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HomeMy WebLinkAboutNC0003468_Application_20220330ROY COOPER Governor DIONNE DEW-GATTI Secretory S. DANIEL SMITH Director Duke Energy Carolinas, LLC Attn: Terry Tuck, GM II 864 South Edgewood Road Eden, NC 27288 Subject: Permit Renewal Application No. NC0003468 Dan River Combined Cycle Rockingham County NORTH CAROLINA Environmental Quality June 03, 2021 Dear Applicant: The Water Quality Permitting Section acknowledges the June 3, 2021 receipt of your permit renewal application and supporting documentation. Your application will be assigned to a permit writer within the Section's NPDES WW permitting branch. Per G.S. 150B-3 your current permit does not expire until permit decision on the application is made. Continuation of the current permit is contingent on timely and sufficient application for renewal of the current permit. The permit writer will contact you if additional information is required to complete your permit renewal. Please respond in a timely manner to requests for additional information necessary to allow a complete review of the application and renewal of the permit. Information regarding the status of your renewal application can be found online using the Department of Environmental Quality's Environmental Application Tracker at: https://deq.nc.gov/permits-regulations/permit-guidance/environmental-application-tracker If you have any additional questions about the permit, please contact the primary reviewer of the application using the links available within the Application Tracker. ec: WQPS Laserfiche File w/application Sincerely, Wren Thedfor Administrative Assistant Water Quality Permitting Section North Carolina Department of Environmental Quality Division of Water Resources Winston-Salem Regional Office 1450 West Hanes Mill Road. Suite 300 I Winston-Salem North Carolina 27105 336.776 9800 DUKE ENERGY May 28, 2021 Dr. Sergei Chernikov NC Division of Water Resources 1617 Mail Services Center Raleigh, NC 27699-1617 Subject: Duke Energy Carolinas, LLC Dan River Combined Cycle Station NPDES Permit No. NC0003468 Rockingham County Permit Renewal Application Dear Dr. Chernikov: Dan River Combined Cycle Duke Energy Carolinas 864 South Edgewood Road Eden, NC 27288 RECEIVED SUN 0 3 2021 NCDEQ/DWR/NPDES Duke Energy Carolinas, LLC, (Duke) requests the subject permit be renewed and reissued. The above referenced permit expires on November 30, 2021. As mandated by North Carolina Administrative Code 15A NCAC 2H.0105(e), this permit renewal is being submitted at least 180 days prior to expiration of the current permit. Please find enclosed in triplicate, the renewal application, which includes the following items: • EPA Form 1 • EPA Form 2C • Site Map showing the location of all outfalls (internal and final) • Waste flow chart and description of waste flows through facility • Narrative description of sources of pollution and treatment technologies • List of Potential items not covered by analysis • 316(a) CORMIX Thermal Mixing Zone Study • 316(b) Report • Fish Tissue Sampling With reissuance, Duke requests the following modifications. Condition A (1) Outfall 001- 1. Removal of once -through cooling water and treated domestic wastewater from the description of authorized discharges. 2. Removal of condition that states "All domestic wastewater produced at the power plant is to be fully treated through the onsite wastewater treatment system prior to being discharged" statement. Domestic wastewater is no longer discharged and is now handled through an on - site septic system permitted through Rockingham County, 4. Duke is requesting the re-insertion of a footnote associated with TSS limit. Previous NPDES permits contained a condition that allows for the monthly average to be 49 mg/L if it is demonstrated that the concentrate above 30 mg/L was due to the concentration of total suspended solids in the intake water. Duke requests this condition be re-inserted into the renewed permit. 5. Removal of mercury monitoring requirement. Mercury monitoring requirement was added to Outfall 001 in 2016 and was based upon one sampling result. The analytical result for Hg was incorrectly entered on EPA Form 2C submitted with the 2016 permit renewal request as 478 ug/L. The actual analytical result for this sampling event was 0.00478 ug/L or 4.86 ng/L. A sample was collected on 1/27/21 for this permit renewal request. The analytical result for this sampling event is 4.30 ng/L. The average mercury concentration for the permit term is 6.47 ng/L with a maximum concentration of 9.6 ng/L. Both the analytical results collected for the Form 2C permit renewal applications and the quarterly average are below the TBEL. Duke requests removal of the monitoring requirement for total mercury. 6. Removal of iron monitoring requirement. Historical data demonstrates that the iron levels are influenced by the level of iron concentration in the upstream intake water from the Dan River. Duke requests removal of the monitoring requirement for total iron. 7. Footnote 3 and the associated temperature parameter are remnants from the coal-fired steam station, now demolished. Duke requests that the terms found in footnote 3 be removed from the permit as they are not applicable and replaced with thermal mixing zone. Basis of Request — Footnote 3 originates from the EPA nomograph from 1976 as the basis for the restrictions to protect aquatic life from cold shock due to the thermal Toad from the retired Dan River Fossil Steam Station. This was first approved by North Carolina DENR in 1993. Additional delta T thermal limits, as noted in Footnote 3, are based upon EPA nomograph (USEPA 1976) and intended to protect warm water fish from cold shock in the event of a winter season plant shut -down event. Historically, fossil steam stations could operate units separately, thus varying discharge flow and heat Toad to the receiving stream. If all units functioned either on one control unit or as autonomous units, this configuration could have impacts on the receiving stream if all units were shutdown at once versus scaled over time. Basically, if all steam units were online, withdrawing water, heating it, and then discharging the heated effluent, losing all units at once would cause a shock to the receiving stream and the aquatic life surrounding the discharge point. The thermal rise calculation paired with the control unit designation seeds to regulate the potential thermal shock of losing one or multiple operating units. Combined cycle plants discharge significantly less heated effluent, i.e. approximately 0.6 MGD compared to 170+ MGD, than the demolished steam station, and have cooling towers that help regulate the effluent discharge temperature. 8. Removal of pH limit and monitoring from internal outfall OO1A as done in previous Duke Energy permits. Outfall 001A is an internal outfall that discharges to the cooling tower and mixes with approximately 0.6 MGD of cooling water and should be considered a contributing flow to outfall 001. Duke requests the removal of the pH monitoring requirement for this internal outfall due to the pH limit of 6.0 to 9.0 at the point of discharge/end of pipe at outfall 001 which provides protection of water quality. 9. Remove permit conditions no longer applicable. The excavation of the ash ponds was completed in accordance with the North Carolina Coal Ash Management Act (CAMA) of 2014, HB 630 of 2016, and the Senate Bill 716; Mountain Energy Act of 2015. Both dams have been razed and remaining remnants are of low hazard reclaimed status and exempt from the Dam Safety Law of 1967. Duke requests removal of the following conditions associated with operation of the former ash ponds. 1. Conditions A (3) and A (4) — Monitoring Requirements for Outfall 002 2. Conditions A (5), A (6), and A (7) — Constructed Seeps - Outfalls 102, 103, and 104. Discharge from the seeps ceased in May 2019 3. Condition A (10) — Chronic Toxicity Limit for Outfall 002 4. Condition A (14) — Structural Integrity Inspections of the Ash Pond Dam 5. Condition A (15) — Instream Monitoring 6. Condition A (16) — Applicable State Law - Senate Bill 729 7. Condition A (19) — Discharge From Seepage 8. Condition A (20) — Fish Tissue Monitoring Near Ash Pond Discharge (Outfall 002) 10. Include new Thermal mixing zone and remove 316 (a) variance. Condition A (12) -Thermal Mixing Variance — Duke Energy contracted with Water Environmental Consultants to model the discharge from the Outfall 001. The model used multiple conservative values and shows that the wastewater from Outfall 001 will readily mix with the receiving water. Based on the model results, Duke requests that Outfall 001 be limited to a daily maximum limit of 99°F and a thermal mixing zone in accordance with the modeled area of the enclosed thermal mixing zone report be included in the renewed permit. The model indicates that the 99°F discharge will mix with the river, and the instream water quality standard of 84.2°F will be met 134 feet downstream of Outfall 001. 11. Condition A (13) — The 316 (b) compliance report is included with this application. 12. Condition A (17) — The domestic sewage package plant was removed from service and replaced with a septic system with drain field. Duke requests removal of this condition. Duke Energy requests notification that this application is complete. Should you have any questions regarding this submittal or require additional information, please contact Joyce Dishmon at 336-623-0238 or email Joyce.Dishmon@duke-energy.com. I certify under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations Sincerely, Terry Tuck GM II — Regulated Stations Dan River Combined Cycle Attachments Cc: Lon Snider — WSRO, 450 West Hanes Mill Road, Suite 300, Winston-Salem, NC 27105 Joyce Dishmon/Filenet - via email Wiliam Milam — via email Shannon Langley — via email EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Form Approved 03/05/19 OMB No. 2040-0004 Form 1 NPDES VT0EPA U.S. Environmental Protection Agency Application for NPDES Permit to Discharge Wastewater GENERAL INFORMATION SECTION 1. ACTIVITIES REQUIRING AN NPDES PERMIT (40 CFR 122.21(f) and (f)(1)) Required to Submit Form 1 cn Name, Mailing Address, and Location o Activities Requiring an NPDES Permit 0 1.1 Applicants Not 1.1.1 Is the facility a new or existing publicly treatment works? If yes, STOP. Do NOT complete Form 1. Complete Form 2A. owned 1 1 2 Is the facility a new treating domestic If yes, STOP. Do NOT complete Form 1. Form 2S. or existing treatment works sewage? ✓ No ✓ No Complete 1.2 Applicants Required to Submit Form 1 1.2.1 Is the facility a concentrated animal operation or a concentrated aquatic production facility? Yes 4 Complete Form 1 and Form 2B. feeding animal 1.2.2 Is the facility an commercial, mining, currently discharging existing manufacturing, or silvicultural facility that is process wastewater? Form ❑ No and Form 2C. i No i Yes 4 Complete 1 1.2.3 Is the facility a new manufacturing, commercial, mining, or silvicultural facility that has commenced to discharge? Yes 4 Complete Form 1 and Form 2D. not yet 1.2.4 Is the facility a new commercial, mining, discharges only nonprocess ❑ Yes 4 Complete 1 and or existing manufacturing, or silvicultural facility that wastewater? i No Form i No Form 2E. 1.2.5 Is the facility a new or existing facility discharge is composed entirely of stormwater associated with industrial activity discharge is composed of both stormwater non-stormwater? Yes 4 Complete Form 1 and Form 2F unless exempted by 40 CFR 122.26(b)(14)(x) or b 15 . whose or whose and i No 2. NAME, 2.1 MAILING ADDRESS, AND LOCATION (40 CFR 122.21(f)(2)) Facility Name Dan River Combined Cycle Station 2.2 EPA Identification Number NCD024665535 2.3 Facility Contact Name (first and last) Terry Tuck Title GM II -Regulated Stations Phone number (336) 635-3080 Email address Terry.Tuck@duke-energy.com 2.4 Facility Mailing Address Street or P.O. box 864 South Edgewood Road City or town Eden State NC ZIP code 27288 EPA Form 3510-1 (revised 3-19) Page 1 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle isOMB Form Approved 03/05/19 No. 2040-0004 KName, Mailing Address, —+ and Location Continued 0 2.5 Facility Location Street, route number, or other specific identifier 864 South Edgewood Road County name Rockingahm County code (if known) 079 City or town Eden State NC ZIP code 27288 3. SIC AND NAICS CODES (40 CFR 122.21(f)(3)) Operator Information SIC and NAICS Codes 3.1 SIC Code(s) Description (optional) 4911 Electric Services 3.2 NAICS Code(s) Description (optional) 221112 Fossil Fuel Electric Power Generation 4. OPERATOR 4.1 INFORMATION (40 CFR 122.21(f)(4)) Name of Operator Duke Energy Carolinas, LLC Is the ✓ name you listed in Item 4.1 also the owner? Yes ❑ No 4.2 4.3 Operator Status ❑ Public —federal ❑ Public —state ❑ Other public (specify) 0 Private • Other (specify) Phone Number of Operator 4.4 (336) 635-3080 Indian m Operator Information Land -I Continued 0 4.5 Operator Address Street or P.O. Box 864 South Edgewood Road City or town Eden State NC ZIP code 27288 Email address of operator Terry.Tuck@duke-energy.com 5. INDIAN LAND (40 CFR 122.21(f)(5)) 5.1 Is the facility ❑ Yes located on Indian Land? ✓ No EPA Form 3510-1 (revised 3-19) Page 2 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Form Approved 03/05/19 OMB No. 2040-0004 SECTION 6. EXISTING ENVIRONMENTAL PERMITS (40 CFR 122.21(f)(6)) d E 0 wa c c w 6.1 Existing Environmental Permits (check all that apply and print or type the corresponding permit number for each) NPDES (discharges to surface water) NC0003468 ❑ RCRA (hazardous wastes) NCD024668535 ❑ UIC (underground injection of fluids) ❑✓ PSD (air emissions) 03455T30 Title V Air ❑ Nonattainment program (CAA) ❑ NESHAPs (CAA) ❑ Ocean dumping (MPRSA) ❑ Dredge or fill (CWA Section 404) ✓❑ Other (specify) NCS000572-ISW; IUP-1013 SECTION 7. MAP (40 CFR 122.21(f)(7)) 7.1 o. Have you attached a topographic map containing all required information to this application? (See instructions for specific requirements.) ✓❑ Yes ❑ No ❑ CAFO—Not Applicable (See requirements in Form 2B.) SECTION 8. NATURE OF BUSINESS (40 CFR 122.21(f)(8)) 8.1 Nature of Business Describe the nature of your business. Natural Gas Fired Electric Generation SECTION 9. COOLING WATER INTAKE STRUCTURES (40 CFR 122.21(f)(9)) 9.1 Does your facility use cooling water? ❑� Yes ❑ No 4 SKIP to Item 10.1. 9.2 Identify the source of cooling water. (Note that facilities that use a cooling water intake structure as described at 40 CFR 125, Subparts I and J may have additional application requirements at 40 CFR 122.21(r). Consult with your NPDES permitting authority to determine what specific information needs to be submitted and when.) Dan River SECTION 10. VARIANCE REQUESTS (40 CFR 122.21(f)(10)) 10.1 Do you intend to request or renew one or more of the variances authorized at 40 CFR 122.21(m)? (Check all that apply. Consult with your NPDES permitting authority to determine what information needs to be submitted and when.) ❑ Fundamentally different factors (CWA Section 301(n)) ❑ Non -conventional pollutants (CWA Section 301(c) and (g)) ❑ Not applicable ❑ Water quality related effluent limitations (CWA Section 302(b)(2)) ✓❑ Thermal discharges (CWA Section 316(a)) EPA Form 3510-1 (revised 3-19) Page 3 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Form Approved 03/05/19 OMB No. 2040-0004 SECTION 11. CHECKLIST AND CERTIFICATION STATEMENT (40 CFR 122.22(a) and (d)) you have completed and are submitting with your application. that you are enclosing to alert the permitting authority. Note Checklist and Certification Statement 11.1 In Column 1 below, mark the sections of Form 1 that For each section, specify in Column 2 any attachments that not all applicants are required to provide attachments. Column 1 Column 2 1: Activities Requiring an NPDES Permit ❑ w/ attachments ✓ Section 2: Name, Mailing Address, and Location ❑ w/ attachments ✓ Section 3: SIC Codes ❑ w/ attachments 1 Section 4: Operator Information ✓ Section ■ w/ attachments 5: Indian Land ❑ w/ attachments ✓ Section 6: Existing Environmental Permits ❑ w/ attachments 1 Section 7: Map ❑ w/ additional attachments ✓ Section ✓ watpopographic 8: Nature of Business ❑ w/ attachments ✓ Section 9: Cooling Water Intake Structures ✓ Section ✓ w/ attachments 10: Variance Requests 1 Section 1 wl attachments 11: Checklist and Certification Statement ✓ Section • w/ attachments 11.2 Certification Statement I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. Name (print or type first and last name) Terry Tuck Official title GM II - Regulated Stations Signature ,P ' ---7 G/. .1.6- c.cc— Date signed SlZ g / z o t. f EPA Form 3510-1 (revised 3-19) Page 4 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Form Approved 03/05/19 OMB No. 2040-0004 Form 2C NPDES ,EPA U.S Environmental Protection Agency Application for NPDES Permit to Discharge Wastewater EXISTING MANUFACTURING, COMMERCIAL, MINING, AND SILVICULTURE OPERATIONS SECTION 1. OUTFALL LOCATION (40 CFR 122.21(g)(1)) 1.1 Outfall Location Provide information on each of the facility's outfalls in the table below. Outfall Number Receiving Water Name Latitude Longitude 001 Dan River 36° 29' 7.9" N -79° 43' 13.96" W SECTION 2. LINE DRAWING (40 CFR 122.21(g)(2)) rn w c 3 J 2.1 Have you attached a line drawing to this application that shows the water flow through your facility with a water balance? (See instructions for drawing requirements. See Exhibit 2C-1 at end of instructions for example.) ✓❑ Yes ❑ No SECTION 3. AVERAGE FLOWS AND TREATMENT (40 CFR 122.21(g)(3)) 3.1 Average Flows and Treatment For each outfall identified under Item 1.1, provide average flow and treatment information. Add additional sheets if necessary. **Outfall Number** 001 Operations Contributing to Flow Operation Average Flow Cooling Tower Blowdown 0.8 mgd Plant Collection Sumps Low Volume Wastewater (OWS) 0.3 mgd 01 mgd mgd Treatment Units Description (include size, flow rate through each treatment unit, retention time, etc.) Clarification and Filtration Ultrafiltration, Reverse Osmosis, Oil/Water Separator Code from Table 2C-1 1-G 1-S, 2-1 2-K Final Disposal of Solid or Liquid Wastes Other Than b Dischar•e Landfill EPA Form 3510-2C (Revised 3-19) Page 1 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Form Approved 03/05/19 OMB No. 2040-0004 Average Flows and Treatment Continued 3.1 cont. **OutfaII Number** Operations Contributing to Flow Operation Average Flow mgd mgd mgd mgd Treatment Units Description (include size. flow rate through each treatment unit, retention time, etc.) Code from Table 2C-1 Final Disposal of Solid or Liquid Wastes Other Than by Discharge **Outfall Number** Operations Contributing to Flow Operation Average Flow mgd mgd mgd mgd Treatment Units Description (include size, flow rate through each treatment unit, retention time, etc.) Code from Table 2C 1 Final Disposal of Solid or Liquid Wastes Other Than by Discharge System Users 3.2 Are • you applying for an NPDES permit to operate a privately owned Yes 0 treatment works? No 4 SKIP to Section 4. 3.3 Have ■ you attached a list that identifies each user of the treatment Yes • works? No EPA Form 3510-2C (Revised 3-19) Page 2 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Form Approved 03/05/19 OMB No. 2040-0004 SECTION 4. INT RMITTENT FLOWS (40 CFR 122.21(g)(4)) 3o u_ mdays/week E m c 4.1 Except for storm runoff, leaks, or spills, are any discharges described ❑ Yes ✓ in Sections 1 and 3 intermittent or seasonal? No 4 SKIP to Section 5. 4.2 Provide information on intermittent or seasonal flows for each applicable outfall. Attach additional pages, if necessary. Fre uency Flow Rate Outfall Number Operation (list) Average DayslWeek Average MonthslYear Long -Term Average Maximum Daily Duration days/week months/year mgd mgd days days/week months/year mgd mgd days months/year mgd mgd days days/week months/year mgd mgd days days/week months/year mgd mgd days days/week months/year mgd mgd days days/week months/year mgd mgd days days/week months/year mgd mgd days days/week months/year mgd mgd days SECTION 5. PRODUCTION (40 Do any effluent ❑ Yes CFR 122.21(g)(5)) limitation guidelines (ELGs) promulgated by EPA ✓ under Section No 4 304 of the CWA SKIP to Section apply to your 6. facility? u) w a) fa U .Q Q a 5.1 5.2 Provide the following information on applicable ELGs. ELG Category ELG Subcategory Regulatory Citation Production -Based Limitations 5.3 Are any of the applicable ELGs expressed in terms of production (or other measure of operation)? ❑ Yes ❑ No 4 SKIP to Section 6. 5.4 Provide an actual measure of daily production expressed in terms and units of applicable ELGs. Outfall Number Operation, Product, or Material Quantity per Day Unit of Measure EPA Form 3510-2C (Revised 3-19) Page 3 EPA Identification Number NPDES Permit Number NCD024668535 NC0003468 Facility Name Dan River Combined Cycle Form Approved 03/05/19 OMB No. 2040-0004 SECTION 6. IMPROVEMENTS (40 CFR 122.21(g)(6)) c E o c E v c cv N m v ca rn 0. n 6.1 Are you presently required by any federal, state, or local authority upgrading, or operating wastewater treatment equipment or practices affect the discharges described in this application? ❑ Yes to meet an implementation or any other environmental schedule for constructing, programs that could 6.3. ✓ No -) SKIP to Item 6.2 Briefly identify each applicable project in the table below. Brief Identification and Description of Project Affected Outfalls (list outfall number) Source(s) of Discharge Final Compliance Dates Required Projected 6.3 Have you attached sheets describing that may affect your discharges) that ❑ Yes any additional you now water pollution have underway No control programs (or or planned? (optional item) other environmental projects Not applicable • ✓ SECTION 7. EFFLUENT AND INTAKE CHARACTERISTICS (40 CFR 122.21(g)(7)) 0 0 43 A z5 (13 co c c di w See the instructions to determine the pollutants and parameters you are required to monitor and, in turn, the tables you must complete. Not all applicants need to complete each table. Table A. Conventional and Non -Conventional Pollutants 7.1 Are you requesting a waiver from your your outfalls? NPDES permitting authority for one or more of the Table A pollutants for any of 7.3. • Yes l9 No 4 SKIP to Item 7.2 If yes, indicate the applicable outfalls Outfall Number below. Attach waiver request Outfall Number and other required information to the application. Outfall Number 7.3 Have you completed monitoring for requested and attached the results all Table A pollutants at to this application package? each of your outfalls for which No; has been a waiver has not been requested from my NPDES for all pollutants at all outfalls. 0 Yes a waiver I permitting authority Table B. Toxic Metals, Cyanide, Total Phenols, and Organic Toxic Pollutants 7.4 Do any of the facility's processes that listed in Exhibit 2C-3? (See end of contribute wastewater instructions for exhibit.) fall into one or more of the primary industry categories 7.8. 1 Yes ■ No 4 SKIP to Item 7.5 Have you checked "Testing Required" for all toxic metals, cyanide, and total phenols in Section 1 of Table B? IS Yes • No 7.6 List the applicable primary industry categories and check the boxes indicating the required GC/MS fraction(s) identified in Exhibit 2C-3. Primary Industry Category Required GC/MS Fraction(s) (Check applicable boxes.) Electric Power Plants ID Volatile 0 Acid 0 Base/Neutral 0 Pesticide ❑ Volatile 0 Acid ❑ Base/Neutral 0 Pesticide ❑ Volatile 0 Acid 0 Base/Neutral 0 Pesticide EPA Form 3510-2C (Revised 3-19) Page 4 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Form Approved 03/05/19 OMB No. 2040-0004 m cn Effluent and Intake Characteristics Continued 0 7.7 Have you checked "Testing Required" for all required pollutants in Sections 2 through 5 of Table B for each of the GC/MS fractions checked in Item 7.6? 0 Yes • No 7.8 Have you checked "Believed Present" or "Believed Absent" for all pollutants listed in Sections 1 through 5 of Table B where testing is not required? ✓ Yes ■ No 7.9 Have you provided (1) quantitative data for those Section 1, Table B, pollutants for which you have indicated testing is required or (2) quantitative data or other required information for those Section 1, Table B, pollutants that you have indicated are "Believed Present" in your discharge? A Yes • No 7.10 Does the applicant qualify for a small business exemption under the criteria specified in the instructions? B,SI ❑ Yes 4 Note that you qualify at the top of Table then SKIP to Item 7.12. No 7.11 Have you provided (1) quantitative data for those Sections 2 through 5, Table B, pollutants for which you have determined testing is required or (2) quantitative data or an explanation for those Sections 2 through 5, Table B, pollutants you have indicated are "Believed Present" in your discharge? A Yes • No Table C. Certain Conventional and Non -Conventional Pollutants 7.12 Have you indicated whether pollutants are "Believed Present" or "Believed Absent" for all pollutants listed on Table C for all outfalls? ✓ Yes ❑ No 7.13 Have you completed Table C by providing (1) quantitative data for those pollutants that are limited either directly or indirectly in an ELG and/or (2) quantitative data or an explanation for those pollutants for which you have indicated "Believed Present"? ✓ Yes ❑ No Table D. Certain Hazardous Substances and Asbestos 7.14 Have you indicated whether pollutants are `Believed Present" or "Believed Absent" for all pollutants listed in Table D for all outfalls? 1 Yes ❑ No 7.15 Have you completed Table D by (1) describing the reasons the applicable pollutants are expected to be discharged and (2) by providing quantitative data, if available? ✓ Yes ❑ No Table E. 2,3,7,8-Tetrachlorodibenzo-p-Dioxin (2,3,7,8-TCDD) 7.16 Does the facility use or manufacture one or more of the 2,3,7,8-TCDD congeners listed in the instructions, or do you know or have reason to believe that TCDD is or may be present in the effluent? ❑ Yes 4 Complete Table E. Fi No 4 SKIP to Section 8. 7.17 Have you completed Table E by reporting qualitative data for TCDD? ❑ Yes ❑ No N 8. USED OR MANUFACTURED TOXICS (40 CFR 122.21(g)(9)) Used or Manufactured Toxics 8.1 Is any pollutant listed in Table B a substance or a component of a substance used or manufactured at your facility as an intermediate or final product or byproduct? ❑ Yes ✓ No - SKIP to Section 9. 8.2 List the pollutants below. 1. 4. 7. 2. 5. 8. 3. 6. 9. EPA Form 3510-2C (Revised 3-19) Page 5 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Form Approved 03/05/19 OMB No. 2040 0004 SECTION 9. BIOLOGICAL TOXICITY TESTS (40 CFR 122.21(g)(11)) u, N 9.1 Do within ✓ you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made the last three years on (1) any of your discharges or (2) on a receiving water in relation to your discharge? Yes ❑ No 4 SKIP to Section 10. ," 9.2 Identify the tests and their purposes below. 0 Test(s) Purpose of Test(s) Submitted to NPDES . Date Submitted 0 1— R co Ceriodaphnia Chronic Effluent Bioassy NPDES Permit Requirement - Outfall 002 I 06/21/2019 0 o m • • SECTION 10. CONTRACT ANALYSES (40 CFR 122.21(g)(12)) 10.1 Were ✓ any of the analyses reported in Section 7 performed by a contract laboratory or consulting firm? Yes ❑ No 4 SKIP to Section 11. 10.2 Provide information for each contract laboratory or consulting firm below. Laboratory Number 1 Laboratory Number 2 Laboratory Number 3 y Name of laboratory/firm Duke Energy Analytical Laboratory NC#248 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) NC#329 au � , ca c Q 0 m c Laboratory address 13339 Hagers Ferry Road Huntersville, NC 28078-7929 106 Vantage Point Drive West Columbia, SC 29172 0 Phone number (980) 875-5245 (803) 791-9700 Pollutant(s) analyzed Metals, TOC, Ammonia, Oil & Grease, Fluoride, Sulfate, Bromide, Nitrate -Nitrite, TKN, Total Phosphorus BOD, COD, PCBs, Sulfide, Sulfite, Semi-Volatiles, Volatiles, TSS, Fecal Coliform, Color, Cyanide, Mercury, Surfactants, pH, TRC, Temperature, Phenol SECTION 11. ADDITIONAL INFORMATION (40 CFR 122.21(g)(13)) c 0 11.1 Has the NPDES permitting authority requested additional ❑ Yes information? ✓ No 4 SKIP to Section 12. E 0 11.2 List the information requested and attach it to this application. 1. 4. c 0 -0 -0 2. 5. Q 3. 6. EPA Form 3510-2C (Revised 3-19) Page 6 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Form Approved 03/05/19 OMB No. 2040-0004 SECTION 12. CHECKLIST AND CERTIFICATION STATEMENT (40 CFR 122.22(a) and (d)) 2C that you have completed and are submitting with your application. attachments that you are enclosing to alert the permitting authority. Note all sections or provide attachments. Checklist and Certification Statement 12.1 In Column 1 below, mark the sections of Form For each section, specify in Column 2 any that not all applicants are required to complete Column 1 Column 2 1: Outfall Location w/ attachments ✓ Section ✓ 2: Line Drawing w/ line drawing ❑ w/ additional attachments 1 Section ✓ Section 3: Average Flows and w/ list of each user of ❑ w/ attachments ❑ privately owned treatment works ✓ Treatment ❑ Section 4: Intermittent Flows ❑ wl attachments ❑ Section 5: Production ❑ w/ attachments ❑ Section 6: Improvements w/ optional additional ❑ w/ attachments ❑ sheets describing any additional pollution control plans Section 7: Effluent and Intake ❑ supporting ❑ request w/ request for a waiver and information w/ small business exemption wl Table A w/ Table C wl Table E ❑ wl explanation for identical outfalls ❑ w/ other attachments ✓ 1 1 w/ Table B Characteristics ✓ ✓ w/ Table D ❑ w/ analytical results as an attachment ✓ ❑ Section 8: Used or Manufactured Toxics ❑ w/ attachments Section 9: Biological Toxicity ❑ w/ attachments ✓ Tests 10: Contract Analyses ❑ w/ attachments ✓ Section ❑ Section 11: Additional Information ❑ wl attachments Section 12: Checklist and Statement ❑ w/ attachments 1 Certification 12.2 Certification Statement 1 certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. Name (print or type first and last name) Terry Tuck Official title GM II - Regulated Stations Signature W, -dL Date signed Sit 8 (2,o&( Page 7 EPA Form 3510-2C (Revised 3-19) EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Station Outfall Number 001 Form Approved 03/05/19 OMB No. 2040-0004 TABLE A. CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS (40 CFR 122.21(g)(7)(iii))1 Effluent Intake (Optional) Pollutant Waiver este Requested (if applicable Units (specify) Maximum Daily Discharge (required) Maximum Monthly Discharge (if available) Long -Term Average Daily Discharge (if available) Number of Analyses Long -Term Average Value Number of Analyses ❑ Check here if you have applied to your NPDES permitting authority for a waiver for all of the pollutants listed on this table for the noted outfall. 