WQ0004797_Monitoring (Report)_20061208

December 8, 2006
Mr. Blake Kehoe
Clement Pappas
Post Office Box 1009
Mountain Home, North
MAR 0 8 2007
50 COLLEGE sTREET, AsHEviLLE, NC 28801
TEL. [phone] FAC. 828.28.13351
www.altamontenvironmentalcom
JAN 112007
Asheville Regional Office
AClmiier Protection✓ -
-
Subject: November 2006 Groundwater Sampling Event
Clement Pappas
125 Industrial Park Road
Mountain Home, North Carolina
Dear Mr. Kehoe:
1.4.
1 F JAN 1 0 2007
l
}
WATER QUALITY SECTION
ASHEVILLE REGIONAL OFFICE I
FEB 1 5 2007
Altamont Environmental, Inc. (Altamont) conducted a groundwater sa pling xemt�at our facility oai L`
November 9 2006. Altamont conducted the groundwater sampling ev `er 2la" tmkht
Carolina Department of Environment and Natural Resources (DENR) spray iMc
number WQ0004797 (permit issued October 23, 2001). Altamont collected groundwater samples from
six monitoring wells: MW-2R, MW-4, MW-5, MW-6, MW-7, and MW-8. Altamont submitted the
groundwater samples to a certified laboratory for analysis of the parameters specified in the permit with
one exception. The laboratory, Pace Analytical Services, Inc. of Asheville, North Carolina (Pace), could
not analyze Volatile Organic Compounds (VOCs) by method 6230D due to equipment repairs. However,
Pace stated that they were able to achieve the same analyte list and detection limits using an alternative
method, 621 OD. Therefore, Altamont obtained approval to analyze VOCs according to method 621 OD
from Ms. Megan Howard of the DENR. Tables 1 and 2 summarize the current and.historic laboratory
analytical results. All parameters analyzed were below permit limits with the exception of the
chlorinated VOCs detected in the sample collected from MW-5.
In addition to Tables 1 and 2, please find attached the following:
• Table 3. - Current and Historical Groundwater Elevation Measurements,
• The laboratory analytical report and chain of custody form,
• Altamont's well sampling logs and equipment documentation and instrument calibration data
sheet,
• One DENR GW-59A - Compliance Report Form, and
• Six DENR GW-59 - Groundwater Quality Monitoring: Compliance Report Forms
In accordance with the permit, Clement Pappas is required to submit the DENR forms along with the
laboratory analytical report and chain of custody form to the DENR.
--✓
PAClement Pappas\Reports\2006\November 2006\cover lettendoc

4
T
-1Ir. Blake Kehoe
December 8, 2006
Page 2 of 2
Altamont will complete the next scheduled groundwater sampling event in May 2007. Ityou have any
questions or would like additional information, please do not hesitate to contact the undersigned at (828)
281-3350.
Respectfully yours,
Enclosures: Tables 1 and 2 - Current and Historical Groundwater Analytical Results
Table 3 - Current and Historical Groundwater Elevation Measurements
Laboratory analytical report and chain of custody form
Well sampling logs and equipment documentation and instrument calibration data sheet
One GW-59A form
Six GW-59 forms
PAClement Pappas\Reports\2006\November 2006\cover letter.doc

' GW 59A COMPLIANCE REPORT FORM Permit # WQ0004797
(Subnut one each monitoring period with GW-59 forms.)
1
Enter date monitoring results were due. ( 12/31/2006) Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
2
Was any required information missing on the GW-59 report forms?
YES
NO
•
IF the answer to question 1 or 2 is 'YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? If the answer is "Yes", contact the Regional Djce for guidance.
•
4
Are any monitored'constituents equal to or above the established standards?
YES
N
if the answer to question 4 is "NO", skip to section B.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below.
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is "NO" skip to section B.
If the answer to question 5 is "YES'; list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s) reported, and sample collection date, for each occurrence (for the last two years).
6
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
If the answer is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells maybe improperly
located, contact the Regional Office.
7
is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO" contact the Regional Office within 90 days; an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation,
fines, and/or penalties.
g
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form.
hhgeby acknowledge that the above mfotmafion was evaluated and the information su6m tted fn this
report (Comp)fance Fteporf GW�59A)/is and complete to the:best,of my_knowledge� ,��x
true
Signature of Permittee (or Authorized Agent) Date
GW-59A 12/8/2003

SUBMIT FORM ON YELLOW PAPER ONLY '
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
r-pm-n-i r T irwynivim t tury mease r-nnr c/eany or t ype .
Facility Name: Clement Pappas
Permit Name (if different):
Facility Address: ' 125 Industrial Park Road
Mountain Home (s'""'i No 28792 County Henderson
• Tr'Ti1 1GTR1:Z 1 T.-i
Contact Person: Mr. Blake Kehoe Telephone#: [phone]
Well Location/Site Name: Irrigation Area No. of wells to be sampled:
Well Depth 14.9
Screened Interval: 6
Depth to Water Level: 6.49
Measuring Point is 3.77
Gallons of water Dumped/ba
from Permit): MW-2R
ft. Well Diameter: 2 in.
ft. to 14.9 ft.
ft. below measuring point.
ft. above land surface.
,d before samolinq: 2.25
if WELL WAS DRY
at time of sampling, Check here
Sample is from system:
❑ Influent I
Date sample collected:
uent
,6 PeMlq
IT No. WQ0004797 EXPIRATION DATE: 06-30-07
scharge X UIC
I
OF PERMITTED OPERATION BEING MONITORED
_ Lagoon Remediation: Inflitration Gallery
_Spray Field Remediation:
_ Rotary Distributor Land Application of Sludge
—Water Source Heat Pump
Other.
Remediation System Influent/Effluent Only (Attach Lab Reports.)
I
nt mg/L (Total VOC Concentration)
ant mg/L (Total VOC Concentration)
Removal
FIELD ANALYSIS: pH 5.40 Specific Conductance 100.0 uMhos Date sample analyzed: varies - see laboratory reoort
Temp. 16.8 eC Odor none Appearance slightly cloudy Laboratory Name: Pace Analvtical Services, Inc.
Certification No. 37712
PARAMETERS (Samples for metals were collected unfiltered YES NO and field acidified YES NO.)
NOTE: Values should reflect dissolved and colloidal concentrations.
COD
mg/I
Nitrite (NO2) as N
mg/I
Ni - Nickel
mg/I
Coliform: MF Fecal
<1.1 mpn
/100ml
Nitrate (NO3) as N 0.95
mg/I
Pb - Lead
mg/I
Coliform: MF Total
/100ml
Phosphorus: Total as P
mg/I
Zn - Zinc
mg/I
(Note: Use MPN method for highly turbid samples)
Orthophosphate
mg/I
re.
c •;,
Dissolved Solids: Total
76
mg/I
A I -Aluminum
mg/I
Other (Specify Compounds and Concentration Units4`'heZ`��
pH (when analyzed)
units
Ba - Barium
mg/I�,;��4�
TOG
3.6
mg/I
Ca - Calcium
mg/I4
Chloride
7.4
mg/I
Cd - Cadmium
mg/I
Arsenic
mg/1
Chromium: Total
mg/I,q
Grease and Oils
mg/I
Cu - Copper
mg/I
Phenol
mg/I
Fe - Iron
mg/I
ORGANICS: (by GC, GC/MS, HPLC)
Sulfate
17
mg/I
Hg - Mercury
mg/1
(Specify test and method #. ATTACH LAB REPORT.)
Specific Conductance
uMhos
K - Potassium
mg/I
Report Attached? Yes x (1) No (0)
Total Ammonia
0.11
mg/I
Mg - Magnesium
mg/I
VOC ; method #= 621 OD
(Ammonia Nitrogen; NH3 as N;
Ammonia Nitrogen, Total)
Mn - Manganese
mg/I
: method #=
TKN as N
mg/I
: method #=
method #=
GW-59
Rev. 11/2005
Signature of Perrnittee (or Authorized Agent) (Date)

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
I'AtALII T INI-UKMA I IUN
i'/ease I'rint.cleany or type
Facility Name: Clement Pappas
Permit Name (if different):
Facility Address: 125 Industrial Park Road
Mountain Home (Streit) NC
29792 County Henderson
ae
p
Contact Person: Mr. Blake Kehoe
Telephone#: [phone]
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
(from emut
Well Identification Number (from Permit): MW4 if WELL WAS DRY
Well Depth: 18.60 ft. Well Diameter: 2 in. at time of sampling, Check here
Screened Interval: 8 ft. to 18.6 ft. Sample is from system:
Depth to Water Level: 8.41 ft. below measuring point. ❑ Influent Dffluent
Measuring Point is 2.43 ft. above land surface. Relative M.P. Elevation in ft. 2064.6
Gallons of water pumped/bailed before sampling: , 5.25 Date sample collected: 11/09/2006
WQ0004797 EXPIRATION DATE: 06-30-07
X UIC
OF PERMITTED OPERATION BEING MONITORED
_Lagoon Remediation: Inflitration Gallery
—Spray Field Remediation:
_ Rotary Distributor Land Application of Sludge
—Water Source Heat Pump
Other:
Remediation System In Only
ant mg/L (Total VOC Concentration)
ent mg/L (Total VOC Concentration) .
Removal %
(FIELD ANALYSIS: pH 6.07 Specific Conductance 183.3 uMhos (Date sample analyzed: varies - see laboratory report
Temp. 15.7 eC Odor None Appearance light brown Laboratory Name: Pace Analvtical Services. Inc.
Certification No. 37712
PARAMETERS (Samples for metals were collected unfiltered YES NO and field acidified YES NO.)
NOTE: Values should reflect dissolved and colloidal concentrations.
COD
mg/I
Nitrite (NO2) as N
mg/I
Ni - Nickel
mg/I
Coliform: MF Fecal
<1.1 mon
/100ml
Nitrate (NO3) as N <0.10
mg/I
Pb - Lead
mg/I
Coliform: MF Total
/100ml
Phosphorus: Total as P
mg/I
Zn - Zinc
mg/I
(Note: Use MPN method for highly turbid samples)
Orthophosphate
mg/I
Dissolved Solids: -Total
180
mg/I
A I- Aluminum
mg/I
Other (Specify Compounds and Concentration Units)
pH (when analyzed)
units
Ba - Barium
mg/I
TOC
8.8
mg/I
Ca - Calcium
mg/I
Chloride
6.9
mg/I
Cd - Cadmium
mg/I
Arsenic
mg/I
Chromium: Total
mg/I
Grease and Oils
mg/I
Cu - Copper
mg/I
Phenol
mg/I
Fe - Iron
mg/I
ORGANICS: (by GC, GC/MS, HPLC)
.?
Sulfate
26
mg/I
Hg - Mercury
mg/I
(Specify test and method #. ATTACH -.LAB REPORTj?
Specific Conductance
uMhos
K - Potassium
mg/I
Report Attached? Yes X (1) N6' ­
Total Ammonia
<0.10
mg/I
Mg - Magnesium
mg/I
VOC • : method #=
6210D
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese
mg/I
: method #=
TKN as N
mgfl
: method #=
method #_
GW-59
Rev. 11 /2005
Signature of Perrnittee (or Authorized Agent) (Date)

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
kliALI I If INI-UKMA I IUN ('/ease 1-nnt Clearly or Type
icility Name: Clement Pappas
trmit Name (if different):
icility Address: 125 Industrial Park Road
Mountain Home (street) NC 2e792 County Henderson
itact Person: . -Mr. Blake Kehoe Telephone#: [phone]
II Location/Site Name:_ _Irrigation Area No. of wells to be sampled: 6
(from Penh)
Well Identification Number
Well Depth: 18.44
Screened Interval: 9
Depth to Water Level: 8,39
Measuring Point is_3
Gallons of water pumped/bai
from Permit); MW-5
ft. Well Diameter: 2 in.
ft. to 18.4 ft,
ft. below measuring'point.
ft. above land surface.
td before samolina: 5.25
If WELL WAS DRY .
at time of sampling, Check here
Sample is from system:
❑ Influent Dffluent
Relative M.P. Elevation in ft. 2086.4
Date sample collected: 11/09/2006
No. WQ0004797 EXPIRATION DATE:
X UIC
OF PERMITTED OPERATION BEING MONITORED
_Lagoon Remedlation: Infiltration Gallery
_Spray Field Remedlation:
_ Rotary Distributor Land Application of Sludge
—Water Source Heat Pump
Other:
Remediation System Influent/Effluent Only
mt mglL (Total VOC Concentration)
ant mglL (Total VOC Concentration)
Removal
FIELD ANALYSIS: pH 5.47 Specific Conductance 150.8 uMhos (Date sample analyzed: -varies - see laboratory report
Temp. 16.4 °C Odor None Appearance light brown Laboratory Name: Pace Analvtical Services, Inc.
Certification No. 37712
PARAMETERS (Samples for metals were collected unfiltered YES NO and field acidified YES NO.)
NOTE: Values should reflect dissolved and colloidal concentrations.
COD I mg/I Nitrite (NO2) as N
Coliform: MF Fecal
<1.1 mpn
/100ml
Coliform: MF Total
/100ml
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total
90
mg/I
pH (when analyzed)
units
TOC
1.3
mg/I
Chloride
37
mg/I
Arsenic
mg/I
Grease and Oils
mg/I
mg/I
Nitrate (NO3) as N 0.20
mg/I
Phosphorus: Total as P
mg/I
Orthophosphate
mg/I
A I- Aluminum
mg/I
Ba - Barium
mg/I
Ca - Calcium
mg/I
Cd - Cadmium
mg/I
Chromium: Total
mg/I
Cu - Copper
mg/I
Ni - Nickel mg/I
Pb - Lead mg/I
Zn - Zing mg/Is "i
Other (Specify Compounds and Concentration Units),;;
.. 1,
Phenol
mg/I
Fe - Iron
mg/I
ORGANICS:'(by GC, GC/MS, HPLC)
Sulfate <5.0
mg/I
Hg - Mercury
mg/I
(Specify test and method #. ATTACH LAB REPORT.)
Specific Conductance
uMhos
K - Potassium
mg/I
Report Attached? Yes X (1) No (0)
Total Ammonia < 0.1
mg/I
Mg - Magnesium
mg/I
VOC : method #=621 OD
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese
mg/I
: method #=
TKN as N
mg/I
: method #=
method #=
GW-59
Rev. 11 /2005
M
of Permittee (or Authorized Agent)
�n J
(Date)
-A

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
Please Print Clearlv or
Facility Name: ' Clement Pappas.
Permit Name (if different):
Facility Address: 125 Industrial Park Road
Mountain Home (stree9 NC 28792 County Henderson
act Person: Mr. Blake Kehoe Telephone#: [phone]
Location/Site. Name: _Irrigation Area No. of wells to be sampled: 6
rom emltt
Well Depth: 11.54
Screened Interval: 5
Depth to Water Level: 5.71
Measuring Point is 3
Gallons of water Dumped/ba
ft. Well Diameter: 2 in.
ft. to 11.5 ft.
ft. below measuring point.
ft. above land surface.
id before sampling: 3.00
time of sampling, Check here
ample is from system:
❑ Influent
Relative M.P. Elevation in
Date sample collected:
No. W00004797 EXPIRATION DATE:
arge X UIC
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
X Spray Field Remediaiion:
Rotary Distributor Land Application of Sludge
Water Source Heat Pump
Other:
Remediation System Influent/Effluent
ant mg/L (Total VOC Concentration)
ant mg/L (Total VOC Concentration)
Removal %
(FIELD ANALYSIS: pH 5.34 Specific Conductance 88.7 uMhos (Date sample analyzed: varies - see laboratory report
Temp. 15.7 °C Odor None Appearance slightly cloudy Laboratory Name: Pace Analvtical Services. Inc.
Certification No. 37712
PARAMETERS (Samples for metals were collected unfiltered
YES NO and field acidified
YES
NO.)
NOTE: Values should reflect dissolved and colloidal concentrations.
COD mg/I
Nitrite (NO2) as N
mg/I
Ni - Nickel mg/1
Coliform: MF Fecal <1.1 mpn /100ml
Nitrate (NO3) as N, 0.20
mg/I
Pb - Lead mg/I
Coliform: MF Total /100ml
Phosphorus: Total as P
mg/1
Zn - Zinc mg/I
(Note: Use MPN method for highly turbid samples)
Orthophosphate
mg/I
Dissolved Solids: Total
54
mg/I
A I- Aluminum
mg/I
Other (Specify Compounds and Concentration Units) ~i
pH (when analyzed)
units
Ba - Barium
mg/l
TOC
1.4
mg/I
Ca - Calcium
mg/1
Chloride
11
mg/1
Cd - Cadmium
mg/I
r:,
Arsenic
mg/I
Chromium: Total
mg/I
Grease and Oils
mg/I
Cu - Copper
mg/I
Phenol
mg/I
Fe - Iron
mg/I
ORGANICS: (by GC, GC/MS, HPLC) -
Sulfate
11
mg/I
Hg - Mercury
mg/I
(Specify test and method #. ATTACH LAB REPORT.)
Specific Conductance
uMhos
K - Potassium
mg/1
Report Attached? Yes X (1) No (0)
Total Ammonia
0.18
mg/I
Mg - Magnesium
mg/I
VOC : method #= 6210D
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese
mg/I
: method #=
TKN as N
mg/I
: method #=
method #=
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations.
GW-59
Rev. 11 /2005
Signature of Permittee (or Authorized Agent)
II
—M
(Date)

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
ILI I If INI-UKngA I IUN mease runt cleany or i ype
ity Name: Clement Pappas
III: Name (if different):
ity Address: 125 Industrial Park Road
Mountain Home (stmo) NC 28792 County Henderson
ntact Person: Mr. Blake Kehoe Telephone#: [phone]
:II Location/Site Name: Irrigation Area No. of wells to be sampled: 6
from e i
PERMIT No. W00004797
Non -Discharge X
NPDES
EXPIRATION DATE:
UIC
OF PERMITTED OPERATION BEING MONITORED
_ Lagoon Remediation: Infiltration Gallery
—Spray Field Remediation:
—Rotary Distributor Land Application of Sludge
Water Source Heat Pump
Well Identification Number (from Permit): MW-7
if WELL WAS DRY
other:
Well Depth: 16.72 ft. Well Diameter: 2 in.
at time of sampling, Check here
Screened Interval: 5 ft. to 16.7 ft.
Sample is from system:
For Remediation System Influent/Effluent Only (Attach Lab Reports.)
Depth to Water Level: 9.71 ft. below measuring point.
❑ Influent Offluent
Influent mg/L (Total VOC Concentration)
Measuring Point is 3 ft. above land surface.
Relative M.P. Elevation in ft. 2o62.7
Effluent mg/L (Total VOC Concentration)
Gallons of water pumped/bailed before sampling: 3.75
Date sample collected: 11/09/2006
VOC Removal a
FIELD ANALYSIS: pH 5.43 Specific Conductance
79.0 uMhos
Date sample analyzed: varies - see laboratory resort
Temp. 16.1 °C Odor None
Appearance light brown
Laboratory Name: Pace Analvtical Services, Inc.
Certification No. 37712
PARAMETERS (Samples for metals were collected unfiltered YES NO and field acidified
YES NO.)
NOTE: Values should reflect dissolved and colloidal concentrations.
COD mg/I
Nitrite (NO2) as N mg/I Ni - Nickel
mg/I
Coliform: MF Fecal <1.1 mon /100ml
Nitrate (NO3) as N 1.1 mg/I Pb - Lead
mg/I
Coliform: MF Total /100ml
Phosphorus: Total as P mg/I Zn - Zinc
mg/I
(Note: Use MPN method for highly turbid samples)
Orthophosphate mg/1
Dissolved Solids: Total 38 mg/I
A I -Aluminum mg/I Other (Specify Compounds and Concentration Units)
'
pH (when analyzed) units
Ba - Barium
mg/1 F,- :!�
t"
TOC 1.9 mg/1
Ca - Calcium mg/I"`;cal;
Chloride 7.0 mg/I
Cd - Cadmium mg/I
Arsenic mg/I
Chromium: Total mg/I "" ` :. 'k
Grease and Oils mg/I
Cu - Copper mg/I vl
Phenol mg/I
Fe - Iron mg/I ORGANICS: (by GC, GC/MS, HPLC)
Sulfate 6.7 mg/I
Hg - Mercury mg/I (Specify test and method #. ATTACH LAB REPORT.)
Specific Conductance uMhos
K - Potassium mg/I Report Attached? Yes X (1) No (0)
Total Ammonia <0.10 mg/I
Mg - Magnesium mg/I VOC : method #= 6210D
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese mg/I : method #=
TKN as N mg/I
: method #=
method #=
Rev. 11 /2005

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
FACILITY INFORMATION Please Print Clearly or Type
PERMIT No. WQ0004797 EXPIRATION DATE: 06-30-07
Facility Name: Clement Pappas
Non -Discharge X UIC
Permit Name (if different):
NPDES
Facility Address: 125 Industrial Park Road
Mountain Home (st w) NC 28792
County Henderson
TYPE OF PERMITTED OPERATION BEING MONITORED
Pry)B0 (Zip)
Lagoon Remediation: Infiltration Gallery
Contact Person: Mr. Blake Kehoe
Telephone#: [phone]
X spray Field Remediation:
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
Rotary Distributor Land Application of Sludge
1 rom ermn
Water Source Heat Pump
other:
Well Identification Number (from Permit): MW-8 If WELL WAS DRY
Well Depth: 13.90 ft. Well Diameter: 2 In.
at time of sampling, Check here
Screened Interval: 3 ft. to 13.9 ft.
Sample is from system:
For Remediation System Influent/Effluent Only (Attach Lab Reports.)
Depth to Water Level: 9,40 ft. below measuring point.
❑ Influent Dffluent
Influent mg/L (Total VOC Concentration)
Measuring Point is 3 ft. above land surface.
Relative M.P. Elevation in ft. 2061.4
Effluent mg/L (Total VOC Concentration)
Gallons of water pumped/bailed before sampling: 2.50
Date sample collected: 11/09/2006
VOC Removal "/o
FIELD ANALYSIS: - pH 5.78 Specific Conductance
156.4 uMhos
Date sample analyzed: varies - see laboratory repbrt
Temp. 16.1 eC Odor None
Appearance light brown
Laboratory Name: Pace Analvtical Services, Inc.
Certification No. 37712
PARAMETERS (Samples for metals werecollected unfiltered YES NO and field acidified
YES NO.)
NOTE: Values should reflect dissolved and colloidal concentrations.
COD mg/1
Nitrite (NO2) as N mg/l Ni - Nickel
mg/I
Coliform: MF Fecal <1.1 /100ml
Nitrate (NOO as N 0.97 mg/I Pb - Lead
mg/I
Coliform: MF Total /100ml
Phosphorus: Total as P mg/l Zn - Zinc
mg/1-
(Note: use MPN method for highly turbid samples)
Orthophosphate mg/I�Z�t``4`�
Dissolved Solids: Total 96 mg/I
A I- Aluminum mg/I Other (Specify Compounds and Concentration Units) . A
pH (when analyzed) units
Ba - Barium mg/I
TOC 4.7 mg/I
Ca - Calcium mg/I�
Chloride 12 mg/I
Cd - Cadmium mg/I
Arsenic mg/I
Chromium: Total mg/I
Grease and Oils mg/I
Cu - Copper mg/I
Phenol mg/I
Fe - Iron mg/I ORGANICS: (by GC, GC/MS, HPLC)
Sulfate 7.7 mg/I
Hg - Mercury mg/I (Specify test and method #. ATTACH LAB REPORT.)
Specific Conductance uMhos
K - Potassium mg/I Report Attached? Yes X (1) No (0)
Total Ammonia <0.10 mg/I
Mg - Magnesium mg/I VOC : method #= -6210D
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total
Mn - Manganese mg/I : method #=.
TKN as N mg/l
: method #=
method #=
Kev. 11/2uu5

