WQ0004797_Monitoring (Report)_20051221

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FO
Please Print Clearly or Type
Facility Name: Clement Pappas, Inc.
Permit Name (if different):
Facility Address: 125 Industrial Park Road
(street)
Hendersonville NC 28792
Count Henderson
y
(state) (zip)
tcevt Mr. Blake Kehoe
Contact Person-
828
Telephone #: ( ) 693-0711
Well Location/ Site Name: Irrigation area
No. of Wells to be Sampled: 6
tram Pemtlt
Well Identification Number (from Permit): MW-7
For Groundwater Treatment Systems
Well Depth: 16.75 ft. Well Diameter: 2
in.
Check one: ❑ Influent (98)
Screened Interval: 6.7 ft. to 16.7 ft.
❑ Effluent (99)
Depth to Water Level: 11.09 ft. below measuring point.
Measuring Point (M.P.) is: - ft. above land surface.
Relative M.P. Elevation in ft.:
Gallons of water pumped/bailed before sampling: 3.0
Date sample collected: 11/03/2005
Field analysis: pH 5.57 , Specific Conductance
86.0 uMhos
Temp. 15.3 OC, Odor None
Appearance Tan
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 MAIL SERVICE CENTER
PERMIT #: W00004797 EXPIRATION DATE: 6-30-2007
Non -Discharge X UIC
NPDES
TYPE OF PERMITTED OPERATION BEING' MONITORED
Lagoon Remediation: Infiltration Gallery
X Spray Field Remediation:
Rotary Distributor Land Application of Sludge
Other:
r_
NOTE: Values should reflect dissolved and
colloidal concentrations.
Date sample analyzed: 11/03/2005
Laboratory Name, Pace Analytical Services, Inc.
Certification No. 37706
PARAMETERS (Samples for metals were collected unfiltered YES NO
and field acidified
COD
mg/I
Nitrite (NO2) as N
mg/I
Coliform: MF Fecal <1.1
/100ml
Nitrate (NO3) as N 0.99
mg/i
Coliform: MF Total
/100ml
Phosphorus: Total as P
mg/l
(Note: Use MPN method for highly turbid samples)
Orthophosphate
mg/I
Dissolved Solids: Total 58
mg/I
Al - Aluminum
mg/I
pH (when analyzed)
units
Ba - Barium
mg/I
TOC 7•7
mg/I
Ca - Calcium
mg/l
Chloride 6.1
mg/i
Cd - Cadmium
mg/I
Arsenic
mg/I
Chromium: Total
mg/I
Grease and Oils
mg/I
Cu - Copper
mg/I
Phenol
mg/I
Fe - Iron
mg/I
Sulfate <5.0
mg/i
Hg - Mercury
mg/I
Specific Conductance
uMhos
K - Potassium
mg/I
Total Ammonia
mg/I
Mg - Magnesium
mg/I
TKN as N
mg/I
Mn - Manganese
mg/I
..G.. vN/GVVV
YES NO)
Ni - Nickel mg/I
Pb - Lead mg/I
Zn - Zinc mg/I
Ammonia Nitrogen 0.10 mg/I
Other (Specify Compounds and Concentration Units)
ORGANICS: (GCGC/MS,HPLC)
(Specify test and method #. Attach lab report.)
Report Attached? Yes X (1) No (0)
VOC : method # = 6230D
method # =
method # =

ace Analytical °
www.pacelabs.com
Lab Sample No: 926299140
Client Sample ID: MW-07
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92106754-002 Date Collected: 11/03/05 10:45
Matrix: Water Date Received: 11/03/05 14:56
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Microbiology
Fecal Coliform MPN Water
Method: SM 9223
Coliform. Fecal
<1.1 mpn/100mL
11/03/05
15:30
MDK
Wet Chemistry
Total Dissolved Solids
Method: EPA
160.1
Total Dissolved Solids
58.
mg/l
20.
11/05/05
17:39
TCM
Chloride (Mercuric Nitrate)
Method: EPA
325.2
Chloride
6.1
mg/l
5.0
11/09/05
11:00
BMF
16887-00-6
Ammonia
Method: EPA
350.1
Nitrogen, Ammonia
0.10
mg/l
0.10
11/07/05
16:30
BMF
7727-37-9
48 Hour NO3 / NO2 / NOX
Method: EPA
353.2
Nitrate as N
0.99
mg/l
0.10
11/03/05
23:28
ARH
Sulfate.Turbidimetric
Method: EPA
375.4
Sulfate
NO
mg/l
5.0
11/09/05
11:30
BMF
Total Organic Carbon
Method: SM
5310B
Total Organic Carbon
7.7
mg/l
1.0
11/16/05
10:00
BMF
7440-44-0
GC Volatiles
GC VOCs in Water
Method: SM 6230D
Benzene
ND
mg/l
0.00050
11/13/05
07:06
PPM
71-43-2
Bromobenzene
ND
mg/l
0.00050
11/13/05
07:06
PPM
108-86-1
Bromochloromethane
NO
mg/l
0.00050
11/13/05
07:06
PPM
74-97-5
Bromodichloromethane
NO
mg/l
0.00050
11/13/05
07:06
PPM
75-27-4
Bromoform
NO
mg/l
0.00050
11/13/05
07:06
PPM
75-25-2
Bromomethane
NO
mg/l
0.00050
11/13/05
07:06
PPM
74-83-9
n-Butylbenzene
NO
mg/l
0.0010
11/13/05
07:06
PPM
104-51-8
sec-Butylbenzene
NO
mg/l
0.00050
11/13/05
07:06
PPM
135-98-8
tert-Butylbenzene
NO
mg/l
0.00050
11/13/05
07:06
PPM
98-06-6
Carbon tetrachloride
ND
mg/l
0.00050
11/13/05
07:06
PPM
56-23-5
Chlorobenzene
NO
mg/l
0.00050
11/13/05
07:06
PPM
108-90-7
Chloroethane
NO
mg/l
0.00050
11/13/05
07:06
PPM
75-00-3
Chloroform
NO
mg/l
0.00050
11/13/05
07:06
PPM
67-66-3
Chloromethane
NO
mg/l
0.0020
11/13/05
07:06
PPM
74-87-3
Date: 11/30/05
Page: 4 of 36
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IN
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
SC
99006
FL NELAP
E87648
,t°T% Aga"°��
FL NELAP
E87627
���e1ac

