WQ0028693_Groundwater Monitoring Report July 2022_20220831

GW-59A COMPLIANCE REPORT FORM Permit # VV O 00 28 6 q -5
(Submit one each monitoring period with CN'=59 forms.)
j
Enter date monitoring results were due. ( 3! Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
V
2
Was any required information missing on the GW-59 report forms?
YES
NO.
IF the answer to question 9 or 2 is "YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? If the answer is "Yes", contact the Regional Office for guidance.
4
Are any monitored constituents equal to or above the established standards?
YES
NO
If the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituents) and concentration(s)
exceeding standards in the space provided below:
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is "NO", skip to section 8.
If the answer to question 5 is "YES"' list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years).
tV s,R PF4 5-
MV2 pH 5.82-
M W -3 P H 5."
Are the monitoring"wells listed in section 5 located at or beyond the review boundary?
YES
NO
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days,; an evaluation may be
required to determine the impact the waste disposal, system is having at the review and compliance
boundaries surrounding this facility, Failure to do so maX subject the permittee to a Notice of Violation
fines, and/or penalties.
S
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current G W-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report (Compliance Report GW-59A) is true and complete to the best of my knowledge.
vvk�- d 31-2Z
Signature of Permittee (or Authorized Agent) Date
GW-59A 12/8/2003

