NC0025534_Renewal (Application)_20220912 (3)

ROY COOPER gJJ u
Governor
ELIZABETH S.BISER `• ^�..0-
Secretary QuAni
RICHARD E.ROGERS,JR. NORTH CAROLINA
Director Environmental Quality
September 12, 2022
City of Hendersonville
Attn: Garrett Demoss, Jr.
305 Williams Street
Hendersonville, NC 28792-1670
Subject: Permit Renewal
Application No. NC0025534
Hendersonville WWTP
Henderson County
Dear Applicant:
The Water Quality Permitting Section acknowledges the September 12, 2022 receipt of your permit renewal application
and supporting documentation. Your application will be assigned to a permit writer within the Section's NPDES WW
permitting branch. Per G.S. 150E-3 your current permit does not expire until permit decision on the application is made.
Continuation of the current permit is contingent on timely and sufficient application for renewal of the current permit. The
permit writer will contact you if additional information is required to complete your permit renewal. Please respond in a
timely manner to requests for additional information necessary to allow a complete review of the application and renewal
of the permit.
Information regarding the status of your renewal application can be found online using the Department of Environmental
Quality's Environmental Application Tracker at:
https://deq.nc.gov/permits-regulations/permit-guidance/environmental-application-tracker
If you have any additional questions about the permit, please contact the primary reviewer of the application using the
links available within the Application Tracker.
Sinc ely,
Wren Thedford
Administrative Assistant
Water Quality Permitting Section
ec: WQPS Laserfiche File w/application
IGD_E Q L North Carolina Department of En S Highway 70 I Swannanoa.North Carolina 28778
��� �� 828 296 4500

EPA Identification Number NPDES Permit Number • Facility Name Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
Form U.S.Environmental Protection Agency
2A a EPA Application for NPDES Permit to Discharge Wastewater
NPDES NEW AND EXISTING PUBLICLY OWNED TREATMENT WORKS
SECTION 1.BASIC APPLICATION INFORMATION FOR ALL APPLICANTS(40 CFR 122.21(j)(1)and(9))
1.1 Facility name 1. E E 9/ED
City of Hendersonville WWTP `
Mailing address(street or P.O.box) r' 0 9 2022
99 Balfour Rd.
City or town NCEMDWR/NPD 792 de
0 Hendersonville N.C.
EContact name(first and last) Title Phone number Email address
Garrett DeMoss Facilities Manager/ORC [phone] [e-mail]
c
Location address(street,route number,or other specific identifier) ❑✓ Same as mailing address
City or town State ZIP code
1.2 Is this application for a facility that has yet to commence discharge?
❑ Yes 4 See instructions on data submission 0 No
requirements for new dischargers.
1.3 Is applicant different from entity listed under Item 1.1 above?
❑ Yes No 4 SKIP to Item 1.4.
Applicant name
Applicant address(street or P.O.box)
0
0 City or town State ZIP code
0.
Contact name(first and last) Title Phone number Email address
0.
a 1.4 Is the applicant the facility's owner,operator,or both?(Check only one response.)
❑ Owner 0 Operator 0 Both
1.5 To which entity should the NPDES permitting authority send correspondence?(Check only one response.)
❑ Facility Applicant ❑ Facility and applicant
(they are one and the same)
1.6 Indicate below any existing environmental permits.(Check all that apply and print or type the corresponding permit
number for each.)
p
Existing Environmental Permits
❑ NPDES(discharges to surface ❑ RCRA(hazardous waste) ❑ UIC(underground injection
water) control)
E
o ❑ PSD(air emissions) ❑ Nonattainment program(CAA) ❑ NESHAPs(CAA)
rn
y ❑ Ocean dumping(MPRSA) ❑ Dredge or fill(CWA Section 0 Other(specify)
1.11
404)
WQ0011381Hendersonville
EPA Form 3510-2A(Revised 3-19) Page 1

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
1.7 Provide the collection system information requested below for the treatment works.
Municipality Population Collection System Type
Served Served (indicate percentage) Ownership Status
Hendersonville 20,000 100 %separate sanitary sewer 0 Own 0 Maintain
-so
%combined storm and sanitary sewer 0 Own ❑ Maintain
co 0 Unknown El Own 0 Maintain
c Laurel Park 1,600 100 %separate sanitary sewer 0 Own ❑ Maintain
o %combined storm and sanitary sewer 0 Own ❑ Maintain
0_
❑ Unknown 0 Own 0 Maintain
o %separate sanitary sewer 0 Own ❑ Maintain
%combined storm and sanitary sewer ❑ Own 0 Maintain
tv
E. ❑ Unknown ❑ Own ❑ Maintain
E; %separate sanitary sewer ❑ Own 0 Maintain
to %combined storm and sanitary sewer 0 Own ❑ Maintain
c 0 Unknown 0 Own ❑ Maintain
o
Total
d Population
c� Served
Separate Sanitary Sewer System Combined Storm and
Sanitary Sewer
Total percentage of each type of ° °
sewer line(in miles) 100 /° /°
Z' 1.8 Is the treatment works located in Indian Country?
c
000 ElYes 0 No
c 1.9 Does the facility discharge to a receiving water that flows through Indian Country?
c 0 Yes 0 No
1.10 Provide design and actual flow rates in the designated spaces. Design Flow Rate
4.8 mgd
toAnnual Average Flow Rates(Actual)
aTwo Years Ago Last Year This Year
c 2.637 mgd 2.748 mgd 2.223 mgd
2'IZ
w Maximum Daily Flow Rates(Actual)
CO
c Two Years Ago Last Year This Year
7.670 mgd 8.242 mgd 6.620 mgd
1.11 Provide the total number of effluent discharge points to waters of the United States by type.
c Total Number of Effluent Discharge Points by Type
a > Combined Sewer Constructed 1
s Treated Effluent Untreated Effluent Overflows Bypasses Emergency
Overflows
H
G 1
EPA Form 3510-2A(Revised 3-19) Page 2

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
Outfalls Other Than to Waters of the United States
1.12 Does the POTW discharge wastewater to basins,ponds,or other surface impoundments that do not have outlets for
discharge to waters of the United States?
0 Yes 0 No 4 SKIP to Item 1.14.
1.13 Provide the location of each surface impoundment and associated discharge information in the table below.
Surface Impoundment Location and Discharge Data
Average Daily Volume Continuous or Intermittent
Location Discharged to Surface
Impoundment (check one)
O Continuous
gpd ❑ Intermittent
O Continuous
gpd
❑ Intermittent
O Continuous
y gpd ❑ Intermittent
v
2 1.14 Is wastewater applied to land?
2 ❑ Yes 0 No 4 SKIP to Item 1.16.
c 1.15 Provide the land application site and discharge data requested below.
y Land Application Site and Discharge Data
c Continuous or
c Average Daily Volume
Location Size Intermittent
Applied
pp (check one)
co acresgpd ❑ Continuous
o ❑ Intermittent
acres d ❑ Continuous
0 9P 0 Intermittent
acresgpd 0 Continuous
10 0 Intermittent
u)
1.16 Is effluent transported to another facility for treatment prior to discharge?
o 0 Yes ElNo 4 SKIP to Item 1.21.
1.17 Describe the means by which the effluent is transported(e.g.,tank truck,pipe).
1.18 Is the effluent transported by a party other than the applicant?
0 Yes ✓❑ No 4 SKIP to Item 1.20.
1.19 Provide information on the transporter below.
Transporter Data
Entity name Mailing address(street or P.O.box)
City or town State ZIP code
Contact name(first and last) Title
Phone number Email address
EPA Form 3510-2A(Revised 3-19) Page 3

1
EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
1.20 In the table below, indicate the name,address,contact information, NPDES number,and average daily flow rate of the
receiving facility.
Receiving Facility Data
Facility name Mailing address(street or P.O.box)
City or town State ZIP code
0
V
Contact name(first and last) Title
0
t
Phone number Email address
c NPDES number of receiving facility(if any) 0 None
CL Average daily flow rate mgd
0
1.21 Is the wastewater disposed of in a manner other than those already mentioned in Items 1.14 through 1.21 that do not
15 have outlets to waters of the United States(e.g., underground percolation, underground injection)?
d
❑ Yes [✓] No 4 SKIP to Item 1.23.
U
0 1.22 Provide information in the table below on these other disposal methods.
Information on Other Disposal Methods
-- Disposal Location of Size of Annual Average Continuous or Intermittent
- Method Daily Discharge
Description Disposal Site Disposal Site Volume (check one)
❑ Continu
ous
0 acres gpd ❑ Intermittent
acres gpd ❑ Continuous
0 Intermittent
acres gpd ❑ Continuous
❑ Intermittent
1.23 Do you intend to request or renew one or more of the variances authorized at 40 CFR 122.21(n)?(Check all that apply.
d w Consult with your NPDES permitting authority to determine what information needs to be submitted and when.)
Rgn
❑ Discharges into marine waters(CWA ❑ Water quality related effluent limitation(CWA Section
Section 301(h)) 302(b)(2))
Not applicable
1.24 Are any operational or maintenance aspects(related to wastewater treatment and effluent quality)of the treatment works
the responsibility of a contractor?
❑ Yes El No+SKIP to Section 2.
1.25 Provide location and contact information for each contractor in addition to a description of the contractor's operational
and maintenance responsibilities.
Contractor Information
Contractor 1 Contractor 2 Contractor 3
0
Contractor name
(company name)
Mailing address
(street or P.O.box)
City,state,and ZIP
code
c Contact name(first and
c� last)
Phone number
Email address
Operational and
maintenance
responsibilities of
contractor
EPA Form 3510-2A(Revised 3-19) Page 4

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
SECTION 2.ADDITIONAL INFORMATION(40 CFR 122.21(j)(1)and(2))
0 Outfalls to Waters of the United States
2.1 Does the treatment works have a design flow greater than or equal to 0.1 mgd?
o ❑✓ Yes ❑ No 4 SKIP to Section 3.
c 2.2 Provide the treatment works'current average daily volume of inflow Average Daily Volume of Inflow and Infiltration
r and infiltration. 438,000
gpd
Indicate the steps the facility is taking to minimize inflow and infiltration.
c I&I reduction program that has an SSES for two of our eight sewersheds;make repairs identified in SSES;CCTV
Inspections,cleaning lines,and smoke testing tOlD needed repairs.
0
w
• 2.3 Have you attached a topographic map to this application that contains all the required information?(See instructions for
C6 O. specific requirements.)
0
o ❑✓ Yes ❑ No
E 2.4 Have you attached a process flow diagram or schematic to this application that contains all the required information?
ct° (See instructions for specific requirements.)
rn
• co
ElYes ❑ No
2.5 Are improvements to the facility scheduled?
❑ Yes El No 4 SKIP to Section 3.
Briefly list and describe the scheduled improvements.
0
1 See attachment CIP from Master Plan
d
E
n 2.
0
N 3.
a)
r
Cn 4.
0 2.6 Provide scheduled or actual dates of completion for improvements.
Scheduled or Actual Dates of Completion for Improvements
Affected Attainment of
Scheduled Begin End Begin
Outfalls Operational
2 Improvement Construction Construction Discharge
(from above) (list outfall (MM/DD/YYYY) (MM/DD/YYYY) (MM/DD/YYYY) Level
number) (MM/DDIYYYY)
a
m
1.
s
2.
co
3.
4.
2.7 Have appropriate permits/clearances concerning other federal/state requirements been obtained?Briefly explain your
response.
El Yes ❑ No ❑ None required or applicable
Explanation:
All design for any projects is permitted through NCDEQ
EPA Form 3510-2A(Revised 3-19) Page 5

Hendersonville E'i McKIM&CREED
Water Sewer
Table 2.1-CIP Pro ects for the Hendersonville WWII'
Project Name Needed for Project Type Project Estimated Project Cost Estimated Project Cost Description of General Work
Expansion to Start with Inflation
6.0 MOD?
UV Disinfection Improvements- s/ Capacity/Replacement 2022 $393,000 - Design of new UV disinfection system between existing disinfection channel and utility '
Design building with clear-span shelter structure,new filtered effluent electromagnetic flow
meter,meter vault,filtered effluent piping modifications,connection to the existing
NPW pump wet well,lightning protection system,and other associated equipment and
appurtenances.Maintain use of existing UV disinfection system and replace existing
fiberglass grating.
Clarifier Drive Mechanism Replacement 2022 $137,000 - Replace secondary clarifier drive mechanisms per Evoqua inspection report and quote.
Replacement
Aeration Basin Rehabilitation- Rehabilitation 2022 $312,000 - Perform engineering analysis of boweing/deflection in aeration basin#2 north wall to
Design develop repair recommendations,survey aeration basin#2 north wall to measure and
monitor deflection,perform engineering analysis of aeration basins to verify structural
integrity and develop repair plans.
biosolids Thermal Drying Risk Reduction 2022 S1,757,000 - Replace biosolids storage shelter roof,install new protective coatings on structural steel
System-Design members,and convert portion of storage shelter to new thermal drying facility structure.
New dewatered cake conveyor to new thermal drying facility.New thermal drying facility
including sludge feed hopper,medium-temperature gas-fired thermal belt dryer,dried
biosolids conveyor,dried biosolids product storage silo and truck load-out station,and all
associated equipment and appurtenances.
Sludge Thickening Rehabilitation Rehabilitation/Risk 2022 $767,000and TWAS Storage-Design Reduction Repair cracks In existing gravity thickener#1 and install interior/exterior coating system,
equipment manufacturer inspect gravity thickener mechanical and drive mechanisms and
provide rehabilitation recommendations,replace belt filter press feed pumps,relocate
isolation valves on thickened sludge suction piping,rehabilitate/rebuild existing gravity
thickener mechanical and drive mechanisms,install interior coating systems in gravity
thickener#2,repair cracks in thickening building and install new steel beams to support
roof slab(if required).Construct two new 50 foot diameter aerated thickened WAS
storage tanks prior to dewatering.Repurpose existing belt filter press feed pumps to
pump TWAS to the new aerated TWAS storage tanks.Modify TWAS suction piping to the
existing pumps to allow any of the three existing pumps to withdraw TWAS from either
gravity thickener.
UV Disinfection Improvements- �/ Capacity/Replacement 2023 $2,407,000 $2,479,210 Construction of new UV disinfection system between existing disinfection channel and
Construction utility building with clear-span shelter structure,new filtered effluent electromagnetic
flow meter,meter vault,filtered effluent piping modifications,connection to the existing
NPW pump wet well,lightning protection system,and other associated equipment and
appurtenances.Maintain use of existing UV disinfection system and replace existing
fiberglass grating.
Aeration Basin Rehabilitation- Rehabilitation 2023 $1,685,000 $1,735,550 Repair aeration basin#2 north wall bowing/deflection following recommendations of
Construction engineering analysis,repair cracks in faces of exterior walls following recommendations
of engineering analysis,repair cracks in walkway slabs and top of walls.Repairs to
aeration basin#2 north wall expected to include installation of new concrete buttresses
and extension to the aeration basin base slab with wooden pile foundation.
City of Hendersonville WWTF Master Plan June 2022
Final Master Plan
06496-0009
16

Hendersonv McKIM&CREED
Water Sewer
Project Name Needed for Project Type Project Estimated Project Cost Estimated Project Cost Description of General Work
Expansion to Start with Inflation
6.0 MGD?
Headworks Improvements and / Capacity 2023 $4,247,000 $4,374,410 Repair cracks in exterior top of existing wet well wall,replace influent flow measurement
Flow Equalization-Design equipment,replace wet well level measurement equipment,repair cracks in walls and
slabs,perform ventilation system improvements.Replace the existing influent pumps
with larger pumps to accommodate anticipated peak wet weather flows,replace the
existing 16-inch force mains with 24-inch diameter force mains,and redirect all influent
flow to a new inline flow equalization basin.Expand the existing influent pump station to
include new mechanical screening upstream of all pumps,construction of a second,
interconnected wet well with additional pumps.Construction of a new mechanically
induced vortex grit removal system upstream of new flow equalization facilities.
Construction of a new 3.0 MG inline flow equalization basin with associated jet aeration
and mixing equipment,and other associated equipment and appurtenances.
Septage Receiving Rehabilitation 2023 5538,000 $554,140 Removal and replacement of existing concrete pavement,curb,and gutter.Removal and
Improvements replacement of existing asphalt access drive to septage receiving area.Improvements to
septage receiving area discharge/drain piping and replacement of existing discharge
manhole.New concrete platform for existing septage receiving equipment.
Biosolids Thermal Drying Risk Reduction 2024 $9,474,000 $10,050,967 Replace biosolids storage shelter roof,install new protective coatings on structural steel
System-Construction members,and convert portion of storage shelter to new thermal drying facility structure.
New dewatered cake conveyor to new thermal drying facility.New thermal drying facility
including sludge feed hopper,medium-temperature gas-fired thermal belt dryer,dried
biosolids conveyor,dried biosolids product storage silo and truck load-out station,and all
associated equipment and appurtenances.
Sludge Thickening Rehabilitation Rehabilitation/Risk 2024 $4,134,000 $4,385,761 Repair cracks in existing gravity thickener Ill and install interior/exterior coating system,
and TWAS Storage- Reduction equipment manufacturer inspect gravity thickener mechanical and drive mechanisms and
Construction provide rehabilitation recommendations,replace belt filter press feed pumps,relocate
isolation valves on thickened sludge suction piping,rehabilitate/rebuild existing gravity
thickener mechanical and drive mechanisms,install interior coating systems in gravity
thickener#2,repair cracks in thickening building and install new steel beams to support
roof slab(if required).Construct two new 50 foot diameter aerated thickened WAS
storage tanks prior to dewatering.Repurpose existing belt filter press feed pumps to
pump TWAS to the new aerated TWAS storage tanks.Modify TWAS suction piping to the
existing pumps to allow any of the three existing pumps to withdraw TWAS from either
gravity thickener.
Headworks Improvements and ./ Capacity 2025 $22,900,000 $25,023,448 Repair cracks in exterior top of existing wet well wall,replace influent flow-measurement
Flow Equalization-Construction equipment,replace wet well level measurement equipment,repair cracks in walls and
slabs,perform ventilation system Improvements.Replace the existing influent pumps
with larger pumps to accommodate anticipated peak wet weather flows,replace the
existing 16-inch force mains with 24-inch diameter force mains,and redirect all influent
flow to a new inline flow equalization basin.Expand the existing influent pump station to
include new mechanical screening upstream of all pumps,construction of a second,
interconnected wet well with additional pumps.Construction of a new mechanically
induced vortex grit removal system upstream of new flow equalization facilities.
Construction of a new 3.0 MG inline flow equalization basin with associated jet aeration
and mixing equipment,and other associated equipment and appurtenances.
City of Hendersonville WWTF Master Plan June 2022
Final Master Plan
06406.0009 17

Hendersonville MCKfM&CREED
Water to Sewer
Project Name Needed for Project Type' Project Estimated Project Cost Estimated Project Cost Description of General Work
Expansion to Start with Inflation
6.0 MGD?
Tertiary Filter No.2 s/ Capacity 2025 1 $246,000 $268,881 Replace tertiary filter#2 with a new AquaDiamond filter system,install clear span
Replacement-Design i structure over tertiary filters repair cracks in north wall.
Blower Building Improvements Replacement/Rehabilitation 2025 4359,000 $392,289 Subsurface soils investigation,recoat blower discharge piping,repair/replace sidewalks,
-Design
pipe supports,access stair framing,columns,footings,and roof framing(if required)
following recommendations of subsurface soils investigation.Replace existing Hoffman
multistage centrifugal blowers with new turbo blowers and VFDs.Conversion of existing
blower building to an enclosed blower room with associated blower intakes,ancillary
equipment,and appurtenances.
Tertiary Filter No,2 t/ Capacity 2026 $1,958,000 $2,203,746 Replace tertiary filter#2 with a new AquaDiamond filter system,install clear span
Replacement-Construction structure over tertiary filters,repair cracks in north wall.
Sludge Dewatering Cake Replacement 2026 $845,000 $951,055 Replace dewatered cake conveyor belt,motor,drive mechanism,chain,rollers,and
Conveyor Belt Replacement
bearings.
Blower Building Improvements Replacement/Rehabilitation 2026 $1,936,000 $2,178,985 Subsurface soils investigation,recoat blower discharge piping,repair/replace sidewalks,
-Construction
pipe supports,access stair framing,columns,footings,and roof framing(if required)
following recommendations of subsurface soils investigation.Replace existing Hoffman
multistage centrifugal blowers with new turbo blowers and VFDs.Conversion of existing
blower building to an enclosed blower room with associated blower intakes,ancillary
equipment,and appurtenances.
Recycle Pumping Station Replacement/Rehabilitation 2026 $967,000 $1,088,367 Replace RAS pump 112 and WAS pumps,RPS heating and ventilation system
Rehabilitation improvements,repair cracks in walls,slabs,and exterior top of walls,repair sidewalk
settlement on west side of RPS to eliminate trip hazard from valve operating nuts.
Dewatering Facility Lightning Risk Reduction 2026 $500,000 $562,754 Install grounding/lightning protection system on existing dewatering building.
Protection Improvements
Aeration Basin Improvements- Process Efficiency 2029 $264,000 $324,687 Conversion of existing extended aeration process to a Modified Ludzack-Ettinger process.
Design Installation of submersible ultra-low-head high-flow type NRCY pumps with associated
NRCY pipelines.Installation of a compressed gas mixing system in the first diffuser grid of
each aeration basin.
Aeration Basin Improvements- Process Efficiency 2030 $1,424,000 $1,803,881 Conversion of existing extended aeration process to a Modified Ludzack-Ettinger process.
Construction Installation of submersible ultra-low-head high-flow type NRCY pumps with associated
NRCY pipelines.Installation of a compressed gas mixing system in the first diffuser grid of
each aeration basin.
Belt Filter Press System Replacement 2030 $281,000 $355,962 Replacement existing belt filter presses with two new 2.0 meter belt filter presses.
Replacement-Design Replace wash water supply system,polymer makedown skids,and other appurtenances
and ancillary equipment.
Belt Filter Press System Replacement 2031 $1,514,000 $1,975,427 Replacement existing belt filter presses with two new 2.0 meter belt filter presses.
Replacement-Construction Replace wash water supply system,polymer makedown skids,and other appurtenances
and ancillary equipment.
Secondary Clarifier Rehabilitation 2031 8328,000 $427,966 Rehabilitate/rebuild existing clarifier mechanical and drive mechanisms,replace clarifier
Rehabilitation-Design scum boxes,repair cracks in exterior walls.
`~__
Secondary Clarifier Rehabilitation 2032 $1,767,000 $2,374,700 Rehabilitate/rebuild existing clarifier mechanical and drive mechanisms,replace clarifier
Rehabilitation-Construction
scum boxes,repair cracks in exterior walls.
City of Hendersonville WWTF Master Plan June 2022
Final Master Plan
06496-0009 18

Hen ersonvdle McicimeiCREED
Water 41 Sewer
Project Name Needed for Project Type' Project Estimated Project Cost Estimated Project Cost Description of General Work
Expansion to Start with Inflation
6.0 MGD?
7.8 MGD Facility Expansion- Capacity 2032 $4,680,000 $6,289,529 Expansion of the existing WWTF to accommodate the predicted 2040 loading conditions.
Design Addition of aeration basin No.3,blower building No.2,90-ft diameter secondary clarifier
No.3,RAS/WAS pump station No.2,flow distribution boxes,and tertiary filter No.3.
Replacement of the existing UV4000 system in UV Channel No.1 with a new 15 MGD UV
disinfection system to match the proposed equipment in UV Channel No.2,replacement
of the cascade reaeration steps,and replacement/expansion of the effluent outfall.
7.8 MGD Facility Expansion- Capacity 2035 S25,851,000 437,963,065 Expansion of the existing WWTF to accommodate the predicted 2040 loading conditions.
Construction Addition of aeration basin No.3,blower building No.2,90-R diameter secondary clarifier
No.3,RAS/WAS pump station No.2,flow distribution boxes,and tertiary filter No.3.
Replacement of the existing UV4000 system in UV Channel No.1 with a new 15 MOD UV
disinfection system to match the proposed equipment in UV Channel No.2,replacement
of the cascade reaeration steps,and replacement/expansion of the effluent outfall.
'Project types include:Capacity Improvements,Replacement,Rehabilitation,Process Efficiency Improvements,Risk Reduction
City of Hendersonville WWTF Master Plan lune 2022
Final Master Plan
06496-0009 19

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PROCESS NARRATIVE
Process units located on site include influent pumping station with bar screens designed to
handle all raw sewage delivered by 42 inch gravity sewer, all septage received at WWTP for
treatment, and waste streams from solids handling facility,consisting of gravity thickener
supernatant overflow and belt press filtrates. Additional facilities include headworks consisting
of mechanical screening and aerated grit removal;biological treatment using an activated sludge
process utilizing fine bubble aeration with single stage nitrification; circular clarifiers; recycle
pumping station; effluent polishing using low head filters; disinfection by ultraviolet light; and
cascade aeration of final effluent prior to surface discharge to Mud Creek. Design for sludge
residuals are treated as prescribed by State and Federal requirements to Class A solid, intended
for land application. Residuals are currently disposed of in class D landfill. Capability for re-use
of treated wastewater has been incorporated into plant design.

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LATTiTUDE: 35 21' 11' a ; '
LONGITUDE: 82 27' 52- CITY OF HENDERSONVILLE
QUAD: F9SW / HENDERSONVILLE
SUB-BASIN: 04-03-02 HENDERSONVILLE WWTP
STREAM CLASS: C
RECEIVING STREAM: MUD CREEK NPDES PERMIT NC00025534
PERMITTED FLOW: PHASED 4.8 AND 6.0 MGD

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gear cid 50• O yo• too' PROCESS PIPING PLAN MN G-11
•.. w. VidillSENGINEERS WASTEWATER FACILITIES 1 August t...