aceAnalytical®
www.pacelahs.com
Lab Sample No: 926299140
Client Sample ID: MW-07
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Nuntersville, NC 28078
Phone: [phone]
Fax [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax [phone]
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92106754-002 Date Collected: 11/03/05 10:45
Matrix: Water Date Received: 11/03/05 14:56
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
2-Chlorotoluene
ND
mg/l
0.00050
11/13/05
07:06
PPM
95.49-8
4-Chlorotoluene
ND
mg/l
0.00050
11/13/05
07:06
PPM
106-43-4
1,2-Dibromo-3-chloropropane
ND
mg/l
0.0020
11/13/05
07:06
PPM
96-12-8
Dibromochloromethane
ND
mg/l
0.00050
11/13/05
07:06
PPM
124-48-1
1,2-Dibromoethane (EDB)
ND
mg/l
0.00050
11/13/05
07:06
PPM
106-93-4
Dibromomethane
ND
mg/l
0.00050
11/13/05
07:06
PPM
74-95-3
1,2-Dichlorobenzene
ND
mg/l
0.0010
11/13/05
07:06
PPM
95-50-1
1,3-Dichlorobenzene
ND
mg/l
0.0010
11/13/05
07:06
PPM
541-73-1
1,4-Dichlorobenzene
ND
mg/1
0.0010
11/13/05
07:06
PPM
106-46-7
Dichlorodifluoromethane
ND
mg/l
0.00050
11/13/05
07:06
PPM
75.71-8
1.1-Dichloroethane
ND
mg/l
0.00050
11/13/05
07:06
PPM
75-34-3
1,2-Dichloroethane
ND
mg/l
0.00050
11/13/05
07:06
PPM
107-06-2
1,1-Dichloroethene
ND
mg/l
0.00050
11/13/05
07:06
PPM
75-35-4
cis-1,2-Dichloroethene
ND
mg/l
0.00050
11/13/05
07:06
PPM
156-59-2
trans-1.2-Dichloroethene
ND
mg/l
0.00050
11/13/05
07:06
PPM
156-60-5
1,2-Dichloropropane
ND
mg/l
0.00050
11/13/05
07:06
PPM
78-87-5
1,3-Dichloropropane
ND
mg/l
0.00050
11/13/05
07:06
PPM
142-28.9
2,2-Dichloropropane
ND
mg/l
0.00050
11/13/05
07:06
PPM
594-20-7
1,1-Dichloropropene
ND
mg/l
0.00050
11/13/05
07:06
PPM
563-58-6
cis-1,3-Dichloropropene
ND
mg/l
0.00050
11/13/05
07:06
PPM
10061-01-5
trans-1,3-Dichloropropene
ND
mg/l
0.00050
11/13/05
07:06
PPM
10061-02-6
Diisopropyl ether
ND
mg/l
0.00050
11/13/05
07:06
PPM
108-20-3
Ethylbenzene
ND
mg/l
0.00050
11/13/05
07:06
PPM
100-41-4
Hexachloro-1,3-butadiene
ND
mg/l
0.0020
11/13/05
07:06
PPM
87-68-3
Isopropylbenzene (Cumene)
ND
mg/l
0.00050
11/13/05
07:06
PPM
98-82-8
p-Isopropyltoluene
ND
mg/l
0.0010
11/13/05
07:06
PPM
99-87-6
Methylene chloride
ND
mg/l
0.0020
11/13/05
07:06
PPM
75-09-2
Methyl-tert-butyl ether
ND
mg/l
0.00050
11/13/05
07:06
PPM
1634-04.4
Naphthalene
ND
mg/l
0.0020
11/13/05
07:06
PPM
91-20-3
n-Propylbenzene
ND
mg/l
0.00050
11/13/05
07:06
PPM
103-65-1
Styrene
ND
mg/l
0.00050
11/13/05
07:06
PPM
100-42-5
1,1,1,2-Tetrachloroethane
ND
mg/l
0.00050
11/13/05
07:06
PPM
630-20-6
1,1,2,2-Tetrachloroethane
ND
mg/1
0.00050
11/13/05
07:06
PPM
79-34-5
Tetrachloroethene
ND
mg/l
0.00050
11/13/05
07:06
PPM
127-18-4
Toluene
ND
mg/l
0.00050
11/13/05
07:06
PPM
108-88-3
1,2,3-Trichlorobenzene
ND
mg/l
0.0020
11/13/05
07:06
PPM
87-61-6
1,2,4-Trichlorobenzene
ND
mg/l
0.0020
11/13/05
07:06
PPM
120-82-1
1,1,1-Trichloroethane
ND
mg/l
0.00050
11/13/05
07:06
PPM
71-55.6
1,1,2-Trichloroethane
ND
mg/l
0.00050
11/13/05
07:06
PPM
79-00-5
Date: 11/30/05
Page: 5 of 36
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
SC
99030
without the written consent of Pace Analytical Services, Inc.
SC
99006
FL NELAP
E87648
�elac.,
FL NELAP
E87627

. aceAnalytical°
www.pacelabs.com
Lab Sample No: 926299140
Client Sample ID: MW-07
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax. [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: 828,252.4618
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92106754-002 Date Collected: 11/03/05 10:45
Matrix: Water Date Received: 11/03/05 14:56
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Trichloroethene
ND
mg/l
0.00050
11/13/05
07:06
PPM
79-01-6
Trichlorofluoromethane
ND
mg/l
0.00050
11/13/05
07:06
PPM
75-69-4
1,2,3-Trichloropropane
ND
mg/l
0.00050
11/13/05
07:06
PPM
96.18-4
1,2,4-Trimethylbenzene
ND
mg/l
0.00050
11/13/05
07:06
PPM
95.63-6
1,3,5-Trimethylbenzene
ND
mg/l
0.00050
11/13/05
07:06
PPM
108-67-8
Vinyl chloride
ND
mg/l
0.00050
11/13/05
07:06
PPM
75-01-4
m&p-Xylene
ND
mg/l
0.00050
11/13/05
07:06
PPM
o-Xylene
ND
mg/l
0.00050
11/13/05
07:06
PPM
95-47-6
1-Chloro-3-fluorobenzene (S)
100
%
11/13/05
07:06
PPM
625-98-9
Date: 11/30/05
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712
Sc 99030 without the written consent of Pace Analytical Services, Inc.
FL NELAP E87648 N ACCpq
W C�
V
Page: 6 of 36
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
CE REPORT FORM
Please Print Clearly or Type
Facility Name: Clement Pappas, Inc.
Permit Name (if different):
Facility Address: 125 Industrial Park Road
Hendersonville (street) NC 28792
County Henderson
(city) (state) (zip)
Contact Person: Mr. Blake Kehoe
Telephone #: [phone]
Well Location/ Site Name: Irrigation Area
No. of Wells to be Sampled: 6
from Permit
Well Identification Number (from Permit): MVV-8
For Groundwater Treatment Systems
Well Depth: 13.91 ft. Well Diameter: 2
in.
Check One: ❑ Influent (98)
Screened Interval: 3.9 ft. to 13.9 ft.
❑ Effluent (99)
Depth to Water Level: 10.61 ft. below measuring point.
Measuring Point (M.P.) is: ft. above land surface.
Relative M.P. Elevation in ft.:
Gallons of water pumped/bailed before sampling: 1.75
Date sample collected: 11/03/2005
Field analysis: pH 5.73 , Specific Conductance
173.9 uMhos
Temp. 15.2 'C, Odor None
Appearance Tan
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 MAIL SERVICE CENTER
PERMIT #: WQ0004797 EXPIRATION DATE: 6-30-2007
Non -Discharge X UIC
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Renediation: Infiltration Gallery
X Spray Field Remediation:
Rotary Distributor Land Application of Sludge
Other.
NOTE: Values should reflect dissolved and
colloidal concentrations. rr
Date sample analyzed: 11/03/2005
Laboratory Name: - Pace Analytical Services, Inc.
Certification No. 37706
PARAMETERS (Samples for metals were collected unfiltered YES NO
and field acidified
COD
mg/I
Nitrite (NO2) as N
mg/I
Coliform: MF Fecal <1.1
/100ml
Nitrate (NO3) as N 0.95
mg/I
Coliform: MF Total
/100ml
Phosphorus: Total as P
mg/I.
(Note: Use MPN method for highly turbid samples)
Orthophosphate
mg/I
Dissolved Solids: Total 100
mg/I
Al - Aluminum
mg/I
pH (when analyzed)
units
Ba - Barium
mg/I
TOC 7.1
mg/1
Ca - Calcium
mg/I
Chloride 11
mg/I
Cd - Cadmium
mg/I
Arsenic
mg/I
Chromium: Total
mg/I
Grease and Oils
mg/I
Cu - Copper
mg/I
Phenol
mg/I
Fe - Iron
mg/I
Sulfate 8.4
mg/I
Hg - Mercury
mg/I
Specific Conductance
uMhos
K - Potassium
mg/I
Total Ammonia
mg/I
Mg - Magnesium
mg/I
TKN as N
mg/I
Mn - Manganese
mg/I
r uv. u314vuu
YES NO)
Ni - Nickel mg/I
Pb - Lead mg/1
Zn - Zinc mg/I
Ammonia Nitrogen <0.10 mg/I
Other (Specify Compounds and Concentration Units)
ORGANICS: (GC,GC/MS,HPLC)
(Specify test and method #. Attach lab report.)
ReportAttached? Yes_.?(1) No (0)
VOC : method # = 6230D
method # =
method # =

