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HomeMy WebLinkAboutWQ0004797_Monitoring (Report)_20131220ALTAMONT ENVIRONMENTAL, INC. 231 HAYWOOD STREET. ASHEVtL LE. NC TEL.828.281.3350 FAC.828.281.3 51 W WW.ALTAM0NTENVfR0KNENTAL.CO December 20, 2013 Mr. Blake Kehoe Plant Engineer Clement Pappas & Co., Inc. 125 Industrial Park Road Hendersonville, North Carolina 28792 Subject: November 2013.Groundwater Sampling Event Clement Pappas 125 Industrial Park Road Hendersonville, North Carolina Dear Mr. Kehoe: JAN 13 2014 Water Quality Regional Operations RECEIVI.Fr JAN 0 3 2014 information PrccL.o,,;,;� urea DWQ/j30; Altamont Environmental, Inc. (Altamont) conducted a groundwater sampling event at your facility on November 20, 2013. A site location map is included as Figure 1. Altamont conducted the groundwater sampling event in accordance with the North Carolina Department of Environment and Natural Resources (DENR) spray irrigation system permit number WQ0004797 (permit issued December 29, 2006 and reissued on October 12, 2012). Altamont collected groundwater samples from six monitoring wells: MW-2R, MW-4, MW-5, MW-6, MW-7R, and MW-8. Monitoring well MW-7R was installed on June 28, 2012 to replace MW-7, which was destroyed in June 2012 by field equipment. Monitoring well MW-7 was also abandoned on June.28, 2012. The locations of the monitoring wells are shown on Figure 2 (attached). Altamont submitted the groundwater samples to Pace Analytical Services, Inc. (Pace), a North Carolina certified laboratory, for analysis of the parameters specifiedin the permit. Table 1 summarizes the current and historical laboratory analytical resultsfor microbiology and wet . chemistry. During this sampling event, the total organic carbon concentrations were in excess of the permit limit in MW-8. The fecal coliform concentrations equaled the permit limit in MW-5. All other parameters - - analyzed were below permit lirnits and -North- Carolina Administrative Code, Title 15A,-Sub-chapter 2L-. - Standard (2L Standard), effective January 201.0. Fecal coliform concentrations decreased in MW-4, MW-6 and MW-8 since the May 2013 sampling event. The fecal coliform concentrations detected in MW-4, MW-6, and MW-8 decreased below the laboratory reporting limit in the three wells. The total organic carbon (TOC) concentrations in MW-2R, MW-4, MW-6, and MW-7R have decreased since the last sampling event. The TOC concentrations detected in MW-5 and MW-8 increased since the May 2013 sampling event. The TOC concentration detected in MW-8 remains above the associated permit limit. Table 2 summarizes the current and historic groundwater laboratory analytical results for volatile. organic compounds (VOCs).. Concentrations of tetrachloroethene, trichloroethene, and cis-:1,2-dichloroethene were detected in excess of the 2L Standard in MW-5. The tetrachloroethene and trichloroethene concentrations have decreased and the cis-:1,2-dichloroethene increased since the previous sampling event in May 2013. All other parameters -analyzed were below 2L Standards. Table 3 summarizes the current and historic groundwater elevations. All of the monitoring well concrete pads and top of the well casings elevations were resurveyed by Wes Cole Land Surveying, PA on November 21, 2012. The new elevations are reflected on Table 3 and on Figure 2. P:\Clement Pappas\Reports\2013\November 2013\Cover Letter_November.Doc Mr. Blake Kehoe December 20, 2013 Page 2 of 2 In accordance with the spray irrigation permit, Clement Pappas is required to submit by December 31, 2013 (on or before the last working day of the month following the sampling month) to the DENR the following: • Laboratory analytical report and chain -of -custody form (Attachment A); the well sampling logs and equipment documentation and instrument calibration data sheet is also included (Attachment B) © DENR GW-59A—Compliance Report Form (Attachment C) o DENR GW-59—Groundwater Quality Monitoring Compliance Report Form for each monitoring well (Attachment D). Altamont proposes to complete the next scheduled groundwater sampling event in May 2014..The spray irrigation permit expires -on November 30, 2015. If you have any questions or would like additional information, please do not hesitate to contact the undersigned at (828) 281-3350. Respectfully yours, ALTAMONT ENVIRONMENTAL, INC. Evan Yurkovich Attachments: o Figure 1—Site Location Map o Figure 2—Site Plan Map o Table 1—Current and Historic Groundwater Analytical Results for Microbiology and Wet Chemistry • Table '2— Current and Historic Groundwater Analytical Results. for Volatile Organic Compounds • Table 3—Current and Historic Groundwater Elevation Measurements • Attachment A: Laboratory Analytical Report and Chain -of -Custody Form o Attachment B: Well Sampling Logs and Equipment Documentation and Instrument Calibration Data Sheet o Attachment C: DENR GW-59A—Compliance Report Form © Attachment D: DENR GW-59—Groundwater Quality Monitoring: Compliance Report Forms IP:\Clement Pappas\Reports\2013\November 2013\Cover Letter_November.Doc FIGURES ♦ % \. 1• Y�'.ti.yA+�i. �, i ���� • � �`it '"+.? 3 ✓`J�'+j `",fin .,,�y��� _,� ,.. �'i 't� .7#,� O �� .��-�;' {V. 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"hj{t��}[7 Ei f �•i- �;---x,,� ~ {` a ,p�� ..*'t� e4 .v� ,T' �� q �# Si ; � `". ,.r "^ ° -S�t �" '•�' � t \ t / � `'•,. ♦ �... a E' �$ ,. }'?'•• 2 .°t" �{ +r4° i-:-. f`P C4 -r L+�"'S°" f t � '*4 �-...^+,.a +. � -�' •'��,. :a p .� �., t,1 r � j� 1 .�"w� �� �.;:�... s.. S�i.'�..�.,}``s �• � t"� `� `� {� ram""` i T, ,T s � ' ,�.�.✓c SOURCES: 1. FRUITLAND, HENDERSONVILLE, HORSESHOE & SKYLAND,NORTH CAROLINA U.S.G.S. QUADRANGLES, MAP DATES: 1985, PHOTOREVISED: 1990 & 1991. 2. HENDERSON COUNTY GIS WEBSITE ACCESSED JANUARY 30, 2006. • � �' � SITE LOCATION MAP FIGURE y &MIKE r 1: - l � a I-i �; 231 HAYWOOD STREET, ASHEVILLE, NC 28801 TEL.828.281.3350 FAC.828.281.3351 CLEMENT PAPPAS www.altamontenviromnenW.com 125 INDUSTRIAL PARK ROAD DRAWN BY: EVANAGE : CHRIS SCALE (FEET) HENDERSONVILLE, NC PROJECT MANAGER: CHRIS GILBERT CLIENT: CLEMENT PAPPAS 1000 0 1000 2000 DATE: 12/10/13 FILE PATH: PACLEMENT PAPPAMFIGUREMCAD\ FIGUREI-GMR.DWG Ii-Rr x' a * yS ( 60) ,. .tAM 3 4 vw-h (2061.1 OField #1 Old Field s * lip .`46 r MW- R ® MW-02 (2062. 6)* 'kQ064.18) m MW-04.. . r# ' • V 2063.7'LEGEND •'SV e �. NI,TORING WELL U5E), -D QR FORME t bMITdkN ('PIEZOME7 66) TOP OF Cif j ELEVATION F.ET ®_ � ALTAMONT ENVIlZONMENTAL, INC. ! \ 11 TABLES Table 1 Current and Historic Groundwater Analytical Results for Microbiology and Wet Chemistry Clement Pappas Hendersonville, North Carolina 4 Sample' Name , r - Sample Date (mm/dd/yyyy) O U b`D ... (meL) o (mg/L) E 6 m ,� (CFU per 100.mL.)- [2 Z (mg/L) .. µ- (mg(L) N .N :> m (mg/L) COin C. o. E -¢ (mg/L) 05/24/2006 7.2 9.7 < 1.1 2 19 82 < 0.10 11/09/2006 3.6 7.4 < 1.1 0.95 17 76 0.11 05/18/2007 4.9 6.0 < 1.0 0.56 14 62 < 0.10 11/13/2007 5.9 16.7 <1.1 2.9 6.9 82.0 < 0.10 05/27/2008 10.2 9.0 <1.1 0.80 21.3 140 < 0.10 11/18/2008 4.7 10.7 <1.1 1.9 8.5 32.0 < 0.10 05/28/2009 14.4 7.1 < 4.0 0.46 24.2 104 < 0.10 11/05/2009 13.5 5.9 < 2.0 0.31 23.5 80.0 < 0.10 MW-213 05/13/2010 8.7 5.8 < 2.0 < 0.10 17.2 57.5 < 0.10 11/08/2010 18.3 10.0 < 2.0 1.1 11.7 60.0 < 0.10 05/17/2011 11.6 < 5.0 < 2.0 < 0.10 14.3 < 62.5 < 0.10 11/15/2011 18.9 10.1 < 2.0 1.2 10.0 86.0 < 0.10 05/17/2012 5.3 7.6 < 4.0 < 0.20 11.9 68.0 < 0.10 11/07/2012 31.1 9.5 < 1.0 1.3 10.0 67.0 < 0.10 05/16/2013 13.5 1.2 < 1.0 < 0.02 13.2 64.0 < 0.10 11/20/2013 6.1. 7.6 < 1.0 0.97 9.3 66.0 < 0.10 05/15/2002 8.9 45 < 1.1 < 0.10 9.3 180 < 0.10 11/05/2002 5.5 48 < 1.1 < 0.1 14 230 < 0.10 05/13/2003 3.3 32 < 1.1 0.051 20 110 0.21 11/04/2003 41 31 < 1.1 < 5.0 66 210 < 0.10 05/05/2004 - 6 29 < 1.1 < 5.0 45 240 0.11 11/09/2004 8.4 13 3.6 < 0.10 52 200 < 0.10 05/17/2005 8.5 10 < 1.1 < 0.10 37 220 < 0.10 11/03/2005 16 14 < 1.1 < 0.10 29 220 0.14 05/24/2006 19 11 < 1.1 < 0.10 28 180 < 0.10 11/09/2006 8.8 6.9 < 1.1 < 0.10 26 180 < 0.10 05/18/2007 8.5 8.9 < 1.0 < 0.10 29 300 < 0.10 11/13/2007 16.7 11.3 < 1.1 < 0.10 25.0 152 < 0.10 MW-4 05/27/2008 < 1.0 10.0 < 1.1 < 0.10 38.6 176 < 0.10 11/18/2008 20.5 9.3 < 1.1 < 0.10 19.6 108 < 0.10 05/28/2009 8.6 13.6 < 4.0 < 0.10 35.5 156 < 0.10 11/05/2009 31.0 13.6 < 2.0 < 0.10 30.7 120 < 0.10 05/13/2010 7.8 18.0 < 2.0 0.17 31.0 141 < 0.10 11/08/2010 23.9 17.5 < 2.0 < 0.10 34.4 144 < 0.10 05/17/2011 7.7 13.5 < 2.0 0.82 25.6 137 < 0.10 11/15/2011 7.3 14.4 < 2.0 < 0.20 27.8 157 < 0.10 05/17/2012 6.7 12.1 2.0 < 0.20 22.3 117 < 0.10 11/07/2012 10.6 14.5 2.0 < 0.020 26.2 150 < 0.10 05/16/2013 31.8 10.2 2.0 0.28 19.1 108 < 0.10 11/20/2013 8.0 14.7 < 1.0 0.026 22.1 157 < 0.10 Standards 10 250 1 10 250 500 7 P:\Clement Pappas\Analytical & Data\Water\November20l3_Historic Analytical Results.xls Page 1 of 5 Table 1 Current and Historic Groundwater Analytical Results for Microbiology and Wet Chemistry Clement Pappas Hendersonville, North Carolina �E .. Sample,.,42 Name . - .. Sample Date (mm/dd/yyyy) U O C (mg/L) v 0 (mg/L). O O U u (CFU per 100 rnQ, m (mg/L) D . (mg/L) B O N 5 CO �O (mg/L),' f0 C o E (mg/L) 05/15/2002 2.9 15 < 1.1 0.42 1.7 < 40 < 0.10 11/05/2002 1.4 16 < 1.1 0.54 < 1.0 83 1.3 05/13/2003 4.6 17 < 1.1 0.65 2 56 0.25 11/04/2003 19 22 < 1.1 0.23 < 5.0 58 < 0.10 05/05/2004 0.7 28 < 1.1 0.57 < 5.0 80 0.15 11/09/2004 1.2 34 < 1.1 0.24 < 5.0 130 < 0.10 05/17/2005 2.1 35 < 1.1 < 0.10 < 5.0 110 < 0.10 11/03/2005 8.1 34 < 1.1 0.11 < 5.0 82 < 0.10 05/24/2006 7.8 34 < 1.1 < 0.10 < 5.0 120 < 2.5 11/09/2006 1.3 37 < 1.1 0.20 < 5.0 90 < 0.1 05/18/2007 1.7 42 < 1.0 0.16 < 5.0 130 < 0.10 11/13/2007 4.2 41.3 < 1.1 0.25 < 5.0 112 < 0.10 MW-5 05/27/2008 6.7 14.3 < 1.1 0.21 <5.0 168 0.17 11/18/2008 25.9 47.6 < 1.1 0.17 < 5.0 80.0 < 0.10 05/28/2009 16.1 29.0 4.0 0.11 < 5.0 188 < 0.10 11/05/2009 4.7 39.1 2.0 0.15 < 5.0 112 < 0.10 05/13/2010 3.2 43.0 23 0.1.7 < 5.0 147 < 0.10 11/08/2010 13.8 43.7 200 < 0.10 < 5.0 113 < 0.10 05/17/2011 . 4.0 32.3 <.4.0 < 0.10 < 5.0 < 167 < 0.10 11/16/2011 3.0 52.6 120 C < 0.20 < 5.0 165 < 0.10 05/17/2012 4.7 36.6 < 2.0 ! < 0.20 < 5.0 110 < 0.10 11/07/2012 4.1 61.1 < 10.0 0.12 < 2.0 139 < 0.10 05/16/2013 4.0 44:2 1.0 0.093 2.3 152 < 0.10 11/20/2013 4.2 64.6 1.0 0.19 < 2.0 162 < 0.10 1 Standards 10 250 1 1 10 1 250 1 500 NL P:\Clement Pappas\Analytical & Data\Water\November2013_Historic Analytical Results.xls Page 2 of 5 Table 1 Current and Historic Groundwater Analytical Results for Microbiology and Wet Chemistry Clement Pappas Hendersonville, North Carolina Sample Name=' Sample -Date . (mm/dd/yyyy) o O 0 . (mg/L) a o (mg/L) E v m LL JCFU per 100 mL)' m o z (mg/L) a; (n (mg/L) CD o . N ` . (mg/L) c0 . o E.. ,a. 05/15/2002 6.8 9.9 5.1 < 0.10 11 < 40 < 0.10 11/05/2002 3.9 4.6 < 1.1 0.49 9.8 51 2.5 05/13/2003 4.4 7.3 > 23.0 0.075 14 52 0.14 11/04/2003 26 6.8 9.2 < 0.050 12 < 20 < 0.10 05/05/2004 1.8 6.7 1.1 < 0.10 11 58 0.13 11/09/2004 3.5 11 9.2 < 0.10 9.3 88 < 0.10 05/17/2005 2.4 7.4 < 1.1 < 0.10 8.7 50 < 0.10 11/03/2005 6.3 9.6 < 1.1 < 0.10 9.6 66 0:17 05/24/2006 7.4 10 < 1.1 < 0.10 9 54 < 0.10 11/09/2006 1.4 11 < 1.1 0.20 11 54 0.18 05/18/2007 3.9 9.4 < 1..0 < 0.10 9.1 58 0.12 11/13/2007 5.7 10.7 3.6 0.24 5.8 114 0.24 MW-6 05/27/2008 10.9 5.4 < 1.1 < 0.10 15.3 92.0 < 0.10 11/18/2008 7.4 7.6 > 23 < 0.10 < 5.0 36.0 < 0.10 05/28/2009 6.4 6.2 276 0.39 8.8 104 < 0.10 11/05/2009 6.4 < 5.0 30 0.10 9.3 52.0 < 0.10 05/13/2010 4.3 5.8 < 2.0 < 0.10 8.1 44.0 < 0.10 11/08/2010 16.5 5.0 7.0 1.5 9.3 48.0 < 0.10 05/17/2011 6.2 9.4 < 2.0 < 0.10 6.8 60.0 < 0.10 11/15/2011 4.6 5.2 5.0 < 0.20 7.5 82.0 < 0.10 05/17/2012 21.6 8.1 28.0 < 0.20 8.8 52.0 < 0.10 11/07/2012 6.4 6.8 3.1 < 0.020 7.5 46.0 < 0.10 05/16/2013 7.5 5.4 12.1 0.048 9.4 62.0 < 0.10 11/20/2013 4.4 7.3 < 1.0 < 0.020 8.6 56.0 < 0.10 Standards 10 250 1 1 10 250 1 500 NL P:\Clement Pappas\Analytical & Data\Water\November20l3_Historic Analytical Results.xls Page 3 of 5 Table 1 Current and Historic Groundwater Analytical Results for Microbiology and Wet Chemistry Clement Pappas Hendersonville, North Carolina. - Sample Name . Sample Date (mm/dd/yyyy) CU CU •C... bD O - �" (mg/L) o o (mg/L) E O O _ U ,? (CFU per 100 mL)• (D z.� (mg/L) +; mCU (mg/L) Cn y '(mg/L) f0 o E r .¢ ° (mg/L) 05/15/2002 20 6.5 < 1.1 5.2 26 < 40 < 0.10 11/05/2002 16 3.3 < 1.1 1.3 1.1 68 1.4 05/13/2003 9.7 3.6 2.2 1.8 9.3 44 0.72 11/04/2003 19 6.1 < 1.1 0.72 < 5.0 < 2.0 < 0.10 05/05/2004 3.0 7.0 < 1.1 1.3 < 5.0 52 < 0.10 11/09/2004 2.2 5.1 5.1 1.9 < 5.0 62 < 0.10 05/17/2005 3.2 6.1 < 1.1 1.2 < 5.0 40 < 0.10 11/03/2005 7.7 6.1 < 1.1 0.99 < 5.0 58 0.10 05/24/2006 8.4 5.5 < 1.1 1.5 < 5.0 48 < 0.10 11/09/2006 1.9 7.0 < 1.1 1.1 6.7 38 < 0.10 MW 7. 05/18/2007 3.6 8.6 < 1.0 2.2 5.9 70 < 0.10 11/13/2007 4.2 6.8 < 1.1 1.7 < 5.0 42.0 < 0.10 05/27/2008 7.6 11.5 < 1.1 2.2 6.9 88.0 < 0.10 11/18/2008 7.5 7.7 < 1.1 1.7 < 5.0 30.0 < 0.10 05/28/2009 23.4 9.8 <.4.0 2.3 < 5.0 336 < 0.10 11/05/2009 5.3 10.7 2.0 2.3 11.2 70.0 < 0.10 05/13/2010 4.6 11.0 < 2.0 2.5 < 5.0 71.0 < 0.10 11/08/2010 15.4 8.9 < 2.0 2.3 < 5.0 60.0 < 0.10 05/17/2011 6.0 11.6 < 2.0 5.3 7.6 103 < 0.10 11/15/2011 2.2 9.9 < 2.0 3.5 < 5.0 89.0 < 0.10 05/17/2012 4.4 10.9 < 2.0 3.8 < 5.0 67.0 < 0.10 11/07/2012 11.6 13.1 < 100. 4.0 14.9 108.0 < 0.10 MW-7R 05/16/2013 12.8 17.1 < 1.0 10.5 28.3 252 < 0.10 11/20/2013 9.4 14.0 < 1.0 5.5 3.5 < 250 < 0.10 Standards 10 1 250 1 1 1 10 250 1 500 1 NL P:\Clement Pappas\Analytical & Data\Water\November20l3_Historic Analytical Results.xis Page 4 of 5 Table 1 Current and Historic Groundwater Analytical Results for Microbiology and Wet Chemistry Clement Pappas Hendersonville, North Carolina .. Sample Name, Sample Date (mm/dd/yyyy) U, v. U ,'C O ��° (mg/L), v o (mg/L) U m ,° ; (CFU per 100 mL) m z.� (mg/L) - ° (mg/L) p U) 0 p (mg/L) c E a (mg/L) 05/15/2002 6.8 8.7 < 1.1 < 0.10 9.1 64 < 0.10 11/05/2002 4.8 9.8 < 1.1 0.16 7 100 0.57 05/13/2003 5.5 3.3 2.2 1.4 9.4 64 0.41 11/04/2003 27 8.1 6.9 < 0.050 13 54 < 0.10 05/05/2004 3.0 7.4 < 1.1 0.24 9.8 140 < 0.10 11/09/2004 3.7 6.7 > 23 0.79 6.8 120 < 0.10 05/17/2005- 3.8 8.3 < 1.1 0.61 6.4 88 < 0.10 11/03/2005 7.1 11 < 1.1 0.95 8.4 100 < 0.10 05/24/2006 15 10 < 1.1 0.39 8.1 130 < 0.10 11/09/2006 4.7 12 < 1.1 0.97 7.7 96 < 0.10 05/18/2007 5.0 15 < 1.0 3.0 13 290 < 0.10 11/13/2007 8.3 19.6 < 1.1 0.97 26.6 154 < 0.10 MW-8 05/27/2008 12.4 20.0 < 1.1 0.55 35.8 184 < 0.10 11/18/2008 14.4 17.2 2.2 < 0.10 21.5 118 < 0.10 05/28/2009 6.2 24.9 240 0.74 24.9 192 < 0.10 11/05/2009 10.8 15.4 50 0.54 18.4 114 < 0.10 05/13/2010 10.8 14.7 < 2.0 1.1 24.1 106 < 0.10 11/08/2010 23.2 24.3 200 < 0.10 26.3 173 < 0.10 05/17/2011 10 16.9 10.0 12.2 16.1 232 < 0.10 11/15/2011 8.0 26.6 < 2.0 3.7 20.2 232 < 0.10 05/17/2012 14.4 24.8 12.0 8.0 22.9 356 < 0.10 11/07/2012 24.8 26.3 < 100 1.9 28.3 324 < 0.10 05/16/2013 15.8 8.8 10.9 6.8 13.4 248 < 0.10 11/20/2013 21.0 15.4 < 1.0 1.3 24.3 342 < 0.10 Standards 10 1 250 1 1 1 10 250 500 1 NL Notes: 1. mg/L = milligrams per liter. 2. mL = milliliters. 3. CFU = Coliform forming units. - 4. Standards from North Carolina Administrative Code, Title 15A, Subchapter 2L April 1, 2013, except Total Organic Carbon and Fecal Coliform. Total Organic Carbon standard from Spray Irrigation Permit Number WQ0004797. Fecal Coliform standard is 2L standard for Total Coliform. 5. Numbers in bold indicate concentration equal to or above the respective standard. 6. NIL indicates that no standard limit is set. 7. "<" means less than laboratory method reporting -limit. 8. Fecal coliform samples for MW-7 and MW-8 were resampled on May 21, 2010 due to a lab error. P:\Clement Pappas\Analytical & Data\Water\November2013_Historic Analytical Results.xis Page 5 of 5 Table 2 Current and Historic Groundwater Analytical Results for Volatile Organic Compounds Clement Pappas Hendersonville, North Carolina _ Sample Name Sample Date (mm/dd/yyyy) L .2 o (Ng/l) C O` O (P /1) Q N O -' O .. N ri �_ `' (Pg/l) 2 L p y (ug/I) d U T j (Pg/l) d ., N O U o � WWI) MW-2R 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 <. 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 < 0.50 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW-4 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.W < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50. < 1.0 < 0.50. 11/18/2008 < 0.50 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW-5 11/05/2002 4,700 980 820 13 24 1.9 11/04/2003 3,500 570 510 < 50 < 50 < 50 11/09/2004 580 62 38 < 10 < 10 < 10 11/03/2005 1,900 210 220 < 50 < 50 < 50 11/09/2006 350 74 67 0.61 1.2 < 0.50 05/18/2007 320 47 60 < 0.50 < 0.50 < 0.50 11/13/2007 1,150 217 209 2.0 3.4 1.0 11/18/2008 2,680 5344 293 < 25.0 < 25.0 < 25.0 11/05/2009 872 106 125 0.92 < 1.0 < 0.50 11/08/2010 578 107 160 < 2.5 < 5.0 < 2.5 11/15/2011 1,450 124 141 < 2.5 < 5.0 < 2.5 11/07/2012 774 68.8 77.8 < 5.0 < 10.0 < 5.0 11/20/2013 332 65.1 80.5 < 1.2 < 2.5 < 1.2 2L Standard 0.7 3 70 100 0.03 7 P:\Clement Pappas\Analytical Data\Water\November20l3_Historic Analytical Results.xis 11 . Page 1 of 3 Table 2 Current and Historic Groundwater Analytical Results for Volatile Organic Compounds Clement. Pappas Hendersonville, North Carolina Sample Name: Sam le Date (mm/dd/YINY) m U m (Pg/l) m O s (ug/I) o N D (Pg/I) -D , o o C Ch c W/l) 2 V (uF.1l) .2 V o (PEA, MW-6 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 .< 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 3.0 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW-7 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < b.50 < 0.50 < 1.0 < 0.50 11/18/2008 0.79 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW-713 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 A Standard 0.7 3 70 100 0.03 7 P:\Clement Pappas\Analytical Data\Water\November20l3_Historic Analytical Results.xls Page 2 of 3 Table 2 Current and Historic Groundwater Analytical Results for Volatile Organic Compounds Clement Pappas Hendersonville, North Carolina ti. Q cu o .. N N O O N' rj O U Sample U r U Name Sample Date N 0 (mm/dd/yyyy) WO (P9/l) W/1). (Pvl) (P /1) ° W/O MW-8 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 < 0.50 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 2L Standard 0.7 3 70 100 0.03 7 Notes: 1. This table only includes compounds that were detected above the laboratory method detection limit since the sampling event in November 2002. 2. The complete suite of compounds analyzed can be found in the individual analytical reports. 3. pg/L = micrograms per liter. 4. 2L Standard from North Carolina Administrative Code, Title 15A, Subchapter 2L, April 1, 2013. 