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HomeMy WebLinkAboutWQ0004797_Monitoring (Report)_20081216S r GW-59A,COMPLIANCE+' EFOR7' FORM Permit # WQ0004797 (Submit one each monitoring period with GW-59 forms.) Enter date monitoring results were due. (12/31/20081 Will this monitoring report (GW-59 and GW-59A) be submitted after the established due date? Was any required information missing on the GW-59 report forms? IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES identification plate, area overgrown, etc.)? Ifthe answer is "Yes", contact the Regional Ofce for guidance. 4 Are any monitored constituents equal to or above the established standards? NO If the answer to question 4 is "NO'; skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentrafion(s) exceeding standards in the space provided below. Total Organic Carbon (limit =10 mg/L) - . MW-4 = 20.5 mg/L, MW-5 = 25.9 mg/L, and MW-8 =14.4 mg/L Fecal Coliform (limit =1 /100 mL) - MW-8 = 2.2/100 mL Tetrachloroethene (limit = 0.7 pg/L) - MW-5 = 2680 pg/L, MW-6 = 3 pg/L, and MW-7 = 0.79 pg/L Trichloroethene (limit = 2.8 pg/L) - MW-5 = 534 µg/L cis-1,2-dichloroethene (limit = 70 pg/L) - MW-5 = 293 µg/L 5 For the constituents identified in question 4 above, have standards been exceeded previously for the ES NO same constituent(s) in the same well(s) in the last two years? If the answer to question 5 is "NO", skip to section S. If the answer to question 5 is "YES'; list in the space provided below, each well with constituent(s) exceeding standards, concentrations) reported, and saimp/e collection date for each occurrence ftur the Fast two years). Total Organic Carbon (limit =10 mg/L) - 05/27/08: MW-211 =10.2 mg/L, MW-6 =10.9 mg/L, and MW-8 =12.4 mg/L, and 11/13/07: MW-4 =16.7 mg/L Fecal Coliform (limit =1 /100 mQ - 11/13/07: MW-6 = 3.6/100 mL Tetrachloroethene (limit = 0.7 pg/L) - 11/13/07: MW-5 =1,150 µg/L, and 05/18/07: MW-5 = 320 µg/L Trichloroethene (limit = 2.8 µg/L) - 11/13107; MW-5 = 217 µg/L, and 05/18107: MW-5 = 47 WJL cis-1,2-dichloroethene (limit= 70 pg/L)-11/13/07: MW-5= 209 pg/L 6 are the monitoring wells listed in section 5 located at or beyond the review boundary? rT.S NO If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. if the answer is "NO", monitoring wells maybe improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this S NO groundwater quality problem? If the answer to question 7 is "YES, describe those actions in the space provided below. If the answer to question 7 is "NO" contact the Repiona/Office within 90 days an evaluation may required to determine the Impact the waste disposal system Is havino at the review and compliance boundaries surroundm this facility. Failure to do so may subject the permittee to a Notice bf V1616fioi► fines, and/orpenaldes. Total Organic Carbon (TOC) was present in samples collected from MW-4, MW-5, and MW-8. The TOC concentration in MW-7 a ri kta le to volatile organic compounds (VOCs). Based upon historic VOC and semi -volatile organic compound (SVOC) analyses, the TOL bn nt ti( ir�%O f R MW-4 and MW-8 is likely naturally occurring. No action is currently being taken with respect to fecal coliform. If subsequent sampling events indicate the continued presence_of this.- constituent in groundwater, further action may be taken. ` t "-% '- "Sai•.'.;r According to a meeting with Mr. Qu Qi of the Aquifer Protection Section on March 8, 2002, the VOCs present in MW-5, MW-6, and M' W-7 are from an offsite source uphill from MW-5, possibly the North Carolina Department of Transportation. g The -person' completing this portion (GW,--59A) of the monitoring report should sign below and submit this fonn with GW-59 forms for required wells to the address provided at the top of the current GW-59 form. �acGiovy�ie`ge"$iat tie abpye Inforlrtattpnwa` eva�ua a apc� tFte tnformabor� submiltted m this grepg%p��ahCe.RepoGW-59)is true anccomplete to the best of mGimow_led9q,' 4 i tir Fx �µ kr . Sig re of Pe ittee (or Authorized Agent) N J�^ 0 7 M9 , Date IV if j Olfice GW-59A 12/8/2003 SUBMIT FORM ON YELLOW PAPER ONLY R QUALITY; MONITORING: tEPORT FORM TY INFORMATION mease mnnr weeny or type Name: Clement Pappas Name (if different): Address: 125 Industrial Park wntain Home' (street) NC 28758 County Henderson act Person: Mr. Blake Kehoe Telephone#: (828) 693-0711 Location/Site Name: Irrigation Area No. of wells to be sampled: 6 PERMIT Number: Expiration Date: 11/30/2011 Non -Discharge WQ0004797 UIC NPDES Other TYPE OF PERMITTED OPE TION. BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery El Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pwmp ❑ Other: WELL ID NUMBER (from Permit): MW-2R Date sample collected: 11/18/2008 FIELD ANALYSES: If WELL WAS Well Depth: 14.90 ft, relative to top of casing Well Diameter: 2 in. pH 6.58 units Temp. 13.17 eC DRY at Depth to Water Level: 8.50 ft. below measuring point Screened Interval: 6 ft.* to 11 V Spec. Cond. 62 µMhos time of Measuring Point is 3.77 ft. above land surface Relative M.P. Elevation: 2063.0 ft, Odor None `` sampling, Volume of water pumped/bailed before sampling: 1.50 gallons "screened Interval Is relative to land surface Appearance �:, check hie: Sam les for metals were collected unfiltered: DYES ❑ NO and field acidified: ❑YES ❑ NO c �t sample analyzed: varies; see analytical report Laboratory Name: Pace_ Analytical Services, Inc. Certification No. 37712 , .!i 61 tAMETERS NOTE: Values should reflect, dissolved and colloidal concentrations. COD mg/I Nitrite (NO2) as N _ mg/l Pb - Lead _ mg/I \, Coliform: MF Fecal < 1.1 /loom[ Nitrate (NO3) as N 1.9 mg/I Zn - Zinc mg/l u r r Coliform: MF Total /100ml Phosphorus: Total as P mg/I Nvi� (Note: Use MINN method for highly turbid samples) Orthophosphate _ mg/l Other (Specify Compounds and Concentration Units) M. — Dissolved Solids: Total 32 mg/l AI - Aluminum mg/I pH (when analyzed) units Ba - Barium _ mg/l 4 -w TOC 4.7 mg/I Ca - Calcium _ mgll -g < Chloride 10.7 mg/l Cd - Cadmium mg/l `> Arsenic mg/1 Chromium: Total_ mg/l - Grease and Oils mg/I Cu - Copper _ mg/l r1 ORGANICS: (by GC, GC/MS, HPLC) k Phenol Sulfate mg/I 8.5 mg/l Fe - Iron, _ Hg mg/I (Specify test and method #.,kTTACH LAB REPORT -Mercury— mg/! �J Report Attached? Yes (1) Specific Conductance µMhos K - Potassium _ mg/I �0method # Z ok 1 Total Ammonia < 0.10 mg/I Mg - Magnesium mg/I method # =- (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese _ mg/I 4: j method # r TKN as N mg/l N! - Nickel mg/I , method # "----- For Remedlation Systems Only IN I• Total • • I certify that, to the best of my knowledge and belief. the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a DWp-ceiiified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. /gtent) Nanne and Title - Please prfnfo pa edA. es1 r ,, / e e 0. avorvu i rvnrvi viv YtLLuvv I'AF'tK ONLY GROUNDWATER QUALITY MONITORING: ' COMPLIANCE REPORT FORM ' FACILITY INFORMATION Please PdntCleadyorType PERMIT Number. Expiration Date: 11/30/2011 Facility Name: Clement Pappas Nan -Discharge WQ0004797 UIC Permit Name (if different):NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Mountain Home' (Street) ` NC 28758 County Henderson ❑Lagoon ❑ Remediatian: Infiltration Gallery (Cify) (State) (Zip) El Spray Field ❑ Remediation: Contact Person: Mr. Blake Kehoe Telephone#: (828) 693-0711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: WELL ID NUMBER (from Permit): MW-4 Well Depth: ' 18.60 ft. relative to top of casing Depth to Water Level: 9.76 ft. below measuring point Measuring Point is 2.43 ft. above land surface Volumecheck of water pumped/bailed before sampling: Samples for metals were collected unfiltered: DYES Date sample collected: 11/18/2008 Well Diameter: 2 in. Screened Interval: 8 ft.* to 16.1 ft.