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HomeMy WebLinkAboutNC0024911_Groundwater Monitoring Report October 2019_20191114oQo \,LPN SEWfggGFo�cP f C 9 Qo o F sF OOVNrY, 00 Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Information Processing Unit: Metropolitan Sewerage District OF BUNCOMBE COUNTY, NORTH CAROLINA November 14th", 2019 Please find attached the Groundwater Quality Monitoring Reports for the month of October 2019 from Metropolitan Sewerage District of Buncombe County (MSD). These monitoring report forms have additional identification on the well ID line, MW-05, MW-06R, MW-07, MW-08R, for ease of reference. Prior to this sampling period, MW-06R and MW-08R, previously referred to as MW-06 and MW-08, were re -drilled and renamed as advised by the Asheville Regional Operations section. Monitoring Well-05 exceeded. allowable limits for pH and manganese. Monitoring Well-06R exceeded allowable limits for pH, iron and manganese. Monitoring Well-07 was dry. Monitoring Well-08R exceeded allowable limits for pH, iron and manganese. Please do not hesitate to contact me at 828-225-8224 with questions regarding the attached reports. Sincerely, Roger C. Edwards Director of Operations & Pretreatment MSD of Buncombe County RECEIVE)' NOV 2 0 2019 InforffmUDn PrQ=^ %eng Unn DWQ/BOG 1, U r-.� �,-,, t''J c 5 Nz,i;r C)u�lif Regional Operations Asheville Regional Office Protecting Our Natural Resources — 2028 RIVERSIDE DRIVE, ASHEVILLE, NORTH CAROLINA28804 TELEPHONE: (828)254-9646 FAX: (828)254-3299 WEBSITE: www.msdbc.org GW-59A COMPLIANCE REPORT FORM Permit # NCO024911 (Submit one each monitoring period ivitb W-59 forms.) I Enter date monitoring results were due. (_11/31/2019_) Will this monit ring report (GW-59 and GW-59A) YE NO be submitted after the established due date? 2 Was any required information missing on the GW-59 report forms? YES O IF the answer to question 1 or 2 is "YES" list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES O identification plate, area overgrown, etc.)? Ifthe answer is "Yes", contact the Regional Ojf1cefor guidance. 4 Are any monitored constituents equal to or above the established standards? YES NO If the answer to question 4 is "NO'; skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below: MW-05 MW-06R MW-07 MW-08R pH 5.7 pH 6.1 pH 6.3 Manganese 302 ug/L Manganese 12,700 ug/L Manganese 10,400 ug/L Iron 50,800 ug/L Iron 2,860 ug/L 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? If the answer to question 5 is WQ'" skip to section 8.If the answer to question 5 is 'lYFS", list in the space provi(!ed t o each well with constituent(s) exceeding standards, concentration(s) repo ed, ;and sample collection dato o a h occurrence (for the last two years). MW-05 pH 5.8 ... .... ... Manganese 482 ug/L Water Quality Regional Operations NOV 2 0 2019 6 Are the monitoring wells listed in ktl 6LV11369bnd the review bot%Vb"on Processing Unk YES NO DW0f80G If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO - groundwater quality problem? If the answer to question 7 is "YES" describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 day • an evaluation may b required to determine the impact the wa to disposal -system is having at the w and compliance b -undaries surroundina this facility, Failure to do so may bi t the t2ormittee to a Notice of Violation fines. and/ornenalties. leting this portion (G W-59A) of the monitoring report should sign below and submit this forms for required wells to the address provided at the top of the current GW-59 form. edge that the above information was evaluated and the information submitted in this 7(Compliance ce Report GW-59A) is true and complete to the best of my knowledge. I vGo( Si pat a of Permittee (or Authorized Agent) p e GW-59A 12/8/2003 J m U' rn � J K ° m wo E 3a=E� c _ Q O Z N L N O. ® O o o V V m E y ED a N b J U o 5 it ivk ivk ivt C. 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ZJ Z Z Q a z❑ 02 O mQ�Q U U m 0 m KO U •u LL u c iW =y n m Emw!K ❑ N a U u a IL U� N �i � O: j Wm J❑ d LL 0 m U j 1 y a `o y " y C N a Q W E � 0 0 0 � n r C O N C y o V � O F ro � U �^ Y o y (\ E v _ 19 � a a o U s+ i > O .. a.�. .� ____ __ N d O J ®. c� n r� n M ti r V E Lm v aceAna4llcal xww.paielabs.com r I October 24, 2019 Mr. Roger Edwards Metropolitan Sewerage District 2028 Riverside Drive Asheville, NC 28804 RE: Project: MW'S 10-2-19 Pace Project No.: 92447981 Dear Mr. Edwards: Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Enclosed are the analytical results for sample(s) received by the laboratory on October 02, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Revised Report. Field data was corrected for MW-6R. If you have any questions concerning this report, please feel free to contact me. Sinc ely, �2� c orri Patton lorri.patton@pacelabs.com 1(828)254-7176 Project Manager Enclosures cc: Ms. Shannon Bergeron, Metropolitan Sewerage District Ryan Dyson, MSD of Buncombe County, NC Mr. Chad Ledford, Metropolitan Sewerage District Mr. Dwayne Martin, Metropolitan Sewerage District Ms. Cassandra McKnight, MSD of Buncombe County Mr. Alan Taylor, Metropolitan Sewerage District 'PC P y REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, L-C. Page 1 of 37 aceAnalytical w mpawlabs.mo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 CERTIFICATIONS Project: MWS 10-2-19 Pace Project No.: 92447981 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 South Carolina Certification #: 99006001 Louisiana/NELAP Certification # LA170028 Florida/NELAP Certification #: E87627 North Carolina Drinking Water Certification #: 37706 Kentucky UST Certification #: 84 North Carolina Field Services Certification #: 5342 VirginiaNELAP Certification #: 460221 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification M E87648 Massachusetts Certification #: M-NC030 North Carolina Drinkinq Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 37 .1-001 aceAnaWical W ..pacefaftm.. SAMPLE ANALYTE COUNT Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Pace Project No.: MWS 10-2-19 92447981 Analytts Lab ID Sample ID Method Analysts Reported Laboratory 92447981001 MW-05 EPA 200.7 Rev 4.41994 DS 10 PASI-A EPA 245.1 Rev 3.01994 SOO 1 PASI-A SM 6200B DLK 63 PASI-C SM 2540C-2011 SAM2 1 PASI-A EPA 300.0 Rev 2.1 1993 BRJ 1 PASI-A EPA 350.1 Rev 2.0 1993 GC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 GC 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92447981002 MW-06R EPA 200.7 Rev 4.41994 DS, SH1 10 PASI-A EPA 245.1 Rev 3.01994 SOO 1 PASI-A SM 6200B DLK 63 PASI-C SM 2540C-2011 SAM2 1 PASI-A EPA 300.0 Rev 2.1 1993 BRJ 1 PASI-A EPA 350.1 Rev 2.01993 GC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 GC 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92447981003 MW-08R EPA 200.7 Rev 4.4 1994 DS, SH1 10 PASI-A EPA 245.1 Rev 3.0 1994 SOO 1 PASI-A SM 6200B GAW 63 PASI-C . SM 254OC-2011 SAM2 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 350.1 Rev 2.0 1993 GC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 GC 1 PASI-A SM 531OB-2011 ECH 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 37 aceAnalytical o w .pacelabscom ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MWS 10-2-19 Pace Project No.: 92447981 Sample: MW-05 Lab ID: 92447981001 Collected: 10/02/1915:30 Received: 10/02/1916:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Collected By Mark 1 10/09/19 14:36 Swann Collected Date 1012/19 1 10/09/19 14:36 Collected Time 15:30 1 10/09/19 14:36 pH 5.7 Std. Units 1 10/09/19 14:36 Temperature 23.4 deg C 1 10/09/19 14:36 Static Water Level 18.05 feet 1 10/09/19 14:36 Specific Conductance 38 umhos/cm 1 10/09/19 14:36 Odor No odor 1 10/09/19 14:36 Appearance Clear 1 10/09/19 14:36 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Arsenic ND ug/L 10.0 1 10/11/1922:46 10115/1923:46 7440-38-2 Barium 15.4 ug/L 5.0 1 10/11/1922:46 10/15/1923:46 7440-39-3 Cadmium ND ug/L 1.0 1 10/11/1922:46 10/15/1923:46 7440-43-9 Chromium ND ug/L 5.0 1 10/11/1922:46 10/15/1923:46 7440-47-3 Iron 162 ug/L 50.0 1 10/11/1922:46 