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HomeMy WebLinkAboutWQ0004797_Groundwater Monitoring Report November 2019_20191220Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 828.281.3350 Tracy Wolfe Lassonde Pappas & Co., Inc. 125 Industrial Park Road Hendersonville, North Carolina 28792 Re: November 2019 Groundwater Sampling Event Clement Pappas NC, LLC Dear Ms. Wolfe, Zy2 ANCHOR QEA December 20, 2019 JAN 0 3 2020 Anchor QEA of North Carolina, PLLC, is pleased to present the results of the November 2019 water quality monitoring event at the Clement Pappas NC, LLC (Clement Pappas) facility (the Site) that is located at 485 Brookside Camp Road in Hendersonville, North Carolina. Groundwater Quality Anchor QEA performed the groundwater sampling event at the subject facility (the Site) on November 14, 2019. A Site location map is included as Figure 1. The groundwater sampling event was performed in accordance with North Carolina Department of Environmental Quality (DEQ) wastewater irrigation system permit No. WQ0004797 (reissued September 3, 2015). Anchor QEA collected groundwater samples from six monitoring wells: MW-4, MW-5, MW-6, MW-7R, MW-8, and MW-9. (Monitoring well MW-9 was installed on April 14, 2015, to replace the previously damaged monitoring well MW-2R.) The locations of the monitoring wells are shown in Figure 2. Anchor QEA submitted the groundwater samples to Pace Analytical Services, Inc., a North Carolina -certified laboratory, for analysis of the parameters specified in the permit. Microbiology and Wet Chemistry Table 1 summarizes the current and historical laboratory analytical results for microbiology and wet chemistry. All parameters analyzed were below the permit limits', except for nitrate. Nitrate detections are summarized as follows: • The permit limit for nitrate is 10 milligrams per liter (mg/L). • Nitrate was detected in MW-4 (0.42 mg/L), MW-5 (0.055 mg/L), MW-6 (0.56 mg/L), MW-8 (1.2 mg/L), and MW-9 (0.89 mg/L) at concentrations below the permit limit. Most of the permit limits are represented by the 2L standards (per Title 15A, North Carolina AdministratRI'PINCAC), Subchapter 2L, Section.0202 JAiJ S 2R�� 1 ! I,.� \\ashevi11e1\asheville\Projects\Clement Pappas\RepoM\2019\Nmember\Nw tuber 2019 Groundwater Sampling Event Clement Pappas NA/4ttqx 0ua l ity Regional Operations Asheville Regional Office December 16, 2019 Page 3 The irrigation fields experienced significant flooding during 2017, 2018, and 2019. As previously stated, flood water from Mud Creek is suspected to have impacts on Site groundwater. Rainfall data associated with each flooding event is summarized as follows: • January 23, 2017: 1.92 inches • March 31, 2017: 3.23 inches • April 4, 2017: 1.50 inches • April 5, 2017: 1.51 inches • April 24, 2017: 3.23 inches • May 25, 2017: 4.25 inches • September 12, 2017: 2.39 inches • October 24, 2017: 4.90 inches • October 28, 2017: 2.53 inches • February 10 through 14, 2018: 2.50 inches • May 15 through 19, 2018: 8.11 inches • May 25 through 31, 2018: 5.02 inches • July 30 through August 3, 2018: 4.93 inches • September 17, 2018: 1.84 inches • October 11, 2018: 3.79 inches • November 13, 2018: 1.76 inches • December 8 through 9, 2018: 13.5 inches snow • December 14 through 15, 2018: 0.74 inches • December 21, 2018: 2.24 inches • February 15 through 24, 2019: 5.47 inches • April 12 through 14, 2019: 2.14 inches • April 19, 2019: 3.96 inches • June 7, 2019: 4.54 inches • June 10, 2019: 4.54 inches • August 23, 2019: 2.11 inches • October 31, 2019: 2.52 inches Volatile Organic Compounds Table 2 summarizes the current and historical laboratory analytical results for volatile organic compounds (VOCs), analyzed by U.S. Environmental Protection Agency Standard Method 62008. In accordance with permit requirements, samples are analyzed for VOCs annually, during November. No VOCs were detected at concentrations above the method detection limits in the monitoring wells December 16, 2019 Page 5 In accordance with the spray irrigation permit, Clement Pappas is required to submit the following to the DEQ by December 31, 2019 (on or before the last working day of the month following the sampling month): • Laboratory analytical reports and chain -of -custody forms (Attachment 1) • Well sampling logs and the equipment documentation and instrument calibration data sheet (Attachment 2) • DEQ GW-59A — Compliance Report Form (Attachment 3) • DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Form, for each monitoring well (Attachment 4) Anchor QEA proposes to complete the next scheduled groundwater sampling event in May 2020. Anchor QEA will also continue to collect surface water data from Mud Creek. If you have any questions or would like additional information, please do not hesitate to contact me at (828) 281-3350 or amacbeth@anchorqea.com. Sincerely, 0_C1a-V__0'w" -P -7✓r i Alec Macbeth, PG Senior Scientist Attachments Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry Table 2 Current and Historical Groundwater Analytical Results for Volatile Organic Compounds Table 3 Current and Historical Groundwater Elevation Measurements Table 4 Current and Historical Surface Water Analytical Results Figure 1 Site Location Map Figure 2 Site Plan Map Attachment 1 Laboratory Analytical Reports and Chain -of -Custody Forms Attachment 2 Well Sampling Logs and Instrument Calibration Data Sheet Attachment DEQ GW-59A —Compliance Report Form Attachment 4 DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Forms Tables Table 1 Current and Historical Groundwater Analytical Results for Microbiology and Wet Chemistry C 0 9 v 2 y € ° 0 > r O 0` v U0 ;; N N 0 N 0 0 a Y E m l0- U u z F ¢ f (CFUs per Sample Name Sample Date (mg/L) (mg/L) 100 ml-) (mg/L) (mg/L) (mg/L) (mg/L) Standards 10 250 1 10 500 7.5 NL 05/02/2017 3.9 7.0 <2.0 0.4 96 <0.10 0.072 11/08/2017 3.0 7.3 <2.0 1 1.2 135 <0.10 0.070 05/02/2018 3.0 10.0 <1.0 2.1 167 <0.020 0.11 MW-4 11/02/2018 3.6 9.0 <10.0 0.48 137 1 <0.10 0.070 05/21/2019 3.0 11.3 <1.0 3.3 170 <0.050 0.044 J 11/14/2019 3.7 11 <1.0 0.42 190 <0.10 <0.050 05/02/2017 8.1 29.0 3.0 <0.020 134 <0.10 0.097 11/08/2017 6.7 12.8 188.0 <0.020 84 <0.10 0.086 MW-5 05/02/2018 5.7 16.1 2.0 0.0 90 <0.10 0.097 11/02/2018 5.1 23.9 <10.0 <0.020 86 <0.10 0.085 05/21/2019 9.4 26.8 7.0 0.1 91 <0.050 0.120 11/14/2019 6.0 20.1 7.0 0.055 202 1 <0.10 0.081 05/02/2017 1.8 12.1 2.0 0.5 93 <0.10 0.090 11/08/2017 1.4 11.1 74.0 0.0 66 <0.10 <0.050 05/02/2018 2.3 9.4 1.0 0.1 81 <0.10 0.097 MW-6 11/02/2018 2.5 10.1 69.0 0.6 88 <0.10 0.057 05/21/2019 3.3 11.3 23.0 0.4 78 <0.050 0.068 11/14/2019 2.9 9.3 44.0 0.56 342 <0.10 0.052 05/02/2017 6.7 17.9 <4.0 8.9 169 <0.10 0.430 11/08/2017 3.9 17.9 19.0 36.8 376 1 <0.10 0.140 MW-7R 05/02/2018 3.2 22.6 <2.0 15.5 207 <0.10 0.320 11/02/2018 5.3 20.2 <10.0 15.7 243 <0.10 0.170 05/21/2019 3.0 29.0 <2.0 20.2 234 <0.050 0.130 11/14/2019 3.0 22.7 <2.0 17.1 73 <0.10 0.084 05/02/2017 11.4 18.9 8.0 12.4 497 <0.10 0300 11/08/2017 8.1 9.7 <4.0 14.4 390 <0.10 0.098 MW-8 05/02/2018 10.8 12.9 <2.0 14.4 548 <0.10 0.190 11/02/2018 9.5 8.0 19.0 6,8 351 1 <0.10 1 0.250 05/21/2019 7.9 7.3 <10.0 6.2 249 <0.050 0.290 11/14/2019 7.7 7.2 2.0 1.2 51 <0.10 0.10 05/02/2017 7.6 3.8 <4.0 0.2 92 <0.10 0.610 11/08/2017 7.0 8.9 10.0 1.0 64 <0.10 0.530 MW-9 05/02/2018 4.6 4.9 <2.0 0.6 69 <0.10 0.370 11/02/2018 8.4 5.8 <10.0 0.6 88 <0.10 0.470 05/21/2019 7.2 4.6 <10.0 0.2 80 <0.050 0.230 11/14/2019 6.1 5.4 <1.0 0.89 56 1 <0.10 1 0.076 November 2019 Groundwater Sampling Event Pagel of 2 Clement Pappas, Hendersonville, North Carolina December 2019 Table 2 Current and Historical Groundwater Analytical Results for Volatile Organic Compounds m d a C « W t p C Ge S ry C p 0 O OC 0 w ° u v c ° `° G O N O L O t U O F H U F > Sample Name Sample Date (pg/L) (pg/L) (pg/L) (pg/L) (pg/L) (pg/L) 2L Standard 0.7 3 70 100 0.03 7 11/05/2002 < 0.50 0.83 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 0.94 0.62 < 0.50 < 0.50 < 0.50 MW 2 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 OS/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 < 0.50 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW-2R 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/05/2002 < 0.50 < O.SO < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11 /03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 < 0.50 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/0S/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW-4 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11 /20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2014 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/09/2016 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2017 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 11/02/2018 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/14/2019 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 November 2018 Groundwater Sampling Event Clement Pappas, Hendersonville, North Carolina Pagel of 5 December 2019 Table 2 Current and Historical Groundwater Analytical Results for Volatile Organic Compounds N L Y O O L u G C y Y O O L a C d L O O L N a, d V O O a N V N O L V _ C C OC y O L Sample Name 1 Sample Date (pg/L) (pg/L) I (pg/L) (pg/L) W/O OWL) 2L Standard 0.7 3 70 100 0.03 7 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 3.0 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW-6 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/07/2012 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/20/2013 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2014 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/04/2015 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11 /09/2016 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2017 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/02/2018 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/14/2019 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/05/2002 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/04/2003 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2004 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/03/2005 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/09/2006 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 MW-7 05/18/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 11/13/2007 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/18/2008 0.79 < 0.50 < 0.50 < 0.50 < 0.5 < 0.50 11/05/2009 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/08/2010 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50 11/15/2011 < 0.50 < 0.50 < 0.50 < 0.50 < 1.0 November 2018 Groundwater Sampling Event Clement Pappas, Hendersonville, North Carolina Page 3 of 5 December 2019 Table 2 Current and Historical Groundwater Analytical Results for Volatile Organic Compounds c C d t � W N p O O C L S d ` C C L w r O V L V W V C y W O O O y O = N C U T G d F C F A V LC F C_ 9 Sample Name Sample Date (pg/L) (pg/L) (pg/L) (pg/L) (pg/L) (pg/L) 2L Standard 0.7 3 70 100 0.03 7 Notes: This table only includes compounds that were detected above the laboratory method detection limit since the sampling event in November 2002. The complete suite of compounds analyzed can be found in the individual analytical reports. Only samples collected during November sampling events were analyzed for volatile organic compounds, in accordance with Spray Irrigation Permit Number W00004797. 