SUBMIT FORM ON YELLOW PAPER ONLY
a r
DEPARTMENT OF ENVIRONMENTAL. QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
a a a
1617 MAIL SERVICE CENTER, RALEIGH, NG 27699-1617
FACILITY INFORMATION
Please Pnnf Clearly or Type
PERMIT Number: Expiration Date: 4130/2025
Facility Name: Mountaintop Golf & Lake Club
Non -Discharge W00028693 UIC
Permit Name (if different): Mountaintop Community Association Inc
NPDES Other
Facility Address: P.O. Box 1460
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Cashiers NC 28717 County Jackson
❑■ Spray Field ❑ Remediation:
Contact Person: Bob Barr
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: MW-01 R
No. of wells to be sampled: 3
❑ Water Source Heat Pump ❑ Other:
(From Permit}
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-01R
Date sample collected: 7/21/2022
FIELD ANALYSES:
WAS
Well Depth: 26.6 ft.
Well Diameter: 2 in.
pH 00400: 5.65 units Temp. 00010: 15.3 -C
DRY at
Depth to Water Level e2546: 12.65 ft. below measuring point Screened Interval: 15.6 ft.
to 25.6
ft. spec. Cond. 000sa: 56.9 µMhos
time ofsampling,
Measuring Point is 0 ft. above land surface
Relative M.P. Elevation:
ft.
Odor o0085: None
check
Volume of water pumped/bailed before sampling:
gallons
Appearance Turbid
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed, 813/2022
Laboratory Name: Pace Analytical
Certification No. 40
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mgi
Nitrite (NO2) as N oo615
mglL
Pb - Lead o1051 ug/L
Coliform: ME Fecal 31616 <1
1100mL
Nitrate (NO3) as N 00620 0.13
mglL
Zn - Zinc 01092 ni
Coliform: MF Total 31504
1100mL
Phosphorus: Total as P 00665 0.84
mglL
(Notes use MPN method for highly turbid Samples)
Orthophosphate 70507
mglL
Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 54.0
1mg1L
Al - Aluminum o11o5
mglL
pH (Lab) 00403
units
Ba - Barium 01007
uglL
TOC 00680 2.7
ni
Ca - Calcium 00916
mglL
Chloride OD940 4.0
mglL
Cd - Cadmium 01027
ugi
Arsenic 01002
uglL
Chromium: Total 01034
uglL
Grease and Oils 00552
mglL
Cu - Copper a1042
mglL
ORGANICS: (by GC, GCIMS, HPLC)
Phenol 32730
uglL
Fe - Iron 01045
uglL
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mglL
Hg - Mercury 71900
uglL
Lab Report Attached? ❑ Yes (1) ❑■ No (0)
Specific Conductance 00095
pMhos
K - Potassium 00937
mglL
VOC 7873 method #
Total Ammonia o0610 0.14
mglL
Mg - Magnesium 00927
ni
method #
(Ammonia Nitrogen: NH, as N: Ammonia Nitrogen, Total)
Mn -Manganese Dross
uglL
,method #
TKN as N 00625
mglL
Ni - Nickel 01067
ug1L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mglL Effluent Total VOCs: mglL VOC Removal%
Robert P. Barr 1 Authorized Agent
Permittee (or Authorized Agent} Name and Title - Please print or type
Y �_
Signature of Permittee (or Authorized Agent)
n-3�-ZZ
(Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617MAIL SERVICE CENTER, RALEIGH,127699.1617
FACILITY INFORMATION
Please PnntCfeartyorType
PERMIT Number: Expiration Date: 4/3012025
Facility Name: Mountaintop Golf & Lake Club
Non -Discharge WQ0028693 UIC
Permit Name (if different): Mountaintop Community Association Inc
NPDES Other
Facility Address: P.O. Box 1480
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Cashiers NC 28717 County Jackson
❑■ Spray Field ❑ Remediation:
Contact Person: Bob Barr
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: MW-2
No. of wells to be sampled: 3
❑ Water Source Heat Pump ❑ Other:
(from Permit}
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-2
Date sample collected: 7/21/2022
FIELD ANALYSES:
WAS
Well Depth: 42 ft.
Well Diameter: 2 in.
pH 00400: 5.82 units Temp. 00010: 13.9 °C
DRY at
Depth to Water Level 82546: 12,34 ft. below measuring point Screened Interval: 42 ft. to
32
ft. Spec. Cond. 00094 151.1 µMhos
time of
sampling,
Measuring Point is 0 ft. above land surface
Relative M.P. Elevation: ft.
Odor 000ae None
check
Volume of water pumpeWbailed before sampling:
gallons
Appearance Clear
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified? ❑■ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 8/3/2022
Laboratory Name: Pace Analytical
Certification No, 40
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N aos15
mglL Pb - Lead oiosi ug/L
Coliform: MF Fecal 31616 <1
1100mL
Nitrate (NO3) as N 00620 1,7
ni Zn - Zinc 01092 mglL
Coliform MF Total 31504
1100mL
Phosphorus: Total as P 00665 <0.50
ni
(Notes use MPN method for highly turbid samples)
Orthophosphate 70507
mglL Other (Specify Compounds and Concentration Units):
issolved Sclids:Total 70300 106
mg1L
Al - Aluminum 01105
mglL
pH (Lab) 00403
units
Ba - Barium 01007
uglL
TOC 00se0 1-2
mg1L
Ca - Calcium oos16
mglL
Chloride 00940 2-7
ni
Cd - Cadmium 01027
uglL
Arsenic 01002
uglL
Chromium: Total 01034
uglL
Grease and Oils 00552
mglL
Cu - Copper 01042
mglL
ORGANICS: (by GC, GCIMS, Hi
Phenol 32730
uglL
Fe - Iron 01045
uglL
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 719ou
uglL
Lab Report Attached? ❑ Yes (1) ❑f No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mglL
VOC 7873 method #
Total Ammonia omio <0.10
mglL
Mg - Magnesium 00927
mglL
method #
(Ammonia Nitrogen-, NH, as N, Ammonia Nitrogen, Total(
Mn - Manganese 01055
ug1L
, method #
Ti as N 00625
ni
Ni - Nickel 01067
ug1L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mglL Effluent Total VOCs: mg1L VOC Removal%
Permittee (or Authorized Agent) Name and Title - Please print or type
Signature of Permittee (or Authorized Agent)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27690-4617
FACILITY INFORMATION
ill PrfntCfeartyorType
PERMIT Number: Expiration Date: 4130/2025
Facility Name: Mountaintop Golf & Lake Club
Non -Discharge WQ0023693 UIC
NPDES Other
Permit Name (if different): Mountaintop Community Association Inc
Facility Address: P.O. Box 1460
TYPE OF PERMITTED OPERATION BEING MONITORED
Cashiers NC
28717 County Jackson
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑■ Spray Field ❑ Remediation:
Contact Person: Bob Barr
Telephone#: [phone]
ElRotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: MW-3
No. of wells to be sampled:
3
❑ Water Source Heat Pump ❑ Other:
(trom Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-3
Date sample collected: 7/21/2022
FIELD ANALYSES:
WAS
Well Depth: 160 ft.
Well Diameter: 4
in.
pH 00400: 5.99 units Temp. 00010: 118.2 °C
DRY at
Depth to Water Level 82546: 13.77 ft. below measuring point Screened Interval:
ft. to _ft.
Spec. Cond. 00094: 82-4 µMhos
time ofsampling,
Measuring Point is o ft. above land surface
Relative M.P. Elevation:
ft.
Odor 00085: None
check
Volume of water pumped/bailed before sampling:
gallons
Appearance Clear
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES
❑ NO
LABORATORYINFORMATION
Date sample analyzed 813/2022
Laboratory Name: Pace Analytical
Certification No. 40
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mglL
Nitrite (NO2) as N oo615
mglL
Pb - Lead o1a51 uglL
Coliform: MF Fecal 31616
110l
Nitrate (NO3) as N 00620 0.40
mg1L
Zn -Zinc 01092 mg1L
Coliform: MF Total 31504
110l
Phosphorus: Total as P ooss5 �0.50
mg1L
(Note: use WIN method for highly turbid samples)
Orthophosphate 70507
mglL
Other (Specify Compounds and Concentration Units)
issolved Solids:Total 70300 50.0
r lL
Al - Aluminum o1105
mglL
PH (Lab) 00403
units
Ba - Barium 01007
ug1L
TOC oosso <1A
mglL
Ca - Calcium 00916
mg1L
Chloride 00940 3.2
mglL
Cd - Cadmium 01027
uglL
Arsenic 01002
ug1L
Chromium: Total 01034
uglL
Grease and Oils 00552
mglL
Cu - Copper 01042
mg1L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
uglL
Fe - Iron 01045
uglL
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
rri
Hg - Mercury 71900
uglL
Lab Report Attached? ❑ Yes (1) ❑■ No (0)
Specific Conductance 000se
µMhos
K - Potassium 00937
mglL
VOC 7873 method #
Total Ammonia 00610 <0-10
mglL
Mg - Magnesium 00927
mglL
method #
(Ammonia Nitrogen: NH,asN; Ammonia Nitrogen, Total)
Mn - Manganese o1055
uglL
method #
TKN as N 00625
mglL
Ni - Nickel 01067
uglL
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mglL Effluent Total VOCs: mglL VOC Removal%
Robert P. Barr I Authorized Agent
Permittee (or Authorized A9en1) Name and Title - Please print or type
3/ 2L-
Signature of Permittee (or Authorized Agent) (Date)
GW-59 Rev.06-07-2018