* Relative M.P. Elevation: 2064.E ft. 4.5 gallons "screened Interval is relative to lend surface ❑ NO and field acidified: ❑ YES ❑ NO f _-- _ FIELDANALYSES: pH_5.99 un� Temp. 14.39 eC Spec. Cond " 112 µMhos Odor None Appearance r�;_ r If WELL WAS DRY at time of sampling here: LABORATORY INFORMATION Date sample analyzed: varies;;see anal tical report P Y ) p Laboratory Name: Pace Analytical Services, Inc. ' 9 ; Certification No. 37712 c PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. C' COD m /I 9 Nitrite(NO2)s N ' ( x) _ _ mg/l 'i Pb -Lead mg/I Coliform: MF Fecal < 1.1 /100ml Nitrate (NO3) as N < 0.10 mg/I Zn - Zinc mg/l Coliform: MF Total /100ml _ Phosphorus: Total as P mg/l i. i , . (Note; Use MPN method for highly turbid samples) _ Orthophosphate_ mg/I ' '"° Other (Specify Compounds and Concentration Unitsj�J("�. Dissolved Solids; Total 108 mg/I Al - Aluminum _ mg/I pH (when analyzed) . -_unfits, Ba - Barium _ mg/I TOC ('20.5 rn �1 Ca - Calcium mg/l Chloride `J.3 mg/I Cd - Cadmium _ mg/I Arsenic mg/l Chromium: Total mg/I Grease and Oils mg/I Cu - Copper_ mg/l ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/I Fe - Iron mg/l (Specify test and method TACH LAB REPORT.) Sulfate 19.E mg/I Hg - Mercury mg/I _#. Repo Attached? L7 Yes (1) ® No (0) Specific Conductance µMhos K - Potassium mg/I 9 e S method # .6 - O Total Ammonia < 0.10 mg/I (Ammonla'Nitrogen; NH3as N; Ammonia Nitrogen, Total) Mg - Magnesium _ m /l 9 method # Mn -Manganese mg/l method # TKN as N mg/I Ni - Nickel mg/i _ method # _ III RAmneff2finn c..eiw...... ^-I.. IA —a 1 _ n F _•••� \---•^-"••��"-•��Y- Y. I11 UCIn IULU! VVVS. mg/L tttluent Total VOCs: mg/L VOC Removal% nittee (or Authorized Agent) Name and Title - Plea a print or type Signature of Perry d(or uthonze Agent) (Date) t3W-59 Rev.1/2007 SUBMIT FORM ON YELLOW PAPER ONLY TER QUALITY MONITORING: E REPORT FORM Name: Clement PaDoas Name (if different): Address: 125 Industrial Park iuntain Home' (S°°°`i NC 28758 County Henderson (City) - M.f.1 n 1 act Person; Mr. Blake Kehoe Telephone#: (828) 693-0711 Location/Site Name: Irrigation Area No. of wells to be sampled: 6 L ID NUMBER (from Permit): MW-5 Date sample collected: 11/18/2008 Depth: 18.44 ft. relative to top of casing Well Diameter: 2 in. 1 to Water Level: 11.59ft. below measuring point Screened Interval: 9 ft.* to 19 ft.* iuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2086.4 ft_ ne of water pumped/bailed before sampling: 3.75 gallons *screened Interval based on well construction record )les for metals were collected unfiltered: ❑YES ❑ NO and field acidified: ❑YES ❑ No ERMIT Number: Expiration in -Discharge, WQ0004797 UIC ~_ 'DES Other PE OF PERMITTED OPERATION BEING ❑ Lagoon ❑ Remedit El Spray Field . ❑ Remedil ❑ Rotary Distributor ❑ Land Ap ❑ Water Source Heat Pump ❑ Other: _ FIELD PH 5.8Lu its Spec. Cond. Odor None Appearance --- Temp. 149 s sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical tAMETERS NOTE: Values,shouid reflect dissolved and colloidal concentrations. Services, Inc. Certification No. 377 -- COD mg/I Nitrite (NO2) as N mg/I Pb - Lead mg/I Coliform: MF Fecal < 1.1 /100ml Nitrate (NOa) as N 0.17 mg/I Zn - Zinc mg/I Coliform: MF Total /100ml Phosphorus: Total as P mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mg/1 Other (Specify Compounds and Concentra Dissolved Solids: Total 80 mg/1 Al - Aluminum mg/I PH (when analyzed) urti Ba - Barium mg/I TOC !l Ca - Calcium _ mg/I Chloride 47.6 mg/I Cd - Cadmium _ mg/I Arsenic mg/I Chromium: Total_ mg/1 Grease and Oils Infiltration Gallery ion of Sludge If WELI WAS oC DRY at time of here: ❑ o- c Unitsy.�__, i mg/i Cu - Copper mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/1 Fe - Iron mg/1 (Specify test and method, CH LAB REPORT.) Sulfate < 5.0 mg/l Hg - Mercury _ mg/I .#. Report Attached? 21 Yes (1) 1� No (0) k SpecConductance µMhos K - Potassium mg/I r Y oc S method # Total Ammonia < 0.10 mg/I (Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total) Mg - Magnesium mgA _6a500 method # Mn - Manganese _ mg/l method # TKN as N mg/I Ni - Nickel — mg/I _ _ method # For Ramadiatinn gVafn—. n..r., iA&d, _k r _. e___ ._,. Perm ittee (.,,Authorized Agent) Name and Tit e - Please Pint.,tyPe GW-59 Rev.1/2007 ,ors trrluent iotai Vacs: Agent) mg/L VOC Removal% RI IRMIT ROPRA nM VFt I r)MI oneGp nnu v GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM ' a FACILITY INFORMATION Please Print Clearly or Type PERMIT Number:' Expiration Date: 11/30/2011 Facility Name; Clement Pappas � Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 125 Industrial Park TYPE OF PERMITTED OPERATION BEING MONITORED Mountain Home' (Streel) NC 28758 County Henderson ❑ Lagoon ❑Remediation: Infiltration Gallery (city) (S1e1e) (zip) ❑x Spray Field ❑ Remediation: Contact Person: Mr. Blake Kehoe Tele honem (828) 693-0711 p ❑ Rotary Distributor ❑Land Application of Sludge Well Location/Site Name; Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other. from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-6 Date sample collected; 11/18/2008 FIELD ANA`YSES: WAS ell Depth: 11.54 ft. relative to top of casing Well Diameter: 2 in. pH 6.3`I'unIfeol Temp. 12.02 °C DRY at Depth to Water Level: 7.38 ft. below measuring point Screened Interval: 5 ft.t to 10 ft.Spec. Cond. 38 uMhos time of Measuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2061.9 ft, Odor None sampling, Volume cif water pumped/baiied`before sampling: 0.75 gallons "screened interval based on well constructIon record Appearance _ _,.. check here: Sam les for metals were collected unfiltered: ❑YES ❑ NO and field acidified: ❑ YES ❑ NO ❑ - LABORATORY INFORMATION Date sample analyzed: varies; see analytical report r Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. c COD .--m Nitrite (NO2) as N _ mgll Pb -Lead mg/l Coliform: MF Fecal (> 2�ffml Nitrate (NO3) as N < 0.10 mg/I Zn - Zinc mg/I Coliform: MF Total /100ml _ Phosphorus: Total as P mg/I (Note: Use MPN method for highly turbid samples) _ Orthophosphate mg/I LLJ Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 36.0 mg/i AI - Aluminum mg/I pH (when analyzed) units Ba - Barium_ mg/I - TOC 7.4 mg/l Ca - Calcium _ mg/I Chloride 7.6 mg/I Cd•- Cadmium mg/I Arsenic mgll Chromium: Total mg/I Grease and Oils mg/I Cu - Copper mg/1 ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/l Fe - Iron mg/I (Specify test and method #. AZTACH LAB REPORT.) Sulfate < 5.0mg/I Hg - Mercury mg/I Report Attached? Yes (1) ® No (0) Specific Conductance µMhos K - Potassium mg/I V0C 5 method # 6'2.30i� Total Ammonia < 0.10 mg/l Mg - Magnesium mg/l method # (Ammonia Nitrogen; NH3ae N; Ammonia Nitrogen, Total) Mn - Manganese mgli method # TKN as N mg/I Ni - Nickel mg/I method.# For Remediation Systems Only (Attach Lab Reports): ' Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% I certify that. to the best of my knowledge d belief, the information submitted . .laboratory.are..r.... in this report -.-War f_lca... .. --- GW-59 Rev.1/2007 ortyps (or l.;i.,J'cb'�' l�. auarvu i ruKivi uiv Y" I DVV PAPER ONLY OUNDWATER QUALITY MONITORING: MPLIANCE REPORT FORM ITY INFORMATION mease rnnt creanyorType Name: Clement Pappas Name (if different): Address: 125 Industrial Park writain Home' (Sff8C1) NC 28758 County Henderson act Person: Mr. Blake Kehoe Telephone#: (828) 693-0711 Location/Site Name: Irrigation Area No. of wells to be sampled:, PERMIT Number: Expiration Date: 11/30/2011 Non -Discharge WQ0004797 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ' ❑ Remediation: Infiltration Gallery 261 Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: LL ID NUMBER (from Permit): MW-7 Date sample collected: 11/18/2008 FIELD A . A YSES: I Depth: 16.72 ft. relative to top of casing Well Diameter: 2 in. pH .64 unite Temp. 14.19 °C th.to Water Level: 11.63 ft. below measuring point Screened Interval: 5 ft.* to 15 ft.* Spec. Cont. 36 µMhos isuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2062.7 ft. Odor None ime of water pumped/bailed.before sampling: 2.75 gallons *screened Interval based on well construction record Appearance iples for metals were collected unfiltered: ❑YES (ORATORY INFORMATION ❑ NO and field acidified: ❑ YES ❑ NO sample analyzed:_ varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712 L4METERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/I Nitrite (NO2) as N mg/I Pb - Lead mg/I ` Coliform: MF Fecal < 1.1 /100ml Nitrate (NO3) as N_ 1.7 mg/I Zn - Zinc mg/I Coliform: MF Total /100ml (Note: Use MPN method for highly turbid samples) Phosphorus: Total as P _ mg/I Orthophosphate_.