4..
f
aceAnalytical
www.pacelabs.com
November 22, 2006
Mr. Stu Ryman
Altamont Environmental
50 College Street
Asheville, NC 28801
RE: Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Dear Mr. Ryman:
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax:[phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 26804
Phone. [phone]
Fax: [phone]
Enclosed are the analytical results for sample(s) received by the laboratory on November 9, 2006. Results
reported herein conform to the most current NELAC standards, where applicable, unless `otherwise narrated in the
body of the report.
Inorganic Wet Chemistry and Metals Analyses were performed at our Pace Asheville laboratory and Organic testing
was performed at our Pace Charlotte laboratory unless otherwise footnoted.
If you have any questions concerning this report please feel free to contact me.
of Patton
[e-mail]
[phone]
Project Manager
Enclosures
Asheville Certification IN REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
SC 99030 without the written consent of Pace Analytical Services, Inc.
A
FL NELAP E87648
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

ace Analytical
www.pacelabs.com
Lab Sample No: 927662213
Client Sample ID: MW-02R
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersvil/e, NC 28076
Phone: [phone]
Fax., 704.675.9091
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-001 Date Collected: 11/09/06 10:57
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Microbiology
Fecal Coliform MPN Water
Method: SM 9223
Coliform, Fecal
<1.1 mpn/100mL
11/09/06
16:00
JGJ
Wet Chemistry
Total Dissolved Solids
Method: EPA
160.1
Total Dissolved Solids
76.
mg/l
20.
11/14/06
14:59
TMR
Chloride (Mercuric Nitrate)
Method: EPA
325.2
Chloride
7.4
mg/l
5.0
11/12/06
10:58
JDA1
16887-00-6
Ammonia
Method: EPA
350.1
Nitrogen, Ammonia
0.11
mg/l
0.10
11/10/06
18:32
NIW
7727-37-9
48 Hour NO3 / NO2 / NOX
Method: EPA
353.2
Nitrate as N
0.95
mg/l
0.10
11/09/06
21:40
JDA1
Sulfate,Turbidimetric
Method: EPA
375.4
Sulfate
17.
mg/1
5.0
11/14/06
12:03
TMR
Total Organic Carbon
Method: SM
5310B
Total Organic Carbon
3.6
mg/l
1.0
11/10/06
13:13
JDA1
7440-44-0 .
GUMS Vol ati l es
SM 6210D VOCs
Method: SM
6210D
Benzene
ND
ug/l
0.50
11/15/06
16:19
MSF
71-43-2
Bromobenzene
NO
ug/l
0.50
11/15/06
16:19
MSF
108-86-1
Bromochloromethane
NO
ug/l
0.50
11/15/06
16:19
MSF
74-97-5
Bromodichloromethane
NO
ug/l
0.50
11/15i06
16:19
MSF
75-27-4
Bromoform
NO
ug/l
0.50
11/15/06
16:19
MSF
75-25.2
Bromomethane
ND
ug/l
0.50
11/15/06
16:19
MSF
74-83-9
n-Butylbenzene
ND
ug/l
0.50
11/15/06
16:19
MSF
104-51.8
sec-Butylbenzene
ND
ug/1
0.50
11/15/06
16:19
MSF
135-98-8
tert-Butylbenzene
NO
ug/l
0.50
11/15/.06
16:19
MSF
98-06-6
tert-Butyl Formate.
NO
ug/1
20.
11/15/06
16:19
MSF
762-75-4
Carbon tetrachloride
ND
ug/l
0.50
11/15/06
16:19
MSF
56-23-5
Chlorobenzene
ND
ug/l
0.50
11/15/06
16:19
MSF
108-90-7
Chloroethane
NO
ug/l
1.0
11/15/06
16:19
MSF
75-00-3
Chloroform
NO
ug/1
0.50
11/15/06
16:19
MSF
67-66-3
Date: 11/22/06
Page: 1 of 38
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IN
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
SC
99006
FL NELAP
E87648
0 N ACCOgo
FL NELAP
E87627
*np- rt.i

4
aceAnalytical°
www.pacelabs.com
Lab Sample No: 927662213
Client Sample ID: MW-02R
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-001 Date Collected: 11/09/06 10:57
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Chloromethane
ND
ug/1
1.0
11/15/06
16:19
MSF
74 87-3
2-Chlorotoluene
ND
ug/1
0.50
11/15/06
16:19
MSF
95-49-8
4-Chlorotoluene
ND
ug/1
0.50
11/15/06
16:19
MSF
106-43-4
1,2-Dibromo-3-chloropropane
ND'
ug/l
1.0
11/15/06
16:19
MSF
96-12-8
Dibromochloromethane
ND
ug/l
0.50
11/15/06
16:19
MSF
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/l
0.50
11/15/06
16:19
MSF
106-93-4
Dibromomethane
ND
ug/l
0.50
11/15/06
16:19
MSF
74-95-3
1,2-Dichlorobenzene
ND
ug/l
0.50
11/15/06
16:19
MSF
95-50-1
1,3-Dichlorobenzene
ND
ug/l
0.50
11/15/06
16:19
MSF
541.73-1
1,4-Dichlorobenzene
. ND
ug/l
0.50
11/15/06
16:19
MSF
106-46-7
Dichlorodifluoromethane
ND
ug/l
1.0
11/15/06
16:19
MSF
75-71-8
1,1-Dichloroethane
ND
ug/1
0.50
11/15/06
16:19
MSF
75-34-3
1,2-Dichloroethane
ND
ug/l
0.50
11/15/06
16:19
MSF
107-06-2
1.1-Dichloroethene
ND
ug/l
0.50
11/15/06
16:19
MSF
75-35-4
cis-1,2-Dichloroethene
ND
ug/l
0.50
11/15/06
16:19
MSF
156-59-2
trans-1,2-Dichloroethene
ND
ug/l
0.50
11/15/06
16:19
MSF
156-60-5
1,2-Dichloropropane
ND
ug/l
0.50
11/15/06
16:19
MSF
78-87-5
1,3-Dichloropropane
ND
ug/l
0.50
11/15/06
16:19
MSF
142-28-9
2,2-Dichloropropane
ND
ug/l
0.50
11/15/06
16:19
MSF
594-20-7
1.1-Dichloropropene
ND
ug/l
0.50
11/15/06
16:19
MSF
563-58-6
cis-1,3-Dichloropropene
ND
ug/l
0.50
11/15/06
16:19
MSF
10061-01.5
trans-1,3-Dichloropropene
ND
ug/l
0.50
11/15/06
16:19
MSF
10061-02-6
Diisopropyl ether
ND
ug/l
0.50
11/15/06
16:19
MSF
108-20-3
Ethylbenzene
ND
ug/1
0.50
11/15/06
16:19
MSF
100-41-4
Hexachloro-1,3-butadiene
ND
ug/l
2.0
11/15/06
16:19
MSF
87-68-3
Isopropylbenzene (Cumene)
ND
ug/l
0.50
11/15/06
16:19
MSF
98-82-8
p-Isopropyltoluene
ND
ug/1
0.50
11/15/06
16:19
MSF
99-87-6
Methylene chloride
ND
ug/l
2.0
11/15/06
16:19
MSF
75-09-2
Methyl-tert-butyl ether
ND
ug/l
0.50
11/15/06
16:19
MSF
1634-04-4
Naphthalene
ND
ug/l
2.0
11/15/06
16:19
MSF
91-20-3
n-Propylbenzene
ND
ug/1
0.50
11/15/06
16:19
MSF
103-65-1
Styrene
ND
ug/l
0.50
11/15/06
16:19
MSF
100-42-5
1,1,1.2-Tetrachloroethane
ND
ug/l
0.50
11/15/06
16:19
MSF
630-20-6
1,1,2.2-Tetrachloroethane
ND
ug/l
0.50
11/15/06
16:19
MSF
79-34-5
Tetrachloroethene
ND
ug/1
0.50
11/15/06
16:19
MSF
127-18-4
Toluene
ND
ug/1
0.50
11/15/06
16:19
MSF
108-88-3
1,2,3-Trichlorobenzene
ND
ug/l
2.0
11/15/06
16:19
MSF
87-61.6
1,2,4-Trichlorobenzene
ND
ug/l
2.0
11/15/06
16:19
MSF
120-82-1
1,1,1-Trichloroethane
ND
ug/l
0.50
11/15/06
16:19
MSF
71-55-6
Date: 11/22/06
Page: 2 of 38
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
Sc
99006
FL NELAP
E87648
FL NELAP
E87627
W��%/.�■�{Ay ■■A'J//��

ace Analytical °
www.patelabs.com
Lab Sample No: 927662213
Client Sample ID: MW-02R
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax., 704.875.9091
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-001 Date Collected: 11/09/06 10:57
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual Re9Lmt
1,1,2-Trichloroethane
ND
ug/l
0.50
11/15/06
16:19
MSF
79.00.5
Trichloroethene
ND
ug/l
0.50
11/15/06
16:19
MSF
79-01.6
Trichlorofluoromethane
ND
ug/l
1.0
11/15/06
16:19
MSF
75-69-4
1,2,3-Trichloropropane
ND
ug/l
0.50
11/15/06
16:19
MSF
96-18-4
1,2,4-Trimethylbenzene
ND
ug/l
0.50
11/15/06
16:19
MSF
95-63-6
1,3,5-Trimethylbenzene
ND
ug/l
0.50
11/15/06
16:19
MSF
108-67-8
Vinyl chloride
ND
ug/l
1.0
11/15/06
16:19
MSF
75-01-4
m&p-Xylene
ND
ug/l
1.0
11/15/06
16:19
MSF
o-Xylene
ND
ug/l
0.50
11/15/06
16:19
MSF
95-47-6
Toluene-d8 (S)
99
%
11/15/06
16:19
MSF
2037-26-5
4-Bromofluorobenzene (S)
97
%
11/15/06
16:19
MSF
460-00-4
Dibromofluoromethane (S)
102
%
11/15/06
16:19
MSF
1868-53-7
1,2-Dichloroethane-d4 (S)
99
%
11/15/06
16:19
MSF
17060-07-0
Date: 11/22/06
Asheville Certification IN REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712
Sc 99030 without the written consent of Pace Analytical Services, Inc.
FL NELAP E87648
Page: 3 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

ace Analytical °
www.pacelabs.com
Lab Sample No: 927662296
Client Sample ID: MW-04
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax:[phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-002 Date Collected: 11/09/06 10:10
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual Re9Lmt
Microbiology
Fecal Coliform MPN Water
Method: SM
9223
Coliform. Fecal
<1.1 mpn/100mL
11/09/06
16:00
JGJ
Wet Chemistry
Total Dissolved Solids
Method: EPA
160.1
Total Dissolved Solids
180
mg/l
20.
11/14/06
15:00
TMR
Chloride (Mercuric Nitrate)
Method: EPA
325.2
Chloride
6.9
mg/l
5.0
11/12/06
10:58
JDA1
16887-00-6
Ammonia
Method: EPA
350.1
Nitrogen. Ammonia
ND
mg/l
0.10
11/10/06
18:32
NIW
7727-37-9
48 Hour NO3 / NO2 / NOX
Method: EPA
353.2
Nitrate as N
NO
mg/l
0.10
11/09/06
21:40
JDA1
Sulfate.Turbidimetric
Method: EPA
375.4
Sulfate
26.
mg/l
5.0
11/14/06
12:06
TMR
Total Organic Carbon
Method: SM
5310B
Total Organic Carbon
8.8
mg/l
1.0
11/10/06
13:13
JDA1
7440-44-0
GUMS Vol ati l es
SM 6210D VOCs
Method: SM
6210D
Benzene
NO
ug/l
0.50
11/15/06
17:30
MSF
71-43-2
Bromobenzene
NO
ug/l
0.50
11/15/06
17:30
MSF
108-86-1
Bromochloromethane
NO
ug/l
0.50
11/15/06
17:30
MSF
74-97-5
Bromodichloromethane
NO
ug/l
0.50
11/15/06
17:30
MSF
75-27-4
Bromoform
NO
ug/l
0.50
11/15/06
17:30
MSF
75-25-2
Bromomethane
NO
ug/l
0.50
11/15/06
17:30
MSF
74-83-9
n-Butylbenzene
NO
ug/l
0.50
11/15/06
17:30
MSF
104-51-8
sec-Butylbenzene
NO
ug/l
0.50
11/15/06
17:30
MSF
135-98-8
tert-Butylbenzene
NO
ug/l
0.50
11/15/06
17:30
MSF
98-06-6
tert-Butyl Formate
ND
ug/l
20.
11/15/06
17:30
MSF
762-75-4
Carbon tetrachloride
NO
ug/l
0.50
11/15/06
17:30
MSF
56-23-5
Chlorobenzene
NO
ug/l
0.50
11/15/06
17:30
MSF
108-90-7
Chloroethane
NO
ug/l
1.0
11/15/06
17:30
MSF
75-00-3
Chloroform
NO
ug/l
0.50
11/15/06
17:30
MSF
67-66-3
Date: 11/22/06
Page: 4 of 38
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
SC
99006
FL NELAP
E87648
tiE�( AC>op�9y
FL NELAP
E87627
W
�!he hc;t

ace Analytical °
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone. [phone]
Fax.- 828.252.4618
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Lab Sample No: 927662296 Project: Sample Number: 92131825-002 Date Collected: 11/09/06 10:10
Client Sample ID: MW-04 Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
BY
CAS No. Qual RegLmt
Chloromethane
ND
ug/l
1.0
11/15/06
17:30
MSF
74-87-3
2-Chlorotoluene
ND
ug/l
0.50
11/15/06
17:30
MSF
95-49-8
4-Chlorotoluene
ND
ug/l
0.50
11/15/06
17:30
MSF
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/1
1.0
11/15/06
17:30
MSF
96-12-8
Dibromochloromethane
ND
ug/l
0.50
11/15/06,
17:30
MSF
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/l
0.50
11/15/06
17:30
MSF
106-93-4
Dibromomethane
ND
ug/l
0.50
11/15/06
17:30
MSF
74-95-3
1,2-Dichlorobenzene
ND
ug/l
0.50
11/15/06
17:30
MSF
95-50-1
1,3-Dichlorobenzene
ND
ug/l
0.50
11/15/06
17:30
MSF
541-73-1
1,4-Dichlorobenzene
ND
ug/1
0.50
11/15/06
17:30
MSF
106-46-7
Dichlorodifluoromethane
ND
ug/l
1.0
11/15/06
17:30
MSF
75-71-8
1,1-Dichloroethane
ND
ug/l
0.50
11/15/06
17:30
MSF
75-34-3
1,2-Dichloroethane
ND
ug/l
0.50
11/15/06
17:30
MSF
107-06-2
1.1-Dichloroethene
ND
ug/l
0.50
11/15/06
17:30
MSF
75-35-4
cis-1,2-Dichloroethene
ND
ug/l
0.50
11/15/06
17:30
MSF
156-59-2
trans-1,2-Dichloroethene
ND
ug/l
0.50
11/15/06
17:30
MSF
156-60-5
1,2-Dichloropropane
ND
ug/l
0.50
11/15/06
17:30
MSF
78-87-5
1,3-Dichloropropane
ND
ug/l
0.50
11/15/06
17:30
MSF
142-28-9
2,2-Dichloropropane
ND
ug/l
0.50
11/15/06
17:30
MSF
594-20-7
1,1-Dichloropropene
ND
ug/l
0.50
11/15/06
17:30
MSF
563-58-6
cis-1,3-Dichloropropene
ND
ug/l
0.50
11/15/06
17:30
MSF
10061-01-5
trans-1,3-Dichloropropene
ND
ug/l
0.50
11/15/06
17:30
MSF
10061-02-6
Diisopropyl ether
ND
ug/l
0.50
11/15/06
17:30
MSF
108-20-3
Ethylbenzene
ND
ug/l
0.50
11/15/06
17:30
MSF
100-41-4
Hexachloro-1,3-butadiene
ND
ug/l
2.0
11/15/06
17:30
MSF
87-68-3
Isopropylbenzene (Cumene)
ND
ug/1
0.50
11/15/06
17:30
MSF
98-82-8
p-Isopropyltoluene
ND
ug/l
0.50
11/15/06
17:30
MSF
99-87-6
Methylene chloride
ND
ug/l
2.0
11/15/06
17.:30
MSF
75-09-2
Methyl-tert-butyl ether
ND
ug/l
0.50
11/15/06
17:30
MSF
1634-04-4
Naphthalene
ND
ug/l
2.0
11/15/06
17:30
MSF
91-20-3
n-Propylbenzene
ND
ug/l
0.50
11/15/06
17:30
MSF
103-65-1
Styrene
ND
ug/l
0.50
11/15/06
17:30
MSF
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/l
0.50
11/15/06
17:30
MSF
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/l
0.50
11/15/06
17:30
MSF
79-34-5
Tetrachloroethene
ND
ug/l
0.50
11/15/06
17:30
MSF
127-18-4
Toluene
ND
ug/l
0.50
11/15/06
17:30
MSF
108-88-3
1,2,3-Trichlorobenzene
ND
ug/l
2.0
11/15/06
17:30
MSF
87-61-6
1,2,4-Trichlorobenzene
ND
ug/l
2.0
11/15/06
17:30
MSF
120-82-1
1,1.1-Trichloroethane
ND
ug/l
0.50
11/15/06
17:30
MSF
71-55-6
Date: 11/22/06
Page: 5 of 38
Asheville Certification IN
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IN
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
Sc
99006
FL NELAP
E87648
„ ACCOq�
FL NELAP
E87627

ace Analytical °
www.pacelabs.com
Lab Sample No: 927662296
Client Sample ID: MW-04
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-002 Date Collected: 11/09/06 10:10
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
1,1,2-Trichloroethane
ND
ug/l
0.50
11/15/06
17:30
MSF
79-00-5
Trichloroethene
ND
ug/l
0.50
11/15/06
17:30
MSF
79-01-6
Trichlorofluoromethane
ND
ug/l
1.0
11/15/06
17:30
MSF
75-69-4
1,2,3-Trichloropropane
ND
ug/l
0.50
11/15/06
17:30
MSF
96-18-4
1,2,4-Trimethylbenzene
ND
ug/l
0.50
11/15/06
17:30
MSF
95-63-6
1,3,5-Trimethylbenzene
ND
ug/1
0.50
11/15/06
17:30
MSF
108-67-8
Vinyl chloride
ND
ug/1
1.0
11/15/06
17:30
MSF
75-01-4
m&p-Xylene
ND
ug/l
1.0
11/15/06
17:30
MSF
o-Xylene
ND
ug/l
0.50
11/15/06
17:30
MSF
95-47-6
Toluene -dB (S)
98
%
11/15/06
17:30
MSF
2037-26-5
4-Bromofluorobenzene (S)
101
%
11/15/06
17:30
MSF
460-00-4
Dibromofluoromethane (S)
102
%
11/15/06
17:30
MSF
1868-53-7
1,2-Dichloroethane-d4 (S)
100
%
11/15/06
17:30
MSF
17060-07-0
Date: 11/22/06
Asheville Certification IN REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
Sc 99030 without the written consent of Pace Analytical Services, Inc.
FL NELAP E87648
Page: 6 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

ace Analytical
www.pacelabs.com
Lab Sample No: 927662304
Client Sample ID: MW-05
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Hunters ville, NC 28078
Phone: [phone]
Fax., 704.875.9091
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax:[phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-003 Date Collected: 11/09/06 12:32
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results Units
Report Limit
Analyzed
By
CAS.No. Qual RegLmt
Microbiology
Fecal Coliform MPN Water
Method:
SM 9223
Coliform, Fecal
<1.1 mpn/100ml-
11/09/06
17:45
JGJ
Wet Chemistry
Total Dissolved Solids
Method:
EPA 160.1
Total Dissolved Solids
90.
mg/l
20.
11/14/06
15:00
TMR
Chloride (Mercuric Nitrate)
Method:
EPA 325.2
Chloride
37.
mg/1
5.0
11/12/06
10:58
JDA1
16887-00.6
Ammonia
Method:
EPA 350.1
Nitrogen, Ammonia
ND
mg/l
0.10
11/10/06
18:42
NIW
7727-37-9
48 Hour NO3 / NO2 / NOX
Method:
EPA 353.2
Nitrate as N
0.20 mg/l
0.10
11/09/06
21:40
JDA1
Sulfate,Turbidimetric
Method:
EPA 375.4
Sulfate
ND
mg/l
5.0
11/14/06
12:06
TMR•
Total Organic Carbon
Method:
SM 5310B
Total Organic Carbon
1.3 mg/1
1.0
11/10/06
13:13
JDA1
7440-44-0
GUMS Vol ati l es
SM 6210D VOCs
Method:
SM 6210D
Benzene
ND
ug/1
0.50
11/15/06
17:54
MSF
71-43-2
Bromobenzene
ND
ug/1
0.50
11/15/06
17:54
MSF
108-86-1
Bromochloromethane
NO
ug/l
0.50
11/15/06
17:54
MSF
74-97-5
Bromodichloromethane
NO
ug/l
0.50
11/15/06
17:54
MSF
75-27-4
Bromoform
ND
ug/l
0.50
11/15/06
17:54
MSF
75-25-2
Bromomethane
ND
ug/l
0.50
11/15/06
17:54
MSF
74-83-9
n-Butylbenzene
ND
ug/1
0.50
11/15/06
17:54
MSF
104-51-8
.sec-Butylbenzene
ND
ug/1
0.50
11/15/06
17:54
MSF
135-98-8
tert-Butylbenzene
ND
ug/l
0.50
11/15/06
17:54
MSF
98-06-6
tert-Butyl Formate
NO
ug/l
20.
11/15/06
17:54
MSF
762-75-4
Carbon tetrachloride
ND
ug/l
0.50
11/15/06
17:54
MSF
56-23-5
Chlorobenzene
ND
ug/l
0.50
11/15/06
17:54
MSF
108-90-7
Chloroethane
ND
ug/l
1.0
11/15/06
17:54
MSF
75-00-3
Chloroform
ND
ug/l
0.50
11/15/06
17:54
MSF
67-66-3
Date: 11/22/06
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
SC 99030 without the written consent of Pace Analytical Services, Inc.
FL NELAP E87648
-i�ehc
Page: 7 of 3e
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