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•
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I STRUCTURE LOCATION SCHEDULE I i I FENCE CORNER LOCATION SCHEDULE
1
S STRUCTURE POINT�LOCATION PLANT GRID COOK. r. CORN R PLANT CAD COOR.
1 „ E H'. E
( N1700 A AD/AINISTRATION BUILDING I SE CORNER 1225,00 467.00 I I _ _ 1161,00. 383.00
B SCREENING ANC GRIT COLLECTION SW CORNER 1247.00 623.00 B" 1389.001 363.00
C AERATION BASIN NO. I 1 SW(CORNER 1204.00 623.00 C 1463.00. 440.00
0 AERATION BASIN NO. 2 NW CORNER 1415.50 623.00 DUKE POWER 'D. 1530.00! 1042.00
E BLOWER BUILDIRG i SW(CORNER 1287,00 911.00 ELECTRIC TO "E. 1503.00! 1098.00 4.
F CLARIFIER N0. 1 CENTER OF TANK 1315.00 1029.00 I 'F. 1454.00, 1116.00
.\\:\
• G CLARIFIER NO. 2 CENTS Of TANK 1439.00 1029.00 "0 1454.00! 1311.00 �, •
1 H POWER UILDING SW CORNER 1153.00 1038.00 I 14 1222.00 1311.00 ` 91„
• I RECYCLE PUMPNG STATION( SW CORNER 1359.42 1081.00 1 1" 1133.00, 1167.00 • C,f
N1600 J INFL PUMPING STATIOA_ _.SW CORNER _ .1227.00.. 11.74.00 .. 'J 1133.00: 1083.00
K UTIUFY BUILDING Sw CORNER 1305.00 • 1174.00 "K" 1066.00; 1083.00 •
L EFFLUENT FILTERS SW CORNER 1350.00 1174.00 • 1." 1070.00 981.00
M
DISINFECTION BASIN SW CORNER 1219.00 1238.00 i �61 It 570.00
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1. ,AIL CURB RADIUS SHALL BE 25 FT 1 16, C "' O II OI
N1300 IuNLESS OTHERWT E SHOwn. 5t _ © E
1 2. 'ALL SIDEWALKS SHALL BE 4 FT wl O �} N I _ - _ IG q 15I R M
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3. 1 CONCRETE APRONS SWILL BE 6" 51 WITH 115 I s- CO I 16• 1
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CITY OF HENDERSONVILLE 1210.003.XX,
? - Ww » WIu15I1Gl(VEERS WASTEWATER FACILITIES SITE PLAN .. G-2
4UGVST IY94

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
SECTION 3.INFORMATION ON EFFLUENT DISCHARGES(40 CFR 122.21(j)(3)to(5))
3.1 Provide the following information for each outfall.(Attach additional sheets if you have more than three outfalls.)
Outfall Number ooi Outfall Number Outfall Number
State North Carolina
County Henderson
O City or town Hendersonville
Distance from shore N/A ft. ft. ft.
Depth below surface N/A ft. ft. ft.
Average daily flow rate 2.223 mgd mgd mgd
Latitude 35° 21' 11
Longitude 82° 2i 52" "
3.2 Do any of the outfalls described under Item 3.1 have seasonal or periodic discharges?
o ❑ Yes r❑ No 4 SKIP to Item 3.4.
F 3.3 If so,provide the following information for each applicable outfall.
H Outfall Number Outfall Number Outfall Number
Number of times per year
° discharge occurs
a Average duration of each
o discharge(specify units)
ra
Average flow of each
discharge mgd mgd mgd
Months in which discharge
occurs
3.4 Are any of the outfalls listed under Item 3.1 equipped with a diffuser?
❑ Yes ❑ No+SKIP to Item 3.6.
3.5 Briefly describe the diffuser type at each applicable outfall.
a
Outfall Number Outfall Number Outfall Number
d
c Does the treatment works discharge or plan to discharge wastewater to waters of the United States from one or more
a = 3.6 discharge points?
w ElYes ❑ No+SKIP to Section 6.
EPA Form 3510-2A(Revised 3-19) Page 6

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
3.7 Provide the receiving water and related information(if known)for each outfall. 1
Outfall Number ow Outfall Number Outfall Number
Receiving water name Mud Creek
Name of watershed,river,
c or stream system Lower Mud Creek
o
a U.S.Soil Conservation
d Service 14-digit watershed 06010105030030
0 code
43 Name of state French Broad
3 management/river basin
rn
U.S.Geological Survey
8-digit hydrologic 06010105
o
re cataloging unit code
Critical low flow(acute) cfs cfs cfs
Critical low flow(chronic) 34.9 cfs cfs cfs
Total hardness at critical mg/L of mg/L of mg/L of
low flow CaCO3 CaCO3 CaCO3
3.8 Provide the following information describing the treatment provided for discharges from each outfall.
Outfall Number°, Outfall Number Outfall Number
Highest Level of 0 Primary 0 Primary ❑ Primary
Treatment(check all that 0 Equivalent to 0 Equivalent to 0 Equivalent to
apply per outfall) secondary secondary secondary
0 Secondary 0 Secondary 0 Secondary
© Advanced 0 Advanced 0 Advanced
❑ Other(specify) 0 Other(specify) 0 Other(specify)
c
0
7-1 Design Removal Rates by
Outfall
to
a►
o BOD5 or CBOD5 96
c
d
E
V.
TSS 90 %
r
0 Not applicable 0 Not applicable 0 Not applicable
Phosphorus
l Not applicable 0 Not applicable 0 Not applicable
Nitrogen % % °
Other(specify) 0 Not applicable 0 Not applicable 0 Not applicable
ok % 0/0
EPA Form 3510-2A(Revised 3-19) Page 7

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
3.9 Describe the type of disinfection used for the effluent from each outfall in the table below.If disinfection varies by
season,describe below.
-a Ultra-Violet
ar
c
w
c
0
U
Outfall Number 001 Outfall Number Outfall Number
Disinfection type Ultra-Violet
Gf
Seasons used all
Dechlorination used? ❑ Not applicable ❑ Not applicable ❑ N• ot applicable
❑ Yes ❑ Yes ❑ Yes
0 No ❑ No ❑ N• o
3.10 Have you completed monitoring for all Table A parameters and attached the results to the application package?
Yes ❑ No
3.11 Have you conducted any WET tests during the 4.5 years prior to the date of the application on any of the facility's
discharges or on any receiving water near the discharge points?
ElYes ❑ No-4 SKIP to Item 3.13.
3.12 Indicate the number of acute and chronic WET tests conducted since the last permit reissuance of the facility's
discharges by outfall number or of the receiving water near the discharge points.
Outfall Number 001 Outfall Number Outfall Number
Acute Chronic Acute Chronic Acute Chronic
Number of tests of discharge
water 18
Number of tests of receiving
water
3.13 Does the treatment works have a design flow greater than or equal to 0.1 mgd?
El Yes ❑ No 4 SKIP to Item 3.16.
0 3.14 Does the POTW use chlorine for disinfection,use chlorine elsewhere in the treatment process,or otherwise have
c reasonable potential to discharge chlorine in its effluent?
❑ Yes.4 Complete Table B,including chlorine. ❑ No 4 Complete Table B,omitting chlorine.
3.15 Have you completed monitoring for all applicable Table B pollutants and attached the results to this application
package?
❑✓ Yes ❑ No
3.16 Does one or more of the following conditions apply?
• The facility has a design flow greater than or equal to 1 mgd.
• The POTW has an approved pretreatment program or is required to develop such a program.
• The NPDES permitting authority has informed the POTW that it must sample for the parameters in Table C,must
sample other additional parameters(Table D),or submit the results of WET tests for acute or chronic toxicity for
each of its discharge outfalls(Table E).
Yes 4 Complete Tables C,D,and E as
❑ applicable. ❑ No 4 SKIP to Section 4.
3.17 Have you completed monitoring for all applicable Table C pollutants and attached the results to this application
package?
El Yes ❑ No
3.18 Have you completed monitoring for all applicable Table D pollutants required by your NPDES permitting authority and
attached the results to this application package?
El Yes El No additional sampling required by NPDES
permitting authority.
EPA Form 3510-2A(Revised 3-19) Page 8

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
3.19 Has the POTW conducted either(1)minimum of four quarterly WET tests for one year preceding this permit application
or(2)at least four annual WET tests in the past 4.5 years?
❑✓ Yes ❑ No 4 Complete tests and Table E and SKIP to
Item 3.26.
3.20 Have you previously submitted the results of the above tests to your NPDES permitting authority?
El Yes ❑ No 4 Provide results in Table E and SKIP to
Item 3.26.
3.21 Indicate the dates the data were submitted to your NPDES permitting authority and provide a summary of the results.
Date(s)Submitted Summary of Results
(MM/DD/YYYY)
Passed
06/13/2022
c
C
' O
3.22 Regardless of howyouprovidedyour WET testingdata to the NPDES permittingauthority,did anyof the tests result in
9
toxicity?
❑ Yes 0 No 4 SKIP to Item 3.26.
3.23 Describe the cause(s)of the toxicity:
C
c
CD
3.24 Has the treatment works conducted a toxicity reduction evaluation?
❑ Yes ❑✓ No 3 SKIP to Item 3.26.
3.25 Provide details of any toxicity reduction evaluations conducted.
3.26 Have you completed Table E for all applicable outfalls and attached the results to the application package?
El Yes ❑ Not applicable because previously submitted
information to the NPDES .ermittinI authori
SECTION 4. INDUSTRIAL DISCHARGES AND HAZARDOUS WASTES(40 CFR 122.21(j)(6)and(7))
4.1 Does the POTW receive discharges from SIUs or NSCIUs?
❑✓ Yes ❑ No 4 SKIP to Item 4.7.
4.2 Indicate the number of SIUs and NSCIUs that discharge to the POTW.
Number of SIUs Number of NSCIUs
6
0
3 4.3 Does the POTW have an approved pretreatment program?
0 Yes ❑ No
-0
4.4 Have you submitted either of the following to the NPDES permitting authority that contains information substantially
identical to that required in Table F:(1)a pretreatment program annual report submitted within one year of the
application or(2)a pretreatment program?
❑ Yes ❑ No 4 SKIP to Item 4.6.
o 4.5 Identify the title and date of the annual report or pretreatment program referenced in Item 4.4.SKIP to Item 4.7.
vPretreatment Annual Report 02/22/2022
4.6 Have you completed and attached Table F to this application package?
❑ Yes ❑ No
EPA Form 3510-2A(Revised 3-19) Page 9

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
4.7 Does the POTW receive,or has it been notified that it will receive, by truck, rail,or dedicated pipe,any wastes that are
regulated as RCRA hazardous wastes pursuant to 40 CFR 261?
❑ Yes 0 No 4 SKIP to Item 4.9.
4,8 If es, •rovide the following information:
Annual
Hazardous Waste Waste Transport Method Amount of Units
Number (check all that apply) Waste
Received
El Truck ❑ Rail
❑ Dedicated pipe ❑ Other(specify)
0
❑ Truck ❑ Rail
111
❑ Dedicated pipe ❑ Other(specify)
❑ Truck ❑ Rail
_ ❑ Dedicated pipe ❑ Other(specify)
N
s4.9 Does the POTW receive,or has it been notified that it will receive,wastewaters that originate from remedial activities,
including those undertaken pursuant to CERCLA and Sections 3004(7)or 3008(h)of RCRA?
❑ Yes d No 4 SKIP to Section 5.
3 4.10 Does the POTW receive(or expect to receive)less than 15 kilograms per month of non-acute hazardous wastes as
c specified in 40 CFR 261.30(d)and 261.33(e)?
❑ Yes 4 SKIP to Section 5. ❑ No
4.11 Have you reported the following information in an attachment to this application: identification and description of the
site(s)or facility(ies)at which the wastewater originates;the identities of the wastewater's hazardous constituents;and
the extent of treatment,if any,the wastewater receives or will receive before entering the POTW?
❑ Yes ❑ No
SECTION 5.COMBINED SEWER OVERFLOWS(40 CFR 122.21(j)(8))
5.1 Does the treatment works have a combined sewer system?
co
❑ Yes ❑ No-SKIP to Section 6.
5.2 Have you attached a CSO system map to this application?(See instructions for map requirements.)
❑ Yes ❑ No
a
m
2 5.3 Have you attached a CSO system diagram to this application?(See instructions for diagram requirements.)
❑ Yes ❑ No
EPA Form 3510-2A(Revised 3-19) Page 10

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
5.4 For each CSO outfall,provide the following information.(Attach additional sheets as necessary.)
CSO Outfall Number CSO Outfall Number CSO Outfall Number
City or town
0
•a State and ZIP code
U
U)
c County
0
Latitude
0
cn Longitude °
U
Distance from shore ft. ft. ft.
Depth below surface ft. ft. ft.
5.5 Did the POTW monitor any of the following items in the past year for its CSO outfalls?
CSO Outfall Number CSO Outfall Number CSO Outfall Number
Rainfall ❑ Yes ❑ No ❑ Yes ❑ No ❑ Yes ❑ No
a)
c
`o CSO flow volume 0 Yes ❑ No ❑ Yes ❑ No 0 Yes 0 No
CSO pollutant 0 Yes ❑ No ❑ Yes ❑ No ❑ Yes 0 No
o concentrations
N
v Receiving water quality 0 Yes ❑ No ❑ Yes ❑ No ❑ Yes 0 No
CSO frequency ❑ Yes ❑ No ❑ Yes ❑ No ❑ Yes ❑ No
Number of storm events ❑ Yes ❑ No ❑ Yes ❑ No ❑ Yes ❑ No
5.6 Provide the following information for each of your CSO outfalls.
CSO Outfall Number CSO Outfall Number CSO Outfall Number
L
} Number of CSO events in events events events
y
the past year
to
a
.c Average duration per hours hours hours
a event 0 Actual or❑ Estimated ❑Actual or 0 Estimated 0 Actual or 0 Estimated
>
U" million gallons million gallons million gallons
o Average volume per event
`n
c.) 0 Actual or 0 Estimated 0 Actual or❑ Estimated 0 Actual or 0 Estimated
Minimum rainfall causing inches of rainfall inches of rainfall inches of rainfall
a CSO event in last year 0 Actual or 0 Estimated 0 Actual or 0 Estimated 0 Actual or 0 Estimated
EPA Form 3510-2A(Revised 3-19) Page 11

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP
OMB No.2040-0004
5.7 Provide the information in the table below for each of your CSO outfalls.
CSO Outfall Number CSO Outfall Number CSO Outfall Number
Receiving water name
Name of watershed/
y stream system
U.S.Soil Conservation 0 Unknown 0 Unknown 0 Unknown
Service 14-digit
watershed code
> (if known)
Name of state
management/river basin
cn U.S.Geological Survey 0 Unknown 0 Unknown 0 Unknown
8-Digit Hydrologic Unit
Code(if known)
Description of known
water quality impacts on
receiving stream by CSO
(see instructions for
exam'les
SECTION 6.CHECKLIST AND CERTIFICATION STATEMENT(40 CFR 122.22(a)and(d))
6.1 In Column 1 below,mark the sections of Form 2A that you have completed and are submitting with your application. For
each section,specify in Column 2 any attachments that you are enclosing to alert the permitting authority.Note that not
all applicants are required to provide attachments.
Column 1 Column 2
Section 1:Basic Application
Information for All Applicants ❑ w/variance request(s) ❑ w/additional attachments
❑ Section 2:Additional ❑r w/topographic map El wl process flow diagram
Information ❑ w/additional attachments
0 w/Table A El w/Table D
© Section 3: Information on r❑ w/Table B ❑ wl Table E
Effluent Discharges
© wl Table C ❑ wl additional attachments
Section 4: Industrial ❑ w/SIU and NSCIU attachments El w/Table F
co ❑ Discharges and Hazardous
Wastes ❑ w/additional attachments
Section 5:Combined Sewer El w/CSO map ❑ w/additional attachments
❑ Overflows
❑ w/CSO system diagram
"0 E Section 6:Checklist and
Certification Statement w/attachments
6.2 Certification Statement
/certify under penalty of law that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible
for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate,and
complete. I am aware that there are significant penalties for submitting false information,including the possibility of fine
and imprisonment for knowing violations.
Name(print or type first and last name) Official title
V A✓'Y C 1-} T)e o1 O SS 00, cs-
Signature Date signed
— r2o�z
EPA Form 3510-2A(Revised 3-19) Page 12
1

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
TABLE A. EFFLUENT PARAMETERS FOR ALL POTWS
Maximum Daily Discharge Average Daily Discharge Analytical ML or MDL
Pollutant Number Value Units Value Units Sams iesf Method1 (include units)
Biochemical oxygen demand
0
CI BODE or❑CBOD5 15.6 mg/I 3.4 mg/L 246 SM5210B 2.0 mg/L ML
resort oneCI ML
0MDL
Fecal coliform 188 MPN 12 MPN 246 5M9222 1 MPN ❑MDL
Design flow rate 4.8 MGD 2.223 MGD 365
pH(minimum) 6.4 su
pH(maximum) 7.3 su
Temperature(winter) 19 celcius 15 celcius 98
Temperature(summer) 24 celcius 21 celcius 148
2 ML
Total suspended solids(TSS) 9'6 mg/L 4.2 mg/L 246 SM2540D 2.5 mg/L ❑MDL
1 Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2A(Revised 3-19) Page 13

This page intentionally left blank.

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
TABLE B.EFFLUENT PARAMETERS FOR ALL POTWS WITH A FLOW EQUAL TO OR GREATER THAN 0.1 MGD
Maximum Daily Discharge Average Daily Discharge Analytical ML or MDL
Pollutant Number of
Value Units Value Units Method1 (include units)
Samples
Ammonia(as N) 4.7 mg/L 0.7 mg/L 246 SM 4500NH3D 0.5 mg/L 0 ML
❑MDL
Chlorine Li ML
(total residual,TRC)2 N/A N/A N/A N/A N/A N/A N/A ❑MDL
0 ML
Dissolved oxygen 9.8 mg/L 7.7 mg/L 246 SM 45000G 0.1 mg/L 0 MDL
Nitrate/nitrite 8.3 mg/L 4.8 mg/L 5 EPA 353.2 0.12 mg/L ML
0 MDL
Kjeldahl nitrogen 1.7 mg/L 1.4 mg/L 5 EPA 351.2 0.5 mg/L ML
0 MDL
Oil and grease ND mg/L ND mg/L 1 EPA 1664E 4.9 mg/L 0 ML
0 MDL
0 ML
Phosphorus 4.3 mg/L 2.4 mg/L 9 EPA 365.1 0.05 mg/L ❑MDL
0 ML
Total dissolved solids 206 mg/L 206 mg/L 1 SM 2504C 25 mg/L 0 MDL
1 Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3).
2 Facilities that do not use chlorine for disinfection,do not use chlorine elsewhere in the treatment process,and have no reasonable potential to discharge chlorine in their effluent are not
required to report data for chlorine.
EPA Form 3510-2A(Revised 3-19) Page 15

This page intentionally left blank.

EPA Identification Number NPDES Permit Number Facility Name Ouffall Number Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
TABLE C. EFFLUENT PARAMETERS FOR SELECTED POTWS
Maximum Daily Discharge Average Daily Discharge Analytical ML or MDL
Pollutant Number of Method.' (include units)
Value Units Value Units Samples
Metals,Cyanide,and Total Phenols
Hardness(as CaCO3) 34800 ug/L 27240 ug/L 5 EPA 200.7 ❑ML
❑MDL
Antimony,total recoverable ND ug/L ND ug/L 1 EPA 200.7 5 ug/L o ML
0 MDL
Arsenic,total recoverable ND ug/L " " lOug/L o ML
❑MDL
Beryllium,total recoverable " " " " " lug/L 0 ML
MDL
Cadmium,total recoverable " " " II
" " o ML
❑MDL
Chromium,total recoverable " " 2 ML
5 ug/L 0 MDL
Copper,total recoverable 16.1 ug/L 11.0 ug/L 9 EPA 200.8 El ML
❑MDL
Lead,total recoverable ND ug/L ND ug/L 4 EPA 200.7 5 ug/L o ML
0 MDL
Mercury,total recoverable 1.16 ng/L 0.7895 ng/L 4 EPA 1631E El ML
❑MDL
Nickel,total recoverable 34.7 ug/L 15.4 ug/L 9 EPA 200.7 ❑ML
❑MDL
El ML
Selenium,total recoverable ND ug/L ND ug/L 4 EPA 200.7 10.0 ug/L 0 MDL
Silver,total recoverable ND ug/L ND ug/L 9 EPA 200.8 0.40 ug/L ❑MMDL
Thallium,total recoverable " " " " 1 EPA 200.7 10.0 ug/L o ML
0 MDL
Zinc,total recoverable 63.2 ug/L 50.2 ug/L 4 " ❑ML
❑MDL
El
Cyanide ND mg/L ND mg/L 5 SM 4500CNE 0080 mg/L ML
❑MDL
Total phenolic compounds ND mg/L 1 EPA 420.4 ).020 mg/L 0 MMDL
Volatile Organic Compounds
l
Acrolein ND ug/L ND ug/L 1 EPA 624.1 50 ug/L ML
0 MDL
Acrylonitrile " 1 10 ug/L 0 ML
❑MDL
Benzene 1 1 ug/L CI ML
g 0 MDL
CI ML
Bromoform " II
II
II
1 " 1 ug/L 0 MDL
EPA Form 3510-2A(Revised 3-19) Page 17

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
TABLE C.EFFLUENT PARAMETERS FOR SELECTED POTWS
Maximum Daily Discharge Average Daily Discharge Analytical ML or MDL
Pollutant Number of Methods (include units)
Value Units Value Units Samples
Carbon tetrachloride ND ug/L ND ug/L 1 EPA 624.1 1 u g/L O ML
❑MDL
Chlorobenzene - 1 ug/L o ML
❑MDL
Chlorodibromomethane - - - - - - 1 ug/L o
�MDL
Chloroethane 5 ug/L o ML
❑MDL
2-chloroethylvinyl ether - - - - - - 50 ug/L o ML
❑MDL
Chloroform - - - - - 5 ug/L 0 ML
❑MDL
Dichlorobromomethane 1 ug/L CI ML
❑MDL
1,1 dichloroethane 1 ug/L 2 ML
❑MDL
1,2-dichloroethane -- - 1 ug/L o ML
❑MDL
trans-1,2-dichloroethylene - - - - --- - 1 ug/L o ML
❑MDL
1,1 dichloroethylene 1 ug/L El ML
❑MDL
1,2 dichloropropane 1 ug/L o ML
❑MDL
1,3-dichloropropylene - - - - - - 1 ug/L o ML
❑MDL
Ethylbenzene -- 1 ug/L o ML
❑MDL
Methyl bromide 5 ug/L CI ML
❑MDL
Methyl chloride - - - - - - 2.5 ug/L U ML
❑MDL
Methylene chloride - - - - - - 5 ug/L o ML
❑MDL
1,1,2,2-tetrachloroethane - - - - - - 1 ug/L CI ML
❑MDL
Tetrachloroethylene 1 ug/L o ML
❑MDL
Toluene 1 ug/L CI ML
❑MDL
1,1,1-trichloroethane 1 ug/L o ML
❑MDL
1,1,2 trichloroethane 1 ug/L o ML
❑MDL
I
EPA Form 3510-2A(Revised 3-19) Page 18

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP 001 OMB No.2040-0004
TABLE E. EFFLUENT MONITORING FOR WHOLE EFFLUENT TOXICITY
The table provides response space for one whole effluent toxicity sample.Copy the table to report additional test results.
Test Information
Test Number Test Number Test Number
Test species SEE Attached
Age at initiation of test
Outfall number
Date sample collected
Date test started
Duration
Toxicity Test Methods
Test method number
Manual title
Edition number and year of publication
Page number(s)
Sample Type
Check one: ❑ Grab ❑ Grab ❑ Grab
❑ 24-hour composite ❑ 24-hour composite ❑ 24-hour composite
Sample Location
Check one: ❑ Before Disinfection ❑ Before Disinfection ❑ Before disinfection
❑After Disinfection ❑After Disinfection ❑After disinfection
❑ After Dechlorination ❑ After Dechlorination ❑ After dechlorination
Point in Treatment Process
Describe the point in the treatment process
at which the sample was collected for each
test.
Toxicity Type
Indicate for each test whether the test was ❑Acute ❑Acute ❑Acute
performed to asses acute or chronic toxicity,
or both.(Check one response.) ❑ Chronic El Chronic ❑ Chronic
❑ Both ❑ Both ❑ Both
EPA Form 3510-2A(Revised 3-19) Page 25

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP 001 OMB No.2040-0004
TABLE E. EFFLUENT MONITORING FOR WHOLE EFFLUENT TOXICITY
The table provides response space for one whole effluent toxicity sample.Copy the table to report additional test results.
Test Number Test Number Test Number
Test Type
Indicate the type of test performed.(Check one ❑ Static ❑ Static ❑ Static
response.)
❑ Static-renewal ❑ Static-renewal ❑ Static-renewal
❑ Flow-through ❑ Flow-through ❑ Flow-through
Source of Dilution Water
Indicate the source of dilution water.(Check ❑ Laboratory water ❑ Laboratory water Cl Laboratory water
one response.)
❑ Receiving water ❑ Receiving water ❑ Receiving water
If laboratory water,specify type.
If receiving water,specify source.
Type of Dilution Water
Indicate the type of dilution water.If salt ❑ Fresh water El Fresh water ❑ Fresh water
water,specify"natural"or type of artificial
sea salts or brine used. CISalt water(specify) ❑ Salt water(specify) CISalt water(specify)
Percentage Effluent Used
Specify the percentage effluent used for all
concentrations in the test series.
Parameters Tested
Check the parameters tested. ❑ pH ❑ Ammonia ❑ pH ❑ Ammonia ❑ pH El Ammonia
❑ Salinity ❑ Dissolved oxygen ❑ Salinity El Dissolved oxygen ❑ Salinity ❑ Dissolved oxygen
❑ Temperature ❑ Temperature ❑ Temperature
Acute Test Results
Percent survival in 100%effluent
LC50
95%confidence interval
Control percent survival
EPA Form 3510-2A(Revised 3-19) Page 26

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP 001 OMB No.2040-0004
TABLE E. EFFLUENT MONITORING FOR WHOLE EFFLUENT TOXICITY
The table provides response space for one whole effluent toxicity sample.Copy the table to report additional test results.
Test Number Test Number Test Number
Acute Test Results Continued
Other(describe)
Chronic Test Results
NOEC
IC25
Control percent survival
Other(describe)
Quality Control/Quality Assurance
Is reference toxicant data available? ❑ Yes ❑ No ❑ Yes ❑ No ❑ Yes ❑ No
Was reference toxicant test within ❑ Yes ❑ No ❑ Yes ❑ No ❑ Yes ❑ No
acceptable bounds?
What date was reference toxicant test run
(MM/DD/YYYY)?
Other(describe)
EPA Form 3510-2A(Revised 3-19) Page 27

Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Asheville,NC 28804
(/)°/
www.pacelabs.com [phone]
Page 1 of 1
Laboratory Report
Mr. Alexander Lillie Report Date: 08/20/2021
City of Hendersonville VVVVfP Date Received: 08/03/2021
99 Balfour Road
Hendersonville, NC 28792
Project: Hville WWTP Bioassay 8/3
Pace Project No.:92553111
Reviewed by: Gam-- -.
Chris Derouen for
Lord Patton
1(828)254-7176
[e-mail]
Page 1 of 10

Document Name: Document Revised:October 28,2020
Sample Condition Upon Receipt(SCUR) Page 1 of 2
aeeAnaiyfical Document No.: Issuing Authority:
F-CAR-CS-033-Rev.07 Pace Carolinas Quality Office
Laboratory rece rig samples:
Asheville[ Eden_ Greenwood Huntersville _ Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑
Sample Condition Client Name:
W0# : 92553111
Upon Receipt Ii-,/r G \/Ir /e Project p: 111111
1111111
Iii III III
Courier: ❑Fed Ex AG
❑USSPSS ['Client 92853111
❑Commercial Y4Y ['Other:
I
Custody Seal Present? Elves ,21 Seals Intact? Eyes Y"
Date/Initials Person Examining Contents: H-i 3
Packing Material: ['Bubble Wrap ❑Bubble Bags None ri Other Biological Tissu,—e-,,F�roze'�? 4
Thermometer: �/ Eyes ❑No L_fl`r/N
/ I:2 et ❑Bice ❑None
❑�n ID: �� + U ,� f Type of Ice: �
Correction Factor:
Cooler Temp: ) '`5 Add/Subtract(°C) U Temp should be above freezing to 6°C
Cooler Temp Corrected( D
Samples out of temp criteria.Samples on ice,cooling process
has begun
USDA Regulated Soil( °N/A,water sample)
Did samples originate in a quarantine zone within the United States:CA,NY,or SC(check maps)? Did samples originate from a foreign source(internationally,
Eves ❑No including Hawaii and Puerto Rico)?Eyes ❑No
Comments/Discrepancy:
Chain of Custody Present? riKes ❑No ❑N/A 1.
Samples Arrived within Hold Time? es No ON/A 2.
Short Hold Time Analysis(<72 hr.)? Yes ONO ON/A 3. r
Rush Turn Around Time Requested? Des ((1No QN/A 4. �_ ----
Sufficient Volume? 6Yes ❑No ON/A 5.
Correct Containers Used? 461es ❑No ON/A 6.
-Pace Containers Used? ,Yes ❑No ON/A
Containers Intact? s ❑No ❑K1 7.
Dissolved analysis:Samples Field Filtered? Oyes ❑No N/A 8.
Sample Labels Match COC? /Wes ENS ON/A 9.
-Includes Date/Time/ID/Analysis Matrix:____ _? ___
Headspace in VOA Vials(>5-6mm)? Des ❑No 1:14A.'
10.
Trip Blank Present? Dyes Diu Di ii.
Trip Blank Custody Seals Present? ❑Yes ❑No_ +IA. —
COMMENTS/SAMPLE DISCREPANCY Field Data Required? ❑Yes ❑No
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time: --
Project Manager SCURF Review: T Date: V/3 t(i) 1
Project Manager SRF Review: Date:
Page 2 of 10

C o W
w �in, •.. o !
Item# * m IA < *
a 7/// /17, / /1,/ / / 3 BP4U-125 ml Plastic Unpreserved(N/A)(CI) o ,� C
5 , .-* o rp .
o j ( I I- BP3u-250 n1L Plastic Unpreserved(N/A) O N vl C 3
r^N., m77i G BP2U-500 mt.Plastic Unpreserved(N/A) D �'
13 j o p
d I ! BP1U-1 titer Plastic Unpreserved(N/A) 1 � a
a s o 3 vI
1 1 ; 8P4S-12S mL Plastc H2SO4(pH<2)(Cl-) x -1 I
-++O O/:/ ( �. m -n Oaoi j 8P3N-250 mL plastic HNO3(pH<2) O O IS O I
3 T 2 j BP42-125:z:::: :: -
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° G 'n ( ( I WGFU-Wide-mouthed Glass jar Unpreserved a 3 -...,
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1 ; AG1U-1 liter Amber Unpreserved(N/A)(Cl-) Cro c w
n o rt { / / / ZZI ���� AG17;-iii'aerAmberHC((pH<2) ra f s
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wn iii m f !! // f III
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tr• sd„ Or ::///,:///7/7/1 AG1S-1 liter Amber H2SO4(pH<2) O 3 H 3 = g
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AG35-2S0 mt.Amber H25O4(pH<2) z
< a . AG3A(DG3A)-250 mt.Amber NH4CI(IV/RHO-) c o
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3 Q VG9T-40 mL VOA Na2S2O3(N/A) r1 V
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^- _ I DG9P-40 mL VOA H3PO4(N/A) m a
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ro � I VOAK(6 vials per kit)-5035 kit(N/A) -1 it r2o
z •O f s I i V/GK(3 vials per kit)-VPH/Gas kit(N/A) w ,�^ v
( I I ( (10 Q. S - 5-
Et o o j 1 SPST-125 mL Sterne Plastic(N/A-lab) Y A♦ N °O m �c
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?! a 1/7:71.7-
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7. roI / BP3A-2S0 mL Plastic(NH2)2SOa(5.3-9.7) i.G 7 ..lCCif o
o I AGOU-100 mi.Amber Unpreserved vials(N/A)
u
OD
x , ! �_ VSGU-20 mL Scintillation vials (N/A) ►�+
CUI (is( I I I i DG9U-40 mL Amber Unpreserved vials(N/A)
to I h.)co r+
O

0
ETT CHAIN OF CUSTODY RECORD
to
n
0 arz„nag {3 , frage _off_
PO Box 16414,Greenville,SC 29606-7414
[phone], [phone] Fax:[phone]
Shipping Address:4 Craftsman Ct,Greer,SC 29650
W W W.6TTENV I R O NM ENTAL.COM
Client:
C.:4-A Program Containers Preservative Parameters
��Etsc�,rsC�tav;l�+t-
Facility: -
f 1 I
t{esAsaniQ.44:\\e— \j qj i t
Whole Effluent Toxicity
State: Vt_ NPDES#: N'e_� '3Ll Acute Chronic Tea Organisms O
�7:
_
c v o n L"
g (Composite only) (Grab or Composite) 7.5 �' H = -c U >O
_ p Z
U r L H
tra
U 2 :5 = 2 i H2SO4 = F. = V V)
c Sign,and Print below 3 = 0) o . 2=HCC = .an Lt L _
the dotted line E U .Y y F. S=HNOS ,B a a _ h .-
c, w. in F 4aNaOH _ _ o ,O = r, '- `o — O N . 6'
SAMPLE ID 8 m o tu o O r o u i=znA& o v 0 _ •, " T >,—' 5,- ' . l2 al5 'I f
Composm Start Date Time Satanic Collection Date Time Collected by U cn h Z z i= C7 > 6=0t]ur < < U U CJ 00 2 ✓i ; U i- 3 2 Chemical 5 r�alysis 8,Other
Wv.TTP '' `" 1
C % C- A,Z-11 p4 g•-• •2-\ WI tesuxy S t.:1.T I _ Net X , X 5 5"> t ! C C
I
1I
Special Instructions:
1
Sample Custody Transfer Record Secure Receipt Sample
Date Time Relinquished By 1 Organization Received By/Organization Area Temp°C Preserved?
?- '"i R' L ..--7't2-// -,._-i ,r i /3•yz— -uz
1
1
COMPOSITE SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES
Composite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours
Time Proportional:1 sample each hour for 24 hours.Equal voluw 0.0 and 6.0°C.Samples must not be frozen.Use water ice in sealed bags. of sample collection(completion of composite sample).
or at minimum I sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection.
Flow Proportional:As per instructions in NPDES permit.

