.6 7.4 < 1.1 0.95 17 76 0.11 NA 05/18/2007 4.9 6.0 < 1.0 0.56 14 62 < 0.10 NA 11/13/2007 5.9 16.7 <1.1 2.9 6.9 82.0 < 0.10 NA 05/27/2008 10.2 9.0 <1.1 0.80 21.3 140 < 0.10 NA 11/18/2008 4.7 10.7 <1.1 1.9 8.5 32.0 < 0.10 NA 05/28/2009 14.4 7.1 < 4.0 0.46 24.2 104 1 < 0.10 NA 11/05/2009 13.5 5.9 < 2.0 0.31 23.5 80.0 < 0.10 NA MW-2R 05/13/2010 8.7 5.8 < 2.0 < 0.10 17.2 57.5 < 0.10 NA 11/08/2010 18.3 10.0 < 2.0 1.1 11.7 60.0 < 0.10 NA 05/17/2011 11.6 < 5.0 < 2.0 < 0.10 14.3 < 62.5 < 0.10 NA 11/15/2011 18.9 10.1 < 2.0 1.2 10.0 86.0 < 0.10 NA 05/17/2012 5.3 7.6 < 4.0 < 0.20 11.9 68.0 < 0.10 NA 11/07/2012 31.1 9.5 < 1.0 1.3 10.0 67.0 < 0.10 NA 05/16/2013 13.5 1.2 < 1.0 < 0.02 13.2 64.0 < 0.10 NA 11/20/2013 6.1 7.6 < 1.0 0.97 9.3 66.0 < 0.10 NA 05/22/2014 8.0 4.1 < 1.0 0.72 8.4 52.0 < 0.10 NA 05/15/2002 8.9 45 < 1.1 < 0.10 9.3 180 < 0.10 NA 11/05/2002 5.5 48 < 1.1 < 0.1 14 230 < 0.10 NA 05/13/2003 3.3 32 < 1.1 0.051 20 110 0.21 NA 11/04/2003 41 31 < 1.1 < 5.0 66 210 < 0.10 NA 05/05/2004 6 29 < 1.1 < 5.0 45 240 0.11 NA 11/09/2004 8.4 13 3.6 < 0.10 52 200 < 0.10 NA 05/17/2005 8.5 10 < 1.1 < 0.10 1 37 220 < 0.10 NA 11/03/2005 16 14 < 1.1 < 0.10 29 220 0.14 NA 05/24/2006 19 11 < 1.1 < 0.10 28 180 < 0.10 NA 11/09/2006 8.8 6.9 < 1.1 < 0.10 26 180 < 0.10 NA 05/18/2007 8.5 8.9 < 1.0 < 0.10 29 300 < 0.10 NA 11/13/2007 16.7 11.3 < 1.1 < 0.10 25.0 152 < 0.10 NA 05/27/2008 < 1.0 10.0 < 1.1 < 0.10 38.6 176 < 0.10 NA 11/18/2008 20.5 9.3 < 1.1 < 0.10 19.6 108 < 0.10 NA MW-4 05/28/2009 8.6 13.6 < 4.0 < 0.10 35.5 156 < 0.10 NA 11/05/2009 31.0 13.6 < 2.0 < 0.10 30.7 120 < 0.10 NA 05/13/2010 7.8 18.0 < 2.0 0.17 31.0 141 < 0.10 NA 11/08/2010 23.9 17.5 < 2.0 < 0.10 34.4 144 < 0.10 NA 05/17/2011 7.7 13.5 < 2.0 0.82 25.6 137 < 0.10 NA 11/15/2011 7.3 14.4 < 2.0 < 0.20 27.8 157 < 0.10 NA 05/17/2012 6.7 12.1 2.0 < 0.20 22.3 117 < 0.10 NA 11/07/2012 10.6 14.5 2.0 < 0.020 26.2 150 < 0.10 NA 05/16/2013 31.8 10.2 2.0 0.28 19.1 108 < 0.10 NA 11/20/2013 8.0 14.7 < 1.0 0.026 22.1 157 < 0.10 NA 05/22/2014 8.7 10.8 < 2.0 0.14 22.5 146 < 0.10 NA 11/18/2014 28.7 12.1 < 2.0 < 0.020 21.9 161 < 0.10 NA 05/13/2015 5.4 9.2 < 1.0 < 0.020 21.5 130 < 0.10 NA 11/04/2015 6.6 6.2 <2.0 < 0.0201 NA 139 < 0.10 0.10 Standards 10 1 250 1 10 1 250 500 1.5 NL P:\Clement Pappas\Reports\2015\November\Tables\November 2015 Historic Analytical Results Page 1 of 5 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Clement Pappas Hendersonville, North Carolina Sample Name Sample Date (mm/dd/yyyy) C a `m U U c m o F (mg/L) g o 0 (mg/L) w -6 o U n LL (CFU per 100 mL) m m z (mg/L) U) (mg/L) N o T d o fe en o F (mg/L) N O E (mg/L) O t a o = a (mg/L) 05/15/2002 2.9 15 < 1.1 0.42 1.7 < 40 < 0.10 NA 11/05/2002 1.4 16 < 1.1 0.54 < 1.0 83 1.3 NA 05/13/2003 4.6 17 < 1.1 0.65 12 56 0.25 NA 11/04/2003 19 22 < 1A 0.23 < 5.0 58 < 0.10 NA 05/05/2004 0.7 28 < 1.1 0.57 < 5.0 80 0.15 NA 11/09/2004 1.2 34 < 1.1 0.24 < 5.0 130 < 0.10 NA 05/17/2005 2.1 35 < 1.1 < 0.10 < 5.0 110 < 0.10 NA 11/03/2005 8.1 34 < 1.1 0.11 < 5.0 82 < 0.10 NA 05/24/2006 7.8 34 < 1.1 < 0.10 < 5.0 120 < 2.5 NA 11/09/2006 1.3 37 < 1.1 0.20 < 5.0 90 < 0.1 NA 05/18/2007 1.7 42 < 1.0 0.16 < 5.0 130 < 0.10 NA 11/13/2007 . 4.2 41.3 < 1.1 0.25 < 5.0 112 < 0.10 NA 05/27/2008 6.7 14.3 < 1.1 0.21 < 5.0 168 0.17 NA 11/18/2008 25.9 47.6 < 1.1 0.17 < 5.0 80.0 < 0.10 NA MW-5 05/28/2009 .16.1 29.0 4.0 0.11 < 5.0 188 < 0.10 NA 11/05/2009 4.7 39.1 2.0 0.15 < 5.0 112 < 0.10 NA 05/13/2010 3.2 43.0 23 0.17 < 5.0 147 < 0.10 NA 11/08/2010 13.8 43.7 200 < 0.10 < 5.0 113 < 0.10 NA 05/17/2011 4.0 32.3 < 4.0 < 0.10 < 5.0 < 167 < 0.10 NA 11/15/2011 3.0 52.6 120 < 0.20 < 5.0 165 < 0.10 NA 05/17/2012 4.7 36.6 < 2.0 < 0.20 < 5.0 110 < 0.10 NA 11/07/2012 4.1 61.1 < 10.0 0.12 < 2.0 139 < 0.10 NA 05/16/2013 4.0 44.2 LO 0.093 2.3 152 < 0.10 NA 11/20/2013 4.2 64.6 1.0 0.19 < 2.0 162 < 0.10 NA 05/22/2014 5.8 6.6 < 10.0 0.099 < 2.0 110 < 0.10 NA 11/18/2014 16.0 57.7 6.0 0.28 < 2.0 160 < 0.10 NA 05/13/2015 21.0 68.4 < 2.0 0.11 < 2.0 176 < 0.10 NA 11/04/2015 7.3 20.3 7.0 < 0.020 NA 68.0 < 0.10 0.21 Standards 10 250 1 10 250 500 1.5 NL P:\Clement Pappas\Reports\2015\November\Tables\November 2015_Historic Analytical Results Page 2 of 5 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Clement Pappas Hendersonville, North Carolina Sample Name Sample Date (mm/dd/yyyy) C O a O U CO O F (mg/L) a o 0 (mg/L) O U LL (CFU per 100 mL) Y m z (mg/L) ..0.. m � (mg/L) y 'O O a > O N O i (mg/L) N E 1 (mg/L) y o L O. O n. m (mg/L) 05/15/2002 6.8 9.9 5.1 < 0.10 11 < 40 < 0.10 NA 11/05/2002 3.9 4.6 < 1.1 0.49 9.8 51 2.5 NA 05/13/2003 4.4 7.3 > 23.0 0.075 14 52 0.14 NA 11/04/2003 26 6.8 9.2 < 0.050 12 < 20 < 0.10 NA 05/05/2004 1.8 6.7 1.1 < 0.10 11 58 0.13 NA 11/09/2004 3.5 11 9.2 < 0.10 9.3 88 < 0.10 NA 05/17/2005 2.4 7.4 < 1.1 < 0.10 8.7 50 < 0.10 NA 11/03/2005 . 6.3 9.6 < 1.1 < 0.10 9.6 66 0.17 NA 05/24/2006 7.4 10 < 1.1 < 0.10 9 54 < 0.10 NA 11/09/2006 1.4 11 < 1.1 0.20 11 54 0.18 NA 05/18/2007 3.9 9.4 <.1.0 < 0.10 9.1 58 0.12 NA 11/13/2007 5.7 .10.7 3.6 0.24 1 5.8 114 0.24 NA 05/27/2008 10.9 5.4 < 1.1 < 0.10 15.3 92.0 < 0.10 NA 11/18/2008 7.4 7.6 > 23 < 0.10 < 5.0 36.0 < 0.10 NA MW-6 05/28/2009 6.4 6.2 276 0.39 8.8 104 < 0.10 NA 11/05/2009 6.4 < 5.0 30 0.10 9.3 52.0 < 0.10 NA 05/13/2010 4.3 5.8 < 2.0 < 0.10 8.1 44.0 < 0.10 NA 11/08/2010 16.5 5.0 7.0 1.5 9.3 48.0 < 0.10 NA 05/17/2011 6.2 9.4 < 2.0 < 0.10 6.8 60.0 < 0.10 NA 11/15/2011 4.6 5.2 5.0 < 0.20 7.5 82.0 < 0.10 NA 05/17/2012 21.6 8.1 28.0 < 0.20 8.8 52.0 < 0.10 NA 11/07/2012 6.4 6.8 3.1 < 0.020 7.5 46.0 < 0.10 NA 05/16/2013 7.5 5.4 12.1 0.048 9.4 62.0 < 0.10 NA 11/20/2013 4.4 7.3 < 1.0 < 0.020 8.6 56.0 < 0.10 NA 05/22/2014 4.6 4.5 1.0 < 0.020 10.1 32.0 < 0.10 NA 11/18/2014 16.3 6.9 13.0 0.078 9.8 49.0 < 0.10 NA 05/13/2015 2.1 6.2 < 1.0 < 0.020 10.1 46.0 < 0.10 NA 11/04/2015 2.2 9.5 136 2.9 NA 58.0 < 0.10 0.12 Standards 10 250 7 1 10 250 500 1.5 NL P:\Clement Pappas\Reports\2015\November\Tables\November 2015_Historic Analytical Results Page 3 of 5 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Clement Pappas Hendersonville, North Carolina Sample Name Sample Date (mm/dd/yyyy) a CO U N 0` (mg/L) D `o 0 (mg/L) ��-�" .O U m LL (CFU per 100 ml-) m m z (mg/L) T in (mg/L) N o N N o F (mg/L) (D o E 1 (mg/L) O CI O a (mg/L) 05/15/2002 20 6.5 < 1.1 5..2 26 < 40 < 0.10 NA 11/05/2002 16 3.3 < 1.1 1.3 1.1 68. 1.4 NA 05/13/2003. 9.7 3.6 2.2 1.8 9.3 44 0.72 NA 11/04/2003 19 6.1 < 1.1 0.72 < 5.0 < 2.0 < 0.10 NA 05/05/2004 3.0 7.0 < 1.1 1.3 < 5.0 52 < 0.10 NA 11/09/2004 2.2 5.1 5.1 1.9 < 5.0 62 <0.10 NA 05/17/2005 3.2 6.1 < 1.1 1.2 < 5.0 40 < 0.10 NA 11/03/2005 7.7 6.1 < 1.1 0.99 < 5:0 58 0.10 NA 05/24/2006 8.4 5.5 < 1.1 1.5 < 5.0 48 < 0.10 NA 11/09/2006 1.9 7.0 < 1.1 1.1 6.7 38 < 0.10 NA MW 7 05/18/2007 3.6 8.6 < 1.0 2.2 5.9 70 < 0.10 NA 11/13/2007 4.2 6.8 < 1.1 1.7 < 5.0 42.0 < 0.10 NA 05/27/2008 7.6 11.5 < 1.1 2.2 6.9 88.0 < 0.10 NA 11/18/2008 7.5 7.7, < 1.1 1.7 < 5.0 30.0 < 0.10 NA 05/28/2009 23.4 9.8 < 4.0 2.3 < 5.0 336 < 0.10 NA 11/05/2009 5.3 10.7 2.0 2.3 11.2 70.0 < 0:10 NA 05/13/2010 4.6 11.0 < 2.0 2.5 < 5.0 71.0 < 0.10 NA 11/08/2010 15.4 8.9 < 2.0 2.3 < 5.0 60.0 < 0.10 NA 05/17/2011 6.0 11.6 < 2.0 5.3 7.6 103 < 0.10 NA 11/15/2011 2.2 9.9 < 2.0 3.5 < 5.0 89.0 < 0.10 NA 05/17/2012 4.4 10.9 < 2.0 3.8 < 5.0 67.0 < 0.10 NA 11/07/2012 11.6 13.1 ' < 100 4.0 14.9 108.0 < 0.10 NA 05/16/2013 12.8 17A < 1.0 10.5 28.3 252 < 0.10 NA 11/20/2013 9.4 14.0 < 1.0 5.5 3.5 < 250 < 0.10 NA 05/22/2014 8.9 13.1 < 10,000 5.7 4.0 93.0 < 0.10 NA MW-7R 11/18/2014 19.1 16.0 < 20.0 7.1 4.4 93.0 < 0.10 NA 05/13/2015 8.5 17.0 < 2.0 9.3 3.7 125 < 0.10 NA 11/04/2015 9.9 18.0 < 2.0 8.3 NA 129 < 0.10 0.35 Standards 10 250 1 10 250 500 1.5 NL P:\Clement Pappas\Reports\2015\November\Tables\November 2015_Historic Analytical Results Page 4 of 5 Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Clement Pappas Hendersonville, North Carolina Sample Name Sample Date (mm/dd/yyyy) C O O A U A `II o F (mg/L) O Q 0 (mg/L) E w O m LL (CFU per 100 mL) Z (mg/L) U (mg/L) N D O U a) N N F (mg/L) CON E ¢ (mg/L) L = F (mg/L) 05/15/2002 6.8 8.7 < 1.1 < 0.10 9.1 64 < 0.10 NA 11/05/2002 4.8 9.8 < 1.1 0.16 7 100 0.57 NA 05/13/2003 5.5 3.3 2.2 1.4 9.4 64 0.41 NA 11/04/2003 27 8.1 6.9 < 0.050 13 54 < 0.10 NA 05/05/2004 3.0 7.4 < 1.1 0.24 9.8 140 < 0.10 NA 11/09/2004 3.7 6.7 > 23 0.79 6.8 120 < 0.10 NA 05/17/2005 3.8 8.3 < 1.1 0.61 6.4 88 _ < 0.10 NA 11/03/2005 7.1 11 < 1.1 0.95 8.4 100 < 0.10 NA 05/24/2006 15 10 < 1.1 0.39 8.1 130 < 0.10 NA 11/09/2006 4.7 12 < 1.1 0.97 7.7 96 < 0.10 NA 05/18/2007 5.0 15 < 1.0 3.0 13 - 290 < 0.10 NA 11/13/2007 8.3 19.6 < 1.1 0.97 1 26.6 154 < 0.10 NA 05/27/2008 12.4 20.0 < 1.1 0.55 35.8 184 < 0.10 NA 11/18/2008 14.4 17.2 2.2 < 0.10 21.5 118 < 0.10 NA MW-8. 05/28/2009 6.2 24.9 240. 0.74 24.9 192 < 0.10 NA 11/05/2009 . 10.8 15.4 50 0.54 18.4 114 < 0.10 NA 05/13/2010 10.8 14.7 < 2.0 1.1 24.1 106 < 0.10 NA 11/08/2010 23.2 . 24.3 200 < 0.10 26.3 173 < 0.10 NA 05/17/2011 10 16.9 10.0 12.2 16.1 232 < 0.10 NA 11/15/2011 8.0 26.6 - < 2.0 3.7 20.2 232 < 0.10 NA 05/17/2012 14.4- 24,8 12.0 8.0 22.9 356 < 0.10 NA 11/07/2012 24.8 26.3 < 100 1.9 28.3 324 < 0.10 NA 05/16/2013 15.8 8.8 10.9 6.8 13.4 248 < 0.10 NA 11/20/2013 21.0 15.4 < 1.0 1.3 24.3 342 < 0.10 NA 05/22/2014 17.6 14.5 < 10.0 0.61 17.8 352 < 0.10 NA 11/18/2014 54.0 16.4 < 4.0 1.1 13.2 421 < 0.10 NA 05/13/2015 19.7 18.3 < 2.0 9.7 12.2 454 < 0.10 NA 11/04/2015 15.0 21.6 4.0 3.0 NA • 396 < 0.10 0.82 05/13/2015 2.2 12.4 < 2.0 1.0 5.5 94.0 < 0.10 NA MW-9 11/04/2015 3.8 2.6 < 1.0 < 0.020 NA 58.0 < 0.10 0.45 Standards 10 250 1 10 1 250 500 1 1.5 NL Notes: 1. mg/L = milligrams per liter. 2. mL = milliliters. 3. CFU = colony forming units. 4. Standards from North Carolina Administrative Code, Title 15A, Subchapter 2L April 1, 2013, except total organic carbon and fecal coliform. Total organic carbon standard from Spray Irrigation Permit Number W00004797. Fecal coliform standard is 2L standard for Total Coliform. 5. Numbers in bold indicate concentration equal to or above the respective standard. 6. NL indicates that no standard limit is set. 7. "<" means less than laboratory method reporting limit. 8. Fecal coliform samples for MW-7 and M W-8 were resampled on May 21, 2010 due to a lab error. 9. Sulfate was removed from the list of necessary analyses as of Fall 2015 and replaced by total phosphorous. 10. NA = Not Analyzed P:\Clement Pappas\Reports\2015\November\Tables\November 2015_Historic Analytical Results Page 5 of 5 Table 2 Current and Historical Groundwater Analytical Results for Volatile Organic Compounds Clement Pappas Hendersonville, North Carolina Sample Name Sample Date (mm/dd/yyyy) N C N OP o m � � (Pg/L) N 2 o r U (pg/L) C O O U _6 N cl Eh (pg/L) y N O O N N Ca (pg/L) U T (pg/L) UI d L r Q (pg/L) MW-2R 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50- < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 < 0.50 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW-4 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 _ < 0.50 < 0.50 -< 0.50 < 0.50 < 0.50 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 < 0.50 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2014 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW-5 11/05/2002 4,700 980 820 13 24 1.9 11/04/2003 3,500 570 510 < 50 < 50 < 50 11/09/2004 580 62 38 < 10 < 10 < 10 11/03/2005 1,900 210 220 < 50 < 50 < 50 11/09/2006 350 74, 67 0.61 - 1.2 < 0.50 05/18/2007 320 47 60 < 0.50 < 0.50 < 0.50 11/13/2007 1,150 217 209 2.0 3.4 1.0 11/18/2008 2,680 534 293 < 25.0 < 25.0 < 25.0 11/05/2009 872 106 .125 0.92 < 1.0 < 0.50 11/08/2010 578 107 160 < 2.5 < 5.0 < 2.5 11/15/2011 1,450 124 141 < 2.5 < 5.0 < 2.5 11/07/2012 774 68.8 77.8 < 5.0 < 10.0 < 5.0 11/20/2013 332 65.1 80.5 < 1.2 < 2.5 < 1.2 11/18/2014 121 22.2 26.4 < 0.50 < 1.0 < 0.50 11/04/2015 26.1 2.6 2.9 < 0.50 < 1.0 < 0.50 2L Standard 0.7 3 70 100 0.03 7 ':\Clement Pappas\Analytical Data\Water\November 2015_Historic Analytical Results Page 1 of 3' Table 2 Current and Historical Groundwater Analytical Results for Volatile Organic Compounds Clement Pappas Hendersonville, North Carolina Sample Name Sample Date (mm/dd/yyyy) m Y 03 UU H (Pg/l) m N o U i (Pg/I) C o O U N (Pg/l) L 2 V ri N C Fes`- (Pg/l) aI 'O U (Pg/l) L N O �_ Q (Pg/l) MW-6 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 3.0 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2014 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW-7 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 0.79 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW-7R 11/07/2012 < 0.50 < 0.50 j < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2014 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 2L Standard 1 0.7 3 70 100 0.03 7 P:\Clement Pappas\Analytical Data\Water\November 2015_Historic Analytical Results Page 2 of 3 Table 2 Current and Historical Groundwater Analytical Results for Volatile Organic Compounds Clement Pappas Hendersonville, North Carolina , W C A r CD C o o 0 C 43 O y � O t U N O N O O � N O o U Ca N N � 0 O L � L o ci Q Sample Sample Date � `� co r Name (mm/dd/yyyy) (ug/I) WWI) W/O (ug/I) (ug/I) W/O MW-8 11/05/2002 < 0.50 < 0.50. < 0.50 <. 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 < 0.50 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2014 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW-9 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 2L Standard 0.7 3 70 100 0.03 7 Notes: 1. This table only includes compounds that were detected above the laboratory method detection limit since the sampling event in November 2002. 2. The complete suite of compounds analyzed can be found in the individual analytical reports. 3. pg/L = micrograms per liter. 4.2L Standard from North Carolina Administrative Code, Title 15A, Subchapter 2L, April 1, 2013. 5. Numbers in bold indicate exceedance of standard. 6. In accordance with Spray Irrigation Permit Number W00004797, only the samples collected during the November sampling events were analyzed for volatile organic compounds with one exception (see note 7). 7. In accordance with the Compliance Evaluation Inspection letter issued by Ms. Beverly Price of the DENR, Division of Water Quality (DWQ) on April 27, 2007, volatile organic compounds and semivdlatile organic compounds were sampled during the May 2007 sampling event. 8. Napthalene was detected in MW-6 for the first time at a concentration of 2.2 pg/L during the November 5, 2002 sampling event, which is below the 2L standard of 6 pg/L. 9. 