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WQ0004797_Monitoring (Report Revised)_20091121
5 S; CLEMENT-P,APP S 11-21-09 Division of Water Quality 1617 Mail Service Center Attn: Information Processing Unit Raleigh, NC 27699-1617 RE: Permit Number WQ0004797 GW-59 Reports C�L DEG 14 2Eu3 Attached please find 2 copies (each) of Amended Clement Pappas GW-59 Compliance Report Forms, for the month of May 2009. Thank You, Blake Kehoe cc: Dale Wolfe I DEC 0 7 2009 iformation Processing Unit pWQJBOG 125 Industrial Park Rd Hendersonville, NC 28792 828-693-0711 GW-59A COli'IPLIANCE REPORT FORM Permit # WQ0004797 (Submit one each monitoring period with GW-59 forms.) 1 Enter date monitoring results were due. (6/30/2009 ) Will this monitoring report (GW-59 and GW-69A) YES NO be submitted after the established due date? 2 Was any required information missing on the GW-59 report forms? YES NO IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? If the answer is "Yes", ", contact the Regional Office for guidance. 4 Are any monitored constituents equal to or above the established standards? YES NO • If the answer to question 4 is NO", skip to section B. If the answer to question 4 is "YES" list the affected wells individually with constituents) and concentration(s) exceeding standards in the space provided below: MW-2R: total organic carbon 14.4 mg/L MW-5: total organic carbon 16.1 mg/L, fecal coliform 4.0 per 100mL MW-6: fecal coliform 276 per 100mL MW-7: total organic carbon 23.4 mg/L MW-8: fecal coliform 240 per 100ml- 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? If the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence'(for the last two years). MW-2R: total organic carbon: 10.2 mg/L 5/27/08 MW-5: total organic carbon: 25.9 mg/L 11/18/08 MW-6: fecal coliform: 3.6 per 100 mL 11/13/07 MW-8: fecal coliform: 2.2 per 100 mL 11/18/08 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO if the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO". monitoring wells may be improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? • If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days; an evaluation may be required to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation fines, and/or penalties. Total Organic Carbon, VOC, and SVOC analyses were completed for all samples during the May 2007 groundwater sampling event. The TOC is not attributable to VOCs or SVOCs. Possibly natural occurring. Although not yet approved by the Division, the permittee intends to analyze the November 2009 groundwater samples according to an alternative fecal coliform method. If the November 2009 results are similar, further action will be taken. g The person completing this portion (G W-59A) of the monitoring report should sign below and submit this form with G W-59 forms for required wells to the address provided at the top of the current G W-59 form. �I hereby acknowledge fhatahe above mformatfon was evalua�edand the mformabon submitted m thfs-�� �: report (Compliance Report.GW-59A) fs, true and.,complete to fheybest of myknowledge� ,M;4 .�,�_ T _ . r2Y� 0 Si nature of ermittee (or Authorized Agent) Date GW-59A 12/8/2003 SI IRMIT PnRM r)M YFI I n1AJ IDAPFR nXII v ROUNDWATER QUALITY MONITORING: DMPLIANCE REPORT FORM TY INFORMATION mease ennr weany or Type Name; Clement Pappas Name (if different); Address; 125 Industrial Park luntain Home, (Street) NC 28758 County Henderson _. . act Person: Mr. Blake Kehoe Telephone#: (828) 693-0711 Location/Site Name: Irrigation Area No. of wells to be sampled: 6 PERMIT Number: Expiration Date: 11/30/2011 Non -Discharge W00004797 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑x Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: L ID NUMBER (from Permit): MW-2R Date sample collected: 5/28/2009 Depth: 14.90 ft. relative to top of casing Well Diameter: 2 in. h to Water Level: 5.43 ft. below measuring point Screened Interval: 6 ft.* to 11 ft.* luring Point is 3.77 ft. above land surface Relative M.P. Elevation: 2063.0 ft. ne of water pumped/bailed before sampling: 1.75 gallons "screened interval is relative to land surface )les for metals were collected unfiltered: DYES ❑ NO and field acidified: ❑ YES ❑ NO FIELD ANALYSES: WAS pH 4.82 unit D Temp. 13.89 QC DRY at Spec. Con . 72 µMhos time of sampling, Odor None check Appearance here: a sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712 tAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/I Nitrite (NO2) as N mg/I Pb - Lead mg/I Coliform; MF Fecal < 4.0 1100ml Nitrate (NO3) as N 0.46 mg/I Zn - Zinc mg/I Coliform: MF Total /100ml Phosphorus: Total as P mg/I (Note; Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 104 mg/I Al - Aluminum mg/I pH (when analyzed) r—=Its1 Ba - Barium mg/1 TOC �14.4 mgH/ �,, Ca - Calcium mg/I Chloride 7.1 mg/I Cd Cadmium mg/I Arsenic mg/I D hromlO .6all,., mg/I Grease and Oils mg/I Ct� opp r</' `�. mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol Sulfate mg/I ;.. E. e mg/I (Specify test and method #. ATTACH LAB REPORT.) 24.2 mg/I F#g - Merct t s?.• c� mg/l Report Attached? ElYes (1) El No (0) Specific Conductance µMhos mg/I method # Total Ammonia < 0.10 mg/I. Mg - Magnesium " mg/I method # (Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total) Mn - Manganese mg/I , method # TKN as N mg/I Ni - Nickel mg/I method # GW-59 Rev.1/2007 SUBMIT FORM ON YELLOW PAPER ONLY UNDWATER QUALITY MONITORING: PLIANCE REPORT FORM 1Tv DJCr%0 ure'rrnKt Please PrintClearly or Name; Clement Pappas Name (if different): Address: 125 Industrial Park )untain Home' (Street) NC 28758 County Henderson act Person: Mr. Blake Kehoe Telephone#: (828) 693-0711 Location/Site Name: Irrigation Area No, of wells to be sampled: 6 PERMIT Number: Expiration Date: 11/30/2011 Non -Discharge W00004797 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery FRI Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: L ID NUMBER (from Permit): MW-4 Date sample collected: 5/28/2009 FIELD ANALYSES: WAS Depth: 18.60 ft. relative to top of casing Well Diameter: 2 in. pH �5. unit� Temp. 14.45 eC DRY at h to Water Level 7.16 ft. below measuring point Screened Interval: 8 ft.* to 16.1 V Spec. o�nd. 153 µMhos time of sampling, wring Point is 2.43 ft. above land surface Relative M.P. Elevation: 2064.6 ft. Odor None check ne of water pumped/bailed before sampling: 6.0 gallons *screened interval is relative to land surface Appearance here: )les for metals were collected unfiltered: ❑YES ❑ NO and field acidified: ❑ YES ❑ NO sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712 IAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/I Nitrite (NO2) as N mg/1 Pb - Lead mg/I Coliform: MF Fecal < 4.0 /100ml Nitrate (NO3) as N < 0.10 mg/1 Zn - Zinc mg/I Coliform: MF Total /100ml Phosphorus: Total as P mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 156 mg/I Al - Aluminum mg/I pH (when analyzed) units Ba - Barium mg/I TOC 8.6 mg/I Ca - Calcium mg/I Chloride 13.6 mg/I Cd - Cadmium mg/I Arsenic mg/I Chromium: Total mg/I Grease and Oils mg/I Cu - Copper mg/1 ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/1 Fe - Iron, mg/1 (Specify test and method #. ATTACH LAB REPORT.) Sulfate 35.5 mg/1 Hg - Mercury mg/I Report Attached? ❑ Yes (1) 0 No (0) Specific Conductance µMhos K - Potassium mg/I method # Total Ammonia < 0.10 mg/l Mg - Magnesium mg/I method # (Ammonia Nitrogen; NH,as N; Ammonia Nitrogen, Total) Mn - Manganese mg/I method # TKN as N mg/1 Ni - Nickel mg/I method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% and Title - Please print or type GW-59 Rev.1/2007 bUbMl 11-UKM UN 7t'LLUVV NAF'tK UNLY DWATER QUALITY MONITORING: IANCE REPORT FORM TY INFORMATION mease t-nnr weany or Type Name Clement Pappas Name (if different): Address: 125 Industrial Park tuntain Home' (street) NC 28758 County Henderson act Person: Mr. Blake Kehoe Telephone#: (828) 693-0711 Location/Site Name: Irrigation Area No, of wells to be sampled: 6 PERMIT Number: Expiration Date: 11/30/2011 Non -Discharge W00004797 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery [Z] Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: L 1D NUMBER (from Permit): MW-5 Date sample collected; 5/28/2009 FIELD ANALY_-SF�: Depth; 18.60 ft. relative to top of casing Well Diameter: 2 in. pH (.5.76 units Temp. 12.74 eC i to Water Level: 7.95 ft. below measuring point Screened interval: 9 ft.* to 19 ft.