10/15/1923:46 7439-89-6 BC Lead ND ug/L 5.0 1 10/11/1922:46 10/15/1923:46 7439-92-1 Manganese 302 ug/L 5.0 1 10/11/1922:46 10/15/1923:46 7439-96-5 Selenium ND ug/L 10.0 1 10/11/1922:46 10/15/1923:46 7782-49-2 Silver ND ug/L 6.0 1 10/1111922:46 10/15/1923:46 7440-22-4 Sodium ND ug/L 5000 1 10/11/1922:46 10/15/1923:46 7440-23-5 245.1 Mercury Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994 Mercury ND ug/L 0.20 1 10/06/1917:42 10/07/1916:38 7439-97-6 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 10114/1909:07 71-43-2 Bromobenzene ND ug/L 0.50 1 10/14/19 09:07 108-86-1 Bromochloromethane ND ug/L 0.50 1 10/14/19 09:07 74-97-5 Bromodichloromethane ND ug/L 0.50 1 10114/1909:07 75-27-4 Bromoform ND ug/L 0.50 1 10/14/19 09:07 75-25-2 Bromomethane ND ug/L 5.0 1 10/14/19 09:07 74-83-9 n-Butylbenzene ND ug/L 0.50 1 10/14/19 09:07 104-51-8 sec-Butylbenzene NO ug/L 0.50 1 10/14/19 09:07 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 10/14/19 09:07 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 10/14/19 09:07 56-23-5 Chlorobenzene ND ug/L 0.50 1 10/14/19 09:07 108-90-7 Chloroelhane ND ug/L 1.0 1 10114/1909:07 75-00-3 Chloroform ND ug/L 5.0 1 10/14/19 09:07 67-66-3 Chloromethane ND ug/L 1.0 1 10/14/19 09:07 74-87-3 2-Chlorotoluene NO ug/L 0.50 1 10/14/19 09:07 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 10/14/19 09:07 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 10/14/19 09:07 96-12-8 Dibromochloromethane ND ug/L 0.50 1 10/14/19 09:07 124-48-1 1,2-Dibromoethane(EDB) ND ug/L 0.50 1 10/14/19 09:07 106-93-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 37 1 aceAnalyticalo w .paaalabsoxn ANALYTICAL RESULTS Project: MW'S 10-2-19 Pace Project No.: 92447981 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MW-05 Lab ID: 92447981001 Collected: 10/02/1915:30 Received: 10/02/1916:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene D i ch lorodifluorom ethan e 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dich loropropen e trans-1, 3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1, 1, 1,2-Tetrachloroethane 1,1,2,2-Tetrachloroeth ane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1, 1, 2-Trichloroethane Trichloroethene Trichlorofluorometh an e 1, 2, 3-Tri ch loropropan e 1, 2,4-Tri m ethylbenzen e 1, 3,5-Trim ethylbenzen e Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Analytical Method: SM 6200B 90 96 115 ug/L 0.50 1 10/14/19 09:07 74-95-3 ug/L 0.50 1 10/14/19 09:07 95-50-1 ug/L 0.50 1 10114/1909:07 541-73-1 ug/L 0.50 1 10/14/19 09:07 106-46-7 ug/L 0.50 1 10/1411909:07 75-71-8 ug/L 0.50 1 10/14/19 09:07 75-34-3 ug/L 0.50 1 10/14/19 09:07 107-06-2 ug/L 0.50 1 10/14/19 09:07 75-35-4 ug/L 0.50 1 10/14/19 09:07 156-59-2 ug/L 0.50 1 10/14/19 09:07 156-60-5 ug/L 0.50 1 10/14/19 09:07 78-87-5 ug/L 0.50 1 10/14/19 09:07 142-28-9 ug/L 0.50 1 10/14/19 09:07 594-20-7 ug/L 0.50 1 10/14/19 09:07 563-58-6 ug/L 0.50 1 10/14/19 09:07 10061-01-5 ug/L 0.50 1 10/14/19 09:07 10061-02-6 ug/L 0.50 1 10/14/19 09:07 108-20-3 ug/L 0.50 1 10114/1909:07 100-41-4 ug/L 2.0 1 10/14/19 09:07 87-68-3 ug/L 0.50 1 10/14/19 09:07 98-82-6 ug/L 2.0 1 10/14/19 09:07 75-09-2 ug/L 0.50 1 10/14/19 09:07 1634-04-4 ug/L 2.0 1 10/14/19 09:07 91-20-3 ug/L 0.50 1 10/14/19 09:07 103-65-1 ug/L 0.50 1 10/14/19 09:07 100-42-5 ug/L 0.50 1 10/14/19 09:07 630-20-6 ug/L 0.50 1 10/14/19 09:07 79-34-5 ug/L 0.50 1 10/14/19 09:07 127-18-4 ug/L 0.50 1 10/14/19 09:07 108-88-3 ug/L 2.0 1 10114/1909:07 87-61-6 ug/1- 2.0 1 10/14/19 09:07 120-82-1 ug/L 0.50 1 10114/1909:07 71-55-6 ug/L 0.50 1 10/14/19 09:07 79-00-5 ug/L 0.50 1 10114/1909:07 79-01-6 ug/L 1.0 1 10/14/19 09:07 75-69-4 ug/L 0.50 1 10/14/19 09:07 96-18-4 ug/L 0.50 1 10/14/19 09:07 95-63-6 ug/L 0.50 1 10/14/19 09:07 108-67-8 ug/L 1.0 1 10/14/19 09:07 75-01-4 ug/L 1.0 1 10/14/19 09:07 179601-23-1 ug/L 0.50 1 10/14/19 09:07 95-47-6 % 70-130 1 10/14/19 09:07 17060-07-0 % 70-130 1 10/14/19 09:07 460-00-4 % 70-130 1 10/14/19 09:07 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 37 aceAnalytical www.pacerabs.cnm ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MWS 10-2-19 Pace Project No.: 92447981 Sample: MW-05 Lab ID: 92447981001 Collected: 10/02/1915:30 Received: 10/02/1916:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Total Dissolved Solids 27.0 mg/L 25.0 1 10/08/19 00:07 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Sulfate 4.1 mg/L 1.0 1 10/04/1905:50 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Nitrogen, Ammonia ND mg/L 0.10 1 10/11/19 19:09 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Nitrogen, Nitrate 0.069 mg/L 0.040 1 10/0211923:46 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 1.3 mg/L 1.0 1 10/09/1920:40 16887-00-6 5310B TOC Analytical Method: SM 531OB-2011 Total Organic Carbon NO mg/L 1.0 1 10/04/1905:25 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, -LC. Page 6 of 37 (�52ceAnalyfical w pamlabsa ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MWS 10-2-19 Pace Project No.: 92447981 Sample: MW-06R Lab ID: 92447981002 Collected: 10/02/1912:00 Received: 10/02/1916:45 Matrix:Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qua[ Monitoring Well Data Analytical Method: Collected By Mark 1 10/09/19 14:37 Swann Collected Date 1012119 1 10/09/19 14:37 Collected Time 12:00 1 10/09/19 14:37 pH 6.1 Sid. Units 1 10/09/19 14:37 Temperature 24.0 deg C 1 10/09/19 14:37 Static Water Level 14.47 feet 1 10/09/19 14:37 Specific Conductance 474 umhos/cm 1 10/09/19 14:37 Odor No odor 1 10/09/19 14:37 Appearance Clear 1 10/09/19 14:37 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Arsenic NO ug/L 10.0 1 10/14/19 11:28 10/15/19 08:01 7440-38-2 Barium 76.1 ug/L 5.0 1 10/14/19 11:28 10/15/1908:01 7440-39-3 Cadmium NO ug/L 1.0 1 10/14/19 11:28 10/15/1908:01 7440-43-9 Chromium ND ug/L 5.0 1 10/1411911:28 10/15/1908:01 7440-47-3 Iron 50800 ug/L 50.0 1 10/14/19 11:28 10/1511908:01 7439-89-6 M1 Lead NO ug/L 5.0 1 10/14/19 11:28 10/15/1908:01 7439-92-1 Manganese 12700 ug/L 25.0 5 10/14/19 11:28 10/15/1922:23 7439-96-5 Mt Selenium ND ug/L 10.0 1 10/1411911:28 10/15/1908:01 7782-49-2 Silver NO ug/L 5.0 1 1011411911:28 10/15/1908:01 7440-22-4 Sodium 14300 ug/L 5000 1 10/14/19 11:28 10/15/19 08:01 7440-23-5 245.1 Mercury Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994 Mercury ND ug/L 0.20 1 10/06/1917:42 10/07/1916:40 7439-97-6 6200B MSV Analytical Method: SM 6200B Benzene NO ug/L 0.50 1 10/14/19 09:25 71-43-2 Bromobenzene NO ug/L 0.50 1 10/14/1909:26 108-86-1 Bromochloromethane NO ug/L 0.50 1 10/14/19 09:25 74-97-5 Bromodichloromethane NO ug/L 0.50 1 10/14/19 09:25 75-27-4 Bromoform NO ug/L 0.50 1 10/14/19 09:25 75-25-2 Bromomethane NO ug/L 5.0 1 10/14/19 09:25 74-83-9 M1 n-Bulylbenzene NO ug/L 0.50 1 10/14/19 09:25 104-51-8 sec-Butylbenzene NO ug/L 0.50 1 10/1411909:25 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 10/1411909:26 98-06-6 Carbon tetrachloride NO ug/L 0.50 1 10/14/19 09:25 56-23-5 Chlorobenzene NO ug/L 0.50 1 10/14/19 09:25 108-90-7 Chloroethane NO ug/L 1.0 1 10/14/19 09:25 75-00-3 M1 Chloroform NO ug/L 5.0 1 10/14/19 09:25 67-66-3 Chloromethane NO ug/L 1.0 1 10/14/19 09:25 74-87-3 2-Ch[orotoluene NO ug/L 0.50 1 10/14/19 09:25 95-49-8 4-Chlorotoluene NO ug/L 0.50 1 10/14/19 09:25 106-43-4 1,2-Dibromo-3-chloropropane NO ug/L 1.0 1 10/14/19 09:25 96-12-8 Dibromochloromethane NO ug/L 0.50 1 10/14/19 09:25 124-48-1 1,2-Dibromoethane(EDS) NO ug/L 0.50 1 10/14/19 09:25 106-93-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, L-C. Page 7 of 37 aceAna4 tical o xww.pacelabs.com Project: MW'S 10-2-19 Pace Project No.: 92447981 Sample: MW-06R Parameters 6200E MSV Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dich lorodifluorometh ane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroelhene cis-1,2-Dich loroethene trans-1, 2-Dichloroelhen e 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1, 3-Dichloropropene trans-1, 3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Telrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trlchlorofluorometha n e 1,2, 3-Tri