E1J01. [phone] .r t x(664)677.6930
P.O. Box 1E414,Oreenvite,SC 29606 4 Craftsman Cairt, Greer,SC 29850
Ceriodaphnia dubia Survival and Reproduction Test
EPA-821-R-02-013 Method 1002
Client: CITY OF HENDERSONVILLE
Facility:WWTP
NPDES#:NC0025534
Test Date: 04-Aug-21
Laboratory ID#: T59782
Test Reviewed and Approved By:
Robert W.Kelley,Ph.D. Patrick D.Timms
President QA/QC Officer
•
N. Certification#E87819 SCDHEC Certification#23104
•
Test results presented in this report conform to all requirements of
NELAC,conducted under NELAC Certification Number E87819
Florida Dept.of Health.Included results pertain only to provided sam les.e 1 of 6 NCDENR Certification# 022 Page 5 of 10
Iag

Effluent Toxicity Report Form-Chronic Pass/Fail and Acute LC50 Date 18-Aug-21
Facility: Hendersonville WWTP NPDES#NC0025534 Pipe# 001 County: Henderson
Laboratory Performing Test: ETT Environmental,Inc. Comments
X
Signature of Operator in Responsible Charge
X
Signature of Laboratory Supervisor '
MAIL ORIGINAL TO Environmental Sciences Branch
Div.of Water Quality
N.C.DENR
1621 Mail Service Center
Raleigh,North Carolina 27699-1621
North Carolina Ceriodaohnia Chronic Pass/Fall Reproduction Toxicity Test Chronic Test Results
Calculated t= -1.518
Critical Value= 2.508
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 %Reduction= -6.8%
#Young Produced 21 21 20 19 19 20 17 18 22 20 18 20 %Mortality Avg.Reprod.
Adult (L)ive (D)ead L L L L L L L L L L L L 0% 19.6
Control Control
Effluent% 18.0% 0% 20.9
Treatment 2 Treatment 2
Control CV
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 7.4%
#Young Produced 19 22 22 23 23 24 22 24 16 20 19 17 %3rd Brood PASS FAIL
Adult (L)ive (D)ead L L L L L L L L L L L L 100% I X I
Complete This for Either Test Test Start Date
Collection(Start)Date 04-Aug-21
pH 1st sample 1st sample 2nd sample Sample 1 02-Aug-21 Sample 2 04-Aug-21
Control 7.8 8.2 7.7 8.0 7.7 7.9 Samole Tvoe(Duration)
Treatment 2 7.6 8.3 7.9 7.4 7.5 7.4 Grab Comp Duration 1st 2nd
Sample 1 X 24hrs. Tox Tox
Sample 2 X 24hrs. Dilution Sample Sample
start end start end start end ,d �+ >1^
D.O. let sample 1st sample 2nd sample Hardness(mg/L) 87.8 , ,
Control 7.9 8.1 8.1 7.8 9.0 7.4 Spec.Cond.(pmhos) 317 282 274
Treatment 2 8.4 8.1 7.9 7.8 8.3 7.4 Chlorine(mg/L) 0.09 0.11
Sample Temp.at receipt(°C) 0.8 0.8
LC50/Acute Toxicity Test
(Mortality expressed as%,combining replicates)
Concentration
Mortality start/end start/end
LC50= % Method of Determination Control I
95%Confidence Limits Moving Average Probit High Conc.
-
% Spearman Kerber Other pH D.O.
Organism Tested Ceriodaphnia dubia I
DEM Form AT-1 Page 6 of 10
Page 2 of 6

STATISTICAL ANALYSIS RESULTS
Facility: Hendersonville NPDES# NC0025534
Sample ID: WWTP Err# T59782 Date: 04-Aug-21
Laborato : FTT Environmental,Inc. Certification#:NCO22 Exp.Date: 11/1/2021
Survival Data
7 Day Survival Test Used: FISHERS TEST
Control 100% Test Statistic: P= 1.000
Effluent 100% Critical Value: P= 0.01
PASS: The effluent does not reduce survival of the test organisms.
Reproduction Data
Raw Data Test for Normality
Mean young/female Std.Dev. Test Used: Shapiro-Wilks Test:
Control 19.6 1.44
Effluent 20.9 2.68 W: 0.959
Critical Value: 0.884
Analysis for Differences in Reproduction Test for Homogeneity of Variance
Test Used: Equal Variance t Test. Test Used: F Test
Calculated t= -1.52 F= 3.44
Critical Value= 2.51 Critical Value= 5.32
The data are homogeneous in variance
PASS:The effluent is not chronically toxic.
Page 7 of 10
Page 3 of 6

Control Mortality and Reproduction by Test Day
source rep 1 2 3 4 5 6 7 8 Total Lab# T59782
K6 7-22 1 +5+7 9 21 Client Hendersonville
H8 7-22 2 +3+7 11 21 Sam le ID W WTP
H6 7-22 3 +4+7 9 20 NPDES# NC0025534
A8 7-23 4 +3+5 11 19 County Henderson
B7 7-23 5 +4+6 9 19 Month 8
C2 7-23 6 +4+6 10 20 Start&fed Date 04-Aug-21
W4 7-23 7 4-3+5 9 17 Start&fed Time 01:45 PM
S2 7-23 8 +3+7 8 18 Started&fed B AM
S7 7-23 9 +4+6 12 22 Test Or anism Cerioda hnia dubia
N5 7-22 10 +3+5 12 20 Neo.born date 03-Aug-21
P7 7-29 11 +3+6 9 18 Neo.born time 1640-2150
P6 7-29 12 +4+5 11 20 Test Type NCCPF
13 N/A 0 Dilution Water MHSF
14 N/A 0 Units for Conc. o
15 N/A 0 IWC 18
16 N/A 0 %3rd BROOD
17 N/A 0 Test vessels 30 ml
18 N/A 0 'Test volume 15 ml
19 N/A 0 Mean Incubator# 1
20 N/A 0 19.6 Light 1611/8dk
18 % Effluent Mortality and Reproduction by Test Day Initial Tem °C 24.8
1 2 3 4 5 6 7 8 Total Selenastrum 0.05 ml
K6 7-22 1 +3+5 11 19 YAT 0-05 ml
H8 7-22 2 +4+6 12 22 1Rr EPA 821-0-02-013',1002
H6 7-22 3 +4+7 11 22
A8 7-23 4 +4+7 12 23
B7 7-23 5 +4+9 10 23
C2 7-23 6 +4+8 12 24
W4 7-2: 7 +4+6 12 22 Comments
S2 7-23 8 +3+8 13 24
S7 7-23 9 +3+6 7 16
N5 7-22 10 +4+7 9 20
P7 7-29 11 +4+4 11 19 Control ini temp 24.7
P6 7-29 12 +3+5 9 17
0 13 N/A 0 T59781&T59782 SHARE A CONTROL
0 14 N/A 0
0 15 N/A 0
0 16 N/A 0
0 17 N/A 0
0 18 N/A 0
0 19 N/A 0 Mean
0 20 N/A 0 20 9
'Kew JC AM " 4'o*ft,+rf%/tY
'`,. JZ JC AM JC AM JC 11-Au.-21
. 02.58 PM 01'.43 PM 01.04 AM 06.22 AM 11 30 AM 08 00 AM bsi7� Ir L 11:40 AM
AM
24.7 24.8
Old temp.°C 25.1 25.5 25.8
Control New temp."C 24.4 24.6 D=Dead N/A-Lost or not used
Page 8 of 10
Page 4 of 6

ETT CHAIN OF CUSTODY RECORD
" -— . "t n .. Page I of____j___
PO Box 16414,Greenville,SC 29606-7414
[phone], [phone] Fax[phone]
Shipping Address:4 Craftsman Ct.Greer,SC 29650
W W W.LTTENVIRCNMENTAL.COM
Client:
C -.y .n4 14,111iL Program Containers Preservative Parameters
Facility: (. __..``__,,�� , ;ff!! `1►v` i _
I' 1�:�!`„c....', E_. Whole EfIlucnt Toxicity p
State: ME NPDES r: f r`Cf �5 acuic Chronic Test Organisms M
Li 1
U (Composite only) (Grab or Composite) < 'p 9 e= !, - — a-
c ° 5 - - o_HSOa y L a " FA.:
Sign,and Print below z ,1 =� Hct_ _ °o _ = —
= ! a- ca o HNo3 o o .- ' m ? 'Y
- the dotted line G = c (3 . y a r aoH = -2 o o y ° = U 2{ —
SAMPLE ID �? CompasiteStartDate Time Sample Collection Date Time Collected by U ti) cn Z c- U > ^ 6=�i, < < 0 v U c 2 i. 7 0 % Chemical Iysis&Other .
WiAr il� � SS 6i1 6 i .� A
glr% C Fi-2-1-k ,zti1 'Ay3�2-1 1C01 'i rata,iSt;\NN _ I l NewX _ �/Z
to
cri
Special Instructions:
Sample Custody Transfer Record Secure Receipt Sample
Date Time Relinquished By/Organization Received By I Organization Area Temp°C Preserved?
2-3--ZI 1119 11A,et ,-y-P i� z ����-- �, —c fir/3, i .V2--1 © _
12d.Qh ojetiftythWeatitialerr ilo 121 ,tria , 1 0.0
I
COIPOSITE SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD Tf ME PROCEDURES
Composite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours
Tinto Proportional:1 sample each hour for 24 hours.Equal volur 0.0 and 6.0°C.Samples must not be frozen.Use water ice in sealed bags. of sample collection(completion of composite sample).
or at minimum 1 sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection.
Flow Proportional:As per instructions in NPDES permit

ETTCHAIN OF CUSTODY RECORD
g.
��.� �� atA t it- Ee-I 6e E Page of
PO Box 16414,Greenville,SC 29606-7414
[phone], [phone] Fax[phone]
Shipping Address:4 Craftsman Ct,Greer,SC 29650 [ �
WWW.CTTENVrp DNS.ENTAL.=M �l/ L! tl tl
Client:
C.;Al,Th� ,t ltvi-su-AAv;,ko Program Containers Preservative Parameters
Facility: , `,�� r _� _
1-►p�y14;�C1�� P W Whole Effluent Toxicity n
State: Nic NPDES#: �9LoD�5-;:3f-1 Acute Chronic Test Organisms m
U —
c ".4 — O O
o >, m — c = U Z
d (Composite only) (Grab or Composite) Q p 9 - U e _ c9 — 0
?? p c I�HSOi y - = = f
aSign,and Print below 3 - m o . 3=HCL = G _ _no = '_,
the dotted line = E p '' U .0 ° = I4I40' Q y - " :� = '? —
C7 0 ._ — 3 4.NaOH _ c o = = • , 0 = o N o —
SAMPLE ID 2 ',Co m o t o 'a 3 t8j 3=zn.4e u o - %+.'_ T's L _ -_,
mposite Start Due I Time Sample Collection Dale Time Collected by U in rn z �. E U > 6=Other < < U U U V Z rn_ _ U _ Chemical Analysis 8 Other
n
R-4 21 1OO 5-5 21 1�54_ t„zy Ss»:4'c,. 1.1_ _ NPa,e� X 14
G O a �q 18[��
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I
Special Instructions:
Sample Custody Transfer Record Secure Receipt Sample
Date Time Relinquished By/Organization R
eceived By/�aan:�.on Area Temp°C Preserved?
$-5-Li t 2.0 1� I ..0 o'vJ_--- �� f�r7 I , , Jt'�Sal I3i2 - / f7At✓kv gC - ,// Y I
gig p4 ogao Fcd&,c O W I A71
I 1
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COMPOSITE SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES
Coniosite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing.the sample must first be used within 36 hours
TimmFroportional: I sample each hour for 24 hours.Equal volur 0.0 and 6.0°C.Samples must not be frozen.Use water ice in sealed bags. of sample collection(completion of composite sample).
or af?rtinimum I sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection.
Flow Proportional:As per instructions in NPDES permit.

Pace Analytical Services,LLC
2225
de Dr.
aceAnalytica! Asheville,NC'28804
www.pacelabs.com [phone]
Page 1 of 1
Laboratory Report
Mr. Alexander Lillie Report Date: 12/08/2021
City of Hendersonville VVVVTP Date Received: 11/16/2021
99 Balfour Road
Hendersonville, NC 28792
Project: Hville WWrP NC0025534 11/16
Pace Project No.:92572628
Reviewed by: � `"—ice- 1c�,—__.
Lorri Patton
1(828)254-7176
[e-mail]
Page 1 of 10
J

—
Document Name: Document Revised:October 28,2020
Sample Condition Upon Recelpt(SCUR) Page 1 of 2
/111UC8fl ldI I(Gat Document No.: Issuing Authority:
, F•CAR-CS-033-Rev.07 Pace Carolinas Quality Office
laboratory rec ' ing samples: _
Asheville Eden_ Greenwood L Huntersville` Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑
Sample Condition Client Name: WO# : 92572628
Upon Receipt Project Sip,;II, l/uw 4 f' 111111III IIIIIIII1I III
Courier: ['Fed ['UPSFed Ex UPS ❑USPS ❑Client
❑Commercial 2(ace ❑other: 9257628
Custody Seal Present? Des No Seals Intact? Des
Date/Initials Person Examining Contents: /! r1C/f
Packing Material: uhble Wrap ❑Bubble Bags ['None ❑ Other Biological Tissue Frozen?
Des [ No [i.''1
Thermometer Wet ❑Blue ❑None
IR Gun ID: 3 To/ ( Type of Ice:
Correction Factor:
Cooler Temp: I. Add/Subtract('Cl _ Temp should be above freezing to 6'C
❑samples out of temp criteria.Samples on ice,cooling process
Cooler Temp Corrected('C): I,'7 has begun
USDA Regulated Soil( NIA,water sample)
Did samples originate in a quarantine cone within the United States:CA,NY,or SC(check maps)? Did samples originate from a foreign source(internationally,
Des ❑No including Hawaii and Puerto Rico)?❑Yes ❑Nu
Comments/Discrepancy:
Chain of Custody Present? Yes ❑No ON/A 1.
Samples Arrived within Hold Time? /s ❑No ON/A -2.
Short Hold Time Analysis(<72 hr.)? ,L'Jres Eke ❑N/A 3.
Rush Turn Around Time Requested? Des No ON/A _ 4.
Sufficient Volume? es ❑rlo ❑N/A 5. _
Correct Containers Used? Zfres Duo DIVA 6.
-Pace Containers Used? s []No ON/A --
Containers intact? res ❑No ❑N/A 7.
Dissolved analysis:Samples Field Filtered? Over DN. 'N/A 8.
Sample Labels Match COC? 1s ❑No ❑N/A 9.
t-/
-Includes Date/Time/ID/Analysis Matrix:^ _ ___.__._.�
Headspace in VOA Vials(>S-6mm)? Elves ❑N° licl/A 10.
Trip Blank Present? Over Onto (JN/A 11.
Trip Blank Custody Seals Present) _ Yes ❑No __ _-- — -
COMMENTS/SAMPLE DISCREPANCY Field Oata Required? Des ❑No
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: - Date/Time:
Project Manager SCURF Review: _ Date:
Project Manager SRF Review: Date:
Page 2 of 10

Document Name: Document Revised:October 28,2020
__Sample Condition Upon Receipt(SCUR) Page 2 of 2
aceAnalytical• Document No.: Issuing Authority:
F-CAR-CS-033-Rev.07 Pace Carolinas Quality Office*Check mark top half of box if pH and/or dechlorination is Project IfWO# : 92572628
verified and within the acceptance range for preservation PM: Lip Due Date: 12/02/21
samples, CLIENT: 93—HVILL WWT
Exceptions:VOA,Coliform,TOC,Oil and Grease,DR0/8015{water)DOC,tlHg
**Bottom half of box is to list number of bottles ,
T L `ZL !Iy V o Z
S 4 Q v• a , d rri A
z 2 r� Z N Q a 5
'D V a 2 ry ry alf y `'r v o Z C r 4 21 e. 2 vv
a v e .o v r 21 A y N v r Z `= r Q Z O u
N N a n 5 -- m v v v a ; ._ ¢ Y 2 yJ� -v- a
a a al 'v !.1 1 ZI
Q a7 0 da v O O Q cO r7 E V ! f l r Q �! 3 O .1. 1 a Z .a
J
,a n _o tA _a ^ :a m 7 a 13 E n E a ¢ d d Q `a Z, u ?; `° E .. 2
"y g E E G E Q ry j O O O a a in ut a ,II Q
a a a a a d S
C J
E E r t E E E E v v t E u a m E E E E .� m E E cE E E
;4, a o ,n 0 ,n Vl Z _ 2 _ al l7 0 0 0 0 .O ' I an ur 0 ry
,�-r �r o .y n , ,-i ',If . .a .t rr r. r,i 0 Y ,j r, .^r. rr ry '
E v m m 6 o et a a L. 6 :[ Ja Jr ee r as 6 a Y x r r 2 d o O s
.-r r+ rn r+ m rn ar ar T m d t7 ut ry a l7 :0 l7
a a a a a. a a a 3 lv '0 r7 t7 l) t7 t7 t7 ' t9 O a a
m m m m m m m m �i 4 4 d d d d O > > O > > '� of m l d > 0
1 — 116,: \-- r\ \3 \
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pH Adjustment Log for Preserved Samples
Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot tt
adjusted added
t_ - 1_ _ _
Nate. Whenever there is a discrepancy affecting North Carolina compliance samples,a copy of this form will be sent to the North Carolina OEHNR Certification Office{Le.
Out of hold,incorrect preservative,out of temp,incorrect containers.
Page 3 of 10

0
ETT CHAIN OF CUSTODY RECORD
re
tr a_
environmental (Page of_
PO Box 16414,Greenville SC 29606-7414 !!!!!!
[phone], [phone] Fax:[phone]
Shipping Address:4 Craftsman Ci.Greer,SC 29650
W W W.r.TTCN V MONM eNTAL.COM
Client: ` - —
•ii-tl f?1-- UP.tstzi-rsca4-4i 4.- Program Containers Preservative Parameters ,
Facility: `, JJ I i
„ _csc Y'k1y� , Whole Effluent Toxicity •
State: NC_ NPDES a: l�(CAa25 '-tl
Cl
Acute Chronic Test Organisms =
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SAMPLE ID E. Composite Date Time Sample ° w o r: = o u 5=znac u o = T- ^ w u
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Special Instructions:
— —
Sample Custody Transfer Record Secure Receipt Sample
Date Time Relinquished By/Organization A,..i
ed By' ma izs tion Area Temp`C Preserved?
hiwb, S ,.
-
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COMPOSITE SAAIPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TIAIE PROCEDURES
Composite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours
Time Proportional: I sample each hour for 24 hours.Equal voltu 0.0 and 6.0°C.Samples must not be frozen.Usc water ice in scaled bags. of sample collection(completion of composite sample).
or at minimum 1 sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection.
Flow Proportional:As per instructions in NPDES permit.

EE] ,Ine. [phone] .f-AX(864)077.6938
P.O. Box 1E414,Creenvlle, GC 29606 4 Craftsman Court, Greet,SC 29650
Ceriodaphnia dubia Survival and Reproduction Test
EPA-82 -R-0 -0 3 Method 1 2 1 1002
Client: CITY OF HENDERSONVILLE
Facility:WWTP
NPDES#:NC0025534
Test Date: 17-Nov-21
Laboratory ID#:T60649
Test Reviewed and Approved By:
c7t,dt. y• Vit--,w.^-i
Robert W.Kelley,Ph.D. Patrick D.Timms
President QA/QC Officer
Certification#E87819 SCDHEC Certification#23104
Test results presented in this report conform to all requirements of
NELAC,conducted under NELAC Certification Number E87819
Florida Dept.of Health.Included results pertain only to provided sam les.e of 6
NCDENR Certification# 022 Page 5 of 10
Wag 1

Effluent Toxicity Report Form-Chronic Pass/Fail and Acute LC50 Date 06-Dec-21
Facility: Hendersonville WWTP NPDES#NC0025534 Pipe# 001 County: Henderson
Laboratory Performing Test: ETT Environmental, Inc. Comments
X
Signature of Operator in Responsible Charge
x 4(' 'i
Signature of Laboratory Supervisor
MAIL ORIGINAL TO Environmental Sciences Branch
Div.of Water Quality
N.C.DENR
1621 Mail Service Center
Raleigh,North Carolina 27699-1621
North Carolina Cerlodaohnia Chronic Pass/Fail Reproduction Toxicity Test Chronic Test Results
Calculated t= -1.0761
Critical Value= 2.508
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 %Reduction= -3.9%
#Young Produced 21 24 20 22 23 21 21 22 24 22 20 17 %Mortality Avg.Reprod.
Adult (L)ive (D)ead L L L L L L L L L L L L 0% 21.4
Control Control
Effluent% 18.0% 0% 22.3
Treatment 2 Treatment 2
Control CV
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 9.0%
#Young Produced 23 24 22 23 19 21 26 21 22 21 24 21 %3rd Brood PASS FAIL
Adult (L)ive (D)ead L L L L L L L L L L L L 100% I X I
Complete This for Either Test Test Start Date
Collection(Start)Date 17-Nov-21
pH 1st sample 1st sample 2nd sample Sample 1 15-Nov-21 Sample 2 17-Nov-21
Control 7.7 8.2 , 7.7 8.4 7.7 8.1 Sample Tvoe(Duration)
Treatment 2 7.8 8.2 7.8 8.5 7.9 8.0 Grab Comp Duration 1st 2nd
Sample 1 X 24hrs. Tox Tox
Sample 2 X 24hrs. Dilution Sample Sample
start end start end start end
D.O. 1st sample 1st sample 2nd sample Hardness(mg/L) 83.7
Control 8.2 7.9 8.0 8.4 8.0 7.5 Spec.Cond.(pmhos) 313 305 329
Treatment 2 8.3 8.2 7.9 8.3 8.0 7.4 Chlorine(mg/L) <.05 <.05
Sample Temp.at receipt(°C) 1.5 0.7
LC50/Acute Toxicity Test
(Mortality expressed as%,combining replicates)
Concentration
1
Mortality start/end start/end
LC50= % Method of Determination Control
95%Confidence Limits Moving Average Probit 11Ell High Conc.
Spearman Karber Other pH D.O.
Organism Tested Ceriodaphnia dubia I
DEM Form AT-1 Page 6 of 10
Page 2 of 6

STATISTICAL ANALYSIS RESULTS
Facility: Hendersonville NPDES# NC0025534
Sample ID: WWTP err# T60649 Date: 17-Nov-21
Laborato : 1:'FT I iivironmental,Inc. Certification#:NCO22 Exp.Date: 11/1/2022
Survival Data
7 Day Survival Test Used: FISHERS TEST
Control 100% Test Statistic: P= 1.000
Effluent 100% Critical Value: P= 0.01
PASS:The effluent does not reduce survival of the test organisms.
Reproduction Data
Raw Data Test for Normality
Mean young/female Std.Dev. Test Used: Shapiro-Wilks Test:
Control 21.4 1.93
Effluent 22.3 1.86 W: 0.970
Critical Value: 0.884
Analysis for Differences in Reproduction Test for Homogeneity of Variance
Test Used: Equal Variance t Test. Test Used: F Test
Calculated t= -1.08 F= 1.07
Critical Value= 2.51 Critical Value= 5.32
The data are homogeneous in variance
PASS:The effluent is not chronically toxic.
Page 7 of 10
Page 3 of 6

Control Mortality and Reproduction by Test Day
source rep 1 2 3 4 5 6 7 8 Total Lab# T60649
KK2 11-1C 1 3 +7+11 21 Client Hendersonville
C9 11-5 2 +4+8 12 24 Sample ID WWTP
U2 11-5 3 +4+6 10 20 NPDES# NC0025534
P10 11-4 4 +3+8 11 22 County. Henderson
11111-10 5 +4+7 12 23 Month 11
E3 11-5 6 +4+7 10 21 Start&fed Date 17-Nov-21
S5 11-5 7 4 +8+9 21 Start&fed Time 02.00 PM
04 11-4 8 +3+7 12 22 Started&fed By JC
JJ9 11-10 9 +4+7 13 24 Test Organism Cerioda hnia dubia
F7 11-5 10 3 +8+11 22 Neo,born date 16-Nov-21
V4 11-5 11 4 +6+10 20 Neo:born time 1705-2200
Q6 11-4 12 +3+7 7 17 Test Type NCCPF
13 N/A 0 Dilution Water MHSF 11/12/21C
14 N/A 0 Units for Conc. %
15 N/A 0 IWC 18
16 N/A 0 %3rd BROOD
17 N/A 0 Test vessels "30 ml
18 N/A 0 Test volume _ 15 ml
19 N/A 0 Mean Incubator# 1
20 N/A 0 21.4 Light 161t/Sdk
18 % Effluent Mortality and Reproduction by Test Day Initial Temp°C 24.8
1 2 3 4 5 6 7 8 Total Selenastrum 0.05 ml
KK2 11- +4+7 12 23 VAT 0.05 ml
C9 11-5 2 4 +9+11 24 t,Sa d °,! „EPA 321-R-0 2-01 3100 2
U2 11-5 3 +4+7 11 22
P 10 11 4 +4+7 12 23
111 11-1( 5 +4+6 9 19
E3 11-5 6 +3+6 12 21
S5 11-5 7 5 +8+13 26 Comments
04 11-4 8 +3+7 11 21
JJ9 11-' 9 4 +8+10 22
F7 11-5 10 4 +6+11 21
V4 11-5 11 +4+7 _ 13 24 Control ini temp 24.7
Q6 11-4 12 4 +5+12 21
O 13 N/A 0
0 14 N/A 0
0 15 N/A 0
0 16 N/A 0
0 17 N/A 0
O 18 N/A 0
0 19 N/A 0 Mean I
1 0 20 N/A 0 22.3
renew JZ JC End Date s
ed JC JZ JZ JC JC JC d S. ( 24-Nov-21
time fed&renew 00'07 AM 04.36 PM 04.36 PM 06 19 AM 10.21 AM 07-34 AM yy y,,.,. , 1st AM AM
f
/Newtemp-'C — 24.7 24.8
Old temp.'C 25.5 24.9 25.1
Control New temp.°C 24.6 24.5 D=Dead N/A-Lost or not used
Page 8 of 10
Page 4 of 6

ETTCHAIN OF CUSTODY RECORD
Pageof 4
PO Box 16414,Greenville,SC 29606-7414
[phone], [phone] Fax[phone]
Shipping Address:4 Craftsman Ci,Greer,SC 29650
W W W.0 V1 ENV IRONMENTAL.COM
Client: �
( '- tc Pp «Lei3at:\ Program Containers Preservative Parameters
Facility• 'f- '\' ,
• 4-143.�t-�jt'�,�3�i tit- 'V Whole Etituent Toxicity
State: HC. NPDES it: i 4C.00Y.S `1 Acute Chronic Test Organisms m
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U (Composite only) (Grab or Composite) < o o — lJ — = .� J
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the dotted line c c .c �' .^ y aa�on = .c = " r ? = `(Z$ 6 2�
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SAMPLE ID O Composite Stan Date I Time Sample Collection Date Time Collected by U Tin Tin z ne E. v > ° 6.other < < J 0 L7 d z . f C i 3 2 Chemical Analysis B.Other
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Special Instructions:
Sample Custody Transfer Record Secure Receipt Sample
Date Time Relinquished By/Oraanization rived By rn ization 1
Area Temp°C Preserved?
at-i‘ v t 11u� G _
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P,ribL. ,st� / _ttItf2! I}l02 I /-S
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i CegIPOSITE SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES
Cogposite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours
Tires Proportional:1 sample each hour for 24 hours.Equal voles 0.0 and 6.0°C.Samples must not be frozen_Use water ice in sealed Imes. of sample collection(completion of composite sample).
or ?minimum 1 sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection.
Flow Proportional:As per instructions in NPDES permit.