* Spec. -on-, 123 µMhos luring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2086.4 ft. Odor None ne of water pumped/bailed before sampling: 5.5 gallons "screened interval based on well construction record Appearance )les for metals were collected unfiltered: OYES ❑ NO and field acidified: ❑ YES ❑ NO a sample analyzed: varies: see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No: 37712 tAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD �r�gfi� Nitrite (NOZ) as N mg/I Pb - Lead mg/I Coliform: MF Fecal / 4.0 J100ml Nitrate (NO3)'as N 0.11 mg/I Zn - Zinc mg/I Coliform: MF Total �' -' /100ml Phosphorus: Total as P mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mg/l , Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 188 mig I Al -Aluminum mg/I pH (when analyzed) ' 'arrits Ba - Barium mg/l TOC 16.1mg/1- Ca -Calcium mg/I Chloride 29.0 mg/I Cd - Cadmium mg/I Arsenic mg/I Chromium: Total mg/I Grease and Oils mg/I Cu - Copper mg/l ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/l Fe - Iron mg/I (Specify test and method #. ATTACH LAB REPORT.) Sulfate < 5.0 mg/I Hg - Mercury mg/I Report Attached? F.1 Yes (1) El No (0) Specific Conductance µMhos K - Potassium mg/I method # Total Ammonia < 0.10 mg/I Mg - Magnesium mg/I method # (Ammonia Nitrogen; NH,as N; Ammonia Nitrogen, Total) Mn - Manganese mg/I method # TKN as N mg/I Ni -Nickel mg/I method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Z_ littee (or Authorized Agent) Naft and Title - Please print or type OW-'59 Rev.112007 WELL at of •❑ JVDIVII I rUMM VIN In I Uw t'ArtK UNLY DWATER QUALITY MONITORING: IANCE REPORT FORM TY INFORMATION mease rnnr weanyor i ype Name: Clement Pappas Name (if different): Address: 125 Industrial Park tuntain Home' (Street) NC 28758 County Henderson act Person: Mr. Blake Kehoe Telephone#: (828) 693-0711 Location/Site Name: Irrigation Area No. of wells to be sampled: 6 PERMIT Number: Expiration Date: 11/30/2011 Non -Discharge WQ0004797 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery 2 Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other. JA1V1rK-114%7 IIVryKMA 11UN If WELL WELL ID NUMBER (from Permit): MW-6 Date sample collected: 5/28/2009 FIELD ANAL-YSES7 WAS Well Depth: 11.54 ft. relative to top of casing Well Diameter: 2 • in. pH C 4.95 units Temp. 15.84 eC DRY at Depth to Water Level: ' 5.63 ft. below measuring point Screened Interval: 5 ft,* to 10 ft," Spec. Co'nd — 48 µMhos time of Measuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2061.9 ft. Odor None sampling, check Volume of water pumped/bailed before sampling: 3.0 gallons *screened Interval based on well construction record Appearance here: Samples for metals were collected unfiltered: DYES ❑ NO and field acidified: ❑ YES ❑ NO ❑ LABORATORY INFORMATION Date sample analyzed:varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD .- -mglk- Nitrite (NO2) as N mg/I Pb - Lead mg/I Coliform: MF Fecal /` 276 /100 1 Nitrate (NO3) as N 0.39 mg/I Zn - Zinc mg/l Coliform: MF Total /100ml Phosphorus: Total as P mg/I (Note; Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 104 mg/I Al - Aluminum mg/I pH (when analyzed) units Ba - Barium mg/I TOC 6.4 mg/I Ca - Calcium mg/I Chloride 6.2 mg11 Cd - Cadmium mg/I Arsenic mg/I Chromium: Total mg/I Grease and Oils mg/l Cu - Copper mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/I Fe - Iron mg/I (Specify test and method #. ATTACH LAB REPORT.) Sulfate 8.8 mg/I Hg - Mercury mg/I Report Attached? ❑ Yes (1) El No (0) Specific Conductance µMhos K - Potassium mg/I method # Total Ammonia < 0.10 mg/l Mg - Magnesium mg/I method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)Mn - Manganese mg/I method # TKN as N mg/I Ni - Nickel mg/I , method # For Remediation Systems Only (Attach Lab Reports): • Influent Total VOCs: ma/L Effluent Total VOCs: mnn VOC RPmnval% GW-59 Rev.1/2007 11-UKM ON YELLOW PAPER ONLY TER QUALITY MONITORING: E REPORT FORM TY INFORMATION Please Pant clearly or Type Name: Clement Pappas Name (if different): Address: 125 Industrial Park iuntain Home' tstreet) NC 28758 County Henderson act Person: Mr. Blake Kehoe Telephone#: (828) 693-0711 Location/Site Name: Irrigation Area No. of wells to be sampled: 6 PERMIT Number: Expiration Date: 11/30/2011 Non -Discharge WQ0004797 UIC NPDES Other _ TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery 0 Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other. L ID' NUMBER (from Permit): MW-7 Date sample collected: 5/28/2009 Depth: 16.72 ft. relative to top of casing Well Diameter: 2 in. h to Water Level: 8.21 ft, below measuring point Screened Interval: 5 ft.* to 15 ft.* luring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2062.7 ft T ne of water pumped/bailed before sampling: 4.5 gallons *screened interval based on well construction record WELL FIELD � I:YSE's WAS pH ,/ 5.09 units Temp. 14.25 eC DRY at Spe cond. 54 µMhos time of samplin Odor None _ chaek Appearance (here: ❑ sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712 iAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/I Nitrite (NO2) as N mg/I Pb - Lead mg/I Coliform: MF Fecal < 4.0 1100ml Nitrate (NO3) as N2.3 mg/I Zn - Zinc mg/I Coliform: MF Total /100ml Phosphorus: Total as P mg/I (Note: Use MPNmethod forhighly turbid samples) Orthophosphate mg/l Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 336 mg/I Al - Aluminum mg/I pH (when analyzed) Ba - Barium mg/I TOC ("23.4 mg/I Ca - Calcium mg/I Chloride 9 8 mg/I Cd - Cadmium mg/I Arsenic mg/I Chromium: Total mg/I Grease and Oils mg/1 Cu - Copper mg/l ORGANICS: (by GC, GC/MS, HPLC) - Phenol mg/1 Fe - Iron mg/l (Specify test and method #. ATTACH LAB REPORT.) Sulfate < 5.0 mg/I Hg - Mercury mg/l Report Attached? . ❑ Yes (1) xn.. No (0) Specific Conductance µMhos K - Potassium mg/I method # Total Ammonia < 0.10 mg/I Mg - Magnesium mg/I method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn -Manganese mg/l - ,method # TKN as N mg/I Ni - Nickel mg/I method # t-or Kemecliation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: _mg/L VOC Removal% —:2- ilttee (or Authorized Agent) Namaland Title - Please print or type - _ -� Signature GW-59 Rev.1/2007 oumivn i ruravl UN Yt:LLUVV I Al'LK UNLY TER QUALITY MONITORING: E REPORT FORM Name: Clement Pappas Name (if different): Address: 125 Industrial Park iuntain Home' (51fBet) NC 28758 County Henderson INhA act Person: Mr. Blake Kehoe Telephone#: (828) 693-0711 Location/Site Name: Irrigation Area 'No, of wells to be sampled; 6 PERMIT Number: Expiration Date: 11/30/2011 Non -Discharge WQ0004797 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remed(ation: infiltration Gallery El Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: LL ID NUMBER (from Permit): MW-8 Date sample collected: 5/28/2009 FIELD ANALYSES; WAS II Depth: 13.90 ft. relative to top of casing Well Diameter: 2 in. pH 5.78 units Temp. 13,81 °C DRY at tth to Water Level: 8.25 ft. below measuring point Screened Interval: 3 ft,* to 13 ft.* Spe;_L n , 123 µMhos time of asuring Point is 3,00 ft. above land surface Relative M.P, Elevation: 2061.4 ft, � Odor None sampling,check Jme of water pumped/bailed before sampling: 3.0. gallons screened interval based on well construction record Appearance here: n les for metals were collected unfiltered: DYES ❑ NO and field acidified: ❑ YES ❑ NO _ f 30RATORY INFORMATION o sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712 ' ; AMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mgn Nitrite (NO2) as N mg/I Pb - Lead mg/l Coliform: MF•Fecal / 2-40 /10 mlf Nitrate (NO3) as N 0.74 mg/i Zn -Zinc mg/1 Collform: MF Total /100ml Phosphorus: Total as P mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 192 mg/I Al - Aluminum mg/1 pH (when analyzed) units Ba - Barium mg/I TOC 6.2 mg/I Ca - Calcium mg/I Chloride 24.9 ing/I Cd - Cadmium mg/I Arsenic mg/I Chromium: Total mg/I Grease and Oils mg/I Cu - Copper mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/I Fe - Iron mg/I (Specify test and method #. ATTACH LAB REPORT.) Sulfate 24.9 mg/1 Hg - Mercury mg/I Report Attached? ❑ Yes (1) 0 No (0) Specific Conductance µMhos K - Potassium mg/I method # Total Ammonia < 0.10 mg/I Mg - Magnesium mg/I method # (Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total) Mn -Manganese mg/l ,method # TKN as N mg/I Ni - Nickel mg/I method # • `.• •wn•cM.q�,-I- .ryownw Willy %MLOW1 6dU MUPOri5): Influent i otai vucs: mg/L Effluent Total VOCs: mg/L VOC Removal% •' 1.1 I�lr I�t't V„ ( UV(F11"77-UO < & `r! 4,1-/ Vr�( d dtee (or Authorized Agent) Name and Title - Please print or type Signature OPermittee (o rized Agent) (Date) GW-59 Rev.112007 acmnalXical o www.pacefabs.cam June 08, 2009 Mr. Chris Gilbert Altamont Environmental 231 Haywood Street Asheville, NC 28801 RE: Project: Clement Pappas 2081.01 Pace Project No.: 9245219 Dear Mr. Gilbert: Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 Enclosed are the analytical results for sample(s) received by the laboratory on May 28, 2009. The results relate only to the samples included in this report. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All Microbiological analyses were performed at the laboratory where the samples were received. If you have any questions concerning this report, please feel free to contact me. Sincerely, Lorn Patton lorri.patton@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. H •ecD4, ��Cf (704)875-9092 Page 1 of 16 acmnalytical www.pacelabacom Project: Clement Pappas 2081.01 Pace Project No.: 9245219 Charlotte Certification IDs West Virginia Certification #: 357 Virginia Certification #: 00213 Tennessee Certification #: 04010 South Carolina Drinking Water Cert. #: 990060003 South Carolina Certification #: 990060001 Pennsylvania Certification #: 68-00784 Connecticut Certification #: PH-0104 Asheville Certification IDs West Virginia Certification #: 356 Virginia Certification #: 00072 Connecticut Certification #: PH-0106 Florida/NELAP Certification #: E87648 Tennessee Certification #: 2980 South Carolina Certification #: 99030001 South Carolina Bioassay Certification #: 99030002 Eden Certification IDs North Carolina Wastewater Certification #: 633 Virginia Drinking Water Certification #: 00424 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 CERTIFICATIONS North Carolina Field Services Certification #: 5342 North Carolina Drinking Water Certification #: 37706 New Jersey Certification #: NCO12 Louisiana/LELAP Certification #: 04034 Kentucky UST Certification #: 84 Florida/NELAP Certification #: E87627 North Carolina Wastewater Certification #: 12 Pennsylvania Certification #: 68-03578 North Carolina Wastewater Certification #: 40 North Carolina Drinking Water Certification #: 37712 North Carolina Bioassay Certification 1P 9 New Jersey Certification #: NC011 Massachusetts Certification #: M-NC030 Louisiana/LELAP Certification #: 03095 North Carolina Drinking Water Certification #: 37738 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. YaCl�d�fl= Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 16 c Pace Analytical Services, Inc. Pace Analytical Services, Inc. 1��acleAnalXicalo 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 www.pawaDsoom Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: Clement Pappas 2081.01 Pace Project No.: 9245219 Sample: MW 2R Lab !D: 9246219001 Collected: 05/28/09 09:27 Received: 05/28/09 13:17 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms ND CFU/100 mL 4.0 4 05/28/09 14:40 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 104 mg/L 40.0 1 05/29/09 09:31 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 05/30/09 17:11 7764-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 0.46 mg/L 0.10 1 05/29/09 17:15 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 7.1 mg/L 5.0 1 05/29/09 09:21 16887-00-6 5310B TOC Analytical Method: SM 5310B Total Organic Carbon 14.4 mg/L 1.0 1 06/04/09 09:30 7440-44-0 ASTM D516-90 Sulfate Water Analytical Method: ASTM D516-90 Sulfate 24.2 mg/L 5.0 1 05/30/09 10:36 14808-79-8 Date:06/08/2009 11:02AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. hccoti 'p Page 3 of 16 J aceAnapical www.parelab acom Project: Clement Pappas 2081.01 Pace Project No.: 9245219 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: IIAW-4 Lab ID: 9245219002 Collected: 05/28/09 11:57 Received: 05/28/09 13:17 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms ND CFU/100 mL 4.0 4 05/28/09 14:40 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 156 mg/L 40.0 1 05/29/09 09:32 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 05/30/0917:11 7764-41-7 353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate ND mg/L 0.10 1 05/29/09 17:30 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 13.6 mg/L 5.0 1 05/29/09 09:19 16887-00-6 5310E TOC Analytical Method: SM 5310B Total Organic Carbon 8.6 mg/L 1.0 1 06/04/09 09:30 7440-44-0 ASTM D516-90 Sulfate Water Analytical Method: ASTM D516-90 Sulfate 35.5 mg/L 5.0 1 05/30/09 10:36 14808-79-8 Date: 06/08/2009 11:02 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full; without the written consent of Pace Analytical Services, Inc.. VL;Ac11 N co.,z Page 4 of 16 4 aceAnalytica!® www.pacefabs.com Project: Clement Pappas 2081.01 Pace Project No.: 9245219 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-6 Parameters Lab ID: 9245219003 Collected: 05/28/09 09:51 Results Units Report Limit DF Received: 05/28/09 13:17 Matrix: Water Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms 276 CFU/100 mL 1.0 1 05/28/09 14:40 ul 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 104 mg/L 40.0 1 05/29/09 09:32 350.1 Ammonia Analytical Method: EPA350.1 Nitrogen, Ammonia ND mg/L 0.10 1 05/30/09 17:12 7764-41-7 363.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 0.39 mg/L 0.10 1 05/29/09 17:17 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 6.2 mg/L 5.0 1 05/29/09 09:19 16887-00-6 5310B TOC Analytical Method: SM 5310B Total Organic Carbon 6.4 mg/L 1.0 1 06/04/09 09:30 7440-44-0 ASTM D516-90 Sulfate Water Analytical Method: ASTM D516-90 Sulfate 8.8 mg/L 5.0 1 05/30/09 10:39 14808-79-8 Date: 06/08/2009 11:02 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. %% lccpq'' Page 5 of 16 Q n ® Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceA►/alX66al/2225 Riverside Dr. 9800 Kincey Ave. Suite 100 www.paMhb&com Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: Clement Pappas 2081.01 Pace Project No.: 9245219 Sample: MW-7 Parameters Lab ID: 9245219004 Collected: 05/28/09 10:54 Results Units Report Limit DF Received: 05/2810913:17 Matrix: Water Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms . ND CFU/100 mL 4.0 4 05/28/0914:40 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 336 mg/L 40.0 1 05/29/09 09:32 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 05/30/0917:13 7764-41-7 MO 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 2.3 mg/L 0.10 1 05/29/0917:21 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 9.8 mg/L 5.0 1 05/29/09 09:19 16887-00-6 5310E TOC Analytical Method: SM 5310B Total Organic Carbon 23.4 mg/L 1.0 1 06/04/09 09:30 7440-44-0 ASTM D516-90 Sulfate Water Analytical Method: ASTM D516-90 Sulfate ND mg/L 5.0 1 05/30/09 10:39 14808 79-8 Date: 06/08/200911:02 AM REPORT OF LABORATORY ANALYSIS Page 6 of 16 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc N .,L11�llff»Iz t. aceAnalytical wmpawlakcom Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Clement Pappas 2081.01 Pace Project No.: 9245219 Sample: MW-8 Lab ID: 9245219005 Collected: 05/28/09 11:19 Received: 05/28/09 13:17 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform AVL Fecal Coliforms 2540C Total Dissolved Solids Total Dissolved Solids 350.1 Ammonia Nitrogen, Ammonia 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 4500 Chloride Chloride 531013 TOC Total Organic Carbon ASTIVI D516-90 Sulfate Water Sulfate Date: 06/08/2009 11:02 AM . Analytical Method: SM 9222D 240 CFU/100 mL 1.0 1 05/28/0914:40 u2 Analytical Method: SM 2540C 192 mg/L 40.0 1 05/29/09 09:33 Analytical Method: EPA 350.1 ND mg/L 0.10 1 05/30/0917:16 7764-41-7 Analytical Method: EPA 353.2 0.74 mg/L 0.10 1 05/29/09 17:29 Analytical Method: SM 4500-CI-E 24.9 mg/L 5.0 1 05/29/09 09:19 16887-00-6 Analytical Method: SM 5310B 6.2 mg/L 1.0 1 06/04/09 09:30 7440-44-0 Analytical Method: ASTM D516-90 24.9 mg/L 5.0 1 05/30/09 10:39 14808-79-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. H 'N � EOx Page 7 of 16 3 ® Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceft yiical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 www.parebbs.com Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: Clement Pappas 2081.01 Pace Project No.: 9245219 Sample: MW-5 Parameters Lab ID: 9245219006 Collected: 05/28/0910:22 Results Units Report Limit DF Received: 05/28/09 13:17 Matrix: Water Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms 4.0 CFU/100 mL 1.0 1 05/28/09 14:40 ul 2640C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 188 mg/L 40.0 1 05/29/09 09:33 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 0513010917:18 7764-41-7 353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 0.11 mg/L 0.10 1 05/29/09 17:20 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 29.0 mg/L 5.0 1 05/29/09 09:19 16887-00-6 5310E TOC Analytical Method: SM 5310B Total Organic Carbon 16.1 mg/L 1.0 1 06/04/09 09:30 7440-44-0 ASTM D516-90 Sulfate Water Analytical Method: ASTM D516-90 Sulfate ND mg/L 5.0 1 0513010910:39 14808-79-8 Date: 061081200911:02 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Acco"� Page 8 of 16 t Pace Analytical Services, Inc. aceAnalXical ® 2225 Riverside Dr. mwcpacelab.com Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Clement Pappas 2081.01 Pace Project No.: 9245219 QC Batch:. MBIO/3131 Analysis Method: SM 9222D QC Batch Method: SM 9222D Analysis Description: 9222D MBIO Fecal Coliform -AVL Associated Lab Samples: 9245219001, 9245219002, 9245219003, 9245219004, 9245219005, 9245219006 METHOD BLANK: 288423 Matrix: Water Associated Lab Samples: 9245219001, 9245219002, 9245219003, 9245219004, 9245219005, 9245219006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 05/28/09 14:40 SAMPLE DUPLICATE: 289739 Parameter Fecal Coliforms Date: 06/08/2009 11:02 AM 9245182007 Dup Units Result Result CFU/100 mL 10.0 ND RPD Qualifiers REPORT OF LABORATORY.ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 16 n o Pace Analytical Services, Inc. Pace Analytical Services, Inc. aCBAl78�yf�Cal 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 www.pacdabs.dom Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 QUALITY CONTROL DATA Project: Clement Pappas 2081.01 Pace Project No.: 9245219 QC Batch: WETA/5177 Analysis Method: ASTM D516-90 QC Batch Method: ASTM D516-90 Analysis Description: ASTM D516-90 Sulfate Water Associated Lab Samples: 9245219001, 9245219002, 9245219003, 9245219004, 9245219005, 9245219006 METHOD BLANK: 286506 Matrix: Water Associated Lab Samples: 9245219001, 9245219002, 9245219003, 9245219004, 9245219005, 9245219006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L ND 5.0 05/3010910:41 LABORATORY CONTROL SAMPLE: 286507 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 20.0 100 90-110 MATRIX SPIKE SAMPLE: 286508 9245216008 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Sulfate mg/L 748 20 752 15 75-125 MO MATRIX SPIKE SAMPLE: 286509 9245361001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Sulfate mg/L 4590 2000 4440 -8 75-125 MO SAMPLE DUPLICATE: 286510 Parameter Sulfate SAMPLE DUPLICATE: 286511 Parameter Sulfate Date: 06/08/200911:02 AM 9245361002 Dup Units Result Result mg/L 7.6 6.6 9245361003 Dup Units Result Result mg/L 117 119 RPD Qualifiers 13 RPD Qualifiers 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 16 /�/+�+® Pace Analytical Services, Inc. Pace Analytical Services, Inc. qceMaiXical 2225 Riverside Dr. 9800 KinceyAve. Suite 100 www.pacelabs com Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 QUALITY CONTROL DATA Project: Clement Pappas 2081.01 Pace Project No.: 9245219 QC Batch: WETA/5173 Analysis Method: EPA 350.1 QG Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia Associated Lab Samples: 9245219001, 9245219002, 9245219003, 9245219004, 9245219005, 9245219006 METHOD BLANK: 286463 Matrix: Water Associated Lab Samples: 9245219001, 9245219002, 9245219003, 9245219004, 9245219005, 9245219006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 05/30/09 16:58 LABORATORY CONTROL SAMPLE: 286464 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.3 105 90-110 MATRIX SPIKE SAMPLE: 286465 9245207001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L ND 10 11.3 113 90-110 MO MATRIX SPIKE SAMPLE: 286467 9245219004 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L ND 10 11.6 116 90-110 MO SAMPLE DUPLICATE: 286466 9245208001 Dup Parameter Units Result Result RPD Qualifiers Nitrogen, Ammonia mg/L 0.14 0.14 5 SAMPLE DUPLICATE: 286468 9245219005 Dup Parameter Units Result Result RPD Qualifiers Nitrogen, Ammonia mg/L ND ND Date: 06/08/200911:02 AM, REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. ` Page 11 of 16 Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceMalXical ® 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 www.pacelabscom Asheville. NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 QUALITY CONTROL DATA Project: Clement Pappas 2081.01 Pace Project No.: 9245219 QC Batch: WETA/5201 Analysis Method: SM 5310B QC Batch Method: SM 5310B Analysis Description: 5310B TOC Associated Lab Samples: 9245219001, 9245219002, 9245219003, 9245219004, 9245219005, 9245219006 . METHOD BLANK: 288650 Matrix: Water Associated Lab Samples: 9245219001, 9245219002, 9245219003, 9245219004, 9245219005, 9245219006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L ND 1.0 06/04/09 09:30 LABORATORY CONTROL SAMPLE: 288651 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 25 25.7 103 90-110 MATRIX SPIKE SAMPLE: 288778 9245219001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 14.4 25 43.3 115 75-125 MATRIX SPIKE SAMPLE: 288779 9245219002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 8.6 25 33.5 99 75-125 SAMPLE DUPLICATE: 288780 9245219003 Dup Parameter Units Result Result RPD Qualifiers Total Organic Carbon mg/L 6.4 6.2 2 SAMPLE DUPLICATE: 288781 9245219004 Dup Parameter Units Result Result RPD Qualifiers Total Organic Carbon mg/L 23.4 23.3 .3 Date: 06/08/2009 11:02 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent ooff Pace Analytical Services, Inc.. `QL�SdCd�i.1� Page 12 of 16 aceAnalytical www.pacefabs.com Project: Clement Pappas 2081.01 Pace Project No.: 9245219 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA QC Batch: WETA15168 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 9245219001, 9245219002, 9245219003, 9245219004, 9245219005, 9245219006 METHOD BLANK: 286289 Matrix: Water Associated Lab Samples: 9245219001, 9245219002, 9245219003, 9245219004, 9245219005, 9245219006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.10 05/29/09 17:12 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 286290 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 5 5.3 106 90-110 MATRIX SPIKE SAMPLE: 286292 9245317013 Spike MS MS Parameter Units Result Conc. Result % Rec Nitrogen, Nitrate mg/L 1.3 5 6.5 104 SAMPLE DUPLICATE: 286291 9245317014 Dup Parameter Units Result Result RPD Qualifiers Nitrogen, Nitrate mg/L 2.0 2.1 1 Date: 06/08/2009 11:02 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. e w ACC,' � LLJ�l1fA�l.11 z % Rec Limits Qualifiers . 90-110 Page 13 of 16 Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceMaOcal ® 2225 Riverside Dr. 9800 KinceyAve. Suite 100 wwwpacelahscom Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 QUALITY CONTROL DATA Project: Clement Pappas 2081.01 Pace Project No.: 9245219 QC Batch: WET/8455 Analysis Method: SM 2540C QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids Associated Lab Samples: 9245219001, 9245219002, 9245219003, 9245219004, 9245219005, 9245219006 METHOD BLANK: 285724 Matrix: Water Associated Lab Samples: 9245219001, 9245219002, 9245219003, 9245219004, 9245219005, 9245219006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L ND 20.0 05/29/09 09:25 LABORATORY CONTROL SAMPLE: 285725 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Total Dissolved Solids mg/L 250 294 118 80-120 SAMPLE DUPLICATE: 285726 9245146001 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 26900 27600 3 Date: 06/08/2009 11:02 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Without the written consent of Pace Analytical Services, Inc.. n Page 14 of 16 awAnaVical www pawk-&com Project: Clement Pappas 2081.01 Pace Project No.: 9245219 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA QC Batch: WETA15167 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 9245219001, 9245219002, 9245219003, 9245219004, 9245219005, 9245219006 METHOD BLANK: 285797 Matrix: Water Associated Lab Samples: 9245219001, 9245219002, 9245219003, 9245219004, 9245219005, 9245219006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 5.0 05/29/09 09:19 Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 285798 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.3 102 90-110 MATRIX SPIKE SAMPLE: 285799 9244233001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chloride mg/L ND 20 22.0 101 75-126 SAMPLE DUPLICATE: 285800 9244233002 Dup Parameter Units Result Result RPD Qualifiers Chloride mg/L ND ND Date: 06108/2009 11:02 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except -in full, without the written consent of Pace Analytical Services, Inc.- J.L�S.1gS.1= Page.15 of 16 A. aceAnalyfical www.pacelabscom QUALIFIERS Project: Clement Pappas 2081.01 Pace Project No.: 9245219 DEFINITIONS Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc.' 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes toAzobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes. U - Indicates the compound was analyzed for, but not detected. ANALYTE QUALIFIERS MO Matrix spike recovery was outside laboratory control limits. ul Results based upon colony counts outside acceptable range. u2 Colonies are too numerous to count. Actual result may be greater than reported. Date: 06/08/2009 11:02 AM REPORT OF LABORATORY ANALYSIS Page 16 of 16 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. CHAIN -OF -CUSTODY 1 Analytical Request Document aeeAnalytieal a The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. www.pacelabs.com Section A Section IS Section C Required Client Information: Required Project Information: Invoice Information: Company: Lit Report / f� Attention: Q,.� 49 T (' �i Page: % of ( 1301412 Address: Copy To: Company Name: REGULATORY -AGENCY. (tt„ � 11C.. ( Address: a j-• NPDES GROUND WATER (— DRINKING WATER r UST r RCRA r OTHER EART ' l a. V Purchase Order No.: Pace Quote Reference: F a P e• ^^aa t Project Name: jeq Pace ProManager.act Site Locatlon STATE: p Requested Due DaterTAT: Project Number: ^ r p Or t Pace Profile #; Requested -Aril Filtered (YIN) I;uk C Section D Matrix Codes Required Client information MATRIX I CODE Drinking Water DW Water WT Paste Water WPW SOIVSolld SL SAMPLE ID Olt a OL (A-2, 0-9 / ) Air AR Sample IDs MUST BE UNIQUE Tissue TS Other OT a 2gf o O O X a s7 KQ w a- a N COLLECTED o W 0 L) ° � o W Z ¢ U O 0 Preservatives z COMPOSITE TE ENDPOSITE GRAaodu a) ayi aU) C O v N = 0 Z _ V = = O fd Z ON m�V� lV Z c m � .'C.• N: ~ a w, m Q.. 14' i a to �`' 7 C o _ w N 9 "^^ Pace Project NoJ Lab I.D. DATE TIME DATE TIME 1 W Q d4 ' x .1 2 w- U64 (V A X 3 1AW-401 61 CN x 11 5 Wi C.A 111 1 k .