5. Numbers in bold indicate exceedance of standard. 6. In accordance with Spray Irrigation Permit Number W00004797, only the samples collected during the November Sampling Events are analyzed for volatile organic compounds with one exception (see note 7). 7. In accordance with the Compliance Evaluation Inspection letter issued by Ms. Beverly Price of the DENR, Division of Water Quality (DWQ) on April 27, 2007, volatile organic compounds and semivolatile organic compounds were sampled during the May 2007 sampling event. 8. Napthalene was detected in MW-6 for the first time at a concentration of 2.2 pg/L during the November 5, 2002 sampling event, which is below the 2L Standard of 6 pg/L. 9. 1,1,2-trichloroethane was detected in MW-5 for the first time on November 20, 2010 at a concentration of 8.0 pg/L,' which exceeds the North Carolina Interim Maximum Allowable Concentration of 0.6 pg/L. 10. Chloroform was detected for the first time in MW-5 at a concentration of 31.3 pg/L during the November 2011 sampling event, which is below the 2L Standard of 70 pg/L. P:\Clement Pappas\Analytical Data\Water\November20l3_Historic Analytical Results.xis Page 3 of 3 Table 3 Current and Historical Groundwater Elevation Measurements Clement Pappas Hendersonville, North Carolina Well Identification Date Measured (mm/dd/yyyy) Depth to Groundwater (ft-BTOC) Top of Casing Elevation � (feet) Top of Casing Height Above Ground Surface (feet) Groundwater Elevation (feet) MW-2R 05/24/2006 9.29 2063.00 3.77 2053.71 11/09/2006 6.49 2063.00. 3.77 2056.51 05/18/2007 7.94 2063.00 3.77 2055.06 11/13/2007 8.46 2063.00 3.77 2054.54 05/27/2008 8.48 2063.00 3.77 2054.52 11/18/2008 8.50 2063.00 3.77 2054.50 05/28/2009 5.43 2063.00 3.77 2057.57 11/05/2009 6.72 2063.00 3.77 2056.28 05/13/2010 7.36 2063.00 3.77 2055.64 11/08/2010 9.60 2063.00 3.77 2053.40 05/17/2011 7.25 2063.00 3.77 2055.75 11/15/2011 7.86 2063.00. 3.77 2055.14 05/17/2012 5.19 2063.00 3.77 2057.81 11/07/2012 7.74 2062.36 3.77 2054.62 05/16/2013 6.86 2062.36 3.77 2055.50 11/20/2013 7.92 2062.36 3.77 2054.44 MW-4 05/15/2002 9.32 2064.60 2.43. 2055.28 11/05/2002 9.49 2064.60 2.43 2055.11 05/13/2003 8.20 2064.60 2.43 2056.40 11/04/2003 9.23 2064.60 2.43 2055.37 05/05/2004 5.35 2064.60 2.43 2055.25 11/09/2004 8.61 2064.60 2.43 2055.99 05/17/2005 6.19 2064.60 2.43 2058.41 11/03/2005 9.57 2064.60 2.43 2055.03 05/24/2006 9.60 2064.60 2.43 2055.00 11/09/2006 8.41 2064.60 2.43 2056.19 05/18/2007 9.42 2064.60 2.43 2055.18 11/13/2007 9.89 2064.60 2.43 2054.71 05/27/2008 9.78 2064.60 2.43 2054.82 11/18/2008 9.76 2064.60 2.43 2054.84 05/28/2009 7.16 2064.60 2.43 2057.44 11/05/2009 8.53 2064.60 2.43 2056.07 05/13/2010 8.83 2064.60 2.43 2055.77 11/08/2010 9.30 2064.60 2.43 2055.30 05/17/2011 8.97 2064.60 2.43 2055.63 11/15/2011 9.48 2064.60 2.43 2055.12 05/17/2012 7.62 2064.60 2.43 2056.98 11/07/2012 9.32 2063.77 2.43 2054.45 05/16/2013 7.93 2063.77 2.43 2055.84 11/20/2013 8.87 2063.77 2.43 2054.90 P:\Clement Pappas\Analybcal & Data\Water\Historic GW Elev.xis Page 1 of 5 Table 3 Current and Historical Groundwater Elevation Measurements Clement Pappas Hendersonville, North Carolina Well Identification Date Measured (mm/dd/yyyy) Depth to Groundwater (ft-BTOC) Top of Casing �• Elevation (feet) Top of Casing Height Above Ground Surface (feet) Groundwater Elevation (feet) MW-5 05/15/2002 8.31 2086.40 3.00 2078.09 11/05/2002 10.20 2086.40 3.00 2076.20 05/13/2003 8.29 2086.40 3.00 2078.11 11/04/2003 9.92 2086.40 3.00 '2076.48 05/05/2004 8.75 2086.40 3.00 2077.65 11/09/2004 8.50 2086.40 3.00 2077.90 05/17/2005 8.87 2086.40 3.00 2077.53 11/03/2005 9.70 2086.40 3.00 2076.70 05/24/2006 9.34 2086.40 3.00 2077.06 11/09/2006 8.39 2086.40 3.00 2078.01 05/18/2007 9.16 2086.40 3.00 2077.24 11/13/2007 11.00 2086.40 3.00 2075.40 05/27/2008 9.84 2086.40 3.00 2076.56 11/18/2008 11.59 2086.40 3.00 2074.81 05/28/2009 7.95 2086.40 3.00. 2078.45 11/05/2009 8.63 2086.40 3.00 2077.77 05/13/2010 8.87 2086.40 3.00 2077.53 11/08/2010 10.24 2086.40 3.00 2076.16 05/17/2011 8.99 2086.40 3.00 2077.41 11/15/2011 10.58 2086.40 3.00 2075.82 05/17/2012 8.73 2086.40 3.00 2077.67 11/07/2012 9.65 2085.60 3.00 2075.95 05/16/2013 8.14 2085.60 3.00 2077.46 11/20/2013 9.33 2085.60 3.00 2076.27 P:\Clement Pappas\Analytical & Data\Water\Historic GW Elev.xls Page 2 of 5 Table 3 Current and Historical Groundwater Elevation Measurements Clement Pappas Hendersonville, North Carolina Well Identification Date Measured (mm/dd/yyyy) Depth to Groundwater (ft-BTOC) Top of Casing Elevation (feet) Top of CasingGroundwater Height'Above Ground Surface (feet) Elevation (feet) MW-6 05/15/2002 6.20 2061.90 3.00 2055.70 11/05/2002 6.15 2061.90 3.00 2055.75 05/13/2003 5.43 2061.90 3.00 2056.47 11/04/2003 5.85 2061.90 3.00 2056.05 05/05/2004 6.00 2061.90 3.00 2055.90 11/09/2004 5.32 2061.90 3.00 2056.58 05/17/2005 6.10 2061.90 3.00 2055.80 11/03/2005 6.01 2061.90 3.00 2055.89 05/24/2006 6.48 2061.90 3.00 2055.42 11/09/2006 5.71 2061.90 3.00 2056.19 05/18/2007 6.50 2061.90 3.00 2055.40 11/13/2007 7.85 2061.90 3.00 2054.05 05/27/2008 7.01 2061.90 3.00 2054.89 11/18/2008 7.38 2061.90 3.00 2054.52 05/28/2009 5.63 2061.90 3.00 2056.27 11/05/2009 5.74 2061.90 3.00 2056.16 05/13/2010 5.90 2061.90 3.00 2056.00 11/08/2010 5.99 2061.90 3.00 2055.91 05/17/2011 5.85 2061.90 3.00 2056.05 11/15/2011 6.14 2061.90 3.00 2055.76 05/17/2012 5.87 2061.90 3.00 2056.03 11/07/2012 6.05 2061.17 3.00 2055.12 05/16/2013 5.84 2061.17 3.00 2055.33 11/20/2013 5.96 2061.17 3.00 2055.21 P:\Clement Pappas\Analytical & Data\Water\Historic GW Elev.xls Page 3 of 5 Table 3 Current and Historical Groundwater Elevation Measurements Clement Pappas Hendersonville, North Carolina Well Identification Date Measured (mm/dd/yyyy) Depth to Groundwater.,, (ft-BTOC) Top of Casing Elevation _ (feet) Top of ,Casing Height Above Ground Surface (feet) Groundwater Elevation (feet) MW-7 05/15/2002 10.90 2062.70 3.00 2051.80 11/05/2002 11.35 2062.70 3.00 2051.35 05/13/2003 8.87 2062.70 3.00 2053.83 11/04/2003 10.78 2062.70 3.00 2051.92 05/05/2004 _ 10.80 2062.70 3.00 2051.90 11/09/2004 9.70 2062.70 3.00 2053.00 05/17/2005 10.60 2062.70 3.00 2052.10 11/03/2005 11.09 2062.70 3.00 2051.61 05/24/2006 11.27 2062.70 3.00 2051.43 11/09/2006 9.71 2062.70 3.00 2052.99 05/18/2007 11.02 2062.70 3.00 2051.68 11/13/2007 11.76 2062.70 3.00 2050.94 05/27/2008 11.55 2062.70 3.00 2051.15 11/18/2008 11.63 2062.70 3.00 2051.07 05/28/2009 8.21 2062.70 3.00 2054.49 11/05/2009 9.89 2062.70 3.00 2052.81 05/13/2010 10.4.4 2062.70 3.00 2052.26 11/08/2010 11.12 2062.70 3.00 2051.58 05/17/2011 _ . 10.80 2062.70 3.00 2051.90 11/15/2011 11.43 2062.70 3.00 2051.27 05/17/2012 8.-91 2062.70 3.00 2053.79 MW-7R 11/07/2012 12.02 2062.86 3.00 2050.84 05/16/2013 1�11/20/2013 10.29 2062.86 3.00 2052.57 11.69 2062.86 3.00 2051.17 P:\Clement Pappas\Analytical & Data\Water\Historic GW Elev.xls Page 4 of 5 . Table 3 Current and Historical Groundwater Elevation Measurements Clement Pappas Hendersonville, North Carolina Well Identification Date Measured (mm/dd/yyyy) Depth to Groundwater (ft-BTOC) Top of Casing Elevation (feet) Top of. Casing Height Above Ground Surface (feet) Groundwater ,Elevation (feet) MW-8 05/15/2002 10.25 2061.40 3.00 2051.15 11/05/2002 10.35 2061.40 3.00 2051.05 05/13/2003 8.16 2061.40 3.00 2053.24 11/04/2003 10.23 2061.40 3.00 2051.17 05/05/2004 10.30 2061.40 3.00 2051.10 11/09/2004 8.90 2061.40 3.00 2052.50 05/17/2005 10.08 2061.40 3.00 2051.32 11/03/2005 10.61 2061.40 3.00 2050.79 05/24/2006 10.60 2061.40 3.00 2050.80- 11/09/2006 9.40 2061.40 3.00 2052.00 05/18/2007 10.31 2061.40 3.00 2051.09 11/13/2007 11.09 2061.40 3.00 2050.31 05/27/2008 10.83 2061.40 3.00 2050.57 11/18/2008 11.11 2061.40 3.00 2050.29 05/28/2009 8.25 2061.40 3.00 2053.15 11/05/2009 9.22 2061.40 3.00 2052.18 05/13/2010 9.88 2061.40 3.00 2051.52 11/08/2010 10.38 2061.40 3.00 2051.02 05/17/2011 10.27 2061.40 3.00 2051.13 11/15/2011 10.87 2061.40 3.00 2050.53 05/17/2012 8.03 2061.40 3.00 2053.37 11/07/2012 10.45 2060:80 3.00 2050.35 05/16/2013 8.58 2060.80 3.00 2052.22 11/20/2013 1 10.34 1 2060.80 1 3.00 2050.46 Notes: 1. ft-BTOC = feet below top of well casing. 2. MW-5 through MW-8 Top of Casing Elevations based upon a survey by Hill and Associates Surveyors dated January 10, 2002 through May 2012. 3. MW-2R and MW-4 Top of Casing Elevations based upon differential level measurements made by Altamont Environmental, Inc. on June 26, 2006 through May 2012. 4. Measurements were taken from the Top of Casing. Top of Casing Heights are given for reference only. 5. Groundwater Elevations = Top of Casing Elevation minus Depth to Groundwater. 6. The Top of Casing elevations for the monitoring wells were resurveyed on November 21, 2012 by Wes Cole Land Surveying. P:\Clement Pappas\Analytical & Data\Water\Historic GW Elev.xls Page 5 of 5 aceAnalytical Www.pacelabs.wm December 11, 2013 Mr. Evan Yurkovich Altamont Environmental 231 Haywood St. Asheville, NC 28801 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 RE: Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-717,6 Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Dear Mr. Yurkovich: Enclosed are the analytical results for sample(s) received by the laboratory on November 20, 2013. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Lord Patton lorri.patton@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 42 aceAnalytical www.pacelaftcam Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. Pace Analytical Services, Inc. 205 East Meadow Road - Suite 2225 Riverside Dr. Eden, NC 27288 Asheville, NC 28804 (336)623-8921 (828)254-7176 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Asheville Certification IDs 2225 Riverside Dr., Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 West Virginia Certification #: 357 VirginiaNELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC.28078 (704)875-9092 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 42 aceAnalytical www.pacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 . SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92186398001 MW-2R SM 9222D AES2 1 PASI-A SM 6200B CAH 63 PASI-C SM 2540C DAS 1 PASI-A EPA 300.0 . SAE 1 PASI-A EPA 350.1 JTM 1 PASI-A EPA353.2 DMN 1 PASI-A SM 4500-CI-E JDA 1 PASI-A SM 5310B SAE 1 PASI-A 92180398002 MW-4 SM 9222D AES2 1 PASI-A SM 6200B CAH 63 PASI-C SM 2540C DAS 1 PASI-A EPA300.0 SAE 1 PASI-A EPA 350.1 JTM 1 PASI-A EPA353.2 DMN 1 PASI-A SM 4500-CI-E JDA 1 PASI-A SM 5310B SAE 1 PASI-A 92180398003 MW-5 SM 9222D AES2 1 PASI-A SM 6200B CAH 63 PASI-C SM 2540C DAS 1 PASI-A EPA 300.0 SAE 1 PASI-A EPA 350.1 JTM 1 PASI-A EPA353.2 DMN 1 PASI-A SM 4500-CI-E JDA 1 PASI-A SM 5310B SAE 1 PASI-A 92180398004 MW-6 SM 9222D AES2 1 PASI-A SM 6200B CAH 63 PASI-C SM 2540C DAS 1 PASI-A EPA 300.0 SAE 1 PASI-A EPA350.1 JTM 1 PASI-A EPA353.2 DMN 1 PASI-A SM 4500-CI-E JDA 1 PASI-A SM 5310E SAE 1 PASI-A 92180398005 MW-7R SM 9222D AES2 1 PASI-A SM 6200B CAH 63 PASI-C SM 2540C DAS 1 PASI-A EPA 300.0 SAE 1 PASI-A EPA350.1 JTM 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 42 Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc. Q ►7�y J �+ ® aceAnalXical 205 East Meadow Road - Suite A Eden, NC 27288 2225 Riverside Dr. Asheville, NC 28804 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (336)623-8921 (828)254-7176 (704)875-9092 SAMPLE ANALYTE COUNT Project: Clement Pappas 2081 Pace Project No.: 92180398 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA353.2 DMN 1 PASI-A SM 4500-CI-E JDA 1 PASI-A SM 5310B SAE 1 PASI-A 92180398006 MW-8 SM 9222D AES2 1 PASI-A SM 6200B CAH 63 PASI-C SM 2540C DAS 1 PASI-A EPA 300.0 SAE 1 PASI-A EPA350.1 JTM 1 PASI-A EPA353.2 DMN 1 PASI-A SM 4500-CI-E JDA 1 PASI-A SM 5310E SAE 1 PASI-A 92180398007 Trip Blank SM 6200B CAH 63 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 42 l acMnaljdical wympacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-2R Parameters Lab ID: 92180398001 Collected: 11/20/13 10:01 Results Units Report Limit DF Received: 11/20/13 13:57 Matrix: Water Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms ND CFU/100 mL 1.0 1 11/20/13 16:14 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 11/26/13 02:52 71-43-2 Bromobenzene ND ug/L 0.50 1. 11/26/13 02:52 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/26/13 02:52 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/26/13 02:52 75-27-4 Bromoform ND ug/L 0.50 1 11/26/13 02:52 75-25-2 Bromomethane ND ug/L 5.0 1 11/26/13 02:52 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/26/13 02:52 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/26/13 02:52 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 11/26/13 02:52' 98-06-6 Carbon tetrachloride ND ug/L 0.50 . 1 11/26/13 02:52 56r23=5 Chlorobenzene ND ug/L 0.50 1 11/26/13 02:52 108-90-7 Chloroethane ND ug/L 1.0 1 11/26/13 02:52 75-00-3 Chloroform ND ug/L 0.50 1 11/26/13 02:52 67-66-3 Chloromethane ND ug/L 1.0 1 11/26/13 02:52 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/26/13 02:52 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/26/13 02:52 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/26/1'3 02:52 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/26/13 02:52 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/26/13 02:52 106-93-4 Dibromomethane ND ug/L 0.50 1 11/26/13 02:52 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/26/13 02:52 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/26/13 02:52 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/26/13 02:52 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/26/13 02:52 75-71-8 1.1-Diehl oroethane ND ug/L 0.50 1 11/26/13 02:52 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/26/13 02:52 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/26/13-02:52 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/26/13 02:52 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/26/13 02:52 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/26/13 02:52 .78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/26/13 02:52 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/26/13 02:52 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/26/13 02:52 563-58-6 cis- 1,3-Dichloropropene ND ug/L 0.50 1 11/26/13 02:52 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/26/13 02:52 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/26/13 02:52 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/26/13 02:52 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/26/13 02:52 87-68-3- Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/26/13 02:52 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/26/13 02:52 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/26/13 02:52 1634-04-4 Naphthalene ND ug/L 2.0 1 11/26/13 02:52 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/26/13 02:52 103-65-1 Styrene ND ug/L 0.50 1 11/26/13 02:52 100-42-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/11/2013 04:33 PM without the written consent of Pace Analytical Services, Inc.. Page 5 of 42 aceAnalyfical www.pacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-2R Parameters Lab ID: 92180398001 Collected: 11/20113 10:01 Results Units Report Limit DF Received: 11/20/13 13:57 Matrix: Water Prepared Analyzed CAS No. Qua[ 6200B MSV Analytical Method: SM 6200B 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/26/13 02:52 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/26/13 02:52 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/26/13 02:52 127-1874 Toluene ND ug/L 0.50 1 11/26/13 02:52 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/26/13 02:52 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/26/13 02:52 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 11/26/13 02:52 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/26/13 02:52 79-00-5 Trichloroethene ND ug/L 0.50 1 11/26/13 02:52 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 11/26/13 02:52 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/26/13 02:52 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/26/13 02:52 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/26/13 02:52 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/26/13 02:52 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/26/13 02:52 179601-23-1 o-Xylene ND ug/L 0.50 1 11/26/13 02:52 95-47-6 Surrogates 1,2-Dichloroethane-d4(S) 112 % 70-130 1 11/26/13 02:52 17060-07-0 4-Bromofluorobenzene (S) 100 % 70-130 1 11/26/13 02:52 460-00-4 Toluene-d8 (S) 100 % 70-130 1 11/26/13 02:52 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 66.0 mg/L 25.0 1 11/26/13 00:59 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Sulfate 9.3 mg/L 2.0 1 12/09/13 06:10 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 11/30/13 11:25 7664-41-7 353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA353.2 Nitrogen, Nitrate 0.97 mg/L 0.020 1 11/22/13 03:06 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 7.6 mg/L 1.0 1 12/10/1316:16 16887-00-6 5310B TOC Analytical Method: SM 5310B Total Organic Carbon . 