1,1,2-trichloroethane was detected in MW-5 for the first time on November 20, 2010 at a concentration of 8.0 pg/L, which exceeds the North Carolina Interim Maximum Allowable Concentration of 0.6 pg/L. 10. Chloroform was detected for the first time in MW-5 at a concentration of 31.3 pg/L during the November 2011 sampling event, which is below the 2L standard of 70 pg/L. 11. Toluene was detected for the first time in MW-4 at a concentration of 0.75 pg/L during the November 2015 sampling event, which is below the 2L standard of 600 pg/L. t P:\Clement Pappas\Analytical Data\Water\November 2015_Historic Analytical Results Page 3 of 3 Table 3 Current and Historical Groundwater Elevation Measurements Clement Pappas Hendersonville, North Carolina Well Identification Date Measured (mm/dd/yyyy) Depth to Groundwater (ft-BTOC) Top. of Casing Elevation (feet) Top of Casing Height Above Ground.Surtace (feet) Groundwater Elevation (feet) MW-2R 05/24/2006 9.29 2063.00 3.77 2053.71 11/09/2006 6.49 2063.00 3.77 2056.51 05/18/2007 7.94 2063.00. 3.77 2055.06 11/13/2007 8.46 2063.00 3.77 2054.54 05/27/2008 8.48 2063.00 3.77 2054.52 11/18/2008 8.50 2063.00 3.77 2054.50 05/28/2009 5.43 2063.00 3.77 2057.57 11/05/2009 6.72 2063.00 3.77 2056.28 05/13/2010 7.36 2063.00 3.77 2055.64 11/08/2010 9.60 2063.00 3.77 2053.40 05/17/2011 7.25 2063.00 3.77 2055.75 11/15/2011 7.86 2063.00 3.77 2055.14 05/17/2012 5.19 2063.00 3.77 2057.81 11/07/2012 7.74 2062.36 3.77 2054.62 05/16/2013 6.86 2062.36 3.77 2055.50 11/20/2013 7.92 2062.36 3.77 2054.44 05/22/2014 7.56 2062.36 3.77 2054.80 11/18/2014 8.89 1 2062.36 1 3.77 2053.47. Well abandoned, replaced by MW-9 MW-4 05/15/2002 9.32 2064.60 2.43 2055.28 11/05/2002 9.49 2064.60 2.43 2055.11 05/13/2003 8.20 2064.60 2.43 2056.40 11/04/2003 9.23 2064.60 2.43 2055.37 05/05/2004 9.35 2064.60 2.43 2055.25 11/09/2004 8.61 2064.60 2.43 2055.99 05/17/2005 6.19 2064.60 2.43 2058.41 11/03/2005 9.57 2064.60 2.43 2055.03 05/24/2006 9.60 2064.60 2.43 2055.00 11/09/2006 8.41 2064.60 2.43. 2056.19 05/18/2007 9.42 2064.60 2.43 2055.18 11/13/2007 9.89 2064.60 2.43 2054.71 05/27/2008 9.78 2064.60 2.43 2054.82 11/18/2008 9.76 2064.60 2.43 2054.84 05/28/2009 7.16 2064.60 2.43 2057.44 11/05/2009 8.53 2064.60 2.43 2056.07 05/13/2010 8.83 2064.60 2.43 2055.77 11/08/2010 9.30 2064.60 2.43 2055.30 05/17/2011 8.97 2064.60 2.43 2055.63 11/15/2011 9.48 2064.60 2.43 2055.12 05/17/2012 7.62 2064.60 2.43 2056.98 11/07/2012 9.32 2063.77 2.43 2054.45 05/16/2013 7.93 2063.77 2.43 2055.84 11/20/2013 8.87 2063.77 2.43 2054.90 05/22/2014 8.70 2063.77 2.43 2055.07 11/18/2014 8.54 2063.77 2.43 2055.23 05/13/2015 9.18 2063.77 2.43 2054.59 11/4/2015 6.93 2063.77 2.43 2056.84 ':\Clement Pappas\Reports\2015\November\Tables\Table 3 Historic GW Elev Page 1 of 5 Table 3 Current and Historical Groundwater Elevation Measurements Clement Pappas Hendersonville, North Carolina Well Identification Date Measured (mm/dd/yyyy) Depth to Groundwater (ft-BTOC) Top of Casing Elevation (feet) Top of Casing Height Above Ground Surface (feet) Groundwater Elevation (feet) MW-5 05/15/2002 8.31 2086.40 3.00 2078.09 11/05/2002 10.20 2086.40 3.00 2076.20 05/13/2003 8.29 2086.40 3.00 2078.11 11/04/2003 9.92 2086.40 3.00 2076.48 05/05/2004 8.75 2086.40 3.00 2077.65 11/09/2004 8.50 2086.40 3.00, 2077.90 05/17/2005 8.87 2086.40 3.00 2077.53 11/03/2005 9.70 2086.40 3.00 2076.70 05/24/2006 9.34 2086.40 3.00 2077.06 11/09/2006 8.39 2086.40 3.00 2078.01 05/18/2007 9.16 2086.40 3.00 2077.24 11/13/2007 11.00 2086.40 3.00 2075.40 05/27/2008 9.84 2086.40 3.00 2076.56 11/18/2008 11.59 2086.40 3.00 2074.81 05/28/2009 7.95 2086.40 3.00 2078.45 11/05/2009 8.63 2086.40 3.00 2077.77 05/13/2010 8.87 2086.40 3.00 2077.53 11/08/2010 10.24 2086.40 3.00 2076.16 05/17/2011 8.99 2086.40 3.00 2077.41 11/15/2011 10.58 2086.40 3.00 2075.82 05/17/2012 8.73 2086.40 3.00 2077.67 11/07/2012 9.65 2085.60 3.00 2075.95 05/16/2013 8.14 2085.60 3.00 2077.46 11/20/2013 9.33 2085.60 3.00 2076.27 05/22/2014 8.57 2085.60 3.00 2077.03 11/18/2014 9.04 2085.60 3.00 2076.56 05/13/2015 8.92 2085.60 3.00 2076.68 11/4/2015 8.12 2085.60 3.00 2077.48 3:\Clement Pappas\Reports\2015\November\Tables\Table 3 Historic GW Elev Page 2 of 5 Table 3 Current and Historical Groundwater Elevation Measurements Clement Pappas Hendersonville, North Carolina Well Identification Date Measured (mm/dd/yyyy) Depth a ter Groundwater (ft-BTOC) Elevation Top of Casing (feet) Top of Casing Height Above Ground Surface (feet) Groundwater Elevation (feet) MW-6 05/15/2002 6.20 2061.90 3.00 2055.70 11/05/2002 6.15 2061.90 3.00 2055.75 05/13/2003 5.43 2061.90 3.00 2056.47 11/04/2003 5.85 2061.90 3.00 2056.05 05/05/2004 6.00 2061.90 3.00 2055.90 11/09/2004 5.32 2061.90 3.00 2056.58 05/17/2005 6.10 2061.90 3.00 2055.80 11/03/2005 6.01 2061.90 3.00 2055.89 05/24/2006 6.48 2061.90 3.00 2055.42 11/09/2006 5.71 2061.90 3.00 2056.19 05/18/2007 6.50 2061.90 3.00 2055.40 11/13/2007 7.85 2061.90 3.00 2054.05 05/27/2008 7.01 2061.90 3.00 2054.89 11/18/2008 7.38 2061.90 3.00 2054.52 05/28/2009 5.63 2061.90 3.00 2056.27 11/05/2009 5.74 2061.90 3.00 2056.16 05/13/2010 5.90 2061.90 3.00 2056.00 11/08/2010 5.99 2061.90 3.00 2055.91 05/17/2011 5.85 2061.90 3.00 2056.05 11/15/2011 6.14 2061.90 3.00 2055.76 05/17/2012 5.87 2061.90 3.00 2056.03 11/07/2012 6.05 2061.17 3.00 2055.12 05/16/2013 5.84 2061.17 3.00 2055.33 11/20/2013 5.96 2061.17 3.00 2055.21 05/22/2014 5.96 2061.17 3.00 2055.21 11/18/2014 5.82 2061.17 3.00 2055.35 05/13/2015 6.05 2061.17 3.00 2055.12 11/4/2015 5.18 2061.17 3.00 2055.99 P:\Clement Pappas\Reports\2015\November\Tables\Table 3 Historic GW Elev Page 3 of 5 Table 3 Current and Historical Groundwater Elevation Measurements Clement Pappas Hendersonville, North Carolina Well Identification Date Measured (mm/dd/yyyy) Depth to Groundwater (ft-BTOC) Top of Casing Elevation (feet) Top of Casing Height Above Ground Surface (feet) Groundwater Elevation (feet) MW-7 05/15/2002 10.90 2062.70 3.00 2051.80 11/05/2002 11.35 2062.70 3.00 2051.35 05/13/2003 8.87 2062.70 3.00 2053.83 11/04/2003 10.78 2062.70 3.00 2051.92 05/05/2004 10.80 2062.70 3.00 2051.90 11/09/2004 9.70 2062.70 3.00 2053.00 05/17/2005 10.60 2062.70 3.00 2052.10 11/03/2005 11.09 2062.70 3.00 2051.61 05/24/2006 11.27 2062.70 3.00 2051.43 11/09/2006 9.71 2062.70 3.00 2052.99 05/18/2007 11.02 2062.70 3.00 2051.68 11/13/2007 11.76 2062.70 3.00 2050.94 05/27/2008 11.55 2062.70 3.00 2051.15 11/18/2008 11.63 2062.70 3.00 2051.07 05/28/2009 8.21 2062.70 3.00 2054.49 11/05/2009 9.89 2062.70 3.00 2052.81 05/13/2010 10.44 2062.70 3.00 2052.26 11/08/2010 11.12 2062.70 3.00 2051.58 05/17/2011 10.80 2062.70 3.00 2051.90 11/15/2011 11.43 2062.70 3.00 2051.27 05/17/2012 8.91 2062.70 3.00 2053.79 MW-7R 11/07/2012 12.02 2062.86 3.00 2050.84 05/16/2013 10.29 2062.86 3.00 2052.57 11/20/2013 11.69 2062.86 3.00 2051.17 05/22/2014 11.38 2062.86 3.00 2051.48 11/18/2014 11.25 2062.86 3.00 2051.61 05/13/2015 11.94 2062.86 3.00 2050.92 11/4/2015 8.43 2062.86 3.00 2054.43 P:\Clement Pappas\Reports\2015\November\Tables\Table 3 Historic GW Elev Page 4 of 5 Table 3 Current and Historical Groundwater Elevation Measurements Clement Pappas Hendersonville, North Carolina Well Identification Date Measured (mm/dd/yyyy) Depth to Groundwater (ft-BTOC) Top of Casing Elevation (feet) Top of Casing Height Above Ground Surface (feet) Groundwater Elevation (feet) MW-8 05/15/2002 10.25 2061.40 3.00 2051.15 11/05/2002 10.35 2061.40 3.00 2051.05 05/13/2003 8.16 2061.40 3.00 2053.24 11/04/2003 10.23 2061.40 3.00 2051.17 05/05/2004 10.30 2061.40 3.00 2051.10 11/09/2004 8.90 2061.40 3.00 2052.50 05/17/2005 10.08 2061.40 3.00 2051.32 11/03/2005 10.61 2061.40 3.00 2050.79 05/24/2006 10.60 2061.40 3.00 2050.80 11/09/2006 9.40 2061.40 3.00 2052.00 05/18/2007 10.31 2061.40 3.00 2051.09 11/13/2007 11.09 2061.40 3.00 2050.31 05/27/2008 10.83 2061.40 3.00 2050.57 11/18/2008 11.11 2061.40 3.00 2050.29 05/28/2009 8.25 2061.40 3.00 2053.15 11/05/2009 9.22 2061.40 3.00 2052.18 05/13/2010 9.88 2061.40 3.00 2051.52 11/08/2010 .10.38 2061.40 3.00 2051.02 05/17/2011 10.27 2061.40 3.00 2051.13 11/15/2011 10.87 2061.40 3.00 2050.53 05/17/2012 8.03 2061.40 3.00, 2053.37 11/07/2012 10.45 2060.80 3.00 2050.35 05/16/2013 8.58 2060.80 3.00 2052.22 11/20/2013 10.34 2060.80 3.00 2050.46 05/22/2014 9.79 2060.80 3.00 2051.01 11/18/2014 10.03 2060.80 3.00 2050.77 05/13/2015 10.34 2060.80 3.00 2050.46 11/4/2015 7.21 2060.80 3.00 2053-. MW-9 05/13/2015 6.03 2060.23 1.44 2054.20 11/4/2015 1 2.89 1 2060.23 1.44 2057.34 Notes: 1. ft-BTOC = feet below top -of -well casing. 2. MW-5 through MW-8 top of casing elevations based upon a survey by Hill and Associates Surveyors dated January 10, 2002 through May 2012. 3. MW-2R and MW-4 Top of Casing Elevations based upon differential level measurements made by Altamont Environmental, Inc. on June 26, 2006 through May 2012. 4. Measurements were taken from the Top of Casing. Top of Casing Heights are given for reference only. 5. Groundwater Elevations = Top of Casing Elevation minus Depth to Groundwater. 6. The Top -of -Casing elevations for the monitoring wells were resurveyed on November 21, 2012 by Wes Cole Land Surveying. 7. The Top -of -Casing elevations for MW-9 surveyed on May 29, 2015 by Wes Cole Land Surveying. P:\Clement Pappas\Reports\2015\November\Tables\Table 3 Historic GW Elev Page 5 of 5 Attachment A Laboratory Analytical Report and Chain -of -Custody Form iceAnal tical J wmpacelabs.com Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ivember 13, 2015 an Gant amont Environmental 1 Haywood Street heville, NC 28804 Project: Clement Pappas 2081.01 Pace Project No.: 92274691 ar Brian Gant: closed are the analytical results for sample(s) received by the laboratory on November 04, 2015. e results relate only to the samples included in this report. Results reported herein conform to the Ist current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless lerwise noted in the body of the report. alyses were performed at the Pace Analytical Services location indicated on the sample analyte ge for analysis unless otherwise footnoted. ,ou have any questions concerning this report, please feel free to contact me. icerely, rri Patton ri.patton@pacelabs.com )ject Manager ;losures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, �9 without the written consent of Pace Analytical Services, Inc.. Page 1 of 36 e0RA10 Analytical www.pacelabs.com t: Clement Pappas 2081.01 Project No.: 92274691 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 tte Certification IDs Kincey Ave. Ste 100, Huntersville, NC 28078 Carolina Drinking Water Certification #: 37706 Carolina Field Services Certification #: 5342 Carolina Wastewater Certification #: 12 i Carolina Certification #: 99006001 Ile Certification IDs Riverside Drive, Asheville, NC 28804 a/NELAP Certification #: E87648 achusetts Certification #: M-NC030 Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 West Virginia Certification #: 357 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 36 Analytical www.pacelabs.com ANALYTICAL RESULTS Clement Pappas 2081.01 roject No.: 92274691 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 le: MW-4 Parameters Lab ID: 92274691001 Collected: 11/04/15 13:40 Results Units Report Limit DF Received: 11/04/15 15:00 Matrix: Water Prepared Analyzed CAS No. Qua] MSV Analytical Method: SM 6200B ne . ND ug/L 0.50 1 11/08/15 16:21 71-43-2 obenzene ND ug/L 0.50 1 11/08/15 16:21 108-86-1 ochloromethane ND ug/L 0.50 1 11/08/15 16:21 74-97-5 odich]oromethane ND ug/L 0.50 1 11/08/15 16:21 75-27-4 oform ND ug/L 0.50 1 11/08/15 16:21 75-25-2 omethane ND ug/L 5.0 1 11/08/15 16:21 74-83-9 ylbenzene ND ug/L 0.50 1 11108/1516:21 104-51-8 utylbenzene ND ug/L 0.50 1 11/08/15 16:21 135-98-8. utylbenzene ND ug/L 0.50 1 11108/1516:21 98-06-6 on tetrachloride ND ug/L 0.50 1 11/08/15 16:21 56-23-5 robenzene ND ug/L 0.50 1 11/08/15 16:21 108-90-7 roethane ND ug/L 1.0 1 11/08/15 16:21 75-00-3 roform ND ug/L 0.50 1 11/08/15 16:21 67-66-3 romethane ND ug/L 1.0 1 11/08/15 16:21 74-87-3 lorotoluene ND ug/L 0.50 1 11/08/15 16:21 95-49-8 lorotoluene ND ug/L 0.50 1 11/08/15 16:21 106-43-4 ibromo-3-chloropropane ND ug/L 1.0 1 11/08/15 16:21 96-12-8 omochloromethane ND ug/L 0.50 1 11/08/15 16:21 124-48-1 Dibromoethane (EDB) ND ug/L 0.50 1 11/08/15 16:21 106-93-4 omomethane ND ug/L 0.50 1 11/08/15 16:21 74-95-3 Dichlorobenzene ND ug/L 0.50 1 11/08/15 16:21 95-50-1 Dichlorobenzene ND ug/L 0.50 1 11/08/15 16:21 541-73-1 Dichlorobenzene ND ug/L 0.50 1 11/08/15 16:21 106-46-7 lorodifluoromethane ND ug/L 0.50 1 11/08/15 16:21 75-71-8 Dichloroethane ND ug/L 0.50 1 11/0811516:21 75-34-3 -Dichloroethane ND ug/L 0.50 1 11/08/15 16:21 107-06-2 -Dichloroethene ND ug/L 0.50 1 11/08/15 16:21 75-35-4 1,2-Dichloroethene ND ug/L 0.50 1 11/08/15 16:21 156-59-2 is-1,2-Dichloroethene ND ug/L 0.50 1 11/08/15 16:21 156-60-5 -Dichloropropane ND ug/L 0.50 1 11/08/15 16:21 78-87-5 -Dichloropropane ND ug/L 0.50 1 11/08/15 16:21 142-28-9 -Dichloropropane ND ug/L 0.50 1 11/08/15 16:21 594-20-7 -Dichloropropene ND ug/L '0.50 1 11/08/15 16:21 563-58-6 -1,3-Dichloropropene ND ug/L 0.50 1 11/0811516:21 10061-01-5 is-1,3-Dichloropropene ND ug/L 0.50 1 11/08/15 16:21 10061-02-6 . >opropyl ether ND ug/L 0.50 1 11/08/15 16:21 108-20-3 ylbenzene ND ug/L 0.50 1 11/08/15 16:21 100-41-4 Kachloro-1,3-butadiene ND ug/L 2.0 1 11/08/15 16:21 87-68-3 propy]benzene (Cumene) ND ug/L 0.50 1 11/08/15 16:21 98-82-8 thylene Chloride ND ug/L 2.0 1 11/08/15 16:21 75-09-2 thyl-tert-butyl ether ND ug/L 0.50 1 11/08/15 16:21 1634-04-4 phthalene ND ug/L 2.0 1 11/08/15 16:21 91-20-3 'ropylbenzene ND ug/L 0.50 1 11/08/15 16:21 103-65-1 'rene ND ug/L 0.50 1 11/08/15 16:21 100-42-5 ,1,2-Tetrachloroethane ND ug/L 0.50 1 11/08/15 16:21 630-20-6 ,2,2-Tetrachloroethane ND ug/L 0.50 1 11/08/15 16:21 79-34-5 rachloroethene ND ug/L 0.50 1 11/08/15 16:21 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, e: 11/13/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 3 of 36 ceAnalytical www.pacelabs,mm ANALYTICAL RESULTS Clement Pappas 2081.01 ject No.: 92274691 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 MW-4 Parameters Lab ID: 92274691001 Collected: 11/04/15 13:40 Results Units Report Limit DF Received: 11/04/15 15:00 Matrix: Water Prepared Analyzed CAS No. Qua[ 5V Analytical Method: SM 6200B 0.75 ug/L 0.50 1 11/08/15 16:21 108-88-3 hlorobenzene ND ug/L 2.0 1 11/08/15 16:21 87-61-6 hlorobenzene ND ug/L 2.0 1 11/08/15 16:21 120-82-1 hloroethane ND ug/L 0.50 1 11/08/15 16:21 71-55-6 hloroethane ND ug/L 0.50 1 11/08/15 16:21 79-00-5 :thene ND ug/L 0.50 1 11/08/15 16:21 79-01-6 luoromethane ND ug/L 1.0 1 11/08/15 16:21 75-69-4 hloropropane ND ug/L 0.50 1 11/08/15 16:21 96-18-4 iethylbenzene._ ND ug/L 0.50 1 11/08/15 16:21 95-63-6 lethylbenzene ND ug/L 0.50 1 11/08/15 16:21 108-67-8 ride ND ug/L 1.0 1 11/08/15 16:21 75, 01-4 ne ND ug/L 1.0 1 11/08/15 16:21 179601-23-1 ND ug/L 0.50 1 11/08/15 16:21 95-47-6 es )roethane-d4 (S) 105 % 70-130 1 11/08/15 16:21 17060-07-0 luorobenzene (S) 100 % 70-130 1 11/08/15 16:21 460-00-4 18 (S) 100 % 70-130 1 11/08/15 16:21 2037-26-5 ital Dissolved Solids Analytical