�00 s G !o X s 9 ' 10 11 121 E—I 1 ADDITIONAL COMMENTS RELINQUISHEDBY/,AFFFIILIIA'TIION 'DATE TIME ACCEPTED BY/ . TE TIME SAMPLE CONDITIONS J. i ORIGINAL SAMPLER NAME AND:SIGNATURE I v = R. m F c m z m U m N rn PRINT Name of SAMPLER: .dA SIGNATURE of SAMPLER: DATE Signed (MMIDD 'Important Note: By signing this forth you are accepting Pace's NET 30 day payment terms and agreeing to late charges of 1.5 % per month for any Invoices Wald within 30 days. F-ALL-Q-020rev.07, 15-May-2007 WELL SAMPLING LOGS AND EQUIPMENT DOCUMENTATION AND INSTRUMENT CALIBRATION DATA SHEET ENGINEERING & HYDROGEOLOGY 50 COLLEGE STREET, ASHEVILLE, NC 28801 TEL. 828.281.3350 FAC .828.281.3351 www.altamontenvironmental.com Well Sampling Log FACILITY NAME: Clement Pappas LOCATION: Henderson County, North Carolina SAMPLING PERSONNEL: E. Yurkovich DATE: 8 SAMPLING TIME: 102- WEATHER: Cloys 40. WELL NUMBER: L-! w- WELL DIAMETER: 9" TYPE OF CASING: c— MEASURING POINT: TO FLUSH MOUNT IC - COMMENTS: Wcd E!vrqe,� dU rjtC is t� , crtt�w -�, ccc0.a.ce ;-#*A talkA S'c WELL DEPTH IN FEET (WD): START TIME: WATER LEVEL IN FEET (WL): 4� LENGTH OF WATER COLUMN: FEET (WD) - (WL) _ (LWC) ONE CASING VOLUME: GALLONS (LWC) x (WCV) THREE CASING VOLUMES: �ll� 3 GALLONS ACTUAL VOLUME PURGED: GALLONS WELL CASING VOLUMES (WCV) 1" = 0.041 Gal/Ft 2" = 0.17 GaUFt 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 GallFt 12" = 5.8 Gal/Ft PURGE METHOD: LER-DIS BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: R-DI BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: READING GALLONS PURGED pH UNITS SPECIFIC COND. (�,6) 11 TEMP (CO) DISSOLVED OXYGEN (mg/L) OXIDATION REDUCTION POTENTIAL mV TURBIDITY (NTU) COMMENTS I 62 1-93 3fr.s � 2 g r3 if Z . 3 3-79a' 4 6—'� 5 6 7 8 9 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 125 ml PLASTIC 2 Ammonia Nitrogen 250 ml PLASTIC 2 Fecal Coliform, Chloride, Sulfate, Nitrate 500 ml PLASTIC 1 TDS 40 ml GLASS 2 TOC PROTECTIVE CASING: PAD: OCK:qjk—_ VEGETATION: -&K ACCESS: 6�C Sampling Personnel Signature: Date: Sf 2tfty Notes: µS = micro-Siemen C° = degrees Celsius mg/L = milligrams per liter mV = millivolt NTU = nephelometric turbidity units P:\Templates\GW Drilling Forms\Well Sampling Log.xls Page 1 of 1 ALTAMONT 1' 1 FEN GIN E E R? N G & HYOROG E O L O G Y 50 COLLEGE STREET, AsHEVILLE, NC 28801 TEL. 828.281.3350 FAc .828.281.3351 www.aItamontenvironmental.com Well Sampling Log FACILITY NAME: Clement Pappas DATE: 5VRI (nq LOCATION: Henderson County, North Carolina SAMPLING TIME: �-7 SAMPLING PERSONNEL: E. Yurkovich WEATHER: Clete' dux -4So WELL NUMBER: 14w-q WELL DIAMETER: �' TYPE OF CASING:- MEASURING POINT: 'TOO FLUSH MOUNT ICK-UP COMMENTS: WELL DEPTH IN FEET (WD): 1,2•fjd START TIME: 11 3a WATER LEVEL IN FEET (WL): LENGTH OF WATER COLUMN: FEET (WD) - (WL) _ (LWC) ONE CASING VOLUME: GALLONS (LWC) x (WCV) THREE CASING VOLUMES: GALLONS ACTUAL VOLUME PURGED: GALLONS WELL CASING VOLUMES (WCV) V = 0.041 Gal/Ft .2" = 0.17 Gal/Ft 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.8 Gal/Ft PURGE METHOD: - BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: E - BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: READING GALLONS PURGED pH UNITS SPECIFIC COND. ( /S) `` TEMP (CO) DISSOLVED OXYGEN (mg/L) OXIDATION REDUCTION POTENTIAL mV TURBIDITY (NM COMMENTS 1 ,` , <7 pa -a 1. as f I l c� 2 1 a_u 6 10 1" f3j i 3,7q log,* 33,, 3 4 ..Z & (b 1 5 13- 5 6 7 8 9 SAMPLING CONTAINER' NUMBER OF CONTAINERS REQUESTED ANALYSIS 125 ml PLASTIC 2 Ammonia Nitrogen 250 ml PLASTIC 2 Fecal Coliform, Chloride, Sulfate, Nitrate 500 ml PLASTIC 1 TDS 40 ml GLASS 2 TOC PROTECTIVE CASING: PAD:_ LOCK: VEGETATION: ACCESS: �L Sampling Personnel Signature: Date: Notes: µS = micro-Siemen C' = degrees Celsius mg/L = milligrams per liter mV = millivolt NTU = nephelometric turbidity units P.\Temnlates\CTW Drilline Forms\Well SamolinE Loa.xls Page I of I ENGINEER ING & HYDROGEOLOGY 50 COLLEGE STREET, AsHEvILLE, NC 28801 TEL. 828.281.3350 FAc .828.281.3351 www.altamontenvironmental.com Well Sampling Log. FACILITY NAME: Clement Pappas DATE: 5 am I a LOCATION: Henderson County, North Carolina SAMPLING TIME: SAMPLING PERSONNEL: E. Yurkovich WEATHER: Clear St•n 7 S o WELL NUMBER: Nj W- 5 WELL DEPTH IN FEET (WD): i $ -60 START TIME: /60 WELL DIAMETER h WATER LEVEL IN FEET (WL): TYPE OF CASING: TVC LENGTH OF WATER COLUMN: FEET MEASURING POINT: TCYc. (WD) - (WL) = (LWC) FLUSH MOUNT / , 2� ONE CASING VOLUME: (-.'a 3 GALLONS COMMENTS: (LWC) x (WCV) THREE CASING VOLUMES: GALLONS ACTUAL VOLUME PURGED: GALLONS WELL CASING VOLUMES (WCV) I" = 0.041 Gal/Ft 2" = 0.17 Gal/Ft 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.8 Gal/Ft PURGE METHOD: LER-D . BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: I SAMPLE METHOD: BA - I AILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: READING GALLONS p&UNITS SPECIFIC TEMP DISSOLVED OXIDATION TURBIDITY COMMENTS PURGED COND. (CO) OXYGEN REDUCTION (NTU) () (mg/L) POTENTIAL t mV 1 7 q '5eq 5 2 10-0 V 4105 a a 13=C�41 .' 916 � 6 3 •Qt7 V fga o� !� '$ a"3 5 6 7 8 9 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 125 ml. PLASTIC 2 Ammonia Nitrogen 250 ml PLASTIC 2 Fecal Coliform, Chloride, Sulfate, Nitrate 500 nil PLASTIC 1 TDS 40 ml GLASS 2 TOC PROTECTIVE CASING: Dk-- PAD: ak �QCK: „ ek- VEGETATION:` ACCESS: dk Sampling Personnel Signature: Notes: µS = micro-Siemen C° = degrees Celsius mg/L = milligrams per liter mV = millivolt NTU = nephelometric turbidity units Date: 3r,, P:\Templates\GW Drilline Forms\Well Samolina LoQ.xls Pate 1 of 1 11, ENGINEERING Well Sampling Log FACILITY NAME: Clement Pappas LOCATION: Henderson County, North Carolina SAMPLING PERSONNEL: E. Yurkovich DATE: ViS f:% SAMPLING TIME: WEATHER: Clew �,a WELL NUMBER: r-t W- t? WELL DIAMETER: TYPE OF CASING: MEASURING POINT: l OG FLUSH MOUNT / - COMMENTS: WELL DEPTH IN FEET (WD): f 1, START TIME: �. WATER LEVEL IN FEET (WL): LENGTH OF WATER COLUMN: ? . Q FEET (WD) - (WL) _ (LWC) ONE CASING VOLUME: 1,00 GALLONS (LWC) x (WCV) THREE CASING VOLUMES: a'o GALLONS ACTUAL VOLUME PURGED: 360' GALLONS 1" = 0.041 Gal/Ft 2" = 0.17 Gal/Ft WELL CASING VOLUMES (WCV) 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.8 Gal/Ft PURGE METHOD: B - AILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: READING GALLONS PURGED pH UNITS SPECIFIC COND. () " t TEMP (CO) DISSOLVED OXYGEN (mg/L) OXIDATION REDUCTION POT POTENTIAL mV TURBIDITY (NTU) COMMENTS 1 5-1 Zq, 5T 2 1r a 5101 CD - r 3 a- 0 4 ls'o �. Ills,r c A Q6 5 6 7 8 9 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 125 ml PLASTIC 2 Ammonia Nitrogen 250 ml PLASTIC 2 Fecal Coliform, Chloride, Sulfate, Nitrate 500 ml PLASTIC 1 TDS 40 ml GLASS 2 ITOC PROTECTIVE CASING:—,:j�, PAD: z k LOCK: 121L VEGETATION: a-L ACCESS: a(C Sampling Personnel Signature: Date: Notes: pS = micro-Siemen C° = degrees Celsius mg/L = milligrams per liter mV = millivolt NTU = nephelometric turbidity units P:\TemDlates\GW Drilling Forms\Well Samnlina Loe.xls Paize 1 of 1 /4 I 7 E N G I N E E R I N G R H Y O R O G E O L O G Y 50 COLLEGE STREET, ASHEVILLE, NC 28801 TEL. 828.281.3350- FAC .828.281.3351 www.altamontenvironmental.com Well Sampling Log FACILITY NAME: Clement Pappas DATE: LOCATION: Henderson County, North Carolina SAMPLING TIME: Los SAMPLING PERSONNEL: E. Yurkovich WEATHER: , 3 WELL NUMBER: WELL DEPTH IN FEET (WD): (0, START TIME: (33G WELL DIAMETER: �� WATER LEVEL IN FEET (WL): 9, TYPE OF CASING: wc, LENGTH OF WATER COLUMN: 'g , S( FEET MEASURING POINT: 70G (WD) - (WL) _ (LWC) FLUSH MOUNT AC-UPONE CASING VOLUME: GALLONS COMMENTS: (LWC) x (WCV) THREE CASING VOLUMES:`r GALLONS ACTUAL VOLUME PURGED: GALLONS WELL CASING VOLUMES (WCV) 1" = 0.041 Gal/Ft 2" = 0.17 aUFt 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.8 GaUFt PURGE METHOD: P. BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: - BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: READING GALLONS pH -UNITS SPECIFIC TEMP DISSOLVED OXIDATION TURBIDITY COMMENTS PURGED COND. (CO) OXYGEN REDUCTION (NTU) (p) (mg/L) POTENTIAL m I ;v1w 6,13 S (04 5•0 'rog, 2 b5*6 &`v 6,0? !3o3."� rho. 4 i4.6-6 5-1o1 5,q.atS =a? 3/-1-;) 6� 5 6 7 8 9 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 125 ml PLASTIC 2 Aminonia Nitrogen 250 ml PLASTIC 2 Fecal Coliform, Chloride, Sulfate, Nitrate 500.ml PLASTIC 1 JTDS 40 ml GLASS 2 ITOC PROTECTIVE CASING: ©t-- PAD: to VEGETATION:ACCESS:_ Sampling Personnel Signature: Date: JLar Notes: µS = micro-Siemen C° = degrees Celsius mg/L = milligrams per liter mV = millivolt NTU = nephelometric turbidity units P:\Templates\GW Drilling Forms\Well Sampling Log.xls Page 1 of 1 ENGINEERING & HYDROG E O L O G Y 50 COLLEGE STREET, AsHFvILLE, NC 28801 TEL. 828.281.3350 FAC .828.281.3351 www.altamontenvironmental.com Well Sampling Log FACILITY NAME: Clement Pappas DATE: LOCATION: Henderson County, North Carolina SAMPLING TIME: (� SAMPLING PERSONNEL: E. Yurkovich WEATHER Cleuy .5vnnU 775 0 WELL NUMBER: WELL DEPTH IN FEET (WD): START TIME: %/aS WELL DIAMETER: �' WATER LEVEL IN FEET (WL): d S TYPE OF CASING: LENGTH OF WATER COLUMN: + FEET MEASURING POINT: —cX- (WD) - (WL) _ (LWC) FLUSH MOUNT STICK-U ONE CASING VOLUME: ©.Q(a GALLONS COMMENTS: (LWC) x (WCV) THREE CASING VOLUMES: GALLONS I ACTUAL VOLUME PURGED: GALLONS WELL CASING VOLUMES (WCV) 1" = 0.041 Gal/Ft 2" = 0.17 Gal/Ft 3" = 038 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.8 Gal/Ft PURGE METHOD: AIL - . BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: . BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: READING GALLONS pH UNITS SPECIFIC TEMP DISSOLVED OXIDATION TURBIDITY COMMENTS PURGED COND. (CO) OXYGEN REDUCTION (NTU) ( to (mg/L) POTENTIAL l mV 1 641 161 � �� a• 3 5 2 f 3';Z7 S 3 a Q-0 �Caa.a 3 4 3+ S 513L a3" qz, a 5 6 7 8 9 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 125 ml