WQ0004797_Monitoring (Report)_20041219

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
FACILITY INFORMATION
Please Print Clearly or Type
Facility Name: Clement Pappas, Inc.
Permit Name (if different):
Facility Address: 125 Industrial Park Road
Hendersonville (street) NC 28792
County Henderson
(city) (State) (zip)
Contact Person: Mr. Blake Kehoe
Telephone #: [phone]
Well Location/ Site Name: Irrigation Area
No. of Wells to be Sampled: 6om
Permit)
Well Identification Number (from Permit): MW-2
For Groundwater Treatment Systems
Well Depth: 16.0 ft. Well Diameter: 4
in.
Check 0ne: ❑ Influent (98)
Screened Interval: 6 ft. to 16 ft.
❑ Effluent (99)
Depth to Water Level: 6.7 ft. below measuring point.
Measuring Point (M.P.) is: ft. above land surface.
Relative M.P. Elevation in ft.:
Gallons of water pumped/bailed before sampling: 8
Date sample collected: 11/09/2004
Field analysis: pH 4.40 , Specific Conductance
190.1 uMhos
Temp. 13.5 OC, Odor none
Appearance
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636 MAIL SERVICE CENTER
PERMIT #: WQ0004797 EXPIRATION DATE: 9-30-06
Non -Discharge X UIC
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
X Spray Field Remediation:
Rotary Distributor Land Application of Sludge
Other:
NOTE: Values should reflect dissolved and
colloidal concentrations.
Date sample analyzed: 11/09/2004
Laboratory Name: Pace Analytical Services, Inc.
Certification No. 37706
PARAMETERS (Samples for metals were collected unfiltered X YES NO
and field acidified
COD
mg/I
Nitrite (NO2) as N
mg/I
Coliform: MF Fecal- > 23
/100ml
Nitrate-(NO3) as N 7.4
mg/I
_ _
Coliform: MF Total
/100ml
Phosphorus: Total as P
mg/I
(Note: Use. MPN method for highly turbid samples)
Orthophosphate
mg/I'
Dissolved Solids: Total 140
mg/I
AI - Aluminum
mg/I
pH (when analyzed)
units
Ba - Barium
mg/I
TOC 2.4
mg/I
Ca - Calcium
mg/I
Chloride 31
mg/I
Cd - Cadmium
mg/I
Arsenic
mg/I
Chromium: Total
mg/I
Grease and Oils
mg/I
Cu - Copper
mg/I
Phenol
mg/l
Fe - Iron
mg/I
Sulfate <5.0
mg/I
Hg - Mercury
mg/I
Specific Conductance
uMhos
K - Potassium
mg/I
Total Ammonia
mg/1
Mg - Magnesium
mg/I
TKN as N
mg/I
Mn - Manganese
mg/I
r(ev. UJ/ZUUU
_A YES NO)
Ni - Nickel
mg/I
Pb-- Lead
= mg/I
Zn - Zinc.
mg/I
Ammonia Nitrogen < 0.10
mg/I
Other (Specify Compounds and Concentration IJ- hits)
�a
rye
_4i
g>
c')
w
°
ORGANICS: (GC,GC/MS,HPLC) o
(Specify test and method #. Attach lanepolatj
Report Attached? Yes-1L(1) No
= (0)
VOC method # = 6230�
method # =
method # =

-02 ---1 aceAnalytical °
www.pacelabs.com
Lab Sample No: 924948904
Client Sample ID: MW-2
Pace Analytical Services, inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 9281068-002 Date Collected: 11/09/04 10:00
Matrix: Water Date Received: 11/09/04 13:38
Parameters Results Units Report Limit Analyzed By CAS No. Qual RegLmt
Microbiology
Fecal Coliform MPN Water Method: SM 9223
Coliform, Fecal >23 11/09/04 MMG
Wet Chemistry
Total Dissolved Solids Method: EPA 160.1
Total Dissolved Solids 140 mg/l 20. 11/12/04 CD1
Chloride (Mercuric Nitrate) Method: EPA 325.2
Chloride
31.
mg/l
5.0
11/15/04
09:27
MMG
16887-00-6
Ammonia
Method: EPA
350.1
Nitrogen, Ammonia
ND
mg/1
0.10
11/12/04
13:55
TMR
7727-37-9
48 Hour NO3 / NO2 / NOX
Method: EPA
353.2
Nitrate as N
7.4
mg/1
0.10
11/10/04
10:15
EWS
Sulfate,Turbidimetric
Method: EPA
375.4
Sulfate
NO
mg/l
5.0
11/22/04
09:40
TMR
Total Organic Carbon
Method: SM
5310B
Total Organic Carbon
2.4
mg/l
0.50
11/10/04
17:01
EWS
7440-44-0
GC Volatiles
GC VOCs in Water
Method: SM
6230D
Benzene
NO
ug/l
0.50
11/19/04
14:39
PPM
71-43-2
Bromobenzene
ND
ug/l
0.50
11/19/04
14:39
PPM
108-86-1
Bromochloromethane
NO
ug/l
0.50
11/19/04
14:39
PPM
74-97-5
Bromodichloromethane
NO
ug/l
0.50
11/19/04
14:39
PPM
75-27-4
Bromoform
ND
ug/l
0.50
11/19/04
14:39
PPM
75-25-2
Bromomethane
ND
ug/l
0.50
11/19/04
14:39
PPM
74-83-9
n-Butylbenzene
ND
ug/l
1.0
11/19/04
14.;39
PPM
104-51-8
sec-Butylbenzene
ND
ug/l
0.50
11/19/04
14:39
PPM
135-98-8
tert-Butylbenzene
NO
ug/l
0.50
11/19/04
14:39
PPM
98-06-6
Carbon tetrachloride
NO
ug/l
0.50
11/19/04
14:39
PPM
56-23-5
Chlorobenzene
NO
ug/l
0.50
11/19/04
14:39
PPM
108-90-7
Chloroethane
NO
ug/l
0.50
11/19/04
14:39
PPM
75-00-3
Chloroform
ND
ug/1
0.50
11/19/04
14:39
PPM
67-66-3
Chloromethane
NO
ug/l
2.0
11/19/04
14:39
PPM
74-87-3
Date: 11/23/04
Page: 4 of 37
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full, Charlotte Certification IDs
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc. NC Wastewater 12
NC Drinking Water 37712 N ACC., NC Drinking Water 37706
SC Environmental 99030 W %.� F Sc 99006