1' Biochemical oxygen demand (BODs) ■ Concentration mg/L <2.0 1 <2.0 1 Mass Ibs/day <6.7 1 2' Chemical oxygen demand (COD) Concentration mg/L 22 1 22 1 Mass Ibs/day 73.4 1 3. Total organic carbon (TOC) ❑ Concentration mg/L 8.0 1 8.0 1 Mass Ibs/day 26.7 1 4. Total suspended solids (TSS) ❑ Concentration mg/L <2.5 1 <2.5 1 Mass Ibs/day 8.34 1 5. Ammonia (as N) ❑ Concentration mg-N/L 0.031 1 0.031 1 Mass Ibs/day 0.003 1 6. Flow ❑ Rate 0.4 MGD 0.4 1 Temperature (winter) ❑ °C °C 26.0 1 7. Temperature (summer) ❑ °C °C 8. pH (minimum) ❑ Standard units S.U. 6.4 1 pH (maximum) ❑ Standard units s.u. 1 Sampling shall be conducted according to sufficiently sensitive test procedures (i e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter I, subchapter N or 0. See instructions and 40 CFR 122.21(e)(3). EPA Form 3510-2C (Revised 3-19) Page 9 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Station 0utfall Number 001 Form Approved 03/05/19 OMB No. 2040-0004 TABLE B. TOXIC METALS, CYANIDE, Pollutant/Parameter (and CAS Number, if available) TOTAL PHENOLS, Testing Required AND ORGANIC TOXIC Presence or Absence (check one) POLLUTANTS (40 CFR 122.21(g)(7)(v))1 Intake (optional) Units (specify) Effluent Believed Present Believed Absent Maximum Daily DischargeD Maximum Monthly (if availablle) Long -Term Average Daily Discharge (if available) Number of Analyses Long- Term Averageischarge Value Number of Analyses Check here if you qualify as a small business per the instructions to Form 2C and, therefore, do not need to submit quantitative data for any of the organic toxic pollutants in Sections 2 through 5 of this table. Note, however, that you must still indicate in the appropriate column of this table if you believe any of the pollutants listed are present in your discharge. Section 1. Toxic Metals, Cyanide, and Total Phenols 1.1 Antimony, total (7440-36-0) Concentration ug/L 7.5 1 7.5 1 Mass Ibs/day 0.02 1 1.2 Arsenic, total (7440-38-2) Concentration ug/L <1 1 <1 1 i i Mass Ibs/day <0.003 1 1.3 Beryllium, total (7440-41-7) Concentration ug/L <1 1 <1 1 Mass Ibs/day <0.003 1 1.4 Cadmium, total (7440-43-9) ❑ Concentration ug/L <0.1 1 <0.1 1 Mass Ibs/day <0.0003 1 1.5 Chromium, total (7440-47-3) ❑ Concentration ug/L 1.13 1 1.13 1 � Mass Ibs/day 0.004 1 1.6 Copper, total (7440-50-8) � Concentration ug/L 63 1 63 1 � Mass Ibs/day 0.21 1 1.7 Lead, total (7439-92-1) Concentration ug/L <1 1 <1 1 Mass Ibs/day <0.003 1 1.8 Mercury, total (7439-97-6) Concentration ng/L 4.30 1 4.30 1 0 Mass Ibs/day 0.00001 1 1.9 Nickel, total (7440-02-0) ❑ Concentration ug/L 1.63 1 1.63 1 Mass lbs/day 0.005 1 1.10 Selenium, total (7782-49-2) Concentration ug/L <1 1 <1 1 Mass Ibs/day <0.003 1 1.11 Silver, total (7440-22-4) Concentration ug/L <1 1 <1 1 � •❑ Mass Ibs/day <0.003 1 EPA Form 3510-2C (Revised 3-19) Page 11 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Station 0utfall Number 001 Form Approved 03/05/19 OMB No. 2040-0004 TABLE B. TOXIC METALS, CYANIDE, TOTAL PHENOLS, AND ORGANIC TOXIC POLLUTANTS (40 CFR 122.21(g)(7)(v))1 Effluent Intake (optional) Pollutant/Parameter (and CAS Number, if available) Testing Required Presence or Absence (check one) Units (specify) Believed Present Believed Absent Maximum Daily Discharge (required) Maximum Monthly Discharge (if available) Long -Term Average Daily Discharge (if available) Number of Analyses Long- Term AverageValue Number of Analyses 1.12 Thallium, total (7440-28-0) ❑ Concentration ug/L <0.2 1 <0.2 1 i Mass Ibs/day <0.0006 1 1.13 Zinc, total (7440-66-6) Concentration mg/L 0.017 1 0017 1 Mass Ibs/day 0.06 1 1.14 Cyanide, total (57-12-5) ❑ Concentration mg/L <0.01 1 <0.01 1 ✓ Mass Ibs/day <0.04 1 1.15 Phenols, total Concentration Ug/L <1.6 1 <1.6 1 Mass Ibs/day <0.005 1 Section 2. Organic Toxic Pollutants (GC/MS Fraction -Volatile Compounds) 2.1 Acrolein (107-02-8) Concentration ug/L <5.0 1 <5.0 1 ✓ Mass Ibs/day <0.02 1 2.2 Acrylonitrile (107-13-1) Concentration ug/L <5.0 1 <5.0 1 i • ✓ Mass Ibs/day <0.02 1 2.3 Benzene (71-43-2) Concentration ug/L <1.0 1 <1.0 1 Mass Ibs/day <0.003 1 2.4 Bromoform (75-25-2) ❑ Concentration ug/L <1.0 1 <1.0 1 � ✓ Mass Ibs/day <0.003 1 2.5 Carbon tetrachloride (56-23-5) Concentration ug/L <1.0 1 <1.0 1 0 Mass Ibs/day <0.003 1 2.6 Chlorobenzene (108-90-7) Concentration ug/L <1.0 1 <1.0 1 Mass Lbs/day <0.003 1 2.7 Chlorodibromomethane (124-48-1) Concentration ug/L <1.0 1 <1.0 1 Mass Ibs/day <0.003 1 2.8 Chloroethane (75-00-3) Concentration ug/L <2.0 1 <2.0 1 Mass Ibs/day <0.007 1 EPA Form 3510-2C (Revised 3-19) Page 12 EPA Identification Number NCD024668535 NPDES Permit Number Facility Name NC0003468 Dan River Combined Cycle Station OutfaII Number 001 Form Approved 03/05/19 OMB No. 2040-0004 TABLE B. TOXIC METALS, CYAN DE, Pollutant/Parameter (and CAS Number, if available) TOTAL PHENOLS, AND ORGANIC TOXIC POLLUTANTS (40 CFR 122.21(g)(7)(v))1 Effluent Intake (optional) Testing Required Presence or Absence (check one) Units (specify) Believed Present Believed Absent Maximum Daily Discharge Maximum Monthly Discharge e) Long -Term Average Daily Discharge (if available) Number of Analyses Long- Term AverageValue Number of Analyses 2'9 2-chloroethylvinyl ether (110-75-8) Concentration ug/L <5.0 1 <5.0 1 Mass Ibs/day <0.02 1 2.10 Chloroform (67-66-3) Concentration ug/L 7.2 1 7.2 1 Mass lbs/day 0.02 1 2.11 Dichlorobromomethane (75-27-4) Concentration ug/L <1.0 1 <1.0 1 Mass Ibs/day <0.003 1 2.12 1,1-dichloroethane (75-34-3) Concentration ug/L <1.0 1 <1.0 1 Mass Ibs/dy <0.003 1 2.13 1,2-dichloroethane (107-06-2) Concentration ug/L <1.0 1 <1.0 1 1 Mass Ibs/day <0.003 1 2.14 1,1-dichloroethylene (75-35-4) Concentration ug/L <1.0 1 <1.0 1 Mass Ibs/day <0.003 1 2.15 1,2-dichloropropane (78-87-5) Concentration ug/L <1.0 1 <1.0 1 Mass Lbs/day <0.003 1 2.16 1,3-dichloropropylene (542-75-6) Concentration ug/L <1.0 1 <1.0 1 0 Mass Ibs/day <0.003 1 217 Ethylbenzene (100-41-4) Concentration ug/L <1.0 1 <1.0 1 Mass Ibs/day <0.003 1 2.18 Methyl bromide (74-83-9) Concentration ug/L <2.0 1 <2.0 1 0 Mass Ibs/day <0.003 1 2.19 Methyl chloride (74-87-3) Concentration ug/L <2.0 1 <2.0 1 0 • ✓ Mass Ibs/day <0.007 1 2.20 Methylene chloride (75-09-2) Concentration ug/L <1.0 1 <1.0 1 ✓ • I Mass Ibs/day <0.003 1 2.21 1,1,2,2- tetrachloroethane (79-34-5) Concentration ug/L <1.0 1 <1.0 1 Mass Ibs/day <0.003 1 EPA Form 3510-2C (Revised 3-19) Page 13 EPA Identification Number NCD024668535 NPDES Permit Number Facility Name NC0003468 Dan River Combined Cycle Station Outfall Number 001 Form Approved 03/05/19 OMB No. 2040-0004 TABLE B. TOXIC METALS, CYANIDE, Pollutant/Parameter (and CAS Number, if available) TOTAL PHENOLS, Testing Required AND ORGANIC TOXIC POLLUTANTS (40 CFR 122.21(g)(7)(v))1 Intake (optional) Presence or Absence (check one) Effluent Believed Present Believed Absent Units (specify) Maximum Daily Discharge erdge ) Maximum Monthly Discharge f available) Long -Term Average Daily Discharge (if available) Number of Analyses Long- Term AverageValue Number of Analyses 2 22 Tetrachloroethylene (127-18-4) Concentration ug/L <1.0 1 <1.0 1 Mass lbs/day <0.003 1 2 23 Toluene (108-88-3) Concentration ug/L <1.0 1 <1.0 1 Mass Ibs/day <0.003 1 2.24 1,2-trans-dichloroethylene (156-60-5) MI Concentration ug/L <1.0 1 <1.0 1 SI Mass lbs/day <0.003 1 2 25 1,1,1-trichloroethane (71-55-6) Concentration ug/L <1.0 1 <1.0 1 Mass Ibs/day <0.003 1 2 26 1,1,2-trichloroethane (79-00-5) Concentration ug/L <1.0 1 <1.0 1 Mass Ibs/day <0.003 1 2 27 Trichloroethylene (79-01-6) Concentration ug/L <1.0 1 <1.0 1 Mass Ibs/day <0.003 1 2.28 Vinyl chloride (75-01-4) Concentration ug/L <1.0 1 <1.0 1 Mass Ibs/day <0.003 1 Section 3. Organic Toxic Pollutants (GC/MS Fraction -Acid Compounds) 3.1 2-chlorophenol (95 57 8) � � Concentration ug/L <1.6 1 <1.6 1 Mass lbs/day <0.005 1 3 2 2,4-dichlorophenol (120-83-2) 0 Concentration ug/L <1.6 1 <1.6 1 Mass Ibs/day <0.005 1 3.3 2,4-dimethylphenol (105-67-9) Concentration ug/L <1.6 1 <1.6 1 Mass Ibs/day <0.005 1 3.4 4,6-dinitro-o-cresol (534-52-1) Concentration ug/L <8.0 1 <8.0 1 Mass Ibs/day <0.03 1 3.5 2,4-dinitrophenol (51-28-5) Concentration ug/L <8.0 1 <8.0 1 Mass Ibs/day <0.03 1 EPA Form 3510-2C (Revised 3-19) Page 14 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name 0utfall Number Dan River Combined Cycle Station 001 Form Approved 03/05/19 OMB No. 2040-0004 TABLE B. TOXIC METALS, CYAN DE, Pollutant/Parameter (and CAS Number, if available) TOTAL PHENOLS, AND ORGANIC TOXIC Presence or Absence (check one) POLLUTANTS (40 CFR 122.21(g)(7)(v))1 Effluent Intake (optional) Testing Required Units (specify) Believed Present Believed Absent Maximum Daily Discharge (required) Maximum Monthly Discharge (if available) Long -Term Average Di aily g a (if available) Number of Analyses Long- Term Term Average Value Number of Analyses 3.6 2-nitrophenol (88 75 5) Concentration ug/L <3.2 1 <3.2 1 Mass Ibs/day <0.01 1 3'7 4-nitrophenol (100-02-7) Concentration ug/L <8.0 1 <8.0 1 Mass Ibs/day <0.03 1 3'8 p-chloro-m-cresol (59-50-7) Concentration ug/L <1.6 1 <1.6 1 Mass Ibs/day <0.005 1 3.9 Pentachlorophenol (87-86-5) Concentration ug/L <8.0 1 <8.0 1 Mass Ibs/day <0.03 <0.03 1 3.10 Phenol (108-95-2) Concentration ug/L <1.6 1 <1.6 1 ✓ i Mass Ibs/day <0.005 1 3.11 2,4,6-trichlorophenol (88-05-2) Concentration ug/L <1.6 1 <1.6 Mass Ibs/day <0.005 1 1 Section 4. Organic Toxic Pollutants (GC/MS Fraction -Base /Neutral Compounds) 4.1 Acenaphthene (83 32 9) Concentration ug/L <1.6 1 <1.6 1 Mass Ibs/day <0.005 1 4'2 Acenaphthylene (208-96-8) Concentration ug/L <1.6 1 <1.6 1 Mass Ibs/day <0.005 1 4'3 Anthracene (120-12-7) Concentration ug/L <1.6 1 <1.6 1 ✓ I Mass Ibs/day <0.005 1 4.4 Benzidine (92-87-5) Concentration ug/L <8.0 1 <8.0 1 Mass Ibs/day <0.03 1 4.5 Benzo (a) anthracene (56-55-3) Concentration ug/L <1.6 1 <1.6 1 ✓ / Mass Ibs/day <0.005 1 4.6 Benzo (a) pyrene (50-32-8) Concentration ug/L <1.6 1 <1.6 1 I • I Mass Ibs/day <0.005 1 EPA Form 3510-2C (Revised 3-19) Page 15 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Station 0utfall Number 001 Form Approved 03/05/19 OMB No. 2040-0004 TABLE B. TOXIC METALS, CYAN DE, TOTAL PHENOLS, AND ORGANIC TOXIC POLLUTANTS (40 CFR 122.21(g)(7)(v))1 Pollutant/Parameter (and CAS Number, if available) Testing Required Presence or Absence (check one) Effluent Intake (optional) Believed Present Believed Absent Units (specify) Maximum Daily Discharge (required) Maximum Monthly Dfavailablgee) Long -Term Average Daily Discharge (if available) Number of Analyses Long- Term AValuee Number of Analyses 4.7 3,4-benzofluoranthene (205-99-2) � ✓ Concentration ug/L <1.6 1 <1.6 1 Mass Ibs/day <0.005 1 4.8 Benzo (ghi) perylene (191-24-2) Concentration ug/L <1.6 1 <1.6 1 Mass Ibs.day <0.005 1 4'9 Benzo (k) fluoranthene (207-08-9) Concentration ug/L <1.6 1 <1.6 1 Mass Ibs/day <0.005 1 4.10 Bis (2-chloroethoxy) methane (111-91-1) Concentration ug/L <1.6 1 <1.6 1 Mass Ibs/day <0.005 1 4.11 Bis (2-chloroethyl) ether (111-44-4) Concentration ug/L <1.6 1 <1.6 1 Mass Ibs/day <0.005 1 4.12 Bis (2-chloroisopropyl) ether (102-80-1) I i Concentration ug/L <1.6 1 <1.6 1 Mass Ibs/day <0.005 1 4.13 Bis (2-ethylhexyl) phthalate (117-81-7) 0 Concentration ug/L <8.0 1 <8.0 1 Mass Ibs/day <0.03 1 4.14 4-bromophenyl phenyl ether (101-55-3) 0 Concentration ug/L <1.6 1 <1.6 1 Mass Ibs./ay <0.005 1 4.15 Butyl benzyl phthalate (85-68-7) / Concentration ug/L <1.6 1 <1.6 1 Mass Ibs/day <0.005 1 4.16 2-chloronaphthalene (91-58-7) I • I Concentration ug/L <1.6 1 <1.6 1 Mass Ibs/day <0.005 1 4.17 4-chlorophenyl phenyl ether (7005-72-3) Concentration ug/L <1.6 1 <1.6 1 Mass Ibs.day <0.005 1 4.18 Chrysene (218-01-9) ■ Concentration ug/L <1.6 1 <1.6 1 Mass Ibs/day <0.005 1 4.19 Dibenzo (a,h) anthracene (53-70-3) 0 Concentration ug/L <1.6 1 <1.6 1 Mass Ibs/day <0.005 1 EPA Form 3510-2C (Revised 3-19) Page 16 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Station Outfall Number 001 Form Approved 03/05/19 OMB No. 2040-0004 TABLE B. TOXIC METALS, CYANIDE, TOTAL PHENOLS, AND ORGANIC TOXIC Presence or Absence (check one) POLLUTANTS (40 CFR 122.21(g)(7)(v))1 Pollutant/Parameter (and CAS Number, if available) (and Testing Required Units (specify) Effluent Intake (optional) Believed Present Believed Absent Maximum Daily Discharge (required) Maximum Monthly Discharge (if available) Long -Term Average Daily Discharge (if available) Number of Analyses Long - Term AValuee of Analyses 4.20 1,2-dichlorobenzene (95-50-1) Concentration ug/L <1.0 1 <1.0 1 Mass lbs.day <0.003 1 4.21 1,3-dichlorobenzene (541-73-1) Concentration ug/L <1.0 1 <1.0 1 1 Mass lbs/day <0.003 1 4.22 14-dichlorobenzene (106-46-7) Concentration ug/L <1.0 1 <1.0 1 ✓ Mass Ibs/day <0.003 1 4.23 3,3-dichlorobenzidine (91-94-1) Concentration ug/L <8.0 1 <8.0 1 Mass lbs/day <0.03 1 4.24 Diethyl phthalate (84-66-2) Concentration ug/L <1.6 1 <1.6 1 Mass Ibs./ay <0.005 1 4.25 Dimethyl phthalate (131-11-3) Concentration ug/L <1.6 1 <1.6 1 0 0 Mass Ibs./ay <0.005 1 4.26 Di-n-butyl phthalate (84-74-2) Concentration ug/L <1.6 1 <1.6 1 II i Mass Ibs/day <0.005 1 • 4 27 2,4-dinitrotoluene (121-14-2) Concentration ug/L <3.2 1 <3.2 1 Mass lbs/day <0.01 1 4 28 • 2,6-dinitrotoluene (606-20-2) Concentration ug/L <3.2 1 <3.2 1 Mass lbs/day <0.01 1 4 29 Di-n-octyl phthalate (117-84-0) Concentration ug/L <1.6 1 <1.6 1 1 I Mass Ibs/day <0.005 1 4.30 1,2-Diphenylhydrazine (as azobenzene) (122-66-7) Concentration ug/L <1.6 1 <1.6 1 Mass lbs/day <0.005 1 4.31 Fluoranthene (206-44-0) Concentration ug/L <1.6 1 <1.6 1 I I Mass Ibs/day <0.005 1 4.32 Fluorene (86-73-7) Concentration ug/L <1.6 1 <1.6 1 Mass lbs/day <0.005 1 EPA Form 3510-2C (Revised 3-19) Page 17 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Station Outfall Number 001 Form Approved 03/05/19 OMB No. 2040-0004 TABLE B. TOXIC METALS, CYAN DE, Pollutant/Parameter (and CAS Number, if available) TOTAL PHENOLS, AND ORGANIC TOXIC Presence or Absence (check one) POLLUTANTS Units (specify) (40 CFR 122.21(g)(7)(v))1 Effluent Intake (optional) Testing Required Believed Present Believed Absent Maximum Daily Discharge (required) Maximum Monthly Discharge (if available) Long -Term Average Daily Discharge (if available) Number of Analyses Long- Term Average Value Number of Analyses 4.33 Hexachlorobenzene (118-74-1) Concentration ug/L <1.6 1 <1.6 1 i Mass Ibs/day <0.005 1 4.34 Hexachlorobutadiene (87-68-3) Concentration ug/L <1.6 1 <1.6 1 Si Mass Ibs/day <0.005 1 4.35 Hexachlorocyclopentadiene (77-47-4) Concentration ug/L <8.0 1 <8.0 1 Si Mass Ibs/day <0.03 1 4.36 Hexachloroethane (67-72-1) Concentration ug/L <1.6 1 <1.6 1 Mass Ibs/day <0.005 1 4.37 Indeno (1,2,3-cd) pyrene (193-39-5) Concentration ug/L <1.6 1 <1.6 1 1 1 Mass Ibs/day <0.005 1 4.38 Isophorone (78-59-1) Concentration ug/L <1.6 1 <1.6 1 i 1 Mass Ibs/day <0.005 1 4.39 Naphthalene (91-20-3) Concentration ug/L <1.6 1 <1.6 1 0 i Mass Ibs/day <0.005 1 4.40 Nitrobenzene (98-95-3) Concentration ug/L <1.6 1 <1.6 1 Mass Ibs/day <0.005 1 4.41 N-nitrosodimethylamine (62-75-9) Concentration ug/L <1.6 1 <1.6 1 1 1 Mass Ibs/day <0.005 1 4.42 N-nitrosodi-n-propylamine (621-64-7) Concentration ug/L <1.6 1 <1.6 1 Mass Ibs.day <0.005 1 4.43 N-nitrosodiphenylamine (86-30-6) Concentration ug/L <1.6 1 <1.6 1 1 Mass Ibs/day <0.005 1 4.44 Phenanthrene (85-01-8) Concentration ug/L <1.6 1 <1.6 1 Mass lbs.day <0.005 1 4.45 Pyrene (129-00-0) Concentration ug/L <1.6 1 <1.6 1 i i Mass Ibs/day <0.005 1 EPA Form 3510-2C (Revised 3-19) Page 18 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Station 0utfall Number 001 Form Approved 03/05/19 OMB No. 2040-0004 TABLE B. TOXIC METALS, CYANIDE, TOTAL PHENOLS, AND ORGANIC TOXIC POLLUTANTS (40 CFR 122.21(g)(7)(v))1 Effluent Intake (op ional) Pollutant]Parameter (and CAS Number, if available) Testing Required Presence or Absence (check one) Believed Present Believed Absent Units (specify) Maximum Daily Discharge (required) Maximum Monthly Discharge (if available) Long -Term Average Daily Discharge (if available) Number of Analyses Long -Number Term Average Value of Analyses 4.46 1,2,4-trichlorobenzene (120-82-1) ✓ ✓ Concentration ug/L <1.6 1 <1.6 1 Mass Ibs/day <0.005 1 <0.005 1 Section 5. Organic Toxic Pollutants (GCIMS Fraction —Pesticides) 5.1 Aldrin (309-00-2) ✓ Concentration Mass 5.2 a-BHC (319-84-6) III✓ ❑ Concentration Mass 5.3 3-BHC (319-85-7) ✓ Concentration Mass 5.4 y-BHC (58-89-9) ✓ Concentration Mass 5.5 6-BHC (319-86-8) Concentration Mass 5.6 Chlordane (57-74-9) Concentration Mass 5.7 4,4'-DDT (50-29-3) ❑ ❑ ✓ Concentration Mass 5.8 4,4'-DDE (72-55-9) 0 Concentration Mass 5.9 4,4'-DDD (72-54-8) Concentration Mass 5.10 Dieldrin (60-57-1) ✓ Concentration Mass 5.11 a-endosulfan •(115-29-7) ✓ Concentration Mass EPA Form 3510-2C (Revised 3-19) Page 19 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Station 0utfall Number 001 Form Approved 03/05/19 OMB No. 2040-0004 TABLE B. TOXIC METALS, CYANIDE, Pollutant/Parameter (and CAS Number, if available) TOTAL PHENOLS, AND ORGANIC TOXIC Presence or Absence (check one) POLLUTANTS Units (specify) (40 CFR 122.21(g)(7)(v))1 Effluent Intake (optional) Testing Required Believed Present Believed Absent Maximum Daily Discharge (required) Maximum Monthly Discharge (if available) Long -Term Average Daily Discharge (if available) Number of Analyses Long - Term Average Value Number of Analyses 5.12 R-endosulfan (115-29-7) Concentration Mass 5.13 Endosulfan sulfate (1031-07-8) Concentration Mass 5.14 Endrin (72-20-8) Concentration ✓ Mass 5.15 Endrin aldehyde (7421-93-4) Concentration Mass 5.16 Heptachlor (76-44-8) ❑ Concentration ✓ Mass 5.17 Heptachlor epoxide (1024-57-3) Concentration 0 Mass 5.18 PCB-1242 (53469-21-9) ❑ Concentration ug/L <0.4 1 <0.4 1 ✓ ✓ Mass Ibs/day <0.001 1 5.19 PCB-1254 (11097-69-1) ❑ Concentration ug/L <0.4 1 <0.4 1 ✓ ✓ Mass Ibs/day <0.001 1 5.20 PCB-1221 (11104-28-2) Concentration ug/L <0.4 1 <0.4 1 ✓ • ✓ Mass Ibs/day <0.001 1 5.21 PCB-1232 (11141 16 5) Concentration ug/L <0.4 1 <0.4 1 ✓ ✓ Mass Ibs/day <0.001 1 5.22 PCB-1248 (12672-29-6) ❑ Concentration ug/L <0.4 1 <0.4 1 ✓ ✓ Mass Ibs/day <0.001 1 5.23 PCB-1260 (11096 82 5) Concentration ug/L <0.4 1 <0.4 1 ✓ • ✓ Mass Ibs/day <0.001 1 5.24 PCB-1016 (12674-11-2) Concentration ug/L <0.4 1 <0.4 1 ✓ • ✓ Mass Ibs/day <0.001 1 EPA Form 3510-2C (Revised 3-19) Page 20 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Station Outfall Number 001 Form Approved 03/05/19 OMB No. 2040-0004 TABLE B. TOXIC METALS, CYANIDE, TOTAL PHENOLS, AND ORGANIC TOXIC POLLUTANTS (40 CFR 122.21(g)(7)(v))1 Effluent Intake (optional) Pollutant/Parameter (and CAS Number, if available) Testing Required Presence or Absence (check one) Units (specify) Believed Present Believed Absent Maximum Daily D(req fireischargd a Maximum Monthly Df available) ischarge Long -Term Average Daily Discharge (if available) Number of Analyses Long- Tenn A Value Number of Analyses 5.25 Toxaphene (8001-35-2) Concentration 0 Mass 1 Sampling shall be conducted according to sufficiently sensitive test procedures (Le., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter I, subchapter N or 0. See instructions and 40 CFR 122.21(e)(3). EPA Form 3510-2C (Revised 3-19) Page 21 EPA Identification Number NCD024668535 TABLE C. CERTAIN CONVENTIONAL NPDES Permit NC0003468 AND NON CONVENTIONAL Number POLLUTANTS Dan River Combined Facility Name Cycle Station (40 CFR 122.21(g)(7)(vi))1 Outfall Number 001 Form Approved 03/05/19 OMB No. 2040-0004 Presence or Absence (check one) Effluent Intake (Optional) Pollutant Believed Present Believed Absent Units (specify) Maximum DailyLong-Term Discharge (required) Maximum Monthly Discharge (if available) Long -Term Average Daily Discharge (if available) Number of Analyses Average Value Number of Analyses Check here if you believe all pollutants on Table C to be present in your discharge from the noted outfall. You need not complete the 'Presence or Absence" column of Table C for each pollutant. Check here if you believe all pollutants on Table C to be absent in your discharge from the noted outfall. You need not complete the "Presence or Absence" column of Table C for each pollutant. 1 Bromide (24959-67-9) 5 Concentration mg/L 0.98 1 0.98 1 Mass Ibs/day 3.3 1 2 Chlorine, total residual Concentration mg/L <0.05 1 <0.05 1 Mass Ibs/day <0.2 1 3. Color 0 Concentration color units <5.0 1 <5.0 1 Mass Ibs/day NA 1 4. Fecal coliform SI Concentration MPN/100 <1 1 <1 1 Mass lbs/day NA 1 5 Fluoride (16984-48-8) • 0 Concentration mg/L <0.5 1 <0.5 1 Mass Ibs/day <2 1 6 Nitrate -nitrite ✓ ■ Concentration mg-N/L 2.2 1 2.2 1 Mass Ibs/day 7.34 1 7 Nitrogen, total organic (as N) ✓ • Concentration mg-N/L 0.62 1 0.62 1 Mass Ibs/day 2.07 1 8. Oil and grease 0 Concentration mg/L <5 1 <5.0 1 Mass mg/L <16.8 1 g Phosphorus (as P), total (7723-14-0) ✓ • Concentration mg-P/L 1.62 1 1.62 1 Mass Ibs/day 5.40 1 10. Sulfate (as SO4) (14808-79-8) 0 ❑ Concentration mg/L 52 1 52 1 Mass Ibs/day 174.72 1 11. Sulfide (as S) ✓ Concentration mg/L <1.0 1 <1.0 1 Mass Ibs/day <0.003 1 EPA Form 3510-2C (Revised 3-19) Page 23 TABLE EPA Identification Number NCD024668535 C. CERTAIN CONVENTIONAL Pollutant Presence or (check NPDES Permit NC0003468 AND NON CONVENTIONAL Absence one) Number POLLUTANTS Units (specify) Dan River Combined Facility Name Cycle Station (40 CFR 122.21(g)(7)(vi))1 0utfall Number 001 Effluent Form Approved 03/05/19 OMB No. 2040-0004 Intake (Optional) Believed Present Believed Absent Maximum DailyLong-Term Discharge (required) Maximum Monthly Discharge (if available) Long -Term Average Daily Discharge (if available) Number of Analyses Average Value Number of Analyses 12. Sulfite (as S03) (14265-45-3) Concentration mg/L 2.5 1 2.5 1 i ■ Mass lbs./ay 8.34 1 13. Surfactants mgMBAS/ 0.079 1 0.079 1 NI Mass Ibs/day 0.26 1 14. Aluminum, total (7429-90-5) Concentration mg/L 0.067 1 0.067 1 ■ Mass Ibs/day 0.22 1 15. Barium, total (7440-39-3) ❑ Concentration mg/L 0.078 1 0.078 1 Mass Ibs/day 0.26 1 16. Boron, total (7440-42-8) ❑ Concentration mg/L 0.095 1 0.095 1 0 Mass lbs/day 0.32 1 17 Cobalt, total (7440-48-4) Concentration ug/L <1 1 <1.0 1 ■ SI Mass Ibs/day <0.003 1 18 Iron total (7439-89-6) Concentration mg/L 0.235 1 0.235 1 ✓ ■ Mass Ibs/day 0.78 1 19 Magnesium, total (7439-95-4) Concentration mg/L 11.4 1 11.4 1 ■ Mass Ibs/day 38.3 1 20. Molybdenum, total (7439-98-7) ❑ Concentration ug/L 6.17 1 6.17 1 0 Mass Ibs/day 20.7 1 21 Manganese, total (7439-96-5) ❑ Concentration mg/L <0.005 1 <0.005 1 Mass Ibs/day <0.02 1 22 Tin, total (7440-31-5) ❑ Concentration mg/L <0.01 1 <0.01 1 0 Mass Ibs/day <0.03 1 23 Titanium, total (7440-32-6) ❑ Concentration mg/L <0.005 1 <0.005 1 0 Mass Ibs/day <0.02 1 EPA Form 3510-2C (Revised 3-19) Page 24 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Station Outfall Number 001 Form Approved 03/05/19 OMB No. 2040-0004 TABLE C. CERTAIN CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS (40 CFR 122.21(g)(7)(vi))1 Presence or Absence (check one) Effluent Intake (Optional) Pollutant Believed Present Believed Absent Units (specify) Maximum Daily Discharge (required) Maximum Monthly Discharge (if available) Long -Term Average Daily Discharge (if available) Number of Analyses Long -Term Average Value Number of Analyses 24. Radioactivity Alpha, total ❑ ✓ Concentration Mass Beta, total • ✓ Concentration Mass Radium, total ❑ ✓ Concentration Mass Radium 226, total ❑ ✓ Concentration Mass 1 Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter I, subchapter N or 0. See instructions and 40 CFR 122.21(e)(3). EPA Form 3510-2C (Revised 3-19) Page 25 TABLE EPA Identification Number NCD024668535 D. CERTAIN HAZARDOUS NPDES SUBSTANCES Permit Number NC0003468 AND ASBESTOS (40 Presence or Absence (check one) Dan River Combined CFR 12221(g)(7)(vii))1 Facility Name Cycle Station Outfall Number 001 Form Approved 03/05/19 OMB No. 2040-0004 Pollutant Reason Pollutant Believed Present in Discharge Available Quantitative Data (specify units) Believed Present Believed Absent 1. Asbestos ■ ✓ 2. Acetaldehyde ■ ✓ 3. Allyl alcohol ■ ✓ 4. Ally' chloride ■ ✓ 5. Amyl acetate ■ ✓ 6. Aniline ■ ✓ 7. Benzonitrile ■ ✓ 8. Benzyl chloride ■ ✓ 9. Butyl acetate 1 ✓ 10. Butylamine ■ ✓ 11. Captan IN ✓ 12. Carbaryl ■ ✓ 13. Carbofuran ■ ✓ 14. Carbon disulfide ■ ✓ 15. Chlorpyrifos ■ ✓ 16. Coumaphos ■ ✓ 17. Cresol ■ ✓ 18. Crotonaldehyde ■ ✓ 19. Cyclohexane ■ ✓ EPA Form 3510-2C (Revised 3-19) Page 27 TABLE EPA Identification Number NCD024668535 D. CERTAIN HAZARDOUS Pollutant NPDES NC0003468 SUBSTANCES Permit Number AND ASBESTOS (40 Presence or Absence (check one) Dan River Combined CFR 122.21(g)(7)(vii))1 Facility Name Cycle Station Reason Pollutant Outfall Number 001 Believed Present in Discharge Form Approved 03/05/19 OMB No. 2040-0004 Available Quantitative Data (specify units) Believed Present Believed Absent 20. 2,4-D (2,4-dichlorophenoxyacetic acid) ■ ✓ 21. Diazinon ■ ✓ 22. Dicamba ■ ✓ 23. Dichlobenil ■ ✓ 24. Dichlone ■ ✓ 25. 2,2-dichloropropionic acid ■ ✓ 26. Dichlorvos ■ ✓ 27. Diethyl amine ■ ✓ 28. Dimethyl amine ■ ✓ 29. Dintrobenzene ■ ✓ 30. Diquat ■ ✓ 31. Disulfoton 1 ✓ 32. Diuron ■ ✓ 33. Epichlorohydrin ■ ✓ 34. Ethion ■ ✓ 35. Ethylene diamine ■ ✓ 36. Ethylene dibromide ■ ✓ 37. Formaldehyde ■ ✓ 38. Furfural ■ ✓ EPA Form 3510-2C (Revised 3-19) Page 28 TABLE EPA Identification Number NCD024668535 D. CERTAIN HAZARDOUS Pollutant NPDES SUBSTANCES Permit Number NC0003468 AND ASBESTOS (40 Presence or Absence (check one) Dan River Combined CFR 12221(g)(7)(vii))1 Facility Name Cycle Station Reason Pollutant Outfall Number 001 Believed Present in Discharge Form Approved 03/05/19 OMB No. 2040-0004 Available Quantitative Data (specify units) Believed Present Believed Absent 39. Guthion ■ ✓ 40. Isoprene ■ ✓ 41. Isopropanolamine ■ ✓ 42. Kelthane ■ ✓ 43. Kepone ■ ✓ 44. Malathion ■ ✓ 45. Mercaptodimethur ■ ✓ 46. Methoxychlor ■ ✓ 47. Methyl mercaptan ■ ✓ 48. Methyl methacrylate ■ ✓ 49. Methyl parathion ■ III 50. Mevinphos ■ ✓ 51. Mexacarbate 1 ✓ 52. Monoethyl amine ■ ✓ 53. Monomethyl amine 1 ✓ 54. Naled ■ ✓ 55. Naphthenic acid ■ ✓ 56. Nitrotoluene ■ 0 57. Parathion ■ GI EPA Form 3510-2C (Revised 3-19) Page 29 TABLE EPA Identification Number NCD024668535 D. CERTAIN HAZARDOUS Pollutant NPDES SUBSTANCES Permit Number NC0003468 AND ASBESTOS (40 Presence or Absence (check one) Dan River Combined CFR 122.21(g)(7)(vii))1 Facility Name Cycle Station 0utfall Number 001 Form Approved 03/05/19 OMB No. 2040-0004 Available Quantitative Data Believed Present Believed Absent Reason Pollutant Believed Present in Discharge (specify units) 58. Phenolsulfonate ❑ ✓ 59. Phosgene ■ ✓ 60. Propargite ■ ✓ 61. Propylene oxide ■ ✓ 62. Pyrethrins ■ ✓ 63. Quinoline ■ ✓ 64. Resorcinol ■ ✓ 65. Strontium ■ ✓ 66. Strychnine ■ ✓ 67. Styrene ■ ✓ 68 2,4,5-T (2,4,5-trichlorophenoxyacetic acid) ✓ 69. TDE (tetrachlorodiphenyl ethane) ■ ✓ 70 2,4,5-TP [2-(2,4,5-trichlorophenoxy)• propanoic acid] ✓ 71. Trichlorofon ■ ✓ 72. Triethanolamine ■ ✓ 73. Triethylamine ■ ✓ 74. Trimethylamine IN ✓ 75. Uranium ■ ✓ 76. Vanadium ■ ✓ EPA Form 3510-2C (Revised 3-19) Page 30 TABLE EPA Identification Number NCD024668535 D. CERTAIN HAZARDOUS Pollutant NPDES SUBSTANCES Permit Number NC0003468 AND ASBESTOS (40 Presence or Absence (check one) Dan River Combined CFR 122.21(g)(7)(vii))1 Facility Name Cycle Station Outfall Number 001 Form Approved 03/05/19 OMB No. 2040-0004 Reason Pollutant Believed Present in Discharge Available Quantitative Data (specify units) Believed Present Believed Absent 77. Vinyl acetate ■ ✓ 78. Xylene ■ ✓ 79. Xylenol ■ ✓ 80. Zirconium ■ ✓ 1 Sampling shall be conducted according to sufficiently sensitive tes procedures (Le., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter I, subchapter N or 0. See instructions and 40 CFR 122.21(e)(3). EPA Form 3510-2C (Revised 3-19) Page 31 EPA Identification Number NCD024668535 NPDES Permit Number NC0003468 Facility Name Dan River Combined Cycle Station Outfall Number 001 Form Approved 03/05/19 OMB No. 2040-0004 TABLE E. 2,3,7,8 TETRACHLORODIBENZO P DIOXIN (2,3,7,8 TCDD) (40 CFR 122.21(g)(7)(viii)) Pollutant TCDD Congeners Used or Manufactured Presence or Absence (check one) Believed Present Believed Absent Results of Screening Procedure 2,3,7,8-TCDD 0 0 ✓❑ EPA Form 3510-2C (Revised 3-19) Page 33 .n. Rtixr I Duke Energy Parcel L Outfall #: 001 Receiving Stream: Dan River Latitude: 36° 29' 7.9" N Longitude: 79° 43' 13.96" W Outfall #: 001A Receiving Stream: Dan River Latitude: 36° 29' 26.22" N Longitude: 79° 43' 14.34" W Duke Energy Carolinas, LLC NC0003468 Dan River Combined Cycle Station 0 1,000 2,000 4,000 Feet 4411111/1 Facility Location EVAPORATIVE LOSS ^. COOLING TOWER DRIFT EVAPORATIVE LOSS I 4062 GPM 0 CONDENSER CLOSED COOLING WATER SUPPLY MUNICIPAL 3 GPM 400 GPM ► POTABLE USERS 9 GPM SEPTIC SYSTEM 55 GPM CHILLER SYSTEM ' 60 GPM 72 GPM CHILLER COIL CONDENSATE MAINTENANCE HOLDING TANK - MAKEUP CLARIFICATION Al FILTERED WATER STORAGE FIRE PROTECTION 77 GPM 70 GPM ' ULTRA - FILTRATION DEMIN CLEANING WASTE NEUTRALIZATION TANK A BLOW DOWN SUMP A 4 37 GPM 20 GPM 77 GPM REVERSE OSMOSIS 58 GPM 5 GPM IF 20 GPM 5 GPM POTABLE MIXED BED DEMIN TRAILER 0 STORAGE TANK 55 GPM AL s GPM MISCELLANEOUS USES OIL SEPARATOR 0 (DISCHARGE OUTFALL 001 A) 28 GPM 40 GPM SLUDGE THICKENER FILTER PRESS 12 GPM L (DAN RIVER 05 GPM OFF SITE TREATMENT/ DISPOSAL A CHILLER SYSTEM SUMPS 4 3 GPM v EVAPORATIVE LOSS HRSG 25 GPM CT WASH WATER 0 GPM ► PLANT SUMPS 1OUTFALL001 0.6MGD WATER SCHEMATIC FLOW DIAGRAM FIGURE 1 DUKE ENERGY PROGRESS INC. DAN RIVER COMBINED CYCLE ROCKINGHAM COUNTY, NC SHEET 1 OF 1 ®� NPDES Supplemental Information For Dan River Combined Cycle Station NPDES Permit # NC0003468 June 2021 General Information The Dan River Combined Cycle (DRCC) Station consists of two General Electric 7FA gas turbine generators with a General Electric D11 Steam Turbine. The nominal output for this facility is rated for 620 MW. DRCC generates the process water used in the plant by treating water from the Dan River. The facility pumps water from the Dan River via 3 raw water pumps to the Graver clarifier. Coagulant (Ferralyte 8130/ferric sulfate), polymer (flocculant), sodium hydroxide (pH control), and sodium hypochlorite (disinfection) are added to the raw water. Water from the clarifier is further treated through gravity filters. The filtered water is stored in the Fire Water/Service Water Tank for fire protection, makeup water to the HRSG, and/or various other plant functions. All waste streams are either directly or indirectly routed back to the Dan River or are hauled off site for disposal. A brief discussion of all the discharges follow. Outfall 001— Combined Cycle Wastewater Sump Discharge Outfall 001 is the gravity flow discharge of the DRCC wastewater sump to the Dan River and consists of various wastewater streams. These wastewater streams include cooling tower blowdown, oil and water separator (Internal Outfall 001A), ultrafiltration backwash, Reverse Osmosis (RO)/portable demineralizer trailer rinse down, RO cleaning wastewater, and fire (service) water/demineralizer tank overflow and drainage. All facility waste streams that are not shipped offsite are discharged to the cooling tower and mixed prior to discharge through Outfall 001. Cooling Tower Blowdown Condenser cooling water (CCW) is supplied through filtered water sent to a ten -cell cooling tower. The cooling tower basin contains approximately 1 million gallons of water. This water is recirculated and cycled with approximately 5% make up added hourly to account for blowdown and evaporation loss. Sodium hypochlorite is fed to the cooling tower for disinfection/biological growth control, a dispersant/corrosion inhibitor is fed for water chemistry parameter monitoring on the tower and corrosion inhibition, and a small amount of defoaming agent is added to prevent foaming issues. A blowdown stream averaging around 400 gpm is used to maintain concentration of total dissolved solids in the cooling tower to within proper operating limits. Sodium bisulfite is fed into the blowdown stream for chlorine removal prior to discharge to the DRCC wastewater sump. During cooling tower maintenance activities, the basin may have to be drained to various level, including emptied. Depending on the activity, the basin may be partially or fully routed through the blowdown line or through retention basins/tanks for dichlorination prior to discharge at Outfall 001. HRSG Blowdown Heat recovery steam generator (HRSG) utilizes approximately 350,000 gallons per day of filtered water drawn from the Service Water/Fire Water tank. In addition, to clarification and filtration, the filtered water undergoes ultrafiltration, reverse osmosis, and mixed bed demineralization. Ultrafiltration uses citric acid and sodium hypochlorite. Reverse Osmosis utilizes an anti-scalant, sodium hydroxide for pH control, and sodium bisulfite for dichlorination. Demineralized water is stored in the demineralized water storage tank and further treated with ammonium hydroxide for pH control, an oxygen scavenger, and phosphate for corrosion inhibitor prior to use in the HRSG. HRSG blowdown is sent to the cooling tower basin via various drains throughout the station that are piped to the HRSG blowdown sump. Other wastestreams that go to the HRSG blowdown sump include auxiliary boiler blowdown, Ultrafiltration (UF) acid cleaning and bleach cleaning wastewater and (RO) concentrate. Chiller Blowdown The chiller system is utilized during the late spring and summer months to increase power output of the gas turbines by cooling the incoming air. The chiller system consists of a heat exchanger which provides an extended surface over which the inlet air is cooled. The chilled water, mixture of 33% propylene glycol and water, is supplied by a chiller plant which has a total system capacity of approximately 65,000 gallons. 