aceAnalytical°
www. pacelahs. c=
Lab Sample No: 926299132
Client Sample ID: MW-08
Parameters
Microbiology
Fecal Coliform MPN Water
Coliform, Fecal
Wet Chemistry
Total Dissolved Solids
Total Dissolved Solids
Results
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax., 828.252.4618
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92106754-001 Date Collected: 11/03/05 10:00
Matrix: Water Date Received: 11/03/05 14:56
Units Report Limit Analyzed By CAS No. Qual RegLmt
Method: SM 9223
<1.1 mpn/100mL
Method: EPA 160.1
100 mg/l
11/03/05 15:30 MDK
20. 11/05/05 17:39 TCM
Chloride (Mercuric Nitrate)
Method: EPA
325.2
Chloride
11.
mg/l
5.0
11/09/05
11:00
BMF
16887-00-6
Ammonia
Method: EPA
350.1
Nitrogen, Ammonia
NO
mg/l
0.10
11/07/05
16:30
BMF
7727-37-9
48 Hour NO3 / NO2 / NOX
Method: EPA
353.2
Nitrate as N
0.95
mg/l
0.10
11/03/05
23:28
ARH
Sulfate,Turbidimetric
Method: EPA
375.4
Sulfate
8.4
mg/l
5.0
11/09/05
11:30
BMF
Total Organic Carbon
Method: SM 5310B
Total Organic Carbon
7.1
mg/l
1.0
11/09/05
18:46
BMF
7440-44-0
GC Volatiles
GC VOCs in Water
Method: SM 6230D
Benzene
ND
mg/l
0.00050
11/13/05
06:24
PPM
71-43-2
Bromobenzene
NO
mg/1
0.00050
11/13/05
06:24
PPM
108-86-1
Bromochloromethane
ND
mg/l
0.00050
11/13/05
06:24
PPM
74-97-5
Bromodichloromethane
NO
mg/l
0.00050
11/13/05
06:24
PPM
75-27-4
Bromoform
NO
mg/l
0.00050
11/13/05
06:24
PPM
75-25-2
Bromomethane
NO
mg/l
0:00050
11/13/05
06:24
PPM
74-83-9
n-Butylbenzene
NO
mg/l
0.0010
11/13/05
06:24
PPM
104-51-8
sec-Butylbenzene
NO
mg/l
0.00050
11/13/05
06:24
PPM
135-98-8
tert-Butylbenzene
NO
mg/l
0.00050
11/13/05
06:24
PPM
98-06-6
Carbon tetrachloride
NO
mg/l
0.00050
11/13/05
06:24
PPM
56-23-5
Chlorobenzene
NO
mg/l
0.00050
11/13/05
06:24
PPM
108-90-7
Chloroethane
ND
mg/l
0.00050
11/13/05
06:24
PPM
75.00-3
Chloroform
ND
mg/l
0.00050
11/13/05
06:24
PPM
67-66-3
Chloromethane
NO
mg/l
0.0020
11/13/05
06:24
PPM
74-87-3
Date: 11/30/05
Asheville Certification IN REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648 F
EO % `:)1-
��qy
�ac:
Page: 1 of 36
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627

ace Analytical °
www.pacelabs.com
Lab Sample No: 926299132
Client Sample ID: MW-08
Pace Analytical Services, Inc.
9800 KinceyAvenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax., 704.875.9091
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92106754-001 Date Collected: 11/03/05 10:00
Matrix: Water Date Received: 11/03/05 14:56
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
2-Chlorotoluene
ND
mg/l
0.00050
11/13/05
06:24
PPM
95-49-8
4-Chlorotoluene
ND
mg/l
0.00050
11/13/05
06:24
PPM
106-43-4
1,2-Dibromo-3-chloropropane
ND
mg/l
0.0020
11/13/05
06:24
PPM
96-12-8
Dibromochloromethane
ND
mg/l
0.00050
11/13/05
06:24
PPM
124-48-1
1,2-Dibromoethane (EDB)
ND
mg/l
0.00050
11/13/05
06:24
PPM
106-93-4
Dibromomethane
ND
mg/l
0.00050
11/13/05
06:24
PPM
74-95-3
1.2-Dichlorobenzene
ND
mg/l
0.0010
11/13/05
06:24
PPM
95-50-1
1,3-Dichlorobenzene
ND
mg/l
0.0010
11/13/05
06:24
PPM
541-73-1
1,4-Dichlorobenzene
ND
mg/l
0.0010
11/13/05
06:24
PPM
106-46-7
Dichlorodifluoromethane
ND
mg/l
0.00050
11/13/05
06:24
PPM
75-71-8
1,1-Dichloroethane
ND
mg/l
0.00050
11/13/05
06:24
PPM
75-34-3
1,2-Dichloroethane
ND
mg/l
0.00050
11/13/05
06:24
PPM
107-06-2
1,1-Dichloroethene
ND
mg/l
0.00050
11/13/05
06:24
PPM
75-35-4
cis-1,2-Dichloroethene
ND
mg/l
0.00050
11/13/05
06:24
PPM'
156-59-2
trans-1,2-Dichloroethene
ND
mg/l
0.00050
11/13/05
06:24
PPM
156-60-5 -
1,2-Dichloropropane
ND
mg/l
0.00050
11/13/05
06:24
PPM
78-87-5
1,3-Dichloropropane
ND
mg/l
0.00050
11/13/05
06:24
PPM
142-28-9
2,2-Dichloropropane
ND
mg/l
0.00050
11/13/05
06:24
PPM
594-20-7
1,1-Dichloropropene
ND
mg/l
0.00050
11/13/05
06:24
PPM
563-58-6
cis-1,3-Dichloropropene
ND
mg/l
0.00050
11/13/05
06:24
PPM
10061-01-5
trans-1,3-Dichloropropene
ND
mg/l
0.00050
11/13/05
06:24
PPM
10061-02-6
Diisopropyl ether
ND
mg/l
0.00050
11/13/05
06:24
PPM
108-20-3
Ethylbenzene
ND
mg/l
0.00050
11/13/05
06:24
PPM
100-41-4
Hexachloro-1,3-butadiene
ND
mg/l
0.0020
11/13/05
06:24
PPM
87-68-3
Isopropylbenzene (Cumene)
ND
mg/l
0.00050
11/13/05
06:24
PPM
98-82-8
p-Isopropyltoluene
ND
mg/l
0.0010
11/13/05
06:24
PPM
99-87-6
Methylene chloride
ND
mg/l
0.0020
11/13/05
06:24
PPM
75-09-2
Methyl-tert-butyl ether
ND
mg/l
0.00050
11/13/05
06:24
PPM
1634-04-4
Naphthalene
ND
mg/l
0.0020
11/13/05
06:24
PPM
91-20-3
n-Propylbenzene
ND
mg/1'
0.00050
11/13/05
06:24
PPM
103-65-1
Styrene
ND
mg/l
0.00050
11/13/05
06:24
PPM
100-42-5
1,1,1,2-Tetrachloroethane
ND
mg/l
0.00050
11/13/05
06:24
PPM
630-20-6
1,1,2,2-Tetrachloroethane
ND
mg/l
0.00050
11/13/05
06:24
PPM
79-34-5
Tetrachloroethene
ND
mg/l
0.00050
11/13/05
06:24
PPM
127-18-4
Toluene
ND
mg/l
0.00050
11/13/05
06:24
PPM
108-88-3
1,2,3-Trichlorobenzene
ND
mg/l
0.0020
11/13/05
06:24
PPM
87-61-6
1,2,4-Trichlorobenzene
ND
mg/l
0.0020
11/13/05
06:24
PPM
120-82-1
1,1,1-Trichloroethane
ND
mg/l
0.00050
11/13/05
06:24
PPM
71-55-6
1,1,2-Trichloroethane
ND
mg/l
0.00050
11/13/05
06:24
PPM
79-00-5
Date: 11/30/05
Page: 2 of 36
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
Sc
99006
FL NELAP
E87648
N ACCoq
tE0 /' Oq c
FL NELAP
E87627

