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HomeMy WebLinkAboutWQ0033677_Groundwater Monitoring Report November 2020_20201229I. vy :;(�IJ'ig le1IWw1C ,-i.�.h'A7f 1"WIP'109 #-fclk-007 (.Snbrrnr one end revnnlmrlogo. hid,rilh Cn 59fottvu.) Y Enter date monitoring results we re due. ) Will this monitoring report(GW-59 and GW59A) YES NO be submitted after the established due date? i Was any required information missing on tkeGW-59 report forma? YES NO IF the answer to question I or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrowq etc.)? Iftlre nnswer is "Yes", contact the Regional Ofcafm guidance. 4 Are any monitored constituents equal to or above the established standards? YES N Il the answer to question 4 is "NO", skip to section 8. If the answer to question 4 is "YES"list the affected wells individually with constituent(s) and concentmtion(s) exceeding standards in the space provided below. g For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constiluent(s) in the same well(s) in the last two years? ll the answer to question 5is °NO; skip to section 8. If the answerto question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (!or the last two years). Are the monitoring wells listed in section 5located at or beyond the review boundary? YES NO If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMED/A TELY FOR GUIDANCE. If the answer is "AID ", monitoring wells may be improperly located; contact the Regional Office. Is the penalties Implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? If the answer fo question 7 is "YES'; describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 dayluation may b required to deteninhu, the impact the to offspesealsystem ishaving at the and compflanc boundaries surroundingthis l 'hit Failure to do 6' ct the a 'tte to a Notice fViolation, floes, and/or penalties g The person completing this portion(GW-59A)ofthe monitoring report should sign below antlsubmit this form with GW-59 forms tbrrequlrod wells M the address provided at the top of the current GW-59 form. I hereby acknowledge that the above information was evaluated and the Information submitted in this report (Complier ee ReportGWJJ/5rr��11I9A) is true and complete to the best of m��y�� knowledge. Signature f ermlttmpv Authorlmii Agent) iDa[e GW-59A 12/9/2003 @.. a.v E E .2 V �. 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GRANITE FALLS, NORTH CAROLINA 28630 (828)396-4444 SAMPLE: Case Farms -Hatchery COLLECTION DATE.., 11/18/2020 PERMIT A COLLECTION TIME: 14:45 ADDRESS: Case Farms Hatchery RECEIVED DATE: 11/18/2020 RECEIVED TIME 15:15 REPORTED: 12/812020 ANALYSIS ANALYSIS EFFLUENT UNITS DATE ANALYST BOD 475 mg/L 11/19/20 jdg TSS 125 mg/L 11/20/20 jrg NH3 12.20 mg/L 11/20/20 jrg Fecal Coliform 1040 /100mL 11/18/20 Irg ConductlAty 722 umhos/cm 11/18/20 jrg NO3-N Ni�n°}�G <0.1 mg/L 12/4120 Jog TKN 68.0 mg/L 12/3/20 jdg T. Nitrogen 68.0 mg/L 12/4/20 jdg T. Phosphorus 7.63 rnyL 12/3/20 jdg Chlodde 44 mg/L 11/25/20 lag IDS 432 mglL 11/19/20 lag LOG ID: 2011-334 REPORTED BY:: @NC�CCERpTIFIED LAB # 50 �fm"-Pp Tony Gragg, Lab Supervisor firPace Anatyflcel8ervicae, LLC aceAnalyticai® m08 Kaemvllle, NO 272 Www.peoelebe.com 330A88-2841-R841 ANALYTICAL RESULTS Project Casa Fars Monitoring Pace Project No.: 92507318 Sample: Case Farms Monitoring Lab ID: U507318001 Collected: IIIIF2013:15 Received: 11/1912014:30 Matrlx: Water Well 93 Parameters Results Unite Report Lint DF Prepared Analyzed CAS