WQ0032016_Groundwater Moniotring Report July 2022_20220831

GW-59A COMPLIANCE REPORT FORM Permit # 3 Z 0 l
(Submit one each moniforing period with GW-59 forms.)
1
Enter date monitoring results were due. (__8L5LL22 Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
2
Was any required information missing on the GW-59 report forms?
YES
NO
1F the answer to question I or 2 is "YES'; list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? If the answer is "Yes", contact the Regional Office for guidance.
4
Are any monitored constituents equal to or above the established standards?
YES
NO
If the answer to question 4 is 'WO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below:
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is 'WO", skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years).
Nt W Z p H 5.5
PAW3 F� 7t.5; MP7 0.&56
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
If the answer to question 7 is "YES" describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days: an evaluation may be
required to determine the imj3act the waste disposal s stem is having of the review and compliance
boundaries surroundina this facility, Failure to do so may sub'ect the permittee to a Notice of Violation
fines andlor Penalties.
g
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current G W-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report (Compliance Report GW-59A) is true and complete to the best of my knowledge.
Signature of Permittee (or Authorized Agent) Date
GW-59A 1218I2003

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY • DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION PteaseP7ntClearly orType
PERMIT Number: Expiration Date: 6130/2028
Facility Name: Rose Hili Plantation Development, Li
Non -Discharge LIIC
Permit Name (if different):
NPDES Other W00032016
Facility Address: 3041 New Leicester Highway
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Leicester NC 28748 County Buncombe
❑ Spray Field ❑ Remediation:
Contact Person: Bob Barr
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Well # 1(MW A on GW-1b)
No. of wells to be sampled: 3
❑ Water Source Heat Pump ❑■ Other: Surface Irrigation
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): Weil # 1 Upgradient
Date sample collected: 7/22/2022
FIELD ANALYSES:
WAS
Well Depth: 69 ft,
Well Diameter: 2 in.
pH 00400: 5.6 units Temp. 000lo: 20.8 °C
DRY at
Depth to Water Level 82545: 34.24 ft, below measuring point Screened Interval: 49 ft.
to 69
ft. Spec. Cond. 00094: 61.9 pMhos
time of sampling,
Measuring Point is 2.5 ft. above land surface
Relative M.P. Elevation:
ft.
Odor cooe5: None
check
Volume of water pumped/bailed before sampling:
gallons
Appearance Ciear
here:❑
Samples for metals were collected unfiltered: K YES
❑ NO and field acidified: 0 YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 81812022
Laboratory Name: Pace Analytical
Certification No. 40
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00333 mg/L
Nitrite (i as N oo615 <0,04C
mg/L Pb -Lead o1a5t <5.0 ugi
Coliform: MF Fecal 31616 1 11OOmL
Nitrate (i as N 00620 <0,040
ni Zn -Zinc 01092 <10.0 mg/L
Coliform: MF Total 31504 11OOmL
Phosphorus: Total as P oa6ss 0.067
ni
(Note: use MPN method for highly lurbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 703oo 67.0 ni
All - Aluminum o11o5
mg/L
pH (Lab) 00403 units
Ba - Barium oto07 20.1
ug/L
TOC oosso <1.0 mg/L
Ca - Calcium cogls
ni
Chloride 00940 <1.0 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 <10.0 ug/L
Chromium: Total 01034 8.6
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042 <5.0
mg/L ORGANICS: (by GC, GCIMS, Hi
Phenol 32730 ug/L
Fe - Iron 01045 474
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 ni
Hg - Mercury 71900
ug/L
Lab Report Attached? ❑ Yes (1) ❑■ No (0)
pecific Conductance 00095 pi
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia o0610 <0.10 mglL
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen: NH, as N: Ammonia Nitrogen, Total)
Mn - Manganese o1o55 9.3
ug/L
, method #
TKN as N 0062s mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: ni VOC Removal% ---
Robert P. Barr I Authorized Agent
Permittee for Authorized Agent) Narne and Title - Please print or type
M.
Signature of Permittee (or Authorized Agent)
3 1
(Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
•
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
• • •
•
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION Please PnnfClearryorType
PERMIT Number: Expiration Date: 6/30/2025
Facility Name: Rose HiII Plantation Development, LLC
Non -Discharge UIC
Permit Name (if different):
NPDES Other WQ0032016
Facility Address: 3041 New Leicester Highway
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Leicester NC 28748 County Buncombe
❑ Spray Field ❑ Remediation:
Contact Person: Bob Barr
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Well # 2(MW B on GW-1 b)
No. of wells to be sampled: 3
❑ Water Source Heat Pump ❑■ Other: Surface Irrigation
Eram Permit
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): Well # 2 downgradient
Date sample collected: 7/22/2022
FIELD ANALYSES:
WAS
Well Depth 30 ft.
Well Diameter: 2 in.
pH 00400: 5.3 units Temp. ooala: 17•6 °C
DRY at
Depth to Water Level 82546: 12,29 ft. below measuring point
Screened Interval: 10 ft. to
30
--
ft. Spec. Cond. 00094: 40.0 uMhos
time of
sampling,
Measuring Point is 2.5 ft. above land surface
Relative M.P. Elevation: ft.
Odor aooa5: None
check
Volume of water pumped/bailed before sampling:
gallons
Appearance Clear
here:❑
Samples for metals were collected unfiltered: 0 YES
❑ NO and field acidified: ❑■ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 8/8/2022
Laboratory Name: Pace Analytical
Certification No, 40
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mglL
Nitrite (NOz) as N o0615 <0.040
mg1L Pb - Lead o1c5i <5.0 ug/L
Coliform: MF Fecal 31616 <1 1100mL
Nitrate (NO3) as N e0620 0.52
mglL Zr -Zinc 01092 <10.0 mgi
Coliform: MF Total 31504 1100mL
Phosphorus: Total as P 00665 <0.050
mglL
(NoteUse MPN method for highly turbid samples)
Orthophosphate 70507
mglL Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 <25 mglL
Al - Aluminum 01195
mglL
pH (Lab) 00403 units
Ba - Barium 01007 29.7
ug1L
TOC 00680 <1.0 ni
Ca - Calcium 00916
mg1L
Chloride 00940 2.3 mglL
Cd - Cadmium 01027
ugi
Arsenic 01002 <10.0 uglL
Chromium: Total 01034 <5.0
uglL
Grease and Oils 00552 mglL
Cu - Copper 01042 <5.0
mglL
ORGANICS: (by GC, GCIMS, HPLC)
Phenol 32730 uglL
Fe - Iron 01045 398
uglL
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mglL
Hg - Mercury 71900
uglL
Lab Report Attached? ❑ Yes (1) ❑■ No (0)
Specific Conductance oao95 iumhos
K - Potassium 00937
mglL VOC 7873 method #
Total Ammonia oo610 <0.10 mglL
Mg - Magnesium 00927
mglL method #
(Ammonia Nitrogen, NH, as N, Ammonia Nitrogen, Total)
Mn - Manganese 01055 7.7
ug/L
method #
TKN as N 00625 ni
Ni - Nickel 01067
uglL
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mglL Effluent Total VOCs: mglL VOC Removal%
Permittee (or Authorized Agent) Name and Title - Please print or type Signature of Permittee (or Authorized Agent) (Date)
GW-59 Rev.06-07.2018