ace Analytical °
www.pacelabs.com
Lab Sample No: 926299132
Client Sample ID: MW-08
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax:[phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92106754-001 Date Collected: 11/03/05 10:00
Matrix: Water Date Received: 11/03/05 14:56
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Trichloroethene
NO
mg/l
0.00050
11/13/05
06:24
PPM
79-01-6
Trichlorofluoromethane
NO
mg/l
0.00050
11/13/05
06:24
PPM
75-69-4
1,2,3-Trichloropropane
ND
mg/l
0.00050
11/13/05
06:24
PPM
96-18-4
1,2,4-Trimethylbenzene
NO
mg/l
0.00050
11/13/05
06:24
PPM
95-63-6
1,3,5-Trimethylbenzene
NO
mg/l
0.00050
11/13/05
06:24
PPM
108-67-8
Vinyl chloride
NO
mg/l
0.00050
11/13/05
06:24
PPM
75-01-4
m&p-Xylene
NO
mg/l
0.00050
11/13/05
06:24
PPM
o-Xylene
NO
mg/l
0.00050
11/13/05
06:24
PPM
95-47-6
1-Chloro-3-fluorobenzene (S)
110
%
11/13/05
06:24
PPM
625-98-9
Date: 11/30/05
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water37712
SC 990309030 without the written consent of Pace Analytical Services, Inc.
FL NELAP E87648 N ACQ�q
�ne1a�c-
Page: 3 of 36
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

aceAnalytical°
www.pacelabs.com
Lab Sample No: 926302712
Client Sample ID: TRIP BLANK
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax., 704.875.9091
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: 828.254,7176
Fax: 828.252,4618
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92106754-007 Date Collected: 11/03/05 00:00
Matrix: Water Date Received: 11/03/05 14:56
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
GC Volatiles
GC VOCs in Water
Method: SM
6230D
Benzene
NO
mg/l
0.00050
11/13/05
10:35
PPM
71-43-2
Bromobenzene
NO
mg/l
0.00050
11/13/05
10:35
PPM
108-86-1
Bromochloromethane
ND
mg/l
0.00050
11/13/05
10:35
PPM
74-97-5
Bromodichloromethane
NO
mg/l
0.00050
11/13/05
10:35
PPM
75-27-4
Bromoform
NO
mg/l
0.00050
11/13/05
10:35
PPM
75-25-2
Bromomethane
NO
mg/l
0.00050
11/13/05
10:35
PPM
74-83-9
n-Butylbenzene
NO
mg/l
0.0010
11/13/05
10:35
PPM
104-51-8
sec-Butylbenzene
NO
mg/l
0.00050
11/13/05
10:35
PPM
135-98-8
tert-Butylbenzene
ND
mg/l
0.00050
11/13/05
10:35
PPM
98-06-6
Carbon tetrachloride
ND
mg/l
0.00050
11/13/05
10:35
PPM
56-23-5
Chlorobenzene
ND
mg/l
0.00050
11/18/05
10:35
PPM
108-90-7
Chloroethane
ND
mg/l
0.00050
11/13/05
10:35
PPM
75-00-3
Chloroform
NO
mg/l
0.00050
11/13/05
10:35
PPM
67-66-3
Chloromethane
NO
mg/l
0.0020
11/13/05
10:35
PPM
74-87-3
2-Chlorotoluene
NO
mg/l
0.00050
11/13/05
10:35
PPM
95-49-8
4-Chlorotoluene
NO
mg/l
0.00050
11/13/05
10:35
PPM
106-43-4
1,2-Dibromo-3-chloropropane
ND
mg/l
0.0020
11/13/05
10:35
PPM
96-12-8
Dibromochloromethane
NO
mg/l
0.00050
11/13/05
10:35
PPM
124-48-1
1,2-Dibromoethane (EDB)
ND
mg/l
0.00050
11/13/05
10:35
PPM
106-93-4
Dibromomethane
ND
mg/l
0.00050
il/13/05
10:35
PPM
74-95-3
1,2-Dichlorobenzene
ND
mg/l
0.0010
11/13/05
10:35
PPM
95.50-1
1,3-Dichlorobenzene
NO
mg/1
0.0010
11/13/05
10:35
PPM
541-73-1
1,4-Dichlorobenzene
NO
mg/l
0.0010
11/13/05
10:35
PPM
106-46-7
Dichlorodifluoromethane
NO
mg/l
0.00050
11/13/65
10:35
PPM
75-71-8
1,1-Dichloroethane
NO
mg/l
0.00050
11/13/05
10:35
PPM
75-34-3
1,2-Dichloroethane
NO
mg/l
0.00050
11/13/05
10:35
PPM'
107-06-2
1,1-Dichloroethene
ND
mg/l
0.00050
11/13/05
10:35
PPM
75-35-4
cis-1,2-Dichloroethene
ND
mg/l
0.00050
11/13/05
10:35
PPM
156-59-2
trans-1,2-Dichloroethene
NO
mg/l
0.00050
11/13/05
10:35
PPM
156-60-5
1,2-Dichloropropane
NO
mg/l
0.00050
11/13/05
10:35
PPM
78-87-5
1,3-Dichloropropane
NO
mg/l
0.00050
11/13/05
10:35
PPM
142-28-9
2,2-Dichloropropane
-ND
mg/l
0.00050
11/13/05
10:35
PPM
594-20-7
1,1-Dichloropropene
NO
mg/l
0.00050
11/13/05
10:35
PPM
563-58-6
cis-1,3-Dichloropropene
NO
mg/l
0.00050
11/13/05
10:35
PPM
10061-01-5
trans-1,3-Dichloropropene
ND
mg/l
0.00050
11/13/05
10:35
PPM
10061-02-6
Diisopropyl ether
NO
mg/l
0.00050
11/13/05
10:35
PPM
108-20-3
Ethylbenzene
NO
mg/l
0.00050
11/13/05
10:35
PPM
100.41-4
Date: 11/30/05
Page: 19 of 36
Asheville Certification IDS-
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
Sc
99006
FL NELAP
E87648
FL NELAP
E87627
N

ace Analytical °
www.paceiahs.com
Lab Sample No: 926302712
Client Sample ID: TRIP BLANK
Pace Analytical Services, Inc.
9800 KinceyAvenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 92106754-007 Date Collected: 11/03/05 00:00
Matrix: Water Date Received: 11/03/05 14:56
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Hexachloro-1,3-butadiene
ND
mg/l
0.0020
11/13/05
10:35
PPM
87-68-3
Isopropylbenzene (Cumene)
ND
mg/l
0.00050
11/13/05
10:35
PPM
98-82-8
p-Isopropyltoluene
ND
mg/l
0.0010
11/13/05
10:35
PPM
,99 87 6
Methylene chloride
ND
mg/l
0.0020
11/13/05
10:35
PPM
75-09-2
Methyl-tert-butyl ether
ND
mg/l
0.00050
11/13/05
10:35
PPM
1634-04-4
Naphthalene
ND
mg/l
0.0020
11/13/05
10:35
PPM
91-20-3
n-Propylbenzene
ND
mg/l
0.00050
11/13/05
10:35
PPM
103-65-1
Styrene
ND
mg/l
0.00050
11/13/05
10:35
PPM
100-42-5
1,1,1,2-Tetrachloroethane
ND
mg/l
0.00050
11/13/05
10:35
PPM
630.20-6
1,1,2,2-Tetrachloroethane
ND
mg/l
0.00050
11/13/05
10:35
PPM
79-34-5
Tetrachloroethene
ND
mg/l
0.00050
11/13/05
10:35
PPM
127-18-4
Toluene
ND
mg/l
0.00050
11/13/05
10:35
PPM
108-88-3
1,2,3-Trichlorobenzene
ND
mg/l
0.0020
11/13/05
10:35
PPM
87-61-6
1,2,4-Trichlorobenzene
ND
mg/l
0.0020
11/13/05
10:35
PPM
120-82-1
1,1,1-Trichloroethane
ND
mg/l
0.00050
11/13/05
10:35
PPM
71-55-6
1,1,2-Trichloroethane
ND
mg/l
0.00050
11/13/05
10:35
PPM
79-00-5
Trichloroethene
ND
mg/l
0.00050
11/13/05
10:35
PPM
79-01-6
Trichlorofluoromethane
ND
mg/l
0.00050
11/13/05
10:35
PPM
75-69-4
1,2,3-Trichloropropane
ND
mg/l
0.00050
11/13/05
10:35
PPM
96-18-4
1,2,4-Trimethylbenzene
ND
mg/l
0.00050
11/13/05
10:35
PPM
95-63-6
1,3,5-Trimethylbenzene
ND
mg/l
0.00050
11/13/05
10:35
PPM
108-67-8
Vinyl chloride
ND
mg/l
0.00050
11/13/05
10:35
PPM
75-01-4
m&p-Xylene
ND
mg/l
0.00050
11/13/05
10:35
PPM
o-Xylene
ND
mg/l
0.00050
11/13/05
10:35
PPM
95-47-6
1-Chloro-3-fluorobenzene (S)
103
%
11/13/05
10:35
PPM
625-98-9
Date: 11/30/05
Asheville Certification IN
NC Wastewater 40
NC Drinking Water 37712
Sc 99030
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
♦ N ACCORp4
l�.. 6C
<W e 2
Page: 20 of 36
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627