2,000 gallons of refrigerant mixed with cooling water is utilized in the chiller plant. The water in the chiller system is recirculated. The cooling water side of the chiller system consists of approximately 20,000 gallons of clarified and filtered water that is treated with sodium hypochlorite for biological control. A dispersant/corrosion inhibitor is used for water chemistry parameter monitoring on the tower and corrosion inhibition. A blowdown stream (chiller blowdown) of approximately 32 gpm is utilized to maintain water chemistry within the tower at proper operating limits. Small volumes of the chilled water (propylene glycol/water mixture) may be discharged to the cooling tower basin via the chiller blowdown during maintenance activities. Prior to the winter months, the cooling water side of the chiller system is winterized utilizing approximately 150 gallons of a sodium hydroxide based chemical which is pumped into the cooling water side of the system, mixed with approximately 20,000 gallons of filtered water, circulated and drained to the cooling tower basin. Oil and Water Separator (Outfall 001A) All powerhouse building floor drains and all outside oil filled equipment drains are piped to an oil and water separator. A new oil and water separator was installed in November of 2016. The discharge of the oil and water separate was routed to the cooling tower basin, to help with basin water makeup. The water chemistry lab is located in the gas combustion turbine building. Several chemicals are used in the lab in small quantities for sample preservation, bottle rinsing, equipment calibration, analytical chemistry, etc. The wastes are poured down the sink, discharged into a bulking drain and gravity fed to the oil and water separator. The powerhouse building floor drains can receive input from spillage/leakage of various chemicals and equipment, floor wash water, and maintenance activities. The following are examples of materials that are stored/used inside the powerhouse: ammonium hydroxide, hydrazine propylene glycol, new/used lube oil, kerosene diesel fuel, phosphate, corrosion inhibitors, industrial cleaning products, and miscellaneous lab chemicals. Treated Domestic Sewage The domestic sewage treatment system was removed in November of 2017. UF Backwash, Portable Demineralizer trailer backwash, and RO rinse water During normal demineralization (demin) water demand periods, the RO system runs every 8 hours with a 4-hour break in between runs. On initial startup the RO system is rinsed to be in the optimum operating conductivity range. The rinse water produced during this initial startup is discharged to DRCC wastewater sump. During high demin water demand periods, portable demin trailers are bought in to supply additional demineralized water. These trailers are rinsed prior to use and drained when the demin trailer is exhausted or upon project completion. When the RO is operating, the UF system typically backwashes every 30-40 minutes. During UF system backwash, 135 gpm of backwash water is discharged to the DRCC wastewater sump for approximately 2 minutes. RO Cleaning Waste The RO system is normally cleaned once a quarter. This process consists of an acid cleaning, a caustic cleaning, and treatment utilizing a biocide. The cleaning waste is sent to the neutralization tank and treated with acid/caustic for pH control. Upon neutralization, the waste is discharged to the DRCC wastewater sump. Service Water/Fire Water Storage Tank and Demineralizer Water Storage Tanks Overflow/Draft Periodically, maintenance will need to be performed on the Service Water/Fire Water Tank and the Demineralizer Water Tank. This maintenance will require the water from the storage tanks to be drained to the DRCC wastewater sump. Sludge Holding Tank In 2019 DRCC installed a 20,000 gallon sludge holding tank for storage of sludge accumulated in the Clarifier during major plant maintenance outages. During clarifier maintenance the activities, the sludge will be pumped to the sludge holding tank and the water layer will be routed through the blowdown line for dichlorination prior to discharge to the DRCC wastewater sump. Outfall 002 — Ash Pond Discharge from outfall 002 ceased in May of 2019. Excavation of ash from the ash ponds was completed in June 2019. Outfall 002 was removed in October 2020. Certificate of Final Approval for breach of the Primary and Secondary Ash Pond dams and reclassification of the dams as low hazard reclaimed status was received in April 2021. Outfalls —102, 103, 104 - Seep Discharge Discharge from the constructed seeps consisted of seepage from the ash ponds and stormwater. The flow from the seeps ceased in May 2019. Combined Cycle Industrial Wastes for Offsite Disposal Clarifier Sludge Sludge is removed from the clarifier and dewatered utilizing a plate and frame filter press. The dewatered sludge is shipped to an industrial landfill. Gas Turbine Compressor Wash Each combustion turbine unit is equipped with a 6000-gallon compressor wash water sump. Periodically, the combustion turbines receive an online or offline compressor wash. This activity involves injecting water with a mild detergent into the compressor section of the turbine and subsequent rinse cycles. The offline wash generates approximately 4000 to 5000 gallons of wastewater per turbine. This activity occurs between 3 to 5 times per year per turbine. An outside waste disposal company is contracted to remove the wastewater for offsite disposal. Chiller Sumps The chiller plant has two chiller sumps where chilled water (propylene glycol/water mixture) is collected during maintenance activities and normal operation. An outside waste disposal company is contracted to remove the wastewater for offsite disposal. Potential Discharges Not Covered by Analysis Location Chemical Quantity Frequency Purpose Water treatment (Clarifier) 60% Ferric Sulfate/Ferralyte 8130 5000 gal tank As needed Coagulant Water Treatment (Clarifier) 25% Sodium Hydroxide 3000 gal tank As Needed pH control Water Treatment (Clarifier) 12.5% Sodium Hypochlorite 6000 gal tank As Needed disinfection Water Treatment (Clarifier and Thickener Tank) Nalclear 7768 400 gal tote As Needed Flocculant Water Treatment (Clarifier and Thickener Tank) Ferralyte 8130 Ferric Sulfate 3000 gallons As Needed Flocculant Water Treatment (Polymer Pumps) PolyClean 7 5 gal pails As Needed Polymer pump cleaning solution Cooling Tower (shared with Chiller Tower) 3D Trasar 3DT187 2000 gals tank As needed Dispersant/corrosion inhibitor Cooling Tower (shared with Chiller Tower) 12.5% Sodium Hypochlorite 6000 gals tank As needed Disinfection/biological growth control Cooling Tower (shared with Chiller Tower) Trasar 3DT199 110 gal tote As needed Corrosion inhibitor Cooling Tower Nalco 7468 5 gal pails As needed Defoamer Chiller System DOWFROST HD (propylene glycol) 63000 gals (system) Circulated, closed system Cooling Agent Chiller System Dupont SUVA 123 2000 gals Circulate, closed system Refrigerant Chiller System NalPrep IV 200 gals 1/year Layup Chemical Closed Cooling Water 33% Propylene Glycol 21000 gals (system) As needed Cooling Agent Closed Cooling Water Nalco C-4710 5 gal pail As needed Corrosion Inhibitor Demineralizer Bldg (RO and Cooling Tower Blow down) 38% Sodium bisulfite 330 gal tote As needed Dechlorination Demineralizer Bldg (RO system) 25% Sodium hydroxide 330 gal tote As needed pH control Demineralizer Bldg (UF system) 50% Citric acid 350 gal tote As needed UF acid cleaning Demineralizer Bldg (UF system) 12.5% sodium hypochlorite 330 gal tote As needed UF bleach cleaning Demineralizer Bldg (RO system) AntiscalantPC- 191T 110 gal tote As needed Corrosion inhibitor Demineralizer Bldg (RO cleaning biocide) RoCide DB20 150 ml 1/quarter or as needed Biocide Demineralizer Bldg (RO cleaning) RoClean P303 96 Ibs 1/quarter or as needed RO acid cleaning Demineralizer Bldg (RO cleaning) RoCide IS2 30 gal tote 1/quarter or as needed Biocide Demineralizer Bldg (RO cleaning) RoClean P111 96 Ibs 1/quarter or as needed RO caustic cleaning Aux Boiler Bldg (HRSG Water) 19% Aqueous Ammonia 330 gal tote As needed pH control Aux Boiler Bldg (HRSG Water) Eliminox 75 gal tote As needed Oxygen scavenger Unit 9 HRSG phosphate skid (HRSG Water) Trisodium phosphate 300 gal tank As needed Corrosion Inhibitor Unit 8 HRSG phosphate skid (HRSG water) Trisodium phosphate 300 gal tank As needed Corrosion Inhibitor Steam Turbine Bldg (HRSG Water) 19% Aqueous ammonia 350 gal tote As needed pH control Selective Catalytic Reduction 19% Aqueous ammonia 20000 gal tank As needed NOx emissions reduction System Maintenance Rhodamine WT Liquid Dye As needed As needed Tracing of Leaks Thermal Modeling Report Duke Energy - Dan River Combined Cycle Prepared for: Duke Energy Carolinas, LLC Charlotte, North Carolina August 11, 2020 Prepared by: Water Environment Consultants Mount Pleasant, South Carolina Thermal Modeling Report - Dan River Steam Station Table of Contents Executive Summary iv 1 Introduction 1 2 NPDES Outfall 001 3 3 EFDC Modeling 5 3.1 Field Data Collection 5 3.2 Model Setup and Calibration 9 3.3 7Q10 Model Conditions 14 3.4 Outfall 001 Mixing Zone Results and Proposed Permit Limits 16 4 References 18 ii Thermal Modeling Report - Dan River Steam Station List of Figures Figure 1-1. Site Location Map 2 Figure 2-1. Location of Dan River Combined Cycle Steam Station Outfall 001 3 Figure 2-2. Photo of discharge pipe at Outfall 001 4 Figure 3-1. Photo of study area (outfall pipe is located at right as shown) 6 Figure 3-2. Photo study area (downstream of outfall) 7 Figure 3-3. Measured depths on August 13, 2019 (aerial at higher flow condition) 8 Figure 3-4. Depth -averaged, measured velocities on August 13, 2019 (aerial at higher flow condition)9 Figure 3-5. Model grid and flow barriers 10 Figure 3-6. Depth grid 11 Figure 3-7. Model grid and bathymetry converted to feet relative to NAVD88 12 Figure 3-8. Calibrated model velocities and measured current velocities (upstream portion) 13 Figure 3-9. Calibrated model velocities and measured current velocities (downstream portion) 14 Figure 3-11. 7Q10 model results for summer (top) and winter (bottom) conditions 17 List of Tables Table 3-1. 7Q10 model inputs 15 A4411:( iii Thermal Modeling Report - Dan River Steam Station Executive Summary Duke Energy Carolinas, LLC (Duke) retained Water Environment Consultants (WEC) to conduct a thermal modeling analysis at Duke's Dan River Combined Cycle Station in Eden, North Carolina. The coal-fired steam station was retired and removed from the site, and a 620-MW combined cycle power plant was constructed in 2012. The current discharge from Outfall 001 is process water and cooling water from the combined cycle plant. A thermal mixing zone evaluation is required to determine the appropriate permit limitations for the discharge without the ambient cooling previously provided by the wastewater treatment basins. This report and the proposed limitations must be reviewed by the North Carolina Department of Environmental Quality (NCDEQ) for incorporation into the next NPDES discharge permit. WEC used the Environmental Fluid Dynamics Code (EFDC) to assess if the discharge will meet the 29°C maximum and 2.8°C rise -above -background requirements (15 NCAC 02B .0211 Fresh Water Quality Standards for Class C Waters) at an acceptable distance downstream. Per EPA's Exposure Assessment Models webpage, "EFDC is a state-of-the-art hydrodynamic model that can be used to simulate aquatic systems in one, two, and three dimensions. It has evolved over the past two decades to become one of the most widely used and technically defensible hydrodynamic models in the world." Local depths and current velocity measurements were collected using a Sontek M9 Acoustic Doppler Current Profiler (ADCP), equipped with a differential GPS to provide horizontal positioning data. A Trimble Geo 7x Centimeter Edition survey unit was used to collect water surface elevations along the river bank. This data was used to set up and calibrate an EFDC model for the project. Once calibrated, the model was used to predict thermal plume mixing under summer and winter 7Q10 conditions. The proposed effluent temperature limits for summer and winter conditions were 99°F and 88°F, respectively. The model was run under a maximum discharge flow rate of 1.33 MGD and with temperature dilution from mixing only (no heat loss from evaporation). Both assumptions provide a conservative estimate of how the effluent plume mixes with the ambient river flow. The critical condition modeled for the summer was the 29°C maximum temperature standard. The critical condition modeled for the winter was the 2.8°C exceedance over background conditions. The model results show that a majority of the thermal plume is contained within the small channel beneath the outfall pipe which connects to Dan River. As the plume mixes with the river, it remains attached to same bank as the outfall. The results indicate the summer and winter limits will be met at a distance of 134 feet and 97 feet downstream, respectively. Because the conservative modeled summer and winter temperatures of 99°F and 88°F respectively support the ambient water quality standards, Duke should request these permit limitations be included in the NPDES permit. Because actual discharge temperatures will be less than the maximum permit limits, the actual instream plume will be smaller than the conservative model prediction results. Therefore, there is no need for Duke to bear the expense of complying with upstream and downstream temperature monitoring/limitations. iv Thermal Modeling Report - Dan River Steam Station 1 Introduction Water Environment Consultants (WEC) prepared this report for Duke to provide the results of a thermal modeling analysis at Duke's Dan River Combined Cycle Station (Dan River) in Eden, North Carolina (Figure 1-1). The coal-fired steam station has been retired and removed from the site, and a 620-MW combined cycle power plant was constructed in 2012. The current discharge from Outfall 001 is process water and cooling water from the combined cycle plant. A thermal mixing zone will be required to meet the discharge permit limitations issued by the North Carolina Department of Environmental Quality (NCDEQ). WEC performed mixing zone modeling to assess if the discharge will meet the 29°C maximum and 2.8°C rise -above -background requirements (15 NCAC 02B .0211 Fresh Water Quality Standards for Class C Waters) at an acceptable distance downstream. A description of the work performed by WEC to complete the assessment and the model results is provided in the following sections: • Section 2, NPDES Outfall 001- provides a brief description of the outfall; • Section 3, EFDC modeling - describes the field data collection methodology, model calibration, and 7010 modeling analysis and results. 1 Thermal Modeling Report - Dan River Steam Station Project Location Figure 1-1. Site Location Map 2 Thermal Modeling Report - Dan River Steam Station 2 NPDES Outfall 001 Per the current NPDES Permit (NC0003468), the Dan River Outfall 001 discharges cooling tower blowdown and plant collection sumps (low volume wastes) from the combined cycle unit directly to the Dan River via Outfall 001. WEC visited the Dan River site on August 13, 2019, to characterize the location and flow geometry at the discharge location. The Outfall 001 discharge pipe is along the dam wall on the northern (downstream) end of a short channel flowing into the Dan River (Figures 2-1 and 2-2). Water flowing from the outfall pipe lands within a rectangular, containment basin before spilling into the channel and slowly flowing into the Dan River. After mixing with the dam overflow, the discharge plume moves downstream within the Dan River. Figure 2-1. Location of Dan River Combined Cycle Steam Station Outfall 001 3 Thermal Modeling Report - Dan River Steam Station Figure 2-2. Photo of discharge pipe at Outfall 001 4 Thermal Modeling Report - Dan River Steam Station 3 EFDC Modeling This summary describes an application of the Environmental Fluid Dynamics Code (EFDC) for modeling the Outfall 001 discharge into the Dan River. The purpose of the model study is to estimate the mixing of the combined cycle wastewaters in the Dan River and determine if the discharge will meet the 29°C maximum and 2.8°C rise -above -background requirements (15 NCAC 02B .0211 Fresh Water Quality Standards for Class C Waters) at an acceptable distance downstream. This section describes: 1) the field data collected to support the model, 2) the model setup and calibration, 3) the application of the model under 7Q10 summer and winter conditions, and 4) model results that estimate where the NCDEQ water quality standards are met. 3.1 Field Data Collection Water depth and current measurements were collected to support the model study. Water depth data is required in order to create a two-dimensional grid for the EFDC model. Current velocity measurements are required for comparison to the modeled currents in order to verify that the model reasonably represents the hydrodynamics in the vicinity of the mixing zone. Together, detailed water depth and velocity data can be used to better select the ambient model geometry and the associated portion of the 7010 flow. Field data was collected on August 13, 2019. The study area extended from the discharge point to approximately 880 feet downstream the Dan River. Photos of the site from the day of data collection are shown in Figures 3-1 and 3-2. A Sontek RiverSurveyor-M9 Acoustic Doppler Current Profiler (ADCP) was used to collect both water depth and current velocity data. The Sontek M9 is equipped with a differential GPS to provide horizontal positioning data. Water surface elevation was also measured using a Trimble Geo 7x Centimeter Edition GPS with 0.1-foot accuracy. This data was used to convert the measured water depths to bottom elevations relative to a fixed vertical datum (i.e., NAVD88). The measured depths are shown in Figure 3-3 and the depth -averaged current velocities measured along transects are shown in Figure 3-4. 5 Thermal Modeling Report - Dan River Steam Station Figure 3-1. Photo of study area (outfall pipe is located at right as shown) 6 Thermal Modeling Report - Dan River Steam Station Figure 3-2. Photo study area (downstream of outfall) 7 Thermal Modeling Report - Dan River Steam Station Feet A 0 50 100 200 300 Legend Measured Depths (ft) 5.0 - 6.0 • 0.75-1.0 6.0-7.0 • 1.0 - 2.0 • 2.0 - 3.0 3.0 - 4.0 4.0 - 5.0 • 7.0 - 8.0 • 8.0 - 9.0 • 9.0 - 10.0 • 10.0 - 10.5 Figure 3-3. Measured depths on August 13, 2019 (aerial at higher flow condition) 8 Thermal Modeling Report - Dan River Steam Station Vector Magnitude • 1.36 - 1.2 1.0 • 0.6 - 0.6 - 0.4 0.2 0.0 Figure 3-4. Depth -averaged, measured velocities on August 13, 2019 (aerial at higher flow condition) 3.2 Model Setup and Calibration WEC created a two-dimensional model grid of the Dan River extending from the dam approximately 1,000 ft downstream (Figure 3-5). Certain areas were known to be dry during low flow conditions, which include several rock outcrops and a sandbar. These locations were noted as very shallow during the field data collection, when flows were higher, and later verified as dry with low -flow aerial imagery. Figure 3-5 uses this low -flow imagery where the dry areas are visible. Therefore, grid cells that overlapped these locations were inactivated in the model in order to redirect flow. The water depths measured with the ADCP were interpolated onto a grid, as shown in Figure 3-6. The grid was then edited to account for shallow areas along rock ledges and the shoreline, as described earlier. The water depths were converted to bottom elevations using the water surface elevations collected with the Trimble survey unit. The bottom elevations are referenced to NAVD88. The bathymetry grid was interpolated onto the EFDC grid for modeling as shown in Figure 3-7. The model boundary conditions included the upstream flow and the downstream water elevation. The upstream flow rate was determined from the ADCP measurements on the data collection day. The average flow measured across the ADCP transects was calculated as 716.9 cubic feet per second (cfs) and distributed across the upstream boundary along the 9 Thermal Modeling Report - Dan River Steam Station Figure 3-5. Model grid and flow barriers dam. Though US Geological Survey (USGS) gage 02071000, located approximately 13.0 miles upstream, reports flow during the field measurement day, several rivers and stream merge into the Dan River prior to the site, so the records could not be used. The downstream boundary was specified as an open boundary with a constant water elevation. The downstream water elevation was measured during field data collection as 479.3 ft NAVD88, roughly two feet lower than the water level just below of the dam. The EFDC model was iteratively calibrated to match the current velocities measured on the field collection day. Figure 3-8 and Figure 3-9 illustrate the modeled and measured current velocities in meters per second (mps). The arrows indicate flow directions and are scaled to a common magnitude. The modeled currents correlate with measured velocities. The measured data shows more local variation in currents, such as a singular, larger peak velocity just north of the first rock outcrop. The slightly lower peak modeled velocity, 1.0 mps, compared to the peak measured, 1.36 mps, is an artifact of the model bathymetry being smoother than the actual river bathymetry. However, when comparing areas on a whole, rather than a singular point, the velocities are much closer. 10 Thermal Modeling Report - Dan River Steam Station Feet A 0 50 100 200 300 Legend Model Depths (ft) 2.5 - 3.0 • 0.0-0.5 • 3.0-4.0 • 0.5 - 1.0 • 4.0 - 6.0 1.0-1.5 • 6.0-8.0 1.5-2.0 • 8.0-10.5 2.0 - 2.5 Figure 3-6. Depth grid Additionally, the model does well in estimating the flow paths, represented by the vector arrows, around shoals and rock ledges. Both the modeled and measured velocities show a peak acceleration of current along the northern (plant side) bank and part of the southern bank. On average, the model tends to under -estimate the velocity magnitude in the rocky shoals. As a result, the model will likely be conservative and under -estimate the amount of mixing and dispersion of the outfall effluent. Overall, the model reasonably represents the current velocities in the river and the model is sufficiently calibrated in this area for the purposes of evaluating the outfall discharge mixing zone. 11 Thermal Modeling Report - Dan River Steam Station Legend Grid Bathymetry II1471.5 - 472.0 M472.0 - 473.0 M473.0 - 474.0 I-1474.0 - 475.0 F 1475.0 - 476.0 0476.0 - 477.0 (ft NAVD88) =477.0 - 478.0 =478.0 - 479.0 1E1479.0 - 480 0 M480.0 - 481.0 M481.0 - 482.0 Figure 3-7. Model grid and bathymetry converted to feet relative to NAVD88 12 Thermal Modeling Report - Dan River Steam Station Figure 3-8. Calibrated model velocities and measured current velocities (upstream portion) 13 Thermal Modeling Report - Dan River Steam Station Figure 3-9. Calibrated model velocities and measured current velocities Measured Velocities 1.36 m/s 0.00 m/s downstream portion) 3.3 7Q10 Model Conditions The 7Q10 model is used to verify whether the thermal mixing zone meets the discharge permit limitations issued by NCDEQ. The NCDEQ water quality standard for temperature has two components: not to exceed 2.8°C (5.04°F) above natural background and not to exceed 29°C (84.2°F). Inputs to the calibrated EFDC model were modified to represent the critical 7Q10 conditions. Both summer and winter conditions were considered in the analysis. The critical condition modeled for the summer was the maximum temperature, and the critical condition modeled for the winter was the temperature exceedance over background conditions. The model was run under two conservative assumptions: maximum design discharge rate of 1.33 MGD and temperature dilution from mixing only (no evaporative losses). The inputs adjusted from the calibrated model included the summer and winter 7010 flow rates, the downstream water surface elevation, and the discharge's temperature excess as compared to the ambient temperature. The water surface elevation measured during field monitoring was lowered based on change in water depths at USGS station 02071000 associated with similar change in flow rates. Figure 3-10 shows the measured 14 Thermal Modeling Report - Dan River Steam Station 4 3.5 3 z. 2.5 c 2 "1/ 1.5 1 0.5 Stage vs. Flow Rate y =-2E-19x6 + 2 E-15x5 - SE-12x4 + 9E-09x3- 8E-06x2 + 0.0054x R2 = 0.9985 0 0 100 200 300 400 500 600 700 800 900 1000 Flow (cfs) • USGS data 7010 Summer • 7010 Winter • Calibration day Best Fit Eq. (USGS data) Figure 3-10. Flow -stage relationship at USGS station 02071000 depths and flow rate data points at the USGS station. Based on the best -fit equation of the data, and similar stream characteristics at both sites, WEC determined downstream water levels at the project site for the summer and winter 7Q10 conditions. Thermal mixing from the discharge was modeled using EFDC's dye tracer module, which simulates dilution from mixing only and excludes evaporative losses as mentioned above. WEC reviewed four years of ambient water temperature records near the outfall. The 95`h and 5' percentile temperatures were used as ambient conditions for the summer and winter critical conditions, respectively. During summer months, the 95`h percentile river temperature was 27.6°C (81.7°F). During winter months, the 5`h percentile temperature was 1.4°C (34.5°F). Duke provided WEC with estimates of the maximum projected effluent discharge temperatures for summer and winter months. The summer maximum temperature was 35.6°C (96°F) and the winter maximum temperature was 29.4°C (85°F). WEC added a 3°F compliance margin similar to the thermal models approved by NCDEQ for Duke's Rogers and Asheville sites. The temperature excess (above background) used for modeling the summer condition was 9.6°C (17.3°F), and the temperature excess for the winter condition was 29.7°C (53.5°F). Table 3-1 summarizes the inputs in SI units as used in EFDC. Table 3-1. 7Q10 model inputs 7Q10 flow rate (cms) Downstream WL (m NAVD88) Effluent flow rate (cms) Effluent Temperature Excess (°F) Summer 8.89 145.9 0.058 17.3 Winter 16.4 146.0 0.058 53.5 15 Thermal Modeling Report - Dan River Steam Station 3.4 Outfall 001 Mixing Zone Results and Proposed Permit Limits The model results for a 1.33 MGD discharge from Outfall 001 are shown in Figure 3-11. The colored contours represent the temperature excess above background in units of degrees Fahrenheit for summer and winter conditions. The downstream position where the water quality standard is met is marked with a magenta line. For the summer condition, this line marks where the 29°C (84.2°F) maximum temperature standard is met. For the winter results, the line marks where the discharge meets the 2.8°C (5.04°F) exceedance above background standard. As shown by the colored contours, the majority of the plume dilution takes place within the small channel where the effluent is initially contained. Downstream, the plume remains narrow and strongly bank attached where the water is deeper and the currents move faster. Near the boat ramp a small rock outcrop pushes the plume away from the bank where it begins to spread. However, the plume meets the summer and winter standards well prior to this point. The results for a 1.33 MGD discharge at 99°F show the plume will meet the maximum temperature standard (84.2°F) approximately 134 feet downstream of the dam. For a 1.33 MGD discharge at 88°F, the no -more -than 5.04°F exceedance above background standard will be met approximately 97 feet downstream. In addition, the very narrow plume widths also support safe passage of aquatic life. Because the conservative modeled summer and winter temperatures of 99°F and 88°F respectively support the ambient water quality standards, Duke should request these permit limitations be included in the NPDES permit. These discharge limitations should be measured at the current compliance point, noting that heat loss through the discharge pipe prior to entering the river should be minimal. Because actual discharge temperatures will be less than the maximum permit limits, the actual instream plume will be smaller than the conservative model prediction results. Therefore, there is no need for Duke to bear the expense of complying with upstream and downstream temperature monitoring/limitations. 16 Thermal Modeling Report - Dan River Steam Station N --.... Feet 0 75 150 225 300 v AMICEENCIMEN Feet 0 75 150 225 300 Legend Temperature Excess °F 0.0 -0.1 - 0.1 -1.0 - 1.0-2.0 2.0 -3.0 3.0 -4.0 - 4.0 -5.0 5.0-17.5 Legend Temperature Excess °F4.0 -5.0 0.0 -0.1 5.0 -10.0 - 0.1 -1.0 (1 10.0 - 20.0 - 1.0-2.0 20.0-30.0 - 2.0-3.0 - 30.0-40.0 - 3.0-4.0 - 40.0-54.0 Figure 3-10. 7Q10 model results for summer (top) and winter (bottom) conditions r`, 17 Thermal Modeling Report - Dan River Steam Station 4 References Martin, Joyce; D. H. Newcomb. "RE: Infor Needed - Future Summer & Winter Daily Max Permit Limits (for modeling)." Correspondence with Duke Energy. June 3, 2020. E-mail U.S. Geological Survey. 