5/18/2007: In accordance with the Compliance Evaluation Inspection letter issued by Beverly Price of the North Carolina Department of Environment and Natural Resources, Division of Water Quality on April 27, 2007, volatile organic compounds and semivolatile organic compounds were sampled during the May 2007 sampling event. Naphthalene was detected in MW-6 for the first time at a concentration of 2.2 pg/L (which is below the 2L standard of 6 pg/L) during the November 5, 2002 sampling event. 1,1,2-trichloroethane was detected in MW-5 for the first time on November 20, 2010, at a concentration of 8.0 pg/L, which exceeds the North Carolina Interim Maximum Allowable Concentration of 0.6 pg/L. Chloroform was detected for the first time in MW-5 during the November 2011 sampling event at a concentration of 31.3 pg/L, which is below the 2L standard of 70 pg/L. Toluene was detected for the first time in MW-4 during the November 2015 sampling event at a concentration of 0.75 pg/L, which is below the 2L standard of 600 pg/L. Bold values indicate an exceedance of the 2L standard. 2L Standard: North Carolina Administrative Code, Title 15A, Subchapter 2L, April 1, 2013 pg/L: micrograms per liter November 2018 Groundwater Sampling Event Page 5 of 5 Clement Pappas, Hendersonville, North Carolina December 2019 Table 3 Current and Historical Groundwater Elevation Measurements Well Identification Date Measured Depth to Groundwater (feet BTOC) Top -of -Casing Elevation (feet) Top -of -Casing Height Above Ground Surface (feet) Groundwater Elevation (feet) 05/15/2002 9.32 2064.60 2.43 2055.28 11/05/2002 9.49 2064.60 2.43 2055.11 05/13/2003 8.20 2064.60 2.43 2056.40 11/04/2003 9.23 2064.60 2.43 2055.37 05/05/2004 9.35 2064.60 2.43 20SS.25 11/09/2004 8.61 2064.60 2.43 2055.99 05/17/2005 6.19 2064.60 2.43 2058A1 11/03/2005 9.57 2064.60 2.43 2055.03 05/24/2006 9.60 2064.60 2.43 2055.00 11/09/2006 8.41 2064.60 2.43 2056.19 05/18/2007 9.42 2064.60 2.43 2055.18 11/13/2007 9.89 2064.60 2.43 2054.71 05/27/2008 9.78 2064.60 2.43 2054.82 11/18/2008 9.76 2064.60 2.43 2054.84 05/28/2009 7.16 2064.60 2.43 2057.44 11/05/2009 8.53 2064.60 2.43 2056.07 MW 4 05/13/2010 8.83 2064.60 2.43 2055.77 11/08/2010 9.30 2064.60 2.43 2055.30 05/17/2011 8.97 2064.60 2.43 2055.63 11/15/2011 9.48 2064.60 2.43 2055.12 05/17/2012 7.62 2064.60 2.43 2056.98 11/07/2012 9.32 2063.77 2.43 2054.45 05/16/2013 7.93 2063.77 2.43 2055.84 11/20/2013 8.87 2063.77 2.43 2054.90 05/22/2014 8.70 2063.77 2.43 2055.07 11/18/2014 8.54 2063.77 2.43 2055.23 05/13/2015 9.18 2063.77 2.43 2054.59 11/4/2015 6.93 2063.77 2.43 2056.84 05/04/2016 8.43 2063.77 2.43 20SS.34 11/09/2016 9.63 2063.77 2.43 2054.14 05/02/2017 7.82 2063.77 2.43 2055.95 11/08/2017 7.88 2063.77 2.43 2055.89 05/02/2018 8.44 2063.77 2.43 2055.33 11/02/2018 8.00 2063.77 2.43 2055.77 05/21/2019 8.49 2663.77 2.43 2055.28 11/14/2019 8.82 2063.77 2.43 2054.95 November 2019 Groundwater Sampling Event Clement Pappas, Hendersonville, North Carolina Page 2 of 7 December 2019 Table 3 Current and Historical Groundwater Elevation Measurements Well Identification Date Measured Depth to Groundwater (feet BTOC) Top -of -Casing Elevation (feet) Top -of -Casing Height Above Ground Surface (feet) Groundwater Elevation (feet) 05/15/2002 6.20 2061.90 3.00 2055.70 11/05/2002 6.15 2061.90 3.00 2055.75 05/13/2003 5.43 2061.90 3.00 2056.47 11/04/2003 5.85 2061.90 3.00 2056.05 05/05/2004 6.00 2061.90 3.00 2055.90 11/09/2004 5.32 2061.90 3.00 2056.58 05/17/2005 6.10 2061.90 3.00 2055.80 11/03/2005 6.01 2061.90 3.00 20S5.89 05/24/2006 1 6.48 2061.90 3.00 1 20S5A2 11/09/2006 5.71 2061.90 3.00 2056.19 05/18/2007 6.50 2061.90 3.00 2055.40 11/13/2007 7.85 2061.90 3.00 2054.05 05/27/2008 7.01 2061.90 3.00 2054.89 11/18/2008 7.38 2061.90 3.00 2054.52 05/28/2009 5.63 2061.90 3.00 2056.27 11/05/2009 5.74 2061.90 3.00 2056.16 MW-6 05/13/2010 5.90 2061.90 3.00 2056.00 11/08/2010 5.99 2061.90 3.00 2055.91 05/17/2011 5.85 2061.90 3.00 2056.05 11/15/2011 6.14 2061.90 3.00 2055.76 OS/17/2012 5.87 2061.90 3.00 2056.03 11/07/2012 6.05 2061.17 3.00 2055.12 05/16/2013 5.84 2061.17 3.00 2055.33 11/20/2013 5.96 2061.17 3.00 20S5.21 05/22/2014 5.96 2061.17 3.00 20S5.21 11/18/2014 5.82 2061.17 3.00 2055.35 OS/13/2015 6.05 2061.17 3.00 2055.12 11/04/2015 5.18 2061.17 3.00 2055.99 05/04/2016 5.59 2061.17 3.00 2055.58 11/09/2016 7.42 2061.17 3.00 2053.75 05/02/2017 5.31 2061.17 3.00 2055.86 11/08/2017 4.80 2061.17 3.00 2056.37 05/02/2018 5.36 2061.17 3.00 2055.81 11/02/2018 5.03 2061.17 3.00 2056.14 05/21/2019 5.53 2061.1, 3.00 2055.64 11/14/2019 5.59 2061.17 3.00 2055.58 November 2019 Groundwater Sampling Event Clement Pappas, Hendersonville, North Carolina Page 4 of 7 December 2019 Table 3 Current and Historical Groundwater Elevation Measurements Well Identification Date Measured Depth to Groundwater (feet BTOC) Top -of -Casing Elevation (feet) Top -of -Casing Height Above Ground Surface (feet) Groundwater Elevation (feet) 05/15/2002 10.25 2061.40 3.00 2051.15 11/05/2002 10.35 2061.40 3.00 2051.05 05/13/2003 8.16 2061.40 3.00 2053.24 11/04/2003 10.23 2061.40 3.00 2051.17 05/05/2004 10.30 2061.40 3.00 2051.10 11/09/2004 8.90 2061.40 3.00 2052.50 05/17/2005 10.08 2061.40 3.00 2051.32 11/03/2005 10.61 2061.40 3.00 2050.79 05/24/2006 10.60 2061.40 3.00 2050.80 11/09/2006 9.40 2061.40 3.00 2052.00 05/18/2007 10.31 2061.40 3.00 2051.09 11/13/2007 11.09 2061.40 3.00 2050.31 05/27/2008 10.83 2061.40 3.00 2050.57 11/18/2008 11.11 2061.40 3.00 2050.29 05/28/2009 8.25 2061.40 3.00 2053.15 11/05/2009 9.22 2061.40 3.00 2052.18 MW 8 05/13/2010 9.88 2061.40 3.00 2051.52 11/08/2010 10.38 2061.40 3.00 2051.02 05/17/2011 10.27 2061.40 3.00 2051.13 11/15/2011 10.87 2061.40 3.00 2050.53 05/17/2012 8.03 2061.40 3.00 2053.37 11/07/2012 10.45 2060.80 3.00 2050.35 05/16/2013 8.58 2060.80 3.00 2052.22 11/20/2013 10.34 2060.80 3.00 2050.46 05/22/2014 9.79 2060.80 3.00 2051.01 11/18/2014 10.03 2060.80 3.00 2050.77 05/13/2015 10.34 2060.80 3.00 2050.46 11/04/2015 7.21 2060.80 3.00 2053.59 05/04/2016 9.84 2060.80 3.00 2050.96 11/09/2016 11.16 2060.80 3.00 2049.64 05/02/2017 8.48 2060.80 3.00 2052.32 11/08/2017 8.73 2060.80 3.00 2052.07 05/02/2018 9.39 2060.80 3.00 2051.41 11/02/2018 8.85 2060.80 3.00 2051.95 05/21/2019 9.38 2060.80 3.00 2051.42 11/14/2019 9.75 2060.80 3.00 2051.05 November 2019 Groundwater Sampling Event Clement Pappas, Hendersonville, North Carolina Page 6 of 7 December 2019 snjogds04d ¢¢ o ¢¢ o o o o o o 0 0 IejOl E 2 z Z d d o 0 0 0 Z Z o d 0 d 0 0 J 0 0 0 0 0 O O N O eluoWWy z z z 0 0 0 0 0 0 z z o 0 0 0 0 0 v v v v 0 0 v sP!IOS ¢¢ o 0 0 0 0 0¢ a o 0 0 0 0 0 E Z z z � N v z z v in o ro Pan!osslp le3ol OMI N 2 E 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a J E o¢¢ M a WAO;II O,�Ie)Bj vt Z Z ao au W¢ Z Z ai 0 00 O O ry 4'1. pO N Ol 00 M Oat N V B IJO P. 147 O¢¢ (� m o m a¢ n ro V Io T 7 E N z Z v v v v v Z Z v v v v v uogJe: )Iue6A0 Ielol E Z ¢¢ Z Z r ni - N - m ni io m¢¢ Z Z - - — - a E w E a W W Ol N n r 00 Ol \ 7 0. E O O\\ \ N O O \ N p0 \ N\\ N V 1p m rn a h m m E Z N a N 3 Y 3 E v E a NW _T O C C A o OZ z 2 v O E E E E E Figures Publish Date: 2018/05/30, 11,36 AM I User: ecmle Filepalh: p\Clement Pappas\Figures\GIS\Figure 1 - Site Location Map.mxd ANCHOR kz OEA � Figure 1 Site Location Map November 2019 Groundwater Sampling Event Clement Pappas, Hendersonville, North Carolina Attachment 1 Laboratory Analytical Reports and Chain -of -Custody Forms aceAnalytical e lmi.0acolebs.ron November 22, 2019 Mr. Alec Macbeth Anchor QEA of North Carolina 231 Haywood Street Asheville, NC 28801 RE: Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 Dear Mr. Macbeth: Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Enclosed are the analytical results for sample(s) received by the laboratory on November 14, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Lorri Patton lorri.patton@pacelabs.com 1(828)254-7176 Project Manager Enclosures cc: Ms. Cassandra Harvey, Anchor QEA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, -LC. Page 1 of 56 aceAnalytical www.pacalabsxoa SAMPLE ANALYTE COUNT Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92453831001 MW-4 SM 6200B CL 63 PASI-C SM 254OC-2011 CJL 1 PASI-A SM 9222D-2006 ECH 1 PASI-A EPA 350.1 Rev 2.01993 KDF1 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.01993 NAL 1 PASI-A SM 4500-CI-E-2011 GC 1 PASI-A SM 531OB-2011 BRJ 1 PASI-A 92453831002 MW-5 SM 6200B CL 63 PASI-C SM 254OC-2011 CJL 1 PASI-A SM 9222D-2006 ECH 1 PASI-A EPA 350.1 Rev 2.01993 CJH1 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.01993 NAL 1 PASI-A SM 4500-CI-E-2011 GC 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92453831003 MW-6 SM 6200B CL 63 PASI-C SM 254OC-2011 CJL 1 PASI-A SM 9222D-2006 ECH 1 PASI-A EPA 350.1 Rev 2.01993 CJH1 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.01993 NAL 1 PASI-A SM 4500-CI-E-2011 GC 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92453831004 MW-7R SM 6200B CL 63 PASI-C SM 254OC-2011 CJL 1 PASI-A SM 9222D-2006 ECH 1 PASI-A EPA 350.1 Rev 2.01993 CJH1 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.01993 NAL 1 PASI-A SM 4500-CI-E-2011 GC 1 PASI-A SM 531 OB-2011 ECH 1 PASI-A 92453831005 MW-8 SM 6200B CL 63 PASI-C SM 254OC-2011 CJL 1 PASI-A SM 9222D-2006 ECH 1 PASI-A EPA 350.1 Rev 2.01993 CJHi 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, I.I.C. Page 3 of 56 Pace Analytical Services, LLC aceAnalXical s 2225 Riverside Asheville, NC 2880404 www.pacsIabs.con (826)254-7176 ANALYTICAL RESULTS Project: LASSONDE PAPPAS 11.14-19 Pace Project No.: 92453831 Sample: MW-4 Lab ID: 92453831001 Collected: 11/14/1913:20 Received: 11/1411915:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 11/17/19 18:49 71-43-2 Bromobenzene ND ug/L 0.50 1 11/17/19 18:49 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/17/19 18:49 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/17/19 18:49 75-27-4 Bromoform ND ug/L 0.50 1 11/17/19 18:49 75-25-2 Bromomethane ND ug/L 6.0 1 11/17/19 18:49 74-83-9 L1 n-Butylbenzene ND ug/L 0.50 1 11/17/19 18:49 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/17/19 18:49 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/17/19 18:49 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/17/19 18:49 56-23-5 Chlorobenzene ND ug/L 0.50 1 11117/1918:49 108-90-7 Chloroethane ND ug/L 1.0 1 11/17/19 18:49 75-00-3 Chloroform ND ug/L 0.50 1 11/17/19 18:49 67-66-3 Chloromethane ND ug/L 1.0 1 11/17/19 18:49 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/1711918:49 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/17/19 18:49 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/17/19 18:49 96-12-8 Dibromochloromelhane ND ug/L 0.50 1 11/17/19 18:49 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/17/19 18:49 106-93-4 Dibromomethane ND ug/L 0.50 1 11/17/19 18:49 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/17/19 18:49 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/17/19 18:49 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/17/19 18:49 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/17/19 18:49 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/17/19 18:49 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/1711918:49 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/17/19 18:49 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/17/19 18:49 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/17/19 18:49 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/17/19 18:49 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/17/19 18:49 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/17/19 18:49 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/17/19 18:49 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/17/19 18:49 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/17/19 18:49 