Pace Analytical Services, Inc.
2225 Riverside Drive
Analytical0 Asheville, NC 28804
Phone: [phone]
www. pacelabs. com - Fax: [phone]
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
Lab Sample No: 924948904 Project Sample Number: 9281068-002 Date Collected: 11/09/04 10:00
Client Sample ID: MW-2 Matrix: Water Date Received: 11/09/04 13:38
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
2-Chlorotoluene
ND
ug/l
0.50
11/19/04
14:39
PPM
95-49-8
4-Chlorotoluene
ND
ug/l
0.50
11/19/04
14:39
PPM
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/l
2.0
11/19/04
14:39
PPM
96-12-8
Dibromochloromethane
ND
ug/l
0.50
11/19/04
14:39
PPM
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/l
0.50
11/19/04
14:39
PPM
106-93-4
Dibromomethane
ND
ug/l
0.50
11/19/04
14:39
PPM
74-95-3
1,2-Dichlorobenzene
ND
ug/l
1.0
11/19/04
14:39
PPM
95-50-1
1,3-Dichlorobenzene
ND
ug/l
1.0
11/19/04
14:39
PPM
541-73-1
1,4-Dichlorobenzene
ND
ug/l
1.0
11/19/04
14:39
PPM
106-46-7
Dichlorodifluoromethane
ND
ug/l
0.50
11/19/04
14:39
PPM
75-71-8
1,1-Dichloroethane
ND
ug/l
0.50
11/19/04
14:39
PPM
75-34-3
1,2-Dichloroethane
ND
ug/l
0.50
11/19/04
14:39
PPM
107-06-2
1,1-Dichloroethene
ND
ug/l
0.50
11/19/04
14:39
PPM
75-35-4
cis-1,2-Dichloroethene
ND
ug/l
0.50
11/19/04
14:39
PPM
156-59-2
trans-1,2-Dichloroethene
ND
ug/l
0.50
11/19/04
14:39
PPM
156-60-5
1,2-Dichloropropane
ND
ug/l
0.50
11/19/04
14:39
PPM
78-87-5
1,3-Dichloropropane
ND
ug/l
0.50
11/19/04
14:39
PPM
142-28-9
2,2-Dichloropropane
ND
ug/l
0.50
11/19/04
14:39
PPM
594-20-7
1,1-Dichloropropene
ND
ug/l
0.50
11/19/04
14:39
PPM
563-58-6
cis-1,3-Dichloropropene
ND
ug/l
0.50
11/19/04
14:39
PPM
10061-01-5
trans-1,3-Dichloropropene
ND
ug/l
0.50
11/19/04
14:39
PPM
10061-02-6
Diisopropyl ether
ND
ug/l
0.50
11/19/04
14:39
PPM
108-20-3
Ethylbenzene
ND
ug/l
0.50
11/19/04
14:39
PPM
100-41-4
Hexachloro-1,3-butadiene
ND
ug/l
2.0
11/19/04
14:39
PPM
87-68-3
Isopropylbenzene (Cumene)
ND
ug/l
0.50
11/19/04
14:39
PPM
98-82-8
p-Isopropyltoluene
ND
ug/l
1.0
11/19/04
14:39
PPM
99-87-6
Methylene chloride
ND
ug/l
2.0
11/19/04
14:39
PPM
75-09-2
Methyl-tert-butyl ether
ND
ug/l
0.50
11/19/04
14:39
PPM
1634-04-4
Naphthalene
ND
ug/l
2.0
11/19/04
14:39
PPM
91-20-3
n-Propylbenzene
ND
ug/l
0.50
11/19/04
14:39
PPM
103-65-1
Styrene
ND
ug/l
0.50
11/19/04
14:39
PPM
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/l
0.50
11/19/04
14:39
PPM
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/l
0.50
11/19/04
14:39
PPM
79-34-5
Tetrachloroethene
ND
ug/l
0.50
11/19/04
14:39
PPM
127-18-4
Toluene
ND
ug/l
0.50
11/19/04
14:39
PPM
108-88-3
1,2,3-Trichlorobenzene
ND
ug/l
2.0
11/19/04
14:39
PPM
87-61-6
1,2,4-Trichlorobenzene
ND
ug/l
2.0
11/19/04
14:39
PPM
120-82-1
1,1,1-Trichloroethane
ND
ug/l
0.50
11/19/04
14:39
PPM
71-55-6
1,1,2-Trichloroethane
ND
ug/l
0.50
11/19/04
14:39
PPM
79-00-5
Date: 11/23/04
Page: 5 of 37
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full, Charlotte Certification IDs
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc. NC Wastewater 12
NC Drinking Water 37712 ,A ACc,, NC Drinking Water 37706
SC Environmental 99030 Sc 99006