2020. National Water Information system. USGS 02071000 Dan River Near Wentworth, NC. Water Data for the Nation, accessed 2020 at https://wate rdata. usgs.gov/usa/nwis/uv?site_no=02071000 18 Clean Water Act § 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Eden, North Carolina NPDES Permit NC0003468 Duke Energy Environmental Services 1 Environmental Programs 526 South Church Street Charlotte NC 28202 May 2021 If DUKE .. ENERGY® 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Contents Executive Summary 1 1 Introduction 4 2 Source Water Physical Data [§122.21(r)(2)] 7 2.1 Description of Source Waterbody [§122.21(r)(2)(i)] 7 2.2 Characterization of Source Waterbody [§122.21(r)(2)(ii)] 8 2.2.1 Geomorphology 8 2.2.2 Hydrology 8 2.2.3 Water Quality 8 2.3 Locational Maps [§ 122.21(r)(2)(ii) 12 3 Cooling Water Intake Structure Data [§ 122.21(r)(3)] 13 3.1 Description of MWIS Configuration [§122.21(r)(3)(i)] 13 3.2 Latitude and Longitude of MWIS [§122.21(r)(3)(ii)] 17 3.3 Description of MWIS Operation [§122.21(r)(3)(iii)] 17 3.4 Description of Intake Flows [§122.21(r)(3)(iv)] 18 3.5 Engineering Drawings of CWIS [§122.21(r)(3)(v)] 18 4 Source Water Baseline Biological Characterization Data [§122.21(r)(4)] 19 4.1 List of Unavailable Biological Data [§122.21(r)(4)(i)] 20 4.2 List of Species and Relative Abundance in the vicinity of CWIS [§122.21(r)(4)(ii)] 20 4.2.1 Exotic Species 26 4.3 Primary Growth Period 26 4.3.1 Reproduction and Larval Recruitment 26 4.4 Species and Life Stages Susceptible to Impingement and Entrainment 32 4.4.1 Impingement 32 4.4.2 Entrainment 33 4.4.3 Selected Species 36 4.5 Threatened, Endangered, and Other Protected Species Susceptible to Impingement and Entrainment at the MWIS 39 4.6 Documentation of Consultation with Services 41 4.7 Incidental Take Exemption or Authorization from Services 41 4.8 Methods and Quality Assurance Procedures for Field Efforts 41 4.9 Fragile Species 41 5 Cooling Water System Data [§122.21(r)(5)(i)] 42 5.1 Description of Cooling Water System Operation [§122.21(r)(5)(i)] 42 5.1.1 Cooling Water System Operation 42 5.1.2 Proportion of Design Flow Used in the Cooling Water System 43 5.1.3 Cooling Water System Operation Characterization 44 5.1.4 Distribution of Water Reuse 45 5.1.5 Description of Reductions in Total Water Withdrawals 45 5.1.6 Description of Cooling Water Used in Manufacturing Process 46 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 5.1.7 Proportion of Source Waterbody Withdrawn 46 5.2 Design and Engineering Calculations [§122.21(r)(5)(ii)] 46 5.3 Description of Existing Impingement and Entrainment Reduction Measures [§122.21(r)(5)(iii)] 47 5.3.1 Best Technology Available for Entrainment 47 6 Chosen Method(s) of Compliance with Impingement Mortality Standard [§122.21(r)(6)] 49 7 Entrainment Performance Studies [§ 122.21(r)(7)] 51 7.1 Site -Specific Studies 51 7.2 Studies Conducted at Other Locations 51 8 Operational Status [§ 122.21(r)(8)] 52 8.1 Description of Operating Status [§ 122.21(r)(8)(i)] 52 8.1.1 Individual Unit Age 52 8.1.2 Utilization for Previous Five Years 52 8.1.3 Major Upgrades in Last Fifteen Years 53 8.2 Description of Consultation with Nuclear Regulatory Commission [§122.21(r)(8)(ii)] 53 8.3 Other Cooling Water Uses for Process Units [§122.21(r)(8)(iii)] 53 8.4 Description of Current and Future Production Schedules [§122.21(r)(8)(iv)] 53 8.5 Description of Plans or Schedules for New Units Planned within Five Years [§122.21(r)(8)(v)] 53 9 References 54 ii 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Tables Table 1-1. Facility and Flow Attributes and Permit Application Requirements 5 Table 1-2. Summary of §316(b) Rule for Existing Facilities Submittal Requirements for §122.21(r)(2)-(8). 6 Table 2-1. Annual Mean Concentration for Select Field and Analytical Parameters in the Vicinity of the DRCCS MWIS (Location B1). 10 Table 2-2. Turbidity at Location B1 and River Flows Recorded at the USGS Gauging Station - Dan River near Wentworth (02071000) and Smith River at Eden (02074000) 12 Table 3-1. DRCCS MWIS Monthly Total Withdrawals During 2016-2020 18 Table 4-1. 2015-2017 Environmental Monitoring Location on the Dan River 21 Table 4-2. Fish Species and Community Composition (%) for Transect B, Collected by Boat Electrofishing, 2015- 2017. 21 Table 4-3. Fish Species, Number Collected and Relative Abundance (fish/hour) for Transect B by Year from Boat Electrofishing, 2015-2017. (NC = No catch) 23 Table 4-4. Known Spawning and Recruitment Period of Fish Collected in the Vicinity of the DRCCS MWIS (Jenkins and Burkhead 1993; Rohde et al. 2009). [Lighter shade indicates the spawning window while the darker shading indicates the peak spawning period] 26 Table 4-5. Seasonal and Daily Activities of Species Collected in the Vicinity of the DRCCS MWIS (Jenkins and Burkhead 1994; Rohde et al. 2009). 27 Table 4-6. Entrainment Potential for Fish (Egg and Larvae) Species Present near the DRCCS MWIS. 33 Table 4-7. Summary of Rare, Threatened, or Endangered (RTE) Aquatic Species Listed for Rockingham County, North Carolina, and Record of Occurrence of Potential to Occur Near the DRCCS MWIS. 39 Table 4-8. List of Fragile Species as Defined by the EPA and Their Occurrence in the Vicinity of the DRCCS MWIS 41 Table 5-1. Percent Monthly Proportion of Design Flow Withdrawn at the DRCCS 44 Table 5-2. Comparison of DRSS and DRCCS 46 Table 5-3. DRCCS Percent of Source Waterbody (Dan River) Withdrawal 46 Table 5-4. MWIS TSV Calculations 47 Table 8-1. DRCCS Annual Capacity Factors, 2016-2020 53 iii 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Figures Figure 2-1. Map Showing the DRCCS MWIS in the Dan River Basin (Hydrologic Unit Code 03010103) 9 Figure 2-2. Duke Energy Dan River Long -Term Sampling Location in the Vicinity of the DRCCS MWIS 10 Figure 2-3. Dan River flows at the USGS Gauging Stations — Dan River near Wentworth (02071000) and Smith River at Eden (0207400) during 2015-2017. 11 Figure 3-1. DRCCS Water Balance Diagram 14 Figure 3-2. Plan View of MWIS at DRCCS 15 Figure 3-3. Section View of MWIS at DRCCS 16 Figure 3-4 Wedgewire Screen Design of DRCCS 17 Figure 4-1. Upstream and Downstream Designation of Transect B. 21 Figure 4-2. Aerial View of the MWIS and orientation within the Dan River 33 Figure 5-1. DRCCS Cooling Tower General Arrangement 43 Figure 5-2. Monthly Total MWIS Withdrawals at DRCCS 45 iv 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Appendices Appendix A. Dan River Combined Cycle Station § 122.21(r)(2)-(8) Submittal Requirement Checklist. Appendix B. Engineering Drawings of Makeup Water Intake Structure. Appendix C. Engineering Calculations for Through -Screen Velocity. v 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Abbreviations °C degrees Celsius °F degrees Fahrenheit µS/cm micro Siemens per centimeter AIF actual intake flow A01 area of influence BTA Best Technology Available CCC closed cycle cooling CFR Code of Federal Regulations cfs cubic feet per second cm centimeter COC cycles of concentration CWA Clean Water Act CWIS Cooling Water Intake Structure DIF design intake flow Director NPDES Director DO dissolved oxygen DRCCS Dan River Combined Cycle Station DRSS Dan River Steam Station Duke Energy Duke Energy Carolinas, LLC EPA United States Environmental Protection Agency ESA Endangered Species Act fps feet per second ft foot/feet ft msl feet above mean sea level gpm gallons per minute HRSG heat recovery steam generator HUC Hydrologic Unit Code IPaC Information for Planning Conservation IRP Integrated Resource Plan m meter µm micrometer µS/cm microsiemens per centimeter m3 cubic meters MDCT mechanical draft cooling tower MGD million gallons per day mg/L milligrams per liter mm millimeters MW megawatts MWIS Makeup Water Intake Structure NCDEQ North Carolina Department of Environmental Quality NCNHP North Carolina Natural Heritage Program NMFS National Marine Fisheries Service NPDES National Pollutant Discharge Elimination System NRDAR Natural Resource Damage Assessment and Restoration NTU Nephelometric Turbidity Units OTC once -through cooling QA Quality Assurance POA percent open area Rule Clean Water Act § 316(b) rule RTE rare, threatened, or endangered VI TL total length TSV through -screen velocity USEPA U.S. Environmental Protection Agency USFWS U.S. Fish and Wildlife Service USGS U.S. Geological Survey VII 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Executive Summary On August 15, 2014, regulations implementing §316(b) of the final Clean Water Act (CWA) rule for existing facilities (the Rule) were published in the Federal Register with an effective date of October 14, 2014. Facilities subject to the Rule are required to develop and submit technical material, in accordance with §122.21(r), that will be used by the National Pollutant Discharge Elimination System (NPDES) permit Director (Director) to make a Best Technology Available (BTA) determination for the facility. The Dan River Combined Cycle Station (DRCCS) began commercial operations in December 2012, replacing three coal-fired units which were subsequently demolished. The DRCCS is a single combined cycle unit, natural gas -fired electric generating facility with a current generating capacity of 718 MW. The DRCCS wastewater discharges are authorized by NPDES Permit NC0003468. Therefore, DRCCS is an existing facility and subject to the Rule. The §122.21(r) submittal material provided herein concludes that the DRCCS employs Best Technology Available (BTA) for impingement and entrainment reduction with currently installed closed -cycle cooling as described below and, as such, no further impingement or entrainment controls are warranted. Impingement BTA The final Rule, at §125.94(c), requires existing facilities to employ one of seven impingement BTA alternatives'. DRCCS is compliant for impingement because it employs two of these alternatives, any one of which would be wholly compliant for impingement: • Primary impingement BTA — Closed -cycle cooling with a mechanical draft cooling tower is utilized to provide makeup water which is consistent with a closed -cycle recirculating system (CCRS) defined at §125.92(c) and meets the BTA Standards for Impingement Mortality at §125.94(c)(1). • Secondary impingement BTA — Cooling tower makeup water intake structure employing cylindrical wedgewire screens with 3.2 mm (0.125") slots designed to have a maximum design through -slot velocity of Tess than 0.5 fps; thus meeting the BTA Standards for Impingement Mortality at §125.94(c)(2). Overall, impingement at the facility is expected to be near or zero due to the combination of low makeup flows to the cooling tower and makeup intake structure low (50.25 fps) through -slot velocity. There are no known federal or state listed species or designated critical habitats within the source waterbody (Dan River) in the vicinity of the DRCCS. As a result, potential adverse impacts due to impingement are not expected to occur. ' Or under specific circumstances one of nine alternatives, which includes §125.94(c)(11) and (12) in addition to §125.94(c)(1)-(7). 1 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Entrainment BTA The Rule does not prescribe BTA for entrainment; however, requires it to be determined on a site -specific basis. This submittal demonstrates that DRCCS meets BTA for entrainment based on the following: • The DRCCS uses closed -cycle cooling, which minimizes entrainment through flow reduction. During the 2016-2020 period, the DRCCS average withdrawal was 3.48 million gallons per day (MGD) which is substantially less than the 125 MGD value of concern technically justified by the Rule. The flow reduction achieved with consideration of the high -efficiency combined cycle facility, is calculated to be 98.8% as compared to an equivalent once -through cooling (OTC) facility based on design flow and 365 days per year operation. Using actual average Dan River makeup withdrawal, the equivalent flow reduction is calculated at 99.4% when compared to an equivalent OTC steam electric facility. In addition, the average flow is reduced 70.3 percent from the design potential flow of 11.88 MGD. • Statements made by the United States Environmental Protection Agency (EPA) in the preamble to the Rule support this conclusion: "Although this rule leaves the BTA entrainment determination to the Director, with the possible BTA decisions ranging from no additional controls to closed -cycle recirculating systems plus additional controls as warranted, EPA expects that the Director, in the site -specific permitting proceeding, will determine that facilities with properly operated closed -cycle recirculating systems do not require additional entrainment reduction control measures. "2 This conclusion is further reiterated in the Response to Public Comments document, where EPA states: "EPA has made it clear that a facility that uses a closed -cycle recirculating system, as defined in the rule, would meet the rule requirements for impingement mortality at § 125.94(c)(1). This rule language specifically identifies closed -cycle as a compliance alternative for the [impingement mortality] performance standards. EPA expects the Director would conclude that such a facility would not be subject to additional entrainment controls to meet BTA."3 • The final Rule for new facilities published in the Federal Register on December 18, 2001 which had an effective date of January 17, 2002, does prescribe BTA for entrainment'', which DRCCS meets. Regulations are more stringent for new facilities than for existing facilities. By virtue of meeting the most stringent entrainment BTA criteria (i.e., applicable to new facilities), DRCCS is compliant for entrainment BTA under the final Rule for existing facilities. 2 79 Fed. Reg. 48344 (15 August 2014) 3 Response to Comments, Essay 14, p. 62. 4 BTA for entrainment under the new facilities rule at 40 CFR §125.84(b) requires facilities with design intake flow equal to or greater than 10 MGD, and under Track 1, to employ closed -cycle recirculating cooling as well. 2 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Potential impacts to fish and shellfish populations due to entrainment are also extremely unlikely due to: • The use of closed cycle cooling via mechanical draft cooling towers; • Low actual and design water withdrawals; and • The operation and configuration of the intake which features cylindrical wedgewire screens with 3.2 mm slots, screen orientation parallel to the Dan River flow, screen submergence at least ten feet below the river elevation, and design through -slot velocity of 0.25 fps. The calculated through screen velocity (TSV) for the design intake flow (DIF) case is 0.15 fps and under actual intake flow (AIF) conditions is 0.07 fps. Based on the above facts, entrainment is reduced to the maximum extent warranted and additional control measures are not warranted nor necessary for the DRCCS. 3 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 1 Introduction Section 316(b) was enacted under the 1972 CWA, which also introduced the NPDES permit program. Certain facilities with NPDES permits are subject to §316(b) requirements, which require the location, design, construction, and capacity of the facility's cooling water intake structure (CWIS)5 to reflect BTA for minimizing potential adverse environmental impacts. On August 15, 2014, regulations implementing §316(b) of the CWA for existing facilities (Rule) were published in the Federal Register with an effective date of October 14, 2014. The Rule applies to existing facilities that withdraw more than 2 MGD from waters of the United States, use at least 25 percent of that water exclusively for cooling purposes, and have or require an NPDES permit. Facilities subject to the Rule are required to develop and submit technical material that will be used by the NPDES Director (Director) to make a Best Technology Available (BTA) determination for the facility. The actual intake flow (AIF)6 and design intake flow (DIF)7 at a facility determines which submittals will be required. As shown in Table 1-1, facilities with an AIF of 125 MGD or Tess have fewer application submittal requirements and will generally be required to select from the impingement compliance options contained in the final Rule. Facilities with an AIF in excess of 125 MGD are required to address both impingement and entrainment, and provide specific entrainment studies, which may involve extensive field studies and the analysis of alternative methods to reduce entrainment (§122.21(r)(9)- (13)). The §316(b) compliance schedule under the Rule is dependent on the facility's NPDES permit renewal date. Facilities are to submit their §316(b) application material to the Director with their next permit renewal application unless that permit renewal application is due prior to July 14, 2018, in which case an alternate schedule may be requested. 5 CWIS is defined as the total physical structure and any associated constructed waterways used to withdraw cooling water from Waters of the United States. The CWIS extends from the point at which water is first withdrawn from waters of the United States up to, and including, the intake pumps. 6 AIF is defined as the average volume of water withdrawn on an annual basis by the cooling intake structure over the past 3 years initially and past 5 years after Oct. 14, 2019. The calculation of AIF includes days of zero flow. AIF does not include flows associated with emergency and fire suppression capacity. ' DIF is defined as the value assigned during the CWIS design to the maximum instantaneous rate of flow of water the CWIS is capable of withdrawing from a source waterbody. The facility's DIF may be adjusted to reflect permanent changes to the maximum capabilities of the cooling water intake system to withdraw cooling water, including pumps permanently removed from service, flow limit devices, and physical limitations of the piping. DIF does not include values associated with emergency and fire suppression capacity or redundant pumps (i.e., back- up pumps). 4 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Table 1-1. Facility and Flow Attributes and Permit Application Requirements. Existing facility with DIF greater than 2 MGD and AIF greater than 125 MGD. Existing facility with DIF greater than 2 MGD and AIF Tess than 125 MGD. Existing facility with DIF of 2 MGD or less, or less than 25 percent of AIF used for cooling purposes. New units at existing facility. §122.21(r)(2)-(13) §122.21(r)(2)-(8) Director Best Professional Judgment §122.21(r)(2), (3), (5), (8), and (14) and applicable paragraphs (r)(4), (6), and (7) of §122.21(r) Duke Energy Carolinas, LLC's (Duke Energy) DRCCS is subject to the existing facility rule and, based on its current configuration and operation (i.e., the facility has a DIF greater than 2 MGD and an AIF of Tess than 125 MGD), Duke Energy is required to develop and submit each of the §122.21(r)(2)-(8) submittal requirements (Table 1-2) with its next permit renewal application in accordance with the facility NPDES operating permit and the Rule's technical and schedule requirements. Appendix A provides a checklist summary of the specific requirements under each of the §122.21(r)(2)-(8) submittal requirements and how each is addressed in this report or why it is not applicable to DRCCS. 5 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Table 1-2. Summary of §316(b) Rule for Existing Facilities Submittal Requirements for §122.21(r)(2)-(8). (2) Source Water Physical Data (3) Cooling Water Intake Structure Data (4) Source Water Baseline Biological Characterization Data (5) Cooling Water System Data (6) Chosen Method of Compliance with Impingement Mortality Standard (7) Entrainment Performance Studies (8) Operational Status Characterization of the source waterbody including intake area of influence. Characterization of the cooling water intake system; includes drawings and narrative; description of operation; water balance. Characterization of the biological community in the vicinity of the intake; life history summaries; susceptibility to impingement and entrainment; existing data; identification of missing data; threatened and endangered species and designated critical habitat summary for action area; identification of fragile fish and shellfish species list (<30 percent impingement survival). Narrative description of cooling water system and intake structure; proportion of design flow used; water reuse summary; proportion of source waterbody withdrawn (monthly); seasonal operation summary; existing impingement mortality and entrainment reduction measures; flow/megawatts (MW) efficiency. Provides facility's proposed approach to meet the impingement mortality requirement (chosen from seven available options); provides detailed study plan for monitoring compliance, if required by selected compliance option; addresses entrapment where required. Provides summary of relevant entrainment studies (latent mortality, technology efficacy); can be from the facility or elsewhere with justification; studies should not be more than 10 years old without justification; new studies are not required. Provides operational status for each unit; age and capacity utilization for the past 5 years; upgrades within last 15 years; uprates and Nuclear Regulatory Committee relicensing status for nuclear facilities; decommissioning and replacement plans; current and future operation as it relates to actual and design intake flow. 6 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 2 Source Water Physical Data [§122.21(r)(2)] The information required to be submitted per 40 Code of Federal Regulations (CFR) §122.21(r)(2), Source Water Physical Data, is as follows: (i) A narrative description and scaled drawings showing the physical configuration of all source water bodies used by your facility, including areal dimensions, depths, salinity and temperature regimes, and other documentation that supports your determination of the waterbody type where each cooling water intake structure is located; (ii) Identification and characterization of the source waterbody's hydrological and geomorphological features, as well as the methods you used to conduct any physical studies to determine your intake's area of influence within the waterbody and the results of such studies; (iii) Locational maps; and, (iv) For new offshore oil and gas facilities that are not fixed facilities, a narrative description and/or Locational maps providing information on predicted locations within the waterbody during the permit term in sufficient detail for the Director to determine the appropriateness of additional impingement requirements under §125.134(b)(4). Each of these requirements is described in the following subsections. 2.1 Description of Source Waterbody [§122.21(r)(2)(i)] The Dan River Makeup Water Intake Structure (MWIS) is located just upstream of a low head dam on the northern shore of the Dan River approximately 4.1 river kilometers downstream of the confluence of the Dan and Smith Rivers. The Dan River is located within the Roanoke River Basin, which includes watersheds in North Carolina and Virginia. The North Carolina portion of the Roanoke River Basin is 3,500 square miles and lies along the northern Piedmont region before terminating in the Albemarle Sound (NCDEQ 2020). The Dan River originates east of the Blue Ridge Parkway in Patrick County, Virginia, and flows south/southeast into North Carolina before joining the Smith River in Eden, NC. The Smith River also originates east of the Blue Ridge Parkway in Patrick County, Virginia. The Smith River flows northeast into Philpot Lake before turning south/southeast and flowing into North Carolina and joining the Dan River in Eden, NC. The North Carolina section of the Dan River is classified as Class C waters (Aquatic Life, Secondary Recreation, Freshwater) and Tr (Trout Waters) by the North Carolina Department of Environmental Quality (NCDEQ). Land uses along the upstream area of the river includes agricultural, forested, industrial, and residential (Duke Energy 2019). 7 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 2.2 Characterization of Source Waterbody [§122.21(r)(2)(ii)] To identify and characterize the primary source waterbody (i.e., the Dan River in the vicinity of the CWIS) the following resource was reviewed: Dan River Long -Term Environmental Monitoring Report (Duke Energy 2019) As a result of a pipe failure and subsequent ash release from the retired Dan River Steam Station (DRSS) ash pond into the Dan River on February 2, 2014, Duke Energy committed to conducting intensive monitoring of the river and the headwaters of Kerr Lake for three years (2015-2017) to assess potential environmental impacts as well as to support the Natural Resource Damage Assessment and Restoration (NRDAR) process. Select data from this report were compiled, synthesized, and are summarized below. 2.2.1 Geomorphology The Dan River is located within the Piedmont Level III ecoregion and, more specifically, the CWIS is located within the Triassic Basin (Level IV) of the Piedmont ecoregion. The Piedmont region is considered to be the non -mountainous portion of the old Appalachians Highland by physiographers, the northeast -southwest trending Piedmont ecoregion comprises a transitional area between the mostly mountainous ecological regions of the Appalachians to the northwest and the relatively flat coastal plain to the southeast. It is an erosional terrain of moderately dissected irregular plains with some hills, with a complex mosaic of Precambrian and Paleozoic metamorphic and igneous rocks. Most rocks of the Piedmont are covered by a thick mantle of saprolite, except along some major stream valley bluffs and on a few scattered granitic domes and flat rocks. The Triassic Basin extends from Virginia, across North Carolina, and just slightly into South Carolina. The Triassic Basins within North Carolina occurs in four narrow bands and have unusual Piedmont geology of un-metamorphosed shales, sandstones, mudstones, siltstones, and conglomerates. Local relief and elevations are often less than the surrounding regions, and with rocks that are easier to erode, stream valleys that cross the region tend to widen. Soils are often clayey with low permeability, and streams have low base flows (Griffith et al. 2002). 2.2.2 Hydrology Within North Carolina, the Roanoke River Basin is divided into five U.S. Geological Survey (USGS) hydrologic units, each designated by Hydrologic Unit Code (HUC). The CWIS is located in the Cascade Creek -Dan River (0301010309) portion of the Dan River HUC 03010103 (Figure 2-1). This section of the river encompasses an area of 61.9 miles with 167.7 miles of stream. Land use within this section of the basin is predominantly forested area followed by agriculture and non -forested stream buffer (NCDEQ 2018). 2.2.3 Water Quality As a component of the Dan River Natural Resources Damage assessment, Duke Energy collected a wide range of water quality data from multiple sampling locations along the Dan River (Duke Energy 2019). Sample data collected from location B1, which is in the vicinity of the CWIS, from 2015 — 2017 (Figure 2- 2) was used to characterize water quality. The sampling program included bi-monthly collection of field parameters and analytical samples from the surface throughout the Dan River system (Duke Energy 8 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 2019). For the purposes of this report, the analytical parameter list has been reduced. Additional analyte data can be found in the Dan River Long -Term Monitoring Report (Duke Energy 2019). =pond Dan Raw 6 Hydraloyo Una stab Boundaries 10 Digit Hydrologic Units Q9tnq Boundaries ® 0301010301 LNe Dan Rww-0an Rw« n CoontyBeundari.s N s 0301010302 Town ForkCrak • Don Riot Catania) Cyob 9t 0301010303 Balms Laka-0an P u ® 030101030t Maio AN or 1111 0301010305 MaMmorty Croak -Dan Ram \ 'a.. 0301010306 Uppet Smith River ow - 0301010307 Middb Smith Rn N 0301010308 Loww Smelt Row 0 5 10 0301010309 Cascade Cr.ek-0an Row Miles Ill0301010310 Sandy Raw Franklin Virginia Floyd Figure 2-1. Map Showing the DRCCS MWIS in the Dan River Basin (Hydrologic Unit Code 03010103). 9 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Dan River Sampling Location (B1) Figure 2-2. Duke Energy Dan River Long -Term Sampling Location in the Vicinity of the DRCCS MWIS. Table 2-1. Annual Mean Concentration for Select Field and Analytical Parameters in the Vicinity of the DRCCS MWIS (Location B1). Parameter 2015 2016 2017 Dissolved oxygen (mg/L) A 9.6 9.6 9.3 pH A 7.1 7.3 7.4 Water Temperature (°C) A 15.6 15.9 17.6 Specific Conductance (µS/cm) A 115 103 103 Turbidity (NTU) A 23.0 95.7 14.5 Total dissolved solids (mg/L) B 91.5 _ 74.4 69.3 Ammonia-N (mg/L) B 0.049 0.013 0.015 Nitrate + nitrite-N (mg/L) B 0.14 0.17 0.18 Total nitrogen (mg/L) B 0.38 1.50 0.26 Total phosphorus (mg/L) B 0.0455 0.2007 0.022 _Total organic carbon (mg/L) B 3.6 4.1 1.7 Calcium (g/ )m LB 9.2 9.6 8.4 Chloride (mg/L) B 15.3 15.4 11.4 Magnesium (mg/L)B 3.5 3.5 2.9 Sodium (mg/L) B < 5.0 < 5.0 5.1 Sulfate (mg/L) B 6.0 6.1 5.0 Total alkalinity (mg/Las CaCO3) B 18.7 19.4 23.6 10 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Hardness (mg equiv. CaCO3/L) B 37.0 38.0 33.1 River Flow (cfs)` 931 980 833 AField parameter. BAnalytical parameter. cRiver flow was calculated by combining the flow from the Dan River at Wentworth gauge (02071000) with the Smith River gauge (02074000). Mean annual concentrations of select water quality parameters within the Dan River near the CWIS appeared to be consistent from 2015 — 2017 except for turbidity. For most parameters, the highest annual mean concentration occurred during 2016. This could potentially be attributed to the multiple high flow events that occurred during the late part of 2015 and lasting though early-2017 (Figure 2-3). 30000 25000 Zs- 20000 u 2 15000 LL it 10000 5000 0 ti�1y ti6yy lac a� �eQ lac ak ,�eQ lac as yeQ ti� ti`s ��111�+ti..i%4hr.r.Mea�il+�w�i �N�Yw1�.1i�o.delrwiq� Date Dan River (02071000) — Smith River (02074000) Figure 2-3. Dan River flows at the USGS Gauging Stations — Dan River near Wentworth (02071000) and Smith River at Eden (0207400) during 2015-2017. Turbidity had the greatest degree of variability. Annual means ranged from 14.5 in 2017 to 95.7 in 2016. One sampling event in 2016 (May 3) resulted in a turbidity value of 521 NTU. Turbidity was also high at other sampling locations upstream and downstream of B1 during this sampling event (Duke 2019). The high turbidity could be linked to the increase in river flow (Figure 2-3 and Table 2-2), land use (NCDEQ 2018), and the flashy nature of the Dan River 11 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Table 2-2. Turbidity at Location B1 and River Flows Recorded at the USGS Gauging Station — Dan River near Wentworth (02071000) and Smith River at Eden (02074000). Sample Collection Date Dan River Flow Smith River Flow and Time Turbidity (NTU) (cfs) (cfs) 01/26/2015 —16:30 21 938 657 03/04/2015 — 14:30 9.0 888 273 05/07/2015 — 11:30 10 772 860 07/27/2015 — 14:30 6.0 330 219 09/22/2015 — 09:15 14 242 207 11/03/2015 — 11:00 79 3,190 1,560 01/05/2016 — 15:50 14 1,480 1,040 03/21/2016 —16:45 8.3 1,420 500 05/03/2016 —16:15 521 12,800 1,880 07/12/2016 — 11:00 18 651 505 09/06/2016 — 14:15 9.8 476 388 11/08/2016 —14:35 3.3 384 115 01/16/2017 —13:00 4.8 563 346 03/21/2017 —11:40 2.8 559 158 05/03/2017 — 13:00 47 1,610 1,090 07/17/2017 — 14:07 7.4 577 382 09/05/2017 —10:36 11 445 315 2.3 Locational Maps [§ 122.21(r)(2)(ii) An aerial photograph of the DRCCS and its environs is provided on Figure 2-2 (Section 2.2.3). 