SUBMIT FORM ON YELLOW PAPER ONLY
a .
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
a a �
a
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699.1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 6/30/2028
Facility Name: Rase Hitl Plantation Development,
LLC
Non -Discharge UIC
NPDES Other WQ0032016
Permit Name (if different):
Facility Address: 3041 New Leicester Highway
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Leicester NC 28748 County Buncombe
❑ Spray Field ❑ Remediation:
Contact Person: Bob Barr
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Welf # 3
No. of wells to be sampled: 3
❑ Water Source Heat Pump ❑■ Other: Surface Irrigation
from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): Well # 3
Date sample collected: 7/22/2022
FIELD ANALYSES:
WAS
Well Depth: 14 ft.
Well Diameter: 2 in.
pH 00400: 6.6 units Temp. 000lo: 27-0 °C
DRY at
Depth to Water Level 62546: 4-81 ft. below measuring point Screened Interval: 4 ft. to
14
ft. Spec. Cond. 00094: 129.9 µMhos
time of
sampling,
Measuring Point is 0 ft. above land surface
Relative M.P. Elevation: ft.
Odor 00086: None
check
Volume of water pumpedlbailed before sampling:
gallons
Appearance Murky
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 31814022
Laboratory Name: Pace Analytical
Certification No. 40
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg1L
Nitrite (NO2) as N oo615 <0.040
mglL
Pb- Lead a1a51 10.8 ug1L
Coliform: MF Fecal 31616 2.0
1100ML
Nitrate (NO3) as N 00620 <0.062
mglL Zn -Zinc 01o92 71.1 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P oo66s 2.3
mglL
(Nate-. Use MPN method for highly turbid samples)
Orthophosphate 70507
mglL Other (Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 70.
mglL
Al -Aluminum 01105
ni
pH (Lab) 00403
units
Ba - Barium 01007 294
ug1L
TOC m6m <1.0
mglL
Ca - Calcium oo916
mglL
Chloride 00940 3-8
mglL
Cd - Cadmium 01027
uglL
Arsenic 01002 <10.0
uglL
Chromium: Total 01034 44.1
uglL
Grease and Oils o0552
mglL
Cu - Copper 01042 11.3
mglL
ORGANICS: (by GC, GCIMS, HPLC)
Phenol 32730
uglL
Fe - Iron 01045 71300
uglL
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mglL
Hg - Mercury 71900
uglL
Lab Report Attached? ❑ Yes (1) 0 No (0)
Specific Conductance 00095
ttMhos
K - Potassium 00937
mglL
VOC 7873 method #
Total Ammonia oo610 <0.10
mglL
Mg - Magnesium 00927
mglL
method #
(Ammonia Nitrogen: NH, as N: Ammonia Nitrogen, Total)
Mn - Manganese o1055 656
11
, method #
TKN as N 00625
mglL
Ni - Nickel 01067
uglL
method #
RemediationFor Only Reports): _ •
I certify that. to the best of my knowledge and belief, the information submitted in this report is true, acCL
DWR-certified laboratory. I am aware that there are significant penalties for submitting false information
Robe Authorized Agent
Perri (or Authorized Agent) Name and Title - Please print or type
GW-59 Rev.06-07-2018
mg/L Effluent Total a
1plete, and that the laboratory analytical data was produ+
possibility of fines and imprisonment for knowing violati
mglL VOC Removal%
(uate)