m02--1 ace Analytical °
www.pacelabs.com
Lab Sample No: 924948904
Client Sample ID: MW-2
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax., 828.252.4618
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
Project Sample Number: 9281068-002 Date Collected: 11/09/04 10:00
Matrix: Water Date Received: 11/09/04 13:38
Parameters
Results
Units
Report Limit
Analyzed
By
CAS No. Qual RegLmt
Trichloroethene
ND
ug/l
0.50
11/19/04
14:39
PPM
79-01-6
Trichlorofluoromethane
ND
ug/l
0.50
11/19/04
14:39
PPM
75-69-4
1,2,3-Trichloropropane
ND
ug/l
0.50
11/19/04
14:39
PPM
96-18-4
1,2,4-Trimethylbenzene
ND
ug/l
0.50
11/19/04
14:39
PPM
95-63-6
1,3,5-Trimethylbenzene
ND
ug/l
0.50
11/19/04
14:39
PPM
108-67-8
Vinyl chloride
ND
ug/l
0.50
11/19/04
14:39
PPM
75-01-4
m&p-Xylene
ND
ug/l
0.50
11/19/04
14:39
PPM
o-Xylene
ND
ug/l
0.50
11/19/04
14:39
PPM
95-47-6
1-Chloro-3-fluorobenzene (S)
96
i
11/19/04
14:39
PPM
625-98-9
Date: 11/23/04
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full,
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc.
NC Drinking Water 37712 ACC,,,,
a
SC Environmental 99030 of°�
�:hn nn,f
Page: 6 of 37
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006

d
aceAnalytical °
www.pacelabs.com
QC Batch: 115152
QC Batch Method: SM 6230D
Associated Lab Samples: 924948896
924948946
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax. [phone]
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
Analysis Method: SM 6230D
Analysis Description: GC VOCs in Water
924948904 924948912 924948920 924948938
METHOD BLANK: 924988975
Associated Lab Samples: 924948896 924948904 924948912 924948920 924948938 924948946
Blank Reporting
Parameter Units Result Limit Footnotes
Benzene
ug/l
ND
0.50
Bromobenzene
ug/l
NO
0.50
Bromochloromethane
ug/l
ND
0.50
Bromodichloromethane
ug/l
ND
0.50
Bromoform
ug/l
ND
0.50
Bromomethane
ug/l
1.3
0.50
n-Butylbenzene
ug/l
NO
1.0
sec-Butylbenzene
ug/l
NO
0.50
tert-Butylbenzene
ug/l
NO
0.50
Carbon tetrachloride
ug/1
NO
0.50
Chlorobenzene
ug/l
NO
0.50
Chloroethane
ug/l
NO
0.50
Chloroform
ug/l
NO
0.50
Chloromethane
ug/l
NO
2.0
2-Chlorotoluene
ug/l
NO
0.50
4-Chlorotoluene
ug/l
NO
0.50
1,2-Dibromo-3-chloropropane
ug/l
NO
2.0
Dibromochloromethane
ug/l
NO
0.50
1,2-Dibromoethane (EDB)
ug/l
ND
0.50
Dibromomethane
ug/l
ND
0.50
1,2-Dichlorobenzene
ug/l
ND
1.0
1,3-Dichlorobenzene
ug/l
ND
1.0
1,4-Dichlorobenzene
ug/l
ND
1.0
Dichlorodifluoromethane
ug/l
ND
0.50
1,1-Dichloroethane
ug/l
NO
0.50
1,2-Dichloroethane
ug/l
NO
0.50
1,1-Dichloroethene
ug/l
NO
0.50
cis-1,2-Dichloroethene
ug/l
NO
0.50
trans-1,2-Dichloroethene
ug/l
NO
0.50
1,2-Dichloropropane
ug/l
ND
0.50
Date: 11/23/04
Page: 20 of 37
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full, Charlotte Certification IN
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc. NC Wastewater 12
NC Drinking Water 37712 %o ^CCoR NC Drinking Water 37706
SC Environmental 99030 W �" Sc 99006

aceAnalytical °
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
METHOD BLANK: 924988975
Associated Lab Samples: 924948896 924948904 924948912 924948920 924948938 924948946
Blank
Reporting
Parameter
Units
Result
Limit Footnotes
1,3-Dichloropropane
ug/l
NO
0.50
2,2-Dichloropropane
ug/l
NO
0.50
1,1-Dichloropropene
ug/l
NO
0.50
cis-1,3-Dichloropropene
ug/l
ND
0.50
trans-1,3-Dichloropropene
ug/l
ND
0.50
Diisopropyl ether
ug/l
ND
0.50
Ethylbenzene
ug/l
ND
0.50
Hexachloro-1,3-butadiene
ug/l
ND
2.0
Isopropylbenzene (Cumene)
ug/l
NO
0.50
p-Isopropyltoluene
ug/l
ND
1.0
Methylene chloride
ug/l
16.
2.0 1
Methyl-tert-butyl ether
ug/l
NO
0.50
Naphthalene
ug/l
NO
2.0
n-Propylbenzene
ug/l
NO
0.50
Styrene
ug/l
NO
0.50
1,1,1,2-Tetrachloroethane
ug/l
ND
0.50
1,1,2,2-Tetrachloroethane
ug/l
NO
0.50
Tetrachloroethene
ug/l
NO
0.50
Toluene
ug/l
NO
0.50
1,2,3-Trichlorobenzene
ug/l
NO
2.0
1,2,4-Trichlorobenzene
ug/l
NO
2.0
1,1,1-Trichloroethane
ug/l
NO
0.50
1,1,2-Trichloroethane
ug/1
NO
0.50
Trichloroethene
ug/l
NO
0.50
Trichlorofluoromethane
ug/l
NO
0.50
1,2,3-Trichloropropane
ug/l
ND
0.50
1,2,4-Trimethylbenzene
ug/l
ND
0.50
1,3,5-Trimethylbenzene
ug/l
NO
0.50
Vinyl chloride
ug/l
NO
0.50
m&p-Xylene
ug/l
NO
0.50
o-Xylene
ug/l
ND
0.50
1-Chloro-3-fluorobenzene (S)
%
104
Date: 11/23/04
Page: 21 of 37
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full, Charlotte Certification IDs
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc. NC Wastewater 12
NC Drinking Water 37712 N a��oRo NC Drinking Water 37706
SC Environmental 99030 Sc 99006

