HomeMy WebLinkAboutWQ0004797_Groundwater Monitoring Report November 2019_20191220Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
828.281.3350
Tracy Wolfe
Lassonde Pappas & Co., Inc.
125 Industrial Park Road
Hendersonville, North Carolina 28792
Re: November 2019 Groundwater Sampling Event
Clement Pappas NC, LLC
Dear Ms. Wolfe,
Zy2 ANCHOR
QEA
December 20, 2019
JAN 0 3 2020
Anchor QEA of North Carolina, PLLC, is pleased to present the results of the November 2019 water
quality monitoring event at the Clement Pappas NC, LLC (Clement Pappas) facility (the Site) that is
located at 485 Brookside Camp Road in Hendersonville, North Carolina.
Groundwater Quality
Anchor QEA performed the groundwater sampling event at the subject facility (the Site) on
November 14, 2019. A Site location map is included as Figure 1. The groundwater sampling event
was performed in accordance with North Carolina Department of Environmental Quality (DEQ)
wastewater irrigation system permit No. WQ0004797 (reissued September 3, 2015). Anchor QEA
collected groundwater samples from six monitoring wells: MW-4, MW-5, MW-6, MW-7R, MW-8,
and MW-9. (Monitoring well MW-9 was installed on April 14, 2015, to replace the previously
damaged monitoring well MW-2R.) The locations of the monitoring wells are shown in Figure 2.
Anchor QEA submitted the groundwater samples to Pace Analytical Services, Inc., a
North Carolina -certified laboratory, for analysis of the parameters specified in the permit.
Microbiology and Wet Chemistry
Table 1 summarizes the current and historical laboratory analytical results for microbiology and wet
chemistry. All parameters analyzed were below the permit limits', except for nitrate.
Nitrate detections are summarized as follows:
• The permit limit for nitrate is 10 milligrams per liter (mg/L).
• Nitrate was detected in MW-4 (0.42 mg/L), MW-5 (0.055 mg/L), MW-6 (0.56 mg/L),
MW-8 (1.2 mg/L), and MW-9 (0.89 mg/L) at concentrations below the permit limit.
Most of the permit limits are represented by the 2L standards (per Title 15A, North Carolina AdministratRI'PINCAC),
Subchapter 2L, Section.0202 JAiJ S 2R�� 1 ! I,.�
\\ashevi11e1\asheville\Projects\Clement Pappas\RepoM\2019\Nmember\Nw tuber 2019 Groundwater Sampling Event Clement Pappas NA/4ttqx 0ua l ity Regional Operations
Asheville Regional Office
December 16, 2019
Page 3
The irrigation fields experienced significant flooding during 2017, 2018, and 2019. As previously
stated, flood water from Mud Creek is suspected to have impacts on Site groundwater. Rainfall data
associated with each flooding event is summarized as follows:
• January 23, 2017: 1.92 inches
• March 31, 2017: 3.23 inches
• April 4, 2017: 1.50 inches
• April 5, 2017: 1.51 inches
• April 24, 2017: 3.23 inches
• May 25, 2017: 4.25 inches
• September 12, 2017: 2.39 inches
• October 24, 2017: 4.90 inches
• October 28, 2017: 2.53 inches
• February 10 through 14, 2018: 2.50 inches
• May 15 through 19, 2018: 8.11 inches
• May 25 through 31, 2018: 5.02 inches
• July 30 through August 3, 2018: 4.93 inches
• September 17, 2018: 1.84 inches
• October 11, 2018: 3.79 inches
• November 13, 2018: 1.76 inches
• December 8 through 9, 2018: 13.5 inches snow
• December 14 through 15, 2018: 0.74 inches
• December 21, 2018: 2.24 inches
• February 15 through 24, 2019: 5.47 inches
• April 12 through 14, 2019: 2.14 inches
• April 19, 2019: 3.96 inches
• June 7, 2019: 4.54 inches
• June 10, 2019: 4.54 inches
• August 23, 2019: 2.11 inches
• October 31, 2019: 2.52 inches
Volatile Organic Compounds
Table 2 summarizes the current and historical laboratory analytical results for volatile organic
compounds (VOCs), analyzed by U.S. Environmental Protection Agency Standard Method 62008. In
accordance with permit requirements, samples are analyzed for VOCs annually, during November.
No VOCs were detected at concentrations above the method detection limits in the monitoring wells
December 16, 2019
Page 5
In accordance with the spray irrigation permit, Clement Pappas is required to submit the following to
the DEQ by December 31, 2019 (on or before the last working day of the month following the
sampling month):
• Laboratory analytical reports and chain -of -custody forms (Attachment 1)
• Well sampling logs and the equipment documentation and instrument calibration data sheet
(Attachment 2)
• DEQ GW-59A — Compliance Report Form (Attachment 3)
• DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Form, for each
monitoring well (Attachment 4)
Anchor QEA proposes to complete the next scheduled groundwater sampling event in May 2020.
Anchor QEA will also continue to collect surface water data from Mud Creek.
If you have any questions or would like additional information, please do not hesitate to contact me
at (828) 281-3350 or amacbeth@anchorqea.com.
Sincerely,
0_C1a-V__0'w" -P -7✓r i
Alec Macbeth, PG
Senior Scientist
Attachments
Table 1 Current and Historical Groundwater Analytical Results for Microbiology
and Wet Chemistry
Table 2 Current and Historical Groundwater Analytical Results for Volatile Organic
Compounds
Table 3 Current and Historical Groundwater Elevation Measurements
Table 4 Current and Historical Surface Water Analytical Results
Figure 1 Site Location Map
Figure 2 Site Plan Map
Attachment 1 Laboratory Analytical Reports and Chain -of -Custody Forms
Attachment 2 Well Sampling Logs and Instrument Calibration Data Sheet
Attachment DEQ GW-59A —Compliance Report Form
Attachment 4 DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Forms
Tables
Table 1
Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry
C
0
9
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2
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N
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0
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0
0
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l0-
U
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F
¢
f
(CFUs per
Sample Name
Sample Date
(mg/L)
(mg/L)
100 ml-)
(mg/L)
(mg/L)
(mg/L)
(mg/L)
Standards
10
250
1
10
500
7.5
NL
05/02/2017
3.9
7.0
<2.0
0.4
96
<0.10
0.072
11/08/2017
3.0
7.3
<2.0
1 1.2
135
<0.10
0.070
05/02/2018
3.0
10.0
<1.0
2.1
167
<0.020
0.11
MW-4
11/02/2018
3.6
9.0
<10.0
0.48
137
1 <0.10
0.070
05/21/2019
3.0
11.3
<1.0
3.3
170
<0.050
0.044 J
11/14/2019
3.7
11
<1.0
0.42
190
<0.10
<0.050
05/02/2017
8.1
29.0
3.0
<0.020
134
<0.10
0.097
11/08/2017
6.7
12.8
188.0
<0.020
84
<0.10
0.086
MW-5
05/02/2018
5.7
16.1
2.0
0.0
90
<0.10
0.097
11/02/2018
5.1
23.9
<10.0
<0.020
86
<0.10
0.085
05/21/2019
9.4
26.8
7.0
0.1
91
<0.050
0.120
11/14/2019
6.0
20.1
7.0
0.055
202
1 <0.10
0.081
05/02/2017
1.8
12.1
2.0
0.5
93
<0.10
0.090
11/08/2017
1.4
11.1
74.0
0.0
66
<0.10
<0.050
05/02/2018
2.3
9.4
1.0
0.1
81
<0.10
0.097
MW-6
11/02/2018
2.5
10.1
69.0
0.6
88
<0.10
0.057
05/21/2019
3.3
11.3
23.0
0.4
78
<0.050
0.068
11/14/2019
2.9
9.3
44.0
0.56
342
<0.10
0.052
05/02/2017
6.7
17.9
<4.0
8.9
169
<0.10
0.430
11/08/2017
3.9
17.9
19.0
36.8
376 1
<0.10
0.140
MW-7R
05/02/2018
3.2
22.6
<2.0
15.5
207
<0.10
0.320
11/02/2018
5.3
20.2
<10.0
15.7
243
<0.10
0.170
05/21/2019
3.0
29.0
<2.0
20.2
234
<0.050
0.130
11/14/2019
3.0
22.7
<2.0
17.1
73
<0.10
0.084
05/02/2017
11.4
18.9
8.0
12.4
497
<0.10
0300
11/08/2017
8.1
9.7
<4.0
14.4
390
<0.10
0.098
MW-8
05/02/2018
10.8
12.9
<2.0
14.4
548
<0.10
0.190
11/02/2018
9.5
8.0
19.0
6,8
351 1
<0.10 1
0.250
05/21/2019
7.9
7.3
<10.0
6.2
249
<0.050
0.290
11/14/2019
7.7
7.2
2.0
1.2
51
<0.10
0.10
05/02/2017
7.6
3.8
<4.0
0.2
92
<0.10
0.610
11/08/2017
7.0
8.9
10.0
1.0
64
<0.10
0.530
MW-9
05/02/2018
4.6
4.9
<2.0
0.6
69
<0.10
0.370
11/02/2018
8.4
5.8
<10.0
0.6
88
<0.10
0.470
05/21/2019
7.2
4.6
<10.0
0.2
80
<0.050
0.230
11/14/2019
6.1
5.4
<1.0
0.89
56 1
<0.10 1
0.076
November 2019 Groundwater Sampling Event Pagel of 2
Clement Pappas, Hendersonville, North Carolina December 2019
Table 2
Current and Historical Groundwater Analytical Results for Volatile Organic Compounds
m
d
a
C
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W
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p
C
Ge
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ry
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p
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`°
G
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Sample Name
Sample Date
(pg/L)
(pg/L)
(pg/L)
(pg/L)
(pg/L)
(pg/L)
2L Standard
0.7
3
70
100
0.03
7
11/05/2002
< 0.50
0.83
< 0.50
< 0.50
< 0.50
< 0.50
11/04/2003
< 0.50
0.94
0.62
< 0.50
< 0.50
< 0.50
MW 2
11/09/2004
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/03/2005
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2006
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
OS/18/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/13/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2008
< 0.50
< 0.50
< 0.50
< 0.50
< 0.5
< 0.50
11/05/2009
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
MW-2R
11/08/2010
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/15/2011
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/07/2012
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/20/2013
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/05/2002
< 0.50
< O.SO
< 0.50
< 0.50
< 0.50
< 0.50
11/04/2003
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2004
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11 /03/2005
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2006
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/18/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/13/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2008
< 0.50
< 0.50
< 0.50
< 0.50
< 0.5
< 0.50
11/0S/2009
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
MW-4
11/08/2010
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/15/2011
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/07/2012
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11 /20/2013
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2014
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/04/2015
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/09/2016
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/08/2017
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
11/02/2018
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/14/2019
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
November 2018 Groundwater Sampling Event
Clement Pappas, Hendersonville, North Carolina
Pagel of 5
December 2019
Table 2
Current and Historical Groundwater Analytical Results for Volatile Organic Compounds
N
L
Y
O
O
L
u
G
C
y
Y
O
O
L
a
C
d
L
O
O
L
N
a,
d
V
O
O
a
N
V
N
O
L
V
_
C
C
OC
y
O
L
Sample Name
1 Sample Date
(pg/L)
(pg/L)
I (pg/L)
(pg/L)
W/O
OWL)
2L Standard
0.7
3
70
100
0.03
7
11/05/2002
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/04/2003
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2004
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/03/2005
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2006
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/18/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/13/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2008
3.0
< 0.50
< 0.50
< 0.50
< 0.5
< 0.50
11/05/2009
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/08/2010
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
MW-6
11/15/2011
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/07/2012
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/20/2013
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2014
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/04/2015
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11 /09/2016
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/08/2017
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/02/2018
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/14/2019
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/05/2002
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/04/2003
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2004
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/03/2005
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/09/2006
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
MW-7
05/18/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/13/2007
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/18/2008
0.79
< 0.50
< 0.50
< 0.50
< 0.5
< 0.50
11/05/2009
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/08/2010
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
11/15/2011
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
November 2018 Groundwater Sampling Event
Clement Pappas, Hendersonville, North Carolina
Page 3 of 5
December 2019
Table 2
Current and Historical Groundwater Analytical Results for Volatile Organic Compounds
c
C
d
t
�
W
N
p
O
O
C
L
S
d
`
C
C
L
w
r
O
V
L
V
W
V
C
y
W
O
O
O
y
O
=
N
C
U
T
G
d
F
C
F
A
V
LC
F
C_
9
Sample Name
Sample Date
(pg/L)
(pg/L)
(pg/L)
(pg/L)
(pg/L)
(pg/L)
2L Standard
0.7
3
70
100
0.03
7
Notes:
This table only includes compounds that were detected above the laboratory method detection limit since the sampling event in November
2002. The complete suite of compounds analyzed can be found in the individual analytical reports. Only samples collected during November
sampling events were analyzed for volatile organic compounds, in accordance with Spray Irrigation Permit Number W00004797.
5/18/2007: In accordance with the Compliance Evaluation Inspection letter issued by Beverly Price of the North Carolina Department of
Environment and Natural Resources, Division of Water Quality on April 27, 2007, volatile organic compounds and semivolatile organic
compounds were sampled during the May 2007 sampling event.
Naphthalene was detected in MW-6 for the first time at a concentration of 2.2 pg/L (which is below the 2L standard of 6 pg/L) during the
November 5, 2002 sampling event.
1,1,2-trichloroethane was detected in MW-5 for the first time on November 20, 2010, at a concentration of 8.0 pg/L, which exceeds the
North Carolina Interim Maximum Allowable Concentration of 0.6 pg/L.