Method: SM 2540C solved Solids 139 mg/L 25.0 1 11/05/15 10:52 ?2D Fecal Coliform AVL Analytical Method: SM 9222D iforms ND CFU/100 mL 2.0 2 11/04/15 17:00 monia Analytical Method: EPA 350.1 Ammonia ND mg/L 0.10 1 11/10/15 04:03 7664-41-7 rogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Nitrate ND mg/L 0.020 1 11/04/1519:08 osphorus, Total Analytical Method: EPA 365.1 'US 0.10 mg/L 0.050 1 11/10/15 03;14 7723-14-0 oride Analytical Method: SM 4500-CI-E 6.2 mg/L 1.0 1 11/10/15 23:33 16887=00-6 )C Analytical Method: SM 5310B anic Carbon 6.6 mg/L 1.0 1 11/07/15 22:57 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 3/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 4 of 36 Analytical www.pacelabs.com Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS ;t: Clement Pappas 2081.01 Project No.: 92274691 e: MW-5 Parameters Lab ID: 92274691002 Collected: 11/04/15 12:55 Received: Results Units Report Limit DF Prepared 11/04/15 15:00 Matrix: Water Analyzed CAS No. Qua[ MSV Analytical Method: SM 6200B ne ND ug/L 0.50 1 11/08/15 21:05 71-43-2 benzene ly."tylbenzene ND ug/L 0.50 1 11/08/15 21:05 108-86-1 chloromethane ND ug/L 0.50 1 11/08/15 21:05 74-97-5 dichloromethane ND ug/L 0.50 1 11/08/15 21:05 75-27-4 form ND ug/L 0.50 1 11/08/15 21:05 75-25-2 methane ND ug/L 5.0 1 11/08/15 21:05 74-83-9 lbenzene ND ug/L 0.50 1 11/08/15 21:05 104-51-8 tylbenzene ND ug/L 0.50 1 11/08/15 21:05 135-98-8 ND ug/L 0.50 1 11/08/15 21:05 98-06-6 n tetrachloride ND ug/L 0.50 1 11/08/15 21:05 56-23-5 obenzene ND ug/L 0.50 1 11/08/15 21:05 108-90-7 oethane ND ug/L 1.0 1 11/08/15 21:05 75-00-3 oform ND ug/L 0.50 1 11/08/15 21:05 67-66-3 omethane ND ug/L 1.0 1 11/08/15 21:05 74-87-3 lorotoluene ND ug/L 0.50 1 11/08/15 21:05 95-49-8 lorotoluene ND ug/L 0.50 1 11/08/15 21:05 106-43-4 ibromo-3-chloropropane ND ug/L 1.0 1 11/08/15 21:05 96-12-8 mochloromethane ND ug/L 0.50 1 11/08/15 21:05 124-48-1 ibromoethane (EDB) ND ug/L 0.50 1 11/08/15 21:05 106-93-4 momethane ND ug/L 0.50 1 11/08/15 21:05 74-95-3 ichlorobenzene ND ug/L 0.50 1 11/08/15 21:05 95-50-1 Dichlorobenzene ND ug/L 0.50 1 11/08/15 21:05 541-73-1 Dichlorobenzene ND ug/L 0.50 1 11/08/15 21:05 106-46-7 lorodifluoromethane ND ug/L 0.50 1 11/08/15 21:05 75-71-8 Dichloroethane ND ug/L 0.50. 1 11/08/15 21:05 75-34-3 Dichloroethane ND ug/L 0.50 1 11/08/15 21:05 107-06-2 Dichloroethene ND ug/L 0.50 1 11/08/15 21:05 75-35-4 1,2-Dichloroethene 2.9 ug/L 0.50 1 11/08/15 21:05 156-59-2 s-1,2-Dichloroethene ND ug/L 0.50 1 11/08/15 21:05 156-60-5 Dichloropropane ND ug/L _ 0.50 1 11/08/15 21:05 78-87-5 Dichloropropane ND ug/L 0.50 1 11/08/15 21:05 142-28-9 Dichloropropane ND ug/L 0.50 1 11/08/15 21:05 594-20-7 Dichloropropene ND ug/L 0.50 1 11/08/15 21:05 563-58-6 1,3-Dichloropropene ND ug/L 0.50 1 11/08/15 21:05 10061-01-5 s-1,3-Dichloropropene ND ug/L 0.50 1 11/08/15 21:05 10061-02-6 opropyl ether ND ug/L 0.50 1 11/08/15 21:05 108-20-3 ylbenzene ND ug/L 0.50 1 11/08/15 21:05 100-41-4 achloro-1,3-butadiene ND ug/L 2.6 1 11/08/15 21:05 87-68-3 iropylbenzene (Cumene) ND ug/L 0.50 1 11/08/15 21:05 98-82-8 hylene Chloride ND ug/L 2.0 1 11/08/15 21:05 75-09-2 hyl-tent-butyl ether ND ug/L 0.50 1 11/08/15 21:05 1634-04-4 ihthalene ND ug/L 2.0 1 11/08/15 21:05 91-20-3 �opylbenzene ND ug/L 0.50 1 11/08/15 21:05 103-65-1 ene ND ug/L 0.50 1 11/08/15 21:05 100-42-5 1,2-Tetrachloroethane ND ug/L 0.50 1 11/08/15 21:05 630-20-6 2,2-Tetrachloroethane ND ug/L 0.50 1 11/08/15 21:05 79-34-5 achloroethene 26.1 ug/L 0.50 1 11/08/15 21:05 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 11/13/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 5 of 36 iceAnalytical www.pacelabs.com Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Clement Pappas 2081.01 )ject No.: 92274691 MW-5 Lab ID: 92274691002 Collected: 11/04/15 12:55 Received: 11/04/15 15:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[ . ',SV Analytical Method: SM 6200B ND ug/L 0.50 1 11/08/15 21:05 108-88-3 ;hlorobenzene ND ug/L 2.0 1 11/08/15 21:05 87-61 6 ;hlorobenzene ND ug/L 2.0 1 11/08/15 21:05 120-82-1 ;hloroethane ND ug/L 0.50 1 11/08/15 21:05 71-55-6 ;hloroethane ND ug/L 0.50 1 11/08/15 21:05 79-00-5 athene 2.6 ug/L 0.50 1 11/08/15 21:05 79-01-6 luoromethane ND ug/L 1.0 1 11/08/15 21:05 75-69-4 :hloropropane ND ug/L 0.50 1 11/08/15 21:05 96-18-4 nethylbenzene ND ug/L 0.50 1 11/08/15 21:05 95-63-6 nethylbenzene ND ug/L 0.50 1 11/08/15 21:05 108-67-8 )ride ND ug/L 1.0 1 11/08/15 21:05 75-01-4 one ND ug/L 1.0 1 11/08/15 21:05 179601-23-1 ND ug/L 0.50 1 11/08/15 21:05 95-47-6 tes oroethane-d4 (S) 100 % 70-130 1 11/08/15 21:05 17060-07-0 luorobenzene (S) 99 % 70-130 1 11/08/15 21:05 460-00-4 J8 (S) 100 % 70-130 1 11/08/15 21:05 2037-26-5 Aal Dissolved Solids Analytical Method: SM 2540C solved Solids 68.0 mg/L 25.0 1 11/05/15 10:52 22D Fecal Coliform AVL Analytical Method: SM 9222D liforms 7.0 CFU/100 mL 1.0 1 11/04/15 17:00 u1 imonia Analytical Method: EPA 350.1 Ammonia ND mg/L . 0.10 1 11/10/15 04:04 7664-41-7 x6gen, N021NO3 unpres Analytical Method: EPA 353.2 Nitrate ND mg/L 0.020 1 11/04/1519:07 osphorus, Total Analytical Method: EPA 365.1 rus 0.21 mg/L 0.050 1 11/10/15 03:14 7723-14-0 loride Analytical Method: SM 4500-CI-E 20.3 mg/L 1.0 1 11/10/15 23:34 16887-00-6 DC Analytical Method: SM 5310B. anic Carbon 7.3 mg/L 1.0 1 11/07/15 23:08 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 13/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 6 of 36 Analytical www.pacelab&com Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS t: Clement Pappas 2081.01 Project No.: 92274691 le: MW-6 Lab ID: 92274691003 Collected: 11/04/15 10:06 Received: 11/04/15 15:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MSV Analytical Method: SM 6200B ne ND ug/L 0.50 1 11/11/15 12:27 71-43-2 obenzene ND ug/L 0.50 1 11/1111512:27 108-86-1 ochloromethane ND ug/L 0.50 1 11/11/15 12:27 74-97-5 odichloromethane ND ug/L 0.50 1 11/11/15 12:27 75-27-4 oform ND ug/L 0.50 1 11/11/15 12:27 75-25-2 omethane ND ug/L 5.0 1 11/11/15 12:27 74-83-9 ylbenzene ND ug/L 0.50 1 11/11/15 12:27 104-51-8 utylbenzene ND ug/L 0.50 1 11/11/15 12:27 135-98-8 utylbenzene ND ug/L 0.50 1 11/11/15 12:27 98-06-6 on tetrachloride ND ug/L 0.50 1 11/11/15 12:27 56-23-5 robenzene ND ug/L 0.50 1 11/11/15 12:27 108-90-7 roethane ND ug/L 1.0 1 11/11/15 12:27 75-00-3 roform ND ug/L 0.50 1 11/11/15 12:27 67-66-3 romethane ND ug/L 1.0 1. 11/11/15 12:27 74-87-3 lorotoluene ND ug/L 0.50 1 11/11/15 12:27 95-49-8 lorotoluene ND ug/L 0.50 1 11/11/15 12:27 106-434 ibromo-3-chloropropane ND ug/L 1.0 1 11/11/15 12:27 96-12-8 omochloromethane ND ug/L 0.50 1 11/11/15 12:27 124-48-1 Dibromoethane (EDB) ND ug/L 0.50 1 11/11/15 12:27 106-93-4 omomethane ND ug/L 0.50 1 .11/11/15 12:27 74-95-3 Dichlorobenzene ND ug/L 0.50. 1 11/1111512:27 95-50-1 Dichlorobenzene ND ug/L 0.50 1 11/11/15 12:27 541-73-1 Dichlorobenzene ND ug/L 0.50 1 11/11/15 12:27 106-46-7 lorodifluoromethane ND ug/L 0.50 1 11/11/15 12:27 75-71-8 Dichloroethane ND ug/L 0.50 1 11/11/15 12:27 75-34-3 Dichloroethane ND ug/L 0.50 1 11/11/1512:27 107-06-2 Dichloroethene ND ug/L 0.50 1 11/11/15 12:27 75-35-4 1,2-Dichloroethene ND ug/L 0.50 1 11/11/15 12:27 156-59-2 s-1,2-Dichloroethene ND ug/L 0.50 1 11/11/15 12:27 156-60-5 -Dichloropropane ND ug/L 0.50 1 11/11/15 12:27 78-87-5 -Dichloropropane ND ug/L 0.50 1 11/11/1512:27 142-28-9 ,-Dichloropropane ND ug/L 0.50 1 11/11/15 12:27 594-20-7 -Dichloropropene ND ug/L 0.50 1 11/11/15 12:27 563-58-6 -1,3-Dichloropropene ND ug/L 0.50 1 11/11/15 12:27 10061-01-5 ns-1,3-Dichloropropene ND ug/L 0.50 1 11/11/15 12:27 10061-02-6 sopropyl ether ND ug/L 0.50 1 11/11/15 12:27 108-20-3 iylbenzene ND ug/L 0.50 1 11/11/15 12:27 100-41-4 xachloro-1,3-butadiene ND ug/L 2.0 1 11/11/1512:27 87-68-3 ipropylbenzene (Cumene) ND ug/L 0.50 1 11/11/15 12:27 98-82-8 ethylene Chloride ND ug/L 2.0 1 11/11/15 12:27 75-09-2 ethyl-tert-butyl ether ND ug/L 0.50 1 11/11/15 12:27 1634-04-4 iphthalene ND ug/L 2.0 1 11/11/15 12:27 91-20-3 'ropylbenzene ND ug/L 0.50 1 11/11/15 12:27 103-65-1 /rene ND ug/L 0.50 1 11/11/15 12:27 100-42-5 1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/11/15 12:27 630-20-6 ,2,2-Tetrachloroethane ND ug/L 0.50 1 11/11/15 12:27 79-34-5 :rachloroethene ND ug/L 0.50 1 11/11/15 12:27 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, :e: 11/13/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 7 of 36 ceAnalytical www.pacelabs.cam Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Clement Pappas 2081.01 >ject No.: 92274691 MW-6 Lab ID: 92274691003 Collected: 11/04/15 10:06 Received: 11/04/15 15:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual SV Analytical Method: SM 6200B ND ug/L 0.50 1 11/11/15 12:27 108-88-3 :hlorobenzene ND ug/L 2.0 1 11/11/15 12:27 87-61-6 :hlorobenzene ND ug/L 2.0 1 11/11/15 12:27 120-82-1 :hloroethane ND ug/L 0.50 1 11/11/15 12:27 71-55-6 :hloroethane ND ug/L 0.50 1 11/11/15 12:27 79-00-5 �thene ND ug/L 0.50 1 11/11/15 12:27 79-01-6 luoromethane ND ug/L 1.0 1 11/11/15 12:27 75-69-4 hloropropane ND ug/L 0.50 1 11/11/15 12:27 96-18-4 nethylbenzene ND ug/L 0.50 1 11/11/15 12:27 95-63-6 nethylbenzene ND ug/L 0.50 1 11/11/15 12:27 108-67-8. ride ND ug/L 1.0 1 11/11/15 12:27 75-01-4 me ND ug/L 1.0 1 11/11/15 12:27 179601-23-1 ND ug/L 0.50 1 11/11/15 12:27 95-47-6 `es Droethane-d4 (S) 100 % 70-130 1 11/11/15 12:27 17060-07-0 luorobenzene (S) 100 % 70-130 1 11/11/15 12:27 460-00-4 l8 (S) 100 % 70-130 1 11/11/15 12:27 2037-26-5 )tal Dissolved Solids Analytical Method: SM 2540C solved Solids 58.0 mg/L 25.0 1 11/05/15 10:53 22D Fecal Coliform AVL Analytical Method: SM 9222D iforms 136 CFU/100 mL 1.0 1 11/04/15 17:00 u1 smonia Analytical Method: EPA 350.1 Ammonia ND mg/L 0.10 1 11/10/15 04:06 7664-41-7 rogen, N021NO3 unpres Analytical Method: EPA 353.2 Nitrate 2.9 mg/L 0.020 1 11/04/1519:00 osphorus, Total Analytical Method: EPA 365.1 'US 0.12 mg/L 0.050 1 11/10/15 03:15 7723-14-0 oride Analytical Method: SM 4500-CI-E 9.5 mg/L 1.0 1 11/10/15 23:35 16887-00-6 )C Analytical Method: SM 5310B anic Carbon 2.2 mg/L 1.0 1 11/07/15 23:22 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 3/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 8 of 36 Analytical www.pacelabs.com ANALYTICAL RESULTS Clement Pappas 2081.01 Project No.: 92274691 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 le: MW-7R Parameters Lab ID: 92274691004 Collected: 11/04/15 11:05 Results Units Report Limit DF Received: 11/04/15 15:00 Matrix: Water Prepared Analyzed CAS No. Qual MSV Analytical Method: SM 6200B ne ND ug/L 0.50 1 11/11/15 12:44 71-43-2 benzene ND ug/L 0.50 1 11/11/15 12:44 108-86-1 chloromethane ND ug/L 0.50 1 11111/1512:44 74-97-5 dichloromethane ND ug/L 0.50 1 11/11/15 12:44 75-27-4 oform ND ug/L 0.50 1 11/11/15 12:44 75-25-2 omethane ND ug/L 5.0 1 11/11/15 12:44 74-83-9 y]benzene ND ug/L 0.50 1 11/11/15 12:44 104-51-8 utylbenzene ND ug/L 0.50 1 11/11/15 12:44 135-98-8 utylbenzene ND ug/L 0.50 1 11/11/15 12:44 98-06-6 n tetrachloride ND ug/L 0.50 1 11/11/15 12:44 56-23-5 obenzene ND ug/L 0.50 1 11/11/15 12:44 108-90-7 oethane ND ug/L 1.0 1 11/11/15 12:44 75-00-3 oform ND ug/L 0.50 1 11/11/15 12:44 67-66-3 omethane ND ug/L 1.0 1 11/11/1512:44 74-87-3 lorotoluene ND ug/L 0.50 1 11/11/15 12:44 95-49-8 lorotoluene ND ug/L 0.50 1 11/11/15 12:44 106-43-4 ibromo-3-chloropropane ND ug/L 1.0 1 11/11/15 12:44 96-12-8 mochloromethane ND ug/L 0.50 1 11/11/15 12:44 124-48-1 ibromoethane (EDB) ND ug/L 0.50 1 11/11/15 12:44 106-93-4 momethane ND ug/L 0.50 1 11/11/15 12:44 74-95-3 ichlorobenzene ND ug/L 0.50 1 11/11/15 12:44 95-50-1 ichlorobenzene ND ug/L 0.50 1 11/11/15 12:44 541-73-1 ichlorobenzene ND ug/L 0.50 1 11/11/15 12:44 106-46-7 lorodifluoromethane ND ug/L 0.50 1 11/11/15 12:44 75-71-8 Ibichloroethane ND ug/L 0.50 1 11/11/15 12:44 75-34-3 Dichloroethane ND ug/L 0.50 1 11/11/15 12:44 107-06-2 Dichloroethene ND ug/L 0.50 1 11/11/15 12:44 75-35-4 1,2-Dichloroethene ND ug/L 0.50 1 11/11/15 12:44 156-59-2 s-1,2-Dichloroethene ND ug/L 0.50 1 11/11/15 12:44 156-60-5 Dichloropropane ND ug/L 0.50 1 11/11/15 12:44 78-87-5 Dichloropropane ND ug/L 0.50 1 11/11/15 12:44 142-28-9 Dichloropropane ND ug/L 0.50 1 11/11/15 12:44 594-20-7 Dichloropropene ND ug/L 0.50 1 11/11/15 12:44 563-58-6 1,3-Dichloropropene ND ug/L 0.50 1 11/11/15 12:44 10061-01-5 s-1,3-Dichloropropene ND ug/L 0.50 1 11/11/15 12:44 10061-02-6 opropyl ether ND ug/L 0.50 1 11/11/15 12:44 108-20-3 ylbenzene ND ug/L 0.50 1 11/11/15 12:44 100-41-4 :achloro-1,3-butadiene ND ug/L 2.0 1 11/11/15 12:44 87-68-3 rropylbenzene (Cumene) ND ug/L 0.50 1 11/11/15 12:44 98-82-8 hylene Chloride ND ug/L 2.0 1 11/11/15 12:44 75-09-2 hyl-tert-butyl ether ND ug/L 0.50 1 11/11/15 12:44 1634-04-4 ihthalene ND ug/L 2.0 1 11/11/15 12:44 91-20-3 ropylbenzene ND ug/L 0.50 1 11/11/15 12:44 103-65-1 'ene ND ug/L 0.50 1 11/11/15 12:44 100-42-5 1,2-Tetrachloroethane ND ug/L 0.50 1 11/11/15 12:44 630-20-6 2,2-Tetrachloroethane ND ug/L 0.50 1 11/11/15 12:44 79-34-5 achloroethene • ND ug/L 0.50 1 11/11/15 12:44 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 11 /13/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 9 of 36 ceMapcal www.pacelabs.com ANALYTICAL RESULTS Clement Pappas 2081.01 ject No.: 92274691 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 MW-7R Parameters Lab ID: 92274691004 Collected: 11/04/15 11:05 Results Units Report Limit DF Received: 11/04/15 15:00 Matrix: Water Prepared Analyzed CAS No. Qua[ iV Analytical Method: SM 6200B ND ug/L 0.50 1 11/11/15 12:44 108-88-3 'nlorobenzene ND ug/L 2.0 1 11/11/15 12:44 87-61-6 hlorobenzene ND ug/L 2.0 1 11/11/15 12:44 120-82-1 hloroethane ND ug/L 0.50 1 11/11/15 12:44 71-55-6 'nloroethane ND ug/L 0.50 1 11/11/15 12:44 79-00-5 thene ND ug/L 0.50 1 11/11/15 12:44 79-01-6 uoromethane ND ug/L 1.0 1 11/11/15 12:44 75-69-4 iloropropane ND ug/L 0.50 1 11/11/15 12:44 96-18-4 iethylbenzene . ND ug/L 0.50 1 11/11/15 12:44 95-63-6 iethylbenzene ND ug/L 0.50 1 11/11/15 12:44 108-67-8 ride ND ug/L 1.0 1 11/11/15 12:44 75-01-4 ne ND ug/L 1.0 1 11/11/15 12:44 179601-23-1 ND ug/L 0.50 1 11/11/15 12:44 95-47-6 3S iroethane-d4 (S) 97 % 70-130 1 11/11/15 12:44 17060-07-0 uorobenzene (S) 100 % 70-130 1 11/11/15 12:44 460-00-4 8 (S) 102 % 70-130 1 11/11/15 12:44 2037-26-5 tal Dissolved Solids Analytical Method: SM 2540C olved Solids 129 mg/L 25.0 1 11/05/15 10:53 !2D Fecal Coliform AVL Analytical Method: SM 9222D forms ND CFU/100 mL 2.0 2 11/04/15 17:00 monia Analytical Method: EPA 350.1 4mmonia ND mg/L . 