12 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 3 Cooling Water Intake Structure Data [§ 122.21(r)(3)] The information required to be submitted per 40 CFR §122.21(r)(3), Cooling Water Intake Structure Data, is outlined as follows: (i) A narrative description of the configuration of each of the cooling water intake structures and where it is located in the waterbody and in the water column; (ii) Latitude and longitude in degrees, minutes, and seconds for each of the cooling water intake structures; (iii) A narrative description of the operation of each of the cooling water intake structures, including design intake flows, daily hours of operation, number of days of the year in operation and seasonal changes, if applicable; (iv) A flow distribution and water balance diagram that includes all sources of water to the facility, recirculating flows, and discharges; and (v) Engineering drawings of the cooling water intake structure. Each of these requirements is described in the following subsections. 3.1 Description of MWIS Configuration [§122.21(r)(3)(i)] Cooling tower makeup water for DRCCS is withdrawn from Dan River via the existing DRSS MWIS. The former DRSS was retired in 2012 and the existing CWIS was retrofitted with three 30-inch-diameter wedgewire screen units with the screen face oriented parallel to the direction of the river flow. Pumped raw water is routed to a clarifier for treatment prior to use by the station. Approximately 94 percent of the treated water from the clarifier is used for cooling tower makeup water (see Figure 3-1 for the water balance diagram). The remaining filtered water is stored in the fire water/service water tank for use as fire protection water, makeup water for the combined cycle unit heat recovery steam generator (HRSG), and/or various other plant functions. The raw water intake system at the DRCCS consists of three wedgewire screens, three submersible intake pumps, and piping retrofitted into the existing DRSS CWIS. Makeup water is withdrawn from Dan River via the three submerged, cylindrical wedgewire screens located along the north bank of Dan River. The wedgewire screen array is located in the flowing section of the river channel just beyond the end of the intake structure wingwall as shown on Figure 3-2. The riverbed elevation in this area is approximately 482.5 feet above mean sea level (ft msl) and the centerline of the cylindrical wedgewire screens is at 487.25 ft msl. The bottom of the screens is at 486.0 ft msl, or approximately 3.5 ft above the riverbed. The top of the screens is at 488.5 ft msl, which is 1.5 ft below the crest of the low -head diversion dam located immediately downstream from the intake structure. It is assumed that the crest elevation of the low -head dam (490 ft msl) represents the minimum water elevation. As a result, the minimum depth at the wedgewire screen array is approximately 7.5 ft. Figure 3-3 provides relevant MWIS elevation data. 13 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Each wedgewire screen unit is 30 inches in diameter and 91.5 inches in total length with 31 inches in screen length on either side of a 24-inch-diameter flange. Each screen has a manufacturer design capacity of 2,500 gallons per minute (gpm) (3.6 MGD) and has 3.2-millimeter (mm) slot openings with 68.7 percent open area (POA). As directed by plant staff, an air sparging system may be operated to remove any accumulated trash and debris. Figure 3-4 provides the wedgewire screen design details. The three wedgewire screens are connected to a common 24-inch-diameter header pipe, which in turn is connected to an 82-foot-long feed pipe that runs across the length of the forebay before it bends at a 90-degree angle and is connected to the three submersible raw water intake pumps located within the reinforced concrete intake structure. The cooling water piping configuration is shown on Figures 3-2 and 3-3. Each of the three raw water intake pumps is rated at 3.6 MGD, however, only two pumps are operated at the same time with one pump remaining as a spare for redundancy. Therefore, the maximum pump capacity (or DIF) of the raw water intake pumps is 7.2 MGD. 10. (OMOWII MOUPI -11111I.IlMOM. H I4F1F S»»'Icon � f1 fltmNt 4- • Fn �rwlxln ,r SU...1 MIAMI WI BED OHM ry • . im YARLF p OAR • MCAT • rmyVISIDA orJt'.(t 1/ Fawn COMPIIVOCYCLI Figure 3-1. DRCCS Water Balance Diagram 14 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION • kialierrY T m 0.i STATION COMMA] ER ewlY A.n MOTEIN%N FY STA M IMMO FOO MIMOYM IOOv L./In Figure 3-2. Plan View of MWIS at the DRCCS 15 Figure 3-3. Section View of MWIS at the DRCCS 16 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 0 25' 45.75' 91.50' O.A.L. 31.00' SCREEN LENGTH 2 PLACES 1 8.37" t- 22.76'-•1 1111111111111111111111111111 111, O O'11111111111111111111111111111 III 111111 1111111111111111111 1 II 111111111111111111111111111111111 1111111111I11111LIP' '1110 11111IIIIIIIIIIIIIIIIIIIIIIIIII 11111 111111111111 1' 1■ _ 111111111111111 111111111111 111 Lt 1111111111I1111111 1■ �� 11111 1111111111111111111111 1111 11111111111111111 111._ _ a 111 s �.11111 11111111 1111111111111111; 11111111 1111 111 111/1111 1 1111 11111 111111111 111111111111 111 11111111111111111111111111 1 I1110 01111111 1111111111111111111111 III NOT TO SCALE Source: Johnson Screens, Drawing #16448-2 (2013) 0.25" 29.94' Nom Screen Dia. 2 Places 24.00' 0 NOTE: 1) Capacity 2,500 GPM 0.25 fVsec Maximum Through -Slot Velocity 2) Designed for 10 ft Depth 3) Screen Open Area = 63.78 % Total Screen Area = 5,044 in2 Total Screen Open Area = 3,500 in2 Figure 3-4. Wedgewire Screen Design of DRCCS 3.2 Latitude and Longitude of MWIS [§122.21(r)(3)(ii)] The latitude and longitude (in degrees, minutes, and seconds) of DRCCS's MWIS is: • Latitude: 36° 29' 08" N • Longitude: 79° 43' 16" W 3.3 Description of MWIS Operation [§122.21(r)(3)(iii)] Withdrawal from the Dan River is dependent on makeup water demand, maximum pump capacity, and water loss due to evaporation and system losses. Because makeup water demand is directly related to the operation of generating units and in turn, the cooling water system, DRCCS MWIS operation generally follows a base load pattern. Operation of the MWIS is nearly continuous with at least one pump withdrawing water from the Dan River. During the 2016-2019 period, the MWIS operated an average of 21.8 hours each day with one or two pumps withdrawing water. 17 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 3.4 Description of Intake Flows [§122.21(r)(3)(iv)] Monthly average water withdrawals during the 2016-2020 period are provided in Table 3-1. The average withdrawal for this period was 3.2 MGD compared to a DIF of 7.2 MGD. Table 3-1. DRCCS MWIS Monthly Total Withdrawals During 2016-2020. Month 2016 2017 2018 2019 2020 January 95.79 96.83 100.28 111.07 100.20 February 91.63 98.26 100.98 105.75 98.54 March 99.38 110.93 114.96 121.88 111.20 April 100.15 50.85 85.53 94.50 62.32 May 74.19 106.13 125.71 136.78 98.45 June 110.48 121.68 117.73 132.60 119.19 July 121.44 130.41 143.88 150.94 138.65 August 120.38 131.39 141.57 153.14 123.52 September 117.84 118.03 87.28 137.09 106.99 October 85.79 95.70 104.65 82.50 109.35 November 114.84 115.83 117.74 3.88 91.54 December 91.21 105.13 103.16 78.13 42.58 Annual 3.34 3.51 3.68 3.58 3.29 Average Units = MG for monthly total, MGD for annual average 3.5 Engineering Drawings of CWIS [§122.21(r)(3)(v)] The following engineering drawings of cooling water intake structures are provided in Appendix B: • Drawing D000830221: Raw Water Intake Screen Downstream Screen T30" HC-24" PS Intake Screen Assembly w/ 3" ABW Connection • Drawing DNROC-GA-M-IS.DS.EN-01: Duke Energy Dan River Combined Cycle Station Raw Water Supply and Wastewater Discharge, Screen and Pump Station Plan • Drawing DNROC-PY-M-IS.DS.EV-01: Duke Energy Dan River Combined Cycle Station Raw Water Supply and Wastewater Discharge, Pump Station and Screen Elevation 18 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 4 Source Water Baseline Biological Characterization Data [§122.21(r)(4)) The information required to be submitted per 40 CFR §122.21(r)(4), Source Water Baseline Biological Characterization, is outlined as follows: (i) A list of the data supplied in paragraphs (r)(4)(ii) through (vi) of this section that are not available and efforts made to identify sources of the data; (ii) A list of species (or relevant taxa) for all life stages and their relative abundance in the vicinity of CWIS; (iii) Identification of the species and life stages that would be most susceptible to impingement and entrainment; (iv) Identification and evaluation of the primary period of reproduction, larval recruitment, and period of peak abundance for relevant taxa; (v) Data representative of the seasonal and daily activities of biological organisms in the vicinity of CWIS; (vi) Identification of all threatened, endangered, and other protected species that might be susceptible to impingement and entrainment at a cooling water intake structure(s); (vii) Documentation of any public participation of consultation with Federal or State agencies undertaken in development of the plan; (viii) Methods and QA procedures for any field efforts; (ix) In the case of the owner or operator of an existing facility or new unit at an existing facility, the Source Water Baseline Biological Characterization Data is the information included in (i) through (xii); (x) Identification of protective measures and stabilization activities that have been implemented, and a description of how these measures and activities affected the baseline water condition in the vicinity of CWIS; (xi) List of fragile species as defined at 40 CFR 125.92(m) at the facility; and (xii) Information submitted to obtain incidental take exemption or authorization for its cooling water intake structure(s) from the U.S. Fish and Wildlife Service or the National Marine Fisheries Service. Each of these requirements is described in the following subsections. 19 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 4.1 List of Unavailable Biological Data [§122.21(r)(4)(i)] The biological data needed to prepare the information required under 40 CFR §122.21(r)(4) are available. The historical data reviewed to develop the baseline biological characterization of the source waterbody, Dan River includes the following: • Dan River Long —Term Environmental Monitoring Report (Duke Energy 2019) These data were compiled and analyzed for this report and are summarized below. This report was developed utilizing the relevant existing data for the Dan River. No impingement or entrainment studies were performed in support of the development of this compliance documentation. 4.2 List of Species and Relative Abundance in the vicinity of CWIS [§122.21(r)(4)(ii)] For the purposes of this report, the monitoring location nearest to the CWIS (Transect B — lower end of the sampling area was located approximately 2.75 rkm upstream of the CWIS) was used to describe the fish community. Boat electrofishing was conducted four times (seasonally) each year during daylight hours on the Dan River during the study period (Figure 4-1, Table 4-1). Transect B was designated by an upstream beginning and downstream ending stretching from bank to bank and divided into two stations, one on each bank. The sampling stations were further divided into three replicates each consisting of 200-300 m distances (depending on the size of the reach) for a total of six replicates. Each station was sampled using a Smith Root equipped, Wisconsin design electrofishing boat with pulsed DC current. In the river, the station replicates were generally staggered in an alternating fashion from one bank to the other to minimize recapture of released fish. During the mid -summer sampling periods (July or August), four three -wing fyke nets were deployed annually during the summer sampling period to ensure that the fish community was adequately sampled. The nets were set for two consecutive days and fished at approximately 24-hour intervals. Collected fish were identified to the species level when possible using regional taxonomic references (Menhinick 1993, Jenkins and Burkhead 1994), measured for total length (TL) to the nearest millimeter, and weighed to the nearest gram. Fish that could not be accurately identified in the field were preserved with 10 percent buffered formalin solution and transported to the laboratory for identification and body measurements. Each specimen was examined for hybridization, anomalies, disease, parasites, and general condition. Photographs were also taken of fish with any deformity or anomaly. Some specimens were retained in 70 percent ethanol for identification in the laboratory. 20 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Table 4-1. 2015-2017 Environmental Monitoring Location on the Dan River. Transect Designation B (Leaksville access ramp, Leaksville, NC) Description Fault Basin Physiographic Province. Deeper and slower location due to low head dam located approximately 2.7 kilometers downstream of the lower crossing of transect. Latitude (North) Longitude (West) Upstream: 36.486000 Upstream: -79.761440 Downstream: 36.471399 Downstream: -79.743094 Figure 4-1. Upstream and Downstream Designation of Transect B. Transect B Upstream Lat. 36.486000 10ng.-79.761440 Transect B Downstream Lat. 36 471399 Long.-79.743094 In total 3,564 fish, representing 39 species (excluding hybrids and unidentified individuals), were collected at Transect B on the Dan River from 2015 to 2017. Species composition was typical for this ecoregion and habitat type. Dominant species included Redbreast Sunfish (26.1%), Golden Redhorse (24.7%), V-Lip Redhorse (11.0%) White Shiner (6.3%), Comely Shiner (6.2%), Bluegill (4.3%), Largemouth Bass (2.9%), Bull Chub (2.2%), and Snail Bullhead (2.1%) (Table 4-2). The fish community composition for each sample year (2015, 2016, and 2017) was similar. Annual mean catch rate (fish/hour) was slightly variable for the dominant species (Table 4-3). Table 4-2. Fish Species and Community Composition (%) for Transect B, Collected by Boat Electrofishing, 2015- 2017. Scientific Name Common Name Total Fish Collected Total Composition Ambloplites cavifrons Roanoke Bass 15 0.4 A. rupestris Rock Bass 1 0.0 Ameiurus brunneus Snail Bullhead 75 2.1 A. platycephalus Flat Bullhead 24 0.7 Carpiodes cyprinus Quillback 37 1.0 Catostomus commersonii White Sucker 45 1.3 Cyprinella analostana Satinfin Shiner 26 0.7 21 C. lutrensis Cyprinus carpio Etheostoma vitreum Hypentelium nigricans H. roanokense Ictalurus furcatus 1. punctatus Lepomis auritus L. cyanellus L. gulosus L. macrochirus L. microlophus Luxilus albeolus L. cerasinus Lythrurus ardens Micropterus dolomieu Micropterus salmoides Moxostoma. cervinum M. collapsum M. erythrurum M. pappillosum Nocomis. leptocephal us N. raneyi Notemigonus crysoleucas Notropis amoenus N. hudsonius N. procne Noturus insignis Percina nevisense Pomoxis annularis P. nigromaculatus Pylodictis olivaris Red Shiner Common Carp Glassy Darter Northern Hog Sucker Roanoke Hogsucker Blue Catfish Channel Catfish Redbreast Sunfish Green Sunfish Warmouth Bluegill Redear Sunfish White Shiner Crescent Shiner Rosefin Shiner Smallmouth Bass Largemouth Bass Blacktip Jumprock Notchlip Redhorse Golden Redhorse V-Lip Redhorse Bluehead Chub Bull Chub Golden Shiner Comely Shiner Spottail Shiner Swallowtail Shiner Margined Madtom Chainback Darter White Crappie Black Crappie Flathead Catfish 22 6 9 3 32 2 1 27 929 12 2 153 62 226 1 50 37 102 4 29 879 393 28 78 221 35 4 5 3 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 0.2 0.3 0.1 0.9 0.1 0.03 0.8 26.1 0.3 0.1 4.3 1.7 6.3 0.03 1.4 1.0 2.9 0.1 0.8 24.7 11.0 0.8 2.2 0.03 6.2 1.0 0.1 0.1 0.1 0.03 4 0.1 2 0.1 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Table 4-3. Fish Species, Number Collected and Relative Abundance (fish/hour) for Transect B by Year from Boat Electrofishing, 2015-2017. (NC = No catch) Scientific Name Common Name Ambloplites Roanoke Bass cavifrons Quantity 2 2015 2016 2017 Composition Fish/Hr Quantity Composition Fish/Hr Quantity Composition Fish/Hr (%) (/u) (/u) 0.16 0.18 6 0.56 1.09 7 0.56 1.13 A. rupestris Rock Bass 1 0.08 0.18 NC NC Ameiurus brunneus Snail Bullhead 29 2.33 1.60 23 2.15 0.73 23 1.85 1.29 A. platycephalus Flat Bullhead 5 0.40 0.89 11 1.03 1.27 8 0.64 1.29 Carpiodes cyprinus Quillback 6 0.48 1.07 22 2.05 2.18 9 0.72 1.45 Catostomus White Sucker 9 0.72 1.60 22 2.05 4.00 14 1.13 2.25 commersonii Cyprinella Satinfin Shiner 16 1.28 2.85 4 0.37 0.73 6 0.48 0.97 analostana C. lutrensis Red Shiner NC 6 0.56 1.09 NC Cyprinus carpio Common Carp NC 3 0.28 0.55 6 0.48 0.97 Etheostoma Glassy Darter 3 0.24 0.53 NC NC vitreum Hypentelium Northern Hog 15 1.20 2.67 6 0.56 1.09 11 0.88 1.77 nigricans Sucker H. roanokense Roanoke NC NC 2 0.16 0.32 Hogsucker lctalurus furcatus Blue Catfish NC NC 1 0.08 0.16 1. punctatus Channel NC 5 0.47 0.73 22 1.77 0.48 Catfish Lepomis auritus Redbreast 321 25.76 57.15 269 25.12 48.91 339 27.25 54.53 Sunfish L. cyanellus Green Sunfish 10 0.80 1.78 NC 2 0.16 0.32 L. gulosus Warmouth NC 1 0.09 0.18 1 0.08 0.16 L. macrochirus Bluegill 15 1.20 2.67 36 3.36 6.55 102 8.20 16.41 23 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION L. microlophus Redear 4 0.32 0.71 24 2.24 4.36 34 2.73 5.47 Sunfish Luxilus albeolus White Shiner 120 9.63 21.36 88 8.22 16.00 18 1.45 2.90 L. cerasinus Crescent NC NC 1 0.08 0.16 Shiner Lythrurus ardens Rosefin Shiner 21 1.69 3.74 25 2.33 4.55 4 0.32 0.64 Micropterus Smallmouth 19 1.52 3.38 10 0.93 1.82 8 0.64 1.13 dolomieu Bass M. salmoides Largemouth 39 3.13 6.94 24 2.24 4.36 39 3.14 6.27 Bass Moxostoma Blacktip 2 0.16 0.36 NC 2 0.16 0.32 cervinum Jumprock M. collapsum Notchlip NC 26 2.43 4.73 3 0.24 0.32 Redhorse M. erythrurum Golden 289 23.19 50.39 213 19.89 38.00 377 30.31 60.32 Redhorse M. pappillosum V-Lip 184 14.77 32.76 83 7.75 15.09 126 10.13 20.11 Redhorse Nocomis Bluhead Cub 16 1.28 2.85 12 1.12- 2.18 NC leptocephalus N. raneyi Bull Chub 28 2.25 4.99 11 1.03 2.00 39 3.14 6.27 Notemigonus Golden Shiner NC NC 1 0.08 0.16 crysoleucas Notropis amoenus Comely Shiner 57 4.57 10.15 126 11.76 22.91 38 3.05 6.11 N. hudsonius Spottail 29 2.33 5.16 6 0.56 1.09 NC Shiner N. procne Swallowtail 1 0.08 0.18 3 0.28 0.55 NC Shiner Noturus insignis Margined NC 3 0.28 0.55 2 0.16 0.32 Madtom 24 Percina nevisense Chainback Darter 3 0.24 0.53 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION NC NC Pomoxis annularis White Crappie NC 1 0.09 0.18 NC P. nigromaculatus Black Crappie 2 0.16 0.36 2 0.19 0.36 NC Pylodictis olivaris Flathead 1 0.08 0.18 NC 1 0.08 0.16 Catfish 25 Roanoke Bass' Rock Bass Snail Bullhead Flat Bullhead Quillback White Sucker 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 4.2.1 Exotic Species Common Carp (Cyprinus carpio) was the only Exotic Species (USGS 2020) collected during the study period and only represented 0.3% of the individuals collected. 4.3 Primary Growth Period Fish are cold blooded, thus primary growth occurs when water temperatures are 10°C or above. The conventional view on seasonal variation in fish growth in North America is that growth is fastest in the spring and early summer, slows in the late summer and fall, and virtually stops in the winter (Gebhart and Summerfelt 1978). The majority of fishes will have their highest densities shortly after the hatch occurs when larvae are concentrated, and natural mortality has not yet reduced numbers. Feeding competition is especially important during late spring through early summer when the bulk of fish are in their early life stages. During this time, they are more susceptible to starvation (May 1974). This is a critical stage in development, where larval fish have a short time period to initiate exogenous feeding before starving (Ehrlich 1974; Miller et al. 1988). 4.3.1 Reproduction and Larval Recruitment Spawning and recruitment details for fish species collected near the Dan River CWIS are described in detail in Table 4-4 and 4-5. Most of the fish species collected prefer a spring — early summer spawning period. During this time period, egg and larval fish in the vicinity of the Dan River CWIS are most susceptible to entrainment. Table 4-4. Known Spawning and Recruitment Period of Fish Collected in the Vicinity of the DRCCS MWIS (Jenkins and Burkhead 1993; Rohde et al. 2009). [Lighter shade indicates the spawning window while the darker shading indicates the peak spawning period] Common Name Jan Feb Mar Apr May Jun a Jul Aug Sep Oct Nov Dec f- Satinfin Shiner Red Shiner2 Common Carp Glassy Darter Northern Hogsucker Roanoke Hogsucker3 Blue Catfish Channel Catfish Green Sunfish Warmouth Bluegill 26 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Redbreast Sunfish fi_9 Redear Sunfish White Shiner Crescent Shiner Rosefin Shiner Smallmouth Bass Largemouth Bass Blacktip Jumprock Notchlip Redhorse 111111111111 Golden Redhorse V-Lip Redhorse Bluehead Chub Bull Chub Golden Shiner Comely Shiner Spottail Shiner Swallowtail Shiner Margined Madtom Chainback Darter White Crappie Black Crappie Flathead Catfish 'Due to the lack of field spawning observations (Jenkins and Burkhead period was uses as a surrogate. 2 https://nas.er.usgs.gov/queries/FactSheet.aspx?specieslD=518 'Due to the lack of field spawning observations (Jenkins and Burkhead spawning period was uses as a surrogate. 1993), the Rock Bass (Ambloplites rupestris) spawning , 1993), the Northern Hogsucker (Hypentelium nigricans) Table 4-5. Seasonal and Daily Activities of Species Collected in the Vicinity of the DRCCS MWIS (Jenkins and Burkhead 1994; Rohde et al. 2009). Species (Common Name) Roanoke Bass Seasonal Activities (Spawning) Natural spawning in streams has not been observed. In hatcheries, spawning occurs when temperatures are between 20-22°C. Males construct circular nest in clay and gravel near banks. After spawning, males guard the nest and attend to the larvae. Fecundity ranges from 3,000 —11,500 mature (or maturing) ova. Daily Activities (Feeding and Habitat) Inhabits firm substrate among boulders and bedrock in moderate to swift current. Young eat small crustaceans and insects. Juveniles and adults prey on fishes, insects and particularly crayfishes. 27 Rock Bass Snail Bullhead Flat Bullhead Quillback White Sucker Satinfin Shiner Red Shiner Common Carp Spawning occurs between April and July when temperatures are between 15.6 — 26°C. Males fan out circular nests in the shallows having coarse sand to large gravel substrate. Males defend the nest against intruders. Fecundity ranges from 2,000 —11,000, with the average around 5,000 eggs. Spawning occurs from May thru July starting at temperatures of 21°C in May. Large nests are constructed on bottom in sand or gravel, near or in fallen tree and logs, eggs are then guarded by males. Similar to Snail Bullheads, spawning occurs in May and June at peaking at temperatures between 21— 24°C in May. Assumed to construct nests and guard eggs similar to other Bullhead catfishes. Spawning occurs between mid -April and much ofJune when temperatures are between 11— 25°C. Spawning has been reported to occur in riffles, calm parts of streams, and in overflow bayous with eggs laid on gravel, sand, mud, and organic matter. Spawning occurs between late -March and much of July when temperatures are between 15 — 23°C. Spawning typically occurs riffles of largely gravel in large creeks to large rivers. Fecundity ranges from 20,000 — 139,000 ova. Spawning occurs between May and mid -August when temperatures are between 18 — 30°C. Fractional spawners that deposit eggs in crevices of wood and other structures. Primary spawning occurs between May and July. Spawning may occur on riffles, on or near submerged objects, over vegetation beds, or in association with sunfish nests. Spawning occurs in the spring in the shallow water and along shorelines in reservoirs, over vegetation, tree roots, or open bottom, peak spawning occurs between 15 and 20°C and usually when aquatic vegetation is 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Inhabits clear, moderate -gradient, cool and warm creeks, streams, and rivers. They also inhabit pools and backwaters, and strongly associate with shelter. As a generalist predator, young eat microcrustaceans, insects and other invertebrates. Adults prey on insects and other invertebrates, fishes, and particularly crayfishes. Inhabits warm, medium and large rivers, reservoirs in near - shore habitats, associates with cover such as large rock, logs, fallen trees. Feeds on aquatic invertebrates and fish, omnivorous feeding on aquatic invertebrates and fishes. Similar to the Snail Bullhead, occupies warm, medium and large rivers, reservoirs in near -shore habitats, associates with cover such as large rock, logs, fallen trees. Feeds on aquatic invertebrates and fishes. Inhabits warm lakes, reservoirs, and low to moderate -gradient rivers. Occasionally found in small streams and ditches. Generalist feeder on fine-grained particles, insects, small mollusks, other invertebrates, plant material, and usually large amounts of flocculent detritus. Inhabits moderate and high gradient, un-silted and heavily silted creeks and streams. Large juvenile and adults occupy pools that are fairly deep or that have structural shelter. Feeds chiefly on midge larvae and small crustaceans., and to a lesser extent on other aquatic insects, other arthropods, snails, finger clams, other invertebrates and fish eggs. Typically inhabit warm medium-sized streams to major rivers of moderate to low gradient. Can be found in pools, backwaters, and runs of shallow to moderate depth over a variety of substrates. Opportunistic feeder particularly on drifting items, principally, microcrustaceans, terrestrial and aquatic insects and algae. Thrives under harsh conditions (e.g. low flow, high turbidity, poor water quality). The red shiner spawns over an extended period of time from spring into fall months, with a peak from early to mid -summer. Spawning may occur on riffles, on or near submerged objects, over vegetation beds, or in association with sunfish nests. Adults typically school in midwater or near the surface. Tolerant of a wide range of environmental conditions. Typically found in the calm and mud -bottomed waters of sluggish pools, backwaters, and reservoirs where vegetation is present. Common Carp are omnivores. They ingest mouthfuls of the soft bottom sediments (detritus), expels them into the water, and then feed on the disclosed insects, crustaceans, 28 Glassy Darter Northern Hogsucker Roanoke Hogsucker Blue Catfish Channel Catfish Green Sunfish flooded during April and May. Spawning activities create lots of turbidity, eggs attach to vegetation or sink into the mud. Fecundity for large females can be over 2,000,000 ova. Spawning occurs between mid -March and mid -April when water temperatures are between 10 —19°C. Communal breeder over hard substrates. Spawning occurs between April and May when water temperatures are between 11— 23°C. Spawning occurs over gravelly tails of pools, shallow sides of pools, medium gravel of riffles, and slow to swift runs. Reproduction is unwitnessed; however, female gonadal conditions indicate a spawning period beginning with but perhaps not as long as the Northern Hogsucker. Spawning occurs between April and July when water temperatures are between 21— 24°C. Nests are constructed in sheltered areas by the male or both sexes. Spawning occurs from May through July, between 21 and 30°C, nests are constructed in sheltered areas. Spawning occurs April through August, constructs nests in colonies as shallow depressions in sand and gravel in pools in sand and gravel near shelter such as logs and vegetation, males guard eggs in nests. Warmouth Spawning occurs from mid -spring into summer, occasionally early fall, starts spawning at 21°C. Males construct a solitary nest often hidden in vegetation and guard eggs. Bluegill Spawning occurs from May through September, generally most of the growing season, peaking in June. Fish construct nests in aggregations in shallow water on sand or gravel bottoms, eggs are guarded by male. Redbreast Spawning occurs from June thru Sunfish August between 16 — 28°C. Nests are constructed over sand and gravel, often with overhead cover, eggs are 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION annelid worms, mollusks, weed and tree seeds, aquatic plants, and algae. Inhabits warm, low and moderate -gradient creeks, streams and rivers. Primarily feeds on aquatic insects. Inhabits clean, cool and warm, gravely and rocky, upland and montane, large creeks to small rivers and occasionally large rivers. Young fish feed mostly on immature aquatic insects and microcrustaceans, and occasionally algae. Larger fish feeding habits are the same as young fish with the addition of small mollusk and rarely eggs. Inhabits cool and warm, moderate to high -gradient creeks and streams. Commonly populates rocky, gravelly, sandy, and moderately silted streams. Primarily feeds on insect larvae (mostly Diptera), algae, and detritus. Inhabits large -river and reservoir systems with deep swift channels and well -flowing pools. Young fish feed on small invertebrates. Juvenile and Adults feed on an array of invertebrates, fishes, mollusk and occasionally frogs. Young feed primarily on plankton and insect larvae and larger fish eat almost any available food items including other fish; found in lakes, rivers, streams occupying a variety of habitats and substrates. Prefer slow pools and backwaters of low- and moderate gradient streams and rivers, but also occur in ponds, lakes, and reservoirs. Highly tolerant of conditions such as turbidity and drought and can rapidly colonize new habitats. Food preferences are aquatic insects and small fishes. Frequently associated with vegetation and large rocky areas or rip -rap shorelines. Inhabits pools and backwaters, swamps, lakes, and frequently associates with aquatic vegetation, and large rocky areas, commonly associates with rip -rap shorelines in reservoirs. Young feed on plankton and small insects while adults eat insects, snails, crayfishes, and fishes. Inhabits pools, lakes, streams, and rivers, with vegetation, overhead cover, structure. Young are planktivores, adults eat aquatic and terrestrial insects. Inhabits pool habitat, lakes, and rivers, associates with woody debris, stumps, and undercut banks, abundant in upstream reaches of reservoirs, rip -rap shoreline, and rocky points. A generalist predator that eats insects, crayfish, arthropods, mollusks, and fishes. 