Chloroform was detected for the first time in MW-5 during the November 2011 sampling event at a concentration of 31.3 pg/L, which is
below the 2L standard of 70 pg/L.
Toluene was detected for the first time in MW-4 during the November 2015 sampling event at a concentration of 0.75 pg/L, which is below
the 2L standard of 600 pg/L.
Bold values indicate an exceedance of the 2L standard.
2L Standard: North Carolina Administrative Code, Title 15A, Subchapter 2L, April 1, 2013
pg/L: micrograms per liter
November 2018 Groundwater Sampling Event Page 5 of 5
Clement Pappas, Hendersonville, North Carolina December 2019
Table 3
Current and Historical Groundwater Elevation Measurements
Well Identification
Date Measured
Depth to
Groundwater
(feet BTOC)
Top -of -Casing
Elevation
(feet)
Top -of -Casing
Height Above
Ground Surface
(feet)
Groundwater
Elevation
(feet)
05/15/2002
9.32
2064.60
2.43
2055.28
11/05/2002
9.49
2064.60
2.43
2055.11
05/13/2003
8.20
2064.60
2.43
2056.40
11/04/2003
9.23
2064.60
2.43
2055.37
05/05/2004
9.35
2064.60
2.43
20SS.25
11/09/2004
8.61
2064.60
2.43
2055.99
05/17/2005
6.19
2064.60
2.43
2058A1
11/03/2005
9.57
2064.60
2.43
2055.03
05/24/2006
9.60
2064.60
2.43
2055.00
11/09/2006
8.41
2064.60
2.43
2056.19
05/18/2007
9.42
2064.60
2.43
2055.18
11/13/2007
9.89
2064.60
2.43
2054.71
05/27/2008
9.78
2064.60
2.43
2054.82
11/18/2008
9.76
2064.60
2.43
2054.84
05/28/2009
7.16
2064.60
2.43
2057.44
11/05/2009
8.53
2064.60
2.43
2056.07
MW 4
05/13/2010
8.83
2064.60
2.43
2055.77
11/08/2010
9.30
2064.60
2.43
2055.30
05/17/2011
8.97
2064.60
2.43
2055.63
11/15/2011
9.48
2064.60
2.43
2055.12
05/17/2012
7.62
2064.60
2.43
2056.98
11/07/2012
9.32
2063.77
2.43
2054.45
05/16/2013
7.93
2063.77
2.43
2055.84
11/20/2013
8.87
2063.77
2.43
2054.90
05/22/2014
8.70
2063.77
2.43
2055.07
11/18/2014
8.54
2063.77
2.43
2055.23
05/13/2015
9.18
2063.77
2.43
2054.59
11/4/2015
6.93
2063.77
2.43
2056.84
05/04/2016
8.43
2063.77
2.43
20SS.34
11/09/2016
9.63
2063.77
2.43
2054.14
05/02/2017
7.82
2063.77
2.43
2055.95
11/08/2017
7.88
2063.77
2.43
2055.89
05/02/2018
8.44
2063.77
2.43
2055.33
11/02/2018
8.00
2063.77
2.43
2055.77
05/21/2019
8.49
2663.77
2.43
2055.28
11/14/2019
8.82
2063.77
2.43
2054.95
November 2019 Groundwater Sampling Event
Clement Pappas, Hendersonville, North Carolina
Page 2 of 7
December 2019
Table 3
Current and Historical Groundwater Elevation Measurements
Well Identification
Date Measured
Depth to
Groundwater
(feet BTOC)
Top -of -Casing
Elevation
(feet)
Top -of -Casing
Height Above
Ground Surface
(feet)
Groundwater
Elevation
(feet)
05/15/2002
6.20
2061.90
3.00
2055.70
11/05/2002
6.15
2061.90
3.00
2055.75
05/13/2003
5.43
2061.90
3.00
2056.47
11/04/2003
5.85
2061.90
3.00
2056.05
05/05/2004
6.00
2061.90
3.00
2055.90
11/09/2004
5.32
2061.90
3.00
2056.58
05/17/2005
6.10
2061.90
3.00
2055.80
11/03/2005
6.01
2061.90
3.00
20S5.89
05/24/2006
1 6.48
2061.90
3.00
1 20S5A2
11/09/2006
5.71
2061.90
3.00
2056.19
05/18/2007
6.50
2061.90
3.00
2055.40
11/13/2007
7.85
2061.90
3.00
2054.05
05/27/2008
7.01
2061.90
3.00
2054.89
11/18/2008
7.38
2061.90
3.00
2054.52
05/28/2009
5.63
2061.90
3.00
2056.27
11/05/2009
5.74
2061.90
3.00
2056.16
MW-6
05/13/2010
5.90
2061.90
3.00
2056.00
11/08/2010
5.99
2061.90
3.00
2055.91
05/17/2011
5.85
2061.90
3.00
2056.05
11/15/2011
6.14
2061.90
3.00
2055.76
OS/17/2012
5.87
2061.90
3.00
2056.03
11/07/2012
6.05
2061.17
3.00
2055.12
05/16/2013
5.84
2061.17
3.00
2055.33
11/20/2013
5.96
2061.17
3.00
20S5.21
05/22/2014
5.96
2061.17
3.00
20S5.21
11/18/2014
5.82
2061.17
3.00
2055.35
OS/13/2015
6.05
2061.17
3.00
2055.12
11/04/2015
5.18
2061.17
3.00
2055.99
05/04/2016
5.59
2061.17
3.00
2055.58
11/09/2016
7.42
2061.17
3.00
2053.75
05/02/2017
5.31
2061.17
3.00
2055.86
11/08/2017
4.80
2061.17
3.00
2056.37
05/02/2018
5.36
2061.17
3.00
2055.81
11/02/2018
5.03
2061.17
3.00
2056.14
05/21/2019
5.53
2061.1,
3.00
2055.64
11/14/2019
5.59
2061.17
3.00
2055.58
November 2019 Groundwater Sampling Event
Clement Pappas, Hendersonville, North Carolina
Page 4 of 7
December 2019
Table 3
Current and Historical Groundwater Elevation Measurements
Well Identification
Date Measured
Depth to
Groundwater
(feet BTOC)
Top -of -Casing
Elevation
(feet)
Top -of -Casing
Height Above
Ground Surface
(feet)
Groundwater
Elevation
(feet)
05/15/2002
10.25
2061.40
3.00
2051.15
11/05/2002
10.35
2061.40
3.00
2051.05
05/13/2003
8.16
2061.40
3.00
2053.24
11/04/2003
10.23
2061.40
3.00
2051.17
05/05/2004
10.30
2061.40
3.00
2051.10
11/09/2004
8.90
2061.40
3.00
2052.50
05/17/2005
10.08
2061.40
3.00
2051.32
11/03/2005
10.61
2061.40
3.00
2050.79
05/24/2006
10.60
2061.40
3.00
2050.80
11/09/2006
9.40
2061.40
3.00
2052.00
05/18/2007
10.31
2061.40
3.00
2051.09
11/13/2007
11.09
2061.40
3.00
2050.31
05/27/2008
10.83
2061.40
3.00
2050.57
11/18/2008
11.11
2061.40
3.00
2050.29
05/28/2009
8.25
2061.40
3.00
2053.15
11/05/2009
9.22
2061.40
3.00
2052.18
MW 8
05/13/2010
9.88
2061.40
3.00
2051.52
11/08/2010
10.38
2061.40
3.00
2051.02
05/17/2011
10.27
2061.40
3.00
2051.13
11/15/2011
10.87
2061.40
3.00
2050.53
05/17/2012
8.03
2061.40
3.00
2053.37
11/07/2012
10.45
2060.80
3.00
2050.35
05/16/2013
8.58
2060.80
3.00
2052.22
11/20/2013
10.34
2060.80
3.00
2050.46
05/22/2014
9.79
2060.80
3.00
2051.01
11/18/2014
10.03
2060.80
3.00
2050.77
05/13/2015
10.34
2060.80
3.00
2050.46
11/04/2015
7.21
2060.80
3.00
2053.59
05/04/2016
9.84
2060.80
3.00
2050.96
11/09/2016
11.16
2060.80
3.00
2049.64
05/02/2017
8.48
2060.80
3.00
2052.32
11/08/2017
8.73
2060.80
3.00
2052.07
05/02/2018
9.39
2060.80
3.00
2051.41
11/02/2018
8.85
2060.80
3.00
2051.95
05/21/2019
9.38
2060.80
3.00
2051.42
11/14/2019
9.75
2060.80
3.00
2051.05
November 2019 Groundwater Sampling Event
Clement Pappas, Hendersonville, North Carolina
Page 6 of 7
December 2019
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Site Location Map
November 2019 Groundwater Sampling Event
Clement Pappas, Hendersonville, North Carolina
Attachment 1
Laboratory Analytical Reports and
Chain -of -Custody Forms
aceAnalytical e
lmi.0acolebs.ron
November 22, 2019
Mr. Alec Macbeth
Anchor QEA of North Carolina
231 Haywood Street
Asheville, NC 28801
RE: Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
Dear Mr. Macbeth:
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Enclosed are the analytical results for sample(s) received by the laboratory on November 14, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
lorri.patton@pacelabs.com
1(828)254-7176
Project Manager
Enclosures
cc: Ms. Cassandra Harvey, Anchor QEA
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, -LC.
Page 1 of 56
aceAnalytical
www.pacalabsxoa
SAMPLE ANALYTE COUNT
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
92453831001
MW-4
SM 6200B
CL
63
PASI-C
SM 254OC-2011
CJL
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.01993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.01993
NAL
1
PASI-A
SM 4500-CI-E-2011
GC
1
PASI-A
SM 531OB-2011
BRJ
1
PASI-A
92453831002
MW-5
SM 6200B
CL
63
PASI-C
SM 254OC-2011
CJL
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.01993
CJH1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.01993
NAL
1
PASI-A
SM 4500-CI-E-2011
GC
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92453831003
MW-6
SM 6200B
CL
63
PASI-C
SM 254OC-2011
CJL
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.01993
CJH1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.01993
NAL
1
PASI-A
SM 4500-CI-E-2011
GC
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92453831004
MW-7R
SM 6200B
CL
63
PASI-C
SM 254OC-2011
CJL
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.01993
CJH1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.01993
NAL
1
PASI-A
SM 4500-CI-E-2011
GC
1
PASI-A
SM 531 OB-2011
ECH
1
PASI-A
92453831005
MW-8
SM 6200B
CL
63
PASI-C
SM 254OC-2011
CJL
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.01993
CJHi
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, I.I.C.