6.1 mg/L 1.0 1 12/05/13 06:45 7440-44-0 REPORT OF LABORATORY ANALYSIS, This report shall not be reproduced, except in full, Date: 12/11/2013 04:33 PM without the written consent of Pace Analytical Services, Inc.. Page 6 of 42 aceAndljdical "Ampacelabs.cam Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Clement Pappas 2081 Pace Project No.: 92180398 Sample: MW-4 Lab ID: 92180398002 Collected: 11/20/13 09:21 Received: 11/20/13 13:57 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No.. Qua] MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms ND CFU/100 mL 1.0 1 11/20/13 16:14 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 11/26/13 03:08 71-43-2 Bromobenzene ND ug/L 0.50 1 11/26/13 03:08 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/26/13 03:08 74-97-5 Bromodichloromethane ND' ug/L 0.50 1 11/26/13 03:08 75-27-4 Bromoform ND ug/L 0.50 1 W26/13 03:08 75-25-2 Bromomethane ND ug/L 5.0 1 11/26/13 03:08 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/26/13 03:08 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/26/13 03:08 135-98-8. tert-Butyl benzene ND ug/L 0.50 1 11/26/13 03:08 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/26/13 03:08 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/26/13 03:08 108-90-7 Chloroethane ND ug/L 1.0 1 11/26/13 03:08 75-00-3 Chloroform ND ug/L 0.50 1 11/26/13 03:08 67-66-3 Chloromethane ND ug/L 1.0 1 11/26/13 03:08 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/26/13 03:08 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/26/13 03:08 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/26/13 03:08 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/26/13 03:08 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/26/13 03:08 106-93-4 Dibromomethane ND ug/L 0.50 1 11/26/13 03:08 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/26/13 03:08 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/26/13 03:08 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/26/13 03:08 106-46-7 Dichlorodifluoromethane ND ug/L r 0.50 1 11/26/13 03:08 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/26/13 03:08 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/26/13 03:08 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/26/13 03:08 75-35-4 cis- 1,2-Dichloroethene ND ug/L 0.50 1 11/26/13 03:08 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/26/13 03:08 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/26/13 03:09 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/26/13 03:08 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/26/13 03:08 594-20-7 - 1,1-Dichloropropene ND ug/L 0.50 1 11/26/13 03:08 563-58-6 cis- 1,3-Dichloropropene ND ug/L 0.50 1 11/26/13 03:08 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 11/26/13 03:08 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/26/13 03:08 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/26/13 03:08 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/26/13 03:08 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/26/13 03:08 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/26/13 03:08 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/26/13 03:08 1634-04-4 Naphthalene ND ug/L 2.0 1 11/26/13 03:08 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/26/13 03:08 103-65-1 Styrene ND ug/L 0.50 1 11/26/13. 03:08. 100-42-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/11/2013 04:33 PM without the written consent of Pace Analytical Services, Inc.. Page 7 of 42 laciAnalytical www.pacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-4 Lab ID: 92180398002 Collected: 11/20/13 09:21 Received: 11/20/13 13:57 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2, 3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trchloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethyl benzene 1,3,5-Trimethyl benzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 2540C Total Dissolved Solids Total Dissolved Solids 300.0 IC Anions 28 Days Sulfate 350.1 Ammonia Nitrogen, Ammonia 353.2 Nitrogen, N021NO3 unpres Nitrogen, Nitrate 4500 Chloride Chloride 5310B TOC Total Organic Carbon Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L Nb ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 111 % 99 % 98 % Analytical Method: SM 2540C 157 mg/L Analytical Method: EPA 300.0 22.1 mg/L Analytical Method: EPA 350.1 ND mg/L Analytical Method: EPA 353.2 0.026 mg/L Analytical Method: SM 4500-CI-E 14.7 mg/L Analytical Method: SM 5310B 8.0 mg/L 0.50 1 11/26/13 03:08 630-20-6 0.50 1 11/26/13 03:08 79-34-5 0.50 1 11/26/13 03:08 127-18-4 0.56 1 11/26/13 03:08 108-88-3 2.0 1 11/26/13 03:08 87-61-6 2.0 1 11/26/13 03:08 120-82-1 0.50 1 11/26/13 03:08 71-55-6 0.50 1 11/26/13 03:08 79-b0-5 0.50 1 11/26/13 03:08 79-01-6 1.0 1 11/26/13 03:08 75-69-4 0.50 1 11/26/13 03:08 96-18-4 0.50 1 11/26/13 03:08 95-63-6 0.50 1 11/26/13 03:08 108-67-8 1.0 1 11/26/13 03:08 75-01-4 1.0 1 11/26/13 03:08 179601-23-1 0.50 1 11/26/13 03:08 95-47-6 70-130 1 11/26/13 03:08 17060-07-0 70-130 1 11/26/13 03:08 460-00-4 70-130 1 11/26/13 03:08 2037-26-5 25.0 1 11/26/13 01:00 2.0 1 12/09/13 06:23 14808-79-8 0.10 1 11/30/1311:25 7664-41-7 0.020 1 11/22/13 02:53 1.0 1 12/10/13 16:16 16887-00-6 2.0 2 12/05/1317:07 7440-44-0 Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 42 aceAnalj&al www.pacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Sample: MW-5 , Parameters MBIO 9222D Fecal Coliform AVL Fecal Coliforms 6200B MSV Benzene Bromobenzene Bromochloromethane Bromodichloromethan Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloro Dibromochloromethan 1,2-Dibromoethane (E Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluorometha 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-*1,2-Dichloroethen trans- 1,2-Dichloroethe 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis- 1,3-Dichloropropene trans- 1,3-Dichloropropene ene mene) Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadi Isopropylbenzene (Cu Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene e propane e DB) ne e ne Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID: 92180398003 Collected: 11/20/13 11:27 Received: 11/20/13 13:57 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual Analytical Method: SM 9222D 1.0 CFU/100 mL A nalytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L" ND ug/L 80.6 ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L -ND ug/L ND ug/L ND ug/L 1.0 1 11/20/1316:14 1.2 2,5 12/03/13 04:04 71-43-2 1.2 2.5 12/03/13 04:04 108-86-1 1.2 2.5 12/03/13 04:04 74-97-5 1.2 2.5 12/03/13 04:04 75-27-4 1.2 2.5 12/03/13 04:04 75-25-2 12.5 2.5 12/03/13 04:04 74-83-9 1.2 2.5 12/03/13 04:04 104-51-8 1.2 2.5 12/03/13 04:04 135-98-8 1.2 2.5 12/03/13 04:04 98-06-6 1.2 2.5 12/03/13 04:04 56-23-5 1.2 2.5 12/03/13 04:04 108-90-7 2.5 2.5 12/03/13 04:04 75-00-3 1.2 2.5 12/03/13 04:04 67-66-3 2.5 2.5 12/03/13 04:04 74-87-3 1.2 2.5 12/03/13 04:04 95-49-8 1.2 2.5 12/03/13 04:04 106-43-4 2,5 2.5 12/03/13 04:04 96-12-8 1.2 2.5 12/03/13 04:04 124-48-1 .1.2 2.5 12/03/13 04:04 106-93-4 1.2 2.5 12/03/13 04:04 74-95-3 1.2 2.5 12/03/13 04:04 95-50-1 1.2 2.5 12/03/13 04:04 541-73-1 1.2 2.5 12/03/13 04:04 106-46-7 1.2 2.5 12/03/13 04:04 75-71-8 1.2 2.5 12/03/13 04:04 75-34-3 1.2 2.5 12/03/13 04:04 107-06-2 1.2 2.5 12/03/13 04:04 75-35-4 1.2 2.5 12/03/13 04:04 156-59-2 1.2 2.5 12/03/13 04:04 156-60-5 1.2 2.5 12/03/13 04:04 78-87-5 1.2 2.5 12/03/13 04:04 142-28-9 1.2 2.5 12/03/13 04:04 594-20-7 1.2 2.5 12/03/13 04:04 563=58-6 1.2 2.5 12/03/13 04:04 10061-01-5 1.2 2.5 12/03/13 04:04 10061-02-6 1.2 2.5 12/03/13 04:04 108-20-3 1.2 2.5 12/03/13 04:04 100-41-4 5.0 2.5 12/03/13 04:04 87-68-3 1.2 .2.5 12/03/13 04:04 98-82-8 5.0 2.5 12/03/13 04:04 75-09-2 1.2 2.5 12/03/13 04:04 1634-04-4 5.0 2.5 12/03/13 04:04 91-20-3 1.2 2.5 12/03/13 04:04 103-65-1 1.2 2.5 -12/03/13 04:04 100-42-5 Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 42 aceAnalytical www.pacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-5 Lab ID: 92180398003 Collected: 11/20/13 11:27 Received: 11/20/13 13:57 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B 1,1,1,2-Tetrachloroethane ND ug/L 1.2 2.5 12/03/13 04:04 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.2 2.5 12/03/13 04:04 79-34-5 Tetrachloroethene 332 ug/L 1.2 2.5 12/03/13 04:04 127-18-4 Toluene ND ug/L 1.2 2.5 12/03/13 04:04 108-88-3 1,2,3-Trichlorobenzene ND ug/L 5.0 2.5 12/03/13 04:04 87-61-6 1,2,4-Trichlorobenzene ND ug/L 5.0 2.5 12/03/13 04:04 120-82-1 1,1,1-Trichloroethane ND ug/L 1.2 2.5 12/03/13 04:04 71-55-6 1,1,2-Trichloroethane ND ug/L 1.2 2.5 12/03/13 04:04 79-00-5 Trichloroethene 65.1 ug/L 1.2 2.5 12/03/13 04:04 79-01-6 Trichlorofluoromethane ND ug/L 2.5 2.5 12/03/13 04:04 75-69-4 1,2,3-Trichloropropane ND ug/L 1.2 2.5 12/03/13 04:04 96-18-4 1,2,4-Trimethylbenzene ND ug/L 1.2 2.5 12/03/13 04:04 95-63-6 1,3,5-Trimethylbenzene ND ug/L 1.2 2.5 12/03/13 04:04 108-67-8 Vinyl chloride ND ug/L 2.5 2.5 12/03/13 04:04 75-01-4 m&p-Xylene ND ug/L 2.5 2.5 12/03/13 04:04 179601-23-1 o-Xylene ND ug/L 1.2 2.5 12/03/13 04:04 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 96 % 70-130 2.5 12/03/13 04:04 17060-07-0 4-Bromofluorobenzene (S) 98 % 70-130 2.5 12/03/13 04:04 460-00-4 Toluene-d8 (S) 100 % 70-130 2.5 12/03/13 04:04 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 162 mg/L 25.0 1 11/26/13 01:00 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Sulfate ND mg/L 2.0 1 12/09/13 06:37 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 11/30/13 11:27 7664-41-7 353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA353.2 . Nitrogen, Nitrate 0.19 mg/L 0.020 1 11/22113 03:19 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 64.6 mg/L 5.0 5 12/10/13 16:48 16887-00-6 5310B TOC Analytical Method: SM 5310B Total Organic Carbon 4.2 mg/L 1.0 1 12/05/13 07:23 7440-44-0 Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 42 aceAnalyfical www.pacelabs.com i Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Clement Pappas 2081 Pace Project No.: 92180398 Sample: MW-6 Lab ID: 92180398004 Collected: 11/20/13 10:45 Received: 11/20/13 13:57 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[ MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms ND CFU/100 mL 1.0 1 11/20/13 16:14 6200E MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 11/26/13 03:24 71-43-2 Bromobenzene ND ug/L 0.50 1 11/26/13 03:24 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/26/13 03:24 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/26/13 03:24 75-27-4 Bromoform ND ug/L 0.50 1 11/26/13 03:24 75-25-2 Bromomethane ND ug/L' 5.0 1 11/26/13 03:24 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/26/13 03:24 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/26/13 03:24 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 11/26/13 03:24 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/26/13 03:24 56-23-5 r Chlorobenzene ND ug/L 0.50 1 11/26/13 03:24 108-90-7 . Chloroethane ND ug/L 1.0 1 11/26/13 03:24 75-00-3 Chloroform ND ug/L 0.50 1 11/26/13 03:24 67-66-3 Chloromethane ND ug/L 1.0 1 11/26/13 03:24 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/26/13 03:24 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/26/13 03-24 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/26/13 03:24 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/26/13 03:24 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/26/13 03:24 106-93-4 Dibromomethane ND ug/L 0.50 1 11/26/13 03:24 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/26/13 03:24 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/26/13 03:24 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/26/13 03:24 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/26/13 03:24 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/26/13 03:24 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/26/13 03:24 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/26/13 03:24 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/26/13 03:24 156-59-2 trans- l,2-Dichi oroethene ND ug/L 0.50 1 11/26/13 03:24 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/26/13 03:24 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/26/13 03:24 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/26/13 03:24 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/26/13 03:24 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/26/13 03:24 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/26/13 03:24 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/26/13 03:24 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/26/13 03:24 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/26/13 03:24 87-68-3 [sop ropy] benzene (Cumene) ND ug/L 0.50 1 11/26/13 03:24 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/26/13 03:24 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/26/13 03:24 1634-04-4 Naphthalene ND ug/L 2.0 1 11/26/13 03:24 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/26/13 03:24 103-65-1 Styrene ND ug/L 0.50 1 11/26/13 03:24 100-42-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/11/2013 04:33 PM without the written consent of Pace Analytical Services, Inc.. Page 11 of 42 aceAnalytkc l www.pacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-6 Lab ID: 92180398004 Collected: 11120/13 10:45 Received: 11/20/13 13:57 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2, 3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Tri chlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 2540C Total Dissolved Solids Total Dissolved Solids 300.0 IC Anions 28 Days Sulfate 350.1 Ammonia Nitrogen, Ammonia 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 4500 Chloride Chloride 5310B TOC Total Organic Carbon Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 116 % 101 % 100 % Analytical Method: SM 2540C 56.0 mg/L Analytical Method: EPA 300.0 8.6 mg/L Analytical Method: EPA 350.1 ND mg/L Analytical Method: EPA 353.2 ND mg/L Analytical Method: SM 4500-CI-E 7.3 mg/L Analytical Method: SM 5310B 4.4 mg/L 0.50 1 11/26/13 03:24 630-20-6 0.50 1 11/26/13 03:24 79-34-5 0.50 1 11/26/13 03:24 127-18-4 0.50 1 11/26/13 03:24 108-88-3 2.0 1 11/26/13 03:24 87-61-6 2.0 1 11/26/13 03:24 120-82-1 0.50 1 11/26/13 03:24 71-55-6 0.50 1 11/26/13 03:24 79-00-5 0.50 1 11/26/13 03:24 79-01-6 1.0 1 11/26/13 03:24 75-69-4 0.50 1 11/26/13 03:24 96-18-4 0.50 1 11/26/13 03:24 95-63-6 0.50 1 11/26/13 03:24 108-67-8 1.0 1 11/26/13 03:24 75-01-4 1.0 1 11/26/13 03:24 179601-23-1 0.50 1 11/26/13 03:24 95-47-6 70-130 1 70-130 1 70-130 1 25.0 1 2.0 1 0.10 1 0.020 1 1.0 1 1.0 1 11/26/13 03:24 17060-07-0 11/26/13 03:24 460-00-4 11/26/13 03:24 2037-26-5 11/26/13 01:01 12/09/13 07:45 14808-79-8 11/30/1311:27 7664-41-7 11/22/13 03:12 12/10/13 16:27 16887-00-6 12/05/13 07:33 7440-44-0 Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 42 aceAnaiyfical® www.pacelabs.com Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Clement Pappas 2081 Pace Project No.: 92180398 Sample: MW-7R Lab ID: 92180398005 Collected: 11/20/13 12:07 Received: 11/20/13 13:57 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform AVL . Analytical Method: SM 9222D Fecal Coliforms ND CFU/100 mL 1.0 1 11/20/13 16:14 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 11/26/13 03:40 71-43-2 Bromobenzene ND ug/L 0.50 1 11/26/13 03:40 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/26/13 03:40 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/26/13 03:40 75-27-4 Bromoform ND ug/L 0.50 1 11/26/13 03:40 75-25-2 Bromomethane ND ug/L 5.0 1 11/26/13 03:40 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/26/13 03:40 104-51-8 sec -Butyl benzene ND ug/L .0.50 1 11/26/13 03:40 135-98-8 lert-Butylbenzene ND ug/L 0.50 1 11/26/13 03:40 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/26/13'03:40 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/26/13 03:40 108-90-7 Chloroethane ND ug/L 1.0 1 11/26/13 03:40 75-00-3 Chloroform ND ug/L 0.50 1 " 11/26/13 03:40 67-66-3 Chloromethane ND ug/L 1.0 1 11/26/13 03:40 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/26/13 03:40 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/26/13 03:40 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/26/13 03:40 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/26/13 03:40 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/26/13 03:40 106-93-4 Dibromomethane ND ug/L 0.50 1 11/26/13 03:40 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/26/13 03:40 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/26/13 03:40 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/26/13 03:40 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/26/13 03:40 75-7118 1,1-Dichloroethane ND ug/L 0.50 1 11/26/13 03:40 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/26/13 03:40 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/26/13 03:40 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/26/13 03:40 156-59-2 trans- 1,2-Dichloroethene ND ug/L 0.50 1 11/26/13 03:40 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/26/13 03:40 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/26/13 03:40 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/26/13 03:40 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/26/13 03:40 563-58-6 cis- 1,3-Dichloropropene ND ug/L 0.50 1 11/26/13 03:40 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/26/13 03:40 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/26/13 03:40 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/26/13 03:40 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/26/13 03:40 87-68-3 Isopropyl benzene (Cumene) ND ug/L 0.50 1 11/26/13 03:40 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/26/13 03:40 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/26/13 03:40 1634-04-4 Naphthalene ND ug/L 2.0 1 11/26/13 03:40 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/26/13 03:40 103-65-1 Styrene ND ug/L 0.50 1 11/26/13 03:40 100-42-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/11/2013 04:33 PM without the written consent of Pace Analytical Services, Inc.. Page 13 of 42 aceAnalytical www.pacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-B921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services; Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-7R Lab ID: 92180398005 Collected: 11/20/13 12:07 Received: 11/20/13 13:57 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 2540C Total Dissolved Solids Total Dissolved Solids 300.0 IC Anions 28 Days Sulfate 350.1 Ammonia Nitrogen, Ammonia 353.2 Nitrogen, N021NO3 unpres Nitrogen, Nitrate 4500 Chloride Chloride 5310B TOC Total Organic Carbon Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 113 % 100 % 97 % Analytical Method: SM 2540C ND mg/L Analytical Method: EPA 300.0 3.5 mg/L Analytical Method: EPA 350.1 ND mg/L Analytical Method: EPA 353.2 5.5 mg/L Analytical Method: SM 4500-CI-E 14.0 mg/L Analytical Method: SM 5310B 9.4 mg/L 0.50 1 11/26/13 03:40 630-20-6 0.50 1 11/26/13 03:40 79-34-5 0.50 1 11/26/13 03:40 127-18-4 0.50 1 11/26/13 03:40 108-88-3 2.0 1 11/26/13 03:40 87-61-6 2.0 1 11/26/13 03:40 120-82-1 0.50 1 11/26/13 03:40 71-55-6 0.50 1 11/26/13 03:40 79-00-5 0.50 1 11/26/13 03:40 79-01-6 1.0 1 11/26/13 03:40 75-69-4 0.50 1 11/26/13 03:40 96-18-4 0.50 1 11/26/13 03:40 95-63-6 0.50 1 11/26/13 03:40 108-67-8 1.0 1 11/26/13 03:40 75-01-4 1.0 1 11/26/13 03:40 179601-23-1 0.50 1 11/26/13 03:40 95-47-6 70-130 1 70-130 1 70-130 1 250 1 2.0 1 0.10 1 0.040 2 1.0 1 1.0 1 11/26/13 03:40 17060-07-0 11/26/13 03:40 460-00-4 11/26/13 03:40 2037-26-5 11/26/13 01:01 12/09/13 08:26 14808-79-8 11/3011311:30 7664-41-7 11/22/13 04:24 12/10/13 16:27 16887-00-6 I W05/13 08:24 7440-44-0 Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 42 aceAnalyticai� www.pacelabs.com Project: Clement Pappas 2081 Pace Analytical Services, Inc. Pace Analytical Services, Inc. 205 East Meadow Road - Suite A 2225 Riverside Dr. Eden, NC 27288 Asheville, NC 28804 (336)623-8921 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Project