NC0006254_Groundwater Monitoring Report July 2022_20220812

PO Box 604 ▪ Fletcher, NC 28732 ▪ Cell: 828-508-4510

July 22, 2022
Mr. Brett Laverty
NCDEQ Division of Water Resources
Asheville Regional Office
2090 US Highway 70
Swannanoa, NC 28778

RE: Groundwater Analytical Results – July 12, 2022
Blue Ridge Tissue Corporation
1427 Yadkin River Road
Patterson, North Carolina

Mr. Laverty:

On July 12, 2022, Singleton Environmental, Inc. (SEI) visited the Blue Ridge Tissue site located at
1427 Yadkin River Road in Patterson, North Carolina, to collect groundwater samples from
monitoring wells MW-1, MW-2, MW-3, MW-4, MW-6, MW-7 and MW-8. The depth to
groundwater in the monitoring wells ranged from 5.94 feet in MW-4 to 51.82 feet in MW-2.
Refer to Table 1 for all monitoring well groundwater depths and Figure 1 for all monitoring well
locations.

All groundwater samples, except for MW-2, were collected using a peristaltic pump connected to
a Horiba U52-2 water quality meter with a flow-through-cell to collect groundwater parameters
(temperature, pH, specific conductivity, dissolved oxygen, ORP, and turbidity). Groundwater
sample MW-2 was collected using a clear PVC bailer. Groundwater parameters in MW-3 did not
completely stabilize prior to sample collection due to the low groundwater level causing it to purge
dry. A sample was eventually collected after the well recharged enough for the pump to pull water
to fill the sample containers.

The groundwater samples were submitted on ice to Pace Analytical for the analysis of 8-RCRA
Metals, pH, ammonia, TKN, sulfate, nitrogen, nitrite and nitrate. MW-3 was also analyzed for
total dissolved solids (TDS) using EPA Method SM 2540C. The groundwater parameters for all
samples are outlined in Table 2.

The laboratory analysis of groundwater sample MW-1 detected concentrations of total iron and
total manganese above the NCAC 2L groundwater standards. Both compounds were detected at
concentrations double the March 2022 concentrations.

The laboratory analysis of groundwater sampler MW-2 detected concentrations of total iron, total
barium, total manganese, arsenic, and chromium above the NCAC 2L groundwater standards. All
compounds were detected at concentrations less than half the November 2021 concentrations.

The laboratory analysis of groundwater sample MW-3 detected concentrations of arsenic, total
iron, total manganese, and ammonia above the NCAC 2L groundwater standards. All
Singleton Environmental, Inc.
Singleton Environmental, Inc.
concentrations were higher than the March 2022 concentrations except total manganese, which
was detected at a slightly lower concentration.

The laboratory analysis of groundwater sample MW-4 detected concentrations of total iron and
total manganese above the NCAC 2L groundwater standards. The concentrations of total iron
were higher than the March 2022 concentrations and total manganese were lower than the March
2022 concentrations.

Laboratory analysis of groundwater samples MW-6, MW-7, and MW-8 did not detect any
concentrations exceeding the NCAC 2L groundwater standards. The analytical results are shown
on attached Table 2 and the attached laboratory data sheets.

During the April 2017 groundwater sampling event, AECOM reported a possible sheen on the
groundwater in monitoring well MW-4. During the July 2022 event a sheen was not observed;
therefore, a VOC sample was not collected from the monitoring well.

The compound levels detected in the groundwater analysis for the July 2022 sampling event
detected relatively higher concentration levels of total iron in monitoring wells MW-1, MW-2,
MW-3, and MW-4 compared to the March 2022 concentrations. Monitoring well MW-1 also
detected a higher concentration of total manganese compared to the March 2022 concentrations.
Monitoring well MW-3 also detected higher concentrations of arsenic and ammonia compared to
the March 2022 concentrations.

Singleton Environmental, Inc. recommends sampling the monitoring wells again in November
2022 to continue tracking the groundwater concentration and groundwater levels.

If you have any questions, you can reach me at [phone].