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Mountain Top MW 7/21
Pace Project No.: 92616213
Sample: MW-01R Lab ID: 92616213001 Collected: 07/21/22 13:00 Received: 07/21/22 16:22 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
08/02/22 16:48
Collected By
M.Swann
1
08/02/22 16:48
Collected Date
7/21/22
1
08/02/22 16:48
Collected Time
13:00
1
08/02/22 16:48
pH
5.65 Std. Units
1
08/02/22 16:48
Temperature
15.3 deg C
1
08/02/22 16:48
Static Water Level
12.65 feet
1
08/02/22 16:48
Specific Conductance
59.9 umhos/cm
1
08/02/22 16:48
Oxygen, Dissolved
4.88 mg/L
1
08/02/22 16:48
7782-44-7
Total Well Depth
25.6 feet
1
08/02/22 16:48
REDOX
-161.6 my
1
08/02/22 16:48
Turbidity
496 NTU
1
08/02/22 16:48
Odor
None
1
08/02/22 16:48
Appearance
Turbid
1
08/02/22 16:48
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
54.0 mg/L 25.0
1
07/26/22 10:53
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation Method:
SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL 2.0
2
07/21/22 17:02 07/22/22 15:50
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
0.14 mg/L 0.10
1
08/03/22 11:23
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
ND mg/L 0.040
1
07/22/22 01:33
14797-55-8
Nitrogen, Nitrite
0.096 mg/L 0.040
1
07/22/22 01:33
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
0.84 mg/L 0.050
1
08/01/22 17:51 08/01/22 20:05
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
4.0 mg/L 1.0
1
07/29/2213:53
16887-00-6
5310B TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
2.7 mg/L 1.0
1
07/26/22 15:55
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/03/2022 04:13 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 18