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/17/19 18:49 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/17/19 18:49 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/17/19 18:49 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/17/19 18:49 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/1711918:49 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/17/19 18:49 1634-04-4 Naphthalene ND ug/L 2.0 1 11/17/19 18:49 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/17/19 18:49 103-65-1 Styrene ND ug/L 0.50 1 11/17/19 18:49 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/1711918:49 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11117/1918:49 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/17/19 18:49 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, I.I.C. Page 5 of 56 Pace Analytical Services, LLC aceAnalytical ® 2225 Riverside 04 Asheville, NC 28804 www.pacalabs.con (828)254-7176 ANALYTICAL RESULTS Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 Sample: MW-5 Lab ID: 92453831002 Collected: 11/14/1913:50 Received: 11/14/19 15:11 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene NO ug/L 0.50 1 11/19/19 14:19 71-43-2 Bromobenzene NO ug/L 0.50 1 11/19/19 14:19 108-86-1 Bromochloromelhane NO ug/L 0.50 1 11/19/19 14:19 74-97-5 Bromodichloromethane NO ug/L 0.50 1 11/19/19 14:19 75-27-4 Bromoform NO ug/L 0.50 1 11/19/19 14:19 75-25-2 Bromomethane NO ug/L 5.0 1 11/19/19 14:19 74-83-9 Ll n-Butylbenzene NO ug/L 0.50 1 11/19/19 14:19 104-51-8 sec-Butylbenzene NO ug/L 0.50 1 11/19/19 14:19 135-98-8 tert-Butylbenzene NO ug/L 0.50 1 11/19/19 14:19 98-06-6 Carbon tetrachloride NO ug/L 0.50 1 11/19/19 14:19 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/19/19 14:19 108-90-7 Chloroethane ND ug/L 1.0 1 11119/1914:19 75-00-3 Chloroform NO ug/L 0.50 1 11/19/19 14:19 67-66-3 Chloromethane NO ug/L 1.0 1 11/19/19 14:19 74-87-3 2-Chlorotoluene NO ug/L 0.50 1 11/19/19 14:19 95-49-8 4-Chlorotoluene NO ug/L 0.50 1 11/19/19 14:19 106-43-4 1,2-Dibromo-3-chloropropane NO ug/L 1.0 1 11/19/19 14:19 96-12-8 Dibromochloromethane NO ug/L 0.50 1 11/19/19 14:19 124.48-1 1,2-Dibromoethane (EDB) NO ug/L 0.50 1 11/19/19 14:19 106-93-4 Dibromomethane NO ug/L 0.50 1 11/19/19 14:19 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/19/19 14:19 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/19/19 14:19 541-73-1 1,4-Dichlorobenzene NO ug/L 0.50 1 11/19/19 14:19 106-46-7 Dichlorodi8uoromethane NO ug/L 0.50 1 11/19/19 14:19 75-71-8 1,1-Dichloroethane NO ug/L 0.50 1 11/19/1g 14:19 75-34-3 1,2-Dichloroethane NO ug/L 0.50 1 11/19/19 14:19 107-06-2 1,1-Dichloroethene NO ug/L 0.50 1 11/19/19 14:19 75-35-4 cis-1,2-Dichloroethene 5.0 ug/L 0.50 1 11/19/19 14:19 156.59.2 trans-1,2-Dichloroethene NO ug/L 0.50 1 11/19/19 14:19 156-60-5 1,2-Dichloropropane NO ug/L 0.50 1 11/19/19 14:19 78-87-5 1,3-Dichloropropane NO ug/L 0.50 1 11/19/19 14:19 142-28-9 2,2-Dichloropropane NO ug/L 0.50 1 11/19/19 14:19 594-20-7 1,1-Dichloropropene NO ug/L 0.50 1 11/19/19 14:19 563-58-6 cis-1,3-Dichloropropene NO ug/L 0.50 1 11/19/19 14:19 10061-01-5 trans-1,3-Dichloropropene NO ug/L 0.50 1 11/19/19 14:19 10061-02-6 Diisopropyl ether NO ug/L 0.50 1 11/19/19 14:19 108.20-3 Ethylbenzene NO ug/L 0.50 1 11/19/19 14:19 100-41-4 Hexachloro-1,3-butadiene NO ug/L 2.0 1 11/19/19 14:19 87-68-3 Isopropylbenzene (Cumene) NO ug/L 0.50 1 11/19/19 14:19 98-82-8 Methylene Chloride NO ug/L 2.0 1 11/19/19 14:19 75-09-2 Methyl-tert-butyl ether NO ug/L 0.50 1 11/19/19 14:19 1634-04-4 Naphthalene NO ug/L 2.0 1 11/19/19 14:19 91-20-3 n-Propylbenzene NO ug/L 0.50 1 11/19/19 14:19 103-65-1 Styrene NO ug/L 0.50 1 11/19/19 14:19 100-42-5 1,1,1,2-Tetrachloroethane NO ug/L 0.50 1 11/19/19 14:19 630-20-6 1,1,2,2-Tetrachloroethane NO ug/L 0.50 1 11119/1914:19 79-34-5 Tetrachloroethene 22.4 ug/L 0.50 1 11/19/19 14:19 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, L-C. Page 7 of 56 Pace Analytical Services, LLC Ice Dr. Analyticalw2225 RivAsheville, NCC 28 04 7676 1 ANALYTICAL RESULTS Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 Sample: MW-6 Lab ID: 92453831003 Collected: 11/14/1912:20 Received: 11/14/1915:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 11/19/19 12:47 71-43-2 Bromobenzene ND ug/L 0.50 1 11/19/19 12:47 108-86-1 Bromochloromethene ND ug/L 0.50 1 11/19/19 12:47 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/19/19 12:47 75-27-4 Bromoform ND ug/L 0.50 1 11/19/19 12:47 75-25-2 Bromomethane ND ug/L 5.0 1 11/19/19 12:47 74-83-9 L1 n-Butylbenzene ND ug/L 0.50 1 11/19/19 12:47 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/19/19 12:47 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/19/19 12:47 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/19/19 12:47 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/19/19 12:47 108-90-7 Chloroethane ND ug/L 1.0 1 11/19/19 12:47 75-00-3 Chloroform ND ug/L 0.50 1 11/19/19 12:47 67.66-3 Chloromethane ND ug/L 1.0 1 11119/1912:47 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/19/19 12:47 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/19/19 12:47 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/19/19 12:47 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/19/19 12:47 124-48.1 1,2-Dibromoethane (EDB) NO ug/L 0.50 1 11119/1912:47 106-93-4 Dibromomethane ND ug/L 0.50 1 11/19/19 12:47 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/19/19 12:47 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/19/19 12:47 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/19/19 12:47 106-46-7 Dichlorodi0uoromethane NO ug/L 0.50 1 11/1911912:47 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/19/19 12:47 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/19/19 12:47 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/19/19 12:47 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/19/19 12:47 156-59.2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/19/19 12:47 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/19/19 12:47 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/19/19 12:47 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/19/19 12:47 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/19/19 12:47 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/19/19 12:47 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/19/19 12:47 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/19/19 12:47 108-20.3 Ethylbenzene ND ug/L 0.50 1 11/19/19 12:47 100-41.4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/19/19 12:47 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.60 1 11/19/19 12:47 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/19/19 12:47 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/19/19 12:47 1634-04-4 Naphthalene ND ug/L 2.0 1 11/19/19 12:47 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/19/19 12:47 103-65-1 Styrene ND ug/L 0.50 1 11/1911912:47 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/19/19 12:47 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/19/19 12:47 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/19/19 12:47 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 56 Pace Analytical Services, LLC aceAnalytical a 2225le,NCRiverside28 04 Asheville, NC 28804 www.panlabs.con (828)254-7176 ANALYTICAL RESULTS Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 Sample: MW-7R Lab ID: 92453831004 Collected: 11/14/1911:50 Received: 11/1411915:11 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene NO ug/L 0.50 1 11/19/19 13:06 71-43-2 Bromobenzene NO ug/L 0.50 1 11/19/19 13:06 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/19/19 13:06 74.97-5 Bromodichloromethane ND ug/L 0.50 1 11/19/19 13:06 75-27-4 Bromoform ND ug/L 0.50 1 11/19/19 13:06 75-25-2 Bromomethane NO ug/L 5.0 1 11/19/19 13:06 74-83-9 Li n-Butylbenzene NO ug/L 0.50 1 11/19/19 13:06 104-51-8 sec-Butylbenzene NO ug/L 0.50 1 11/19/19 13:06 135-98-8 tert-Butylbenzene NO ug/L 0.50 1 11119/1913:06 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/19/19 13:06 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/1911913:06 108-90-7 Chloroethane ND ug/L 1.0 1 11/19/19 13:06 75-00-3 Chloroform ND ug/L 0.50 1 11/19/19 13:06 67-66-3 Chloromethane ND ug/L 1.0 1 11/19/19 13:06 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/19/19 13:06 95-49-8 4-Chlorotoluene NO ug/L 0.50 1 11/19/19 13:06 106-43-4 1,2-Dibromo-3-chloropropane NO ug/L 1.0 1 11/19/19 13:06 96-12-8 Dibromochloromethane NO ug/L 0.50 1 11/19/19 13:06 124-48-1 1,2-Dibromoethane (EDB) NO ug/L 0.50 1 1111911913:06 106-93-4 Dibromomethane NO ug/L 0.50 1 11/19/19 13:06 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/19/19 13:06 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/19/19 13:06 541-73-1 1,4-Dichlorobenzene NO ug/L 0.50 1 11/19/19 13:06 106-46-7 Dichlorodi6uoromethane ND ug/L 0.50 1 11/19/19 13:06 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/19/19 13:06 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/19/19 13:06 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/19/19 13:06 75.35-4 cis-1,2-Dichloroethene NO ug/L 0.50 1 11/19/19 13:06 156-59-2 trans-1,2-Dichloroethene NO ug/L 0.50 1 11/19/19 13:06 156-60-5 1,2-Dichloropropane NO ug/L 0.50 1 11/19/19 13:06 78-87-5 1,3-Dichloropropane NO ug/L 0.50 1 11/19/19 13:06 142-28-9 2,2-Dichloropropane NO ug/L 0.50 1 11/19/19 13:06 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/19/19 13:06 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/19/19 13:06 10061-01-5 trans-1,3-Dichloropropene NO ug/L 0.50 1 11/19/19 13:06 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/19/19 13:06 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/19/19 13:06 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11119/1913:06 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/19/19 13:06 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/19/19 13:06 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/19/19 13:06 1634.04.4 Naphthalene ND ug/L 2.0 1 11/19/19 13:06 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/19/19 13:06 103.65-1 Styrene ND ug/L 0.50 1 11/19/19 13:06 100-42-5 1,1,1,2-Tetrachloroethane NO ug/L 0S0 1 11/19/19 13:06 630-20-6 1,1,2,2-Tetrachloroethane NO ug/L 0.50 1 11/19/19 13:06 79-34-5 Tetrachloroethene NO ug/L 0.50 1 11/19/19 13:06 127-18.