ETTCHAIN OF CUSTODY RECORD
T ' rim3at rteo `Page of
PO Box 16414,Greenville,SC 29606-7414
[phone], [phone] Faic(864)877 6938
Shipping Address:4 Craftsman Ct,Greer,SC 29650
WwW.ETeNviRos NTAL.c M
Client:
C>t-ti tr ' 14 �v`i�,� Program Containers Preservative Parameters
Faculty: )
i�emcie� mu At ww-i-2 Whole Effluent Toxicity
State: 1\'PDES �5C.2frsrj4 Acute Chronic Test Organisms
o (Composite only) (Grab or Composite) < p = U `� - o — .
U C U =tiSOd ^ Z G -^ J V V]
Sign,and Print below 3 > 5 o o _HCL a' Z o o = --V m ^ o .N ? '`'
the dotted line ' - .. .0 _=Hno, — _ — 5 _. �j
U G = ._ . m 4=NaOH = O o = -m -P N cJ' 43 2 S/9-C 2 y
O O tom., O O -- _ O j rZnAc U U ,- _^ >,L,� r -
SAMPLE ID U Composite Start Date lime Semple Collection Dote Time Collected by U ra rn Z C7 > 6_o < < U 0 U C1 tt .2 _ i.) = 3 2. Chemical Analysis&Other
wvn-q' 1A-411 4°13
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Special Instructions:
Sample Custody Transfer Record Secure Receipt Sample
Date Time Relinquished By/Organization Rec ''ed By/ anizalion Area Temp°C Preserved?
!J-/ ''Si i,Zj 110 - / 1--11(- .e I I
ii!iglaI ias 01J1i(./ �V . /t Il5/sJ t i .- -3. 1
P (J(2IY 1 igl 10/1 (ire iI jig iii "I"
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CYjt1POSITE SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES
Cgitposite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing_the sample must first be used within 36 hours
Time Proportional:1 sample each hour for 24 hours.Equal volts 0.0 and 6.0'C.Samples must not be ftucen.Use water ice in sealed bags. of sample collection(completion of composite sample).
or at minimum 1 sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection.
Flow Proportional:As per instructions in INNPDES permit.

E:,iJ .. [phone] .rii.x(864)877.6938
P.O. Box 1E414,Creenvlle, SC 29606 4 Craftsman Cwrt,Greer,SC 29550
Ceriodaphnia dubia Survival and Reproduction Test
EPA-821-R-02-013 Method 1002
Client: CITY OF HENDERSONVILLE
Facility:WWTP
NPDES#:NC0025534
Test Date: 02-Feb-22
Laboratory ID#:T61162
Test Reviewed and Approved By:
zW V- 1' rat,',4 3). O v
Robert W.Kelley,Ph.D. Patrick D.Timms
President QA/QC Officer
`
.7 ..
Certification#E87819 SCDHEC Certification#23104
Test results presented in this report conform to all requirements of
NELAC,conducted under NELAC Certification Number E87819
Florida Dept.of Health.Included results pertain only to provided samples. NCDENR Certification# 022
Page 1 of 6

1
Effluent Toxicity Report Form-Chronic Pass/Fail and Acute LC50 Date 16-Feb-22
Facility: Hendersonville WWTP NPDES#NC0025534 Pipe# 001 County: Henderson
Laboratory Performing Test: ETT Environmental. Inc. Comments
X
Signature of Operator in Responsible Charge
X !
Signature of Laboratory Supervisor
MAIL ORIGINAL TO Environmental Sciences Branch
Div.of Water Quality
N.C.DENR
1621 Mail Service Center
Raleigh,North Carolina 27699-1621
North Carolina CeriodaDhnia Chronic Pass/Fail Reproduction Toxicity Test Chronic Test Results
Rank sum= 113
Critical Value= 109
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 %Reduction= 4.0%
#Young Produced 22 23 22 21 23 22 22 24 22 24 23 24 %Mortality Avg.Reprod.
Adult (L)ive (D)ead L L L L L L L L L L L L 0% 22.7
Control Control
Effluent% 18.0% 0% 21.8
Treatment 2 Treatment 2
Control CV
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 4.3%
#Young Produced 21 22 21 23 22 22 22 21 22 21 21 23 %3rd Brood PASS FAIL
Adult (L)ive (D)ead L L L L L L L L L L L L 100% I X I
Complete This for Either Test Test Start Date
Collection(Start)Date 02-Feb-22
pH 1st sample 1st sample 2nd sample Sample 1 31-Jan-22 Sample 2 02-Feb-22
Control 7.7 8.0 7.9 8.2 7.7 8.2 Sample Type(Duration)
Treatment 2 7.7 8.1 7.8 8.3 7.7 8.2 Grab Comp Duration lst 2nd
Sample 1 X 24hrs. Tox Tox
Sample 2 X 24hrs. Dilution Sample Sample
start end start end start end
D.O. 1st sample sample 2nd sample Hardness(mg/L) 85.4
Control 7.7 7.7, 7.8 7.9 8.1 7.7 Spec.Cond.(pmhos) 312 285 310
Treatment 2 8.0 8.0 7.9 7.8 8.4 7.7 Chlorine(mg/L) <.05 <.05
Sample Temp.at receipt(CC) 1.0 0.9
LC50/Acute Toxicity Test
(Mortality expressed as%,combining replicates)
Concentration
a
Mortality start/end start/end
LC50= % Method of Determination Control I
95%Confidence Limits Moving Average Probit High Conc.
% % Spearman Karber Other pH D.O.
Organism Tested Ceriodaphnia dubia I
DEM Form AT-1
Page 2 of 6
1

STATISTICAL ANALYSIS RESULTS
Facility: Hendersonville NPDES# NC0025534
Sample ID: WWTP Err# T61162 Date: 02-Feb-22
Laborato : l:'I"I'Environmental,Inc. Certification#:NCO22 Exp.Date: 11/1/2022
Survival Data
7 Day Survival Test Used: FISHERS TEST
Control 100% Test Statistic: P= 1.000
Effluent 100% Critical Value: P= 0.01
PASS: The effluent does not reduce survival of the test organisms.
Reproduction Data
Raw Data Test for Normality
Mean young/female Std.Dev. Test Used: Shapiro-Wilke Test:
Control 22.7 0.98
Effluent 21.8 0.75 W: 0.879
Critical Value: 0.884
Analysis for Differences in Reproduction Test for Homogeneity of Variance
Test Used: Wilcoxon Test Test Used: F Test
Rank sum= 113.00 F= 1.71
Critical Value= 109.00 Critical Value= 5.32
The data are homogeneous in variance
PASS:The effluent is not chronically toxic.
Page 3 of 6

Control Mortality and Reproduction by Test Day
source rep 1 2 3 4 5 6 7 8 Total Lab# T61162
C8 1-21 1 +4+7 11 22 ,Client Hendersonville
U 1-21 2 +4+7 12 23 Sample lD WWTP
GG6 1-26 3 +3+8 11 22 NPDES# NC0025534
F4 1-21 4 +4+7 10 21 County Henderson
T6 1-21 5 +4+8 11 23 Month 2
LL5 1-26 6 5 +7+10 22 Start&fed Date 02-Feb-22
D5 1-21 7 +3+7 12 22 Start&fed Time 01.35 PM
W10 1-21 8 +5+8 11 24 Started&fed B JC
HH10 1-2 f, 9 +4+7 11 22 Test Or anism Cerioda hnia dubia
A8 1-21 10 +4+8 12 24 Neo.born date 01-Feb-22
V6 1-21 11 +5+7 11 23 Neo.born time 1700-2200
JJ 1-26 12 +4+9 11 24 Test T e NCCPF
13 N/A 0 Dilution Water MHSF 1/23/22C
14 N/A 0 Units for Cone,
15 N/A 0 IWC 18
16 N/A 0 %3rd BROOD
17 N/A 0 Test Test vessels 30 ml
18 N/A 0 Test volume 15 ml
19 N/A 0 rMean Incubator# I' 1
20 N/A 0 22.7 Light 161tl8dk
18 % Effluent Mortality and Reproduction by Test Day Initial Temp°C 24.8
1 2 3 4 5 6 7 8 Total Selenastrum 0.05 ml
C8 1-21 1 +4+7 10 21 YAT 0.05 ml
U 1-21 2 +4+7 11 22 Test method EPA 821-3-02-013_1002
GG6 14 3 +4+6 11 21
F4 1-21 4 +4+8 11 23
T6 1-21 5 +5+7 10 22
LL5 1-2( 6 5 +7+10 22
D5 1-21 7 +4+7 11 22 Comments
W1O 14 8 4 +6+11 21
HH10 1- 9 +4+7 11 22
A8 1-21 10 +3+8 10 21
V6 1-21 11 +4+7 10 21 Control ini temp 24.7
JJ 1-26 12 +5+7 11 23
0 13 N/A 0
0 14 N/A 0 61161 AND 61162 SHARE A CONTROL
0 15 N/A 0
0 16 N/A 0
0 17 N/A 0
0 18 N/A 0
0 19 N/A a yean I
0 20 N/A 0 21 8
renew '"' JG JC End Date
fed JC JG A JG JC AM ( 09-Feb-22
time fed&renew l 07'37 AM 03.34 PM 07'34 AM 08'.25 AM 10 17 AM 05-38 AM ',7, 12 28 PM JZ
New temp.'C 24.7 24.6
,-
Old temp.°C 25.2 25.2
Control New temp.°C 24.6 24.6 D-Dead NIA-Lost or not used
Page 4 of 6

ETTCHAIN OF CUSTODY RECORD
. ._ Page i of I
PO Box 16414.Greenville,SC 29606-7414
[phone], [phone] Fa,c(864)877 6938
Shipping Address:4 Craftsman Ct,Greer,SC 29650
W W W_ETTENVln QNM ENTgLcoM
Client:
C ) �D„�„r 14_ Program Containers Preservative Parameters
Facility: ttt 1�`�t� `z�1y(
�{hifa.161. 3li,,r1,11� Y\ i,iP Whole ErlluentTozicity n
State: I4 L NPDES�►I0 S Acute Chronic Test Organisms ,-,
<
ti L� n
e c p o
a (Composite only) (Grab or Composite) < p o = U = v 0 _ .0 Z
U = r. _ t-. i=FBSO4 - - — en
Sign and Print below + F t c 2=HCL r= L o p _ .no o =N F- <
v the dotted line 3 E '' U u H � a=x�ao • o = ' -. = o O
u. _ c. = t256 J SZ
SAMPLE ID U Composite Start Cute Time Sample Collection Datc Time Collected by U en Z 's U > v g=D� < < U U U U L .a cn U i 13 Chemical Analysis&Other
c; G 1-31-2iru .2 talk 2.-t 1 a-Acm .:k� . I x 1Jea�
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Special Instructions:
Sample Custody Transfer Record Secure Receipt Sample
Date Time Relinquished By/Organization Received By/Organization l ,Area Temp nC Preserved?
2-(^2(.., t
d VII / uu mod \fu-----l�.\`\24 ' 3n I N
-gsot'e IA_9 __W NS 1-r , z z- �3 3 r /2z r 3;37 I i/
z.'1 ° I A)_
61.1t27:1- UP
COMPOSITE SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES
Composite samples must be collected over a 24 hour period. Sample temperature durine collection and transport must be between For toxicity testing the sample must first be used within 36 hours
Time Proportional:I sample each hour for 24 hours_Equal volur 0.0 and 6.0°C.Samples must not be frozen.Use water ice in sealed bags. of sample collection(completion of composite sample).
or at minimum I sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection.
Flow Proportional:As per instructions in NPDES permit.

______
ETTCHAIN OF CUSTODY RECORD
qe.
= gts €c'.vatr"c= Page __of___
PO Box 16414,Greenville,SC 29806-7414
[phone], [phone] Fax[phone]
Shipping Address:4 Craftsman Ct,Greer,SC 29650
W W W.ETTENV IRCINMENTAL,COM
Client: }
C:Try 4 He cM v e 1 Program Containers Preservative Parameters
Facility: iii 1 F( , ,� V(--,1-�
�l\1(�4f �, I \Vh°IcClilucntTozidtr '
State: �L.. NPDES m: i•4LQ0�SSS4 Acute Chronic Test Organisms O
i
=
3 p
F. J C_ D'
e (Composite only (] n ti _ O = =cl) O :+
u ( P ) (Grab or Composite) Q o - U ,n _- _ - Z
U = `o = = t=HS0. _ 4 = .E v7
Sign and Print below r a g. ? HCL = - z _ u = _
3 � s s 2 "I' . ems •- _ —
the dotted line �_ —' re = a=l�eo — " = _ ? Z S 5 Y S -
U _ y w _O J®IOH -. _ E. O v ^ O _ Q.` .✓ -
O O = O 2.SAMPLE ID U Composite Start Date Time Sample Collection Date Time Collected by U m rn Z .^— O > = 6-per 1< < U U U C r` z ^U 3 z Chemical Analysis 8 Other
d =� C. ` .-?--22 kot$ 23=Z.Z. la23 �Nis/ % i -It Nam, x Y.
to
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0
Special Instructions:
Sample Custody Transfer Record Secure Receipt Sample
Date Time Relinquished By/Organization PO �\'2' Received By/Organization `\• Area Temp°C Preserved?
0 V 0 kA, - i-f- =-\-- 1- -tom--- "2., VCi 0, t_C.=—, .r) I Vim—Ia"2-\3\v- I
'mil d 0.� 3_. .0 \ f -` 1 2i312-�-1 ,3:5� =-, ,......,e1.....„2 ?�/ /--- ---3� I r. I A./
9ktiaa ig0 4.4,v,,,_, 4)../IgcL¢c, \V erL-- - \ 1-14 VIZ.\ a:10 o-T- I o_9 I
COMPOSITE SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES HOLD TIME PROCEDURES
Composite samples must be collected over a 24 hour period. Sample temperature during collection and transport must be between For toxicity testing the sample must first be used within 36 hours
Time Proportional:I sample each hour for 24 hours.Equal voles 0.0 and 6.0°C.Samples must not be frozen.Use water ice in sealed bags. of sample collection(completion of composite sample).
or at minimum I sample every 4 hours over 24 hours. Sample may not be used after 72 hours from sample collection.
Flow Proportional:As per instructions in NPDES permit

PACE ANALYTICAL SERVICES, LLC
Detection Summary
Pace Analytical Services, LLC
Lot Number: WJ30051
Project Name: WWTP PPA 9/29
Project Number: 92564018
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 WWTP EFF (PPA)Grab Aqueous Mercury(CVAFS) 1631E 0.740 ng/L 5
(1 detection)
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 52 of 60
Page 4 of 12

Mercury (CVAFS)
Client:Pace Analytical Services,LLC Laboratory ID:WJ30051-001
Description:WWTP EFF(PPA)Grab Matrix:Aqueous
Date Sampled:09/28/2021 1519 Project Name:WWTP PPA 9/29
Date Received:10/28/2021 Project Number:92564018
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 11/02/2021 0739 JAB2 11/01/2021 0841 20744
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Mercury(CVAFS) 7439-97-6 1631E 0.740 0.500 ng/L 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range O=Surrogate failure
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% L=LCS/LCSD failure
H=Out of holding time W=Reported on wet weight basis S=MS/MSD failure
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 53 of 60
Page 5 of 12

Mercury (CVAFS)
Client:Pace Analytical Services,LLC Laboratory ID:WJ30051-002
Description:WWTP EFF(PPA)Grab Blank Matrix:Aqueous
Date Sampled:09/28/2021 1519 Project Name:WWTP PPA 9/29
Date Received:10/28/2021 Project Number:92564018
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 11/02/2021 0712 JAB2 11/01/2021 0841 20744
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Mercury(CVAFS) 7439-97-6 1631E ND 0.500 ng/L 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range Q=Surrogate failure
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% L=LCS/LCSD failure
H=Out of holding time W=Reported on wet weight basis S=MS/MSD failure
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 54 of 60
Page 6 of 12

1
WG1749985 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 625.1 L1411440-02 I
Method Blank (MB)
(MB)R3713039-4 10/04/21 02:14 Cp
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/I ugh' ugh! Tc
Pyrene U 0.107 1.00
1,2,4-Trichlorobenzene U 0.0698 10.0 3
SS I
Azobenzene U 0.105 10.0
4-Chloro-3-methylphenol U 0.131 10.0 4
2-Chlorophenol U 0.133 10.0 Cn
2-Nitrophenol U 0.117 10.0
4-Nitrophenol U 0.143 10.0 5
Sr
Pentachlorophenol U 0.313 10.0
Phenol U 4.33 10.0
2,4,6-Trichlorophenol U 0.100 10.0 Qc
2,4-Dichlorophenol U 0.102 10.0
2,4-Dimethylphenol U 0.0636 10.0 7GI
4,6-Dinitro-2-methylphenol U 1.12 10.0
2,4-Dinitrophenol U 5.93 10.0
(5)Nitrobenzene-d5 56.2 15.0-314 Al
(S)2-Fluorobiphenyl 64.8 22.0-127
(5)p-Terphenyl-d14 69.0 29.0-141 9
SC
(S)Phenol-d5 19.5 8.00-424
(5)2-Fluorophenol 2Z3 10.0-120
(5)2,4,6-Tribromophenol 59.0 10.0-153
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS)R3713039-1 10/04/21 01:10•(LCSD)R3713039-2 10/04/21 01:32
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec.Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ugh ug/I ugh % % % % %
Acenaphthene 50.0 33.9 35.0 67.8 70.0 47.0-145 3.19 48
Acenaphthylene 50.0 37.9 38.2 75.8 76.4 33.0-145 0.788 74
Anthracene 50.0 35.3 37.1 70.6 74.2 27.0-133 4.97 66
Benzidine 100 26.0 14.3 26.0 14.3 1.00-120 J3 58.1 36
Benzo(a)anthracene 50.0 41.6 41.5 83.2 83.0 33.0-143 0.241 53
Benzo(b)fluoranthene 50.0 36.8 36.8 73.6 73.6 24.0-159 0.000 71
Benzo(k)fluoranthene 50.0 37.2 36.5 74.4 73.0 11.0-162 1.90 63
Benzo(g,h,i)perylene 50.0 35.1 35.2 70.2 70.4 1.00-219 0.284 97
Benzo(a)pyrene 50.0 38.0 38.1 76.0 76.2 17.0-163 0.263 72
Bis(2-chlorethoxy)methane 50.0 31.5 31.4 63.0 62.8 1.00-219 0.318 54
Bis(2-chloroethyl)ether 50.0 34.6 32.5 69.2 65.0 33.0-185 6.26 108
2,2-oxybis(1-chloropropane) 50.0 31.2 30.5 62.4 61.0 36.0-166 2.27 76
4-Bromophenyl-phenylether 50.0 35.0 35.4 70.0 70.8 53.0-127 1.14 43
Page 40 of 60
I ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Pace Analytical-Asheville,NC 92564018 L1411440 10/07/21 21:01 11 of 19

r
WG1749985 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 625.1 L1411440-02
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS)R3713039-1 10/04/21 01:10•(LCSD)R3713039-2 10/04/21 01:32 Cp
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec.Limits LCS Qualifier LCSD Qualifier RPD RPD Limits 2
Analyte ugh ugh ug!I % % Ic
2-Chloronaphthalene 50.0 35.5 35.7 71.0 71.4 60.0-120 0.562 24
4-Chlorophenyl-phenylether 50.0 36.8 36.7 73.6 73.4 25.0-158 0.272 61 3
Ss
Chrysene 50.0 40.9 40.3 81.8 80.6 17.0-168 1.48 87
Dibenz(a,h)anthracene 50.0 33.4 33.6 66.8 67.2 1.00-227 0.597 126 4
3,3-Dichlorobenzidine 100 64.5 81.2 64.5 81.2 1.00-262 22.9 108 Cn
2,4-Dinitrotoluene 50.0 45.0 44.4 90.0 88.8 39.0-139 1.34 42
2,6-Dinitrotoluene 50.0 39.5 39.9 79.0 79.8 50.0-158 1.01 48 E.
Sr
Fluoranthene 50.0 39.3 38.2 78.6 76.4 26.0-137 2.84 66
Fluorene 50.0 37.2 37.1 74.4 74.2 59.0-121 0.269 38
Hexachlorobenzene 50.0 33.6 33.9 67.2 67.8 1.00-152 0.889 55 Qc
Hexachloro-1,3-butadiene 50.0 28.0 28.7 56.0 57.4 24.0-120 2.47 62
Hexachlorocyclopentadiene 50.0 27.3 27.1 54.6 54.2 10.0-120 0.735 31 'GI
Hexachloroethane 50.0 30.7 29.9 61.4 59.8 40.0-120 2.64 52
Indeno(1,2,3-cd)pyrene 50.0 36.5 35.7 73.0 71.4 1.00-171 2.22 99
Isophorone 50.0 32.0 32.2 64.0 64.4 21.0-196 0.623 93 Al
Naphthalene 50.0 28.5 28.8 57.0 57.6 21.0-133 1.05 65
Nitrobenzene 50.0 30.6 31.2 61.2 62.4 35.0-180 1.94 62 g
Sc
n-Nitrosodimethylamine 50.0 21.9 21.1 43.8 42.2 10.0-120 3.72 34
n-Nitrosodiphenylamine 50.0 31.1 36.6 62.2 73.2 44.0-120 16.2 21
n-Nitrosodi-n-propylamine 50.0 35.4 33.0 70.8 66.0 1.00-230 7.02 87
Phenanthrene 50.0 37.6 37.5 75.2 75.0 54.0-120 0.266 39
Benzylbutyl phthalate 50.0 41.0 39.9 82.0 79.8 1.00-152 2.72 60
Bis(2-ethylhexyl)phthalate 50.0 38.1 37.5 76.2 75.0 8.00-158 1.59 82
Di-n-butyl phthalate 50.0 40.9 39.7 81.8 79.4 1.00-120 2.98 47
Diethyl phthalate 50.0 39.5 39.0 79.0 78.0 1.00-120 1.27 100
Dimethyl phthalate 50.0 37.6 37.7 75.2 75.4 1.00-120 0.266 183
Di-n-octyl phthalate 50.0 41.0 40.0 82.0 80.0 4.00-146 2.47 69
Pyrene 50.0 38.5 39.8 77.0 79.6 52.0-120 3.32 49
1,2,4-Trichlorobenzene 50.0 28.5 28.8 57.0 57.6 44.0-142 1.05 50
1,2-Diphenylhydrazine 50.0 38.3 38.2 76.6 76.4 37.0-125 0.261 20
4-Chloro-3-methylphenol 50.0 28.6 29.8 57.2 59.6 22.0-147 4.11 73
2-Chlorophenol 50.0 28.6 27.3 57.2 54.6 23.0-134 4.65 61
2,4-Dichlorophenol 50.0 30.1 31.4 60.2 62.8 39.0-135 4.23 50
2,4-Dimethylphenol 50.0 24.0 28.6 48.0 57.2 32.0-120 17.5 58
4,6-Dinitro-2-methylphenol 50.0 52.7 52.9 105 106 1.00-181 0.379 203
2,4-Dinitrophenol 50.0 48.5 50.0 97.0 100 1.00-191 3.05 132
2-Nitrophenol 50.0 32.8 33.0 65.6 66.0 29.0-182 0.608 55
4-Nitrophenol 50.0 14.9 16.5 29.8 33.0 1.00-132 10.2 131
Pentachlorophenol 50.0 40.7 43.2 81.4 86.4 14.0-176 5.96 86
Phenol 50.0 12.7 12.4 25.4 24.8 5.00-120 2.39 64
Page 41 of 60
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Pace Analytical-Asheville,NC 92564018 L1411440 10/07/21 21:01 12 of 19

.�1 *V nft, IS& E. . <: 2
WG1749985 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 625.1 11411440-02
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS)R3713039-1 10/04/21 01:10•(LCSD)R3713039-2 10/04/21 01:32 Cp
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec.Limits LCS Qualifier LCSD Qualifier RPD RPD Limits 2
Analyte ug/I ug/I ug/I % % % % % Tc
2,4,6-Trichlorophenol 50.0 35.1 37.5 70.2 75.0 37.0-144 6.61 58
(S)Nitrobenzene-d5 572 57.8 15.0-314 3
SS
(S)2-Fluorobiphenyl 73.9 74.5 22.0-127
(S)p-Terphenyl-d14 69.3 71.3 29.0-141
4
(S)Phenol-d5 24.9 25.1 8.00-424 C n
(S)2-Fluorophenol 35.8 36.3 10.0-120
(S)2,4,6-Tribromophenol 68.5 75.5 10.0-153 5
Sr
Qc
7
GI
3
Al
9
SC
Page 42 of 60
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Pace Analytical-Asheville,NC 92564018 L1411440 10/07/21 21:01 13 of 19

GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not Cp
intended as a comprehensive explanation,and if you have additional questions please contact your project representative.
z
Results Disclaimer-Information that may be provided by the customer,and contained within this report,include Permit Limits,Project Name, Tc
Sample ID,Sample Matrix,Sample Preservation,Field Blanks,Field Spikes,Field Duplicates,On-Site Data,Sampling Collection Dates/Times,and
Sampling Location.Results relate to the accuracy of this Information provided,and as the samples are received.
3
Abbreviations and Definitions Ss
MDL Method Detection Limit.
4
RDL Reported Detection Limit. Cn
Rec. Recovery.
RPD Relative Percent Difference. 5
SDG Sample Delivery Group. Sr
Surrogate(Surrogate Standard)-Analyses added to every blank,sample,Laboratory Control Sample/Duplicate and
(S) Matrix Spike/Duplicate;used to evaluate analytical efficiency by measuring recovery.Surrogates are not expected to be r'QC
detected in all environmental media.
U Not detected at the Reporting Limit(or MDL where applicable).
Analyte The name of the particular compound or analysis performed.Some Analyses and Methods will have multiple analytes �,i
reported.
If the sample matrix contains an interfering material,the sample preparation volume or weight values differ from the
Dilution standard,or if concentrations of analytes in the sample are higher than the highest limit of concentration that the 3Al
laboratory can accurately report,the sample may be diluted for analysis.If a value different than 1 is used in this field,the
result reported has already been corrected for this factor.
These are the target%recovery ranges or%difference value that the laboratory has historically determined as normal 9
Limits for the method and analyte being reported.Successful QC Sample analysis will target all analytes recovered or SC
duplicated within these ranges.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier reported.If a Qualifier is present,a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
The actual analytical final result(corrected for any sample specific characteristics)reported for your sample.If there was
no measurable result returned for a specific analyte,the result in this column may state"ND"(Not Detected)or"BDL"
Result (Below Detectable Levels).The information in the results column should always be accompanied by either an MDL
(Method Detection Limit)or RDL(Reporting Detection Limit)that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty Confidence level of 2 sigma.
(Radiochemistry)
A brief discussion about the included sample results,including a discussion of any non-conformances to protocol
Case Narrative(Cn) observed either at sample receipt by the laboratory from the field or during the analytical process.If present,there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control This section of the report includes the results of the laboratory quality control analyses required by procedure or
Summary Control
analytical methods to assist in evaluating the validity of the results reported for your samples.These analyses are not
being performed on your samples typically,but on laboratory generated material.
This Is the document created in the field when your samples were initially collected.This is used to verify the time and
Sample Chain of date of collection,the person collecting the samples,and the analyses that the laboratory is requested to perform.This
Custody(Sc) chain of custody also documents all persons(excluding commercial shippers)that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
This section of your report will provide the results of all testing performed on your samples.These results are provided
Sample Results(Sr) by sample ID and are separated by the analyses performed on each sample.The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary(Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID,including the dates and
times of preparation and/or analysis.
Qualifier Description
J The identification of the analyte is acceptable;the reported value is an estimate.
J3 The associated batch QC was outside the established quality control range for precision.
Page 43 of 60
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Pace Analytical-Asheville,NC 92564018 L1411440 10/07/2121:01 14 of 19

ACCREDITATIONS & LOCATIONS
r' 1,: e. Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122 Cp
Alabama 40660 Nebraska NE-OS-15-05
Alaska 17-026 Nevada TN000032021-1 2
Arizona AZ0612 New Hampshire 2975 Tc
Arkansas 88-0469 New Jersey—NELAP TN002
California 2932 New Mexico' TN00003
.._ t
Colorado TN00003 New York 11742 SS
Connecticut PH-0197 North Carolina Env375
Florida E87487 North Carolina' DW21704 4
Georgia NELAP North Carolina' 41 Cn
Georgia' 923 North Dakota R-140
Idaho TN00003 Ohio—VAP CL0069 5
Illinois 200008 Oklahoma 9915 Sr
Indiana C-TN-01 Oregon TN200002
Iowa 364 Pennsylvania 68-02979 6
Kansas E-10277 Rhode Island LA000356 QC
Kentucky 1S KY90010 South Carolina 84004002
Kentucky' 16 South Dakota n/a 7
Louisiana A130792 Tennessee' 2006 GI
Louisiana LA018 Texas 1104704245-20-18
Maine TN00003 Texas' LAB0152 9,
Maryland 324 Utah TN000032021-11 Al
Massachusetts M-TN003 Vermont VT2006
Michigan 9958 Virginia 110033 9
_Minnesota 047-999-395 Washington C847 SC
Mississippi TN00003 West Virginia 233
Missouri 340 Wisconsin 998093910
Montana CERT0086 Wyoming A2LA
A2LA—ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789
A2LA—150 17025 5 1461.02 DOD 1461.01
Canada 1461.01 USDA P330-15-00234
EPA—Crypto TN00003
'Drinking Water 2 Underground Storage Tanks 3 Aquatic Toxicity °Chemical/Microbiological 5 Mold 'Wastewater n/a Accreditation not applicable
"Not all certifications held by the laboratory are applicable to the results reported In the attached report.
"Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
Page 44 of 60
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Pace Analytical-Asheville,NC 92564018 L1411440 10/07/21 21:01 15 of 19