0.10 1 11/10/15 04:07 7664-41-7 -ogen, N021NO3 unpres Analytical Method: EPA 353.2 Nitrate 8.3 mg/L 0.060 3 11/04/1519:26, )sphorus, Total . Analytical Method: EPA 365.1 us 0.35 mg/L 0.050 1 11/10/15 03:16 7723-14-0 )ride Analytical Method: SM 4500-CI-E 18.0 mg/L 1.0 1 11/10/15 23:36 16887-00-6 ►C Analytical Method: SM 5310B inic Carbon 9.9 mg/L 1.0 1 11/07/15 23:34 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 3/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 10 of 36 ceAnalytical www.pacelabs.com Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Clement Pappas 2081.01 ject No.: 92274691 MW-8 Lab ID: 92274691005 Collected: 11/04/15 11:45 Received: 11/04/15 15:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 5V Analytical Method: SM 6200B ND ug/L 0.50 1 11/11/15 13:01 71-43-2 izene ND ug/L 0.50 1 11/11/15 13:01 108-86-1 oromethane ND ug/L 0.50 1 11/11/15 13:01 74-97-5 hloromethane ND ug/L 0.50 1 11/11/15 13:01 75-27-4 m ND ug/L 0.50 1 11/1111513:01 75-25-2 !thane ND ug/L 5.0 1 11/11/15 13:01 74-83-9 nzene ND ug/L 0.50 1 11/11/15 13:01 104-51-8 benzene ND ug/L 0.50 1 11/11/15 13:01 135-98-8 )enzene ND ug/L 0.50 1 11/11/15 13:01 98-06-6 �trachloride ND ug/L 0.50 1 11/11/15 13:01 56-23-5 izene ND ug/L 0.50 1 11/11/15 13:01 108-90-7 ane ND ug/L 1.0 1 11/11/15 13:01 75-00-3 m ND ug/L 0.50 1 11/11/15 13:01 67-66-3 ethane ND ug/L 1.0 1 11/11/15 13:01 74-87-3 bluene ND ug/L 0.50 1 11/11/15 13:01 95-49-8 bluene ND ug/L 0.50 1 11/11/15 13:01 106-43-4 mo-3-chloropropane ND ug/L 1.0 1 11/11/15 13:01 96-12-8 hloromethane ND ug/L 0.50 1 11/11/15 13:01 124-48-1 moethane (EDB) ND ug/L 0.50 1 11/11/15 13:01 106-93-4 iethane ND ug/L 0.50 1 11/11/15 13:01 74-95-3 )robenzene ND ug/L 0.50 1 11/11/15 13:01 95-50-1 )robenzene ND ug/L 0.50 1 11/11/15 13:01 541-73-1 )rotienzene ND ug/L 0.50 1 11/11/15 13:01 106-46-7 ifluoromethane ND ug/L 0.50 1 11/11/15 13:01 75-71-8 )roethane ND ug/L 0.50 1 11/11/15 13:01 75-34-3 )roethane ND ug/L 0.50 1 11/11/15 13:01 107-06-2 )roethene ND ug/L 0.50 1 11/11/15 13:01 75-35-4 chloroethene ND ug/L 0.50 1 11/11/15 13:01 156-59-2 Dichloroethene ND ug/L 0.50 1 11/11/15 13:01 156-60-5 )ropropane ND ug/L 0.50 1 11/11/15 13:01 78-87-5 )ropropane ND ug/L 0.50 1 11/11/15 13:01 142-28-9 )ropropane ND ug/L 0.50 1 11/11/15 13:01 594-20-7 >ropropene ND ug/L 0.50 1 11/11/15 13:01 563-58-6 chloropropene ND ug/L 0.50 1 11/11/15 13:01 10061-01-5 Dichloropropene ND ug/L 0.50 1 11/11/15 13:01 10061-02-6 yl ether ND ug/L 0.50 1 11/11/15 13:01 108-20-3 :ene ND ug/L 0.50 1 11/11/15 13:01 100-41-4 ro-1,3-butadiene ND ug/L 2.0 1 11/11/15 13:01 87-68-3 benzene (Cumene) ND ug/L 0.50 1 11/11/15 13:01 98-82-8 Chloride ND ug/L 2.0 1 11/11/15 13:01 75-09-2 rt-butyl ether ND ug/L 0.50 1 11/11/15 13:01 1634-04-4 ane ND ug/L 2.0 1 11/11/15 13:01 91-20-3 enzene ND ug/L 0.50 1 11/11/15 13:01 103-65-1 ND ug/L 0.50 1 11/11/15 13:01 100-42-5 :trachloroethane ND ug/L 0.50 1 11/11/15 13:01 630-20-6 :trachloroethane ND ug/L 0.50 1 11/11/15 13:01 79-34-5 -oethene ND ug/L 0.50 1 11/11/15 13:01 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 3/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 11 of 36 ceMa0cal www.pacela6s.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Clement Pappas 2081.01 rject No.: 92274691 MW-8 Lab ID: 92274691005 Collected: 11/04/15 11:45 Received: 11/04/15 15:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual SV Analytical Method: SM 6200B ND ug/L 0.50 1 11/11/15 13:01 108-88-3 ;hlorobenzene ND ug/L 2.0 1 11/11/15 13:01. 87-61-6 :hlorobenzene ND ug/L 2.0 1 11/11/15 13:01 120-82-1 .hloroethane ND ug/L 0.50 1 11/11/15 13:01 71-55-6 .hloroethane ND ug/L 0.50 1 11/11/15 13:01 79-00-5 )thene ND ug/L 0.50 1 11/11/15 13:01 79-01-6 luoromethane ND ug/L 1.0 1 11/11/15 13:01 75-69-4 hloropropane ND ug/L 0.50 1 11/11/15 13:01 96-18-4 iethylbenzene ND ug/L 0.50 1 11/11/15 13:01 95-63-6 iethylbenzene ND ug/L 0.50 1 11/11/15 13:01 108-67-8 ride ND ug/L 1.0 1 11/11/15 13:01 75-01-4 me ND ug/L 1.0 1 11/11/15 13:01 179601-23-1 ND ug/L 0.50 1 11/11/15 13:01 95-47-6 'es )roethane-d4 (S) 97 % 70-130 1 11/11/15 13:01 17060-07-0 luorobenzene(S) 101 % 70-130 1 11/11/15 13:01 460-00-4 18 (S) 99 % 70-130 1 11/11/15 13:01 2037-26-5 )tal Dissolved Solids Analytical Method: SM 2540C solved Solids 396 mg/L 25.0 1 11/05/15 10:53 22D Fecal Coliform AVL Analytical Method: SM 9222D iforms 4.0 CFU/100 mL 1.0 1 11/04/15 17:00 u1 imonia Analytical Method: EPA 350.1 Ammonia ND mg/L 0.10 1 11/10/15 04:09 7664-41-7 rogen, N021NO3 unpres Analytical Method: EPA 353.2 Nitrate 3.0 mg/L 0.020 1 11/04/1519:05 osphorus, Total Analytical Method: EPA 365.1 'US 0.82 mg/L 0.050 1 11/10/15 03:17 7723-14-0 oride Analytical Method: SM 4500-CI-E 21.6 mg/L 1.0 1 11/10/15 23:36 16887-00-6 )C Analytical Method: SM 5310B anic Carbon 15.0 mg/L 1.0 1 11/07/15 23:51 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 3/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 12 of 36 Analytical www.pacelabs.com ANALYTICAL RESULTS Clement Pappas 2081.01 No.: 92274691 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 le: MW-9 Parameters Lab ID: 92274691006 Collected: 11/04/15 14:00 Results Units Report Limit DF Received: 11/04/15 15:00 Matrix: Water Prepared Analyzed CAS No. Qua[ MSV Analytical Method: SM 6200B ne ND ug/L 0.50 1 11/11/15 18:01 71-43-2 benzene ND ug/L 0.50 1 11/11/15 18:01 108-86-1 chloromethane ND ug/L 0.50 1 11/11/15 18:01 74-97-5 dich[oromethane ND ug/L 0.50 1 11/11/15 18:01 75-27-4 form ND ug/L 0.50 1 11/11/15 18:01 75-25-2 methane ND ug/L 5.0 1 11/11/15 18:01 74-83-9 [benzene ND ug/L 0.50 1 11/11/15 18:01 104-51-8 utylbenzene ND ug/L 0.50 1 11/11/15 18:01 135-98-8 utylbenzene ND ug/L 0.50 1 11/11/15 18:01 98-06-6 n tetrachloride ND ug/L 0.50 1 11/11/15 18:01 56-23-5 obenzene ND ug/L 0.50 1 11/11/15 18:01 108-90-7 oethane ND ug/L 1.0 1 11/11/15 18:01 75-00-3 oform ND ug/L 0.50 1 11/11/15 18:01 67-66-3 omethane ND ug/L 1.0 1 11/11/15 18:01 74-87-3 lorotoluene ND ug/L 0.50 1 11/11/15 18:01 95-49-8 lorotoluene ND ug/L 0.50 1 11/11/15 18:01 106-43-4 ibromo-3-chloropropane ND ug/L 1.0 1 11/11/15 18:01 96-12-8 mochloromethane ND ug/L 0.50 1 11/11/15 18:01 124-48-1 ibromoethane (EDB) ND ug/L 0.50 1 11/11/15 18:01 106-93-4 momethane . ND ug/L 0.50 1 11/11/15 18:01 74-95-3 ichlorobenzene ND ug/L 0.50 1 11/11/15 18:01 95-50-1 ichlorobenzene ND ug/L 0.50 1 11/11/15 18:01 541-73-1 ichlorobenzene ND ug/L 0.50 1 11/11/15 18:01 106-46-7 lorodifluoromethane ND ug/L 0.50 1 11/11/15 18:01 75-71-8 'Dichloroethane ND ug/L 0.50 1 11/11/15 18:01 75-34-3 (Dichloroethane ND ug/L 0.50 1 11/11/15 18:01 107-06-2 Dichloroethene ND ug/L 0.50 1 11/11/15 18:01 75-35-4 1,2-Dichloroethene ND ug/L 0.50 1 11/11/15 18:01 156-59-2 s-1,2-Dichloroethene ND ug/L 0.50 1 11/11/15 18:01 156-60-5 Dichloropropane ND ug/L 0.50 1 11/11/15 18:01 78-87-5 Dichloropropane ND ug/L 0.50 1 11/11/15 18:01 142-28-9 Dichloropropane ND ug/L 0.50 1 11/11/15 18:01 594-20-7 Dichloropropene ND ug/L 0.50 1 11/11/15 18:01 563-58-6 1,3-Dichloropropene ND ug/L 0.50 1 11/11/15 18:01 10061-01-5 s-1,3-Dichloropropene ND ug/L 0.50 1 11/11/15 18:01 10061-02-6 opropyl ether ND ug/L 0.50 1 11/11/15 18:01 108-20-3 ylbenzene ND ug/L 0.50 1 11/11/15 18:01 100-41-4 :achloro-1,3-butadiene ND ug/L 2.0 1 11/11/15 18:01 87-68-3 xopylbenzene (Cumene) ND ug/L 0.50 1 11/11/15 18:01 98=82-8 hylene Chloride ND ug/L 2.0 1 11/11/15 18:01 75-09-2 hyl-tert-butyl ether ND ug/L 0.50 1 11/11/15 18:01 1634-04-4 )hthalene ND ug/L 2.0 1 11/11/15 18:01 91-20-3 ropylbenzene ND ug/L 0.50 1 11/11/15 18:01 103-65-1 'ene ND ug/L 0.50 1 11/11/15 18:01 100-42-5 1,2-Tetrachloroethane ND ug/L 0.50 1 11/11/15 18:01 630-20-6 2,2-Tetrachloroethane ND ug/L 0.50 1 11/11/15 18:01 79-34-5 achloroethene ND ug/L 0.50 1 11/11/15 18:01 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 11 /13/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 13 of 36 lceAnalytical www.pacelabs.com Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Clement Pappas 2081.01 )ject No.: 92274691 MW-9 Parameters Lab ID: 92274691006 Collected: 11/04/15 14:00 Results Units Report Limit DF Received: 11/04/15 15:00 Matrix: Water Prepared Analyzed CAS No. Qua[ Sv Analytical Method: SM 6200B ND ug/L 0.50 1 11/11/15 18:01 108-88-3 ;hlorobenzene ND ug/L 2.0 1 11/11/15 18:01 87-61-6 :hlorobenzene ND ug/L 2.0 1 11/11/15 18:01 120-82-1 :hloroethane ND ug/L 0.50 1 11/11/15 18:01 71-55-6 ;hloroethane ND ug/L 0.50 1 11/11/15 18:01 79-00-5 �thene ND ug/L 0.50 1 11/11/15 18:01 79-01-6 luoromethane ND ug/L 1.0 1 11/11/15 18:01 75-69-4 ohloropropane ND ug/L 0.50 1 11/11/15 18:01 96-18-4 nethylbenzene ND ug/L 0.50 1 11/11/15 18:01 95-63-6 nethylbenzene ND ug/L 0.50 1 11/11/15 18:01 108-67-8 hide ND ug/L 1.0 1 11/11/15 18:01 75-01-4 :ne ND ug/L 1.0 1 11/11/15 18:01 179601-23-1 ND ug/L .0.50 1 11/11/15 18:01 95-47-6 `es :)roethane-d4 (S) 100 % 70-130 1 11/11/15 18:01 17060-07-0 luorobenzene (S) 101 % 70-130 1 11/11/15 18:01 460-00-4 l8 (S) 100 % 70-130 1 11/11/15 18:01 2037-26-5 )tal Dissolved Solids Analytical Method: SM 2540C solved Solids 58.0 mg/L 25.0 1 11/05/15 10:54 22D Fecal Coliform AVL Analytical Method: SM 9222D liforms ND CFU/100 mL 1.0 1 11/04/15 17:00 imonia Analytical Method: EPA 350.1 Ammonia ND mg/L 0.10 1 11/10/15 04:10 7664-41-7 rogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Nitrate ND mg/L 0.020 1 11/04/1519:10 osphorus, Total Analytical Method: EPA 365.1 rus 0.45 mg/L 0.050 1 11/10/15 03:19 7723-14-0 oride Analytical Method: SM 4500-CI-E 2.6 mg/L 1.0 1 11/10/15 23:37 16887-00-6 )C Analytical Method: SM 5310B anic Carbon 3.8 mg/L 1.0 1 11/08/15 00:03 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 3/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 14 of 36 Analytical www.pacelabs.com QUALITY CONTROL DATA Clement Pappas 2081.01 No.: 92274691 tch: MSV/34200 Analysis Method: SM 6200B tch Method: SM 6200B Analysis Description: . 6200B MSV iated Lab Samples: 92274691001, 92274691002 BLANK: 1601649 Matrix: Water I Lab Samples: 92274691001, 92274691002 Parameter 2-Tetrachloroethane •Trichloroethane 2-Tetrachloroethane Trichloroethane ichloroethane ichloroethene ichloropropene Trichlorobenzene Trichloropropane Trichlorobenzene Trimethylbenzene ibromo-3-chloropropane ibromoethane (EDB) ichlorobenzene ichloroethane ichloropropane Trimethylbenzene ichlorobenzene ichloropropane ne romethane loromethane momethane rbon tetrachloride lorobenzene iloroethane iloroform iloromethane ,-1,2-Dichloroethene -1,3-Dichloropropene bromochloromethane bromomethane chlorodifluoromethane isopropyl ether hylbenzene Units Blank Result Reporting Limit Analyzed ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 2.0 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 2.0 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 1.0 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND. 0.50 11/08/15 15:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND � 5.0 11/08/15 15:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 1.0 11/08/1515:14 ug/L ND 0.50 11 /08/15 15:14 ug/L ND .1.0 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 Qualifiers Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, :e: 11 /13/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 15 of 36 Analytical www.pacelab&com QUALITY CONTROL DATA Clement Pappas 2081.01 No.: 92274691 BLANK: 1601649 Matrix: Water i Lab Samples: 92274691001, 92274691002 Parameter Toro-1,3-butadiene ylbenzene (Cumene) Ilene tert-butyl ether one Chloride )enzene ribenzene alene e ylbenzene ylbenzene loroethene I1,2-Dichloroethene -1,3-Dichloropropene loroethene lorofluoromethane chloride ichlorcethane-d4 (S) - mofluorobenzene (S) ne-d8 (S) Units Blank Result Reporting Limit Analyzed ug/L ND 2.0 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 1.0 11/08/1515:14 ug/L ND 0.50 11/0811515:14 ug/L ND 2.0 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1.515:14 ug/L ND 2.0 11/08/1515:14 ug/L ND 0.50 11108/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/0811515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 0.50 11/08/1515:14 ug/L ND 1.0 11/08/15.15:14 ug/L ND 1.0 11/08/1515:14 % 102 70-130 11 /08/15 15:14 % 103 70-130 11/08/1515:14 % 100 70-130 11/08/1515:14 RY CONTROL SAMPLE: 1601650 Qualifiers Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Spike LCS . LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,2-Tetrachloroethane ug/L 50 54.7 109 60-140 1-Trichloroethane ug/L 50 56.3 113 60-140 2,2-Tetrachloroethane ug/L 50 53.8 108 60-140 2-Trichloroethane ug/L 50 51.0 102 60-140 -Dichloroethane ug/L 50 52.6 105 60-140 -Dichloroethene ug/L 50 55.8 112 60-140 -Dichloropropene ug/L 50 55.8 112 60-140 ,3-Trichlorobenzene ug/L. 50 56.6 113 60-140 ,3-Trichloropropane ug/L 50 55.2 110 60-140 4-Trichlorobenzene ug/L 50 55.41 111 60-140 4-Trimethylbenzene ug/L 50 54.8 110 60-140 -Dibromo-3-chloropropane ug/L 50 58.0 116 60-140 -Dibromoethane (EDB) ug/L 50 56.8 114 60-140 -Dichlorobenzene ug/L 50 51.9 104 60-140 -Dichloroethane ug/L 50 47.1 94 60-140 -Dichloropropane ug/L 50 51.3 103 60-140 ,5-Trimethylbenzene ug/L 50 54.9 110 60-140 -Dichlorobenzene ug/L 50 52.4 105 60-140 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 11 /13/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 16 of 36 ceAnalytical www.pacelabs.com QUALITY CONTROL DATA Clement Pappas 2081.01 ject No.: 92274691 TORY CONTROL SAMPLE: 1601650 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits )ropropane ug/L 50 52.8 106 60-140 )robenzene ug/L 50 51.3 103 60-140 >ropropane ug/L 50 59.8 120 60-140 oluene ug/L 50 52.9 106 60-140 oluene ug/L 50 52.3 105 60-140 ug/L 50. 52.5 105 60-140 nzene ug/L 50 54.7 109 60-140 oromethane ug/L 50 56.2 112 60-140 hloromethane ug/L 50 54.8 110 60-140 m ug/L 50 57.9 116 60-140 !thane ug/L . 50 55.9 112 60-140 :trachloride ug/L 50 57.5 115 60-140 nzene ug/L 50 51.1 102 60-140 lane ug/L 50 49.1 98 60-140 m ug/L 50 51.4 103 60-140 !thane ug/L 50 56.1 112 60-140 chloroethene ug/L 50 53.0 106 60-140 chloropropene ug/L 50 56.3 113 60-140 :hloromethane ug/L 50 56.9 114 60-140 nethane ug/L 50 53.6 107 60-140 ifluoromethane ug/L 50 56.6 113 60-140 yl ether ug/L 50 53.7 107 60-140 :ene ug/L 50 53.2 106 60-140 ro-1,3-butadiene ug/L 50 64.7 129 60-140 jenzene (Cumene) ug/L 50 54.8 110 60-140 !ne ug/L 100 107 .107 60-140 rt-butyl ether ug/L 50 54.3 109 60-140 Chloride ug/L 50 53.9 108 60-140 nzene ug/L 50 56.3 113 60-140 ienzene ug/L 50 54.8 110 60-140 ane ug/L 50 , 58.1 116 60-140 ug/L 50 53.6 107 60-140 benzene ug/L 50 55.2 110 60-140 ug/L 50 55.7 111 60-140 oenzene ug/L 50 45.6 .91 60-140 roethene ug/L 50 52.2 104 60-140 ug/L 50 52.4 105 60-140 -Dichloroethene ug/L 50. 