chloropro pa ne 1,2, 4-Trim ethyl benzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NO 28804 (828)254-7176 ANALYTICAL RESULTS Lab ID: 92447981002 Collected: 1010211912:00 Received: 10/02/19 16:45 Matrix: Water Results Units Report Limit OF Prepared Analyzed CAS No. Qual Analytical Method: SM 6200B NO ug/L 0.50 1 10/14/19 09:25 74-95-3 NO ug/L 0.50 1 10/14/19 09:25 95-50-1 NO ug/L 0.50 1 10/14/19 09:25 541-73-1 NO ug/L 0.50 1 10/14/19 09:25 106-46-7 NO ug/L 0.50 1 10/14/19 09:25 75-71-8 NO ug/L 0.50 1 10/14/19 09:25 75-34-3 NO ug/L 0.50 1 10114/1909:25 107-06-2 NO ug/L 0.50 1 10/14/19 09:25 75-35-4 NO ug/L 0.50 1 10/14/19 09:25 156-59-2 NO ug/L 0.50 1 10/14/19 09:25 156-60-5 NO ug/L 0.50 1 10/14/19 09:25 78-87-5 NO ug/L 0.50 1 10/14/19 09:25 142-28-9 NO ug/L 0.50 1 10/14/19 09:25 594-20-7 NO ug/L 0.50 1 10/14/19 09:25 563-58-6 NO ug/L 0.50 1 10/14/19 09:25 10061-01-5 NO ug/L 0.50 1 10/14/19 09:25 10061-02-6 ND ug/L 0.50 1 10/14/19 09:25 108-20-3 ND ug/L 0.50 1 10/14/19 09:25 100-41-4 ND ug/L 2.0 1 10/14/19 09:25 87.68-3 ND ug/L 0.50 1 10/14/19 09:25 98-82-8 NO ug/L 2.0 1 10/14/19 09:25 75-09-2 NO ug/L 0.50 1 10/14/19 09:25 1634-04-4 NO ug/L 2.0 1 10/14/19 09:25 91-20-3 ND ug/L 0.50 1 10/14/19 09:26 103-65-1 ND ug/L 0.50 1 10/14/19 09:25 100-42-5 ND ug/L 0.50 1 10/14/19 09:25 630-20-6 NO ug/L 0.50 1 10/14/19 09:25 79-34-5 ND ug/L 0.50 1 10/14/19 09:25 127-18-4 ND ug/L 0.50 1 10/14/19 09:25 108-88-3 NO ug/L 2.0 1 10/14/19 09:25 87-61-6 ND ug/L 2.0 1 10/14/19 09:25 120-82-1 NO ug/L 0.50 1 10/14/19 09:25 71-55-6 NO ug/L 0.50 1 10/14/19 09:25 79-00-5 NO ug/L 0.50 1 10/14/19 09:25 79-01-6 NO ug/L 1.0 1 10/14/19 09:25 75-69-4 NO ug/L 0.50 1 10/14/19 09:25 96-18-4 NO ug/L 0.50 1 10/14/19 09:25 95-63-6 NO ug/L 0.50 1 10/14/19 09:25 108-67-8 NO ug/L 1.0 1 10/14/19 09:25 75-01-4 NO ug/L 1.0 1 10/14/19 09:25 179601-23-1 NO ug/L 0.50 1 10/14/19 09:25 95-47-6 91 % 70-130 1 10/14/19 09:25 17060-07-0 100 % 70-130 1 10/14/19 09:25 460-00-4 ill % 70-130 1 10/14/19 09:25 2037-26-5 REPORT OF LABORATORY ANALYSIS M1 M1 M1 M1 This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 37 Pace Analytical Services, LLC 2225 Riverside Dr. ZeAnalytical' Asheville, NC 28804 ..pacelabs.. (828)254-7176 ANALYTICAL RESULTS Project: MW S 10-2-19 Pace Project No.: 92447981 Sample: MW-06R Lab ID: 92447981002 Collected: 10/02/1912:00 Received: 10/02/1916:45 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 254OC-2011 Total Dissolved Solids 239 mg/L 25.0 1 10/08/19 00:07 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Sulfate 106 mg/L 2.0 2 10/04/19 09:08 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Nitrogen, Ammonia 0.46 mg/L 0.10 1 10/11/19 19:11 7664-41-7 353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Nitrogen, Nitrate 0.052 mg/L 0.040 1 10/02/1923:44 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 12.5 mg/L 1.0 1 10/09/19 20:41 16887-00-6 5310B TOC Analytical Method: SM 531OB-2011 Total Organic Carbon 2.3 mg/L 1.0 1 10/04/19 05:36 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 37 aceAnalytical® w,nvpacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MW'S 10-2-19 Pace Project No.: 92447981 Sample: MW-08R Lab ID: 92447981003 Collected: 10/02/19 14:00 Received: 10/02/19 16:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Dust Monitoring Well Data Analytical Method: Collected By Mark 1 10/09/19 14:38 Swann Collected Date 10/2/19 1 10/09/19 14:38 Collected Time 14:00 1 10/09/19 14:38 pry 6.3 Std. Units 1 10/09/19 14:38 Temperature 28.3 deg C 1 10/09/19 14:38 Static Water Level 14.00 feet 1 10/09/19 14:38 Specific Conductance 320 umhos/cm 1 10/0911914:38 Odor No odor 1 10/09/19 14:38 Appearance Clear 1 10/09/19 14:38 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Arsenic NO ug/L 10.0 1 10/14/19 11:28 10/15/19 08:10 7440-38-2 Badum 32.4 ug/L 5.0 1 10/14/19 11:28 10/15/19 08:10 7440-39-3 Cadmium NO ug/L 1.0 1 10/14/19 11:28 10/1511908:10 7440-43-9 Chromium NO ug/L 5.0 1 10/14/19 11:28 10/15/19 08:10 7440-47-3 Iron 2860 ug/L 50.0 1 10/14/19 11:28 10/15/19 08:10 7439-89-6 Lead NO ug/L 5.0 1 10/14/19 11:28 10/15/19 08:10 7439-92-1 Manganese 10400 ug/L 25.0 5 10/14/19 11:28 10/15/19 22:33 7439-96-5 Selenium NO ug/L 10.0 1 10/14/19 11:28 10/15/19 08:10 7782-49-2 Silver NO ug/L 5.0 1 10/14/19 11:28 10/15/19 08:10 7440-22-4 Sodium 35200 ug/L 5000 1 10/14/19 11:28 10/15/19 08:10 7440-23-5 245.1 Mercury Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994 Mercury NO ug/L 0.20 1 10/0611917:42 10/07/1916:47 7439-97-6 6200B MSV Analytical Method: SM 6200B Benzene NO ug/L 0.50 1 10/14/19 23:26 71-43-2 M1 Bromobenzene NO ug/L 0.50 1 10/14/19 23:26 108-86-1 Bromochloromethane NO ug/L 0.50 1 10/14/19 23:26 74-97-5 Bromodichloromethane NO ug/L 0.50 1 10/14/19 23:26 75-27.4 Bromoform NO ug/L 0.50 1 10/14/19 23:26 75-25-2 Bromomethane NO ug/L 5.0 1 10/14/19 23:26 74-83-9 n-Butylbenzene NO ug/L 0.50 1 10/14/19 23:26 104-51-8 sec-Butylbenzene NO ug/L 0.50 1 10/14/19 23:26 135-98-8 tert-Butylbenzene NO ug/L 0.50 1 10/14/19 23:26 98-06-6 Carbon tetrachloride NO ug/L 0.50 1 10/14/19 23:26 56-23-5 Chlorobenzene NO ug/L 0.50 1 10/14/19 23:26 108-90-7 Chloroethane NO ug/L 1.0 1 10/14/19 23:26 75-00-3 Chloroform NO ug/L 5.0 1 10/14/19 23:26 67-66-3 Chloromethane NO ug/L 1.0 1 10/14/19 23:26 74-87-3 2-Chlorotoluene NO ug/L 0.50 1 10/14/19 23:26 95-49-8 4-Chlorotoluene NO ug/L 0.50 1 10/14/19 23:26 106-43-4 1,2-Dibromo-3-chloropropane NO ug/L 1.0 1 10/14/19 23:26 96-12-8 Dibromochloromethane NO ug/L 0.50 1 10/14/19 23:26 124-48-1 1,2-Dibromoethane(EDB) NO ug/L 0.50 1 10/14/19 23:26 106-93-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 37 PaceAnaly#ical wnw.pauelabs.Nm Project: MWS 10-2-19 Pace Project No.: 92447981 Sample: MW-08R Parameters 6200E MSV Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorod ifl uorom ethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrach loroethane 1,1, 2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofl uoromethane 1,2,3-Trichloropropan e 1,2,4-Tri methyl benzen e 1,3,5-Tri m ethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NO 28804 (828)254-7176 ANALYTICAL RESULTS Lab ID: 92447981003 Collected: 10/02/1914:00 Received: 10/02/19 16:45 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual Analytical Method: SM 6200B ND ug/L 0.50 1 10/14/19 23:26 74-95-3 ND ug/L 0.50 1 10/14/19 23:26 95-50-1 ND ug/L 0.50 1 10/14/19 23:26 541-73-1 ND ug/L 0.50 1 10/14/19 23:26 106-46-7 ND ug/L 0.50 1 10/14/19 23:26 75-71-8 ND ug/L 0.50 1 10114/1923:26 75-34-3 ND ug/L 0.50 1 10/14/19 23:26 107-06-2 ND ug/L 0.50 1 10/14/19 23:26 75-35-4 ND ug/L 0.50 1 10/14/19 23:26 156-59-2 ND ug/L 0.50 1 10/14/19 23:26 156-60-5 ND ug/L 0.50 1 10/14/19 23:26 78-87-5 ND ug/L 0.50 1 10/14/19 23:26 142-28-9 ND ug/L 0.50 1 10/14/19 23:26 594-20-7 ND ug/L 0.50 1 10/14/19 23:26 563-58-6 ND ug/L 0.50 1 10/14/19 23:26 10061-01-5 ND ug/L 0.50 1 10/14/19 23:26 10061-02-6 ND ug/L 0.50 1 10/14/19 23:26 108-20-3 M1 ND ug/L 0.50 1 10/14/19 23:26 100-41-4 M1 ND ug/L 2.0 1 10/14/19 23:26 87-68-3 ND ug/L 0.50 1 10/1411923:26 98-82-8 ND ug/L 2.0 1 10/14/19 23:26 75-09-2 ND ug/L 0.50 1 10/14/19 23:26 1634-04-4 ND ug/L 2.0 1 10/14/19 23:26 91-20-3 ND ug/L 0.50 1 10/14/19 23:26 103-65-1 ND ug/L 0.50 1 10/14/19 23:26 100-42-5 ND ug/L 0.50 1 10/14/19 23:26 630-20-6 ND ug/L 0.50 1 10/14/19 23:26 79-34-5 ND ug/L 0.50 1 1011411923:26 127-18-4 ND ug/L 0.50 1 10/14/19 23:26 108-88-3 M1 ND ug/L 2.0 1 10/14/19 23:26 87-61-6 ND ug/L 2.0 1 10/14/19 23:26 120-82-1 ND ug/L 0.50 1 10/14/19 23:26 71-55-6 ND ug/L 0.50 1 10/14/19 23:26 79-00-5 ND ug/L 0.50 1 10/14/19 23:26 79-01-6 ND ug/L 1.0 1 10114/1923:26 75-69-4 ND ug/L 0.50 1 10/14/19 23:26 96-18-4 ND ug/L 0.50 1 10/14/19 23:26 95-63-6 ND ug/L 0.50 1 10/14/19 23:26 108-67-8 ND ug/L 1.0 1 - 10/14/19 23:26 75-01-4 ND ug/L 1.0 1 10/14/19 23:26 179601-23-1 M1 ND ug/L 0.50 1 10114/1923:26 95-47-6 M1 100 % 70-130 1 10/14/19 23:26 17060-07-0 99 % 70-130 1 10/14/19 23:26 460-00-4 103 % 70-130 1 10/14/19 23:26 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, L-C. Page 11 of 37 ZaceAnalytica! w .pvwlaba w. ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MWS 10-2-19 Pace Project No.: 92447981 Sample: MW-08R Lab ID: 92447981003 Collected: 10/02/19 14:00 Received: 10/02/1916:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Total Dissolved Solids 144 mg/L 25.0 1 10/08/19 00:07 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Sulfate 12.6 mg/L 1.0 1 10/04/1904:02 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Nitrogen, Ammonia 0.10 mg/L 0.10 1 10/11/19 19:12 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Nitrogen, Nitrate ND mg/L 0.040 1 10/02/1923:45 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 20.9 mg/L 1.0 1 10/09/19 20:42 16887-00-6 5310B TOC Analytical Method: SM 531OB-2011 Total Organic Carbon 2.2 mg/L 1.0 1 10/04/19 06:14 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 37 aceAnalXical w pawlabs.00m ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MWS 10-2-19 Pace Project No.: 92447981 Sample: MW-07 Lab ID: 92447981004 Collected: 10/02/1913:45 Received: 10/02/1916:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method Collected By Mark 1 10/09/19 14:39 Swann Collected Date 1012119 1 10/09/19 14:39 Collected Time 13:45 1 10/09/19 14:39 Static Water Level DRY feet 1 10/09/19 14:39 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, L-C. Page 13 of 37 aceAnalytical wwwpacelabs.cdm QUALITY CONTROL DATA Project: MWS 10-2-19 Pace Project No.: 92447981 QC Batch: 501853 Analysis Method: EPA 245.1 Rev 3.0 1994 QC Batch Method: EPA 245.1 Rev 3.0 1994 Analysis Description: 245.1 Mercury Associated Lab Samples: 92447981001, 92447981002, 92447981003 METHOD BLANK: 2698783 Matrix: Water Associated Lab Samples: 92447981001, 92447981002, 92447981003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 10/07/1915:50 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 2698784 Spike LCS LCS % Rae Parameter Units Cone. Result % Rae Limits Qualifiers Mercury ug/L 2.5 2.4 95 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2698785 2698786 MS MSD 92447913002 Spike Spike MS MSD MS MSD % Rae Parameter Units Result Cone. Cone. Result Result % Rae % Rec Limits RPD Qual Mercury ug/L ND 2.5 2.5 2.4 2.5 97 99 70-130 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2698787 2698788 MS MSD 92448067002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rae % Rae Limits RPD Qual Mercury ug/L ND 2.5 2.5 2.4 2.4 95 96 70-130 1 Results presented on this page are in the units indicated by the "Unite" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, L-C. Page 14 of 37 aceAnalytical wwwpabelabs.com QUALITY CONTROL DATA Project: MW'S 10-2-19 Pace Project No.: 92447981 QC Batch: 503205 Analysis Method: EPA 200.7 Rev 4.4 1994 QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET Associated Lab Samples: 92447981001 METHOD BLANK: 2705096 Associated Lab Samples: 92447981001 Parameter Units Arsenic ug/L Barium ug/L Cadmium ug/L Chromium ug/L Iron ug/L Lead ug/L Manganese ug/L Selenium ug/L Silver ug/L Sodium ug/L Matrix: Water Blank Result Reporting Limit Analyzed Qualifiers ND 10.0 10/15/1913:30 NO 5.0 10115/1913:30 NO 1.0 10/15/1913:30 ND 5.0 10/15/1913:30 ND 50.0 10/15/1913:30 BC ND 5.0 10/1511913:30 NO 5.0 10/15/1913:30 NO 10.0 10/15/1913:30 ND 5.0 1011511913:30 ND 5000 10/15/1913:30 Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: Parameter 2705097 Units Spike Conc. LCS Result LCS % Rec %Rae Limits Qualifiers Arsenic ug/L 500 492 98 85-115 Barium ug/L 500 489 98 85-115 Cadmium ug/L 500 489 98 85-115 Chromium ug/L 500 484 97 85-115 Iron ug/L 5000 4600 92 85-115 BC Lead ug/L 500 496 99 85-115 Manganese ug/L 500 488 98 85-115 Selenium ug/L 500 492 98 85-115 Silver ug/L 250 247 99 85-115 Sodium ug/L 5000 4860J 97 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2705098 2705099 MS MSD 2624014001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Arsenic ug/L ND 500 500 473 480 94 96 70-130 2 Barium ug/L ND 500 500 492 497 97 98 70-130 1 Cadmium ug/L ND 500 500 478 481 96 96 70-130 1 Chromium ug/L ND 500 500 477 478 95 96 70.130 0 Iron ug/L ND 5000 5000 5140 5180 102 103 70-130 1 Lead ug/L ND 500 500 463 462 93 92 70-130 0 Manganese ug/L 44.5 500 500 515 516 94 94 70-130 0 Selenium ug/L ND 500 500 481 488 96 98 70-130 1 Silver ug/L ND 250 250 254 255 102 102 70-130 0 Results presented on (his page are in the units Ind tested by the "Units" column except where an alternate unit is presented to the right of the Mail It. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 37 ace Analyticalo wvraypaielaba:ctlrp QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MW S 10-2-19 Pace Project No.: 92447981 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2705098 2705099 MS MSD 2624014001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Sodium ug/L 89600 5000 5000 95900 95400 125 117 70-130 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2705100 MS 92447917001 Spike Parameter Units Result Conc. MSD Spike Conc. 2705101 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Qual Arsenic ug/L ND 500 500 496 494 99 98 70-130 0 Barium ug/L 7.3 500 500 482 475 95 94 70-130 1 Cadmium ug/L ND 500 500 485 482 97 96 70-130 0 Chromium ug/L ND 500 500 471 466 94 93 70-130 1 Iron ug/L 0.089 5000 5000 4800 4740 94 93 70-130 1 BC mg/L Lead ug/L ND 500 500 483 480 97 96 70-130 1 Manganese ug/L 57.8 500 500 531* 526 95 94 70-130 1 Selenium ug/L ND 500 500 511 509 102 102 70-130 0 Silver ug/L ND 250 250 254 253 102 101 70-130 1 Sodium ug/L 7240 5000 5000 12100 12000 97 95 70-130 1 Results presented on this page are in the units indicated by the "Units' column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical services, LLC. Page 16 of 37 ' aceAnalytical w ..paie/abs.wm QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MW S 10-2-19 Pace Project No.: 92447981 QC Batch: 503333 Analysis Method: EPA 200.7 Rev 4.4 1994 QC Balch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET Associated Lab Samples: 92447981002, 92447981003 METHOD BLANK: 2705433 Matrix: Water Associated Lab Samples: 92447981002, 92447981003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Arsenic ug/L ND 10.0 10/1511907:54 Barium ug/L NO 5.0 10/15/19 07:54 Cadmium ug/L NO 1.0 10/15/19 07:54 Chromium ug/L NO 5.0 10/15/19 07:54 Iron ug/L ND 50.0 10/15/19 07:54 Lead ug/L NO 5.0 10/1511907:54 Manganese ug/L ND 5.0 10/15/19 07:54 Selenium ug/L NO 10.0 10/15/19 07:54 Silver ug/L ND 5.0 10/15/19 07:54 Sodium ug/L NO 5000 10/15/19 07:54 LABORATORY CONTROL SAMPLE: 2705434 Spike LCS LCS % Rec Parameter Units Cone. Result %Rec Limits Qualifiers Arsenic ug/L 500 499 100 85-115 Barium ug/L 500 487 97 85-115 Cadmium ug/L 500 492 98 85-115 Chromium ug/L 500 498 100 85-115 Iron ug/L 5000 4710 94 85-115 Lead ug/L 500 508 102 85-115 Manganese ug/L 500 505 101 85-115 Selenium ug/L 500 493 99 85-115 Silver ug/L 250 251 100 85-115 Sodium ug/L 5000 4910J 98 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2705435 2705436 MS MSD 92447981002 Spike Spike MS MSD MS MSD % Rae Parameter Units Result Cone. Cone. Result Result % Rae % Rec Limits RPD Qual Arsenic ug/L NO 500 500 488 485 96 96 70-130 1 Barium ug/L 76.1 500 500 526 518 90 88 70-130 2 Cadmium ug/L NO 500 500 466 458 93 92 70-130 2 Chromium ug/L NO 500 500 449 437 90 87 70-130 3 Iron ug/L 50800 5000 5000 53200 53700 48 58 70-130 1 M1 Lead ug/L ND 500 500 470 464 93 92 70-130 1 Manganese ug/L 12700 500 500 12400 13000 -52 57 70-130 4 M1 Selenium ug/L ND 500 500 493 491 97 97 70-130 0 Silver ug/L NO 250 250 248 242 98 96 70-130 2 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 37 ZeAnalyficalo wwwpacefabs.com QUALITY CONTROL DATA Project: MWS 10-2-19 Pace Project No.: 92447981 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2705435 2705436 MS MSD 92447981002 Spike Spike MS MSD MS MSD % Rae Parameter Units Result Cone. Cone. Result Result % Rae % Rae Limits RPD Qual Sodium ug/L 14300 5000 5000 18600 18600 84 86 70-130 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2705437 MS 92448137001 Spike Parameter Units Result