Sincerely,

Chris Singleton, P.G.
Singleton Environmental, Inc.

cc: Dave Hallock, Blue Ridge Tissue Corporation

Attachments
@A
@A @A
@A
@A
@A
@A
@A
MW-2
MW-3
MW-4
MW-1
@A
MW-5
MW-7
MW-6
MW-8
1
2
8
0
12601
3
2
0
1340
1360
1380
124014201240
1420
Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/AirbusDS, USDA, USGS, AEX, Getmapping, Aerogrid, IGN, IGP, swisstopo, and theGIS User Community
Figure
60540673
1
May 2017
§
0 200 400Feet
1 inch = 200 feet
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R
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Whisnant RdYad
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R
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Yadkin
R
iver
Roby Martin Rd#0
Site Layout MapBlue Ridge Tissue CorporationPatterson, North Carolina
Legend
Property Boundary
Yadkin River Flow Direction
#Land Surface Elevation Contour (ft above mean sea level)
Monitoring Well Location
Abandoned Water Well#0@A
Well ID Date Installed Total Depth (feet
bls)
Screened Interval
(feet bls)
Top of Casing
Elevation (feet msl)
Date Water Level
Measured
Depth to Water (feet
BTOC)
Groundwater Elevation
(feet msl)
MW-1 02/08/11 11 6-11 1253.71 07/12/22 12.71 1,241.00
MW-2 08/12/09 50 40-50 1323.03 07/12/22 51.82 1,271.21
MW-3 08/13/09 20 10-20 1299.02 07/12/22 20.35 1,278.67
MW-4 08/13/09 15 5-15 1247.23 07/12/22 5.94 1,241.29
MW-5 08/16/11 21 11-21 1285.46 N/A N/A N/A
MW-6 08/06/14 29 19-29 1341.55 07/12/22 29.44 1,312.11
MW-7 08/06/14 24 14-24 1274.41 07/12/22 19.80 1,254.61
MW-8 08/06/14 20 10-20 1253.14 07/12/22 14.82 1,238.32
Notes:
bls - feet below land surface BTOC - below top of casing msl - above mean sea level NG - not gauged
AECOM
Table 1
Monitoring Well Construction and Groundwater Elevations
Blue Ridge Tissue Corporation
1427 Yadkin River Road
Patterson, North Carolina
Sample ID MW-1 MW-2*MW-3 MW-4 MW-6 MW-7 MW-8
Sample Date 07/12/22 07/12/22 07/12/22 07/12/22 07/12/22 07/12/22 07/12/22
Temperature (°C)NS 16.6 N/A 21.20 22.24 20.10 23.00 22.50
pH (standard units)NS 6.30 N/A 6.20 6.30 5.68 5.92 6.30
Specific Conductivity (mS/cm)NS 0.389 N/A 0.35 0.173 0.032 0.07 0.072
Dissolved Oxygen (mg/L)NS 0.62 N/A 1.81 0.20 6.15 3.30 4.90
ORP (mV)NS -4.0 N/A 75.00 36.0 123.0 136.0 65.0
Turbidity (NTU)NS 6.1 N/A 71.00 4.1 6.9 4.8 7.2
Gallons Pumped NS 1.5 N/A 0.5 2 1.5 2 2.5
Cloudy/Odor No/No No/Odor Cloudy/Odor Cloudy/Odor No/No No/No No/No No/No
Total Barium (ug/L)700 228 1890 317 92.6 68.6 47 10.6
Total Iron (ug/L)300 25800 77700 125000 5700 63 ND ND
Total Manganese (ug/L)50 4490 480 4350 659 15.1 ND ND
Aresenic (ug/L)10 ND 19.7 56.9 ND ND ND ND
Chromium (ug/L)10 ND 69.9 5.2 ND ND ND ND
Lead (ug/L)15 ND 15.0 5.6 ND ND ND ND
Sulfate N/A ND 2.5 29.3 7 ND 1.5 20.1
Ammonia (mg/L)1.5 0.5 18.0 15.1 0.65 ND ND ND
TKN (mg/L)N/A ND 16.9 13 0.65 ND ND ND
Nitrogen NO2 plus NO3 (mg/L)N/A ND 0.055 0.052 ND ND 0.94 2.2
Nitrate (mg/L)10 ND 0.055 ND ND ND 0.94 2.2
Nitrite (mg/L)1 0.043 ND 0.051 ND ND ND ND
pH (standard units)N/A 6.5 6.5 6.5 6.4 5.4 6.3 6