Page 3 of 56
Pace Analytical Services, LLC
aceAnalXical s 2225 Riverside Asheville, NC 2880404
www.pacsIabs.con
(826)254-7176
ANALYTICAL RESULTS
Project: LASSONDE PAPPAS 11.14-19
Pace Project No.: 92453831
Sample: MW-4 Lab ID: 92453831001 Collected: 11/14/1913:20 Received: 11/1411915:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Benzene
ND
ug/L
0.50
1
11/17/19 18:49
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/17/19 18:49
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/17/19 18:49
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/17/19 18:49
75-27-4
Bromoform
ND
ug/L
0.50
1
11/17/19 18:49
75-25-2
Bromomethane
ND
ug/L
6.0
1
11/17/19 18:49
74-83-9 L1
n-Butylbenzene
ND
ug/L
0.50
1
11/17/19 18:49
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/17/19 18:49
135-98-8
tert-Butylbenzene
ND
ug/L
0.50
1
11/17/19 18:49
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/17/19 18:49
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11117/1918:49
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/17/19 18:49
75-00-3
Chloroform
ND
ug/L
0.50
1
11/17/19 18:49
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/17/19 18:49
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/1711918:49
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/17/19 18:49
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/17/19 18:49
96-12-8
Dibromochloromelhane
ND
ug/L
0.50
1
11/17/19 18:49
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/17/19 18:49
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/17/19 18:49
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/17/19 18:49
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/17/19 18:49
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/17/19 18:49
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/17/19 18:49
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/17/19 18:49
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/1711918:49
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/17/19 18:49
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/17/19 18:49
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/17/19 18:49
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/17/19 18:49
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/17/19 18:49
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/17/19 18:49
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/17/19 18:49
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/17/19 18:49
10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
0.50
1
11/17/19 18:49
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/17/19 18:49
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/17/19 18:49
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/17/19 18:49
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/17/19 18:49
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/1711918:49
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/17/19 18:49
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/17/19 18:49
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/17/19 18:49
103-65-1
Styrene
ND
ug/L
0.50
1
11/17/19 18:49
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/1711918:49
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11117/1918:49
79-34-5
Tetrachloroethene
ND
ug/L
0.50
1
11/17/19 18:49
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, I.I.C. Page 5 of 56
Pace Analytical Services, LLC
aceAnalytical ® 2225 Riverside 04
Asheville, NC 28804
www.pacalabs.con
(828)254-7176
ANALYTICAL RESULTS
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
Sample: MW-5 Lab ID: 92453831002 Collected: 11/14/1913:50 Received: 11/14/19 15:11 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method: SM 6200B
Benzene
NO
ug/L
0.50
1
11/19/19 14:19
71-43-2
Bromobenzene
NO
ug/L
0.50
1
11/19/19 14:19
108-86-1
Bromochloromelhane
NO
ug/L
0.50
1
11/19/19 14:19
74-97-5
Bromodichloromethane
NO
ug/L
0.50
1
11/19/19 14:19
75-27-4
Bromoform
NO
ug/L
0.50
1
11/19/19 14:19
75-25-2
Bromomethane
NO
ug/L
5.0
1
11/19/19 14:19
74-83-9 Ll
n-Butylbenzene
NO
ug/L
0.50
1
11/19/19 14:19
104-51-8
sec-Butylbenzene
NO
ug/L
0.50
1
11/19/19 14:19
135-98-8
tert-Butylbenzene
NO
ug/L
0.50
1
11/19/19 14:19
98-06-6
Carbon tetrachloride
NO
ug/L
0.50
1
11/19/19 14:19
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/19/19 14:19
108-90-7
Chloroethane
ND
ug/L
1.0
1
11119/1914:19
75-00-3
Chloroform
NO
ug/L
0.50
1
11/19/19 14:19
67-66-3
Chloromethane
NO
ug/L
1.0
1
11/19/19 14:19
74-87-3
2-Chlorotoluene
NO
ug/L
0.50
1
11/19/19 14:19
95-49-8
4-Chlorotoluene
NO
ug/L
0.50
1
11/19/19 14:19
106-43-4
1,2-Dibromo-3-chloropropane
NO
ug/L
1.0
1
11/19/19 14:19
96-12-8
Dibromochloromethane
NO
ug/L
0.50
1
11/19/19 14:19
124.48-1
1,2-Dibromoethane (EDB)
NO
ug/L
0.50
1
11/19/19 14:19
106-93-4
Dibromomethane
NO
ug/L
0.50
1
11/19/19 14:19
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/19/19 14:19
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/19/19 14:19
541-73-1
1,4-Dichlorobenzene
NO
ug/L
0.50
1
11/19/19 14:19
106-46-7
Dichlorodi8uoromethane
NO
ug/L
0.50
1
11/19/19 14:19
75-71-8
1,1-Dichloroethane
NO
ug/L
0.50
1
11/19/1g 14:19
75-34-3
1,2-Dichloroethane
NO
ug/L
0.50
1
11/19/19 14:19
107-06-2
1,1-Dichloroethene
NO
ug/L
0.50
1
11/19/19 14:19
75-35-4
cis-1,2-Dichloroethene
5.0
ug/L
0.50
1
11/19/19 14:19
156.59.2
trans-1,2-Dichloroethene
NO
ug/L
0.50
1
11/19/19 14:19
156-60-5
1,2-Dichloropropane
NO
ug/L
0.50
1
11/19/19 14:19
78-87-5
1,3-Dichloropropane
NO
ug/L
0.50
1
11/19/19 14:19
142-28-9
2,2-Dichloropropane
NO
ug/L
0.50
1
11/19/19 14:19
594-20-7
1,1-Dichloropropene
NO
ug/L
0.50
1
11/19/19 14:19
563-58-6
cis-1,3-Dichloropropene
NO
ug/L
0.50
1
11/19/19 14:19
10061-01-5
trans-1,3-Dichloropropene
NO
ug/L
0.50
1
11/19/19 14:19
10061-02-6
Diisopropyl ether
NO
ug/L
0.50
1
11/19/19 14:19
108.20-3
Ethylbenzene
NO
ug/L
0.50
1
11/19/19 14:19
100-41-4
Hexachloro-1,3-butadiene
NO
ug/L
2.0
1
11/19/19 14:19
87-68-3
Isopropylbenzene (Cumene)
NO
ug/L
0.50
1
11/19/19 14:19
98-82-8
Methylene Chloride
NO
ug/L
2.0
1
11/19/19 14:19
75-09-2
Methyl-tert-butyl ether
NO
ug/L
0.50
1
11/19/19 14:19
1634-04-4
Naphthalene
NO
ug/L
2.0
1
11/19/19 14:19
91-20-3
n-Propylbenzene
NO
ug/L
0.50
1
11/19/19 14:19
103-65-1
Styrene
NO
ug/L
0.50
1
11/19/19 14:19
100-42-5
1,1,1,2-Tetrachloroethane
NO
ug/L
0.50
1
11/19/19 14:19
630-20-6
1,1,2,2-Tetrachloroethane
NO
ug/L
0.50
1
11119/1914:19
79-34-5
Tetrachloroethene
22.4
ug/L
0.50
1
11/19/19 14:19
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Dale: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, L-C. Page 7 of 56
Pace Analytical Services, LLC
Ice Dr.
Analyticalw2225 RivAsheville, NCC 28 04 7676
1
ANALYTICAL RESULTS
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
Sample: MW-6 Lab ID: 92453831003 Collected: 11/14/1912:20 Received: 11/14/1915:11 Matrix: Water
Parameters
Results
Units
Report Limit
DF
Prepared Analyzed
CAS No. Qual
6200E MSV
Analytical Method: SM 6200B
Benzene
ND
ug/L
0.50
1
11/19/19 12:47
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/19/19 12:47
108-86-1
Bromochloromethene
ND
ug/L
0.50
1
11/19/19 12:47
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/19/19 12:47
75-27-4
Bromoform
ND
ug/L
0.50
1
11/19/19 12:47
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/19/19 12:47
74-83-9 L1
n-Butylbenzene
ND
ug/L
0.50
1
11/19/19 12:47
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/19/19 12:47
135-98-8
tert-Butylbenzene
ND
ug/L
0.50
1
11/19/19 12:47
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/19/19 12:47
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/19/19 12:47
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/19/19 12:47
75-00-3
Chloroform
ND
ug/L
0.50
1
11/19/19 12:47
67.66-3
Chloromethane
ND
ug/L
1.0
1
11119/1912:47
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/19/19 12:47
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/19/19 12:47
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/19/19 12:47
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/19/19 12:47
124-48.1
1,2-Dibromoethane (EDB)
NO
ug/L
0.50
1
11119/1912:47
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/19/19 12:47
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/19/19 12:47
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/19/19 12:47
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/19/19 12:47
106-46-7
Dichlorodi0uoromethane
NO
ug/L
0.50
1
11/1911912:47
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/19/19 12:47
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/19/19 12:47
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/19/19 12:47
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/19/19 12:47
156-59.2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/19/19 12:47
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/19/19 12:47
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/19/19 12:47
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/19/19 12:47
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/19/19 12:47
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/19/19 12:47
10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
0.50
1
11/19/19 12:47
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/19/19 12:47
108-20.3
Ethylbenzene
ND
ug/L
0.50
1
11/19/19 12:47
100-41.4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/19/19 12:47
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.60
1
11/19/19 12:47
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/19/19 12:47
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/19/19 12:47
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/19/19 12:47
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/19/19 12:47
103-65-1
Styrene
ND
ug/L
0.50
1
11/1911912:47
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/19/19 12:47
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/19/19 12:47
79-34-5
Tetrachloroethene
ND
ug/L
0.50
1
11/19/19 12:47
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 56
Pace Analytical Services, LLC
aceAnalytical a 2225le,NCRiverside28 04
Asheville, NC 28804
www.panlabs.con
(828)254-7176
ANALYTICAL RESULTS
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
Sample: MW-7R Lab ID: 92453831004 Collected: 11/14/1911:50 Received: 11/1411915:11 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method: SM 6200B
Benzene
NO
ug/L
0.50
1
11/19/19 13:06
71-43-2
Bromobenzene
NO
ug/L
0.50
1
11/19/19 13:06
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/19/19 13:06
74.97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/19/19 13:06
75-27-4
Bromoform
ND
ug/L
0.50
1
11/19/19 13:06
75-25-2
Bromomethane
NO
ug/L
5.0
1
11/19/19 13:06
74-83-9 Li
n-Butylbenzene
NO
ug/L
0.50
1
11/19/19 13:06
104-51-8
sec-Butylbenzene
NO
ug/L
0.50
1
11/19/19 13:06
135-98-8
tert-Butylbenzene
NO
ug/L
0.50
1
11119/1913:06
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/19/19 13:06
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/1911913:06
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/19/19 13:06
75-00-3
Chloroform
ND
ug/L
0.50
1
11/19/19 13:06
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/19/19 13:06
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/19/19 13:06
95-49-8
4-Chlorotoluene
NO
ug/L
0.50
1
11/19/19 13:06
106-43-4
1,2-Dibromo-3-chloropropane
NO
ug/L
1.0
1
11/19/19 13:06
96-12-8
Dibromochloromethane
NO
ug/L
0.50
1
11/19/19 13:06
124-48-1
1,2-Dibromoethane (EDB)
NO
ug/L
0.50
1
1111911913:06
106-93-4
Dibromomethane
NO
ug/L
0.50
1
11/19/19 13:06
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/19/19 13:06
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/19/19 13:06
541-73-1
1,4-Dichlorobenzene
NO
ug/L
0.50
1
11/19/19 13:06
106-46-7
Dichlorodi6uoromethane
ND
ug/L
0.50
1
11/19/19 13:06
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/19/19 13:06
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/19/19 13:06
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/19/19 13:06
75.35-4
cis-1,2-Dichloroethene
NO
ug/L
0.50
1
11/19/19 13:06
156-59-2
trans-1,2-Dichloroethene
NO
ug/L
0.50
1
11/19/19 13:06
156-60-5
1,2-Dichloropropane
NO
ug/L
0.50
1
11/19/19 13:06
78-87-5
1,3-Dichloropropane
NO
ug/L
0.50
1
11/19/19 13:06
142-28-9
2,2-Dichloropropane
NO
ug/L
0.50
1
11/19/19 13:06
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/19/19 13:06
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/19/19 13:06
10061-01-5
trans-1,3-Dichloropropene
NO
ug/L
0.50
1
11/19/19 13:06
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/19/19 13:06
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/19/19 13:06
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11119/1913:06
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/19/19 13:06
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/19/19 13:06
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/19/19 13:06
1634.04.4
Naphthalene
ND
ug/L
2.0
1
11/19/19 13:06
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/19/19 13:06
103.65-1
Styrene
ND
ug/L
0.50
1
11/19/19 13:06
100-42-5
1,1,1,2-Tetrachloroethane
NO
ug/L
0S0
1
11/19/19 13:06
630-20-6
1,1,2,2-Tetrachloroethane
NO
ug/L
0.50
1
11/19/19 13:06
79-34-5
Tetrachloroethene
NO
ug/L
0.50
1
11/19/19 13:06
127-18.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/22/201902:19 PM without the written consent of Pace Analytical Services,LLC.