No.: 92180398 Sample: MW-8 Lab ID: 92180398006 Collected: 11/20/13 12:40 Received: 11/20/13 13:57 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua] MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms ND CFU/100 mL 1.0 1 11/20/13 16:14 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 11/26/13 03:56 71-43-2 Bromobenzene ND ug/L 0.50 1 11/26/13 03:56 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/26/13 03:56 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/26/13 03:56 75-27-4 Bromoform ND ug/L 0.50 1 11/26/13 03:56 75-25-2 Bromomethane ND ug/L 5.0 1 11/26/13 03:56 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/26/13 03:56 104-51-8 . sec-Butylbenzene ND ug/L 0.50 1 11/26/13 03:56 135-98-8 _ tert-Butyl benzene ND ug/L 0.50 1 11/26/13 03:56 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/26/13 03:56 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/26/13 03:56 108-90-7 Chloroethane ND ug/L 1.0 1 11/26/13 03:56 75-00-3 Chloroform ND ug/L 0.50 1 11/26/13 03:56 67-66-3 Chloromethane ND ug/L 1.0 1 11/26/13 03:56 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/26/13 03:56 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/26/13 03:56 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 •11/26/13 03:56 96-12-8 Dibromochloromethane ND `ug/L 0.50 1 11/26/13 03:56 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/26/13 03:56 106-93-4 Dibromomethane ND ug/L 0.50 1 11/26/13 03:56 74-95-3 1,2-Dichlorobenzene ND ug/L 6.50 1 11/26/13 03:56 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/26/13 03:56 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/26/13 03:56 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/26/13 03:56 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/26/13 03:56 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/26/13 03:56 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/26/13 03:56 75-35-4 cis-1,2-Dichloroethene ND' ug/L 0.50 1 11/26/13 03:56 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/26/13 03:56 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/26/13 03:56 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/26/13 03:56 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/26/13 03:56 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/26/13 03:56 563-58-6 cis- 1,3-Dichloropropene ND ug/L 0.50 1 11/26/13 03:56 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/26/13 03:56 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/26/13 03:56 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/26/13 03:56 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/26/13 03:56 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/26/13 03:56 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/26/13 03:56 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/26/13 03:56 1634-04-4 Naphthalene ND ug/L 2.0 1 11/26/13 03:56 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/26/13 03:56 103-65-1 Styrene ND ug/L 0.50 1 11/26/13 03:56 100-42-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/11/2013 04:33 PM without the written consent of Pace Analytical Services, Inc.. Page 15 of 42 IeAnalytical www.pacelabs.com Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Clement Pappas 2081 Pace Project No.: 92180398 Sample: MW-8 Lab ID: 92180398006 Collected: 11/20/13 12:40 Received: 11/20/13 13:57 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/26/13 03:56 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/26/13 03:56 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/26/13 03:56 127-18-4 Toluene ND ug/L 0.50 1 11/26/13 03:56 108-88-3 1,2,3-Trichlorobenzene. ND ug/L 2.0 1 11/26/13 03:56 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/2611303:56 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 11/26/13 03:56 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/26/13 03:56 79-00-5 Trichloroethene ND ug/L 0.50 1 11/26/13 03:56 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 11/26/13 03:56 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/26/13 03:56 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/26/13 03:56 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/26/13 03:56 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/26/13 03:56 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/26/13 03:56 179601-23-1 o-Xylene ND ug/L 0.50 1 11/26/13 03:56 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 114 % 70-130 1 11/26/13 03:56 17060-07-0 4-Bromofluorobenzene (S) 101 % 70-130 1 11/26/13 03:56 460-00-4 Toluene-d8 (S) 97 % 70-130 1 11/26/13 03:56 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 342 mg/L 25.0 1 11/26/13 01:01 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Sulfate 24.3 mg/L 2.0 1 12/09/13 08:39 14808-79-8 350.1 Ammonia Analytical Method: EPA350.1 Nitrogen, Ammonia ND mg/L 0.10 1 11/30/13 11:32 7664-41-7 353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA353.2 Nitrogen, Nitrate 1.3 mg/L 0.020 1 11/22/13 03:22 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 15.4 mg/L 1.0 1 12/10/1316:28 16887-00-6 5310E TOC Analytical Method: SM 5310B Total Organic Carbon 21.0 mg/L 1.0 1 12/05/13 08:35 7440-44-0 Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 42 aceAndiXical wmpacelabs.com Project: Clement Pappas 2081 Pace Project. No.: 92180398 Sample: Trip Blank Parameters 6200B MSV Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec -Butyl benzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlo rodifl uorometha ne 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3. Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID: 92180398007 Collected: 11/20/13 00:00 Received: 11/20/13 13:57 Matrix: Water Results Units Report Limit DF Analytical Method: SM 6200B Prepared Analyzed CAS No. Qua[ ND ug/L 0.50 1 11/26/13 04:11 71-43-2 ND ug/L 0.50 1 11/26/13 04:11 108-86-1 ND ug/L 0.50 1 11/26/13 04:11 74-97-5 ND ug/L 0.50 1 11/26/13 04:11 75-27-4 ND ug/L 0.50 1 11/26/13 04:11 75-25-2 ND ug/L 5.0 1 11/26/13 04:11 74-83-9 ND ug/L 0.50 1 11/26/13 04:11 104-51-8 ND ug/L 0.50 1 11/26/13 04:11 135-98-8 ND ug/L 0.50 1 11/26/13 04:11 98-06-6 ND ug/L 0.50 1 11/26/13 04:11 56-23-5 ND ug/L 0.50 1 11/26/13 04:11 108-90-7 ND ug/L 1.0 1 11/26/13 04:11 75-00-3 ND ug/L 0.50 1 11/26/13 04:11 67-66-3 ND ug/L , 1.0 1 11/26/13 04:11 74-87-3 ND ug/L 0.50 1 11/26/13 04:11 95-49-8 ND ug/L 0.50 1 11/26/13 04:11 106-43-4 ND ug/L 1.0 1 11/26/13 04:11 96-12-8 ND ug/L 0.50 1 11/26/13 04:11 124-48-1 ND ug/L 0.50 1 11/26/13 04:11 106-93-4 ND ug/L 0.50 1 11/26/13 04:11 74-95-3 ND ug/L 0.50 1 11/26/13 04:11 95-50-1 ND ug/L 0.50 1 11/26/13 04:11 541-73-1 ND ug/L 0.50 1 11/26/13 04:11 106-46-7 ND ug/L 0.50 1 11/26/13 04:11 75-71-8 ND ug/L 0.50 1 11/26/13 04:11 75-34-3 ND ug/L 0.50 1 11/26/13 04:11 107=06-2 ND ug/L 0.50 1 11/26/13 04:11 75-35-4 ND ug/L -0.50 1 11/26/13 04:11 156-59-2 ND ug/L 0.50 1 11/26/13 04:11 156-60-5 ND ug/L 0.50 .1 11/26/13 04:11 78-87-5 ND ug/L 0.50 1 11/26/13 04:11 142-28-9 ND ug/L 0.50 1 11/26/13 04:11 594-20-7 ND ug/L 0.50 1 11/26/13 04:11 563-58-6 ND ug/L - 0.50 1 11/26/13 04:11 10061-01-5 ND ug/L 0.50 1 11/26/13 04:11 10061-02-6 ND ug/L 0.50 1 11/26/13 04:11 108-20-3 ND ug/L 0.50 1 11/26/13 04:11 100-41-4 ND ug/L 2.0 1 11/26/13 04:11 87-68-3 ND ug/L 0.50 1 11/26/13 04:11 98-82-8 ND ug/L 2.0 1 11/26/13 04:11 75-09-2 ND ug/L 0.50 1 11/26/13 04:11 1634-04-4 ND ug/L 2.0 1 11/26/13 04:11 91-20-3 ND ug/L 0.50 1 11/26/13 04:11 103-65-1 ND ug/L 0.50 1 11/26/13 04:11 100-42-5 ND ug/L 0.50 1 11/26/13 04:11 630-20-6 ND ug/L 0.50 1 11/26/13 04:11 79-34-5 ND ug/L 0.50 1 11/26/13 04:11 127-18-4 Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 42 1ceAnafyfical www.pacelabs.com Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project:. Clement Pappas 2081 Pace Project No.: 92180398 Sample: Trip Blank Lab ID: 92180398007 Collected: 11/20/13 00:00 Received: 11/20/13 13:57 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B Toluene ND ug/L ' 0.50 1 11/26/13 04:11 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/26/13 04:11 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/26/13 04:11 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 11/26/13 04:11 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/26/13 04:11 .79-00-5 Trichloroethene ND ug/L 0.50 1 11/26/13 04:11 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 11/26/13 04:11 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/26/13 04:11 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/26/13 04:11 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/26/13 04:11 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/26/13 04:11 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/26/13 04:11 179601-23-1 o-Xylene ND ug/L 0.50 1 11/26/13 04:11 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 112 % 70-130 1 11/26/13 04:11 17060-07-0 4-Bromofluorobenzene (S) 100 % 70-130 1 11/26/13 04:11 460-00-4 Toluene-d8 (S) 98 % 70-130 1 11/26/13 04:11 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/11/2013 04:33 PM without the written consent of Pace Analytical Services, Inc.. Page 18 of 42 aceAnalyfical www.pacefabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA QC Batch: MBIO/7418 Analysis Method: SM 9222D QC Batch Method: SM 9222D Analysis Description: 9222D MBIO Fecal Coliform -AVL Associated Lab Samples: 92180398001, 92180398002, 92180398003, 92180398004, 92180398005, 92180398006 METHOD BLANK: 1091847 Matrix: Water Associated Lab Samples: 92180398001, 92180398002, 92180398003, 92180398004, 92180398005, 92180398006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 11/20/13 16:14 SAMPLE DUPLICATE: 1091848 92180180005 Dup Parameter Units Result Result Fecal Coliforms CFU/100 mL 29.0 27.0 RPD Qualifiers VA Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 42 aceAnalytkal www.pacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 QC Batch: MSV/25038 QC Batch Method: SM 6200B Pace Analytical Services, Inc. Pace Analytical Services, Inc. 205 East Meadow Road - Suite A 2225 Riverside Dr. Eden, NC 27288 Asheville, NC 28804 (336)623-8921 (828)254-7176 QUALITY CONTROL DATA Analysis Method: SM 6200B Analysis Description: 6200B MSV Associated Lab Samples: 92180398001, 92180398002, 92180398004, 92180398005, 92180398006, 92180398007 METHOD BLANK: 1093873 Matrix: Water Associated Lab Samples: 92180398001, 92180398002, 92180398004, 92180398005, 92180398006, 92180398007 Blank Reporting Parameter Units Result Limit Analyzed- Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 0.50 11/26/13 01:01 1,1,1-Trichloroethane ug/L ND 0.50 11/26/13 01:01 1,1,2,2-Tetrachloroethane ug/L ND 0.50 11/26/13 01:01 1,1,2-Trichloroethane ug/L ND 0.50 11/26/13 01:01 1,1-Dichloroethane ug/L- ND 0.50 11/26/13 01:01 1,1-Dichloroethene ug/L ND 0.50 11/26/13 01:01 1,1-Dichloropropene ug/L ND 0.50 11/26/13 01:01 1,2,3-Trichlorobenzene ug/L ND 2.0 11/26/13 01:01 1,2,3-Trichloropropane ug/L ND 0.50 11/26/13 01:01 1,2,4-Trichlorobenzene ug/L ND 2.0 11/26/13 01:01 1,2,4-Trimethylbenzene ug/L ND 0.50 11/26/13 01:01 1,2-Dibromo-3-chloropropane ug/L k ND 1.0 11/26/13 01:01 1,2-Dibromoethane (EDB) ug/L ND 0.50 .11/26113 01:01 1,2-Dichlorobenzene ug/L ND 0.50 11/26/13 01:01 1,2-Dichloroethane ug/L ND 0:50 11/26/13 01:01 1,2-Dichloropropane ug/L ND 0.50 11/26/13 01:01 1,3,5-Trimethylbenzene ug/L ND 0.50 11/26/13 01:01 1,3-Dichlorobenzene ug/L ND 0.50 11/26/13 01:01 1,3-Dichloropropane ug/L ND 0.50 11/26/13 01:01 1,4-Dichlorobenzene ug/L ND 0.50 11/26/13 01:01 2,2-Dichloropropane ug/L ND 0.50 11/26/13 01:01 2-Chlorotoluene ug/L ND 0.50 11/26/13 01:01 4-Chlorotoluene ug/L ND 0.50 11/26/13 01:01 Benzene ug/L ND 0.50 11/26/13 01:01 Bromobenzene ug/L ND 0.50 11/26/13 01:01 Bromochloromethane ug/L ND 0.50 11/26/13 01:01 Bromodichloromethane ug/L ND 0.50 11/26/13 01:01 Bromoform ug/L ND 0.50 11/26/13 01:01 Bromomethane ug/L ND 5.0 11/26/13 01:01 Carbon tetrachloride ug/L ND 0.50 11/26/13 01:01 Chlorobenzene ug/L ND 0.50 11/26/13 01:01 Chloroethane ug/L ND 1.0 11/26/13 01:01 Chloroform ug/L ND 0.50 11/26/13 01:01 Chloromethane ug/L ND 1.0 11/26/13 01:01 cis- 1,2-Dichloroethene ug/L ND 0.50 11/26/13 01:01 cis- 1,3-Dichloropropene ug/L ND 0.50 11/26/13 01:01 Dibromochloromethane ug/L ND 0.50 11/26/13 01:01 Dibromomethane ug/L ND 0.50 11/26/13 01:01 Dichlorodifluoromethane ug/L ND 0.50 11/26/13 01:01 Diisopropyl ether ug/L ND 0.50 11/26/13 01:01 Ethylbenzene ug/L ND 0.50 11/26/13 01:01 Hexachloro-1,3-butadiene ug/L ND 2.0 11/26/13 01:01 Isopropylbenzene (Cumene) ug/L ND 0.50 11/26/13 01:01 Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/11/2013 04:33 PM without the written consent of Pace Analytical Services, Inc.. Page 20 of 42 (�IaneAnalytical www.pacelabs.mm Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA METHOD BLANK: 1093873 Matrix: Water Associated Lab Samples: 92180398001, 92180398002, 92180398004, 92180398005, 92180398006, 92180398007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers m&p-Xylene ug/L ND 1.0 11/26/13 01:01 Methyl-tert-butyl ether ug/L ND 0.50 11/26/13 01:01 Methylene Chloride ug/L ND 2.0 11/26/13 01:01 n-Butylbenzene ug/L ND 0.50 11/26/13 01:01 n-Propylbenzene ug/L, ND 0.50 11/26/13 01:01 Naphthalene ug/L ND 2.0 11/26/13 01:01 o-Xylene. ug/L ND 0.50 11/26/13 01:01 sec-Butylbenzene ug/L ND 0.50 11/26/13 01:01 Styrene ug/L ND 0.50 11/26/13 01:01 tert-Butylbenzene ug/L ND 0.50 11/26/13 01:01 Tetrachloroethene ug/L ND 0.50 11/26/13 01:01 Toluene ug/L ND 0.50 11/26/13 01:01 trans- l,2-Dichloroethene ug/L ND 0.50 11/26/13 01:01 trans- l,3-Dichloropropene ug/L ND 0.50 11/26/13 01:01 Trichloroethene ug/L ND 0.50 11/26/13 01:01 Trichlorofluoromethane ug/L ND 1.0 .11/26/13 01:01 Vinyl chloride ug/L ND 1.0 11/26/13 01:01 1,2-Dichloroethane-d4 (S) % 111 70-130 11/26/13 01:01 4-Bromofluorobenzene (S) % 98 70-130 11/26/13 01:01 Toluene-d8 (S) % 99 70-130 11/26/13 01:01 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1093874 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 50.0 100 60-140 1,1,1-Trichloroethane ug/L 50 47.4 95 60-140 1,1,2,2-Tetrachlor6ethane ug/L 50 46.2 92 60-140 1,1,2-Trichloroethane ug/L 50 47.8 96 60-140 1,1-Dichloroethane ug/L 50 43.4 87 60-140 1,1-Dichloroethene ug/L 50 47.7 95 60-140 1,1-Dichloropropene ug/L 50 46.8 94 60-140 1,2,3-Trichlorobenzene ug/L 50 50.6 101 60-140 1,2,3-Trichloropropane ug/L 50 46.8 94 60-140 1,2,4-Trichlorobenzene ug/L 50 49.7 99 60-140 1,2,4-Trimethylbenzene ug/L 50 48.7 97 60-140 1,2-Dibromo-3-chloropropane ug/L 50 53.0 106 60-140 1,2-Dibromoethane (EDB) ug/L 50 48.6 97 60-140 1,2-Dichlorobenzene ug/L 50 48.7 97 60-140 1,2-Dichloroethane ug/L 50 47.6 .95 60-140 1,2-Dichloropropane ug/L 50 43.7 87 60-140 1,3,5-Trimethylbenzene ug/L 50 48.3 97 60-140 1,3-Dichlorobenzene ug/L 50 47.4 95 60-140 1,3-Dichloropropane ug/L 50 48.7 97 60-140 1,4-Dichlorobenzene ug/L 50 46.8 94 60-140 2,2-Dichloropropane ug/L 50 44.1 88 60-140 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/11/2013 04:33 PM without the written consent of Pace Analytical Services, Inc.. Page 21 of 42 coeAnalytical www.pacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE: 1093874 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Parameter Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 2-Chlorotoluene ug/L 50. 47.8 96 607140 4-Chlorotoluene ug/L 50 49.6 99 60-140 Benzene ug/L 50. 44.1 88 60-140 Bromobenzene ug/L 50 48.0 96 60-140 Bromochloromethane ug/L 50 41.6 83 60-140 Bromodichloromethane ug/L 50 48.2 96 60-140 Bromoform ug/L 50 49.8 100 60-140 Bromomethane ug/L 50 67.2 134 60-140 CU,F3 Carbon tetrachloride ug/L 50 46.8 94 60-140 Chlorobenzene ug/L 50 45.3 91 60-140 Chloroethane ug/L. 50 47.0 94 60-140 Chloroform ug/L 50 43.4 87 60-140 Chloromethane ug/L 50 54.6 109 60-140 cis-1,2-Dichloroethene ug/L 50 43.1 86 60-140 cis-1,3-Dichloropropene ug/L 50 48.3 97 60-140 Dibromochloromethane ug/L 50 50.0 100 60-140 Dibromomethane ug/L 50 47.2 94 60-140 Dichlorodifluoromethane ug/L 50 41.1 82 60-140 Diisopropyl ether ug/L 50 46.0 92 60-140 Ethylbenzene. ug/L 50 46.2 92 60-140 Hexachloro-1,3-butadiene ug/L 50 49.5 99 60-140 Isopropylbenzene (Cumene) ug/L 50 47.3 95 60-140 m&p-Xylene ug/L 100 92.3 92 60-140 Methyl-tert-butyl ether ug/L 50 48.0 96 60-140 Methylene Chloride ug/L 50 44.1 88 60-140 n-Butylbenzene ug/L 50 48.5 97 60-140 n-Propylbenzene ug/L 50 49.2 98 60-140 Naphthalene ug/L 50 51.3 103 60-140 o-Xylene ug/L 50 47.0 94 60-140 sec-Butylbenzene ug/L 50 48.5 97 60-140 Styrene ug/L 50 47.5 95 60-140 tert-Butylbenzene ug/L 50 48.8 98 60-140 Tetrachloroethene ug/L 50 47.3 95 60-140 Toluene ug/L 50 44.9 90 60-140 trans-1,2-Dichloroethene ug/L 50 46.1 92 60-140 trans-1,3-Dichloropropene ug/L 50 48.5 97 60-140 Trichloroethene ug/L 50 45.2 90 60-140 Trichlorofluoromethane ug/L 50 52.2 104 60-140 Vinyl chloride ug/L 50 63.1 126 60-140 1,2-Dichloroethane-d4 (S) % 105 70-130 4-Bromofluorobenzene (S) % 97 70-130 Toluene-d8 (S) % 103 70-130 Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report Shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 42 aneAnalXkal www.pacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27286 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1093876 1093876 MS MSD 92180742005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec %Rec Limits RPD Qua] 1,1,1,2-Tetrachloroethane ug/L <0.50 20 20 18.5 19.0 93 95 60-140 2 1,1,1-Trichloroethane ug/L <0.50 20 20 18.3 18.7 91 93 60-140 2 1,1,2,2-Tetrachloroethane ug/L <0.50 20 20 18.2 18.8 91 94 60-140 3 1,1,2-Trichloroethane ug/L <0.50 20 20 18.2 18.0 91 90 60-140 1 1,1-Dichloroethane ug/L <0.50 20 20 17.2 17.4 86 - 87 60-140 2 1,1-Dichloroethene ug/L <0.50 20 20 16.8 16.9 84 85 60-140 1 1,1-Dichloropropene ug/L <0.50 20 20 18.0 18.6 90 93 60-140 3 1,2,3-Trichlorobenzene ug/L <2.0 20 20 16.4 16.6 82 83 60-140 1 1,2,3-Trichloropropane ug/L <0.50 20 20 17.7 18.5 89 92 60-140 4 1,2,4-Trichlorobenzene ug/L <2.0 20 20 16.0 16.1 80 80 60-140 1 1,2,4-Trimethylbenzene ug/L 2.2 20 20 19.8 20.3 88 90 60-140 3 1,2-Dibromo-3-chloropropane ug/L <1.0 20 20 17.2 17.8 86 89 60-140 3 1,2-Dibromoethane (EDB) ug/L <0.50 20 20 17.5 18.1 88 90 60-140 3 1,2-Dichlorobenzene ug/L <0.50 20 20 16.9 17.5 84 88 60-140 4 1,2-Dichloroethane ug/L 9.8 20 20 25.8 26.1 80 81 60-140 1 1,2-Dichlor8propane. ug/L <0.50 20 20 17.5 17.8 87 89 60-140 2 1,3,5-Trimethylbenzene ug/L 4.4 20 20 22.0 22.5 88 90 60-140 2 1,3-Dichlorobenzene ug/L <0.50 20 20 16.7 16.9 83 85 60-140 1 1,3-Dichloropropane ug/L <0.50 20 20 17.7 17.8 88 89 60-140 1 1,4-Dichlorobenzene ug/L <0.50 20 20 16.8 17.1 84 86 60-140 2 2,2-Dichloropropane ug/L <0.50 20 20 16.5 16.8 82 84 60-140 2 2-Ch]oroto]uene ug/L <0.50 20 20 16.7 17.2 84 86 60-140 3 4-Ch]oroto]uene ug/L <0.50 20 20 17.3 17.9 86 89 60-140 3 Benzene ug/L 25.1 20 20 41.4 41.8 81 83 60-140 1 Bromobenzene ug/L <0.50 20 20 16.8 17.2 84 86 60-140 2 Bromochloromethane ug/L <0.50 20 20 18.0 18.2 90 91 60-140 1 Bromodichloromethane ug/L <0.50 20 20 17.6 18.5 88 92 60-140 5 Bromoform rig/L <0.50 20 20 15.6 16.2 78 81 60-140 4 Bromomethane ug/L <5.0 20 20 16.0 15.6 80 78 60-140 2 Carbon tetrachloride ug/L <0.50 20 20 18.4 18.3 92 91 60-140 1 Chlorobenzene ug/L <0.50 20 20 17.4 17.7 87 .89 60-140 2 Chloroethane ug/L <1.0 20 20 16.5 16.5. 