HomeMy WebLinkAboutWQ0002503_Monitoring - 04-2022_20220601(���a?eAnalVfical' ANALYTICAL REPORT
May 20, 2022
Frit Car Inc.
Sample Delivery Group
Samples Received:
Project Number:
Description:
L1488058 `-'
04/30/2022
Bridgeton Facility Moht ly
Report To: Danny Hornbeck
2012 US Hwy 17N
New Bern, NC 28560
Entire Report Reviewed By: 4�il"]
Heather J Wagner
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace
Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and
ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided,
and as the samples are received.
5
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Frit Car Inc. L1488058 05/20/22 08:22 1 of 21
TABLE OF CONTENTS
Cp: Cover Page
Tc: Table of Contents
Ss: Sample Summary
Cn: Case Narrative
Sr: Sample Results
EFFLUENT L1488058-01
Qc: Quality Control Summary
Gravimetric Analysis by Method 2540 C-2011
Gravimetric Analysis by Method 2540 D-2015
Wet Chemistry by Method 300.0
Wet Chemistry by Method 350.1
Wet Chemistry by Method 365.4
Wet Chemistry by Method 420.4
Wet Chemistry by Method 4500H+ B-2011
Wet Chemistry by Method 4500P E-2011
Wet Chemistry by Method 5210 B-2016
Wet Chemistry by Method 5310 B-2014
Metals (ICP) by Method 200.7
GI: Glossary of Terms
AI: Accreditations & Locations
Sc: Sample Chain of Custody
1
RP2
3
4
FS5
5 Fn
7
7 1Sr
8
9 RC
11
�GI
12
18 AI
14
15 ISCI
16
17
18
19
20
21
ACCOUNT: PROJECT:
Frit Car Inc.
SDG: DATE/TIME: PAGE:
L1488058 05/20/22 08:22 2 of 21
SAMPLE SUMMARY
Collected by Collected date/time Received date/time
EFFLUENT L1488058-01 WW Danny Hornbeck 04/29/2213:00 04/30/2209:00 FC(�
Method
Batch
Dilution
Preparation
Analysis
Analyst
Location
date/time
date/time
TC
Gravimetric Analysis by Method 2540 C-2011
WG1859268
1
05/05/2211:51
05/05/2217:03
SJF
Mt. Juliet, TN
Gravimetric Analysis by Method 2540 D-2015
WG1860219
1
05/06/2219:43
05/06/22 21:06
SJF
Mt. Juliet, TN
Wet Chemistry by Method 300.0
WG1860694
10
05/10/22 05:24
05/10/22 05:24
KEG
Mt. Juliet, TN
Wet Chemistry by Method 300.0
WG1860694
500
05/10/22 05:40
05/10/22 05:40
KEG
Mt. Juliet, TN
Wet Chemistry by Method 350.1
WG1858815
10
05/09/2215:43
05/09/2215:43
SL
Mt. Juliet, TN
a
Cn
Wet Chemistry by Method 365.4
WG1863480
400
05/11/22 07:43
05/14/2216:58
LDT
Mt. Juliet, TN
Wet Chemistry by Method 420.4
WG1866242
1
05/19/22 09:01
05/19/2217:34
CAT
Mt. Juliet, TN
Wet Chemistry by Method 4500H+ B-2011
WG1859886
1
05/07/2210:00
05/07/2210:00
GI
Mt. Juliet, TN
Fr
Wet Chemistry by Method 4500P E-2011
WG1856784
1
04/30/2212:25
04/30/2212:25
JAR
Mt. Juliet, TN
Wet Chemistry by Method 5210 B-2016
WG1856842
10
04/30/2212:41
05/05/2210:05
CAY
Mt. Juliet, TN
RC
Wet Chemistry by Method 5310 B-2014
WG1860089
1
05/06/2219:51
05/06/2219:51
VRP
Mt. Juliet, TN
Metals (ICP) by Method 200.7
WG1857707
1
05/05/2213:49
05/06/2217:25
ZSA
Mt. Juliet, TN
Metals (ICP) by Method 200.7
WG1857707
10
05/05/2213:49
05/09/2212:27
ZSA
Mt. Juliet, TN
G1
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Frit Car Inc. L1488058 05/20/22 08:22 3 of 21
CASE NARRATIVE
RP
All sample aliquots were received at the correct temperature, in the proper containers, with the
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples
ITC
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my
Ss
I
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
0
Fr
RC
[GI
Heather J Wagner
AI
Project Manager
BSc
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Frit Car Inc. L1488058 05/20/22 08:22 4 of 21
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EFFLUENT
SAMPLE
RESULTS
- 01
Collected date/time: 04/29/22 13:00
L1488058
Gravimetric Analysis by Method 2540 C-2011
Result
Qualifier RDL
Dilution
Analysis
Batch
FP1
Analyte ug/I
ug/I
date / time
_
ETC
Dissolved Solids 14700000
400000
1
05/05/20221T03