No. Qual 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.41994 Preparatlon Method: EPA 200.7 Rev 4.41994 Pace Analytical Servicea -Asheville Arsenic ND mg/L 0.010 1 1210112001:66 12/01/2018:45 7440-38-2 Copper ND mull- 0.0050 1 12/0112001:66 12/012018:45 7440.50.8 Pat esalurn ND mg& 6.0 1 12/0112001:56 1210112018:46 7440.09-7 Sodlum 7.3 mg& 5.0 1 121012001:66 12101120 1 8:46 7440-235 Zinc NO mglL 0.010 1 12/0V2001:66 1210V2018: 5 7440.66.6 8260D MSV Low Level Analytical Method: EPA 8260D Pace Analytioal Servlces - Charlotte Acetone ND mg/L 0.026 1 11/2412019:30 67-64-1 Barreana ND mg/L 0.0010 1 111242019:30 71-43-2 Bromobenzene ND mg/L omlo 1 111242019:30 108-86-1 Bromochlommethane ND mglL 0.0010 1 112412D 19:30 7"7-5 Bromodlchlomme0mne ND mg1L 0.0010 1 11/24I201930 76-27-4 grue rm NO all 0,0010 1 112412019:30 75-26-2 Bromomathana ND mglL 0.0020 1 11/242019:30 74-835 2-Butarmna(MEK) ND neck 0.0050 1 1124/2019:30 78-93-3 Carbon tetrachloride ND mgl- 0.0010 1 IV24/2019:30 50-235 Chlombenzene ND mull- 0.0010 1 11124/2019:30 108.90-7 Chlomethene ND mall- 0.0010 1 11/242019:30 75-00-3 Chloroform ND mg/L 0.0060 1 11242019:31) 67-80-3 Chlommethana ND mg/L 0.0010 1 112412019:30 74-87-3 2-Chlorolcluane ND mg/L 0.0010 1 11242019:30 96.49-6 4-Chlorotoluene ND mg/L 0.0010 1 112412019:30 106-43.4 1,2-DlbmmoJ-ahlcropropano ND mglL 0.0060 1 111242019:30 96-12-8 Dlbromochloromethane ND mull- 0.0010 1 1112412019:30 12448.1 12-Dlbramce9-ana(EDE) ND mg)L 0,0010 1 1 IJ24120 19:30 106-e3-0 Dibmmomethane ND mull- 0,0010 1 11/242019:30 74-95-3 1,2-Dichlorobenzene ND mg/L 0.0010 1 111242019:30 96-50-1 1,3-Dichlombenzene ND mglL 0.0010 1 11/242019:30 641-73-1 1,4-Dichlombenzano ND mglL 0.0010 1 111242019:30 106.46-7 Dlohlorodl0uoromethene ND mat- 0.0010 1 111242019:30 76-71-8 1,1-Dichloroethane ND mWIL 0.0010 1 111242019:30 76-34-3 1,2.Dichloroethane ND mg/L 0.0010 1 11/2412019:30 107-06-2 1,1-Dichloroethane ND mglL 0.0010 1 11/242019:30 75-35.4 ds-1,2-Dichtoroathene ND mgc- 0.0010 1 11242019:30 16M5 2 tmnsA,2{nchlomelhene ND mg/L 0.0010 1 11242019:30 156-60-5 1,2-Dlchloropmparae ND all 0.0010 1 112412019:30 78-87-5 1,3-Dlchlompmpane ND mg/L 0.0010 1 11/2412019:30 142-28-9 2,2-Dlchloropropane ND mg/L 0.0010 1 1124/2019:30 594-20.7 1,1-Dichlaropropane ND mg/L 0.0010 1 11124/2019:30 563-58-6 cls-1,3 Dlchloropropens ND mglL 0,0010 1 111242019:30 10081-01-5 hans-1,3-Dichlompmpene ND mull- 0.0010 1 1112412019:30 10061-02-6 Dllaopropyl ether ND mgl- 0.0010 1 11/2412019:30 108-203 Ethyfberoene ND mg/L 0.0010 1 111242019:30 100-41-4 Hexechlom-1,3-butad1ene ND mgc- 0.0010 1 1112412019:30 87-683 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full. Date: 12128/202012:39 PM Wahoutthe Wduan consentof Peca Analytical Services,LLC. Page 4 of 38 Pace Analytical Sorolcas, LLC aceAnalytical a 1 loa 64 ed al, Kernerevlle, NC 272a4 WMpacalaEa.00m 336-996.2841 ANALYTICAL RESULTS Project: Case Farms Moellering Pace Project No.: 92507318 Sample: Case Farms Manlloring Lal 92507318001 Collected: 111482013:16 Racal 11119/2014:30 Matriz: Waler Well 83 Parameters Beaune Units Report Limit DF Prepared Analyzed CAS No. Duel 82600 MSV Low Laval Analytical Method: EPA 82600 Pece Analytical Services - Charlotte 2-Hexanone ND mg/L 0.0050 1 1112420 19:30 691-79-6 p-Isop opyltolueno ND mg l- 0.0010 1 112412019:30 9&87-8 Methylene Chloride ND r lL 0.0050 1 11242010:30 75-09.2 4-Methyl-2-penlancne(MIBK) ND mil 0.0050 1 11242019:30 108-10-1 Mefhld-ted-butyl ether ND mg/L 0.0010 1 1112412019:30 1634-044 Naphthalene ND all 0.0010 1 111242019:30 91-20-3 Styrene ND mg/L 0.0010 1 1112412019:30 100-424l 1,1,1,2-Tetmchleroemane ND mg/L 0.0010 1 1124/2019:30 630.20-6 1,1,2,2-Tetmchlomethane ND mg/L 0.0010 1 lI24/2019:30 7934-5 Tetmchloroethena ND mg8. 