aceAnalytical °
www.pacelabs.com
LABORATORY CONTROL SAMPLE: 924988983
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
Spike
LCS
LCS
Parameter
Units
Conc.
Result
% Rec Footnotes
Benzene
ug/l
20.00
20.59
103
Bromobenzene
ug/l
20.00
19.15
96
Bromochloromethane
ug/l
20.00
21.37
107
Bromodichloromethane
ug/l
20.00
19.86
99
Bromoform
ug/l
20.00
19.29
96
Bromomethane
ug/l
20.00
12.42
62
n-Butylbenzene
ug/l
20.00
19.02
95
sec-Butylbenzene
ug/l
20.00
18.77
94
tert-Butylbenzene
ug/l
20.00
18.62
93
Carbon tetrachloride
ug/l
20.00
21.60
108
Chlorobenzene
ug/l
20.00
21.04
105
Chloroethane
ug/l
20.00
20.03
100
Chloroform
ug/l
20.00
21.55
108
Chloromethane
ug/l
20.00
17.36
87
2-Chlorotoluene
ug/l
20.00
20.73
104
4-Chlorotoluene
ug/l
20.00
20.54
103
1,2-Dibromo-3-chloropropane
ug/l
20.00
18.64
93
Dibromochloromethane
ug/l
20.00
18.29
92
1,2-Dibromoethane (EDB)
ug/l
20.00
19.09
95
Dibromomethane
ug/l
20.00
19.28
96
1,2-Dichlorobenzene
ug/l
20.00
20.76
104
1,3-Dichlorobenzene
ug/l
20.00
19.63
98
1,4-Dichlorobenzene
ug/l
20.00
21.41
107
Dichlorodifluoromethane
ug/l
20.00
15.93
80
1,1-Dichloroethane
ug/l
20.00
21.93
110
1,2-Dichloroethane
ug/l
20.00
21.65
108
1,1-Dichloroethene
ug/l
20.00
20.98
105
cis-1,2-Dichloroethene
ug/l
20.00
20.68
103
trans-1,2-Dichloroethene
ug/l
20.00
19.84
99
1,2-Dichloropropane
ug/l
20.00
20.53
103
1,3-Dichloropropane
ug/l
20.00
20.69
103
2,2-Dichloropropane
ug/l
20.00
21.41
107
1,1-Dichloropropene
ug/l
20.00
22.28
111
cis-1,3-Dichloropropene
ug/l
20.00
18.96
95
trans-1,3-Dichloropropene
ug/l
20.00
18.99
95
Diisopropyl ether
ug/l
20.00
19.41
97
Ethylbenzene
ug/l
20.00
19.86
99
Date: 11/23/04
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full,
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc.
NC Drinking Water 37712 K
O N�
SC Environmental 99030
Page: 22 of 37
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
SC _ _ 99006

aceAnalytical °
www.pacelabs.com
LABORATORY CONTROL SAMPLE: 924988983
QUALITY CONTROL DATA
Spike
LCS
LCS
Parameter
Units
Conc.
Result
i Rec
Hexachloro-1.3-butadiene
ug/l
20.00
17.40
87
Isopropylbenzene (Cumene)
ug/l
20.00
20.31
102
p-Isopropyltoluene
ug/1
20.00
18.30
92
Methylene chloride
ug/l
20.00
19.08
95
Methyl-tert-butyl ether
ug/l
20.00
19.47
97
Naphthalene
ug/l
20.00
17.67
88
n-Propylbenzene
ug/l
20.00
18.82
94
Styrene
ug/l
20.00
18.73
94
1,1,1,2-Tetrachloroethane
ug/1
20.00
19.42
97
1,1,2,2-Tetrachloroethane
ug/l
20.00
19.03
95
Tetrachloroethene
ug/l
20.00
19.93
100
Toluene
ug/l
20.00
19.20
96
1,2,3-Trichlorobenzene
ug/l
20.00
19.25
96
1,2,4-Trichlorobenzene
ug/l
20.00
17.35
87
1,1,1-Trichloroethane
ug/l
20.00
22.47
112
1,1,2-Trichloroethane
ug/l
20.00
19.73
99
Trichloroethene
ug/l
20.00
20.87
104
Trichlorofluoromethane
ug/l
20.00
17.54
88
1,2,3-Trichloropropane
ug/l
20.00
21.66
108
1,2,4-Trimethylbenzene
ug/l
20.00
19.15
96
1,3,5-Trimethylbenzene
ug/l
20.00
19.26
96
Vinyl chloride
ug/1
20.00
18.17
91
m&p-Xylene
ug/l
40.00
42.09
105
o-Xylene
ug/l
20.00
19.97
100
1-Chloro-3-fluorobenzene (S)
105
SAMPLE DUPLICATE: 924989007
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
Footnotes
924948599
DUP
Parameter
Units
Result
Result
RPD Footnotes
Benzene
ug/l
NO
ND
NC
Bromobenzene
ug/l
NO
NO
NC
Bromochloromethane
ug/l
ND
NO
NC
Bromodichloromethane
ug/l
NO
NO
NC
Bromoform
ug/l
NO
NO
NC
Bromomethane
ug/l
NO
NO
NC
Date: 11/23/04
Page: 23 of 37
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full, Charlotte Certification IDs
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc. NC Wastewater 12
NC Drinking Water 37712 N ACCg'9 NC Drinking Water 37706
SC Environmental 99030 Wi_�`) TT \� Sc 99006