Page 11 of 56
Pace Analytical Services, LLC
aceAnalytical a Ashhevievi Riverside Riverside
NC 2880404
waw.pacalabs.com (828)254-7176
ANALYTICAL RESULTS
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
Sample: MW-8 Lab ID: 92453831005 Collected: 11/14/1910:15 Received: 11/14/1915:11 Matrix: Water
Parameters
Results
Units
Report Limit
OF
Prepared Analyzed
CAS No. Oual
6200B MSV
Analytical Method:
SM 6200B
Benzene
ND
ug/L
0.50
1
11/19/19 13:24
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/19/19 13:24
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/19/19 13:24
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/19/19 13:24
75.27-4
Bromoform
ND
ug/L
0.50
1
11/19/19 13:24
75.25-2
Bromomethane
ND
ug/L
5.0
1
11/19/1913:24
74-83-9 L1
n-Butylbenzene
ND
ug/L
0.50
1
11/1911913:24
104.51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/19/19 13:24
135.98-8
lert-Butylbenzene
ND
ug/L
0.50
1
11/19/19 13:24
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/19/19 13:24
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/19/19 13:24
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/19/19 13:24
75-00-3
Chloroform
ND
ug/L
0.50
1
11/19/19 13:24
67.66-3
Chloromethane
ND
ug/L
1.0
1
11/19/19 13:24
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/19/19 13:24
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/19/19 13:24
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/19/19 13:24
96-12-8
Dibromochloromelhane
ND
ug/L
0.50
1
11/19/19 13:24
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/19/19 13:24
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/19/19 13:24
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/19/19 13:24
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/19/19 13:24
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/19/19 13:24
106-46.7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/19/19 13:24
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/19/19 13:24
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/19/19 13:24
107-06-2
1,1-Dichloroethane
ND
ug/L
0.50
1
11/19/19 13:24
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.60
1
11/19/19 13:24
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/19/19 13:24
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/19/19 13:24
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/19/19 13:24
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/19/19 13:24
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/19/19 13:24
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/19/19 13:24
10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
0.50
1
11/19/19 13:24
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/19/19 13:24
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/19/19 13:24
100-41.4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/19/19 13:24
87.68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/19/19 13:24
98-82.8
Methylene Chloride
ND
ug/L
2.0
1
11/19/19 13:24
75-09-2
Methyl -tart -butyl ether
ND
ug/L
0.50
1
11/19/19 13:24
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/19/19 13:24
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/19/19 13:24
103-65-1
Styrene
ND
ug/L
0.50
1
11/19/19 13:24
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/19/19 13:24
630-20-6
1, 1,2,2-Tetmchloroethane
ND
ug/L
0.50
1
11/19/19 13:24
79-34-5
Tetrachloroethene
ND
ug/L
0.50
1
11/19/19 13:24
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, L-C. Page 13 of 56
Pace Analytical Services, LLC
2225 Riverside
aceAnalytical
Asheville, NC 2880404
awa.pecelebacoa (828)254-7176
ANALYTICAL RESULTS
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
Sample: MW-9 Lab ID: 92453831006 Collected: 11/14/19 12:55 Received: 11114/1915:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method: SM 6200B
Benzene
ND
ug/L
0.50
1
11/19/19 13:42
71-43.2
Bromobenzene
ND
ug/L
0.50
1
11/19/19 13:42
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/19/19 13:42
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/19/19 13:42
75-27-4
Bromoform
ND
ug/L
0.50
1
11/19/19 13:42
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/19/19 13:42
74-83-9 Lt
n-Butylbenzene
ND
ug/L
0.50
1
11/19/19 13:42
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/19/19 13:42
135-98-8
tert-Butylbenzene
ND
ug/L
0.60
1
11/19/19 13:42
98-06.6
Carbon tetrachloride
ND
ug/L
0.50
1
11/19/19 13:42
56.23-5
Chlorobenzene
ND
ug/L
0.50
1
11/19/19 13:42
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/19/19 13:42
75-00-3
Chloroform
ND
ug/L
0.50
1
11/19/19 13:42
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/19/19 13:42
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/19/19 13:42
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/19/19 13:42
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/19/19 13:42
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/1911913:42
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/19/19 13:42
106.93-4
Dibromomethane
ND
ug/L
0.50
1
11/19/19 13:42
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/19/19 13:42
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/19/19 13:42
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/19/19 13:42
106-46-7
Dichlorodi0uoromethane
ND
ug/L
0.50
1
11/19/19 13:42
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/19/19 13:42
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/19/19 13:42
107-06-2
1,1-Dichloroethane
ND
ug/L
0.50
1
11/19/19 13:42
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/19/19 13:42
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/19/19 13:42
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/19/19 13:42
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/19/19 13:42
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/19/19 13:42
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/19/19 13:42
563-58-6
cis-1,3-Dichloropropane
ND
ug/L
0.50
1
11/19/19 13:42
10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
0.50
1
11119/1913:42
10061-02-6
Dilsopropyl ether
ND
ug/L
0.50
1
11/19/19 13:42
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/19/19 13:42
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/19/19 13:42
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11119/19 13:42
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/1911913:42
75-09.2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/19/19 13:42
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/19/19 13:42
91.20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/19/19 13:42
103-65-1
Styrene
ND
ug/L
0.50
1
11/19/19 13:42
100-42.5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/19/19 13:42
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/19/19 13:42
79-34.5
Tetrachloroethene
ND
ug/L
0.50
1
11/19/19 13:42
127-18-4
(
REPORT OF LABORATORY
ANALYSIS
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Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, U.C. Page 15 of 56
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ANALYTICAL RESULTS
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
Sample: SW-1 Lab ID: 92453831007 Collected: 11/14/19 11:15 Received: 11/14/1915:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Toluene
ND ug/L
0.50
1
11/19/19 14:01
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/19/19 14:01
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/19/19 14:01
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/19/19 14:01
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/19/19 14:01
79-00-5
Trichloroethene
NO ug/L
0.50
1
11/1911914:01
79-01-6
Tdchlorofluoromethane
NO ug/L
1.0
1
11/19/19 14:01
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/19/19 14:01
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/19/19 14:01
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/19/19 14:01
108-67-8
Vinyl chloride
NO ug/L
1.0
1
11/19/19 14:01
75-01.4
m&p-Xylene
ND ug/L
1.0
1
11/19/19 14:01
179601.23.1
o-Xylene
NO ug/L
0.50
1
11/19/19 14:01
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
95 %
70-130
1
11/19/19 14:01
17060-07-0
4-Bromofluorobenzene (S)
102 %
70-130
1
11/19/19 14:01
460-00-4
Toluene-d8(S)
97 %
70-130
1
11/19/19 14:01
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2011
Total Dissolved Solids
57.0 mg/L
25.0
1
11/19/19 23:33
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D.2006
Preparation Method: SM 9222D-2006
Fecal Coliforms
118 CFU/100 mL
1.0
1
11/14/1917:03 11/15/1915:45
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0
1993
Nitrogen, Ammonia
ND mg/L
0.10
1
1111611916:10
7664-41-7
353.2 Nitrogen, N021NO3 unpres
Analytical Method: EPA 353.2 Rev 2.01993
Nitrogen, Nitrate
0.83 mg/L
0.040
1
11/15/19 03:09
14797-55-6
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
Phosphorus
0.10 mg/L
0.050
1
11/17/19 16:26 11/18/19 16:31
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Chloride
5.3 mg/L
1.0
1
11/15/1919:30
16887-00-6
5310E TOC
Analytical Method: SM 531OB-2011
Total Organic Carbon
1.9 mg/L
1.0
1
11/1911920:50
7440-44-0
Date: 11/22/2019 02:19 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC,
Page 18 of 56
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
Sample: SW-2 Lab ID: 92453831008 Collected: 11/1411910:00 Received: 11/14/19 15:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method: SM 6200B
Benzene
ND
ug/L
0.50
1
11/20/19 17:23
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/20/19 17:23
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/20/19 17:23
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/20/19 17:23
75-27-4
Bromoform
ND
ug/L
0.50
1
11/20/19 17:23
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/20/19 17:23
74-83.9
n-Butylbenzene
ND
ug/L
0.50
1
11/20/19 17:23
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/20/19 17:23
135-98-8
tert-Butylbenzene
ND
ug/L
0.50
1
11120/1917:23
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/20/19 17:23
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/2011917:23
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/20/19 17:23
75-00-3
Chloroform
ND
ug/L
0.50
1
11/20/19 17:23
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/20/19 17:23
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/20/19 17:23
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/20/19 17:23
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/20/19 17:23
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/2011917:23
124-48-1
1,2-Dibromoethane(EDB)
ND
ug/L
0.50
1
1112011917:23
106-93-4
Dibromomelhane
ND
ug/L
0.50
1
1112011917:23
74-95.3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/20/19 17:23
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/20/19 17:23
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/20/19 17:23
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/20/19 17:23
75-71.8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/20/19 17:23
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/20/19 17:23
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/20/19 17:23
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/20/19 17:23
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/20/19 17:23
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/20/19 17:23
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/20/19 17:23
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/20/19 17:23
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/20/19 17:23
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/20/19 17:23
10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
0.50
1
11/20/19 17:23
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/20/19 17:23
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11120/1917:23
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/20/19 17:23
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/20/19 17:23
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/20/19 17:23
75-09.2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/20/19 17:23
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/20/19 17:23
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/20/19 17:23
103-65-1
Styrene
ND
ug/L
0.50
1
11/20/19 17:23
100-42-5
1,1,1,2-Telrachloroethane
ND
ug/L
0.50
1
11/20/19 17:23
630.20-6
1.1,2,2-Telrachloroethane
ND
ug/L
0.50
1
11/20/19 17:23
79-34-5
Tetrachloroethene
ND
ug/L
0.50
1
11/20/19 17:23
127.18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 56
Pace Analytical Services, LLC
aceAnalytical a 2225 Riverside Dr.
Asheville, NC 2880404
wim.patalabs.coa (828)254-7176
ANALYTICAL RESULTS
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
Sample: TRIP BLANK Lab ID: 92453831009 Collected: 11/14/19 00:00 Received: 11/14/19 15:11 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Oual
6200B MSV Analytical Method: SM 6200B
Benzene
ND
ug/L
0.50
1
11/20/19 17:05
71-43-2
Bromobenzene
NO
ug/L
0.50
1
11/20/19 17:05
108-86-1
Bromochloromethane
NO
ug/L
0.50
1
11/20/19 17:05
74-97-5
Bromodichloromethane
NO
ug/L
0.50
1
11/20/19 17:05
75.27.4
Bromoform
NO
ug/L
0.50
1
11/20/19 17:05
75-25.2
Bromomelhane
NO
ug/L
5.0
1
11/20/19 17:05
74-83-9
n-Butylbenzene
NO
ug/L
0.50
1
11/20/19 17:05
104-51-8
sec-Butylbenzene
NO
ug/L
0.50
1
11/20/19 17:05
135-98-8
tert-Butyl benzene
NO
ug/L
0.50
1
11/20/19 17:05
98-06-6
Carbon tetrachloride
NO
ug/L
0.50
1
11/20/19 17:05
56-23-5
Chlorobenzene
NO
ug/L
0.50
1
11120/1917:05
108-90-7
Chloroethane
NO
ug/L
1.0
1
11/20/19 17:05
75-00-3
Chloroform
ND
ug/L
0.50
1
11/20/19 17:05
67-66-3
Chloromethane
NO
ug/L
1.0
1
11/20/19 17:05
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/20/19 17:05
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11120/1917:05
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/2011917:05
96-12.8
Dibromochloromethane
ND
ug/L
0.50
1
11/20/19 17:05
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/20/19 17:05
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/20/19 17:05
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/20/19 17:05
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/20/19 17:05
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/20/19 17:05
106.46-7
Dichlorodi6uoromethane
ND
ug/L
0.50
1
11/20/19 17:05
75-71-8
1,1-Dichloroethane
NO
ug/L
0.50
1
11/20/19 17:05
75-34-3
1,2-Dichloroethane
NO
ug/L
0.50
1
11/20/19 17:05
107-06-2
1,1-Dichloroethene
NO
ug/L
0.50
1
11/2011917:05
75-35-4
cis-1,2-Dichloroethene
NO
ug/L
0.50
1
11/2011917:05
156.59-2
trans-1,2-Dichloroethene
NO
ug/L
0.50
1
11/20/19 17:05
156.60-5
1,2-Dichloropropane
NO
ug/L
0.50
1
11/20/19 17:05
78-87-5
1,3-Dichloropropane
NO
ug/L
0.50
1
11120/1917:05
142-28-9
2,2-Dichloropropane
NO
ug/L
0.50
1
1112011917:05
594-20-7
1,1-Dichloropropene
NO
ug/L
0.50
1
1112011917:05
563-58-6
cis-1,3-Dichloropropene
NO
ug/L
0.50
1
11/20/19 17:05
10061-01-5
trans-1,3-Dichloropropene
NO
ug/L
0.50
1
11/20/19 17:05
10061-02-6
Diisopropyl ether
NO
ug/L
0.50
1
11/20/19 17:05
108-20-3
Etylbenzene
NO
ug/L
0.50
1
11/20/19 17:05
100-41-4
Hexachloro-1,3-butadiene
NO
ug/L
2.0
1
11/20/19 17:05
87.68-3
Isopropylbenzene (Cumene)
NO
ug/L
0.50
1
11/20/19 17:05
98-82.8
Methylene Chloride
ND
ug/L
2.0
1
11/20/19 17:05
75-09-2
Methyl-tert-butyl ether
NO
ug/L
0.50
1
11/20/19 17:05
1634-04-4
Naphthalene
NO
ug/L
2.0
1
11/20/19 17:05
91-20-3
n-Propylbenzene
NO
ug/L
0.50
1
11/20/19 17:05
103-65-1
Styrene
ND
ug/L
0.50
1
11/20/19 17:05
100-42-5
1,1,1,2-Tetrachloroethane
NO
ug/L
0.50
1
11/20/19 17:05
630-20-6
1,1,2,2-Tetrachloroelhane
NO
ug/L
0.50
1
11/20/19 17:05
79-34-5
Tetrachloroelhene
NO
ug/L
0.50
1
11/20/19 17:05
127-18-4
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, L-C. Page 21 of 56
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QUALITY CONTROL DATA
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
QC Batch: 509790 Analysis Method: SM 6200B
QC Batch Method: SM 6200B Analysis Description: 6200E MSV
Associated Lab Samples: 92453831001
METHOD BLANK: 2735800
Associated Lab Samples: 92453831001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
NO
0.50
11/17/19 14:34
1,1,1-Tdchloroethane
ug/L
NO
0.50
11/17/19 14:34
1.1,2,2-Tetrachloroethane
ug/L
NO
0.50
11/17/19 14:34
1, 1,2-Trich loroethane
ug/L
NO
0.50
11117/1914:34
1,1-Dlchloroethane
ug/L
ND
0.50
11/17/19 14:34
1,1-Dichloroelhene
ug/L
ND
0.50
11/17/19 14:34
1,1-Dichloropropene
ug/L
ND
0.50
11/17/19 14:34
1,2,3-Trichlorobenzene
ug/L
ND
2.0
11/17/19 14:34
1,2,3-Trichloropropane
ug/L
ND
0.50
11/17/19 14:34
1,2,4-Trichlorobenzene
ug/L
ND
2.0
11/17/19 14:34
1,2,4-Trimethylbenzene
ug/L
ND
0.50
11/17/19 14:34
1,2-Dibromo-3-chloropropane
ug/L
NO
1.0
11/17/19 14:34
1,2-Dibromoethane (EDB)
ug/L
NO
0.50
11/17/19 14:34
1,2-Dichlorobenzene
ug/L
NO
0.50
11/17/19 14:34
1,2-Dlchloroethane
ug/L
NO
0.50
1111711914:34
1,2-Dichloropropane
ug/L
NO
0.50
11/17/19 14:34
1,3,5-Trimethylbenzene
ug/L
NO
0.50
11/17/19 14:34
1,3-Dichlorobenzene
ug/L
ND
0.50
11/17/19 14:34
1,3-Dichloropropane
ug/L
NO
0.50
11/17/19 14:34
1,4-Dichlorobenzene
ug/L
NO
0.50
11/17/19 14:34
2,2-Dichloropropane
ug/L
NO
0.50
11/17/19 14:34
2-Chlorotoluene
ug/L
NO
0.50
11/17/19 14:34
4-Chlorotoluene
ug/L
NO
0.50
11/17/19 14:34
Benzene
ug/L
ND
0.50
11/1711914:34
Bromobenzene
ug/L
NO
0.50
11/17/19 14:34
Bromochloromethane
ug/L
NO
0.50
11/17/19 14:34
Bromodichloromethane
ug/L
ND
0.50
11/17/19 14:34
Bromoform
ug/L
ND
0.50
11/17/19 14:34
Bromomethane
ug/L
NO
5.0
11/17/19 14:34
Carbon tetrachloride
ug/L
NO
0.50
11/17/19 14:34
Chlorobenzene
ug/L
NO
0.50
11/17/19 14:34
Chloroethane
ug/L
NO
1.0
11/17/19 14:34
Chloroform
ug/L
NO
0.50
11/17/19 14:34
Chloromethane
ug/L
ND
1.0
11/17/19 14:34
cis-1,2-Dlchloroethane
ug/L
ND
0.50
11/17/19 14:34
cis-1,3-Dichloropropene
ug/L
ND
0.50
11/17/19 14:34
Dibromochloromethane
ug/L
NO
0.50
11117/1914:34
Dibromomethane
ug/L
NO
0.50
11117/1914:34
Dichlorodifluoromethane
ug/L
NO
0.50
11117/1914:34
Diisopropyl ether
ug/L
NO
0.50
11/17/19 14:34
Ethylbenzene
ug/L
NO
0.50
1111711914:34
Qualifiers
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Results presented on this page are In the units Indicated by the 'units' column except where an alternate unit Is presented to the right of the result.