0.0010 1 11242019:30 127-16-4 Toluene ND ml 0.0010 1 11124201090 10&8&3 1,2,3-Trtahlarobemene ND ml 0.0010 1 111242019:30 87-61-e 1,2,44dchiombnecone ND ml 0.0010 1 11242019:30 12&82-1 1,1,1-TrIch1amethane ND mg/L 0.0010 1 111242019:30 71-55.6 1,1,2-Trichlomethane ND mg/L 0.0010 1 1112412019:30 79-00S Thom ... than. ND mg/L 0.0010 1 11/242019:30 79-01-6 Tichicrocuoromethme ND mg/L 0.0010 1 11/242019:30 75-694 1,2,3-Trlchloropropaee ND mg/L 0,0010 1 1M24/2019:30 98484 Vinyl acetate ND mg/L 0,0020 1 11/24/2D 19:30 108-05-4 Vinyl chloride ND all 0.0010 1 1M4/20 19:30 75-01-4 Xylene(Total) ND mg1L 0.0010 1 112412019:30 1330-20-7 map-Xylene ND all 0.0020 1 11242019:30 179601-23-1 o-Xylene ND mg/L 0.0010 1 112412019:30 96-47-6 Surrogates 4-Bromollucrobenzene(8) 103 % 70-130 1 11242019:30 460-004 1,2-Dichlomathul(S) ill % 70-130 1 11/242019:30 17060-07-0 Toluened8(S) 101 % 70-130 1 111242019:30 2037-26-5 5310B TOC Analytical Method: SM 531OB-2011 Pace Anaiyllcal Selvlcas -Asheville Total Organic Carbon ND mg/L 1.0 1 12r06/2007:41 7440-44-0 REPORT OF LABORATORYANALYSIS This rated shell not be lapmdused, except In full, Date: 12128/202012:39 PM without the antic, consent of Pace Anelyticel BeMeee,LLC. Page 5 of 38 Analytical Environmental Services, Inc Date: 28-D¢b-20 Client: Pace Analytical Services, Re. Client Sample ID: CASE FARMS MONITORING 1' PmjectName: 92507319 Collection Dale: 11/18120201:45:00 PM Lab ID: 2011048-003 - Monist Aqueous In-,. Reporting ...._, __a,_ __,_an_ Dliunnn .._._._.__. . Formaldehyde by SW8315A Formaldehyde Ijandaa: • v inn azrenh mmbnant—lano..lore able. oeaw repMlne limit to {blde, lmm fmpneema ab.—Iysa amoind N Ablybn.tN AC.,tiaed n Allelyle delooladia Ne anDDIIed mwM1M blank > Glan ',kno.1"alm BRL 0,050 IaalL 306232 1 1121202009:56 Ill. e SAmnlod h.luu.bnn nmlilnlnn tance s sylk.n.... n n:namn umlh duo to boar, No" noonat onwo It Avalyml In iM 16 wM.W.. doolan nfmm llw mgMd < Ian lMn...It vnl.. I mubonbnwab:n talemod bebw.epmun. until Page 34 of 38 Page a of 10 Pace Analytical Bervices, LLC acaAnalytical® 10 6d86 Kemersvll11le, NNC G227284 Www.pavolaEanom 336-966-2841 ANALYTICAL RESULTS Project Case Farm. Monitoring Pace Project No.: 92507318 Sample: Case Parma Monitoring Lab ID: 92507318001 Collected: 11118/2013:15 Received: 11119/2014:30 Mablx: Water Well 83 Parameters Results Unite Report Limit DP Prepared I Analyzed CAS No. Qual 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.41994 Preparation Method: EPA 200.7 Rev 441994 Pace Analytical Service. -Asheville Anemia NO mglL 0.010 1 1210112001:56 12/01t2018:46 7440-38-2 Copper NO mg/L 0.0060 1 1001/2001:66 12/012018:46 7440.50-8 potassium NO mglL 6.0 1 1210112001:65 1210112018:46 7440.09-7 Sodium 7.3 mg/L 6.0 1 1210I2001:66 12101/2018:46 7440-235 Zinc NO m0/L 0.010 1 1210112001:66 1210112018:46 7440.66.E 0260D MSV Low Leval Analytical Method: EPA82BOD Pace Analylcal Services - Charlotte Acetone NO mglL 0.025 1 1124/2019:30 67-64-1 Benzene NO MIL 0,0010 1 1124/2019:30 7143-2 Bromobeusene NO mill- 0.0010 1 1112412019:30 10&80-1 Bromochloromethane NO mg1L 0.0010 1 1112412019:30 74-975 Bromodlchloromethane ND mglL 0.0010 1 11124/2019:30 76-274 