Cone. MSD Spike Cone. 2705438 MS Result MSD Result MS % Rae MSD % Rae % Rae Limits RPD Qual Arsenic ug/L 0.0105 500 500 509 509 101 101 70-130 0 mg/L Barium ug/L 0.024 500 500 492 487 94 93 70-130 1 mg/L Cadmium ug/L 0.00105 500 500 486 481 97 96 70-130 1 mg/L Chromium ug/L 0.00505 500 500 465 460 93 92 70-130 1 mg/L Iron ug/L 0.37 5000 5000 5060 5040 94 94 70-130 0 mg/L Lead ug/L 0.00505 500 500 479 474 96 94 70-130 1 mg/L Manganese ug/L 0.016 500 500 484 483 94 93 70-130 0 mg/L Selenium ug/L 0.0105 500 500 520 515 103 102 70-130 1 mg/L Silver ug/L 0.00505 250 250 253 252 101 101 70-130 0 mg/L Sodium ug/L 44.7 5000 5000 47900 49100 63 87 70-130 2 M1 mg/L Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, L-C. Page 18 of 37 (�;ZeAnalyfical- wew.paoilabsooso QUALITY CONTROL DATA Project: MWS 10-2-19 Pace Project No.: 92447981 QC Batch: 503296 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Description: 6200B MSV Associated Lab Samples: 92447981001, 92447981002 METHOD BLANK: 2705348 Matrix: Water Associated Lab Samples: 92447981001, 92447981002 Blank Reporting Parameter Units Result Limit Analyzed 1,1,1,2-Tetrachloroelhane ug/L ND 0.50 10/14/19 00:17 1,1,1-Trichloroethane ug/L ND 0.50 10/14/19 00:17 1,1,2,2-Tetrachloroethane ug/L ND 0.50 10/14/19 00:17 1,1,2-Trichloroethane ug/L ND 0.50 10/1411900:17 1,1-Dichloroethane ug/L ND 0.50 10/14/19 00:17 1,1-Dichioroethene ug/L ND 0.50 10/14/19 00:17 1,1-Dichloropropene ug/L ND 0.50 10/14/19 00:17 1,2,3-Trichlorobenzene ug/L ND 2.0 10/14/19 00:17 1,2,3-Trichloropropane ug/L ND 0.50 10/14/19 00:17 1,2,4-Trichlorobenzene ug/L NO 2.0 10/14/19 00:17 1,2,4-Trimethylbenzene ug/L NO 0.50 10/14/19 00:17 1,2-Dibromo-3-chioropropane ug/L ND 1.0 10/14/19 00:17 1,2-Dibromoethane (EDB) ug/L ND 0.50 10/14/19 00:17 1,2-Dichlorobenzene ug/L ND 0.50 10/14/19 00:17 1,2-Dichloroethane ug/L ND 0.50 1011411900:17 1,2-Dichloropropane ug/L ND 0.50 10/14/19 00:17 1,3,5-Trimethylbenzene ug/L ND 0.50 10/14/19 00:17 1,3-Dichlorobenzene ug/L NO 0.50 10/14/19 00:17 1,3-Dichloropropane ug/L ND 0,50 10/14/19 00:17 1,4-Dichlorobenzene ug/L NO 0.50 10/14/19 00:17 2,2-Dichloropropane ug/L ND 0.50 10/14/19 00:17 2-Chlorotoluene ug/L ND 0.50 10/14/19 00:17 4-Chlorotoluene ug/L ND 0.50 10/14/19 00:17 Benzene ug/L ND 0.50 10/14/19 00:17 Bromobenzene ug/L ND 0.50 10/14/19 00:17 Bromochloromelhane ug/L ND 0.50 10/14/19 00:17 Bromodichloromethane ug/L ND 0.50 10/14/19 00:17 Bromoform ug/L NO 0.50 10/14/19 00:17 Bromomethane ug/L NO 5.0 10/14/19 00:17 Carbon tetrachloride ug/L NO 0.50 10/14/19 00:17 Chlorobenzene ug/L ND 0.50 10/14/19 00:17 Chloroethane ug/L ND 1.0 10/14/19 00:17 Chloroform ug/L ND 5.0 10/14/19 00:17 Chloromethane ug/L ND 1.0 10114/1900:17 cis-1,2-Dichloroethene ug/L ND 0.50 10/14/19 00:17 cis-1,3-Dichloropropene ug/L NO 0.50 10/1411900:17 Dibromochloromethane ug/L ND 0.50 10/14/19 00:17 Dibromomethane ug/L ND 0.50 10/14/19 00:17 Dichlorodifluoromethane ug/L ND 0.50 10/14/19 00:17 Diisopropyl ether ug/L ND 0.50 10/14/19 00:17 Ethyibenzene ug/L ND 0.50 10/14/19 00:17 Qualifiers Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 37 • aceAnalyiical® .pacelabs com QUALITY CONTROL DATA Project: MWS 10-2-19 Pace Project No.: 92447981 METHOD BLANK: 2705348 Matrix: Water Associated Lab Samples: 92447981001, 92447981002 Blank Reporting Parameter Units Result Limit Analyzed Hexachloro-1,3-butadiene ug/L ND 2.0 10/14/19 00:17 Isopropylbenzene (Cumene) ug/L ND 0.50 10/14/19 00:17 m&p-Xylene ug/L ND 1.0 10/14/19 00:17 Methyl-tert-butyl ether ug/L ND 0.50 10/14/19 00:17 Methylene Chloride ug/L ND 2.0 1011411900:17 n-Butylbenzene ug/L ND 0.50 10/14/19 00:17 n-Propylbenzene ug/L ND 0.50 10/14/19 00:17 Naphthalene ug/L NO 2.0 10/14/19 00:17 o-Xylene ug/L ND 0.50 10/14/19 00:17 sec-Butylbenzene ug/L ND 0.50 10/14/19 00:17 Styrene ug/L ND 0.50 10/14/19 00:17 tert-Butylbenzene ug/L NO 0.50 10/14/19 00:17 Tetrachloroethene ug/L ND 0.50 10/14/19 00:17 Toluene ug/L ND 0.50 10114/1900:17 trans-1,2-Dichloroethene ug/L ND 0.50 10/14/19 00:17 trans-1,3-Dichloropropene ug/L NO 0.50 10/14/19 00:17 Trchloroethene ug/L ND 0.50 10/14/19 00:17 Trichlorofluoromethane ug/L ND 1.0 10/14/19 00:17 Vinyl chloride ug/L ND 1.0 10/14/19 00:17 1,2-Dichloroethane-d4 (S) e/ 93 70-130 10/14/19 00:17 4-Bromofluorobenzene(S) % 98 70-130 10/14/19 00:17 Toluene-d8 (S) % 112 70-130 10/14/19 00:17 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2705349 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 55.5 111 60-140 1,1,1-Trichloroethane ug/L 50 44.5 89 60-140 1,1,2,2-Tetrachloroethane ug/L 50 57.8 116 60-140 1,1,2-Trichloroethane ug/L 50 54.6 109 60-140 1,1-Dichloroethane ug/L 50 46.2 92 60-140 1,1-Dichloroethene ug/L 50 47.8 96 60-140 1,1-Dichloropropene ug/L 50 50.0 100 60-140 1,2,3-Trichlorobenzene ug/L 50 53.9 108 60-140 1,2,3-Trichloropropane ug/L 50 62.7 125 60-140 1,2,4-Trichlorobenzene ug/L 50 50.3 101 60-140 1,2,4-Trimethylbenzene ug/L 50 51.3 103 60-140 1,2-Dibromo-3-chloropropane ug/L 50 51.3 103 60-140 1,2-Dibromoethane (EDB) ug/L 50 55.2 110 60-140 1,2-Dichlorobenzene ug/L 50 51.2 102 60-140 1,2-Dichloroethane ug/L 50 57.4 115 60-140 1,2-Dichloropropane ug/L 50 52.7 105 60-140 1,3,5-Trimethylbenzene ug/L 50 50.3 101 60-140 1,3-Dichlorobenzene ug/L 50 49.0 98 60-140 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Qualifiers Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, L-C. Page 20 of 37 aceAnalytical amwpocslabs:com.. QUALITY CONTROL DATA Project: MWS 10-2-19 Pace Project No.: 92447981 LABORATORY CONTROL SAMPLE: Parameter 2705349 Units Spike Conc. LCS Result LCS % Rec e/ Rao Limits 1,3-Dichloropropane ug/L 50 58.9 118 60-140 1,4-Dichlorobenzene ug/L 50 50.5 101 60-140 2,2-Dichloropropane ug/L 50 42.0 84 60-140 2-Chlorotoluene ug/L 50 51.6 103 60-140 4-Chlorotoluene ug/L 50 51.8 104 60-140 Benzene ug/L 50 51.1 102 60-140 Bromobenzene ug/L 50 48.9 98 60-140 Bromochloromethane ug/L 50 42.4 85 60-140 Bromodichloromethane ug/L 50 53.7 107 60-140 Bromoform ug/L 50 48.0 96 60-140 Bromomethane ug/L 50 50.0 100 60-140 Carbon tetrachloride ug/L 50 48.7 97 60-140 Chlorobenzene ug/L 50 50.7 101 60-140 Chloroethane ug/L 50 44.7 89 60-140 Chloroform ug/L 50 47.3 95 60-140 Chloromethane ug/L 50 49.8 100 60-140 cis-1,2-Dichloroelhene ug/L 50 46.8 94 60-140 cis-1,3-Dichloropropene ug/L 50 57.3 115 60-140 Dibromochloromethane ug/L 50 49.8 100 60-140 Dibromomethane ug/L 50 48.9 98 60-140 Dichlorodifluoromethane ug/L 50 42.3 85 60-140 Diisopropyl ether ug/L 50 52.4 105 60-140 Ethylbenzene ug/L 50 51.9 104 60-140 Hexachloro-1,3-butadiene ug/L 50 50.4 101 60-140 Isopropylbenzene (Cumene) ug/L 50 53.2 106 60-140 m&p-Xylene ug/L 100 107 107 60-140 Methyl-tert-butyl ether ug/L 50 53.8 108 60-140 Methylene Chloride ug/L 50 51.8 104 60-140 n-Butylbenzene ug/L 50 48.0 96 60-140 n-Propylbenzene ug/L 50 48.5 97 60-140 Naphthalene ug/L 50 48.6 97 60-140 o-Xylene ug/L 50 51.3 103 60-140 sec-Butylbenzene ug/L 50 48.8 98 60-140 Styrene ug/L 50 52.0 104 60-140 tert-Butylbenzene ug/L 50 43.6 87 60-140 Tetrachloroethene ug/L 50 49.7 99 60-140 Toluene ug/L 50 48.2 96 60-140 trans-1,2-Dichloroethene ug/L 50 46.6 93 60-140 trans-1,3-Dichloropropene ug/L 50 55.9 112 60-140 Trichloroethene ug/L 50 50.9 102 60-140 Trichlorofluoromethane ug/L 50 45.4 91 60-140 Vinyl chloride ug/L 50 46.8 94 60-140 1,2-Dichloroethane-d4 (S) % 108 70-130 4-Bromofluorobenzene (S) % 110 70-130 Toluene-d8 (S) % 95 70-130 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 37 aceAnalyiical 'wvrxpaiulabscam. QUALITY CONTROL DATA Project: MW'S 10-2-19 Pace Project No.: 92447981 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2705350 MS 92447981002 Spike Parameter Units Result Conc. MSD Spike Conc. 2705351 MS Result MSD Result MS % Rec MSD % Rec % Rao Limits RPD Qual 1,1,1,2-Tetrachloroethane ug/L NO 20 20 21.2 21.0 106 105 60-140 1 1,1,1-Trichloroethane ug/L NO 20 20 19.5 21.3 98 107 60-140 9 1,1,2,2-Tetrachloroethane ug/L NO 20 20 22.2 22.5 111 113 60-140 1 1,1,2-Trichloroethane ug/L NO 20 20 22.4 23.3 112 116 60-140 4 1,1-Dichloroethane ug/L NO 20 20 