WG1859268
Gravimetric Analysis by Method 2540 D-2015
17S
Result
Qualifier RDL
Dilution
Analysis
Batch
Analyte ug/I
ug/I
date / time
4
Cn
Suspended Solids 171000
2500
1
05/06/2022 21:06
WG1860219
Wet Chemistry by Method 300.0
Result
Qualifier RDL
Dilution
Analysis
Batch
Analyte ug/I
ug/I
date / time
RC
Chloride 7610000
500000
500
05/10/2022 05:40
WG1860694
Sulfate 604000
50000
10
05/10/202205:24
WG1860694
FGI
Wet Chemistry by Method 350.1
YA
Result
Qualifier RDL
Dilution
Analysis
Batch
Analyte ug/I
ug/I
date / time
y
Ammonia Nitrogen 57700
2500
10
05/09/202215:43
WG1858815
SC
Wet Chemistry by Method 365.4
Result
Qualifier RDL
Dilution
Analysis
Batch
Analyte ug/I
ug/I
date / time
Phosphorus,Total 908000
40000
400
05/14/202216:58
WG1863480
Wet Chemistry by Method 420.4
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/I ug/I date / time
Total Phenol by 4AAP ND P1 40.0 1 05/19/202217:34 WG1866242
Wet Chemistry by Method 4500H+ B-2011
Result Qualifier Dilution Analysis Batch
Analyte su date / time
pH 6.13 T8 1 05/07/202210.00 WG1859886
Sample Narrative:
L1488058-01 WG1859886: 6.13 at 20.9C
Wet Chemistry by Method 4500P E-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/I ug/I date / time
Phosphate,Ortho ND 30.0 1 04/30/202212:25 WG1856784
Wet Chemistry by Method 5210 B-2016
Result Qualifier
RDL
Dilution Analysis
Batch
Analyte ug/I
ug/I
date / time
BOD 15700 K1 K5 K8
2000
10 05/05/202210:05
WG1856842
Wet Chemistry by Method 5310 B-2014
Result Qualifier
RDL
Dilution Analysis
Batch
Analyte ug/I
ug/I
date / time
TOC (Total Organic Carbon) 14900
1000
1 05/06/202219:51
WG1860089
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Frit Car Inc. L1488058 05/20/22 08:22 5 of 21
EFFLUENT SAMPLE RESULTS - 01
Collected date/time: 04/29/22 13:00 L1488058
Metals (ICP) by Method 200.7
Result
Qualifier RDL
Dilution Analysis
Batch
Analyte
ug/I
ug/1
date / time
Chromium
28.6
10.0
1 05/06/202217:25
WG1857707
Iron
ND
100
1 05/06/202217:25
WG1857707
Sodium
5500000
10000
10 05/09/202212:27
WG1857707
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Frit Car Inc. L1488058 05/20/22 08:22 6 of 21
s itfitY cssrti ii'K.Y ei'r,r%ca tff�w'i�. .
WG1859268 QUALITY CONTROL SUMMARY
Gravimetrlc Analysis by Method 2540 C-2011 L1488058-01
Method Blank (MB)
C�
(MB) R3789233-1 05/05/22 17:03
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/I ug/I ug/I
Dissolved Solids U 10000 10000
L1488430-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1488430-01 05/05/22 17:03 • (DUP) R3789233-3 05/05/22 17:03
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/I % %
Dissolved Solids 733000 777000 1 5.83 J 2 5
L1489440-09 Original Sample (OS) - Duplicate (DUP)
(OS) L1489440-09 05/05/22 17:03 • (DUP) R3789233-4 05/05/22 17:03
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/I % %
Dissolved Solids 913000 900000 1 1.47 5
Laboratory Control Sample (LCS)
(LCS) R3789233-2 05/05/22 17:03
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte ug/I ug/I % %
Dissolved Solids 2460000 2580000 105 81.7-118
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Frit Car Inc. L1488058 05/20/22 08:22 7 of 21
f r `f.'ii'Pr i 'c�i�i rYi[tL ty .n_ti r..0
WG1860219 QUALITY CONTROL SUMMARY
Gravlmetric Analysis by Method 2540 D-2015 1-1488058-01
Method Blank (MB)
Iinl
(MB) R3789246-1 05/06/22 21:06
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/I ug/I ug/I
Suspended Solids U 2500 2500
L1488103-01 Original Sample (OS) - Duplicate (DUP)
(OS) L1488103-01 05/06/22 21:06 - (DUP) R3789246-3 05/06/22 21:06
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/I % %
Suspended Solids 32400 39200 1 19.0 - 5
L1488639-02 Original Sample (OS) - Duplicate (DUP)
(OS) L1488639-02 05/06/22 21:06 - (DUP) R3789246-4 05/06/22 21:06