Date: 11/22/2019 02:19 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 23 of 56
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: LASSONDE
Pace Project No.: 92453831
PAPPAS 11-14-19
LABORATORY CONTROL SAMPLE: 2735801
Spike
LCS
LCS
% Rec
Parameter
Units
Cone.
Result
%Rec
Limits Qualifiers
1,3-Dichloropropane
ug/L
50
52.8
106
60-140
1,4-Dichlorobenzene
ug/L
50
50.6
101
60-140
2,2-Dichloropropane
ug/L
50
55.5
111
60.140
2-Chlorotoluene
ug/L
50
51.1
102
60.140
4-Chlorotoluene
ug/L
50
51.6
103
60-140
Benzene
ug/L
50
51.1
102
60-140
Bromobenzene
ug/L
50
51.7
103
60-140
Bromochloromelhane
ug/L
50
54.0
108
60-140
Bromodichloromethane
ug/L
50
52.7
105
60-140
Bromoform
ug/L
50
56.7
113
60-140
Bromomethane
ug/L
50
88.9
178
60-140 L1
Carbon tetrachloride
ug/L
50
53.0
106
60-140
Chlorobenzene
ug/L
50
50.3
101
60.140
Chloroethane
ug/L
50
40.7
81
60-140
Chloroform
ug/L
50
52.7
105
60-140
Chloromethane
ug/L
50
51.3
103
60-140
cis-1,2-Dichloroethene
ug/L
50
51.6
103
60-140
cis-1,3-Dichloropropene
ug/L
50
56.2
112
60-140
Dibromochloromelhane
ug/L
50
55.1
110
60-140
Dibromomethane
ug/L
50
50.9
102
60-140
Dichlorodifluoromethane
ug/L
50
51.3
103
60-140
Diisopropyl ether
ug/L
50
54.6
109
60-140
Ethylbenzene
ug/L
50
50.4
101
60-140
Hexachloro-1,3-butadiene
ug/L
50
54.9
110
60-140
Isopropylbenzene (Cumene)
ug/L
50
53.3
107
60-140
m&p-Xylene
ug/L
100
104
104
60-140
Methyl-tert-butyl ether
ug/L
50
54.2
108
60-140
Methylene Chloride
ug/L
50
47.7
95
60.140
n-Butylbenzene
ug/L
50
52.0
104
60.140
n-Propylbenzene
ug/L
50
51.2
102
60-140
Naphthalene
ug/L
50
51.5
103
60-140
o-Xylene
ug/L
50
52.9
106
60-140
sec-Butylbenzene
ug/L
50
51.3
103
60-140
Styrene
ug/L
50
55.1
110
60-140
tert-Butylbenzene
ug/L
50
42.9
86
60-140
Tetrachloroethene
ug/L
50
51.5
103
60-140
Toluene
ug/L
50
49.0
98
60-140
trans-1,2-Dichloroethene
ug/L
50
52.9
106
60-140
trans-1,B-Dichloropropene
ug/L
50
55.6
111
60-140
Trichloroethene
ug/L
50
51.9
104
60-140
Trichlorofluoromethane
ug/L
50
49.6
99
60-140
Vinyl chloride
ug/L
50
57.9
116
60-140
1,2-Dichloroethane-d4 (S)
%
105
70-130
4-BromoBuorobenzene (S)
%
102
70-130
Toluene-d8(8)
%
99
70-130
/\ Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 11/22/2019 02:19 PM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 25 of 56
aceAnalytical
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QUALITY CONTROL DATA
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
MATRIX SPIKE & MATRIX
Parameter
SPIKE DUPLICATE: 2736904
MS
92453051007 Spike
Units Result Cone.
MSD
Spike
Cone.
2736905
MS
Result
MSD
Result
MS
% Rae
MSD
% Rae
% Rae
Limits
RPD Qual
n-Butylbenzene
ug/L
<0.35
20
20
19.1
19.0
96
95
60-140
1
n-Propylbenzene
ug/L
<0.24
20
20
20.4
20.6
102
103
60-140
1
Naphthalene
ug/L
<0.66
20
20
21.5
21.4
107
107
60-140
0
o-Xylene
ug/L
<0.24
20
20
22.2
22.1
111
110
60-140
0
sec-Butylbenzene
ug/L
<0.25
20
20
20.7
20.9
103
104
60-140
1
Styrene
ug/L
<0.26
20
20
21.7
21.6
108
108
60-140
1
tert-Butylbenzene
ug/L
<0.25
20
20
17.8
18.5
89
92
60-140
3
Tetrachloroethene
ug/L
<0.23
20
20
19.8
20.0
99
100
60-140
1
Toluene
ug/L
<0.23
20
20
21.2
21.0
106
105
60-140
1
trans-1,2-Dichloroethene
ug/L
<0.26
20
20
21.4
21.1
107
105
60-140
2
trans-1,3-Dichloropropene
ug/L
<0.39
20
20
18.8
19.5
94
97
60-140
3
Trichloroethene
ug/L
<0.23
20
20
21.4
21.5
107
108
60-140
1
Trichlorofluoromethane
ug/L
<0.34
20
20
23.8
23.9
119
119
60-140
0
Vinyl chloride
ug/L
<0.41
20
20
24.1
23.4
121
117
60-140
3
1,2-Dichloroethane-d4 (S)
%
101
100
70-130
4-Bromofluorobenzene (S)
%
100
100
70.130
Toluene-d8 (S)
%
97
99
70-130
1\ Results presented on this page are In the units ind1rated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, L-C.
Page 27 of 56
aceAnalytical0
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QUALITY CONTROL DATA
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
METHOD BLANK: 2738320 Matrix: Water
Associated Lab Samples: 92453831002, 92453831003, 92453831004, 92453831005, 92453831006, 92453831007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Hexachloro-1,3-butadiene
ug/L
NO
2.0
11/19/19 06:30
Isopropylbenzene(Cumene)
ug/L
NO
0.50
11/19/19 06:30
m&p-Xylene
ug/L
ND
1.0
11/19/19 06:30
Methyl-tert-butyl ether
ug/L
NO
0.50
11/19/19 06:30
Methylene Chloride
ug/L
ND
2.0
11/1911906:30
n-Butylbenzene
ug/L
NO
0.50
11/19/19 06:30
n-Propylbenzene
ug/L
NO
0.50
11/19/19 06:30
Naphthalene
ug/L
NO
2.0
11/1911906:30
o-Xylene
ug/L
NO
0.50
11/19/19 06:30
sec-Butylbenzene
ug/L
ND
0.50
11/19/19 06:30
Styrene
ug/L
ND
0.50
11/19/19 06:30
tert-Butylbenzene
ug/L
ND
0.50
11/19/19 06:30
Tetachloroethene
ug/L
ND
0.50
11/19/19 06:30
Toluene
ug/L
ND
0.50
11/19/19 06:30
trans-1,2-Dichloroethene
ug/L
NO
0.50
11/19/19 06:30
trans-1,3-Dichloropropene
ug/L
NO
0.50
11/19/19 06:30
Trichloroethene
ug/L
NO
0.50
11/19/19 06:30
Trichlorofiuoromethane
ug/L
NO
1.0
11/19/19 06:30
Vinyl chloride
ug/L
NO
1.0
11/19/19 06:30
1,2-Dichloroethane-d4 (S)
%
94
70-130
11/19/19 06:30
4-Bromofiuorobenzene (S)
%
102
70-130
11/19/19 06:30
Toluene-d8 (S)
%
100
70-130
11/19/19 06:30
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
LABORATORY CONTROL SAMPLE:
Parameter
2738321
Units
Spike
Cone.
LCS
Result
LCS
%Rec
%Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
57.4
115
60-140
1,1,1-Tdchloroethane
ug/L
50
52.3
105
60-140
1,1,2,2-Tetrachloroethane
ug/L
50
55.0
110
60-140
1,1,2-Trichloroethane
ug/L
50
53.1
106
60-140
1,1-Dichloroethane
ug/L
50
52.1
104
60-140
1,1-Dichloroelhene
ug/L
50
52.0
104
60-140
1,1-Dichloropropene
ug/L
50
56.1
112
60-140
1,2,3-Trichlorobenzene
ug/L
50
58.0
116
60-140
1,2,3-Trichloropropane
ug/L
50
61.8
124
60-140
1,2,4-Trichlorobenzene
ug/L
50
57.6
115
60-140
1,2,4-Trimethylbenzene
ug/L
50
55.3
111
60-140
1,2-Dibromo-3-chloropropane
ug/L
50
59.6
119
60-140
1,2-Dibromoethane (EDB)
ug/L
50
56.2
112
60-140
1,2-Dichlorobenzene
ug/L
50
54.4
109
60-140
1,2-Dichloroethane
ug/L
50
45.9
92
60-140
1,2-Dichloropropane
ug/L
50
54.1
108
60-140
1,3,5-Trimethylbenzene
ug/L
50
55.7
111
60-140
1,3-Dichlorobenzene
ug/L
50
53.5
107
60-140
Results presented on this page are In the units Indicated by the "Units' column except where an alternate unit Is presentee to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 56
aceAnalytical x
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2739604
2739605
MS
MSD
92453831007
Spike
Spike
MS
MSD
MS
MSD
%Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
%Rec
%Rec
Limits
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
21.1
21.0
106
105
60-140
1
1,1,1-Trichloroethane
ug/L
ND
20
20
21.2
20.9
106
105
60-140
1
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
20.9
20.8
104
104
60-140
1
1,1,2-Trichloroethane
ug/L
ND
20
20
21.2
21.4
106
107
60-140
1
1,1-Dichloroethane
ug/L
ND
20
20
21.1
20.6
106
103
60-140
3
1,1-Dichloroethene
ug/L
ND
20
20
21.3
20.6
106
103
60-140
3
1,1-Dichloropropene
ug/L
ND
20
20
22.0
21.3
110
106
60-140
3
1,2,3-Trichlorobenzene
ug/L
ND
20
20
20.2
19.4
101
97
60-140
4
1,2,3-Trichloropropane
ug/L
ND
20
20
20.7
20.8
103
104
60-140
1
1,2,4-Trichlorobenzene
ug/L
ND
20
20
19.7
18.9
99
94
60-140
4
1,2,4-Trimethylbenzene
ug/L
ND
20
20
20.0
19.1
100
95
60-140
5
1,2-Dibromo-3-chloropropane
ug/L
ND
20
20
21.4
21.1
107
105
60-140
1
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
20.9
20.9
105
104
60.140
0
1,2-Dichlorobenzene
ug/L
ND
20
20
20.8
19.6
104
98
60-140
6
1,2-Dichloroethane
ug/L
ND
20
20
19.0
18.8
95
94
60-140
1
1,2-Dichloropropane
ug/L
ND
20
20
21.1
20.7
106
103
60-140
2
1,3,5-Trimethylbenzene
ug/L
ND
20
20
20.4
19.3
102
96
60-140
6
1,3-Dichlorobenzene
ug/L
ND
20
20
20.1
19.2
101
96
60-140
4
1,3-Dichloropropane
ug/L
ND
20
20
21.5
21.5
108
108
60-140
0
1,4-Dichlorobenzene
ug/L
ND
20
20
20.1
19.2
101
96
60-140
5
2,2-Dichloropropane
ug/L
ND
20
20
17.8
17.6
89
88
60-140
1
2-Chlorotoluene
ug/L
ND
20
20
20.1
19.1
100
96
60-140
5
4-Chlorotohlene
ug/L
ND
20
20
20.4
19.1
102
95
60-140
7
Benzene
ug/L
ND
20
20
21.5
20.7
107
104
60-140
3
Bromobenzene
ug/L
ND
20
20
21.1
20.1
105
100
60-140
5
Bromochloromethane
ug/L
ND
20
20
21.9
21.4
110
107
60-140
2
Bromodichloromethane
ug/L
ND
20
20
20.8
20.4
104
102
60-140
2
Bromoform
ug/L
ND
20
20
21.8
21.0
109
105
60-140
4
Bromomethane
ug/L
ND
20
20
21.2
20.5
106
102
60-140
3
Carbon tetrachloride
ug/L
ND
20
20
21.7
21.3
109
106
60-140
2
Chlorobenzene
ug/L
ND
20
20
20.3
19.4
101
97
60-140
5
Chloroethane
ug/L
ND
20
20
21.7
19.5
108
97
60-140
11
Chloroform
ug/L
ND
20
20
21.4
20.5
107
103
60-140
4
Chloromethane
ug/L
ND
20
20
21.8
20.7
109
103
60-140
5
cis-1,2-Dichloroethene
ug/L
ND
20
20
20.5
19.6
102
98
60-140
4
cis-1,3-Dichloropropene
ug/L
ND
20
20
21.1
20.6
106
103
60-140
2
Dibromochloromethane
ug/L
ND
20
20
20.8
20.3
104
102
60-140
2
Dibromomethane
ug/L
ND
20
20
20.8
20.6
104
103
60.140
1
Dichlorodi8uoromelhane
ug/L
ND
20
20
25.7
24.7
129
124
60-140
4
Diisopropyl ether
ug/L
ND
20
20
20.7
20.3
103
101
60-140
2
Ethylbenzene
ug/L
ND
20
20
20.1
19.1
100
95
60-140
5
Hexachloro-1,3-butadiene
ug/L
ND
20
20
20.1
18.3
100
92
60-140
9
Isopropylbenzene (Cumene)
ug/L
ND
20
20
21.0
19.9
105
100
60-140
5
m&p-Xylene
ug/L
ND
40
40
40.3
39.4
101
98
60-140
2
Methyl -tart -butyl ether
ug/L
ND
20
20
20.4
20.1
102
101
60-140
2
Methylene Chloride
ug/L
ND
20
20
18.5
18.3
93
91
60-140
1
Results presented on this page are In the units Indicated by me "Units' column except where an alternate unit Is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Dale: 11/22/2019 02:19 PM without the written wnsent of Pace Analytical Services, LLC. Page 31 of 56
aceAnalytical e
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QUALITY CONTROL DATA
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