21.3 22.9 106 114 60-140 7 1,1-Dichloroethene ug/L NO 20 20 27.8 28.3 139 142 60-140 2 M1 1,1-Dichloropropene ug/L ND 20 20 23.2 24.2 116 121 60-140 4 1,2,3-Trichlorobenzene ug/L ND 20 20 20.9 21.4 104 107 60-140 2 1,2,3-Trichooropropane ug/L NO 20 20 31.7 29.2 159 146 60-140 8 M1 1,2,4-Trichlorobenzene ug/L ND 20 20 19.6 20.6 98 103 60-140 5 1,2,4-Trimethylbenzene ug/L NO 20 20 22.5 21.3 113 106 60-140 6 1,2-Dibromo-3-chloropropane ug/L NO 20 20 19.3 18.0 96 90 60-140 7 1,2-Dibromoethane (EDB) ug/L NO 20 20 20.9 20.2 104 101 60-140 3 1,2-Dichlorobenzene ug/L NO 20 20 21.2 21.4 106 107 60-140 1 1,2-Dichloroethane ug/L NO 20 20 22.7 24.2 114 121 60-140 6 1,2-Dichloropropane ug/L NO 20 20 23.0 24.1 115 121 60-140 5 1,3,5-Trimethylbenzene ug/L ND 20 20 21.4 21.6 107 108 60-140 1 1,3-Dichlorobenzene ug/L ND 20 20 21.3 20.9 107 105 60-140 2 1,3-Dichloropropane ug/L NO 20 20 22.9 23.0 115 115 60-140 1 1,4-Dichlorobenzene ug/L NO 20 20 20.9 21.3 104 107 60-140 2 2,2-Dichloropropane ug/L NO 20 20 19.8 22.1 99 111 60-140 11 2-Chlorotoluene ug/L NO 20 20 22.7 22.8 114 114 60-140 0 4-Chlorotoluene ug/L ND 20 20 22.0 21.9 110 110 60-140 0 Benzene ug/L NO 20 20 22.1 23.0 111 115 60-140 4 Bromobenzene ug/L ND 20 20 21.1 20.4 106 102 60-140 3 Bromochloromethane ug/L ND 20 20 17.6 19.8 88 99 60-140 12 Bromodichloromethane ug/L NO 20 20 22.5 23.1 112 115 60A40 2 Bromoform ug/L ND 20 20 18.4 17.3 92 86 60-140 6 Bromomethane ug/L NO 20 20 31.9 37.1 160 186 60-140 15 Ml Carbon tetrachloride ug/L ND 20 20 20.4 21.5 102 107 60-140 5 Chlorobenzene ug/L ND 20 20 21.8 21.8 109 109 60-140 0 Chloroethane ug/L ND 20 20 28.0 28.5 140 143 60-140 2 M1 Chloroform ug/L ND 20 20 20.0 23.3 100 117 60-140 15 Chloromethane ug/L ND 20 20 24.7 26.6 123 133 60-140 8 cis-1,2-Dichloroethene ug/L ND 20 20 20.7 23.2 103 116 60-140 11 cis-1,3-Dichloropropene ug/L ND 20 20 23.0 24.0 115 120 60-140 5 Dibromochloromethane ug/L NO 20 20 19.3 19.4 96 97 60-140 1 Dibromomethane ug/L NO 20 20 19.8 20.6 99 103 60-140 4 Dichlorodlfluoromethane ug/L ND 20 20 19.3 23.3 96 117 60-140 19 Diisopropyl ether ug/L ND 20 20 22.9 23.2 115 116 60-140 1 Ethylbenzene ug/L ND 20 20 22.4 23.0 112 115 60-140 3 Hexachloro-1,3-butadiene ug/L ND 20 20 23.7 24.1 119 120 60-140 1 Isopropylbenzene (Cumene) ug/L NO 20 20 22.4 22.9 112 115 60-140 2 m&p-Xylene ug/L ND 40 40 46.7 47.8 117 120 60-140 2 Methyl-tert-butyl ether ug/L NO 20 20 21.1 21.9 106 109 60-140 4 Methylene Chloride ug/L NO 20 20 22.7 26.4 113 132 60-140 15 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 37 aceAnalytical o wwwiaam,labs.com QUALITY CONTROL DATA Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MW'S 10-2-19 Pace Project No.: 92447981 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2705350 2705351 MS MSD 92447981002 Spike Spike MS MSD MS MSD e/ Rao Parameter Units Result Conc. Conc. Result Result % Rec % Rao Limits RPD Dual n-Butylbenzene ug/L ND 20 20 22.1 22.7 111 114 60-140 3 n-Propylbenzene ug/L ND 20 20 22.0 21.7 110 108 60-140 2 Naphthalene ug/L ND 20 20 19.8 19.2 99 96 60.140 3 o-Xylene ug/L ND 20 20 21.8 22.7 109 113 60-140 4 sec-Butylbenzene ug/L ND 20 20 22.6 22.6 113 113 60-140 0 Styrene ug/L ND 20 20 21.9 22.6 110 113 60-140 3 tert-Butylbenzene ug/L ND 20 20 18.5 18.3 92 92 60-140 1 Tetrachloroethene ug/L ND 20 20 22.5 21.4 112 107 60-140 5 Toluene ug/L ND 20 20 22.0 22.8 110 114 60-140 4 trans-1,2-Dichloroethene ug/L ND 20 20 20.9 23.4 104 117 60-140 12 trans-1,3-Dichloropropene ug/L ND 20 20 22.0 22.6 110 113 60-140 3 Trichloroethene ug/L ND 20 20 21.6 21.5 108 107 60-140 1 Trichlorolluoromelhane ug/L ND 20 20 27.4 28.7 137 143 60-140 4 Mt Vinyl chloride ug/L ND 20 20 26.9 28.5 134 142 60-140 6 M1 1,2-Dichloroethane-d4 (S) % 102 107 70-130 4-Bromofluorobenzene (S) % 105 105 70-130 Toluene-d8 (S) % 101 104 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 37 aceAnalyticalo w ..paiefsbs.cam QUALITY CONTROL DATA Project: MW'S 10-2-19 Pace Project No.: 92447981 QC Batch: 503388 Analysis Method: SM 6200B QC Balch Method: SM 6200B Analysis Description: 6200B MSV Associated Lab Samples: 92447981003 METHOD BLANK: 2705775 Associated Lab Samples: 92447981003 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 0.50 10/14/19 17:47 1,1,1-Trichloroethane ug/L ND 0.50 10/14/19 17:47 1,1,2,2-Tetrachloroethane ug/L ND 0.50 10/14/19 17:47 1,1,2-Trichloroethane ug/L ND 0.50 10/14/19 17:47 1,1-Dichloroethane ug/L ND 0.50 10/14/19 17:47 1,1-Dichloroethene ug/L ND 0.50 10/14/19 17:47 1,1-Dichloropropene ug/L NO 0.50 10/14/19 17:47 1,2,3-Trichlorobenzene ug/L ND 2.0 10/14/19 17:47 1,2,3-Trichloropropane ug/L ND 0.50 10/14/19 17:47 1,2,4-Trichlorobenzene ug/L ND 2.0 10114/1917:47 1,2,4-Trimethylbenzene ug/L NO 0.50 10/14/19 17:47 1,2-Dibromo-3-chloropropane ug/L ND 1.0 10/14/19 17:47 1,2-Dibromoethene (EDB) ug/L NO 0.50 10/14/19 17:47 1,2-Dichlorobenzene ug/L ND 0.50 10/14/19 17:47 1,2-Dichloroethane ug/L ND 0.50 10/14/19 17:47 1,2-Dichloropropane ug/L ND 0.50 10/14/19 17:47 1,3,5-Trimethylbenzene ug/L ND 0.50 10/1411917:47 1,3-Dichlorobenzene ug/L ND 0.50 10/1411917:47 1,3-Dichloropropane ug/L ND 0.50 10/14/19 17:47 1,4-Dichlorobenzene ug/L ND 0.50 10/14/19 17:47 2,2-Dichloropropane ug/L NO 0.50 10/14/19 17:47 2-Chlorotoluene ug/L NO 0.50 10/14/19 17:47 4-Chlorotoluene ug/L ND 0.50 10/14/19 17:47 Benzene ug/L ND 0.50 10/14/19 17:47 Bromobenzene ug/L NO 0.50 10/14/19 17:47 Bromochloromethane ug/L ND 0.50 10/14/19 17:47 Bromodichloromethane ug/L ND 0.50 10/14/19 17:47 Bromoform ug/L ND 0.50 10/1411917:47 Bromomethane ug/L ND 5.0 10/14/19 17:47 Carbon tetrachloride ug/L ND 0.50 10/14/19 17:47 Chlorobenzene ug/L ND 0.50 10/14/19 17:47 Chloroethane ug/L ND 1.0 10/14/19 17:47 Chloroform ug/L ND 5.0 10/14/19 17:47 Chloromethane ug/L ND 1.0 10/14/19 17:47 cis-1,2-Dichloroethene ug/L NO 0.50 10/14/19 17:47 cis-1,3-Dichloropropene ug/L ND 0.50 10/14/19 17:47 Dibromochloromethane ug/L ND 0.60 10/14/19 17:47 Dibromomethane ug/L ND 0.50 10114/1917:47 DichlorodiFluoromethane ug/L ND 0.50 10/14/19 17:47 Dilsopropyl ether ug/L NO 0.50 10/14/19 17:47 Ethylbenzene ug/L NO 0.50 10/14/19 17:47 Qualifiers Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 37 ace Analytical wemlpabelabecam QUALITY CONTROL DATA Project: MW S 10-2-19 Pace Project No.: 92447981 METHOD BLANK: 2705775 Associated Lab Samples: 92447981003 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Hexachloro-1,3-butadiene ug/L ND 2.0 10/14/19 17:47 Isopropylbenzene (Cumene) ug/L NO 0,50 10/14/19 17:47 m&p-Xylene - ug/L ND. 1.0 10/14/19 17:47 Methyl-tert-butyl ether ug/L NO 0.50 10/14/19 17:47 Methylene Chloride ug/L NO 2.0 10/14/19 17:47 n-Butylbenzene ug/L NO 0.50 10/14/19 17:47 n-Propylbenzene ug/L NO 0.50 10/14/19 17:47 Naphthalene ug/L NO 2.0 10/14/19 17:47 o-Xylene ug/L NO 0.50 10/14/19 17:47 sec-Butylbenzene ug/L ND 0.50 10/14/19 17:47 Styrene ug/L ND 0.50 10/14/19 17:47 tert-Butylbenzene ug/L ND 0.50 10/14/19 17:47 Tetrachloroethene ug/L ND 0.50 10/1411917:47 Toluene ug/L NO 0.50 10/1411917:47 trans-1,2-Dichloroethene ug/L ND 0.50 10114/1917:47 trans-1,3-Dichloropropene ug/L NO 0.50 1011411917:47 Trichloroethene ug/L NO 0.50 10/14/19 17:47 Trichlorofluoromethane ug/L ND 1.0 10/14/19 17:47 Vinyl chloride ug/L ND 1.0 10/14/19 17:47 1,2-Dichloroethane-d4 (S) % 100 70-130 10/14/19 17:47 4-Bromofluorobenzene (S) % 97 70-130 10/14/19 17:47 Toluene-d8 (S) % 100 70-130 10/14/19 17:47 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2705776 Units Spike Conc. LIDS Result LCS % Rao % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 54.5 109 60-140 1,1,1-Trichloroethane ug/L 50 59.2 118 60-140 1,1,2,2-Tetrachloroethane ug/L 50 51.6 103 60-140 1,1,2-Trichloroethane ug/L 50 57.2 114 60-140 1,1-Dichloroethane ug/L 50 57.7 115 60-140 1,1-Dichloroethene ug/L 50 58.6 117 60-140 1,1-Dichloropropene ug/L 50 59.6 119 60-140 1,2,3-Trichlorobenzene ug/L 50 53.3 107 60-140 1,2,3-Trichloropropane ug/L 50 52.5 105 60-140 1,2,4-Trichlorobenzene ug/L 50 51.3 103 60-140 1,2,4-Trimethylbenzene ug/L 50 52.0 104 60-140 1,2-Dibromo-3-chloropropane ug/L 