ace Analytical °
www.pacelahs.com
Lab Sample No: 927662304
Client Sample ID: MW-05
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax. [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: 828.252!4618
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-003 Date Collected: 11/09/06 12:32
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual Re9Lmt
Chloromethane
ND
ug/l
1.0
11/15/06
17:54
MSF
74-87-3
2-Chlorotoluene
ND
ug/l
0.50
11/15/06
17:54
MSF
95-49-8
4-Chlorotoluene
ND
ug/l
0.50
11/15/06
17:54
MSF
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/l
1.0
11/15/06
17:54
MSF
96-12-8
Dibromochloromethane
ND
ug/l
0.50
11/15/06
17:54
MSF
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/l
0.50
11/15/06
17:54
MSF
106-93-4
Dibromomethane
ND
ug/l
0.50
11/15/06
17:54
MSF
74-95-3
1,2-Dichlorobenzene
ND
ug/l
0.50
11/15/06
17:54
MSF
95-50-1
1,3-Dichlorobenzene
ND
ug/l
0.50
11/15/06
17:54
MSF
541-73-1
1,4-Dichlorobenzene
ND
ug/l
0.50
11/15/06
17:54
MSF
106-46-7
Dichlorodifluoromethane
ND
ug/l
1.0
11/15/06
17:54
MSF
75-71-8
1,1-Dichloroethane
ND
ug/l
0.50
11/15/06
17:54
MSF
75-34-3
1,2-Dichloroethane
ND
ug/l
0.50
11/15/06
17:54
MSF
107-06-2
1,1-Dichloroethene
ND
ug/l
0.50
11/15/06
17:54
MSF
75-35-4
cis-1,2-Dichloroethene
67.
ug/l
0.50
11/15/06
17:54'MSF
156-59-2
trans-1,2-Dichloroethene
c,L,9.61
ug/l
0.50
11/15/06
17:54
MSF
156-60-5
1,2-Dichloropropane
ND
ug/l
0.50
11/15/06
17:54
MSF
78-87-5
1,3-Dichloropropane
ND
ug/l
0.50
11/15/06
17:54
MSF
142-28-9
2,2-Dichloropropane
ND
ug/l
0.50
11/15/06
17:54
MSF
594-20-7
1,1-Dichloropropene
ND
ug/l
0.50
11/15/06
17:54
MSF
563-58-6
cis-1,3-Dichloropropene
ND
ug/l
0.50
11/15/06
17:54
MSF
10061-01-5
trans-1,3-Dichloropropene
ND
ug/l
0.50
11/15/06
17:54
MSF
10061-02-6
Diisopropyl ether
ND
ug/l
0.50
11/15/06
17:54
MSF
108-20-3
Ethylbenzene
ND
ug/l
0.50
11/15/06
17:54
MSF
100-41-4
Hexachloro-1,3-butadiene
ND
ug/l
2.0
11/15/06
17:54
MSF
87-68-3
Isopropylbenzene (Cumene)
ND
ug/l
0.50
11/15/06
17:54
MSF
98-82-8
p-Isopropyltoluene
ND
ug/l
0.50
11/15/06
17:54
MSF
99-87-6
Methylene chloride
ND
ug/l
2.0
11/15/06
17:54
MSF
75-09-2
Methyl-tert-butyl ether
ND
ug/l
0.50
11/15/06
17:54
MSF
1634-04-4
Naphthalene
ND
ug/l
2.0
11/15/06
17:54
MSF
91-20-3
n-Propylbenzene
ND
ug/l
0.50
11/15/06
17:54
MSF
103-65-1
Styrene
ND
ug/l
0.50
11/15/06
17:54
MSF
100.42-5
1,1,1,2-Tetrachloroethane
ND
ug/l
0.50
11/15/06
17:54
MSF
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/l
0.50
11/15/06
17:54
MSF
79-34-5
Tetrachloroethene
350
ug/l
2.5
11/15/06
17:54
MSF
127-18-4
Toluene
ND
ug/l
0.�0
11/15/06
17:54
MSF
108-88-3
1,2,3-Trichlorobenzene
ND
ug/l
2.0
11/15/06
17:54
MSF
87-61-6
1,2,4-Trichlorobenzene
ND
ug/l
2.0
11/15/06
17:54
MSF
120-82-1
1,1,1-Trichloroethane
ND
ug/l
0.50
11/15/06
17:54
MSF
71-55-6
Date: 11/22/06
Page: 8 of 38
Asheville Certification IN
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
Sc
99006
FL NELAP
E87648
FL NELAP
E87627
]��.//9,J,►cam
^�

aceAnalytical
www.pacelabs.com
Lab Sample No: 927662304
Client Sample ID: MW-05
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax. [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-003 Date Collected: 11/09/06 12:32
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
1,1.2-Trichloroethene
ND
ug/l
0.50
11/15/06
17:54
MSF
Trichloroethene
74.
ug/l
0.50
11/15/06
17:54
MSF
Trichlorofluoromethane
ND
ug/l
1.0
11/15/06
17:54
MSF
1,2,3-Trichloropropane
ND
ug/l
0.50
11/15/06
17:54
MSF
1,2,4-Trimethylbenzene
ND
ug/l
0.50
11/15/06
17:54
MSF
1.3,5-Trimethylbenzene
ND
ug/l
0.50
11/15/06
17:54
MSF
Vinyl chloride
.1.2
ug/l
1.0
11/15/06
17:54
MSF
m&p-Xylene
ND
ug/l
1.0
11/15/06
17:54
MSF
o-Xylene
ND
ug/l
0.50
11/15/06
17:54
MSF
Toluene-d8 (S)
99
%
11/15/06
17:54
MSF
4-Bromofluorobenzene (S)
98
%
11/15/06
17:54
MSF
Dibromofluoromethane (S)
103
%
11/15/06
17:54
MSF
1,2-Dichloroethane-d4 (S)
100
%
11/15/06
17:54
MSF
Date: 11/22/06
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648
f
%t'YP_Iac�
CAS No. Qual RegLmt
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
75-01-4
95-47-6
2037-26-5
460-00-4
1868-53-7
17060-07-0
Page: 9 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

ace Analytical °
www.pacelabs.com
Lab Sample No: 927662312
Client Sample ID: MW-06
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax., 704.875.9091
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax., 828.252.4616
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-004 Date Collected: 11/09/06 11:47
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Microbiology
Fecal Coliform MPN Water
Method: SM 9223
Coliform, Fecal
<1.1 mpn/100mL
11/09/06
17:45
JGJ
Wet Chemistry
Total Dissolved Solids
Method: EPA
160.1
Total Dissolved Solids
54.
mg/l
20.
11/14/06
15:01
TMR
Chloride (Mercuric Nitrate)
Method: EPA
325.2
Chloride
11.
mg/1
5.0
11/12/06
10:58
JDA1
16887-00-6
Ammonia
Method: EPA
350.1
Nitrogen, Ammonia
0.18
mg/l
0.10
11/10/06
18:42
NIW
7727-37-9
48 Hour NO3 / NO2 / NOX
Method: EPA
353.2
Nitrate as N
0.20
mg/l
0.10
11/09/06
21:40
JDA1
Sulfate,Turbidimetric
Method: EPA
375.4
Sulfate
11.
mg/l
5.0
11/14/06
12:06
TMR
Total Organic Carbon
Method: SM 5310B
Total Organic Carbon
1.4
mg/l
1.0
11/14/06
11:15
JDA1
7440-44-0
GUMS Vol ati l es
SM 6210D VOCs
Method: SM 6210D
Benzene
NO
ug/l
0.50
11/16/06
11:38
MSF
71-43-2
Bromobenzene
NO
ug/l
0.50
11/16/06
11:38
MSF
108-86-1
Bromochloromethane
NO
ug/l
0.50
11/16/06
11:38
MSF
74-97-5
Bromodichloromethane
ND
ug/1
0.50
11/16/06
11:38
MSF
75-27-4
Bromoform
NO
ug/l
0.50
11/16/06
11:38
MSF
75-25-2
Bromomethane
NO
ug/l
0.50
11/16/06
11:38
MSF
74-83-9
n-Butylbenzene
ND
ug/l
0.50
11/16/06
11:38
MSF
104-51-8
sec-Butylbenzene
ND
ug/l
0.50
11/16/06
11:38
MSF
135-98-8
tert-Butylbenzene
NO
ug/l
0.50
11/16/06
11:38
MSF
98-06-6
tert-Butyl Formate
NO
ug/l
20.
11/16/06
11:38
MSF
762-75-4
Carbon tetrachloride
ND
ug/l
0.50
11/16/06
11:38
MSF
56-23-5
Chlorobenzene
NO
ug/1
0.50
11/16/06
11:38
MSF
108-90-7
Chloroethane
NO
ug/l
1.0
11/16/06
11:38
MSF
75-00-3
Chloroform
NO
ug/l
0.50
11/16/06
11:38
MSF
67-66-3
Date: 11/22/06
Page: 10 of 38
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
Sc
99006
FL NELAP
E87648
N _A°c°'°
FL NELAP
E87627

ace Analytical °
www.pacelabs.com
Lab Sample No: 927662312
Client Sample ID: MW-06
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax., 704.875.9091
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-004 Date Collected: 11/09/06 11:47
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual Re9Lmt
Chloromethane
ND
ug/l
1.0
11/16/06
11:38
MSF
74-87-3
2-Chlorotoluene
ND
ug/l
0.50
11/16/06
11:38
MSF
95-49-8
4-Chlorotoluene
ND
ug/l
0.50
11/16/06
11:38
MSF
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/l
1.0
11/16/06
11:38
MSF
96-12-8
Dibromochloromethane
ND
ug/1
0.50
11/16/06
11:38
MSF
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/l
0.50
11/16/06
11:38
MSF
106-93.4
Dibromomethane
ND
ug/l
0.50
11/16/06
11:38
MSF
74-95-3
1,2-Dichlorobenzene
ND
ug/l
0.50
11/16/06
11:38
MSF
95-50-1
1,3-Dichlorobenzene
ND
ug/l
0.50
11/16/06
11:38
MSF
541-73-1
1,4-Dichlorobenzene
ND
ug/l
0.50
11/16/06
11:38
MSF
106-46-7
Dichlorodifluoromethane
ND
ug/l
1.0
11/16/06
11:38
MSF
75-71-8
1,1-Dichloroethane
ND
ug/l
0.50
11/16/06
11:38
MSF
75-34-3
1,2-Dichloroethane
ND
ug/l
0.50
11/16/06
11:38
MSF
107-06-2
1.1-Dichloroethene
ND
ug/l
0.50
11/16/06
11:38
MSF
75-35-4
cis-1,2-Dichloroethene
ND
ug/l
0.50
11/16/06
11:38
MSF
156-59-2
trans-1,2-Dichloroethene
ND
ug/l
0.50
11/16/06
11:38
MSF
156-60-5
1,2-Dichloropropane
ND
ug/1
0.50
11/16/06
11:38
MSF
78-87-5
1,3-Dichloropropane
ND
ug/1
0.50
11/16/06
11:38
MSF
142-28-9
2,2-Dichloropropane
ND
ug/l
0.50
11/16/06
11:38
MSF
594-20-7
1,1-Dichloropropene
ND
ug/1
0.50
11/16/06
11:38
MSF
563-58-6
cis-1,3-Dichloropropene
ND
ug/l
0.50
11/16/06
11:38
MSF
10061-01-5
trans-1,3-Dichloropropene
ND
ug/l
0.50
11/16/06
11:38
MSF
10061-02-6
Diisopropyl ether
ND
ug/l
0.50
11/16/06
11:38
MSF
108-20-3
Ethylbenzene
ND
ug/l
0.50
11/16/06
11:38
MSF
100-41-4
Hexachloro-1,3-butadiene
ND
ug/l
2.0
11/16/06
11:38
MSF
87-68-3
Isopropylbenzene (Cumene)
ND
ug/l
0.50
11/16/06
11:38
MSF
98-82-8
p-Isopropyltoluene
ND
ug/l
0.50
11/16/06
11:38
MSF
99-87-6
Methylene chloride
ND
ug/l
2.0
11/16/06
11:38
MSF
75-09-2
Methyl-tert-butyl ether
ND
ug/l
0.50
11/16/06
11:38
MSF
1634-04-4
Naphthalene
ND
ug/l
2.0
11/16/06
11:38
MSF
91-20-3
n-Propylbenzene
ND
ug/l
0.50
11/16/06
11:38
MSF
103-65-1
Styrene
ND
ug/l
0.50
11/16/06
11:38
MSF
100-42-5
1,1,1,2-Tetrachl6roethane
ND
ug/l
0.50
11/16/06
11:38
MSF
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/l
0.50
11/16/06
11:38
MSF
79-34-5
Tetrachloroethene
ND
ug/1
0.50
11/16/06
11:38
MSF
127-18-4
Toluene
ND
ug/l
0.50
11/16/06
11:38
MSF
108-88-3
1,2,3-Trichlorobenzene
ND
ug/l
2.0
11/16/06
11:38
MSF
87-61-6
1,2,4-Trichlorobenzene
ND
ug/l
2.0
11/16/06
11:38
MSF
120-82-1
1,1,1-Trichloroethane
ND
ug/l
0.50
11/16/06
11:38
MSF
71-55-6
Date: 11/22/06
Page: 11 of 38
Asheville Certification IN
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IN
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
Sc
99006
FL NELAP
E87648
N Ac°°R°
FL NELAP
E87627
C
-Heiac4

aceAnalytical °
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Hunters ville, NC 28078
Phone: [phone]
Fax:[phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone., 828.254.7176
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Lab Sample No: 927662312 Project Sample Number: 92131825-004 Date Collected: 11/09/06 11:47
Client Sample ID: MW-06 Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
1,1,2-Trichloroethane
ND
ug/1
0.50
11/16/06
11:38
MSF
79-00-5
Trichloroethene
ND
ug/1
0.50
11/16/06
11:38
MSF
79-01-6
Trichlorofluoromethane
ND
ug/1
1.0
11/16/06
11:38
MSF
75-69-4
1,2,3-Trichloropropane
ND
ug/l
0.50
11/16/06
11:38
MSF
96-18-4
1,2,4-Trimethylbenzene
ND
ug/l
0.50
11/16/06
11:38
MSF
95-63-6
1,3,5-Trimethylbenzene
ND
ug/l
0.50
11/16/06
11:38
MSF
108-67-8
Vinyl chloride
ND
ug/l
1.0
11/16/06
11:38
MSF
75-01-4
m&p-Xylene
ND
ug/l
1.0
11/16/06
11:38
MSF
o-Xylene
ND
ug/l
0.50
11/16/06
11:38
MSF
95-47.6
Toluene-d8 (S)
98
%
11/16/06
11:38
MSF
2037-26-5
4-Bromofluorobenzene (S)
98
%
11/16/06
11:38
MSF
460-00-4
Dibromofluoromethane (S)
100
%
11/16/06
11:38
MSF
1868-53-7
1,2-Dichloroethane-d4 (S)
96
%
11/16/06
11:38
MSF
17060-07-0
Date: 11/22/06 Page: 12 of 38
Asheville Certification IN REPORT OF LABORATORY ANALYSIS Charlotte Certification IN
NC Wastewater 40 NC Wastewater 12
NC Drinking Water 37712 This report shall not be reproduced, except in full, NC Drinking Water 37706
without the written consent of Pace Analytical Services, Inc.
Sc 99030 Sc 99006
FL NELAP E87648 " a°° FL NELAP E87627

aceAnalytical °
www.pacelabs.com
Lab Sample No: 927662320
Client Sample ID: MW-07
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax., 828.252.4618
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-005 Date Collected: 11/09/06 13:35
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Microbiology
Fecal Coliform MPN Water
Method: SM 9223
Coliform, Fecal
<1.1 mpn/100ml-
11/09/06
17:45
JGJ
Wet Chemistry
Total Dissolved Solids
Method: EPA
160.1
Total Dissolved Solids
38.
mg/l
20.
11/14/06
15:01
TMR
Chloride (Mercuric Nitrate)
Method: EPA
325.2
Chloride
7.0
mg/1
5.0
11/12/06
11:04
JDA1
16887-00-6
Ammonia
Method: EPA
350.1
Nitrogen, Ammonia
ND
mg/l
0.10
11/10/06
19:19
NIW
7727-37-9
48 Hour NO3 / NO2 / NOX
Method: EPA
353.2
Nitrate as N
1.1
mg/l
0.10
11/10/06
06:48
EWS
Sulfate.Turbidimetric
Method: EPA
375.4
Sulfate
6.7
mg/l
5.0
11/14/06
12:11
TMR
Total Organic Carbon
Method: SM 5310B
Total Organic Carbon
1.9
mg/l
1.0
11/14/06
11:15
JDA1
7440-44-0
GUMS Vol ati l es
SM 6210D VOCs
Method: SM 6210D
Benzene
ND
ug/l
0.50
11/15/06
18:41
MSF
71-43-2
Bromobenzene
NO
ug/l
0.50
11/15/06
18:41
MSF
108-86-1
Bromochloromethane
NO
ug/l
0.50
11/15/06
18:41
MSF
74-97-5
Bromodichloromethane
NO
ug/l
0.50
11/15/06
18:41
MSF
75-27-4
Bromoform
NO
ug/l
0.50
11/15/06
18:41
MSF
75-25-2
Bromomethane
ND
ug/l
0.50
11/15/06
18:41
MSF
74-83-9
n-Butylbenzene
ND
ug/l
0.50
11/15/06
18:41
MSF
104-51-8
sec-Butylbenzene
ND
ug/l
0.50
11/15/06
18:41
MSF
135-98-8
tert-Butylbenzene
ND
ug/l
0.50
11/15/06
18:41
MSF
98-06-6
tert-Butyl Formate
ND
ug/l
20.
11/15/06
18:41
MSF
762-75-4
Carbon tetrachloride
ND
ug/l
0.50
11/15/06
18:41
MSF
56-23-5
Chlorobenzene
ND
ug/l
0.50
11/15/06
18:41
MSF
108-90-7
Chloroethane
ND
ug/l
1.0
11/15/06
18:41
MSF
75-00-3
Chloroform
ND
ug/l
0.50
11/15/06
18:41
MSF
67-66-3
Date: 11/22/06
Page: 13 of 3B
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
Sc
99006
FL NELAP
E87648
♦F� N ncgo'y
FL NELAP
E87627
� i�neIAt

aceAnalytical °
www.pacelabs.com
Lab Sample No: 927662320
Client Sample ID: MW-07
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax. [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-005 Date Collected: 11/09/06 13:35
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Chloromethane
ND
ug/l
1.0
11/15/06
18:41
MSF
74-87-3
2-Chlorotoluene
ND
ug/l
0.50
11/15/06
18:41
MSF
95-49-8
4-Chlorotoluene
ND
ug/l
0.50
11/15/06
18:41
MSF
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/l
1.0
11/15/06
18:41
MSF
96-12-8
Dibromochloromethane
ND
ug/l
0.50
11/15/06
18:41
MSF
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/l
0.50
11/15/06
18:41
MSF
106-93-4
Dibromomethane
ND
ug/l
0.50
11/15/06
18:41
MSF
74-95-3
1,2-Dichlorobenzene
ND
ug/l
0.50
11/15/06
18:41
MSF
95-50-1
1,3-Dichlorobenzene
ND
ug/l
0.50
11/15/06
18:41
MSF
541-73-1
1,4-Dichlorobenzene
ND
ug/l
0.50
11/15/06
18:41
MSF
106-46-7
Dichlorodifluoromethane
ND
ug/l
1.0
11/15/06
18:41
MSF
75-71-8
1,1-Dichloroethane
ND
ug/l
0.50
11/15/06
18:41
MSF
75-34-3
1,2-Dichloroethane
ND
ug/l
0.50
11/15/06
18:41
MSF
107-06-2
1,1-Dichloroethene
ND
ug/l
0.50
11/15/06
18:41
MSF
75-35-4
cis-1,2-Dichloroethene
ND
ug/l
0.50
11/15/06
18:41
MSF
156-59-2
trans-1,2-Dichloroethene
ND
ug/l
0.50
11/15/06
18:41
MSF
156-60-5
1,2-Dichloropropane
ND
ug/l
0.50
11/15/06
18:41
MSF
78-87-5
1,3-Dichloropropane
ND
ug/l
0.50
11/15/06
18:41
MSF
142-28-9
2,2-Dichloropropane
ND
ug/l
0.50
11/15/06
18:41
MSF
594-20-7
1,1-Dichloropropene
ND
ug/l
0.50
11/15/06
18:41
MSF
563-58-6
cis-1,3-Dichloropropene
ND
ug/l
0.50
11/15/06
18:41
MSF
10061-01-5
trans-1,3-Dichloropropene
ND
ug/l
0.50
11/15/06
18:41
MSF
10061-02-6
Diisopropyl ether
ND
ug/l
0.50
11/15/06
18:41
MSF
108-20-3
Ethylbenzene
ND
ug/l
0.50
11/15/06
18:41
MSF
100-41-4
Hexachloro-1,3-butadiene
ND
ug/l
2.0
11/15/06
18:41
MSF
87-68-3
Isopropylbenzene (Cumene)
ND
ug/l
0.50
11/15/06
18:41
MSF
98-82-8
p-Isopropyltoluene
ND
ug/l
0.50
11/15/06
18:41
MSF
99-87-6
Methylene chloride
ND
ug/l
2.0
11/15/06
18:41
MSF
75-09-2
Methyl-tert-butyl ether
ND
ug/l
0.50
11/15/06
18:41
MSF
1634-04-4
Naphthalene
ND
ug/l
2.0
11/15/06
18:41
MSF
91-20-3
n-Propylbenzene
ND
ug/l
0.50
11/15/06
18:41
MSF
103-65-1
Styrene
ND
ug/l
0.50
11/15/06
18:41
MSF
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/l
0.50
11/15/06
18:41
MSF
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/l
0.50
11/15/06
18:41
MSF
79-34-5
Tetrachloroethene
ND
ug/l
0.50
11/15/06
18:41
MSF
127-18-4
Toluene
ND
ug/l
0.50
11/15/06
18:41
MSF
108-88-3
1,2,3-Trichlorobenzene
ND
ug/l
2.0
11/15/06
18:41
MSF
87-61-6
1,2,4-Trichlorobenzene
ND
ug/l
2.0
11/15/06
18:41
MSF
120-82-1
1,1,1-Trichloroethane
ND
ug/l
0.50
11/15/06
18:41
MSF
71-55-6
Date: 11/22/06
Page: 14 of 38
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
Sc
99006
FL NELAP
E87648
N`pZIP.
FL NELAP
E87627

ace Analytical °
www.pacelahs.com
Lab Sample No: 927662320
Client Sample ID: MW-07
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax. [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-005 Date Collected: 11/09/06 13:35
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual Re9Lmt
1,1,2-Trichloroethane
ND
ug/l
0.50
11/15/06
18:41
MSF
79-00-5
Trichloroethene
ND
ug/l
0.50
11/15/06
18:41
MSF
79-01.6
Trichlorofluoromethane
ND
ug/1
1.0
11/15/06
18:41
MSF
75-69-4
1.2.3-Trichloropropane
ND
ug/l
0.50
11/15/06
18:41
MSF
96-18-4
1,2,4-Trimethylbenzene
ND
ug/l
0.50
11/15/06
18:41
MSF
95-63-6
1,3,5-Trimethylbenzene
ND
ug/l
0.50
11/15/06
18:41
MSF
108-67-8
Vinyl chloride
ND
ug/l
1.0
11/15/06
18:41
MSF
75-01-4
m&p-Xylene
ND
ug/l
1.0
11/15/06
18:41
MSF
o-Xylene
ND
ug/l
0.50
11/15/06
18:41
MSF
95-47-6
Toluene-d8 (S)
98
%
11/15/06
18:41
MSF
2037-26-5
4-Bromofluorobenzene (S)
98
%
11/15/06
18:41
MSF
460-00-4
Dibromofluoromethane (S)
100
%
11/15/06
18:41
MSF
1868-53-7
1,2-Dichloroethane-d4 (S)
100
%
11/15/06
18:41
MSF
17060-07-0
Date: 11/22/06
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648 N AC�pq
Page: 15 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

aceAnalyfical °
www.pacelabs.com
Lab Sample No: 927662338
Client Sample ID: MW-08 .
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone. [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-006 Date Collected: 11/09/06 14:20
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Microbiology
Fecal Coliform MPN Water
Method: SM 9223
Coliform, Fecal
<1.1 mpn/100mL
11/09/06
17:45
JGJ
Wet Chemistry
Total Dissolved Solids
Method: EPA
160.1
Total Dissolved Solids
96.
mg/1
20.
11/14/06
15:02
TMR
Chloride (Mercuric Nitrate)
Method: EPA
325.2
Chloride
12.
mg/l
5.0
11/12/06
11:04
JDA1
16887-00-6
Ammonia
Method: EPA
350.1
Nitrogen, Ammonia
NO
mg/l
0.10
11/10/06
19:19
NIW
7727-37-9
48 Hour NO3 / NO2 / NOX
Method: EPA
353.2
Nitrate as N
0.97
mg/l
0.10
11/10/06
06:48
EWS
Sulfate,Turbidimetric
Method: EPA
375.4
Sulfate
7.7
mg/1
5.0
11/14/06
12:12
TMR
Total Organic Carbon
Method: SM 5310B
Total Organic Carbon
4.7
mg/l
1.0
11/14/06
11:15
JDA1
7440-44-0
GUMS Vol ati l es
SM 6210D VOCs
Method: SM 6210D
Benzene
ND
ug/l
0.50
11/16/06
00:52
MSF
71-43-2
Bromobenzene
NO
ug/1
0.50
11/16/06
00:52
MSF
108-86-1
Bromochloromethane
NO
ug/l
0.50
11/16/06
00:52
MSF
74-97-5
Bromodichloromethane
NO
ug/l
0.50
11/16/06
00:52
MSF
75.27-4
Bromoform
NO
ug/l
0.50
11/16/06
00:52
MSF
75-25-2
Bromomethane
NO
ug/1
0.50
11/16/06
00:52
MSF
74-83-9
n-Butylbenzene
NO
ug/l
0.50
11/16/06
00:52
MSF
104-51-8
sec-Butylbenzene
NO
ug/l
0.50
11/16/06
00:52
MSF
135.98.8
tert-Butylbenzene
NO
ug/l
0.50
11/16/06
00:52
MSF
98-06-6
tert-Butyl Formate
NO
ug/1
20.
11/16/06
00:52
MSF
762-75-4
Carbon tetrachloride
NO
ug/l
0.50
11/16/06
00:52
MSF
56-23-5
Chlorobenzene
NO
ug/l
0.50
11/16/06
00:52
MSF
108-90-7
Chloroethane
NO
ug/1
1.0
11/16/06
00:52
MSF
75-00-3
Chloroform
NO
ug/1
0.50
11/16/06
00:52
MSF
67-66-3
Date: 11/22/06
Page: 16 of 38
Asheville certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IN
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
Sc
99006
FL NELAP
E87648
,E° Ac °"°4
FL NELAP
E87627