QC Batch: 510408 Analysis Method: SM 6200B
QC Batch Method: SM 6200B Analysis Description: 6200B MSV
Associated Lab Samples: 92453831008. 92453831009
METHOD BLANK: 2738569
Associated Lab Samples: 92453831008, 92453831009
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
NO
0.50
11/20/19 16:28
1,1,1-Trichloroethane
ug/L
NO
0.50
11/20/19 16:28
1,1,2,2-Tetrachloroethane
ug/L
NO
0.50
11/2011916:28
1,1,2-Trichloroethane
ug/L
ND
0.50
11/2011916:28
1,1-Dichloroethane
ug/L
ND
0.50
11/20/19 16:28
1,1-Dichloroethene
ug/L
NO
0.50
11/20/19 16:28
1,1-Dichloropropene
ug/L
NO
0.60
11/20/19 16:28
1,2,3-Trichlorobenzene
ug/L
NO
2.0
11/20/19 16:28
1,2,3-Trichloropropane
ug/L
NO
0.50
11/20/19 16:28
1,2,4-Trichlorobenzene
ug/L
NO
2.0
11/20/19 16:28
1,2,4-Trimethylbenzene
ug/L
NO
0.50
11/20/19 16:28
1,2-Dibromo-3-chloropropane
ug/L
NO
1.0
11/20/19 16:28
1,2-Dibromoethane(EDB)
ug/L
ND
0.50
11/20/19 16:28
1,2-Dichlorobenzene
ug/L
ND
0.50
11/2011916:28
1,2-Dichloroethane
ug/L
ND
0.50
11/20/19 16:28
1,2-Dichloropropane
ug/L
ND
0.50
11/2011916:28
1,3,5-Trimethylbenzene
ug/L
ND
0.50
11/20/19 16:28
1,3-Dichlorobenzene
ug/L
NO
0.50
11/20/19 16:28
1,3-Dichloropropane
ug/L
NO
0.50
11/20/19 16:28
1,4-Dichlorobenzene
ug/L
NO
0.50
11/20/19 16:28
2,2-Dichloropropane
ug/L
NO
0.50
11/20/19 16:28
2-Chlorotoluene
ug/L
ND
0.50
11/20/19 16:28
4-Chlorotoluene
ug/L
NO
0.50
11/20/19 16:28
Benzene
ug/L
NO
0.50
11/20/19 16:28
Bromobenzene
ug/L
NO
0.50
11/20/19 16:28
Bromochloromethane
ug/L
NO
0.50
11/2011916:28
Bromodichloromethane
ug/L
ND
0.50
11/20/19 16:28
Bromoform
ug/L
ND
0.50
11/20/19 16:28
Bromomethane
ug/L
ND
5.0
1112011916:28
Carbon tetrachloride
ug/L
ND
0.60
11/20/19 16:28
Chlorobenzene
ug/L
ND
0.50
11120/1916:28
Chloroethane
ug/L
ND
1.0
11/20/19 16:28
Chloroform
ug/L
NO
0.50
11/20/19 16:28
Chloromethane
ug/L
NO
1.0
11/20/19 16:28
cis-1,2-Dichloroethene
ug/L
NO
0.50
11/20/19 16:28
cis-1,3-Dichloropropene
ug/L
NO
0.60
11/2011916:28
Dibromochloromethane
ug/L
NO
0.50
11120/1916:28
Dibromomethane
ug/L
NO
0.50
11/2011916:28
Dichlorodifluoromethane
ug/L
NO
0.50
11/2011916:28
Diisopropyl ether
ug/L
NO
0.50
11/20/19 16:28
Ethylbenzene
ug/L
NO
0.50
11/20/19 16:28
Qualifiers
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Results presented on thb peas are In the units Indicated by the "unite" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, L-C. Page 33 of 56
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QUALITY CONTROL DATA
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
LABORATORY CONTROL SAMPLE:
Parameter
2738570
Units
Spike
Cone.
LCS
Result
LCS
%Rec
% Rae
Limits
1,3-Dichloropropane
ug/L
50
50.2
100
60-140
1,4-Dichlorobenzene
ug/L
50
47.9
96
60-140
2,2-Dichloropropane
ug/L
50
46.0
92
60-140
2-Chlorotoiuene
ug/L
50
47.3
95
6D-140
4-Chlorotoluene
ug/L
50
48.0
96
60-140
Benzene
ug/L
50
47.9
96
60-140
Bromobenzene
ug/L
50
49.7
99
60-140
Bromochloromethane
ug/L
50
48.5
97
60.140
Bromodichloromethane
ug/L
50
48.4
97
60-140
Bromoform
ug/L
50
54.3
109
60-140
Bromomethane
ug/L
50
54.2
108
60-140
Carbon tetrachloride
ug/L
50
47.9
96
60-140
Chlorobenzene
ug/L
50
46.1
92
60-140
Chloroethane
ug/L
50
36.0
72
60-140
Chloroform
ug/L
50
45.8
92
60-140
Chloromethane
ug/L
50
50.5
101
60-140
cis-1,2-Dichloroethene
ug/L
50
46.0
92
60-140
cis-1,3-Dichloropropene
ug/L
50
52.1
104
60-140
Dibromochloromethane
ug/L
50
48.9
98
60-140
Dibromomethane
ug/L
50
49.5
99
60-140
Dichlorodifluoromethane
ug/L
50
60.1
120
60-140
Diisopropyl ether
ug/L
50
48.5
97
60-140
Ethylbenzene
ug/L
50
45.0
90
60-140
Hexachloro-1,3-butadiene
ug/L
50
49.8
100
60-140
Isopropylbenzene (Cumene)
ug/L
50
47.8
96
60-140
m&p-Xylene
ug/L
100
91.0
91
60-140
Methyl-tert-butyl ether
ug/L
50
48.5
97
60-140
Methylene Chloride
ug/L
50
42.5
85
60-140
n-Butylbenzene
ug/L
50
48.1
96
60-140
n-Propylbenzene
ug/L
50
47.0
94
60-140
Naphthalene
ug/L
50
51.5
103
60-140
o-Xylene
ug/L
50
46.9
94
60-140
sec-Butylbenzene
ug/L
50
48.0
96
60-140
Styrene
ug/L
50
49.1
98
60-140
tert-Butylbenzene
ug/L
50
39.3
79
60-140
Tetrachloroethene
ug/L
50
44.8
90
60-140
Toluene
ug/L
50
45.9
92
60-140
trans-1,2-Dichloroethene
ug/L
50
48.2
96
60-140
trans-1,3-Dichloropropene
ug/L
50
51.8
104
60-140
Trichloroethene
ug/L
50
46.6
93
60-140
Tdchlorofluoromethane
ug/L
50
41.3
83
60-140
Vinyl chloride
ug/L
50
53.3
107
60-140
1,2-Dichloroethane-d4 (S)
%
101
70-130
4-Bromofluorobenzene (S)
%
98
70-130
Toluene-d8 (S)
%
100
70.130
Pace Analytical Services, LLC
2226 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Qualifiers
Results presented on this papa are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
MATRIX SPIKE & MATRIX SPIKE
Parameter
DUPLICATE: 2738571
MS
92453831008 Spike
Units Result Conc.
MSD
Spike
Conc.
2738572
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
n-Butylbenzene
ug/L
ND
20
20
18.9
20.3
94
102
60-140
7
n-Propylbenzene
ug/L
ND
20
20
19.0
20.4
95
102
60-140
7
Naphthalene
ug/L
ND
20
20
18.7
20.8
93
104
60-140
11
o-Xylene
ug/L
ND
20
20
19.8
20.9
99
104
60-140
6
sec-Butylbenzene
ug/L
ND
20
20
19.1
20.8
96
104
60-140
8
Styrene
ug/L
ND
20
20
20.1
21.4
100
107
60-140
6
tert-Butylbenzene
ug/L
ND
20
20
16.1
17.7
80
88
60-140
9
Tetrachloroethene
ug/L
ND
20
20
18.7
19.5
94
98
60-140
4
Toluene
ug/L
ND
20
20
19.1
19.9
95
99
60-140
4
trans-1,2-Dichloroethene
ug/L
ND
20
20
20.7
21.8
104
109
60-140
5
trans-1,3-Dichloropropene
ug/L
ND
20
20
20.0
20.8
100
104
60-140
4
Trichloroethens
ug/L
ND
20
20
19.7
20.6
98
103
60-140
5
Trichlorofluoromethane
ug/L
ND
20
20
22.1
22.5
111
112
60-140
2
Vinyl chloride
ug/L
ND
20
20
23.4
24.6
117
123
60-140
5
1,2-Dichloroethane-d4 (S)
%
102
100
70-130
4-Bromofluorobenzene (S)
%
100
99
70-130
Toluene-d8 (S)
%
99
98
70-130
Results presented on this page are In the units Indicated by the "Units" column except where an alternate, unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/22/201902:19 PM without the written consent of Pace Analytical Services,LLC.
Page 37 of 56
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1
QUALITY CONTROL DATA
Pace Analylical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
QC Batch: 510493 Analysis Method: SM 254OC-2011
QC Batch Method: SM 254OC-2011 Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 92453831002, 92453831003, 92453831004, 92453831005, 92453831006, 92453831007, 92453831008
METHOD BLANK: 2739011 Matrix: Water
Associated Lab Samples: 92453831002, 92453831003, 92453831004, 92453831005, 92453831006, 92453831007, 92453831008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 11/19/19 23:31
LABORATORY CONTROL SAMPLE: 2739012
Spike LCS LCS %Rec
Parameter Units Cone. Result %Rec Limits Qualifiers
Total Dissolved Solids Ill 250 250 100 90-110
SAMPLE DUPLICATE: 2739013
92453977006 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 78000 u9/L 81.0 4
SAMPLE DUPLICATE: 2739014
92453831008 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 83.0 81.0 2
Results presented on this page are In the units indicated by the "Units' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, U.C.
Page 39 of 56
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7178
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
QC Batch: 509698
Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993
Analysis Description: 350.1
Ammonia
Associated Lab Samples: 92453831001
METHOD BLANK: 2735400
Matrix: Water
Associated Lab Samples: 92453831001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Ammonia mg/L
ND 0.10
11/15/1912:02
LABORATORY CONTROL SAMPLE: 2735401
Spike
LCS
LCS %Rec
Parameter Units
Cone.
Result
%Rec Limits
Qualifiers
Nitrogen, Ammonia mg/L
5
4.9
97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2735402
2735403
MS
MSD
92453325001
Spike
Spike MS
MSD MS
MSD
%Rec
Parameter Units Result
Cone.
Cone. Result
Result % Rae
% Rae
Limits RPD Oual
Nitrogen, Ammonia mg/L 5.4
5
5 10.3
10.3 99
97
90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2735404
2735405
MS
MSD
92453831001
Spike
Spike MS
MSD MS
MSD
%Rec
Parameter Units Result
Cone.
Cone. Result
Result %Rec
%Rec
Limits RPD Qual
Nitrogen, Ammonia mg/L ND
5
5 4.6
4.5 91
91
90-110 0
Results presentee on this page are In the units Indicated by the -Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Dale: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, I.I.C.
Page 41 of 56
w
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I
QUALITY CONTROL DATA
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
QC Batch: 509665 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92453831001, 92453831003, 92453831004, 92453831005, 92453831006, 92453831007, 92453831008
METHOD BLANK: 2735311 Matrix: Water
Associated Lab Samples: 92453831001, 92453831003, 92453831004, 92453831005, 92453831006, 92453831007, 92453831008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L NO 0.040 11/15/1902:37
LABORATORY CONTROL SAMPLE: 2735312
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rae Limits Qualifiers
Nitrogen, Nitrate mg/L 1.5 1.5 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2735315 2735316
MS MSD
92453750002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Cone. Cone. Result Result % Rae % Rae Limits RPD Qual
Nitrogen, Nitrate mg/L 22.2 1.5 1.5 23.3 26.5 68 287 90-110 13
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2735347
2735348
MS
MSD
92453752001 Spike
Spike
MS
MSD MS MSD % Rae
Parameter Units Result Cone.
Conc,
Result
Result % Rae % Rae Limits RPD Qual
Nitrogen, Nitrate mg/L 29.8 1.5
1.5
35.1
37.0 355 478 90-110 5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presentee to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/221201902:19 PM without the written consent of Pace Analytical Services,LLC.