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/I % %
Suspended Solids 16000 16000 1 0.000 5
Laboratory Control Sample (LCS)
(LCS) R3789246-2 05/06/22 21:06
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte ug/I ug/I % %
Suspended Solids 951000 1000000 105 87.0-115
u
Fc
FS1
F,---]
u
Fr
FGI
u
5AI
7
s
SC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Frit Car Inc. L1488058 05/20/22 08:22 8 of 21
e i-Y� rY"ter,x. rYti c.Ym_Yt'i at i r x} rYr':
WG1860694
Wet Chemistry by Method 300.0
Method Blank (MB)
(MB) R3790100-1 05/09/22 23:53
MB Result
MB Qualifier MB MDL
MB RDL
Analyte ug/I
ug/I
ug/I
Chloride U
379
1000
Sulfate U
594
5000
L1488025-01 Original Sample (OS) • Duplicate (DUP)
QUALITY CONTROL SUMMARY
L1468058-01
(OS) L1488025-01 05/10/22 03:17 r (DUP) R3790100-3 05/10/22 03:33
Original Result
DUP Result
Dilution DUP RPD
DUP Qualifier DUP RPD
Limits
Analyte
ug/I
ug/I
%
%
Chloride
18100
18500
1 1.97
20
Sulfate
39400
39300
1 0.296
20
L1488317-03 Original Sample (OS) • Duplicate (DUP)
(OS) L1488317-03 05/10/22 10:10 • (DUP) R3790100-6 05/10/22 10:58
Original Result
DUP Result
Dilution DUP RPD
DUP Qualifier DUP RPD
Limits
Analyte ug/I
ug/1
%
%
Chloride 20000
19900
1 0.288
20
Sulfate 28600
28700
1 0.532
20
Laboratory Control Sample (LCS)
(LCS) R3790100-2 05/10/22 00:09
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte ug/I
ug/I
%
%
Chloride 40000
41000
102
90.0-110
Sulfate 40000
41300
103
90.0-110
L1488025-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(0,S) L1488025-01 05/10/22 03:17 • (MS) R3790100-4 05/10/22 03:48 • (MSD) R3790100-5 05/10/22 04:36
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
Analyte ug/I
ug/I
ug/I
ug/I
%
%
%
%
%
Chloride 50000
18100
66900
66200
97.5
96.2
1 80.0-120
0.973
20
Sulfate 50000
39400
85600
85600
92.5
92.4
1 80.0-120
0.0805
20
ACCOUNT: PROJECT: SDG: DATEITIME: PAGE:
Frit Car Inc. L1488058 05/20/22 08:22 9 of 21
WG1860694 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 300.0 L1488058-01
L1488317-03 Original Sample (OS) • Matrix Spike (MS)
(OS) L1488317-03 05/10/22 10:10 • (MS) R3790100-7 05/10/22 11:14
Spike Amount
Original Result
MS Result
MS Rec.
Dilution Rec. Limits
Analyte
ug/I
ug/1
ug/I
%
%
Chloride
50000
20000
69500
99.1
1 80.0-120
Sulfate
50000
28600
76600
96.1
1 80.0-120
MS Qualifier
ACCOUNT: PROJECT: SDG:
Frit Car Inc. L1488058
DATE/TIME:
05/20/22 08:22
PAGE:
10 of 21
WG1858815 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 350.1 L1488058-01
Method Blank (MB)
(MB) R3789846-1 05/09/22 15:38 F P]
MB Result MB Qualifier MB MDL MB RDL Fc
Analyte ug/I ug/I ug/I
Ammonia Nitrogen U 117 250
L1488093-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1488093-01 05/09/22 15:49 • (DUP) R3789846-5 05/09/22 15:50
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/I % %
Ammonia Nitrogen 88200 88500 10 0.385 10
L1488498-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1488498-02 05/09/22 16:25 • (DUP) R3789846-7 05/09/22 16:26
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/I % %
Ammonia Nitrogen ND ND 1 0.000 10
Laboratory Control Sample (LCS)
(LCS) R3789846-2 05/09/22 15:40
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte ug/I ug/1 % %
Ammonia Nitrogen 7500 7510 100 90.0-110
L1488O91-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1488091-01 05/09/22 15:44 • (MS) R3789846-3 05/09/22 15:46 • (MSD) R3789846-4 05/09/22 15:47
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits
Analyte ug/I ug/I ug/I ug/I % % %
Ammonia Nitrogen 5000 ND 5170 5140 99.2 98.8 1 90.0-110
L1488456-01 Original Sample (OS) • Matrix Spike (MS)
(OS) L1488456-01 05/09/22 16:22 • (MS) R3789846-6 05/09/2216:23
Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier
Analyte ug/I ug/I ug/I % %
Ammonia Nitrogen 5000 1900 6720 96.5 1 90.0-110