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Rose Hill MW 7/22
Pace Project No.: 92616363
Sample: MWA Lab ID: 92616363001 Collected: 07/22/22 09:50 Received: 07/22/22 15:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
08/08/22 10:23
Collected By
S.Warlick
1
08/08/22 10:23
Collected Date
7/22122
1
08/08/22 10:23
Collected Time
09:50
1
08/08/22 10:23
pH
5.6 Std. Units
1
08/08/22 10:23
Temperature
20.8 deg C
1
08/08/22 10:23
Static Water Level
34.24 feet
1
08/08/22 10:23
Specific Conductance
61.9 umhos/cm
1
08/08/22 10:23
Oxygen, Dissolved
4.7 mg/L
1
08/08/22 10:23
7782-44-7
Total Well Depth
69.0 feet
1
08/08/22 10:23
REDOX
103.9 my
1
08/08/22 10:23
Turbidity
9.8 NTU
1
08/08/22 10:23
Odor
None
1
08/08/22 10:23
Appearance
Clear
1
08/08/22 10:23
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4
1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
Arsenic
ND ug/L
10.0
1
08/02/2219:05
08/03/2218:13
7440-38-2
Barium
21.0 ug/L
5.0
1
08/02/2219:05
08/03/2218:13
7440-39-3
Chromium
8.6 ug/L
5.0
1
08/02/2219:05
08/03/2218:13
7440-47-3
Copper
ND ug/L
5.0
1
08/02/2219:05
08/03/2218:13
7440-50-8
Iron
474 ug/L
50.0
1
08/02/2219:05
08/03/2218:13
7439-89-6
Lead
ND ug/L
5.0
1
08/02/2219:05
08/03/2218:13
7439-92-1 BC
Manganese
9.3 ug/L
5.0
1
08/02/2219:05
08/03/2218:13
7439-96-5
Zinc
ND ug/L
10.0
1
08/02/2219:05
08/03/2218:13
7440-66-6
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
67.0 mg/L
25.0
1
07/27/22 13:08
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL
1.0
1
07/22/22 16:30
07/23/22 16:58
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
08/03/22 12:35
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
ND mg/L
0.040
1
07/23/22 03:30
14797-55-8
Nitrogen, Nitrite
ND mg/L
0.040
1
07/23/22 03:30
14797-65-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/08/2022 10:28 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 24