83 82 60-140 0 Chloroform ug/L <0.50 20 20 17.7 17.6 87 86 60-140 0 Chloromethane ug/L <1.0 20 20 17.8 17.9 89 89 60-140 0 cis-1,2-Dichloroethene ug/L <0.50 20 20 16.7 17.3 84 86 60-140 3 cis-1,3-Dichloropropene ug/L <0.50 20 20 17.3 17.6 87 88 60-140 1 Dibromochloromethane ug/L <0.50 20 20 16.4 17.0 82 85 60-140 4 Dibromomethane ug/L <0.50 20 20 17.2 17.7 86 88 60-140 3 Dichlorodifluoromethane ug/L <0.50 20 20 18.7 19.0 94 95 60-140 1 Diisopropy] ether ug/L 7.2 20 20 22.4 23.0 76 79 60-140 3 Ethylbenzene ug/L 3.3 20 20 21.1 21.4 89 90 60-140 1 Hexach]oro-1,3-butadiene ug/L <2.0 20 20 17.4 17.9 87 90 60-140 3 Isopropylbenzene (Cumene) ug/L 0.82 20 20 19.7 20.0 94 96 60-140 1 m&p-Xylene ug/L 4.1 -40 40 41.3 41.7 93 94 60-140 1 Methyl-tert-butyl ether ug/L 32.6 20 .20 36.1 39.7 17 35 60-140 10 MO Methylene Chloride ug/L <2.0 20 20 18.0 18.2 90 91 60-140 1 n-Butylbenzene ug/L <0.50 20 20 18.9 19.2 93 94 60-140 2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/11/2013 04:33 PM without the written consent of Pace Analytical Services, Inc.. Page 23 of 42 aceAnalytical mmpacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1093875 1093876 MS MSD - 92180742005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua] n-Propylbenzene ug/L 0.68 20 20 19.4 19.7 93 95 60-140 1 Naphthalene ug/L 6.9 20 20 22.6 23.6 78 84 60-140 4 o-Xy]ene ug/L 1.2 20 20 19.4 19.7 91 93 60-140 2 sec -Butyl benzene ug/L <0.50 20 20 18.9 19.3 94 96 60-140 2 Styrene ug/L <0.50 20 20 18.8 18.8 94 94 60-140 0 tert-Butylbenzene ug/L <0.50 20 20 18.2 19.0 91 95 60-140 5 Tetrachloroethene ug/L <0.50 20 20 18.7 19.2 94 96 60-140 2 Toluene ug/L 1.4 20 20 19.2 19.5 89 90 60-140 1 trans-1,2-Dich]oroethene ug/L <0.50 20 20 15.4 15.7 77 78 60-140 2 trans-1,3-Dichloropropene ug/L <0.50 20 20 17.2 18.0 86 90 60-140 4 Trichloroethene ug/L <0.50 20 20 17.9 18.4 90 92 60-140 2 Trichlorofluoromethane ug/L <1.0 20 20 19.1 18.9 96 94 60-140 1 Vinyl chloride ug/L <1.0 20 20 18.3 18.3 92 92 60-140 0 1,2-Dichloroethane-d4 (S) % 98 100 70-130 4-Bromofluorobenzene (S) % 101 100 70-130 Toluene-d8 (S) % 99 100 70-130 Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 42 aceAnaWkal "pacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. Pace Analytical Services, Inc. 205 East Meadow Road - Suite A 2225 Riverside Dr. Eden, NC 27288 Asheville, NC 28804 (336)623-8921 (828)254-7176 QUALITY CONTROL DATA QC Batch: MSV/25114 Analysis Method: SM 62008 QC Batch Method: SM 6200B Analysis Description: 6200B MSV Associated Lab Samples: 92180398003 METHOD BLANK: 1096884 Associated Lab Samples: 92180398003 Parameter Units Matrix: Water Blank Reporting Result Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 0.50 12/02/13 23:22 1,1,1-Trichloroethane ug/L ND 0.50 12/02/13 23:22 1,1,2,2-Tetrachloroethane ug/L ND 0.50 12/02/1323:22 1,1,2-Trichloroethane ug/L ND 0.50 12/02/13 23:22 1,1-Dichloroethane ug/L ND 0.50 12/02/13 23:22 1,1-Dichloroethene ug/L ND 0.50 12/02/13 23:22 1,1-Dichloropropene ug/L ND 0.50 12/02/13 23:22 1,2,3-Trichlorobenzene ug/L ND 2.0 12/0211323:22 1,2,3-Trichloropropane ug/L ND 0.50 12/02/13 23:22 1,2,4-Trichlorobenzene ug/L ND 2.0 12/02/13 23:22 1,2,4-Trimethylbenzene ug/L ND 0.50 12/02/13 23:22 1,2-Dibromo-3-chloropropane ug/L ND 1.0 12/02/13 23:22 1,2-Dibromoethane(EDB) ug/L ND 0.50 12/02/13 23:22 1,2-Dichlorobenzene ug/L ND 0.50 12/02/13 23:22 1,2-Dichloroethane ug/L ND 0.50 12/02/1323:22 1,2-Dichloropropane ug/L ND 0.50 12/02/13 23:22 1,3,5-Trimethylbenzene ug/L ND 0.50 12/0211323:22 1,3-Dichlorobenzene ug/L ND 0.50 12/02/13 23:22 1,3-Dichloropropane ug/L ND - 0.50 12/02/13 23:22 1,4-Dichlorobenzene ug/L ND 0.50 12/02/13 23:22 2,2-Dichloropropane ug/L ND 0.50 12/02/13 23:22 2-Chlorotoluene ug/L ND 0.50 12/02/13 23:22 4-Chlorotoluene ug/L ND 0.50 12/02/13 23:22 Benzene ug/L ND 0.50 12/02/13 23:22 Bromobenzene ug/L ND 0.50 12/02/13 23:22 Bromochloromethane ug/L ND 0.50 12/02/13 23:22 Bromodichloromethane ug/L ND 0.50 12/02/13 23:22 Bromoform ug/L ND 0.50 12/02/13 23:22 Bromomethane ug/L ND 5.0 12/02/13 23:22 Carbon tetrachloride ug/L ND 0.50 12/02/13 23:22 Chlorobenzene ug/L ND 6.50 12/02/13 23:22 Chloroethane ug/L ND 1.0 12/02/13 23:22 Chloroform ug/L ND 0.50 12/02/13 23:22 Chloromethane ug/L ND 1.0 12/02/13 23:22 cis- 1,2-Dichloroethene ug/L ND 0.50 12/02/13 23:22 cis- 1,3-Dichloropropene ug/L ND 0.50 12/02/13 23:22 Dibromochloromethane ug/L ND 0.50 12/0211323:22 Dibromomethane ug/L ND 0.50 12/02/13 23:22 Dichlorodifluoromethane ug/L ND 0.50 12/02/13 23:22 Diisopropyl ether ug/L ND . 0.50 12/02/13 23:22 Ethylbenzene ug/L ND 0.50 12/02/13 23:22 Hexachloro-1,3-butadiene ug/L ND 2.0 12102/1323:22 Isopropylbenzene (Cumene) ug/L ND 0.50 12/02/13 23:22 Qualifiers Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/11/2013 04:33 PM without the written consent of Pace Analytical Services, Inc.. Page 25 of 42 laiAnalytical www.pacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 METHOD BLANK: 1096884 Matrix: Water Associated Lab Samples: 92180398003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers m&p-Xylene ug/L ND" 1.0 12/02/13 23:22 Methyl-tert-butyl ether ug/L ND 0.50 12/02/13 23:22 Methylene Chloride ug/L ND 2.0 12/02/13 23:22 n-Butylbenzene ug/L ND 0.50 12/02/13 23:22 n-Propylbenzene ug/L ND 0.50 12/02/13 23:22 Naphthalene ug/L ND 2.0 12/02/13 23:22 o-Xylene ug/L ND 0.50 12/02/13 23:22 sec-Butylbenzene ug/L ND 0.50 12/02/13 23:22 Styrene ug/L ND 0.50 12/02/13 23:22 tert-Butylbenzene ug/L ND 0.50 12/02/13 23:22 Tetrachloroethene ug/L ND 0.50 12/02/13 23:22 Toluene ug/L ND 0.50 12/02/13 23:22 trans-1,2-Dichloroethene ug/L ND 0.50 12/02/13 23:22 trans-1,3-Dichloropropene ug/L ND 0.50 12/02/13 23:22 Trichloroethene ug/L ND 0.50 12/02/13 23:22 Trichlo rofluo ro methane ug/L. ND 1.0 12/0211323:22 Vinyl chloride ug/L ND 1.0 12/02/13 23:22 1,2-Dichloroethane-d4 (S) % 99 70-130 12/02/13 23:22 4-Bromofluorobenzene (S) % 97 70-130 12/02/13 23:22 Toluene-d8 (S) % . 102 70-130 12/02/13 23:22 LABORATORY CONTROL SAMPLE: 1096885 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 53.7 107 60-140 1,1,1-Trichloroethane ug/L 50 50.6 101 60-140 1,1,2,2-Tetrachloroethane ug/L 50 49.9 100 60-140 1,1,2-Trichloroethane ug/L 50 50.6 101 60-140 1,1-Dichloroethane ug/L 50 47.4 95 60-140 1,1-Dichloroethene ug/L 50 45.9 92 60-140 1,1-Dichloropropene ug/L 50 49.3 99 60-140 1,2,3-Trichlorobenzene ug/L 50 47.0 94 60-140 1,2,3-Trichloropropane ug/L 50 48.9 98 60-140 1,2,4-Trichlorobenzene ug/L 50 47.1 94 60-140 1,2,4-Trimethylbenzene ug/L 50 48.8 98 60-140 1,2-Dibromo-3-chloropropane ug/L 50 51.9 104 60-140 1,2-Dlbromoethane (EDB) ug/L 50 50.9 102 60-140 1,2-Dichlorobenzene ug/L 50 47.7 95 60-140 1,2-Dichloroethane ug/L 50 47.0 94 60-140 1,2-Dichloropropane ug/L 50 49.2 98 60-140" 1,3,5-Trimethylberizene ug/L 50 49.6 99 60-140 1,3-Dichlorobenzene ug/L 50 46.8 94 60-140 1,3-Dichloropropane ug/L 50 49.2 98 60-140 1,4-Dichlorobenzene ug/L 50 46.7 93 60-140 2,2-Dichloropropane ug/L 50 47.5 95 60-140 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/11/2013 04:33 PM without the written consent of Pace Analytical Services, Inc.. Page 26 of 42 aceAnalytical www.pacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road -Suite A Eden, NC 27288 (336)623-8921 LABORATORY CONTROL SAMPLE: 1096885 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Analytical Services, Inc. 9806 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Parameter Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 2-Chlorotoluene ug/L 50 46.8 94 60-140 4-Chlorotoluene ug/L 50 47.9 96 60-140 Benzene ug/L 50 47.3 95 60-140 Bromobenzene ug/L 50 47.7 95 60-140 Bromochloromethane ug/L 50 48.1 96 60-140 Bromodichloromethane ug/L 50 53.3 107 60-140 Bromoform ug/L 50 46.7 93 60-140 Bromomethane ug/L 50 59.8 120 60-140 Carbon tetrachloride ug/L 50 50.2 100 60-140 Chlorobenzene ug/L 50 48.5 97 60-140 Chloroethane ug/L 50 40.8 82. 60-140 Chloroform ug/L 50 48.7. - 97 60-140 Chloromethane ug/L 50 52.8 106 60-140 cis-1,2-Dichloroethene ug/L 50 47.1 94 60-140 cis-1,3-Dichloropropene ug/L 50 52.5 105 60-140. Dibromochloromethane ug/L 50 55.8 112 60-140 Dibromomethane ug/L 50 48.8 98 60-140 Dichlorodifluoromethane ug/L 50 52.1 104 60-140 Diisopropyl ether ug/L 50 50.4 101 60-140 Ethylbenzene ug/L 50 49.4 99 60-140 Hexachloro-1',3-butadiene ug/L 50 49.2 98 60-140 Isopropylbenzene (Cumene) ug/L 50 51.6 103 60-140 m&p-Xylene ug/L 100 99.8 100 60-140 Methyl-tert-butyl ether ug/L 50 49.8 100 60-140 Methylene Chloride ug/L 50 49.6 99 60-140. n-Butylbenzene ug/L 50 49.4 99 60-140 n-Propylbenzene ug/L 50 49.5 99 60-140 Naphthalene ug/L 50 47.8 96 60-140 o-Xylene ug/L 50 50.0 100 60-140 sec -Butyl benzene ug/L 50 50.4 101 60-140 Styrene ug/L 50 53.0 106 60-140 tert-Butylbenzene ug/L 50 49.9 100 60-140 Tetrachloroethene ug/L 50 49.0 98 60-140 Toluene ug/L 50 46.7 93 60-140 trans-1,2-Dichloroethene ug/L 50 49.4 99 60-140 trans-1,3-Dichloropropene ug/L 50 53.6 107 60-140 Trichloroethene ug/L 50 47.7 95 60-140 Trichlorofluoromethane ug/L 50 44.5 89 60-140 Vinyl chloride ug/L 50 50.8 102 60-140 1,2-Dichloroethane-d4 (S) % 100 70-130 4-Bromofluorobenzene (S) % 101 70-130 Toluene-d8 (S) % 99 70-130 Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 42 Pace Analytical Services, Inc. Pace Analytical Services, Inc. aCCAn ® 205 East Meadow Road - Suite A 2225 Riverside Dr. ! I�IICaI Eden, NC 27288 Asheville, NC 28804 www.pacelabs.com (336)623-8921 (1328)254-7176 QUALITY CONTROL DATA Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1096886 MS 92181258002 Spike Parameter Units Result Conc. MSD Spike Conc. 1096887 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Qua] 1,1,1,2-Tetrach]oroethane ug/L ND 20 20 16.4 20.1 82 101 60-140 20 1,1,1-Tr]ch]oroethane ug/L ND 20 20 16.7 20.3 83 101 60-140 20 1,1,2,2-Tetrachloroethane ug/L ND 20 20 15.6 18.9 78 94 60-140 19 1,1,2-Trichloroethane ug/L ND 20 20 16.5 19.7 82 98 60-140 18 1,1-Dichloroethane ug/L ND 20 20 15.7 18.7 79 93 60-140 17 1,1-Dichloroethene ug/L ND 20 20 16.5 19.1 83 95 60-140 15 1,1-Dichloropropene ug/L ND 20 20 16.7 19.8 83 99 60-140 17 1,2,3-Trichlorobenzene ug/L ND 20 20 13.4 16.6 67 83 60-140 21 1,2,3-Trichloropropane ug/L ND 20 20 15.4 18.7 77 93 60-140 20 1,2,4-Trichlorobenzene ug/L ND 20 20 13.8 16.6 69 83 60-140 18 1,2,4-Trimethylbenzene ug/L ND 20 20 15.5 18.7 78 93 60-140 19 - 1,2-Dibromo-3-chloropropane ug/L ND 20 20 14.4 18.2 72 91 60-140 24 1,2-Dibromoethane (EDB) ug/L ND 20 20 15.9 19.2 79 96 60-140 19 1,2-Dichlorobenzene ug/L ND 20 20 15.0 18.0 75 - 90 60-140 18 1,2-Dichloroethane ug/L ND 20 20 15.1 18.2 75 91 60-140 19 1,2-Dichloropropane ug/L ND 20 20 16.2 19.9 81 100 60-140 21 1,3,5-Trimethylbenzene ug/L ND 20 20 16.0 19.0 80 95 60-140 17 1,3-Dichlorobenzene ug/L ND 20 20 14.8 17.4 74 87 60-140 16 1,3-Dichloropropane ug/L ND 20 20 16.0 19.2 80 96 60-140 . 18 1,4-Dichlorobenzene ug/L ND 20 20 14.9 17.9 75 90 60-140 18 2,2-Dichloropropane ug/L ND 20 20 13.8 16.6 69 83 60-140 18 2-Chlorotoluene - ug/L ND 20 20 15.0 18.0 75 90 60-140 18 4-Chlorotoluene ug/L ND 20 20 15.3 18.5 77 93 60-140 19 Benzene ug/L ND 20 20 15.9 19.2 79 96 60-140 19 Bromobenzene ug/L ND 20 20 15.3 18.3 77 91 60-140 17 Bromochloromethane ug/L ND 20 20 - 16.1 19.1 81 95 60-140 17 Bromodichloromethane ug/L ND 20 20 16.3 19.9 81 99 60-140 20 Bromoform ug/L ND 20 20 14.1 16.7 70 84 60-140 17 Bromomethane ug/L ND 20 20 17.1 21.0 86 105 60-140 21 Carbon tetrachloride ug/L ND 20 20 16.2 19.9 81 99 60-140 20 Chlorobenzene ug/L ND 20 20 15.8 19.0 79 95 60-140 19 Chloroethane ug/L ND 20 20 15.8 17.3 79 87 60-140 10 Chloroform ug/L ND 20 20 16.0 19.0 80 95 60-140 17 Ch]oromethane ug/L ND 20 20 17.2 20.5 86 103 60-140 18 cis-1,2-Dichloroethene ug/L ND 20 20 15.6 18.7 78 94 60-140 18 cis-1,3-Dichloropropene ug/L ND 20 20 15.8 19.1 79 95 60-140 19 Dibromochloromethane ug/L ND 20 20 .15.4 19.3 77 97 60-140 23 Dibromomethane ug/L ND 20 20 15.8 19.0 79 95 60-140 19 Dichlorodifluoromethane ug/L ND 20 20 19.5 22.5 97 112 60-140 14 Diisopropy] ether ug/L ND 20 20 15.9 19.4 79 97 60-140 20 Ethy]benzene ug/L ND 20 20 16.0 19.4 80 97 60-140 19 Hexachloro-1,3-butadiene ug/L ND 20 20 14.6 17.4 73 87 60-140 - 18 Isopropy]benzene (Cumene) ug/L ND 20 20 16.8 20.1 84 101 60-140 18 m&p-Xylene ug/L ND 40 40 32.6 39.3 81 98 60-140 19 Methyl-tert-butyl ether ug/L ND 20 20 14.1 19.0 70 95 60-140 30 Methylene Chloride ug/L ND 20 20 16.7 19.0 83 95 60-140 13 n-Butylbenzene ug/L ND 20 20 15.4 18.3 77 91 60-140 17 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/11/2013 04:33 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 42 aceAnalj4kal www.p,acelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1096886 MS 92181258002 Spike Parameter Units Result Conc. n-Propylbenzene ug/L ND 20 Naphthalene ug/L ND 20 o-Xylene ug/L ND 20 sec-Butylbenzene ug/L ND 20 Styrene ug/L ND 20 tert-Butylbenzene ug/L ND 20 Tetrachloroethene ug/L ND 20 Toluene ug/L ND 20 trans- 1,2-Dichloroethene ug/L ND 20. trans- 1,3-Dichloropropene ug/L ND 20 Trichloroethene ' ug/L ND 20 Trichlorofluoromethane ug/L ND 20 Vinyl chloride ug/L ND 20 1,2-Dichloroethane-d4 (S) % 4-Brorriofluorobenzene (S) % Toluene-d8 (S) % Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 1096887 MSD Spike MS MSD MS MSD % Rec Conc. Result Result % Rec % Rec Limits RPD 20 . 16.1 19.4 81 97 60-140 18 20 14.3 17.5 71 87 60-140 20 20 16.3 19.5 81 97 60-140 18 20 16.4 - 19.4 82 97 60-140 17 20 16.5 20.2 83 101 60-140 20 20 16.1 19.4 80 97 60-140 18 20 16.5 19.3 83 96 60-140 15 20 15.6 18.7 78 93 60-140 18 20 14.6 18.5 73 93 60-140 23 20 15.8 19.5 79 97 60-140 21 20 16.3 19.6 82 98 60-140 18 20 17.0 19.7 85 98 60-140 14 20 18.3 21.3 92 106 60-140 15 93 97 70-130 99 100 70-130 100 100 70-130 Qual . Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 42 aceAnalyfical Wm.pacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA QC Batch: WET/28317 Analysis Method: SM 2540C QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids Associated Lab Samples: 92180398001, 92180398002, 92180398003, 92180398004, 92180398005, 92180398006 METHOD BLANK: 1094011 Matrix: Water Associated Lab Samples: 92180398001, 92180398002, 92180398003, 92180398004, 92180398005, 92180398006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 11/26/13 00:58 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 . (704)875-9092 LABORATORY CONTROL SAMPLE: 1094012 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Dissolved Solids mg/L 250 248 99 80-120 SAMPLE DUPLICATE: 1094013 92180398001 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 66.0 68.0 3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/11/2013 04:33 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 42 aceAnalytical www.pacelabsxom Pace Analytical Services, Inc. 205 East Meadow Road - Suite Eden, NC 27288 (336)623-B921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Clement Pappas 2081 Pace Project No.: 92180398 QC Batch: WETA/17339 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92180398001, 92180398002, 92180398003 METHOD BLANK: 1097579 Matrix: Water Associated Lab Samples: 92180398001, 92180398002, 92180398003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L ND 2.0 12/09/13 00:03 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1097580 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.5 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1097581 1097582 MS MSD 92179943004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Sulfate mg/L 5.0 20• 20 23.0 22.8 90 89 90-110 1 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1097583 1097584 MS MSD 92180299001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD . Qual Sulfate mg/L ND 20 20 17.3 15.2 86 76 90-110 13 M1 Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 42 aceAnalytical® www.pacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA QC Batch: WETA/17340 Analysis Method: EPA300.0 QC Batch Method: EPA300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92180398004, 92180398005, 92180398006 METHOD BLANK: 1097586 Matrix: Water Associated Lab Samples: 92180398004, 92180398005, 92180398006 Blank Reporting Parameter Units Result Limit Analyzed Sulfate mg/L ND 2.0 12/09/13 07:18 Qualifiers Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1097587 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.0 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1097588 1097589 MS MSD 92180398004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua] Sulfate mg/L 8.6 20 20 27.8 27.8 96 96 90-110 0 Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 32 of 42 aceAnalytical www.pace1abs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road -Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA QC Batch: WETA/17314 Analysis Method: EPA 350.1 QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia Associated Lab Samples: 92180398001, 92180398002, 92180398003, 92180398004, 92180398005, 92180398006 METHOD BLANK: 1096424 Matrix: Water Associated Lab Samples: 92180398001, 92180398002, 92180398003, 92180398004, 92180398005, 92180398006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 11/30/13 11:14 LABORATORY CONTROL SAMPLE: 1096425 Spike LCS Parameter Units Conc. Result Nitrogen, Ammonia mg/L 5 5.0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1096426 1096427 MS MSD 92180379002. Spike Spike MS Parameter Units Result Conc. Conc. Result Nitrogen, Ammonia mg/L - 0.16 5 5 5.0 Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 LCS % Rec % Rec Limits Qualifiers 100 90-110 MSD MS MSD % Rec Result % Rec % Rec Limits RPD Qual 4.9 96 96 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1096428 1096429 MS MSD 92180398005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua] Nitrogen, Ammonia mg/L ND 5 5 4.7 4.7 95 94 90-110 1 Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 33 of 42 aceAnNXical www.pacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA QC Batch: WETA/17230 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92180398001, 92180398002, 92180398003, 92180398004, 92180398005, 92180398006 Pace Analytical Services, Inc. 9800 KinceyAve. Suite 1o0 Huntersville, NC 28078 (704)875-9092 METHOD BLANK: 1092184 Matrix: Water Associated Lab Samples: 92180398001, 92180398002, 92180398003, 92180398004, 92180398005, 92180398006 Blank Reporting . Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.020 11/22/13 02:48 LABORATORY CONTROL SAMPLE: 1092185 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1092186 1092187 MS MSD 92180398002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. ' Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 0.026 2.5 2.5 2.5 2.5 99 98 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1092188 1092189 MS MSD 92180398001. Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 0.97 2.5 2.5 3.4 3.4 96 96 90-110 0 Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 34 of 42 Wce**'ical www.pacelabs.com Project: • Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 QC Batch: WETA/17421 QC Batch Method: SM 4500-CI-E Associated Lab Samples: 92180398001, 92180398002 METHOD BLANK: 1101950 Associated Lab Samples: 92180398001, 92180398002 Parameter Units Chloride mg/L Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 I QUALITY CONTROL DATA Analysis Method: SM 4500-CI-E Analysis Description: 4500 Chloride Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 1.0 12/10/1315:54 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1101951 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 21.0 105 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1101952 1101953 MS MSD 92179945004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits' RPD Q6al Chloride mg/L 2.1 20 20 23.3 22.8 106 104 75-125 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1101954 1101955 MS MSD 92180272002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 25.8 20 20 44.7 48.7 95 115 75-125 8 Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without. the written consent of Pace Analytical Services, Inc.. Page 35 of 42 aceAnalXical www.ppcelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA QC Batch: WETA/17422 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92180398003, 92180398004, 92180398005, 92180398006 METHOD BLANK: 1101960 Matrix: Water Associated Lab Samples: 92180398003, 92180398004, 92180398005, 92180398006 Blank Reporting Parameter Units Result Limit Analyzed Chloride mg/L ND 1.0 12/10/1316:17 Qualifiers Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1101961 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 21.0 105 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1101962 1101963 MS MSD 92180356001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua] Chloride mg/L 1.1 20 - 20 22.1 22.5 105 107 75-125 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1101964 1101965 MS MSD 92180866002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. ' Conc. Result Result % Rec % Rec Limits RPD Qua] Chloride mg/L 3.7 20 20 24.5 24.1 104 102 75-125 2 Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 36 of 42 acoAnaiXical--® tw w.pacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 205 East Meadow Road -Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA QC Batch: WETA/17342 Analysis Method: SM 5310B QC Batch Method: SM 5310B Analysis Description: 5310B TOC Associated Lab Samples: 92180398001, 92180398002, 92180398003, 92180398004, 92180398005, 92180398006 METHOD BLANK: 1097596 Matrix: Water Associated Lab Samples: 92180398001, 92180398002, 92180398003, 92180398004, 92180398005, 92180398006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon . mg/L ND 1.0 12/05/13 03:05 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1097597 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 25 23.4 94 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1097598 MS 92179943005 Spike Parameter Units Result Conc. Total Organic Carbon mg/L 1.8 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1097600 MS 92180398001 Spike Parameter Units Result Conc. Total Organic Carbon mg/L 6.1 25 1097599 MSD Spike MS MSD MS MSD % Rec Conc. Result Result % Rec % Rec Limits RPD 25 23.1 23.2 85 85 75-125 0 1097601 MSD Spike MS MSD MS MSD % Rec Conc. Result Result % Rec % Rec . Limits RPD 25 26.6 26.4 82 81 75-125 1 Qual Qua] Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 37 of 42 aceAnalyical rwnvpacelabs.com Project: Clement Pappas 2081 Pace Project No.: 92180398 DEFINITIONS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 QUALIFIERS Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PRL- Pace Reporting Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services -Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS CU The continuing calibration for this compound is outside of Pace Analytical acceptance limits. Analyte presence below reporting limits in associated samples. Results unaffected by high bias. F3 . The recovery of the second source standard used to verify the initial calibration curve for this analyte is outside the laboratory's control limits. The result is estimated. Mo Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/11/2013 04:33 PM without the written consent of Pace Analytical Services, Inc.. Page 38 of 42 aceAnalX cal m..pecelabs.com Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Clement Pappas 2081 Pace Project No.: 92180398 Lab ID 92180398001 92180398002 92180398003 92180398004 92180398005 92180398006 92180398001 92180398002 92180398003 92180398004 92180398005 92180398006 92180398007 92180398001 92180398002 92180398003 92180398004 92180398005 92180398006 92180398001 92180398002 92180308003 92180398004 92180398005 92180398006 92180398001. 92180398002 92180398003 92180396004 92180398005 92180398006 92180398001 92180398002 92180398003 92180398004 92180398005 92180398006 92180398001 92180398002 92180398003 92180398004 92180398005 92180398006 Sample ID MW-2R MW-4 MW-5 MW-6 MW-7R MW-8 MW-2R M W-4 MW-5 MW-6 MW-7R MW-8 Trip Blank MW-2R MW-4 MW-5 MW-6 MW-7R MW-2R MW-4 MW-5 MW-6 MW-7R MW-8 MW-2R MW-4 MW-5 MW-6 MW-7R MW-8 MW-2R MW-4 MW-5 MW-6 MW-7R MW-8 MW-2R MW-4 MW-5 MW-6 MW-7R MW-8 QC Batch Method SM 9222D SM 9222D SM 9222D SM 9222D SM 9222D SM 9222D SM 6200B SM 6200B SM 6200B SM 6200B SM 6200B SM 6200B SM 6200B SM 2540C SM 2540C SM 2540C SM 2540C SM 2540C SM 2540C ^~ EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 350.1 EPA 350.1 EPA 350.1 EPA 350.1 EPA 350.1 EPA 350.1 EPA 353.2 EPA 353.2 EPA 353.2 EPA 353.2 EPA 353.2 EPA 353.2 SM 4500-CI-E SM 4500-CI-E SM 4500-CI-E SM 4500-CI-E SM 4500-CI-E SM 4500-CI-E QC Batch MBIO/7418 MB10/7418 MBIO/7418 MB10/7418 MBIO/7418 MBIO/7418 MSV/25038 MSV/25038 MSV/25114 MSV/25038 MSV/25038 MSV/25038 MSV/25038 WET/28317 WET/28317 WET/28317 WET/28317 WET/28317 WET/28317 WETA/17339 WETAJ17339 WETA/17339 WETA/17340 WETA/17340 WETA/17340 WETA/17314 WETA/17314 WETA/17314 WETA/17314 WETA/17314 WETA/17314 WETA/17230 WETA/17230 WETA/17230 WETA/17230 WETA/17230 WETA117230 WETA/17421 WETA/17421 WETA/17422 WETA/17422 WETA/17422 WETA/17422 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersvilie, NC 28078 (704)875-9092 Analytical Method Analytical Batch Date: 12/11/2013 04:33 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 39 of 42 aceAnalytcal wmpacelabs.cam Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Clement Pappas 2081 Pace Project No.: 92180398 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 92180398001 MW-2R SM 5310B WETA/17342 92180398002 MW-4 SM 5310B WETA/17342 92180398003 MW-5 SM 5310E WETN17342 92180398004 MW-6 SM 5310E WETA/17342 92180398005 MW-71R. SM 5310B WETA/17342 92180398006 MW-8 SM 5310E WETA/17342 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/11/2013 04:33 PM without the written consent of Pace Analytical Services, Inc.. Page 40 of 42 ace Analytical m _ i www.pacelahs.com CHAIWOF-CUSTODY / Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Oil 0 Section A Section B Section C.• Page: of Required Client Information: Required Project Information: Invoice Information: a Company:. II Report To: Attention: •L L / VVV Address: Q Copy J To: Company Name:. REGULATORY AGENCY:. rz--* ` A4%a'J;'11. Address: j` NPDES -"-GROUND WATER ? DRINKING WATER r UST r RCRA j OTHER Email To: :• .. \ Purchase Order No.: Pace quote Reference: Phone: Fax ,: Project L Name: Pace Project Sete Location tD�n .;. Manager. Requested Due Date/iAT:' Project Number. I Pace Profits 'Requested Analgsis Filtered .{YIN) Section D , Matrix Codes- d y RequiredClientinformaaon MATRIX / CODE COLLECTED. Preservatives ->,_ � 2- Drinking Water DW 0 cOt z Water WT �� O Waste Water ' W W m COMPOSITE COMPOSITE 1= PfadDCi P START ENDIGRAS Ul SOII/SOlid SL r9 - €y: SAMPLE ID Wipe WP it ¢ a) (AMUSTB) ar AR z y Sample IDS MUST BE UNIQUE Tissue TS O a 0= ¢ b ` � Other OT X w, W. 'N U # OZ o tW ¢ O ca. V U DATE TIME DATE TIME' �' _ 2 Z Z O j _ Pace Project No./ Lab I.D. = _Ir w tt �� 1 ► -y Z_'. w V n 3 IQ It XXI YY Jr W G 11 I _' ,� t►' 'G n4lis 104.19 5 11 XV N V Y Azolts 6 n V, s60 ►1 g t1 ^. �- 3gs 5- __ "; ADDITIONALCOM(VIENjS - RELINQUISHEDBY/AFFILIgT10N DATE TIME CQEPTEDaY/AFFILIATION'; DATE TIME [ SAMPLE CONDITIONS ' ft •'�35� �� o r .� SAINPLER-NAMEXIND�I'GNATUR� _ U o o'LE ORIGINAL E 1. �� o g PRINTNatneofSAMPLER: SIGNATURE of SAMPLER: DATE Signed ci(MM/DD-1- J' a^�a yea a- d Iju ,y races not au aay payment terms ana agreeing to late charges of 1.5% per month for any invoices not paid w�i 1m 30 days. ,j F-ALL-Q-020rev.07,15-May-2007 Document. NAme::$ariiple' Condition .Up.on : Docurrient Revised: June 4, 2013 :. aceAnal}j/��rcal Recer t SCUR p pa e 1 of 2 :Document No.: . ,... ': .: F=ASV=CS=003=rev:11 :.' : "` .::: .. . Issuing Authorities::. Pace Asheville Quality Office •. .w,ww.Pta.Celobs.Com ^ CCie'nt-'Nam. Where Received: Huntersville AsFievllle• �.:Ederi.: .:.:: Raleigh : . ' Courier (Circle): fed Ex • UPS USPS . Clien Commercial Pace Other Custody Seal on Cooler/Boz Present: , ; yes no Seals intact: :yes; E, no .. Packing Material:. Bubble Wrap Bubble Bags None Other " Circle Thermometer Used: IR.Gun#3-130265963 Type of Ice:. We Blue . None Samples on ice, cooling process has begun . •.. lFrGU1n = 80344 Temp Correcfion Factor: Add / Gib C Corrected Cooler -Temp.: C. Tem" .should be above freezin to 6°C P 9 Biological Tissue is. Frozen:' Yes No NIA Comments: . Date and Initials of Aerso mining contents: li 3 Chain of Custody Present: Yes ONo . ❑NIA 1. .Chain of Custody.Filled'Qut: Yes ❑No ONIA 2. Chain of -Custody Relinquished', • Yes. -❑No ON/A. 3_ . Sampler -Name & Sigriature on COC: Yes -.C1No ❑NIA 4. Samples Arrived within Hold Time:. Yes --.❑No ❑N/A 5_ Short. Hold TirrteAnalysis.(<72hr):• P(Yes ❑No ❑NIA 6. jvr Rush.Turn Around Time Requested: -❑Yes No DNA- 7. Sufficient Volume:. PYei ❑No ❑NiA 8. Correct Containers.Used: -Pace Containers Used: Yes E�No Yes ' ❑No ON/A ❑N/A 9. ' Containers Intact: PYes ❑No ❑N{A .10. Filtered volume received for Dissolved tests ❑Yes ❑No PTN/A 11-. Sample Labels match COC: Aes' ❑No ❑N/A -Includes. date/time/ID/Analysis . Matrix: L �' 12. All containers needing preservation have been checked. - All containers needing preservation aro found to be in compliance with EPA recommendation. exceptions: VO conform, Oc O&O, WI-DRO (water) r;(Yes❑No %Yes El No Yes ❑No ON/A. ❑NIA 13. Samples checked for dechlorination: Yes •❑No ❑N/A 14. Headspace in VOA Vials ( >6mm): ❑Yes X.N. ❑NIA 15, Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank -Lot # (if purchased): Yes ❑No Yes ❑No ❑N/A ❑N/A 16: Client Notification/ Resolution: Person Contacted: Date/Time: Comments/ Resolution: SCURF Review: Date: Thal 11 i . SRF Review: Date: i:;__;:..:. Note: Wheriever there is a discrepancy. affecting North Carolina i compliance samples, a copy of this form will'be sent to the North i I':Ilf If l Carolina DEHNR Certification Office (Le out of hold, incorrect preservative, out of temp, " p p, incorrect containers) Field•Data Required? Y / N Page 42 of 42 AI,`A1V1,NT� F 2 ' fROi�T`NTAL iNc: . . 231 HAYWOOD STREET, ASFIEVILLE, NC 28801 TEL.a2a.281.3350 FAC.828.281.3351 ' LVWW.ALTAdtONTEMVIPOri MENTAL.COM . Well Sampling Log PROJECT NAME: Clement Pappas PROJECT NUMBER: 2081 SAMPLING PERSONNEL: E. Yurkovich DATE: Jd � �63 WEATHE :yMMI SAMPLE TIME: 609 WELL NUMBER: aw- ag WELL DIAMETER: ep" TYPE OF CASING:' MEASURING POINT: FLUSH MOUNT STICK-UP COMMENTS: ® r w rr WELL DEPTH IN FEET (WD): ¢� WATER LEVEL IN FEET (WL): • �� LENGTH OF WATER COLUMN: (WD) - (WL) = (LWC) ONE CASING VOLUME: �o �� (LWC) x (WCV) THREE CASING VOLUMES: ACTUAL VOLUME PURGED: FEET GALLONS GALLONS GALLONS WELL CASING VOLUMES (WCV) 1" = 0.041 Gal/Ft 2" = 0.17 Gal/Ft T = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.8 Gal/Ft PURGE METHOD: AIL - ISP BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: IS BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: READING TIME GALLONS PURGED TEMP (IC) SPECIFIC COND. (PS/cm) DISSOLVED OXYGEN (mg/L) pH (S.U.) -report to 0.1 S.U. OXIDATION REDUCTION POTENTIAL (TV) TURBIDITY (NTU) COMMENTS w 1J51 'ri' Q-86. 9,q I. -Is 6.35 ® .� 2 .3 4 5 6 7 8 9 10 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 500 mL PLASTIC 1 TDS, Chloride, Sulfate 250 mL PLASTIC 1 Febal Coliform 125 mL PLASTIC 2. Ammonia, Nitrate 40 mL GLASS 7 VOCs 6200B, TOC 1 L GLASS OTHER PROTECTIVE CASING: EA.- PAD:ok LOCK: ot_ VEGET TION: ACCESS: CM Sampling Personnel Signature: Date: 1i 12 Notes: °C=degrees Celsius pS/cm = micro-Siemen per centimeter mg/L = milligrams per liter S.U. = Standard Units my = millivolt NTU = nephelometric turbidity units Samples are analyzed immediately upon collection. P:\Templates\GW Drilling Forms\Well Sampling Log.xis Page 1 of 1 E N GI N E'E RI N G'' 8c H YD'R O'GEO`CD GY 231 HAYWOOD STREET. ASHEVILLE, INC 28801 TEL.828.281.3350. FAC.828.281.3351 W W W.ALTAMONTEMV I RONMENTAL.COM Well Sampling Log PROJECT NAME:_Clement Pappas PROJECT NUMBER: 2081 SAMPLING PERSONNEL: E. Yurkovich DATE: Oiry WEATHER: 'Ze SAMPLE TIME: 8 WELL NUMBER: WELL DIAMETER: °' . TYPE OF CASING: �, MEASURING POINT: A®r• FLUSH MOUNT STICK-UP COMMENTS: WELL DEPTH IN FEET (WD): WATER LEVEL IN FEET (WL): LENGTH OF WATER COLUMN: FEET (WD) _ (WL) = (LWC) ONE CASING VOLUME: �, f�°� GALLONS (LWC) x(WCV) THREE CASING VOLUMES: GALLONS ACTUAL VOLUME PURGED: GALLONS WELL CASING VOLUMES (WCV) 1" = 0.041 Gal F 2" = 0.17 Gal/Ft 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" =1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.8 Gal/Ft PURGE METHOD: AILER-DIS AIL"ER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: CBAILER-DISP. BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: READING TIME GALLONS PURGED TEMP (°C) SPECIFIC COND. (PS/cm) DISSOLVED OXYGEN (mg/L).. pH (S.U.) J. reportto 0.1 S.U. OXIDATION REDUCTION POTENTIAL (mV) TURBIDITY (NTU) COMMENTS �M 2 Oill 1-76 15-36 4--g-LINg L -53-12 1 �,� 11-.31 9GP 6-SaL 3•0 1 4 1610 13.60 5 6 7 < 8 9 10 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS . 500 mL PLASTIC 1 TDS, Chloride, Sulfate 250 mL PLASTIC 1 Fecal Coliform 125 mL PLASTIC 2• Ammonia, Nitrate 40 mL GLASS 7 VOCs 6200B, TOC 1 L GLASS OTHER PROTECTIVE CASING: . PAD: e& LOCK:Dr- VEGETATIO : _ ACCESS: Sampling Personnel Signature: Date: 11 Notes: °C = degrees Celsius uS/cm = micro-Siemen per centimeter mg/L =-milligrams per liter S.U. = Standard Units mv= millivolt NTU = nephelometric turbidity units Samples are analyzed immediately upon collection. P:\Templates\GW Drilling Forms\Well Sampling Log.xls Page 1 of 1 E,_NGrrNE'ERING­& HYDROGEt' .OL'OGY.',' 231 HAYWOOD STREET, ASHEVILLE, NC 28801 TEL.828.281.3350 FAC.828.261.3351 W W W.ALTAMONTENV I RONMENTAL.COPl Well Sampling Log PROJECT NAME: Clement Pappas PROJECT NUMBER: 2081 SAMPLING PERSONNEL: E. Yurkovich DATE: u � a WEATHER: '35o SAMPLETIME: WELL NUMBER: r1/I- 1 WELL DIAMETER:' TYPE OF CASING: MEASURING POINT- I FLUSH MOUNT STICK-UP COMMENTS: WELL DEPTH IN FEET (WD): 1&(90 WATER LEVEL IN FEET (WL): 9,SS LENGTH OF WATER COLUMN : FEET (WD) _ (WL) = (LWC) ONE CASING VOLUME: I. GALLONS (LWC) x (WCV) ' J THREE CASING VOLUMES: �•�� GALLONS ACTUAL VOLUME PURGED GALLONS WELL CASING VOLUMES (WCV) 1" = 0.041 Gal/Ft 2" = 0.17 Gal/Ft 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft ' 6" =1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.8 Gal/Ft PURGE METHOD: AIL BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: AILER-DIS BAILER-TEFL•ON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: READING TIME GALLONS PURGED TEMP (°C) SPECIFIC COND. (PS/cm) DISSOLVED OXYGEN (mg/L) pH (S.U.) report to 0.1 S.U. OXIDATION REDUCTION POTENTIAL (TV) TURBIDITY (NTU) COMMENTS - 1 iq lw4a ?as 6653 134? 2 1119 1.79 3 aS '3.5 .� 51 ASS 6-all 4 Is.-Io Pon S, q aP. P.3,7 5 6 7 t 8 9 10 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS . 500 mL PLASTIC 1 TDS, Chloride,,Sulfate 250 mL PLASTIC 1 Fecal Coliform 125 mL PLASTIC 2• Ammonia, Nitrate 40 mL GLASS 7 VOCs 6200B, TOC 1 L GLASS OTHER PROTECTIVE CASING: PAD: LOCK: VEGETATION: ok ACCESS: C � Sampling Personnel Signature: Date: Notes: °C= degrees Celsius U pS/cm = microSiemen per centimeter mg/L = milligrams per liter S.U. = Standard Units mV = millivolt NTU = nephelometric turbidity units Samples are analyzed immediately upon collection. P:\Templates\GW Drilling FormslWell Sampling Log.xls Page 1 of 1 �_E NG I N E,ER_I N_G. & H'.YDRO6-EbC'66Y 231 HAYWOOD STREET. ASHENILLE, NC 23801 TEL.828.281.3350 FAC.828.281.3351 . tNWW.ALTAMONTENVI RON MEMTAL.COM Well Sampling Log PROJECT NAME: Clement Pappas PROJECT NUMBER: 2081 SAMPLING PERSONNEL: E.Yurkovich DATE: I q90 I is WEATHER: SMLAV, 35®F SAMPLETIME: 1046 WELL NUMBER: WELL DIAMETER: `' TYPE OF CASING: �. �, MEASURING POINT: FLUSH MOUNT SICK -UP COMMENTS: WELL DEPTH IN FEET (WD): WATER LEVEL IN FEET I(WL)- LENGTH OF WATER COLUMN: 15, J FEET (WD) _ (WL) _ (LWC) ONE CASING VOLUME: ®-�� GALLONS (LWC) x (WCV) THREE CASING VOLUMES: V-85 GALLONS ACTUAL VOLUME PURGED: Soo GALLONS WELL CASING VOLUMES (WCV) 1" = 0.041 Gal/F " = 0.17 Gal/Ft 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" =1.5 GaVFt 8" = 2.6 Gal/Ft 12" = 5.8 GaVFt PURGE METHOD: AILER-DISP. AILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: READING TIME GALLONS PURGED TEMP (°C) SPECIFIC COND. (PS/cm) DISSOLVED OXYGEN (mg/L) pH (S.U.) report to. 0.1 S.U. OXIDATION REDUCTION POTENTIAL (mV) TURBIDITY (NTU) COMMENTS 1 1 13.39 88 5do 617,.3Q 2�- 3 LP .O�1�. 