MS Qualifier MSD Qualifier RPD
0.446
RPD Limits
10
ACCOUNT: PROJECT: SDG:
Frit Car Inc. L1488058
DATE/TIME:
05/20/22 08:22
PAGE:
11 of 21
WG1863480
QUALITY CONTROL SUMMARY
Wet Chemistry by Method 365.4
1-1488058-01
Method Blank (MB)
Cp
(MB) R3791855-1 05/14/22 14:20
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/I ug/I ug/I
F1
Phosphorus,Total U 35.0 100
FS
L1488493-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1488493-01 05/14/2214:28 • (DUP) R3791855-3 05/14/22 14:29
Fn]
Original Result DUP Result Dilution DUP RPD
DUP Qualifier DUP RPD
Limits
Sr
Analyte ug/I ug/I %
%
Phosphorus,Total 3640 3590 1 1.38
20
L1488609-01 Original Sample (OS) • Duplicate (DUP)
�GI
(OS) L1488609-01 05/14/22 14:38 • (DUP) R3791855-6 05/14/2214:39
Original Result DUP Result Dilution DUP RPD
DUP Qualifier DUP RPD
Limits
El
Analyte ug/I ug/I %
%
Phosphorus,Total ND ND 1 0.000
20
FC
Laboratory Control Sample (LCS)
(LCS) R3791855-2 05/14/22 14:21
Spike Amount LCS Result LCS Rec. Rec. Limits
LCS Qualifier
Analyte ug/I ug/I % %
Phosphorus,Total 3780 4000 106 83.2-116
L1488493-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1488493-01 05/14/22 14:28 • (MS) R3791855-4 05/14/22 14:30 • (MSD) R3791855-5 05/14/22 14:32
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/I ug/I ug/I ug/I % % % % %
Phosphorus,Total 2500 3640 5750 6010 84.4 94.8 1 90.0-110 _ 4.42 20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Frit Car Inc. L1488058 05/20/22 08:22 12 of 21
WG1866242 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 420.4 1-1488058-01
Method Blank (MB)
(MB) R3793961-1 05/19/22 17:18
MB Result
Analyte ug/I
Total Phenol by 4AAP U
MB Qualifier MB MDL MB RDL
ug/I ug/1
8.30 40.0
L1486932-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1486932-02 05/19/22 17:20 • (DUP) R3793961-3 05/19/22 17:21
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/I °% %
Total Phenol by 4AAP ND NO 1 0.000 20
L1488058-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1488058-01 05/19/22 17:34 • (DUP) R3793961-6 05/19/22 17:34
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/1 ug/I % %
Total Phenol by 4AAP ND ND 1 200 P20
Laboratory Control Sample (LCS)
(LCS) R3793961-2 05/19/22 17:19
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte ug/1 ug/I % °%
Total Phenol by 4AAP 500 504 101 90.0-110
L1488O09-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1488009-02 05/19/22 17:29 • (MS) R3793961-4 05/19/22 17:30 • (MSD) R3793961-5 05/19/22 17:31
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/I ug/I ug/1 ug/I % % % % %
Total Phenol by 4AAP 1000 ND 879 879 87.9 87.9 1 90.0-110 1 0.0341 20
L1488703-02 Original Sample (OS) • Matrix Spike (MS)
(OS) L1488703-02 05/19/22 17:40 • (MS) R3793961-7 05/19/22 17:41
Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier
Analyte ug/1 ug/I ug/I % %
Total Phenol by 4AAP 1000 ND 894 89A 1 90.0-110 Ji5
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Frit Car Inc. L1488058 05/20/22 08:22 13 of 21
WG1859886 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 4500H+ g-2011 L1488058-01
L1488676-06 Original Sample (OS) • Duplicate (DUP)
'C
(OS) L1488676-06 05/07/22 10:00 • (DUP) R3789183-3 05/07/22 10:00
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte su Su
pH 6.46 6.49 1 0.463 1
Sample Narrative:
OS: 6.46 at 20.8C
DUP: 6.49 at 20.8C
Laboratory Control Sample (LCS)
(LCS) R3789183-1 05/07/22 10:00
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte su su
pH 10.0 9.95 99.5 99.0-101
Sample Narrative:
LCS: 9.95 at 203C
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Frit Car Inc. L1488058 05/20/22 08:22 14 of 21
WG1856784 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 4500P E-2011 L1488058-01
Method Blank (MB)
(MB) R3786723-1 04/30/2212:23