ace Analytical °
www.pacelabs.com
n
PARAMETER FOOTNOTES
Method 9071E modified to use ASE.
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: 828.254,7176
Fax. [phone]
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
All pH, Free Chlorine, Total Chlorine and Ferrous Iron analyses conducted outside of EPA recommended immediate
hold time.
Depending on the moisture content the PRLs can be elevated for all soil samples reported on a dry weight basis.
2-Chloroethyl vinyl ether has been shown to degrade in the presence of acid.
ND Not detected at or above adjusted reporting limit
NC Not Calculable
J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
(S) Surrogate
Date: 11/30/05
Asheville certification IN REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712 without the written consent of Pace Analytical Services, Inc.
Sc 99030
FL NELAP E87648
�Ia1%m=
Page: 21 of 36
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Analytical k Phone:704.875.909
/ fax: [phone]
www.pacelabs.com QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax., 828.252.4618
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
QC Batch: 142553 Analysis Method: SM 6230D
QC Batch Method: SM 6230D Analysis Description: GC VOCs in Water
Associated Lab Samples: 926299132 926299140 926299157 926299165 926299173
926299181 926302712
METHOD BLANK: 926333402
Associated Lab Samples: 926299132 926299140 926299157 926299165 926299173 926299181 926302712
Blank
Reporting
Parameter
Units
Result
Limit Footnotes
Benzene.
ug/l
NO
0.50
Bromobenzene
ug/l
NO
0.50
Bromochloromethane
ug/l
NO
0.50
Bromodichloromethane
ug/l
NO
0.50
Bromoform
ug/l
NO
0.50
Bromomethane
ug/l
ND
0.50
n-Butylbenzene
ug/l
NO
1.0
sec-Butylbenzene
ug/l
NO
0.50
tert-Butylbenzene
ug/l
NO
0.50
Carbon tetrachloride
ug/l
ND
0.50
Chlorobenzene
ug/l
NO
0.50
Chloroethane
ug/l
NO
0.50
Chloroform
ug/l
ND
0.50
Chloromethane
ug/l
ND
2.0
2-Chlorotoluene
ug/l
NO
0.50
4-Chlorotoluene
ug/l
NO
0.50
1,2-Dibromo-3-chloropropane
ug/l
ND
2.0
Dibromochloromethane
ug/l
ND
0.50
1,2-Dibromoethane (EDB)
ug/l
NO
0.50
Dibromomethane
ug/l
NO
0.50
1,2-Dichlorobenzene
ug/l
NO
1.0
1,3-Dichlorobenzene
ug/l
ND
1.0
1,4-Dichlorobenzene
ug/l
ND
1.0
Dichlorodifluoromethane
ug/l
NO
0.50
1,1-Dichloroethane
ug/l
NO
0.50
1,2-Dichloroethane
ug/l
ND
0.50
1,1-Dichloroethene
ug/l
ND
0.50
cis-1,2-Dichloroethene
ug/l
NO
0.50
trans-1,2-Dichloroethene
ug/l
ND
0.50
1,2-Dichloropropane
ug/l
ND
0.50
Date: 11/30/05
Page: 22 of 36
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
SC
99006
FL NELAP
E87648
Ro
W
FL NELAP
E87627
P „Yr.r�f
n

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 2225 Riverside Drive
Huntersville, NC 28078 Asheville, NC 28804
Analytical � Phone: [phone] Phone: [phone]
Fax., 704.875.9091 Fax. [phone]
www.pace►abs.com QUALITY CONTROL DATA
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
METHOD BLANK: 926333402
Associated Lab Samples: 926299132 926299140 926299157 926299165 926299173 926299181 926302712
Blank
Reporting
Parameter
Units
Result
Limit Footnotes
1,3-Dichloropropane
ug/l
ND
0.50
2,2-Dichloropropane
ug/l
NO
0.50
1,1-Dichloropropene
ug/l
NO
0.50
cis-1,3-Dichloropropene
ug/l
NO
0.50
trans-1,3-Dichloropropene
ug/1
NO
0.50
Diisopropyl ether
ug/l
NO
0.50
Ethylbenzene
ug/1
ND
0.50
Hexachloro-1,3-butadiene
ug/l
ND
2.0
Isopropylbenzene (Cumene)
ug/l
ND
0.50
p-Isopropyltoluene
ug/l
ND
1.0
Methylene chloride
ug/l
NO
2.0
Methyl-tert-butyl ether
ug/l
NO
0.50
Naphthalene
ug/l
NO
2.0
n-Propylbenzene
ug/l
NO
0.50
Styrene
ug/l
ND
0.50
1,1,1,2-Tetrachloroethane
ug/l
ND
0.50
1,1,2,2-Tetrachloroethane
ug/l
ND
0.50
Tetrachloroethene
ug/l
ND
0.50
Toluene
ug/l
NO
0.50
1,2,3-Trichlorobenzene
ug/l
NO
2.0
1,2,4-Trichlorobenzene
ug/l
NO
2.0
1,1,1-Trichloroethane
ug/l
ND
0.50
1.1,2-Trichloroethane
ug/l
ND
0.50
Trichloroethene
ug/l
ND
0.50
Trichlorofluoromethane
ug/l
ND
0.50
1,2,3-Trichloropropane
ug/l
NO
0.50
1,2,4-Trimethylbenzene
ug/l
NO
0.50
1,3,5-Trimethylbenzene
ug/l
NO
0.50
Vinyl chloride
ug/l
ND
0.50
m&p-Xylene
ug/l
ND
0.50
o-Xylene
ug/l
ND
0.50
1-Chloro-3-fluorobenzene (S)
%
110
Date: 11/30/05
Asheville Certification IN REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648
. ,jiJact.
Page: 23 of 36
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