50 53.0 106 60-140 1,2-Dibromoethane (EDB) ug/L 50 56.0 112 60-140 1,2-Dlchlorobenzene ug/L 50 52.3 105 60-140 1,2-Dichloroethane ug/L 50 54.2 108 60-140 1,2-Dichloropropane ug/L 50 55.3 111 60-140 1,3,5-Trimethylbenzene ug/L 50 52.9 106 60-140 1,3-Dichlorobenzene ug/L 50 51.6 103 60-140 Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Qualifiers Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 37 aceAnalXical ' wwwpooclabs:wrn QUALITY CONTROL DATA Project: MW S 10-2-19 Pace Project No.: 92447981 LABORATORY CONTROL SAMPLE: Parameter 2705776 Units Spike Conc. 1-CS Result LCS % Rec % Rec Limits 1,3-Dichloropropane ug/L 50 55.1 110 60-140 1,4-Dichlorobenzene ug/L 50 51.2 102 60-140 2,2-Dichloropropane ug/L 50 64.0 128 60-140 2-Chlorotoluene ug/L 50 51.9 104 60-140 4-Chlorotoluene ug/L 50 51.1 102 60-140 Benzene ug/L 50 55.3 111 60-140 Bromobenzene ug/L 50 51.8 104 60-140 Bromochloromethane ug/L 50 58.8 118 60-140 Bromodichloromethane ug/L 50 58.8 118 60-140 Bromoform ug/L 50 55.9 112 60-140 Bromomethane ug/L 50 51.2 102 60-140 Carbon tetrachloride ug/L 50 56.5 113 60-140 Chlorobenzene ug/L 50 52.1 104 60-140 Chloroelhane ug/L 50 50.0 100 60-140 Chloroform ug/L 50 57.2 114 60-140 Chloromethane ug/L 50 46.1 92 60-140 cis-1,2-Dichloroethene ug/L 50 57.7 115 60-140 cis-1,3-Dichloropropene ug/L 50 60.6 121 60-140 Dibromochloromethane ug/L 50 55.1 110 60-140 Dibromomethane ug/L 50 58.0 116 60-140 Dichlorodifluoromethane ug/L 50 60.6 121 60-140 Diisopropyl ether ug/L 50 56.9 114 60-140 Ethylbenzene ug/L 50 53.3 107 60-140 Hexachloro-1,3-butadiene ug/L 50 52.2 104 60-140 Isopropylbenzene (Cumene) ug/L 50 54.0 108 60-140 m&p-Xylene ug/L 100 107 107 60-140 Methyl-tert-butyl ether ug/L 50 62.4 125 60-140 Methylene Chloride ug/L 50 55.2 110 60-140 n-Butylbenzene ug/L 50 52.7 105 60-140 n-Propylbenzene ug/L 50 52.0 104 60-140 Naphthalene ug/L 50 52.3 105 60-140 o-Xylene ug/L 50 55.1 110 60-140 sec-Butylbenzene ug/L 50 54.2 108 60-140 Styrene ug/L 50 53.7 107 60-140 tert-Butylbenzene ug/L 50 46.4 93 60-140 Tetrachloroethene ug/L 50 55.1 110 60-140 Toluene ug/L 50 53.9 108 60-140 trans-1,2-Dichloroethene ug/L 50 57.8 116 60-140 trans-1,3-Dlchloropropene ug/L 50 58.8 118 60-140 Trichloroethene ug/L 50 57.4 115 60-140 Trichlorofluoromethane ug/L 50 59.5 119 60-140 Vinyl chloride ug/L 50 58.3 117 60-140 1,2-Dichloroethane-d4 (S) % 107 70-130 4-Bromofluorobenzene (S) % 102 70-130 Toluene-d8 (S) % 99 70-130 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Qualifiers Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, U.C. Page 26 of 37 dC Analytical w ..paidfabaixvp QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MWS 10-2-19 Pace Project No.: 92447981 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2705777 2705778 MS MSD 92447981003 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 2000 2000 2180 2250 109 112 60-140 3 1,1,1-Trichloroethane ug/L ND 2000 2000 2300 2440 115 122 60-140 6 1,1,2,2-Tetrachloroethane ug/L ND 2000 2000 2060 2160 103 108 60-140 5 1,1,2-Trichloroethane ug/L ND 2000 2000 2230 2320 112 116 60-140 4 1,1-Dichloroethane ug/L ND 2000 2000 2290 2330 114 116 60-140 2 1,1-Dichloroethene ug/L ND 2000 2000 2330 2400 117 120 60-140 3 1,1-Dichloropropene ug/L ND 2000 2000 2340 2380 117 119 60-140 2 1,2,3-Trichlorobenzene ug/L ND 2000 2000 1940 2080 97 104 60-140 7 1,2,3-Trichloropropane ug/L ND 2000 2000 2060 2100 103 105 60-140 2 1,2,4-Trichlorobenzene ug/L ND 2000 2000 1900 2080 95 104 60-140 9 1,2,4-Trimethylbenzene ug/L ND 2000 2000 2520 2650 126 132 60-140 5 1,2-Dibromo-3-chloropropane ug/L ND 2000 2000 2030 2160 101 108 60-140 6 1,2-Dibromoethane (EDB) ug/L ND 2000 2000 2120 2200 106 110 60-140 4 1,2-Dichlorobenzene ug/L ND 2000 2000 2060 2190 103 109 60-140 6 1,2-Dichloroethane ug/L ND 2000 2000 2090 2180 104 109 60-140 5 1,2-Dichloropropane ug/L ND 2000 2000 2180 2260 109 113 60-140 4 1,3,5-Trimethylbenzene ug/L ND 2000 2000 2250 2360 112 118 60-140 5 1,3-Dichlorobenzene ug/L ND 2000 2000 2030 2140 102 107 60-140 5 1,3-Dichloropropane ug/L ND 2000 2000 2130 2190 107 110 60-140 3 1,4-Dichlorobenzene ug/L ND 2000 2000 2020 2140 101 107 60-140 6 2,2-Dichloropropane ug/L ND 2000 2000 2340 2420 117 121 60-140 3 2-Chlorotoluene ug/L ND 2000 2000 2110 2150 106 107 60-140 2 4-Chlorotoluene ug/L ND 2000 2000 2050 2170 103 108 60-140 5 Benzene ug/L ND 2000 2000 11200 11300 561 563 60-140 0 M1 Bromobenzene ug/L ND 2000 2000 2090 2190 105 110 60-140 5 Bromochloromethane ug/L ND 2000 2000 2250 2260 112 113 60-140 1 Bromodichloromethane ug/L ND 2000 2000 2330 2450 117 122 60-140 5 Bromoform ug/L ND 2000 2000 2180 2270 109 113 60-140 4 Bromomelhane ug/L ND 2000 2000 1370 1630 68 82 60-140 18 Carbon tetrachloride ug/L ND 2000 2000 2370 2430 118 122 60-140 3 Chlorobenzene ug/L ND 2000 2000 2120 2200 106 110 60-140 4 Chloroethane ug/L ND 2000 2000 2210 2310 110 115 60-140 4 Chloroform ug/L ND 2000 2000 2220 2230 111 112 60-140 1 Chloromethane ug/L ND 2000 2000 1800 1920 90 96 60-140 6 cis-1,2-Dichloroethene ug/L ND 2000 2000 2220 2280 111 114 60-140 3 cis-1,3-Dichloropropene ug/L ND 2000 2000 2360 2450 118 122 60-140 4 Dibromochloromethane ug/L ND 2000 2000 2170 2270 109 113 60-140 4 Dibromomethane ug/L ND 2000 2000 2230 2320 111 116 60-140 4 Dichlorodifluoromethane ug/L ND 2000 2000 2220 2200 111 110 60-140 1 Diisopropyl ether ug/L ND 2000 2000 3790 3910 189 195 60-140 3 M1 Elhylbenzene ug/L ND 2000 2000 2980 3030 149 152 60-140 2 M1 Hexachloro-1,3-butadiene ug/L ND 2000 2000 2030 2150 102 108 60-140 6 Isopropylbenzene (Cumene) ug/L ND 2000 2000 2210 2310 111 116 60-140 4 m&p-Xylene ug/L ND 4000 4000 7460 7510 186 188 60-140 1 M1 Methyl-tert-butyl ether ug/L ND 2000 2000 2260 2380 113 119 60-140 5 Methylene Chloride ug/L ND 2000 2000 2090 2170 104 108 60-140 4 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 37 r.-A'OAnaWicalo w .pacefabecom QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MWS 10-2-19 Pace Project No.: 92447981 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2705777 2705778 MS MSD 92447981003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result %Rec e/ Rec Limits RPD Qua] n-Butylbenzene ug/L ND 2000 2000 2010 2190 100 109 60-140 9 n-Propy]benzene ug/L ND 2000 2000 2130 2250 107 112 60-140 5 Naphthalene ug/L ND 2000 2000 2060 2200 103 110 60-140 7 o-Xylene ug/L ND 2000 2000 2940 2970 147 149 60-140 1 M1 sec-Butylbenzene ug/L ND 2000 2000 2170 2300 109 115 60-140 6 Styrene ug/L ND 2000 2000 2180 2240 109 112 60-140 3 tert-Butylbenzene ug/L ND 2000 2000 1850 1980 93 99 60-140 7 Tetrachloroethene ug/L ND 2000 2000 2200 2260 110 113 60-140 3 Toluene ug/L ND 2000 2000 8620 8550 431 427 60-140 1 M1 trans-1,2-Dichloroelhene ug/L ND 2000 2000 2240 2350 112 118 60-140 5 trans-1,3-Dichloropropene ug/L ND 2000 2000 2260 2350 113 117 60-140 4 Trichloroethene ug/L ND 2000 2000 2360 2400 118 120 60-140 2 Trichlorofluoromethane ug/L ND 2000 2000 2430 2480 122 124 60-140 2 Vinyl chloride ug/L ND 2000 2000 2350 2390 118 119 60-140 1 1,2-Dichloroethane-d4 (S) % 100 102 70-130 4-Bromofluorobenzene (S) % 101 101 70-130 Toluene-d8 (S) % 99 100 70-130 Results presented on this page are in the units Intl tested by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, U.C. Page 28 of 37 aceAnalyticalo ..paselabscom QUALITY CONTROL DATA Project: MWS 10-2-19 Pace Project No.: 92447981 QC Batch: 501840 Analysis Method: SM 2540C-2011 QC Batch Method: SM 2540C-2011 Analysis Description: 2540C Total Dissolved Solids Associated Lab Samples: 92447981001, 92447981002, 92447981003 METHOD BLANK: 2698641 Matrix: Water Associated Lab Samples: 92447981001, 92447981002, 92447981003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L NO 25.0 10/08/19 00:06 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 2698642 Spike LCS LCS % Rec Parameter Units Conc. Result % Rao Limits Qualifiers Total Dissolved Solids mg/L 250 248 99 90-110 SAMPLE DUPLICATE: 2698643 92447775004 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 41.0 41.0 0 SAMPLE DUPLICATE: 2698644 92447981002 