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/22/201902:19 PM without the written consent of Pace Analytical Services,LLC. Page 11 of 56 Pace Analytical Services, LLC aceAnalytical a Ashhevievi Riverside Riverside NC 2880404 waw.pacalabs.com (828)254-7176 ANALYTICAL RESULTS Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 Sample: MW-8 Lab ID: 92453831005 Collected: 11/14/1910:15 Received: 11/14/1915:11 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Oual 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 11/19/19 13:24 71-43-2 Bromobenzene ND ug/L 0.50 1 11/19/19 13:24 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/19/19 13:24 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/19/19 13:24 75.27-4 Bromoform ND ug/L 0.50 1 11/19/19 13:24 75.25-2 Bromomethane ND ug/L 5.0 1 11/19/1913:24 74-83-9 L1 n-Butylbenzene ND ug/L 0.50 1 11/1911913:24 104.51-8 sec-Butylbenzene ND ug/L 0.50 1 11/19/19 13:24 135.98-8 lert-Butylbenzene ND ug/L 0.50 1 11/19/19 13:24 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/19/19 13:24 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/19/19 13:24 108-90-7 Chloroethane ND ug/L 1.0 1 11/19/19 13:24 75-00-3 Chloroform ND ug/L 0.50 1 11/19/19 13:24 67.66-3 Chloromethane ND ug/L 1.0 1 11/19/19 13:24 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/19/19 13:24 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/19/19 13:24 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/19/19 13:24 96-12-8 Dibromochloromelhane ND ug/L 0.50 1 11/19/19 13:24 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/19/19 13:24 106-93-4 Dibromomethane ND ug/L 0.50 1 11/19/19 13:24 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/19/19 13:24 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/19/19 13:24 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/19/19 13:24 106-46.7 Dichlorodifluoromethane ND ug/L 0.50 1 11/19/19 13:24 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/19/19 13:24 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/19/19 13:24 107-06-2 1,1-Dichloroethane ND ug/L 0.50 1 11/19/19 13:24 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.60 1 11/19/19 13:24 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/19/19 13:24 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/19/19 13:24 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/19/19 13:24 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/19/19 13:24 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/19/19 13:24 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/19/19 13:24 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/19/19 13:24 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/19/19 13:24 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/19/19 13:24 100-41.4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/19/19 13:24 87.68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/19/19 13:24 98-82.8 Methylene Chloride ND ug/L 2.0 1 11/19/19 13:24 75-09-2 Methyl -tart -butyl ether ND ug/L 0.50 1 11/19/19 13:24 1634-04-4 Naphthalene ND ug/L 2.0 1 11/19/19 13:24 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/19/19 13:24 103-65-1 Styrene ND ug/L 0.50 1 11/19/19 13:24 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/19/19 13:24 630-20-6 1, 1,2,2-Tetmchloroethane ND ug/L 0.50 1 11/19/19 13:24 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/19/19 13:24 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, L-C. Page 13 of 56 Pace Analytical Services, LLC 2225 Riverside aceAnalytical Asheville, NC 2880404 awa.pecelebacoa (828)254-7176 ANALYTICAL RESULTS Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 Sample: MW-9 Lab ID: 92453831006 Collected: 11/14/19 12:55 Received: 11114/1915:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 11/19/19 13:42 71-43.2 Bromobenzene ND ug/L 0.50 1 11/19/19 13:42 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/19/19 13:42 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/19/19 13:42 75-27-4 Bromoform ND ug/L 0.50 1 11/19/19 13:42 75-25-2 Bromomethane ND ug/L 5.0 1 11/19/19 13:42 74-83-9 Lt n-Butylbenzene ND ug/L 0.50 1 11/19/19 13:42 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/19/19 13:42 135-98-8 tert-Butylbenzene ND ug/L 0.60 1 11/19/19 13:42 98-06.6 Carbon tetrachloride ND ug/L 0.50 1 11/19/19 13:42 56.23-5 Chlorobenzene ND ug/L 0.50 1 11/19/19 13:42 108-90-7 Chloroethane ND ug/L 1.0 1 11/19/19 13:42 75-00-3 Chloroform ND ug/L 0.50 1 11/19/19 13:42 67-66-3 Chloromethane ND ug/L 1.0 1 11/19/19 13:42 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/19/19 13:42 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/19/19 13:42 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/19/19 13:42 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/1911913:42 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/19/19 13:42 106.93-4 Dibromomethane ND ug/L 0.50 1 11/19/19 13:42 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/19/19 13:42 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/19/19 13:42 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/19/19 13:42 106-46-7 Dichlorodi0uoromethane ND ug/L 0.50 1 11/19/19 13:42 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/19/19 13:42 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/19/19 13:42 107-06-2 1,1-Dichloroethane ND ug/L 0.50 1 11/19/19 13:42 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/19/19 13:42 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/19/19 13:42 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/19/19 13:42 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/19/19 13:42 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/19/19 13:42 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/19/19 13:42 563-58-6 cis-1,3-Dichloropropane ND ug/L 0.50 1 11/19/19 13:42 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11119/1913:42 10061-02-6 Dilsopropyl ether ND ug/L 0.50 1 11/19/19 13:42 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/19/19 13:42 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/19/19 13:42 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11119/19 13:42 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/1911913:42 75-09.2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/19/19 13:42 1634-04-4 Naphthalene ND ug/L 2.0 1 11/19/19 13:42 91.20-3 n-Propylbenzene ND ug/L 0.50 1 11/19/19 13:42 103-65-1 Styrene ND ug/L 0.50 1 11/19/19 13:42 100-42.5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/19/19 13:42 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/19/19 13:42 79-34.5 Tetrachloroethene ND ug/L 0.50 1 11/19/19 13:42 127-18-4 ( REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, U.C. Page 15 of 56 ace Analytical www.panlabs con ANALYTICAL RESULTS Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 Sample: SW-1 Lab ID: 92453831007 Collected: 11/14/19 11:15 Received: 11/14/1915:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Toluene ND ug/L 0.50 1 11/19/19 14:01 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/19/19 14:01 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/19/19 14:01 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 11/19/19 14:01 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/19/19 14:01 79-00-5 Trichloroethene NO ug/L 0.50 1 11/1911914:01 79-01-6 Tdchlorofluoromethane NO ug/L 1.0 1 11/19/19 14:01 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/19/19 14:01 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/19/19 14:01 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/19/19 14:01 108-67-8 Vinyl chloride NO ug/L 1.0 1 11/19/19 14:01 75-01.4 m&p-Xylene ND ug/L 1.0 1 11/19/19 14:01 179601.23.1 o-Xylene NO ug/L 0.50 1 11/19/19 14:01 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 95 % 70-130 1 11/19/19 14:01 17060-07-0 4-Bromofluorobenzene (S) 102 % 70-130 1 11/19/19 14:01 460-00-4 Toluene-d8(S) 97 % 70-130 1 11/19/19 14:01 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 254OC-2011 Total Dissolved Solids 57.0 mg/L 25.0 1 11/19/19 23:33 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D.2006 Preparation Method: SM 9222D-2006 Fecal Coliforms 118 CFU/100 mL 1.0 1 11/14/1917:03 11/15/1915:45 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Nitrogen, Ammonia ND mg/L 0.10 1 1111611916:10 7664-41-7 353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2 Rev 2.01993 Nitrogen, Nitrate 0.83 mg/L 0.040 1 11/15/19 03:09 14797-55-6 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Phosphorus 0.10 mg/L 0.050 1 11/17/19 16:26 11/18/19 16:31 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 5.3 mg/L 1.0 1 11/15/1919:30 16887-00-6 5310E TOC Analytical Method: SM 531OB-2011 Total Organic Carbon 1.9 mg/L 1.0 1 11/1911920:50 7440-44-0 Date: 11/22/2019 02:19 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC, Page 18 of 56 aceAnalytical www.0anlebsxoa ( ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 Sample: SW-2 Lab ID: 92453831008 Collected: 11/1411910:00 Received: 11/14/19 15:11 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 11/20/19 17:23 71-43-2 Bromobenzene ND ug/L 0.50 1 11/20/19 17:23 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/20/19 17:23 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/20/19 17:23 75-27-4 Bromoform ND ug/L 0.50 1 11/20/19 17:23 75-25-2 Bromomethane ND ug/L 5.0 1 11/20/19 17:23 74-83.9 n-Butylbenzene ND ug/L 0.50 1 11/20/19 17:23 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/20/19 17:23 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11120/1917:23 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/20/19 17:23 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/2011917:23 108-90-7 Chloroethane ND ug/L 1.0 1 11/20/19 17:23 75-00-3 Chloroform ND ug/L 0.50 1 11/20/19 17:23 67-66-3 Chloromethane ND ug/L 1.0 1 11/20/19 17:23 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/20/19 17:23 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/20/19 17:23 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/20/19 17:23 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/2011917:23 124-48-1 1,2-Dibromoethane(EDB) ND ug/L 0.50 1 1112011917:23 106-93-4 Dibromomelhane ND ug/L 0.50 1 1112011917:23 74-95.3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/20/19 17:23 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/20/19 17:23 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/20/19 17:23 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/20/19 17:23 75-71.8 1,1-Dichloroethane ND ug/L 0.50 1 11/20/19 17:23 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/20/19 17:23 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/20/19 17:23 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/20/19 17:23 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/20/19 17:23 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/20/19 17:23 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/20/19 17:23 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/20/19 17:23 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/20/19 17:23 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/20/19 17:23 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/20/19 17:23 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/20/19 17:23 108-20-3 Ethylbenzene ND ug/L 0.50 1 11120/1917:23 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/20/19 17:23 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/20/19 17:23 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/20/19 17:23 75-09.2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/20/19 17:23 1634-04-4 Naphthalene ND ug/L 2.0 1 11/20/19 17:23 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/20/19 17:23 103-65-1 Styrene ND ug/L 0.50 1 11/20/19 17:23 100-42-5 1,1,1,2-Telrachloroethane ND ug/L 0.50 1 11/20/19 17:23 630.20-6 1.1,2,2-Telrachloroethane ND ug/L 0.50 1 11/20/19 17:23 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/20/19 17:23 127.18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 56 Pace Analytical Services, LLC aceAnalytical a 2225 Riverside Dr. Asheville, NC 2880404 wim.patalabs.coa (828)254-7176 ANALYTICAL RESULTS Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 Sample: TRIP BLANK Lab ID: 92453831009 Collected: 11/14/19 00:00 Received: 11/14/19 15:11 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Oual 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 11/20/19 17:05 71-43-2 Bromobenzene NO ug/L 0.50 1 11/20/19 17:05 108-86-1 Bromochloromethane NO ug/L 0.50 1 11/20/19 17:05 74-97-5 Bromodichloromethane NO ug/L 0.50 1 11/20/19 17:05 75.27.4 Bromoform NO ug/L 0.50 1 11/20/19 17:05 75-25.2 Bromomelhane NO ug/L 5.0 1 11/20/19 17:05 74-83-9 n-Butylbenzene NO ug/L 0.50 1 11/20/19 17:05 104-51-8 sec-Butylbenzene NO ug/L 0.50 1 11/20/19 17:05 135-98-8 tert-Butyl benzene NO ug/L 0.50 1 11/20/19 17:05 98-06-6 Carbon tetrachloride NO ug/L 0.50 1 11/20/19 17:05 56-23-5 