1219
• Internal Transfer Chain of Custody
7)111:-_ ac
IEMUI113111M1___ 171 Samples Pre-Logged into eCOC State Of Origin: NC 2e Analytical
Cert. Needed: I j Yes
i i No vernopacelabsom
Workorder: 92564018 Workorder Name: Miviri5-PPA-912S ---------Ownor-ReceivextDate:. _9/29/2021 Results Requested By: 10/13/2021
Report To ----I Subcontract To Requested Analysis — —
,Lorri Patton Pace National 1 .
I Pace Analytical Asheville 12065 Lebanon Rd
2225 Riverside Dr. Mt.Juliet,TN 37122
i Asheville. NC 28804 Phone[phone]
I Phone [phone] ,
C N '
N, 4
T
Preserved Containers Z,
I I
i -
1 , I .
iSamphr 1CollQct. .
i,H11
Item Sample If) 'Type Date:Tiriu Lab ID Matn1 ;-:. LAB USE ONLY
•
1 WWTP EFF(PPA)Grab ,PS 9/28/2021 15:19 92564018001 Water 1 , X ...---at
2 VVYYTP EFF iPPA)Comb PS 9/29f2021 1049 92564018003 Water 01, X , .,...-C Z,
, 4 ----- ,
3 . :
4 .
I Comments -
Transfers Rele /ased By Date/Time Reced By ive Datenime -1 c9I-1-1 ‘ie)10Y if fLi W//ICY°)ei 0 u i
erif ached
?a-oz Ain,
...-A
;2
3
!Cooler Temperature on Receipt °C I Custody Seal j or N Received on Ice or N
-(-. -,-.
Samples Intact (11)or N i
***In order to maintain client confidentiality, location/name of the sampling site, sampler's name and signature may not be provided on this COC document.
This chain of custody is considered complete as is since this information is available in the owner laboratory'.
/9/, y igif
Saincls Ajaelpt CheciclIst
COC Seal Present/Intact:.."Y N If Applicable ei,./
COC StignediAccrurste: ,2( 11 VO. Zero Readspace: N:
Bottles arrive intact: iIir li Pres.Correct/Check: YN
Correct bottles used: ge N
Sufficient volume vent; _,X.IEN
PAD Screen <0.5 mA,'hr: it N
Wednesday.September 29,2021 4,0552 PM FMT-ALL-C-002rev.00 24March2009 Page I of 1
Page 45 of 60

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Item Acode Coif)List Crup Analyte CAS No, PLIL 10 IVIDL ID Units Fig
10 1631E W 1631E V% {,'.,,, Mercury :439-91,6 6 5 75523 0 25 87642ng/L.
1664 W92 1664 17V92 og Oil and Grease 5 9233 1 1 89753 mg/L E
2007 W 2007 W Sb Antimony 7440-36-0 5 9310 3 87692 ugil. E
As Arsenic 7440-38-2 10 9310 4 7 87692ugt. E
I Be Beryllium 7440-41-7 1 9310 0.7027 87692ug/L E
Cd Cadmium 7440-43-9 1 9310 0 4 87692 ugn. E
Ca Calcium 7440-70-2 100 9310 94 2279 87692ugil E
Cr Chromvam 7440-47-3 5 9310 1 8585 67692 ug/L E
Cu Copper 7440-50-8 5 9310 4 1551 87692 ug/L E
Pb Lead 7439-92.1 5 9310 4 5325 87692 tigil E
Mg Magnesium 7439-95-4 100 9310 67 8062 87692 ug/L E
Ni Nickel 7440-02-0 5 9310 3 467 87692ug/L E
Sc Selenium 7782-49,2 10 9310 4 7 87692ug/L E
i Ag Silver 7440-22-4 5 9310 2 5 617692u91 E
II Thallium 7440-28-0 10 9310 8.1465 87692ugl E
thrd Hardness,Total(SM 23400) 662 9310 131 87692 ug/L E
Zn Zinc 7440-66-6 10 9310 9 4505 87892 ug/l. E
2008 W 2008 W Cu Copper 7440-50-8 2 89820 1 1437 89819 ugl E
Ag Silver 7440-22,4 0.4 89820 0.07 89819 ug/t. E
2451 W9. 7470 VV Hg Mercury 7439-97-6 0 2 9328 0,1227 87644 tig/L E
2540C W 2540C W tdsw Total Dissolved Solids 25 87018 25 87019mg/L E
3501 W 3501 W NH3N Nitrogen,Ammonia 7664-41-7 0 1 9222 0,031 89907 rng/L e
3512 W2 3512 W2 tkn Nitmgen,Kjeldahl,Total 7727-37-9 0 5 9292 0 25 07674 mg/I. E
3532 WN 3532 VVN NaN Nitrogen,NO2 plus NO3 0 04 76746 0.0172 87702 mg/L E
3651 VV2 3651 W2 P Phosphorus 7723-14-0 0 05 55974 0.025 87858 mg/I. E
4204 W2 4204W2 phot Phenolics,Total Recoverable 64743-03-9 0,02 89895 0 0076 139094 mg/L E
4500C z 4500CNEVV2 CN Cyanide 57.12-5 0.008 73591 0,006 87678mg/L E
624 WA- 624 WAc acro Acrolein 107-02-0 5 77088 3.62 89912 ug/L E
acyl Acrytonitrile 107-13-1 5 77068 2.3 89912ug/L E
benz Benzene 71-49-2 1 7706.9 0,423 89912 u9/1.. E
brod Bromodichloromethane 75-27-4 2 77068 0 411 89912 ug/L E
brot Bromororm 75-25-2 2 77068 0,589 8991290. E
broe Broinomethano 74-83-9 2 77068 1.54 89912 ug/L e
cate Carbon tetrachlonde 58-23-5 2 77068 0 472 89912 ug/L E
chit) Chiorobenzene 108-90-7 2 77068 0.307 69912 ug/L E
choe Chtoroethane 75-00,1 2 77068 0 707 89912ug/L E
2cve 2-Chlor0e1hytvinyl ether 110-75-8 5 77068 0 941 89912 ugit. E
chot Chloroform 67-66-3 2 77068 0.49 89912ug/t. E
chom Chloromethane 74-87-3 2 77068 0 602 89912ug/L E
dibm Dibromochloromethane 124-48-1 2 77068 0 388 89612 ug/L E
12db 1,2-0tchlorobenzene 95-50-1 2 77068 0 329 89912ug/L E
13dc 1,3-Dichlorobenzene 541-73-1 2 77068 0.398 89912 ug/L E
14db 1,4-Dichlorobenzene 106-48-7 2 77068 0,312 89912ug/L E
lids 1.1-Dichloroethane 75-34-3 2 77060 0.474 89912 ug/L E
12de 1,2-Dichloroethane 107-06-2 2 77085 0.422 89912 ug/L E
ildd 1,1-Clichlonsathene 75-3.5-4 2 77068 0 415 89912ug/L E
c12d cls-1.2-Dichloroeihene 156-59-2 2 77068 0.484 8991299,1 E
Wednesday,September 29,2021 3:50:31 PM Page 1 of 3
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0
ace Analytical
Report of Analysis
Pace Analytical Services, LLC
2225 Riverside Drive
Asheville, NC 28804
Attention: Lorri Patton
Project Name: VVVVTP PPA 9/29
Project Number: 92564018
Lot Number:WJ30051
Date Completed:11/04/2021
2:,,,,,,,..:,_e)7}.7.____,_
11/04/2021 4:37 PM
Approved and released by:
Project Manager I: Blaire M. Gagne
1l .\Ij A A
ANSI N tonal Awed fal on Board
0. /r ACCRDITEO
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety,without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel: [phone] Fax: [phone] www.pacelabs.com
Page 49 of 60
Page I of 12

PACE ANALYTICAL SERVICES, LLC
SC DHEC No:32010001 NELAC No:E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Pace Analytical Services, LLC
Lot Number: WJ30051
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation:
Biological Tissue: All, Non-Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium,
Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, Fecal
Coliform SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011,
Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-dichloroethane) EPA 524.2, Solid
Chemical Material: TOC Walkley-Black.
If you have any questions regarding this report please contact the Pace Project Manager listed on the
cover page.
Pace Analytical Services,LLC(formerly Shealy Environmetal Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172(803)791-9700 Fax[phone] www.pacelabs.com
Page 50 of 60
Page 2 of 12

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Pace Analytical Services, LLC
Lot Number: WJ30051
Project Name: WWTP PPA 9/29
Project Number: 92564018
Sample Number Sample ID Matrix Date Sampled Date Received
001 WWTP EFF(PPA)Grab Aqueous 09/28/2021 1519 10/28/2021
002 WWTP EFF(PPA)Grab Blank Aqueous 09/28/2021 1519 10/28/2021
(2 samples)
Pace Analytical Services,LLC (formerly Shealy Environmental Services.Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www pacelabs.com
Page 51 of 60
Page 3 of 12

QC Summary
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) QC Data for Lot Number:WJ30051
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 55 of 60
Page 7 of 12

Mercury (CVAFS) - MB
Sample ID:WQ20744-001 Matrix: Aqueous
Batch:20744 Prep Method:
Analytical Method: 1631E Prep Date: 11/01/2021 0841
Parameter Result Q DiI LOQ Units Analysis Date
Mercury(CVAFS) ND 1 0.500 ng/L 11/02/2021 0438
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
*=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) QC Data for Lot Number:WJ30051
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 56 of 60
Page 8 of 12

Mercury (CVAFS) - LCS
Sample ID: WQ20744-002 Matrix: Aqueous
Batch:20744 Prep Method:
Analytical Method: 1631E Prep Date: 11/01/2021 0841
Spike
Amount Result %Rec
Parameter (ng/L) (ng/L) Q Dil % Rec Limit Analysis Date
Mercury(CVAFS) 5.00 5.11 1 102 75-125 11/02/2021 0449
= = =Recovery is out of criteria
Limit of Quantization ND Not detected at or above the LOQ N eco ery
P=The RPD between two GC columns exceeds 40%
•=RSD is out of critera +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) QC Data for Lot Number:WJ30051
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 57 of 60
Page 9 of 12
1

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 58 of 60
Page 10 of 12

g
m D
ili 2 l
- 2.
Internal Transfer Chain of Custody
__ ceAalAcal•
Sam '.ris Pre-Logged Into eCOC. State Ct Origin: NC ,.,hnal•u a►cd^
III li ll Iillll��� �I�!III�I 1� I I Cert. Needed: I I Yes Li No
51291N121 Results Requested By: 10/27/2021
� Workorder Name: Owner Received Date: q �'
n 92564018 V�1VYfP PPA 9r29 nna s <�. FS�a f :r:: r. a.="
Workorder
h .. c..- ,. y - n 4 r ^ ." .. `'.'! ",`..,�:,�:1�..�1d %�: iftequa=tazs. �i isc. � :`..�,x s.,
o p 1"Qt'Rrn2 jQ' •.� r'��;tFY^C?tF.a i�'tiC'Ni:t.�.r,,,� Yri:"c"_[!:SUticontr��,TCf.�' +i�.-ic <.,r x �4t`'..._ ...+: 4
3 .1
Lorri Patton Pax Analytical West Columba t
U'< 'Pace Analydnal Astcvit.c 108 Vantage Pont Drive iiii
° en2225 Riverside Dr. WcutColurrtie,SC 29172
i m Asheville,NC 243804 Pnoro(803)791-9700
m Phone 1(823)2b4 7178
,
13 Wkt(J13<0i �154t1p iI >
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Oo y t , ah 4' • .• �*NtIr.� .x: -..1 Vi z. P LAB USE ONLY
Mr.;imta►a-R.:"" . _ :1: G ':^: 0 <x .rfin. � s . �",.. 3 :,fly.,
m n n
(2X � r v,�Mp-�-t (c'fl4:,Crfln P� 9f25'207'1ti:lfi e25G901 PA�t Vu�ter S �— X ,
CD,-- 0 2 'eAffP EFF(PPA)Grab EUnic Ps 9N262021 16:19 9250401E002 lattaf 1 X _ '..1
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v _.aX.�:♦Y_.T:?.. .11..."4:`3'.LY.i'�:�}�; :.\. •.4'ti �:. `r;.Y 3s`r. w
3 Transfers Rsteseed By tiitr/Time /1ace1Ved By Datenme Ch
1 .17 --ranqw/1�;A.L. ,WC, Jo t:11 !7,s, m
Ti 2 �_
3 f=t'r iesC 042,17 119r qri r, I1yi/14 -c-v+t t172/ It '5 -,�Cooler Temperature on Recel ' -l C ) Custodyly Y or Received on Ice Y or I 1 I Samples Intact or N n
"'In order to rnainl eir?client conpdentiaLly,hxatiottfiarne Of the sampling site,sampler's name and signature may not be provided on this COC document
This chau,of cusiedy is considered complete as is since this infarriatron is available in the owner laboratory.
r
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m Tuesday,Octe.tier 26,2021 9:5'.:54 PM FMT-.l l•C 002rev_9u 24'Aatch2009 Pare 1 M. 1
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PACE ANALYTICAL SERVICES, LLC
Samples Receipt ChemWist(SRC)(ME0018C-15) Revised:9179/7071)
at:e toalytucaf Issuing Authority:Pace ENV-WCOL Page 1 of 1
Sample Receipt Checklist(SRC)
Client: Gaoler I• r eted by/date: ]RG2 1013Qr202 I Lot it: wrsuos t
1 Means of receipt: Pace Tlient UPS p Fed1,x Other.
rYes r No 1.Wean custody sears pre cmt on the cooler?
Yes U No I'9 2.If custody seals were •rest nt,were th intact and.mbrokcn?
v H Strip II): w1 Chlorine Strip I D: ?'A Tested by:NA _
riginal temperature upon receipt/Derived(Corrected)temperature upon receipt VSulid Snap-Cup Ill: NA
15.1 111.1 or NA /NA oC NA /NA v�. NA /NA oc
lethotk OTemperature Blank gjA2ainst Bottles IR Oun ID: 5 IR Gun Correction Factor: o _ °C
Method of coolart: D Wet Ice CI Ice Packs E Dry Ice Lrr l None
2 Yes []No ❑QNA 3. If temperature of any cooler exceeded 6.&rC,was Project Manager Notified?
PM was Notified by:phone l�a1-7niT7)faco-to-face(circle one),
�ID ■No L 4. Is the commercial courier's asking slip attached to this form?
,(Ip® �15. Were proper custody procedures(relinquished/received)followed?
n Yes ■No_6. Were sam•le Ills listed on the COI;?
MUM II No 7. Were sample ION!ivied on all sample containers?
A ■No 8. Was collection date&time listed on the COC? 1
✓ Yes ■No 9. Was collection date&time fisted on all sample containers?
o Ycs No 10. Did all container label information(ID,date,time)agree with the CX)C?
(0�[MEM I I,Were tests to be performed listed on the COC?
✓❑Yes ❑No 12.Did all samples arrive in the proper containers for each test and/or in good condition
(unbroken,lids on,etc.)?
t A Yes LJNo 13, Was adequate sample volume available? ,
• Yes !%Nu 14. Were all samples received within '4 the holding time or 4B hours,whichever comes first?
1111 Yes 12_1rNo 15. Were any samples cundtaincrs missing/excess(c:rcic ore)samples Not listed on COC?
❑Yes ❑No [�NA 16.Fur VOA and RSK•175 samples,wcrc bubbles present>••pca•size"(te er 6mm in diameter)
in any of the VOA vials?
■Yes LfNo ❑✓ NA 17.\Vere all DROlnuercls?nutricntsamples received eta pH of<2?
Marl II NoI51M21 18.Were all cyanide sane des received at a yH>12 and sulfide samples received at a II>9?
19.Were all applicable NI I50TE.'/cyani • p eno 1625.1160', (<0.Smg/L)samp cs ree o
0 Yes CI No QNA
residual chlorine?
0 Yes [DM; DNA 20.Were client:eanarksPrequests(i.e.requested dilutions,MS/?dSD designations,etc...)
correctly transcribed from the COC into the comment section in LIMS?
■Yes ii No 21.Was the•uote number listed on the container label?If s, tote 1l .
Sample Preservation (Must be completed for any samples)incorrectly preserved or with headspuec.)
Sample(s) n were received incorrectly preserved and were adjusted accordingly
in sample receiving with NA_, _mL o circle one:H7.SO4,HNO3,HCl,NaOH using SR It NA •
Time of preservation VA _ _ If more than one preservative:s needed,please note in the comments below.
Satnple(s) NA were received with bubbles>6 mm in diameter.
amples(s)N•^ ._ were r o.:ved with TRC>0.5 mg/L(If rr 19 is no)and were
adjusted accordingly in sample receiving with sodium lhiosulfate(Na2S2O1)with Shealy ID: N'
SR barcocle tahels applied by: ltt{i2 Date. 104u#1021
Comments:
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 60 of 60
Page 12 of 12

Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
Page 1 of 1
Laboratory Report
Mr. Alexander Lillie Report Date: 06/03/2022
City of Hendersonville VVVVfP Date Received: 05/03/2022
99 Balfour Road
Hendersonville, NC 28792
Project: NC0025534 WWTP 5/3
Pace Project No.:92602413
Reviewed by:
Lorri Patton
1(828)254-7176
[e-mail]
Page 1 of 10

Document Name: Document Revised:November 15,2021
/�� ( fCc41. Sample Condition Upon Receipt(SCUR) Page 1 of 2
/
1. � Document No.: Issuing Authority:
F-CAR.CS-033-Rev.08 Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville L' Eden[ Greenwood[ Huntersville � Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑
Sample Condition Client Name: Project q W V# 92602413
Upon Receipt
I1�„ fly w,�
Courier: ['Fed Ex ['UPSRtr:
LISPS ❑Client 111111111111111111 III
❑Commercial ace
92502413
Custody Seal Present? Dyes o Seals Intact? Dyes ,-JNo //�
Date/Initials Person Examining Content4r"'s > 7{.;/-)
Packing Material: ❑Bubble Wrap ❑Bubble Bags ,one ❑ Other Biological Tissue Frozen? f'
Thermometer - Dyes ❑No,-PJN/A
IR Gun ID . Wet [Niue ['None
'� o 1 f Type of Ice:
Co ction Factor:
Cooler Temp: — ) Acf Subtract('C) Q. I _ Temp should be above freezing to 6'C
❑Samples out of temp criteria.Samples on ice,cooling process
Cooler Temp Corrected("C); j. has begun
USDA Regulated Soil(j24/A,water sample)
Did samples originate in a quarantine zone within the United States.CA,NY,or SC(check maps)? Did samples originate from a foreign source(Internationally,
Dyes ❑No includ!ng Hawaii and Puerto Rico)?❑Yes ❑No
Comments/Discrepancy:
Chain of Custody Present? s ❑No ON/A 1.
Samples Arrived within Hold Time? ,,,24es Otto ON/A 2.
Short Hold Time Analysis(<72 hr.)? _29es ❑No ON/A 3.
Rush Turn Around Time Requested? Des [ago ON/A 4.
Sufficient Volume? es Elmo ❑N/A 5.
Correct Containers Used? rs ❑No ON/A 6.
•Pace Containers Used? j,:i,res Li No ON/A
Containers Intact? oyes Otto ❑N/A 7.
Dissolved analysts:Samples Field Filtered? Des ❑No E<A 8.
Sample Labels Match COC? /eves No OHM 9.
-Includes Date/Time/ID/Analysis Matrix: IA777
Heads pace in VOA Vials(>5-6mm)? ❑Yes ❑No N/A 10.
Trip Blank Present? Des Otto jaa%A 11.
Trip Blank Custody Seals present? LlYes No u/A
COMMENTS/SAMPLE DISCREPANCY Field Data Required? Des ONO
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time:
Project Manager SCURF Review: Date:
Project Manager SRF Review: Date: Page 2 of 10

1 �
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0
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ETT
CHAIN OF CUSTODYlllire X RECORDv.
PO Box 16414,Greenville,SC 29606-7414 t
(Page of
[phone], [phone] F2r(864)877 6938 II
Shipping Address:4 Craftsman Cl.Greer,SC 29650
W Ww.ETTCNvIRQNMt_NTAL,CCIM
Client: ®��
: C k i ""'^^kt a+\\ii Program Containers Preservative
F'acility: Parameters
1�z►,t��0t:11a 4J if�1� ,
State: N(„ NPDES r: [JC25 Whole Effluent Toxicity _
Acute Chronic Test Organisms Q
co
e.
v (Composite only) (Grab or Composite) 4 C p - U
o ? U - a Z
c I=H?SO4 r` y = c U
Sign,and Print below -5 is E 8 o =Het. = .^ <
the dotted line c U yHND3 = 5) - ' x = -= _ a a = 2 •2
SAMPLE ID it �; o 'c c a-Na0H - - ei c u . " z- ? i-
Composite SG�n Date Time Snmple Collection bole Time °' C' O U 5=zn4e o o -- ) — - 3 � y : i-
7Coloolllleectteedd by U En to ;C �a E 5 'e
i_' lr_, , G=Da e < v C3 U O i n U r 5 c Chemical Analysis K Other
tY�)
S
Ct`� C 5 2 27 �1a '-3 2. Loa ' MZ}
I `� X �i,�.(:v=4113 -cam
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1 1 Special Instructions: —'-
woNe
Sample Custody Transfer Record -- —
Secure Receipt Sample
Date Time J �
R/elliinquished Organization 2L
�j j '-C 12I !art L (�. k W y,/'r ` Received By/Organization \ Area Tent °C Preserved^
-) N 'i 6- a 5 � 15-1$
COMPOSITE SAMPLING PROCEDURES TEMPERATURE MONITORING PROCEDURES
Composite samples must be collected over a 24 hourperiod. Sample temperature duringHOLD TIME PROCEDURES
P p collection and transport must be between For toxicity testing the sample must first be used within 36 hours
Time Proportional: 1 sample each hour for 24 hours.Equal volur 0.0 and 6.0°C.Samples must not be frozen.Use water ice in sealed bags.
of sample collection(completion of composite sample),
or at minimum I sample event 4 hours over 24 hours.
Sample may not be used after 72 hours from sample collection.
Flow Proportional:As per instructions in NPDES permit.

U. (E64)877-6942 .rxx(864)077.6936
P.O. Box 1E414,Creenvlle,6C 29606 4 Craftsman Court,Greer,SC 29650
Ceriodaphnia dubia Survival and Reproduction Test
EPA-821-R-02-013 Method 1002
Client: CITY OF HENDERSONVILLE
Facility:WWTP
NPDES#:NC0025534
Test Date: 04-May-22
Laboratory ID#: T61849
Test Reviewed and Approved By:
Robert W.Kelley,Ph.D. Patrick D.Timms
President QA/QC Officer
Certification#E87819 SCDHEC Certification#23104
Test results presented in this report conform to all requirements of
NELAC,conducted under NELAC Certification Number E87819
NCDENR Certification# 022 Page 5 of 10
Florida Dept.of Health.Included results pertain only to provided sam les.
I-'age 1 of 6

Effluent Toxicity Report Form-Chronic Pass/Fall and Acute LC50 Date 17-May-22
Facility: Hendersonville WWTP NPDES#NC0025534 Pipe# 001 County: Henderson
Laboratory Performing Test: ETT Environmental.Inc. Comments
X
Signature of Operator in Responsible Charge
Signature of Laboratory Supervisor
MAIL ORIGINAL TO Environmental Sciences Branch
Div.of Water Quality
N.C.DENR
1621 Mail Service Center
Raleigh,North Carolina 27699-1621
North Carolina Ceriodaohnia Chronic Pass/Fall Reproduction Toxicity Test Chronic Test Results
Rank sum= 131
Critical Value= 109
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 %Reduction= 4.2%
#Young Produced 23 23 21 22 21 22 21 23 22 22 22 23 %Mortality Avg.Reprod.
Adult (L)ive (D)ead L L L L L L L L L L L L 0% 22.1
Control Control
Effluent% 18.0% 0% 21.2
Treatment 2 Treatment 2
Control CV
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 3.6%
#Young Produced 23 20 20 21 21 22 22 15 23 24 21 22 %3rd Brood PASS FAIL
Adult (L)ive (D)ead L L L L L L L L L L L L 100% I X I
Complete This for Either Test Test Start Date
Collection(Startl Date 04-May-22
pH 1st sample 1st sample 2nd sample Sample 1 02-May-22 Sample 2 04-May-22
Control 7.8 8.0 7.8 8.1 7.7 8.0 Sample Type()uratiof
Treatment 2 7.8 8.2 7.9 8.2 7.8 8.1 Grab 1 Comp Duration 1st 2nd
Sample 1 X 24hrs. Tox Tox
Sample 2 X 24hrs. Dilution Sample Sample
start end start end start end
D.O. 1st sample 1st sample 2nd sample Hardness(mg/L)
Control 8.0 7.7 7.6 8.8 8.5 7.8 Spec.Cond.(pmhos) 307 297 287
Treatment 2 7.7 7.7 7.5 9.0 8.6 7.8 Chlorine(mg/L) a M <.05 <.05
Sample Temp.at receipt(°C) 1.6 3.0
LC50/Acute Toxicity Test
(Mortality expressed as%,combining replicates)
Concentration
Mortality start/end start/end
LC50= % Method of Determination Control
i
95%Confidence Limits Moving Average Probit IIII High Conc.
% Spearman Kerber Other pH D.O.
Organism Tested Ceriodaphnia dubia I
DEM Form AT-1 Page 6 of 10
Page 2 of 6

STATISTICAL ANALYSIS RESULTS
Facility: Hendersonville NPDES# NC0025534
Sample ID: WWTP Errs T61849 Date: 04-May-22
Laboratory: FIT 1 Fm irnnmrntal,inc. Certification#:NCO22 Exp.Date: 11/1/2022
Survival Data
7 Day Survival Test Used: FISHERS TEST
Control 100% Test Statistic: P= 1.000
Effluent 100% Critical Value: P= 0.01
PASS: The effluent does not reduce survival of the test organisms.
Reproduction Data
Raw Data Test for Normality
Mean young/female Std.Dev. Test Used: Shapiro-Walks Test:
Control 22.1 0.79
Effluent 21.2 2.29 W: 0.802
Critical Value: 0.884
Analysis for Differences in Reproduction Test for Homogeneity of Variance
Test Used: Wilcoxon Test Test Used: F Test
Rank sum= 131.00 F= 8.34
Critical Value= 109.00 Critical Value= 5.32
The data are not homogeneous in variance.
PASS:The effluent is not chronically toxic.
Page 7 of 10
Page 3 of 6

Pace Analytical Services,LLC
aceAnalytical//
2225 Riverside Dr.
Asheville,NC 28804
www.pacetabs.com [phone]
1
November 09, 2021
Mr. Alexander Lillie
City of Hendersonville WWTP
99 Balfour Road
Hendersonville, NC 28792
RE: Project: VVV TP PPA 9/29
Pace Project No.: 92564018
Dear Mr. Lillie:
Enclosed are the analytical results for sample(s) received by the laboratory on September 29, 2021. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace National- Mt. Juliet
• Pace Analytical Services-Asheville
•Pace Analytical Services-Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
.1"d REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services,LLC. Page 1 of 60
01. ./