� aceAnalytical °
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Hunters ville, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
LABORATORY CONTROL SAMPLE & LCSD: 926333410 926333428
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax., 828.252.4618
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
Spike
LCS
LCSD
LCS
LCSD
Parameter
Units
Conc.
Result
Result
Y. Rec
i Rec
RPD
Benzene
ug/l
20.00
20.01
19.91
100
100
1
Bromobenzene
ug/l
20.00
20.34
20.90
102
105
3
Bromochloromethane
ug/l
20.00
15.47
16.65
77
83
7
Bromodichloromethane
ug/l
20.00
18.98
20.32
95
102
7
Bromoform
ug/l
20.00
19.91
20.60
100
103
3
Bromomethane
ug/1
20.00
29.85
33.14
149
166
10
n-Butylbenzene
ug/l
20.00
19.44
19.30
97
96
1
sec-Butylbenzene
ug/l
20.00
21.96
21.64
110
108
1
tert-Butylbenzene
ug/l
20.00
20.37
20.24
102
101
1
Carbon tetrachloride
ug/l
20.00
19.49
20.94
97
105
7
Chlorobenzene
ug/l
20.00
26.03
28.37
130
142
9
Chloroethane
ug/l
20.00
21.05
22.54
105
113
7
Chloroform
ug/l
20.00
21.46
22.51
107
113
5
Chloromethane
ug/l
20.00
21.00
22.39
105
112
6
2-Chlorotoluene
ug/l
20.00
18.76
20.24
94
101
8
4-Chlorotoluene
ug/l
20.00
19.21
18.74
96
94
2
1,2-Dibromo-3-chloropropane
ug/l
20.00
24.24
24.40
121
122
1
Dibromochloromethane
ug/l
20.00
19.92
21.26
100
106
7
1,2-Dibromoethane (EDB)
ug/l
20.00
19.21
20.16
96
101
5
Dibromomethane
ug/l
20.00
21.22
22.40
106
112
5
1,2-Dichlorobenzene
ug/l
20.00
19.51
20.42
98
102
5
1,3-Dichlorobenzene
ug/l
20.00
18.67
18.67
93
93
0
1,4-Dichlorobenzene
ug/l
20.00
19.46
21.21
97
106
9
Dichlorodifluoromethane
ug/l
20.00
23.97
25.48
120
127
6
1,1-Dichloroethane
ug/l
20.00
19.70
22.26
98
111
12
1,2-Dichloroethane
ug/l
20.00
19.11
20.55
96
103
7
1,1-Dichloroethene
ug/l
20.00
18.89
19.66
94
98
4
cis-1,2-Dichloroethene
ug/l
20.00
18.94
20.83
95
104
10
trans-1,2-Dichloroethene
ug/l
20.00
18.42
20.35
92
102
10
1,2-Dichloropropane
ug/l
20.00
19.55
20.80
98
104
6
1,3-Dichloropropane
ug/l
20.00
18.76
20.71
94
104
10
2,2-Dichloropropane
ug/l
20.00
13.75
14.51
69
72
5
1,1-Dichloropropene
ug/l
20.00
18.74
20.47
94
102
9
cis-1,3-Dichloropropene
ug/l
20.00
16.72
18.26
84
91
9
trans-1,3-Dichloropropene
ug/l
20.00
16.68
17.88
83
89
7
Diisopropyl ether
ug/l
20.00
21.67
20.42
108
102
6
Ethylbenzene
ug/l
20.00
21.28
21.12
106
106
1
Date: 11/30/05
Asheville Certification IN
REPORT OF LABORATORY ANALYSIS
NC Wastewater
40
NC Drinking Water
37712 7712
This report shall not be reproduced, except in full,
SC
99030
without the written consent of Pace Analytical Services, Inc.
FL NELAP
E87648
/,N RCCpq
ilia"
Footnotes
1.1
Page: 24 of 36
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 2225 Riverside Drive
Huntersville, NC 28078 Asheville, NC 28804
7"", Anal vocal Phone: [phone] Phone: [phone]
Fax: [phone] Fax. [phone]
www.pacelahs.com QUALITY CONTROL DATA
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
LABORATORY CONTROL SAMPLE & LCSD: 926333410 926333428
Spike
LCS
LCSD
LCS
LCSD
Parameter
Units
Conc.
Result
Result
% Rec
% Rec
RPD Footnotes
Hexachloro-1,3-butadiene
ug/l
20.00
17.19
18.58
86
93
8
Isopropylbenzene (Cumene)
ug/l
20.00
20.46
20.32
102
102
1
p-Isopropyltoluene
ug/l
20.00
20.22
20.12
101
101
1
Methylene chloride
ug/l
20.00
18.63
19.68
93
98
6
Methyl-tert-butyl ether
ug/l
20.00
20.32
20.09
102
100
1
Naphthalene
ug/l
20.00
18.83
18.44
94
92
2
n-Propylbenzene
ug/l
20.00
19.75
19.63
99
98
1
Styrene
ug/l
20.00
20.64r
20.52
103
103
1
1,1,1,2-Tetrachloroethane
ug/l
20.00
19.47
20.54
97
103
5
1,1,2,2-Tetrachloroethane
ug/l
20.00
18.94
17.41
95
87
8
Tetrachloroethene
ug/l
20.00
19.68
20.79
98
104
5
Toluene
ug/l
20.00
21.26
21.13
106
106
1
1,2,3-Trichlorobenzene
ug/l
20.00
18.64
20.02
93
. 100
7
1,2,4-Trichlorobenzene
ug/l
20.00
20.57
18.24
103
91
12
1.1,1-Trichloroethane
ug/l
20.00
20.16
21.71
101
109
7
1,1,2-Trichloroethane
ug/l
20.00
19.48
20.90
97
105
7
Trichloroethene
ug/l
20.00
20.39
23.97
102
120
16
Trichlorofluoromethane
ug/l
20.00
21.27
22.61
106
113
6
1,2,3-Trichloropropane
ug/l
20.00
20.17
20.22
101
101
0
1,2,4-Trimethylbenzene
ug/l
20.00
20.33
20.20
102
101
1
1,3,5-Trimethylbenzene
ug/l
20.00
21.23
21.00
106
105
1
Vinyl chloride
ug/l
20.00
22.29
24.60
ill
123
10
m&p-Xylene
ug/l
40.00
39.75
39.40
99
98
1
o-Xylene
ug/l
20.00
21.20
21.02
106
105
1
1-Chloro-3-fluorobenzene (S)
101
106
SAMPLE DUPLICATE: 926333436
926301292
DUP
Parameter
Units
Result
Result
RPD Footnotes
Benzene
mg/l
ND
ND
NC
Bromobenzene
mg/l
ND
ND
NC
Bromochloromethane
mg/l
ND
ND
NC
Bromodichloromethane
mg/l
ND
ND
NC
Bromoform
mg/l
ND
ND
NC
Bromomethane
mg/l
ND
ND
NC
Date: 11/30/05
Page: 25 of 36
Asheville Certification IN
REPORT OF LABORATORY ANALYSIS
Charlotte Certification IDs
NC Wastewater
40
NC Wastewater
12
NC Drinking Water
37712
This report shall not be reproduced, except in full,
NC Drinking Water
37706
Sc
99030
without the written consent of Pace Analytical Services, Inc.
Sc
99006
FL NELAP
E87648
ACCORo4y
FL NELAP
E87627
`�O�N
neiact.