0 959® • UP G-01 4 S.® a.' -SO 96.g ar'.a1 5 6 7 8 9 10 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS - 500 mL PLASTIC 1 TDS, Chloride, Sulfate 250 mL PLASTIC 1 Fecal Coliform 125 mL PLASTIC 2• Ammonia, Nitrate 40 mL GLASS 7 VOCs 6200B, TOO 1 L GLASS OTHER PROTECTIVE CASING:—& PAD: LOCK: ®/ VEGET 6K ACCESS: GWI— Sampling Personnel Signature: Date: Notes: °C = degrees Celsius uS/cm = microSiemen per centimeter mg/L= milligrams per liter S.U. = Standard Units mV = millivolt NTU = nephelometric turbidity units Samples are analyzed immediately upon collection. . P:1TemplateslGW Drilling FormslWell Sampling Log.xls Page 1 of 1 E N6INE_ ERIN'd H.YD ROGE&LQGY 231 HAYWOOD STREET. ASHEVILLE, NC 28801 . TEL.828.281.3350 FAC.e28.281.3351 VZW W.ALTAMONTENV I RONMENTAL.COM Well Sampling Log PROJECT NAME: Clement Pappas PROJECT NUMBER: 2081 SAMPLING PERSONNEL: E. Yurkovich DATE: i1 WEATHER: 850F SAMPLE TIME: 1222 WELL NUMBER: MA f— WELL DIAMETER:°' TYPE OF CASING: MEASURING POINT: FLUSH MOUNT STICK-UP COMMENTS: WELL DEPTH IN FEET (WD): 17.80. WATER LEVEL IN FEET (WL): LENGTH OF WATER COLUMN: ", Q8 FEET (WD) _ (WL) _ (LWC) ONE CASING VOLUME: GALLONS (LWC) x (WCV) THREE CASING VOLUMES: `j �� GALLONS ACTUAL VOLUME PURGED: GALLONS WELL CASING VOLUMES (WCV) 1" = 0.041 Gal/F " = 0.17 Gal/Ft 3" = 0.38 GaVFt 4" = 0.66 GaVFt 6" = 1.5 GaVFt 8" = 2_y6'Gal/Ft 12" = 5.8 Gal/Ft PURGE METHOD: AAILER- SP. BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS- OTHER: SAMPLE METHOD: - SP BAILER-TEFLON. DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER:. ' READING TIME GALLONS PURGED TEMP (°C) SPECIFIC COND. (PS/cm) DISSOLVED OXYGEN (mg/L) pH (S.U.) report to 0.1 S.U. OXIDATION REDUCTION POTENTIAL (mV) TURBIDITY (NTU) COMMENTS 1I 154e In ,d 118G 3 3 jp63 0.5 2n 6c53 9 4 Q �•�� ��3 �� J �5�. (P9 D 6 8 . 9 10 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 500. mL PLASTIC 1 TDS, Chloride, Sulfate 250 mL PLASTIC 1 Fecal Coliform A-25 mL PLASTIC 2• Ammonia, Nitrate 40 mL GLASS 7 VOCs 6200B, TOC 1 L GLASS OTHER PROTECTIVE CASING: PAD:LOCK:or-rVEGET TION: bK ACCESS: G Sampling Personnel Signature: Date: Notes: °C= degrees Celsius pS/cm = micro-Siemen per centimeter mg/L = milligrams per liter S.U. = Standard Units mV = millivolt NTU = nephelometric turbidity units Samples are analyzed immediately upon collection. P:\Templates\GW Drilling Forms\Well Sampling Log.xls Page 1 of 1 " AMO TT- `b ` RO "I1! Er1 OM C 231 HAYWOOD STREET, ASHEVILLE, NC 28601 TEL.828.281.3350 FAC.826.261.3351 W WW.ALTA MONTE NV I RON MENTAL.COM Well Sampling Log PROJECT NAME: Clement Pappas PROJECT NUMBER:2081 SAMPLING PERSONNEL: E. Yurkovich DATE: ilea 113 WEATHER:��' SAMPLE TIME: WELL NUMBER: WELL DIAMETER:°' TYPE OF CASING: MEASURING POINT: FLUSH MOUNT /` TS ICK U COMMENTS: WELL DEPTH IN FEET (WD): B� WATER LEVEL IN FEET (WL): LENGTH OF WATER COLUMN: — FEET (WD) _ (WL) = (LWC) ONE CASING VOLUME: dq•Cp� GALLONS (LWC) x (WCV) THREE CASING VOLUMES: GALLONS. ACTUAL VOLUME PURGED: GALLONS WELL CASING VOLUMES (WCV) 1" = 0.041 Gal/Ft 2" = 0.17 Gal/Ft. 3" = 0.38 Gal/Ft . 4" = 0.66 GaVFt 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.8 Gal/Ft PURGE METHOD: -D1S 'AILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: -DIS BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: READING TIME GALLONS PURGED TEMP CC) SPECIFIC COND. (PS/cm) DISSOLVED OXYGEN' (mg/L) pH (S.U.) report to 0.1 S.U. OXIDATION REDUCTION POTENTIAL (mV) TURBIDITY- (NTU) COMMENTS 2 _.. � �1q,13 P36 6aS .4 3 OS4 : S 16,10 cov coq r4,94 11. 4 5 6 8 9 _ 10 SAMPLING CONTAINER. NUMBER OF CONTAINERS REQUESTED ANALYSIS 500 ir1L PLASTIC 1 TDS, Chloride, Sulfate 250 mL PLASTIC 1 Fecal Coliform- 125 mL PLASTIC 2• Ammonia, Nitrate 40 mL GLASS 7 VOCs 6200B, TOC 1 L GLASS OTHER PROTECTIVE CASING:._ PAD:_ LOCK:_ VEG N: ACCESS: . Sampling Personnel Signature: Date: fit, 91 �J Notes: °C= degrees Celsius uS/cm = micro-Siemen per centimeter mg/L= milligrams per liter S.U. = Standard Units mV = millivolt NTU = nephelometric turbidity units Samples are analyzed immediately upon collection. P:\Templates\GW Drilling Forms\Well Sampling Log.xls Page 1 of 1 r ENGINEERING Sc_ H YDROGE'OL OGY 231 HAYWOOD STREET. ASHEVILLE. NC 28BOT TEL.828.281.335O FAC.828.281.3351 WWW.ALTAMONTCNYIRONMENTAL.GOM Equipment Documentation & Instrument Calibration Data Sheet Calibration Documentation Equipment Documentation Equipment or meters used to take measurements (e.g. Water level meters, survey equipment, etc.): Equipment Type Serial Number Brand Date of Use 150-ft Water Level 26154 Solinist 150-ft Water Level 22754 Solinist 150-ft Water Level 150 Testwell 150-ftDrawdown MP30-1527 QED Il 1� Other . Micro TPW Turbidity Meter Calibration Standards Exp Date Instrument Serial # Instrument Reading 0.02 NTU 10.0 NTU 1 1000 NTU 200601045 Initial: '� Initial:P Initi • ,�� Cal: Cal: 01 Cal: Time: Time: 77� Time: 7__V YSI 556 Multiparameter Meter Instrument Serial Number I121-101057 Instrument Readings Calibration Expiration Date Dissolved Oxygen Initial,Cal: mmHg (D Time: NA PH 7 S.U. report to 0.1 S.U. Initial: . % pHmV: Cal: �® pHmV: Time: 74a PH 4 S.U. report to 0.1 S. U. Initial: . cp pHmV: Cal- pHmV: Time* PH 10 S.U. report to 0.1S.U. Initial: V. pHmV: Cal: 0 pHmV: Time: QC* pH 7 S.U. report to 0.1 S.U. AM Time: Meas: Mid Day Time: Check: PM Time: Check: Spec. Cond. 1413//cm**/23 Initial: 1 V� Cal: N'� Time: QC* 84 ppSS/cm AM Meas: Mid Day Time: Check: PM Time: Check: ORP�4u mV (Initial: 6,.g.del Cal: � ITime:,:t5'� Comments: Signature: Date:' I krzn 112 Notes: �� f 1. Electronic equipment calibrated according to the manufacturer's operation manual. 2. Specific Conductivity should be calibrated accordingto values representative of historic range. 3.Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, ORP, QC checks. 4. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If readings are out of these ranges, meter needs to be recalibrated. 5. * Indicates that a QC check must be performed in the morning,, afternoon, and the end of the day, or every four hours. 6. ** Indicates to choose a Specific Conductivity buffer of 1413, 447, 84, or 23 mS which is closestto historical readings from the project location. P:\Templates\GW-Drilling Forms\Calibration Data Sheet YSI 556-Rev 2.xis Page 1 of 1 GW-59A OOMPLUNCE REPORT FORM Permit # WQ0004797 (Subnul one each monitoring period with GT --59 fornzs.) 1 Enter date monitoring results were due. (12131/2013 ) Will this monitoring report (GW-59 and GW-59A) YES NO be submitted after the established due date? 2 Was any required information missing on the GAY-59 report forms? YES NO iF the answer to question I or 2 is 'YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? If the ansiver is "I'es ", contact the Regional Office for guidance. 4 Are any monitored constituents equal to or above the established standards? YES NO If the answer to question 4 is "NO", skip to section B. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below: Total Organic Carbon (limit = 10 mg/L) - MW-8 = 21.Omg/L Fecal Coliform (limit = 1/100 mL) - MW-5 = 1.0/100 mL 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? If the answer to question 5 is "NO'; skip to section 8. if the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentrations) reported, and sample collection date for each occurrence (for the last two years). TOU OwaNc C,., on (I'mit - 10 mglL) . 1120113: MW-8 - 21.0 mgL 5116J2013: FM-2R = 13.5 m11. 31.8 mg L. AMJ-7R - 12.8 mg1. ­8 - 15.8 m41 I IM12: AMJ-2R = 31.1 mg1. MN4 = 10.6 wA, FRY.7R = 11.6 m , LIVJ-6 - 2=.6 JL Y17/12: MW-6=21.6_"L. hm-s- llimgL t VIV,I M'N-2R-18.6—,t Few Co ft 0r4 = 111M mL) - 1120113: I.MJ-5 = 1.C/100 mL 5'162013: ARV_ • 2.01100 L. 4M1-5 = 1.01100mL. LrN-6 • 12.11100 IL. W1.8 = 10.91100 m1 11/7112MLY= = 2.01100 I.L. A11-6 = 3.11100 mL 5/17/12' M 4 - 2.W 000 L. LTN-6 = 28.0/100mL, I.RY-8 - 12.0/100mL. 1111911: I.RV-5 - 1201100 mL, l 6 = 5.0/100 mL 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO', monitoring wells may be improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? O if the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO" contact the Regional Office within 90 days; an evaluation may be required to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation fines. and/or penalties. Total Organic Carbon (TOC), VOC, and SVOC analyses Were completed for all samples during the May 2007 groundwater sampling event. The TOC is not attributable to VOCs or SVOCs and is possibly naturally occurring. Fecal coliform was detected in the November 2013 MW-5 sample and contained concentrations similar to the May 2013 results. Fecal coliform was detected in MW-4, MW-5, MW-6 and MW-8 during the May 2013 sampling event. An investigation regarding the source and occurrence of the fecal coliforms exceedances was reported in October 2011 and is ongoing. 8 The person completing this portion (G W-59A) of the monitoring report should sign below and submit this form with G W-59 forms for required wells to the address provided at the top of the current G W-59 form. Thereby acknowledge that t e- bove�information was evaluated and'the information submitted m this report(C.omplian.c Report:GW�9AA}llstrue,an)omplete_to_thebestof,my:knowledge = C� Signature of Perrriittee (o Authorized Agent} Date GW-59A 12/8/2003 ROUNDWATER QUALITY MONITORING: OMPLIANCE REPORT FORM Please Print cioeHy or Type Name: Clement Pappas -- Name. (if different): Address: 125 Industrial Park endersonville ' (Street) NC 28792 County Henderson act Person: Mr. Blake Kehoe Location/Site Name: Irrigation Area Telephone#: (828)693-0711 No. of wells to be sampled: PERMIT Number: Expiration Date: 11/30/2015 Non -Discharge WQ0004797 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery 0 Spray Field ❑ Remediation: ❑ Rotary bistributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other. • If WELL TELL ID NUMBER (from Permit): MW-7R Date sample collected: 11/20/2013 FIELD ANALYSES: (ell Depth: 17.80 ft. relative to top of casing Well Diameter. 2 in. pH . 5.59 units Temp. 14.66 eC epth to Water Level: 11.69 ft. below measuring point Screened Interval: 5 ft.* to 15 ft.* Spec-Cond. 173µMhos easuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2062.86 ft. Odor None olume of water pumped/bailed before sampling: 3.25 gallons *screened Interval based an well construction record Appearance am les for metals were collected unfiltered: El YES ❑ NO and field acidified: DYES ❑ NO ABORATORY INFORMATION ate sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712 ARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/I Nitrite (NO2) as N mg/I Pb - Lead mg/l Coliform: MF Fecal < 1.0 /100ml Nitrate (NO3) as N 5.5 mg/I Zn - Zinc mg/I Coliform: MF Total /100ml Phosphorus: Total as P mgll (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total < 250 mg/l Al - Aluminum mg/I pH (when analyzed) units Ba - Barium mg/I TOC 9.4 mg/l Ca - Calcium mg/1 Chloride 14.0 mg/I Cd - Cadmium mg/I Arsenic mg/I Chromium: Total mg/I Grease and Oils mg/I Cu - Copper mg/l ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/I Fe - Iron mg/I (Specify test and method #,r4TTACH LAB REPORT.) Sulfate 3•5 mg/l Hg - Mercury mg/I Report Attached? V Yes.(1) ❑ No (0) Specific Conductance µMhos K - Potassium mg/I VOC method # 6200B Total Ammonia < 0.10 mg/I Mg - Magnesium mg/I method '# (Ammonia Nitrogen; NH,as N; Ammonia Nitrogen, Total) Mn - Manganese mg/I , method # TKN as N mg/I Ni - Nickel mg/I method # For Remediation GW-59 Rev, 112007 at of SUBMIT FORM ON YELLOW FAFtK ONLY OUNDWATER QUALITY MONITORING: MPLIANCE REPORT FORM Please Print Clearly or Type Name: Clement Pappas Name (If different): Address: 125 Industrial Park !ndersonville ' (Street) NC 28792 County Henderson (city) (Slate) (lip) act,Person: Mr. Blake Kehoe Telephone#: (828) 693-0711 Location/Site Name: Irrigation Area No. of wells to be sampled: 6 PERMIT Number: Expiration. Date: 11/3012015 Non -Discharge WQ0004797 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Z Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other. L ID NUMBER (from Permit): MW-8 Date sample collected: 11/20/2013 Depth: 13.90 ft. relative to top of casing Well Diameter: 2 in. i to Water Level: 10.34 ft. below measuring point Screened Interval: 3 ft.` to 13 ft.* ,wring Point is 3.00 ft. above land surface. Relative M.P, Elevation: 2060.80 ft ne of water pumped/bailed before sampling: 2.25 gallons `screened Interval based on well construction record ales for metals were collected unfiltered: ❑YES ❑ NO and field acidified: ❑ YES ❑ NO FIELD ANALYSES: WAS PH 6.26 units Temp. 14.07 eC DRY at Spec. Cond. 572 µMhos time of sampling, Odor None check Appearance here: ❑ sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. %METERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/I Nitrite (NO2) as N mg/I Pb - Lead Coliform: MF Fecal < 1.0 /100ml Nitrate (NO3) as N 1.3 m94 Zn - Zinc Coliform: MF Total 1100ml Phosphorus: Total as P mgA " Certification No. 37712 mg/I mg/l (Note: Use MPN method for highly turbid samples) Ortho hos hate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 342 mg/I PH (when analyzed) units r TOC 21.0 mg/l Chloride 15.4 mg/I Arsenic mg/I Grease and Oils mg/I Phenol mg/I Sulfate 24.3 mg/I Specific Conductance µMhos Total Ammonia < 0.10 mg/I (Ammonia Nitrogen; N1­13as N; Ammonia Nitrogen, Total) TKN as N mg/I p P Al - Aluminum mg/I Ba - Barium mg/I Ca - Calcium mg/I Cd - Cadmium mgfl Chromium: Total mg/I Cu - Copper mg/I 'ORGANICS: (by GC, GC/MS, HPLC) Fe - Iron mg/I (Specify test and method _#/ATTACH LAB REPORT.) Hg - Mercury mg/l Report Attached? IJ Yes (1) ❑ No (0) K - Potassium mg/I VOC , method # 6200B Mg - Magnesium mg/I method # Mn - Manganese mg/I , method # Ni -Nickel mg/I , method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%. Permittee (or Authorized Agent) Name and Title - Please print or type Signature of GW-59 Rev.1/2007 SUBMIT FOKM UN rtl-lUw rHrcrc UNL-1 NDWATER QUALITY MONITORING: LIANCE REPORT FORM Name: Clement Pappas Name (if different): Address: 125 Industrial Park ndersonville ' (StrecQ NC 28792 County Henderson act Person: Mr. Blake Kehoe Telephone#: (828) 693-0711 LocationlSite Name: Irrigation Area No. of wells to be sampled: 6 PERMIT Number: Expiration Date: 11/30/2015 Non -Discharge WQ0004797 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery El Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other. L ID NUMBER (from Permit): MW-2R Date sample collected: 11/2012013 Depth: 14.90 ft. relative to top of casing Well Diameter: 2 in. i to Water Level: 7.92 ft. below measuring point Screened Interval: 6 ft.* to 11 ft.* wring Point is 3.77 ft. above land surface Relative M.P. Elevation: 2062.36 ft. ne of water pumped/bailed before sampling: 1.25 gallons *scroened interval is relative to land surface Iles for metals were collected unfiltered: DYES El NO and field acidified: ❑ YES ❑ NO If WE FIELD ANALYSES: VVAS pH 5.49 units Temp. 13.44 eC DRY at - Spec. µMhos Spec. Cond. time of sampling, Odor None check Appearance here: ❑ sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services, Inc. ;AMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/l Nitrite (NO.) as N mg/I Pb - Lead Coliform: MF Fecal < 1.0 /100ml Nitrate (NO3) as N 0.97 mg/l Zn - Zinc Coliform: MF Total /100ml Phosphorus: Total as P mg/I Certification No. 37712 mg/I mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mg/l Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 66.0 mg/I All - Aluminum mg/l pH (when analyzed) units Ba - Barium mg/I TOC 6.1 mg/I Ca - Calcium ? = • mg/I Chloride 7.6' mg/l Cd - Cadmium mg/I Arsenic mg/I Chromium: Total mg/I ,_ Grease and Oils mg/I Cu - Copper, _„ I ORGANICS: (by GC, GC1MS, HPLC) Phenol mg/I Fe - Iron mg/I (Specify test and method TTACH LAB'REPORT.) Sulfate 9.3 mg/I Hg - Mercury _ ` mgJ/I.n' Report Attached? M#.,AYes (1) ❑ No (0) Specific Conductance µMhos K - Potassium mg/I VOC method # 6200B Total Ammonia < 0.10 mg/I Mg - Magnesium mg/J method # (Ammonia Nitrogen; N1­13as N; Ammonia Nitrogen, metal) Mn - Manganese mg/I , method # TKN as N mg/l Ni - Nickel mg/l method # For Remediation Svstems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.112007 SU13MI I i-UKM UN YF-I I LHV YArt:K UNLY UNDWATER QUALITY MONITORING: , PLIANCE REPORT FORM FACILITY INFORMATION_ Pleaso Pnnt cvcany or Typo Facility Name: Clement Pappas Permit Name (if different): Facility. Address: 125 Industrial Park Hendersonville " ls`r°°q NC 28792 County Henderson (City) (Slat.) (Zip) Contact Person: Mr. -Blake Kehoe Telephone#: (828) 693-0711 Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 PERMIT Number: Expiration Date: 11/30/2015 Non -Discharge WQ0004797 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon • ❑ Remediation: Infiltration Gallery 0 Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other. .L ID NUMBER (from Permit): MW-4 Date sample collected: 11/20/2013 FIELD ANALYSES: Depth: 18.60 ft. relative to top of casing Well Diameter: 2 in. pH 5.92 units Temp. 15.50 °C h to Water Level: 8.87 ft. below measuring point Screened Interval: 8 ft.* to 16.1 ft.