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/I ug/I ug/I�-
Phosphate,Ortho U 14.0 30.0 "
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3786723-2 04/30/2212:23 • (LCSD) R3786723-3 04/30/22 12:24
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/I ug/I ug/I % % % % %
Phosphate,Ortho 245 240 253 98.2 103 85.0-115 5.27 20
L1487818-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1487818-01 04/30/2212:24 • (MS) R3786723-4 04/30/2212:24 • (MSD) R3786723-5 04/30/22 12:25
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/I ug/I ug/I ug/1 % % % % %
Phosphate,Ortho 500 513 964 992 90.2 95.8 1 80.0-120 2.86 20
ACCOUNT: PROJECT: SDG:
Frit Car Inc. L1488058
DATE/TI M E:
05/20/22 08:22
PAGE:
15 of 21
WG1856842 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 5210 B-2016 L1488058-01
Method Blank (MB)
(MB) R3788637-1 05/05/22 11:04
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/I ug/I ug/I
TC;
BOD 923 31 200 200
FS
L1488032-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1488032-02 05/05/22 09:57 • (DUP) R3788637-3 05/05/22 09:59
[�n]
Original Result DUP Result Dilution DUP RPD
DUP Qualifier DUP RPD
Limits
Sr
Analyte ug/I ug/I %
%
BOD 11700 13800 1 16.4
30
Laboratory Control Sample (LCS)
GI
(LCS) R3788637-2 05/05/22 08:58
Spike Amount LCS Result LCS Rec. Rec. Limits
LCS Qualifier,
7Al
Analyte ug/I ug/I % %
BOD 198000 223000 113 84.6-115
FS—C
Laboratory Control Sample (LCS)
(LCS) R3788637-4 05/05/22 10:11
Spike Amount LCS Result LCS Rec. Rec. Limits
LCS Qualifier
Analyte ug/I ug/I % %
BOD 198000 256000 129 84.6-115
ACCOUNT: PROJECT: SDG:
Frit Car Inc. L1488058
DATElrIME:
05/20/22 08:22
PAGE:
16 of 21
WG1860089 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 5310 B-2014 L1488058-01
Method Blank (MB)
FC
(MB) R3789240-2 05/06/22 15:04
MB Result MB Qualifier MB MDL MB RDL
l
Analyte ug/I ug/1 ug/I
Tc
TOC (Total Organic Carbon) 616 102 1000
_
FS
L1487994-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1487994-01 05/06/2219:10 • (DUP) R3789240-3 05/06/22 19:31
FCn]
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUPRPD
Fr
Analyte ug/I ug/I % %
TOC (Total Organic Carbon) 10100 10100 1 0.297 20
L1488317-03 Original Sample (OS) • Duplicate (DUP)
7G1
(OS) L1488317-03 05/07/22 00:40 • (DUP) R3789240-8 05/07/22 01:00
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
AI
Analyte ug/I ug/I % %
TOC (Total Organic Carbon) 9150 8760 1 4.33 20
FC
Laboratory Control Sample (LCS)
(LCS) R3789240-1 05/06/22 14:51
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte ug/I ug/I % %
TOC (Total Organic Carbon) 75000 78900 105 85.0-115
L1488111-17 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1488111-17 05/06/22 20:23 • (MS) R3789240-4 05/06/22 20:49 • (MSD) R3789240-5 05/06/22 21:18
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution
Rec. Limits MS Qualifier MSD Qualifier RPD
RPD Limits
Analyte ug/I ug/1 ug/I ug/I % %
% %
%
TOC (Total Organic Carbon) 50000 ND 52900 53000 104 104 1
80.0-120 0.227
20
L1488111-19 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1488111-19 05/06/22 22:11 • (MS) R3789240-6 05/06/22 22:38 • (MSD) R3789240-7 05/06/22 23:05
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution
Rec. Limits MS Qualifier MSD Qualifier RPD
RPD Limits
Analyte ug/I ug/I ug/1 ug/1 % %
% %
%
TOC (Total Organic Carbon) 50000 ND 51500 51600 101 102 1
80.0-120 0.369
20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Frit Car Inc. L1488058 05/20/22 08:22 17 of 21
WG1857707 QUALITY CONTROL SUMMARY
Metals (ICP) by Method 200.7 L1488058-01
Method Blank (MB)
CP
(MB) R3789385-1 05/06/22 16:48
MB Result M8 Qualifier MB MDL MB RDL
1TC
Analyte ug/I ug/I ug/I
Chromium U 1.63 10.0
Iron U 20.5 100
FSSI
Sodium U 444 1000
rCn
Laboratory Control Sample (LCS)