4 .
ace Analytical °
www.pacelabs.com
SAMPLE DUPLICATE: 924989007
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
924948599
DUP
Parameter
Units
Result
Result
RPD
n-Butylbenzene
ug/l
ND
ND
NC
sec-Butylbenzene
ug/l
ND
ND
NC
tert-Butylbenzene
ug/l
ND
ND
NC
Carbon tetrachloride
ug/l
ND
ND
NC
Chlorobenzene
ug/l
ND
ND
NC
Chloroethane
ug/l
ND
ND
NC
Chloroform
ug/l
ND
ND
NC
Chloromethane
ug/l
ND
ND
NC
2-Chlorotoluene
ug/l
ND
ND
NC
4-Chlorotoluene
ug/l
ND
ND
NC
1,2-Dibromo-3-chloropropane
ug/l
ND
ND
NC
Dibromochloromethane
ug/l
ND
ND
NC
1,2-Dibromoethane (EDB)
ug/l
ND
ND
NC
Dibromomethane
ug/l
ND
ND
NC
1,2-Dichlorobenzene
ug/l
ND
ND
NC
1,3-Dichlorobenzene
ug/l
ND
ND
NC
1,4-Dichlorobenzene
ug/l
ND
ND
NC
Dichlorodifluoromethane
ug/l
ND
ND
NC
1,1-Dichloroethane
ug/l
ND
ND
NC
1,2-Dichloroethane
ug/l
ND
ND
NC
1,1-Dichloroethene
ug/l
ND
ND
NC
cis-1,2-Dichloroethene
ug/l
ND
ND
NC
trans-1,2-Dichloroethene
ug/l
ND
ND
NC
1,2-Dichloropropane
ug/l
ND
ND
NC
1,3-Dichloropropane
ug/l
ND
ND
NC
2,2-Dichloropropane
ug/l
ND
ND
NC
1,1-Dichloropropene
ug/l
ND
ND
NC
cis-1,3-Dichloropropene
ug/l
ND
ND
NC
trans-1,3-Dichloropropene
ug/l
ND
ND
NC
Diisopropyl ether
ug/l
ND
ND
NC
Ethylbenzene
ug/l
ND
ND
NC
Hexachloro-1,3-butadiene
ug/l
ND
ND
NC
Isopropylbenzene (Cumene)
ug/l
ND
ND
NC
p-Isopropyltoluene
ug/l
ND
ND
NC
Methylene chloride
ug/l
ND
ND
NC
Methyl-tert-butyl ether
ug/l
ND
ND
NC
Naphthalene
ug/l
ND
ND
NC
Date: 11/23/04
Footnotes
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full,
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc.
NC Drinking Water 37712 %' HC 0-9,
SC Environmental 99030 �/��•\`�
Page: 24 of 37
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
1. .r ^^ '

Analytical °
www.pacelabs.com QUALITY CONTROL DATA
SAMPLE DUPLICATE: 924989007
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax. [phone]
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
924948599
DUP
Parameter
Units
Result
Result
RPD
n-Propylbenzene
ug/l
ND
ND
NC
Styrene
ug/l
ND
ND
NC
1,1,1,2-Tetrachloroethane
ug/l
ND
ND
NC
1,1,2,2-Tetrachloroethane
ug/l
ND
ND
NC
Tetrachloroethene
ug/l
ND
ND
NC
Toluene
ug/l
ND
ND
NC
1,2,3-Trichlorobenzene
ug/l
ND
ND
NC
1,2,4-Trichlorobenzene
ug/l
ND
ND
NC
1,1,1-Trichloroethane
ug/l
ND
ND
NC
1,1,2-Trichloroethane
ug/l
ND
ND
NC
Trichloroethene
ug/l
ND
ND
NC
Trichlorofluoromethane
ug/l
ND
ND
NC
1,2,3-Trichloropropane
ug/l
ND
ND
NC
1,2,4-Trimethylbenzene
ug/l
ND
ND
NC
1,3,5-Trimethylbenzene
ug/l
ND
ND
NC
Vinyl chloride
ug/l
ND
ND
NC
m&p-Xylene
ug/l
ND
ND
NC
o-Xylene
ug/l
ND
ND
NC
1-Chloro-3-fluorobenzene (S)
Y.
106
99
SAMPLE DUPLICATE: 924993298
Parameter
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Date: 11/23/04
Asheville Certification IDs
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
Footnotes
924970692 DUP
Units
Result Result RPD Footnotes
ug/l
ND ND NC
ug/l
ND ND NC
ug/l
ND ND NC
ug/l
ND ND NC
ug/l
ND ND NC
ug/l
ND ND NC
ug/l
ND ND NC
ug/l
ND ND NC
ug/l
ND ND NC
ug/l
ND ND NC
ug/l
ND ND NC
ug/l
ND ND NC
Page: 25 of 37
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Charlotte Certification IN
without
the.written consent of Pace Analytical Services, Inc.
NC Wastewater 12
A��oRo
NC Drinking Water 37706
Sc 99006
:ram Oft

r'
aceAnalytical°
www.pacelabs.com
SAMPLE DUPLICATE: 924993298
Parameter
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Date: 11/23/04
Units
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
QUALITY CONTROL DATA
924970692
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DUP
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
RPD
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
Footnotes
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full,
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc.
NC Drinking Water 37712 k ACCOR
SC Environmental 99030ON
Page: 26 of 37
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006^

Analytical °
www.pacelabs.com QUALITY CONTROL DATA
SAMPLE DUPLICATE: 924993298
Parameter
Units
1,2,3-Trichlorobenzene
ug/l
1,2,4-Trichlorobenzene
ug/l
1,1,1-Trichloroethane
ug/l
1,1,2-Trichloroethane
ug/l
Trichloroethene
ug/1
Trichlorofluoromethane
ug/l
1,2,3-Trichloropropane
ug/l
1,2,4-Trimethylbenzene
ug/l
1,3,5-Trimethylbenzene
ug/l
Vinyl chloride
ug/l
m&p-Xylene
ug/l
o-Xylene
ug/l
1-Chloro-3-fluorobenzene (S) i
Date: 11/23/04
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
924970692
DUP
Result
Result
RPD
ND
ND
NC
ND
ND
NC
ND
ND
NC
ND
ND
NC
ND
ND
NC
ND
ND
NC
ND
ND
NC
ND
ND
NC
ND
ND
NC
ND
ND
NC
ND
ND
NC
ND
ND
NC
101
98
Footnotes
Page: 27 of 37
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full, Charlotte Certification IDs
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc. NC Wastewater 12
NC Drinking Water 37712 N A��oRo NC Drinking Water 37706
SC Environmental 99030 W r�'jon•�� Sc 99006