Chlorobenzene NO ug/L 0.50 1 11120/1917:05 108-90-7 Chloroethane NO ug/L 1.0 1 11/20/19 17:05 75-00-3 Chloroform ND ug/L 0.50 1 11/20/19 17:05 67-66-3 Chloromethane NO ug/L 1.0 1 11/20/19 17:05 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/20/19 17:05 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11120/1917:05 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/2011917:05 96-12.8 Dibromochloromethane ND ug/L 0.50 1 11/20/19 17:05 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/20/19 17:05 106-93-4 Dibromomethane ND ug/L 0.50 1 11/20/19 17:05 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/20/19 17:05 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/20/19 17:05 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/20/19 17:05 106.46-7 Dichlorodi6uoromethane ND ug/L 0.50 1 11/20/19 17:05 75-71-8 1,1-Dichloroethane NO ug/L 0.50 1 11/20/19 17:05 75-34-3 1,2-Dichloroethane NO ug/L 0.50 1 11/20/19 17:05 107-06-2 1,1-Dichloroethene NO ug/L 0.50 1 11/2011917:05 75-35-4 cis-1,2-Dichloroethene NO ug/L 0.50 1 11/2011917:05 156.59-2 trans-1,2-Dichloroethene NO ug/L 0.50 1 11/20/19 17:05 156.60-5 1,2-Dichloropropane NO ug/L 0.50 1 11/20/19 17:05 78-87-5 1,3-Dichloropropane NO ug/L 0.50 1 11120/1917:05 142-28-9 2,2-Dichloropropane NO ug/L 0.50 1 1112011917:05 594-20-7 1,1-Dichloropropene NO ug/L 0.50 1 1112011917:05 563-58-6 cis-1,3-Dichloropropene NO ug/L 0.50 1 11/20/19 17:05 10061-01-5 trans-1,3-Dichloropropene NO ug/L 0.50 1 11/20/19 17:05 10061-02-6 Diisopropyl ether NO ug/L 0.50 1 11/20/19 17:05 108-20-3 Etylbenzene NO ug/L 0.50 1 11/20/19 17:05 100-41-4 Hexachloro-1,3-butadiene NO ug/L 2.0 1 11/20/19 17:05 87.68-3 Isopropylbenzene (Cumene) NO ug/L 0.50 1 11/20/19 17:05 98-82.8 Methylene Chloride ND ug/L 2.0 1 11/20/19 17:05 75-09-2 Methyl-tert-butyl ether NO ug/L 0.50 1 11/20/19 17:05 1634-04-4 Naphthalene NO ug/L 2.0 1 11/20/19 17:05 91-20-3 n-Propylbenzene NO ug/L 0.50 1 11/20/19 17:05 103-65-1 Styrene ND ug/L 0.50 1 11/20/19 17:05 100-42-5 1,1,1,2-Tetrachloroethane NO ug/L 0.50 1 11/20/19 17:05 630-20-6 1,1,2,2-Tetrachloroelhane NO ug/L 0.50 1 11/20/19 17:05 79-34-5 Tetrachloroelhene NO ug/L 0.50 1 11/20/19 17:05 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, L-C. Page 21 of 56 aceAnalXical0 warmpacelabs core QUALITY CONTROL DATA Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 QC Batch: 509790 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Description: 6200E MSV Associated Lab Samples: 92453831001 METHOD BLANK: 2735800 Associated Lab Samples: 92453831001 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L NO 0.50 11/17/19 14:34 1,1,1-Tdchloroethane ug/L NO 0.50 11/17/19 14:34 1.1,2,2-Tetrachloroethane ug/L NO 0.50 11/17/19 14:34 1, 1,2-Trich loroethane ug/L NO 0.50 11117/1914:34 1,1-Dlchloroethane ug/L ND 0.50 11/17/19 14:34 1,1-Dichloroelhene ug/L ND 0.50 11/17/19 14:34 1,1-Dichloropropene ug/L ND 0.50 11/17/19 14:34 1,2,3-Trichlorobenzene ug/L ND 2.0 11/17/19 14:34 1,2,3-Trichloropropane ug/L ND 0.50 11/17/19 14:34 1,2,4-Trichlorobenzene ug/L ND 2.0 11/17/19 14:34 1,2,4-Trimethylbenzene ug/L ND 0.50 11/17/19 14:34 1,2-Dibromo-3-chloropropane ug/L NO 1.0 11/17/19 14:34 1,2-Dibromoethane (EDB) ug/L NO 0.50 11/17/19 14:34 1,2-Dichlorobenzene ug/L NO 0.50 11/17/19 14:34 1,2-Dlchloroethane ug/L NO 0.50 1111711914:34 1,2-Dichloropropane ug/L NO 0.50 11/17/19 14:34 1,3,5-Trimethylbenzene ug/L NO 0.50 11/17/19 14:34 1,3-Dichlorobenzene ug/L ND 0.50 11/17/19 14:34 1,3-Dichloropropane ug/L NO 0.50 11/17/19 14:34 1,4-Dichlorobenzene ug/L NO 0.50 11/17/19 14:34 2,2-Dichloropropane ug/L NO 0.50 11/17/19 14:34 2-Chlorotoluene ug/L NO 0.50 11/17/19 14:34 4-Chlorotoluene ug/L NO 0.50 11/17/19 14:34 Benzene ug/L ND 0.50 11/1711914:34 Bromobenzene ug/L NO 0.50 11/17/19 14:34 Bromochloromethane ug/L NO 0.50 11/17/19 14:34 Bromodichloromethane ug/L ND 0.50 11/17/19 14:34 Bromoform ug/L ND 0.50 11/17/19 14:34 Bromomethane ug/L NO 5.0 11/17/19 14:34 Carbon tetrachloride ug/L NO 0.50 11/17/19 14:34 Chlorobenzene ug/L NO 0.50 11/17/19 14:34 Chloroethane ug/L NO 1.0 11/17/19 14:34 Chloroform ug/L NO 0.50 11/17/19 14:34 Chloromethane ug/L ND 1.0 11/17/19 14:34 cis-1,2-Dlchloroethane ug/L ND 0.50 11/17/19 14:34 cis-1,3-Dichloropropene ug/L ND 0.50 11/17/19 14:34 Dibromochloromethane ug/L NO 0.50 11117/1914:34 Dibromomethane ug/L NO 0.50 11117/1914:34 Dichlorodifluoromethane ug/L NO 0.50 11117/1914:34 Diisopropyl ether ug/L NO 0.50 11/17/19 14:34 Ethylbenzene ug/L NO 0.50 1111711914:34 Qualifiers Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on this page are In the units Indicated by the 'units' column except where an alternate unit Is presented to the right of the result. Date: 11/22/2019 02:19 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 56 aceAnalytical s wW .pacslmbs.c011 QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: LASSONDE Pace Project No.: 92453831 PAPPAS 11-14-19 LABORATORY CONTROL SAMPLE: 2735801 Spike LCS LCS % Rec Parameter Units Cone. Result %Rec Limits Qualifiers 1,3-Dichloropropane ug/L 50 52.8 106 60-140 1,4-Dichlorobenzene ug/L 50 50.6 101 60-140 2,2-Dichloropropane ug/L 50 55.5 111 60.140 2-Chlorotoluene ug/L 50 51.1 102 60.140 4-Chlorotoluene ug/L 50 51.6 103 60-140 Benzene ug/L 50 51.1 102 60-140 Bromobenzene ug/L 50 51.7 103 60-140 Bromochloromelhane ug/L 50 54.0 108 60-140 Bromodichloromethane ug/L 50 52.7 105 60-140 Bromoform ug/L 50 56.7 113 60-140 Bromomethane ug/L 50 88.9 178 60-140 L1 Carbon tetrachloride ug/L 50 53.0 106 60-140 Chlorobenzene ug/L 50 50.3 101 60.140 Chloroethane ug/L 50 40.7 81 60-140 Chloroform ug/L 50 52.7 105 60-140 Chloromethane ug/L 50 51.3 103 60-140 cis-1,2-Dichloroethene ug/L 50 51.6 103 60-140 cis-1,3-Dichloropropene ug/L 50 56.2 112 60-140 Dibromochloromelhane ug/L 50 55.1 110 60-140 Dibromomethane ug/L 50 50.9 102 60-140 Dichlorodifluoromethane ug/L 50 51.3 103 60-140 Diisopropyl ether ug/L 50 54.6 109 60-140 Ethylbenzene ug/L 50 50.4 101 60-140 Hexachloro-1,3-butadiene ug/L 50 54.9 110 60-140 Isopropylbenzene (Cumene) ug/L 50 53.3 107 60-140 m&p-Xylene ug/L 100 104 104 60-140 Methyl-tert-butyl ether ug/L 50 54.2 108 60-140 Methylene Chloride ug/L 50 47.7 95 60.140 n-Butylbenzene ug/L 50 52.0 104 60.140 n-Propylbenzene ug/L 50 51.2 102 60-140 Naphthalene ug/L 50 51.5 103 60-140 o-Xylene ug/L 50 52.9 106 60-140 sec-Butylbenzene ug/L 50 51.3 103 60-140 Styrene ug/L 50 55.1 110 60-140 tert-Butylbenzene ug/L 50 42.9 86 60-140 Tetrachloroethene ug/L 50 51.5 103 60-140 Toluene ug/L 50 49.0 98 60-140 trans-1,2-Dichloroethene ug/L 50 52.9 106 60-140 trans-1,B-Dichloropropene ug/L 50 55.6 111 60-140 Trichloroethene ug/L 50 51.9 104 60-140 Trichlorofluoromethane ug/L 50 49.6 99 60-140 Vinyl chloride ug/L 50 57.9 116 60-140 1,2-Dichloroethane-d4 (S) % 105 70-130 4-BromoBuorobenzene (S) % 102 70-130 Toluene-d8(8) % 99 70-130 /\ Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS Date: 11/22/2019 02:19 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 56 aceAnalytical www.Deeslebs.coe QUALITY CONTROL DATA Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 MATRIX SPIKE & MATRIX Parameter SPIKE DUPLICATE: 2736904 MS 92453051007 Spike Units Result Cone. MSD Spike Cone. 2736905 MS Result MSD Result MS % Rae MSD % Rae % Rae Limits RPD Qual n-Butylbenzene ug/L <0.35 20 20 19.1 19.0 96 95 60-140 1 n-Propylbenzene ug/L <0.24 20 20 20.4 20.6 102 103 60-140 1 Naphthalene ug/L <0.66 20 20 21.5 21.4 107 107 60-140 0 o-Xylene ug/L <0.24 20 20 22.2 22.1 111 110 60-140 0 sec-Butylbenzene ug/L <0.25 20 20 20.7 20.9 103 104 60-140 1 Styrene ug/L <0.26 20 20 21.7 21.6 108 108 60-140 1 tert-Butylbenzene ug/L <0.25 20 20 17.8 18.5 89 92 60-140 3 Tetrachloroethene ug/L <0.23 20 20 19.8 20.0 99 100 60-140 1 Toluene ug/L <0.23 20 20 21.2 21.0 106 105 60-140 1 trans-1,2-Dichloroethene ug/L <0.26 20 20 21.4 21.1 107 105 60-140 2 trans-1,3-Dichloropropene ug/L <0.39 20 20 18.8 19.5 94 97 60-140 3 Trichloroethene ug/L <0.23 20 20 21.4 21.5 107 108 60-140 1 Trichlorofluoromethane ug/L <0.34 20 20 23.8 23.9 119 119 60-140 0 Vinyl chloride ug/L <0.41 20 20 24.1 23.4 121 117 60-140 3 1,2-Dichloroethane-d4 (S) % 101 100 70-130 4-Bromofluorobenzene (S) % 100 100 70.130 Toluene-d8 (S) % 97 99 70-130 1\ Results presented on this page are In the units ind1rated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, L-C. Page 27 of 56 aceAnalytical0 www.panleEa.wn QUALITY CONTROL DATA Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 METHOD BLANK: 2738320 Matrix: Water Associated Lab Samples: 92453831002, 92453831003, 92453831004, 92453831005, 92453831006, 92453831007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Hexachloro-1,3-butadiene ug/L NO 2.0 11/19/19 06:30 Isopropylbenzene(Cumene) ug/L NO 0.50 11/19/19 06:30 m&p-Xylene ug/L ND 1.0 11/19/19 06:30 Methyl-tert-butyl ether ug/L NO 0.50 11/19/19 06:30 Methylene Chloride ug/L ND 2.0 11/1911906:30 n-Butylbenzene ug/L NO 0.50 11/19/19 06:30 n-Propylbenzene ug/L NO 0.50 11/19/19 06:30 Naphthalene ug/L NO 2.0 11/1911906:30 o-Xylene ug/L NO 0.50 11/19/19 06:30 sec-Butylbenzene ug/L ND 0.50 11/19/19 06:30 Styrene ug/L ND 0.50 11/19/19 06:30 tert-Butylbenzene ug/L ND 0.50 11/19/19 06:30 Tetachloroethene ug/L ND 0.50 11/19/19 06:30 Toluene ug/L ND 0.50 11/19/19 06:30 trans-1,2-Dichloroethene ug/L NO 0.50 11/19/19 06:30 trans-1,3-Dichloropropene ug/L NO 0.50 11/19/19 06:30 Trichloroethene ug/L NO 0.50 11/19/19 06:30 Trichlorofiuoromethane ug/L NO 1.0 11/19/19 06:30 Vinyl chloride ug/L NO 1.0 11/19/19 06:30 1,2-Dichloroethane-d4 (S) % 94 70-130 11/19/19 06:30 4-Bromofiuorobenzene (S) % 102 70-130 11/19/19 06:30 Toluene-d8 (S) % 100 70-130 11/19/19 06:30 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: Parameter 2738321 Units Spike Cone. LCS Result LCS %Rec %Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 57.4 115 60-140 1,1,1-Tdchloroethane ug/L 50 52.3 105 60-140 1,1,2,2-Tetrachloroethane ug/L 50 55.0 110 60-140 1,1,2-Trichloroethane ug/L 50 53.1 106 60-140 1,1-Dichloroethane ug/L 50 52.1 104 60-140 1,1-Dichloroelhene ug/L 50 52.0 104 60-140 1,1-Dichloropropene ug/L 50 56.1 112 60-140 1,2,3-Trichlorobenzene ug/L 50 58.0 116 60-140 1,2,3-Trichloropropane ug/L 50 61.8 124 60-140 1,2,4-Trichlorobenzene ug/L 50 57.6 115 60-140 1,2,4-Trimethylbenzene ug/L 50 55.3 111 60-140 1,2-Dibromo-3-chloropropane ug/L 50 59.6 119 60-140 1,2-Dibromoethane (EDB) ug/L 50 56.2 112 60-140 1,2-Dichlorobenzene ug/L 50 54.4 109 60-140 1,2-Dichloroethane ug/L 50 45.9 92 60-140 1,2-Dichloropropane ug/L 50 54.1 108 60-140 1,3,5-Trimethylbenzene ug/L 50 55.7 111 60-140 1,3-Dichlorobenzene ug/L 50 53.5 107 60-140 Results presented on this page are In the units Indicated by the "Units' column except where an alternate unit Is presentee to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 56 aceAnalytical x www.pealebs.can QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2739604 2739605 MS MSD 92453831007 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 21.1 21.0 106 105 60-140 1 1,1,1-Trichloroethane ug/L ND 20 20 21.2 20.9 106 105 60-140 1 1,1,2,2-Tetrachloroethane ug/L ND 20 20 20.9 20.8 104 104 60-140 1 1,1,2-Trichloroethane ug/L ND 20 20 21.2 21.4 106 107 60-140 1 1,1-Dichloroethane ug/L ND 20 20 21.1 20.6 106 103 60-140 3 1,1-Dichloroethene ug/L ND 20 20 21.3 20.6 106 103 60-140 3 1,1-Dichloropropene ug/L ND 20 20 22.0 21.3 110 106 60-140 3 1,2,3-Trichlorobenzene ug/L ND 20 20 20.2 19.4 101 97 60-140 4 1,2,3-Trichloropropane ug/L ND 20 20 20.7 20.8 103 104 60-140 1 1,2,4-Trichlorobenzene ug/L ND 20 20 19.7 18.9 99 94 60-140 4 1,2,4-Trimethylbenzene ug/L ND 20 20 20.0 19.1 