53.8 108 60-140 Dichloropropene ug/L 50 57.9 116 60-140 ;thene ug/L 50 51.2 102 60-140 luoromethane ug/L 50 57.8 116 60-140 hide ug/L 50 56.9 114 60-140 )roethane-d4 (S) % 98 70-130 luorobenzene (S) % 103 70A 30 M (S) % 99 70-130 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 3/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 17 of 36 ceAnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Clement Pappas 2081.01 ject No.: 92274691 SPIKE & MATRIX SPIKE DUPLICATE: 1601651 1601652 MS MSD 92274262003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual :trachloroethane ug/L <0.25 20 20 21.5 21.1 108 106 60-140 2 :hloroethane ug/L <0.25 20 20 22.9 22.6 114 113 60-140 1 �trachloroethane ug/L <0.25 20 20 20.3 20.8 102 104 60-140 2 :hloroethane ug/L <0.25 20 20 19.9 19.7 100 99 60-140 1 :)roethane ug/L <0.25 20 20 20.8 20.9 104 105 60-140 0 )roethene ug/L <0.25 20 20 23.1 22.9 116 115 60-140 1 )ropropene ug/L <0.25 20 20 22.9 22.5 115 112 60-140 2 •hlorobenzene ug/L <1.0 20 20 21.7 22.1 108 110 60-140 2 •hloropropane ug/L <0.25 20 20 20.9 21.3 104 106 60-140 2 hlorobenzene ug/L <1.0 20 20 20.5 20.5 103 102 60-140 0 nethylbenzene ug/L <0.25 20 20 20.6 20.2 103 101 60-140 2 mo-3-chloropropane ug/L <0.50 20 20 19.9 20.3 100 101 60-140 2 moethane (EDB) ug/L <0.25 20 20 22.1 22.2 111 111 60-140 1 )robenzene ug/L <0.25 20 20 20.8 20.2 104 101 60-140 3 )roethane ug/L <0.25 I 20 20 19.0 18.6 94 92 60-140 2 )ropropane ug/L <0.25 20 20 20.6 20.0 103 100 60-140 3 nethylbenzene ug/L <0.25 20 20 20.9 20.6 104 103 60-140 1 )robenzene ug/L <0.25 20 20 20.8 20.5 104 102 60-140 1 )ropropane ug/L <0.25 20 20 20.6 21.0 103 105 60-140 2 Drobenzene ug/L <0.25 20 20 20.4 20.2 102 101 60-140 1 )ropropane ug/L <0.25 20 20 20.4 20.0 102. 100 60-140 2 oluene ug/L <0.25 20 20 21.4 20.4 107 102 60-140 5 oluene ug/L <0.25 20 20 20.9 20.4 104 102 60-140 2 ug/L <0.25 20 20 21.6 21.1 108 106 60-140 2 nzene ug/L <0.25 20 20 22.0 21.7 110 108 60-140 2 oromethane ug/L <0.25 20 20 22.3 22.5 112 112 60-140 1 hloromethane ug/L <0.25 20 20 21.8 21.6 109 108 60-140 1 m ug/L <0.25 20 20 20.8 - 20.8 104 104 60-140 0 :thane ug/L <0.50 20 20 23.0 23.1 115 115 60-140 1 ,trachloride ug/L <0.25 20 20 23.9 23.7 120 119 60-140 1 nzene ug/L <0.25 20 20 20.7 20.6 104 103 60-140 1 lane ug/L <0.50 20 20 20.2 19.9 101 99 60-140 1 m ug/L <0.25 20 20 20.8 20.7 104 103 60-140 1 'thane ug/L <0.50 20 20 23.5 23.0 118 115 60-140 2 ichloroethene ug/L <0.25 20 20 20.9 21.0 105 105 60-140 0 ichloropropene ug/L <0.25 20 20 21.6 21.1 108 106 60-140 2 :hloromethane ug/L <0.25 20 20 21.3 21.4 107 107 60-140 0 nethane ug/L <0.25 20 20 22.3 21.9 111 109 60-140 2 ifluoromethane ug/L <0.25 20 20 23.5 22.7 118 114 60-140 3 ylether ug/L <0.25 20 20 20.8 20.5 104 102 60-140 1 :ene ug/L <0.25 20 20 20.9 20.8 105 104 60-140 1 ro-1,3-butadiene ug/L <1.0 20 20 18.1 18.8 90 94 60-140 4 benzene (Cumene) ug/L <0.25 20 20 20.5 20.5 103 102 60-140 0 .ne ug/L <0.50 40 40 41.2 41.1 103 103 60-140 0 rt-butyl ether ug/L <0.25 20 20 21.3 21.0 107 105 60-140 2 e Chloride ug/L <1.0 20 20 20.0 20.2 100 101 60-140 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 3/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 18 of 36 ceAnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Clement Pappas 2081.01 ject No.: 92274691 SPIKE & MATRIX SPIKE DUPLICATE: 1601651 1601652 MS MSD 92274262003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual nzene ug/L <0.25 20 20 18.8 18.4 94 92 60-140 2 ,enzene ug/L <0.25 20 20 21.5 20.7 107 104 60-140 4 ane ug/L <1.0 20 20 21.6 22.1 108 111 60-140 2 ug/L <0.25 20 20 20.6 20.7 103 103 60-140 0 benzene ug/L <0.25 20 20 20.0 19.6 100 98 60-140 2 ug/L <0.25 20 20 20.8 21.1 104 106 60-140 2 )enzene ug/L <0.25 20 20 17.2 17.0 86 85 60-140 1 -oethene ug/L <0.25 20 20 21.1 20.5 106 103 60-140 3 ug/L <0.25 20 20 21.2 20.8 106 104 60-140 2 Dichloroethene ug/L <0.25 20 20 21.8.. 21.2 109 106 60-140 3 Dichloropropene ug/L <0.25 20 20 21.7 21.5 108 108 60-140 1 �thene ug/L <0.25 20 20 21.3 21.0 106 105 60-140 1 luoromethane ug/L <0.50 20 20 25.3 24.8 127 124 60-140 2 ride ug/L <0.25 20 20 23.0 22.6 115 113 60-140 1 )roethane-d4 (S) %. 98 99 70-130 luorobenzene (S) % 101 103 70-130 18 (S) % 99 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 3/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 19 of 36 Analytical www.pacelabs.com Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Clement Pappas 2081.01 No.: 92274691 tch: MSV/34233 Analysis Method: SM 6200B tch Method: SM 6200B Analysis Description: 6200B MSV iated Lab Samples: 92274691003, 92274691004, 92274691005, 92274691006 D BLANK: 1602999 Matrix: Water ed Lab Samples: 92274691003, 92274691004, 92274691005, 92274691006 Blank Reporting Parameter Units Result Limit Tetrachloroethane 2-Tetrachloroethane Trichloroethane ichloroethane ichloroethene ichloropropene Trichlorobenzene Trichloropropane Trichlorobenzene Trimethylbenzene ibromoethane (EDB) ichlorobenzene ichloroethane ichloropropane Trimethylbenzene ichloropropane ichlorobenzene Dichloropropane ilorotoluene ilorotoluene zene mobenzene mochloromethane 'nodichloromethane moform momethane bon tetrachloride xobenzene )roethane )roform )romethane 1,2-Dichloroethene 1,3-Dichloropropene ,omochloromethane romomethane ilorodifluoromethane opropyl ether ylbenzene ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 2.0 ug/L ND 0.50 ug/L ND 2.0 ug/L ND 0.50 ug/L ND 1.0 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 5.0 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 1.0 ug/L ND 0.50 ug/L ND 1.0 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 ug/L ND 0.50 Analyzed 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10' 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 11/11/15 12:10 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 11 /13/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 20 of 36 ;eAnalytical www.pacelabs.com QUALITY CONTROL DATA Clement Pappas 2081.01 'ect No.: 92274691 BLANK: 1602999 Matrix: Water d Lab Samples: 92274691003, 92274691004, 92274691005, 92274691006 Blank Reporting Parameter Units Result . Limit Analyzed ro-1,3-butadiene ug/L ND 2.0 11/11/15 12:10 )enzene (Cumene) ug/L ND 0.50 11/11/15 12:10 ne ug/L ND 1.0 11/11/15 12:10 d-butyl ether ug/L ND 0.50 11/11/15 12:10 Chloride ug/L ND 2.0 11/11/15 12:10 nzene ug/L ND 0.50 11/11/1512:10 enzene ug/L ND 0.50 11/11/15 12:10 me ug/L ND 2.0 11/11/15 12:10 ug/L ND 0.50 11/11/15 12:10 )enzene ug/L ND 0.50 11/11/15 12:10 ug/L ND 0.50 11/11/15 12:10 )enzene ug/L ND 0.50 11/11/15 12:10 oethene ug/L ND 0.50 11/11/15 12:10 ug/L ND 0.50 11/11/15 12:10 Dichloroethene ug/L ND 0.50 11/11/15 12:10 Dichloropropene ug/L ND 0.50 11/11/15 12:10 ,thene ug/L ND 0.50 11/11/15 12:10 uoromethane ug/L ND 1.0 11/11/15 12:10 ride ug/L ND 1.0 11/11/15 12:10 Iroethane-d4 (S) % 97 70-130 11/11/15 12:10 uorobenzene (S) % 101 70-130 11/11/15 12:10 8 (S) % 100 70-130 11/11/15 12:10 -ORY CONTROL SAMPLE: Parameter 1603000 Units Spike Conc. LCS Result LCS % Rec :trachloroethane ug/L 50 52.8 106 hloroethane ug/L 50 52.2 104 (trachloroethane ug/L 50 51.7 103 hloroethane ug/L 50 49.8 100 )roethane ug/L 50 48.9 98 )roethene ug/L 50 51.2 102 )ropropene ug/L 50 51.1 102 hlorobenzene ug/L 50 54.6 109 hloropropane ug/L 50 52.5 105 hlorobenzene ug/L 50 54.1 108 iethylbenzene ug/L 50 51.8 104 no-3-chloropropane ug/L 50 52.8 106 noethane (EDB) ug/L 50 54.2 108 )robenzene ug/L 50 50.0 100 Iroethane ug/L 50 45.0 90 )ropropane ug/L 50 48.9 98 iethylbenzene ug/L 50 51.8 104 Irobenzene ug/L 50 51.4 103 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Qualifiers % Rec Limits Qualifiers 60-140 60-140 60-140 60-140 . 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 3/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 21 of 36 Analytical www.pacelabs.com QUALITY CONTROL DATA Clement Pappas 2081.01 No.: 92274691 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 TORY CONTROL SAMPLE: Parameter 1603000 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers hloropropane ug/L 50 50.9 102 60-140 hlorobenzene ug/L 50 49.7 99 60-140 hloropropane ug/L 50 54.6 109 60-140 rotoluene ug/L 50 48.7 97 60-140 rotoluene ug/L 50 50.6 101 60-140 ne ug/L 50 51.5 103 60-140 benzene ug/L 50 52.4 105 60-140 chloromethane ug/L 50 52.5 105 60-140 dichloromethane ug/L 50 53.7 107 60-140 form ug/L 50 56.6 113 60-140 methane ug/L 50 54.0 108 60-140 n tetrachloride ug/L 50 55.8 112 60-140 obenzene ug/L 50 49.8 100 60-140 oethane ug/L 50 45.8 92 60-140 oform ug/L 50 48.2 96 60-140 omethane ug/L 50 44.5 89 60-140 2-Dichloroethene ug/L 50 49.1 98 60-140 3-Dichloropropene ug/L 50 55.2 110 60-140 mochloromethane ug/L 50 54.6 109 60-140 momethane ug/L 50 53.6 107 60-140 orodifluoromethane ug/L 50 57.9 116 60-140 propyl ether. ug/L 50 49.6 99 60-140 �benzene ug/L 50 50.6 101 60-140 chloro-1,3-butadiene ug/L 50 61.6 123 60-140 ropylbenzene (Cumene) ug/L 50 51.6 103 60-140 -Xylene ug/L 100 101 101 60-140 yl-tert-butyl ether ug/L 50 50.8 102 60-140 ylene Chloride ug/L 50 51.4 103 60-146 tylbenzene ug/L 50 52.9 106 60-140 opylbenzene ug/L 50 50.4 101 60-140 hthalene ug/L 50 54.5 109 60-140 Ilene ug/L 50 50.2 100 60-140 Butylbenzene ug/L 50 51.2 102 60-140 ene ug/L 50 54.4 109 60-140 -Butylbenzene ug/L 50 43.0 86 60-140 -achloroethene ug/L 50 49.7 99 60-140 iene ug/L 50 50.3 101 60-140 is-1,2-Dichloroethene ug/L 50 49.3 99 60-140 is-1,3-Dichloropropene ug/L 50 55.7 111 60-140 .hloroethene ug/L 50 50.0 100 60-140 :hlorofluoromethane ug/L 50 55.7 111 60-140 yl chloride ug/L 50 52.6 105 60-140 -Dichloroethane-d4 (S) % 98 70-130 romofluorobenzene (S) % 105 70-130 jene-d8 (S) % 99 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 11 /13/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 22 of 36 r ;eAnalytical www.pacelabs.= QUALITY CONTROL DATA Clement Pappas 2081.01 act No.: 92274691 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ;PIKE & MATRIX SPIKE DUPLICATE: 1603001 MS 92274691003 Spike Parameter Units Result Conc. MSD Spike Conc. 1603002 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Qua] trach]oroethane ug/L ND 20 20 21.0 21.6 105 108 60-140 3 iloroethane ug/L ND 20 20 23.1 22.6 115 113 60-140 2 trach]oroethane ug/L ND 20 20 21.6 22.3 108 111 60-140 3 iloroethane ug/L ND 20 20 19.3 18.6 97 93 60-140 4 roethane ug/L ND 20 20 21.6 21.2 108 106 60-140 2 roethene ug/L ND 20 20 23.5 23.2 118 116 60-140 1 ropropene ug/L ND 20 20 22.8 22.8 114 114 60-140 0 ilorobenzene ug/L ND 20 20 22.3 22.0 112 110 60-140 2 i]oropropane ug/L ND 20 20 22.3 22.7 112 113 60-140 2 ilorobenzene ug/L ND 20 20 21.0 20.8 105 104 60-140 1 ethylbenzene ug/L ND 20 20 21.0 20.7 105 104 60-140 1 no-3-chloropropane ug/L ND 20 20 20.7 20.3 103 101 60-140 .2 noethane (EDB) ug/L ND 20 20 21.2 22.2 106 111 60-140 5 robenzene ug/L ND 20 20 20.3 20.4 102 102 60-140 0 roethane ug/L ND 20 20 18.7 18.5 93 91 60-140 1 ropropane ug/L ND. 20 20 19.8 20.2 99 101 60-140 2 ethylbenzene ug/L ND 20 20 21.0 20.9 105 105 60-140 0 robenzene ug/L ND 20 20 20.6 20.9 103 104 60-140 2 ropropane ug/L ND 20 20 20.5 21.5 103 107 60-140 4 robenzene ug/L ND 20 20 20.3 20.2 101 101 60-140 0 ropropane ug/L ND 20 20 16.7 16.3 84 81 60-140 3 iluene ug/L ND 20 20 20.1 20.6 101 103 60-140 2 iluene ug/L ND 20 20 20.2. 20.4 101 102 60-140 1 ug/L ND 20 20 21.9 21.6 110 108 60-140 2 izene ug/L ND 20 20 21.2 21.6 106 108 60-140 2 xomethane ug/L ND 20 20 22.7 21.9 114 109 60-140 4 iloromethane ug/L ND 20 20 20.8 21.7 104 109 60-140 5 n ug/L ND 20 20 21.1 22.5 105 112 60-140 6 thane ug/L ND 20 20 19.1 20.3 95 102 60-140 6 trachloride ug/L ND 20 20 24.3 23.8 121 119 60-140 2 Izene ug/L ND 20 20 20.8 21.0 104 105 60-140 1 ane ug/L ND 20 20 19.0 19.1 95 95 60-140 0 n ug/L ND 20 20 21.2 20.8 106 104 60-140 2 thane ug/L ND 20 20 21.9 20.1 110 101 60-140 9 ;hloroethene ug/L ND 20 20 21.2 21.0 106 105 60-140 1 -hloropropene ug/L ND 20 .20 19.2 19.3 96 96 60-140 0 hloromethane ug/L ND 20 20 20.6 21.6 103 108 60-140. 5 lethane ug/L ND 20 20 21.7 21.3 108 107 60-140 2 fluoromethane ug/L ND 20 20 22.9 22.4 115 112 60-140 _ 2 yl ether ug/L ND 20 20 21.4 20.8 107 104 60-140 3 ene ug/L ND 20 20 20.8 21.3 104 106 60-140 2 -o-1,3-butadiene ug/L ND 20 20 24.4 23.6 122 118 60-140 3 )enzene (Cumene) ug/L ND 20 20 21.6 22.2 108 111 60-140 3 ne ug/L ND 40 40 42.0 42.5 105 106 60-140 1 t-butyl ether ug/L ND 20 20 21.5 20.9 108 104 60-140 3 Chloride ug/L ND 20 20 21.0 20.4 105 102 60-140 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, V2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 23 of 36 ;eAnalytica( www.pacelabs.com QUALITY CONTROL DATA Clement, Pappas 2081.01 ect No.: 92274691 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 'PIKE &MATRIX SPIKE DUPLICATE: 1603001 MS 92274691003 Spike Parameter Units Result Conc. MSD Spike Conc. 1603002 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD izene ug/L ND 20 20 19.9 19.2 99 96 60-140 3 enzene ug/L ND 20 20 21.2 21.3 106 107 60-140 1 ene ug/L ND 20 20 21.8 21.8 109 109 60-140 0 ug/L ND 20 20 21.2 21.9 106 109 60-140 3 )enzene ug/L ND 20 20 20.4 20.2 102 101 60-140 1 ug/L ND 20 20 21.9 22.6 109 113 60-140 3 ienzene ug/L ND 20 20 17.3 17.3 86 86 60-140 0 oethene ug/L ND 20 20 20.7 21.7 103 109 60-140 5 ug/L ND 20 20 20.4 19.7 101 97 60-140 3 Dichloroethene ug/L ND 20 20 22.0 21.3 110 107 60-140 3 Dichloropropene ug/L ND 20 20 19.9 19.1 99 95 60-140 4 thene ug/L ND 20 20 21.3 21.0 107 105 60-140 2 uoromethane ug/L ND 20 20 23.3 23.1 116 116 60-140 1 �ide ug/L ND 20 20 23.2 22.3 116 112 60-140 4 roethane-d4 (S) % 97 98 70-130 uorobenzene (S) % 105 111 70-130. 8 (S) % 96, 92 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 3/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Qual Page 24 of 36 Analytical www.pacelabs.com QUALITY CONTROL DATA Clement Pappas 2081.01 roject No.: 92274691 tch: WET/41220 Analysis Method: SM 2540C tch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids ated Lab Samples: 92274691001, 92274691002, 92274691003, 92274691004, 92274691005, 92274691006 D BLANK: 1599359 Matrix: Water :ed Lab Samples: 92274691001, 92274691002, 92274691003, 92274691004, 92274691005, 92274691006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers ;solved Solids mg/L ND 25.0 11/05/15 10:45 '(CONTROL SAMPLE: 1599360 Parameter Units d Solids mg/L Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 232 93 90-110 LE DUPLICATE: 1599361 92274375001 Dup Parameter Units Result Result Dissolved Solids mg/L 480 320 PLE DUPLICATE: 1599362 Parameter II Dissolved Solids 92274614001 Dup Units Result - Result mg/L 1260 1140 RPD Qualifiers 40 D6 RPD Qualifiers 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 11 /13/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 25 of 36 ceAnalytica( www.pacelabs.com QUALITY CONTROL DATA Clement Pappas 2081.01 ject No.: 92274691 l: WET/41241 Analysis Method: SM 9222D I Method: SM 9222D Analysis Description: 9222D MBIO Fecal Coliform -AVL :d Lab Samples: 92274691001, ,92274691002, 92274691003, 92274691004, 92274691005, 92274691006 ) BLANK: 1600047 Matrix: Water A Lab Samples: 92274691001,922746910.02,92274691003,92274691004,92274691005,92274691006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers liforms CFU/100 mL ND 1.0 11/04/15 17:00 DUPLICATE: 1600048 92274691003 Dup Parameter Units Result Result RPD Qualifiers liforms CFU/100 mL 136 140 3 u1 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 3/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 26 of 36 ;eAnalytical www.pacelabs.com QUALITY CONTROL DATA Clement Pappas 2081.01 ect No.: 92274691 WETA/25322 Analysis Method: EPA 350.1 Method: EPA 350.1 Analysis Description: 350.1 Ammonia d Lab Samples: 92274691001, 92274691002, 92274691003, 92274691004, 92274691005, 92274691006 BLANK: 1602397 Matrix: Water d Lab Samples: 92274691001, 92274691002, 92274691003, 92274691004, 92274691005, 92274691006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Ammonia mg/L ND 0.10 11/10/15 03:23 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 'ORY CONTROL SAMPLE: 1602398 Spike LCS LCS % Rec Parameter Units Conc. -Result % Rec Limits Qualifiers Ammonia mg/L 5 4.9 97 90-110 'PIKE & MATRIX SPIKE DUPLICATE: 1602399 1602400 MS MSD 92274589001 Spike Spike MS MSD Ms. MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Ammonia mg/L ND 5 5 5.2 5.2 105 105 90-110 0 'PIKE &MATRIX SPIKE DUPLICATE: 1602401 1602402 MS MSD . 