aceAnalytical °
www.pacelahs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax.[phone]
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
QC Batch: 115135 Analysis Method: SM 9223
QC Batch Method: Standard Methods Analysis Description: Fecal Coliform MPN Water
Associated Lab Samples: 924948896 924948904 924948912 924948920 924948938
924948946
METHOD BLANK: 924987506
Associated Lab Samples: 924948896 924948904 924948912 924948920 924948938 924948946
Blank Reporting
Parameter Units Result Limit Footnotes
Coliform, Fecal <1.1
Date: 11/23/04
Page: 28 of 37
REPORT OF LABORATORY ANALYSIS
Asheville Certification IN This report shall not be reproduced; except in full, Charlotte Certification IN
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc. NC Wastewater 12
NC Drinking Water 37712 o 1 ACC,., NC Drinking Water 37706
SC Environmental 99030 Sc 99006

:Analytical °
www.pacelabs.com QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax, 828.252.4618
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
QC Batch: 114783 Analysis Method: EPA 160.1
QC Batch Method: EPA 160.1 Analysis Description: Total Dissolved Solids
Associated Lab Samples: 924948896 924948904 924948912 924948920 924948938
924948946
METHOD BLANK: 924970163
Associated Lab Samples: 924948896 924948904 924948912 924948920 924948938 924948946
Blank Reporting
Parameter Units Result Limit Footnotes
Total Dissolved Solids mg/l ND 20.
LABORATORY CONTROL SAMPLE: 924970171
Spike LCS LCS
Parameter Units Conc. Result % Rec Footnotes
Total Dissolved Solids mg/l 250.00 248.0 99
SAMPLE DUPLICATE: 924970189
924948649 DUP
Parameter Units Result Result RPD Footnotes
Total Dissolved Solids mg/l 50.00 54.00 8
Date: 11/23/04 Page: 29 of 37
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full, Charlotte Certification IDs
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc. NC Wastewater 12
NC Drinking Water 37712 H AC10RO NC Drinking Water 37706
SC Environmental Sc 99006
99030 W ��_�?•)�.

ace Analytical °
www.pacelabs.com QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone. [phone]
Fax: [phone]
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
QC Batch: 114448 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 48 Hour NO3 / NO2 / NOX
Associated Lab Samples: 924948896 924948904 924948912 924948920 924948938
924948946
METHOD BLANK: 924952096
Associated Lab Samples: 924948896 924948904 924948912 924948920 924948938 924948946
Blank Reporting
Parameter Units Result Limit Footnotes
Nitrate as N mg/l NO 0.10
LABORATORY CONTROL SAMPLE: 924952104
Spike LCS LCS
Parameter Units Conc. Result Y. Rec Footnotes
Nitrate as N mg/l 5.000 5.030 101
MATRIX SPIKE: 924952112
924948698 Spike MS MS
Parameter Units Result Conc. Result % Rec Footnotes
Nitrate as N mg/l 3.570 5.000 8.630 101
SAMPLE DUPLICATE: 924952120
924948789 DUP
Parameter Units Result Result RPD Footnotes
Nitrate as N mg/l NO NO NC
Date: 11/23/04 Page: 30 of 37
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full, Charlotte Certification IDs
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc. NC Wastewater 12
NC Drinking Water 37712 NC Drinking Water 37706
Sr Frniimnmontni o4ngn o``,/ a \F Sc 99006

Analytical °
www.pacelabs.com QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
QC Batch: 114486 Analysis Method: SM 5310B
QC Batch Method: SM 5310B Analysis Description: Total Organic Carbon
Associated Lab Samples: .924948896
METHOD BLANK: 924953631
Associated Lab Samples: 924948896
Blank Reporting
Parameter Units Result Limit Footnotes
Total Organic Carbon mg/l ND 0.50
LABORATORY CONTROL SAMPLE: 924953649
Spike LCS LCS
Parameter Units Conc. Result i Rec Footnotes
Total Organic Carbon mg/l 10.00 9.690 97
MATRIX SPIKE: 924953656
924947377 Spike MS MS
Parameter Units Result Conc. Result % Rec Footnotes
Total Organic Carbon mg/l 792.8 100.00 175.3 0
SAMPLE DUPLICATE: 924953664
Parameter Units
Total Organic Carbon mg/l
Date: 11/23/04
924947385 DUP
Result Result RPD Footnotes
1100 1100 3
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full,
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc.
NC Drinking Water 37712
SC Environmental 99030
Page: 31 of 37
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
Sc 99006

Analytical °
www.pacelabs.com QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
QC Batch: 114489 Analysis Method: SM 5310B
QC Batch Method: SM 5310B Analysis Description: Total Organic Carbon
Associated Lab Samples: 924948904 924948912 924948920 924948938 924948946
METHOD BLANK: 924953763
Associated Lab Samples: 924948904 924948912 924948920 924948938 924948946
Blank Reporting
Parameter Units Result Limit Footnotes
Total Organic Carbon mg/l NO 0.50
LABORATORY CONTROL SAMPLE: 924953771
Spike LCS LCS
Parameter Units Conc. Result i Rec Footnotes
Total Organic Carbon mg/l 10.00 9.740 97
MATRIX SPIKE: 924953789
924948904 Spike MS MS
Parameter Units Result Conc. Result % Rec Footnotes
Total Organic Carbon mg/l 2.419 10.00 15.28 129 2
SAMPLE DUPLICATE: 924953797
924948912 DUP
Parameter Units Result Result RPD Footnotes
Total Organic Carbon mg/l 3.500 3.600 4
Date: 11/23/04 Page: 32 of 37
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full, Charlotte Certification IDs
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc. NC Wastewater 12
NC Drinking Water 37712 0 ,N 0.CCCq�, NC Drinking Water 37706
SC 99006
SC Environmental 99030