PLASTIC 2 Ammonia Nitrogen 250 ml PLASTIC 2 Fecal Coliform, Chloride, Sulfate, Nitrate 500 ml PLASTIC 1 TDS 40 ml GLASS 2 ITOC PROTECTIVE CASING: MC PAD: VEGETATION:_ ACCESS: Sampling Personnel Signature: Date:6l a Notes: µS = micro-Siemen C° = degrees Celsius mg/L = milligrams per liter mV = millivolt NTU = nephelometric turbidity units P:\Templates\GW Drilling Forms\Well Sampling Log.xls Page 1 of 1 ALTAMONT ENVIRONMENTAL, INC. Engineering & Hydrogeology 50 COLLEGE STREET, ASHEVILLE, NC 28801 TEL.828.821.3350 FAC.828.281.3351 www.altamontenvironmental com Equipment Documentation & Instrument Calibration Data Sheet Project Name: a(-,P� Project Number: 4Va12l - 6 t Project Location: 8zrS +1 ANe- Equipment Documentation: Equipment or meters used to take measurements (e.g. water level meters, survey equipment, etc.): Equipment Type Manufacturer Serial Number Date of Use 150-ft Water Level Heron 7186 150-ft Water Level Solinst 26154 150-ft Water Level Solinst 22754 Water Level Testwell 150 [50-ft 'Calibration Documentation Person Conducting Calibration: irk Date of Calibration:' Date of Field Measurements: $ a� YSI 556 Multiparameter Meter Micro TPW Turbidity Meter Calibration Time Calib Standard Exp Instrument Serial # Instrument Reading 1000 NTU 10.0 NTU 0.02 NTU ��� '"� at'io 200601045 Initial: r4 Cal: 'p Initial: 2 t Cal: Initial: 0-00 Cal: O, v 1 Calib Standard Instrument _ Instrument Readings Calibration Time Expiration Serial pH 7 pH 4 pH 10 QC Spec. Cond. QC ORP Date Number pH 7 447/84/23 µs 84 µS 200 mV �G AID 07DIO0979 Initial: 7�p Cal: Initial: 4 ,c-o Cal: Initial: "g Cal: Meas: JO Initial: .55 Cal: Meas: ? T/ Initial: QO. :7 �00 � � ,�� Cal: Initial: Initial: Initial: Meas: Initial: Meas: Initial: Cal: Cal: Cal: Cal: Cal: Comments nature and Date:/ Note: Electronic equipment calibrated according to the manufacturer's operation manual. Specific Conductivity should be calibrated according to values representative of historic range Order of Calibration is as follows : Specific Conductivity, pH 7, pH 4, pH 10, ORP, QC checks. PATemplateslGW-Drilling FormslCalibration Data Sheet YSI 556 Page 1 of 1 DENR GW-59A - COMPLIANCE REPORT FORM GW-59A COMPLIANCE REPORT FORM Permit # WQ0004797 (Subndt one each monitoring period with GW-59 forms.) j Enter date monitoring results were due. (6/30/2009 ) Will this monitoring report (GW-59 and GW-59A) YES NO be submitted after the established due date? 2 Was any required information missing on the GW-59 report forms? YES NO iF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and • explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? If the answer is "Yes", contact the Regional Ofce for guidance. 4 Are any monitored constituents equal to or above the established standards? YES NO If the answer to question 4 is "NO", skip to section 8. If the answer to question 4 Is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below. MW-2R: total organic carbon 14.4 mg/L MW-5: total organic carbon 16.1 mg/L, fecal collform 4.0 per 100mL MW-6: fecal coliform 276 per 100mL MW-7: total organic carbon 23.4 mg/L MW-8: fecal coliform 240 per 100mL 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? Q If the answer to question 5 is "NO", skip to section 8. If the answer• to question 51s "YES" list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence'(for the last two years). MW-2R: total organic carbon: 10.2 mg/L 5/27/08 MW-5: total organic carbon: 25.9 mg/L 11/18/08 MW-6: fecal coliform: 3.6 per 100 mL 11/13/07 MW-8: fecal coliform: 2.2 per 100 mL 11/18/08 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO e; If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located; contact the Regional Office. 7 Is the permittee Implementing previously approved actions required by the Division Involving this YES NO groundwater quality problem? If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO" contact the Regional Office within 90 days; an evaluation may be required to determine the impact the waste disposal system Is havino at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation fines, and/or penalties. Total Organic Carbon, VOC, and SVOC analyses were completed for all samples during the May 2007 groundwater sampling event. The TOC is not attributable to VOCs or SVOCs. Possibly natural occurring. Although not yet approved by the Division, the permittee Intends to analyze the November 2009 groundwater samples according to an alternative fecal coliform method. If the November 2009 results are similar, further action will be taken. g The person completing this portion (G W--59A) of the monitoring report should sign below and submit this form with G W-59 forms. for required wells to the address provided at the top of the current G W-59 form. �1 f ere6y acknowledge than d4baiEfiffomtation wa �evaivae InfoftnaU"on subttSt ted :this" Fepol (Compltance Report GWA .L is trUe,�hcf complete to the best of �t}(,koovllletlge, ��� ��' 3 SI nature okenh-Itte, (orAuthoriaed Agent) Date GW-59A 12/8/2003 Pace Analytical Services, Inc. 1® Analytica www.pacela6s. ace . June 08, 2009 Mr. Chris Gilbert Altamont Environmental 231 Haywood Street Asheville, NC 28801 RE: Project: Clement Pappas 2081.01 Pace Project No.: 9245219 Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersvllle, NC 28078 (704)875-9092 Dear Mr. Gilbert: Enclosed are the analytical results for sample(s) received by the laboratory on May 28, 2009. The results relate only to the samples included in this report. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All Microbiological analyses were performed at the laboratory where the samples were received. If you have any questions concerning this report, please feel free to contact me. Sincerely, Lord Patton lorri.patton@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS Page 1 of 16 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. co„o V= aceAnayical wws:pacdabsWm Project Clement Pappas 2081.01 Pace Project No.: 9245219 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-211 Parameters Lab ID: 9245219001 Collected: 05/28/09 09:27 Results Units Report Limit DF Received: 05/28/09 13:17 Matrix: Water Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms NO CFU/100 mL 4.0 4 05/28/09 14AO 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 104 mg/L 40.0 1 05/29/09 09:31 350.1 Ammonia Analytical Method: EPA350.1 Nitrogen, Ammonia ND mg/L 0.10 1 05/30/0917:11 776441-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 0.46 mg/L 0.10 1 05/29/09 17:15 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 7.1 mg/L 5.0 1 05/29/09 09:21 16887-00-6 5310E TOC Analytical Method: SM 5310B Total Organic Carbon 14.4 mg/L 1.0 1 06/04/09 09:30 7440-44-0 ASTM D616-90 Sulfate Water Analytical Method: ASTM D516-90 Sulfate 24.2 mg/L 5.0 1 05/30/09 10:36 14808-79-8 Date: 06/08/2009 11:02 AM REPORT OF LABORATORY ANALYSIS Page 3 of 16 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Cee. aceft ytical e mww.pacdabswm Project: Clement Pappas 2081.01 Pace Project No.: 9245219 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 98001GnceyAve. Suite 100 Huntersville. NC 28078 (704)875-9M2 Sample: MW-4 Lab ID. 9245219002 • Collected: 05/28/0911:57 Received: 0512810913:17 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed' CAS No. Qual MBIO 92220 Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms NO CFU/100 mL 4.0 4 05128/0914:40 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 166 mg/L 40.0 1 05/29/09 09:32 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia NO mg/L 0.10 1 05/30/09 17:11 7764-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 3532 Nitrogen, Nitrate NO mg/L 0.10 1 05/2910917:30 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 13.6 mg/L 5.0 1 05/29/09 09:19 16887-00-6 5310E TOC Analytical Method: SM 5310B Total Organic Carbon 8.6 mg/L 1.0 1 06/04/09 09.30 7440-44-0 ASTM D516-90 Sulfate Water Analytical Method: ASTM D516-90 Sulfate 35.5 mgfL 5.0 1 05/30/0910:36 14808-79-8 Date: 06108/2009 11.02 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in ful; without the written consent of Pace Analytical Services, Inc.. Page 4 of 16 aceAnalytical www.p&odabsc= Project: Clement Pappas 2081.01 Pace Project No.: 9245219 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-6 Lab ID: 9245219003 Collected: 05/28/09 09:51 Received: 05/28/09 13:17 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms 276 CFU/100 mL 1.0 1 05/28/09 14:40 ul 2640C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 104 mg/L 40.0 1 05/29/09 09:32 360.