92274684001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Ammonia mg/L ND 5 5 5.2 5.2 104 104 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 3/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 27 of 36 .eAnalytical www.pacelabs.com Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Clement Pappas 2081.01 ect No.: 92274691 WETA/25259 Analysis Method: EPA 353.2 Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. d Lab Samples: 92274691001, 92274691002, 92274691003, 92274691004, 92274691005, 92274691006 BLANK: 1599033 Matrix: Water d Lab Samples: 92274691001, 92274691002, 92274691003, 92274691004, 92274691005, 92274691006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate mg/L ND 0.020 11/04/1518:51 I-ORY CONTROL SAMPLE: 1599034 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate - mg/L 2.5 2.5 102 90-110 SPIKE & MATRIX SPIKE DUPLICATE: 1599035 MS MSD 92274437002 Spike Spike Parameter Units Result Conc. Conc. Nitrate mg/L 6.6 2.5 2.5 1599036 MS MSD. MS MSD % Rec Result Result % Rec % Rec Limits RPD Qua[ 8.7 8.7 84 84 90-110 0 M 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 3/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 36 Analytical www.pacelab&com QUALITY CONTROL DATA Clement Pappas 2081.01 No.: 92274691 Iltch: WETA/25271 Analysis Method: EPA 365.1 tch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total ated Lab Samples: 92274691001, 92274691002, 92274691003, 92274691004, 92274691005, 92274691006 BLANK: 1600300 Matrix: Water i Lab Samples: 92274691001, 92274691002, 92274691003, 92274691004, 92274691005, 92274691006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers is mg/L ND 0.050 11/10/15 02:57 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 RATORY CONTROL SAMPLE: 1600301 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers horus mg/L 2.5 2.5 100 90-110 IX SPIKE & MATRIX SPIKE DUPLICATE: 1600302 1600303 MS MSD 92274380002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual phorus mg/L 1.2 2.5 2.5 3.8 3.8 103 105 90-110 1 RIX SPIKE & MATRIX SPIKE DUPLICATE: 1600304 1600305 MS MSD 92274644001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual ;phorus mg/L 1.6 2.5 2.5 4.2 4.1 104 100 90-110 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 11/13/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 29 of 36 Analytical www.pacelabs.com QUALITY CONTROL DATA �roject Clement Pappas 2081.01 No.: 92274691 tch: WETA/25339 Analysis Method: SM 4500-CI-E tch Method: SM 4500-CI-E Analysis Description: 4500 Chloride iated Lab Samples: 92274691001, 92274691002, 92274691003, 92274691004, 92274691005, 92274691006 4OD BLANK: 1603297 Matrix: Water dated Lab Samples: 92274691001, 92274691002, 92274691003, 92274691004, 92274691005, 92274691006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers ,ide mg/L ND 1.0 11/10/15 23:14 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 IRATORY CONTROL SAMPLE: 1603298 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers de mg/L 20 19.9 100 90-110 tIX SPIKE & MATRIX SPIKE DUPLICATE: 1603299 1603300 MS MSD 92275286001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual de mg/L 120 20 20 145 145 126 124 90-110 0 M1 'IX SPIKE &MATRIX SPIKE DUPLICATE: 1603301 1603302 MS MSD 92275296001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua] 'de mg/L 115 20 20 120 117 24 10 90-110 2 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 11/13/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 36 Analytical www.pacelabs.com QUALITY CONTROL DATA Clement Pappas 2081.01 N o.: 92274691 tch: WETA/25299 Analysis Method: SM 531013' tch Method: SM 5310B Analysis Description: 5310B TOC iated Lab Samples: 92274691001, 92274691002, 92274691003, 92274691004, 92274691005, 92274691006 1OD BLANK: 1601596 Matrix: Water :fated Lab Samples: 92274691001, 92274691002, 92274691003, 92274691004, 92274691005, 92274691006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Organic Carbon mg/L ND 1.0 11/07/15 20:34 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 )RATORY CONTROL SAMPLE: 1601597 - Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Organic Carbon mg/L 25 24.4 97 90-110 ZIX SPIKE & MATRIX SPIKE DUPLICATE: 1601598 1601599 MS MSD 92274821001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua] Organic Carbon mg/L 3.3 25 25 28.4 28.4 101 100 90-110 0 RIX SPIKE & MATRIX SPIKE DUPLICATE: 1601600 1601601 MS MSD 92274853001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua] I Organic Carbon mg/L 359 25 25 413 412 216 213 90-110 0 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 11 /13/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 36 Analytical www.pacelab&cam QUALIFIERS • Clement Pappas 2081.01 No.: 92274691 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND -'Not Detected at or above adjusted reporting limit. J - Estimated concentration above the. adjusted method detection Iimii and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) _ Laboratory Control Sample (Duplicate). MS(D) - Matrix Spike (Duplicate) DUP -Sample Duplicate . RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel -Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be.separated from Diphenylarnine using Method 8270. The result reported for each analyte isa combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LYTE QUALIFIERS D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery.not evaluated against control limits due to sample dilution. ul Results based upon colony counts outside acceptable range. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 11/13/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Ia Page 32 of 36 Pace 6cemapical". wwwpacelab&com i QUALITY CONTROL DATA CROSS REFERENCE TABLE Clement Pappas 2081.01 roject No.: 92274691 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ID Sample ID QC Batch Method QC Batch Analytical Method '4691001 MW-4 SM 6200B MSV/34200 '4691002 MW-5 SM 6200E MSV/34200 '4691003 MW-6 SM 6200B MSV/34233 14691004 MW-7R SM-6200B MSV/34233 F4691006 MW-8 SM 62008 MSV/34233 r4691006 MW-9 SM 6200B MSV/34233 '4691001 MW-4 SM 2540C WET/41220 '4691002 MW-5 SM 2540C WET/41220 '4691003 MW-6 SM 2540C WET/41220 '4691004 MW-7R SM 2540C WET/41220 '4691006 MW-8 ' SM 2540C WET/41220 '4691006 MW 9 SM 2540C WET/41220 691001 MW-4. SM 9222D WET/41241 . 691002 MW-5 SM.9222D . WET/41241 4691003 _ MW-6 -SM 9222D WET/41241 4691004 MW-7R SM 9222D WET/41241 4691006 MW-8 SM 9222D WET/41241 4691006 MW 9 SM 9222D WET/41241 4691001 MW74 EPA 350.1 WETA/25322 4691002 MW-5 EPA 350A WETA/25322 . 4691003 MW-6 EPA 350.1 WETA/25322 4691004 MW 7R EPA 350.1 WETA/25322 4691005 MW-8 EPA 350.1 WETA/25322 4691006 MW-9 EPA 350.1 WETA/25322 I4691001 MW-4 EPA 353.2 WETA125259 r4691002 MW-5 ' EPA 353.2 WETA/25259 r4691003 MW-6 EPA 353.2 WETA/25259 14691004 MW-7R EPA 353.2 WETA/25259. F4691005 MW-8 EPA 353.2 WETA/25259 . 74691006 MW-9 EPA 353.2 WETA/25259 74691001 MW-4 EPA 365.1 WETA/25271 74691002 MW-5 EPA 365.1 WETA/25271 74691003 MW-6 EPA 365.*1 WETA/25271 . 74691004 MW-7R EPA365�1 WETA/25271 74691005 - MW-8 EPA 365.1 WETA/25271 74691006 MW-9 EPA.365.1 WETA/25271 7469/001 MW-4 SM 4500-CI-E WETA/25339 74691002 MW-5 SM 4500-CI-E ` WETA/25339 74691003 MW-6 SM 4500-CI-E WETA/25339 74691004 MW-7R SM 4500-CI-E WETA/25339 74691005 MW-8 SM 4500-CI-E WETA/25339 74691006 MW-9 SM 4500-CI-E WETA/25339 74691001 MW-4 SM 5310B- WETA/25299 ,74691002 MW-5 SM 5310E WETA/25299 '74691003 MW-6 SM 5310B WETA125299 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 11 /13/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Analytical Batch Page 33 of 36 Iri �4ceAnalyfical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE roject: Clement Pappas 2081.01 ace Project No.: 92274691 ib ID Sample ID QC Batch Method !274691004 MW-7R SM 5310B !274691005 MW-8 SM 5310B !274691006 MW-9 SM 5310B Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QC Batch Analytical Method WETA/25299 WETA/25299 WETA/25299 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 11/13/2015 02:00 PM without the written consent of Pace Analytical Services, Inc.. Analytical Batch Page 34 of 36 i . CHAIN -.OF -CUSTODY/ Analytical Request. Document M aceAnalytieal ( The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. o i www.pacelabs.com M Section A Section B Section C Page: off a Required Client Infomtation: Roqulred Project1nfonnation: Invoice.lnformation: ( g�1p Company: �tllvnL*flt �r 2tA q Report To: F G Gtf11 Attention: �, l7 t�i iJ 0.0 4 '9 Address: S3i L& W -. {` Copy To: CompanyName:��l1ffrr__ REGULATORY AGENCY � /71 TU H7 �- ✓� S 'w' f12 Nt: ��a Address: 23r Ka w,,.Is�." t/t?Il.r12 N i 1 NPDES . r GROUND WATER' i- DRINKING WATER il To: Purchase.Ofder ►mil enr', me 1. FPhone: No.:. m Paco nuota Reference: } UST r RCRA i OTHER O Fax: Project Z.O-29��33� Name: / j 1 ! -C� L t Lis Pars Project Manager. Site Location n / ` v . Requested Due DatefrAT: S, / Project 4r/INOG Number. �LC�� Pace Prone #: t�J STATE: Requested Analysis Filtered (YIN), Section D Matrix Codes z RoQulrodOliont lnfovnatton MATRIX' /CODE S. o' 'COLLECTED Preservatives. r. Drinking, Water DW 0 z Water... WT Waste Water WW •m; , COMPOSITE START' COMPOSITE ErorcRae o V .. Product P. CO 4 Z SoNSoGd SL SAMPLE ID'., Oil OL: d a. to, -�► (Az as/;) a AR w v a Z Sample IDS MUST BE UNIQUE . Tissue TS - p . a 2 - �" ~ t'^• o t Other OT V X w:' w Z 0, i' ar o y Z. s o+ U _ U m cy t— — W °DATE . TIME DATE TIME Q co o •#• C � N 2 Z = U _ Z tU Z. m M .r O Q. .y �, S U ca 4) Pace Project NoJ Lab I.D. 6. X 2 w` 2 5Sr i X X X .X X pp s w—� ;�f �1 X� K X X X 6 9 10 17 � 12 E 'ADDITIONAL COMMENTS I RELINQUISHED BYIAFFILIATION; DATE CCEPTEDBY'/AFFILIATION DATE TIME SAMPLE CONDITIONS n/ — V0' I i"I GI'1 1 , lj /►7�%7� Av - )�T+IME ;1700 S d- d P-y 6. ORIGINAL $AMPLERNAME AND SIGNATURE o c ^ m 1 Document Name: Sample Condition Upon Document Revised: May 15, 2015 aceAnalyiical� Receipt (SCUR ' Page 'I of 2* Document No.: Document Issuing Authorities: www.pocalebs.coni Pace Asheville Quality Office Client Name: komA----- * Page 2 of 2 is for Internal Use Only wrier (Circle): Fed Ex UPS USPSPCIlent. Commercial Pace Other stody Seal on Cooler/Box Present: [] ye .Seals intact: yes [] no eking Material: ❑Bubble Wrap ubble Bags ❑ None Other I QLQ orrgometer-US d: IR Gun#3-130265963 Type of Ice: Wet Blue None Samples on Ice, cooling process has begun Sun #4 SN:1402903—/-��Other: n'i, Correction Factor: /Add /a6ubtract (1, 2— C rrected Cooler Temp.:~W'.lA C Biological Tissue Is Frozen: Yes No N/A Date and Initials of pers n xaf�Ining- ii I ` ip should be above freezing to 6°C Comments: contents: ain of Custody Present: es ❑No ❑N/A 1. ain of Custody Filled Out: 12 es QNo ❑NIA 2. ain of Custody Relinquished: P4.,0N0 ❑NIA 3. tpler Name & Signature on COC: es ONo ❑NIA 4. Ales Arrived within Hold Time: es ❑No ❑N/A 5. rt Hold Time Analysis (<72hr): es oho ❑N/A 6.� h Turn Around Time Requested: Dyes No ❑N/A 7. Tent Volume: 9 es ❑No ❑N/A 8. ct Containers Used: Ye [:Ill.o ❑NIA 9. ace Containers Used: 12Yesws No ❑NIA iners Intact: 131. ❑No ❑N/A AO, d volume received for Dissolved tests ❑Ye No LLD /A 11. le Labels match COC: Yes ❑No ❑N/A 12. cludes datehimeAD/Analysis Matrix: Mainers needing preservation have been checked. p es ❑No ❑NIA 13. tainers needing preservation are found to be InZY e�s No ❑N/A lance with EPA recoMmendation. ons: VOA, coiiform, C, 8G, wl-DRO (water) Yes ❑No ' pies checked"for dechlorination: Yes ❑No ❑N/A 14. space in VOA Vials (1>6mm): ❑Yes Ko ❑N/A 45. Blank Present: ❑Yes ❑No 16. Blank Custody Seals Present ❑Yes ❑No 7NIA Trip Blank Lot # (if purchased): t Notification/ Resolution: Field Data Required? Y / N Person Contacted: Date/Time: mments/ Resolution: RF Review: Date; 101.5_ W® ; 92274691 5RF Review: Date: i( �-f s Vote: Whenever there is a discrepancy affecting North Carolina II II� II I I� IBIII III ICI :ompliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) OZZ74OUl Page 36 of 36 Attachment B Well Sampling Logs. and Equipment Documentation and Instrument Calibration Data Sheet Ai.TAl4 ONO EN viRoNmF-NTAL, INN PSI PAYWOOD STRCET. Asti.rY7LLE, NC 2B$01' 'rn l„Ei88.281.3:i '30 Fq c.B28.2e 1. S351 W4'/LV. hI.'rA MPN7�KVIgpNNEKTii L.GpM Well Sampling Log 'ROJECT NAME: Clement Pappas 'ROJECT NUMBER: 2081.01 :AMPLINGPERSONNEL: ALeSueur DATE: 11/4/2015 WEATHER: CCj SAMPLETIME: Ih DELL NUMBER: 1m t.y i�L WELL DEPTH IN FEET (WD): I . G'd' YELL DIAMETER: 19 V. WATER LEVEL IN FEET (INQ: G, q 1'PE OF CASING: I/G LENGTH OF WATER COLUMN: FEET EASURING POIN.J; ® (WD)- (WL) c (LWC) USH MOUNT STICKUP ONE CASING VOLUME: l j 9kq GALLONS ViMENTS: (LWC) x (WCV) THREE CASING VOLUMES: GS GALLONS ACTUALVOLUME PURGED: GALLONS WELL CASING VOLUMES (WCV) 1" = 0.041 Galj Ft 2" - 0.17 Gal/Ft 3" - 0.38 Gat/Ft 4" = 0.66 Gai/Ft 6" = 1,5 GaVFt 8" = 2.6 Gal/Ft 12" = 5.8 GaI/Ft iE METHOD: BAILER-DISP. BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: ALE METHOD; DAILER-DISP, BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: ING TIME GALLONS PURGED TEMP (IC) SPECIFIC COND. (tlS/cm) DISSOLVED OXYGEN (Ing/L) PH (S.U.) report to 0.1 S.U. OXIDATION REDUCTION POTENTIAL (mV) TURBIDITY (NTU) COMMENTS S' L( 4650 ^, 0 7? �-rf) 3 64 q' 52,1 0 PLING CONTAINER NUMRFER OF CONTAINERS REQUESTED ANALYSIS niL PLASTIC mLPLASTIC �SiU P K i 1 nL PLASTIC rSS / mrt'r� re L GLASS '7 _ 7 v r LA SER ° C - cde' ees Celsius ItS/enl - micro-Siemen per centimeter mg/L= milligrams per liter S.U. - Standard Units mV = millivolt NTU = nephelametric turbidity units Samples are analyzed immediately upon collection. l f gill E NG,1 N E E R 1 N - G Be H Y p ROC4Eo LOGY 231 HAYWOOD STHEET, AsnEYILLK. NC 2131301 rr:t.