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 2225 Riverside Drive
Huntersville, NC 28078 Asheville, NC 28804
Analytical � Phone: [phone] Phone: [phone]
in Fax: [phone] Fax: [phone]
www.pacelabs.com QUALITY CONTROL DATA
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
SAMPLE DUPLICATE: 926333436
926301292
DUP
Parameter
Units
Result
Result
RPD Footnotes
n-Butylbenzene
mg/l
ND
ND
NC
sec-Butylbenzene
mg/l
ND
ND
NC
tert-Butylbenzene
mg/l
ND
ND
NC
Carbon tetrachloride
mg/l
ND
ND
NC
Chlorobenzene
mg/l
ND
ND
NC
Chloroethane
mg/l
ND
ND
NC
Chloroform
mg/l
ND
ND
NC
Chloromethane
mg/l
ND
ND
NC
2-Chlorotoluene
mg/l
ND
ND
NC
4-Chlorotoluene
mg/l
ND
ND
NC
1,2-Dibromo-3-chloropropane
mg/l
ND
ND
NC
Dibromochloromethane
mg/l
ND
ND
NC
1,2-Dibromoethane (EDB)
mg/l
ND
ND
NC
Dibromomethane
mg/l
ND
ND
NC
1,2-Dichlorobenzene
mg/l
ND
ND
NC
1,3-Dichlorobenzene
mg/l
ND
ND
NC
1,4-Dichlorobenzene
mg/l
ND
ND
NC
Dichlorodifluoromethane
mg/l
ND
ND
NC
1,1-Dichloroethane
mg/l
ND
ND
NC
1,2-Dichloroethane
mg/l
ND
ND
NC
1,1-Dichloroethene
mg/l
ND
ND
NC
cis-1,2-Dichloroethene
mg/l
ND
ND
NC
trans-1,2-Dichloroethene
mg/l
ND
ND
NC
1,2-Dichloropropane
mg/l
ND
ND
NC
1,3-Dichloropropane
mg/l
ND
ND
NC
2,2-Dichloropropane
mg/l
ND
ND
NC
1,1-Dichloropropene
mg/l
ND
ND
NC
cis-1,3-Dichloropropene
mg/l
ND
ND
NC
trans-1,3-Dichloropropene
mg/l
ND
ND
NC
Diisopropyl ether
mg/l
ND
ND
NC
Ethylbenzene
mg/l
ND
ND
NC
Hexachloro-1,3-butadiene
mg/l
ND
ND
NC
Isopropylbenzene (Cumene)
mg/l
ND
ND
NC
p-Isopropyltoluene
mg/l
ND
ND
NC
Methylene chloride
mg/1
ND
ND
NC
Methyl-tert-butyl ether
mg/l
ND
ND
NC
Naphthalene
mg/l
ND
ND
NC
Date: 11/30/05
Page: 26 of 36
Asheville Certification IN
NC Wastewater 40
NC Drinking Water 37712
SC 99030
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
x nccoe
meia
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Analytical'5 Phone: 704.875.909
Fax: [phone]
www.pace►abs.com QUALITY CONTROL DATA
SAMPLE DUPLICATE: 926333436
926301292
DUP
Parameter
Units
Result
Result
n-Propylbenzene
mg/l
ND
ND
Styrene
mg/l
ND
ND
1,1,1,2-Tetrachloroethane
mg/l
ND
ND
1,1,2,2-Tetrachloroethane
mg/l
ND
ND
Tetrachloroethene
mg/l
ND
ND
Toluene
mg/l
ND
ND
1,2,3-Trichlorobenzene
mg/l
ND
ND
1,2,4-Trichlorobenzene
mg/l
ND
ND
1,1,1-Trichloroethane
mg/l
ND
ND
1,1,2-Trichloroethane
mg/l
ND
ND
Trichloroethene
mg/l
ND
ND
Trichlorofluoromethane
mg/l
ND
ND
1,2,3-Trichloropropane
mg/l
ND
ND
1,2,4-Trimethylbenzene
mg/l
ND
ND
1,3,5-Trimethylbenzene
mg/l
ND
ND
Vinyl chloride
mg/l
ND
ND
m&p-Xylene
mg/l
ND
ND
o-Xylene
mg/l
ND
ND
1-Chloro-3-fluorobenzene (S)
Y.
105
100
Date: 11/30/05
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
RPD Footnotes
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
NC Wastewater
40
NC Drinking Water
37712
This report shall not be reproduced, except in full,
SC
99030
without the written consent of Pace Analytical Services, Inc.
FL NELAP
E87648
Page: 27 of 36
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

acmnalytical°
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax., 828.252.4618
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
QC Batch: 142521 Analysis Method: SM 9223
QC Batch Method: Standard Methods Analysis Description: Fecal Coliform MPN Water
Associated Lab Samples: 926299132 926299140 926299157 926299165 926299173
926299181
METHOD BLANK: 926331612
Associated Lab Samples: 926299132 926299140 926299157 926299165 926299173 926299181
Blank Reporting
Parameter Units Result Limit Footnotes
Coliform, Fecal negative
Date: 11/30/05
Asheville Certification IN REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
SC 99030 without the written consent of Pace Analytical Services, Inc.
FL NELAP E87648 N ACCpRo c
Page: 28 of 36
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 2225 Riverside Drive
Huntersville, NC 28078 Asheville, NC 28804
Analytical Phone: [phone] Phone: [phone]
Fax: [phone] Fax. [phone]
www.pacelabs.com QUALITY CONTROL DATA
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
QC Batch: 141954
Analysis Method: EPA 160.1
QC Batch Method: EPA 160.1
Analysis
Description: Total Dissolved Solids
Associated Lab Samples:
926299132
926299140 926299157 926299165 926299173
926299181
METHOD BLANK: §26308255
Associated Lab Samples:
926299132 926299140
926299157 926299165 926299173 926299181
Blank
Reporting
Parameter
Units
Result
Limit Footnotes
Total Dissolved Solids
mg/l
NO
20'.
LABORATORY CONTROL SAMPLE:
926308263
Spike
LCS LCS
Parameter
Units
Conc.
Result Y, Rec Footnotes
Total Dissolved Solids
mg/1
250.00
206.0 82
SAMPLE DUPLICATE: 926308271
926293226 DUP
Parameter Units Result Result RPD Footnotes
Total Dissolved Solids mg/l 1500 1500 1
Date: 11/30/05
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648
W a,
�.y
Page: 29 of 36
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Analytical o Phone. 704.875.909
. Fax: [phone]
www.pacelabs.com QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
QC Batch: 141819 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 48 Hour NO3 / NO2 / NOX
Associated Lab Samples: 926299132 926299140 926299157 926299165 926299173
926299181
METHOD BLANK: 926301664
Associated Lab Samples: 926299132 926299140 926299157 926299165 926299173 926299181
Blank Reporting
Parameter Units Result Limit Footnotes
Nitrate as N mg/l NO 0.10
LABORATORY CONTROL SAMPLE: 926301672
Spike LCS LCS
Parameter Units Conc. Result i Rec Footnotes
Nitrate as N mg/l 5.000 5.000 100
MATRIX SPIKE: 926301698
926300807 Spike MS MS
Parameter Units Result Conc. Result % Rec Footnotes
Nitrate as N mg/l 0.1050 5.000 5.736 113
SAMPLE DUPLICATE: 926301680
Parameter Units
Nitrate as N mg/l
Date: 11/30/05
926300781 DUP
Result Result RPD Footnotes
0.3000 0.3200 6
Asheville Certification IDs
REPORT OF LABORATORY ANALYSIS
NC Wastewater
40
NC Drinking Water
37712
37712
This report shall not be reproduced, except in full,
SC
99030
without the written consent of Pace Analytical Services, Inc.
FL NELAP
E87648
Page: 30 of 36
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Analytical" Phone: 704.875.909
Fax: [phone]
www.pacelabs.com QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax. [phone]
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
QC Batch: 141988
Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1
Analysis
Description: Ammonia
Associated Lab Samples:
926299132
926299140 926299157 926299165 926299173
926299181
METHOD BLANK: 926310020
Associated Lab Samples:
926299132 926299140
926299157 926299165 926299173 926299181
Blank
Reporting
Parameter
Units
Result
Limit Footnotes
Nitrogen, Ammonia
mg/l
ND
0.10
LABORATORY CONTROL SAMPLE:
926310038
Spike
LCS LCS
Parameter
Units
Conc.
Result i Rec Footnotes
Nitrogen, Ammonia
mg/l
1.000
1.010 101
MATRIX SPIKE: 926310046
926292566 Spike MS MS
Parameter Units Result Conc. Result % Rec Footnotes
Nitrogen, Ammonia mg/l 0 1.000 0.8980 90
SAMPLE DUPLICATE: 926310053
926292608 DUP
Parameter Units Result Result RPD Footnotes
Nitrogen, Ammonia mg/l 0.1800 0.1800 2
Date: 11/30/05
Asheville Certification IN REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648
is ac
Page: 31 of 36
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Analytical o Phone: 704.875.909
� Fax: [phone]
www.pacelabs.com QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax., 828.252.4618
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
QC Batch: 142236 Analysis Method: SM 5310B
QC Batch Method: SM 5310B Analysis Description: Total Organic Carbon
Associated Lab Samples: 926299132
METHOD BLANK: 926318635
Associated Lab Samples: 926299132
Blank Reporting
Parameter Units Result Limit Footnotes
Total Organic Carbon mg/1 NO 1.0
LABORATORY CONTROL SAMPLE: 926318643
Spike LCS LCS
Parameter Units Conc. Result % Rec Footnotes
Total Organic Carbon mg/l 10.00 8.983 90
MATRIX SPIKE: 926318650
926260795 Spike MS MS
Parameter Units Result Conc. Result % Rec Footnotes
Total Organic Carbon mg/l 357.5 10.00 357.5 0 2
SAMPLE DUPLICATE: 926318668
Parameter Units
Total Organic Carbon mg/l
Date: 11/30/05
926314758 DUP
Result Result RPD Footnotes
4.100 4.300 4
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
SC 99030 without the written consent of Pace Analytical Services, Inc.
& accc
FL NELAP E87648
-neizic.
Page: 32 of 36
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