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 05/30/09 17:12 7764-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 0.39 mg/L 0.10 1 05/29/09 17:17 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 6.2 mglL 5.0 1 05/29/09 09:19 16887-00-6 6310B TOG Analytical Method: SM 5310B Total Organic Carbon 6.4 mg/L 1.0 1 06/04/09 09:30 7440-44-0 ASTM D516-90 Sulfate Water Analytical Method: ASTM D516-90 Sulfate 8.8 mg/L 5.0 1 05/30/09 10:39 14808-79-8 Date: 06/08/200911:02 AM REPORT OF LABORATORY ANALYSIS Page 5 of 16 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. i Ana� � if• ® Pace Analytical Services, Inc. 2225 Riverside Dr. Pace Analytical Services, Inc. 9800 Kmcey Ave. Suite 100 wwwpi-Jakwm Asheville. NC 28804 Huntersviile, NC 28078 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: Clement Pappas 2081.01 Pace ProjectNo.: 9245219 Sample: MW-5 Lab 10: 9245219006 Collected: 05128/0910:22 Received: 0512810913:17 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MBIO 92220 Fecal Catiform AVL Analytical Method: SM 9222D Fecal Coliforms 4.0 CFU/100 mL 1.0 1 05128/09 14.40 ul 2640C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 188 mg/L 40.0 1 05129/09 09:33 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 0513010917:18 7764-41-7 353.2 Nitrogen, NO2fNO3 unpres Analytical Method: EPA3532 Nitrogen, Nitrate 0.11 mg/L 0.10 1 05/29/09 17:20 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 29.0 mglL 6.0 1 05/29/09 09:19 16887-00-6 5310E TOC Analytical Method: SM 5310B Total Organic Carbon 16.1 mg/L 1.0 1 06/04/09 09.30 7440-44-0 ASTM D516-90 Sulfate Water Analytical Method: ASTM D516-90 Sulfate ND mg/L 5.0 1 05/3010910:39 14808-79-8 Date: 06/08/2009 11:02 AM REPORT OF LABORATORY ANALYSIS Page 8 of 16 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Y A/j�� �g ® Pace Analytical Services, Inc. Pace Analytical Services, Inc. acoMa cai . 2225 Riverside Dr. 9800 ftceyAve. Suite 100 tywwpacefabscem Asheville, NC 28804 Iiuntersville. NC 28078 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project Clement Pappas 2081.01 Pace Project No.: 9245219 Sample: MW 7 Parameters Lab ID: 9246219004 Collected: 05128/0910:54 Results . Units Report Limit DF Received: 05/2810913:17 Matrix: Water Prepared Analyzed CAS No. Qua[ MBIO 9222D Fecal Colfform AVL Analytical Method: SM 9222D Fecal Coliforms , ND CFU/100 ml- 4.0 4 05/28/0914.40 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids" 336 mg/L 40.0 1 05/29/09 09:32 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 0513016917.13 7764-41-7 MO 353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 2.3 mg/L 0.10 1 05/29/09 17:21 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 9.8 mg/L 5.0 1 05/29/09 09:19 16887-00-6 5310B TOC Analytical Method: SM 5310B Total Organic Carbon 23.4 mg/L 1.0 1 06/04/09 09:30 7440-44-0 ASTM D516-90 Sulfate Water Analytical Method: ASTM D516-90 Sulfate ND mg/L 5.0 1 05/3010910.39 14808-79-8 Date: 06/08/200911.02 AM REPORT OF LABORATORY ANALYSIS Page 6 of 16 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. ® Pace Analytical Services, Inc. Pace Analytical Services, Inc. aeAnaljftal 2225 Riverside Dr. a 9800 Kincey Ave. Suite 100 wimpacelab&mm Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: . Clement Pappas 2081.01 Pace Project No.: 9245219 Sample: MW 8 Lab ID: 9245219006 Collected: 05/28/09 11:19 Received: 05/28/09 13:17 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual i MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Colifonns 240 CFU/100 mL 1.0 1 05128/0914:40 u2 2540C Total Dissolved Solids Analytical Method: SM 2540C i Total Dissolved Solids 192 mg/L 40.0 1 05/29/09 09:33 i 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 05/30/0917:15 7764-41-7 353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA353.2 Nitrogen, Nitrate 0.74 mg/L 0.10 1 05/29/09 17:29 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 24.9 mg/L 5.0 1 05/29/09 09:19 16887-00-6 5310E TOC Analytical Method: SM 6310B Total Organic Carbon 6.2 mg/L 1.0 1 06/04/09 09:30 7440-44-0 ASTM D516-90 Sulfate Water Analytical Method: ASTM D516-90 Sulfate 24.9 mg/L 5.0 1 05/3010910:39 14808-79-8 Date: 06/081200911:02AM REPORT OF LABORATORY ANALYSIS Page 7 of 16 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. RI IRMIT F(1RM r1N YFI I MAI PAPFP M11 v GROUNDWATER QUALITY MONITORING: o1 a o COMPLIANCE REPORT FORM • • FACILITY INFORMATION Please Print Clearly or Type PERMIT Number. Expiration Date: 11130/2011 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Mountain Home' (s'reeq NC 28758 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery (city) (state) (Zap) I] Spray Field ❑ Remediation: Contact Person: Mr. Blake Kehoe Telephone#: (828) 693-0711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other. from Pemdl SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW 2R Date sample collected: 5/28/2009 FIELD A WAS Well Depth: 14.90 it. relative to top of casing Well Diameter. 2 in. p 1 4.82 units Temp. 13.89 °C DRY at Depth to Water Level: 5.43 ft, below measuring point Screened Interval: 6 ft.* to 11 V Spec. on . 72 µMhos time of Measuring Point is 3.77 ft. above land surface Relative M.P. Elevation; 2063.0 ft. Odor None sampling, check Volume of water pumpe"ailed before sampling: 1.75 gallons 'screened interval is relative to land surface Appearance here: Samples for metals were collected unfiltered: ❑YES ❑ NO and field acidified: ❑YES ❑ NO ❑ LABORATORY INFORMATION Date sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD MgA Nitrite (NO2) as N mg/1 Pb - Lead mgA Coliform: MF Fecal < 4.0 /100m Nitrate (NO3) as N 0.46 mg/1 Zn - Zinc mgA Coliform: MF Total �� ml Phosphorus: Total as P mgA (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 104 mg/I Al - Aluminum' mg/I pH (when analyzed) its Ba - Barium mgA TOC 14.4 m Ca - Calcium mgA Chloride 7.1 mg/I Cd - Cadmium mg/I Arsenic mgn Chromium: Total mg/I Grease and Oils mg/I Cu - Copper mg/I ORGANICS: (by GC, GCIMS, HPLC) Phenol mg/1 Fe - Iron mgA (Specify test and method #. ATTACH LAB REPORT.) Sulfate 24.2 mg/I Hg - Mercury mg/l Report Attached? ❑ Yes (1) x❑ No (0) Specific Conductance µMhos K - Potassium mgA , method # Total Ammonia < 0.10 mg/l. Mg - Magnesium mg/I , method # (Ammonia Nitrogen; NII N; Ammonia Nitrogen, Total) Mn -Manganese mgA ,method # TKN as N mgA Ni - Nickel mg/l method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mgA. Effluent Total VOCs: mg/L VOC Removal% I certify that, to the best of my knowledge and belief, the information submitted DWO-cerlified laboratory. I am aware that there are significant penalties for in this report is true, accurate, and complete, and that the submittinci false informaWn. itcluchrri-fte oossibilitv offites laboratory aydm�unricnvupit analytical data was produced using approved methods ofanalysis by a fir VT*%tjiwr vitfstisiq k L& H A-w ,,tAjAcL-_,e _& A� 9 - �L* --o Perrnittee (or Authorized Agent) Name and Title - Please print ortype SlgnatuK of Pemtittee (or Authorized Agent) (Date) GW-59 Rev.112007 .7UCIVII I rUKIVI UN TI-1L)VV F'HYtK UIVLT TER QUALITY MONITORING: E REPORT FORM Name: Clement Pappas Name (if different): Address: 125 Industrial Park writain Home (Street) NC 28758 County Henderson act Person: 'Mr. Blake Kehoe Telephone#: (828) 693-0711 Location/Site Name: Irrigation Area No. of wells to be sampled; 6 :RMIT Number: Expiration Date: 11/30/2011 in -Discharge WQ0004797 UIC - IDES Other 'PE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery 0 Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other. L ID NUMBER (from Permit): MW4 Date sample collected: 5/28/2009 FIELD WAS Depth: 18.60 fL relative to top of casing Well Diameter. 2 in. pH 5.98 units Temp. 14.45 oC DRY at h to Water Level: 7.16 ft. below measuring point Screened Interval: 8 V to 16.1 V Spec. Cond. 153 µMhos time of sampling, wring Point is 2.43 ft. above land surface Relative M.P. Elevation: 2064.6 ft. Odor None check ne of water pumped/bailed before sampling: 6.0 gallons *screened interval is relative to land surface Appearance here: 0 )les for metals were collected unfiltered: ❑YES ❑ NO and field acidified: ❑ YES ❑ NO sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712 IAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD Nitrite (NO2) as N mg/I Pb - Lead mg/I Coliform: MF Fecal C< 4.0 1100m Nitrate (NO3) as N < 0.10 mgA Zn - Zinc mg/1 Coliform: MF Total /100ml Phosphorus: Total as P mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 156 mg/I AI -Aluminum mg/I pH (when analyzed) units Ba - Barium mgA TOC 8.6 mg/I Ca - Calcium mg/I Chloride 13.6 mg/I Cd - Cadmium mg/I Arsenic mg/I Chromium: Total mg/I Grease and Oils mgA Cu - Copper mgA ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/1 Fe - Iron. mg/I (Specify test and method #. ATTACH LAB REPORT.) Sulfate 35.5 mg/I Hg - Mercury mg/I Report Attached? ❑ . Yes (1) El No (0) Speck Conductance µMhos K - Potassium mg/I method # Total Ammonia < 0.10 mg/I Mg - Magnesium mgA method # (Ammonia Nitrogen; NH,as N; Ammonia Nitrogen, Total) Mn - Manganese mgA , method # TKN as N mg/l Ni - Nickel mgA , method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.1/2007 oucivu r rUKlvl my rri! U_ t'HYCK UNLT :R QUALITY MONITORING: REPORT FORM LITY INFORMATION PERMIT Number: Expiration Date: 11/30/2011 ity Name: Clement Pappas Non -Discharge WQ0004797 UIC lit Name (if different): NPDES Other ityAddress: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Mountain Home' rsueep NC 28758 County Henderson ❑ Lagoon ❑ Remediation: infiltration Gallery (cay> (State) (zip) ❑x Spray Field ❑ Remediation: act Person: Mr. Blake Kehoe Telephone#: (828) 693-0711 ❑ Rotary Distributor ❑ Land Application of Sludge Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other. SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW 5 Date sample collected: 5/28/2009 FIELD AS Well Depth: 18.60 ft. relative to top of casing , Well Diameter. 