(LCS) R3789385-2 05/06/22 16:51
Sr
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte ug/I ugh % %
Chromium 1000 953 95.3 85.0-115
Iron 10000 9590 95.9 85.0-115
Sodium 10000 10100 101 85.0-115
GI
Spike Matrix Spike Duplicate
CAI
L1486192-01 Original Sample (OS) Matrix (MS)' (MSD)
(OS) L1486192-01 05/06/22 16:53 • (MS) R3789385-4 05/06/22 16:59 • (MSD) R3789385-5 05/06/22 17:01
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution
Rec. Limits MS Qualifier
MSD Qualifier RPD
RPD Limits
Iq
Analyte ug/I ug/I ug/I ug/I % %
%
%
%
Chromium 1000 ND 990 986 98.3 98.0 1
70.0-130
0.338
20
Iron 10000 ND 9810 9820 97.5 97.6 1
70.0-130
0.115
20
Sodium 10000 7300 17100 17200 98.0 99.1 1
70.0-130
0.606
20
L1488164-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1488164-01 05/06/22 17:04 • (MS) R3789385-6 05/06/22 17:06 • (MSD) R3789385-7 05/06/22 17:09
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution
Rec. Limits MS Qualifier
MSD Qualifier RPD
RPD Limits
Analyte ug/I ug/I ug/I ug/I % %
%
%
%
Chromium 1000 ND 966 984 96.6 98.4 1
70.0-130
1.81
20
Iron 10000 NO 9660 9860 96.6 98.6 1
70.0-130
2.06
20
Sodium 10000 14700 24200 24300 95.5 95.9 1
70.0-130
0.193
20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Frit Car Inc. L1488058 05/20/22 08:22 18 of 21
GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
MDL Method Detection Limit.
ND
Not detected at the Reporting Limit (or MDL where applicable).
RDL
Reported Detection Limit.
Rec.
Recovery.
RPD
Relative Percent Difference.
SDG
Sample Delivery Group.
U
Not detected at the Reporting Limit (or MDL where applicable).
Anatyte
The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
Dilution
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
Limits
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample
The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier
reported. If a Qualifier is present, a definition per Qualifier Is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL"
Result
(Below Detectable Levels). The Information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma.
A brief discussion about the included sample results, including a discussion of any non -conformances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
This section of the report includes the results of the laboratory quality control analyses required by procedure or
Summary (Qc)
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
Custody (Sc)
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
This section of your report will provide the results of all testing performed on your samples. These results are provided
Sample Results (Sr)
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)
This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier Description
B1 The blank depletion was greater than the recommended maximum depletion of 0.2mg/L.
E The analyte concentration exceeds the upper limit of the calibration range of the instrument established by the initial
calibration ([CAL).
J The identification of the analyte is acceptable; the reported value is an estimate.
J3 The associated batch QC was outside the established quality control range for precision.
J6 The sample matrix interfered with the ability to make any accurate determination; spike value is low.
J+ The associated batch QC was outside the upper control limits; associated data has a potential positive bias.
Kt The sample dilutions set-up for the BOD/CBOD analysis did not meet the oxygen depletion criteria of at least 2 mg/L.
Reported result is an estimated value.
K5 The Dilution water D.O. depletion was > 0.2 mg/L.
K8 Glucose/glutamic acid BOD/CBOD was above method acceptance levels.
P1 RPD value not applicable for sample concentrations less than 5 times the reporting limit.