__, mg/l Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 30.0 mg/I Al - Aluminum _ mg/l PH (when analyzed) units Ba - Barium _ mg/I TOC 7.5 mg/I Ca - Calcium mg/I >j Chloride %. % A1&mg/i Cd - Cadmium _ mg/I Arsenic mg/I Chromium: Total_ mg/I Grease and Oils mg/I Cu - Copper _ mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol _ mg/I Fe - Iron mg/I (Specify test and method #. ATTACH LAB REPORT,) Sulfate < 5.0 mg/I Hg - Mercury mg/I Report ttached? 2Yes (1) 91 No (0) Specific Conductance µMhos K - Potassium mg/I VOCS method # 4,7 Yo,D Total Ammonia < 0.10 mg/1 (Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total) Mg - Magnesium mgA method # Mn - Manganese mgA method # TKN as N mg/l Ni - Nickel _ mg/l method # at Of uvvaa Rev.1/2007 RI IrthA1T POORA nk1 VCt t nrAr t3Amcm neu v GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM im , FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 11/30/2011 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 125 Industrial Park (street) TYPE OF PERMITTED OPERATION BEING MONITORED Mountain Home a NC 28758 Count y Henderson (city) El Lagoon ❑Remediation: Infiltration Gallery (Stale) (zip) El Spray Field ❑ Remediation: Contact Person: Mr. Blake Kehoe Telephone* (828) 693-0711 p ❑ Rotary Distributor El Land Application of Sludge Well LocatiordSite Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION WELL ID NUMBER (from Permit): MW-8 Date sample collected: 11/18/2008 FIELD ANALYSES . If WELL AS Well Depth: 13.90 ft. relative to top of casing Well Diameter. 2 in. pH 6�11 u ' Temp. 12.32 eC DRY at Depth to Water Level: 11.11 ft, below measuring point Screened Interval: 3 ft.* to 13 ft.* Spec. Cond. 131 µMhos time of MeasuringPoint is 3.00 ft. above land'surface Relative M.P. Elevation. 2061.4 ft. " -- Odor None sampling, olume of water pumped/bailed before sampling: 1.50 gallons *screened Interval based on well construction record Appearance cfteck here: Samples for metals were collected unfiltered: --El YES ❑ NO and field acidified: ❑ YES ❑ NO ❑ LABORATORYINFORMATION Date sample analyzed: varies; see analytical report Laboratory Name: Pace Analytical Services, Inc. Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg./I Nitrite (NO2) as N mg/I j++` Pb - Lead mg/l Coliform: MF Fecal 2.2 / oonr'I)I Nitrate (NO3) as N < 0.10ng/I Zn - Zinc mg/l Coliform: MF Total /100ml Phosphorus: Total as P mg/I -� (Note: Use MPN method for highly turbid samples) Orthophosphate.' mg/I =� ° e1 Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 118 mg/I All - Aluminum mg/I pH (when analyzed) units Be - Barium mg/I TOC 14. g/I/1 Ca - Calcium mg/l Chloride 17.2 mg/I Cd - Cadmium mg/I Arsenic mg4 Chromium: Total mg/I Grease and Oils mg/I Cu - Copper, mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/l . Fe - Iron mg/I (Specify test and method #. LAB REPORT.) Sulfate 21.5 mg/I Hg - Mercury mg/l YeEACH Report Attached? s (1) ® No (0) Specific Conductance µMhos K- Potassium mg/l �� (' S method # Total Ammonia < 0.10 mg/I (Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total) Mgt- Magnesium mg/l method # Mn - Manganese m /I 9 method # TKN as N mg/I Ni - Nickel mg/I method # For Remedlation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% .. • .. .. .._ 01 Permittee (or Authorized Agent) Name and Title - Please p Int or type Signature of Pc&ltlee (or Authorized Agent) (Date) GW-69 Rev.1/2007 •r � ceAnalyiical ► WWWpWd&l scorn December 02, 2008 Mr. Chris Gilbert Altamont Environmental 50 College Street Asheville, NC 28801 RE: Project: CLEMENT PAPPAS 11/18 Pace Project No.: 9232546 Pact Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (B28)254-7176 Pace Anaytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 Dear Mr. Gilbert: Enclosed are the analytical results for sample(s) received by the laboratory on November 18, 2008. The results relate only to the samples. included in this report. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All Microbiological analyses were performed at the laboratory where the samples were received. If you have any questions concerning this report, please feel free to contact me. Sincerely, Lorri Patton lorri.patton@pacelabs.com Project Manager Enclosures (704)875-9092 REPORT OF LABORATORY ANALYSIS Page 1 of 29 This report shag not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. � 7 y ® Pace Analytical Services, Inc. Pace Analytical Services, Inc. Analyiical 2225 Riverside Dr. 961K) fCincey Ave_ Suite 100 ace W*Wpacews com Asheville. NC 28804 Huntersvitte, NC 28078 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: CLEMENT PAPPAS 11/18 Pace Project No.: 9232546 Sample: MYY-2R Parameters Lab ID: 9232646001 Collected: 11118/0613:58 Received: 11/18/0816:53 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6230D GCV Analytical Method: 6230D W Benzene ND ug/L 0.50 1 11/23/08 0026 71-43-2 Bromobenzene ND ug/L 0.50 1 11/23/08 0025 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/23/08 00:25 74-97-5 Bromodichloromethane ND ug/L 0.50- 1 11/23/08OD-25 75-27-4 Bromofonn ND. ug/L 0.50 1 11/23/DS 0025 75-25-2 Bromomethane ND ug/L 0.50 1 111=08 00:25 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/23/08 00:26 104-51-8 sec-Bhylbenzene ND ug/L 0.50 1 11/23/08 00.26 135-98-8 tert-Buylbenzene ND ug/L 0.50 1 11/23/08 00:26 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/23/08 0D25 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/23/08 00,25 108-90-7 Chloroethane ND ug/L 0.50 1 11/23/08 00:25 75-00-3 Chloroform ND uglL 0.50 1 11/23/D8 00:25 67-66-3 Chloromethane ND ug/L 0.50 1 11/23/08 00:25 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/23/08 00:25 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/23/08 00:25 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 11/23/08 00:25 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/23/08 00:25 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/23/08 00:25 106-93-4 Dibromomethane ND ug/L 0.50 1 11/23/08 D025 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 1 11/23/08 00:25 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 1 11/23/08 00:25 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 1 11/23/08 00:25 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/23/08 00:25 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/23/08 0025 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/23/08 00:25 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/23/08 0025 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/23/08 D0:25 156-59-2 Vans-1,2-Dichloroethene ND ug/L 0.50 1 11/23/08 00:25 156-60-5 1,2-Dichtoropropane ND ug/L 0.50 1 11/23/08 00:25 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/23/08 00:25 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/23/08 00:25 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/23/08 00:25 563-58-0 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/23/08 00:25 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.5D 1 11/23/08 00:25 10061-02-6 Diisopropyl ether ND ug/L 0.50' 1 11/23/08 00:26 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/23/08 00:26 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/23/08 00:25 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/23/08 0026 98-82-8 p-Isopropyltoluene ND ug/L 0.50 1 11/23/08 00:26 99-87-6 Methylene Chloride ND ug/L 2.0 1 11/23/08 00:25 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/23/08 00:26 1634-04-4 Naphthalene ND ug/L 2.0 1 11/23/08 00:26 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/23/08 00:26 103-65-1 Styrene ND ug/L 0.50 1 11/2310800:26 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/2310800:25 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/23/08 00:25 79.34-5 Date: 12/02/2008 02:15 PM REPORT OF LABORATORY ANALYSIS Page 3 of 29 This report shall not be reproduced, except in fult, without the written consent of Pace Analytical Services, Inc- ® Pace Analytical Services, Inc. Pace Analytical ServIem, Inc. ceAnaljftal 2225 Riverside Dr. 9800 Kincey Ave. SOD 100 www4welsbsawn Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875.9092 ANALYTICAL RESULTS Project CLEMENT PAPPAS 11118 Pace Project No.: 9232546 Sample: MW 2R Parameters Lab ID: 9232546001 Collected: 11/18/0813:58 Results Units Report Limit DF Received: 11/18/0815:53 Matra: Water Prepared Analyzed CAS No. Qua[ 6230D GCV Analytical Method: 6230D W Tetrachloroethene ND ug/L 0.50 1 11/23/08 00:25 127-18-4 Toluene ND ug/L 0.50 1 11/23/08 0026 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/23/086025 87-61-6 1,2,4 Trichlorobenzene ND ug/L 2.0 1 11/23/08 00:25 120-82-1 1,1,1 Trichloroethane ND ug/L 0.50 1 11/23/08 00:25 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/23/08 00:25 79-00-5 Trichloroethene ND ug/L 0.50 1 11/23/08 00:25 79-01-6 Trichlorofluoromethane ND ug/L 0.50 1 11/23/0800:26. 