Pace Analytical Services,LLC
a
aceAnaiyticai 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com
[phone]
CERTIFICATIONS
Project WWTP PPA 9/29
Pace Project No.: 92564018
Pace Analytical Services National
12065 Lebanon Road,Mt.Juliet,TN 37122 Nevada Certification#:TN-03-2002-34
Alabama Certification#:40660 New Hampshire Certification#: 2975
Alaska Certification 17-026 New Jersey Certification#:TN002
Arizona Certification#:AZ0612 New Mexico DW Certification
Arkansas Certification#:88-0469 New York Certification#: 11742
California Certification#:2932 North Carolina Aquatic Toxicity Certification#:41
Canada Certification#: 1461.01 North Carolina Drinking Water Certification#:21704
Colorado Certification#:TN00003 North Carolina Environmental Certificate#:375
Connecticut Certification#:PH-0197 North Dakota Certification#:R-140
DOD Certification:#1461.01 Ohio VAP Certification#:CL0069
EPA#TN00003 Oklahoma Certification#:9915
Florida Certification#:E87487 Oregon Certification#:TN200002
Georgia DW Certification#:923 Pennsylvania Certification#:68-02979
Georgia Certification:NELAP Rhode Island Certification#:LA000356
Idaho Certification#:TN00003 South Carolina Certification#:84004
Illinois Certification#: 200008 South Dakota Certification
Indiana Certification#:C-TN-01 Tennessee DW/Chem/Micro Certification#: 2006
Iowa Certification#:364 Texas Certification#:T 104704245-17-14
Kansas Certification#:E-10277 Texas Mold Certification#: LAB0152
Kentucky UST Certification#: 16 USDA Soil Permit#: P330-15-00234
Kentucky Certification#:90010 Utah Certification#:TN00003
Louisiana Certification#:A130792 Vermont Dept.of Health: ID#VT-2006
Louisiana DW Certification#: LA180010 Virginia Certification#:VT2006
Maine Certification#:TN0002 Virginia Certification#:460132
Maryland Certification#:324 Washington Certification#:C847
Massachusetts Certification#:M-TN003 West Virginia Certification#:233
Michigan Certification#:9958 Wisconsin Certification#:998093910
Minnesota Certification#: 047-999-395 Wyoming UST Certification#:via A2LA 2926.01
Mississippi Certification#:TN00003 A2LA-ISO 17025 Certification#: 1461.01
Missouri Certification#:340 A2LA-ISO 17025 Certification#: 1461.02
Montana Certification#:CERT0086 AIHA-LAP/LLC EMLAP Certification#:100789
Nebraska Certification#:NE-OS-15-05
Pace Analytical Services Charlotte
9800 Kincey Ave.Ste 100, Huntersville,NC 28078 South Carolina Certification#:99006001
Louisiana/NELAP Certification#LA170028 Florida/NELAP Certification#: E87627
North Carolina Drinking Water Certification#:37706 Kentucky UST Certification#:84
North Carolina Field Services Certification#:5342 VirginiaNELAP Certification#:460221
North Carolina Wastewater Certification#: 12
Pace Analytical Services Asheville
2225 Riverside Drive,Asheville,NC 28804 North Carolina Wastewater Certification#:40
Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001
North Carolina Drinking Water Certification#:37712 VirginiaNELAP Certification#:460222
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
(/4?
Je nalyt cal 2225 Riverside Or.
G H l.i Asheville,NC 28804
www.pacelabs.com
[phone]
SAMPLE ANALYTE COUNT
Project: WWTP PPA 9/29
Pace Project No.: 92564018
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92564018001 WWTP EFF(PPA)Grab EPA 1664B TEG 1 PASI-C
EPA 624.1 JHH 35 PAN
EPA 420.4 Rev 1.0 1993 NGP 1 PASI-A
SM 4500-CN-E-2011 DMN 1 PASI-A
92564018003 WWTP EFF(PPA)Comp EPA 200.7 Rev 4.4 1994 DS 13 PASI-A
EPA 200.8 Rev 5.4 JOR 2 PASI-A
EPA 245.1 Rev 3.0 1994 DBB1 1 PASI-A
EPA 625.1 AMG 60 PAN
SM 2540C-2011 ZMC 1 PASI-A
EPA 350.1 Rev 2.0 1993 KDF1 1 PASI-A
EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 353.2 Rev 2.0 1993 KDF1 1 PASI-A
EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A
PAN=Pace National-Mt.Juliet
PASI-A=Pace Analytical Services-Asheville
PASI-C=Pace Analytical Services-Charlotte
REPORT OF LABORATORY ANALYSIS
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aceAnaiytical Pace Analytical Services,LLC
e
2225 Riverside Dr.
Asheville,NC 28804
ww.pecNahs.cae [phone]
ANALYTICAL RESULTS
Project: WWTP PPA 9/29
Pace Project No.: 92564018
Sample: WWTP EFF(PPA)Grab Lab ID: 92564018001 Collected: 09/28/21 15:19 Received: 09/29/21 13:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM,Oil and Grease Analytical Method:EPA 1664B
Pace Analytical Services-Charlotte
Oil and Grease ND mg/L 4.9 1 10/13/21 10:26
VOA(GC/MS)624.1 Analytical Method:EPA 624.1 Preparation Method:624.1
Pace National-Mt.Juliet
Acrolein ND ug/L 50.0 1 10/01/21 12:56 10/01/21 12:56 107-02-8
Acrylonitrile ND ug/L 10.0 1 10/01/21 12:56 10/01/21 12:56 107-13-1
Benzene ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 71-43-2
Bromodichloromethane ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 75-27-4
Bromoform ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 75-25-2
Bromomethane ND ug/L 5.00 1 10/01/21 12:56 10/01/21 12:56 74-83-9
Carbon tetrachloride ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 56-23-5
Chlorobenzene ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 108-90-7
Dibromochloromethane ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 124-48-1
Chloroethane ND ug/L 5.00 1 10/01/21 12:56 10/01/21 12:56 75-00-3
2-Chloroethylvinyl ether ND ug/L 50.0 1 10/01/21 12:56 10/01/21 12:56 110-75-8
Chloroform ND ug/L 5.00 1 10/01/21 12:56 10/01/21 12:56 67-66-3
Chloromethane ND ug/L 2.50 1 10/01/21 12:56 10/01/21 12:56 74-87-3
1,2-Dichlorobenzene ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 95-50-1
1,3-Dichlorobenzene ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 541-73-1
1,4-Dichlorobenzene ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 106-46-7
1,1-Dichloroethane ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 75-34-3
1,2-Dichloroethane ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 107-06-2
1,1-Dichloroethene ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 75-35-4
trans-1,2-Dichloroethene ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 156-60-5
1,2-Dichloropropane ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 78-87-5
cis-1,3-Dichloropropene ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 10061-01-5
trans-1,3-Dichloropropene ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 10061-02-6
Ethylbenzene ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 100-41-4
Methylene Chloride ND ug/L 5.00 1 10/01/21 12:56 10/01/21 12:56 75-09-2
1,1,2,2-Tetrachloroethane ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 79-34-5
Tetrachloroethene ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 127-18-4
Toluene ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 108-88-3
1,1,1-Trichloroethane ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 71-55-6
1,1,2-Trichloroethane ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 79-00-5
Trichloroethene ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 79-01-6
Vinyl chloride ND ug/L 1.00 1 10/01/21 12:56 10/01/21 12:56 75-01-4
Surrogates
Toluene-d8(S) 106 % 80.0-120 1 10/01/21 12:56 10/01/21 12:56 2037-26-5
4-Bromofluorobenzene(S) 95.1 % 80.0-120 1 10/01/21 12:56 10/01/21 12:56 460-00-4
1,2-Dichloroethane-d4(S) 93.8 % 70.0-130 1 10/01/21 12:56 10/01/21 12:56 17060-07-0
420.4 Phenolics,Total Analytical Method:EPA 420.4 Rev 1.0 1993 Preparation Method:EPA 420.4 Rev 1.0 1993
Pace Analytical Services-Asheville
Phenolics,Total Recoverable ND mg/L 0.020 1 10/04/21 02:28 10/04/21 05:21 64743-03-9
REPORT OF LABORATORY ANALYSIS
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Date: 11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 4 of 60
I

Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Asheville,NC 28804
(//1
www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project: 1M/VfP PPA 9/29
Pace Project No.: 92564018
Sample: WWTP EFF(PPA)Grab Lab ID: 92564018001 Collected: 09/28/21 15:19 Received: 09/29/21 13:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
4500CNE Cyanide,Total Analytical Method:SM 4500-CN-E-2011 Preparation Method:SM 4500-CN-E-2011
Pace Analytical Services-Asheville
Cyanide ND mg/L 0.0080 1 10/07/21 14:23 10/07/21 17:31 57-12-5
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project: WWTP PPA 9/29
Pace Project No.: 92564018
Sample: WWTP EFF(PPA)Comp Lab ID: 92564018003 Collected: 09/29/21 10:49 Received: 09/29/21 13:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.7 MET ICP Analytical Method:EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services-Asheville
Antimony ND ug/L 5.0 1 09/30/21 14:12 10/02/21 02:50 7440-36-0
Arsenic ND ug/L 10.0 1 09/30/21 14:12 10/02/21 02:50 7440-38-2
Beryllium ND ug/L 1.0 1 09/30/21 14:12 10/02/21 02:50 7440-41-7
Cadmium ND ug/L 1.0 1 09/30/21 14:12 10/02/21 02:50 7440-43-9
Calcium 8480 ug/L 100 1 09/30/21 14:12 10/02/21 02:50 7440-70-2
Chromium ND ug/L 5.0 1 09/30/21 14:12 10/02/21 02:50 7440-47-3
Lead ND ug/L 5.0 1 09/30/21 14:12 10/02/21 02:50 7439-92-1
Magnesium 2430 ug/L 100 1 09/30/21 14:12 10/02/21 02:50 7439-95-4
Nickel 10.2 ug/L 5.0 1 09/30/21 14:12 10/02/21 02:50 7440-02-0
Selenium ND ug/L 10.0 1 09/30/21 14:12 10/02/21 02:50 7782-49-2
Thallium ND ug/L 10.0 1 09/30/21 14:12 10/02/21 02:50 7440-28-0
Hardness,Total(SM 2340B) 31200 ug/L 662 1 09/30/21 14:12 10/02/21 02:50
Zinc 51.9 ug/L 10.0 1 09/30/21 14:12 10/02/21 02:50 7440-66-6
200.8 MET ICPMS Analytical Method: EPA 200.8 Rev 5.4 Preparation Method:EPA 200.8 Rev 5.4
Pace Analytical Services-Asheville
Copper 11.7 ug/L 2.0 1 09/30/21 13:22 10/01/21 00:10 7440-50-8
Silver ND ug/L 0.40 1 09/30/21 13:22 10/01/21 00:10 7440-22-4
245.1 Mercury Analytical Method:EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994
Pace Analytical Services-Asheville
Mercury ND ug/L 0.20 1 10/06/21 11:30 10/07/21 13:30 7439-97-6 M1
SVOA (GC/MS)625.1 Analytical Method:EPA 625.1 Preparation Method:3510C
Pace National-Mt.Juliet
Acenaphthene ND ug/L 1.00 1 10/03/21 17:28 10/05/21 03:08 83-32-9
Acenaphthylene ND ug/L 1.00 1 10/03/21 17:28 10/05/21 03:08 208-96-8
Anthracene ND ug/L 1.00 1 10/03/21 17:28 10/05/21 03:08 120-12-7
Benzidine ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 92-87-5 R1
Benzo(a)anthracene ND ug/L 1.00 1 10/03/21 17:28 10/05/21 03:08 56-55-3
Benzo(b)fluoranthene ND ug/L 1.00 1 10/03/21 17:28 10/05/21 03:08 205-99-2
Benzo(k)fluoranthene ND ug/L 1.00 1 10/03/21 17:28 10/05/21 03:08 207-08-9
Benzo(g,h,i)perylene ND ug/L 1.00 1 10/03/21 17:28 10/05/21 03:08 191-24-2
Benzo(a)pyrene ND ug/L 1.00 1 10/03/21 17:28 10/05/21 03:08 50-32-8
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 111-91-1
bis(2-Chloroethyl)ether ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 111-44-4
2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 108-60-1
4-Bromophenylphenyl ether ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 101-55-3
2-Chloronaphthalene ND ug/L 1.00 1 10/03/21 17:28 10/05/21 03:08 91-58-7
4-Chlorophenylphenyl ether ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 7005-72-3
Chrysene ND ug/L 1.00 1 10/03/21 17:28 10/05/21 03:08 218-01-9
Dibenz(a,h)anthracene ND ug/L 1.00 1 10/03/21 17:28 10/05/21 03:08 53-70-3
3,3'-Dichlorobenzidine ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 91-94-1
2,4-Dinitrotoluene ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 121-14-2
2,6-Dinitrotoluene ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 606-20-2
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
aceAnalytical® Asheville,
Riverside Dr.
Asheville,NC 28804
www.Peedebs.eon [phone]
ANALYTICAL RESULTS
Project: WWTP PPA 9/29
Pace Project No.: 92564018
Sample: WWTP EFF(PPA)Comp Lab ID: 92564018003 Collected: 09/29/21 10:49 Received: 09/29/21 13:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
SVOA (GC/MS)625.1 Analytical Method:EPA 625.1 Preparation Method:3510C
Pace National-Mt.Juliet
1,2-Diphenylhydrazine ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 122-66-7
Fluoranthene ND ug/L 1.00 1 10/03/21 17:28 10/05/21 03:08 206-44-0
Fluorene ND ug/L 1.00 1 10/03/21 17:28 10/05/21 03:08 86-73-7
Hexachlorobenzene ND ug/L 1.00 1 10/03/21 17:28 10/05/21 03:08 118-74-1
Hexachloro-1,3-butadiene ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 87-68-3
Hexachlorocyclopentadiene ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 77-47-4
Hexachloroethane ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 1.00 1 10/03/21 17:28 10/05/21 03:08 193-39-5
Isophorone ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 78-59-1
Naphthalene ND ug/L 1.00 1 10/03/21 17:28 10/05/21 03:08 91-20-3
Nitrobenzene ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 98-95-3
N-Nitrosodimethylamine ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 62-75-9
N-Nitrosodiphenylamine ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 86-30-6
N-Nitroso-di-n-propylamine ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 621-64-7
Phenanthrene ND ug/L 1.00 1 10/03/21 17:28 10/05/21 03:08 85-01-8
Butylbenzylphthalate ND ug/L 3.00 1 10/03/21 17:28 10/05/21 03:08 85-68-7
bis(2-Ethylhexyl)phthalate ND ug/L 3.00 1 10/03/21 17:28 10/05/21 03:08 117-81-7
Di-n-butylphthalate ND ug/L 3.00 1 10/03/21 17:28 10/05/21 03:08 84-74-2
Diethylphthalate ND ug/L 3.00 1 10/03/21 17:28 10/05/21 03:08 84-66-2
Dimethylphthalate ND ug/L 3.00 1 10/03/21 17:28 10/05/21 03:08 131-11-3
Di-n-octylphthalate ND ug/L 3.00 1 10/03/21 17:28 10/05/21 03:08 117-84-0
Pyrene ND ug/L 1.00 1 10/03/21 17:28 10/05/21 03:08 129-00-0
1,2,4-Trichlorobenzene ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 120-82-1
4-Chloro-3-methylphenol ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 59-50-7
2-Chlorophenol ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 95-57-8
2,4-Dichlorophenol ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 120-83-2
2,4-Dimethylphenol ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 105-67-9
4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 534-52-1
2,4-Dinitrophenol ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 51-28-5
2-Nitrophenol ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 88-75-5
4-Nitrophenol ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 100-02-7
Pentachlorophenol ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 87-86-5
Phenol ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 108-95-2
2,4,6-Trichlorophenol ND ug/L 10.0 1 10/03/21 17:28 10/05/21 03:08 88-06-2
Surrogates
Nitrobenzene-d5(S) 60.2 % 15.0-314 1 10/03/21 17:28 10/05/21 03:08 4165-60-0
2-Fluorobiphenyl(S) 59.8 % 22.0-127 1 10/03/21 17:28 10/05/21 03:08 321-60-8
Terphenyl-d14(S) 60.4 % 29.0-141 1 10/03/21 17:28 10/05/21 03:08 1718-51-0
Phenol-d5(S) 14.3 % 8.00-424 1 10/03/21 17:28 10/05/21 03:08 4165-62-2
2-Fluorophenol(S) 25.1 % 10.0-120 1 10/03/21 17:28 10/05/21 03:08 367-12-4
2,4,6-Tribromophenol(S) 58.9 % 10.0-153 1 10/03/21 17:28 10/05/21 03:08 118-79-6
2540C Total Dissolved Solids Analytical Method:SM 2540C-2011
Pace Analytical Services-Asheville
Total Dissolved Solids 206 mg/L 25.0 1 10/01/21 17:47
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 7 of 60

Pace Analytical Services,LLC
7/1aceAnalytical Asheville,
Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
i
ANALYTICAL RESULTS
Project: WWTP PPA 9/29
Pace Project No.: 92564018
Sample: WWTP EFF(PPA)Comp Lab ID: 92564018003 Collected: 09/29/21 10:49 Received: 09/29/21 13:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method:EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia ND mg/L 0.10 1 10/13/21 16:21 7664-41-7
351.2 Total Kjeldahl Nitrogen Analytical Method:EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Kjeldahl,Total 1.2 mg/L 0.50 1 10/08/21 16:56 10/09/21 06:00 7727-37-9
353.2 Nitrogen, NO2/NO3 pres. Analytical Method:EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,NO2 plus NO3 6.0 mg/L 0.12 3 10/13/21 10:26
365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus 3.0 mg/L 0.050 1 10/07/21 21:13 10/08/21 20:50 7723-14-0
REPORT OF LABORATORY ANALYSIS
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Date: 11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 8 of 60

Pace Analytical Services,LLC
aceAnalytical a Riverside Dr.
Asheville,NC 28804
wintpacelalis.cont [phone]
QUALITY CONTROL DATA
Project: WWTP PPA 9/29
Pace Project No.: 92564018
QC Batch: 652414 Analysis Method: EPA 1664E
QC Batch Method: EPA 1664B Analysis Description: 1664 HEM,Oil and Grease
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92564018001
METHOD BLANK: 3421015 Matrix: Water
Associated Lab Samples: 92564018001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 5.0 10/13/21 10:26
LABORATORY CONTROL SAMPLE: 3421016
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L 40 40.9 102 78-114
MATRIX SPIKE SAMPLE: 3421017
92565536002 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L ND 38.8 30.5 77 78-114 M1
SAMPLE DUPLICATE: 3421018
92565880002 Dup
Parameter Units Result Result RPD Qualifiers
Oil and Grease mg/L ND 4.4J
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 60

Pace Analytical Services,LLC
® 2225 Riverside Dr.
aceAnalytical Asheville,NC 28804
www.pacstabscale [phone]
QUALITY CONTROL DATA
Project: WWTP PPA 9/29
Pace Project No.: 92564018
QC Batch: 650850 Analysis Method: EPA 245.1 Rev 3.0 1994
QC Batch Method: EPA 245.1 Rev 3.0 1994 Analysis Description: 245.1 Mercury
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92564018003
METHOD BLANK: 3413092 Matrix: Water
Associated Lab Samples: 92564018003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ug/L ND 0.20 10/07/21 13:16
LABORATORY CONTROL SAMPLE: 3413093
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Mercury ug/L 2.5 2.3 93 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3413094 3413095
MS MSD
92564018003 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Mercury ug/L ND 2.5 2.5 ND ND 0 -1 70-130 M1
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 60

aceAnalytical
Pace Analytical Services,LLC
2225 Riverside Dr.
Asheville,NC 28804
www.pacelaDs.com [phone]
QUALITY CONTROL DATA
Project: WWTP PPA 9/29
Pace Project No.: 92564018
QC Batch: 650171 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92564018003
METHOD BLANK: 3409990 Matrix: Water
Associated Lab Samples: 92564018003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Antimony ug/L ND 5.0 10/04/21 10:47
Arsenic ug/L ND 10.0 10/04/21 10:47
Beryllium ug/L ND 1.0 10/04/21 10:47
Cadmium ug/L ND 1.0 10/04/21 10:47
Calcium ug/L ND 100 10/04/21 10:47
Chromium ug/L ND 5.0 10/04/21 10:47
Hardness,Total(SM 2340B) ug/L ND 662 10/04/21 10:47
Lead ug/L ND 5.0 10/04/21 10:47
Magnesium ug/L ND 100 10/04/21 10:47
Nickel ug/L ND 5.0 10/04/21 10:47
Selenium ug/L ND 10.0 10/04/21 10:47
Thallium ug/L ND 10.0 10/04/21 10:47
Zinc ug/L ND 10.0 10/04/21 10:47
LABORATORY CONTROL SAMPLE: 3409991
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Antimony ug/L 500 495 99 85-115
Arsenic ug/L 500 482 96 85-115
Beryllium ug/L 500 498 100 85-115
Cadmium ug/L 500 504 101 85-115
Calcium ug/L 5000 4930 99 85-115
Chromium ug/L 500 495 99 85-115
Hardness,Total(SM 2340B) ug/L 33100 32400 98 85-115
Lead ug/L 500 498 100 85-115 '
Magnesium ug/L 5000 4870 97 85-115
Nickel ug/L 500 493 99 85-115
Selenium ug/L 500 476 95 85-115
Thallium ug/L 500 482 96 85-115
Zinc ug/L 500 491 98 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3409992 3409993
MS MSD
92563479001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Antimony ug/L ND 500 500 535 527 107 105 70-130 1
Arsenic ug/L ND 500 500 536 527 107 105 70-130 2
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 11 of 60

Pace Analytical Services,LLC
As
heville,2225 Riverside Dr.
NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: WWTP PPA 9/29 !
Pace Project No.: 92564018
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3409992 3409993
MS MSD
92563479001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Beryllium ug/L ND 500 500 523 518 105 104 70-130 1
Cadmium ug/L ND 500 500 518 511 104 102 70-130 1
Calcium ug/L 25600 5000 5000 33300 32500 155 138 70-130 3
Chromium ug/L ND 500 500 513 506 102 101 70-130 1
Hardness,Total(SM 2340B) ug/L 86700 33100 33100 130000 127000 132 123 70-130 2
Lead ug/L ND 500 500 514 506 103 101 70-130 2
Magnesium ug/L 5540 5000 5000 11400 11200 118 114 70-130 2
Nickel ug/L ND 500 500 494 486 99 97 70-130 1 ,
Selenium ug/L ND 500 500 548 540 110 108 70-130 1
Thallium ug/L ND 500 500 520 514 104 103 70-130 1
Zinc ug/L 53.2 500 500 587 570 107 103 70-130 3
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3409994 3409995
MS MSD
92564081001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Antimony ug/L ND 500 500 521 520 104 104 70-130 0
Arsenic ug/L ND 500 500 534 529 106 105 70-130 1
Beryllium ug/L ND 500 500 508 509 102 102 70-130 0
Cadmium ug/L ND 500 500 507 507 101 101 70-130 0
Calcium ug/L 1570 5000 5000 6360 6390 96 96 70-130 1
Chromium ug/L 31.8 500 500 520 522 98 98 70-130 0
Hardness,Total(SM 2340B) ug/L 4260 33100 33100 37600 37700 101 101 70-130 0
Lead ug/L ND 500 500 501 500 100 100 70-130 0
Magnesium ug/L ND 5000 5000 5270 5280 104 104 70-130 0
Nickel ug/L 10.7 500 500 506 507 99 99 70-130 0
Selenium ug/L ND 500 500 536 538 107 108 70-130 0
Thallium ug/L ND 500 500 494 494 99 99 70-130 0
Zinc ug/L 0.12 500 500 636 637 103 103 70-130 0
mg/L
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 12 of 60

Pace Analytical Services,LLC
2225 Riverside Dr.
aceAnalytical Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: WWTP PPA 9/29
Pace Project No.: 92564018
QC Batch: 650123 Analysis Method: EPA 200.8 Rev 5.4
QC Batch Method: EPA 200.8 Rev 5.4 Analysis Description: 200.8 MET
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92564018003
METHOD BLANK: 3409711 Matrix: Water
Associated Lab Samples: 92564018003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Copper ug/L ND 2.0 09/30/21 23:38
Silver ug/L ND 0.40 09/30/21 23:38
LABORATORY CONTROL SAMPLE: 3409712
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Copper ug/L 50 50.2 100 85-115
Silver ug/L 25 25.6 102 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3409713 3409714
MS MSD
92563460001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Copper ug/L 113 50 50 122 167 18 107 70-130 31 M1,R1
Silver ug/L ND 25 25 ND 25.1 0 100 70-130 M1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 13 of 60

Pace Analytical Services,LLC
s 2225 Riverside Dr.
(/. aceAnalytical Asheville,NC 28804
www.pacelabs.com
[phone]
QUALITY CONTROL DATA
Project: WWTP PPA 9/29
Pace Project No.: 92564018
QC Batch: 1749985 Analysis Method: EPA 625.1
QC Batch Method: 3510C Analysis Description: SVOA (GC/MS)625.1
Laboratory: Pace National-Mt.Juliet
Associated Lab Samples: 92564018003
METHOD BLANK: R3713039-4 Matrix: Water
Associated Lab Samples: 92564018003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Acenaphthene ug/L ND 1.00 10/04/21 02:14
Acenaphthylene ug/L ND 1.00 10/04/21 02:14
Anthracene ug/L ND 1.00 10/04/21 02:14
Benzidine ug/L ND 10.0 10/04/21 02:14
Benzo(a)anthracene ug/L ND 1.00 10/04/21 02:14
Benzo(b)fluoranthene ug/L ND 1.00 10/04/21 02:14
Benzo(k)fluoranthene ug/L ND 1.00 10/04/21 02:14
Benzo(g,h,i)perylene ug/L ND 1.00 10/04/21 02:14
Benzo(a)pyrene ug/L ND 1.00 10/04/21 02:14
bis(2-Chloroethoxy)methane ug/L ND 10.0 10/04/21 02:14
bis(2-Chloroethyl)ether ug/L ND 10.0 10/04/21 02:14
2,2'-Oxybis(1-chloropropane) ug/L ND 10.0 10/04/21 02:14
4-Bromophenylphenyl ether ug/L ND 10.0 10/04/21 02:14
2-Chloronaphthalene ug/L ND 1.00 10/04/21 02:14
4-Chlorophenylphenyl ether ug/L ND 10.0 10/04/21 02:14
Chrysene ug/L ND 1.00 10/04/21 02:14
Dibenz(a,h)anthracene ug/L ND 1.00 10/04/21 02:14
3,3'-Dichlorobenzidine ug/L ND 10.0 10/04/21 02:14
2,4-Dinitrotoluene ug/L ND 10.0 10/04/21 02:14
2,6-Dinitrotoluene ug/L ND 10.0 10/04/21 02:14
Fluoranthene ug/L ND 1.00 10/04/21 02:14
Fluorene ug/L ND 1.00 10/04/21 02:14
Hexachlorobenzene ug/L ND 1.00 10/04/21 02:14
Hexachloro-1,3-butadiene ug/L ND 10.0 10/04/21 02:14
Hexachlorocyclopentadiene ug/L ND 10.0 10/04/21 02:14
Hexachloroethane ug/L ND 10.0 10/04/21 02:14
Indeno(1,2,3-cd)pyrene ug/L ND 1.00 10/04/21 02:14
Isophorone ug/L ND 10.0 10/04/21 02:14
Naphthalene ug/L ND 1.00 10/04/21 02:14
Nitrobenzene ug/L ND 10.0 10/04/21 02:14
N-Nitrosodimethylamine ug/L ND 10.0 10/04/21 02:14
N-Nitrosodiphenylamine ug/L ND 10.0 10/04/21 02:14
N-Nitroso-di-n-propylamine ug/L ND 10.0 10/04/21 02:14
Phenanthrene ug/L ND 1.00 10/04/21 02:14
Butylbenzylphthalate ug/L ND 3.00 10/04/21 02:14
bis(2-Ethylhexyl)phthalate ug/L ND 3.00 10/04/21 02:14
Di-n-butylphthalate ug/L ND 3.00 10/04/21 02:14
Diethylphthalate ug/L ND 3.00 10/04/21 02:14
Dimethylphthalate ug/L ND 3.00 10/04/21 02:14
Di-n-octylphthalate ug/L ND 3.00 10/04/21 02:14
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 14 of 60