Bromoform NO mill- 0.0010 1 1V2412019:30 76-25-2 Bromomethane NO mill- 0.0020 1 1112412019:30 74-83-9 2-Bumnano(MEK) NO mg/L 0.0060 1 111242019:30 78-93.3 Carbon tetrachloride ND m9/L 0.0010 1 111242019:30 56-23-5 Chlombenzene NO mglL 0.0010 1 11124/2019:30 10&90.7 Chlomethane NO mg/L 0.0010 1 11242019:30 7&M-3 Chloroform No mg/L 0.0060 1 11242019:30 07-69-3 Chlammethane NO mg/L 0.0010 1 11242019:30 74-87-3 2-Chloraloluene NO mglL 0.0010 1 11/242019:30 95-495 4-Chiorotoluens NO mg/L 0.0010 1 1V242019:30 10643-4 1,2-Dlbmmo-3-chioropropane NO mg/L 0.0060 1 111242019:30 96-12-8 Dibromachlaromethene NO mg/L 0.0010 1 1112412019:30 124-48.1 1,2-Dibmmoethaoe(EDB) NO mg/L 0.0010 1 1112412019:30 10"3.4 Dlbromomethana ND mg/L 0.0010 1 111242019:30 74-95-3 1,2-Dlchlombanzene NO mg/L 0.0010 1 11/24120 19:30 95-50-1 1,3-Dlchiorobeneene ND mg/L 0.0010 1 11124120 19:30 641-73-1 1A-Dichlorobemmne ND mg/L 0.0010 1 1112412019:30 106.46-7 Dlohlorodl9uoromethane NO mg/L 0.0010 1 11/242019:30 76-71-8 1,1-Dlchloroethane ND mill- 0.0010 1 11/24/20 19:30 7&343 1,2-Dlchlomethane ND mglL 0.001D 1 111242019:30 107.06-2 1,1-Dlchloroelhene ND mg& 0,0010 1 1112420 19:30 75.354 cis-1,2-Dichleroethene ND lag/L 0,0010 1 IV24/2019:30 15659-2 tmns-1,2-Dlch1oroelhene ND mglL 0.0010 1 IV242019:30 156505 1,2-Dlchlompropane ND mglL 0.0010 1 111242019:30 78-875 1,3-Dlchloropmpane ND mg/L 0.0010 1 111242019% 142-211-9 2,2-Dlchloropropane NO mglL 0.0010 1 11124/2019:30 594-20-7 IIJ-Dlchloropeopene NO mglL 0,0010 1 11124/2019:30 663-5B43 cis-1,3-Dlchloropropene NO mglL 0,0010 1 111242010:30 10061.015 trans-1,3-01chiorepropene ND mg/L 0,0010 1 11/2412019:30 1006142-6 Dlisopropyl ether ND mg/L 0.0010 1 11124/2019:30 108-20-3 Ethy[benzene NO mglL 0.0010 1 111242019:30 111 Hexachloro-1,3butadlene NO mgA. 0.0010 1 11/2412019:30 87-683 1:4=391:i941a111.1*]:7ViU 410.11LIF'" " This report shell net be repreduced. except In full, Date: 121281202012:39 PM wlihe.t the w,lden consent of Paca M.M[cW Services, LLC. Page 4 of 38 Pan Anelyl1oa19srvlces, LLC ace100 O2724 Short . AnaliMcal a Kernerevllle, NO 272e www.pemleEaapm 336-963-2891 ANALYTICAL RESULTS Project Case Fars Monitoring Pace Pmlecl No.: 92507318 Semple: Case Farms Monitoring Lab ID: 92507318001 Collected: 1111812013:16 Received: 11119/2014:30 Mmrla: Wm r Wall #3 Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Coal 8260D MSV Low Level Analytical Method: EPA 8260D Pace Analytical Services Charlotte 2-Hezenone NO mg/L 0.0050 1 111242019:30 591-78,6 p-180propylloluene NO mg/L 0.0010 1 1112412019:30 99-876 Methylene Chloride NO mg/L 0.0050 1 112412019:30 75.09-2 44ethyl-2-perdanone(MICK) NO mg/L 0.0050 1 112412019:30 108-10-1 Methyl -tart -butyl ether NO n,I 0.0010 1 11/2420 19:30 1634-04-4 Naphthalene NO mg/L 0.0010 1 1112420 10:30 91-20-3 Styrene NO mI 0.0010 1 11/2MO 19:30 100-42.5 1,1,1,2-Temachloroethana NO MI 0.0010 1 11/242019:30 630.20-6 1,1,2,2-Tetrachlomethan. NO mg1L 0.0010 1 11124/2019:30 7&34-5 Tatrachlorcethene NO mg/L 0.0010 1 1112412019:30 127AII-4 Toluene NO mg1L 0.0010 1 11124/2019:30 108-88.3 1,2,3-1pdchlombanzene NO mg/L 0.0010 1 112412D 19130 87-61-6 1,2,4-Trichlorobenzene NO mg/L 0.0010 1 112412019:30 12042-1 1,1,1-Trlchloroelhane NO ng/L 0.0010 1 1112412010:30 71-56-8 1,1,2-Trichloroethane NO mg/L 0.0010 1 1124/2019:30 79-00-5 Tdchlaroalheme NO og/L 0.0010 1 112412019:30 79-01-6 Tdohloro6uoromethane ND mg/L 0,0010 1 1112412019:30 75-04 1,2,3-Tdchloropropune ND mg/L 0.0010 1 11124/2019:30 