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/23/0800:25 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/23/08 00:26 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/23/08 00:26 108-67-8 Vinyl chloride ND ug/L 0.50 1 11/23/08 0025 75-01-4 m&p-Xy[ene ND ug/L 0.50 1 11/23/08 00:26 1330-20-7 o-Xylene ND ug/L 0.50 1 11/23/08 00:26 95-47-6 1-Chloro-3-fluorobenzene (S) 99 °% 60-140 1 11/23/08 0025 625-98-9 92210E Fecal Collform, MPN . Analytical Method: SM 9221C/E Fecal Collfomts, MPN < 1.1 MPN/100mL 1.0 1 11/18/0817:20 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 32.0 mg/L 20.0 1 11/24/0815:57 360.1 Ammonia Analytical Method: EPA 350A Nitrogen, Ammonia ND mg/L 0.10 1 11122/0810:46 7764.41-7 363.2 Nitrogen, NO2IM03 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 1.9 mg/L 0.10 1 11/18/08 23:28 45W Chloride Analytical Method: SM 4500-CI-E Chloride 10.7 mg/L 5.0 1 11/2410811AI 16887-U0-6 5310E TOC Analytical Method: SM 5310B Total Organic Carbon 4.7 mg/L 1.0 1 11/26/0818:20 7440-44-0 ASTM D516-90 Sulfate Water Analytical Method: ASTM D516-90 Sulfate 8.5 mg/L 5.0 1 11/2110812:15 14808-79-6 Date: 12/02/2008 02:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Setvices, Inc.. • Page 4 of 29 Pace Analytical Services, Inc. Pace Analytical Services, Inc. Q ►�'r ,,,,/� celk CII ice 2225 Riverside Dr. 9800 KinceyAve. Suite 100 Asheville, NC 281104 Huntersville, NC 28078 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project CLEMENT PAPPAS 11/18 Pace Project No.: 9232546 Sample: MW-4 Parameters Lab ID: 9232646002 Collected, 11/1810813:36 Received: 11/18/0815:53 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6230D GCV Analytical Method: 6230D W Benzene ND ug/L 0.50 1 11/23/08 01:07 71-43-2 Bromobenzene ND ug/L 0.50 1 11/23/08 01:06 108-864 Bromochloromethane ND ug/L 0.50 1 11/23/08 01:06 74-97-5 Bromodichloromethene ND ug/L 0.50 1 11/23/08 01:06 75-27-4 Bromoform ND ug/L 0.50 1 11/23/08 01:06 75-25-2 Bromomethane ND ug/L 0.50 1 11/23/08 01:06 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/23/08 01:07 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/23/08 01:07 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/23/08 01:07 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/23/08 01:06 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/23/08 01:06 10B-90-7 Chloroethane ND ug/L 0.50 1 11/23/08 01:06 .75-00-3 Chloroform ND ug/L 0.50 1 11/23/08 01:06 67-66-3 Chloromethane ND ug/L 0.50 1 11/23/08 01:06 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/23/08 01:06 95-49-B 4-Chlorotoluene ND ug/L 0.50 1 11/23/08 01:06 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 11/23/08 01:06 9612-8 Dibromochloromethane ND ug/L 0.50 1 11/23/08 01:06 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/23/08 01:06 106-934 •Dibromomethane ND ug/L 0.50 1 11/23/08 01.06 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 1 11/23/08 01:06 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 1 11/23/08 01:06 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 1 11/23/08 01:06 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/23/08 01:06 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/23/08 01:06 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/23/08 01:06 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/23/08 01:06 75-354 cis-1,2-Dichloroethene ND ug/L 0.50 1 1123/08 01:06 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/23/08 01:06 156-60-5 1,2-Dichioropropane ND ug/L 0.50 1 11/23/08 01:06 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/23/08 01:06 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/23/08 01:06 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/23/08 01:06 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/23/08 01:06 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/23/08 01:06 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/23/08 01:07 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/23/08 01:07 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/23/08 01:06 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/23/08 01:07 98-82-8 p4sopropyitoluene ND ug/L 0.50 1 11123/08 01:07 99-87-6 Methylene Chloride ND ug/L 2.0 1 11/23/08 01:06 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/23/08 01:07 1634-04-4 Naphthalene ND ug/L 2.0 1 1123/08 01:07 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/23/08 01:07 1d3-65-1 Styrene ND ug/L 0.50 1 11/23/08 01:07 10042-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/2310801:06 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/23/08 01:06 79-34-5 Date:12/02/2008 02:15 PM REPORT OF LABORATORY ANALYSIS Page 5 of 29 This report shall not be reproduced, except in full, without the written consent of Pare Analytical Services, Inc.. �'Ziu - -(��aceAn* ical e wo w.psceletrscom Project CLEMENT PAPPAS 1ill 8 Pace Project No.: 9232546 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NG 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 10D Huntersville. NC 28078 (704)875.9092 Sample: KW-4 Lab ID: 9232646002 Collected: 11/18/0813:36 Received: 11/18/0815:53 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6230D GCV Analytical Method: 6230D W Tetrachloroethene ND ug/L 0.50 1 11/23/08.01:06 127-184 Toluene ND ug/L 0.50 1 11/23/08 01:D7 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/23/08 01:06 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/23/08 01:06 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 11/23108 01:06 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/23/08 01-.06 7940D-5 Trichloroethene ND ug/L 0.50 1 11/23/08 01:06 79-01-6 Trichlorofluoromethane ND ug/L 0.50 1 11/23/08 01:06 75-69-4 1,2,3-Tdchloropropane ND ug/L 0.50 1 11/23/08 01:06 96-18-4 1,2,4-Trimethylbenzene ND uglL 0.50 1 11/23/08 01:07 95-63-6 1;3,5-Trimethylbenzene ND ug/L 0.50 1 11/23/08 01:07 108-67-8 Vinyl chloride ND ug/L 0.50 1 11/23/08 01.06 75-01-4 m&p-Xylene ND ug/L 0.50 1 11/23/08 01:07 133D-20-7 o-Xylene ND ug/L 0.50 1 11/23/08 01:07 95-47-6 1-Chloro-3-fluorobenzene (S) 101 °% 60-140 1 11/23/08 01:06 625-98-9 92210E Fecal Coliform, MPH Analytical Method: SM 9221C/E Feral Colifomts, MPN 1.1 MPN/100ml- 1.0 1 11/1810817:20 2640C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 108 mg/L 20.0 1 11/24/0815:57 360.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 11122/0810:46 7764-41-7 3512 Nitrogen, NO2IN03 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate ND mg/L 0.10 1 11/18/08 23:28 46W Chloride Analytical Method: SM 45OD-CI-E Chloride 9.3 mg/L 5.0 1 11/2410811:41 16887-00.6 6310B TOC Analytical Method: SM 5310B Total Organic Carbon 20.5 mg/L 1.0 1 1112610818:39 7440-44-0 ASTM D516-90 Sulfate Water Analytical Method: ASTM D516-90 Sulfate 19.6 mg/L 5.0 1 11/21/0812:15 14808-79-8 Date: 12/02/2008 02:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 29 ` 2 Pace Anaytical Services, Inc. Pace Analytical Services, Inc. ��/ • t�W7/i'tiQ1 2225 Riverside ter. 9800 KlnceyAve. Suite 100 www, bbs.com. Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-W92 ANALYTICAL RESULTS Project CLEMENT PAPPAS 11/18 Pace Project No.: 9232546 f Sample: NW-S Lab ID: 9232546003 Collected: 11/18/0811:29 Received: 11/18/0815:53 Matrix: Water Parameters Results Units Report Limit DF Peepared -Analyzed CAS No. Qual 6230D GCV Analytical Method: 6230D W y Benzene ND ug/L 25.0 50 12/02/08 11:13 71-43-2 - Bromoberizene ND ug/L 25.0 50 1210210811:12 108-86-1 Bromochloromethane ND ug/L 25.0 50 12/0210811:12 74-97-5 Bromodichloromethane ND ug/L 25.0 50 12/0210811:12 75-27-4 Bromoform ND ug/L 25.0 50 12/02/08 11:12 75-25-2 '-, Bromomethane ND ug/L 25-0 50 12/02/0811:12 74-83-9 n-Butylbehzene ND ug/L 25.0 50 12/0210811:13 104-51-8 i sec Butylbenzene ND ug/L 25.0 50 1210210811:13 135-98-8 tert-Butylbenzene ND ug/L 25.0 50 12/0210811:13 98-06-6 Carbon tetrachloride ND ug/L 25.0 50 1210210811:12 56-23-5 Chlorobenzene ND ug/L 25.0 50 12/02/08 11:12 108-90-7 Chloroethane ND ug/L 25.0 50 1210210811:12 75-00-3 Chloroform ND ug/L 25.0 50 12/0210811:12 67-66-3 Chloromethane ND ug/L 25.0 50 1210210811:12 74-87-3 2-Chlorotoluene ND ug/L 25.0 50 12102/0811:12 95-49-8 4-Chlorotoluene ND ug/L 25.0 50 12/02/08 11:12 10643-4 1,2-Dibromo-3-chloropropane ND ug/L 100 50 12/0210811:12 96-12-8 Dibromochloromethane ND ug/L 25.0 50 12/0210811:12 124-48-1 s 1,2-Dbromoethane (EDB) ND ug/L 25-0 50 12/02/08 11:12 106-93-4 Dibromomethane ND ug/L 25.0 50 12/0210811.12 74-95-3 1,2-Dichlorobenzene ND ug/L 50.0 50 12102/0811:12 95-50-1 1,3-Dichlorobenzene ND ug/L 50.0 50 12/0210811:12 541-73-1 1.4-Dichlorobenzene ND ug/L 50.0 50 12/02/08 11:12 106-46-7 Dichlorodifluoromethane ND ug/L 25.0 50 12/02/0811:12 75-71-8 a 1,1-Dichloroethane ND ug/L 25.0 50 12/0210811:12 75-34-3 1,2-Dichloroethane ND ug/L 25.0 50 12/0210811:12 l(7-O6-2 1,1-Dichloroethene ND ug/L 25.0 50 1210210811:12 75-35-4 cis-1,2-Dichloroethene �­293, ug1L 25.0 50 12/0210811:13 156-59-2 trans-1,2-Dfchloroethene ND ug/L 25.0 50 12/02/08 11:12 156 60 5 3 1,2-Dichloropropane ND ug/L 25.0 50 12/02/08 11:12 78-87-5 1,3-Dichloropropane ND ug/L 25.0 50 12/0210811:12 142-28-9 i 2,2-Dichloropropane ND ug/L 25.0 50 12/02/0811:12 594-20-7 1,1-Dichloropropene ND ug/L 25.0 50 12/02/08 11:12 563-58-6 cis-1,3-Dichloropropene ND ug/L 25.0 50 12/02/0811:12 10061-01-5 trans-1,3-Dichloropropene ND ug/L 25.0 50 12/02/0811:12 10061-02-6 Di(sopropyi ether ND ug/L 25.0 50 12/02/68 11:13 108-20-3 Ethylbenzene ND ug/L 25.0 50 12/0210811:13 100-41.4 s s Hexachloro-1,3-butadiene ND ug/L 100 50 12/0210811:12 87-68-3 Isopropylbenzene (Cumene) ND ug/L 25.0 50 12/02/08 11:13 98-82-8 p4sopropyltoluene ND ug/L 25.0 50 1210210811:13 99-87-6 Methylene Chloride ND ug/L 100 50 12/02/0811:12 75-09-2 Methyl-tert-butyl ether ND ug/L 25.0 50 12102/0811:13 1634-04-4 Naphthalene ND ug/L 100 50 12/0210811:13 91-20-3 n-Propylbenzene ND ug/L 25.0 50 12/0210811:13 103-65-1 Styrene ND ug1L 25.0 50 12/0210811:13 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 25.0 50 12/02/0811:12 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 25.0 50 12/0210811:12 79-34-5 3 Date: 12/02/2008 02:15 PM REPORT' OF LABORATORY ANALYSIS Page 7 of 29 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. cekdytical. www.pKewmcorn Project: CLEMENT PAPPAS 11/18 Pace Project No.: 9232546 PaceAna"cal Services, Inc. 2226 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800KInceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-5 Lab ID: 9232546003 Collected: 11118/0811:29 Received: 11/18/0815:53 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6230D GCV Analytical Method: 6230D W Tetrachloroethene C" 2680 uglL� 25.0 50 12/0210811:13 127-18-4 Toluene ` ND ug/L 25.0 50 12/02/0811:13 108-88-3 1,2,3-Trichlorobenzene ND ug/L 100 50 12/02/0811:12 87-61-6 1,2,4-Trichlorobenzene ND ug/L 100 50 12/02/08 11:12 120-82-1 1,1,1-Trichloroethane ND ug/L 25.0 50 12/02/0811:12 71-55-6 1,1,2-Trichloroethane ND ug/L 25.0 50 12/0210811:12 79-OD-5 Trichloroethene 534 ug/L 25.0 50 12/02/0811:12 79-01-6 Trichlorofluoromethane ND ug/L 25.0 50 12102/0811:12 75-69-4 1,2,3-Trichloropropane ND ug/L 25.0 50 12102/0811:12 96-18-4 1,2,4-Trimethylbenzene ND ug/L 25.0 5D 12/02/0811:13 95-63-6 1,3,5-Trimethylbenzene ND ug/L 25.0 50 1210210811:13 108-67-8 Vinyl chloride ND ug/L 25.0 50 12/02/0811:12 75-01-4 m&p-Xylene ND ug/L 25.0 50 12/02/0811:13 1330-20-7 o-Xylene ND ug/L 25.0 50 12102/0811:13 95-47-6 1-Chloro-3-fluorobenzene (S) 119 % 60-140 50 12/0210811:12 625-98-9 92210E Fecal Coliform, MPN Analytical Method; SM 9221C/E Fecal Colifomts, MPN < 1.1 MPN/100mL 1.0 1 11/18/081720 2640C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 80.0 mg/L 20.0 1 11124/0815:67 360.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.1D 1 11/22/0810.47 7764-41-7 353.2 Nitrogen, NO2IN03 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 0.17 mg/L 0.10 1 11/181082328 4600 Chloride Analytical Method: SM 4500-CI-E Chloride 47.6 mg/L 10.0 2 11/24/0811:55 16887-00-6 6310B TOC Analytical Method: SM 5310B Total Organic Carbon 25.9 mg/L 1.0 1 11/26/0818:57 7440-44-0 ASTM D516-90 Sulfate Water Analytical Method: ASTM D516-90 Sutiate ND mg/L 5.0 1 11/21/0812:27 14808-79-8 Date: 12/02/2008 02:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. eea,e� Page 8 of 29 ® Pace Analytical Services, Inc. Pace Analytical Services, Inc. Ana1/1ti1 al 2225 Riverside Dr. 9600 Kincey Ave. Suite 100 www c" Com Asheville, NC 28804 Hurderswlie, NC 28078 (828)254-7176 (704)875-8092 ace ANALYTICAL RESULTS Project: CLEMENT PAPPAS 11/18 Pace Project No.: 9232546 Sample: NW-6 Parameters Lab ID: 9232546004 'Collected: 11118/081420 Received: 11/18/0815:53 Matrix: Water Results Units Report limit DF Prepared Analyzed CAS No. Qual 6230D GCV Analytical Method: 623DD W Benzene ND ug/L 0.50 1 11/23/08 02:30 71-43-2 Bromobenzene ND ug/L 0.50 1 11/23/08 0229 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/23/08 02:29 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/23/08 0229 75-27-4 Bromoform ND ug/L 0.50 1 11/23/08 0229 75-25-2 Bromomethane ND ug/L 0.50 1 11/23/08 02:29 74-83-9 n-Buylbenzene ND ug/L 0.50 1 11/23/08 02:30 104-51-8 sec-Bhylbenzene ND ug/L 0.50 1 11/23/08 02:30 •135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/23/08 02:30 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/23/08 0229 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/23/08 02:29 108-90-7 Chloroethane ND ug/L 0.50 1 11/23/08 02:29 75-00-3 Chloroform ND ug/L 0.50 1 11/23/08 0229 67-66-3 Chloromethane ND ug/L 0.50 1 11/23/08 02:29 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/23/08 02:29 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/23/08 0229 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 11/23/08 02:29 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/23/08 02:29 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/23/08 02:29 106-93-4 Dibromomethane ND ug/L 0.50 1 11/23/08 02:29 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 1 11/23/08 02:29 95-50-1 1,3-Dichlorobenzens ND ug/L 1.0 1 11/23/08 02:29 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 1 11/23/08 02:29 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/23/08 02:29 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/23/08 02:29 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/23/08 02:29 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/23/08 02:29 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/23/08 02:29 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/23/08 02:29 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/23/0602:29 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/23/08 02:29 142-28-9 22-Dichl6ropropane ND ug/L 0.50 1 11/23/08 02:29 594-20-7 1,1-Dichloropropene ND uglL 0.50 1 11/23/08 02:29 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/23/08 02:29 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/23/08 0229 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/23/08 02:30 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/23/08 02:30 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/23/08 02:29 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1. 