29 adhesive and can form large clumps in the nest, males guard eggs in the nest. Redear Sunfish Generally, spawning occurs from April through August, with the onset of temperatures between 20— 21°C. Nests found in aggregate and are constructed in waters shallower than 2 meters, often near vegetation and in colonies, males guard eggs in the nest. White Shiner Spawning occurs from May through July with temperatures between 17.5 — 24°C. Spawning is typically associated with the nest -building chubs or other nest builders. Crescent Shiner Rosefin Shiner Smallmouth Bass Largemouth Bass Blacktip Jumprock Notchlip Redhorse Spawning occurs from May through June with temperatures between 17.8 — 25.3°C. Spawning is typically associated with the nest -building chubs or other nest builders. Spawning occurs from April through mid or late -June when temperatures are between 12.5 — 25.6°C. Spawning is typically associated the nest - building chubs. Spawning occurs in May when water temperatures range from 16 — 22°C. Males vigorously defend nests having eggs and remain aggressive for several days after the eggs hatch. Spawning occurs late April to June when temperatures are between 16 — 18°C, with peak spawning occurring in April and May. Nests are generally located in sand or gravel at the base of logs, stumps, and emergent vegetation along shorelines usually at depths of 0.6 meters. Both male and female guard eggs in nest. Spawning occurs April through July when water temperatures range from 14 — 23°C. Spawning occurs in April and May when water temperatures range from 11 — 15°C. Spawning is typically associated with shallow riffles over gravel and rubble. 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Inhabits lacustrine ecosystems, generally found in vegetated lakes, ponds, reservoirs, streams, rivers, or backwater areas. Generally, feeds on small prey, snails, and small mussels and clams, small insects and fishes. Inhabits pools within cool and warm streams of moderate gradient. Primarily feeds on aquatic and terrestrial insects. Inhabits pools of creeks, streams and small rivers of moderate to somewhat high -gradient. Generally, feeds in the lower levels of the water column with a diet primarily consisting of aquatic insects. Inhabits warm large creeks to rivers of moderate gradient. Typically found in mid and higher depths over soft and hard bottoms. In warmer times of the year, the Rosefin Shiner feeds on terrestrial insects. Also feeds on benthic aquatic insects, algae, and detritus. Inhabits cool and warm, generally clear, large creeks, streams and rivers with gravelly and rocky substrates and a frequent succession of riffles, runs, and pools. Fingerlings exhibit the carnivorous appetite of adults, eating microcrustaceans, insects, and smaller fish. Juveniles and adults feed on crayfishes and fishes principally, but also prey on insects. Inhabits a wide variety of habitats. Prefer warm, calm, and clear water and thrive in slow streams, farm ponds, lakes, and reservoirs. Young feed primarily on plankton, insects, small fishes, adults feed on fishes, frogs, and almost any other animal of appropriate size. Inhabits well -flowing to rather swift current in warm, moderate -gradient, large creeks to small rivers. Typically occupy clean rubble, boulder, and bedrock substrates. Feeds on insect larvae, water mites and small amounts of algae and detritus. Inhabits large streams, small to big rivers, and natural and artificial lakes. Feeds on insect larvae, microcrustaceans, crayfishes, mollusks, algae and detritus. 30 Golden Redhorse V-Lip Redhorse Bluehead Chub Bull Chub Golden Shiner Comely Shiner Spawning occurs in April — early -June when water temperatures range from 10 — 22.5°C. Spawning typically occurs over gravel beds associated with shallow runs and riffles. Fecundity ranges from 5,041— 25,350 eggs. Spawning occurs in late -April — early - July. Spawning occurs from late -April — early July when water temperatures range from 12 — 25.3°C. Spawning is associated with gravel -mounded nest in runs, pocket areas of riffles, and tails of pools, generally next to a boulder, log, or bank. Spawning occurs in April —June when water temperatures range from 18 — 23.3°C. Spawning is associated with gravel -mounded nest. Spawning may occur from April thru August, from 15 — 26°C. Adhesive eggs are cast over rooted aquatic vegetation, filamentous algae, gravel, and sometime on nests of black basses and sunfishes. Spawning occurs from April through August. Spottail Shiner Spawning occurs from mid -April through mid -June. Spawning occurs in large aggregations and in groups of two to five individuals. Fecundity ranges from 100 — 8,898 eggs. Swallowtail Spawning occurs from mid -May Shiner through late July. Spawning may occur over the nest of other fishes. Margined Madtom Chainback Darter Spawning occurs in May and June. Nest are sited beneath flat rocks in gentle runs and in slow water above and below riffles. Fecundity ranges from 53 — 223 eggs. Spawning occurs during April and May. Considered an egg-burier with each spawning activity producing 15 — 25 eggs. 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Inhabits the broadest spectrum of warm -water habitats of any redhorse, e.g. large creeks, big rivers, natural lake, and impoundments, in montane to somewhat lowland areas. Feeds on aquatic insects, other invertebrates, detritus; and small amounts of algae. Inhabits warm, medium-sized streams to medium rivers of moderate or gentle gradient. Feeds on ostracods, vascular plants, and aquatic insects. Inhabits streams from the headwaters to points where the stream widens to 20 — 30 meters. Occupies pools, runs, and riffles, and sand to boulder and bedrock substrates. Omnivorous species, feeding on a wide variety of aquatic insects and plant material (particularly algae). Inhabits major rivers and their larger tributaries. Occupies pools, riffles, runs and higher flow areas of pools. Feeds on benthic and drifting insects, snails, and occasionally crayfishes and fishes. Inhabits open water and along edges of weedy habitat, moves from shallow inshore areas to open waters following plankton migrations. Feeds primarily from midwater to surface depths on plankton, microcrustaceans, and insects, sometimes algae. Inhabits warm, medium streams to large rivers of moderate to low gradient. Inhabits an array of lotic habitats, ranging from typically clear, mostly rocky, moderate gradient streams to often turbid, sandy, muddy, silty, and sluggish water. Feeds on microcrustaceans, aquatic and terrestrial insects, young shiners, fish eggs, and plant material. Inhabits warm, clear and turbid, large creeks to large rivers of moderate to low gradient. Primarily a pool shiner, found near the head and tail of pools over areas of soft and firm bottoms and is sometimes associated with plants. Feeds on worms, mites, microcrustaceans, aquatic and terrestrial insects, diatoms, and filamentous algae. Inhabits low and moderate -gradient sections of large creeks to large rivers. Occupies soft and hard bottoms of pools, runs and riffles. Feeds on a variety of aquatic invertebrates, mostly aquatic insect larvae, fishes and terrestrial insects are occasionally taken. Inhabits warm streams and rivers of low to moderate gradient and varied substrates. Feeds mainly on insects. 31 White Crappie Black Crappie Flathead Catfish Spawning occurs from March through July throughout the species range. Spawning occurs when water temperatures are between 16 — 20°C. Fecundity ranges from 2,900 to 213,000 mature eggs. Spawning occurs from late February to early June. Nests are constructed in shallow water to moderately deep water (to 6 meters), sometimes in close proximity to each other and usually associated with vegetation or structure, larvae are pelagic and move inshore as larger juveniles. Spawning occurs in June and July. Nests consist of cleaned substrate near cover or in a cavity. Fecundity ranges from 6,900 —11,300 eggs. 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Inhabits warm ponds, lakes, reservoirs and pools of low to moderate gradient streams and rivers. Young and juvenile fish feed on crustaceans and insets. Adults feed on a variety of fishes, insects, and other aquatic invertebrates including plankton. Inhabits vegetated areas of backwaters in streams and rivers in ponds and reservoirs, aggregates around structure and associates with aquatic vegetation, fallen trees, stumps. Young Black Crappie feed on aquatic insects and small fishes and adults feed primarily on fishes. Inhabits warm large streams, big rivers, lakes and reservoirs. In streams, young and juveniles are usually associated with riffles, while larger fish favor moderate to deep pools with cover. Young feed on microcrustaceans and insect larvae; adults feed on crayfishes, clams, and particularly, fishes. 4.4 Species and Life Stages Susceptible to Impingement and Entrainment The MWIS design, with a TSV of less than 0.5 fps, is compliant with impingement BTA requirements of the Rule. As such, no species or life stages are anticipated to be susceptible to impingement at the Dan River CWIS (Table 4-6). While some species may have the potential to be entrained, based on the operational parameters of the CWIS on the Dan River (low DIF, low AIF, and low TSV) and orientation of the MWIS and wedgewire screens, interactions with aquatic organisms are expected to be limited with no potential for adverse environmental impacts. 4.4.1 Impingement The degree of vulnerability to impingement exhibited by adult and juvenile fish species depends upon biological and behavioral factors including seasonal fish community structure, spawning effects on distribution, habitat surrounding intake structures, high flow events, and attraction to the flow associated with the intake. In addition, swimming speed, intake velocity, screen mesh size, trash rack spacing, and other intake configurations will also affect the susceptibility to impingement. For example, clupeids have high susceptibility to impingement based on multiple factors such as schooling behavior, distribution in the water column, negative rheotactic response to intake flows, and poor swimming performance in winter months due to lower water temperatures (Loar et al 1978). No clupeid species were collected during the data collection period. No ongoing or historical impingement studies have been performed at the DRCCS. The MWIS withdraws water from the Dan River through cylindrical wedgewire screens with a TSV of Tess than 0.5 fps. In the Rule, screens designed to achieve a TSV at or below 0.5 fps are compliant with the impingement reduction standard. 32 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 4.4.2 Entrainment Ichthyoplankton (the egg and larval life stage of fishes) exhibit the highest degree of susceptibility to entrainment based on body size and swimming ability. Therefore, an organism is most susceptible to entrainment for a portion of its life cycle. Larger juvenile and adult life stages have the swimming ability to avoid entrainment. Life history characteristics can influence the vulnerability of a fish species to entrainment. For example, broadcast spawners with non -adhesive, free-floating eggs can drift with water currents and may become entrained in a CWIS, while nest -building species with adhesive eggs are Tess susceptible to entrainment during early life stages. The habitat in the immediate vicinity MWIS is described as pool/deep run habitat depending of the river flow. The intake structure is oriented parallel to the river flow and is out of the main stem (Figure 4-2). The habitat within the vicinity of the DRCCS MWIS is not preferred spawning habitat for many of the species present within the vicinity of the MWIS (Table 4-6), thus the potential for entraining eggs and larvae is low. Figure 4-2. Aerial View of the MWIS and orientation within the Dan River. Table 4-6. Entrainment Potential for Fish (Egg and Larvae) Species Present near the DRCCS MWIS. Species Spawning Habitat (Common Name) Use/Preference Roanoke Bass Nest constructed in shallows having coarse sand to large gravel substrate. Rock Bass Nest constructed in shallows having coarse sand to large gravel substrate. Snail Bullhead Cavity nesters. Flat Bullhead Cavity nesters. 33 Potential for Entrainment' Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Quillback White Sucker Satinfin Shiner Red Shiner Common Carp Glassy Darter Northern Hogsucker Roanoke Hogsucker Blue Catfish Channel Catfish Green Sunfish Warmouth Bluegill Redbreast Sunfish Redear Sunfish Upstream spawning migration. Lays eggs over sand, silt or mud in streams. Demersal eggs. Upstream spawning migration. Typical spawning occurs over riffles of large creeks to large rivers. Demersal eggs. Fractional spawners that deposit adhesive eggs in crevices of wood and other structures. Spawning may occur on riffles, on or near submerged objects, over vegetation beds, or in association with sunfish nests. Lays adhesive eggs in shallow vegetation. Communal breeder that deposits adhesive eggs over hard substrates. Deposits demersal eggs over gravelly tails of pools, shallow sides of pools, medium gravel of riffles, and slow to swift runs. Deposits demersal eggs over gravelly tails of pools, shallow sides of pools, medium gravel of riffles, and slow to swift runs. Cavity nesters, found in large open areas with woody debris, bank cavities; moderate currents. Cavity nesters, found in large open areas with woody debris, bank cavities; moderate currents. Construct nests around vegetation. Construct nests in cover. Nest generally constructed in shallow waters. Construct nests over silt -free or lightly silted sand and gravel in cover. Nest generally constructed in shallow waters. 34 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to absence of vegetated habitat in the vicinity of the CWIS Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely; limited quantity of vegetation available in the vicinity of the CWIS Unlikely; no cover near intake. Unlikely due to water depth in the vicinity of the CWIS, demersal and adhesive eggs, parental care of nest until larvae swim -up. Likely due to relative abundance. Unlikely due to water depth in the vicinity of the CWIS, demersal and adhesive eggs, parental care of nest until larvae swim -up. White Shiner Crescent Shiner Rosefin Shiner Smallmouth Bass Largemouth Bass Blacktip Jumprock Notchlip Redhorse Golden Redhorse V-Lip Redhorse Bluehead Chub Bull Chub Golden Shiner Comely Shiner Spottail Shiner Swallowtail Shiner Margined Madtom Demersal eggs are deposited over nest constructed by chubs and other nest builders. Demersal eggs are deposited over nest constructed by chubs and other nest builders. Demersal eggs are deposited over chub nest or other cyprinid nest. Nest constructed near shore on firm bottoms in slow currents often adjacent to cover. Nest constructed in shallow areas of one to six feet. Deposits demersal eggs in swift water. Spawning occurs in shallow riffles over gravel and rubble. Spawning occurs over gravel beds in often very shallow runs and riffles. Spawning occurs in shallow riffles over gravel and rubble. Spawning is associated with gravel - mounded nest in runs, pocket areas of riffles, and tails of pools, generally next to a boulder, log, or bank. Spawning is associated with gravel - mounded nest. Adhesive eggs are cast over rooted aquatic vegetation, filamentous algae, gravel, and sometime on nests of black basses and sunfishes, schools in open water and along edges of weedy habitat. Demersal eggs are deposited over the nest of other nest builders (primarily chubs). Adhesive eggs are deposited over sand and gravel in shallow riffles. Adhesive eggs are deposited over nest of other fishes. Nest are sited beneath flat rocks in gentle runs and in slow water above and below riffles. 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to water depth in the vicinity of the CWIS. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, adhesive and demersal eggs, relatively low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. Unlikely due to habitat and spawning preference, and low abundance. 35 Chainback Darter White Crappie 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Considered an egg-burier, demersal Unlikely due to habitat and spawning preference, and low eggs are deposited over sand and abundance. fine gravel mix in areas of rubble and boulder at the head of, or in riffles. Constructs a nest on firm or soft bottoms, in open areas or under banks and other cover. Adhesive eggs are deposited on the substrate, algae, macrophyte leaves and tree roots. Black Crappie Construct nests around vegetation close to other nests. Flathead Catfish Unlikely due to water depth in the vicinity of the CWIS, demersal and adhesive eggs, parental care of nest until larvae swim -up. Unlikely due to water depth in the vicinity of the CWIS, demersal and adhesive eggs, parental care of nest until larvae swim -up. Nest consist of cleaned substrate Unlikely due to habitat and spawning preference, and low near cover or in a cavity. abundance. 1TSV below 0.5 fps at the MWIS will minimize potential for entrainment for all species based on their ability for avoidance of the intake. Species with floating eggs would continue to have some susceptibility to entrainment. 4.4.3 Selected Species A subset of species present (dominant species) in the vicinity of the DRCCS MWIS with the highest likelihood to be entrained was selected for detailed life history descriptions including reproduction, recruitment, and peak abundance as detailed in Freshwater Fishes of Virginia. (Jenkins 1993). The habitat in the immediate vicinity of the MWIS is described as pool/deep run habitat depending of the river flow. Most fish species are using the vicinity of the MWIS for staging or foraging. Of the species present, the Redbreast Sunfish has the highest likelihood of being entrained based on species abundance. Redbreast Sunfish Redbreast Sunfish are native to the Atlantic slope probably from New Brunswick to Central Florida and are frequently found in pools and backwaters of warm, usually clear but occasionally turbid creeks, streams, and rivers of low or moderate gradient. Fish are also found in ponds and reservoirs (Jenkins 1993). Spawning occurs when water temperatures range from 16 to 28°C with peak spawning occurring between 20 and 28°C (Davis 1972 and Hardy 1978). Nests are constructed by males over usually silt -free or lightly silted sand and gravel, often in association with cover. Nests may be closely spaced, occasionally touching (Breder 1936, Richmond 1940, Davis 1972, and Jenkins 1993). Nests are typically located in calm pool margins in less than 1 meter of water, but may be constructed in the lee of large rocks near swift current (Breder 1936, Buynak and Mohr 1978). Fecundity ranged from an average of 963 ova in age-2 females and 8,250 in age-6 fish (Gerald 1971). Golden Redhorse The Golden Redhorse is widespread in the southern Great Lakes basin, the Mississippi basin, and the Mobile drainage; it is localized in the upper Hudson Bay, isolated in a few eastern lower Mississippi River tributaries, and occupies the Atlantic slope in the Potomac, James, Chowan, and Roanoke drainages 36 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION (Jenkins 1993). Golden Redhorse occupies about the broadest spectrum of warm water habitats of any redhorse; for example, large creeks, big rivers, natural lakes, and impoundments, in montane to somewhat lowland areas (Jenkins 1970). Highest abundances occur in moderately clear, un-polluted streams with large permanent pool and well-defined rocky riffles (Pflieger 1975 and Trautman 1981). In streams, the species is essentially restricted to pools (except during the spawning period), occurring over silt, sand, gravel, rubble, and bedrock. Spawning in Virginia typically occurs in April and May when water temperatures are between 19.5 and 21.5°C (Jenkins 1993). Spawning sites are gravel beds in often very shallow runs and riffles. A trio of two males and one female consummate the typical spawning act, as in most suckers. Males are highly aggressive, defending spawning sites or individual distances usually by forceful butting with the ram of the snout tubercles. Repeated localized spawning sometimes results in shallow substrate depression (Jenkins 1993). Fecundity ranges from 5,041— 23,350 eggs (Meyer 1962, Smith 1977, Curry and Spacie 1984, and Becker 1983). V-Lip Redhorse V-Lip Redhorse occupies the major Atlantic slope drainages from the Chowan and Roanoke south to the Santee in South Carolina favoring warm, medium-sized streams to medium rivers of moderate or gentle gradient. Inhabits streams that are clear and some that most often are slightly or moderately turbid and moderately silted. Large juveniles and adults occur in pools, foraging there and into runs; young and small juveniles often are found in calm shallows. All stages occur over a variety of soft and hard bottoms. Based on tuberculation and gonad development, V-Lip Redhorse apparently is the latest - spawning Redhorse in Virginia. Spawning starts in Tate -April and early -May and lasting through July (Jenkins 1993). White Shiner The White Shiner is indigenous to the drainages from the Chowan south to the Cape Fear, and in the New. It ranges from mountains to the Fall Line with few populations occurring in the upper Coastal Plain. The White Shiner is principally a pool inhabitant in cool and warm streams of moderate gradient; it occurs Tess frequently in fast water and is found over firm and soft bottoms including moderately silted ones. Spawning is typically associated with Bullhead Chub nests between May and July when water temperatures range from 17.5 — 24°C (Jenkins 1993). Comely Shiner The Comely Shiner ranges on the Atlantic slope from the Hudson to the Pee Dee drainage and is known long ago from a Finger Lakes tributary. The Comely Shiner typically occupies warm, medium streams to large rivers of moderate to low gradient. The preferred habitat includes a variety of substrates and is usually associated with slow runs and pools adjacent to moderate current. Large adults have been found to be associated with swift riffles. Little has been published on the life history of the Comely Shiner (Jenkins 1993), however spawning is known to occur from early -April through late -August (Snelson 1968). Bluegill Bluegill are native to the Great Lakes -St. Lawrence and Mississippi basins, the Atlantic slope probably from North Carolina southward, and the Gulf slope west to Texas. It is the most widely introduced species of Sunfish (Jenkins 1993). Bluegills are found in pools and backwaters of low to moderate- 37 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION gradient creeks, streams, and rivers, and in all types of lacustrine habitats. The Bluegill occupies clear and turbid waters, hard and silted substrates (Grahm and Hastings 1984). Spawning likely occurs from May to August or September. Spawning typically occurs over nest constructed by Males in shallows on sand or gravel; nest frequently occur in colonies (Coggeshall 1924, Crowe 1959, and Gross and MacMillan 1981). Bluegill average five spawnings and produce about 80,000 eggs per year. Largemouth Bass Largemouth Bass are native to the Great Lakes -St. Lawrence and Mississippi basins and the Gulf and south Atlantic slopes; both subspecies have been widely transplanted in North American and beyond (Robbins and MacCrimmon 1974). Largemouth Bass inhabits marshes, swamps, ponds, lakes, reservoirs, and creeks to large rivers. In lotic situations (like the Dan River) it occupies pools and backwaters. Largemouth Bass prefer warm, generally clear water, and are less tolerant of turbidity than the Spotted Bass (Trautman 1981). Spawning occurs in the spring (May and June) when water temperatures approach 16 — 18°C and continue to 24°C (Carlander 1977). Males fan out a nest and guard it against intruders; sometime spawning occurs on unprepared bottoms. Nests are made on a variety of substrates in pools and backwaters of streams and along the shores of ponds and reservoirs at a depth of 0.3 — 0.6 meters typically, but up to 8.2 meters deep (Carlander 1977). Nests may be found in open settings or in association with ledges, logs, or aquatic macrophytes, and may be well spaced or crowded. Bull Chub The Bull Chub occurs in the James, Chowan, Roanoke, Tar and Neuse river drainages in Virginia and North Carolina. Bull Chubs typically occupy major rivers and their larger tributaries; populations in smaller (8 —12 meters wide) streams also are strong. The species occupies both fast and slow water; large individuals are most often found in pools, while small ones are found in riffles, runs, and well - flowing parts of pools (Jenkins 1993). Spawning typically occurs in May and June when water temperatures range from 18 — 23.3°C. Spawning occurs over nest or gravel mounds constructed in runs, pocket areas of riffles and tails of pools, general next to a boulder, log, or bank (Lachner and Wiley 1971 Snail Bullhead The northern most range of the Snail Bullhead is the Dan River system. The Snail Bullhead occupies warm, medium to large streams and rivers (Jenkins 1993). It is thought by Yerger and Relyea (1968) to favor higher -gradient rocky sections and to inhabit well -flowing pools and riffles. Spawning behaviors have been essentially unstudied but are reported to be similar to the Flat Bullhead which spawn in June and July when water temperatures range from 21— 24°C. The spawning behavior of the Flat Bullhead has not been reported (Olmsted and Cloutman 1979). 38 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 4.5 Threatened, Endangered, and Other Protected Species Susceptible to Impingement and Entrainment at the MWIS The Rule requires the permittee to document the presence of federally listed species and designated critical habitat in the action area (see 40 CFR 125.98[f]). For the purpose of defining listed species, the action area is defined as a one -mile radius around the Dan River CWIS. A desktop review of available resources was performed to develop a list of species with protected, endangered, or threatened status that might be susceptible to impingement and entrainment at the CWIS on the Dan River. The USFWS's map -based search tool (Information for Planning and Consultation [IPaC]) was used to identify state or federally listed rare, threatened, or endangered (RTE) aquatic species or critical habitat designations within the defined search area. Listed species spatial occurrence data from the North Carolina Natural Heritage Program was cross-referenced spatially with the Dan River CWIS. Because the Dan River CWIS is in a freshwater environment, marine and anadromous federally listed species and designated critical habitat under National Marine Fisheries Service jurisdiction were not considered. State or federally listed rare, threatened, or endangered (RTE) aquatic species or critical habitat designations occurring within the vicinity of the Dan River CWIS, are provided in Table 4-7. Federal species of concern and candidate species were omitted from the list (unless they were also state threatened or endangered), as there are no requirements to address those species under the Rule or Section 7 of the ESA. The following materials were reviewed to develop the species list in Table 4-7: IPaC (https://ecos.fws.gov/ipac/) (USFWS 2020) for the search area shown on Figure 4-1, and North Carolina Department of Natural and Cultural Resources (NCDNCR) Natural Heritage Program Data explorer listed species element occurrence data (NCDNCR 2020). Dan River Long Term monitoring results discussed in Section 4.2 of this report resulted in no collections of federally or state -listed species from 2015 to 2017. The UFWS IPAC search indicated that the Roanoke Logperch (Percina rex) might be affected by activities in the search location (1.0-mile circumference of the Dan River CWIS). The CWIS is outside of any critical habitat designation and is not included in any of the known or managed populations (USFWS 2021). The Roanoke Logperch is not likely to occur in the vicinity of the CWIS as most collections have occurred in the upper Dan and Smith rivers, not below the confluence. Table 4-7. Summary of Rare, Threatened, or Endangered (RTE) Aquatic Species Listed for Rockingham County, North Carolina, and Record of Occurrence of Potential to Occur Near the DRCCS MWIS. Source USFWS Scientific Common Federal Name Name Status* Percina rex Roanoke Endangered Logperch NCNHP Moxostoma Bigeye arimomum Jumprock n/a 39 State Status Endangered Record of occurrence or potential to occur Near the Dan River CWIS Not likely to occur, most collection records are above the confluence of the Dan and Smith Rivers. The Dan River CWIS is below the confluence and the habitat type is not preferred. Threatened Unlikely as none were collected in the vicinity of the CWIS. Preferred habitat is not present in the vicinity of the CWIS. 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION NCNHP Ambloplites Roanoke Bass n/a Rare Unlikely as none were collected in the cavifrons vicinity of the CWIS. Preferred habitat is not present in the vicinity of the CWIS. NCNHP Carpiodes Quillback n/a Rare Unlikely as few were collected in the cyprinus vicinity of the CWIS. NCNHP Etheostoma Riverweed n/a Rare Unlikely as none were collected in the podostemone Darter vicinity of the CWIS. Preferred habitat is not present in the vicinity of the CWIS. NCNHP Exoglossum Cutlip Minnow n/a Concern Unlikely as none were collected in the maxillingua vicinity of the CWIS. Preferred habitat is not present in the vicinity of the CWIS. USFWS Fusconaia Atlantic Pigtoe Proposed masoni Threatened n/a Unlikely as none were collected in the vicinity of the CWIS. Preferred habitat is not present in the vicinity of the CWIS. USFWS Parvaspina James Endangered Endangered Unlikely as none were collected in the collina Spinymussel vicinity of the CWIS. Preferred habitat is not present in the vicinity of the CWIS. NCNHP Strophitus Creeper n/a Threatened Unlikely as none were collected in the undulates vicinity of the CWIS. Preferred habitat is not present in the vicinity of the CWIS. NCNHP Villosa Notched constricta Rainbow n/a Threatened Unlikely as none were collected in the vicinity of the CWIS. Preferred habitat is not present in the vicinity of the CWIS. NCNHP Villosa delumbis Eastern n/a Rare Unlikely as none were collected in the Creekshell vicinity of the CWIS. Preferred habitat is not present in the vicinity of the CWIS. NCNHP Lampsilis Yellow cariosa Lampmussel n/a Endangered Unlikely as none were collected in the vicinity of the CWIS. Preferred habitat is not present in the vicinity of the CWIS. NCNHP Lasmigona Green Floater n/a Endangered Unlikely, however they are present in the subviridis vicinity of the CWIS. 40 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 4.6 Documentation of Consultation with Services In preparing this response package for compliance with the Rule, there has been neither public participation, nor coordination undertaken with the USFWS or NMFS. Duke Energy has not submitted information to obtain incidental take exemption or authorization from any Agency. 4.7 Incidental Take Exemption or Authorization from Services Duke Energy has not submitted information to obtain incidental take exemption or authorization from the Services. 4.8 Methods and Quality Assurance Procedures for Field Efforts Data presented in this report were compiled from Duke Energy's Dan River Long -Term Environmental Monitoring Program (Duke Energy 2019). All data were collected according to NCDEQ approved procedures under the Duke Energy Progress Biological Laboratory Certification number 006. 