96d&4 Vinyl acetate NO ng/L 0.0020 1 11124/2019:30 108A5-4 Vinyl chloride NO mg/L 0,0010 1 11124/20 19:30 75-01-4 Xylem (Well ND mg/L 0.0010 1 111242019:30 1330-20-7 m&p.Xylene ND mglL 0.0020 1 11242019:30 179001-23.1 o-Xylre NO mg/L 0.0010 1 111242019:30 9G47-6 Surrogates 4-Bromo6uorobenzene(S) 103 % 7&130 1 111242019:30 460-00-4 1,2-Dichloroethene-d4(S) 111 % 70-130 1 111242019:30 17060-07-0 Toluene.dtl(S) 101 % 70-130 1 1U242019:30 2037-20-5 53108 TOO Analytical Method: SM 5310B-2011 Pace Analytical Services -Asheville Total Organic Carbon NO mg1L 1.0 1 12(06/2007:41 7440-44A REPORT OF LABORATORYANALYSIS This mpod shall not be reprodumd, except In full, Date: 12/28/202012:39 PM without the written cmmon fPace A,.Vl el BeMces,LLC. Page 5 of 38 Pace Analytical Services, LLC ace Analytical® 1, Short84 Kernersve C272 Www.paalaW.esm 306339�906.2091 ANALYTICAL RESULTS Project Case Farms Monitoring Pecs Protect No.: 92507318 Sample: Case Farms Monitoring Lab ID: 9007318002 Collected: 11/182014:15 Received: 1111912014:30 Moblx: Water Wall#4 Parameters Results Units Report Llmlt OF Prepared Analyzed CAS No. Qua[ 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.41994 Preparation Method; EPA 200.7 Rev 4.41994 Pace Analytical Services -Asheville Amenic NO mg/L 0.010 1 121022001:59 1210312020:41 7440-38-2 Copper NO mg/L 0.0050 1 1210212001:50 1210312020:41 744&50-8 Potassium NO mg/L 5.0 1 1210212001:59 1210312020:41 7440-09-7 Sodium NO malt 5.0 1 12/0212001:69 1210312020:41 7440-235 Zinc 0.613 TO& 0.010 1 12/0212001:69 12/0312020:41 7440.66.6 BC 8280D MSV Low Level Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone NO mg/L 0.025 1 11/24/2019:48 67-64-1 Benzene ND mg/L 0.0010 1 11/242019:48 71-93-2 Bromobemzene NO mg/L 0.0010 1 11/242019:48 108.86-0 Bromochloramelhene NO mg/L 0.0010 1 11/2412019:48 74-97-6 Bromodichlommethane ND mg/L U.0010 1 111242019:48 7&27-4 Brom06. NO mg1L 0.0010 1 1124/2019.48 75-25-2 Bromomethane NO mg1L 9.0020 1 1124/2019.48 7"3-9 2-Sutenone(MEK) NO m9IL 0.0050 1 1112412019.48 7&93. Carbon tetrachloride NO mglL 0.0010 1 11124/20 WAS 66-235 ChImcbenzene NO n0l. 0.0010 1 111242019:48 108-90-7 Chloroethane ND m9/1- 0.0010 1 11124/2019:48 7&00.3 Chloroform ND mg/L 0,0050 1 111242019:48 67-66.3 Chloromethrum NO mg/L 0,0010 1 111242019:4B 7487-3 2-Chiamtoluene ND mg/L 0.0010 1 11/242019:48 9&49-8 4-Chiomto[uene NO mg/L 0.0010 1 11242019A8 106-43-4 1,2-Dlbromo-3-chloropropane NO mg/L 0.0050 1 11242019:48 9&12-8 Dibmmochlorome(hane NO mg/L 0.0010 1 11124/2019:48 12448-1 1,2-Dlbromoethane FOR) NO mgtL 0.0010 1 11242019:48 106-93-4 Dibromamelhana NO mg/L 0.0010 1 112412019:48 74-95-3 1,2-Dichiorobenzene NO mg1L 0.0010 1 1124/2019:48 95-50-1 0-Dlchiorobenzene NO mglL 0.0010 1 1124/2019:48 541-73-1 1,4-Dlchiorobenzeoe NO mg1L 0.0010 1 1112412019:48 106-0 -7 Dlchlomdi0uommethane NO mglL 0.0010 1 111242019:48 76-71-8 1,1-Dichloroethane NO mg/L 0.0010 1 11124/20 19:48 75.34-3 1,2-Dichioroethane NO mg/L 0,0010 1 11124/20 19:48 107.06-2 1,1-Dichlomethene NO mg/L 0.0010 1 111242019:48 75.3&4 ci-1,2-Mahioroethene NO mg/L 0.0010 1 11124/2019:48 15659-2 trans-1,2-Dichiom men. NO malt 0.0010 1 111242019:48 166.00-5 1,2-131chiomprapane NO malt 0.0010 1 111242019:48 78,875 1,3A1gdampropane ND mg/L 0.0010 1 11/242019:48 142-28A 2,2-131chlompropane NO m9IL 0.0010 1 11/242019:48 594-20-7 1,1-131chiompmpene NO mgn- 0,0010 1 111242019:48 563-58-6 cla-1,3-Dlchlaropropene NO mglL 0.0010 1 111242019AS 10061-015 