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Rose Hill MW 7/22
Pace Project No.: 92616363
Sample: MWA
Lab ID: 92616363001 Collected: 07/22/22 09:50
Received: 07/22/22 15:50 Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed CAS No. Qual
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
0.067 mg/L 0.050 1
08/02/22 16:44 08/02/22 20:02 7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
ND mg/L 1.0 1
07/29/2214:31 16887-00-6
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
ND mg/L 1.0 1
07/26/22 16:52 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/08/2022 10:28 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 24

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Rose Hill MW 7/22
Pace Project No.: 92616363
Sample: MW-2 Lab ID: 92616363002 Collected: 07/22/22 13:10 Received: 07/22/22 15:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
08/08/22 10:24
Collected By
S.Warlick
1
08/08/22 10:24
Collected Date
7/22122
1
08/08/22 10:24
Collected Time
13:10
1
08/08/22 10:24
pH
5.3 Std. Units
1
08/08/22 10:24
Temperature
17.6 deg C
1
08/08/22 10:24
Static Water Level
12.29 feet
1
08/08/22 10:24
Specific Conductance
40.0 umhos/cm
1
08/08/22 10:24
Oxygen, Dissolved
1.7 mg/L
1
08/08/22 10:24
7782-44-7
Total Well Depth
30.0 feet
1
08/08/22 10:24
REDOX
121.1 my
1
08/08/22 10:24
Turbidity
8.7 NTU
1
08/08/22 10:24
Odor
None
1
08/08/22 10:24
Appearance
Clear
1
08/08/22 10:24
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4
1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
Arsenic
ND ug/L
10.0
1
08/02/2219:05
08/03/2218:16
7440-38-2
Barium
29.7 ug/L
5.0
1
08/02/2219:05
08/03/2218:16
7440-39-3
Chromium
ND ug/L
5.0
1
08/02/2219:05
08/03/2218:16
7440-47-3
Copper
ND ug/L
5.0
1
08/02/2219:05
08/03/2218:16
7440-50-8
Iron
398 ug/L
50.0
1
08/02/2219:05
08/03/2218:16
7439-89-6
Lead
ND ug/L
5.0
1
08/02/2219:05
08/03/2218:16
7439-92-1 BC
Manganese
7.7 ug/L
5.0
1
08/02/2219:05
08/03/2218:16
7439-96-5
Zinc
ND ug/L
10.0
1
08/02/2219:05
08/03/2218:16
7440-66-6
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
ND mg/L
25.0
1
07/27/22 13:08
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL
1.0
1
07/22/22 16:30
07/23/22 16:58
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
08/03/22 12:37
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
0.52 mg/L
0.040
1
07/23/22 03:34
14797-55-8
Nitrogen, Nitrite
ND mg/L
0.040
1
07/23/22 03:34
14797-65-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/08/2022 10:28 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 24

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Rose Hill MW 7/22
Pace Project No.: 92616363
Sample: MW-2
Lab ID: 92616363002 Collected: 07/22/22 13:10
Received: 07/22/22 15:50 Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed CAS No. Qual
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L 0.050 1
08/02/22 16:44 08/02/22 20:19 7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
2.3 mg/L 1.0 1
07/29/2214:00 16887-00-6
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
ND mg/L 1.0 1
07/26/22 17:09 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/08/2022 10:28 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 24