ace Analytical °
www.pacoiabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
QC Batch: 114758 Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1 Analysis Description: Ammonia
Associated Lab Samples: 924948896 924948904 924948912 924948920
METHOD BLANK: 924967094
Associated Lab Samples: 924948896 924948904 924948912 924948920
Blank Reporting
Parameter Units Result Limit Footnotes
Nitrogen, Ammonia mg/l ND 0.10
LABORATORY CONTROL SAMPLE: 924967102
Spike LCS LCS
Parameter Units Conc. Result % Rec Footnotes
Nitrogen, Ammonia mg/l 1.000 0.9330 93
MATRIX SPIKE: 924967110
924943921 Spike MS MS
Parameter Units Result Conc. Result Y. Rec Footnotes
Nitrogen, Ammonia mg/l 10.25 1.000 11.23 98
SAMPLE DUPLICATE: 924967128
924943939 DUP
Parameter Units Result Result RPD Footnotes
Nitrogen, Ammonia mg/l 6.800 6.800 0
Date: 11/23/04 Page: 33 of 37
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full, Charlotte Certification IDs
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc. NC Wastewater 12
NC Drinking Water 37712 NC Drinking Water 37706
Sc99006
SC Environmental 99030

2ceAnalytical@
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax., 828.252.4618
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
QC Batch: 114833 Analysis Method: EPA 325.2
QC Batch Method: EPA 325.2 Analysis Description: Chloride (Mercuric Nitrate)
Associated Lab Samples: 924948896 924948904 924948912 924948920 924948938
924948946
METHOD BLANK: 924972854
Associated Lab Samples: 924948896 924948904 924948912 924948920 924948938 924948946
Blank Reporting
Parameter Units Result Limit Footnotes
Chloride mg/l NO 5.0
LABORATORY CONTROL SAMPLE: 924972862
Parameter Units
Chloride mg/l
MATRIX SPIKE: 924972870
Spike LCS LCS
Conc. Result i Rec Footnotes
20.00 21.19 106
924959935 Spike MS MS
Parameter Units Result Conc. Result % Rec Footnotes
Chloride mg/l 222.9 20.00 203.1 0 2
SAMPLE DUPLICATE: 924972888
Parameter Units
Chloride mg/l
Date: 11/23/04
924955404 DUP
Result Result RPD Footnotes
NO NO NC
Page: 34 of 37
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full, Charlotte Certification IDs
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc. NC Wastewater 12
NC Drinking Water 37712 NC Drinking Water 37706
`�
SC Environmental 99030 W/`} �"a•��� Sc 99006

Pace Analytical Services, Inc.
2225 ,Analytical ° Riverside Drive
Asheville,
� Asheville, NC 28804
www.pacelabs.com QUALITY CONTROL DATA Phone.[phone]
.828.25
Fax: 618
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
QC Batch: 114860
Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1
Analysis
Description: Ammonia
Associated Lab Samples:
924948938
924948946
METHOD BLANK: 924973829
Associated Lab Samples:
924948938
924948946
Blank
Reporting
Parameter
Units
Result
Limit Footnotes
Nitrogen, Ammonia
mg/l
NO
0.10
LABORATORY CONTROL SAMPLE:
924973837
Spike
LCS LCS
Parameter
Units
Conc.
Result Y. Rec Footnotes
Nitrogen, Ammonia
mg/l
1.000
1.035 104
MATRIX SPIKE: 924973845
924948573 Spike MS MS
Parameter Units Result Conc. Result % Rec Footnotes
Nitrogen, Ammonia mg/l 0 1.000 0.8154 82
SAMPLE DUPLICATE: 924973852
Parameter Units
Nitrogen, Ammonia mg/l
Date: 11/23/04
924958275 DUP
Result ' Result RPD Footnotes
NO NO NC
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full,
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc.
NC Drinking Water 37712 0'N ^°co*e
SC Environmental 99030 W'(,,,,,�•„s
Page: 35 of 37
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006_

2ceAnalytical@
www.pacelahs.com
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
QUALITY CONTROL DATA Phone:[phone]
Fax: [phone]
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
QC Batch: 115382
Analysis
Method: EPA 375.4
QC Batch Method: EPA 375.4
Analysis
Description: Sulfate,Turbidimetric
Associated Lab Samples:
924948896
924948904
924948912 924948920 924948938
924948946
METHOD BLANK: 925000572
Associated Lab Samples:
924948896 924948904
924948912 924948920 924948938 924948946
Blank
Reporting
Parameter
Units
Result
Limit Footnotes
Sulfate
mg/l
ND
5.0
LABORATORY CONTROL SAMPLE:
925000580
Spike
LCS LCS
Parameter
Units
Conc.
Result Y. Rec Footnotes
Sulfate
mg/1
20.00
19.33 97
MATRIX SPIKE: 925000598
924961550 Spike MS MS
Parameter Units Result Conc. Result % Rec Footnotes
Sulfate mg/l 0.2890 20.00 20.82 103
SAMPLE DUPLICATE: 925000606
924961568 DUP
Parameter Units Result Result
Sulfate mg/l 16.00 16.00
Date: 11/23/04
RPD Footnotes
1
REPORT OF LABORATORY ANALYSIS
Asheville Certification IN This report shall not be reproduced, except in full,
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc.
NC Drinking Water 37712 w ^CCoRo
SC Environmental 99030
Page: 36 of 37
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Sc 99006