2 in. pH nits Temp. 12.74 °C o7n DRY at Depth to Water Level: 7.95 ft. below measuring point Screened Interval: 9 ft.* to 19 ft * Spec. 123 µMhos time of sampling, Measuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2086.4 ft. Odor None check olume of water pumped/bailed before sampling: 5.5 gallons *screened interval based on well construction record Appearance here: ❑ Samales for metals were collected unfiltered: ❑YES ❑ NO and field acidified: ❑ YES IDNO sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712 IAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD . g Nitrite (NO.) as N mg/I Pb - Lead mg/1 Col'rform: MF Fecal 4.0 /100m Nitrate (NO3) as N 0.11 mgA Zn -Zinc mgA Coliform: MF Total /100m1 Phosphorus: Total as P mgA (Note: Use MPN method for highly turbid samples) Orthophosphate mg/1 " Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 188 mg/I AI - Aluminum mgA pH (when analyzed) Ba - Barium mgA TOC 16.1mg/I Ca - Calcium mgA Chloride mg/I Cd - Cadmium mgA Arsenic mgA Chromium: Total mg/I Grease and Oils mgA Cu - Copper mg/1 ORGANICS: (by GC, GC/MS, HPLC) Phenol mgA Fe - Iron mgA (Specify test and method #. ATTACH LAB REPORT.) Sulfate < 5.0 mg/I Hg - Mercury mg/I Report Attached? El Yes (1) x❑ No (0) Speck Conductance µMhos K - Potassium mg/I , method # Total Ammonia < 0.10 mgA Mg - Magnesium mgA , method # (Ammonia N'drogen; NH,as N; Ammonia Nitrogen. Total) Mn - Manganese mgA , method # TKN as N mgA Ni - Nickel mg/I , method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.112007 SUBMIT FORM ON YELLOW PAPER ONLY :R QUALITY MONITORING: REPORT FORM Name: Clement Pappas Name (if different): Address: 125 Industrial Park runtain Home' ' (street) NC 28758 County Henderson act Person: Mr. Blake Kehoe Telephone#: (828) 693-0711 Location/Site Name: Irrigation Area No. of wells to be sampled: 6 :RMIT Number: Expiration Date: 11/30/2011 In -Discharge W00004797 UIC )DES Other PE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery 0 Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other. L ID NUMBER (from Permit): MW-6 Date sample collected: 5/28/2009 FIELD ANAL,AS Depth: 11.54 ft. relative to top of casing Well Diameter. 2-in. pH 4.95 un' Temp. 15.84 •C DRY at h to Water Level: 5.63 ft. below measuring point Screened Interval: 5 ft.* to 10 ft.* Spec. Con . 48 µMhos time luring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2061.9 ft. Odor None sampling, check ne,of water pumped/bailed before sampling: 3.0 gallons, *screened interval based on well construction record Appearance here: )les for metals were collected unfiltered: DYES ❑ NO and field acidified: El YES ❑ NO ❑ sample analyzed:varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712 tAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD g Nitrite (NO2) as N mg/I Pb - Lead mgn Coliform: MF Fecal 276 A-0-003yNitrate (NO3) as N 0.39 mg/I Zn - Zinc mg/I Coliform: MF Total /100ml Phosphorus: Total as P mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 104 mg/I AI - Aluminum mg/I pH (when analyzed) units Ba - Barium mg/l - TOC 6.4 mg/I Ca - Calcium mg/I Chloride 6.2 mg/l Cd - Cadmium mg/I Arsenic mg/l Chromium: Total mg/l Grease and Oils mg/I Cu - Copper mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/l Fe - Iron mg/I (Specify test and method #. ATTACH LAB REPORT.) Sulfate 8.8 mgA Hg - Mercury mg/I Report Attached? ❑ Yes (1) 0 No (0) Specific Conductance µMhos K - Potassium mg/I , method # Total Ammonia < 0.10 mg/l Mg - Magnesium mg/I method # (Ammonia Nitrogen; NH,as IT Ammonia Nitrogen, Total) Mn - Manganese mg/I method # TKN as N mg/I Ni - Nickel mgA , method # For Remediation Systems Only Reports): . • ./L Effluent Total VOCs:. • I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a DWO-certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and impriso,aient for knowing violations. I 1 , /A i •. ,...,.....:.:...�.,.,-.,.... -_ __.,.,,, ........r:.:..._.::.,�.::...�.....,..e..,�_.,.:-. _..,. ._, ..... �....�..�:..�«..:�w--...a...a.... ..... .......... �auw,cgq.,-,.,.woos SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: a (r mc• COMPLIANCE REPORT FORM rn of MM s FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 11/30/2011 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 125 Industrial Park . TYPE OF PERMITTED OPERATION BEING MONITORED Mountain Home' (Sseeq NC 28758 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery (City) (State) (zip) ❑ Spray Field ❑ Remediation: Contact Person: Mr. Blake Kehoe Telephone#: (828) 693-0711 ElRotary Distributor ElLand Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other. from Pe SAMPLING *INFORMATION If WELL WELL ID NUMBER (from Permit): MW 7 Date sample collected: 5/28/2009 FIELD ANA AS Well Depth: 16.72 it relative to top of casing Well Diameter. 2 in. pH 5.09 uni Temp. 14.25 aC DRY at Depth to Water Level: 8.21 fL below measuring point Screened Interval: 5 V to 15 ft.* Spec. Cond. 54 µMhos time of Measuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2062.7 ft Odor None sampling, check Volume of water pumped/bailed before sampling: 4.5 gallons -screened interval based on well construction record Appearance here: ❑ Samples for metals were collected unfiltered: ❑YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD g Nitrite (NO2) as N mgA Pb - Lead mgA Coliform: MF Fecal 4.0 1100 Nitrate (NO3) as N 2.3 mgA Zn -Zinc mgA Col'iform: MF Total A 00ml Phosphorus: Total as P mgA (Note: Use MPN method for hlghly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 336 mg/I AI - Aluminum mgA pH (when analyzed) u ' s Ba - Barium mg/I TOC 23.4 m / Ca - Calcium mgA Chloride 9.8 mgA Cd - Cadmium mg/I Arsenic mgA Chromium: Total mg/I Grease and Oils mgA Cu - Copper mgA ORGANICS. (by GC, GC/MS, HPLC) Phenol mgA Fe - Iron mgA (Specify test and method #. ATTACH LAB REPORT.) Sulfate < 5.0 mgA Hg - Mercury mg/I Report Attached? . ❑ Yes (1) 0 No (0) Specific Conductance µMhos K - Potassium mgA , method # Total Ammonia < 0.10 mgA Mg - Magnesium mgA method # (Ammonia Nitrogen; NH.as N; Ammonia Ntmilen, Total) Mn - Manganese mgA method # TKN as N mg/I Ni - Nickel mg/I method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mgA- Effluent Total VOCs: mgA- VOC Removal% I certify that, to the best of my knowledge and belief, the information submitted DWO-ce,tified laboratory. I am aware that there are significant penalties for submittinq in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods ofanalysis by a false informatiop. itcludina tle DOssibilitv of Mies aird innrisorfrreit for lki*vji-ir visbfisr.q Title:. Please print or GW59 Rev.112007 Signature 2y (Date) ALR9tlllt r r-UKNt UN Yt_I_Ll)w PNI'tK UNLY UNDWATER QUALITY MONITORING: PLIANCE REPORT FORM ITY INFORMATION Please Pdnt CleadyorType Name: Clement Pappas Name (if different): Address: 125 Industrial Park writain Home (straet) NC 28758 County Henderson (City) (state) (Zip) act Person: Mr. Blake Kehoe Telephone#: (828) 693-0711 Location/Site Name: Irrigation Area No. of wells to be sampled: _ ERMIT Number: Expiration Date: 11/30/2011 rn-Discharge WQ0004797 UIC 'DES Other 'PE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑x Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other ,L ID NUMBER (from Permit): MW 8 Date sample collected: 5/28/2009 Depth: 13.90 ft. relative to top of casing Well Diameter. 2 in. h to Water Level: 8.25 ft. below measuring point Screened Interval: 3 ft.* to 13 ft.* wring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2061.4 ft. ne of water pumped/bailed before sampling: 3.0. gallons `screened interval based on well construction record )les for metals were collected unfiltered: El YES ❑ NO and field acidified: [DYES ❑ NO FIELD ANALYSES:_ PH 5.78 units Spec. Cond. Odor None Appearance WELL Temp. 13.81 eC DRY at 123 µMhos rime of sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712 IAMEfERS NOTE: Values should reflect dissolved and colloidal concentrations. COD __mg1L Nitrite (NO2) as N mg/I Pb - Lead mg/I Coliform: MF Fecal 240 1100ml Nitrate (NO3) as N 0.74 mgA Zn - Zinc mgA Coliform: MF Total /100ml Phosphorus: Total as P mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mgA Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 192 mgA AI - Aluminum mgA PH (when analyzed) units Ba - Barium mg/I TOC 6.2 mgA Ca - Calcium mg/I Chloride 24.9 mgA Cd - Cadmium mgA Arsenic mgA Chromium: Total mgA Grease and Oils mg/I Cu - Copper mgA ORGANICS: (by GC, GC/MS, HPLC) Phenol mgA Fe - Iron mgA (Specify test and method #. ATTACH LAB REPORT.) Sulfate 24.9 mgA Hg - Mercury mg/1 Report Attached? ❑ Yes (1) x❑ No (0) Speck Conductance µMhos K - Potassium mgA , method # Total Ammonia < 0.10 mgA Mg - Magnesium mgA ,method # (Ammonia Nitrogen; NH�as N; Ammonia Nitrogen, Total) Mn - Manganese mgA , method # TKN as N mgA Ni - Nickel mgA , method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOC;: mg/L Effluent Total VOCs: mg/L VOC Removal% print or type GW-59 Rev.112007 u