11/23/08 02:30 98-82-8 p-Isopropyltoluene ND ug/L 0.50 1 11/23/08 02:30 99-87-6 Methylene Chloride ND ug/L 2.0 1 11/23/08 0229 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/23/08 02:30 1634-04-4 Naphthalene ND ug/L 2.0 1 11/23/08 02:30 91-20-3 n-Propylbeniene ND ug/L 0.50 1 11/23/08 02:30 103-65-1 Styrene ND ug/L 0.50 1 11/23/08 02:30 100.42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/23/08 02:29 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/23/08 02:29 79-34-5 Date: 12/02/2008 02:15 PM REPORT OF LABORATORY ANALYSIS Page 9 of 29 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. • ` aceAnalyiical' wwwpaaeb"com Project: CLEMENT PAPPAS 11118 Pace Project No.: 9232546 Pace Analytical Services, Inc. 2225 Riverside Dr. Ashevgle, NC 28BD4 (828)254-7176 ANALYTICAL RESULTS PaceAnalitlal Services, Inc. 9800KinceyAve. Suite 100 Hunlersville, NC 28078 (704)876-9092 Sample: MW-8 LWID: 9232646004 Collected: 11/18/0814:20 Received: 11/18/0815:53 Matrix- Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[ 6230D GCV Analytical Method, 230D W Tetrachloroethene A 0.50 1 11/23/08 0229 127-18-4 Toluene ND ug/L 0.50 1 11/23/08 02:30 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/23/08 0229 87-61-6 1,2,4-Tdchlorobenzene ND ug/L 2.0 1 11/23/08 0229 120-82-1 1,1,1 Trichloroethane ND ug/L 0.50 1 11/23/08 02:29 71-55-6 1,1,2 Trichloroethane ND ug/L 0.50 1 11/23/08 02:29 79-00.5 Trichloroethene ND ug/L 0.50 1 11/23/08 02:29 79-01-6 Trichlorofluoromethane ND ug/L 0.50 1 11/23/08 02:29 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/23/08 0229 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/23/08 02:30 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/23/08 02:30 108-67-8 Vinyl chloride ND ug/L 0.50 1 11/23/08 02:29 75-01.4 m&p-Xylene ND ug/L 0.50 1 11/23/08 02:30 1330-20-7 o-Xylene ND ug/L 0.50 1 11/23/08 02:30 95-47-6 1-Chloro-3-fluorobenzene (S) 107 % 60-140 1 11/23/08 02:29 625-98-9 92210E Fecal Colifonn, MPN Analytical Method: SM 9221C/E Fecal Col"lfonns, MPN > 23 MPN1100mL 1.0 1 11/1810817:20 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 36.0 mg/L 20.0 1 1112410815:58 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 11122/0810:50 7764-41-7 353.2 Nhrogen, NO2/NO3 unpres Analytical Method: EPA 3532 Nitrogen, Nitrate ND mg/L 0.10 1 11/18/08 23:28 4600 Chloride Analytical Method: SM 4500-CI-E Chloride 7.6 mg/L 5.0 1 11/24/0811:42 16887-00-6 631OB TOC Analytical Method: SM 5310B Total Organic Carbon 7.4 mg/L 1.0 1 11/26/0819:10 7440-44-0 ASTM D616-90 Sulfate Water Analytical Method: ASTM D516-90 Sulfate ND mg/L 5.0 1 11121/081227 14808-79-8 Date:12/0212008 02:15 PM REPORT OF LABORATORY ANALYSIS Page 10 of 29 This report shag not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. r' • ' aceAnOcal www.pawlMscan Project- CLEMENT PAPPAS 11/18 Pace Project No.: 9232546 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 KinceyAve. Sine too Huntersville, NC 28078 (704)875-9092 Sample: NW-7 Lab ID: 92326MOS Collected: 11/18/0812:15 Received: 11/18/0815:63 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Oual 6230D GCV Benzene Bromobenzene Bromodhloromethane Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chiorotoluene 1,2-Dibromo-3-chloropropane Dbromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1, 3-Dichloropropene trans-1,3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene (Cumene) p-IsopropyRoluene Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Date: 12/02/2008 02:15 PM Analytical Method: 6230D W ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND uglL 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1. ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 2.0 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 1.0 1 ND ug/L 1.0 1 ND ug/L 1.0 1 ND ug/L 0.50 1 ND ug/L 0.5Q 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.5D 1 ND ug/L 0.50 1 ND ug/L 0.50 •1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 2.0 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 2.0 1 ND ug/L 0.50 1 ND ug/L 2.0 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 REPORT OF LABORATORY ANALYSIS This report shag not be reproduced, except in lull, without the written consent of Pace Analytical Services, Inc.. 11/23/08 03:11 71-43-2 11/23/08 03:10 108-86-1 11/23/08 03:10 74-97-5 11/23/08 03:10 75-274 11/23/08 03:10 75-25-2 11/23/08 03:10 74-83-9 11/23/08 03:11 104-51-8 11/23/08 03:11 135-98-8 11/23/08 03:11 98-06-6 11/23/08 03:10 56-23-5 11/23/08 03:10 108-90-7 11/23/08 03:10 75-00-3 11/23/08 03:10 67-66-3 11/23/08 03.10 74-87-3 11/23/08 03:10 95-49=8 11/23/08 03:10 106-43-4 11/23/08 03:10 W12-8 11/23/08 03:10 124-48-1 11/23/08 03:10 106-93-4 11/23/08 03:10 74-95-3 11/23/08 03:10 95-50-1 11/23/08 03:10 541-73-1 11/23/08 0310 10646-7 11/23/08 03:10 75-71-8 11/23/08 03:10 75-34-3 11/23/08 03:10 107-06-2 11/23/08 03:10 75-35-4 11/23/08 03:10 156-59-2 11/23/08 03:10 156-60-5 11/23/08 03:10 78-87-5 11/23/08 03:10 142-28-9 11/23/08 03:10 594-20-7 11/23/08 03:10 563-58-6 11/23/08 03:10 10061-01-5 11/23/08 0310 10061-02-6 11/23/08 03:11 108-2D-3 11/23/08 03:11 100-41-4 11/23/08 03:10 87-68-3 11/23/08 03:11 98-82-8 11/23/08 03:11 99-87-6 11/23/08 03:10 75-09-2 11/23/08 03:11 1634-04-4 11/23/08 03:11 91-20-3 11/23/08 03:11 103-65-1 11/23/08 03:11 100-42-5 11/23/08 03:10 630-20-6 11/23/08 03:10 •79-34-5 Page 11 of 29 acigkdj tical e xempacam com Project CLEMENT PAPPAS 11/18 Pace Project No.: 9232546 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 10o Huntersville, NC 28078 (704)875.9092 Sample: MW-7 Lab ID: 9232646006 Collected: 11/18/0812:15 Received: 11118/0815:53 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6230D GCV Ana"c@I.Method: 6230D W Tetrachloroethene �_1.79 ug/L) 0.50 1 11/23/08 03:10 127-18-4 Toluene ND ug/L 0.50 1 11/23/0803:11 108-88-3 1,2,3-Tdchlorobenzene ND ug/L 2.0 1 11/23/0803:10 87-61-6 1,2,4-Trichlorobenzene ND ugA- 2.0 1 11/23/08 03:10 120-82-1 1,1,1-Tdchloroethane ND ug/L 0.50 1 11/23/0803:10 71-55-6 1,1,2 Tdchloroethane ND ug/L 0.50 1 11/23/08 03:10 7D-MS Trichloroethene ND ug/L 0.50 1 11/23/08 03:10 79-01-8 Trichlorofluoromethane ND ug/L 0.50 1 11/23/08 03:10 75.69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/23/08 03:10 96-18-4 1,2,4-Trimethylbenzene NO ug/L 0.50 1 11/2310803:11 95-63-6 1,3,5-Tdmethylberizene ND ug/L 0.50 1 11/23/08 03:11 108-67-8 Vinyl chloride ND ug/L 0.50 1 11/23/08 03:10 75-01-4 m&p-Xylene ND ug/L 0.50 1 11/23/08 03:11 1330-20-7 o-Xylene ND ug/L 0.50 1 11/23/08 03:11 9547-6 1-Chloro-3-fluorobenzens (S) 105 % 60-140 1 11/23/08 03:10 625-9B-9 92210E Fecal Coliform, MPH Analytical Method: SM 9221C/E Fecal Coliforms, MPN < 1.1 MPN/100ml- 1.0 1 11/1810817:20 2640C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 30.0 mg/L 20.0 1 11/24/0815:59 350.1 Ammonia Analytical Method: EPA 350.1. Nitrogen, Ammonia ND mg/L 0.10 1 11/22/0810.51 7764-41-7 363.2 Nitrogen, NO2IN03 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 1.7 mg/L 0.10 1 11/18/08 23:28 4600 Chloride Analytical Method: SM 450D-CI-E Chloride 7.7 mg/L 5.0 1 11/24/0811:42 16887-00-6 6310B TOC Analytical Method: SM 5310B Total Organic Carbon 7.6 mg/L 1.0 1. 11126/0819:19 7440-44-0 ASTM D516-90 Sulfate Water Analytical Method: ASTM D516-90 Sulfate ND mg/L 5.0 1 11/21/0812:30 14808-79-8 Date: 12/02/2008 02:15 PM REPORT OF LABORATORY ANALYSIS Page 12 of 29 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. eeo„e� v 2 It6 Pace Analytical Services, Inc. Pace Analytical Services, Inc. y" VLr/ 27-25 Riverside Dr. 9B00 KinceyAve. Suite 100 ./VIf� com Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: CLEMENT PAPPAS 11/18 Pace Project No.: 9232546 Sample: MW-6 Lab ID: 9232646006 Collected: 11/1810812:47 Received: 11/18/0815:53 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[ 1 6230D GCV Analytical Method: 6230D W a Benzene ND ug/L 0.50 1 11/23/08 03:53 71-43-2 Bromobenzene ND ug/L 0.50 1 11/23/08 03:52 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/23/08 03:52 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/23/08 03:52 75-27-4 1 Bromoform ND ug/L 0.50 1 11/23/08 03:52 75-25-2 Bromomethane ND ug/L 0.50 1 11/23/08 03:52 744839 1 n-Butylbenzene ND ug/L 0.50 1 11/23/08 03:53 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/23/08 03:53 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/23/08 03:53 98406-6 f Carbon tetrachloride ND ug/L 0.50 1 11/23/08 03:52 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/23/08 03:52 108-90-7 Chloroethane ND ug/L 0.50 1 11/23/08 03:52 .75-00-3 . Chloroform ND ug/L 0.50 1 11/23/08 03:52 67-66-3 