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Rose Hill MW 7/22
Pace Project No.: 92616363
Sample: MW-313 Lab ID: 92616363003 Collected: 07/22/22 14:50 Received: 07/22/22 15:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
08/08/22 10:25
Collected By
S.Warlick
1
08/08/22 10:25
Collected Date
7/22122
1
08/08/22 10:25
Collected Time
14:50
1
08/08/22 10:25
pH
6.6 Std. Units
1
08/08/22 10:25
Temperature
27.0 deg C
1
08/08/22 10:25
Static Water Level
4.81 feet
1
08/08/22 10:25
Specific Conductance
129.9 umhos/cm
1
08/08/22 10:25
Oxygen, Dissolved
1.1 mg/L
1
08/08/22 10:25
7782-44-7
Total Well Depth
13.52 feet
1
08/08/22 10:25
REDOX
47.7 my
1
08/08/22 10:25
Turbidity
90.5 NTU
1
08/08/22 10:25
Odor
None
1
08/08/22 10:25
Appearance
Murky
1
08/08/22 10:25
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4
1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
Arsenic
ND ug/L
10.0
1
08/02/2219:05
08/03/2218:20
7440-38-2
Barium
294 ug/L
5.0
1
08/02/2219:05
08/03/2218:20
7440-39-3
Chromium
44.1 ug/L
5.0
1
08/02/2219:05
08/03/2218:20
7440-47-3
Copper
11.3 ug/L
5.0
1
08/02/2219:05
08/03/2218:20
7440-50-8
Iron
71300 ug/L
50.0
1
08/02/2219:05
08/03/2218:20
7439-89-6
Lead
10.8 ug/L
5.0
1
08/02/2219:05
08/03/2218:20
7439-92-1 BC
Manganese
656 ug/L
5.0
1
08/02/2219:05
08/03/22 18:20
7439-96-5
Zinc
71.1 ug/L
10.0
1
08/02/2219:05
08/03/2218:20
7440-66-6
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
70.0 mg/L
25.0
1
07/27/22 13:08
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
2.0 CFU/100 mL
1.0
1
07/22/22 16:45
07/23/22 16:58
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
08/03/22 12:41
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
ND mg/L
0.040
1
07/23/22 03:35
14797-55-8
Nitrogen, Nitrite
0.062 mg/L
0.040
1
07/23/22 03:35
14797-65-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/08/2022 10:28 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 24

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Rose Hill MW 7/22
Pace Project No.: 92616363
Sample: MW-313
Lab ID: 92616363003 Collected: 07/22/22 14:50
Received: 07/22/22 15:50 Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed CAS No. Qual
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
2.3 mg/L 0.050 1
08/02/22 16:44 08/02/22 20:25 7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
3.8 mg/L 1.0 1
07/29/2214:01 16887-00-6
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
ND mg/L 1.0 1
07/26/22 17:58 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/08/2022 10:28 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 24

Pace Analytical Services, LLC
leac,yficalAnal2225 Riverside Dr.
Asheville, NC 28804
www.pacelabs.com [phone]
QUALIFIERS
Project: Rose Hill MW 7/22
Pace Project No.: 92616363
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
BC The same analyte was detected in an associated blank at a concentration above 1/2 the reporting limit but below the
laboratory reporting limit.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/08/2022 10:28 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 24

CHAIN -OF -CUSTODY ! Analytical Request Document
ace The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Submitting a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace Terms and Conditions found at https:t/info.pacelabs.com/hubfs/pas-standard-terms.pdf.
pecTron ra Section U Section C
Required Client Information: Required Project Information: Invoice Information: Pa e - 1 Of
3
Company: RPB Systerl Inc. Report To: Robert Garr Attention:
Al P.O, Box 1325 Copy To: Company Name:
Asheville NC 28802 Address: Re ulato A en
Email: rbarr@rpbsystems-corn
Purchase Order #:
Pace Quote:
Phone: [phone] Fax
Project Name: Rose HIII MW
Pace Project Manager; [e-mail],
State I Location
Requested Due Date: Project #:
Pace
Profile #: 2315
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Requested
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SAMPLE CONCIYIONS
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leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
August 08, 2022
Kimber Reese
RPB Systems Inc.
P.O. Box 1325
Asheville, NC 28802
RE: Project: Rose Hill MW 7/22
Pace Project No.: 92616363
Dear Kimber Reese:
Enclosed are the analytical results for sample(s) received by the laboratory on July 22, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
(Z/� ` -
Lord Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
cc: Mr. Robert Barr, RPB Systems Inc.
Ms. Liz Barr, RPB Systems Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 24

1a6)�s0
U4c4menl N9mc: Flelsi data Sheet
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Welllnformatim Date: 7fZgf-z2 By RMJ
Well ID: _ JPA Q/_Well Locked: Y / NO Fluslunqunt )
Well Diameter: Construction: (W /Steel/Stainless Steel)
Total Well Depth; Mu1tl Ractm*: (lQ ft(Radtlus/12)2x:3.14x 7.4s)
Static Water Level: � 2.' it Casing Volume: , 6-7 gallons
Helol t of Water Column: 7faft Co. � Volumes; I ,qR .gallons
Pump Intake: 6% ^ . ft
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Date Purged,_,/ 7?./ 2~_._Start:.��.:Pinish- PurgoRate: i,)13
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