trans-1,3-17dch1oropropene NO mglL 0.0010 1 111242019AB 10061-02-6 Dlisopropyl ether NO mglL 0.0010 1 11/2412019:48 108-20-3 Ethylbenzene NO mg/L 0.0010 1 11/242010AB 100-41-4 Hexechloro-1,3-butadltam NO mg/L 0.0010 1 111242019:48 87-68.3 REPORT OF LABORATORY ANALYSIS This report shell not be repmtlucst, except In fall. Date: 121=02012:39 PM wnhoul me wrhmn consents; Pesa Analyllwl8ervlcee,LLC. Page 6 of 38 acaAnalytical e wwwpepaleN.e4m ANALYTICAL RESULTS Pace Analytical Services, LLC ice Shansi, Kemomvllle, NC 27284 338-999.2841 Project: Case Farms Monitoring Paco Pmject No.: 92507318 Sample: Case Farms Monitoring Lob ID: 92507318002 Collected: 11/1812014:15 Received: 1111912014:30 Matrix: Water Well H4 Parameters Results Unite Report Limit OF Prepared Analymcl CAS No. Qual 82ND MSV Low Level Analytical Method: EPA8260D PacriAnalytical Servlcea - Charlotte 2-Hexenone ND mg/L 0.0050 1 11/24/20 19:48 591-78-6 p-Isopropyltoluene NO mg/L 0.0010 1 11/24/20 WAS 99-87.8 Methylene Chloride NO mg/L 0.0060 1 11/242019:48 75-09-2 4-Methyl-2-penlanone(10I13K) NO rrg1L 0.0050 1 11124/2019:48 108AW-1 MethyNert-butyl ether NO mglL 0.0010 1 112412019:48 1634-04-4 Naphthalene NO mglL 0.0010 1 11/242019:48 91-20.3 Styrene NO m81L 0.0010 1 11/242019A8 100.42-5 1,1,1,2-Tetmahlomethan. NO mg/L 0.0010 1 11/2412019:48 630-2M 1,1,2,2-Tatrachloroethano NO mg1L 0.0010 1 11/2412019:48 79-34-5 Tat echlomethree ND mg/L 0.0010 1 1112412019:48 127-18.4 Toluene NO mg/L 0.0010 1 111242019:48 108-88-3 1,2,3-Trichlumbentaw NO mg/L 0.0010 1 11242019:48 87-61-6 1,2,4ttich1mmbenoene NO ni 0,0010 1 112412019:48 120-82-1 1,1,1-Trichiomathene NO mg/L 0.0010 1 11242019:48 71-55-6 1,1,2-Trichioroethane NO higlL 0.0010 1 112412D 19AS 79.00-5 Tdchlorcethene NO mg1L 0.0010 1 111242D 19:48 79-01-8 Trlchlorolluomerathane NO mglL 0.0010 1 112412019:48 76-69.4 1,2,3-Trichioropropme NO mg1L 0.0010 1 11/2412D 19:48 96-18-4 Vinyl acetate NO mg/L 0.0020 1 11124/2D 19:48 108-06-4 Vinyl chloride NO mglL 0.0010 1 11/24/2D 10:48 75-01-4 Xylan,(Tmal) ND mglL 0.0010 1 11124/2019:48 1330-20-7 m&p-Xylene NO mg/L 0.0020 1 1V24/2019:48 17D801-23-1 o-Xylene NO mg/L 0.0010 1 11124/2019:48 96A7-6 Surrogates 4-SmmcOuorobenzene(S) 104 % 7( 1UO 1 1112412019:48 460-00-4 1,2-Dlchloroethaned4(S) 116 % 70-130 1 111242019AB 17060-07.0 Toluene-de(S) 99 % 70-130 1 1112412019t48 2037-26-5 5310B TOO Analytical Method: SM 53108.2011 Pace Analytcal Services-Ashevllls Total Organlc Carbon NO mglL 1.0 1 12O612D 07:58 744044-0 REPORT OF LABORATORY ANALYSIS This repo4ahall not be reproduced, except In lull, Data 12/2812MO 12:39 PM Without the written consentof Psne AnalyWal Services. D.C. Page 7 of 38 aceAnalyiical a am psoolabs.wln ANALYTICAL RESULTS Pace Anelylictl eervtce., LLC toe short St. Kemeavllle, NC 27294 336.99e2941 Project: Case Farms Monitodng Pace Project No.: 92607318 Sample: Case Farms, Monitoring Lab ID: 92507318003 ColkGel: 1111812013:45 Received: 11/19,2014:30 Matrix: Water Well 05 Parametsm Results Unite Report Llmll OF Prepared Analyzed CAS No. Qual 200.7 MET ICP Analytical Method: EPA200.7 Rev 4.41994 Pmpamtlon Method: EPA200.7 Rev 4,41994 Pace Analytical Services-AsheNlle Amenlc NO mgll- 0.010 1 121022001:69 12103/2020:60 7440-38-2 Copper NO mrrL 0,0050 1 1210212001:59 1210312020:60 7440-50-8 Potassium NO mglL 5.0 1 1210212004:59 12J0312020:50 7440-097 Sodium 5A mg1L 6.0 1 1210212001:69 1210312020:50 7440-235 Zinc 0.019 mglL 0,010 1 12102J2001:59 121032020:50 7440-66-6 