T8 Sample(s) received past/too close to holding time expiration.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Frit Car Inc. L1488058 05/20/22 08:22 19 of 21
ACCREDITATIONS & LOCATIONS
Pace Analytical National 12O65 Lebanon Rd Mount Juliet, TN 37122
Alabama
40660
Nebraska
NE-05-15-05
Alaska
17-026
Nevada
TN000032021-1
Arizona
AZ0612
New Hampshire
2975
Arkansas
88-0469
New Jersey-NELAP
TNO02
California
2932
New Mexico'
TN00003
Colorado
TN00003
New York
11742
Connecticut
PH-0197
North Carolina
Env375
Florida
E87487
North Carolina
DW21704
Georgia
NELAP
North Carolina'
41
Georgia'
923
North Dakota
R-140
Idaho
TN00003
Ohio-VAP
CL0069
Illinois
200008
Oklahoma
9915
Indiana
C-TN-01
Oregon
TN200002
Iowa
364
Pennsylvania
68-02979
Kansas
E-10277
Rhode Island
LA000356
Kentucky' 6
KY90010
South Carolina
84004002
Kentucky Z
16
South Dakota
n/a
Louisiana
A130792
Tennessee' °
2006
Louisiana
LA018
Texas
T104704245-20-18
Maine
TN00003
Texas5
LABO152
Maryland
324
Utah
TN000032021-11
Massachusetts
M-TNO03
Vermont
VT2006
Michigan
9958
Virginia
110033
Minnesota
047-999-395
Washington
C847
Mississippi
TN00003
West Virginia
233
Missouri
340
Wisconsin
998093910
Montana
CERT0086
Wyoming
A21-A
A21-A -ISO 17025
1461.01
AIHA-LAP,LLC EMLAP
100789
QLA - ISO 17025 5
1461.02
DOD
1461.01
Canada
1461.01
USDA
P330-15-00234
EPA-Crypto
TN00003
Drinking Water 2 Underground Storage Tanks 3 Aquatic Toxicity 4 Chemical/Microbiological 'Mold 6 Wastewater n/a Accreditation not applicable
Not all certifications held by the laboratory are applicable to the results reported in the attached report.
Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Frit Car Inc. L1488058 05/20/22 08:22 20 of 21
Company Name/Address.
Billing Information:
AnRl
i Chain of Custody Page — of
Frit Car Inc.
Accounts Payable
rhk
PO Box 1340
ace,
2012 US Hwy 17N
Brewton, AL 36427
New Bern, NC 28560
CL
0
MT JULIET, TN
TN 37122
Report to.
En3d T-i.-eb+xnei,@frttcarnc.com
Vc
e
006s Lfhan- Rd Mt
W"'V rice '-—I the
. 1i`dC-&f..-.t
Project Description,
C;ty/State
13 Air-
Please Circle
Bridgeton Facility Monthly
Collected:
PT MT CT E7
I
hl
ttmlhA
SDG
Phone 252-638-694W
Client Project$$
Lab Project 0
2 Cc -7
FRITINCNBNC-MONTHLY
Ln
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Collected by (print):
Sile/Facoity!D #
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Acctnum: FIRITINCNBNC
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LL
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WS
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tie
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Collected by (signature)
Rush? (Lab MUST Be Notified) Quote #
Same Day Five Day
:3�
E
.6
E
E
o.
CL
z
Prelogin: P915246
Next Day v 5 Day {Bad Orly) Date Results Needed
S
CL
E
0
U-1
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<
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0
X
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PM. 873 - Heather I Wagner
Immediately
— Two Day 10 Day (Rad Only) Pi
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Packed on Ice N Y
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Shipped viaFed EX Ground
SampipID
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Depth Date
0
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X
0
0
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WW
X
X
X
X
X
X
X
X
X
X
Matrix, Remarks:
SS - Soil AIR - Air F - Filter pH Temp CDC Seal Present/intact- .-NP Y-N
COC Signed/Accurato: N
GW Groundwater 8-Bioassay intact'. N
Flow_,_,__ Other__,.____ Bottles arrive
-N
WW - Wastewater Correct
DW - Drinking Water Samples returned via: sufficient volum.p. sent: —N
OT Other— if Applicable
VC..ner Tracking # S-6 71 5-3 �7-2 4,,
-UPS -FedEx V0A Zero Headspace: N
Relinquished by (Signature) Dat rin, e Received by (Signaturul Trip Blank Received: Yes 0 Pre3erVatiOn
RAD Screen <0.51 mR/br:
HCL1 MeoH
TBR
Relinquished by (Signature)
Date
Time:
Received by (Signature)
Temp: c Bottles Receved:
if preservation required by Login: Date/Time
Relinquished by: (Signature)
Date
Time
RR e �*r lab T-r tu
Date: Time;
4old:
Condit n
&Z-)p
F 0
7
FORM: NDAR-1 08-11 NON -DISCHARGE APPLICATION REPORT (NDAR-1) Page of
Permit No.: WQ0002503•
` •
D irrigation
�i
• occurYES
Area (acres):'
Area acres):
Area (acres):
Area (acres):
at this facility?
NO
• '.
1 1
• '.
. '.
,
Annual Rate (in):;
Annual Rate (in):]
Annual Rate (in):
••. •Field
Irrigated
0 •
1111111112T-31. Mi. •.
•
•Irrigated?•Field
Irrigated?•
Monthly... .
1 11
2 I`sFloat._-
12 Month • •
r
FORM: NDAR-1 08-11 NON -DISCHARGE APPLICATION REPORT (NDAR-1) Page of
Did the application rates exceed the limits in Attachment B of your permit?