Pace Analytical Services,LLC
t 2225 Riverside Dr.
aceAnalytical Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: WWTP PPA 9/29
Pace Project No.: 92564018
METHOD BLANK: R3713039-4 Matrix: Water
Associated Lab Samples: 92564018003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Pyrene ug/L ND 1.00 10/04/21 02:14
1,2,4-Trichlorobenzene ug/L ND 10.0 10/04/21 02:14
Azobenzene ug/L ND 10.0 10/04/21 02:14
4-Chloro-3-methylphenol ug/L ND 10.0 10/04/21 02:14
2-Chlorophenol ug/L ND 10.0 10/04/21 02:14
2-Nitrophenol ug/L ND 10.0 10/04/21 02:14
4-Nitrophenol ug/L ND 10.0 10/04/21 02:14
Pentachlorophenol ug/L ND 10.0 10/04/21 02:14
Phenol ug/L ND 10.0 10/04/21 02:14
2,4,6-Trichlorophenol ug/L ND 10.0 10/04/21 02:14
2,4-Dichlorophenol ug/L ND 10.0 10/04/21 02:14
ug/L 4-DimethY IP henol u /L ND 10.0 10/04/21 02:14
4,6-Dinitro-2-methylphenol ug/L ND 10.0 10/04/21 02:14
2,4-Dinitrophenol ug/L ND 10.0 10/04/21 02:14
Nitrobenzene-d5(S) % 56.2 15.0-314 10/04/21 02:14
2-Fluorobiphenyl(S) % 64.8 22.0-127 10/04/21 02:14
Terphenyl-d14(S) % 69 29.0-141 10/04/21 02:14
Phenol-d5(S) % 19.5 8.00-424 10/04/21 02:14
2-Fluorophenol(S) % 27.3 10.0-120 10/04/21 02:14
2,4,6-Tribromophenol(S) % 59 10.0-153 10/04/21 02:14
LABORATORY CONTROL SAMPLE&LCSD: R3713039-1 R3713039-2
Spike LCS LCSD LCS LCSD %Rec Max
Parameter Units Conc. Result Result %Rec %Rec Limits RPD RPD Qualifiers
Acenaphthene ug/L 50.0 33.9 35.0 67.8 70.0 47.0-145 3.19 48
Acenaphthylene ug/L 50.0 37.9 38.2 75.8 76.4 33.0-145 0.788 74
Anthracene ug/L 50.0 35.3 37.1 70.6 74.2 27.0-133 4.97 66
Benzidine ug/L 100 26.0 14.3 26.0 14.3 1.00-120 58.1 36 R1
Benzo(a)anthracene ug/L 50.0 41.6 41.5 83.2 83.0 33.0-143 0.241 53
Benzo(b)fluoranthene ug/L 50.0 36.8 36.8 73.6 73.6 24.0-159 0.00 71
Benzo(k)fluoranthene ug/L 50.0 37.2 36.5 74.4 73.0 11.0-162 1.90 63
Benzo(g,h,i)perylene ug/L 50.0 35.1 35.2 70.2 70.4 1.00-219 0.284 97
Benzo(a)pyrene ug/L 50.0 38.0 38.1 76.0 76.2 17.0-163 0.263 72
bis(2-Chloroethoxy)methane ug/L 50.0 31.5 31.4 63.0 62.8 1.00-219 0.318 54
bis(2-Chloroethyl)ether ug/L 50.0 34.6 32.5 69.2 65.0 33.0-185 6.26 108 1
2,2'-Oxybis(1-chloropropane) ug/L 50.0 31.2 30.5 62.4 61.0 36.0-166 2.27 76
4-Bromophenylphenyl ether ug/L 50.0 35.0 35.4 70.0 70.8 53.0-127 1.14 43
2-Chloronaphthalene ug/L 50.0 35.5 35.7 71.0 71.4 60.0-120 0.562 24
4-Chlorophenylphenyl ether ug/L 50.0 36.8 36.7 73.6 73.4 25.0-158 0.272 61
Chrysene ug/L 50.0 40.9 40.3 81.8 80.6 17.0-168 1.48 87
Dibenz(a,h)anthracene ug/L 50.0 33.4 33.6 66.8 67.2 1.00-227 0.597 126
3,3'-Dichlorobenzidine ug/L 100 64.5 81.2 64.5 81.2 1.00-262 22.9 108
2,4-Dinitrotoluene ug/L 50.0 45.0 44.4 90.0 88.8 39.0-139 1.34 42
2,6-Dinitrotoluene ug/L 50.0 39.5 39.9 79.0 79.8 50.0-158 1.01 48
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 15 of 60

Pace Analytical Services,LLC
a^eAna' r^al 2225 Riverside Dr.
!�(i I f yt
/G Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: WVVTP PPA 9/29
Pace Project No.: 92564018
LABORATORY CONTROL SAMPLE&LCSD: R3713039-1 R3713039-2
Spike LCS LCSD LCS LCSD %Rec Max
Parameter Units Conc. Result Result %Rec %Rec Limits RPD RPD Qualifiers
Fluoranthene ug/L 50.0 39.3 38.2 78.6 76.4 26.0-137 2.84 66
Fluorene ug/L 50.0 37.2 37.1 74.4 74.2 59.0-121 0.269 38
Hexachlorobenzene ug/L 50.0 33.6 33.9 67.2 67.8 1.00-152 0.889 55
Hexachloro-1,3-butadiene ug/L 50.0 28.0 28.7 56.0 57.4 24.0-120 2.47 62
Hexachlorocyclopentadiene ug/L 50.0 27.3 27.1 54.6 54.2 10.0-120 0.735 31
Hexachloroethane ug/L 50.0 30.7 29.9 61.4 59.8 40.0-120 2.64 52
Indeno(1,2,3-cd)pyrene ug/L 50.0 36.5 35.7 73.0 71.4 1.00-171 2.22 99
Isophorone ug/L 50.0 32.0 32.2 64.0 64.4 21.0-196 0.623 93
Naphthalene ug/L 50.0 28.5 28.8 57.0 57.6 21.0-133 1.05 65
Nitrobenzene ug/L 50.0 30.6 31.2 61.2 62.4 35.0-180 1.94 62
N-Nitrosodimethylamine ug/L 50.0 21.9 21.1 43.8 42.2 10.0-120 3.72 34
N-Nitrosodiphenylamine ug/L 50.0 31.1 36.6 62.2 73.2 44.0-120 16.2 21
N-Nitroso-di-n-propylamine ug/L 50.0 35.4 33.0 70.8 66.0 1.00-230 7.02 87
Phenanthrene ug/L 50.0 37.6 37.5 75.2 75.0 54.0-120 0.266 39
Butylbenzylphthalate ug/L 50.0 41.0 39.9 82.0 79.8 1.00-152 2.72 60
bis(2-Ethylhexyl)phthalate ug/L 50.0 38.1 37.5 76.2 75.0 8.00-158 1.59 82
Di-n-butylphthalate ug/L 50.0 40.9 39.7 81.8 79.4 1.00-120 2.98 47
Diethylphthalate ug/L 50.0 39.5 39.0 79.0 78.0 1.00-120 1.27 100
Dimethylphthalate ug/L 50.0 37.6 37.7 75.2 75.4 1.00-120 0.266 183
Di-n-octylphthalate ug/L 50.0 41.0 40.0 82.0 80.0 4.00-146 2.47 69
Pyrene ug/L 50.0 38.5 39.8 77.0 79.6 52.0-120 3.32 49
1,2,4-Trichlorobenzene ug/L 50.0 28.5 28.8 57.0 57.6 44.0-142 1.05 50
1,2-Diphenylhydrazine ug/L 50.0 38.3 38.2 76.6 76.4 37.0-125 0.261 20
4-Chloro-3-methylphenol ug/L 50.0 28.6 29.8 57.2 59.6 22.0-147 4.11 73
2-Chlorophenol ug/L 50.0 28.6 27.3 57.2 54.6 23.0-134 4.65 61
2,4-Dichlorophenol ug/L 50.0 30.1 31.4 60.2 62.8 39.0-135 4.23 50
2,4-Dimethylphenol ug/L 50.0 24.0 28.6 48.0 57.2 32.0-120 17.5 58
4,6-Dinitro-2-methylphenol ug/L 50.0 52.7 52.9 105 106 1.00-181 0.379 203
2,4-Dinitrophenol ug/L 50.0 48.5 50.0 97.0 100 1.00-191 3.05 132
2-Nitrophenol ug/L 50.0 32.8 33.0 65.6 66.0 29.0-182 0.608 55
4-Nitrophenol ug/L 50.0 14.9 16.5 29.8 33.0 1.00-132 10.2 131
Pentachlorophenol ug/L 50.0 40.7 43.2 81.4 86.4 14.0-176 5.96 86
Phenol ug/L 50.0 12.7 12.4 25.4 24.8 5.00-120 2.39 64
2,4,6-Trichlorophenol ug/L 50.0 35.1 37.5 70.2 75.0 37.0-144 6.61 58
Nitrobenzene-d5(S) % 57.2 57.8 15.0-314
2-Fluorobiphenyl(S) % 73.9 74.5 22.0-127
Terphenyl-d14(S) % 69.3 71.3 29.0-141
Phenol-d5(S) % 24.9 25.1 8.00-424
2-Fluorophenol(S) % 35.8 36.3 10.0-120
2,4,6-Tribromophenol(S) % 68.5 75.5 10.0-153
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 16 of 60
i

Pace Analytical Services,LLC
ace Analytical Asheville,
e,v NC 28 04
Asheville, 28804
www.pacelabs.com [phone]
f
QUALITY CONTROL DATA
Project: WWTP PPA 9/29
Pace Project No.: 92564018
QC Batch: 1749778 Analysis Method: EPA 624.1
QC Batch Method: 624.1 Analysis Description: VOA(GC/MS)624.1
Laboratory: Pace National-Mt.Juliet
Associated Lab Samples: 92564018001
METHOD BLANK: R3711442-3 Matrix: Water
Associated Lab Samples: 92564018001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,1,1-Trichloroethane ug/L ND 1.00 10/01/21 10:12
1,1,2,2-Tetrachloroethane ug/L ND 1.00 10/01/21 10:12
1,1,2-Trichloroethane ug/L ND 1.00 10/01/21 10:12
1,1-Dichloroethane ug/L ND 1.00 10/01/21 10:12
1,1-Dichloroethene ug/L ND 1.00 10/01/21 10:12
1,2-Dichlorobenzene ug/L ND 1.00 10/01/21 10:12
g 1,2-Dichloroethane u /L ND 1.00 10/01/21 10:12
1,2-Dichloropropane ug/L ND 1.00 10/01/21 10:12
1,3-Dichlorobenzene ug/L ND 1.00 10/01/21 10:12
1,4-Dichlorobenzene ug/L ND 1.00 10/01/21 10:12
2-Chloroethylvinyl ether ug/L ND 50.0 10/01/21 10:12
Acrolein ug/L ND 50.0 10/01/21 10:12
Acrylonitrile ug/L ND 10.0 10/01/21 10:12
Benzene ug/L ND 1.00 10/01/21 10:12
Bromodichloromethane ug/L ND 1.00 10/01/21 10:12
Bromoform ug/L ND 1.00 10/01/21 10:12
Bromomethane ug/L ND 5.00 10/01/21 10:12
Carbon tetrachloride ug/L ND 1.00 10/01/21 10:12
Chlorobenzene ug/L ND 1.00 10/01/21 10:12
Dibromochloromethane ug/L ND 1.00 10/01/21 10:12
Chloroethane ug/L ND 5.00 10/01/21 10:12
Chloroform ug/L ND 5.00 10/01/21 10:12
Chloromethane ug/L ND 2.50 10/01/21 10:12
cis-1,3-Dichloropropene ug/L ND 1.00 10/01/21 10:12
Ethylbenzene ug/L ND 1.00 10/01/21 10:12
Methylene Chloride ug/L ND 5.00 10/01/21 10:12
Tetrachloroethene ug/L ND 1.00 10/01/21 10:12
Toluene ug/L ND 1.00 10/01/21 10:12
trans-1,2-Dichloroethene ug/L ND 1.00 10/01/21 10:12
trans-1,3-Dichloropropene ug/L ND 1.00 10/01/21 10:12
Trichloroethene ug/L ND 1.00 10/01/21 10:12
Vinyl chloride ug/L ND 1.00 10/01/21 10:12
1,2-Dichloroethane-d4(S) % 93.1 70.0-130 10/01/21 10:12
4-Bromofluorobenzene(S) % 92.4 80.0-120 10/01/21 10:12
Toluene-d8(S) % 104 80.0-120 10/01/21 10:12
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
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Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Asheville,NC 28804
www.pacalabs.com [phone]
QUALITY CONTROL DATA
Project: WINTP PPA 9/29
Pace Project No.: 92564018
LABORATORY CONTROL SAMPLE&LCSD: R3711442-1 R3711442-2
Spike LCS LCSD LCS LCSD %Rec Max
Parameter Units Conc. Result Result %Rec %Rec Limits RPD RPD Qualifiers
1,1,1-Trichloroethane ug/L 5.00 4.20 4.41 84.0 88.2 70.0-130 4.88 20
1,1,2,2-Tetrachloroethane ug/L 5.00 3.76 3.87 75.2 77.4 60.0-140 2.88 20
1,1,2-Trichloroethane ug/L 5.00 4.06 3.99 81.2 79.8 70.0-130 1.74 20 i
1,1-Dichloroethane ug/L 5.00 4.33 4.33 86.6 86.6 70.0-130 0.00 20
1,1-Dichloroethene ug/L 5.00 4.20 4.04 84.0 80.8 50.0-150 3.88 20
1,2-Dichlorobenzene ug/L 5.00 3.54 3.68 70.8 73.6 65.0-135 3.88 20
1,2-Dichloroethane ug/L 5.00 3.62 3.63 72.4 72.6 70.0-130 0.276 20
1,2-Dichloropropane ug/L 5.00 4.03 3.94 80.6 78.8 35.0-165 2.26 20
1,3-Dichlorobenzene ug/L 5.00 4.01 3.91 80.2 78.2 70.0-130 2.53 20
1,4-Dichlorobenzene ug/L 5.00 3.96 3.77 79.2 75.4 65.0-135 4.92 20
2-Chloroethylvinyl ether ug/L 25.0 15.2 16.2 60.8 64.8 0.100-225 6.37 20
Acrolein ug/L 25.0 17.7 19.5 70.8 78.0 60.0-140 9.68 20
Acrylonitrile ug/L 25.0 18.3 18.7 73.2 74.8 60.0-140 2.16 20
Benzene ug/L 5.00 4.21 4.30 84.2 86.0 65.0-135 2.12 20
Bromodichloromethane ug/L 5.00 4.10 4.11 82.0 82.2 65.0-135 0.244 20
Bromoform ug/L 5.00 3.88 4.22 77.6 84.4 70.0-130 8.40 20
Bromomethane ug/L 5.00 2.33 2.51 46.6 50.2 15.0-185 7.44 20
Carbon tetrachloride ug/L 5.00 3.98 4.08 79.6 81.6 70.0-130 2.48 20
Chlorobenzene ug/L 5.00 4.25 4.11 85.0 82.2 65.0-135 3.35 20
Dibromochloromethane ug/L 5.00 3.86 4.02 77.2 80.4 70.0-135 4.06 20
Chloroethane ug/L 5.00 4.54 4.53 90.8 90.6 40.0-160 0.221 20
Chloroform ug/L 5.00 4.15 4.11 83.0 82.2 70.0-135 0.969 20
Chloromethane ug/L 5.00 3.16 3.37 63.2 67.4 0.100-205 6.43 20
cis-1,3-Dichloropropene ug/L 5.00 3.93 3.87 78.6 77.4 25.0-175 1.54 20
Ethylbenzene ug/L 5.00 4.51 4.16 90.2 83.2 60.0-140 8.07 20
Methylene Chloride ug/L 5.00 4.12 4.26 82.4 85.2 60.0-140 3.34 20
Tetrachloroethene ug/L 5.00 5.08 5.03 102 101 70.0-130 0.989 20
Toluene ug/L 5.00 4.30 4.16 86.0 83.2 70.0-130 3.31 20
trans-1,2-Dichloroethene ug/L 5.00 4.28 4.19 85.6 83.8 70.0-130 2.13 20
trans-1,3-Dichloropropene ug/L 5.00 3.80 3.84 76.0 76.8 50.0-150 1.05 20
Trichloroethene ug/L 5.00 4.15 4.29 83.0 85.8 65.0-135 3.32 20 1
Vinyl chloride ug/L 5.00 4.00 4.27 80.0 85.4 5.00-195 6.53 20
1,2-Dichloroethane-d4(S) % 94.7 95.3 70.0-130
4-Bromofluorobenzene(S) % 96.3 94.8 80.0-120
Toluene-d8(S) % 103 100 80.0-120
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 18 of 60

Pace Analytical Services,LLC
('" aceAnalytical 2225 Riverside Dr.
Asheville,NC 28804
www.pacetabs.com [phone]
i
QUALITY CONTROL DATA
Project: WWTP PPA 9/29
Pace Project No.: 92564018
QC Batch: 650440 Analysis Method: SM 2540C-2011
QC Batch Method: SM 2540C-2011 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92564018003
METHOD BLANK: 3411459 Matrix: Water
Associated Lab Samples: 92564018003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 10/01/21 17:45
LABORATORY CONTROL SAMPLE: 3411460
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 250 100 90-110
SAMPLE DUPLICATE: 3411461
92564140001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 491 495 1 H1
SAMPLE DUPLICATE: 3411462
92564128001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 44.0 43.0 2 ,
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 19 of 60

Pace Analytical Services,LLC
aceAnalytical b 2225 Riverside Dr.
7
Asheville,NC 28804
www.pecelabs.com [phone]
1
QUALITY CONTROL DATA
Project: WWTP PPA 9/29
Pace Project No.: 92564018
QC Batch: 652508 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92564018003
METHOD BLANK: 3421402 Matrix: Water
Associated Lab Samples: 92564018003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Ammonia mg/L ND 0.10 10/13/21 15:43
LABORATORY CONTROL SAMPLE: 3421403
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5 4.9 98 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3421404 3421405
MS MSD
92563920001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L 0.64 5 5 5.6 5.6 98 98 90-110 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3421406 3421407
MS MSD
92563921001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L ND 5 5 4.8 4.8 96 96 90-110 0
Results presented on this page are in the units indicated by the"units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 20 of 60

Pace Analytical Services,LLC
aceAnalytical® Asheville,
Riverside Dr.
NC 28804
www.pacalabs.cora [phone]
QUALITY CONTROL DATA
Project: WWTP PPA 9/29
Pace Project No.: 92564018
QC Batch: 651744 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92564018003
METHOD BLANK: 3417959 Matrix: Water
Associated Lab Samples: 92564018003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Kjeldahl,Total mg/L ND 0.50 10/09/21 05:29
LABORATORY CONTROL SAMPLE: 3417960
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Kjeldahl,Total mg/L 10 10.3 103 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3417961 3417962
MS MSD
92563593001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Kjeldahl,Total mg/L 1.6 10 10 10.8 10.8 92 93 90-110 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3417963 3417964
MS MSD
92563596001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Kjeldahl,Total mg/L 14.9 10 10 27.9 26.2 130 113 90-110 6 M1
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 21 of 60

Pace Analytical Services,LLC
2225 Riverside Dr.
aceAnalytical Asheville,NC 28804
www.Pacalabs.cxsn [phone]
QUALITY CONTROL DATA
Project: WWTP PPA 9/29
Pace Project No.: 92564018
QC Batch: 652511 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate+Nitrite,preserved
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92564018003
METHOD BLANK: 3421414 Matrix: Water
Associated Lab Samples: 92564018003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,NO2 plus NO3 mg/L ND 0.040 10/13/21 10:13
LABORATORY CONTROL SAMPLE: 3421415
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,NO2 plus NO3 mg/L 2.5 2.5 102 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3421416 3421417
MS MSD
92563948002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,NO2plus NO3 mg/L 16.3 2.5 2.5 18.8 18.9 103 105 90-110 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3421418 3421419
MS MSD
92563960002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,NO2 plus NO3 mg/L 9.5 2.5 2.5 11.8 11.8 92 92 90-110 0
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 22 of 60

Pace Analytical Services,LLC
/11aceAnalytical Asheville,
RiversideNC28 04
Asheville,NC 28804
www.pecelabs.com
[phone]
i
QUALITY CONTROL DATA
Project: WWTP PPA 9/29
Pace Project No.: 92564018
QC Batch: 651509 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus,Total
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92564018003
METHOD BLANK: 3416792 Matrix: Water
Associated Lab Samples: 92564018003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 10/08/21 20:41
LABORATORY CONTROL SAMPLE: 3416793
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.3 92 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3416794 3416795
MS MSD
92563834001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus mg/L 2.3 2.5 2.5 4.6 4.6 95 93 90-110 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3416796 3416797
MS MSD
92563842001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus mg/L 1.7 2.5 2.5 4.4 4.5 106 113 90-110 4 M1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 23 of 60

aceAnalytical a
Pace Analytical Services,LLC
2225 Riverside Dr.
Asheville,NC 28804
www.pseslebs.cas [phone]
QUALITY CONTROL DATA
Project: WWTP PPA 9/29
Pace Project No.: 92564018
QC Batch: 650584 Analysis Method: EPA 420.4 Rev 1.0 1993 I
QC Batch Method: EPA 420.4 Rev 1.0 1993 Analysis Description: 420.4 Phenolics
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92564018001
METHOD BLANK: 3412155 Matrix: Water
Associated Lab Samples: 92564018001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phenolics,Total Recoverable mg/L ND 0.020 10/04/21 04:58
LABORATORY CONTROL SAMPLE: 3412156
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phenolics,Total Recoverable mg/L 0.05 0.047 95 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3412157 3412158
MS MSD
92563222001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phenolics,Total Recoverable mg/L <0.020 0.05 0.05 0.051 0.043 98 83 90-110 16 M1,R1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3412159 3412160
MS MSD
92563336001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phenolics,Total Recoverable mg/L ND 0.05 0.05 0.084 .042J 142 59 90-110 D3,M1
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date:11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 24 of 60

Pace Analytical Services,LLC
aceAnalytical a 2225 Riverside Dr.
Asheville,NC 28804
www.pacalabs.cora [phone]
QU
ALITY CONTROL DATA
Project: WWTP PPA 9/29
Pace Project No.: 92564018
QC Batch: 651279 Analysis Method: SM 4500-CN-E-2011
QC Batch Method: SM 4500-CN-E-2011 Analysis Description: 4500CNE Cyanide,Total
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92564018001
METHOD BLANK: 3415658 Matrix: Water
Associated Lab Samples: 92564018001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Cyanide mg/L ND 0.0080 10/07/21 17:20
LABORATORY CONTROL SAMPLE: 3415659
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Cyanide mg/L 0.1 0.10 103 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3415662 3415663
MS MSD
92564727002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Cyanide mg/L ND 0.1 0.1 0.038 0.059 35 56 80-120 44 M1,R1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3415877 3415878
MS MSD
92563655002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Cyanide mg/L 0.044 0.1 0.1 0.12 0.15 76 103 80-120 21 M1,R1
Results presented on this page are In the units indicated by the"Units'column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
QUALIFIERS
Project: WWTP PPA 9/29
Pace Project No.: 92564018
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
TNTC-Too Numerous To Count
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting.Therefore,calculated parameters that are typically reported as
"Total"may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
ANALYTE QUALIFIERS
D3 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
H1 Analysis conducted outside the EPA method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
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Date: 11/09/2021 11:41 PM without the written consent of Pace Analytical Services,LLC. Page 26 of 60

Pace Analytical Services,LLC
2225 Riverside Dr.
aceAnalytical Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: VWVfP PPA 9/29
Pace Project No.: 92564018
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92564018001 WWTP EFF(PPA)Grab EPA 1664B 652414
92564018003 WWTP EFF(PPA)Comp EPA 200.7 Rev 4.4 1994 650171 EPA 200.7 Rev 4.4 1994 650230
92564018003 WWTP EFF(PPA)Comp EPA 200.8 Rev 5.4 650123 EPA 200.8 Rev 5.4 650221
92564018003 WWTP EFF(PPA)Comp EPA 245.1 Rev 3.0 1994 650850 EPA 245.1 Rev 3.0 1994 651178
92564018003 WWTP EFF(PPA)Comp 3510C 1749985 EPA 625.1 1749985
92564018001 WWTP EFF(PPA)Grab 624.1 1749778 EPA 624.1 1749778
92564018003 WWTP EFF(PPA)Comp SM 2540C-2011 650440
92564018003 WWTP EFF(PPA)Comp EPA 350.1 Rev 2.0 1993 652508
92564018003 WWTP EFF(PPA)Comp EPA 351.2 Rev 2.0 1993 651744 EPA 351.2 Rev 2.0 1993 651870
92564018003 WWTP EFF(PPA)Comp EPA 353.2 Rev 2.0 1993 652511
92564018003 WWTP EFF(PPA)Comp EPA 365.1 Rev 2.0 1993 651509 EPA 365.1 Rev 2.0 1993 651578
92564018001 WWTP EFF(PPA)Grab EPA420.4 Rev 1.0 1993 650584 EPA420.4 Rev 1.0 1993 650586
92564018001 WWTP EFF(PPA)Grab SM 4500-CN-E-2011 651279 SM 4500-CN-E-2011 651500
REPORT OF LABORATORY ANALYSIS
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G CHAIN-OF-CUSTODY Analytical Request Document LAB USE C wo# : 9256/�018 „ber or
Pace Analytical• V M'
Chain-of-Custody is a LEGAL DOCUMENT-Complete all relevent fields 111111
III 111111111
III
Company: Billing Information:
II tiiIIL WWrP 92554018
Address: -,f n f j Container
Report To: •HA AIL
Q^ Email To- •'Preservative Types:(i)nitric acid,(2)sulfuric acid,(3)hydrochloric acid,(a)sodium hydroxide,(5)zinc acetate,
r
V._•t' J L ) 9 2, (6)methanol,(7)sodium bisulfate,(8)sodium thiosulfate,(9)hexane,(A)ascorbic acid,(B)ammonium sulfate,
Copy To: iy. _ Site Collection Info/Address: (C)ammonium hydroxide,(D)TSP,(U)Unpreserved,(0)Other
� �ft ~k,,,),_/- `!�� r Analyses Lab Profile/Line:
Customer Project Name/Number: State: County/City: Time Zone Collected: Mil Lab Sample Receipt Checklist:
Al// !t Jill` [ )PT[ ]MT[ jCT ET
Phone: SiteJFaility ID It: t Co ante Monitoring? Custody Seals Present/Intact YA
f'Q'1 ; ,) Custody Signatures Present ,�l'N NA
Email: W r 1 1 list:l[t, Lid-t-l [i.r Yes [ ]No Collector Signature Present 4t NA
Bottles Intact "Y'"Ii NA
Collected By(print): urchase Order#: OW PWS ID#: \ Correct Bottles f4 N NA
it-V la' L: .,� Quote#: N3 q t, DW Location Code: (� Sufficient Volume ,y.41 NA
Samples Received on ice „Art N NA
Collette (sign re)' Turnaround Date Required: Im diately Packed on Ice:
��1' q � � VOA - Headspace Acceptable ,s'Q N NA
No [4es [ )No USDA Regulated Soils Y N 2tA"
t c; i- Samples in Holding Time .� N A
Sa ple Disposal: Rush: Field Filtered(if applicable): Q Residual Chlorine Present Y X NA
1,40ispose as appropriate I I Return [ )Same Day [ ]Next Day [ )Yes I No --a Cl Strips: _ Y1"; err
( I Archive: ( 1 2 Day [ ]3 Day [ )4 Day ( ]5 Day c" Sample pH Accep 2 w4 NA
H Analysis: pH Strips: •'7 1
I ) old: (Expedite Charges Apply) -} p C`� (`^tom`j,J1 Sulfide Present Y Nye.T-"
SA
.Matrix Codes(Insert in Matrix box below):Drinking Water(OW),Ground Water(OW),Wastewater(WW), T o �� Lead Acetate Strips: -�
Product(P),Soil/Solid(SL),Oil(OL),Wipe(WP),Air(AR),Tissue(TS),Bioassay(B),Vapor(V),Other(OT) -...4 ;�• to 5 vn 7,, (((A
-c rr' rs3 - LAB USE ONLY:
Comp/ Collected(or Res #of 41- ` •s' --r Lab Sample # / Comments
Customer Sample ID Matrix• Grab Composite Start) Composite End Cl Ctns -! _'^
Date Time Date Time --.1
i,.. s T F ,FF C.P' n 1 ‘,...,-,-,/ Cr9-?% zi /S i 9- NA 9 X.A X .k X
%-.� (__ '3-zv-� l0-33 9.24-11 t o , -_ x ,( X
Customer Rem arks/Special Conditions/Pos$'ibblle,fazards: Type of Ice Used: /Yet Blue Dry None SHORT HOLDS PRESENT(<72 hours): Y� N/A Lab Sample Temperature Info:
¢A 1h,Ji°L 6e- '004 t-o Packing Material Used: Lab Tracking#: Temp Blank eceived: Y-^DVNA
a. O k
tt-1t� i•'a w s 1 i t! • /�. 4 ,, r 2615431 Therm IOU:L" �7T11 tiff
E
e. c� ,,,,� $Lr�_ - ,1 ;~j L Cooler 1 Temp Upon Receipt: S t oC
`� Samples received via: Cooler 1 Therm Corr.Factor: t) oC
Radchem sample(s)screened(<500 cpm): Y N NA
r FEDEX UPS Client Courier Pac ourier Cooler 1 Corrected Temp: ( i oC
Relingyi ed by/Company:(Signature) Date/Time: 7'ay.7 n 1 Received bier✓:mpany:(Signature Date/Ti f MT.IL LAB USE ONLY Comments:
/ /10 I f z9t,tom f '- GrTable#:
I: Acctnum:
Reli 'uish pang:(Signs Date/Time: Rec•'•-d by ompany:(Signature) D e/Time:
na /J,�! j a i { ¢ !^} Template: Trip Blank Received: Y � NA
o/�'° �'-- jjf/2'ii t l�'5� ',�,1 _ 1 1 t I t't s Prelogin: HCL McOH TSP Other
Relio fished by/Company:(Signature) Date/Time: Received b /Corttpany (Signature) Date/Time: PM_ Non Conformance(s): Page:
+ PB: YES /� of:

Document Name: Document Revised:October 28,2020
Sample Condition Upon Recelpt(SCUR) Page 2 of 2
aceAna(ytical Document No.: issuing Authority:
f e`
f-CAR-CS-033-Rev.07 Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is Project# r WO# R 9256401 V
verified and within the acceptance range for preservation •/ Due Date.: 10/13/21
samples. PM: UJP
Exceptions:VOA,Coliform,TOC,Oil and Grease,DR0/8015(water)DOC,LIHg CLIENT: 93-HVILL WWT
**Bottom half of box is to list number of bottles
E a _ d z
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Z T, N _ ` (Sr v 4. a
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pH Adjustment Log for Preserved Samples
Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative lot a
adjusted added
Note: whenever there is a discrepancy affecting North Carolina compliance samples,a copy of this form will be sent to the North Carolina DEHNR Certification Office(i.e.
Out of hold,incorrect preservative,out of temp,incorrect containers.
Page 29 of 60