1, ,-FaceAnalytical
Ur1A1N—ur-c;us i tour o Anaiyucai Request u®cument
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must j be completed accurately.
��
OAO
CZJ70 •
www.pacelahs.com
Re uired Client Information: Section B
' f
Required Client Information:
Section. A
Page: Of li
To Be CompletedCompletecr by Pace
Quote Reference:
-
Analytical and Client Section. C
t'
Report
Company
AI
iarl o"
Copy To: I
NJf r-D
Client Information (Check quote/contract):
Address O C
Invoice To: —; /
�>✓ I
Requested
Project Manager:
G J I6
1.
i7 erN
/Cat
PO.
'Turn around time less than 14 days subject to
laboratory and contractual obligations and may result in a
Rush Turnaround Surcharge.
Turn Around Time (TAT) in calendar days.
Project #:
b (p
r
Project Name: `
Profile #:
j
Phone , � 1— 3 3 ��
Fax � �
Q j
Project Number: �i O U ` s
Analysis:
J. m,/
Section D Required Client Information: Valid Matrix Codes O
MATRIX CODE a: Preservatives D
DRINKING WATER OW w l a Z �-
GROUNDWATER GW 0 a.0 O M
S a4 M P L E I D SURFACE WATER SW O H u Fw- U O v
WASTE WATER WW O l w w
! SOIL ODUCT SL ¢ EL COLLECTED d JO ch _ ` �3
I One character per box. OIL oL a a, o �; C\Jo o fit-
11J �A Z, 0-9 ._� WIPE WP u7� START END , Q N o Om = U) N �� v Q' [�
AIR AR C7 a cA O ' a
Sample IDs MUST BE UNIQUE OTHER OT DATE TIME DATE TIME r- _ _ = Z Z O V'
i
2
os■
3
MOM
4
5
MOM
■■@
6
m■®
mm■
n■noo®■n■
■■■■■■■■■■■■t ■■■ .. e11NOM■is■11IN11e■o®v■
REGULATORYSITE LOCATION
7ciNC ElSC ElGA ❑ NPDES ROUND WATER ❑ DRINKING WATER
Other ❑- UST ❑ RCRA ❑ Other
SAMPLE CONDITION SAMPLE NOTES
Temp in °C
2
Received on Icy
\
Y N
Sealed Cooler.
Y
Samples Intact
Additional Comments:
2 )
a
L °I ILI q &
19gl Soy
149 L18� Q
1pg29aCl
133
WUNHi uHt of mr H: DATE Signed: (MM / DD / YY)
11 - 0q - oy
SEE RE ERSE SIDE FOR INSTRUCTIONS Form C0001 Rev. 0304

Pace Analytical Services, Inc.
2225 Riverside Drive
Analytical o Asheville, NC 28804
Phone: [phone]
www.pacelabs.com Fax. [phone]
Lab Project Number: 9281068
Client Project ID: Clement Pappas 2081.01
QUALITY CONTROL DATA PARAMETER FOOTNOTES
Consistent with EPA guidelines, unrounded concentrations are displayed and have been used to calculate Y. Rec and RPD values.
LCS(D) Laboratory Control Sample (Duplicate)
MS(D) Matrix Spike (Duplicate)
DUP Sample Duplicate
ND Not detected at or above adjusted reporting limit
NC Not Calculable
J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
RPD Relative Percent Difference
(S) Surrogate
[1] Common laboratory contaminant.
[2] The spike recovery was outside acceptance limits for the MS and /or MSD due to matrix interference. The LCS
and/or LCSD were within acceptance limits showing that the laboratory is in control and the data is
acceptable.
Date: 11/23/04
Page: 37 of 37
REPORT OF LABORATORY ANALYSIS
Asheville Certification IDs This report shall not be reproduced, except in full, Charlotte Certification IN
NC Wastewater 40 without the written consent of Pace Analytical Services, Inc. NC Wastewater 12
NC Drinking Water 37712 N a'10R NC Drinking Water 37706
SC Environmental 99030 Sc 99006

aRO
GW-59A COMPLIANCE REPORT, FORM Permit # W Q 4001k lest l
(Submit one each monitoringperiod with Gi Z 59 forms.)
1
Enter date monitoring results were due. (la 3\-0 1Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
2
Was any requited information missing on the GW-59 report forms?
YES
NO
IF the answer to question 1 or,2is "YES'; list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? If the answer is "Yes", contact the Regional Officefor guidance.
4
Are any monitored constituents equal to or above the established standards?
YES
NO
If the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below.
1 0Oqlf}`i }r.tl�l�'o�' {%.c•,:L O.G (c p�.Y1r�G''�L
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YE&
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is "NO", skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentrations) reported, and sample collection date for each occurrence (f r the last two ye s).
mIw)-5 j't�C�MW—S'Q44/()S1a2—.
J
i r7 "tI Z�Oi LtA IGPu I:rja%2� O:7I m��jr i5 t!Z IiiClf<G rJC
t �ewic`j �l �rej-r:,chloru�+�,rz.
Z.Zr11
11 r y .� j �l.
@}rAC�.IOr✓C�hGN�'. �.7 t�� Wig' ����1C:�I6C':fivfLzni2:5 ++�r� I—j ricl.ty,^t�.Lil�tuz. 0
may►
fi MAIL
fL
}t�( \�,0� trc� � Q.t�(O M ' L Iris in�Cir9rrtV�B,-Je 0.S % �+�r �G.
/ iriM f 6ilfar;�ie. D.G
J
�{ ih
L.
Are the monitoring wells listed in section 5 located at or beyond the review boundary.
YES
NO
If the answer is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly
-located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
if the answer to question 7 is "YES", describe those actions in the space provided below. u
"NO"
If the answer to question 7 is contact the Regional Office within 90 days; an et aluatiohina{"' a
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation,
fines, and/orpena/ties.vim`!
1-tn1I VC,Qr-', At.
{ i" �lril r %�.?•i`i
iiV:l i,-t"I'iLL
g
The person completing this portion (G W-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the fop of the current GW-59 form.
h„e seby:acknow�ledge�fhat thewabove information was evaluated and the nformat,��n submitted�m this ; .
'report,(Cornplian�e RepotsGW�59A) is t"rue and complete £o the best of myyknowledge ��{e
�.5twe.'&P,-z;rmVittee
(or Authorized Agent) Date
GW-59A 12/8/2003