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
OC Batch: 510002
Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993
Analysis Description: 365.1 Phosphorus, Total
Associated Lab Samples: 92453831001
METHOD BLANK: 2736847
Matrix: Water
Associated Lab Samples: 92453831001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Phosphorus mg/L
ND 0.050
11/18/1915:59
LABORATORY CONTROL SAMPLE: 2736848
Spike
LIDS
LCS % Rec
Parameter Units
Conc.
Result
%Rec Limits
Qualifiers
Phosphorus mg/L
2.5
2.5
100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2736849
2736850
MS
MSD
92453361001
Spike
Spike MS
MSD MS
MSD
%Rec
Parameter Units Result
Conc.
Conc. Result
Result %Rec
e/ Rec
Limits RPD Qual
Phosphorus mg/L 0.30
2.5
2.5 2.8
2.8 101
100
90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2736851
2736852
MS
MSD
92453445001
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec
% Rec
Limits RPD Qual
Phosphorus mg/L 1.0
2.5
2.5 3.6
3.6 103
102
90-110 1
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right or the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
Date: 11/22/201902:19 PM without the written consent of Pace Analytical Services,LLC.
Page 45 of 56
aceAnalytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
QC Batch: 509855
Analysis Method: SM 4500-CI-E-2011
QC Balch Method: SM 4500-CI-E-2011
Analysis Description: 4500
Chloride
Associated Lab Samples: 92453831001
METHOD BLANK: 2736127
Matrix: Water
Associated Lab Samples: 92453831001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed
Qualifiers
Chloride mg/L
NO 1.0
11/15/1918:49
LABORATORY CONTROL SAMPLE: 2736128
Spike
LCS
LCS %Rec
Parameter Units
Cone.
Result
%Rec Limits
Qualifiers
Chloride mg/L
20
20.3
102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2736129
2736130
MS
MSD
92453831001
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Cone.
Cone. Result
Result %Rec
%Rec
Limits RPD Qual
I
l Chloride mg/L 11.0
10
10 21.0
21.0 100
100
90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2736131
2736132
MS
MSD
92453089003
Spike
Spike MS
MSD MS
MSD
e/ Rae
Parameter Units Result
Conc.
Cone. Result
Result % Rae
% Rae
Limits RPD Qual
Chloride mg/L 16.8
10
10 26.6
26.5 98
98
90-110 0
Results presented on this page are In the units Indicated by the "Units" column except More an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
QC Batch: 509866
Analysis Method: SM 531 OB-2011
QC Batch Method: SM 531OB-2011
Analysis Description: 5310B
TOG
Associated Lab Samples: 92453831001
METHOD BLANK: 2736234
Matrix: Water
Associated Lab Samples: 92453831001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Total Organic Carbon mg/L
NO 1.0
11/15/1918:54
LABORATORY CONTROL SAMPLE: 2736235
Spike
LCS
LCS e/ Rae
Parameter Units
Cone.
Result
%Rec Limits
Qualifiers
Total Organic Carbon mg/L
25
25.8
103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2736236
2736237
MS
MSD
92453831001
Spike
Spike MS
MSD MS
MSD
% Rae
Parameter Units Result
Cone.
Cone. Result
Result %Rec
%Rec
Limits RPD Qual
Total Organic Carbon mg/L 3.7
25
25 28.6
28.7 100
100
90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2736336
2736337
MS
MSD
2625494001
Spike
Spike MS
MSD MS
MSD
%Rec
Parameter Units Result
Cone.
Cone. Result
Result %Rec
%Rec
Limits RPD Qual
Total Organic Carbon mg/L 3.6
25
25 29.1
28.9 102
101
90-110 1
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
QC Batch: 510389
Analysis Method: SM 531OB-2011
QC Batch Method: SM 531OB-2011
Analysis Description: 5310E TOC
Associated Lab Samples: 92453831006, 92453831007,
92453831008
METHOD BLANK: 2738479
Matrix: Water
Associated Lab Samples: 92453831006, 92453831007,
92453831008
Blank Reporting
Parameter Units
Result Limit
Analyzed
Qualifiers
Total Organic Carbon mg/L
NO 1.0
11/19/19 19:32
LABORATORY CONTROL SAMPLE: 2738480
Spike LCS
LCS % Rae
Parameter Units
Cone. Result
%Rec Limits
Qualifiers
Total Organic Carbon mg/L
25 25.2
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2738481 2738482
MS MSD
92453831006
Spike Spike MS
MSD MS
MSD
%Rec
Parameter Units Result
Cone. Cone. Result
Result % Rae
% Rae
Limits RPD Qual
Total Organic Carbon mg/L 6.1
25 25 28.4
28.8 89
91
90-110 1 M7
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2738527 2738528
MS MSD
92452885003
Spike Spike MS
MSD MS
MSD
% Rae
Parameter Units Result
Cone. Cone. Result
Result %Rec
%,Rec
Limits RPD Qua]
Total Organic Carbon mg/L ND
25 25 24.4
24.7 97
98
90-110 1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: LASSONDE PAPPAS 11-14-19
Pace Project No.: 92453831
Lab ID
92453831001
92453831002
92453831003
92453831004
92453831005
92453831006
92453831007
92453831008
92453831009
92453831001
92453831002
92453831003
92453831004
92453831005
92453831006
92453831007
92453831008
92453831001
92453831002
92453831003
92453831004
92453831005
92453831006
92453831007
92453831008
92453831001
92453831002
92453831003
92453831004
92453831005
92453831006
92453831007
92453831008
92453831001
92453831002
92453831003
92453831004
92453831005
92453831006
92453831007
92453831008
92453831001
92453831002
Sample ID
MW-4
MW-5
MW-6
MW-7R
MW-8
MW-9
SW-1
SW-2
TRIP BLANK
MW-4
MW-5
MW-6
MW-7R
MW-8
MW-9
SW-1
SW-2
MW-4
MW-5
MW-6
MW-7R
MW-8
MW-9
SW-1
SW-2
MW-4
MW-5
MW-6
MW-7R
MW-8
MW-9
SW-1
SW-2
MW-4
MW-5
MW-6
MW-7R
MW-8
MW-9
SW-1
SW-2
MW-4
MW-5
Date: 11 /22/2019 02:19 PM
QC Batch Method
SM 6200B
SM 6200B
SM 62006
SM 6200B
SM 6200B
SM 6200B
SM 6200B
SM 6200B
SM 6200B
SM 254OC-2011
SM 254OC-2011
SM 254OC-2011
SM 2540C-2011
SM 254OC-2011
SM 2540C-2011
SM 254OC-2011
SM 2540C-2011
SM 9222D-2006
SM 9222D-2006
SM 9222D-2006
SM 9222D-2006
SM 9222D-2006
SM 9222D-2006
SM 9222D-2006
SM 9222D-2006
EPA350.1 Rev 2.01993
EPA 350.1 Rev 2.0 1993
EPA 350.1 Rev 2.0 1993
EPA 350.1 Rev 2.0 1993
EPA 350.1 Rev 2.0 1993
EPA 350.1 Rev 2.0 1993
EPA 350.1 Rev 2.0 1993
EPA 350.1 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
EPA 365.1 Rev 2.0 1993
EPA 365.1 Rev 2.0 1993
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
QC Batch Analytical Method
509790
510347
510347
510347
510347
510347
510347
510408
510408
509672
510493
510493
510493
510493
510493
510493
510493
509769
509769
509769
509769
509769
509769
509769
509769
509698
509701
509701
509701
509701
509701
509701
509701
509665
509667
509665
509665
509665
509665
509665
509665
510002
510004
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
SM 9222D-2006
SM 9222D-2006
SM 9222D-2006
SM 9222D-2006
SM 9222D-2006
SM 9222D-2006
SM 9222D-2006
SM 9222D-2006
Analytical
Batch
509771
509771
509771
509771
509771
509771
509771
509771
EPA 365.1 Rev 2.0 1993 510105
EPA 365.1 Rev 2.0 1993 510106
Page 53 of 56
Document Name:
Document Revised: February 7, 2018
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
aceAnallnlcal
F-CAR-CS-033-Rev.06
Pace Carolinas Quailt OfOce
*Check mark top half of box if pH and/or dechlorination Is
verified and within the acceptance range for preservation
samples,
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottle
Projec' WO# : 92453831
111111111111111111111111
92453831
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pH Adjustment Log for Preserved Samples
Sample ID
Type of preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot x
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will beset to the North Carolina DEHNR Certification Office (i.e.
Out of hold, Incorrect preservative, out of temp, Incorrect containers.
Page 55 of 56
Attachment 2
Well Sampling Logs and Instrument
Calibration Data Sheet
ANCHOR
QEA. '
Well Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name:
L NS !r g-vl
l 1,- Q��.ry/t� Date:
// /jV I q
Project Number.
C� 08X_ U1. 01 Weather
0-1-0 1 t) "1 j0 S j C . 6 4-tb-LK
Sampling Personnel:
G PA-1 Twos m A f5 oyt Sample Time:
1 r
3 5v
Well Number.
j
r
Well Depth in Feet (WD):
/
Well Diameter.
.2- `r
Water Level in Feet (WL):
CI
Type of Casing:
/RUC
Length of Water Column:
O�� %: feet/t Ln ,
Measuring Point
7� �;,
(WD) - NO = (LWC)
Flush Mount / uk-Up
One Casing Volume:
gallons
b
Comments:
(LWC) x (WCV)
Three Casing Volumes:
S� gallons
Actual Volume Purged:
y J gallons
tagged bottom at: (%
rJ ft TOC
Well Casing Volumes (WCV)
1" = 0.04 Gal/Ft " = 0.16
Gal/F 3" = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" = 1.5 GaVFt 8" = 2.6 Gal/Ft 12" = 5.9 Gal/Ft
Purge Method:
alter- is . Bailer -Teflon Dedicated Pump Whale Pump Grundfos
Other.
Sample Method:
Bailer-Dis Bailer -Teflon
Dedicated Pump Whale Pump Gruni fos
Other:
1 Oxidation --
Gallons Temp
Dissolved Specific Cond. pH (S.U.)
Reduction Turbidity
Reading Time
Purged (•C)
Oxygen (mg/L) (pS/cm) report to 0.7 S.U.
Potential (mV) (NTU) Comments
1 /33+-
D t;-.Y
_ i.C(� GL,c 6. -1
3
2 Ilya
�. 1s r�.,i
3rYy L'j 5•v P
- /c%i•%
3 nys-
}' T 14. 6
3 .J r I k: 5: b5
/9/r 7 9s.�
4 1351
,1,5"15"%
3,/, 172.6 s.> %
zeS i)
5
/"rs'W vr/W:
e
B-iG T 1= lac
7
8
9
10
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
TDS
250 mL Plastic
jreep' f
125 mL Plastic
- �%��N
40 mL Glass
`•�'MH�!'�.sf�Ps+sav
ti VUG- 6-00
*L / saf�oru Ira
1 L Glass
Other
,r ''`
Protective Casing: � Pad: rO % Lock:.� Vegetation: y� Access: GO
Sampling Personnel Signature:
/ �..
ck
Date: /., Ni ry/' 01
Notes:
Well Casing Volumes defined in Table 2 of the Region 4 Environmental Protection Agency (EPA) Science and Ecosystem Support Division (SESD) document utled Operating Procedure -
Groundwoter5amptliy last revised Apol 26, 2017.
Samples are analyzed immediately upon collection.
Minimum volume purged: 3 well volumes. Sample time determined by parameter stabilludon.
°C: degrees Celsius
pS/on: micro-Siemen per centimeter
mg/L milligrams per liter
Method Reference:
Temperature: SM 2550 B-2010
DO: SM 4500 O 6-2011
mV: millivolt
MU: nephelometdc turbidity units
S.U: Standard Units
Specific conductivity EPA Method 120.1, Rev. 1982
pH: SM 4500-H' B-2011
I
Page 1 of 1
kZANCHOR
QEA
Well Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: 1- 4" i,`s d e pAe () l)�i
Date:
/ I / / y
/ )
Project Number. 782 01
Weather.
e " "O.I
30'"'0 { S j / I, L
Sampling Personnel: C , 104-n ylSfa � . ^+41.1 o,4 Sample Time:
/ L 2
p
r
II
Well Number. 1 m 1 (v1/ - b
Well Depth in Feet (WD):
p' s0'� s
`� 4
Well Diameter. 7, ''
Water Level in Feet (WL):
/5. 5 9
r 714 L
Type of Casing: PVC C
Length of Water Column:
`Jl,
feet
Measuring Point: IT) C
(WD) - (WL) = (LWC)
Flush Mount / 5 DIP
One Casing Volume:
3
gallons
Comments:
(LWC) x (WCV)
Three Casing Volumes:
3 O
gallons
Actual Volume Purged:
Q
gallons
tagged bottom at R TOC
Well Casing Volumes (WCV)
1" = 0.04 GaII/Ft 0.16 Gal/Ft 3' = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" - 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12' = 5.9 Gal/Ft
Purge Method: ;' Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Gmndfos Other.
Sample Method: Bailer-Disp._.J Bailer -Teflon Dedicated Pump Whale Pump Gmndfos Other.
Oxidation
FMGam TempDissolved
Specific Cond, PH(S.U.)
Reduction
Turbidity
Reading Timeed
(°C) Oxygen (mg/L)
(ps/cm) report to 0.11111.