BC 8260D MSV Low Level Analytical Method: EPAM600 Pace Analy1 cal Services - Charlotte Anshan. ND mg/L 0.025 1 11/24/2020:06 67-64-1 Benzen. ND mglL 0.0010 1 112412020:06 7143-2 Bromobenzene NO mill 0.0010 1 111242020:06 10&86-1 Bromochloram.thane NO mg1L 0.0010 1 111242020:06 74-975 Bromodlchlommrthane ND mg1L 0,0010 1 11/24/2020:06 75-274 Bromofarm ND mgiL 0.0010 1 11/242020:06 76-2&2 Bromarmethane ND mgiL 0.0020 1 11/242020:06 74.83-9 2-Butanone(MEK) ND ml 0,0050 1 11/2412020:06 78.93-3 Carbon tetrachloride ND mglL 0.0010 1 111242020:06 66-235 Chlorobmrzene ND mglL 0.0D10 1 111242020:06 108.90-7 Chioroethane ND m9/L 0.0010 1 11/242020:06 76-00-3 Chloroform NO mg/L 0.0050 1 111242020A6 67-66-3 Chlorome0mrs ND mg/L 0.0010 1 111242020:06 7487-3 2-Chlomtaluena ND mg/L 0.0010 1 11/242020:08 96-49-8 4-ChlDrotoluens ND ml 0.0010 1 1124/2020:06 10BA3-4 1,2-Dibromc-3-chlompropane ND ml 0.00(50 1 11/242D20:06 96-12-8 Dlbromachloromehhan. ND mglL 0.0010 1 11/2412020:00 124A8-1 1,2-Dlbromcathane(EDB) ND mglL 0.0010 1 1124/2020:06 106-934 Dlbromamethane NO mglL 0.0010 1 11242020:06 74-95-3 1,2-Dichiorobenzene NO mglL 0,0010 1 1124/2020:06 95.50-1 1,3-Dichiombtal ND ml 0.0010 1 1112412020:06 641-73-1 1,4-Dich1mobenzene ND mglL 0,0010 1 1112412020:06 106.46-7 Dlchloradilluoram.thane ND mg1L 0,0010 1 1112412020:06 76-71-8 1,1-Dlchioroethane ND mglL 0.0010 1 11/24)2020.06 75-3441 1,2-Dlchlomethane ND mg1L 0.0010 1 11/242020:06 107-06-2 10-DIcdrloroethene ND mg1L 0,0010 1 11124202"(S 75-354 cls-1,2-Dlchiomethe. ND ml 0,0010 1 11/24/2020.06 166-59-2 Imps-1,2-Dldlloroethene ND mg/L 0.0010 1 111242020:00 15MO5 1.2-Dichicmpmp... NO mg/L 0.0010 1 111242020:06 7&875 1,3-Dlchiaroprop... NO mg/L 0.0010 1 11/2412020:06 142-28-9 2,2-Dlchiaropropane NO 111911- 0.0010 1 11124/2020:06 594-204 1,1-Dlchhoropropene NO all 0.0010 1 111242020:06 5635E-6 cis 1,3-Dlchioropromme ND ml 0.0010 1 1124/2020:06 1001 Irons-1,3-Dich1aropropNa, ND ml 0.0010 1 112412020:06 10061-02-6 Dlisopropyl ether ND nr lL 0.0010 1 11/24a020:O6 108-20-3 Ethylbenzene ND mglL 0.0010 1 112412020:06 10041-4 Hexachlaro-1,&butadlene ND re lL 0.0010 1 172412020:00 87.68-3 REPORT OF LABORATORY ANALYSIS This sail shall notba mpmduced, except In full, Date: 12/26202012:39 PM without the wrlflan consent of Pace Analytical S.Mr., LLC. Page 8 of 38 .014 ir Pace Analytical Semites, LLC mlytical m me Shod acaA Kemra avNO 22284 34 wwwpattleee,e23am 330-Boa-2891 ANALYTICAL RESULTS Project: Case Farms Monitoring Paco Poled No.: 92607318 Semple: Case Farms Monitoring Lab ID: 92607318003 Collected: 111182013:45 Received: 1111912014:30 Matrix: Water Well $5 Parameters Results Units Report Urnit DF Prepared Analyzed CAS No. QwI 8280E MSV Low Level Analytical Method: EPA 8260D Paw Analytical Servlow- Charlotte 2-1-fexanone NO mglL 0.0050 1 11/242020:06 591-7" p-Isopropyltoloene NO mill- 0.0010 1 11242020:06 99-87-6 Methylene Chloride NO mglL 0.0060 1 11242020:08 75-09.2 4-Methyl-2-pentenono(MIBK) NO m911- 0.0050 1 11/242020:06 108.10.1 Methyl-taddlutyl ether NO mg1L 0.0010 1 11/242020:06 1634-04-4 Naphthalene NO mg/L 0.0010 1 111242020:06 91-20.8 Styrene ND mg/f. 0.0010 1 11242020:06 100-42-6 1,1,1,2-Tetmchlomethane ND mg/L 0.0010 1 111242020:06 630-206 1,1,2,2-Tetmchloroethane ND mg/L 0.0010 1 11242020:06 79-34.5 Tatrachlomathene ND mg/L 0.0010 1 11242020:00 127-18.4 Toluene NO mglL D.0010 1 112412020:05 108-88-3 1,2,34dchlorober¢ens NO mglL 0.0010 1 112412020:06 87-61-8 