0 Compliant
❑ Non -Compliant
Were adequate measures taken to prevent effluent ponding in or runoff from the sites?
[ ]Compliant
❑Non -Compliant
Was a suitable vegetative cover maintained on all sites as specified in your permit?
[J Compliant
❑ Non -Compliant
Were all setbacks listed in your permit maintained for every application to each permitted site?
2 Compliant
❑ Non -Compliant
Were all freeboards maintained in accordance with the specified freeboard heights in your permit?
❑Compliant
❑Non -Compliant
If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance. Provide in your explanation the date(s) of
the non-compliance and
describe the corrective
action(s) taken. Attach additional sheets if necessary.
Operator in Responsible Charge (ORC) Certification Permittee Certification I
ORC: Danny Hornbeck
Certification No.: 26718
Grade: Phone Number: 252-638-2675
Has the ORC changed since the previous NDAR-1? ❑ Yes ❑ No
Permittee:
Frit Car, Inc.
Signing Official: Michael Newby
Signing Official's Title: Senior Vice President
Phone Number: 51-867-7752 Permit Exp.: 6/30/22
M A- .
r;iiii— �/
5/25/22 ' 5/25/22
Signature Date Signature Date
By this signature, I certify that this report is accurrate and complete to the best of my knowledge. I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance
with a system designed to assure that all qualified personnel properly gathered and evaluated the information submitted. Based on my
inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the
information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.
Mail Original and Two Copies to:
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
FORM: NDMR 07-13 NON -DISCHARGE MONITORING REPORT (NDMR) Page
Permit No.: W00002503
Facility Name: Frit Car, Inc.
County: Craven
Month: April
Year: 2022
PPI:
Flow Measuring Point: [ j Influent ❑� Effluent ❑ No flow generated
Parameter Monitoring Point: ❑ Influent O Effluent Groundwater Lowering ❑ Surface water
Parameter Code 0
50050
00400
00945
00310
00940
C0665
00610
00680
00660
00929
70300
C0530
N
O
>=
Oco
U
00
N
O
O
O a 0
U
o
a
O
E
EOf
Q
U
UC
O
O
i
F
0L
u,
O
o
toE
j
°O
O o
E�
Nrn
O
cn
r
24-hr
hrs
GPD
su
mg/L
mg/L
mg/L
mg/L
I mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
1
07:00
8
6.13
604
15.7
7610
908
57.7
14.9
<.03
5500
14700
171
2
3
4
07:00
8
60
5
07:00
8
6
07:00
8
7
07:00
8
8
1 07:00
8
9
10
11
07:00
8
12
07:00
8
13
07:00
8
141
07:00
8
15
07:00
8
16
17
18
07:00
8
19
07:00
8
201
07:00 1
8
70
21
07:00
8
22
07:00
8
23
24
25
07:00
8
261
07:00
8
27
07:00
8
28
07:00
8
29
07:00
8
30
31
Average:
65
604.00
15.70
7,610.00
908.00
57.70
14.90
0.00
5,500.00
14,700.00
171.00
Daily Maximum:
70
6.13
604.00
15.70
7,610.00
908.00
57.70
14.90
0.03
5,500.00
14,700.00
171.00
Daily Minimum:
60
6.13 1
604.00
15.70
7,610.00
908.00
57.70
14.90
0.03
5,500.00
14,700.00
171.00
Sampling Type:
Monthly Avg. Limit:
Daily Limit:
Sample Frequency:
FORM: NDMR 07-13
NON -DISCHARGE MONITORING REPORT (NDMR)
Sampling Person(s) Certified Laboratories
Name: Danny Hornbeck Name: Pace Analytical
Name: Name:
Page of
Does all monitoring data and sampling frequencies meet the requirements in Attachment A of your permit? E) Compliant ❑ Non -Compliant
If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance. Provide in your explanation the date(s) of the non-compliance and describe the corrective
action(s) taken. Attach additional sheets if necessary.
Operator in Responsible Charge (ORC) Certification
Permittee Certification
ORC: Danny Hornbeck
Permittee: Frit Car, Inc.
Certification No.: 26718
Signing Official: Michael Newby
Grade: Phone Number: 252-638-2675
Signing Official's Title: Senior Vice President
Has the ORC changed since the previous NDMR? ❑ yes No
Phone Number: 251-867-7752 Permit Expiration: 6/30/2022
P!!22�
(--7"
1 5/25/2022
5/25/2022
Signature Date
nature Date
By this signature, I certify that this report is accurrate and complete to the best of my knowledge.
I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that all qualified personnel properly gathered and evaluated the information
submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for
gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for
knowing violations.
Mail Original and Two Copies to:
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617