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 239 234 2 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, L-C. Page 29 of 37 ace Analytical 'www.pacelabs.cdm QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MWS 10-2-19 Pace Project No.: 92447981 QC Batch: 501340 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92447981001, 92447981002 METHOD BLANK: 2696405 Matrix: Water Associated Lab Samples: 92447981001, 92447981002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L NO 1.0 10/03/19 22:35 LABORATORY CONTROL SAMPLE: 2696406 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 50 53.3 107 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2696407 2696408 MS MSD 92446196002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Sulfate mg/L 312 50 50 355 353 85 82 90-110 0 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2696409 2696410 MS MSD 92447949001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Sulfate mg/L 90.0 50 50 123 123 67 65 90-110 1 M1 Results presented on this page are in the units Indicated by the "Units' column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 37 aceAnalyiical w wpacelabs.com QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MWS 10-2-19 Pace Project No.: 92447981 QC Batch: 501418 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92447981003 METHOD BLANK: 2696606 Matrix: Water Associated Lab Samples: 92447981003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L ND 1.0 10/0411900:31 LABORATORY CONTROL SAMPLE: 2696607 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 50 52.3 105 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2696608 2696609 MS MSD 92447775005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Sulfate mg/L 17.1 50 50 70.1 70.5 106 107 90-110 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 37 aceAnalXical e www.pace/abs.cvm QUALITY CONTROL DATA Project: MWS 10-2-19 Pace Project No.: 92447981 QC Batch: 503027 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Associated Lab Samples: 92447981001, 92447981002, 92447981003 METHOD BLANK: 2703937 Matrix: Water Associated Lab Samples: 92447981001, 92447981002, 92447981003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 10/11/19 18:52 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 2703938 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 4.8 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2703939 MS 92447924001 Spike Parameter Units Result Cone. Nitrogen, Ammonia mg/L 0.10 5 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2703941 MS 92447922002 Spike Parameter Units Result Cone. Nitrogen, Ammonia mg/L 14.3 5 2703940 MSD Spike MS MSD MS MSD %Rec Cone. Result Result % Rec % Rec Limits RPD 5 4.9 4.9 95 95 90-110 0 2703942 MSD Spike MS MSD MS MSD e/ Rec Cone. Result Result % Rec % Rec Limits RPD 5 18.8 18.8 91 90 90-110 0 Results presented on this page are in the units Intl icated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Qual Qual Page 32 of 37 .00011111 aceAnalytical www.pocelabs.com QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MW S 10-2-19 Pace Project No.: 92447981 QC Batch: 501347 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92447981001, 92447981002, 92447981003 METHOD BLANK: 2696426 Matrix: Water Associated Lab Samples: 92447981001, 92447981002, 92447981003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L NO 0.040 10/02/19 23:34 LABORATORY CONTROL SAMPLE: 2696427 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 1.5 1.5 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2696428 2696429 MS MSD 92447888001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 30.1 1.5 1.5 32.0 29.6 129 -33 90-110 8 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 37 cr aceAnalytical wvmpacelabscom QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MW'S 10-2-19 Pace Project No.: 92447981 QC Batch: 502671 Analysis Method: SM 4500-CI-E-2011 QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Associated Lab Samples: 92447981001, 92447981002, 92447981003 METHOD BLANK: 2702336 Matrix: Water Associated Lab Samples: 92447981001, 92447981002, 92447981003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 10/09/1920:17 LABORATORY CONTROL SAMPLE: 2702336 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.3 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2702337 2702338 MS MSD 92447934001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 223 10 10 229 279 57 557 90-110 20 M6, Rt MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2702339 2702340 MS MSD 92448085001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 53.0 10 10 65.0 70.4 120 174 90-110 8 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 37 aceAnalXical w .pacelabs.com QUALITY CONTROL DATA Project: MWS 10-2-19 Pace Project No.: 92447981 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QC Batch: 501485 Analysis Method: SM 531OB-2011 QC Batch Method: SM 531OB-2011 Analysis Description: 5310B TOC Associated Lab Samples: 92447981001, 92447981002, 92447981003 METHOD BLANK: 2697047 Matrix: Water Associated Lab Samples: 92447981001, 92447981002, 92447981003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L ND 1.0 10/04/19 01:58 LABORATORY CONTROL SAMPLE: 2697048 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 25 25.4 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2697049 2697050 MS MSD 92447385003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qua[ Total Organic Carbon mg/L 12.5 25 25 33.9 34.1 86 86 90-110 1 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2697051 2697052 MS MSD 92447981002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L 2.3 25 25 25.9 26.1 94 95 90-110 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical services, U.C. Page 35 of 37 Pace Analytical Services, LLC ® 2225 Riverside Dr. • aceAnalyticalAsheville, NC 28804 W ..pawkbs.wm (828)254-7176 QUALIFIERS Project: MWS 10-2-19 Pace Project No.: 92447981 DEFINITIONS OF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL- Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS BC The same analyte was detected in an associated blank at a concentration above 1/2 the reporting limit but below the laboratory reporting limit. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/24/2019 03:09 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 37 aceAnalytical v wivpeeelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Pace Project No.: MW S 10-2-19 92447981 Lab ID Sample ID QC Batch Method QC Batch Analytical Analytical Method Batch 92447981001 MW-05 92447981002 MW-06R 92447981003 MW-08R 92447981004 MW-07 92447981001 MW-05 EPA 200.7 Rev 4.4 1994 503205 EPA 200.7 Rev 4.4 1994 503227 92447981002 MW-06R EPA 200.7 Rev 4.4 1994 503333 EPA 200.7 Rev 4.4 1994 503407 92447981003 MW-08R EPA 200.7 Rev 4.4 1994 503333 EPA 200.7 Rev 4.4 1994 503407 92447981001 MW-05 EPA 245.1 Rev 3.0 1994 501853 EPA 245.1 Rev 3.0 1994 502054 92447981002 M W-06R EPA 245.1 Rev 3.0 1994 501853 EPA 245.1 Rev 3.0 1994 502054 92447981003 MW-08R EPA 245.1 Rev 3.0 1994 501853 EPA 245.1 Rev 3.0 1994 502054 92447981001 MW-05 SM 6200B 503296 92447981002 MW-06R SM 62008 503296 92447981003 MW-08R SM 6200B 503388 92447981001 MW-05 SM 2540C-2011 501840 92447981002 MW-06R SM 2540C-2011 501840 92447981003 MW-08R SM 2540C-2011 501840 92447981001 MW-05 EPA 300.0 Rev 2.1 1993 501340 92447981002 MW-06R EPA 300.0 Rev 2.1 1993 501340 92447981003 M W-08R EPA 300.0 Rev 2.1 1993 501418 92447981001 MW-05 EPA 350.1 Rev 2.01993 503027 92447981002 MW-06R EPA 350.1 Rev 2.01993 503027 92447981003 MW-08R EPA 350.1 Rev 2.01993 503027 92447981001 MW45 EPA 353.2 Rev 2.0 1993 501347 92447981002 M W-06R EPA 353.2 Rev 2.0 1993 501347 92447981003 M W-08R EPA 353.2 Rev 2.0 1993 501347 92447981001 MW-05 SM 4500-CI-E-2011 502671 92447981002 MW-06R SM 4500-CI-E-2011 502671 92447981003 MW-08R SM 4500-01-E-2011 502671 92447981001 MW-05 SM 5310B-2011 501485 92447981002 MW-06R SM 5310B-2011 501485 92447981003 MW-08R SM 5310B-2011 501485 Date: 10/24/2019 03:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 37 of 37