100 95 60-140 5 1,2-Dibromo-3-chloropropane ug/L ND 20 20 21.4 21.1 107 105 60-140 1 1,2-Dibromoethane (EDB) ug/L ND 20 20 20.9 20.9 105 104 60.140 0 1,2-Dichlorobenzene ug/L ND 20 20 20.8 19.6 104 98 60-140 6 1,2-Dichloroethane ug/L ND 20 20 19.0 18.8 95 94 60-140 1 1,2-Dichloropropane ug/L ND 20 20 21.1 20.7 106 103 60-140 2 1,3,5-Trimethylbenzene ug/L ND 20 20 20.4 19.3 102 96 60-140 6 1,3-Dichlorobenzene ug/L ND 20 20 20.1 19.2 101 96 60-140 4 1,3-Dichloropropane ug/L ND 20 20 21.5 21.5 108 108 60-140 0 1,4-Dichlorobenzene ug/L ND 20 20 20.1 19.2 101 96 60-140 5 2,2-Dichloropropane ug/L ND 20 20 17.8 17.6 89 88 60-140 1 2-Chlorotoluene ug/L ND 20 20 20.1 19.1 100 96 60-140 5 4-Chlorotohlene ug/L ND 20 20 20.4 19.1 102 95 60-140 7 Benzene ug/L ND 20 20 21.5 20.7 107 104 60-140 3 Bromobenzene ug/L ND 20 20 21.1 20.1 105 100 60-140 5 Bromochloromethane ug/L ND 20 20 21.9 21.4 110 107 60-140 2 Bromodichloromethane ug/L ND 20 20 20.8 20.4 104 102 60-140 2 Bromoform ug/L ND 20 20 21.8 21.0 109 105 60-140 4 Bromomethane ug/L ND 20 20 21.2 20.5 106 102 60-140 3 Carbon tetrachloride ug/L ND 20 20 21.7 21.3 109 106 60-140 2 Chlorobenzene ug/L ND 20 20 20.3 19.4 101 97 60-140 5 Chloroethane ug/L ND 20 20 21.7 19.5 108 97 60-140 11 Chloroform ug/L ND 20 20 21.4 20.5 107 103 60-140 4 Chloromethane ug/L ND 20 20 21.8 20.7 109 103 60-140 5 cis-1,2-Dichloroethene ug/L ND 20 20 20.5 19.6 102 98 60-140 4 cis-1,3-Dichloropropene ug/L ND 20 20 21.1 20.6 106 103 60-140 2 Dibromochloromethane ug/L ND 20 20 20.8 20.3 104 102 60-140 2 Dibromomethane ug/L ND 20 20 20.8 20.6 104 103 60.140 1 Dichlorodi8uoromelhane ug/L ND 20 20 25.7 24.7 129 124 60-140 4 Diisopropyl ether ug/L ND 20 20 20.7 20.3 103 101 60-140 2 Ethylbenzene ug/L ND 20 20 20.1 19.1 100 95 60-140 5 Hexachloro-1,3-butadiene ug/L ND 20 20 20.1 18.3 100 92 60-140 9 Isopropylbenzene (Cumene) ug/L ND 20 20 21.0 19.9 105 100 60-140 5 m&p-Xylene ug/L ND 40 40 40.3 39.4 101 98 60-140 2 Methyl -tart -butyl ether ug/L ND 20 20 20.4 20.1 102 101 60-140 2 Methylene Chloride ug/L ND 20 20 18.5 18.3 93 91 60-140 1 Results presented on this page are In the units Indicated by me "Units' column except where an alternate unit Is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 11/22/2019 02:19 PM without the written wnsent of Pace Analytical Services, LLC. Page 31 of 56 aceAnalytical e www.Derele6s.con QUALITY CONTROL DATA Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 QC Batch: 510408 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Description: 6200B MSV Associated Lab Samples: 92453831008. 92453831009 METHOD BLANK: 2738569 Associated Lab Samples: 92453831008, 92453831009 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L NO 0.50 11/20/19 16:28 1,1,1-Trichloroethane ug/L NO 0.50 11/20/19 16:28 1,1,2,2-Tetrachloroethane ug/L NO 0.50 11/2011916:28 1,1,2-Trichloroethane ug/L ND 0.50 11/2011916:28 1,1-Dichloroethane ug/L ND 0.50 11/20/19 16:28 1,1-Dichloroethene ug/L NO 0.50 11/20/19 16:28 1,1-Dichloropropene ug/L NO 0.60 11/20/19 16:28 1,2,3-Trichlorobenzene ug/L NO 2.0 11/20/19 16:28 1,2,3-Trichloropropane ug/L NO 0.50 11/20/19 16:28 1,2,4-Trichlorobenzene ug/L NO 2.0 11/20/19 16:28 1,2,4-Trimethylbenzene ug/L NO 0.50 11/20/19 16:28 1,2-Dibromo-3-chloropropane ug/L NO 1.0 11/20/19 16:28 1,2-Dibromoethane(EDB) ug/L ND 0.50 11/20/19 16:28 1,2-Dichlorobenzene ug/L ND 0.50 11/2011916:28 1,2-Dichloroethane ug/L ND 0.50 11/20/19 16:28 1,2-Dichloropropane ug/L ND 0.50 11/2011916:28 1,3,5-Trimethylbenzene ug/L ND 0.50 11/20/19 16:28 1,3-Dichlorobenzene ug/L NO 0.50 11/20/19 16:28 1,3-Dichloropropane ug/L NO 0.50 11/20/19 16:28 1,4-Dichlorobenzene ug/L NO 0.50 11/20/19 16:28 2,2-Dichloropropane ug/L NO 0.50 11/20/19 16:28 2-Chlorotoluene ug/L ND 0.50 11/20/19 16:28 4-Chlorotoluene ug/L NO 0.50 11/20/19 16:28 Benzene ug/L NO 0.50 11/20/19 16:28 Bromobenzene ug/L NO 0.50 11/20/19 16:28 Bromochloromethane ug/L NO 0.50 11/2011916:28 Bromodichloromethane ug/L ND 0.50 11/20/19 16:28 Bromoform ug/L ND 0.50 11/20/19 16:28 Bromomethane ug/L ND 5.0 1112011916:28 Carbon tetrachloride ug/L ND 0.60 11/20/19 16:28 Chlorobenzene ug/L ND 0.50 11120/1916:28 Chloroethane ug/L ND 1.0 11/20/19 16:28 Chloroform ug/L NO 0.50 11/20/19 16:28 Chloromethane ug/L NO 1.0 11/20/19 16:28 cis-1,2-Dichloroethene ug/L NO 0.50 11/20/19 16:28 cis-1,3-Dichloropropene ug/L NO 0.60 11/2011916:28 Dibromochloromethane ug/L NO 0.50 11120/1916:28 Dibromomethane ug/L NO 0.50 11/2011916:28 Dichlorodifluoromethane ug/L NO 0.50 11/2011916:28 Diisopropyl ether ug/L NO 0.50 11/20/19 16:28 Ethylbenzene ug/L NO 0.50 11/20/19 16:28 Qualifiers Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on thb peas are In the units Indicated by the "unite" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, L-C. Page 33 of 56 aceAnalytical www.pacalabs.wn QUALITY CONTROL DATA Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 LABORATORY CONTROL SAMPLE: Parameter 2738570 Units Spike Cone. LCS Result LCS %Rec % Rae Limits 1,3-Dichloropropane ug/L 50 50.2 100 60-140 1,4-Dichlorobenzene ug/L 50 47.9 96 60-140 2,2-Dichloropropane ug/L 50 46.0 92 60-140 2-Chlorotoiuene ug/L 50 47.3 95 6D-140 4-Chlorotoluene ug/L 50 48.0 96 60-140 Benzene ug/L 50 47.9 96 60-140 Bromobenzene ug/L 50 49.7 99 60-140 Bromochloromethane ug/L 50 48.5 97 60.140 Bromodichloromethane ug/L 50 48.4 97 60-140 Bromoform ug/L 50 54.3 109 60-140 Bromomethane ug/L 50 54.2 108 60-140 Carbon tetrachloride ug/L 50 47.9 96 60-140 Chlorobenzene ug/L 50 46.1 92 60-140 Chloroethane ug/L 50 36.0 72 60-140 Chloroform ug/L 50 45.8 92 60-140 Chloromethane ug/L 50 50.5 101 60-140 cis-1,2-Dichloroethene ug/L 50 46.0 92 60-140 cis-1,3-Dichloropropene ug/L 50 52.1 104 60-140 Dibromochloromethane ug/L 50 48.9 98 60-140 Dibromomethane ug/L 50 49.5 99 60-140 Dichlorodifluoromethane ug/L 50 60.1 120 60-140 Diisopropyl ether ug/L 50 48.5 97 60-140 Ethylbenzene ug/L 50 45.0 90 60-140 Hexachloro-1,3-butadiene ug/L 50 49.8 100 60-140 Isopropylbenzene (Cumene) ug/L 50 47.8 96 60-140 m&p-Xylene ug/L 100 91.0 91 60-140 Methyl-tert-butyl ether ug/L 50 48.5 97 60-140 Methylene Chloride ug/L 50 42.5 85 60-140 n-Butylbenzene ug/L 50 48.1 96 60-140 n-Propylbenzene ug/L 50 47.0 94 60-140 Naphthalene ug/L 50 51.5 103 60-140 o-Xylene ug/L 50 46.9 94 60-140 sec-Butylbenzene ug/L 50 48.0 96 60-140 Styrene ug/L 50 49.1 98 60-140 tert-Butylbenzene ug/L 50 39.3 79 60-140 Tetrachloroethene ug/L 50 44.8 90 60-140 Toluene ug/L 50 45.9 92 60-140 trans-1,2-Dichloroethene ug/L 50 48.2 96 60-140 trans-1,3-Dichloropropene ug/L 50 51.8 104 60-140 Trichloroethene ug/L 50 46.6 93 60-140 Tdchlorofluoromethane ug/L 50 41.3 83 60-140 Vinyl chloride ug/L 50 53.3 107 60-140 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 100 70.130 Pace Analytical Services, LLC 2226 Riverside Dr. Asheville, NC 28804 (828)254-7176 Qualifiers Results presented on this papa are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Dale: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 56 aceAnalytical www incolaba.cou QUALITY CONTROL DATA Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 MATRIX SPIKE & MATRIX SPIKE Parameter DUPLICATE: 2738571 MS 92453831008 Spike Units Result Conc. MSD Spike Conc. 2738572 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Qual n-Butylbenzene ug/L ND 20 20 18.9 20.3 94 102 60-140 7 n-Propylbenzene ug/L ND 20 20 19.0 20.4 95 102 60-140 7 Naphthalene ug/L ND 20 20 18.7 20.8 93 104 60-140 11 o-Xylene ug/L ND 20 20 19.8 20.9 99 104 60-140 6 sec-Butylbenzene ug/L ND 20 20 19.1 20.8 96 104 60-140 8 Styrene ug/L ND 20 20 20.1 21.4 100 107 60-140 6 tert-Butylbenzene ug/L ND 20 20 16.1 17.7 80 88 60-140 9 Tetrachloroethene ug/L ND 20 20 18.7 19.5 94 98 60-140 4 Toluene ug/L ND 20 20 19.1 19.9 95 99 60-140 4 trans-1,2-Dichloroethene ug/L ND 20 20 20.7 21.8 104 109 60-140 5 trans-1,3-Dichloropropene ug/L ND 20 20 20.0 20.8 100 104 60-140 4 Trichloroethens ug/L ND 20 20 19.7 20.6 98 103 60-140 5 Trichlorofluoromethane ug/L ND 20 20 22.1 22.5 111 112 60-140 2 Vinyl chloride ug/L ND 20 20 23.4 24.6 117 123 60-140 5 1,2-Dichloroethane-d4 (S) % 102 100 70-130 4-Bromofluorobenzene (S) % 100 99 70-130 Toluene-d8 (S) % 99 98 70-130 Results presented on this page are In the units Indicated by the "Units" column except where an alternate, unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/22/201902:19 PM without the written consent of Pace Analytical Services,LLC. Page 37 of 56 aceAnalytical / www.pacelabs.wn 1 QUALITY CONTROL DATA Pace Analylical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 QC Batch: 510493 Analysis Method: SM 254OC-2011 QC Batch Method: SM 254OC-2011 Analysis Description: 2540C Total Dissolved Solids Associated Lab Samples: 92453831002, 92453831003, 92453831004, 92453831005, 92453831006, 92453831007, 92453831008 METHOD BLANK: 2739011 Matrix: Water Associated Lab Samples: 92453831002, 92453831003, 92453831004, 92453831005, 92453831006, 92453831007, 92453831008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 11/19/19 23:31 LABORATORY CONTROL SAMPLE: 2739012 Spike LCS LCS %Rec Parameter Units Cone. Result %Rec Limits Qualifiers Total Dissolved Solids Ill 250 250 100 90-110 SAMPLE DUPLICATE: 2739013 92453977006 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 78000 u9/L 81.0 4 SAMPLE DUPLICATE: 2739014 92453831008 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 83.0 81.0 2 Results presented on this page are In the units indicated by the "Units' column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, U.C. Page 39 of 56 aceAnalytical www.pcelabs.ren QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7178 Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 QC Batch: 509698 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Associated Lab Samples: 92453831001 METHOD BLANK: 2735400 Matrix: Water Associated Lab Samples: 92453831001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 11/15/1912:02 LABORATORY CONTROL SAMPLE: 2735401 Spike LCS LCS %Rec Parameter Units Cone. Result %Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 4.9 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2735402 2735403 MS MSD 92453325001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result % Rae % Rae Limits RPD Oual Nitrogen, Ammonia mg/L 5.4 5 5 10.3 10.3 99 97 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2735404 2735405 MS MSD 92453831001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 4.6 4.5 91 91 90-110 0 Results presentee on this page are In the units Indicated by the -Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, I.I.C. Page 41 of 56 w aceAnalytical / wew.pacelabs.con I QUALITY CONTROL DATA Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QC Batch: 509665 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92453831001, 92453831003, 92453831004, 92453831005, 92453831006, 92453831007, 92453831008 METHOD BLANK: 2735311 Matrix: Water Associated Lab Samples: 92453831001, 92453831003, 92453831004, 92453831005, 92453831006, 92453831007, 92453831008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L NO 0.040 11/15/1902:37 LABORATORY CONTROL SAMPLE: 2735312 Spike LCS LCS % Rec Parameter Units Cone. Result % Rae Limits Qualifiers Nitrogen, Nitrate mg/L 1.5 1.5 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2735315 2735316 MS MSD 92453750002 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result % Rae % Rae Limits RPD Qual Nitrogen, Nitrate mg/L 22.2 1.5 1.5 23.3 26.5 68 287 90-110 13 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2735347 2735348 MS MSD 92453752001 Spike Spike MS MSD MS MSD % Rae Parameter Units