&7.8,281.33Ei0 Pgr_.826.?p1.3351 W�VW.ALTAMoNrar4viRoND3[LNTAL.COM Well Sampling Log PROJECT NAME: Clement Pappas PROJECT NUMBER: 2081.01 SAMPLING PERSONNEL: ALeSueur DATE: 11/4/2015 WEATHER: SANIPLE TIME, i2 WELL NUMBER: /V><t+/ S WELL DEPTH IN FEET (WD): I "� WELL DIAMETER: WATER LEVEL IN FEET (WL): T LENGTH OF WATER COLUMN : FEET TYPE OF CASING: la4it; MEASURING POINT: TO MD) - (WL) _ (LWC) f '7 =LUSH MOUNT/STICK UP ONE CASING VOLUME: (1 GALLONS COMMENTS: (LWC) x (WCV) THREE CASING VOLUMES: *� GALLONS ACTUAL VOLUME PURGED: r 0 GALLONS WELL CASING VOLUMES (VeCV) 1' = O.0T16a(/Ft 2° = 0.17 GgVFT 3' = 0.38 GC- VR A" = 0.66 Gal/Ft 6" =1..5 Gal/Ft 8' 2.6 GaVFt PURGE METHOD: BAILER-DISP.BAILER•TEFLON DEDICATED PUMP WHALE PUMP, GRUNDFOS OTHER: SAMPLE METHOD: BAILER-DISP._ B.AILER-TEFLON DEDICATED PUMP WHALE PUMP GRUh1DFOS O7hIER: READING TIME G1NLLONS TEMP SPECIFIC DISSOLVED pH OXIDATION TURBIDITY PURGED ( °(%) 1 COND OXYGEN (S.U.) REDUCTION (NTU) 3 k,o i a A J (0 C) , 5 6 7 E 9 10 SAMPLING CONTAINER 50'D mL PLASTIC 25 0 mL PLASTIC 145 mL PLASTIC lCt mL GLASS 1 L GLASS 4HER ' OTECTIVE CASING:r rf PAD: G 1� piing personnel Signature: (ug/Gmj (mg/L) report to 0.1 S.U. POTENTIAL (mV) /J S V L L 11� i Lr G2- r !/ r.20 , �i l G- 77 2 ?6v---yy, ci 10, •TZ S.�� r 2- 57, Z NUM BEP OF CONTAINERS REQUESTED ANALYSIS d- S -Z I -C ]CK:LL VEGETATION&If ACCESS: J L) � Date: 1 11q Notes: 3C = degrees CGISIU5 pS/cm - micro-Slemen per centimeter mg/L o milligrariis. per liter S.U. = Standard Units mV- millivolt NTU = nephelometric turbidity units Samplesare analyzed immediately upon collection. Pffumplates0i') Drilling Forms%Well Sampling Lod.xls 12' - 5.8 Gal/Ft COMMENTS Page 1 611 • E iNGI NEERIN0 & 1-1 YUA0GE0LOGY 291 11AYWOOD STREET, ASFIEVILLE. FTC 2B001 TF1.,878,201.3350 rAc,828.281.S331 WWIY. ALTA PIC PIT CNV in ON M ENT AL. CC l•1 Well Sampling Log PROJECT NAME: Clement Pappas DATE: 11/4/2015 PROJECT NUMBER: 2081-01 WEATHER: 6r0 , C SAMPLING PERSONNEL: ALeSueur SAMPLETIME; • e WELL NUMBER: Mw- 6 WELL DEPTH IN FEET (WD): I �i- I WELL DIAMETER: WATER LEVEL IN FEET (WL): TYPE OF CASING: Pyc LENGTH OF WATER COLUMN: G. f'7 FEET MEASURING POINT I-cr_ (WD) - (WL) = (LbVC) 3 LUSH IJ,OUNT 571CK UP. ONE CASING VOLUME: + 0 GALLONS COMMENTS: (LbVC) x (WGV) THREE CASING VOLUMES: GALLONS ACTUALVOLUME PURGED: -3, GALLONS WELL CASING VOLUMES (WCV) 1 = 0.0�{10n1jFt Q•.17 Gal/Fc 3° = 0.38 Gal/Ft A 0.66 Gal/Ft G 15 GBI/R. 8' = 2.G Gal/Ft 12' — 5.8 Gal/Ft PURGE METHOD: BAILER-DISP. ' AILER-TEFLON _ DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: A1LER-DISP_,/BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: READING TIME GA1 L-OPTS TEMP SPECIFIC DISSOLVED pH OXIDATION TURBIDITY COMMENTS PURGED (°C) COND, OXYGEN (S.U.) REDUCTION (INTU) (hS/cm) (rng/L) report to POTENTIAL 0.1 SLU. (mV) G' . I , ri f' ,:� z J-2 1.3 � �Sr 4 (006 3.75 S + 84 613? 8 Y 8 10 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 500 mL PLASTIC —F7�, 250i mL PLASTIC +? C p;-,-dP 1(-4 n-1RE.Plr CD 1251 mL PLASTIC ( Dmm n; d?r±S pbomys 'A 1 L LASS OTH ER PR TECTIVE CASING:O PAD: _ LOCK: U l VEGETATION: U ACCESS: O(( a pling Personnel Signature: �' f �y,,�^ Date: Nntes: °C n degrees Ce(slus IiS/cm - micro-Siemen per centime_er mg/L = milligrams per liter S.U. a Standard Units mV= millivolt 11111.1 � nephelometrlc turbidiLy units Samples are analyzed immediately upon collection. P:1TempiateslG'N Drilling Form 001cH Sampling Log,xls Page 1 o.I'I .* I E N G1 N. E E- R I N G & .H Y 0 .4 O G E O L O G Y 251 HAY'NOou STRr;cT, rt5HFV1l.l,v. NC 28801 TFL.828,28T,3350 FAC.828.201.8351 www. A LYA M ON`TCNV I R D NM ENTA L. CO WWII Sampling L6g e PROJECT NAME Clement Pappas i PROJECT NUMBER: 2081.01 SAMPLING PERSONNEL: ALeSueur DATE: 11/4/2015. VtiIEATHER: i1'S c / - SAMPLETIME: WELL NUMBER: WELL DIAMETER: TYPE OF CASING: Ptk MEASURING POINT: Tp(, 'LUSki (MOUNT TIGK UP COTAIAENTS: WELL DEPTH IN FEET (WD):(�-i WATER LEVEL IN FEET (VI-0: i 1 Ll LENGTH OF WATER COLUMN, Jt� FEET (WO) - (WL) _ {LWCj -- ONEC�ISING VOLUME: f.q GALLONS (Lvvc) z (WCV) 7 THREE CASING VOLUMES: GALLONS ACTUAL VOLUME PURGED: T, 2- 5— GALLONS S' _ 0.041.Ga1' 2" WELL CASING. VOLUMES (WCV) D.17 Gal/Ft . 3" = 0,38 Gal/Ft 4' = 0.66.Ga1/Ft 6' = 1.5 GaljFt S" = 2.6 Gal/Ft 12" =5.8 Gal/Ft PURGE METHOQ: JLE -bISP BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: IPAILER-D P. BAILER-TEFLON DEDICATED PUIYIP WHALE PUMP GRUNDFOS OTHER: READING 1 TIME GALLONS PURGED TEMP (°C) SPECIFIC COND. "Ps/cm) DISSOLVED OXYGEN (mg/L) pH (S.U.) report to 0.1 S.U. OXIDATION REDUCTION POTENTIAL (111V) TURBIDITY -(NTU) CDMMENTS L x 1 -I,'72 G'� 3 • � ' ;;"I too G 7 Ira 10 -z':,AMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS il- PLASTIC L PLASTICL PLASTIC ') „le1,tL GLASS VO = 2 U' . LASS I R ECTIVECASING: �- PAD:O LOCK: ''C VEGETATION: DiACCESS:ring Personnel Signature: 4�&A Date: I V,/ r I (es: °C=degrees CElsius IiS/cm = microSiemen per centimeter mWL = milligrams per liter Standard Units mV a millivolt NTU = neplielometric turbidity units Samples are analyzed immediately upon collection. P:1TernplaleslGW Drilling FormOWell Sampling Lo6.xls Page 4 of 1 E MG114EEFf-1(Vfi, & II YonocCoL.9G.Y 231 HAYY/000 S'rRE FVT. A5HE"VILLL. NC 28801 iri-ap-7.291.3556 rn�.828.291.3351 1YW 11'. /.L7A MONT 6N YIIiDNhICNTA L.GOM Well Sampling Log PROJECT NAME: Clement Pappas DATE: i1/4/2015 PROJECT NUMBER: 2081.01 WEATHER: 05 L pUt' t SAMPLING PERSONNEL: ALeSueur SAMPLE TIME: (� WELL NUMBER: WELL DEPTH IN FEET (WD): i 3,'K- WELL DIAMETER: 2" WATER LEVEL IN FEET (WL): 7. Z TYPE OF CASING: V6 LENGTH OF WATER COLUMN: (�„ % �( FEET MEASURING. POINT: '-dC (WD) - (WQ � (LWC) FLUSH MOUNT STICK-U ONE CASING VOLUME: I 14` (� GALLONS COMMENTS: ) Lo(-I( ads -1.0 6", ait�JIGII.(�ll (LWC) x (WCV) � THREE CASING VOLUMES: } G GALLONS ACTUAL VOLUME PURGED: GALLONS WELL CASING VOLUMES (WCV) 11 = 0.0111 Gal/Ft 2" = 0.17 Gal/Ft 3" = 0.3B Gal/Ft 411= 0.66 Gal/Ft 6" -1.5 GaVFt 8" - 2.6 Gal/Ft 17 = 5.8 Gal/Ft, PURGE METHOD: BAILER-DIS_P. BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: BAILER-DISP. BAILER TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: _ READING TIME GALLONS TEMP SPECIFIC DISSOLVED pH OXIDATION TURBIDITY COMMENTS PURGED {°C) COND. OXYGEN (S.U.) REDUCTION (NTU) { is/cm) (mg/L) report to POTENTIAL 0.1 S.U. (111V) "( k3 % 3.1-3 Ott- 5 6 7 8 9 - 10 - SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS ;500 mL PLASTIC /_ 71) j 250 mL PLASTIC 2 Cti r,,-A1 + r C•o Cot: 125 mL PLASTIC r /mma 0 kwry 1;.1 40 mLGLASS 1. L GLASS OTHER PR �TECTIVE CASING: L PAD: 0( LOCK: ?-/s VEGETATION:. ACCESS: o� a piing Personnel Signature:f Date: (��r otes: °C - degrees Celsius pS/mn - microSlernen per.pontlmeter:; mg/L = milligrams pet' liter S.U. - Standard Units mV = millivolt m7U = nephelornetrio turbidity units Samples are analyzed immediately upon collection. PATcmptateslGby Rrilling FormslWoll Sampling Log.xls Page 1 of i • i 13 E (JG IN E ER I N G a H YDR04E0LrO'G�Y —� 231 HnYtvoon STREET, AsHEVILLE, NC 201301 T li l..8?.$.281.539G nc�.B 2i3.2H1.3351 LY W W.ALTAh10NTCt4VIRDHMENTAL.COM Well Sampling Log PROJECT NAME: Clement Pappas PROJECT NUMBER: 2081.01 SAMPLING PERSONNEL: ALcSmir DATE:11/4/2015 WEATHER: 'i rlolA SAMPLETIME: 1 r-10 f WELL NUMBER: WELL DIAMETER: 7 k% TYPE OF CASING: PUG MEASURING POINT: FLUSIi MOUNT% TICK -UP COMMENTS: I�, r� r' J('1 F fc V'` tiJ (' 1 lv e (1i,� 1rI/ l f z7 f—P C a 1t WELL DEPTH IN FEET (WD): Jfr, WATER LEVEL IN FEET (WL): J 21 9 LENGTH OF WATER COLUMN.: 15,21 FEET (WD) -(WL) = (LWC) ONE CASING VOLUME: t i 14 GALLONS (LVJC)X (WCV) THREE CASING VOLUMES: 7GALLONS ACTUALVOLUME PURGED: A,-2 16 GALLONS WELL CASING VOLUMES (WCV) 1" - 0.041 GaII/Ft 2" = 0.17 GaVFt 3" = 0.38 GaVFt 4° - 0.G6 Gal/Ft o` = :1..5 Gal/Ft 8' = 2.G Gal/Ft h" = 5.8 Gal/Ft J PURGE METHOD: BAILER-DISP. BAILER-TEFL4_N PUMP PUMP GRUNDFOS OTHER: _ SAMPLE METHOD: BAILER-DISP. BAILER-TEFLON _DEDICATED DEDICATED PUMP _WHALE WHALE PUMP GRUNDFOS OTHER: READING TIME GALLONS PURGED TEMP (°C) SPECIFIC COND. (PS/cm) DISSOLVED OXYGEN (mg/L) pH (S.U.) report to 0A S.U. OXIDATION REDUCTION POTENTIAL (mV) TURBIDITY (NTU) COMMENTS 2 i223 , G ,V c� , fi �. 7M 7-121 L( S-�-�` -1 r 3 4 Jr ` Lt {/ ✓`�, to r.. V ( 1 f `t ... V ✓-J -�1 �i7' (' L�� i�E'y 7 9 I _ 10 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 500 mL PLASTIC 250 mL PLASTIC 117 125 mLPLASTIC 40 mLGLASS 7 �C► _ j 1 L GLASS OTHER PRQTECTIVE CASING:_ PAD: C ! ( LOCK: 0 rc VEGETATIONQ t� ACCESS: ' Sa pling Personnel Signature: ," f�L% Date:�j% 1 1 Notes: " C = degrees Celsius pS/om = micro-Slemen parcentimeter mg11L = milligrams per liter S.U. = Standard Units mV = millivolt NTU - nephelometric tufbid! ty units Samples are analyzed immediately upon collection. P.VemplakslG�'J priliing FormstlNeli Sampling Log.Xls Page 1 br "1 ALT11.MONT ENVIRONM,EN'�',t1Ly INC.- . 231 HAYWOOD SYHt@Y,'ASHEYILLE: NC 286D1 T E L. 020,a©1. 33 L 0 FA C. 828, 281 .3351 W W W.A LY/1 M a NY C N.V r rfONN CNY A L. CON Well Gauging Log PROJECTNAME; gm-eri �+. 1� PROJECTNUMBER: Z08j G1 LOCATION: Ht aerS v i fi . ,/ L DATE: SAMPLIiNG Pf;RSONNEL: A�c5L i1 WEA*ER: C� COMMENTS: Well ID DTW (feet) Notes "7 ,1 W Sampling Personnel Signature: Date: rlf�jr�r GATempluteMW & Drilling Ponns%latcr Lcvcl Gagging Lug l'tpc I or i C N G I tl L' G•R I N G _&� t-t Y.n r( v a E a L o [i Y' .^.3r MAY .YOil tl .r'il pl: C.f. hArIC VILI_[, NC: 21l IlOt t CL,�J 2O.201.98ua PAC.F7 ^a,2B1.73u1 1V W�1'.h 6TA t1PNT[t fl YIMbN NCt1YA LroON Equipment Documentation & Instrument Calibration Data Sheet CaBbratlon Documentatfon FroJect Name: G e S t✓ Person Conducting Calibration: 191 Lf e FroJect Number: o j 6f Date of Calibration`' Prv)ect Locatloh: 160Ar1ftrVAri1lLWt*, W. Date of Field Meas'.rrernents: l i OliC- Equipment Documeritatfon Equipment or meters used to take measurements (e.g. water level meters; sun -ay equipmont, etc;): Equlpment Typo Serial Number Brand Date afUse A50-ftWater Level 26154 solinist iso-ih Wirtor Level '22754 Sollnist i50-ft bYeter Level 150 Tostwall 150-ft Dravrdown NIP30.1527 QPD Other E4 I t Micro TOW Turbidity Meter Calibration Standards Drp Date Instrument Serlal #t Instrument Reading 0.02 NTU 10.0 NTU 1000 NTU - 200601045 initial � Initial* Initial' (rad Cal:. Cal:. !0: II Cal: ��Od Time. f1 jTime: 6d VT lime: iD 1.-t i YSI SN Multipararneter Meter Instrument Serial Number 070100979 Instrument Readings Celibrallon 4piratlon Date DlssaIved Oxygen Initial; 133 Cal: � Mess; mm)i Mid Day Time; Timy I Check: Plot Time: Check: NA NA QC AM Time; pH 7 S.U. report fa Initiali pHm!" Cal: pHmV: Time: pH 4 S.U. report to o.x pFl 10 S.U. repo,-t to 0.1 S.U. Initial: Initial; pHmV" pHmV: Cal; ► G� C 1131 pHmV; —j pHmV. Time: Time; QC*IcH7S.U.repor7 tao.iS.rJ. Ah9Time: mews:. Mid Day Time: Check: RVI,TIma: Check: SpeaXond. 447/84/23 mS** Initial: Cal: �a�� . Time:, �( QC*.84 m$ AP+I Time:&j. I Nloas• Mid Day Time: Check:. PM Time: Check: 0RP 200 ro Initial:Z Cal; 5?, 6 (Time: I Notes: t f r 2. Electronic cquipmeril'calibrat.d accordirg to the manufacturer's operation manual. 2. Speoiffc Conductivity should be calibrated according to values representative of filMoric range. 3. Order of Calibration Is as foilbw$ : Specific Conductivity, pl-I 7, p,4'4, p`i 2.010RF, QC chocks. 4. Q.-Acceptable Ranges; lay +/- 0.1 S.U. and Specific ConductiJfly 10Y5 of the true "clue. [f readings are cut of these ranges, meter needs to be recalibrated. , 5. * Indicates that a f C chul< must be performed Iri the morning, ajtarnoon, and the end of the flay, or every four hours. 6. ** Indicates to choose a Spa -,!flu Conductivity buffer of 447, 84, or 23 mS wlileh Is closest to historieaLreadings horn the project location. F;ITq_meratesVG'N•6fI1lInF.Forms\CalilirationM aShmtYS1553Pev2.als p.nnp nr Attachment C . DEQ GW-59A Compliance Report Form GW-59A COMPLIANCE REPORT FORM Permit # WQ0004797 (Srtbmit one each monitoring period with Gl f� -59 farms.) j Enter date monitoring results were due. (12/31/2015) Will this monitoring report (GW-59 and GW-59A) YES NO be submitted after the established due date? X Z Was any required information missing on the GW-59 report forms? YES NO 1F the answer to question 9 or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? If the ansiver is "I es ", contact the Regional Office for guidance. X The lock on monitodngweil MW-8 is broken and will need to be replaced. 4 Are any monitored constituents equal to or above the established standards? YES NO If the answer to question 4 is `NO", skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituents) and concentration(s) exceeding standards in the space provided below. MW-8: Total Organic Carbon =.15.0 mg/L; MW-5: Fecal Coliform = 7.0 CFU/100 mL; MW-5: Tetrachlorethene = 26.1 ug/L; MW-6: Fecal coliform = 136 CFU/100 mL; MW-8: Fecal Coliform = 4.0 CFU/100 mL Total Organic Carbon Limit = 10 mg/L; Fecal Coliform limit =1.0 CFU/100 mL; Tetrachloroethene limit = 0.7 ug/L. ' 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? X ' If the answer to question 5 is "NO", skip to section 8. . If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). Fecal Coliform (limit= 1 CFU/100 mL)-11/18/2014: MW-5=6.0 CFU/100 mL; MW-6 =13.0 CFU/100 mL; 5/22/2014: MW-6=1.0 CFU/100 mL 11/20/2013: MW-5 =1.0 CFU/100 mL Total Organic Carbon (limit =10 mg/L)-5/13/2015: MW-8 = 19.7 mg/L . 11/18/2014: MW-8=54.0 mg/L; 5/22/2014: MW-8=17.6 mg/L;11/20/2013: MW-8=21.0 mg/L Tetrachloroethene (limit = 0.7 ug/L) - 11/18/2014: MW-5 =121 ug/L;11/20/2013: MW-5 = 332 ug/L ( Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO if the answer is "YES". a groundwater quality problem maybe occurring. CONTACT THE REGIONAL. OFFICEiMMEDIATELYFOR GUIDANCE. If the answer is "NO", monitoring wells maybe improperly located, contact the Regional Office. MW-5 and MW-8 are beyond the review boundary. MW-6 is not. 7 is the permittee implementing previously approved actions required by the Division involving this IT, NO groundwater quality problem? X If the answer to question 7 is "YES', describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days; an evaluation may be required to determine the impact the waste disposal system is having at the review and com)olfance boundaries surrounding this facility. Failure to do so may subject the vermittee to a. Notice of Violation, fines, andlornenalties. Fecal coliform was detected in MW-5 during the November 2014 sampling event as well as the November 2013 sampling event. Fecal coliform was last detected In MW-8 during the May 2013 and May 2012 sampling events. Tetrachloroethene has been detected in M W-5 during every November sampling event since November 2002. The concentrations of tetrachloroethene have been trending downward since the initial detection in 2002. Total Organic Carbon (TOC), VOC, and SVOC analyses were completed for all samples during the May 2007 groundwater sampling event. TOC concentrations are not attributable to VOCs or SVOCs and is possibly naturally occurring. g The person completing this portion (GW-59A) of the monitoring report should sign below and submit this form with GW-59 forms forrequired wells to the apfdress provided at the top of the current GW-59 form. it hereby ackn get at th ab v mformat n as evaluated and the information submitted iri this i ' report (Co Lance Qrt G is true a d omplle a to the best of my knowledge Z'21h- Signat Lr/of Permittee (o Auth rued Agent) Date Gll`-9A 12/8/2003 Attachment D DEQ GW-59 Groundwater Quality Monitoring: Compliance Report Forms rROUf4DWATER QUALITY MONITORING: OMPLIANCE REPORT FORM Facility Name: Clement Pappas Permit Name (if different): Facility Address: 125 Industrial Park Hendersonville (street) NC 28792 County Henderson Contact Person: Mr. Blake Kehoe Telephone#: 828 - 6 9 3 - 0 711 Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 PERMIT Number: Expiration Date: 0 8/ 31 / 2 0 2 C Non -Discharge WQ 0 0 0 4 7 9 7 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ® Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: WELL ID NUMBER (from Permit): - 4 sample collected: 11 / 04 / 2 015 FIELD ANALYSES: Well Depth: 18 . 