Chloromethane ND ug/L 0.50 1 11/23/08 03:52 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/23/08 03:52 95-4" 4-Chlorotoluene ND ug/L 0.50 1 11/23/08 03:52 10643-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 11/23/08 03:52 96-12-8 ' Dibromochloromethane ND ug/L 0.50 1 11/23108 03:52 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/23/08 03:52 106-93-4 Dibromomethane ND ug/L 0.50 1 11/23/08 03:52 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 • 1 11/23/08 03:52 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 1 11/23/0803:52 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 1 11/23/08 03:52 106-46-7 Dichlorodifluoromethane ND uglL 0.50 1 11/23/08 03:52 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/23/08 03:52 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/23/08 03:52 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/23/08 03:52 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/23/08 03:52 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/23/OB 03:52 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/23/08 03:52 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 1V23108 03:52 142-28-9 i 2,2-Dichloropropane ND ug/L 0.50 1 11/23/08 03:52 594-20-7 . 1,1-Dichloropropene ND ug/L 0.50 1 11/23/08 03:52 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/2310803:52 10061-01-5 trans-1,3-Dichioropropene ND ug/L 0.50 1 11/23/08 03:52 10061-02-6 f Diisopropyl ether. ND ug/L 0.60 1 11/23/08 03.53 108-20-3 j Ethylbenzene ND ug/L 0.50 1 11/23/08 03:53 100-41-4 Hexachloro-1,3-butadiene ND uglL 2.0 1 11/23/08 03:52 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/23/08 03:53 98-82-8 p-Isopropyholuene ND ug/L 0.50 1 11/23/08 03:53 99-87-6 Methylene Chloride ND uglL 2.0 1 11/23/08 03:52 75-09-2 f Methyl-tert-butyl ether ND ug/L 0.50 1 11/23/08 03:53 1634-044 I Naphthalene ND ug/L 2.0 1 11/23/08 03:53 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/23/08 03:53 103-65-1 Styrene ND ug/L 0.50 1 11/23/08 03:53 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/23/08 03:52 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/23/08 03:52 79-34-5 Date: 12/02/2008 02:15 PM REPORT OF LABORATORY ANALYSIS Page 13 of 29 This report shall not be reproduced, except in full, v j without the written consent of Pace Analytical Services, Inc.. dl jk 'l e Pace Analytical Services, Inc. Pace Analytical Services, Inc. ceAn�(1//2225 Riverside Dr. 980D I(incey Ave. Suite 100 a,W 8 CDM Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875.9092 ANALYTICAL RESULTS Project: CLEMENT PAPPAS 11/18 Pace Project No.: 9232546 Sample: NW-6 Lab ID: 9232546006 Collected: 11/18/0812:47 Received: 11/18/0816:53 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6230D GCV Analytical Method: 6230D W Tetrachloroethene ND ug/L Toluene ND ug/L 1,2,3-Trichlorobenzene ND ug/L 1,2,4-Trichlorobenzene ND ug/L 1,1,1-Trichloroethane ND ug/L 1,1,2-Trich►oroethane ND ug/L Trichloroethene ND ug/L Trichlorofluoromethane ND ug/L 1,2,3 Trichloropropane ND ug/L 1,2,4-Trimethyibenzene ND ug/L 1,3,5-Trimethylbenzene ND ug)L Vinyl chloride ND ug/L m&p-Xylene ND ug/L o-Xylene ND ug/L 1-Chloro-3-fluorobenzene (S) 103 % 92210E Fecal Coliform, MPN Analytical Method: SM 9221C/E Fecal Coliforms, MPN 2.2 MPN/100mL 2640C Total Disso R/ Solids Analytical Method: SM 2540C Total Dissolved Solids 118 mg/L 360.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 363.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate ND mg/L 4500 Chloride Analytical Method: SM 450D-CI-E Chloride 17.2 mg/L 5310E TOC Analytical Method: SM 5310B Total Organic Carbon 14.4 mg/L ASTM D516-00 Sufate Water Analytical Method: ASTM D516-90 Sulfate 21.5 mg/L 0.50 1 11/23/08 03:52 127-18-4 0.50 1 11/23/08 03:53 108-88-3 2.0 1 11/23/08 03:52 87-61-6 2.0 1 11/23/08 03:52 120-82-1 0.50 1 11/23/08 03:52 71-55-6 0.50 1 11/23/08 03:52 79400-5 0.50 1 11/231D8 03:52 79-01-6 0.50 1 11/23/08 03:52 75-69-4 0.60 1 11/23/08 03:52 96-18-4 0.50 1 11/23/08 03:53 95-63-6 0.50 1 11/23/08 03:53 108-67-8 0.50 1 11/23/08 03:52 75-01-4 0.50 1 11/23/08 03:53 1330-20-7 0.50 1 11/23/08 03:53 95-47-6 60-140 1 11/23/08 03:52 625-98-9 1.0 1 11118/081720 20.0 1 11/24/0815:69 0.10 1 11/2210810:53 7764-41-7 0.10 1 11/18/08 23:28 5.0 1 11/24/0811.42 16887-00-6 1.0 1 11126/0819:29 7440-44-0 5.0 1 11/21/01111:28 14808 79-8 Date: 12/02/2008 02:15 PM REPORT OF LABORATORY ANALYSIS Page 14 of 29 This report shall not be,reproduced, except in full, withoutthe written consent of PaceAnalytical Services, Inc.. w 50 COLLEGE STREET, AsHEvn1 u •NC 28801 TEL. 828.2813350 FAC .828281.3351 www.altamontenvironmental.com Well Sampling Log FACILITY NAME: 6tz"" • Pe . • •s S DATE: / /,S' •d , . LOCATION: " d"� G l SAMPLING TBvIE: 3' SAMPLING PERSONNEL: tr ► �^'l eG �.; 6�a n WEATHEI;L cc 5 yw w WELL NUMBER: T4 W -). N WELL DEPTH IN FEET (WD): l y, 1D START TIME: /6 ? `' WELL DIAMETER: 9- n WATER LEVEL IN FEET (WL): 1 S L TYPE OF CASING: LENGTH OF WATER COLUMN: , pit% FEET MEASURING POINT:• ._..- (WD) - (WL) = (LWC) N FLUSH MOUNT /` TI - ONE CASING VOLUME: i GALLONS COMMENTS: pN.«j mil. .-z44;, (LWC) x (WCV) ' - / ► 5-0 c a THREE CASING VOLUMES: 3, 2 GALLONS ACTUAL VOLUME PURGED: I r.% GALLONS WELL CASING VOLUMES (WCV) 2" = 0.17 Gal/Ft 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" =1.5 Ga1/Ft 8" = 2.6 Gal/Ft 12" = 5.8 Gal/Ft PURGE METHOD: BAILER DISP. BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: BAILER-DISP. BAILER-TEFLON DEDICATED PUMP_ WHALE PUMP GRUNDFOS OTHER: READING GALLONS PURGED pH UNITS SPECIFIC COND. (µS) TEMP (C°) DISSOLVED OXYGEN (mg/L) OXIDATION REDUCTION POTENTIAL (m TURBIDITY (NTU) COMMENTS :2 Tt, 9 C./arfl.r 3 1,5v '� t�. 3 3 , rl �; `I` , !� t + r►-l„ 4 5 6 7 8 9 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 250 ml PLASTIC fec"r- Lola 40. ml GLASS `rot, w-L I. Glnlor:ole 5 1'nS OTHER t 2s PROTECTIVE CASING: vlt PAD:-',, Q_ LOCK: o}L VEGETATION: ACCESS: Sampling Personnel Signature: Date: 1 /is ITL",4 Notes: µS = micro-Siemen C° = degrees Celsius mg/L = milligrams per liter mV = millivolt NTU = nephelometric turbidity units P:\Templates\GW Drilling FormslWell Sampling Logxls Page 1 of 1 no ON a MR111 1' • 1 .,05TXit FIT E' C-"R.I. N13 &"' H' Y D R' O 'O :E iU:!i rGwYW 50 COLLEGE SIREFT, ASHMLLE,-NC 28801 TEL.828.281.3350 FAC.828.2813351 www.altamontenvironmental.com Well Sampling Log FACILITY NAME: LOCATION: . SAMPLING PERSONNEL: DATE: 1 1 -1 t - e f SAMPLING TIME: 1.5 34 WEATHER: C oI k s •�cw WELL NUMBER: N1 vj Lj WELL DIAMETER: TYPE OF CASING: 1' V MEASURING POINT: _ FLUSH MOUNT /�ffiCIC-UP COMMENTS: WELL DEPTH IN FEET (WD): 1 u . 0 D START TIME: i 3 WATER LEVEL IN FEET (WL): 1,14 LENGTH OF WATER COLUMN :.'t+ `1 FEET (WD) - (WL) _ (LWC) ONE CASING VOLUME: 11 S GALLONS (LWC) x (WCV) THREE CASING VOLUMES: i�� GALLONS ACTUAL VOLUME PURGED: 1'I s GALLONS WELL CASING VOLUMES (WCV) 2" = 0.17 Ga1/Ft 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft I2" = 5.8 Gal/Ft PURGE METHOD: BAILER-DISP. BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: BAILER-DISP. BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: READING GALLONS PURGED pH UNITS SPECIFIC COND. (µS) TEMP (CO) DISSOLVED OXYGEN (mg/L) OXIDATION REDUCTION POTENTIAL m TURBIDITY (NTU) COMMENTS 2 }iS 51 U?' - 3 3- S -it / 3 Z Lam; .c-- 4 LA5 Ste, `7 `1 1 1 2 t '-i , -3 'I -2% 1b — 21, , C LILAC 5 6 .7 8 9 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 250 ml PLASTIC 1 6 A-�-- 40 ml GLASS o L ► c s L to I> 5 Do ,„ L l.,.s K, 5 OTHER l 2S t �,kZ 2 h} . ik JtR i ,,,„ ►`n PROTECTIVE CASING: a 1t ' PAD: o L- LOCK: r v-, VEGETATION: ACCESS: wt°� amplingPersonnelSignature: ,J Date: 11 I10 /g Notes: µS = micro-Siemen C" = degrees Celsius mg/L = milligrams per liter mV = millivolt NTU = nephelometric turbidity units P:\Templates\GW Dn7ling.Fomns\Well Sampling Log.xls Page 1 of 1 raft i:EC'f7•; ti2Y• E' E' R"1 K'Ci 8" H' Y D R' O •G •EiDtiO a'O•;Y. 50 Cou.EGE STREET AsHEvui.E,-NC 28801 TEL. 828.281.3350 FAC .8282813351 www.altamonteiivironmental.com Well Sampline Loe FACILITY NAME: CLvju� �, s DATE: III I $ x� LOCATION: Co • P] t- SAMPLING TIME: 1/ �5 SAMPLING PERSONNEL: e M !S WEATHER S r-w WELL NUMBER: 04 W `a WELL DIAMETER: 3.