Potential (mV)
(NTU) Comments
1 0
I11-s.9 •3S
2-79• 3
)'L6
2 i4b /.0 /5 z.� /
ivy 1 51J/
% Eo• 3
9,V,3
3 i ilu 7, '157,-7 2 .5-2_
l y/9. L S'e3 D
7- 55, 3
4 iLls'3.o !/s.) 1.g1_
!Y'>',Z S•3
2-5/.�/
7
8
9
10
Sampling Container Number of Containers Requested Analysis
500 mL Plastic
250 ml. Plastic 2
125 mt. Plastic
/? L
IKO�G/'�-NNI(A�LI Q� / �Or/lrtp/FtrS
(� ,•'jlyi /.
40 mL Glass rl Git•f
IN,
3 s.'/3k rv,rL VQG' a2Oo/ f O
1 L Glass
Other
Protective Casing: B S Pad: _*.F Lock: ` Vegetation: Access:
Sampling Personnel Signature: G' /
Date: / /
/- -2V1 /
Notes:
Well Casing Volumes defined in Table 2 of the Region 4 Environmental Protection Agency (EPA) Science and Ecosystem Support Division (SESO) document tided Operotalg Procedure -
Groundwoter5ampfng last revised Apol 26, 2017.
Samples are analyzed immediately upon collection.
Minimum volume purged: 3 well volumes. Sample time determined by parameter stabilization
'C.' degrees Celsius
pS/cm: micro-Siamen per centimeter
mg/L• milligrams per I ter
Method Reference:
Temperature: SM 2550 B-2010
DO: SM 4500 O G-2011
mV: millivolt
NTU: nephelometric turbidity units
S.U. Standard Units
SpecfiC conductivity. EPA Method 120.1, Rev. 1982
PH: SM 4500-H' B-2011
Page 1 of 1
r
kizANCHOR
QEA
well
Project Name:
Lars,s;Waf Po�epCS-
Project Number.
c -1 7 #8 7-
Sampling Personnel:
C PAIAcr-ro l-4
Well Number.
Well Diameter.
Type of Casing:
PVC
Measuring Point
TUC
Flush Mount / S�flc•k=Up t
Comments:
bottom at: /S_yy- ft TOC
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Date:
! 1// -111" /
Weather.
Oven« r 3pdFr
S� i? b �ezt
Sample Time:
fiJ 15
Well Depth in Feet (WD):
1 .73
Water Level in Feet(WL):
q 75
Length of Water Column:
14. 1b'
feet
(WD) - (WL) = (LWC)
One Casing Volume:
0.4p Q
r
gallons
(LWQ x(WCV)
Three Casing Volumes:
„7-. L' J
gallons
Actual Volume Purged:
a 00
gallons
_ Well Casing Volumes (WCV)
_
1" = 0.04 Gal/Ft (2" = 6.16 Gal/Fo 3' = 0.37 Gal/Ft 4' a 0.65 Gal/Pt 6' = 1.5 Gal/Ft a" = 2.6 Gal/Ft 12" = 5.9 Gal/Ft
Purge Method: oiler -Di Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other.
Sample Method: Bailer-Dis Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other.
1
z
3
4
5
6
7
8
9
10
Gallons
Temp
I
Dissolved
Specific Cond.
PH (S.U.)
Reduction
Turbidity
Time
Purged
CC)
Oxygen (mg/L)
(PS/cm)
report to 0.7 S.U.
Potential (mV)
1 (NTU)
Comments
73"l4
'_iq1"/
!t •'
�,t�r
CC
!b � '1
�j,(7.
'J 3(I,�
.3. �
L.[aai
76, 7
_r,
/Ota�',�•?>
��.0
r.7C
5L2.5.
G.73
i
/odor
/45
2, cr
�y,i
a{.(,a
j 45,L
4.71
'�'H'
2,&1
17-7
4t.,4cavw1)
Number of Contalners
Analysis
250 mL Plastic
125 mL Plastic 2- feel 6vl!�rxrn a"rsl I(.�tv),{%
Glass 2 ' V d oar 4M�11k
40 m
u/r��f 3 u7fv, voc Quo e'J roc
1 LGlass
Other
Protective Casing: 0 Pad: S- Lock Vegetation:- 1M Access: AJo
Sampling Personnel Signature:
Data:
P'l,J Vw
iAPM} Fit 'rx
Y,BI
Well Casing Volumes defined in Table 2 of the Region 4 Environmental Protection Agency (EPA) Science and Ecosystem Support Division (SESD) document titled Operoting Procedure -
Groundwater Sompting last revised April 26, 2017.
Samples are analyzed immediately upon collection.
Minimum volume purged: 3 well volumes. Sample time determined by parameter stabilization.
'C: degrees Celsius MV. millivolt
pS/cm micro-Siamen per centimeter NTU: nephelometfic turbidity units
mg/L milligrams per liter S.U.: Standard Units
Method Reference: Speciflc conductivity. EPA Method 120.1, Rev. 1982
Temperature: SM 2550 8- 20 10 pH: SM 4500-H' 8.2011
D6. SM 4500 O G-2011
Page 1 of 1
ANCHOR
QE'A 64..4/
6.L.4.n
Surface Water Samplina Lou
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name:
t,41 S 0.-VbC Ph2e,i 5 _
Date:
Project Number.
CU42.2 _oh Ul
Weather.
Sampling Personnel:
A. v%, A C GS L1"1
Sample Name:
/� W . I
.Iln S I
Comments:
P L L (^L Y L` r Z /i►yr /V (/X ti/
v
I? /�. V'L V I" lr 1%L L-A-,, 0 I -
13 a It) c' ( 111.)0 it SIDc' ( A)^
P Pgro-1J
hr AnN-Y L. S " I L L
Sample Method:
Grab Syringe Pump
Bailer-Disp. Other
Oxidation
Dissolved
Specific Cond.
pH (S.U.)
Reduction
Turbidity
Time I Temp ('C)
Oxygen (mqN
(PS/an)
report to 0.1 S.U.
Potential (mV)
(NTU)
Comments
015' (P.H
/2,tiD
goi-�
6116
'LUS.L
y5,( C���
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
r
C vt1Ca t
250 mL Plastic
1_ i 1_
s•�
125 mL Plastic
D
40mLGlass
♦ V0C- i
1 L Glass
Other
Vegetation: it A -A s Access: ( � I)
Sampling Personnel Signature: Q V'--e �s Date: 11 11 4 11 C
Notes:
Samples are analyzed immediately upon collection.
'C degrees Celsius
PS/cm: micro-Siemen per cubic centimeter
mg/L• milligrams per liter
mV: millivolt
NTU: nephelometric turbidity units
S.U.: standard units
Method Reference:
Temperature: SM 2550 B-2010
Speck conductivity EPA Method 120.1. Rev. 1982
DO: SM 4500 O G-2011
pH: SM 4S00-H' 8.2011
Page 1 of 1
ANCHOR
IDEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
equipment uocumentation and instrument Calibration Data Sheet
11 � � CALIBRATION DOCUMENTATION
Project Name: ,r30.t a Pappi WOtter (i(r.ea✓� C� l-1 -i
'1o9 Lq`tr Person Conducting Calibration: ns a
Project Number. Cq/49*?--bJ.OI Date of Calibration:
Project Location: T�endt�s ad vlf✓Cr NG Date of Field Measurements•.
EQUIPMENT DOCUMENTATION
Equipment or meters used to take measurements (e.g., water level meters, survey equipment):
Equipment Type
I Serial Number
I Brand
I Date of Use
150-ft Water Level
26154
T Solinlst
150-ft Water Level
22754
Sotinist
150-ft Water Level
150
Testwell
150-ft Drawdmn
MP30-1527
QED
Other
Select Turbidimeter. Hach 210OQ (s/n 151006045207)
HF Scientific MicroTPW (s/n 200601045)
Calibration 1 20 NTU 1 100 NTU I B00 NTU
NTU 1 0.02 NTU
Dissolved Oxygen
--
Inmapn r'
6'[-7
Lai:
,r'(j.
mmHg:
kEy-
Temperature CC):
/2.rl
'7�/
Time:
NA
PH 7 S.U.
report to 0.1 S.U.
Initial:
,..
pHmV.
�22. `'�'
Cal:
�rG�
'eL�m1��
/
Tlme: o
_ 07✓Q
reporttoaIs.u.
4-10
1`F2
*.U'
72-2
.a
PH 10S.U.
report to 0.1 S.U.",
Initial: ,,/I
7
pHm V;
CAC ,'�8'�.Z
Cal:
/
p 1V:
Time: r—
7
QC- PH 7 S.U.
moort to o.I Su.
AM Time:
07 µi4
Meas:
`-T n2
Mid Day Time:
Check:
PM Time;
Check
_._
✓!1 %9n -�:,
S/cm••
q56 I
l00�
GZvt
I I
H.inlq
QC-:
PS/cm
AM Time:
WZY1
Mass:
lY8
Mid Day Time:
Check
PM Time
Check
CAP
A
te�rr..""
ORP-262.y//_mV
Initial:
�FZ-5
Cal:
C*2-5'
Temperature CC):
I .fl
Time:
073`
!i/2/`adiy
Signature: l Jk7T1/ Date: 1111I /2 v
Notes)
1. Electmnk equipment calibrated according to the manufacturers operation manual.
2. Specific conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows: Specific Conductiviry, pH 7, pH 4, pH 10, DO, ORP, QC checks.
4. QC Acceptable Ranges pH +/- 0.1 SA. and Specific conductivity IM of the true value. If QC readings are out of mrge, the Instrument needs to be recalibrated.
5.. Ind'lates that a QC check must be performed In the morning, afternoon, and the end of the day, or every four houn.
6." Indicates to choose a Specific Conductivity buffer of 1413.447, 84, or 23 mS which is closest to historical readings from the project location,
Method Reference: Temperature: SM 2550 B-2070 1 Spedfic conductivity: EPA Method 120.7, Rev. 7982 1 DO: SM 45000 G-2011 1 pH: SM 4500-Ha B-2011
Page 1 of 1
Attachment 3
DEQ GW-59A — Compliance Report Form
GW-59A COMPLIANCE REPORT FORM Permit # WQ0004797
(Submit one each nmoilaring perlod )eilh GII=59 forth.)
I
Enter date monitoring results were due. (12/3i/2o1g) Will this monitoring report (GW-59 and GW59A)
YES
NO
be submitted after the established due date?
X
2
Was any required information missing on the GW-59 report forms?
YES
NO
IF the answer to question 1 or 21s 'YES, list in the space provided below the well Identification numbers) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged easing, unlocked or missing cap, missing
YES
NO
Identification plate, area overgrown, etc.)? Ifthe ansiver is "Yes", contact the Regional Ofce forguidm(ce.
X
4
Are any monitored constituents equal to or above the established standards?
YES
NO
If the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituents) and concentratlon(s)
exceeding standards in the space provided below:
Nitrate (2L - 30 mg/L): MW-7R®19.1 mg/L
Fecal Coliform (Total Conform 2L standard. 1.0 CFU/100m ): MW-6044.0 CM1100mL, MW-802.0 CFU/300m1, MW-507.0 CPU/mL
Tetrachloroethene (2L = 0.9 pg/L) : MW-5822.4 pg/L
Trichlomethene (2L - 3 4g/L) : MW-504.4 pg/L
5
For the constituents Identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) In the same well(s) In the last two years?
X
If the answer to question 5Is "NO" skip to section 8.
If the answer to question 5 Is "YES", list in the space provided below, each well with constituents) exceeding
standards, concentration(s) reported, and sample collection date foreach occurrence (for the last two years).
Nitrate Fecal Coliform Fecal Coliferm Fecal Conform T8trachloreethene Trichlomethene
MW-9R (mg/L) MW-5 (CFU/100W MW-6 (CFU/100m ) MW-8 (CFU/10omL) MW-5 (ug/L) MR-5 (ug/L)
05/02/18: 15.5 05/02/18:2.0 05/02/18: 1.0 05/02/18: ND 11/8/11: 35.9 11/08/17: 4.6
11/02/18: 69.0 11/02/18: ND 11/02/18; 69.0 11/02/18: 19.0 11/02/18: 39.1 11/02/18: 6.0
05/21/19: 20.2 05/21/19: ]A 05/21/19: 23.0 05/21/19: ND 11/14/19: 22.4 11/14/19; 4.4
11/14/19: 17.1 11/14/19: 7.0 11/14/19; 44.0 11/14/29: 2.0
6
Are the monitoring wells listed In section 6 located at or beyond the review boundary?
YES
NO
MW-5, MW-TR, and MW-6 are at or beyond the review boundary.
X
If the answer Is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer Is "NO", monitoring wells may be Improperly
located; contact the Regional Office.
7
Is the permittee Implementing previously approved actions required by the Division Involving this
YES
NO
groundwater quality problem?
X
If the answer to question 71s 'YES'; describe those actions In the space provided below.
If the answer to question 7Is "NO ; contact the Regional Office within 90 days: an evaluation may be
reaulred to determine the Impact the waste disposal system /s having at the review and compliance
boundaries surrounding this facility. Failure to do so may sublect the oermlttee to a Notice of Violation,
fines, and/or penalties.
Fecal coliforn should not be attributable to site operations. Historical monitoring of an on -site tributary of Mud
Creek has found high levels of fecal caliform.
Nitrate concentrations exceeded the groundwater standard in MW-TR and MW-8 for the first time in May 2016.
The high concentrations of nitrate are likely attributable to the frequent flooding of Mud Creek.
8
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with G W-59 forms for required wells to the address provided at the top of the current G W-59 form.
I hereby acknowledge that the above Information was evaluated and the Information submitted in this
report (Compllance Report GW-59A) is true and complete to the best of my knowledge.
Signature of Permlltee (or Authorized Agent) Date
M-59A 12/8/2903
Attachment 4
DEQ GW-59 — Groundwater Quality
Monitoring: Compliance Report Forms
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