ace Analytical °
www.pacelabs.com
Lab Sample No: 927662338
Client Sample ID: MW-08
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-006 Date Collected: 11/09/06 14:20
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Chloromethane
ND
ug/l
1.0
11/16/06
00:52
MSF
74-87-3
2-Chlorotoluene
ND
ug/l
0.50
11/16/06
00:52
MSF
95-49-8
4-Chlorotoluene
ND
ug/l
0.50
11/16/06
00:52
MSF
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/l
1.0
11/16/06
00:52
MSF
96-12-8
Dibromochloromethane
ND
ug/l
0.50
11/16/06
00:52
MSF
124-48-1
1.2-Dibromoethane (EDB)
ND
ug/l
0.50
11/16/06
00:52
MSF
106-93.4
Dibromomethane
ND
ug/l
0.50
11/16/06
00:52
MSF
74-95-3
1,2-Dichlorobenzene
ND
ug/l
0.50
11/16/06
00:52
MSF
95-50-1
1,3-Dichlorobenzene
ND
ug/l
0.50
11/16/06
00:52
MSF
541-73-1
1,4-Dichlorobenzene
ND
ug/l
0.50
11/16/06
00:52
MSF
106-46-7
Dichlorodifluoromethane
ND
ug/1
1.0
11/16/06
00:52
MSF
75-71-8
1.1-Dichloroethane
ND
ug/1
0.50
11/16/06
00:52
MSF
75-34-3
1,2-Dichloroethane
ND
ug/l
0.50
11/16/06
00:52
MSF
107-06-2
1,1-Dichloroethene
ND
ug/l
0.50
11/16/06
00:52
MSF
75-35-4
cis-1,2-Dichloroethene
ND
ug/l
0.50
11/16/06
00:52
MSF
156-59-2
trans-1,2-Dichloroethene
ND
ug/l
0.50
11/16/06
00:52
MSF
156-60-5
1,2-Dichloropropane
ND
ug/l
0.50
11/16/06
00:52
MSF
78-87-5
1.3-Dichloropropane
ND
ug/l
0.50
11/16/06
00:52
MSF
142-28-9
2,2-Dichloropropane
ND
ug/1
0.50
11/16/06
00:52
MSF
594-20-7
1,1-Dichloropropene
ND
ug/1
0.50
11/16/06
00:52
MSF
563-58-6
cis-1,3-Dichloropropene
ND
ug/l
0.50
11/16/06
00:52
MSF
10061-01-5
trans-1,3-Dichloropropene
ND
ug/l
0.50
11/16/06
00:52
MSF
10061-02-6
Diisopropyl ether
ND
ug/1
0.50
11/16/06
00:52
MSF
108-20-3
Ethylbenzene
ND
ug/1
0.50
11/16/06
00:52
MSF
100-41-4.
Hexachloro-1,3-butadiene
ND
ug/l
2.0
11/16/06
00:52
MSF
87-68-3
Isopropylbenzene (Cumene)
ND
ug/l
0.50
11/16/06
00:52
MSF
98-82-8
p-Isopropyltoluene
ND
ug/l
0.50
11/16/06
00:52
MSF
99-87-6
Methylene chloride
ND
ug/l
2.0
11/16/06
00:52
MSF
75-09-2
Methyl-tert-butyl ether
ND
ug/l
0.50
11/16/06
00:52
MSF
1634-04-4
Naphthalene
ND
ug/1
2.0
11/16/06
00:52
MSF
91-20-3
n-Propylbenzene
ND
ug/l
0.50
11/16/06
00:52
MSF
103-65-1
Styrene
ND
ug/l
0.50
11/16/06
00:52
MSF
100-42.5
1,1,1,2-Tetrachloroethane
ND
ug/1
0.50
11/16/06
00:52
MSF
630.20.6
1,1,2,2-Tetrachloroethane
ND
ug/l
0.50
11/16/06
00:52
MSF
79-34-5
Tetrachloroethene
ND
ug/l
0.50
11/16/06
00:52
MSF
127-18-4
Toluene
ND
ug/l
0.50
11/16/06
00:52
MSF
108-88-3
1,2,3-Trichlorobenzene
ND
ug/1
2.0
11/16/06
00:52
MSF
87-61-6
1.2.4-Trichlorobenzene
ND
ug/l
2.0
11/16/06
00:52
MSF
120-82-1
1,1,1-Trichloroethane
ND
ug/l
0.50
11/16/06
00:52
MSF
71-55-6
Date: 11/22/06
Page: 17 of 38
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
SC
99030
without the written consent of Pace Analytical Services, Inc.
Sc
99006
FL NELAP
E87648
FL NELAP
E87627
Wc

aceAnalytical
www.pacelabs.com
Lab Sample No: 927662338
Client Sample ID: MW-08
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-006 Date Collected: 11/09/06 14:20
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
1,1,2-Trichloroethane
ND
ug/l
0.50
11/16/06
00:52
MSF
79-00-5
Trichloroethene
ND
ug/l
0.50
11/16/06
00:52
MSF
79-01-6
7richlorofluoromethane
ND
ug/l
1.0
11/16/06
00:52
MSF
75-69-4
1,2,3-Trichloropropane
ND
ug/l
0.50
11/16/06
00:52
MSF
96-18-4
1,2,4-Trimethylbenzene
ND
ug/l
0.50
11/16/06
00:52
MSF
95-63-6
1,3,5-Trimethylbenzene
ND
ug/l
0.50
11/16/06
00:52
MSF
108-67-8
Vinyl chloride
ND
ug/l
1.0
11/16/06
00:52
MSF
75-01-4
m&p-Xylene
ND
ug/l
1.0
11/16/06
00:52
MSF
o-Xylene
ND
ug/l
0.50
11/16/06
00:52
MSF
95-47-6
Toluene-d8 (S)
99
%
11/16/06
00:52
MSF
2037-26-5
4-Bromofluorobenzene (S)
97
%
11/16/06
00:52
MSF
460-00-4
Dibromofluoromethane (S)
98
%
11/16/06
00:52
MSF
1868-53-7
1,2-Dichloroethane-d4 (S)
99
%
11/16/06
00:52
MSF
17060-07-0
Date: 11/22/06
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
37712 This report shall not be reproduced, except in full,
NC Drinking Water
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648
Page: 18 of 38
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NC Wastewater 12
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1�ceAnalytical@
www.pacelabs.com
PARAMETER FOOTNOTES
Method 9071E modified to use ASE.
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax. [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
All pH, Free Chlorine, Total Chlorine and Ferrous Iron analyses conducted outside of EPA recommended immediate
hold time.
Depending on the moisture content the PRLs can be elevated for all soil samples reported on a dry weight basis.
2-Chloroethyl vinyl ether has been shown to degrade in the presence of acid.
ND Not detected at or above adjusted reporting limit
NC Not Calculable
J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
(S) Surrogate
Date: 11/22/06
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648 „ AC!pgo
W I Cf
it a";C
Page: 19 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627

ace Analytical °
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax. [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax., 828.252.4618
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
QC Batch: 172913 Analysis Method: SM 6210D
QC Batch Method: SM 6210D Analysis Description: SM 6210D VOCs
Associated Lab Samples: 927662213 927662296 927662304 927662312 927662320
METHOD BLANK: 927677062
Associated Lab Samples: 927662213 927662296 927662304 927662312 927662320
Blank
Reporting
Parameter
Units
Result
Limit Footnotes
Benzene
ug/l
ND
0.50
Bromobenzene
ug/l
NO
0.50
Bromochloromethane
ug/l
ND
0.50
Bromodichloromethane
ug/l
ND
0.50
Bromoform
ug/l
NO
0.50
Bromomethane
ug/l
ND
0.50
n-Butylbenzene
ug/l
ND
0.50
sec-Butylbenzene
ug/l
ND
0.50
tert-Butylbenzene
ug/l
ND
0.50
tert-Butyl Formate
ug/l
ND
20.
Carbon tetrachloride
ug/l
ND
0.50
Chlorobenzene
ug/l
ND
0.50
Chloroethane
ug/l
ND
1.0
Chloroform
ug/l
NO
0.50
Chloromethane
ug/l
NO
1.0
2-Chlorotoluene
ug/l
NO
0.50
4-Chlorotoluene
ug/l
ND
0.50
1.2-Dibromo-3-chloropropane
ug/l
ND
1.0
Dibromochloromethane
ug/l
ND
0.50
1,2-Dibromoethane (EDB)
ug/l
ND
0.50
Dibromomethane
ug/l
ND
0.50
1,2-Dichlorobenzene
ug/l
ND
0.50
1,3-Dichlorobenzene
ug/l
NO
0.50
1,4-Dichlorobenzene
ug/l
ND
0.50
Dichlorodifluoromethane
ug/l
ND
1.0
1,1-Dichloroethane
ug/l
ND
0.50
1,2-Dichloroethane
ug/l
NO
0.50
1,1-Dichloroethene
ug/l
ND
0.50
cis-1,2-Dichloroethene
ug/l
NO
0.50
trans-1,2-Dichloroethene
ug/l
NO
0.50
1,2-Dichloropropane
ug/l
ND
0.50
Date: 11/22/06
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648
Page: 20 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 2225 Riverside Drive
Huntersville, IVC 28078 Asheville, NC 28804
Analytical Phone: [phone] Phone: [phone]
in Fax: [phone] Fax: [phone]
www.pacelabs.com QUALITY CONTROL DATA
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
METHOD BLANK: 927677062
Associated Lab Samples: 927662213 927662296 927662304 927662312 927662320
Blank
Reporting
Parameter
Units
Result
Limit Footnotes
1,3-Dichloropropane
ug/l
NO
0.50
2.2-Dichloropropane
ug/l
NO
0.50
1,1-Dichloropropene
ug/l
ND
0.50
cis-1,3-Dichloropropene
ug/l
NO
0:50
trans-1.3-Dichloropropene
ug/l
NO
0.50
Diisopropyl ether
ug/l
NO
0.50
Ethylbenzene
ug/l
NO
0.50
Hexachloro-1,3-butadiene
ug/l
NO
2.0
Isopropylbenzene (Cumene)
ug/l
NO
0.50
p-Isopropyltoluene
ug/l
NO
0.50
Methylene chloride
ug/1
NO
2.0
Methyl-tert-butyl ether
ug/l
NO
0.50
Naphthalene
ug/l
NO
2.0
n-Propylbenzene
ug/l
NO
0.50
Styrene
ug/l
NO
0.50
1,1,1,2-Tetrachloroethane
ug/1
NO
0.50
1,1,2,2-Tetrachloroethane
ug/l
NO
0.50
Tetrachloroethene
ug/l
NO
0.50
Toluene
ug/l
NO
0.50
1.2,3-Trichlorobenzene
ug/l
ND
2.0
1,2,4-Trichlorobenzene
ug/l
ND
2.0
1,1,1-Trichloroethane
ug/l
NO
0.50
1,1,2-Trichloroethane
ug/l
ND
0.50
Trichloroethene
ug/l
NO
0.50
Trichlorofluoromethane
ug/l
NO
1.0
1,2,3-Trichloropropane
ug/l
NO
0.50
1,2,4-Trimethylbenzene
ug/l
ND
0.50
1,3,5-Trimethylbenzene
ug/l
ND
0.50
Vinyl chloride
ug/l
ND
1.0
m&p-Xylene
ug/l
NO
1.0
o-Xylene
ug/l
ND
0.50
Toluene-d8 (S)
%
100
4-Bromofluorobenzene (S)
%
98
Dibromofluoromethane (S)
%
103
1.2-Dichloroethane-d4 (S)
%
100
Date: 11/22/06
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648 N ACCggO
elRC\t
Page: 21 of 38
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 2225 Riverside Drive
Huntersville, NC 28078 Asheville, NC 28804
Analytical ® Phone: [phone] Phone: [phone]
Fax- 704.875.9091 Fax: [phone]
www.pacelabs.com QUALITY CONTROL DATA
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
LABORATORY CONTROL SAMPLE & LCSD: 927677070 927677088
Spike
LCS
LCSD
LCS
LCSD
Parameter
Units
Conc.
Result
Result
X Rec
% Rec
RPD Footnotes
Benzene
ug/l
10.00
10.73
10.60
107
106
1
Bromobenzene
ug/1.
10.00
10.44
10.21
104
102
2
Bromochloromethane
ug/l
10.00
10.78
11.00
108
110
2
Bromodichloromethane
ug/1
10.00
10.13
10.05
101
101
1
Bromoform
ug/1
10.00
9.950
10.25
100
103
3
Bromomethane
ug/l
10.00
12.40
12.29
124
123
1
n-Butylbenzene
ug/l
10.00
8.952
8.757
90
88
2
sec-Butylbenzene
ug/l
10.00
10.39
10.27
104
103
1
tert-Butylbenzene
ug/l
10.00
10.20
10.13
102
101
1
tert-Butyl Formate
ug/l
10.00
8.171
9.147
82
92
11
Carbon tetrachloride
ug/l
10.00
10.27
9.123
103
91
12
Chlorobenzene
ug/l
10.00
10.16
10.34
102
103
2
Chloroethane
ug/l
10.00
12.22
12.08
122
121
1
Chloroform
ug/l
10.00
10.14
10.77
101
108
6
Chloromethane
ug/l
10.00
10.07
10.03
101
100
0
2-Chlorotoluene
ug/l
10.00
10.01
9.952
100
100
1
4-Chlorotoluene
ug/l
10.00
10.20
10.01
102
100
2
1,2-Dibromo-3-chloropropane
ug/l
10.00
9.760
10.16
98
102
4
Dibromochloromethane
ug/l
10.00
9.724
9.881
97
99
2
1,2-Dibromoethane (EDB)
ug/l
10.00
9.864
10.25
99
102
4
Dibromomethane
ug/l
10.00
10.50
10.64
105
106
1
1,2-Dichlorobenzene
ug/l
10.00
10.06
9.988
101
100
1
1,3-Dichlorobenzene
ug/1
10.00
9.927
9.615
99
96
3
1,4-Dichlorobenzene
ug/l
10.00
9.756
9.933
98
99
2
Dichlorodifluoromethane
ug/1
10.00
8.828
8.411
88
84
5
1.1-Dichloroethane
ug/l
10.00
10.89
10.88
109
109
0
1,2-Dichloroethane
ug/1
10.00
10.18
10.19
102
102
0
1.1-Dichloroethene
ug/l
10.00
11.80
12.06
118
121
2
cis-1,2-Dichloroethene
ug/l
10.00
11.51
11.14
115
111
3
trans-1,2-Dichloroethene
ug/l
10.00
10.57
11.36
106
114
7
1,2-Dichloropropane
ug/l
10.00
10.73
11.02
107
110
3
1,3-Dichloropropane
ug/1
10.00
10.09
10.08
101
101
0
2,2-Dichloropropane
ug/l
10.00
7.889
7.761
79
78
2
1,1-Dichloropropene
ug/l
10.00
10.57
10.45
106
104
1
cis-1,3-Dichloropropene
ug/1
10.00
9.505
9.364
95
94
1
trans-1,3-Dichloropropene
ug/l
10.00
9.452
9.356
94
94
1
Diisopropyl ether
ug/l
10.00
10.36
10.23
104
102
1
Date: 11/22/06
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712
Sc 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648 " A"
E� % CFF ,q,,yC
° PIn r
Page: 22 of 38
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NC Wastewater 12
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FL NELAP E87627

aceAnalytical °
www.pacelahs.com
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Nuntersville, NC 28076
Phone: [phone]
Fax.- 704.875.9091
QUALITY CONTROL DATA
LABORATORY CONTROL SAMPLE & LCSD: 927677070 927677088
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Spike
LCS
LCSD
LCS
LCSD
Parameter
Units
Conc.
Result
Result
% Rec
X Rec
RPD Footnotes
Ethylbenzene
ug/l
10.00
10.07
10.14
101
101
1
Hexachloro-1.3-butadiene
ug/l
10.00
9.593
9.440
96
94
2
Isopropylbenzene (Cumene)
ug/l
10.00
10.29
10.42
103
104
1
p-Isopropyltoluene
ug/l
10.00
9.296
9.176
93
92
1
Methylene chloride
ug/l
10.00
9.948
10.17
100
102
2
Methyl-tert-butyl ether
ug/l
10.00
10.10
9.680
101
97
4
Naphthalene
ug/l
10.00
7.692
7.246
77
72
6
n-Propylbenzene
ug/l
10.00
10.25
10.14
102
101
1
Styrene
ug/l
10.00
10.60
10.41
106
104
2
1,1,1,2-Tetrachloroethane
ug/l
10.00
10.07
10.20
101
102
1
1,1,2,2-Tetrachloroethane
ug/l
10.00
9.138
9.443
91
94
3
Tetrachloroethene
ug/l
10:00
9.996
9.988
100
100
0
Toluene
ug/l
10.00
10.29
10.29
103
103
0
1,2,3-Trichlorobenzene
ug/l
10.00
9.772
9.538
98
95
2
1,2,4-Trichlorobenzene
ug/l
10.00
9.809
9.845
98
98
0
1,1,1-Trichloroethane
ug/l
10.00
10.83
10.73
108
107
1
1,1,2-Trichloroethane
ug/l
10.00
10.05
9.971
101
100
1
Trichloroethene
ug/l
10.00
11.01
10.68
110
107
3
Trichlorofluoromethane
ug/l
10.00
11.57
11.42
116
114
1
1,2,3-Trichloropropane
ug/l
10.00
9.997
10.20
100
102
2
1,2,4-Trimethylbenzene
ug/l
10.00
9.156
9.126
92
91
0
1,3,5-Trimethylbenzene
ug/l
10.00
9.414
9.255
94
93
2
Vinyl chloride
ug/l
10.00
9.823
9.624
98
96
2
m&p-Xylene
ug/l
20.00
20.72
20.50
104
102
1
o-Xylene
ug/l
10.00
10.13
10.35
101
103
2
Toluene-d8 (S)
99
99
4-Bromofluorobenzene (S)
100
99
Dibromofluoromethane (S)
101
99
1,2-Dichloroethane-d4 (S)
101
99
Date: 11/22/06
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 40
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648
Page: 23 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

ace Analytical °
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
QC Batch: 172990 Analysis Method: SM 6210D
QC Batch Method: SM 6210D Analysis Description: SM 6210D VOCs
Associated Lab Samples: 927662338
METHOD BLANK: 927682245
Associated Lab Samples: 927662338
Blank
Reporting
Parameter
Units
Result
Limit Footnotes
Benzene
ug/l
ND
0.50
Bromobenzene
ug/1
ND
0.50
Bromochloromethane
ug/l
ND
0.50
Bromodichloromethane
ug/l
ND
0.50
Bromoform
ug/l
ND
0.50
Bromomethane
ug/l
NO
0.50
n-Butylbenzene
ug/l
NO
0.50
sec-Butylbenzene
ug/l
NO
0.50
tert-Butylbenzene
ug/l
NO
0.50
tert-Butyl Formate
ug/l
NO
20.
Carbon tetrachloride
ug/l
ND
0.50
Chlorobenzene
ug/l
NO
0.50
Chloroethane
ug/l
ND
1.0
Chloroform
ug/l
ND
0.50
Chloromethane
ug/l
ND
1.0
2-Chlorotoluene
ug/l
NO
0.50
4-Chlorotoluene
ug/l
NO
0.50
1,2-Dibromo-3-chloropropane
ug/l
NO
1.0
Dibromochloromethane
ug/l
NO
0.50
1,2-Dibromoethane (EDB)
ug/l
NO
0.50
Dibromomethane
ug/l
NO
0.50
1,2-Dichlorobenzene
ug/l
NO
0.50
1,3-Dichlorobenzene
ug/l
ND
0.50
1,4-Dichlorobenzene
ug/l
NO
0.50
Dichlorodifluoromethane
ug/l
NO
1.0
1,1-Dichloroethane
ug/l
NO
0.50
1,2-Dichloroethane
ug/l
ND
0.50
1,1-Dichloroethene
ug/l
ND
0.50
cis-1,2-Dichloroethene
ug/l
NO
0.50
trans-1,2-Dichloroethene
ug/l
ND
0.50
1,2-Dichloropropane
ug/l
NO
0.50
Date: 11/22/06
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648 w pCCpq
W`4� ^ o*yam
Page: 24 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 2225 Riverside Drive
Nuntersville, NC 28078 Asheville, NC 28804
ace Analytical o Phone: [phone] Phone: [phone]
Fax., 704.875.9091 Fax: [phone]
www.pacelabs.com QUALITY CONTROL DATA
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
METHOD BLANK: 927682245
Associated Lab Samples: 927662338
Blank
Reporting
Parameter
Units
Result
Limit Footnotes
1,3-Dichloropropane
ug/l
ND
0.50
2,2-Dichloropropane
ug/l
ND
0.50
1,1-Dichloropropene
ug/l
NO
0.50
cis-1,3-Dichloropropene
ug/l
ND
0.50
trans-1,3-Dichloropropene
ug/l
ND
0.50
Diisopropyl ether
ug/l
ND
0.50
Ethylbenzene
ug/l
ND
0.50
Hexachloro-1.3-butadiene
ug/l
ND
2.0
Isopropylbenzene (Cumene)
ug/l
ND
0.50
p-Isopropyltoluene
ug/l
NO
0.50
Methylene chloride
ug/l
NO
2.0
Methyl-tert-butyl ether
ug/l
ND
0.50
Naphthalene
ug/l
ND
2.0
n-Propylbenzene
ug/l
NO
0.50
Styrene
ug/l
NO
0.50
1,1,1,2-Tetrachloroethane
ug/l
NO
0.50
1,1,2,2-Tetrachloroethane
ug/l
NO
0.50
Tetrachloroethene.
ug/l
NO
0.50
Toluene
ug/l
NO
0.50
1,2,3-Trichlorobenzene
ug/l
NO
2.0
1,2,4-Trichlorobenzene
ug/l
ND
2.0
1,1,1-Trichloroethane
ug/l
NO
0.50
1,1,2-Trichloroethane
ug/l
ND
0.50
Trichloroethene
ug/l
ND
0.50
Trichlorofluoromethane
ug/l
ND
1.0
1,2,3-Trichloropropane
ug/l
ND
0.50
1,2,4-Trimethylbenzene
ug/l
ND
0.50
1,3,5-Trimethylbenzene
ug/1
ND
0.50
Vinyl chloride
ug/l
ND
1.0
m&p-Xylene
ug/l
ND
1.0
o-Xylene
ug/l
ND
0.50
Toluene-d8 (S)
%
99
4-Bromofluorobenzene (S)
%
98
Dibromofluoromethane (S)
%
101
1,2-Dichloroethane-d4 (S)
%
101
Date: 11/22/06
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
SC 99030 without the written consent of Pace Analytical Services, Inc.
FL NELAP E87648 " Acc
�0��' rC o
Page: 25 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627
�,��Il Ci _ice