`I TYPE OF CASING: 11>4 t. MEASURING POINT a FLUSH MOUNT /ICK UPS COMMENTS: WELL DEPTH IN FEET (WD): l Li;'/'1 START TIME: 169 WATER LEVEL IN FEET (WL): u7_� LENGTH OF WATER COLUMN: FEET (WD) - (WL) _ (LWC) ONE CASING VOLUME: l t I l' GALLONS (LWC) x (WCV) THREE CASING VOLUMES: GALLONS ACTUAL VOLUME PURGED: GALLONS WELL CASING VOLUMES (WCV) 2" = 0.17 Gal/Ft 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = I.5 Gal/Ft 8" = 2.6 Gal/Ft I2" = 5.8 GaI/Ft PURGE.METHOD: BAILER-DISP. BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER SAMPLE METHOD: BAILER DISP. BAILER-TEFLON DEDICATED'PUMP WHALE PUMP GRUNDFOS OTHER: READING GALLONS PURGED pH UNITS SPECIFIC COND. (µS) TEMP (CO) DISSOLVED OXYGEN (mg/L) OXIDATION REDUCTION POTENTIAL m TURBIDITY (NTU) COMMENTS �y 7 s 2 i.Lt 5-: 5 lq 1 4 41 7. v/ 3'& Zi z. 3 Z 151 t .1,L 2-A 3I1' D 4 3.� i r( 1 `l r S Z t 6 rhr� 5 6 7 8 4 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 250 ml PLASTIC r, (o 43- 40 ml GLASS '7b L oc • 6 7-w I-L-cL o r.L- I".s6° i CtLc, ry S N=olrz 1� s OTHER 12s t ta.th' Z IJ r'e PROTECTIVE CASING: ,, lL PAD: ©tl- LOCK: ol" VEGETATION: ACCESS: oiy Sampling Personnel Signature: Date: 1A , L moo$ Notes: µS = micro-Siemen C° = degrees Celsius mg/L = milligrams per liter mV = millivolt NTU = nephelometric turbidity units P:lTemplateslGW Drilling FormslWell Sampling Log xls, Page I of I • e a:E•+N%Si: 1'N-E' E"R"t. N"O"" &'" H Y D R' O:O-£: G••i•'OYO-V 50 COLLEGE SIR=, ASHEvnix, •NC 28801 TEL. 828:2813350 FAc .828.281.335I www.altamontenvironmental.com Well SamDling Log FACILITY NAME: (' ^, ,, .� DATE: LOCATION: 't t� '✓ i :. SAMPLING TIME: I �f t SAMPLING PERSONNEL: /<1 ; ;w WEATHER: a 1,1 S k.' WELL NUMBER: !A vv ' v WELL DEPTH IN -FEET (WD): it try START TIME: Ic WELL DIAMETER: ' A " WATER LEVEL IN FEET (WL):_ % ; 3 ik TYPE OF CASING: P, �- LENGTH OF WATER COLUMN: t{,16 FEET MEASURING POINT: (WD) - (WL) _ (LW.C) FLUSH MOUNT /_ ,STICK-UP.! ONE CASING VOLUME: p GALLONS COM(MENTS:I/J� Z I{ Aw.•:" c - (LWC) x (WCV) _ t- 7'i .'c c/• THREE CASING VOLUMES: "� 110 GALLONS ACTUAL VOLUME PURGED: 0 , GALLONS WELL CASING VOLUMES (WCV) 2" = 0.17 Gal/Ft 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Ga1/Ft 8" = 2.6 Gal/Ft 12" = 5.8 Ga1/Ft PURGE METHOD: BAILER-DISP. BAILER-TEFLON .DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: BAILER-DISP. BAILEEFLON R T DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: READING GALLONS pH UNITS SPECIFIC TEMP DISSOLVED OXIDATION TURBIDITY COMMENTS PURGED COND. (CO) OXYGEN REDUCTION (NTU) (µS) (mg/L) POTENTIAL m 1 IA14,-Q t 6 t2jeq , ! 2 C. Ci 3f� .t,o� `EtB� 2G[L stl,xt�.b�d 3 4 5 6 7 8 9 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 250mlPLASTIC 40 nil GLASS sv ti r• �— lati h ` c In i v • : 1 Sa ► �c, T� j OTHER 2;) 1 Z., n,l, 2 IJ 1 �� .% [ 1'�-y,,,,,�,•+'; •L PROTECTIVE CASING: c V-- PAD: e \L LOCK: &t, VEGETATION: o tL ACCESS - Sampling Personnel Signature: /l Date: /, 1,5 Notes: pS = micro-Siemen Co = degrees Celsius mg/L = milligrams per liter mV = millivolt NTU = nephelometric turbidity units P:\Templates\GW Drilling Forms\Well Sampling Log.xls Page I of 1 ...E?7J;:C3.'I N E' E'R'`1 N`b"•• 8'" K Y 'O R' O `b •f 'D "L'�OYO'a! SO COLLEGE STREET, AsHEvnr.E,•NC 28801 TEL. 828.281.3350 FAC .828281.3351 www.altamontenvironmental.com Well SamnIinLy Log FACILITY NAME: LOCATION: SAMPLING PERSONNEL: (: M u {�, , DATE: SAMPLING TIME: (Z W WEATHER: I WELL NUMBER: fXt w -•- WELL DIAMETER: t TYPE OF CASING: p v C MEASURING POINT: FLUSH MOUNT/ -STICK-UP COMMENTS: ..... " . WELL DEPTH IN FEET (WD): START TIME: f; if . WATER LEVEL IN FEET (WI.):_ r t ty LENGTH OF WATER COLUMN: S•G`i FEET (WD) - (WL) _ (LWC) ONE CASING VOLUME: it _ GALLONS (LWC) x (WCV) THREE CASING VOLUMES: 2, b GALLONS ACTUAL VOLUME PURGED: 7_ 4i" GALLONS WELL CASING VOLUMES (WCV) 2" = O.I7 Gal/Ft 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.8 GaI/Ft PURGE METHOD: BAILER-DISP. BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER SAMPLE METHOD: BAILER-DISP. BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: READING GALLONS PURGED pH UNITS SPECIFIC COND.. (µS) TEMP (CO) DISSOLVED OXYGEN (mg/L) OXIDATION REDUCTION POTENTIAL m TURBIDITY (NTU) COMMENTS �^ •z P?-;t 2 ►.c '.-j V. 3 cl .�. le i:K, i 31Nr Y 3 2A S 0 U 3 ' 1 �l,v • !, c -L�� s/, fr r4 4 2, r.5'1 5 6 7 8 9 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 250 ml PLASTIC ( Fec.,,,P— cam+ h 40 ml GLASS S t-o C Voi 12ro i5 4-L-61695 Szv P l.� OTHER 2 , . L , f.� Z IV. h�. PROTECTIVE CASING: Holz-• PAD: G K.- LOCK: o V-- VEGETATION: o tL ACCESS: oer� Sampling Personnel Signature: Date: / ! N / Lo Notes: µS = micro-Siemen V CO = degrees Celsius mg/L = milligrams per liter mV = millivolt NTU = nephelometric turbidity units P:\Templates\GW Drilling ForniAWell Sampling Log.xls Page I of I ! • RM # -w FiFf rwg^ 8• • H' Y D R' O G 50 CoLLecE SMzM, ASHEvn.LE,•NC 28801 TEL.928.2813350 FAc.828.281.3351 www.altamontenvironmejital.com WAI Camnlina Tnm o - a FACILITY NAME: F 5 DATE: ) f- i h _v 4 LOCATION: f ' . . s E, G , (.; it SAMPLING TIME: SAMPLING PERSONNEL: WEATHER: (+itA- WELLNUMBER: M tv ' WELL DIAMETER: TYPE OF CASING: P •' MEASURING POINT: FLUSH MOUNT A STICK_i P } COMMENTS: WELL DEPTH IN FEET (WD): i 3 • 10START TIME: {'Li3 WATER LEVEL IN FEET (WL): ) 1, lI LENGTH OF WATER COLUMN: 'Z t -1t FEET (WD) - (WL) _ (LWC) ONE CASING VOLUME: t,`, y- GALLONS (LWC) x (WCV) THREE CASING VOLUMES: • , `'t Z GALLONS ACTUAL VOLUME PURGED: / , !�'u GALLONS WELL CASING VOLUMES (WCV) 2" = 0.17 GaUFt 3" = 0.38 GaUFt . 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft . 12" = 5.8 Gal/Ft PURGE METHOD: BAILER-DISP. BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: SAMPLE METHOD: BAILER-DISP. BAILER-TEFLON DEDICATED PUMP WHALE PUMP GRUNDFOS OTHER: READING GALLONS PURGED pH UNITS SPECIFIC COND. (µS) TEMP (CO) DISSOLVED OXYGEN (mg/L) OXIDATION REDUCTION POTENTIAL m TURBIDITY (NTU) COMMENTS 2 0 i S () ! 7 J. [. rt1 2/ '55 1 cw / S/ i 5 *N�br 3 j! 4 i;50 Loll 3/ 12 jz Zrl'�- Lb:,E► 1/ 5 6 7 8 9 SAMPLING CONTAINER NUMBER OF CONTAINERS REQUESTED ANALYSIS 250 ml PLASTIC 40 ml GLASS S ..M t , poi b, t 210 t7 I L GLASS / rn s OTHER z N. f n rn vh PROTECTIVE CASING: !� t`- PAD: LOCK: ►L VEGETATION: o �— ACCESS: a a A Sampling Personnel Signature: �f /rQ Date: i 1 I f b j v Notes: µS = micro-Siemen C' = degrees Celsius mg/L = milligrams per liter mV = millivolt NTU = nephelometric turbidity units RlTemplateslGW Drilling FormslWell Sampling Log.xls Page I of I i ALTAMONT ENVIRONMENTAL, INC. Engineering & Hydrogeology 50 COLLEGE STREET, ASHEVILLE, NC 28801 TEL,828.821.3350 FAC.828.281.3351 www.altamontenvironmental.com Equipment Documentation & Instrument Calibration Data Sheet Project Name: C.l¢rwc�. �ca PSGi Project Number: aW , tt) a,(� Project Location: 1�1_ V1A1-,0vt (o , fv 0L Equipment Documentation Y T' N r, ;,,� �S ;Eo •l�7 Equipment or meters used to take measurements (e.g. water level meters, survev eauipment. etc.): Equipment Type Manufacturer 'Serial Number Date of Use 150-ft Water Level Heron 7186 150-11 Water Level Solinst 26154 150-11 Water Level Solinst 22754 150-ft Water Level Testwell 150 Calibration Documentation n Person Conducting Calibration: `+ M ,Ut/ 1.- Date of Calibration: 1 q pQ Date of Field Measurements: 1 ty pF. YSI 556 Multiparameter Meter Micro TPW Turbiditv Meter Calibration Time Calib Standard Exp Instrument Serial # Instrument Readin 1000 NTU 10.0 NTU 0.02 NTU —200i60l°0 _.11utial: __- Initial: Cal: Cal• Cal: Calib Standard Instrument Instrument Readings H 4 p H 7 p H 10 QC Conductivity Calibration Time Expiration Expiration Serial Date Number 06116ti b jig 7 bAF V0%,- 447 µS 844 µS 200 mV t,' 1 07D100979 Initial: )_�q Initial:. -a , l Initial: A,V.I6 Meas: 3-. o\ Initial: y--8 Meas: Initial: Is ,� Cal: �.0�1 Cal: -70� Cal: 10111— Cal: 44� �� Cal: aterrf� Initial: Initial: Initial: Meas: Initial: Meas: Initial: Cal: Cal: Cal: Cal: Cal: 0 Note: Electronic equipment calmrated according to the manufacturer's operation manual. PATemplateAGW-Drilling FormslCalibration Data Sheet YSI 556.xis wog' Page IofI r,