...
zaa, r,
ace Analytical
A \ ALYTICAL REORT
Yt
October 07, 2021
3
SS
Pace Analytical - Asheville, NC
4
Sample Delivery Group: L1411440 Cn
Samples Received: 09/30/2021
Sr
Project Number: 92564018
Description: WWTP PPA 9/29 Qc
Site: 001
7
GI
Report To: Lorri Patton
2225 Riverside Drive "AI
Asheville, NC 28804
9
Sc
Entire Report Reviewed By: 04:450itit,C4_ft,
Christi M Wagner
.., Project Manager
Results relate only to the Items tested or calibrated and are reported as rounded values.This test report shall not be
reproduced,except In full,without written approval of the laboratory.Where applicable,sampling conducted by Pace
"`",. Analytical National is performed per guidance provided In laboratory standard operating procedures ENV-SOP-MTJL-0067 and
ENV-SOP-MTJL-0068.Where samplin >ronducted by the customer,results relate to the accuracy of the information provided,
and as the samples are received.
OO,it,:04,,,'','''''''I'0,..
} Z a 'N 'yp�:
10
.i.
a , ;:. .
y a'
- r
F " yk 4. V y p 4.;'A waN
,a., F*hry a a , { a � s , p
1. ,
„ ' g r , 1 , � v r n ,td�4.a ,x,,'� zi-) ''
i
Pace Analytical National
12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com s� ;.',;,.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Pace Analytical-Asheville,NC 92564018 L1411440 10/07/21 21:01 1 of 19

TABLE OF CONTENTS
Cp:Cover Page 1
Cp
Tc:Table of Contents 2
Ss:Sample Summary 3 1-
Cn:Case Narrative 4
3
Sr:Sample Results 5 Ss
WWTP EFF(PPA)GRAB L1411440-01 5 4
Cn
WWTP EFF(PPA)COMP L1411440-02 6
Qc:Quality Control Summary 8 5Sr
Volatile Organic Compounds(GC/MS)by Method 624.1 8
6
Semi Volatile Organic Compounds (GC/MS) by Method 625.1 10 Qc
GI:Glossary of Terms 14 7
GI
Al:Accreditations&Locations 15
Sc:Sample Chain of Custody 16 AI
9
SC
Page 31 of 60
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Pace Analytical-Asheville,NC 92564018 L1411440 10/07/21 21:01 2 of 19

SAMPLE SUMMARY
Coll cti^d by Collected date time ReCeIVed date/time
WWTP EFF (PPA) GRAB L1411440-01 WW 09/28/2115:19 09/30/21 09:00 Cp
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time 2
TC
Volatile Organic Compounds(GC/MS)by Method 624.1 WG1749778 1 10/01/2112:56 10/01/2112:56 JHH Mt.Juliet,TN r
Collected by Collected date/time Received date/time SS
WWTP EFF (PPA) COMP L1411440-02 WW 09/28/2110:49 09/30/21 09:00 4Cn
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
5
Semi Volatile Organic Compounds (GC/MS)by Method 625.1 WG1749985 1 10/03/2117:28 10/05/21 03:08 AMG Mt.Juliet,TN Sr
6
QC
7
GI
8
Al
9
SC
Page 32 of 60
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Pace Analytical-Asheville,NC 92564018 L1411440 10/07/21 21:01 3 of 19

CASE NARRATIVE
All sample aliquots were received at the correct temperature, in the proper containers,with the
appropriate preservatives,and within method specified holding times, unless qualified or notated within
the report. Where applicable,all MDL(LOD)and RDL(LOQ)values reported for environmental samples Tc
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative,a non-conformance form .3
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my Ss
knowledge,all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory,and no information or data have been
knowingly withheld that would affect the quality of the data.
5
Sr
• E I
Oc
aitiates643....
GI
Christi M Wagner
Project Manager Al
9
SC
Page 33 of 60
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Pace Analytical-Asheville,NC 92564018 L1411440 10/07/21 21:01 4 of 19

i /
WWTP EFF (PPA) GRAB SAMPLE RESULTS - 01
Collected date/time: 09/28/21 15:19 L1411440
Volatile Organic Compounds (GC/MS) by Method 624.1 i
Result Qualifier MDL RDL Dilution Analysis Batch Cp
Analyte ug/I ug/1 ug/I date/time
Acrolein U 2.54 50.0 1 10/01/202112:56 WG1749778 Tc
Acrylonitrile U 0.671 10,0 1 10/01/202112:56 WG1749778
Benzene U 0.0941 1.00 1 10/01/202112:56 WG1749778 3
SS
Bromodichloromethane U 0.136 1.00 1 10/01/202112:56 WG1749778
Bromoform U 0.129 1.00 1 10/01/202112:56 WG1749778 4
Bromomethane U 0.605 5.00 1 10/01/202112:56 WG1749778 Cn
Carbon tetrachloride U 0.128 1.00 1 10/01/202112:56 WG1749778
Chlorobenzene U 0.116 1.00 1 10/01/202112:56 WG1749778 Sr
Chlorodibromomethane U 0.140 1.00 1 10/01/202112:56 WG1749778
Chloroethane U 0.192 5.00 1 10/01/202112:56 WG1749778
2-Chloroethyl vinyl ether U 0.575 50.0 1 10/01/202112:56 WG1749778 QC
Chloroform 0.205 J 0.111 5.00 1 10/01/202112:56 WG1749778
Chloromethane U 0.960 2.50 1 10/01/202112:56 WG1749778 7 GI
1,2-Dichlorobenzene U 0.107 1.00 1 10/01/202112:56 WG1749778
1,3-Dichlorobenzene U 0.110 1.00 1 10/01/202112:56 WG1749778 3
1,4-Dichlorobenzene 0.422 J 0.120 1.00 1 10/01/202112:56 WG1749778 Al
1,1-Dichloroethane U 0.100 1.00 1 10/01/202112:56 WG1749778
1,2-Dichloroethane U 0.0819 1.00 1 10/01/202112:56 WG1749778 I9SC
1,1-Dichloroethene U 0.188 1.00 1 10/01/202112:56 WG1749778
trans-1,2-Dichloroethene U 0.149 1.00 1 10/01/202112:56 WG1749778
1,2-Dichloropropane U 0.149 1.00 1 10/01/202112:56 WG1749778
cls-1,3-Dichloropropene U 0.111 1.00 1 10/01/202112:56 WG1749778
trans-1,3-Dichloropropene U 0.118 1.00 1 10/01/202112:56 WG1749778
Ethylbenzene U 0.137 1.00 1 10/01/202112:56 WG1749778
Methylene Chloride U 0.430 5.00 1 10/01/202112:56 WG1749778
1,1,2,2-Tetrachloroethane U 0.133 1.00 1 10/01/202112:56 WG1749778
Tetrachloroethene U 0.300 1.00 1 10/01/202112:56 WG1749778
Toluene U 0.278 1.00 1 10/01/202112:56 WG1749778
1,1,1-Trichloroethane U 0.149 1.00 1 10/01/202112:56 WG1749778
1,1,2-Trichloroethane U 0.158 1.00 1 10/01/202112:56 WG1749778
Trichloroethene U 0.190 1.00 1 10/01/202112:56 WG1749778
Vinyl chloride U 0.234 1.00 1 10/01/202112:56 WG1749778
(S)Toluene-d8 106 80.0-120 10/01/202112:56 WG1749778
(S)4-Bromofluorobenzene 95.1 80.0-120 10/01/202112:56 WG1749778
(S)1,2-Dichloroethane-d4 93.8 70.0-130 10/01/202112:56 WG1749778
Page 34 of 60
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Pace Analytical-Asheville,NC 92564018 L1411440 10/07/21 21:01 5 of 19
l

um.
WWTP EFF (PPA) COMP SAMPLE RESULTS - 02
Collected date/time: 09/28/21 10:49 L1411440
Semi Volatile Organic Compounds (GC/MS) by Method 625.1
Result Qualifier MDL RDL Dilution Analysis Batch Cp
Analyte ug/I ug/I ug/I date I time
Acenaphthene U 0.0886 1.00 1 10/05/2021 03:08 WG1749985 Tc
Acenaphthylene U 0.0921 1.00 1 10/05/202103:08 WG1749985 '
Anthracene U 0.0804 1.00 1 10/05/2021 03:08 WG1749985 3
SS
Benzidine U J3 3.74 10.0 1 10/05/2021 03:08 WG1749985
Benzo(a)anthracene U 0.199 1.00 1 10/05/2021 03:08 WG1749985 4
Benzo(b)fluoranthene U 0.130 1.00 1 10/05/202103:08 WG1749985 Cn
Benzo(k)fluoranthene U 0.120 1.00 1 10/05/2021 03:08 WG1749985
Benzo(g,h,i)perylene U 0.121 1.00 1 10/05/2021 03:08 WG1749985
.)I
Benzo(a)pyrene U 0.0381 1.00 1 10/05/2021 03:08 WG1749985
Bis(2-chlorethoxy)methane U 0.116 10.0 1 10/05/2021 03:08 WG1749985 6
Bis(2-chloroethyl)ether U 0.137 10.0 1 10/05/2021 03:08 WG1749985 CSC
2,2-Oxybis(1-Chloropropane) U 0.210 10.0 1 10/05/2021 03:08 WG1749985
4-Bromophenyl-phenylether U 0.0877 10.0 1 10/05/2021 03:08 WG1749985 7Gl
2-Chloronaphthalene U 0.0648 1.00 1 10/05/2021 03:08 WG1749985
4-Chloraphenyl-phenylether U 0.0926 10.0 1 10/05/2021 03:08 WG1749985 3
Chrysene U 0.130 1.00 1 10/05/2021 03:08 WG1749985 Al
Dlbenz(a,h)anthracene U 0.0644 1.00 1 10/05/2021 03:08 WG1749985
3,3-Dichlorobenzidine U 0.212 10.0 1 10/05/2021 03:08 WG1749985 9
SC
2,4-Dinitrotoluene U 0.0983 10.0 1 10/05/2021 03:08 WG1749985
2,6-Dinitrotoluene U 0.250 10.0 1 10/05/2021 03:08 WG1749985
1,2-Diphenylhydrazine U 0.105 10.0 1 10/05/2021 03:08 WG1749985
Fluoranthene U 0.102 1.00 1 10/05/2021 03:08 WG1749985
Fluorene U 0.0844 1.00 1 10/05/2021 03:08 WG1749985
Hexachlorobenzene U 0.0755 1.00 1 10/05/2021 03:08 WG1749985
Hexachloro-1,3-butadiene U 0.0968 10.0 1 10/05/2021 03:08 WG1749985
Hexachlorocyclopentadiene U 0.0598 10.0 1 10/05/2021 03:08 WG1749985
Hexachloroethane U 0.127 10.0 1 10/05/2021 03:08 WG1749985
Indeno(1,2,3-cd)pyrene U 0.279 1.00 1 10/05/2021 03:08 WG1749985
lsophorone U 0.143 10.0 1 10/05/2021 03:08 WG1749985
Naphthalene U 0.159 1.00 1 10/05/2021 03:08 WG1749985
Nitrobenzene U 0.297 10.0 1 10/05/2021 03:08 WG1749985
n-Nltrosodimethylamine U 0.998 10.0 1 10/05/2021 03:08 WG1749985
n-Nitrosodiphenylamine U 2.37 10.0 1 10/05/2021 03:08 WG1749985
n-Nitrosodl-n-propylamine U 0.261 10.0 1 10/05/2021 03:08 WG1749985
Phenanthrene U 0.112 1.00 1 10/05/2021 03:08 WG1749985
Benzylbutyl phthalate U 0.765 3.00 1 10/05/202103:08 WG1749985
Bis(2-ethylhexyl)phthalate U 0.895 3.00 1 10/05/2021 03:08 WG1749985
Di-n-butyl phthalate U 0.453 3.00 1 10/05/2021 03:08 WG1749985
Diethyl phthalate U 0.287 3.00 1 10/05/2021 03:08 WG1749985
Dimethyl phthalate U 0.260 3.00 1 10/05/2021 03:08 WG1749985
Di-n-octyl phthalate U 0.932 3.00 1 10/05/2021 03:08 WG1749985
Pyrene U 0.107 1.00 1 10/05/2021 03:08 WG1749985
1,2,4-Trichlorobenzene U 0.0698 10.0 1 10/05/2021 03:08 WG1749985
4-Chloro-3-methylphenol U 0.131 10.0 1 10/05/2021 03:08 WG1749985
2-Chlorophenol U 0.133 10.0 1 10/05/2021 03:08 WG1749985
2,4-Dichlorophenol U 0.102 10.0 1 10/05/2021 03:08 WG1749985
2,4-Dimethylphenol U 0.0636 10.0 1 10/05/2021 03:08 WG1749985
4,6-Dinitro-2-methylphenol U 1.12 10.0 1 10/05/2021 03:08 WG1749985
2,4-Dinitrophenol U 5.93 10.0 1 10/05/2021 03:08 WG1749985
2-Nitrophenol U 0.117 10.0 1 10/05/2021 03:08 WG1749985
4-Nitrophenol U 0.143 10.0 1 10/05/202103:08 WG1749985
Pentachlorophenol U 0.313 10.0 1 10/05/202103:08 WG1749985
Phenol U 4.33 10.0 1 10/05/2021 03:08 WG1749985
2,4,6-Trichlorophenol U 0.100 10.0 1 10/05/2021 03:08 WG1749985
(S)Nitrobenzene-d5 60.2 15.0-314 10/05/202103:08 WG1749985
(S)2-Fluorobiphenyl 59.8 22.0-127 10/05/202103:08 WG1749985
Page 35 of 60
ACCOUNT: PROJECT: SOG: DATE/TIME: PAGE:
II
Pace Analytical-Asheville,NC 92564018 L1411440 10/07/21 21:01 6 of 19

WWTP EFF (PPA) COMP SAMPLE RESULTS - 02
Collected date/time: 09/28/21 10:49 L1411440
Semi Volatile Organic Compounds (GC/MS) by Method 625.1
Result Qualifier MDL RDL Dilution Analysis Batch Cp
Analyte ug/I ug/I ug/I date/time
(S)p-Terphenyl-d14 60.4 29.0-141 10/05/202103:08 WG1749985 I2TC
(S)Phenol-d5 14.3 8.00-424 10/05/202103:08 WG1749985
(S)2-Fluorophenol 25.1 10.0-120 10/05/202103:08 WG1749985 3
(S)2,4,6-Tdbromophenol 58.9 10.0-153 10/05/202103:08 WG1749985 SS
4
Cn
SI
6
ac
7
GI
3
Al
Isc
Page 36 of 60
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Pace Analytical-Asheville,NC 92564018 L1411440 10/07/21 21:01 7 of 19

WG1749778 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 624.1 L1411440-01
Method Blank (MB) i Cp
(MB)R3711442-3 10/01/2110:12
MB Result MB Qualifier MB MDL MB RDL
1
Analyte ug/I ugh' ug/I Tc
1,1,1-Trichloroethane U 0.149 1.00
1,1,2,2-Tetrachloroethane U 0.133 1.00 3
SS
1,1,2-Trichloroethane U 0.158 1.00
1,1-Dichloroethane U 0.100 1.00 4
1,1-Dichloroethene U 0.188 1.00 Cn
1,2-Dichlorobenzene U 0.107 1.00
1,2-Dichloroethane U 0.0819 1.00 5
Sr
1,2-Dichloropropane U 0.149 1.00
1,3-Dichlorobenzene U 0.110 1.00
1,4-Dichlorobenzene U 0.120 1.00 QC
2-Chloroethyl vinyl ether U 0.575 50.0
Acrolein U 2.54 50.0 7Gl
Acrylonitrile U 0.671 10.0
Benzene U 0.0941 1.00
Bromodichloromethane U 0.136 1.00 Al
8romoform U 0.129 1.00
Bromomethane U 0.605 5.00 9
SC
Carbon tetrachloride U 0.128 1.00
Chlorobenzene U 0.116 1.00
Chlorodibromomethane U 0.140 1.00
Chloroethane U 0.192 5.00
Chloroform U 0.111 5.00
Chioromethane U 0.960 2.50
cis-1,3-Dichloropropene U 0.111 1.00
Ethylbenzene U 0.137 1.00
Methylene Chloride U 0.430 5.00
Tetrachloroethene U 0.300 1.00
Toluene U 0.278 1.00
trans-1,2-Dichloroethene U 0.149 1.00
trans-1,3-Dichloropropene U 0.118 1.00
Trichloroethene U 0.190 1.00
Vinyl chloride U 0.234 1.00
(S)1,2-Dichloroethane-d4 93.1 70.0-130
(S)4-Bromofluorobenzene 92.4 80.0-120
(S)Toluene-d8 104 80.0-120
Page 37 of 60
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Pace Analytical-Asheville,NC 92564018 L1411440 10/07/21 21:01 8 of 19

ems` G < r.P-,•:''":
WG1749778 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 624.1 L14114 40-01
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS)R3711442-1 10/01/21 08:26•(LCSD)R3711442-2 10/01/21 08:47 Cp
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec.Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
2
Analyte ug/I ughl ug/I 90 % % �, % Tc
1,1,1-Trichloroethane 5.00 4.20 4.41 84.0 88.2 70.0-130 4.88 20
1,1,2,2-Tetrachloroethane 5.00 3.76 3.87 75.2 77.4 60.0-140 2.88 20 3SS
1,1,2-Trichloroethane 5.00 4.06 3.99 81.2 79.8 70.0-130 1.74 20
1,1-Dichloroethane 5.00 4.33 4.33 86.6 86.6 70.0-130 0.000 20 4
1,1-Dichloroethene 5.00 4.20 4.04 84.0 80.8 50.0-150 3.88 20 Cn
1,2-Dichtorobenzene 5.00 3.54 3.68 70.8 73.6 65.0-135 3.88 20
1,2-Dichloroethane 5.00 3.62 3.63 72.4 72.6 70.0-130 0.276 20 Sr
1,2-Dichloropropane 5.00 4.03 3.94 80.6 78.8 35.0-165 2.26 20
1,3-Dichlorobenzene 5.00 4.01 3.91 80.2 78.2 70.0-130 2.53 20 6
1,4-Dichlorobenzene 5.00 3.96 3.77 79.2 75.4 65.0-135 4.92 20 Qc
2-Chloroethyl vinyl ether 25.0 15.2 16.2 60.8 64.8 0.100-225 6.37 20
Acrolein 25.0 17.7 19.5 70.8 78.0 60.0-140 9.68 20 7
GI
Acrylonitrile 25.0 18.3 18.7 73.2 74.8 60.0-140 2.16 20
Benzene 5.00 4.21 4.30 84.2 86.0 65.0-135 2.12 20
Bromodichloromethane 5.00 4.10 4.11 82.0 82.2 65.0-135 0.244 20 Al
Bromoform 5.00 3.88 4.22 77.6 84.4 70.0-130 8.40 20
Bromomethane 5.00 2.33 2.51 46.6 50.2 15.0-185 7.44 20 9
SC
Carbon tetrachloride 5.00 3.98 4.08 79.6 81.6 70.0-130 2.48 20
Chlorobenzene 5.00 4.25 4.11 85.0 82.2 65.0-135 3.35 20
Chlorodibromomethane 5.00 3.86 4.02 17.2 80.4 70.0-135 4.06 20
Chloroethane 5.00 4.54 4.53 90.8 90.6 40.0-160 0.221 20
Chloroform 5.00 4.15 4.11 83.0 82.2 70.0-135 0.969 20
Chloromethane 5.00 3.16 3.37 63.2 67.4 0.100-205 6.43 20
cis-1,3-Dichloropropene 5.00 3.93 3.87 78.6 77.4 25.0-175 1.54 20
Ethylbenzene 5.00 4.51 4.16 90.2 83.2 60.0-140 8.07 20
Methylene Chloride 5.00 4.12 4.26 82.4 85.2 60.0-140 3.34 20
Tetrachloroethene 5.00 5.08 5.03 102 101 70.0-130 0.989 20
Toluene 5.00 4.30 4.16 86.0 83.2 70.0-130 3.31 20
trans-1,2-Dichloroethene 5.00 4.28 4.19 85.6 83.8 70.0-130 2.13 20
trans-1,3-Dichloropropene 5.00 3.80 3.84 76.0 76.8 50.0-150 1.05 20
Trichloroethene 5.00 4.15 4.29 83.0 85.8 65.0-135 3.32 20
Vinyl chloride 5.00 4.00 4.27 80.0 85.4 5.00-195 6.53 20
(S)1,2-Dichloroethane-d4 94.7 95.3 70.0-130
(S)4-Bromofluorobenzene 96.3 94.8 80.0-120
(S)Toluene-d8 103 100 80.0-120
Page 38 of 60
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Pace Analytical-Asheville,NC 92564018 L1411440 10/07/21 21:01 9 of 19

WG1749985 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 625.1 L14114 4 0-0 2
Method Blank (MB)
(MB)R3713039-4 10/04/21 02:14 Cp
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/I ug/I ug/I Tc
Acenaphthene U 0.0886 1.00
Acenaphthylene U 0.0921 1.00 3
SS
Anthracene U 0.0804 1.00
Benzidine U 3.74 10.0 4
Benzo(a)anthracene U 0.199 1.00 Cn
Benzo(b)fluoranthene U 0.130 1.00
Benzo(k)fluoranthene U 0.120 1.00 5
Sr
Benzo(g,h,i)perylene U 0.121 1.00
Benzo(a)pyrene U 0.0381 1.00
Bis(2-chlorethoxy)methane U 0.116 10.0 QC
Bis(2-chloroethyl)ether U 0.137 10.0
2,2-oxybis(1-chloropropane) U 0.210 10.0
GI
4-Bromophenyl-phenylether U 0.0877 10.0
2-Chloronaphthalene U 0.0648 1.00 3
4-Chlorophenyl-phenylether U 0.0926 10.0 Al
Chrysene U 0.130 1.00
Dibenz(a,h)anthracene U 0.0644 1.00 9
SC
3,3-Dichlorobenzidine U 0.212 10.0
2,4-Dinitrotoluene U 0.0983 10.0
2,6-Dinitrotoluene U 0.250 10.0
Fluoranthene U 0.102 1.00
Fluorene U 0.0844 1.00
Hexachlorobenzene U 0.0755 1.00
Hexachloro-1,3-butadiene U 0.0968 10.0
Hexachlorocyclopentadiene U 0.0598 10.0
Hexachloroethane U 0.127 10.0
Indeno(1,2,3-cd)pyrene U 0.279 1.00
Isophorone U 0.143 10.0
Naphthalene U 0.159 1.00
Nitrobenzene U 0.297 10.0
n-Nitrosodimethylamine U 0.998 10.0
n-Nitrosodiphenylamine U 2.37 10.0
n-Nitrosodi-n-propylamine U 0.261 10.0
Phenanthrene U 0.112 1.00
Benzylbutyl phthalate U 0.765 3.00
Bis(2-ethyihexyl)phthalate U 0.895 3.00
Di-n-butyl phthalate U 0.453 3.00
Diethyl phthalate U 0.287 3.00
Dimethyl phthalate U 0.260 3.00
Di-n-octyl phthalate U 0.932 3.00
Page 39 of 60
ACCOUNT: PROJECT: SDG: DATEITIME: PAGE:
Pace Analytical-Asheville,NC 92564018 L1411440 10/07/21 21:01 10 of 19

This page intentionally left blank.

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
TABLE F.INDUSTRIAL DISCHARGE INFORMATION
Response space is provided for three SIUs.Copy the table to report information for additional SIUs.
SIU 1 SIU 2 SIU 1
Name of SIU Clement Pappas,N.C.LLC Coats North America Kimberley Clark Corporation
Mailing address(street or P.O.box) 125 Industrial Park Road 1710 Brevard,Road 32 Smyth Avenue
City,state,and ZIP code Hendersonville,N.C.28791 Hendersonville,N.C.28792 Hendersonville,N.C.28792
Description of all industrial processes that affect Produces fruit juice,and juice concentrate Manufacturing of industrial sewing thread Nonwoven fabrics manufacturer,made
or contribute to the discharge. using twisting dyeing,coating,finish from polymer pellets using an extrusian
applicationand packaging intermediate process.
processes.Also modifynylon resin in
seperate process to be the in
a ffnrementinedrnatinp nrnresc.
List the principal products and raw materials that Juice concentrate,sugar,fruit Industrial sewing thread,BC!Resin,Greige Polypropolyne,polyethylenepellets and
affect or contribute to the SIU's discharge. yarns,pyramids,metaraminds,nylon, fibers,cirrasol(surfactants)and pigments
polyester,waxes,silicon based finish,PVC,
fiberglass,para-aramid fibers,isopropyl
alcohol solovent,silicon lubricant,
methafnrm SSA ammonia-nhncnhnrir
Indicate the average daily volume of wastewater
discharged by the SIU. 11,300 gpd 2080 gpd l0000 gpd
How much of the average daily volume is
attributable to process flow? 11,300 gpd 7392 gpd 66432 gpd
How much of the average daily volume is
attributable to non-process flow? 158,700 gpd 5312 gpd 56432 gpd
Is the SIU subject to local limits?
CI Yes ❑ No CI Yes 0 No El Yes ❑ No
Is the SIU subject to categorical standards?
CI Yes ❑ No 0 Yes ❑ No CI Yes ❑ No
EPA Form 3510-2A(Revised 3-19) Page 29

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
TABLE F.INDUSTRIAL DISCHARGE INFORMATION
Response space is provided for three SIUs.Copy the table to report information for additional SIUs.
SIU 1 SIU 2 SIU 3
Under what categories and subcategories is the 40 CFR 407 Subpart F 40 CFR 414 OCPSF 40 CFR 410 Textile
SIU subject? 40 CFR 410 Textile Mills
Mills
Has the POTW experienced problems(e.g.,
upsets,pass-through interferences)in the past 4.5 ❑ Yes El No ❑ Yes CI No ❑ Yes ❑r No
years that are attributable to the SIU?
If yes,describe.
EPA Form 3510-2A(Revised 3-19) Page 30

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
TABLE F.INDUSTRIAL DISCHARGE INFORMATION
Response space is provided for three SIUs.Copy the table to report information for additional Sills.
SIU 4 SIU 5 SIU 6
Name of SIU
Current Lighting Solutions Lipman Produce/Custom Pack Selee Corporation
Mailing address(street or P.O.box) 310 Spartanburg Hwy. 2123 Ridge Road 700 Shepard Street
City,state,and ZIP code Hendersonville,N.C.28792 Hendersonville,N.C.28792 Hendersonville,N.C.28792
Description of all industrial processes that affect PManufactures components for high Grading and repackaging vegetables and Manufactures ceramics,primarily ceramic
or contribute to the discharge. intensity discharge and LED lighting fixtures, sliced and diced vegetables foam,which involves impregnation of a
electrical components,ballast asembly and polyurethane foam blanket with ceramic
sheet metal part fabrication.Most all LED slurry,subsequent drying,and firing at
componentsare purchased for assembly. high temperatures of the foam blanket.
Fxterinr of the fixtures are nainted with
List the principal products and raw materials that Aluminum Reflector Finish,3002/3003 Sliced/Diced vegetables-tomatoes,bell Ceramic Filters and castable shapes are
affect or contribute to the SIU's discharge. Aluminum,Cleaning processes chemicals peppers,onions,cucumbers,salsa mix, produced at this facility.Raw materials
used include-342 acid cleaner,metal medic citric acid,sodium hypochlorite. include Alumina powder,silicon carbide
7590,50%caustic soda,potassium silicate powder,silica powder,polyvinyl alcohal,
blendwith proprietary chemical,67%nitric boric acid powder,collodial silica,
arid RCM nhnsnhorir arid and water magnesium oxide nnwder nnlvurethane
Indicate the average daily volume of wastewater
discharged by the SIU. 6000 gpd 200 gpd 3100 gpd
How much of the average daily volume is
attributable to process flow? 54000 gpd 19,000 gpd 12680 gpd
How much of the average daily volume is
attributable to non-process flow? 48000 gpd 18,80o gpd 9580 gpd
Is the SIU subject to local limits?
✓❑ Yes ❑ No El Yes ❑ No 0 Yes 0 No
Is the SIU subject to categorical standards?
❑✓ Yes ❑ No 0 Yes 0 No 0 Yes ❑ No
EPA Form 3510-2A(Revised 3-19) Page 29

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
NC0025534 City of Hendersonville WWTP OMB No.2040-0004
TABLE F.INDUSTRIAL DISCHARGE INFORMATION
Response space is provided for three Sills.Copy the table to report information for additional Sills.
SIU 4 SIU 5 SIU 6
Under what categories and subcategories is the 40 CFR 433 Metal Finishing N/A N/A
SIU subject?
Has the POTW experienced problems(e.g.,
upsets, pass-through interferences)in the past 4.5 ❑ Yes ❑✓ No ❑ Yes © No ❑ Yes ❑✓ No
years that are attributable to the SIU?
If yes,describe. New permitted user-in the process of
installing pretreatment equipment.No
upsets at the WWTP have occured because
of this facility.However they have caused
SSO's,as well as regularly in non
compliance with their permitted
wastewater levels.
EPA Form 3510-2A(Revised 3-19) Page 30

EPA Identification Number NPDES Number Facility Name Outfall Number
NC0025534 City of Hendersonville WWTP 1
Method Number Estimated Concentration (If
Pollutant(Required) CAS number (if Applicable) Reason Pollutant Believed Present in Discharge Known)
No change anticipated