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 2225 Riverside Drive
Huntersville, NC 28078 Asheville, NC 28804
Analytical ® Phone: [phone] Phone: [phone]
Fax. [phone] Fax: [phone]
www.pacelabs.com QUALITY CONTROL DATA
Lab Project Number: 92131825.
Client Project ID: Clement Pappas 2081.01
LABORATORY CONTROL SAMPLE & LCSD: 927682252 927682260
Spike
LCS
LCSD
LCS
LCSD
Parameter
Units
Conc.
Result
Result
X Rec
% Rec
RPD
Benzene
ug/l
10.00
10.58
10.80
106
108
2
Bromobenzene
ug/l
10.00
10.26
10.56
103
106
3
Bromochloromethane
ug/l
10.00
10.80
10.94
108
109
1
Bromodichloromethane
ug/l
10.00
10.33
10.34
103
103
0
Bromoform
ug/l
10.00
9.808
10.22
98
102
4
Bromomethane
ug/l
10.00
12.19
11.76
122
118
4
n-Butylbenzene
ug/l
10.00
9.017
9.335
90
93
3
sec-Butylbenzene
ug/l
10.00
10.39
10.54
104
105
1
tert-Butylbenzene
ug/l
10.00
9.973
10.27
100
103
3
tert-Butyl Formate
ug/l
10.00
6.878
7.541
69
75
9
Carbon tetrachloride
ug/l
10.00
10.06
10.24
101
102
2
Chlorobenzene
ug/l
10.00
10.30
10.52
103
105
2
Chloroethane
ug/l
10.00
12.06
11.19
121
112
7
Chloroform
ug/1
10.00
10.67
10.76
107
108
1
Chloromethane
ug/l
10.00
9.981
10.12
100
101
1
2-Chlorotoluene
ug/1
10.00
10.10
10.32
101
103
2
4-Chlorotoluene
ug/l
10.00
10.11
10.36
101
104
2
1,2-Dibromo-3-chloropropane
ug/l
10.00
9.791
10.10
98
101
3
Dibromochloromethane
ug/l
10.00
9.811
10.23
98
102
4
1.2-Dibromoethane (EDB)
ug/l
10.00
10.11
10.61
101
106
5
Dibromomethane
ug/l
10.00
10.54
10.92
105
109
4
1.2-Dichlorobenzene
ug/l
10.00
9.915
10.16
99
102
2
1,3-Dichlorobenzene
ug/1
10.00
10.03
9.984
100
100
0
1,4-Dichlorobenzene
ug/l
10.00
9.891
10.02
99
100
1
Dichlorodifluoromethane
ug/l
10.00
8.951
8.921
90
89
0
1,1-Dichloroethane
ug/l
10.00
10.52
11.29
105
113
7
1,2-Dichloroethane
ug/l
10.00
10.33
10.24
103
102
1
1.1-Dichloroethene
ug/1
10.00
12.41
12.46
124
125
0
cis-1,2-Dichloroethene
ug/l
10.00
13.58
11.81
136
118
14
trans-1,2-Dichloroethene
ug/l
10.00
11.80
10.15
118
102
15
1,2-Dichloropropane
ug/l
10.00
10.61
10.91
106
109
3
1,3-Dichloropropane
ug/l
10.00
10.19
10.28
102
103
1
2,2-Dichloropropane
ug/1
10.00
9.583
9.779
96
98
2
1,1-Dichloropropene
ug/l
10.00
10.88
10.91
109
109
0
cis-1,3-Dichloropropene
ug/l
10.00
9.847
10.02
98
100
2
trans-1.3-Dichloropropene
ug/l
10.00
9.688
9.979
97
100
3
Diisopropyl ether
ug/l
10.00
10.29
10.71
103
107
4
Date: 11/22/06
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
Sc 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648
Footnotes
Page: 26 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 2225 Riverside Drive
Huntersville; NC 28078 Asheville, NC 28804
Analytical . Phone: [phone] Phone: [phone]
Fax. [phone] Fax: [phone]
www.pacelabs.com QUALITY CONTROL DATA
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
LABORATORY CONTROL SAMPLE & LCSD: 927682252 927682260
Spike
LCS
LCSD
LCS
LCSD
Parameter
Units
Conc.
Result
Result
X Rec
% Rec
Ethylbenzene
ug/l
10.00
10.09
10.47
101
105
Hexachloro-1,3-butadiene
ug/l
10.00
9.690
9.807
97
98
Isopropylbenzene (Cumene)
ug/l
10.00
10.44
10.76
104
108
p-Isopropyltoluene
ug/l
10.00
9.273
9.540
93
95
Methylene chloride
ug/l
10.00
9.645
10.02
96
100
Methyl-tert-butyl ether
ug/1
10.00
9.950
10.32
100
103
Naphthalene
ug/l
10.00
6.713
9.659
67
97
n-Propylbenzene
ug/l
10.00
10.30
10.50
103
105
Styrene
ug/l
10.00
10.46
10.90
105
109
1,1,1,2-Tetrachloroethane
ug/l
10.00
10.23
10.45
102
105
1,1,2,2-Tetrachloroethane
ug/l
10.00
9.167
9.750
92
98
Tetrachloroethene
ug/1
10.00
10.30
10.38
103
104
Toluene
ug/l
10.00
10.07
10.34
101
103
1,2,3-Trichlorobenzene
ug/l
10.00
9.647
10.11
96
101
1,2,4-Trichlorobenzene
ug/l
10.00
9.640
10.13
96
101
1,1.1-Trichloroethane
ug/l
10.00
10.59
11.16
106
112
1,1.2-Trichloroethane
ug/l
10.00
9.885
10.19
99
102
Trichloroethene
ug/l
10.00
11.08
11.40
ill
114
Trichlorofluoromethane
ug/l
10.00
11.69
11.83
117
118
1,2,3-Trichloropropane
ug/l
10.00
10.26
10.56
103
106
1,2,4-Trimethylbenzene
ug/l
10.00
9.347
9.375
94
94
1,3,5-Trimethylbenzene
ug/l
10.00
9.217
9.523
92
95
Vinyl chloride
ug/l
10.00
9.725
10.17
97
102
m&p-Xylene
ug/l
20.00
20.74
21.22
104
106
o-Xylene
ug/l
10.00
10.31
10.41
103
104
Toluene-d8 (S)
99
100
4-Bromofluorobenzene (S)
100
100
Dibromofluoromethane (S)
103
101
1.2-Dichloroethane-d4 (S)
101
100
Date: 11/22/06
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
SC 99030 without the written consent of Pace Analytical Services, Inc.
FL NELAP E87648
R
RPD
4
1
3
3
4
4
36
2
4
2
6
1
3
5
5
5
3
3
1
3
0
3
5
2
1
Footnotes
-
1
Page: 27 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

aceAnalytical °
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Nuntersville, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
QC Batch: 172906 Analysis Method: SM 9223
QC Batch Method: Standard Methods Analysis Description: Fecal Coliform MPN Water
Associated Lab Samples: 927662213 927662296 927662304 927662312 927662320
927662338
METHOD BLANK: 927676718
Associated Lab Samples: 927662213 927662296 927662304 927662312 927662320 927662338
Blank Reporting
Parameter Units Result Limit Footnotes
Coliform, Fecal negative
Date: 11/22/06
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712
Sc 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648 A°°°R
MP.taC';�
Page: 28 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 2225 Riverside Drive
Huntersville, NC 28078 Asheville, NC 28804
Analytical o Phone: [phone] Phone. [phone]
Fax., 704.875.9091 Fax: [phone]
www.pacelabs.com QUALITY CONTROL DATA
QC Batch: 172813
QC Batch Method: EPA 160.1
Associated Lab Samples:
Date: 11/22/06
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Analysis Method: EPA 160.1
Analysis Description: Total Dissolved Solids
927662213 927662296 927662304 927662312 927662320
927662338
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
NC Wastewater
40
NC Drinking Water
37712
This report shall not be reproduced, except in full,
SC
99030
without the written consent of Pace Analytical Services, Inc.
FL NELAP
E87648
C
Page: 29 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Analytical Phone: 704.875.909
✓ Fax: [phone]
www.pacelabs.com QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax., 828,252.4618
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
QC Batch: 172567 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 48 Hour NO3 / NO2 / NOX
Associated Lab Samples: 927662213 927662296 927662304 927662312
METHOD BLANK: 927663443
Associated Lab Samples: 927662213 927662296 927662304 927662312
Blank Reporting
Parameter Units Result Limit Footnotes
Nitrate asN mg/1 ND 0.10
LABORATORY CONTROL SAMPLE: 927663450
Spike LCS LCS
Parameter Units Conc. Result % Rec Footnotes
Nitrate as N mg/l 5.000 5.000 100
MATRIX SPIKE: 927663468
•927658666 Spike MS MS
Parameter Units Result Conc. Result % Rec Footnotes
Nitrate as N mg/l 0 5.000 4.600 92
SAMPLE DUPLICATE: 927663484
Parameter Units
Nitrate as N mg/l
Date: 11/22/06
927658674 DUP
Result Result
ND
ND
RPD Footnotes
NC
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712
SC 99030 without the written consent of Pace Analytical Services, Inc.
FL NELAP E87648
Page: 30 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 2225 Riverside Drive
Huntersville, NC 28078 Asheville, NC 28804
Analytical Phone: [phone] Phone: [phone]
Fax: [phone] Fax: [phone]
www.pacelabs.com QUALITY CONTROL DATA
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
QC Batch: 172577 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 48 Hour NO3 / NO2 / NOX
Associated Lab Samples: 927662320 927662338
METHOD BLANK: 927663732
Associated Lab Samples: 927662320 927662338
Blank Reporting
Parameter Units Result Limit Footnotes
Nitrate as N mg/l NO 0.10
LABORATORY CONTROL SAMPLE: 927663740
Spike LCS LCS
Parameter Units Conc. Result % Rec Footnotes
Nitrate as N mg/l 5.000 5.150 103
MATRIX SPIKE: 927663757
927662320 Spike MS MS
Parameter Units Result Conc. Result % Rec Footnotes
Nitrate as N mg/l 1.130 5.000 6.220 102
SAMPLE DUPLICATE: 927663765
Parameter Units
Nitrate as N mg/l
Date: 11/22/06
927662338 DUP
Result Result RPD Footnotes
0.9700 •0.9900 2
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648 " A
Page: 31 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 2225 Riverside Drive
Huntersville, NC 28078 Asheville, NC 28804
AAnal�tical Phone: [phone] Phone: [phone]
., Fax: [phone] Fax: [phone]
www.pacelabs.com . QUALITY CONTROL DATA
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
QC Batch: 172598 Analysis Method: SM 5310B
QC Batch Method: SM 5310B Analysis Description: Total Organic Carbon
Associated Lab Samples: 927662213 927662296 - 927662304
METHOD BLANK: 927664466
Associated Lab Samples: 927662213 927662296 927662304
Blank Reporting
Parameter Units Result Limit Footnotes
Total Organic Carbon mg/l NO 1.0
LABORATORY CONTROL SAMPLE: 927664474
Spike LCS LCS
Parameter Units Conc. Result Rec Footnotes
Total Organic Carbon mg/l 10.00 9.800 98
MATRIX SPIKE: 927664482
927632232 Spike MS MS
Parameter Units Result Conc. Result % Rec Footnotes
Total Organic Carbon mg/l. 9.400 10.00 16.90 75
SAMPLE DUPLICATE: 927664490
Parameter Units
Total Organic Carbon mg/l
Date: 11/22/06
927632257 DUP
Result Result RPD Footnotes
20.00 20.00 1
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 99030 This report shall not be reproduced, except in full,
SC 903
NC Drinking Water 2 without the written consent of Pace Analytical Services, Inc.
FL NELAP E87648 ° N Acc°
Page: 32 of 38
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 2225 Riverside Drive
Huntersville, NC 28078 Asheville, NC 28804
Analytical o Phone: [phone] Phone: [phone]
✓ Fax: [phone] Fax: [phone]
www.pace►abs.com QUALITY CONTROL DATA
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
QC Batch: 172645 Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1 Analysis Description: Ammonia
Associated Lab Samples: 927662213 927662296 927662304 927662312 927662320
927662338
METHOD BLANK: 927667105
Associated Lab Samples: 927662213 927662296 927662304 927662312 927662320 927662338
Blank Reporting
Parameter Units Result Limit Footnotes
Nitrogen, Ammonia mg/l ND 0.10
LABORATORY CONTROL SAMPLE: 927667113
Spike LCS LCS
Parameter Units Conc. Result Rec Footnotes
Nitrogen, Ammonia mg/1 1.000 1.073 107
MATRIX SPIKE: 927667121
927624577 Spike MS MS
Parameter Units Result Conc. Result Y Rec Footnotes
Nitrogen, Ammonia mg/1 0.3223 1.000 1.584 126 2
SAMPLE DUPLICATE: 927667139
Parameter Units
Nitrogen, Ammonia mg/l
Date: 11/22/06
927631390 DUP
Result Result RPD Footnotes
6.500 6.500 1
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
Sc 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648 " .°°°
Page: 33 of 38
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627

ace Analytical °
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey A venue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project,Number: 92131825
Client Project ID: Clement Pappas 2081.01
QC Batch: 172678 Analysis Method: EPA 325.2
QC Batch Method: EPA 325.2 Analysis Description: Chloride (Mercuric Nitrate)
Associated Lab Samples: 927662213 927662296 927662304 927662312
METHOD BLANK: 927669457
Associated Lab Samples: 927662213 927662296 927662304 927662312
Blank Reporting
Parameter Units Result Limit Footnotes
Chloride mg/l NO 5.0
LABORATORY CONTROL SAMPLE: 927669465
Spike LCS LCS
Parameter Units Conc. Result X Rec Footnotes
Chloride mg/l 20.00 21.48 107
MATRIX SPIKE: 927669473
927648923 Spike MS MS
Parameter Units Result Conc. Result % Rec Footnotes
Chloride mg/l 367.9 20.00 379.0 56 2
SAMPLE DUPLICATE: 927669481
927648931 DUP
Parameter Units Result Result RPD Footnotes
Chloride mg/l 370.0 370.0 1
Date: 11/22/06
As Wastewater Certification o s REPORT OF LABORATORY ANALYSIS
NC Drinking Water 37712 This report shall not be reproduced, except in full,
Sc 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648 " Ac°°
`to�„.. C; Ra i
Page: 34 of 38
Charlotte Certification IN
NC Wastewater . 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Analytical o Phone: 704.875.909
� Fax.' 704.875.9091
www.pace►abs.com QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
QC Batch: 172679
Analysis
Method: EPA 325.2
QC Batch Method: EPA 325.2
Analysis Description: Chloride (Mercuric Nitrate)
Associated Lab Samples:
927662320
927662338
METHOD BLANK: 927669499
Associated Lab Samples:
927662320
927662338
Blank
Reporting
Parameter
Units
Result
Limit Footnotes
Chloride
mg/l
ND
5.0
LABORATORY CONTROL SAMPLE: 927669507
Spike LCS LCS
Parameter Units Conc. Result X Rec Footnotes
Chloride mg/l 20.00 21.62 108
MATRIX SPIKE: 927669515
927662320 Spike MS MS
Parameter Units Result Conc. Result % Rec Footnotes
Chloride mg/l 7.024 20.00 28.09 105
SAMPLE DUPLICATE: 927669523
Parameter Units
Chloride mg/1
Date: 11/22/06
927662338 DUP
Result Result RPD Footnotes
12.00 12.00 0
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NO Wastewater 40 NO Drinking Water 37712 This report shall not be reproduced, except in full,
SC 99030 without the written consent of Pace Analytical Services, Inc.
FL NELAP E87648 �0� 'ACCOROAy
Page: 35 of 3B
Charlotte Certification IDs
NO Wastewater 12
NO Drinking Water 37706
SC 99006
FL NELAP E87627

Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Analytical0 Phone: 704.875.909
� Fax: [phone]
www.pacelabs.com QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
QC Batch: 172815 Analysis Method: EPA 375.4
QC Batch Method: EPA 375.4 Analysis Description: Sulfate,Turbidimetric
Associated Lab Samples: 927662213 927662296 927662304 927662312 927662320
927662338
METHOD BLANK: 927673343
Associated Lab Samples: 927662213 927662296 927662304 927662312 927662320 927662338
Blank Reporting
Parameter Units Result Limit Footnotes
Sulfate mg/l ND 5.0
LABORATORY CONTROL SAMPLE: 927673350
Spike LCS LCS
Parameter Units Conc. Result % Rec Footnotes
Sulfate mg/l 20.00 18.89 94
MATRIX SPIKE: 927674754
927662213 Spike MS MS
Parameter Units Result Conc. Result % Rec Footnotes
Sulfate mg/l 17.03 20.00 29.18 61 2
SAMPLE DUPLICATE: 927674762
Parameter Units
Sulfate mg/l
Date: 11/22/06
927662296 DUP
Result Result RPD Footnotes
26.00 27.00 5
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648 " p
Page: 36 of 38.
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627

Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Analytical' Phone: 704.875.909
� Fax: [phone]
www.pacelabs.com QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
QC Batch: 172841 Analysis Method: SM 5310B
QC Batch Method: SM 5310B Analysis Description: Total Organic Carbon
Associated Lab Samples: 927662312 927662320 927662338
METHOD BLANK: 927674119
Associated Lab Samples: 927662312 927662320 927662338
Blank Reporting
Parameter Units Result Limit Footnotes
Total Organic Carbon mg/l NO 1.0
LABORATORY CONTROL SAMPLE: 927674127
Spike LCS LCS
Parameter Units Conc. Result % Rec Footnotes
Total Organic Carbon mg/l 10.00 9.710 97
MATRIX SPIKE: 927674135
927662312 Spike MS MS
Parameter Units Result Conc. Result % Rec Footnotes
Total Organic Carbon mg/l 1.440 10.00 11.72 103
SAMPLE DUPLICATE: 927674143
Parameter Units
Total Organic Carbon mg/l
Date: 11/22/06
927662320 DUP
Result Result RPD Footnotes
1.900 2.500 26
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648 " ACCOqa
Page: 37 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627

} aceAnalytical °
wrww.pacelabs.com
QUALITY CONTROL DATA PARAMETER FOOTNOTES
Pace Analytical Services, inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax. [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax., 828.252.4618
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Consistent with EPA guidelines, unrounded concentrations are displayed and have been used to calculate % Rec and RPD values.
LCS(D) Laboratory Control Sample (Duplicate)
MS(D) Matrix Spike (Duplicate)
DUP Sample Duplicate
ND Not detected at or above adjusted reporting limit
NC Not Calculable
J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
RPD Relative Percent Difference
(S) Surrogate
[1] RPD value was outside control limits, however both percent recoveries were acceptable. Sample results for the
QC batch were accepted based on percent recoveries and completeness of QC data.
[21 The spike recovery was outside acceptance limits for the MS and /or MSD due to matrix interference. The LCS
and/or LCSD were within acceptance limits showing that the laboratory is in control and the data is
acceptable.
Date: 11/22/06
Asheville certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648 a AGCCq
W c�
Page: 38 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627

UHAIN-OF-CU5TODY / Analytical: Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
aceAnalytical®
Page: of
Section A,:.
-Section B,
,Section.0
/�
O'�t He'
,Required Client Information:
Required Project Information:
Inv oice'lnformation:
Comp a L( qq Report To: „
�1MMOn r/. S'Fv
Attention: y�REGULATORY
~ ��
AGENCY
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Address
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❑ UST
❑ RCRA
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Address:
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Email To: 11
S✓.�� ONT
Purchase Order No.:
Pace Quote Reference:
❑OH ❑SC ❑ WI ❑OTHER
Phone Fax-
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Project Name; j`� / Pace Projeot Manager: `�-/
Gl�iw C.14 Pc, (,t S J
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Flltered.(
Requested Due Date[TAT: S, A r/1
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Project Number:
7_09 1 r 0
Pace Profile #:
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Requested
Section D' Required Client Information
Valid Matrix Codes
MATRIX- CODE
Preservatives'
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WE REVERSE SIDE FOR INSTRUCTIONS
ORIGINAL.
SIGNATURE of S
DATE
Signed (MM / DD / YY)
—0 G
F� K o U 0 co
tb-
ALL0020rev.3,31 Mar05

GW 59A COMPLIANCE REPORT FORM . Permit # WQ0004797
(Submit one each monitoring period with GW-59 forms.)
1
Enterdate monitoring results were due. ( 12/31/2006) Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
.Z
Was any required information missing on the GW-59 report forms?
YES
NO
1F the answer to question 1 or 2 is "YES" list in the space provided below the well identfcation number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? If the answer is "Yes", contact the Regional Of ce for guidance.
4
Are any monitored *constituents equal to or above the established standards?
YES
NO
•
if the answer to question 4 is "NO", sidp to section B.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentrations)
exceeding standards in the space provided below.
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is 'NO", skip to section B.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentrations) reported, and sample collection date for each occurrence (for the last two years).
6
Are the monitoring.welis listed in section 5 located at or beyond the review boundary?
YES
NO
If the answer is "YES". a groundwater quality problem maybe occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells maybe improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below
if the answer to question 7 is "NO" contact the Regional Office within 90 days; an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surroundin4 this facility. Failure to do so may subject the penmittee to a Notice of Violation,
fines, and/or penalties.
g
The person completing this portion (GW--59A) of the monitoring report should sign below and submit this
form with G W-59 forms for required wells to the address provided at the top of the current G W-59 form.
`i hereby acknotnrledge that the above mforrnafionwas evaluated and the information submttted in this':
report�(Compl ante Report GW;b9A),is rue anti'complete to he best of my knowledge .'x�-���.<��;����'
Signature of Permittee (or Authorized Agent) Date
GNY-59A 12/8/2003

SUBMIT FORM ON YELLOW PAPER ONLY
�S
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
LITY INFORMATION Please Print Clearly or Type.
ty Name: Clement Pappas
A Name (if different):
ty Address: • 125 Industrial Park Road
mtaln Home jetni•'t NO 28792 County IHenderson
a
act Person: Mr. Blake Kehoe Telephone#: [phone]
Location/Site Name: Irrigation Area No. of wells to be sampled: 6
prom •rm
weu taenTITlcation Numner (trom Permit): MW-2R If WELL WAS DRY
Well Depth: 14.9 ft. Well Diameter: 2 in. at time of sampling, check here
Screened Interval: 6 ft. to 14.9 ft. Sample is from system:
Depth to Water Level: 6.49 ft. below measuring point. ❑ Influent [effluent
Measuring Point is 3.77 ft. above land surface. Relative M.P. Elevation in ft. 20610
Gallons of water pu)npe;/bailect before sampling: 2.25 Date sample collected: 11/09/2006
Specific Conductance 100.0 uMhos
°C Odor none Appearance slightly cloudy
No. WQ0004797
X
NPDES
EXPIRATION DATE:
UIC
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Inflitration Gallery
X Spray Field Remediation:
Rotary Distributor Land Application of Sludge
Water Source Heat Pump
Other:
Influent mg/L (Total VOC Concentration)
Effluent mg/L (Total VOC Concentration)
VOC Removal °/,
Date sample analyzed: varies - see labc
Laboratory Name: Pace
Certification No. 3771
PARAMETERS (Samples for metals were collected unfiltered YES NO and field acidified YES NO.)
NOTE: Values should reflect dissolved and colloidal concentrations.
COD
mg/I
Nitrite (NO,) as N
mg/I
Coliform: MF Fecal 51.1 mpn ✓
/100ml
Nitrate (NO3) as N 0.95
mg/I
Coliform: MF Total
/100ml
Phosphorus: Total as P ,
mg/I
(Note: Use MPN method for highly turbid Samples)
Orthophosphate
mg/I
Dissolved.Solids: Total • 76 v
mg/I
A I- Aluminum
mg/I
pH (when analyzed)
units
Ba - Barium
mg/I
TOC 3.6 .y
mg/I
Ca - Calcium
mg/I
Chloride 7.4 v
mg/I
Cd - Cadmium
mg/I
Arsenic
mg/I
Chromium: Total
mg/I
Grease and Oils
mg/I
Cu - Copper
mg/I
Phenol
mg/I
Fe - Iron
mg/I
Sulfate 17 os
mg/I
Hg - Mercury
mg/I
Specific Conductance
uMhos
K - Potassium
mg/I
Total Ammonia 0.11
mg/I
Mg - Magnesium
mg/I
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese
mg/I
TKN as N
mg/I
GW-56
Rev.A 1/2005
of Permlttee (or Authorized Agent)
Ni - Nickel
mg/I
Pb - Lead
mg/I
Zn - Zinc
mg/I
Other (Specify Compounds and Concentration Units)
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Report Attached? Yes x (1) No (0)
VOC ; method #= 6210D
method #=
method #=
• mc4hnrl $_
(Date)