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Mountain Top MW 7/21
Pace Project No.: 92616213
Sample: MW-2 Lab ID: 92616213002 Collected: 07/21/22 12:35 Received: 07/21/22 16:22 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
08/02/22 16:49
Collected By
M.Swann
1
08/02/22 16:49
Collected Date
7/21/22
1
08/02/22 16:49
Collected Time
12:35
1
08/02/22 16:49
pH
5.82 Std. Units
1
08/02/22 16:49
Temperature
13.9 deg C
1
08/02/22 16:49
Static Water Level
12.34 feet
1
08/02/22 16:49
Specific Conductance
151.1 umhos/cm
1
08/02/22 16:49
Oxygen, Dissolved
5.11 mg/L
1
08/02/22 16:49
7782-44-7
Total Well Depth
160.0 feet
1
08/02/22 16:49
REDOX
-172.3 my
1
08/02/22 16:49
Turbidity
0.52 NTU
1
08/02/22 16:49
Odor
None
1
08/02/22 16:49
Appearance
Clear
1
08/02/22 16:49
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
106 mg/L 25.0
1
07/26/22 10:53
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation Method:
SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL 1.0
1
07/21/22 17:02 07/22/22 15:50
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
08/03/22 11:24
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
1.7 mg/L 0.040
1
07/22/22 01:31
14797-55-8
Nitrogen, Nitrite
ND mg/L 0.040
1
07/22/22 01:31
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L 0.050
1
08/01/22 17:51 08/01/22 20:08
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
2.7 mg/L 1.0
1
07/29/2213:56
16887-00-6
5310B TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
1.2 mg/L 1.0
1
07/26/22 16:13
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/03/2022 04:13 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 18

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Mountain Top MW 7/21
Pace Project No.: 92616213
Sample: MW-3 Lab ID: 92616213003 Collected: 07/21/22 11:35 Received: 07/21/22 16:22 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
08/02/22 16:51
Collected By
M.Swann
1
08/02/22 16:51
Collected Date
7/21/22
1
08/02/22 16:51
Collected Time
11:35
1
08/02/22 16:51
pH
5.99 Std. Units
1
08/02/22 16:51
Temperature
18.2 deg C
1
08/02/22 16:51
Static Water Level
13.77 feet
1
08/02/22 16:51
Specific Conductance
82.4 umhos/cm
1
08/02/22 16:51
Oxygen, Dissolved
5.84 mg/L
1
08/02/22 16:51
7782-44-7
Total Well Depth
33.77 feet
1
08/02/22 16:51
REDOX
-128.6 my
1
08/02/22 16:51
Turbidity
4.76 NTU
1
08/02/22 16:51
Odor
None
1
08/02/22 16:51
Appearance
Clear
1
08/02/22 16:51
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
50.0 mg/L 25.0
1
07/26/22 10:53
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation Method:
SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL 1.0
1
07/21/22 17:02 07/22/22 15:50
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
08/03/22 11:25
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
0.40 mg/L 0.040
1
07/22/22 01:27
14797-55-8
Nitrogen, Nitrite
ND mg/L 0.040
1
07/22/22 01:27
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L 0.050
1
08/01/22 17:51 08/01/22 20:08
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
3.2 mg/L 1.0
1
07/29/2213:56
16887-00-6
5310B TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
ND mg/L 1.0
1
07/26/22 16:32
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/03/2022 04:13 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 18

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Project: Mountain Top MW 7/21
Pace Project No.: 92616213
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/03/2022 04:13 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 18

00
CHAIN -OF -CUSTODY if Analytical Request Document
ace The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be Completed accurately,
Submitting a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace Terms and Conditions found at https:/iinfo.pacelabs.com/hubfslpas-standard-terms.pdf.
SeCbOn A Section B Section C
Required Client Information: Required Project Information: Invoice Information: Page: 1 Of 1
Company, RPB Systems Inc. Report To: Robert Barr Attention,
Address: P,O, Box 1325 Copy To Company Name:
Asheville, NC 28802
Address:
Re Mato A enc
Email: rbarr@rpbsystems,corn
Purchase Order #:
Pace Quote:
Phone[phone] JFax
Project Name_ Mountain Top MWs
Pace Project Manager: lorri.patton@pacelahs,corn
State I Location
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leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
August 03, 2022
Kimber Reese
RPB Systems Inc.
P.O. Box 1325
Asheville, NC 28802
RE: Project: Mountain Top MW 7/21
Pace Project No.: 92616213
Dear Kimber Reese:
Enclosed are the analytical results for sample(s) received by the laboratory on July 21, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
(Z/� ` -
Lord Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
cc: Mr. Robert Barr, RPB Systems Inc.
Ms. Liz Barr, RPB Systems Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 18

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