Result Cone. Conc, Result Result % Rae % Rae Limits RPD Qual Nitrogen, Nitrate mg/L 29.8 1.5 1.5 35.1 37.0 355 478 90-110 5 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presentee to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/221201902:19 PM without the written consent of Pace Analytical Services,LLC. Page 43 of 56 aceAnalytical e www.pacelabacan QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 OC Batch: 510002 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Associated Lab Samples: 92453831001 METHOD BLANK: 2736847 Matrix: Water Associated Lab Samples: 92453831001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phosphorus mg/L ND 0.050 11/18/1915:59 LABORATORY CONTROL SAMPLE: 2736848 Spike LIDS LCS % Rec Parameter Units Conc. Result %Rec Limits Qualifiers Phosphorus mg/L 2.5 2.5 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2736849 2736850 MS MSD 92453361001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec e/ Rec Limits RPD Qual Phosphorus mg/L 0.30 2.5 2.5 2.8 2.8 101 100 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2736851 2736852 MS MSD 92453445001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 1.0 2.5 2.5 3.6 3.6 103 102 90-110 1 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right or the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 11/22/201902:19 PM without the written consent of Pace Analytical Services,LLC. Page 45 of 56 aceAnalytical www.pactlabs.ron QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 QC Batch: 509855 Analysis Method: SM 4500-CI-E-2011 QC Balch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Associated Lab Samples: 92453831001 METHOD BLANK: 2736127 Matrix: Water Associated Lab Samples: 92453831001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L NO 1.0 11/15/1918:49 LABORATORY CONTROL SAMPLE: 2736128 Spike LCS LCS %Rec Parameter Units Cone. Result %Rec Limits Qualifiers Chloride mg/L 20 20.3 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2736129 2736130 MS MSD 92453831001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qual I l Chloride mg/L 11.0 10 10 21.0 21.0 100 100 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2736131 2736132 MS MSD 92453089003 Spike Spike MS MSD MS MSD e/ Rae Parameter Units Result Conc. Cone. Result Result % Rae % Rae Limits RPD Qual Chloride mg/L 16.8 10 10 26.6 26.5 98 98 90-110 0 Results presented on this page are In the units Indicated by the "Units" column except More an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 56 ace Analytical ytwe.pacslabs.can QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 QC Batch: 509866 Analysis Method: SM 531 OB-2011 QC Batch Method: SM 531OB-2011 Analysis Description: 5310B TOG Associated Lab Samples: 92453831001 METHOD BLANK: 2736234 Matrix: Water Associated Lab Samples: 92453831001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L NO 1.0 11/15/1918:54 LABORATORY CONTROL SAMPLE: 2736235 Spike LCS LCS e/ Rae Parameter Units Cone. Result %Rec Limits Qualifiers Total Organic Carbon mg/L 25 25.8 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2736236 2736237 MS MSD 92453831001 Spike Spike MS MSD MS MSD % Rae Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qual Total Organic Carbon mg/L 3.7 25 25 28.6 28.7 100 100 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2736336 2736337 MS MSD 2625494001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qual Total Organic Carbon mg/L 3.6 25 25 29.1 28.9 102 101 90-110 1 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, LLC. Page 49 of 56 aceAnalytical www.pacelabs.tela QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 QC Batch: 510389 Analysis Method: SM 531OB-2011 QC Batch Method: SM 531OB-2011 Analysis Description: 5310E TOC Associated Lab Samples: 92453831006, 92453831007, 92453831008 METHOD BLANK: 2738479 Matrix: Water Associated Lab Samples: 92453831006, 92453831007, 92453831008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L NO 1.0 11/19/19 19:32 LABORATORY CONTROL SAMPLE: 2738480 Spike LCS LCS % Rae Parameter Units Cone. Result %Rec Limits Qualifiers Total Organic Carbon mg/L 25 25.2 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2738481 2738482 MS MSD 92453831006 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result % Rae % Rae Limits RPD Qual Total Organic Carbon mg/L 6.1 25 25 28.4 28.8 89 91 90-110 1 M7 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2738527 2738528 MS MSD 92452885003 Spike Spike MS MSD MS MSD % Rae Parameter Units Result Cone. Cone. Result Result %Rec %,Rec Limits RPD Qua] Total Organic Carbon mg/L ND 25 25 24.4 24.7 97 98 90-110 1 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/22/2019 02:19 PM without the written consent of Pace Analytical Services, LLC. Page 51 of 56 aceAnalytical w .prnlabs<oa QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: LASSONDE PAPPAS 11-14-19 Pace Project No.: 92453831 Lab ID 92453831001 92453831002 92453831003 92453831004 92453831005 92453831006 92453831007 92453831008 92453831009 92453831001 92453831002 92453831003 92453831004 92453831005 92453831006 92453831007 92453831008 92453831001 92453831002 92453831003 92453831004 92453831005 92453831006 92453831007 92453831008 92453831001 92453831002 92453831003 92453831004 92453831005 92453831006 92453831007 92453831008 92453831001 92453831002 92453831003 92453831004 92453831005 92453831006 92453831007 92453831008 92453831001 92453831002 Sample ID MW-4 MW-5 MW-6 MW-7R MW-8 MW-9 SW-1 SW-2 TRIP BLANK MW-4 MW-5 MW-6 MW-7R MW-8 MW-9 SW-1 SW-2 MW-4 MW-5 MW-6 MW-7R MW-8 MW-9 SW-1 SW-2 MW-4 MW-5 MW-6 MW-7R MW-8 MW-9 SW-1 SW-2 MW-4 MW-5 MW-6 MW-7R MW-8 MW-9 SW-1 SW-2 MW-4 MW-5 Date: 11 /22/2019 02:19 PM QC Batch Method SM 6200B SM 6200B SM 62006 SM 6200B SM 6200B SM 6200B SM 6200B SM 6200B SM 6200B SM 254OC-2011 SM 254OC-2011 SM 254OC-2011 SM 2540C-2011 SM 254OC-2011 SM 2540C-2011 SM 254OC-2011 SM 2540C-2011 SM 9222D-2006 SM 9222D-2006 SM 9222D-2006 SM 9222D-2006 SM 9222D-2006 SM 9222D-2006 SM 9222D-2006 SM 9222D-2006 EPA350.1 Rev 2.01993 EPA 350.1 Rev 2.0 1993 EPA 350.1 Rev 2.0 1993 EPA 350.1 Rev 2.0 1993 EPA 350.1 Rev 2.0 1993 EPA 350.1 Rev 2.0 1993 EPA 350.1 Rev 2.0 1993 EPA 350.1 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 365.1 Rev 2.0 1993 EPA 365.1 Rev 2.0 1993 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QC Batch Analytical Method 509790 510347 510347 510347 510347 510347 510347 510408 510408 509672 510493 510493 510493 510493 510493 510493 510493 509769 509769 509769 509769 509769 509769 509769 509769 509698 509701 509701 509701 509701 509701 509701 509701 509665 509667 509665 509665 509665 509665 509665 509665 510002 510004 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. SM 9222D-2006 SM 9222D-2006 SM 9222D-2006 SM 9222D-2006 SM 9222D-2006 SM 9222D-2006 SM 9222D-2006 SM 9222D-2006 Analytical Batch 509771 509771 509771 509771 509771 509771 509771 509771 EPA 365.1 Rev 2.0 1993 510105 EPA 365.1 Rev 2.0 1993 510106 Page 53 of 56 Document Name: Document Revised: February 7, 2018 Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: aceAnallnlcal F-CAR-CS-033-Rev.06 Pace Carolinas Quailt OfOce *Check mark top half of box if pH and/or dechlorination Is verified and within the acceptance range for preservation samples, Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottle Projec' WO# : 92453831 111111111111111111111111 92453831 w -J V m vAi Bi U N m o $i ,=j m,,, o C y .e v i3 = U ry E v x m O x o o0 s a U yE r n x =o Z V E c m -spy y -`' ? aa� n 7 N ¢ 8 v 9 x d a ¢ .e v 2 Y c =y 31 o r�� U' a v V N 'E � a v x a = d ¢ E a x E .¢.1 E o ^vl r� ryQ1 V' a i _ = ¢ O E C 2 a ` O'mod Z ¢ p E l9 a a 7 a 0 E e Q 8 6 = ¢y O E $ z j2 o .Y 3 a R a Y n Z 1 V E Z 6 `v 1plE� N i ? ✓ m QE N g } c _ L E pE O e q c c E O n 7 d E E v 1 1 11 i K � 1 5 I ) 6 1 I I 2 7 I I I y 1 8 �T B � 10 11 12 pH Adjustment Log for Preserved Samples Sample ID Type of preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot x Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will beset to the North Carolina DEHNR Certification Office (i.e. Out of hold, Incorrect preservative, out of temp, Incorrect containers. Page 55 of 56 Attachment 2 Well Sampling Logs and Instrument Calibration Data Sheet ANCHOR QEA. ' Well Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: L NS !r g-vl l 1,- Q��.ry/t� Date: // /jV I q Project Number. C� 08X_ U1. 01 Weather 0-1-0 1 t) "1 j0 S j C . 6 4-tb-LK Sampling Personnel: G PA-1 Twos m A f5 oyt Sample Time: 1 r 3 5v Well Number. j r Well Depth in Feet (WD): / Well Diameter. .2- `r Water Level in Feet (WL): CI Type of Casing: /RUC Length of Water Column: O�� %: feet/t Ln , Measuring Point 7� �;, (WD) - NO = (LWC) Flush Mount / uk-Up One Casing Volume: gallons b Comments: (LWC) x (WCV) Three Casing Volumes: S� gallons Actual Volume Purged: y J gallons tagged bottom at: (% rJ ft TOC Well Casing Volumes (WCV) 1" = 0.04 Gal/Ft " = 0.16 Gal/F 3" = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" = 1.5 GaVFt 8" = 2.6 Gal/Ft 12" = 5.9 Gal/Ft Purge Method: alter- is . Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. Sample Method: Bailer-Dis Bailer -Teflon Dedicated Pump Whale Pump Gruni fos Other: 1 Oxidation -- Gallons Temp Dissolved Specific Cond. pH (S.U.) Reduction Turbidity Reading Time Purged (•C) Oxygen (mg/L) (pS/cm) report to 0.7 S.U. Potential (mV) (NTU) Comments 1 /33+- D t;-.Y _ i.C(� GL,c 6. -1 3 2 Ilya �. 1s r�.,i 3rYy L'j 5•v P - /c%i•% 3 nys- }' T 14. 6 3 .J r I k: 5: b5 /9/r 7 9s.� 4 1351 ,1,5"15"% 3,/, 172.6 s.> % zeS i) 5 /"rs'W vr/W: e B-iG T 1= lac 7 8 9 10 Sampling Container Number of Containers Requested Analysis 500 mL Plastic TDS 250 mL Plastic jreep' f 125 mL Plastic - �%��N 40 mL Glass `•�'MH�!'�.sf�Ps+sav ti VUG- 6-00 *L / saf�oru Ira 1 L Glass Other ,r ''` Protective Casing: � Pad: rO % Lock:.� Vegetation: y� Access: GO Sampling Personnel Signature: / �.. ck Date: /., Ni ry/' 01 Notes: Well Casing Volumes defined in Table 2 of the Region 4 Environmental Protection Agency (EPA) Science and Ecosystem Support Division (SESD) document utled Operating Procedure - Groundwoter5amptliy last revised Apol 26, 2017. Samples are analyzed immediately upon collection. Minimum volume purged: 3 well volumes. Sample time determined by parameter stabilludon. °C: degrees Celsius pS/on: micro-Siemen per centimeter mg/L milligrams per liter Method Reference: Temperature: SM 2550 B-2010 DO: SM 4500 O 6-2011 mV: millivolt MU: nephelometdc turbidity units S.U: Standard Units Specific conductivity EPA Method 120.1, Rev. 1982 pH: SM 4500-H' B-2011 I Page 1 of 1 kZANCHOR QEA Well Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: 1- 4" i,`s d e pAe () l)�i Date: / I / / y / ) Project Number. 782 01 Weather. e " "O.I 30'"'0 { S j / I, L Sampling Personnel: C , 104-n ylSfa � . ^+41.1 o,4 Sample Time: / L 2 p r II Well Number. 1 m 1 (v1/ - b Well Depth in Feet (WD): p' s0'� s `� 4 Well Diameter. 7, '' Water Level in Feet (WL): /5. 5 9 r 714 L Type of Casing: PVC C Length of Water Column: `Jl, feet Measuring Point: IT) C (WD) - (WL) = (LWC) Flush Mount / 5 DIP One Casing Volume: 3 gallons Comments: (LWC) x (WCV) Three Casing Volumes: 3 O gallons Actual Volume Purged: Q gallons tagged bottom at R TOC Well Casing Volumes (WCV) 1" = 0.04 GaII/Ft 0.16 Gal/Ft 3' = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" - 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12' = 5.9 Gal/Ft Purge Method: ;' Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Gmndfos Other. Sample Method: Bailer-Disp._.J Bailer -Teflon Dedicated Pump Whale Pump Gmndfos Other. Oxidation FMGam TempDissolved Specific Cond, PH(S.U.) Reduction Turbidity Reading Timeed (°C) Oxygen (mg/L) (ps/cm) report to 0.11111. Potential (mV) (NTU) Comments 1 0 I11-s.9 •3S 2-79• 3 )'L6 2 i4b /.0 /5 z.