SUBMIT FORM ON YELLOW PAPER ONLY
IGROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM.
F•AGILI I T INFURMA I IUN f7eaSe j-nnr.Gleany of I ype
Facility Name: Clement Pappas
Permit Name (if different):
Facility Address: 125 Industrial Park Road
Mountain Home tstre•tt NO 2e792 County Henderson
act Person: Mr. Blake Kehoe Telephone#: [phone]
Location/Site Name: _ Irrigation Area No. of wells to be sampled: 6
(from Venal
Well Depth: 18.60
Screened Interval: 8
Depth to Water Level: 8.41
Measuring Point is 2,43
Gallons of water pumped/ba
ft. Well Diameter: 2 in.
ft. to 18.6 ft.
ft. below measuring point.
ft. above land surface.
td before sampling: • 5.25
if WELL WAS DRY
at time of sampling, Check here
Date
Influent
Non -Discharge
NPDES
W00004797 EXPIRATION DATE:
X UIC
OF PERMITTED OPERATION BEING MONITORED
—Lagoon Remediation: Infiltration Gallery
—Spray Field Remedlation:
—Rotary Distributor Land Application of Sludge
—Water Source Heat Pump
Other.
For Remediation System Influent/Effluent I
Influent mg/L (Total VOC Concentration)
Effluent mg/L (Total VOC Concentration)
VOC Removal
(FIELD ANALYSIS: pH 6.07 Specific Conductance 183.3 uMhos (Date sample analyzed: varies - see laboratory report
Temp.`f5.7 °C Odor None ' Appearance light brown Laboratory Name: Pace Analvtical Services, Inc:
Certification No. 37712
PARAMETERS (Samples for metals were collected unflltered YES NO and field acidifled YES NO.)
NOTE:•Values should reflect dissolved and colloidal concentrations.
COD mg/I Nitrite (NO2) as N mg/I
Coliform: MF Fecal <1.1 mon /100ml Nitrate (NO3) as N <0.10 mg/I
Coliform: MF Total
/100ml
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: -Total 180
mg/I
pH (when analyzed)
units
TOC 8.8
mg/I
Chloride 6.9
✓ mg/I
Arsenic
mg/I
Grease and Oils
mg/I
Phosphorus: Total as P
mg/I
Orthophosphate
mg/I
A I- Aluminum
mg/I
Ba - Barium
mg/I
Ca - Calcium
mg/I
Cd - Cadmium
mg/I
Chromium: Total
mg/I
Cu - Copper
mg/I
Ni - Nickel
mg/I
Pb - Lead
mg/I
Zn - Zinc
mg/I
Other (Specify Compounds and Concentration Units)
Phenol
mg/I
Fe - Iron
mg/I
ORGANICS: (by GC, GC/MS, HPLC)
Sulfate 26
✓ mg/I
Hg - Mercury
mg/I
(Specify test and method#. ATTACH LAB REPORT.)
Specific Conductance
uMhos
K - Potassium
mg/I
Report Attached? Yes X (1) No (0)
Total Ammonia: <0.10
✓ mg/I
Mg - Magnesium
mg/I
VOC : method #= 6210D
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese
mg/I
: method #=
TKN as N.
mg/l
: method #=
method #='
i'
GW-59
• Re\r:11/2005
Signature of Perrnittee (or Authorized Agent) (Date)

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
rAL,ILI IT [NrUKmA I lute Please l'nnt Clearly or Type
Facility Name: Clement Pappas
Permit Name (if different):
Facility Address: - 125 Industrial Park Road
Mountain Home NC 28792 County Henderson
ruarar r err.,
Contact Person: . -Mr. Blake Kehoe Telephone#: [phone]
Well Location/Site Name:_ Irrigation Area No. of wells to be sampled: 6
rpm armrt
well mentitication Number
Well Depth: 18.44
Screened Interval: 9
Depth to Water Level: 8.39
Measuring Point is 9 _
Gallons of water pumped/bai
ft. Well Diameter: 2 in.
ft. to 18.4 ft.
ft. below measuring point.
ft. above land surface.
!d before samolino: 5.25
at time of sampling, Check here
Sample is from system:
❑ Influent Dffluen
Relative M.P. Elevation in ft. 2086•
Date sample collected: 11/09/20
PERMIT No. W00004797 EXPIRATION DATE:
Non -Discharge X UIC
NPDES
OF PERMITTED OPERATION BEING MONITORED'
—Lagoon Remediation: Infiltration Gallery
_Spray Field Remediation:
—Rotary Distributor Land Application of Sludge
—Water Source Heat Pump
Other.
For Remediation System Influent/Effluent Only
Influent mg/L (Total VOC Concentration)
Effluent mg/L (Total VOC Concentration)
VOC Removal %
PH 5 Specific Conductance 150.8 uMhos Date sample analyzed:
Temp. 4 °C. Odor None Appearance light brown. Laboratory Name:
Certification No.
PARAMETERS (Samples for metals were collected unfiltered YES NO and field acidified YES NO.)
NOTE: Values should reflect dissolved and colloidal concentrations.
COD I mg/I Nitrite (NO2) as N mg/I Ni - Nickel
Col'iform: MF Fecal
<1.1 mon
,. /100ml
Coliform: MF Total
/100ml
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total
90
,, mg/I
PH. (when analyzed)
units
TOC
1.3
mg/l
Chloride
37
tr mg/I
Arsenic
mg/1
Grease and Oils
mg/I
Nitrate (NO3) as N
0.20 yr mg/I
Phosphorus: Total as P
mg/I
Orthophosphate
mg/I
A I -Aluminum
mg/I
Ba - Barium
mg/I
Ca - Calcium
mg/I
Cd - Cadmium
mg/l
Chromium: Total
mg/I
Cu - Copper
mg/I
Pb - Lead
Zn - Zinc
I - see laboratory report
Analvtical Services. Inc.
Other (Specify Compounds and Concentration Units)
mg/I
mg/I
mg/I
Phenol
mg/I
Fe - Iron
mg/I
ORGANICS:'(by GC, GC/MS, HPLC)
Sulfate <5.0
v mg/I
Hg - Mercury
mg/I
(Specify test and method #. ATTACH LAB REPORT.)
Specific Conductance
uMhos
K -. Potassium
mg/I
Report Attached? Yes X (1) No (0)
Total Ammonia < 0.1
V , mg/I
Mg - Magnesium
mg/I
VOC : method #=621 OD
(Ammonia Nitrogen; NH; as N; Ammonia Nitrogen, Total)
Mn - Manganese
mg/I
method #=
TKN as N
mg/I
; method #=
method #_
Rev. -11 /2005

SUBMIT FORM*ON
ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
rAGRI I Y INr UKMA I JUN Please rnnr uleany or 1 ype
Facility Name: ' Clement -Pappas.
Permit Name (if different):
Facility Address: ' 125 Industrial Park Road
Mountain Home NC 28792 County Henderson
act Person: Mr. Blake Kehoe Telephone#: [phone]
Location/Site. Name:_ irriaation'Area No, of wells to be sampled: 6
rom ertn
Well Depth: 11.54
Screened Interval: 5
Depth to Water Level: 5.71
Measuring Point is 3
Gallons of water oumaed/ba
ft. Well Diameter: 2 in.
ft. to 11.5 ft.
ft. below measuring point.
ft. above land surface.
id before samolinc: 3.00
FIELD ANALYSIS: pH ".341 Specific Conductance
Temp. 15.7 °C Odor None
time of sampling, Check here
Rmple is from system:
❑ Influent
sample collected: 11/09/2006
uMhos
Appearance slightly cloudy
No. W00004797 EXPIRA
X UIC
PDES
TE:
OF PERMITTED OPERATION BEING MONITORED
_ Lagoon Remediation: Infiltration Gallery
_Spray Field Remedial ion:
_ Rotary Distributor Land Application of Sludge
—Water Source Heat Pump
Other.
For Remediation System Influent/Effluent
Influent mg/L (Total VOC Concentration)
Effluent mglL (Total VOC Concentration)
VOC Removal °/
Laboratory Name:
Certification No.
PARAMETERS (Samples for metals were collected unfiltered YES NO and field acidified YES NO.)
NOTE: Values should reflect dissolved and colloidal concentrations.'
COD mg/I Nitrite (NO2) as N mg/I
Coliform: MF Fecal <1.1 mon /100ml Nitrate (NOO as N 0,20 mg/I
Coliform: MF Total
/100ml
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total 54
v mg/I
pH (when analyzed)
units
TOC 1.4
,. mg/I
Chloride 11
✓ mg/I
Arsenic
mg/I
Grease and Oils
mg/I
Phosphorus: Total as P
mg/I
Orthophosphate
mg/I
A I -Aluminum
mg/I
Ba - Barium
mg/I
Ca - Calcium
mg/1
Cd - Cadmium
mg/I
Chromium: Total
mg/I
Cu - Copper
mg/I
Ni - Nickel
- see IaDoraiory report
Analvtical Services, Inc.
mg/I
Pb - Lead mg/I
Zn - Zinc mg/I
Other (Specify Compounds and Concentration Units)
Phenol
mg/I
Fe - Iron
mg/I
ORGANICS: (by GC, GC/MS, HPLC)
Sulfate 11 ✓
mg/I
Hg - Mercury
mg/I
(Specify test and method #. ATTACH LAB REPORT.)
Specific Conductance
uMhos
K - Potassium
mg/I
Report Attached? Yes X (1) No (0)
Total Ammonia 0.18 V
mg/I
Mg - Magnesium
mg/I
VOC : method #= 6210D
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese
mg/I
: method #=
TKN as N
mg/I
: method #=
method #_
GW-59
Rev'11/2005
Signature of Permittee (or Authorized
z i7—
(Date)

SUBMIT FORM ON YELLOW PAPER ONLY
a.
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
1 Y IIVI'UKMA I IUn mease rnnr L;leany or 1 ype
Name: Clement Pappas
Name (if different):
Address: 125 Industrial Park Road
runtain Home tetie1> NC 28792 County Henderson
act Person: Mr. Blake Kehoe Telephone#: [phone]
Location/Site Name: Irrigation Area No, of wells to be sampled: 6
(from °rm
Well Depth: 16,72
Screened Interval: 5
Depth to Water Level: 9.71
Measuring Point is 3
Gallons of water pumped/ba.
ANALYSIS: pH
from Permit): MW-7
ft. Well Diameter: 2 in.
ft. to 16.7 ft.
ft. below measuring point,
ft. above land surface.
d before sampling: 3.75
_ Specific Conductance
.1 eC Odor None
if WELL WAS DRY
at time of sampling, Check here
Date
Influent
NO. W00004797 EXPIRATION DATE:
arge X UIC -
OF PERMITTED OPERATION BEING MONITORED
_Lagoon . Remediation: Infiltration Gallery
_Spray Field Remediation:
—Rotary Distributor Land Application of Sludge
—Water Source Heat Pump
Other:
For Remediation System Influent/Effluent
Dffluent Influent mgiL (Total VOC Concentration)
ft. 2062.7 Effluent mg/L (Total VOC Concentration)
11/09/2006 VOC Removal %
umnos uate sample anaiyzea: varies - see laboratory report
Appearance light brown Laboratory Name: Pace Analytical Services. Inc.
Certification No. 37712
PARAMETERS (Samples for metals were collected unfiltered
YES NO and field acidified
YES
NO.)
NOTE: Values should reflect dissolved and colloidal
concentrations.
COD
mg/I
Nitrite (NO2) as N
mg/I
Ni - Nickel mg/I
Coliform: MF Fecal <1.1 mpn /
/100ml
Nitrate (NO3) as N 1.1 ,o
mg/I
Pb - Lead mg/I
Coliform: MF Total
/100ml
Phosphorus: Total as P
mg/I
Zn - Zinc' mg/I
(Note: Use MPN method for highly turbld semples)
-
Orthophosphate
mg/I
Dissolved Solids: Total 38 v
mg/I
A I -Aluminum
mg/I
Other (Specify Compounds and Concentration Units)
pH (when analyzed)
units
Ba - Barium
mg/I
TOC 1.9
mg/I
Ca - Calcium
mg/I
Chloride 7.0 v
mg/I
Cd - Cadmium •
mg/I
Arsenic
mg/l
Chromium: Total
mg/I
Grease and Oils
mg/I
Cu - Copper
mg/I
Phenol
mg/I
Fe - Iron
mg/I
ORGANICS: (by GC, GC/MS, -HPLC)
Sulfate 6.7
mg/I
Hg - Mercury
mg/I
(Specify test and method #. ATTACH LAB REPORT.)
Specific Conductance
uMhos
K - Potassium
mg/I
Report Attached? Yes X (1) No (0)
Total Ammonia <0.10 W
mg/I
Mg - Magnesium
mg/I
VOC : method #= 6210D
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese
mg/I
: method #=
TKN as N
mg/I
: method #=
method #=
GW-59
' Rev.11/2005
/o e
(or Authorized Agent)
i 1,47f /-
-
(Date)

SUBMIT FORM ON
ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
I 1 7 Inrumrdim i aVry /''/ease rnnt tilearly or Type
Name: ' Clement Pappas
Name (if different):
Address: 125 Industrial Park Road
Aountaln Home (�"t) I NC 28792 County Henderson
fcra)ac 4�,e.�
:ontact Person: Mr. Blake Kehoe Telephonem [phone]
Veil Location/Site Name:_ Irrigation Area No, of wells to be sampled: 6
• from cn )
Well Identification Number
Well Depth: 13.90
Screened Interval: 3
Depth to Water Level: 9,40
Measuring Point is . 3
Gallons of water pumped/bai
FIELD ANALYSIS: • pH - \5,7
Temp:'i
(from Permit): MW-8
ft. Well Diameter: 2 in.
ft, to 13.9 ft.
ft. below measuring point,
ft, above land surface.
led before sampling: 2.50
If WELL WAS DRY
at time of sampling, Check here _
LJ Influent
Relative M.P. E
Date sample cc
PERMIT No. W00004797 EXPIRATION DATE:
Non -Discharge X UIC _
NPDES
OF PERMITTED OPERATION BEING MONITORED
_ Lagoon Remedlation: Infiltration Gallery
_Spray Field Remedlation:
Rotary Distributor Land Application of Sludge
—Water Source Heat Pump
Other:
Remedlation System Influent/Effluent Only (Attach Lab
)nt mg/L (Total VOC Concentration)
ant mg/L (Total VOC Concentration)
Removal %
Specific Conductance 156.4 uMhos Date,sample analyzed: varies - see laboratory report
eC Odor None Appearance light brown Laboratory Name: Pace Analvtical Services, Inc.
lCertification No, 37712
PARAMETERS (Samples for metals were collected unflltered YES NO and field acidified YES NO.)
NOTE: Values should reflect dissolved and colloidal concentrations.
COD mg/I Nitrite (NO2) as N mg/I
Coliform: MF Fecal <1.1 /100ml Nitrate (NO3) as N 0.97 mg/I
Coliform: MF Total
/100m1
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total 96
v mg/I
pH (when analyzed)
units
TOC 4.7
r mg/I
Chloride 12
V mg/I
Arsenic
mg/I
Grease and Oils
rrtg/I
Phosphorus: Total as P
mg/I
Orthophosphate
mg/I
A I -Aluminum
mg/I
Ba - Barium
mg/I
Ca - Calcium
mg/I
Cd : Cadmium
mg/I
Chromium: Total
mg/I
Cu- Copper
mg/I
N1- Nickel
mg/I
Pb - Lead mg/I
Zn - Zinc mg/I
Other (Specify Compounds and Concentration Units)
Phenol
mg/I
Fe - Iron
mg/I
ORGANICS:( by GC, GC/MS, HPLC) ,
Sulfate 7.7
W mg/1
Hg - Mercury.
mg/I
(Specify test and method #. ATTACH LAB REPORT.)
Specific Conductance
uMhos
K - Potassium
mg/I
Report Attached? Yes X (1) No (0)
Total Ammonia <0,10
mg/I
Mg - Magnesium
mg/I
VOC : method #= .6210D
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn -.Manganese
mg/I
: method ft.
TKN as N
mg/I
: method #_
method #=
- Kev. 1112uub

aceAnaly cal °
www.pacelabs.com
Lab Sample No: 927662213
Client Sample ID: MW-02R
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax. [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax. [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-001 Date Collected: 11/09/06 10:57
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Microbiology
Fecal Coliform MPN Water
Method: SM 9223
Coliform, Fecal
<1.1 mpn/100mL
11/09/06
16:00
JGJ
Wet Chemistry
Total'Dissolved Solids
Method: EPA
160.1
Total Dissolved Solids
76.
mg/l
20.
11/14/06
14:59
TMR
Chloride (Mercuric Nitrate)
Method: EPA
325.2
Chloride
7.4
mg/l
5.0
11/12/06
10:58
JDA1
16887-00-6
Ammonia
Method: EPA
350.1
Nitrogen, Ammonia
0.11
mg/l
0.10
11/10/06
18:32
NIW
7727-37-9
48 Hour NO3 / NO2 / NOX
Method: EPA
353.2
Nitrate as N
0.95
mg/l
0.10
11/09/06
21:40
JDA1
Sulfate,Turbidimetric
Method: EPA
375.4
Sulfate
17.
mg/l
5.0
11/14/06
12:03
TMR
Total Organic Carbon
Method: SM 5310B
Total Organic Carbon
3.6
mg/l
1.0
11/10/06
13:13
JDA1
7440-44-0
GUMS Vol ati l es
SM 6210D VOCs
Method: SM 6210D
Benzene
ND
ug/l
0.50
11/15/06
16:19
MSF
71-43-2
Bromobenzene
ND
ug/l
0.50
11/15/06
16:19
MSF
108-86-1
Bromochloromethane
ND
ug/l
0.50
11/15/06
16:19
MSF
74-97-5
Bromodichloromethane
NO
ug/l
0.50
11/15/06
16:19
MSF
75-27-4
Bromoform
ND
ug/l
0.50
11/15/06
16:19
MSF
75-25-2
Bromomethane
ND
ug/l
0.50
11/15/06
16:19
MSF
74-83-9
n-Butylbenzene
NO
ug/l
0.50
11/15/06
16:19
MSF
104-51-8
sec-Butylbenzene
NO
ug/l
0.50
11/15/06
16:19
MSF
135-98-8
tert-Butylbenzene
NO
ug/l
0.50
11/15/06
16:19
MSF
98-06-6
tert-Butyl Formate
NO
ug/1
20.
11/15/06
16:19
MSF
762-75-4
Carbon tetrachloride
NO
ug/1
0.50
11/15/06
16:19
MSF
56-23-5
Chlorobenzene
NO
ug/1
0.50
11/15/06
16:19
MSF
108-90-7
Chloroethane
NO
ug/1
1.0
11/15/06
16:19
MSF
75-00-3
Chloroform
ND
ug/1
0.50
11/15/06
16:19
MSF
67-66-3
Date: 11/22/06
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
SC 99030 without the written consent of Pace Analytical Services, Inc.
FL NELAP E87648
Page: 1 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627

aceAnalytical °
www.pacelabs.com
Lab Sample No: 927662213
Client Sample ID: MW-02R
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax. [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax.[phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-001 Date Collected: 11/09/06 10:57
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No.Qua] RegLmt
Chloromethane
ND
ug/l
1.0
11/15/06
16:19
MSF
74 87-3
2-Chlorotoluene
ND
ug/l
0.50
11/15/06
16:19
MSF
95-49-8
4-Chlorotoluene
ND
ug/1
0.50
11/15/06
16:19
MSF
106-43-4
1,2-Dibromo-3-chloropropane
ND-
ug/l
1.0
11/15/06
16:19
MSF
96-12-8
Dibromochloromethane
ND
ug/l
0.50
.11/15/06
16:19
MSF
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/1
0.50
11/15/06
16:19
MSF
106-93-4
Dibromomethane
ND
ug/l
0.50
11/15/06
16:19
MSF
74-95-3
1,2-Dichlorobenzene
ND
ug/l
0.50
11/15/06
16:19
MSF
95-50-1
1,3-Dichlorobenzene
ND
ug/l
0.50
11/15/06
16:19
MSF
541-73-1
1,4-Dichlorobenzene
ND
ug/1
0.50
11/15/06
16:19
MSF
106-46-7
Dichlorodifluoromethane
ND
ug/l
1.0
11/15/06
16:19
MSF
75-71-8
1,1-Dichloroethane
ND
ug/l
0.50
11/15/06
16:19
MSF
75-34-3
1,2-Dichloroethane
ND
ug/1
0.50
11/15/06
16:19
MSF
107-06-2
1,1-Dichloroethene
ND
ug/l
0.50
11/15/06
16:19
MSF
75-35-4
cis-1,2-Dichloroethene
ND
ug/l
0.50
11/15/06
16:19
MSF
156-59-2
trans-1,2-Dichloroethene
ND
ug/l
0.50
11/15/06
16:19
MSF
156-60-5
1,2-Dichloropropane
ND
ug/l
0.50
11/15/06
16:19
MSF
78-87-5
1,3-Dichloropropane
ND
ug/l
0.50
11/15/06
16:19
MSF
142-28-9
2,2-Dichloropropane
ND
ug/l
0.50
11/15/06
16:19
MSF
594-20-7
1.1-Dichloropropene
ND
ug/l
0.50
11/15/06
16:19
MSF
563-58-6
cis-1,3-Dichloropropene
ND
ug/1
0.50
11/15/06
16:19
MSF
10061-01-5
trans-1,3-Dichloropropene
ND
ug/l
0.50
11/15/06
16:19
MSF
10061-02-6
Diisopropyl ether
ND
ug/l
0.50
11/15/06
16:19
MSF
108-20-3
Ethylbenzene
ND
ug/l
0.50
11/15/06
16:19
MSF
100-41-4
Hexachloro-1,3-butadiene
ND
ug/1
2.0
11/15/06
16:19
MSF
87-68-3
Isopropylbenzene (Cumene)
ND
ug/l
0.50
11/15/06
16:19
MSF
98-82-8
p-Isopropyltoluene
ND
ug/l
0.50
11/15/06
16:19
MSF
99-87-6
Methylene chloride
ND
ug/l
2.0
11/15/06
16:19
MSF
75-09-2
Methyl-tert-butyl ether
ND
ug/1
0.50
11/15/06
16:19
MSF
1634-04-4'
Naphthalene
ND
ug/l
2.0
11/15/06
16:19
MSF
91-20-3
n-Propylbenzene
ND
ug/l
0.50
11/15/06
16:19
MSF
103-65-1
Styrene
ND
ug/1
0.50
11/15/06
16:19
MSF
100-42-5
1.1,1,2-Tetrachloroethane
ND
ug/1
0.50
11/15/06
16:19
MSF
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/l
0.50
11/15/06
16:19
MSF
79-34-5
Tetrachloroethene
ND
ug/l
0.50
11/15/06
16:19
MSF
127.18-4
Toluene
ND
ug/l
0.50
11/15/06
16:19
MSF
108-88-3
1,2,3-Trichlorobenzene
ND
ug/l
2.0
11/15/06
16:19
MSF
87-61-6
1,2,4-Trichlorobenzene
ND
ug/l
2.0
11/15/06
16:19
MSF
120-82-1
1,1,1-Trichloroethane
ND
ug/l
0.50
11/15/06
16:19
MSF
71-55-6
Date: 11/22/06
Page: 2 of 38
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IN
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shalt not be reproduced, except in full,
NC Drinking Water
37706
SC
99030
without the written consent of Pace Analytical Services, Inc.
SC
99006
FL NEAP
E87648
`t p ACCpq
FL NELAP
E87627
c