1,2,4-Trichlorobeluene NO mlyk 0.0010 1 1112412020:06 120.82-1 1,1,1-TrichbmwOrana NO mglL 0.0010 1 1112412020:06 71-55-8 1,1,2-Trichloroutheme NO m91L 0.0010 1 11/24/2020:06 79�00.5 Trlchloroethene NO mglL 0.0010 1 1V24/2020:06 79-01-8 Trlchioro0oommelhans ND mill- 0.0010 1 111242020:06 76-69-4 1,2,3-Trlchlaropropana NO mg/L 0.0010 1 111242020:00 96-18.4 Vinyl acetate ND mg/L 0.0020 1 111242020:06 108-136-4 Vinyl chloride NO mg/L 0.0010 1 111242020:06 75-01-4 Xylene(Total) ND mg/L 0.0010 1 11/242020:06 1330-20-7 m&p-Xylene NO mg/L 0.0020 1 1124/2020:06 179601-23A o-Xylene NO mg/L 0.0010 1 11/24/2020:06 95-47-6 Surrogates 4-Bromoflumobenzene(S) 101 % 70.130 1 11/24/2020:06 460-00-4 1,2-D1chlomdhmroA4(8) 115 % 70-130 1 1124/2020:06 17060-07-0 Toluene-de(S) 100 % 70-130 1 11/2412020:06 2037-265 5310E MC Analytical Method: SM 5310E-2011 Pace Analytical SeMws-Asheville Total Organic Carbon NO m9IL 1.0 1 12/052009:05 7440-44-0 REPORT OF LABORATORY ANALYSIS Thla report shell not be reproduced. except In full, Date: 121281202012:39 PM without the written consent of Pace Analynal SerAcee,LLC. Page 9 of 38 Analytical Environmental Services, Inc Data: 28-Dee-20 Client: Pace Analytical Services, file. Cliont SampblD: CASE FARMS MONP[ORINGN Project Name: 92507318 Collection Data: 11/18/20201:15:00 PM Lob ID: 2011O49-001 Matrix: Aqueous Reporting D1lhtion Formaldehyde by SW8315A Formaldehyde (imimenl • NJueen<vdamewmm—imemimmirvel DIW B'i—pam, limit H rlultlil�alimea Po,pmemlal,al'emlyei[oxmltlod N Amlywratte"Cm1iM1M e AnelybdelwudiftdmmmouW J,Whmiblun4 > Omwnlwnamultvnluo BRL 0.050 -A 306232 1 11/2 1/2020 09:29 HL B aeimnmd(valunbove quiraiaim, mn+yo D Spae B1.1 ounideliml6 due wlnmri. Nnrt Aeoaaonrtmrvo P AalWediu aula6 Wtlablsedevlaliou lum piemeNod < Lm am, Bmua ndue r aaimnled.owauaawa belnwAopn�sngegMl page 32 of 38 Page 4 of 10 Analytical Environmental Services, Inc Data: 28-Dec-20 Client: Pace Analytical Services, Inc. Client Sample ID: CASH FARMS MONITORING Project Name: 92507318 Collection Date: 11/18/2020 2:15:00 PM Lab ID: 2011048-002 Matrix: Aqueous _ .. Reoortlna _ _ ._ .. _ ___ Dilution r V. ...<.... Limit min. .,.met .,n..m... Factor ..net„ ... ...,yat Formaldehyde by SW8315A Fonnaldehyde HRL 0.050 mI)L 306232 1 1121202009:42 HL tinum,en ^ 4atue wrxrRmnmmnmmnlomimip lgel em. Below mmmi Iona N Lmlalnenmm mr p.nw•eannw.mt�i. o. dwl N MmlytamlN cw4aea a Am000 doeota in the mtoomed nulboa VIA ntoo umeetoollvnl" e Pm-W(.lot ebme momi mono) s spike..., wtrlao tlmio tem to mete N., Scoom--11- P Amlyea in the lob whirl tan deviation Poet Ole method < Lm.IMn RxNlwlo, I Bali sees aseod molw Ropenim Limit Page 33 of 38 Page 5 of 10 Analytical Envifronmental Services, Inc Date; 28-Dec-20 Client: Pace Analytical Services, Inc. Client Sample ID: CASE FARMS MONITORING Project Name: 92507318 Collection Date: 11/182020 1:45:00 PM Lab ID: 2011048-003 Matrix: Aqueous Analyses Reporting Result Real Dnhs EatchlD Dilution Date Analyzed Analyst Limit Factor Formaldehyde by SW8315A Formaldehyde EItL 0.050 ""A, 306232 1 1121/2020 09:56 IIL goelmen: a VJmexmedemix:m neoowmmorohool OlL BBlow repopine llmil H fWldigtimmfmpmpvmllonaeennlyd[envedW N Annbmnot N9LAC nNaetl n Audyle danted In llm mtuele. mtlhea i1ek > atmldw.cam.mue e&amnlod(nmodwvequuddetionee:lg•) 5 Spike aamvery muside Hotin duo to meld:: Nen Seecmm—Uu, p Aootud lu Ito at, wMaWo a doAA. fie. the not I Len aeu amok vnluo f anm.mlraumeneweaxW.aremlWe Vmil page 34 of 38 Page 6 of 10