� / ivy 1 51J/ % Eo• 3 9,V,3 3 i ilu 7, '157,-7 2 .5-2_ l y/9. L S'e3 D 7- 55, 3 4 iLls'3.o !/s.) 1.g1_ !Y'>',Z S•3 2-5/.�/ 7 8 9 10 Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 ml. Plastic 2 125 mt. Plastic /? L IKO�G/'�-NNI(A�LI Q� / �Or/lrtp/FtrS (� ,•'jlyi /. 40 mL Glass rl Git•f IN, 3 s.'/3k rv,rL VQG' a2Oo/ f O 1 L Glass Other Protective Casing: B S Pad: _*.F Lock: ` Vegetation: Access: Sampling Personnel Signature: G' / Date: / / /- -2V1 / Notes: Well Casing Volumes defined in Table 2 of the Region 4 Environmental Protection Agency (EPA) Science and Ecosystem Support Division (SESO) document tided Operotalg Procedure - Groundwoter5ampfng last revised Apol 26, 2017. Samples are analyzed immediately upon collection. Minimum volume purged: 3 well volumes. Sample time determined by parameter stabilization 'C.' degrees Celsius pS/cm: micro-Siamen per centimeter mg/L• milligrams per I ter Method Reference: Temperature: SM 2550 B-2010 DO: SM 4500 O G-2011 mV: millivolt NTU: nephelometric turbidity units S.U. Standard Units SpecfiC conductivity. EPA Method 120.1, Rev. 1982 PH: SM 4500-H' B-2011 Page 1 of 1 r kizANCHOR QEA well Project Name: Lars,s;Waf Po�epCS- Project Number. c -1 7 #8 7- Sampling Personnel: C PAIAcr-ro l-4 Well Number. Well Diameter. Type of Casing: PVC Measuring Point TUC Flush Mount / S�flc•k=Up t Comments: bottom at: /S_yy- ft TOC Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Date: ! 1// -111" / Weather. Oven« r 3pdFr S� i? b �ezt Sample Time: fiJ 15 Well Depth in Feet (WD): 1 .73 Water Level in Feet(WL): q 75 Length of Water Column: 14. 1b' feet (WD) - (WL) = (LWC) One Casing Volume: 0.4p Q r gallons (LWQ x(WCV) Three Casing Volumes: „7-. L' J gallons Actual Volume Purged: a 00 gallons _ Well Casing Volumes (WCV) _ 1" = 0.04 Gal/Ft (2" = 6.16 Gal/Fo 3' = 0.37 Gal/Ft 4' a 0.65 Gal/Pt 6' = 1.5 Gal/Ft a" = 2.6 Gal/Ft 12" = 5.9 Gal/Ft Purge Method: oiler -Di Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. Sample Method: Bailer-Dis Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. 1 z 3 4 5 6 7 8 9 10 Gallons Temp I Dissolved Specific Cond. PH (S.U.) Reduction Turbidity Time Purged CC) Oxygen (mg/L) (PS/cm) report to 0.7 S.U. Potential (mV) 1 (NTU) Comments 73"l4 '_iq1"/ !t •' �,t�r CC !b � '1 �j,(7. 'J 3(I,� .3. � L.[aai 76, 7 _r, /Ota�',�•?> ��.0 r.7C 5L2.5. G.73 i /odor /45 2, cr �y,i a{.(,a j 45,L 4.71 '�'H' 2,&1 17-7 4t.,4cavw1) Number of Contalners Analysis 250 mL Plastic 125 mL Plastic 2- feel 6vl!�rxrn a"rsl I(.�tv),{% Glass 2 ' V d oar 4M�11k 40 m u/r��f 3 u7fv, voc Quo e'J roc 1 LGlass Other Protective Casing: 0 Pad: S- Lock Vegetation:- 1M Access: AJo Sampling Personnel Signature: Data: P'l,J Vw iAPM} Fit 'rx Y,BI Well Casing Volumes defined in Table 2 of the Region 4 Environmental Protection Agency (EPA) Science and Ecosystem Support Division (SESD) document titled Operoting Procedure - Groundwater Sompting last revised April 26, 2017. Samples are analyzed immediately upon collection. Minimum volume purged: 3 well volumes. Sample time determined by parameter stabilization. 'C: degrees Celsius MV. millivolt pS/cm micro-Siamen per centimeter NTU: nephelometfic turbidity units mg/L milligrams per liter S.U.: Standard Units Method Reference: Speciflc conductivity. EPA Method 120.1, Rev. 1982 Temperature: SM 2550 8- 20 10 pH: SM 4500-H' 8.2011 D6. SM 4500 O G-2011 Page 1 of 1 ANCHOR QE'A 64..4/ 6.L.4.n Surface Water Samplina Lou Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: t,41 S 0.-VbC Ph2e,i 5 _ Date: Project Number. CU42.2 _oh Ul Weather. Sampling Personnel: A. v%, A C GS L1"1 Sample Name: /� W . I .Iln S I Comments: P L L (^L Y L` r Z /i►yr /V (/X ti/ v I? /�. V'L V I" lr 1%L L-A-,, 0 I - 13 a It) c' ( 111.)0 it SIDc' ( A)^ P Pgro-1J hr AnN-Y L. S " I L L Sample Method: Grab Syringe Pump Bailer-Disp. Other Oxidation Dissolved Specific Cond. pH (S.U.) Reduction Turbidity Time I Temp ('C) Oxygen (mqN (PS/an) report to 0.1 S.U. Potential (mV) (NTU) Comments 015' (P.H /2,tiD goi-� 6116 'LUS.L y5,( C��� Sampling Container Number of Containers Requested Analysis 500 mL Plastic r C vt1Ca t 250 mL Plastic 1_ i 1_ s•� 125 mL Plastic D 40mLGlass ♦ V0C- i 1 L Glass Other Vegetation: it A -A s Access: ( � I) Sampling Personnel Signature: Q V'--e �s Date: 11 11 4 11 C Notes: Samples are analyzed immediately upon collection. 'C degrees Celsius PS/cm: micro-Siemen per cubic centimeter mg/L• milligrams per liter mV: millivolt NTU: nephelometric turbidity units S.U.: standard units Method Reference: Temperature: SM 2550 B-2010 Speck conductivity EPA Method 120.1. Rev. 1982 DO: SM 4500 O G-2011 pH: SM 4S00-H' 8.2011 Page 1 of 1 ANCHOR IDEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 equipment uocumentation and instrument Calibration Data Sheet 11 � � CALIBRATION DOCUMENTATION Project Name: ,r30.t a Pappi WOtter (i(r.ea✓� C� l-1 -i '1o9 Lq`tr Person Conducting Calibration: ns a Project Number. Cq/49*?--bJ.OI Date of Calibration: Project Location: T�endt�s ad vlf✓Cr NG Date of Field Measurements•. EQUIPMENT DOCUMENTATION Equipment or meters used to take measurements (e.g., water level meters, survey equipment): Equipment Type I Serial Number I Brand I Date of Use 150-ft Water Level 26154 T Solinlst 150-ft Water Level 22754 Sotinist 150-ft Water Level 150 Testwell 150-ft Drawdmn MP30-1527 QED Other Select Turbidimeter. Hach 210OQ (s/n 151006045207) HF Scientific MicroTPW (s/n 200601045) Calibration 1 20 NTU 1 100 NTU I B00 NTU NTU 1 0.02 NTU Dissolved Oxygen -- Inmapn r' 6'[-7 Lai: ,r'(j. mmHg: kEy- Temperature CC): /2.rl '7�/ Time: NA PH 7 S.U. report to 0.1 S.U. Initial: ,.. pHmV. �22. `'�' Cal: �rG� 'eL�m1�� / Tlme: o _ 07✓Q reporttoaIs.u. 4-10 1`F2 *.U' 72-2 .a PH 10S.U. report to 0.1 S.U.", Initial: ,,/I 7 pHm V; CAC ,'�8'�.Z Cal: / p 1V: Time: r— 7 QC- PH 7 S.U. moort to o.I Su. AM Time: 07 µi4 Meas: `-T n2 Mid Day Time: Check: PM Time; Check _._ ✓!1 %9n -�:, S/cm•• q56 I l00� GZvt I I H.inlq QC-: PS/cm AM Time: WZY1 Mass: lY8 Mid Day Time: Check PM Time Check CAP A te�rr.."" ORP-262.y//_mV Initial: �FZ-5 Cal: C*2-5' Temperature CC): I .fl Time: 073` !i/2/`adiy Signature: l Jk7T1/ Date: 1111I /2 v Notes) 1. Electmnk equipment calibrated according to the manufacturers operation manual. 2. Specific conductivity should be calibrated according to values representative of historic range. 3. Order of Calibration is as follows: Specific Conductiviry, pH 7, pH 4, pH 10, DO, ORP, QC checks. 4. QC Acceptable Ranges pH +/- 0.1 SA. and Specific conductivity IM of the true value. If QC readings are out of mrge, the Instrument needs to be recalibrated. 5.. Ind'lates that a QC check must be performed In the morning, afternoon, and the end of the day, or every four houn. 6." Indicates to choose a Specific Conductivity buffer of 1413.447, 84, or 23 mS which is closest to historical readings from the project location, Method Reference: Temperature: SM 2550 B-2070 1 Spedfic conductivity: EPA Method 120.7, Rev. 7982 1 DO: SM 45000 G-2011 1 pH: SM 4500-Ha B-2011 Page 1 of 1 Attachment 3 DEQ GW-59A — Compliance Report Form GW-59A COMPLIANCE REPORT FORM Permit # WQ0004797 (Submit one each nmoilaring perlod )eilh GII=59 forth.) I Enter date monitoring results were due. (12/3i/2o1g) Will this monitoring report (GW-59 and GW59A) YES NO be submitted after the established due date? X 2 Was any required information missing on the GW-59 report forms? YES NO IF the answer to question 1 or 21s 'YES, list in the space provided below the well Identification numbers) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged easing, unlocked or missing cap, missing YES NO Identification plate, area overgrown, etc.)? Ifthe ansiver is "Yes", contact the Regional Ofce forguidm(ce. X 4 Are any monitored constituents equal to or above the established standards? YES NO If the answer to question 4 is "NO", skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituents) and concentratlon(s) exceeding standards in the space provided below: Nitrate (2L - 30 mg/L): MW-7R®19.1 mg/L Fecal Coliform (Total Conform 2L standard. 1.0 CFU/100m ): MW-6044.0 CM1100mL, MW-802.0 CFU/300m1, MW-507.0 CPU/mL Tetrachloroethene (2L = 0.9 pg/L) : MW-5822.4 pg/L Trichlomethene (2L - 3 4g/L) : MW-504.4 pg/L 5 For the constituents Identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) In the same well(s) In the last two years? X If the answer to question 5Is "NO" skip to section 8. If the answer to question 5 Is "YES", list in the space provided below, each well with constituents) exceeding standards, concentration(s) reported, and sample collection date foreach occurrence (for the last two years). Nitrate Fecal Coliform Fecal Coliferm Fecal Conform T8trachloreethene Trichlomethene MW-9R (mg/L) MW-5 (CFU/100W MW-6 (CFU/100m ) MW-8 (CFU/10omL) MW-5 (ug/L) MR-5 (ug/L) 05/02/18: 15.5 05/02/18:2.0 05/02/18: 1.0 05/02/18: ND 11/8/11: 35.9 11/08/17: 4.6 11/02/18: 69.0 11/02/18: ND 11/02/18; 69.0 11/02/18: 19.0 11/02/18: 39.1 11/02/18: 6.0 05/21/19: 20.2 05/21/19: ]A 05/21/19: 23.0 05/21/19: ND 11/14/19: 22.4 11/14/19; 4.4 11/14/19: 17.1 11/14/19: 7.0 11/14/19; 44.0 11/14/29: 2.0 6 Are the monitoring wells listed In section 6 located at or beyond the review boundary? YES NO MW-5, MW-TR, and MW-6 are at or beyond the review boundary. X If the answer Is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer Is "NO", monitoring wells may be Improperly located; contact the Regional Office. 7 Is the permittee Implementing previously approved actions required by the Division Involving this YES NO groundwater quality problem? X If the answer to question 71s 'YES'; describe those actions In the space provided below. If the answer to question 7Is "NO ; contact the Regional Office within 90 days: an evaluation may be reaulred to determine the Impact the waste disposal system /s having at the review and compliance boundaries surrounding this facility. Failure to do so may sublect the oermlttee to a Notice of Violation, fines, and/or penalties. Fecal coliforn should not be attributable to site operations. Historical monitoring of an on -site tributary of Mud Creek has found high levels of fecal caliform. Nitrate concentrations exceeded the groundwater standard in MW-TR and MW-8 for the first time in May 2016. The high concentrations of nitrate are likely attributable to the frequent flooding of Mud Creek. 8 The person completing this portion (GW-59A) of the monitoring report should sign below and submit this form with G W-59 forms for required wells to the address provided at the top of the current G W-59 form. I hereby acknowledge that the above Information was evaluated and the Information submitted in this report (Compllance Report GW-59A) is true and complete to the best of my knowledge. Signature of Permlltee (or Authorized Agent) Date M-59A 12/8/2903 Attachment 4 DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Forms m� n M N d a E m t d O.N U L C re) LU i K `° b U n o ui o aD O w c N W o N N t f C O C Y. Z O m m m a y. E a ry O d w m t o Z0. W o a m a a a ca 'J-O z W O❑❑❑❑ E `n c d ffi m m z i r AJH H v® E E E E 1- w �+- E z u' W W aIL 42 i J w O O HLLI e q E U 'Eo V K N i O W i V) N o N U N S K U a F j OD I o UI LL F O d N 0 JZ 1I1 CoNN' C U O O a U« O O< E W c LL 0 0a v U c d •ryyi c fn ,Z` d vwi Z t a° A« J o o 1a N d d z a F m 0) 0 t� 3 u a N O u� d N O O V 0. 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