aceAnalytical °
www.patelabs.com
Lab Sample No: 927662213
Client Sample ID: MW-02R
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax.- 704.875.9091
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax. [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-001 Date Collected: 11/09/06 10:57
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No, Qual RegLmt
1,1,2-Trichloroethane
ND
ug/l
0.50
11/15/06
16:19 MSF
79-00-5
Trichloroethene
ND
ug/l
0.50
11/15/06
16:19 MSF
79-01-6
Trichlorofluoromethane
ND
ug/1
1.0
11/15/06
16:19 MSF
75-69-4
1,2,3-Trichloropropane
ND
ug/1
0.50
11/15/06
16:19 MSF
96-18-4
1,2,4-Trimethylbenzene
ND
ug/l
0.50
11/15/06
16:19 MSF
95-63-6
1,3,5-Trimethylbenzene
ND
ug/l
0.50
11/15/06
16:19 MSF
108-67-8
Vinyl chloride
ND
ug/l
1.0
11/15/06
16:19 MSF
75-01-4
m&p-Xylene
ND
ug/l
1.0
11/15/06
16:19 MSF
o-Xylene
ND
ug/l
0.50
11/15/06
16:19 MSF
95-47-6
Toluene-d8 (S)
99
%
11/15/06
16:19 MSF
2037-26-5
4-Bromofluorobenzene (S)
97
%
11/15/06
16:19 MSF
460-00-4
Dibromofluoromethane (S)
102
%
11/15/06
16:19 MSF
1868-53-7
1,2-Dichloroethane-d4 (S)
99
%
11/15/06
16:19 MSF
17060-07-0
Date: 11/22/D6
Asheville Certification IN REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
Sc 99030 without the written consent of Pace Analytical Services, Inc.
FL NELAP E87648
Vt,
Page: 3 of 38
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627

r'
ace Analytical °
www.pacelabs.com
Lab Sample No: 927662296
Client Sample ID: MW-04
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax., 704.875.9091
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax.[phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-002 Date Collected: 11/09/06 10:10
Matrix: Water Date Received: 11/09/06 15:34
Parameters Results Units Report Limit Analyzed By CAS No. Qual RegLmt
Microbiology
Fecal Coliform MPN Water Method: SM 9223
Coliform. Fecal <1.1 mpn/100mL 11/09/06 16:00 JGJ
Wet Chemistry
Total Dissolved Solids Method: EPA 160.1
Total Dissolved Solids 180 mg/l
Chloride (Mercuric Nitrate) Method: EPA 325.2
Chloride 6.9 mg/l
20. 11/14/06 15:00 TMR
5.0 11/12/06 10:58 JDA1 16887-00-6
Ammonia
Method:
EPA 350.1
Nitrogen, Ammonia
NO
mg/l
0.10
11/10/06
18:32
NIW
7727-37-9
48 Hour NO3 / NO2 / NOX
Method:
EPA 353.2
Nitrate as N
ND
mg/l
0.10
11/09/06
21:40
JDA1
Sulfate.Turbidimetric
Method:
EPA 375.4
Sulfate
26.
mg/1
5.0
11/14/06
12:06
TMR
Total Organic Carbon
Method:
SM 5310B
Total Organic Carbon
8.8 mg/l
1.0
11/10/06
13:13
JDA1
7440-44-0
GC/MS Volatiles
SM 6210D VOCs
Method:
SM 6210D
Benzene
ND
ug/l
0.50
11/15/06
17:30
MSF
71-43-2
Bromobenzene
ND
ug/l
0.50
11/15/06
17:30
MSF
108-86-1
8romochloromethane
ND
ug/l
0.50
11/15/06
17:30
MSF
74-97-5
Bromodichloromethane
ND
ug/l
0.50
11/15/06
17:30
MSF
75-27-4
Bromoform
NO
ug/l
0.50
11/15/06
17:30
MSF
75-25-2
Bromomethane
ND
ug/l
0.50
11/15/06
17:30
MSF
74-83-9
n-Butylbenzene
NO
ug/l
0.50
11/15/06
17:30
MSF
104-51-8
sec-Butylbenzene
ND
ug/1
0.50
11/15/06
17:30
MSF
135-98-8
tert-Butylbenzene
NO
ug/1
0.50
11/15/06
17:30
MSF
98-06-6
tert-Butyl Formate
NO
ug/l
20.
11/15/06
17:30
MSF
762-75-4
Carbon tetrachloride
ND
ug/l
0.50
11/15/06
17:30
MSF
56-23-5
Chlorobenzene
NO
ug/l
0.50
11/15/06
17:30
MSF
108-90-7
Chloroethane
ND
ug/l
1.0
11/15/06
17:30
MSF
75-00-3
Chloroform
NO
ug/l
0.50
11/15/06
17:30
MSF
67-66-3
Date: 11/22/06
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648 " A"
Page: 4 of 3B
Charlotte Certification IDs
NC Wastewater
12
NC Drinking Water
37706
Sc
99006
FL NELAP
E87627

aceAnaV cal °
www.pacelabs.com
Lab Sample No: 927662296
Client Sample ID: MW-04
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone. [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-002 Date Collected: 11/09/06 10:10
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Chloromethane
ND
ug/l
1.0
11/15/06
17:30
MSF
74-87-3
2-Chlorotoluene
ND
ug/l
0.50
11/15/06
17:30
MSF
95-49-8
4-Chlorotoluene
ND
ug/l
0.50
11/15/06
17:30
MSF
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/1
1.0
11/15/06
17:30
MSF
96-12-8
Dibromochloromethane
ND
ug/l
0.50
11/15/06.
17:30
MSF
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/l
0.50
11/15/06
17:30
MSF
106-93-4
Dibromomethane
ND
ug/l
0.50
11/15/06
17:30
MSF
74-95-3
1,2-Dichlorobenzene
ND
ug/l
0.50
11/15/06
17:30
MSF
95-50-1
1,3-Dichlorobenzene
ND
ug/l
0.50
11/15/06
17:30
MSF
541-73-1
1,4-Dichlorobenzene
ND
ug/l
0.50
11/15/06
17:30
MSF
106-46-7
Dichlorodifluoromethane
ND
ug/l
1.0
11/15/06
17:30
MSF
75-71-8
1,1-Dichloroethane
ND
ug/l
0.50
11/15/06
17:30
MSF
75-34-3
1,2-Dichloroethane
ND
ug/l
0.50
11/15/06
17:30
MSF
107-06-2
1,1-Dichloroethene
ND
ug/l
0.50
11/15/06
17:30
MSF
75-35-4
cis-1,2-Dichloroethene
ND
ug/l
0.50
11/15/06
17:30
MSF
156-59-2
trans-1,2-Dichloroethene
ND
ug/l
0.50
11/15/06
17:30
MSF
156-60-5
1,2-Dichloropropane
ND
ug/l
0.50
11/15/06
17:30
MSF
78-87-5
1.3-Dichloropropane
ND
ug/l
0.50
11/15/06
17:30
MSF
142-28-9
2,2-Dichloropropane
ND
ug/l
0.50
11/15/06
17:30
MSF
594-20-7
1,1-Dichloropropene
ND
ug/l
0.50
11/15/06
17:30
MSF
563-58-6
cis-1,3-Dichloropropene
ND
ug/l
0.50
11/15/06
17:30
MSF
10061-01-5
trans-1.3-Dichloropropene
ND
ug/l
0.50
11/15/06
17:30
MSF
10061-02-6
Diisopropyl ether
ND
ug/l
0.50
11/15/06
17:30
MSF
108-20-3
Ethylbenzene
ND
ug/l
0.50
11/15/06
17:30
MSF
100-41-4
Hexachloro-1,3-butadiene
ND
ug/l
2.0
11/15/06
17:30
MSF
87-68-3
Isopropylbenzene (Cumene)
ND
ug/l
0.50
11/15/06
17:30
MSF
98-82-8
p-Isopropyltoluene
ND
ug/l
0.50
11/15/06
17:30
MSF
99-87-6
Methylene chloride
ND
ug/l
2.0
11/15/06
17:30
MSF
75-09-2
Methyl-tert-butyl ether
ND
ug/l
0.50
11/15/06
17:30
MSF
1634-04-4
Naphthalene
ND
ug/l
2.0
11/15/06
17:30
MSF
91-20-3
n-Propylbenzene
ND
ug/l
0.50
11/15/06
17:30
MSF
103-65-1
Styrene
ND
ug/l
0.50
11/15/06
17:30
MSF
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/l
0.50
11/15/06
17:30
MSF
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/l
0.50
11/15/06
17:30
MSF
79-34-5
Tetrachloroethene
ND
ug/l
0.50
11/15/06
17:30
MSF
127-18-4
Toluene
ND
ug/l
0.50
11/15/06
17:30
MSF
108-88-3
1,2,3-Trichlorobenzene
ND
ug/l
2.0
11/15/06
17:30
MSF
87-61-6
1,2,4-Trichlorobenzene
ND
ug/l
2.0
11/15/06
17:30
MSF
120-82-1
1,1,1-Trichloroethane
ND
ug/l
0.50
11/15/06
17:30
MSF
71-55-6
Date: 11/22/06
Page: 5 of 38
Asheville Certification IN
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IN
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shalt not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
Sc
99006
FL NELAP
E87648
H ���° A
;Prar
FL NELAP
E87627

ace Analytical °
www.pacelabs.com
Lab Sample No: 927662296
Client Sample ID: MW-04
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28076
Phone., 704.875.9092
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-002 Date Collected: 11/09/06 10:10
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
1,1,2-Trichloroethane
ND
ug/1
0.50
11/15/06
17:30
MSF
79-00-5
Trichloroethene
ND
ug/l
0.50
11/15/06
17:30
MSF
79-01-6
Trichlorofluoromethane
ND
ug/1
1.0
11/15/06
17:30
MSF
75-69-4
1,2,3-Trichloropropane
ND
ug/l
0.50
11/15/06
17:30
MSF
96-18-4
1,2,4-Trimethylbenzene
ND
ug/l
0.50
11/15/06
17:30
MSF
95-63-6
1,3,5-Trimethylbenzene
ND
ug/l
0.50
11/15/06
17:30
MSF
108-67-8
Vinyl chloride
ND
ug/l
1.0
11/15/06
17:30
MSF
75-01-4
m&p-Xylene
ND
ug/l
1.0
11/15/06
17:30
MSF
o-Xylene
ND
ug/l
0.50
11/15/06
17:30
MSF
95-47-6
Toluene-d8 (S)
98
%
11/15/06
17:30
MSF
2037-26-5
4-Bromofluorobenzene (S)
101
%
11/15/06
17:30
MSF
460-00-4
Dibromofluoromethane (S)
102
%
11/15/06
17:30
MSF
1868-53-7
1,2-Dichloroethane-d4 (S)
100
%
11/15/06
17:30
MSF
17060-07-0
Date: 11/22/06
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
SC 99030 without the written consent of Pace Analytical Services, Inc.
FL NELAP E87648
Ear --:, •°+,
O \F
Page: 6 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

aceAnalytical °
www.pacelabs.com
Lab Sample No: 927662304
Client Sample ID: MW-05
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax. [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-003 Date Collected: 11/09/06 12:32
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results Units
Report Limit
Analyzed
By
CAS.No. Quaff RegLmt
Microbiology
Fecal Coliform MPN Water
Method:
SM 9223
Coliform, Fecal
<1.1
mpn/100mL
11/09/06
17:45
JGJ
Wet Chemistry
Total Dissolved Solids
Method:
EPA 160.1
Total Dissolved Solids
90.
mg/l
20.
11/14/06
15:00
TMR
Chloride (Mercuric Nitrate)
Method:
EPA 325.2
Chloride
37.
mg/l
5.0
11/12/06
10:58
JDA1
16887-00.6
Ammonia
Method:
EPA 350.1
Nitrogen, Ammonia
NO
mg/l
0.10
11/10/06
18:42
NIW
7727-37-9
48 Hour NO3 / NO2 / NOX
Method:
EPA 353.2
Nitrate as N
0.20 mg/l
0.10
11/09/06
21:40
JDA1
Sulfate,Turbidimetric
Method:
EPA 375.4
Sulfate
ND
mg/l
5.0
11/14/06
12:06
TMR
Total Organic Carbon
Method:
SM 5310B
Total Organic Carbon
1.3
mg/l
1.0
11/10/06
13:13
JDA1
7440-44-0
GUMS Vol ati l es
SM 6210D VOCs
Method:
SM 6210D
Benzene
NO
ug/l
0.50
11/15/06
17:54
MSF
71-43-2
Bromobenzene
NO
ug/l
0.50
11/15/06
17:54
MSF
108-86-1
Bromochloromethane
NO
ug/l
0.50
11/15/06
17:54
MSF
74-97-5
Bromodichloromethane
ND
ug/l
0.50
11/15/06
17:54
MSF
75-27-4
Bromoform
NO
ug/l
0.50
11/15/06
17:54
MSF
75-25-2
Bromomethane
ND
ug/l
0.50
11/15/06
17:54
MSF
74-83-9
n-Butylbenzene
ND
ug/l
0.50
11/15/06
17:54
MSF
104-51-8
_sec-Butylbenzene
ND
ug/l
0.50
11/15/06
17:54
MSF
135-98-8
tert-Butylbenzene
NO
ug/l
0.50
11/15/06
17:54
MSF
98-06-6
tert-Butyl Formate
ND
ug/l
20.
11/15/06
17:54
MSF
762-75-4
Carbon tetrachloride
NO
ug/l
0.50
11/15/06
17:54
MSF
56-23-5
Chlorobenzene
NO
ug/l
0.50
11/15/06
17:54
MSF
108-90-7
Chloroethane
NO
ug/l
1.0
11/15/06
17:54
MSF
75-00-3
Chloroform
NO
ug/l
0.50
11/15/06
17:54
MSF
67-66-3
Date: 1I/22/06
Page: 7 of 38
Asheville Certification
IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification
IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
Sc
99006
FL NELAP
E87648
FL NELAP
E87627
!,'I AnIONJ"'

ace Analytical °
www.pacelabs.com
Lab Sample No: 927662304
Client Sample ID: MW-05
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-003 Date Collected: 11/09/06 12:32
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Chloromethane
ND
ug/l
1.0
11/15/06
17:54 MSF
74-87-3
2-Chlorotoluene
ND
ug/l
0.50
11/15/06
17:54 MSF
95-49-8
4-Chlorotoluene
ND
ug/l
0.50
11/15/06
17:54 MSF
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/l
1.0
11/15/06
17:54 MSF
96-12-8
Dibromochloromethane
ND
ug/l
0.50
11/15/06
17:54 MSF
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/l
0.50
11/15/06
17:54 MSF
106-93-4
Dibromomethane
ND
ug/l
0.50
11/15/06
17:54 MSF
74-95-3
1,2-Dichlorobenzene
ND
ug/l
0.50
11/15/06
17:54 MSF
95-50-1
1,3-Dichlorobenzene
ND
ug/l
0.50
11/15/06
17:54 MSF
541-73-1
1,4-Dichlorobenzene
ND
ug/l
0.50
11/15/06
17:54 MSF
106-46-7
Dichlorodifluoromethane
ND
ug/l
1.0
11/15/06
17:54 MSF
75-71-8
1,1-Dichloroethane
ND
ug/l
0.50
11/15/06
17:54 MSF
75-34-3
1,2-Dichloroethane
ND
ug/l
0.50
11/15/06
17:54 MSF
107-06-2
1.1-Dichloroethene
ND
ug/l
0.50
11/15/06
17:54 MSF
75-35-4
cis-1,2-Dichloroethene
67.
ug/l
0.50
11/15/06
17:54'MSF
156-59-2
trans-1,2-Dichloroethene
0.61
ug/l
0.50
11/15/06
17:54 MSF
156-60-5
1.2-Dichloropropane
ND
ug/l
0.50
11/15/06
17:54 MSF
78-87-5
1,3-Dichloropropane
ND
ug/l
0.50
11/15/06
17:54 MSF
142-28-9
2.2-Dichloropropane
ND
ug/l
0.50
11/15/06
17:54 MSF
594-20-7
1,1-Dichloropropene
ND
ug/l
0.50
11/15/06'17:54
MSF
563-58-6
cis-1,3-Dichloropropene
ND
ug/l
0.50
11/15/06
17:54 MSF
10061-01-5
trans-1,3-Dichloropropene
ND
ug/l
0.50
11/15/06
17:54 MSF
10061-02-6
Diisopropyl ether
ND
ug/l
0.50
11/15/06
17:54 MSF
108-20-3
Ethylbenzene
ND
ug/l
0.50
11/15/06
17:54 MSF
100-41-4
Hexachloro-1,3-butadiene
ND
ug/l
2.0
11/15/06
17:54 MSF
87-68-3
Isopropylbenzene (Cumene)
ND
ug/l
0.50
11/15/06
17:54 MSF
98-82-8
p-Isopropyltoiuene
ND
ug/l
0.50
11/15/06
17:54 MSF
99-87-6
Methylene chloride
ND
ug/l
2.0
11/15/06
17:54 MSF
75-09-2
Methyl-tert-butyl ether
ND
ug/l
0.50
11/15/06
17:54 MSF
1634-04-4
Naphthalene
ND
ug/l
2.0
11/15/06
17:54 MSF
91-20-3
n-Propylbenzene
ND
ug/l
0.50
11/15/06
17:54 MSF
103-65-1
Styrene
ND
ug/1
0.50
11/15/06
17:54 MSF
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/l
0.50
11/15/06
17:54 MSF
630-20-6
1,1.2,2-Tetrachloroethane
ND
ug/l
0.50
11/15/06
17:54 MSF
79-34-5
Tetrachloroethene
350
ug/l
2.5
11/15/06
17:54 MSF
127-18-4
Toluene
ND
ug/l
0.50
11/15/06
17:54 MSF
108-88-3
1,2,3-Trichlorobenzene
ND
ug/l
2.0
11/15/06
17:54 MSF
87-61-6
1,2,4-Trichlorobenzene
ND
ug/l
2.0
11/15/06
17:54 MSF
120-82-1
1,1,1-Trichloroethane
ND
ug/l
0.50
11/15/06
17:54 MSF
71-55-6
Date: 11/22/06
Page: 8 of 38
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
g
37712
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
without the written consent of Pace Analytical Services, Inc.
SC
99006
FL NELAP
E87648
FL NELAP
E87627

aceAnalytical
, www.pacelabs.com
Lab Sample No: 927662304
Client Sample ID: MW-05
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax. [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: 828,252.4618
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-003 Date Collected: 11/09/06 12:32
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
1,1,2-Trichloroethane
ND
ug/1
0.50
11/15/06
17:54 MSF
79-00-5'
Trichloroethene
74.
ug/l
0.50
11/15/06
17:54 MSF
79-01-6
Trichlorofluoromethane
ND
ug/l
1.0
11/15/06
17:54 MSF
75-69-4
1,2.3-Trichloropropane
ND
ug/l
0.50
11/15/06
17:54 MSF
96-18-4
1,2,4-Trimethylbenzene
ND
ug/l
0.50
11/15/06
17:54 MSF
95-63-6
1.3,5-Trimethylbenzene
ND
ug/l
0.50
11/15/06
17:54 MSF
108-67-8
Vinyl chloride
1.2
ug/l
1.0
11/15/06
17:54 MSF
75-01-4
m&p-Xylene
ND
ug/l
1.0
11/15/06
17:54 MSF
o-Xylene
ND
ug/l
0.50
11/15/06
17:54 MSF
95-47-6
Toluene-d8 (S)
99
%
11/15/06
17:54 MSF
2037-26-5
4-Bromofluorobenzene (S)
98
%
11/15/06
17:54 MSF
460-00-4
Dibromofluoromethane (S)
103
%
11/15/06
17:54 MSF
1868-53-7
1,2-Dichloroethane-d4 (S)
100
k
11/15/06
17:54 MSF
17060-07-0
Date: 11/22/06
Asheville Certification IN REPORT .OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648
Page: 9 of 38
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

aceAnalytical °
www.pacelabs.com
Lab Sample No: 927662312
Client Sample ID: MW-06
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Nuntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-004 Date Collected: 11/09/06 11:47
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual Re9Lmt
Microbiology
Fecal Coliform MPN Water
Method: SM 9223
Coliform, Fecal
<1.1 mpn/100ml-
11/09/06
17:45
JGJ
Wet Chemistry
Total,Dissolved Solids
Method: EPA
160.1
Total Dissolved Solids
54.
mg/l
20.
11/14/06'15:01
TMR
Chloride (Mercuric Nitrate)
Method: EPA
325.2
Chloride
11.
mg/l
5.0
11/12/06
10:58
JDA1
16887-00-6
Ammonia
Method: EPA
350.1
Nitrogen, Ammonia
0.18
mg/l
0.10
11/10/06
18:42
NIW
7727-37-9
48 Hour NO3 / NO2 / NOX
Method: EPA
353.2
Nitrate as N
0.20
mg/l
0.10
11/09/06
21:40
JDA1
Sulfate,Turbidimetric
Method: EPA
375.4
Sulfate
11.
mg/l
5.0
11/14/06
12:06
TMR
Total Organic Carbon
Method: SM 5310B
Total Organic Carbon
1.4
mg/l
1.0
11/14/06
11:15
JDA1
7440-44-0
GUMS Vol ati l es
SM 6210D VOCs
Method: SM 6210D
Benzene
NO
ug/l
0.50
11/16/06
11:38
MSF
71-43.2
Bromobenzene
NO
ug/l
0.50
11/16/06
11:38
MSF
108-86-1
Bromochloromethane
ND
ug/l
0.50
11/16/06
11:38
MSF
74-97-5
Bromodichloromethane
NO
ug/l
0.50
11/16/06
11:38
MSF
75-27-4
Bromoform
ND
ug/l
0.50
11/16/06
11:38
MSF
75-25-2
Bromomethane
NO
ug/l
0.50
11/16/06
11:38
MSF
74-83-9
n-Butylbenzene
NO
ug/l
0.50
11/16/06
11:38
MSF
104-51-8
sec-Butylbenzene
ND
ug/l
0.50
11/16/06
11:38
MSF
135-98-8
tert-Butylbenzene
NO
ug/l
0.50
11/16/06
11:38
MSF
98-06-6
tert-Butyl Formate
NO
ug/l
20.
11/16/06
11:38
MSF
762-75-4
Carbon tetrachloride
NO
ug/l
0.50
11/16/06
11:38
MSF
56-23-5
Chlorobenzene
NO
ug/l
0.50
11/16/06
11:38
MSF
108-90-7
Chloroethane
NO
ug/l
1.0
11/16/06
11:38
MSF
75-00-3
Chloroform
NO
ug/l
0.50
11/16/06
11:38
MSF
67-66-3
Date: 11/22/06
Page: I0 of 38
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
Sc
99006
FL NELAP
E87648
w A«°
-'°
FL NELAP
E87627