6 0 ft. Well Diameter: 2 in. pH 00400: 6. 07 units Temp. 000lo: 16 . 53 eC Depth to Water Level 82546: 6 . 93 ft. below measuring point Screened Interval: 8*ft. t016.1*ft. Spec. Cond. 00094: 165 µMhos Measuring Point is 2 . 43 ft. above land surface Relative M.P. Elevation: 2063.77 none ft. Odor 000s5: Volume of water pumped/bailed before sampling: 6.0 gallons screenea interval is relative to land Surfac'Appearance Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO IT vuCLLDate WAS DRY at time of sampling, check here:❑ LABORATORY INFORMATION Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal31616 <2 0 /100mL `l Nitrate (NO3) as N 00620 <0 . 020 mg/L Zn - Zinc 01092 m9 /L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.10 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): )issolved Solids:Total 70300 139 mg/L AI -Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC oomo 6.6 mg/L Ca - Calcium 00916 mg/L Chloride o0940 6.2 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury'71900 ug/L Lab Report Attached? ® Yes (1) ❑ No (0) Specific Conductance o0095 µMhos K - Potassium 00937 mg/L VOC 7873 method # 6200 Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn -Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L ' Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev. 8/2013 GROUNDWATER QUALITY MONITORING: mm f 1 GOMPL' IANCE REPORT FORM I i Please Print Clearly or Type FACILITY INFORMATION Y YP Facility Name: Clement Pappas Permit Name (if different): Facility Address: 125 Industrial Park Hendersonville (street) NC 28792 County Henderson (City) (State) (Zip) Contact Person: Mr. Blake Keho e Telephone#: 8 2 8- 6 9 3- 0 711 Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 UNIT ERMIT Number: Expiration Date: 0 8/ 31 / 2 0 2 0 on -Discharge WQ0004797 UIC PDES Other YPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ER Spray Field ❑ .Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: --�mra uw uvrvrttvts�t tvry MW- 5 WELL 1D NUMBER (from Permit): Date sample collected: 11 / 04 /2 015 FIELD ANALYSES: If WELL WAS Well Depth: 18 . 60ft. Well Diameter: 2 . in. pH 00400: 5 .58 units Temp. 000lo: 16 . 68 °C DRY at Depth to Water Level 82546: 8 _ 12 ft. below measuring point Screened Interval: 9 * ft. to 19 * ft. Spec. Cond. 00094: 105 µMhos time of Measuring Point is 3 . 00 ft. above land surface Relative M.P. Elevation: 2085.60 ft. Odor o0085: none sampling, check Volume of water Um ed/bailed before sampling: 6 . 0 P p p g: gallons *screened interval is relative to land surface Appearance here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES El NO i e,z2,ATnov TK1Cn13eeTT r%K1 Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Coliform: MF Fecal 31616 7.0 /100mL Nitrate (NO3) as N 00620 < 0 . 0 2 0 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.21 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 m9 /L )issolved Solids:Total 70300 68.0 mg/L Al - Aluminum oilo5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug1L TOC 00680 7.3 mg/L Ca - Calcium o0916 mg/L Chloride 00940 20.3 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L Phenol. 32730 ug/L Fe - Iron 01045 ug/L Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Specific Conductance 00095 µMhos K - Potassium 00937 mg/L Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L TKN as N 00625 mg/L Ni - Nickel 01067 ug/L Certification No. 37712 Pb - Lead 01051 ug/L Zn - Zinc 01092 mg/L Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? ® Yes (1) ❑ No (0) VOC 7873 method # 6200 method # method # method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.8/2013 LCOMP!IOUNDWATER QUALITY MONITORING: LIANCE REPORT FORM or Facility Name: Clement Pappas Permit Name (if different): Facility Address: 125 Industrial Park Hendersonville (street) NC 28792 County Henderson (City) (state) OD) act Person: Mr. Blake Kehoe Telephone#: 8 2 8 - 6 93 - 0 711 Location/Site Name: Irrigation Area No. of wells to be sampled: 6 PERMIT Number: Expiration Date: 0 8/ 3.1 / 2 0 2 0 Non -Discharge WQ 0 0 0 4 7 9 7 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery FX Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: - -.... _........._.. MW-6 WELL ID NUMBER (from Permit): Date sample collected: 11 / 04 /2 015 FIELD ANALYSES: Well Depth: 11 . 54ft. Well Diameter: 2 in. pH 00400: 5.37 units Depth to Water Level 82546: 5 . 18 ft. below measuring point Screened Interval: 5 * ft. to 10 * ft. Spec. Cond. o0094: Measuring Point is 3 . 0 0 ft. above land surface Relative M.P. Elevation: 2061.17 ft. Odor 00085: none Volume of water pumped/bailed before sampling: 3 . 75 gallons screened interval is relative to land surface 9 Appearance Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO ite sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services kRAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Coliform: MF Fecal 31616 136 /100mL Nitrate (NO3) as N 00620 2.9 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.12 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L solved Solids:Total 70300 58.0 mg/L AI - Aluminum oil o5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 2.2 mg/L Ca - Calcium 00916 mg/L Chloride 00940 9.5 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L Phenol 32730 ug/L Fe - Iron 01045 ug/L Sulfate 00945 mg/L Hg - Mercury 71900 ug/L ecific Conductance 00095 µMhos K - Potassium 00937 mg/L Total Ammonia 00810 <0 . 10 mg/L Mg - Magnesium 00927 mg/L (Ammonia Nitrogen; N%as N; Ammonia Nitrogen, Total) Mn -Manganese 01055 ug/L TKN as N 00625 mg/L Ni - Nickel 01067 ug/L Certification No. 37712 Pb - Lead 01051 ug/L Zn - Zinc 01092 mg/L Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? IN Yes (1) ❑ No (0) VOC 7873 method # 6200 method # method # method # Temp 00010: 15 .58 eC DRY at 59 µMhos I time of check here: ❑ For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% . GW-59 Rev.8/2013 GROUNDWATER QUALITY MONITORING: \ COMPLIANCE REPORT FORM 1617'IfAAIL,SERVIGE CENTER, tZALEfGH, NC 27699461,7 Phone: 919-807-G306 or Type Facility Name: Clement Pappas. Permit Name (if different): Facility Address: 125 Industrial Park Hendersonville , (Street) NC 28792 County Henderson (City) (state) (zip) Contact Person: Mr. Blake Kehoe Telephone#: 8 2 8 - 6 9 3 - 0 7.11 Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 PERMIT Number: Expiration Date: 0 8 / 31 / 2 02 0 Non -Discharge WQ 0 0 0 4 7 9 7 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ER Spray Field ❑ Remediation: ❑ Rotary Distributor El Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: "• 1-1. MW- 7R WELL ID NUMBER (from Permit): Date sample collected: _ 11 / 04 / 2 015 FIELD ANALYSES: If WELL WAS Well Depth: 17 -4nft• Well Diameter: 2' in. pH 00400: 5 •47 units Temp. 000lo: 17. 06 °C DRY at Depth to Water Level 82546: 8 . 43 ft. below measuring point Screened Interval: 5 ft.* to 15ft* Spec. Cond. 00094: 185 µMhos time of Measuring Point is 3 . 0 0 ft. above land surface Relative M.P. Elevation: 2062.86 ft. Odor 00085: none sampling, Volume of water pumped/bailed before sampling: 5.25 gallons ecreened interval is relative to land surfac 'Appearance check here:❑ formetalswere Samples for metals were collected unfiltered: El YES ❑ NO . Samples ----- and field acidified: ❑YES ❑ NO ate sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services kRAMETERS NOTE:'Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead o1051 Coliform: MF Fecal 31616 <2 . 0 1100mL Nitrate (NO3) as N 00620 8 . 3 mg/L Zn - Zinc 01092 Coliform: MF Total 31504 /100mL Phosphorus: Total as P o0665 (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 issolved Solids:Total 70300 129 mg/L Al - Aluminum o1105 pH (Lab) 00403 units Ba - Barium 01007 TOC o0680 9'. 9 'mg/L Ca - Calcium 00916 Chloride 00940 18.0 mg/L Cd - Cadmium 01027 Arsenic 01002 ug/L Chromium: Total 01034 Grease and Oils 00552 mg/L Cu - Copper 01042 Phenol 32730 ug1L Fe - Iron 01045 Sulfate 00945 mg/L Hg - Mercury 71900 pecific Conductance 00095 µMhos K - Potassium 00937 Total Ammonia o0610 < 0 . 10 mg/L Mg - Magnesium 00927 (Ammonia Nitrogen; NH3 as N;Ammonia Nitrogen, Total) Mn - Manganese 01055 TKN as N 00625 mg/L Ni - Nickel 01067 0.35 mg/L mg/L mg/L ug/L mg/L ug/L ug/L mg/L ug/L ug/L mg/L mg/L ug/L ug/L Certification No. 37712 ug/L mg/L Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? ® Yes (1) ❑ No (0) VOC 7873 method # 6200 method # method method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% � a'� L ✓+ � L1.°�li/i 7 l r-6779l a0,V11A ' — ��i✓� _ _51' �Ccti _ ir_12� itteb (or Authorized Agent) Name and Title - Please print or type Signature ofPerm tffee (or Authorized Agent)— (Date GW-59 Rev.8/201.3 II GROUNDWATER QUALITY MONITORING: �1 COMPLIANCE REPORT FORM SING UNIT or Facility Name: Clement Pappas Permit Name (if different): Facility Address: 125 Industrial Park Hendersonville (street) NC 28792 County Henderson (City) (state) (zip) Contact Person: Mr. Blake Keho e Telephone#: 828 - 6 9 3 - 0 711 Well Location/Site Name: Irrigation area No. of wells to be sampled: 6 ERMIT Number: Expiration Date: 0 8/ 31 / 2 0 2 0 on=Discharge WQ0004797 UIC PDES Other YPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery IN Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: _..........,, WELL 1D NUMBER from Permit : MW- 8 ( ) Date sample collected: l l / 0 4 / 2 015 FIELD ANALYSES: If WELL WAS Well Depth: 13 . 95ft. Well Diameter: 2 in. pH 00400: 6 .45 units Temp. 000lo: 16 . 93 °C DRY at Depth to Water Level 82546: 7 . 21 ft. below measuring point Screened Interval: 3 ft* to 13 ft* Spec. Cond. 00094: 637 µMhos time of Measuring Point is 3 . 00 ft. above land surface Relative M.P. Elevation: 2060. so ft. Odor o0065: none sampling, Volume of water pumped/bailed before sampling: 3.75 gallons screened interval is relative to land surface Appearance check here: Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO ❑ Date sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Coliform: MF Fecal 31616 4.0 /100mL Nitrate (NO3) as N 00620 3.0 mg/L Coliform: MF Total 31504 /100ml- Phosphorus: Total as P 00665 0 .82 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 m9 /L )issolved Solids:Total 70300 396 mg/L Al - Aluminum o11o5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 15 . 0 mg/L Ca - Calcium oo916 mg/L Chloride 00940 21.6 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L Phenol 32730 ug/L Fe - Iron 01045 ug/L Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Specific Conductance 00095 µMhos K - Potassium 00937 mg/L Total Ammonia 00610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L TKN as N oo625 mg/L Ni -Nickel 01067 ug/L Certification No. 37712 Pb - Lead 01051 ug/L Zn - Zinc 01092 mg/L Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? 0 Yes (1) ❑ No (0) VOC 7873 method # 6200 method # method # method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Ztff- TUV1� Ittee (or Authorized Agent) Name and Title - Please print or type GW-59 , Rev, 8/2013 of Agent) FACILITY INFORMATION Please Print Clearly or Type Facility Name: Clement Pappas Permit Name (if different): Facility Address: 1-25 Industrial Park Hendersonville (street) NC 28792 County Henderson (City) (State) (zip) Contact Person: Mr . Blake Keho e Telephone#: 8 2 8- 6 9 3- 0 711 Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 rf...... o..... 1 nnnir4 nAlurtAL'tZtSOUFZCES- IRCES INFORMATION;.PROCE$SING "UNIT ' ERMIT Number: Expiration Date: 0 8/ 31 / 2 0 2 0 on -Discharge WQ0004797 UIC FIDES Other YPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ® Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: _...... _.........,,.. ,-.' r.,�. WELL ID NUMBER (from Permit):- 9 Date sample collected: 11 / 04 /2 015 FIELD ANALYSES: !f WELL WAS Well Depth: 18 . 1ft• Well Diameter: 2 in. pH 00400: 5'. 57units Temp. 00010: 17. 62 C DRY at Depth to Water Level 82546: 2 , 89 ft. below measuring point Screened Interval: 6*ft. to 16*ft. Spec. Cond. 00094: 77 µMhos time of Measuring Point is 1.44 ft. above land surface Relative M.P. Elevation: 2, 0 6 0 . 23 ft, Odor 00085: none sampling, Volume of water pumped/bailed before sampling: 2.6 gallons9areene4 interval is relative to land surface Appearance check here: Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑' YES El NO ❑ Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N oo615 mg/L Coliform: MF Fecal 31616 <1 , 0 1100mL Nitrate (NO3) as N 00620 <0 . 02 0 mg/,L Coliform: MF Total 3.1504 /100mL Phosphorus: Total as P oo665 0.45 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 m9 /L Dissolved Solids:Total 70300 58.0 mg/L Al -Aluminum oilo5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC oo68o 3 . 8 mg/L Ca - Calcium oo91e mg/L Chloride 00940 2 . 6 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L Phenol 32730 ug/L Fe - Iron 01045 ug/L Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Specific Conductance 00095 µMhos K - Potassium 00937 mg/L Total Ammonia oo610 < 0 . 10 mg/L Mg - Magnesium 00927 mg/L (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 U9 /L TKN as N 00625 mg/L Ni - Nickel 01067 ug/L Pb - Lead 01051 Zn - Zinc 01092 Certification No. 37712 ug/L mg/L Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? ® Yes (1) ❑ No (0) VOC 7873 method # 6200 method # method # method # 1-11VU10LIVII �y,�Lc,,,, t4iny It+iiacn t_ao rceports): influent Total VUGs: mg/L Effluent Total VOCs: mg/L VOC Removal% ittee (or Authorized Agent) Name and Title - Please print or type GW-59 Rev.8/2013 Authorized '1�1?1e</i