4.9 Fragile Species In the Rule, the EPA identifies 14 species of fish as fragile or having post -impingement survival rates of less than 30 percent. Occurrence of fragile species in the Dan River system have been documented, but none were collected in the vicinity of the CWIS (Table 4-8). Table 4-8. List of Fragile Species as Defined by the EPA and Their Occurrence in the Vicinity of the DRCCS MWIS. Scientific Name Common Name Alosa pseudoharengus Alewife Alosa sapidissima Clupea harengus American Shad Atlantic Herring Occurrence in vicinity of the Dan River CWIS' No No No Doryteuthis (Amerigo) Atlantic Long -fin Squid No pealeii Anchors mitchilli Bay Anchovy No Alosa aestivalis Blueback Herring No Pomatomus saltatrix Bluefish No Poronotus triacanthus Butterfish No Lutjanus griseus _ Grey Snapper No Alosa mediocris Hickory Shad No Brevoortia tyrannus Atlantic Menhaden No Osmerus mordax Rainbow Smelt No Etrumeus sadina Round Herring No Engraulis eurystole Silver Anchovy No 41 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 5 Cooling Water System Data [§122.21(r)(5)(i)] The information required to be submitted per 40 CFR §122.21(r)(5), Cooling water system data, is outlined as follows: (i) A narrative description of the operation of the cooling water system and its relationship to cooling water intake structures; the proportion of the design intake flow that is used in the system; the number of days of the year the cooling water system is in operation and seasonal changes in the operation of the system, if applicable; the proportion of design intake flow for contact cooling, non - contact cooling, and process uses; a distribution of water reuse to include cooling water reused as process water, process water reused for cooling, and the use of gray water for cooling; a description of reductions in total water withdrawals including cooling water intake flow reductions already achieved through minimized process water withdrawals; a description of any cooling water that is used in a manufacturing process either before or after it is used for cooling, including other recycled process water flows; the proportion of the source waterbody withdrawn (on a monthly basis); (ii) Design and engineering calculations prepared by a qualified professional and supporting data to support the description required by paragraph (r)(5)(i) of this section; and, (iii) Description of existing impingement and entrainment technologies or operational measures and a summary of their performance, including but not limited to reductions in impingement mortality and entrainment due to intake location and reductions in total water withdrawals and usage. Each of these requirements is described in the following subsections. 5.1 Description of Cooling Water System Operation [§122.21(r)(5)(i)] The DRCCS circulating water system is a closed -loop system with cooling water recycled and reused in the steam turbine condenser. The purpose of the circulating water system is to supply cooling water to the main and auxiliary steam condensers, the cooling water chiller system, and to be used as service water for various plant uses such as fire water, boiler area wash water, and makeup water to the HRSG. The heat transferred to the circulating water in the condenser is rejected to the atmosphere by the evaporation process in the cooling tower. Approximately 94 percent of water withdrawn by the MWIS is used for cooling tower makeup. 5.1.1 Cooling Water System Operation Two vertical circulating water pumps, each rated at 135.4 MGD (94,000 gpm) supply cooling water to the condenser and additional circulating water to the auxiliary cooling water heat exchangers. Heated water from these systems is returned to the cooling tower through the circulating water piping. The heated circulating water is cooled by the cooling tower and then collected in the cooling tower basin where it flows back to the circulation pumps, and the cycle is repeated. The DRCCS has one mechanical draft counterflow cooling tower equipped with ten cooling cells, motor -driven fans, and two pumps in the tower basin to recirculate the cooling water to the condenser. Figure 5-1 provides a schematic of the DRCCS cooling tower. 42 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION The cooling tower is always in operation whenever the DRCCS is in operation. The cooling tower is designed to operate with at least eight of the ten cells in operation. Typically, during the warmer months of the year (mid -May to mid-October)all ten cells of the cooling tower are in service. Most of water losses in the circulating water system is through evaporation in the cooling tower. Evaporation does not carry away solids in the water such as mud, silt, or dissolved solids; therefore, it is necessary to continuously discharge some of the circulating water to remove waste and prevent a buildup of solids in the circulating water. This discharge, called blowdown, is routed to Outfall 001. The cooling tower has five main components: 1. the blower type fans which direct the airflow upward, 2. the heat transfer section commonly called the "fill", 3. the water distribution system, 4. the drift eliminator section, and 5. the concrete basin which collects water for return to the condenser and other heat exchangers. o PO PA V'EW Figure 5-1. DRCCS Cooling Tower General Arrangement 5.1.2 Proportion of Design Flow Used in the Cooling Water System Water withdrawals from Dan River to support DRCCS operations from 2016 through 2020 are provided in Table 3-1 (Section 3.4). Based on the engineering design water balance diagram (Figure 3-1), approximately 94 percent of the MWIS withdrawal is used for makeup to the cooling tower. The remainder is used as service water for various plant uses such as fire protection water, boiler wash water, and HRSG makeup water. Table 5-1 provides the proportion of the 7.2 MGD DIF withdrawn during the 2016-2020 period. 43 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Table 5-1. Percent Monthly Proportion of Design Flow Withdrawn at the DRCCS. Month 2016 2017 2018 2019 2020 Average January 42.9 43.4 44.9 49.8 44.9 45.2 February 43.9 48.7 50.1 52.5 47.2 48.5 March 44.5 49.7 51.5 54.6 49.8 50.0 April 46.4 23.5 39.6 43.8 28.9 36.4 May 33.2 47.6 56.3 61.3 44.1 48.5 June 51.1 56.3 54.5 61.4 55.2 55.7 July 54.4 58.4 64.5 67.6 62.1 61.4 August 53.9 58.9 63.4 68.6 55.3 60.0 September 54.6 54.6 40.4 63.5 49.5 52.5 October 38.4 42.9 46.9 37.0 49.0 42.8 November 53.2 53.6 54.5 1.8 42.4 41.1 December 40.9 47.1 46.2 35.0 19.1 37.7 Although historical averages are not necessarily indicative of future withdrawals, only 48.3 percent of the DIF was withdrawn from the Dan River from 2016 through 2020. 5.1.3 Cooling Water System Operation Characterization Operation of the cooling water system results in an increased makeup water demand and makeup water pump operation. As presented in Section 3.3, the MWIS operated nearly continuously during the 2016- 2019 period with an average daily operation of approximately 21.8 hours each day (i.e., about 91% each day). Steam turbine and/or combustion turbine outages typically occur in the spring and/or fall. Monthly total flow data during the 2016-2020 period are provided n Figure 5-2. MWIS withdrawals during the summer months (i.e., May to September) are typically higher than the remainder of the year due to increased cooling tower evaporation due to higher ambient temperatures. 44 160.0 140.0 120.0 c 100.0 E 80.0 60.0 40.0 20.0 0.0 �a$) e� a� �a� QQ�� ' 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION �3� sec o�c vet s ec � O& �o� o�`ec�` ■ 2016 ■ 2017 ■ 2018 ■ 2019 ■ 2020 Figure 5-2. Monthly Total MWIS Withdrawals at DRCCS At the DIF (5,000 gpm) the calculated TSV is 0.15 fps while at the AIF (2,417 gpm) the calculated TSV is 0.07 fps. Both of these values are considerably less than the 0.5 fps alternative in the 316(b) Rule for impingement compliance. Appendix C provides TSV calculations. 5.1.4 Distribution of Water Reuse The distribution of water reuse does not apply to DRCCS because this facility does not reuse cooling water as process water, reuse process water for cooling purposes, or use grey water for cooling purposes. 5.1.5 Description of Reductions in Total Water Withdrawals With the retirement of DRSS Units 1-3, maximum water withdrawals from the Dan River have been reduced by 97.5 percent (i.e., 7.2 MGD vs. 285.1 MGD). The DRCCS is a single combined cycle unit, natural gas -fired electric generating facility with a current generating capacity of 718 MW. The DRCCS has a DIF of 7.2 MGD and an average AIF of 3.48 MGD for 2016-2020. As shown in Table 5 2, the DRCCS is more efficient in cooling water usage, producing 2.3 times more power output while using 97.5 percent Tess cooling water compared to the retired DRSS at design flows and 98.8 less at actual withdrawal flows. 45 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Table 5-2. Comparison of DRSS and DRCCS. Characteristic DRSS DRCCS Total Generation, MW 290 718 Fuel Coal Natural Gas Total Design Withdrawal, MGD 285.12 7.2 Cooling System Once -Through Closed -Cycle MW/MGD Ratio 1.01 99.7 5.1.6 Description of Cooling Water Used in Manufacturing Process DRCCS cooling water is not used in a manufacturing process either before or after the water is used for cooling. 5.1.7 Proportion of Source Waterbody Withdrawn Withdrawal from the Dan River is dependent on the cooling tower makeup water demand, maximum pump capacity, and water losses due to evaporation and system losses. Monthly average Dan River flows and monthly average DRCCS water withdrawals during the 2016-2020 period are provided in Table 5-3. The percent of source water withdrawal ranges from a low of 0.01 percent (November 2019) to a high of 0.88 percent (November 2016). Table 5-3. DRCCS Percent of Source Waterbody (Dan River) Withdrawal Month 2016 2017 2018 January 0.17 0.27 0.58 February 0.11 0.52 0.26 2019 0.12 0.11 March 0.20 0.53 0.34 April 0.25 0.06 0.18 May 0.11 0.12 0.19 June 0.37 0.26 0.54 July 0.43 0.58 0.63 August 0.34 0.72 0.34 September 0.72 0.71 0.10 October 0.38 0.65 0.12 November 0.88 0.87 0.15 December 0.56 0.74 _ 0.09 Annual 0.26 0.33 0.20 Average 0.17 0.14 0.32 0.21 0.49 0.68 0.87 2020 0.21 0.08 0.27 0.10 0.06 0.18 0.40 0.23 0.28 0.33 0.17 0.01 0.08 0.17 0.05 0.21 0.13 During the 2016-2020 period of record for this report, the DRCCS average withdrawal was 0.23 percent of the Dan River source waterbody flow. [insert Table 5-3 with updated data from last five years] 5.2 Design and Engineering Calculations [§122.21(r)(5)(ii)] The following table provides calculated TSV values. Appendix C presents the engineering calculations of TSV for the cylindrical wedgewire screen design as prepared by a qualified professional. 46 Table 5-4. MWIS TSV Calculations Flow Scenario AIF (2016-2020) DIF (two pumps) Maximum possible (three pumps) Calculated TSV 0.07 fps 0.15 fps 0.22 fps 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 5.3 Description of Existing Impingement and Entrainment Reduction Measures [§122.21(r)(5)(iii)] The DRCCS achieves substantial reductions in entrainment and impingement by means of flow reduction. The underlying assumption for entrainment is that entrainable organisms have limited or no motility and passively move with the water entering the power plant; therefore, reduction in flow results in a commensurate reduction in entrainment. This flow reduction is achieved through the use of mechanical draft wet cooling towers. Utilization of closed -cycle cooling results in a flow reduction of 97.6 percent relative to OTC at DRCCS. In addition to providing a significant reduction of organisms entrained, the lower flows associated with closed -cycle cooling also result in a commensurate reduction in the potential for impingement at the facility. As the MWIS wedgewire screens have a maximum TSV of 0.15 fps at the DIF, the risk of impingement is essentially eliminated. The annual average AIF of 3.2 MGD at DRCCS (see Section 3.4) is small and the calculated TSV is 0.07 fps. Thus, the MWIS AOI would not extend beyond the face of the screens and is substantially less than the source waterbody current. Based on the AO1 calculations, impingement at DRCCS is negligible and more likely approaches zero. 5.3.1 Best Technology Available for Entrainment To aid the Director in making a BTA determination, the following is provided to support the conclusion that the existing DRCCS configuration and operation results in the maximum reduction in entrainment warranted and no additional entrainment controls are warranted. Most importantly, the DRCCS uses closed -cycle cooling, which minimizes entrainment through flow reduction. The flow reduction achieved, compared to OTC, is calculated at 97.6 percent based on 3.0 COC. The EPA allows broad flexibility in the BTA determination for individual facilities, but also supports closed -cycle cooling as a BTA option for entrainment as confirmed through this statement in the preamble to the Rule: "Although this rule leaves the BTA entrainment determination to the Director, with the possible BTA decisions ranging from no additional controls to closed -cycle recirculating systems plus additional controls as warranted, EPA expects that the Director, in the site - specific permitting proceeding, will determine that facilities with properly operated closed -cycle recirculating systems do not require additional entrainment reduction control measures." Closed -cycle cooling as a potential entrainment BTA is further reiterated in the Response to Public Comments document, where EPA states: 47 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION "EPA has made it clear that a facility that uses a closed -cycle recirculating system, as defined in the rule, would meet the rule requirements for impingement mortality at § 125.94(c)(1). This rule language specifically identifies closed -cycle as a compliance alternative for the [impingement mortality] performance standards. EPA expects the Director would conclude that such a facility would not be subject to additional entrainment controls to meet BTA." The final rule for new facilities as well as the new units provision within the Rule provide similar support for closed -cycle cooling as entrainment BTA at DRCCS: • The final Rule for new facilities published in the Federal Register on December 18, 2001 and with an effective date of January 17, 2002 does prescribe BTA for entrainment, which DRCCS meets. Regulations are more stringent for new facilities than for existing facilities. By virtue of meeting the most stringent entrainment BTA criteria (i.e., applicable to new facilities), DRCCS is compliant for entrainment BTA under the final Rule for existing facilities. • If DRCCS were classified as a new unit at an existing facility, the station would be in compliance with the more stringent requirements stated at §125.94(e), BTA standards for impingement mortality and entrainment for new units at existing facilities. Beyond this regulatory guidance, the number of organisms expected to be entrained at DRCCS is very low. Since entrainment is proportional to flow, reductions in flow equate to commensurate reductions in entrainment. The use of closed -cycle cooling as compared to an equivalent OTC facility is estimated to reduce entrainment by 97.5 percent. 48 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 6 Chosen Method(s) of Compliance with Impingement Mortality Standard [§122.21(r)(6)] The information required to be submitted per 40 CFR § 122.21(r)(6) is as follows: The owner or operator of the facility must identify the chosen compliance method for the entire facility; alternatively, the applicant must identify the chosen compliance method for each cooling water intake structure at its facility. The applicant must identify any intake structure for which a BTA determination for Impingement Mortality under 40 CFR 125.94 (c)(11) or (12) is requested. The Rule at 40 CFR 125.94(c) gives existing facilities seven BTA options for achieving impingement mortality compliance. These are listed below. A facility needs to implement only one of these options. 1. Operate a closed -cycle recirculating system as defined at 40 CFR 125.92(c)(1) (this includes wet, dry or hybrid cooling towers, a system of impoundments that are not WOTUS, or any combination thereof); 2. Operate a cooling water intake structure that has a maximum design through -screen velocity of 0.5 fps or less; 3. Operate a cooling water intake structure that has a maximum actual through -screen velocity of 0.5 fps or less; 4. Operate an existing offshore velocity cap that is a minimum of 800 feet offshore and has bar screens or otherwise excludes marine mammals, sea turtles, and other large aquatic organisms; 5. Operate a modified traveling screen system such as modified Ristroph screens with a fish handling and return system, dual flow screens with smooth mesh, or rotary screens with fish returns. Demonstrate that the technology is or will be optimized to minimize impingement mortality of all non -fragile species; 6. Operate any combination of technologies, management practices, and operational measures that the Director determines is BTA for reducing impingement. As appropriate to the system of protective measures implemented, demonstrate the system of technologies has been optimized to minimize impingement mortality of all non -fragile species; and 7. Achieve a 12-month performance standard of no more than 24 percent mortality including latent mortality for all non -fragile species. Compliance options 1, 2, and 4 are essentially pre -approved technologies that require minimal additional monitoring after their installation and proper operation. Options 3, 5, and 6 require that more detailed information be submitted to the Director before they can be specified as the BTA to reduce impingement mortality. Options 5, 6, and 7 require demonstrations with field studies that the technologies have been optimized to minimize impingement mortality of non -fragile species. In addition, the Rule provides two other impingement compliance BTA options for which the Director may consider little or no additional controls for impingement mortality (USEPA 2014a). These options apply under very specific circumstances. 49 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION • De minimis rate of impingement — if the rates of impingement at a facility are so low that additional impingement controls may not be justified (Section 125.94(c)(11)); and • Low Capacity utilization of generating units — if the annual average capacity utilization rate of a 24-month contiguous period is Tess than 8 percent (Section 125.94(c)(12)). The DRCCS meets the requirements of 40 CFR §125.94(c)(1) (BTA Option #1) based on data provided in Table 5-2. In addition, the MWIS has a design and actual through -screen velocity of <0.5 fps and therefore is compliant with the requirements of 40 CFR §125.94(c)(2) and (3) (BTA Options 2 and 3). By meeting the CCRS criterion (BTA #1) the existing technologies in use at the DRCCS are BTA for impingement mortality compliance. Furthermore, the MWIS has a design through -screen velocity that is Tower than the 0.5fps standard for impingement mortality compliance. 50 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 7 Entrainment Performance Studies [§ 122.21(r)(7)] The information required to be submitted per 40 CFR § 122.21(r)(7), Entrainment performance studies, is as follows: The owner or operator of an existing facility must submit any previously conducted studies or studies obtained from other facilities addressing technology efficacy, through - facility entrainment survival, and other entrainment studies. Any such submittals must include a description of each study, together with underlying data, and a summary of any conclusions or results. Any studies conducted at other locations must include an explanation as to why the data from other locations are relevant and representative of conditions at your facility. In the case of studies more than 10 years old, the applicant must explain why the data are still relevant and representative of conditions at the facility and explain how the data should be interpreted using the definition of entrainment at 40 CFR 125.92(h). 7.1 Site -Specific Studies DRCCS utilizes a CCRS, therefore entrainment (and survival) is not anticipated. Hence, no site -specific entrainment performance studies (such as studies evaluating biological efficacy of specific entrainment reducing technologies or through -facility entrainment survival) have been conducted for the DRCCS. Section 4 of this report provides a discussion of fishery monitoring conducted at or near the facility. Section 5.3 contains information regarding entrainment reductions resulting from lower cooling water withdrawals of the DRCCS as compared to the prior DRSS. 7.2 Studies Conducted at Other Locations As of the date of this report, no entrainment performance studies conducted at other facilities have been determined relevant for documentation in this section. 51 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 8 Operational Status [§ 122.21(r)(8)] The information required to be submitted per 40 CFR §122.21(r)(8), Operational status, is outlined as follows: (I) For power production or steam generation, descriptions of individual unit operating status including age of each unit, capacity utilization rate (or equivalent) for the previous 5 years, including any extended or unusual outages that significantly affect current data for flow, impingement, entrainment, or other factors, including identification of any operating unit with a capacity utilization rate of less than 8 percent averaged over a 24-month block contiguous period, and any major upgrades completed within the last 15 years, including but not limited to boiler replacement, condenser replacement, turbine replacement, or changes to fuel type; (ii) Descriptions of completed, approved, or scheduled uprates and Nuclear Regulatory Commission relicensing status of each unit at nuclear facilities; (iii) For process units at your facility that use cooling water other than for power production or steam generation, if you intend to use reductions in flow or changes in operations to meet the requirements of 40 CFR 125.94(c), descriptions of individual production processes and product lines, operating status including age of each line, seasonal operation, including any extended or unusual outages that significantly affect current data for flow, impingement, entrainment, or other factors, any major upgrades completed within the last 15 years, and plans or schedules for decommissioning or replacement of process units or production processes and product lines; (iv) For all manufacturing facilities, descriptions of current and future production schedules; and, (v) Descriptions of plans or schedules for any new units planned within the next 5 years. Each of these requirements is described in the following subsections. 8.1 Description of Operating Status [§ 122.21(r)(8)(i)] DRCCS is normally used for base load generation. Plant outages typically occur during the spring (February to May) and/or in the fall/winter (October to December) months. 8.1.1 Individual Unit Age DRCCS began commercial operations in December 2012. According to the Duke Energy Carolinas 2020 Integrated Resource Plan (IRP), there is no current projected retirement date for the DRCCS. 8.1.2 Utilization for Previous Five Years Monthly and annual average capacity factor information for 2016-2020 is provided in Table 8-1. Annual capacity factors during this period ranged from 72.6 to 82.1 percent. 52 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Table 8-1. DRCCS Annual Capacity Factors, 2016-2020. Month 2016 2017 2018 2019 2020 January 82.2 80.6 86.4 86.1 80.1 February 88.6 82.2 86.8 88.7 83.0 March 76.2 84.9 85.8 88.8 78.7 April 75.5 36.3 56.1 49.5 43.8 May 54.7 82.7 88.3 89.2 72.5 June 86.0 90.5 79.0 88.6 84.4 July 87.9 91.4 96.0 93.4 91.5 August 85.6 92.8 96.4 93.1 86.4 September 88.6 90.6 64.5 89.8 80.8 October 57.6 68.1 77.6 50.8 80.1 November 91.2 90.9 89.4 0.2 72.0 December 80.6 82.9 78.8 59.8 31.6 Annual Average 79.4 80.9 82.1 72.6 73.4 Note: Annual average may not equal monthly total average due to rounding. 8.1.3 Major Upgrades in Last Fifteen Years As part of a modernization effort, Duke Energy retired DRSS coal-fired generating Units 1-3 in 2012 and replaced them with a new, more efficient, natural gas -fired combined cycle facility on the existing site. DRCCS began commercial operations in December 2012. 8.2 Description of Consultation with Nuclear Regulatory Commission [§122.21(r)(8)(ii)] The DRCCS is not a nuclear fueled unit; therefore, this subsection is not applicable. 8.3 Other Cooling Water Uses for Process Units [§122.21(r)(8)(iii)] The DRCCS is not a manufacturing facility; therefore, this subsection is not applicable. 8.4 Description of Current and Future Production Schedules [§122.21(r)(8)(iv)] The DRCCS is not a manufacturing facility; therefore, this subsection is not applicable. 8.5 Description of Plans or Schedules for New Units Planned within Five Years [§122.21(r)(8)(v)] During the next five years, there are no plans to decommission, replace, or add new units at this facility as stated in the 2020 IRP. 53 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 9 References Becker, G. C. 1983. Fishes of Wisconsin. University of Wisconsin Press, Madison WI. Breder, C. M. 1936. The reproductive habits of North American sunfishes (family Centrarchidae. Zoologica (New York) 21:1-48. Buynak, G. L., and Morh, H. W. 1978. Larval development of the Redbreast Sunfish (Lepomis auratus) from the Sesquehanna River. Transactions of the American Fisheries Society 107:600-604. Carlander, K.D. 1977. Handbook of Freshwater Fishery Biology. Vol. 2. The Iowa State University Press, Ames IA. 431 pp. Coggeshall, L. T. 1924. A study of the productivity and breading habits of the Bluegill, Lepomis pallidus (Mitch.). Proceedings of Indiana Academy of Science 33:315-320. Crowe, W. R. 1959. The Bluegill in Michigan. Michigan Department of Conservation Fish Division Pamphlet 31. Curry, K. D., and A. Spacie. 1984. Differential use of stream habitat by spawning catostomids. American Midland Naturalist 111:267-279. Davis, J. R. 1972. The spawning behavior, fecundity rates, and food habits of the Redbreast Sunfish in southeastern North Carolina. Proceedings of the Annual Conference Southeastern Association of Came and Fish Commissioners 25(1971):556-560. Duke Energy. 2019. Dan River Long -Term Environmental Monitoring Report. Water Resources. Raleigh NC. Ehrlich, K. F. 1974. Chemical changes during growth and starvation of herring larvae. Pages 301-323 in J. H. S. Blaxter, editor. The early life history of fish. Springer-Verlag, New York. Gebhart, Glen E., and Robert C. Summerfelt. 1978. Seasonal Growth of Fishes in Relation to Conditions of Lake Stratification. Oklahoma Cooperative Fishery Research Unit 58 (1978): 6-10. Oklahoma State University, Stillwater OK. Gerald, J. W. 1971. Sound production during courtship in six species of sunfish (Centrarchidae). Evolution 25:75-87. Graham, J. H., and Hastings, R. W. 1984. Distributional patterns of sunfishes on the New Jersey Coastal Plain. Environmental Biology of Fishes 10:137-148. Griffith, G.E., Omemik, J.M., Comstock, M.P., Schafale, W.H., McNab, D.R., Lenat, D.R., and MacPherson, T.F. 2002. Ecoregions of North Carolina. U.S. Environmental Protection Agency, Corvallis OR. (map scale 1:1,500,000). Gross, M. R., and MacMillan, A. M. 1981. Predation and the evolution of colonial nesting in Bluegill sunfish (Lepomis macrochirus). Behavioral Ecology and Sociobiology 8:167-174. Hardy, J.D. 1978. Development of fishes of the Mid -Atlantic Bight. An atlas of egg, larval and juveniles sates, Volume 3. U. S. Fish and Wildlife Services Biological Services ProgramFWS-OBS-78/12. 54 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Jenkins, R.E. and Burkhead, N.M.1994. Freshwater Fishes of Virginia. American Fisheries Society, Bethesda MD. Jenkins, R.E., and Burkhead, N.M. 1993. Freshwater Fishes of Virginia. American Fisheries Society, Bethesda MD. Jenkins, R. E. 1970. Systematic studies of the catostomid fish tribe Moxostomitini. Doctoral dissertation. Cornell University, Ithaca NY. Lachner, E. A., and Wiley, M. L. 1971. Populations of the polytypic species Nocomis leptocephalus (Girard) with a description of a new subspecies. Smithsonian Contributions to Zoology 92. Menhinick, E.F. 1991. The Freshwater Fishes of North Carolina. North Carolina Wildlife Resources Commission, Raleigh, NC. Meyer, W. H. 1962. Life history of three species of redhorse (Moxostoma) in the Des Moines River, Iowa. Transactions of the American Fisheries Society 91:412-419. Miller, T.J., Crowder, L.B., Rice, J.A., Marshall, E.A. 1988. Larval size and recruitment mechanisms in fishes: toward a conceptual framework. Canadian Journal of Fisheries and Aquatic Sciences 45:1657-1670 p. North Carolina Department of Environmental Quality (NCDEQ). 2020. Roanoke River Basin Documents. Accessed February 27, 2020. https://deq.nc.gov/about/divisions/mitigation-services/dms- planning/watershed-planning-documents/roanoke-river-basin North Carolina Department of Environmental Quality (NCDEQ) 2018. Roanoke River Basin Restoration Priorities. October 2009, Amended August 2018. Accessed February 27, 2020. https://files.nc.gov/ncdeq/Mitigation%20Services/Watershed Planning/Roanoke River Basin/R oa noke-RBRP-082018. pdf North Carolina Department of Natural and Cultural Resources (NCDNCR). 2020. North Carolina Natural Heritage Data Explorer element occurrence data. NCDNCR, Raleigh NC. https://deq.nc.gov/about/divisions/water-resources/planning/basin-planning/water-resource- plans/roanoke-2006 Olmsted, L. L., and Cloutman, D. G. 1979. Life history of the Flat Bullhead, Ictalurus platycephalus, in Lake Norman, North Carolina. Transactions of the American Fisheries Society 108:38-42. Pflieger, W. L. 1975. The fishes of Missouri. Missouri Department of Conservation, Columbia MO. Richmond, N.D. 1940. Nesting of the sunfish, (Lepomis auratus (Linnaeus), in tidal waters. Zoologica (New York) 25:329-331. Rohde, F. C., Arndt, J. W., Foltz, and Quattro, J. W. 2009. Freshwater Fishes of South Carolina. University of South Carolina Press, Columbia SC. 430 pp. Smith, C. G. 1977. The biology of three species of Moxostoma (Pisces: Catostomidae) in Clear Creek, Hocking and Fairfield counties, Ohio, with emphasis on the Golden Redhorse, M. erythrurum (Rafinesque). Doctorial dissertation. Ohio State University, Columbus OH. 55 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Snelson, F. F. 1968. Systematics of the cyprinid fish Notropis ameonus, with comments on the subgenus Notropis. Copeia 1968:776-802. Trautman, M. B. 1981. Fishes of Ohio with illustrated keys, revised edition. Ohio State University Press, Columbus OH. United States Environmental Protection Agency (USEPA). 