0
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Analytical o Phone. 704.875.909
� Fax: [phone]
www.pacelabs.com QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
QC Batch: 142249
Analysis
Method: EPA 375.4
QC Batch Method: EPA 375.4
Analysis
Description: Sulfate,Turbidimetric
Associated Lab Samples:
926299132
926299140
926299157 926299165 926299173
926299181
METHOD BLANK: 926319047
Associated Lab Samples:
926299132 926299140
926299157 926299165 926299173 926299181
Blank
Reporting
Parameter
Units
Result
Limit Footnotes
Sulfate
mg/l
ND
5.0
LABORATORY CONTROL SAMPLE:
926319054
Spike
LCS LCS
Parameter
Units
Conc.
Result Y. Rec Footnotes
Sulfate
mg/l
20.00
20.42 102
MATRIX SPIKE: 926319062
926266008
Spike MS MS
Parameter
Units
Result
Conc. Result Y Rec Footnotes
Sulfate
mg/l
12.04
20.00 30.70 93
SAMPLE DUPLICATE: 926319070
926300781 DUP
Parameter Units Result Result RPD Footnotes
Sulfate mg/l 35.00 36.00 1
Date: 11/30/05
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712
SC 99030 without the written consent of Pace Analytical Services, Inc.
FL NELAP E87648 4� % ACCpRo4
,-neiaC
Page: 33 of 36
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

aceAnalytical °
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
QC Batch: 142250 Analysis Method: EPA 325.2
QC Batch Method: EPA 325.2 'Analysis Description: Chloride (Mercuric Nitrate)
Associated Lab Samples: 926299132 926299140 926299157 926299165 926299173
926299181
METHOD BLANK: 926319088
Associated Lab Samples: 926299132 926299140 926299157 926299165 926299173 926299181
Blank Reporting
Parameter Units Result Limit Footnotes
Chloride mg/l NO 5.0
LABORATORY CONTROL SAMPLE: 926319096
Spike LCS LCS
Parameter Units Conc. Result Y. Rec Footnotes
Chloride mg/l 20.00 20.18 101
MATRIX SPIKE: 926319104
926293697 Spike MS MS
Parameter Units Result Conc. Result i Rec Footnotes
Chloride mg/l 33.92 20.00 50.18 81
SAMPLE DUPLICATE: 926319112
926296906 DUP
Parameter Units Result Result RPD Footnotes
Chloride mg/l NO NO NC
Date: 11/30/05
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water 37712 This report shall not be reproduced, except in full,
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648 " ACCOR
act.
Page: 34 of 36
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

aceAnalytical °
www. pacelabs. com
Pace Analytical Services, Inc.
9800 KinceyAvenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax., 828,252.4618
Lab Project Number: 92106754
Client Project ID: Clement Pappas 2081.01
QC Batch: 142734 Analysis Method: SM 5310B
QC Batch Method: SM 5310B Analysis Description: Total Organic Carbon
Associated,Lab Samples: 926299140 926299157 926299165 926299173 926299181
METHOD BLANK: 926340472
Associated Lab Samples: 926299140 926299157 926299165 926299173 926299181
Blank Reporting
Parameter Units Result Limit Footnotes
Total Organic Carbon mg/l NO 1.0
LABORATORY CONTROL SAMPLE: 926340480
Spike LCS LCS
Parameter Units Conc. Result % Rec Footnotes
Total Organic Carbon mg/l 10.00 9.300 93
MATRIX SPIKE: 926340498
926299140 Spike MS MS
Parameter Units Result Conc. Result % Rec Footnotes
Total Organic Carbon mg/l 7.690 10.00 17.96 103
SAMPLE DUPLICATE: 926340506
Parameter Units
Total Organic Carbon mg/l
Date: 11/30/05
926299157 DUP
Result Result RPD Footnotes
6.300 6.200 2
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40
NC Drinking Water This report shall not be reproduced, except in full,
SC 37712 7712 without the written consent of Pace Analytical Services, Inc.
99030
t� \N ACppR04
FL NELAP E87648 ¢o,� �—, _�:���
J., neka t.
Page: 35 of 36
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

ace Analytical °
www.pacelabs.com
QUALITY CONTROL DATA PARAMETER FOOTNOTES
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: 828.254,7176
Fax., 828.252.4618
Lab Project Number: 92106754
Client Project ID: Clement.Pappas 2081.01
Consistent with EPA guidelines, unrounded concentrations are displayed and have been used to calculate % Rec and RPD values.
LCS(D) Laboratory Control Sample (Duplicate)
MS(D) Matrix Spike (Duplicate)
DUP Sample Duplicate
ND Not detected at or above adjusted reporting limit
NC Not Calculable
J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
RPD Relative Percent Difference
(S) Surrogate
[1] Recovery falls outside of QC limits, however, this compound is not found in the associated samples.
[21 The spike recovery was outside acceptance limits for the MS and/or MSD due to an analyte concentration in the
sample at four times greater than the spike concentration. The QC batch was accepted based upon LCS and/or
LCSD recoveries within acceptance limits.
Date: 11/30/05
Asheville Certification IDs REPORT OF LABORATORY ANALYSIS
NC Wastewater 40 This report shall not be reproduced, except in full,
NC Drinking Water 37712
SC 37712 without the written consent of Pace Analytical Services, Inc.
99030
FL NELAP E87648 N ACCOgO
W �
Page: 36 of 36
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

.11
GW-59A COMPLIANCE REPORT FORM
Permit # W Q 000 i-119 rl
(Submit one each monitoring period with Gff 59 for•nis.)
j tnter sate monitoring results were due. (io1-J l-oS) Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
2 Was any required information missing on the GW-59 report forms?
YES
NO
—s
IF the answer to question 1 or 2 is 'YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? If the answer is "Yes", contact the Regional Office for guidance.
"-
4 Are any monitored constituents equal to or above the established standards?
YES
NO
If the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells indi 'dually with constituent(s) and concentration(s)
exceeding standards in the space provided below. MG/-S $ _ 1i2 i_ iGt lor�*h�i✓G= O.ZZ
1
n%I}ra�LZ10,M)�L mw-y iuG=fbW1j�L \&JrrcAe oro�i�CNr=L t �K)
11 �03 dais / f
11`031210r )Il03lacbS Tric�1orocS4c,ve-= 0,attv5{
5 For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
No
same constituent(s) in the same well(s) in the last two years?
�-"-
if the answer to question 5 is NO", skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s) reported, and sampleril cfion date for each occurrence (for the last two years).
/11(n/-� G-irgoil�or�C'G�enr•P= �•Jr��
J I6+rq c k 10 ro A ee,Je - 3 , S- m) % L✓
)IJb4f03
111o9104 Ic.,Uoroe-+L'.NL=Q.Oba�,��L I
IL
l
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL
- -----OFFICEIMMEDIA-T-EL-Y-FOR-GUIDANCE. If -the answeris-"NO'; monitoring -wells maybe improperly
-"-
- --
located; contact the Regional Office.
7 Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO" contact the Regional Office within 90 days; an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation
fines, and/or penalties.
H- AIN v C,, I' G nr 7br n c� L> r- V 0 6 S
g The person completing this portion (G W-59A) of the monitoring report should sign below and submit this
form with G W-59 forms for required wells to the address provided at the top of the current G W-59 form.
�I porthere y;acknow ge th theyaboweanformation�wa a Yaluated�and tiie�nf matron submitted m thls�''{ ��
re Report GW 59A),is rue and complete,o the best of my knowledge �, "tt6u
_(Comgliance
Signature of Permittee (or Authorized Agent) Date
G11'-59A 12/3/2003