ace Analytical
www.pacelabs.com
Lab Sample No: 927662312
Client Sample ID: MW-06
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Hunters ville, NC28078
Phone: [phone]
Fax.[phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-004 Date Collected: 11/09/06 11:47
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Chloromethane
ND
ug/l
1.0
11/16/06
11:38
MSF
74-87-3
2-Chlorotoluene
ND
ug/l
0.50
11/16/06
11:38
MSF
95-49-8
4-Chlorotoluene
ND
ug/l
0.50
11/16/06
11:38
MSF
106-43-4
1.2-Dibromo-3-chloropropane
ND
ug/l
1.0
11/16/06
11:38
MSF
96-12-8
Dibromochloromethane
ND
ug/l
0.50
11/16/06
11:38
MSF
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/l
0.50
11/16/06
11:38
MSF
106-93-4
Dibromomethane
ND
ug/1
0.50
11/16/06
11:38
MSF
74-95-3
1,2-Dichlorobenzene
ND
ug/l
0.50
11/16/06
11:38
MSF
95-50-1
1,3-Dichlorobenzene
ND
ug/1
0.50
11/16/06
11:38
MSF
541-73-1
1,4-Dichlorobenzene
ND
ug/l
0.50
11/16/06
11:38
MSF
106-46-7
Dichlorodifluoromethane
ND
ug/l
1.0
11/16/06
11:38
MSF
75-71-8
1,1-Dichloroethane
ND
ug/l
0.50
11/16/06
11:38
MSF
75-34-3
1,2-Dichloroethane
ND
ug/1
0.50
11/16/06
11:38
MSF
107-06-2
1,1-Dichloroethene
ND
ug/l
0.50
11/16/06
11:38
MSF
75-35-4
cis-1,2-Dichloroethene
ND
ug/l
0.50
11/16/06
11:38
MSF
156-59-2
trans-1,2-Dichloroethene
ND
ug/l
0.50
11/16/06
11:38
MSF
156-60-5
1.2-Dichloropropane
ND
ug/l
0.50
11/16/06
11:38
MSF
78-87-5
1,3-Dichloropropane
ND
ug/1
0.50
11/16/06
11:38
MSF
142-28-9
2,2-Dichloropropane
ND
ug/l
0.50
11/16/06
11:38
MSF
594-20-7
1,1-Dichloropropene
ND
ug/l
0.50
11/16/06
11:38
MSF
563-58-6
cis-1,3-Dichloropropene
ND
ug/l
0.50
11/16/06
11:38
MSF
10061-01-5
trans-1,3-Dichloropropene
ND
ug/l
0.50
11/16/06
11:38
MSF
10061-02-6
Diisopropyl ether
ND
ug/l
0.50
11/16/06
11:38
MSF
108-20-3
Ethylbenzene
ND
ug/l
0.50
11/16/06
11:38
MSF
100-41-4
Hexachloro-1,3-butadiene
ND
ug/l
2.0
11/16/06
11:38
MSF
87-68-3
Isopropylbenzene (Cumene)
ND
ug/l
0.50
11/16/06
11:38
MSF
98-82-8
p-Isopropyltoluene
ND
ug/l
0.50
11/16/06
11:38
MSF
99-87-6
Methylene chloride
ND
ug/1
2.0
11/16/06
11:38
MSF
75-09-2
Methyl-tert-butyl ether
ND
ug/l
0.50
11/16/06
11:38
MSF
1634-04-4
Naphthalene
ND
ug/1
2.0
11/16/06
11:38
MSF
91-20-3
n-Propylbenzene
ND
ug/l
0.50
11/16/06
11:38
MSF
103-65-1
Styrene
ND
ug/l
0.50
11/16/06
11:38
MSF
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/l
0.50
11/16/06
11:38
MSF
630-20-6
1.1,2,2-Tetrachloroethane
ND
ug/1
0.50
11/16/06
11:38
MSF
79-34-5
Tetrachloroethene
ND
ug/l
0.50
11/16/06
11:38
MSF
127-18-4
Toluene
ND
ug/l
0.50
11/16/06
11:38
MSF
108-88-3
1,2,3-Trichlorobenzene
ND
ug/l
2.0
11/16/06
11:38
MSF
87.61-6
1,2,4-Trichlorobenzene
ND
ug/l
2.0
11/16/06
11:38
MSF
120-82-1
1.1,1-Trichloroethane
ND
ug/l
0.50
11/16/06
11:38
MSF
71-55-6
Date: 11/22/06
Page: 11 of 38
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
NC Drinking Water
40
37712
This report shall not be reproduced, except in full,
NC Wastewater
12
Sc
99030
without the written consent of Pace Analytical Services, Inc.
NC Drinking Water
37706
Sc
99006
FL NELAP
E87648
♦'� �' ^ ' ��H
FL NELAP
E87627

aO Analytical
www.pacelabs.com
Lab Sample No: 927662312
Client Sample ID: NW-06
Pace Analytical Services, Inc.
9800 Kincey Avenue; Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28604
Phone. [phone]
Fax. [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-004 Date Collected: 11/09/06 11:47
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. ual Re9Lmt
1,1,2-Trichloroethane
ND
ug/l
0.50
11/16/06
11:38
MSF
79-00-5
Trichloroethene
ND
ug/l
0.50
11/16/06
11:38
MSF
79-01-6
Trichlorofluoromethane
ND
ug/l
1.0
11/16/06
11:38
MSF
75-69-4
1,2,3-Trichloropropane
ND
ug/l
0.50
11/16/06
11:38
MSF
96-18-4
1,2,4-Trimethylbenzene
ND
ug/l
0.50
11/16/06
11:38
MSF
95-63-6
1,3,5-Trimethylbenzene
ND
ug/l
0.50
11/16/06
11:38
MSF
108-67-8
Vinyl chloride
ND
ug/l
1.0
11/16/06
11:38
MSF
75-01-4
mbp-Xylene
ND
ug/l
1.0
11/16/06
11:38
MSF
o-Xylene
ND
ug/l
0.50
11/16/06
11:38
MSF
95-47-6
Toluene-d8 (S)
98
%
11/16/06
11:38
MSF
2037-26-5
4-Bromofluorobenzene (S)
98
%
11/16/06
11:38
MSF
460-00-4
Dibromofluoromethane (S)
100
%
11/16/06
11:38
MSF
1868-53-7
1,2-Dichloroethane-d4 (S)
96
X
11/16/06
11:38
MSF
17060-07-0
Date: 11/22/06
As Wastewater CertificationlDs REPORT OF LABORATORY ANALYSIS
NC Drinking Water 40 This report shall not be reproduced, except in full,
SC 99030 without the written consent of Pace Analytical Services, Inc.
ACC N
FL NELAP E87648
Page: 12 of 38
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

aceAnalytical °
www.pacelabs.com
Lab Sample No: 927662320
Client Sample ID: MW-07
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone. [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-005 Date Collected: 11/09/06 13:35
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Microbiology
Fecal Coliform MPN Water
Method: SM 9223
Coliform, Fecal
<1.1 mpn/100mL
11/09/06
17:45
JGJ
Wet Chemistry
Total Dissolved Solids
Method: EPA
160.1
Total Dissolved Solids
38.
mg/l
20.
11/14/06
15:01
TMR
Chloride (Mercuric Nitrate)
Method: EPA
325.2
Chloride
7.0
mg/l
5.0
11/12/06
11:04
JDA1
16887-00-6
Ammonia
Method: EPA
350.1
Nitrogen, Ammonia
ND
mg/l
0.10
11/10/06
19:19
NIW
7727-37-9
48 Hour NO3 / NO2 / NOX
Method: EPA
353.2
Nitrate as N
1.1
mg/l
0.10
11/10/06
06:48
EWS
Sulfate,Turbidimetric
Method: EPA
375.4
Sulfate
6.7
mg/l
5.0
11/14/06
12:11
TMR
Total Organic Carbon
Method: SM 5310B
Total Organic Carbon
1.9
mg/l
1.0
11/14/06
11:15
JDA1
7440-44-0
GUMS Vol ati l es
SM 6210D VOCs
Method: SM 6210D
Benzene
ND
ug/l
0.50
11/15/06
18:41
MSF
71-43-2
Bromobenzene
NO
ug/1
0.50
11/15/06
18:41
MSF
108-86-1
Bromochloromethane
ND
ug/l
0.50
11/15/06
18:41
MSF
74-97-5
Bromodichloromethane
ND
ug/l
0.50
11/15/06
18:41
MSF
75-27-4
Bromoform
ND
ug/1
0.50
11/15/06
18:41
MSF
75-25-2
Bromomethane
NO
ug/l
0.50
11/15/06
18:41
MSF
74-83-9
n-Butylbenzene
ND
ug/l
0.50
11/15/06
18:41
MSF
104-51.8
sec-Butylbenzene
NO
ug/l
0.50
11/15/06
18:41
MSF
135-98-8
tert-Butylbenzene
ND
ug/l
0.50
11/15/06
18:41
MSF
98-06-6
tert-Butyl Formate
NO
ug/l
20.
11/15/06
18:41
MSF
762-75-4
Carbon tetrachloride
ND
ug/l
0.50
11/15/06
18:41
MSF
56-23-5
Chlorobenzene
NO
ug/l
0.50
11/15/06
18:41
MSF
108-90-7
Chloroethane
NO
ug/l
1.0
11/15/06
18:41
MSF
75-00-3
Chloroform
ND
ug/l
0.50
11/15/06
18:41
MSF
67-66-3
Date: 11/22/06
Page: 13 of 38
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
Sc
99006
FL NELAP
E87648
,°r `arc°"°��
FL NELAP
E87627

ace Analytical
www.pacelabs.com
Lab Sample No: 927662320
Client Sample ID: MW-07
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-005 Date Collected: 11/09/06 13:35
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Chloromethane
ND
ug/l
1.0
11/15/06
18:41
MSF
74-87.3
2-Chlorotoluene
ND
ug/l
0.50
11/15/06
18:41
MSF
95-49-8
4-Chlorotoluene
ND
ug/l
0.50
11/15/06
18:41
MSF
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/l
1.0
11/15/06
18:41
MSF
96-12-8
Dibromochloromethane
ND
ug/l
0.50
11/15/06
18:41
MSF
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/l
0.50
11/15/06
18:41
MSF
106-93-4
Dibromomethane
ND
ug/l
0.50
11/15/06
18:41
MSF
74-95-3
1,2-Dichlorobenzene
ND
ug/l
0.50
11/15/06
18:41
MSF
95-50-1
1,3-Dichlorobenzene
ND
ug/l
0.50
11/15/06
18:41
MSF
541-73-1
1,4-Dichlorobenzene
ND
ug/l
0.50
11/15/06
18:41
MSF
106.46-7
Dichlorodifluoromethane
ND
ug/l
1.0
11/15/06
18:41
MSF
75-71-8
1,1-Dichloroethane
ND
ug/l
0.50
11/15/06
18:41
MSF
75-34-3
1,2-Dichloroethane
ND
ug/l
0.50
11/15/06
18:41
MSF
107-06-2
1,1-Dichloroethene
ND
ug/l
0.50
11/15/06
18:41
MSF
75-35-4
cis-1,2-Dichloroethene
ND
ug/l
0.50
11/15/06
18:41
MSF
156-59-2
trans-1,2-Dichloroethene
ND
ug/l
0.50
11/15/06
18:41
MSF
156-60-5
1,2-Dichloropropane
ND
ug/l
0.50
11/15/06
18:41
MSF
78-87-5
1,3-Dichloropropane
ND
ug/l
0.50
11/15/06
18:41
MSF
142-28-9
2,2-Dichloropropane
ND
ug/l
0.50
11/15/06
18:41
MSF
594-20-7
1,1-Dichloropropene
ND
ug/l
0.50
11/15/06
18:41
MSF
563-58-6
cis-1,3-Dichloropropene
ND
ug/l
0.50
11/15/06
18:41
MSF
10061-01-5
trans-1,3-Dichloropropene
ND
ug/l
0.50
11/15/06
18:41
MSF
10061-02-6
Diisopropyl ether
ND
ug/l
0.50
11/15/06
18:41
MSF
108-20-3
Ethylbenzene
ND
ug/l
0.50
11/15/06
18:41
MSF
100-41-4
Nexachloro-1,3-butadiene
ND
ug/l
2.0
11/15/06
18:41
MSF
87-68-3
Isopropylbenzene (Cumene)
ND
ug/l
0.50
11/15/06
18:41
MSF
98-82-8
p-Isopropyltoluene
ND
ug/1
0.50
11/15/06
18:41
MSF
99-87-6
Methylene chloride
ND
ug/l
2.0
11/15/06
18:41
MSF
75-09-2
Methyl-tert-butyl ether
ND
ug/l
0.50
11/15/06
18:41
MSF
1634-04-4
Naphthalene
ND
ug/l
2.0
11/15/06
18:41
MSF
91-20-3
n-Propylbenzene
ND
ug/l
0.50
11/15/06
18:41
MSF
103-65-1
Styrene
ND
ug/l
0.50
11/15/06
18:41
MSF
100-42-5
1.1,1,2-Tetrachloroethane
ND
ug/l
0.50
11/15/06
18:41
MSF
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/l
0.50
11/15/06
18:41
MSF
79-34-5
Tetrachloroethene
ND
ug/l
0.50
11/15/06
18:41
MSF
127-18-4
Toluene
ND
ug/l
0.50
11/15/06
18:41
MSF
108-88-3
1,2,3-Trichlorobenzene
ND
ug/l
2.0
11/15/06
18:41
MSF
87-61-6
1,2,4-Trichlorobenzene
ND
ug/l
2.0
11/15/06
18:41
MSF
120-82-1
1,1,1-Trichloroethane
ND
ug/l
0.50
11/15/06
18:41
MSF
71-55-6
Date: 1I/22/06
Page: 14 of 38
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
SC
99030
without the written consent of Pace Analytical Services, Inc.
Sc
99006
FL NELAP
E87648
,fir%'A"°�,�
FL NELAP
E87627

aceAnalytical °
www.pacelabs.com
Lab Sample No: 927662320
Client Sample ID: MW-07
Pace Analytical Services, Inc.
9800KinceyAvenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28604
Phone: [phone]
Fax.' 828.252.4618
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-005 Date Collected: 11/09/06 13:35
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
1,1,2-Trichloroethane
ND
ug/l
0.50
11/15/06
18:41
MSF
79-00-5
Trichloroethene
ND
ug/l
0.50
11/15/06
18:41
MSF
79-01-6
Trichlorofluoromethane
ND
ug/l
1.0
11/15/06
18:41
MSF
75-69-4
1,2.3-Trichloropropane
ND
ug/1
0.50
11/15/06
18:41
MSF
96-18-4
1,2.4-Trimethylbenzene
ND
ug/i
0.50
11/15/06
18:41
MSF
95-63-6
1,3,5-Trimethylbenzene
ND
ug/1
0.50
11/15/06
18:41
MSF
108-67-8
Vinyl chloride
ND
ug/1
1.0
11/15/06
18:41
MSF
75.01-4
m&p-Xylene
ND
ug/l
1.0
11/15/06
18:41
MSF
o-Xylene
ND
ug/1
0.50
11/15/06
18:41
MSF
95-47-6
Toluene-d8 (S)
98
X
11/15/06
18:41
MSF
2037-26-5
4-Bromofluorobenzene (S)
98
%
11/15/06
18:41
MSF
460-00-4
Dibromofluoromethane (S)
100
%
11/15/06
18:41
MSF
1868-53-7
1,2-Dichloroethane-d4 (S)
100
%
11/15/06
18:41
MSF
17060-07-0
Date: 11/22/06
Asheville Certification IN REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712
SC 99030 without the written consent of Pace Analytical Services, Inc.
N ALCOH
FL NELAP E87648
Page: 15 of 38
Charlotte Certification IDs
NC Wastewater
12
NC Drinking Water
37706
SC
99006
FL NELAP
E87627

ace Analytical
www.pacelabs.com
Lab Sample No: 927662338
Client Sample ID: MW-08 .
Pace Analytical Services, Inc.
9800 07cey Avenue, Suite 100
Huntersville, NC 28078
Phone. [phone]
Fax. [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, W 28804
Phone., 828.254.7176
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-006 Date Collected: 11/09/06 14:20
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Microbiology
Fecal Coliform MPN Water
Method: SM 9223
Coliform. Fecal
<1.1 mpn/100mL
11/09/06
17:45
JGJ
Wet Chemistry
Total Dissolved Solids
Method: EPA
160.1
Total Dissolved Solids
96.
mg/1
20.
11/14/06
15:02
TMR
Chloride (Mercuric Nitrate)
Method: EPA
325.2
Chloride
12.
mg/l
5.0
11/12/06
11:04
JDA1
16887-00-6
Ammonia
Method: EPA
350.1
Nitrogen, Ammonia
NO
mg/l
0.10
11/10/06
19:19
NIW
7727-37-9
48 Hour NO3 / NO2 / NOX
Method: EPA
353.2
Nitrate as N
0.97
mg/l
0.10
11/10/06
06:48
EWS
Sulfate,Turbidimetric
Method: EPA
375.4
Sulfate
7.7
mg/1
5.0
11/14/06
12:12
TMR
Total Organic Carbon
Method: SM 5310B
Total Organic Carbon
4.7
mg/1
1.0
11/14/06
11:15
JDA1
7440-44-0
GC/MS Volatiles
SM 6210D VOCs
Method: SM 6210D
Benzene
ND
ug/1
0.50
11/16/06
00:52
MSF
71-43-2
Bromobenzene
ND
ug/1
0.50
11/16/06
00:52
MSF
108-86-1
Bromochloromethane
NO
ug/l
0.50
11/16/06
00:52
MSF
74-97-5
Bromodichloromethane
ND
ug/l
0.50
11/16/06
00:52
MSF
75-27-4
Bromoform
ND
ug/l
0.50
11/16/06
00:52
MSF
75-25-2
Bromomethane
NO
ug/l
0.50
11/16/06
00:52
MSF
74-83-9
n-Butylbenzene
ND
ug/l
0.50
11/16/06
00:52
MSF
104-51-8
sec-Butylbenzene
NO
ug/1
0.50
11/16/06
00:52
MSF
135-98-8
tert-Butylbenzene
NO
ug/l
0.50
11/16/06
00:52
MSF
98-06-6
tert-Butyl Formate
NO
ug/l
20.
11/16/06
00:52
MSF
762-75-4
Carbon tetrachloride
NO
ug/l
0.50
11/16/06
00:52
HSF
56-23-5
Chlorobenzene
NO
ug/l
0.50
11/16/06
00:52
MSF
108-90-7
Chloroethane
NO
ug/1
1.0
11/16/06
00:52
MSF
75-00-3
Chloroform
NO
ug/1
0.50
11/16/06
00:52
MSF
67-66-3
Date: 11/22/06
Page: 16 of 38
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
Sc
99006
FL NELAP
E87648
�''°
FL NELAP
E87627
"nallir'f

aceAnalytical °
www.pacelabs.com
Lab Sample No: 927662338
Client Sample ID: MW-08
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax., 704.875.9091
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax.- 828.252.4618
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-006 Date Collected: 11/09/06 14:20
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No, Qual RegLmt
Chloromethane
ND
ug/l
1.0
11/16/06
00:52
MSF
74-87-3
2-Chlorotoluene
ND
ug/1
0.50
11/16/06
00:52
MSF
95-49-8
4-Chlorotoluene
ND
ug/l
0.5D
11/16/06
00:52
MSF
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/l
1.0
11/16/06
00:52
MSF
96-12-8
Dibromochloromethane
ND
ug/1
0.50
11/16/06
00:52
MSF
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/l
0.50
11/16/06
00:52
MSF
106-93-4
Dibromomethane
ND
ug/l
0.50
11/16/06
00:52
MSF
74-95-3
1,2-Dichlorobenzene
ND
ug/l
0.50
11/16/06
00:52
MSF
95-50-1
1,3-Dichlorobenzene
ND
ug/1
0.50
11/16/06
00:52
MSF
541-73-1
1,4-Dichlorobenzene
ND
ug/l
0.50
11/16/06
00:52
MSF
106-46-7
Dichlorodifluoromethane
ND
ug/l
1.0
I1/16/06
00:52
MSF
75-71-8
1,1-Dichloroethane
ND
ug/l
0.50
11/16/06
00:52
MSF
75-34-3
1,2-Dichloroethane
ND
ug/l
0.50
11/16/06
00:52
MSF
107-06-2
1,1-Dichloroethene
ND
ug/l
0.50
11/16/06
00:52
MSF
75-35-4
cis-1,2-Dichloroethene
ND
ug/1
0.50
11/16/06
00:52
MSF
156-59-2
trans-1,2-Dichloroethene
ND
ug/l
0.50
11/16/06
00:52
MSF
156-60-5
1,2-Dichloropropane
ND
ug/1
0.50
11/16/06
00:52
MSF
78-87-5
1,3-Dichloropropane
ND
ug/l
0.50
11/16/06
00:52
MSF
142-28-9
2,2-Dichloropropane
ND
ug/l
0.50
11/16/06
00:52
MSF
594-20-7
1,1-Dichloropropene
ND
ug/l
0.50
11/16/06
00:52
MSF
563-58-6
cis-1,3-Dichloropropene
ND
ug/l
0.50
11/16/06
00:52
MSF
10061-01-5
trans-1,3-Dichloropropene
ND
ug/l
0.50
11/16/06
00:52
MSF
10061-02-6
Diisopropyl ether
ND
ug/l
0.50
11/16/06
00:52
MSF
108-20-3
Ethylbenzene
ND
ug/l
0.50
11/16/06
00:52
MSF
100-41-4
Mexachloro-1,3-butadiene
ND
ug/l
2.0
11/16/06
00:52
MSF
87-68-3
Isopropylbenzene (Cumene)
ND
ug/l
0.50
11/16/06
00:52
MSF
98-82-8
p-Isopropyltoluene
ND
ug/l
0.50
11/16/06
00:52
MSF
99-87-6
Methylene chloride
ND
ug/1
2.0
11/16/06
00:52
MSF
75-09-2
Methyl-tert-butyl ether
ND
ug/l
0.50
11/16/06
00:52
MSF
1634-04-4
Naphthalene
ND
ug/l
2.0
11/16/06
00:52
MSF
91-20-3
n-Propylbenzene
ND
ug/l
0.50
11/16/06
00:52
MSF
103-65-1
Styrene
ND
ug/l
0.50
11/16/06
00:52
MSF
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/l
0.50
11/16/06
00:52
MSF
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/l
0.50
11/16/06
00:52
MSF
79-34-5
Tetrachloroethene
ND
ug/1
0.50
11/16/06
00:52
MSF
127-18-4
Toluene
ND
ug/l
0.50
11/16/06
00:52
MSF
108-88-3
1,2,3-Trichlorobenzene
ND
ug/l
2.0
11/16/06
00:52
MSF
87-61-6
1,2,4-Trichlorobenzene
ND
ug/l
2.0
11/16/06
00:52
MSF
120-82-1
1,1,1-Trichloroethane
ND
ug/l
0.50
11/16/06
00:52
MSF
71-55-6
Date: I1122106
Page: 17 of 38
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IN
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
SC
99030
without the written consent of Pace Analytical Services, Inc.
SC
99006
FL NELAP
E87648
FL NELAP
E87627

aceAnalytical®
www.pacelabs.com
Lab Sample No: 927662338
Client Sample ID: MW-08
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone. [phone]
Fax. [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone., 828.254.7176
Fax: [phone]
Lab Project Number: 92131825
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92131825-006 Date Collected: 11/09/06 14:20
Matrix: Water Date Received: 11/09/06 15:34
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
1,1,2-Trichloroethane
ND
ug/1
0.50
11/16/06
00:52
MSF
79-00-5
Trichloroethene
ND
ug/l
0.50
11/16/06
00:52
MSF
79-01-6
Trichlorofluoromethane
ND
ug/l
1.0
11/16/06
00:52
MSF
75-69-4
1,2,3-Trichloropropane
ND
ug/l
0.50
11/16/06
00:52
MSF
96-18-4
1,2,4-Trimethylbenzene
ND
ug/l
0.50
11/16/06
00:52
MSF
95-63-6
1,3,5-Trimethylbenzene
ND
ug/l
0.50
11/16/06
00:52
MSF
108-67-8
Vinyl chloride
ND
ug/l
1.0
11/16/06
00:52
MSF
75-01-4
m&p-Xylene
ND
ug/l
1.0
11/16/06
00:52
MSF
o-Xylene
ND
ug/l
0.50
11/16/06
00:52
MSF
95-47-6
Toluene-d8 (S)
99
%
11/16/06
00:52
MSF
2037-26-5
4-Bromofluorobenzene (S)
97
%
11/16/06
00:52
MSF
460-00-4
Dibromofluoromethane (S)
98
%
11/16/06
00:52
MSF
1868-53-7
1,2-Dichloroethane-d4 (S)
99
%
11/16/06
00:52
MSF
17060-07-0
Date: 11/22/06 Page: 18 of 38
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
g
37712
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
SC
without the written consent of Pace Analytical Services, Inc.
SC
99006
FL NELAP
E87648
FL NELAP
E87627
h'Plr`