2014. National Pollutant Discharge Elimination System - Final Regulations to Establish Requirements for Cooling Water Intake Structures at Existing Facilities and Amend Requirement at Phase I Facilities; Final Rule. 40 CFR Parts 122 and 125. Federal Register Vol. 79 No. 158. August 15, 2014. United States Fish and Wildlife Service (USFWS). 1987, 1988, 2017. Environmental Conservation Online System (ECOS). Accessed May 3, 2021. https://ecos.fws.gov/ecp/species/1134#conservation P la ns. 56 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Appendices 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Appendix A. Dan River Combined Cycle Station §122.21(r)(2) — (8) Submittal Requirement Checklist. fo 0 0 (4) Source Water Baseline Biological Characterization Data (2)(i) Narrative description and scaled drawings of source waterbody. (2)(ii) Identification and characterization of the source waterbody's hydrological and geomorphological features, as well as the methods used to conduct any physical studies to determine intake's area of influence within the waterbody and the results of such studies. (2)(iii) Locational maps. (3)(i) Narrative description of the configuration of each CWIS and where it is located in the waterbody and in the water column. (3)(ii) Latitude and Longitude of CWIS. (3)(iii) Narrative description of the operation of each CWIS. (3)(iv) Flow distribution and water balance diagram. (3)(v) Engineering drawing of CWIS. (4)(i) A list of the data supplied in paragraphs (r)(4)(ii) through (vi) of this section that are not available and efforts made to identify sources of the data. (4)(ii) A list of species (or relevant taxa) for all life stages and their relative abundance in the vicinity of CWIS. (4)(iii) Identification of the species and life stages that would be most susceptible to impingement and entrainment. (4)(iv) Identification and evaluation of the primary period of reproduction, larval recruitment, and period of peak abundance for relevant taxa. (4)(v) Data representative of the seasonal and daily activities of biological organisms in the vicinity of CWIS. (4)(vi) Identification of all threatened, endangered, and other protected species that might be susceptible to impingement and entrainment at cooling water intake structures. (4)(vii) Documentation of any public participation or consultation with Federal or State agencies undertaken in development of the plan. A-1 Yes Yes Yes Yes Yes Yes Yes Yes Yes, but not applicable because all data is available. Yes Yes Yes Yes Yes Yes, but not applicable. (5) Cooling Water System Data 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION (4)(viii) Methods and QA procedures for any field efforts. (4)(ix) In the case of the owner or operator of an existing facility or new unit at an existing facility, the Source Water Baseline Biological Characterization Data is the information included in (i) through (xii). (4)(x) Identification of protective measures and stabilization activities that have been implemented, and a description of how these measures and activities affected the baseline water condition in the vicinity of CWIS. List of fragile species as defined at 40 CFR 125.92(m) at the facility. Information submitted to obtain Incidental take exemption or authorization for its cooling water intake structure(s) from the U.S. Fish and Wildlife Service or the National Marine Fisheries Service. Narrative description of the operation of the cooling water system and its relationship to CWIS. Number of days of the year the cooling water system is in operation and seasonal changes in the operation of the system. Proportion of the design intake flow that is used in the system. Proportion of design intake flow for contact cooling, non -contact cooling, and process uses. Distribution of water reuse to include cooling water reused as process water, process water reused for cooling, and the use of gray water for cooling. Description of reductions in total water withdrawals including cooling water intake flow reductions already achieved through minimized process water withdrawals. (5)(i) Description of any cooling water that is used in a manufacturing process either before or after it is used for cooling, including other recycled process water flows. (5)(i) Proportion of the source waterbody withdrawn (on a monthly basis). A-2 Yes, but not applicable as no new data have been collected. Yes, noted in report that (i) through (xii) provide this information. Yes Yes Yes, but not applicable. Yes Yes Yes Yes not applicable Yes not applicable Yes u co E 0 i a, a c ar E m c W N Ta 3 0o a, C o O E - (5)(ii) 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Design and engineering calculations prepared by a qualified professional and supporting data to support the description required by paragraph (r)(5)(i) of this section. (5)(iii) Description of existing impingement and entrainment technologies or operational measures and a summary of their performance. Identification of the chosen compliance method for the entire CWIS or each CWIS at its facility. (6)(i) Impingement Technology Performance Optimization Study for Modified Travelling Screen. Two years of biological data collection. Demonstration of Operation that has been optimized to minimize impingement mortality. Complete description of the modified traveling screens and associated equipment. (6)(ii) Impingement Technology Performance Optimization Study for Systems of Technologies as BTA for Impingement Mortality. Minimum of two years of biological data measuring the reduction in impingement mortality achieved by the system. (7)(i) Site -specific studies addressing technology efficacy, through plant entrainment survival, and other impingement and entrainment mortality studies. (7)(ii) Studies conducted at other locations including an explanation of how they relevant and representative. Studies older than 10 years must include an explanation of why the data are still relevant and representative. Description of individual unit age, utilization for previous 5 year, major upgrades in last 15 years. A-3 Yes Yes Yes No, not selected compliance path and thus not applicable. Yes; note that no site -specific studies were conducted at this facility. Yes; note that studies at other locations were not determined to be relevant. not applicable Yes 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Descriptions of completed, approved, or scheduled uprates and Nuclear Regulatory Commission relicensing status of each unit at nuclear facilities. Other cooling water uses and plans or schedules for decommissioning or replacing units. For all manufacturing facilities, descriptions of current and future production schedules. Descriptions of plans or schedules for any new units planned within the next 5 years. Yes, but not applicable. Yes, but not applicable. Yes, but not applicable. Yes 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Appendix B. Engineering Drawings of Cooling Water Intake Structure • Drawing D000830221: Raw Water Intake Screen Downstream Screen T30"HC-24" PS Intake Screen Assembly w/ 3" ABW Connection • Drawing DNROC-GA-M-IS.DS.EN-01: Duke Energy Dan River Combined Cycle Station Raw Water Supply and Wastewater Discharge, Screen and Pump Station Plan • Drawing DNROC-PY-M-IS.DS.EV-01: Duke Energy Dan River Combined Cycle Station Raw Water Supply and Wastewater Discharge, Pump Station and Screen Elevation B-1 1AC•••••"----.. 1. 1 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION 4 '011111•111••••••••••••••••• inn 4/4.16 WO. t. a ! 1 11 *1 —,................. illitlftalle.' =11001111011411 S I SS 7 ININIIMINIMPO11111.111111111111 ••• 11161M1111101111111111111111111111 III IINIIIIIIIIRNIIMMIHN 0 1111111.111"Mit 10 1111111111111111111NN III ti ilia insislom it r 11111 IIII MOO MIS m ' AM, 1 1 NOMMINIMB ii 1111 a 11 I lek 91114111.1111N101111111111111iIIII 1111181111MIIIMINIMMIIM111111111 MIIIIVIIIII. 14=121411111111:11111 tree=glinglinliasei: tr. 0 0 '•••••••••••1•40••••••••••••• 0 0 J SI 2114:4=.4..P.--1 Me. 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W. 4 WON Ce011 /u • Assws MA. OXUS AWA . wAs yol toarA %OM C0'04 AtEA • Zee Pat tritelz wouit two "on Q/mews Amway . esi tikanollidilaCkWar COCCKNII§J.PRISSUNt• AZT ICJY - magma arm ars 4411•40.! grammig. P.M III•b mow 1NMAL FttaZASIE sworwrow Oak J_Qbasaa..me. M. P.Illbaarsole 11,1440140 mo. RAW WATER Igt/JCE SME:Eti COMMA EAU SEP EEN T ar mic .2e P$ WAX! SCRECN AESDISLY r ASW COMEC DO NOT SCALE Isre Mum** mammogram* 4Alusase4asat 1,711,1111 •1•11,111.0.64 reamitAa I4a14111411•011041 0.111.6 fa* 10rAIII • lit • •AN JAN••••• • •II.• • V/ NMI& • le RHEA 0044p4:0 tidal PLANT tux RivtA. NC imp" 'mewl t 0. .41.00a11112,14.110, PC0:11=91 mall t —1 sow en r — .r ilTLaC.... = -. w A-,lam- .a w +++rw ,jI' fiii�i�i�•fit _ ♦!..•..rrf 1<1 r y K .MO._.— 't "{.I"ft,. V.-CT "V-1'[T. Y'Y ^l l Y, l... 1.1 T.' :1"f Y.'i.'Y-/. {. 'd. I 'A Lova•a 1,I3T 4 •• .t•t..� i'1 oaw w `wrw MOMS 111.16 yy-•r.. . • I/ Yt or or ano M Ltd MIN y�•s i�7. ..,.. to �...« ..,. tr.r Mei . rsrw�.w aes wr.•om ..... • t.~mom WI t Minima -mein • i�l?r"t�tw.w.wImo amOWN .•• • _wrreirw_wr.ar 1 atev.e. NM 0 • B-3 • D.t+wb.ny SUNS MOW OM ■lYA wraso O•R. MUM MOS MSS SUPPON ASP , WTI. - POI M.PM& WM .ynutua 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION zl r SEVICAPAY Ord SS WIND& *ON NAIIMESitar- gar— B-4 ti..9.' .a..r. •...• ♦ -R IMYW moan - Ms ▪ rMMtMAI 40.POW 4P 1.i41111.t... sLair of Ili rrrYeti r NO* IOW • raMINN ♦fOno, Ir allihr NM WM MINT O� RAYOI OMpOlO MU *MIN lW WEI OMRY JW IUM FM AMOK On ILwIrUr 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Appendix C. Engineering Calculations for Through - Screen Velocity C-1 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Dan River Combined Cycle Station 316(b) Report Through -Screen Velocity Calculations - Data Sheet Mike Smallwood (rev 2021-0420) E illlll111111111111llllllllllllul lllt11111111111111111111111111 1 1111111111 1111111111111111111 1 11 11111111111111111111111111111 11111111111111111111111111111111 11 11111111111111111111111111111 11 1111 llllll 1111111111111111111 —4575. 91. 50' 0 4.l .1 3100' SCREEN lE1461N 2PLACES -.IF 025. sir i«— 22.7e Enli 11111111lllllllhll111lllllllll 11 11111111111llllllIl 11 11111 11 111 Illlll1111111111 r 11 11 111 lllll1111111111 Y�`�1■ 111I1111111111111111, 1 1 111111111111111111111u4 11 111 IIIt1111111111111t111111ll 11 NOT TO SCALE Source: Johnson Screens, Drawing 116448-2 (2013) 1111111111111111111111111111II11 llllll11111111111111111111111111 111 111 u 11111111111111111111111 I I 01 11111llllllIlllll1111111111 1 flllllllhlul1111llllll11111111111 29.04 Nmn Sown or 2 P NOTE: 1) Cspseey 2,500 GPM re 0251Vsec Maximum Through -Slot Velocity 2) Designed for 10 5 Depth 3) Screen Open Area = 63.78 % Total Screen Ares = 5.044 in, Tote! Saeen Open Area = 3,500 Net Screen Data Screen Open Area = 63.78% Total Screen Area = 5,044 in2 Total Screen Open Area = 3,500 in2 Slot Size = 3.2mm Diameter = 30 in Total Length = 91.5 in Screen Length = 31 in (x2 for each T screen = 62 in) Pump Data Design Flow/Pump = 2,500 gpm Design Intake Flow = 5,000 gpm (assumes two pumps running and one spare) Actual Intake Flow (2016-2020) = 2,417 gpm (3.48 MGD) Screen Source Data: Johnson Screens Drawing 16448-2 (2013) C-2 316(b) Compliance Submittal DAN RIVER COMBINED CYCLE STATION Screen Data Screen Open Area = 63.78% Total Screen Area = 5,044 in2 Total Screen Open Area = 3,500 in2 Slot Size = 3.2mm Diameter = 30 in Total Length = 91.5 in Screen Length = 31 in (x2 for each T screen = 62 in) Pump Data Design Flow/Pump = 2,500 gpm Design Intake Flow = 5,000 gpm (assumes two pumps running and one spare) Actual Intake Flow (2016-2020) = 2,417 gpm (3.48 MGD) Formulas 1: V = QJA 2: A = N*n*D*L*POA conversion factors 1 gallon = 0.1337 ft3 1 minute = 60 seconds Solve for A Using Formula 2 where: V = through screen velocity, fps Q = pump flow, gpm A = surface area of screen open mesh, ft2 N = number of wedgewire screen units (3) D = diameter of wedgewire screen unit, ft L = length of open mesh area for each screen unit, ft POA = percent open area A = (3) * (n) * (2.5) * (5.0) * (0.6378) = 75.14 ft2 Solve for TSV at Design Flow Using Formula 1 TSV = [(5000) * (0.1337) * (1/60)] / (75.14) DIF TSV = 0.15 fps Solve for TSV at Average Flow Using Formula 1 TSV = [(2417) * (0.1337) * (1/60)] / (75.14) AIF TSV = 0.07 fps C-3 Fish Tissue Monitoring of the Dan River DAN RIVER COMBINED CYCLE STATION Eden, North Carolina NPDES Permit # NC0003468 Duke Energy Environmental Sciences Huntersville, NC March 2021 gfe� DUKE ENERGY. Fish Tissue Monitoring of the Dan River DAN RIVER COMBINED CYCLE STATION Contents 1 Introduction 1 2 Methods 3 2.1 Fish Collection 3 2.2 Fish Muscle Tissue Analysis 3 3 Results and Discussion 3 3.1 Fish Collection 3 3.2 Fish Muscle Tissue Analysis 4 4 Summary 6 5 References 6 Tables Table 3-1. Numbers and total length ranges (mm) of different species of fish collected for trace element analyses in the three areas of the Dan River during 2017-2020 4 Table 3-2. Means and ranges of trace elements in fish muscle tissue collected from three sampling areas of the Dan River during 2017, 2019, and 2020. All values are in wet weight (µg/g). USEPA screening values are shown next to each element. When concentrations were less than the reporting limit, the reporting limit value was used for analysis. 4 Figures Figure 1-1. Sampling areas for trace element fish tissue monitoring in the Dan River. 2 Figure 3-1. Box plots of trace element concentrations in fish muscle tissue of sunfish and suckers collected from three areas in the Dan River during 2017, 2019, and 2020. The horizontal line represents the median, the boxes represent the 25th and 75th percentile, and the whiskers show 10th and 90th percentiles. Outliers are shown as points. 5 Appendices Appendix A. Arsenic, selenium, and mercury concentrations (wet weight) in axial muscle of fish from the Dan River during 2017-2020. Fish Tissue Monitoring of the Dan River DAN RIVER COMBINED CYCLE STATION 1 Introduction Duke Energy Carolinas (DEC) owns and operates the Dan River Combined Cycle (DRCC) Station located on the Dan River in Rockingham County, Eden, North Carolina. The DRCC National Pollutant Discharge Elimination System (NPDES) Permit (No. NC0003468, Section A. 24.) requires DEC to conduct annual trace element monitoring of fish muscle tissue, specifically arsenic, selenium, and mercury, associated with ash basin discharges at Outfall 002. This work was conducted in accordance with a study plan (Duke Energy 2017) submitted on August 1, 2017, and the North Carolina Department of Environmental Quality (NCDEQ) subsequently approved on September 6, 2017. Target fish were collected from three areas on the Dan River (Figure 1-1) for trace element analysis of muscle tissue. Area B was located approximately 4.02 km upstream of the plant discharge and served as a reference area for monitoring background trace element concentrations in fish muscle tissue. Area D was in the vicinity of the DRCC discharge point and served to monitor potential near -field uptake of elements in fish muscle tissue. Area E was located approximately 3.22 km downstream of the plant discharge point and served to monitor far -field uptake of trace elements in fish muscle tissue. These areas were similar to those previously monitored for trace elements in fish muscle tissue near the former Dan River Steam Station (DRSS) (Duke Energy 2019). 1 1 aye n• 0 CO Cr m u • 1D • Dan River CC Plant NORTH CAROLINA 0 0 0 0 0 rn w Dan River • CC Plan Fish Tissue Monitoring of the Dan River DAN RIVER COMBINED CYCLE STATION Area D Low Head Dam • Area E Dan River Trace Element Sampling Areas ��DUKE NRGY O 0.25 0.5 1 mi I 1 I I' O 0.5 1 2km Figure 1-1. Sampling areas for trace element fish tissue monitoring in the Dan River. 2 Fish Tissue Monitoring of the Dan River DAN RIVER COMBINED CYCLE STATION 2 Methods 2.1 Fish Collection Fish were collected using boat electrofishing (pulsed DC current). Fish retained for trace element analysis were identified to species, measured for total length to the nearest millimeter, weighed to the nearest gram, and marked with a unique tag identifier. Fish were then placed in a labeled (sample date, sample area, facility, etc.) bag on ice while in the field. Each day the sealed bags of fish were transferred to a deep freezer. Species targeted for collection were based on prior sampling experience, likely availability, importance as food fish, and general trophic level. Species groups identified for collection were suckers (Moxostoma spp.) and sunfish (Lepomis spp.). Each year, DEC personnel collected six individuals of each taxa from each of the three identified sampling areas. Specimens retained for analysis were individuals considered of sufficient size for human consumption (>60 g). At a given site, and as recommended by the U.S. Environmental Protection Agency (USEPA), fish were retained such that the size of the smallest individual was not Tess than 75% of the total length of the largest fish within each taxa group (USEPA 2000). 2.2 Fish Muscle Tissue Analysis All fish were processed in the laboratory for muscle tissue sample preparation and trace element (metals) analysis according to Duke Energy Procedure NR-00107 Rev. 4 Trace Element Monitoring Laboratory Procedure (approved Standard Operating Procedure [SOP] on file with NCDEQ as of the study plan submittal date). Quality control was achieved utilizing analytical standards, replicates, and certified reference materials. Following analysis, residual processed samples were archived and saved for at least two years for possible reanalysis. 3 Results and Discussion 3.1 Fish Collection During the four years evaluated in this report (2017-2020), a total of 144 individuals from each taxon were collected. This total included 24 of each taxon from each sampling area in the Dan River (Table 3- 1). Species collected for analysis included Golden Redhorse Moxostoma erythrurum, Notchlip Redhorse M. collapsum, V-lip Redhorse M. pappillosum, Bluegill Lepomis macrochirus, Redbreast sunfish L. auritus, and Redear Sunfish L. macrochirus. Fish were collected in relative proportions to their abundances in the Dan River with respect to the minimum size requirement. Golden Redhorse and Redbreast Sunfish were the most frequently collected species, although other species were collected where available (Table 3-1). The sizes of suckers and sunfish collected for analysis were generally similar across species and sampling areas (Table 3-1). Raw data for fish collected during 2017-2020 and associated trace element concentrations are presented in Appendix A. 3 Fish Tissue Monitoring of the Dan River DAN RIVER COMBINED CYCLE STATION Table 3-1. Numbers and total length ranges (mm) of different species of fish collected for trace element analyses in the three areas of the Dan River during 2017-2020. Area B Area D Area E Number Total length range Number Total length range Number Total length range Suckers (Moxostoma) Sunfish (Lepomis) Golden Redhorse V-Iip Redhorse Notchlip Redhorse Bluegill Redbreast Sunfish Redear Sunfish 20 295-385 0 4 319-340 0 24 147-195 0 19 2 3 3 18 3 253-366 302-327 327-372 155-171 145-200 154-190 17 1 6 1 19 4 269-352 326 325-345 186 146-187 154-177 3.2 Fish Muscle Tissue Analysis Fish were collected according to the study plan in all years, however the fish collected in 2018 were not analyzed for trace element concentrations due to a freezer failure that resulted in spoilage at the laboratory facility prior to processing. The resulting fish muscle tissue trace element concentrations of the remaining fish were compared to screening values, in wet weight, of 1.2 µg/g for arsenic, 20 µg/g for selenium, and 0.4 µg/g for mercury (USEPA 2000). All fish analyzed during 2017-2020 were below the USEPA screening values for all three trace elements (Table 3-2; Figure 3-1). Table 3-2. Means and ranges of trace elements in fish muscle tissue collected from three sampling areas of the Dan River during 2017, 2019, and 2020. All values are in wet weight (µg/g). USEPA screening values are shown next to each element. When concentrations were less than the reporting limit, the reporting limit value was used for analysis. Arsenic (1.2) Mean Range Selenium (20) Mercury (0.4) Mean Range Mean Range Area B Area D Area E Suckers Sunfish Suckers Sunfish Suckers Sunfish 0.10 0.01-0.16 0.41 0.27-0.67 0.10 0.01-0.16 0.52 0.30-0.72 0.11 0.02-0.17 0.43 0.32-0.60 0.10 0.01-0.15 0.51 0.32-0.92 0.10 0.02-0.17 0.43 0.34-0.53 0.09 0.01-0.16 0.50 0.34-0.84 0.15 0.07 0.16 0.08 0.18 0.07 0.07-0.26 <0.06-0.17 0.10-0.29 <0.06-0.14 0.12-0.25 0.06-0.10 4 Concentration (pg/g freshweight) 0.6 0.5 0.4 Fish Tissue Monitoring of the Dan River DAN RIVER COMBINED CYCLE STATION Sunfish Suckers 0.3 - 0.2 - 0.1 - 0.0 1.2 Arsenic • B D E 1.0 - 0.8 - 0.6 - 0.4 - 1 1 T i Selenium 0.2 - 0.0 0.6 0.5 0.4 0.3 - 0.2 - 0.1 - 0.0 B D E Mercury .4 B D E 0.6 0.5 0.4 0.3 0.2 - 0.1 0.0 1.2 t Arsenic B D E 1.0 - 0.8 - 0.6 - 0.4 0.2 0.0 0.6 0.5 0.4 T E;i Selenium B D E 0.3 - 0.2 - 0.1 - 0.0 • • T 1 B D Mercury • T E Figure 3-1. Box plots of trace element concentrations in fish muscle tissue of sunfish and suckers collected from three areas in the Dan River during 2017, 2019, and 2020. The horizontal line represents the median, the boxes represent the 25th and 75th percentile, and the whiskers show 10th and 90th percentiles. Outliers are shown as points. 5 Fish Tissue Monitoring of the Dan River DAN RIVER COMBINED CYCLE STATION 4 Summary In accordance with NPDES Permit # NC0003468, 72 sunfish and 72 suckers were collected from the Dan River during 2017-2020 for analysis of trace elements in muscle tissue. All samples of fish muscle tissue that were analyzed during this period were below the USEPA screening levels for the three metals analyzed. Additionally, the concentrations of all three metals in fish muscle tissue were not elevated in the near field discharge area when compared to the upstream reference. Fish muscle tissue trace element data collected during 2017-2020 were consistent with data reported previously from the Dan River (Duke Energy 2019). 5 References Duke Energy. 2019. Dan River Long -Term Environmental Monitoring Report. Raleigh, NC. Duke Energy. 2017. Arsenic, Selenium, and Mercury Monitoring in Fish Tissue Study Plan. Dan River Combined Cycle. NPDES No. NC0003468. Charlotte, NC. USEPA. 2000. Guidance for assessing chemical contaminant data for use in fish advisories. Vol. 1. Fish sampling and analysis. Third edition. EPA 823-B-00-007. United States Environmental Protection Agency, Office of Water, Washington, DC. 6 Fish Tissue Monitoring of the Dan River DAN RIVER COMBINED CYCLE STATION Appendices Fish Tissue Monitoring of the Dan River DAN RIVER COMBINED CYCLE STATION Appendix A. Arsenic, selenium, and mercury concentrations (wet weight) in axial muscle fish from the Dan River during 2017-2020. A-1 Fish Tissue Monitoring of the Dan River DAN RIVER COMBINED CYCLE STATION Dry -to - fresh Length Weight As Se Hg weight Fish species Location Sample date (mm) (g) (µg/g) (µg/g) (µg/g) ratio Golden Redhorse B 1/20/2017 346 386 0.01 0.32 0.13 0.19 Golden Redhorse B 1/20/2017 345 420 0.02 0.33 0.09 0.19 Golden Redhorse B 1/20/2017 343 402 0.02 0.40 0.07 0.19 Golden Redhorse B 1/20/2017 337 391 0.02 0.27 0.07 0.20 Golden Redhorse B 1/20/2017 342 426 0.03 0.46 0.13 0.18 Golden Redhorse B 1/20/2017 347 462 0.03 0.48 0.11 0.20 Redbreast Sunfish B 4/10/2017 170 84 0.01 0.43 0.03 0.19 Redbreast Sunfish B 1/20/2017 172 85 0.01 0.30 0.03 0.19 Redbreast Sunfish B 1/20/2017 180 89 0.00 0.48 0.05 0.18 Redbreast Sunfish B 8/10/2017 174 100 0.01 0.47 0.03 0.20 Redbreast Sunfish B 8/10/2017 173 116 0.01 0.55 0.03 0.19 Redbreast Sunfish B 4/10/2017 184 115 0.01 0.30 0.05 0.20 Golden Redhorse D 4/18/2017 362 480 0.04 0.35 0.12 0.19 Golden Redhorse D 1/26/2017 332 390 0.04 0.35 0.14 0.19 Golden Redhorse D 1/25/2017 349 415 0.03 0.41 0.22 0.19 Golden Redhorse D 1/26/2017 323 370 0.06 0.33 0.14 0.18 Golden Redhorse D 1/27/2017 328 377 0.04 0.34 0.10 0.18 Golden Redhorse D 4/18/2017 366 487 0.02 0.34 0.12 0.17 Redbreast Sunfish D 4/18/2017 185 125 0.01 0.39 0.07 0.19 Redbreast Sunfish D 4/18/2017 182 101 0.01 0.35 0.06 0.17 Redbreast Sunfish D 4/18/2017 181 110 0.01 0.43 0.03 0.19 Redbreast Sunfish D 1/25/2017 176 100 0.01 0.52 0.05 0.18 Redbreast Sunfish D 1/26/2017 176 96 0.01 0.32 0.04 0.17 Redbreast Sunfish D 4/18/2017 192 136 0.01 0.44 0.08 0.20 Golden Redhorse E 1/25/2017 340 431 0.03 0.43 0.20 0.18 Golden Redhorse E 1/25/2017 341 424 0.03 0.50 0.16 0.21 Golden Redhorse E 1/25/2017 330 390 0.03 0.42 0.20 0.18 Golden Redhorse E 1/25/2017 345 426 0.03 0.47 0.22 0.20 Golden Redhorse E 1/25/2017 330 348 0.02 0.38 0.23 0.18 Golden Redhorse E 4/19/2017 325 378 0.04 0.41 0.13 0.20 Redbreast Sunfish E 4/19/2017 170 103 0.01 0.39 0.07 0.19 Redbreast Sunfish E 4/19/2017 185 114 0.01 0.34 0.06 0.18 Redbreast Sunfish E 4/19/2017 170 104 0.01 0.40 0.05 0.18 Redbreast Sunfish E 4/19/2017 166 100 0.01 0.47 0.04 0.20 Redbreast Sunfish E 1/25/2017 187 122 0.01 0.45 0.06 0.18 Redbreast Sunfish E 4/19/2017 182 117 0.01 0.46 0.05 0.20 A-2 Fish Tissue Monitoring of the Dan River DAN RIVER COMBINED CYCLE STATION Dry -to - fresh Length Weight As Se Hg weight Fish species Location Sample date (mm) (g) (µg/g) (µg/g) (µg/g) ratio Golden Redhorsel B 6/26/2018 315 273 - - - Golden Redhorsel B 6/26/2018 315 293 - - Golden Redhorsel B 6/26/2018 295 242 - - Golden Redhorsel B 6/26/2018 321 309 - - Golden Redhorsel B 6/26/2018 306 284 - - Golden Redhorsel B 6/26/2018 301 240 - - Redbreast Sunfish' B 6/26/2018 195 136 - - Redbreast Sunfish' B 6/26/2018 162 89 - - Redbreast Sunfish' B 6/26/2018 193 141 - - Redbreast Sunfish' B 6/26/2018 175 114 - Redbreast Sunfish' B 6/26/2018 186 124 - - Redbreast Sunfish' B 6/26/2018 168 93 - Golden Redhorse' D 6/25/2018 294 250 - Golden Redhorse' D 6/25/2018 265 184 - - Golden Redhorse' D 6/25/2018 290 217 - - Golden Redhorse' D 6/25/2018 273 184 - Golden Redhorse' D 6/25/2018 253 152 - Golden Redhorse' D 6/25/2018 280 221 - - Redbreast Sunfish' D 6/25/2018 159 87 Redbreast Sunfish' D 6/25/2018 153 66 - Redbreast Sunfish' D 6/25/2018 154 81 - Bluegill' D 6/25/2018 155 74 Bluegill' D 6/25/2018 171 87 Redbreast Sunfish' D 6/25/2018 163 79 - Golden Redhorse' E 6/25/2018 298 250 - Golden Redhorse' E 6/25/2018 296 248 - Golden Redhorse' E 6/25/2018 299 276 - Golden Redhorse' E 6/25/2018 299 268 - Golden Redhorse' E 6/25/2018 269 208 - Golden Redhorse' E 6/25/2018 274 202 - Redear Sunfish' E 6/25/2018 175 86 - Redear Sunfish' E 6/25/2018 177 92 Redbreast Sunfish' E 6/25/2018 176 112 Redbreast Sunfish' E 6/25/2018 165 83 - Redbreast Sunfish' E 6/25/2018 146 61 Bluegill' E 6/25/2018 186 131 A-3 Fish Tissue Monitoring of the Dan River DAN RIVER COMBINED CYCLE STATION Dry -to - fresh Length Weight As Se Hg weight Fish species Location Sample date (mm) (g) (µg/g) (µg/g) (µg/g) ratio Redbreast Sunfish B 11/19/2019 151 63 0.15 0.55 0.03 0.21 Redbreast Sunfish B 11/19/2019 150 61 0.14 0.72 0.09 0.20 Redbreast Sunfish B 11/19/2019 156 61 0.13 0.55 0.08 0.19 Redbreast Sunfish B 11/19/2019 159 65 0.14 0.57 0.17 0.20 Redbreast Sunfish B 11/19/2019 158 69 0.16 0.65 0.11 0.21 Redbreast Sunfish B 11/19/2019 173 84 0.13 0.46 0.11 0.19 Golden Redhorse B 11/19/2019 343 410 0.15 0.31 0.10 0.20 Golden Redhorse B 11/19/2019 315 288 0.16 0.29 0.13 0.20 Golden Redhorse B 11/19/2019 364 487 0.12 0.27 0.09 0.15 Notchlip Redhorse B 11/19/2019 340 383 0.14 0.67 0.11 0.19 Golden Redhorse B 11/19/2019 356 433 0.14 0.38 0.19 0.19 Notchlip Redhorse B 11/19/2019 319 264 0.13 0.44 0.23 0.17 Golden Redhorse D 6/24/2019 352 327 0.15 0.47 0.16 0.20 V-Iip Redhorse D 6/24/2019 327 323 0.16 0.59 0.21 0.20 Golden Redhorse D 6/24/2019 322 325 0.15 0.48 0.19 0.20 Golden Redhorse D 6/24/2019 309 312 0.16 0.37 0.12 0.20 Golden Redhorse D 6/24/2019 287 251 0.17 0.32 0.16 0.20 V-Iip Redhorse D 6/24/2019 302 251 0.14 0.60 0.13 0.19 Redbreast Sunfish D 6/24/2019 162 83 0.15 0.48 0.08 0.20 Redear Sunfish D 6/24/2019 190 110 0.15 0.92 0.07 0.20 Redbreast Sunfish D 6/24/2019 145 50 0.13 0.54 0.13 0.18 Bluegill D 6/24/2019 156 71 0.14 0.46 0.07 0.19 Redbreast Sunfish D 6/24/2019 145 56 0.14 0.49 0.13 0.19 Redear Sunfish D 6/24/2019 154 58 0.14 0.62 0.07 0.20 Golden Redhorse E 6/24/2019 352 327 0.14 0.38 0.06 0.18 Golden Redhorse E 6/24/2019 315 299 0.14 0.42 0.10 0.19 Golden Redhorse E 6/24/2019 296 284 0.15 0.44 0.17 0.19 Golden Redhorse E 6/24/2019 324 318 0.14 0.40 0.14 0.19 V-lip Redhorse E 6/24/2019 326 309 0.11 0.53 0.12 0.15 Golden Redhorse E 6/24/2019 269 238 0.14 0.44 0.13 0.19 Redbreast Sunfish E 6/24/2019 165 86 0.14 0.51 0.19 0.19 Redbreast Sunfish E 6/24/2019 169 86 0.13 0.56 0.12 0.19 Redbreast Sunfish E 6/24/2019 155 68 0.14 0.62 0.07 0.19 Redbreast Sunfish E 6/24/2019 177 123 0.14 0.48 0.07 0.20 Redbreast Sunfish E 6/24/2019 176 109 0.14 0.41 0.07 0.19 Redbreast Sunfish E 6/24/2019 151 75 0.14 0.43 0.09 0.20 A-4 Fish Tissue Monitoring of the Dan River DAN RIVER COMBINED CYCLE STATION Dry -to - fresh Length Weight As Se Hg weight Fish species Location Sample date (mm) (g) (µg/g) (µg/g) (µg/g) ratio Golden Redhorse B 6/30/2020 385 556 0.15 0.38 0.19 0.19 Golden Redhorse B 6/30/2020 342 357 0.14 0.43 0.20 0.19 Notchlip Redhorse B 6/30/2020 323 301 0.15 0.50 0.23 0.20 Notchlip Red horse B 6/30/2020 323 329 0.14 0.46 0.21 0.21 Golden Redhorse B 6/30/2020 341 388 0.15 0.46 0.26 0.19 Golden Redhorse B 6/30/2020 370 481 0.15 0.44 0.16 0.20 Redbreast Sunfish B 6/30/2020 171 100 0.14 0.51 0.06 0.20 Redbreast Sunfish B 6/30/2020 172 103 0.15 0.51 < 0.06 0.21 Redbreast Sunfish B 6/30/2020 155 71 0.14 0.42 0.06 0.20 Redbreast Sunfish B 6/30/2020 147 63 0.14 0.57 < 0.06 0.20 Redbreast Sunfish B 6/30/2020 159 77 0.14 0.68 < 0.06 0.20 Redbreast Sunfish B 6/30/2020 164 81 0.14 0.56 < 0.06 0.20 Notchlip Redhorse D 6/30/2020 327 304 0.13 0.53 0.17 0.19 Golden Redhorse D 6/30/2020 328 314 0.13 0.41 0.13 0.19 Notchlip Redhorse D 6/30/2020 337 345 0.13 0.46 0.18 0.18 Notchlip Redhorse D 6/30/2020 372 448 0.14 0.57 0.29 0.19 Golden Redhorse D 6/30/2020 314 297 0.15 0.34 0.11 0.20 Golden Redhorse D 6/30/2020 320 296 0.15 0.49 0.18 0.19 Redear Sunfish D 6/30/2020 168 69 0.15 0.60 < 0.06 0.20 Redbreast Sunfish D 6/30/2020 170 104 0.15 0.57 0.07 0.21 Redbreast Sunfish D 6/30/2020 200 155 0.15 0.55 0.09 0.20 Redbreast Sunfish D 6/30/2020 179 94 0.13 0.41 0.06 0.19 Redbreast Sunfish D 6/30/2020 152 63 0.13 0.47 0.14 0.18 Redbreast Sunfish D 6/30/2020 152 63 0.15 0.61 < 0.06 0.20 Notchlip Redhorse E 10/1/2020 332 364 0.15 0.35 0.19 0.18 Notchlip Redhorse E 10/1/2020 345 363 0.16 0.53 0.20 0.19 Notchlip Redhorse E 10/1/2020 330 350 0.15 0.36 0.18 0.19 Notchlip Redhorse E 10/1/2020 325 354 0.16 0.34 0.25 0.18 Notchlip Redhorse E 10/1/2020 340 343 0.14 0.42 0.19 0.18 Notchlip Redhorse E 10/1/2020 342 344 0.14 0.42 0.19 0.19 Redbreast Sunfish E 10/1/2020 155 59 0.14 0.58 0.10 0.19 Redbreast Sunfish E 10/1/2020 156 66 0.13 0.50 0.08 0.19 Redbreast Sunfish E 10/1/2020 165 69 0.13 0.69 0.10 0.19 Redbreast Sunfish E 10/1/2020 165 71 0.15 0.59 0.10 0.20 Redear Sunfish E 10/1/2020 159 58 0.13 0.36 0.09 0.19 Redear Sunfish E 10/1/2020 154 52 0.16 0.84 0.10 0.20 'Note that fish collected from the Dan River in 2018 were not analyzed due to a freezer failure at the laboratory facility. Freezer failure led to deterioration of fish tissue, which disqualified such fish for analyses. A-5