* Spec. Cond. 250 µMhos suring Point is 2.43 ft. above land surface Relative M.P. Elevation: 2063.77 ft. Odor None me of water pumped/bailed before sampling: 5.0 gallons . *screened Interval is relative to land surface Appearance ples for metals were collected unfiltered: ❑YES ❑ NO and field acidified: ❑ YES ''ONO ORATORY INFORMATION sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712, _ AMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/I Nitrite (NO2) as N mg/I Pb - Lead mg/l Coliform: MF Fecal < 1.0 1100ml Nitrate (NO3) as N 0.026 mg/I Zn - Zinc mgll Coliform: MF Total /100m1 Phosphorus: Total as P mg/I (Note; Use MPN method for highly turbid samples) Orthophosphate mg/l Other (Specify,Compounds and Concentration, Units): Dissolved Solids: Total 157 mg/I Al - Aluminum mg/I pH (when analyzed) units Ba - Barium mg/I If WELL WAS DRY at time of sampling, check here: ❑ TOC 8.0 mg/I Ca - Calcium mg/I Chloride 14.7 mg/I Cd - Cadmium mg/l Arsenic mg/I Chromium: Total mg/l Grease and Oils mg/l Cu - Copper mgll ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/I Fe - Iron mg/I (Specify test and method # ATTACH LAB REPORT.) Sulfate 22.1 mg/I Hg - Mercury mg/l Report Attached? Yes (1) ❑ No (0) Specific Conductance I.lMhos K - Potassium mg/I VOC method # 6200B Total Ammonia < 0.10 m9/1 Mg - Magnesium mg/I method # (Ammonia Nitrogen; NHaas N; Ammonia Nitrogen, Total) Mn - Manganese mg/I ,method # TKN as N mg/l Ni - Nickel mg/l method # For Remediation Systems Only (Attach Lab Reports): llteo (or Authorized Agent) Name and Title - Please print or type GW-59 Rev.1/2007 Influent Total VOCs: • • -mg/L Effluent Total I complete, and that the laboratory analytical data was produced using approved methods of analysis by a ig the possibility of fines ll�,�`L n violaii Signature of 13�6ittp`6'forAutFoited Agent) (Dat6) CI IRMIT P:nQhA r1N VPI I r11A/ PAPFR r1Nl Y ROUNDWATER QUALITY MONITORING: OMPLIANCE REPORT FORM .... ... .... Pleaso Print Clcarly or acility Name: Clement Pappas armit Name (if different): acility Address: 125 Industrial Park Hendersonville ' (street) NC 28792 County Henderson (City) (Slate) (ZIP) ont'act Person: Mr. Blake Kehoe Telephone#: (828) 693-0711 fell Location/Site Name: Irrigation Area No. of wells to be sampled: 6 PERMIT Number: Expiration Date: 11/30/2015 Non -Discharge WQ0004797 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon 0 Remediation: Infiltration Gallery 0 Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge _ ❑ Water Source Heat Pump ❑ Other. If WELL L ID NUMBER (from Permit): MW-5 Date sample collected: 1112012013 Depth: 18.60 ft. relative to top of casing Well Diameter: 2 in. h to Water Level: 9.33 ft. below measuring point Screened Interval: 9 ft.* to 19 ft.* curing Point is 3.00 ft. above land surface Relative M.P. Elevation: 2085.60 ft. Tie of water pumped/balled.before sampling: 4.75 gallons *screened interval based on well construction record oles for metals were collected unfiltered: ❑YES ❑ NO and field acidified: ❑ YES ❑ NO FIELD ANALYSES: pH 5.44 units Spec. Cond. Odor None Appearance Temp. 13.70 eC DRY at 229 µMhos time of sampling, ate sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712 ARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/I Nitrite (NO2) as N mg/I Pb - Lead mg/l Coliform: MF Fecal 1.0 /100ml Nitrate (NOa) as N 0.19 mg/I Zn -Zinc mg/I Coliform: MF Total /100ml Phosphorus: Total as P mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 162 mg/I Al - Aluminum mg/I pH (when analyzed) units Ba - Barium mg/I TOC 4.2 mg/I Ca - Calcium mg/I Chloride 64.6 mg/I Cd - Cadmium mg/I Arsenic mg/I Chromium: Total mg/I Grease and Oils mg/I Cu - Copper mg/I ORGANICS. (by GC, GC/MS, HPLC) Phenol mg/l Fe - Iron mg/I (Specify test and method # ATTACH LAB REPORT.) Sulfate < 2.0 mg/I Hg - Mercury mg/I Report Attached? Wr Yes (1) ❑ No (0) Specific Conductance µMhos K- Potassium mg/I VOC method # 6200B Total Ammonia < 0.10 mg/I Mg - Magnesium mg/I method # (Ammonia Nitrogen; NHaas N; Ammonia Nitrogen, Total) Mn -Manganese mg/1 ,method # , TKN as N mg/I Ni - Nickel mg/I method It For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.1/2007 of lonnlm enoee ntJ VRl I rMAI PAPER M1 V NDWATER QUALITY MONITORING: LIANCE REPORT FORM TY INFORMATION_ Please Print clearly or Type Name: Clement Pappas Name (if different): Address: 125 Industrial Park ndersonville " (street) NC 28792. County Henderson ntact'Person: Mr. Blake Kehoe Telephone#: (828) 693-0711 ;II Locatian/Site Name: Irrigation Area No. of wells to be sampled: 6 PERMIT Number: Expiration Date: 11/30/2015 Non -Discharge WQ0004797 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: infiltration Gallery El Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other. If WELL L ID NUMBER (from Permit): MW-6 Date sample collected: 11/20/2013 FIELD ANALYSES: Depth: 11.54 ft. relative to top of casing Well Diameter: 2 in. pH 5.31 units Temp. 12.75 °C h to Water Level: 5.96 ft. below measuring point Screened Interval: 5 ft.* to 10 ft.* Spec. Cand. 79 µMhos• wring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2061.17 ft. Odor None Tie of water pumped/bailed before sampling: 3.0 gallons *screened interval based on well construction record Appearance ales for metals were collected unfiltered: DYES ❑ NO and field acidified: ❑ YES ' ❑ NO sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712 AMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/l Nitrite (NO..) as N mg/I Pb - Lead mg/I Coliform: MF Fecal < 1.0/100ml Nitrate (NO3) as N < 0.02 mg/I Zn - Zinc mg/I Coliform: MF Total /100ml Phosphorus: Total as P mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 56.0 mg/I AI - Aluminum mg/I pH (when analyzed) units Ba - Barium mg/I TOC 4.4 mg/I Ca - Calcium mg/I Chloride 7.3 mg/I Cd - Cadmium mg/I Arsenic mg/I Chromium: Total mg/I Grease and Oils mg/I Cu - Copper mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/I Fe - Iron mg/I (Specify test and method # ATTACH LAB REPORT.) Sulfate 8.6 mg/I Hg - Mercury mg/I Report Attached? Z Yes (1) ❑ No (0) Specific Conductance µMhos K - Potassium mg/I VOC method # 6200B Total Ammonia < 0.10 mg/I - Mg - Magnesium mg/I method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese mg/I method # TKN as N mg/I Ni - Nickel mg/I method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: ittee (or Authorized Agent) Name and Title - Please print or type Slgnatuf6 of Permftlee (or -Authorized Agent) GW-59 Rev.1/2007 • using approved methods of analysis by a 3. 1000 D. at of a SUM-01T FORM ON YELI O�rkl PAPER ONLY NDWATER QUALITY MONITORING: LIANCE REPORT FORM 'V IA11=fl0ARflT1nA1 r;pace F'rrrt L?early nr ,Type lity Name: Clamant Pappas •fit Name (if different): lity Address: 125 Industrial Park t` `' NC 92 Hendersonville " 28i County Henderson Intact Person: Mr. Blake Kehoe ell Location/Site Name. Irrigation Area Teiephcns•# (828) 693-0711 No. of wells to be sampled: 6 ((,pp'1 'r`" M-1, PERMIT Number: Expiration. Date: 11130/2015 Norr-Discharge WQ0004797 UIC NPCIES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery K Spray Feld ❑ Remediation: r� Rotary Distributor Land Application of Sludge ❑ tAlater Source Heat Pump ❑ Other. ELL ID NUMBER (from Permit): MVV-2R Date sempte cn;lected: 5!'16/2013 ell Depth: 14 9C ft. relative to top of casing Well Diameter: 2 ir,. �pth. to Water Level: (3.86 fl. below measuring point Screened Interva!: 6 ft ' to 11 fL easuring Point is 3.77 ft. above land st.irface Relative VA.P. Elevation: 2062.36 ft. )lume of water pumped'bailed before sampling: 1.50 gallons cra.ncc interva �!, n;,atve tr:and U,�C amoles for metals viere collected unfiltered: ❑1 YES D. NJ and field acidified: ❑ YES ❑ NO FIELD ANALYSES. PH r 53 1 units Spec. Cond. Odor None Anpearance If WELL WAS Tep. 13.53 °C DRY at m 13;1 p.,Mhos time of to sample analyzed: varies: see analytical report Laboratory Name: Pace Analytical Services. Inc. Certification No. 37712 RAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COL} moll N trite (NO) as N mgll Pb - Lead mg/l Coliform: MF Fecal 1.0 /100m! Nitrate (NO3) as N 0.02-ng 1 Zn-Zinc mall Coliform MF Total I I00m1 Phcspnarus: Tate: as .a mgll !Nffirt' lJ5c w"PP! Y^EtfkOti `4r ;Vignly !ur6i; S�rnpias} t Orthophospha.e mail Othern if. P 1- r' : (Specify Compounds and Conce cont Units): Dissolved Solids' Total 64.0 rngll Al - Aluminum mgii pH (when analyzed) units Ba - Barium mg/1 TOG 13.51?'ioli Ca - Calcium mgil Chloride 1 2 mg!I Cd - Cadmiorri mall Arsenic_ mgfl Chromium: Total mg•i Grease anti Oils mg/l Cu - Copper mg -'I ORGANICS: (by GC.. GCAIS. HPLC) Phenol mg/i Fe - Iron ma/l (Specify test and method #. ATTACH LAB REPORT.) Sulfate 13.2 mall Ng - Mercury ma'1 Report attached? ❑ Yes (1) ❑ No (0) Specific Conductance: +.;fAho" K -Potassium mg/l method # � Tota! Ammonia < 0 '10 rng/1 Ps+ig - Magnesium mail method # tA.mm -no Nitrogen. NH;.3:: N. r,mnronia'�i�tmge�i. -,�t,!; Mn - Manganese IT19/1 , method # TKN as N mg/l Ni - Nickel mg!i method f# For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg1L VOC Removal% GW-59 Rev. ?f2C107 SUBMITFORrVi ON YELLQYJ, PAPER ONLY ROUNDWATER QUALITY MONITOMINIG: OMPLIANCE REPORT FORM FACILITY INFOfdfldlATi R mpEise PERMIT Number: Expiration Date; 11130,12015 Facility Name cierrent Pappas Non -Discharge VVQOG04797 — UIC Permit Name (lf different): NPDES Other Facility Address: 125Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville71 Lagoon NC 28792 County Henderson Remediatior: infiltration Gallery Spra,,-; Field C Pernediavon: Contact Person: Mr. Blake Kehou Telephone#: 693-0711 FJ Rotary Distributor Land Application of Sludgc !{dell Lacaf: Icn1�)ite {Fame: Irrication Area No of -wellq to be sampled. 6 Water Source Hnat Pump Other, ,' ELL ID NUMBER (from Permit): Mtn!-4 Date sample collected: :1`1!16f2013 ?11 Depth: 18 60 ft. relative to top Of C1,3Sing Well Diameter: 2 in. pth to IA! ester Leval 7_93 ft. belm,; F)eCiSLJFJMQ. point Screened In1eval. 8 ft,* to __,C.1 ft.' asuring Point is 2 43 ft. above land surface Relative f,�,.P. Elevation. 2063-77 ft, Urno of water pumped!bailed before sampling: 5.5 callom, "=- ,,-rid mlvT•iaj i�a Ili ZWItCO )ate sample analyzed- varies, see arai,�Iicai report Laboratory Name. Pace An2lytica! Services, Inc. 3ARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. FIELD ANALYSES: p"i 53P units Sp ec. Cond. Odor None Appearance COD m 9 1: Nitrite (NO,� as N M. O,i l Pb - Lead Coliform: MF Feral 2.0 1100ml Nitrate NW as N 0.28 rng.'l Zn - Zinc Temp. '. 3. 15- 0 01 178 JLMhQS Certification No. 37712 MM1 Coliform: NIP Total "100ml Phosphorus: Total as P Nlo! a, QMF` , ,r tlln a j fc, hiply 0rt.hcpM07,Pn8ie mg/i Other (SpetiFy Compounds and Concentlation Units). Dissolved Solids: Total "OG rlg]# A! - Aluminum mgll pH (when analyzed) units Ba - Barium moll TOC 31 8 M.911 Ca - Calcium ma;l Chlcridc 10 2 rrlgIi Cd - caarnium _,mg�l Amenic mo/i Chrorrium. Total mg Griesse and Oils nigil Cu - Copper Moll ORGANICS: (by GC, GC/hIS, HFILG) Fc - Iron marl 1 (Specify test and method ATTACH LJkB REPORT.) Sulfate 19 1 mgq 14.g - Aiercvrj mg? i Report Attached+ L I Yes l` .1 o (0) Specific Conductance Il lhos K - POtISSILIM moll method 4 Total Ammcni-a < 7 r1911 ,My - Miagne-,lum, T I method it Um - Manganese mig I method # TKN as N moll . Ni -Nickel rng"I method # For Remediation Systems Only (Attach Lab Reports). influent Total VOCs: mg!L Effluent Total VOGs: mg/L VOC Removal% Parmtee for Aulhovz3d Aclent) Name zinif 716v - riense print or type S:Qn-AtLife Of Pffrnift'0 (0! Authorized Amin") krV Rev V2007 at of )ling, F-1 C;Ni 'i`.i �(itrd Pr0i)F-P:, GROUNDWATER QUAUTY IVIOMTORING COMPLIANCE REPORT FORM ;1 . �' or Facility NWT)e. Per rnit Name h` different',-. Fac-Ttv Address: 1 2.5 Industrial Pw', -P702 ^r Lir H tir 3 ,5 C� 21 -7 VVell Lacat9or1/Site Marne: irri'lat.ml ArEa Nl c. of if,,,elis to be samp!uu d ff ID NUMBER (from Pertyft): VI — - - ",��-5 i� V I - 1:�. V � (� I 1 1:1; ". n 1 C"! C": �:il- Depth, P C pth 10 "VIjaie.• Leve n-ic.1---inc asurino Fl*rt i°, [ko,,,e land 31iuni ;,-CS JiO ft.. t!�rprrebk"d �lr!:r� 7g-,Aluw�line ofv;aumdJri�G. r-noies fc,, metais unfiltereo N nr t f;eIlc scid:ried. YES NC, If r N—rw 'r� �, :1.l L PARAMETERS NOTE: Values :3hculd rcfloCt dlSsDlved azld Colloidal zOtl'-entrations. � I , , , , r ,, I617 MAIL SERVICF CENTER. nAL£, G�, NC1.27690-1W.:". Phone: PERMIT Number: Expiration Date. idrlr-Disc`: Sae V2Q30'47-7 Uic Other T o YPF OF PERI,.MTTED OPERA710N, BEING rVIOMTORED Heat P,.rrp CUD -Y: N,' Col;forrnIMF 1:--ecd 1 CCnl; D— J'..I 0.oL';o rr, C-7 t 41. , r , NIF -otal— 1 -1 "D I- -I! zz P rno, Cr` c orr o -; p h a `e Salias To'al mg"! PH when -;indyzed) Bu, - parlurn TOCI mr Phenv; Fe - Pon rn, Mprc-lr1 Total A�TIMCM13 1(t yl: lvil TKN as N FIELD ANALYSES. N Appear2nc, 1C. Nr,. 712 Pb -[-�t�ad Zn - Zinc m, 2, 1 ORGANICS: (by CC. (sped/ test and method Rmcl? e�rt Attached goal ',--&MS. HFL.C) 9.ATT ACGH LAE3 REPOPT.) 'Yes No W' -n cthadl rne i 1) c, J fi VVELL at For Remediation Systems Only (Attach Lau Reports): 7,-.11al VoCa. rncCL Efflue,it --, 0',2' VC)Cs: mg, L VOC Removal%— . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ArentNnrt-.- Tj*,je PiF a,era4nt a Pernutiev ,m .11tj —Q"�,PAP.ER CV,Y GROUNDWATER QUALITY MOKHTOMNG: COMPLIANCE REPORT FORM c7ACIII Iry r. n, Facjitv Name Ciement Pappas Permit Narne (.,' diffe-ent;: �a-dflty Address. 125 Industrial Park Hendersonville ^fr 28722 C. ou n H.erderson ?ci Person kP,. Slake Kell)oc T f- Location/Sile Narne. Irrigation Area Nrj. oF,,volls to rsar-,m!zed- jPERMIT NUMLle7: NiP D E S Yher 7YPE OF PER1101ITTED OPERATION BEING F00HITCREID Infiftra"or. Gallery P,)'ar, Piq-rip vn- L3,,id An flcn of Sludge P1,C3 -j WareSOI)r-Cl tjr,,aj Fl-jr- .p ;-j ELL ID NUMBER (from Pcrm' t): 7vl,`V - 9 Dite, coilectce, 516,'20" 3 'r I '11 De0h. 11. 54 f-_ -,c -cItj,,,c to top c` 2 I!'. 3Pth t,Vatcr 1-evej, 5.84 fl.. b,�,j,,` r"12' j )i"ll C) , 1.' - 10 - fz C231.irna Point 3.00 Ift- abavc� 1'�znd surrac., Elev�ntion. 2061, 17 ft. )lurne of urnter purnped"ba)-led b'efcre sarnr+nzi: 3.0 gallons Sc'em!iA rl!e, -;a' niscv on well tin Y rnole� for metals `.Pere collecte-i unfiltercd: V�=S N,,') ardl «,c!:l oc7di4:-�. - , ES N, 0 F!FLD ANALYSE:C: 5.34 ur,115 O for None! Apoea,arlce 1C Date som;Dic anaWca: vanes;F E aruvtCai rr-,q)crt Pacu An,.-ly'Lic:)l Scrv7ces, Inc. Cuiic3ticn No. '37712 NOTE: ValUr--!� shoUld reflect dissolved and C.-olloidal Concentrations. ,PARAMETERS GOD N.; t n , r-, ,,NU„) a s N 1: Pb - LE`ad mpll Coll*orni: I'AF Fecal 0C-i Kiratc (N.:)- as 1\1 0. 04 81 'riciol Zr, - Zinc rng.l r3ulilxrr, MF -, ot---) i u - i C., a S P mql Omer Z Dissoived So' ids' Total ma"I A] - F"Jurninjr-,-, pH (when analyzed) unit Ba - Dafiu,n. TOC .0 -I CC 4 Cb -1 3tai mq If WELL DRY )t to-e of :;am0tln, Grcasc nnid Cil, r1rVi Cu - Cnppur C ') R G A N I C S b GC; I S. 1-1 P L C,) Pheno" F tx - i rc,-i nlg!I {Specify test and rnethod #. ATTACHI LAD REPORT.) sultale 9-4 11 iqi: 7-1:7 P•.-lcrcury rn 01 ❑7 Report At' tachC67 Yes Specific. n I I] Total Arn-monip NO-19anc5e, rq",,. TKN as N mail M - Rickel me i --method 1, For Remediation Systems Only (Attach Lab Reports): IT­!.f!Llr2nf —1 Clr:;l VOCS: rnu, L EfflueTA 7 . ot2l VrjCs ma VOC Rernoval% P Prrr, file c, 'C r Az ith o. i zed A ent ri om e and T!Cn - P I e a s -1 0 vo e Sib M1 I FORV, OKI Y,LLQ.!i1.P/,PrF,0:NLY DEPARTMENT OF ENVIRONMENT NATURAL REBQURCE: ROUNDWATER QUALj7Y MONITORING: DMPLANCE REPORT FORM if_lt Y_ry 1K1T7f1%D1LqAT1nT11 ,ility Nnrnc Clemcmt Papp-az rmit N.arne !if differer,4'1 125Industrial Paris 28 7 S)2 tj n, snn Mt. Riake K _,hoo, Lcc-aficn,'Sitc Name: Irrigation Arcx: To ')e LL ID NUMBED (from Porm'1tl: tR I 17.W 1W MAIL SERVICE GENT EP, PALEIGH., NC.2,69 is . Phone �(91B) T3342.2 PERfV,JT Narnberl Exph ation, Date I 1;;30/2P! 5 1A!C00CA19_/ LHO NN PF P E OF PERIMITTED OPEPATION BEING MONITORED R n ,, d I a -:1 c,, n i 1 nfi r 1 a i e T-1, Lztr, AnPII_mric- oi' 1Amcr Sou,cc. Hrnt Piimp 'U! 10 VV- 0 P D! ti L I k .Isurinc, Point is A 3.00 n, above lnn!l _n't-ve Mi. P Elevnition: 2062.86 ft- JM@ Of Le'or .,. ri7�,. a! ha_ -.Er: we,; mmes f17 Mejaj,� �nler� C unfiltvri,d E S ENO _7S Nc� s:)-rn1n_ nnalgec:vance anaiyiicarercr.. LP b -!-a' -_ ry N Ll ­,IPace !.ical Scrv_Ac--- fro. AMETERS NIOTE; Values shmild rc-flcc3: dissolved and collridal t;omerntralicris. COD rrclri N,mu- (N1()-'? P-,; N rn7 Lead Col:c­n: ".27 Fecra! N�vate ("'Cj n,� 5 , ng 7n - Zi'( f WELL DFY al. U-1.1 of 76 Nc �771 12 !-gfl 'S',,-:f';L'M,_C.�i_,nS Z(M C',JM�-erjlr:it:on D;s_clvced 3olid-,'. Total 252 'r,­.Vt AA, - Alurnw-inn r7q,11 pH (vlhcn analyzed, _,jl,ts 5D - Barit.Irn 73C 12. 6 n ci.' 7.1 n d QRGAN1!G9 ' v C, (Specify test and method it. ATTACH LAD REPORT.) 28.3 rngll hg - fvle-cu,y ma i Report Attached? Yes 111) N'o (0, Cor r-1t. t�. on I otal Ammonia 6 KN as rrg:'; N; - Nhcke� -�4 OLI For Remediation Systems Only (Attach Lab Reports): T-,tud VOC>, -nia"L Effl.,cnt Tota! VDr-, mg!L VOC Removal X0 Pozqi;0ep. ALJth0'!ze-_,r Au rlt) NW1C and I it-.- PIPas i ,.L:T Vil" of 67IIit -,-cf a c k SUBMIT FC)Rrvi ON YELLOW PAPER ONLY EPARTMENT OF, ENVI�2pNMENT $NATURAL RESOURCES „y . � y , GROUNDWATER QUALITY MONITORING: IM'617 IVISION OF WATER 6UALITY INFORMATION:PROc{wS f6G KNIT COMPLIANCE REPORT FORM NlAIL SERVICE` CENTER; RALEIGH, NC 27699 1617;-Phone: pip) 733322i FACILITY INFO_>EhLAIION, P%awse Prat Crea ; or PERMIT Number: Expiration Date: 11 /30/2015 Facility Name: Clement Pappas Non -Discharge: IN00004797 1J1C Permit Name (if different): NPDES Other h Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville NC 28792 runtHenderson „c �' J Lagoon ❑ Remediarion: Infiltration Gallery ii L Il ER Sway Field ❑ Remediation: II Contact Person: Mr. Blake Kehoe Telepho,e#. (828) 693-0711 j Rotary Distributor Land Application of Sludge I Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 � � Water Source Heat pump ❑ Other � ff,, Penn•T dSAMPLING INFORMATION If WELI:A VVELL ID NUMBER (from Permit): MW-8 Date sample collected: 5,11612013 FIELD ANALYSES: WAS Well Depth: 13.90 ft. relative to top of rasing %/fell Diameter: 2 in. pH 6.33 units Temp. 13.46 'C DRY at Depth to Water Level: 8.58 ft. below measuring point Screened Interval: 3 ft.` to 13 T it..' Spec. Cord. 633 pAMhos time ofsampling, Measuring Point is 3.00 ft. above land surface Relative M-P. Elevatlon7 2060.80 ft. Odor None check Volume of water purriced'bailed before sampling: 2.75 gallons `screened interval based on well GOnStNC:iDn record Appearance here: Sam les for metals were collected unfiltered: YES C NC and field acidified. ! 1 YES r NO `— LAt3ORATOF�Y INFORMATION Date sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloldai concentrations. COD mail Nitrite (NCB,) as N mgl'. P; - Lead mg/l 6 Coliform: MF Fecal 10.9 110 0mi Nitrate (NO,-: i as N 6,8 mg•'I 7_n - Zinc mg/1 , j Coliform MFTotal 1100ml Phosnhorua: Total as F mail - 6S C Orthophosphate mg,l ! Ocher Specify �ompaunds arid CAneentratian Units}: b Dissolved Solids: Total 248 mall Al - Aiuminum mg/1 t' pH (when analyzed] units Ba - Barium mg/l ITOC 15.8 m-A Ca-;'airiurn mg;i Chloride 8.8 m g % i Cd - C:adn;ium mail 1 Arsenic mg/I Chromium: Total mg/' t Grease and Oils mg/I Cu - Copper mg /l (by `b} , Gr , GC/MS, HPLC) i Phenol mgli Fe - iron mg/l (Specify test and method #. ATTACH LAB REPORT.) Sulfate 13.4 mg;l Hq - Mercury mg;i Report Attached? Yes(!) ❑ No (0) Specific Conductance Mhos K - Potassium mg; I method # 87.60 Total Ammonia ¢ 0.10 mg/I Mg - (Jagnesium rrlg/I method # ,Amamnia Nitrorden; N'l-l3aE N; Ammonia Nitracer.,- Iv]n - Mariganese _ rna/i method # TKN as N mall Ni - Nickel mgil method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: ma/L Effluent Total VOCs: mg/L VOC Removal% GVt-59 Rev.112007