Total Disolved Solids (mg/L)N/A N/A 366 N/A N/A N/A N/A N/A
EPA Method 6200B for VOCs N/A N/A N/A N/A N/A N/A N/A N/A
Notes:
Samples analyzed for total and dissolved iron, barium and manganese by EPA Method 200.7
2L Standard - North Carolina groundwater quality standards established in Title 15A of the North Carolina Administrative Code, Subchapter 2L, Section 0.20
°C - degrees Celsius
µS/cm - microsiemens per centimeter
EPA - United States Environmental Protection Agency mg/L - milligrams per liter
mV - millivolt
NA - Not analyzed NS - No standard
NTU - Nephelometric Turbidity Unit
RCRA - Resource Conservation Recovery Act
Bold samples indicate concentrations above the 2L Standard
*MW-2 purged with disposable bailer, water quality parameters collected from same bail as sample.
2L
Standard
Field Parameters
Analytical Parameters
Table 2
Blue Ridge Tissue Corporation
1427 Yadkin River Road
Patterson, North Carolina
#=CL#
July 20, 2022
LIMS USE: FR - CHRIS SINGLETON
LIMS OBJECT ID: 92614358
92614358
Project:
Pace Project No.:
RE:
Chris Singleton
Singleton Environmental
105 Charlotte Highway
Asheville, NC 28803
Blue Ridge Tissue Corp
Dear Chris Singleton:
Enclosed are the analytical results for sample(s) received by the laboratory on July 12, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
Project Manager
1(828)254-7176
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 26
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 26
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92614358001 MW-1 EPA 200.7 Rev 4.4 1994 6 PASI-ADEC
SM 4500-H+B-2011 1 PASI-ASMS
TKN+NO3+NO2 Calculation 1 PASI-AMAB2
EPA 300.0 Rev 2.1 1993 1 PASI-AMJP
EPA 350.1 Rev 2.0 1993 1 PASI-ANDS
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AMFO
92614358002 MW-2 EPA 200.7 Rev 4.4 1994 6 PASI-ADEC
SM 2540C-2015 1 PASI-AZMC
SM 4500-H+B-2011 1 PASI-ASMS
TKN+NO3+NO2 Calculation 1 PASI-AMAB2
EPA 300.0 Rev 2.1 1993 1 PASI-AMJP
EPA 350.1 Rev 2.0 1993 1 PASI-ANDS
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AMFO
92614358003 MW-3 EPA 200.7 Rev 4.4 1994 6 PASI-ADEC
SM 4500-H+B-2011 1 PASI-ASMS
TKN+NO3+NO2 Calculation 1 PASI-AMAB2
EPA 300.0 Rev 2.1 1993 1 PASI-AMJP
EPA 350.1 Rev 2.0 1993 1 PASI-ANDS
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AMFO
92614358004 MW-4 EPA 200.7 Rev 4.4 1994 6 PASI-ADEC
SM 4500-H+B-2011 1 PASI-ASMS
TKN+NO3+NO2 Calculation 1 PASI-AMAB2
EPA 300.0 Rev 2.1 1993 1 PASI-AMJP
EPA 350.1 Rev 2.0 1993 1 PASI-ANDS
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AMFO
92614358005 MW-6 EPA 200.7 Rev 4.4 1994 6 PASI-ADEC
SM 4500-H+B-2011 1 PASI-ASMS
TKN+NO3+NO2 Calculation 1 PASI-AMAB2
EPA 300.0 Rev 2.1 1993 1 PASI-AMJP
EPA 350.1 Rev 2.0 1993 1 PASI-ANDS
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AMFO
92614358006 MW-7 EPA 200.7 Rev 4.4 1994 6 PASI-ADEC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 3 of 26
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SM 4500-H+B-2011 1 PASI-ASMS
TKN+NO3+NO2 Calculation 1 PASI-AMAB2
EPA 300.0 Rev 2.1 1993 1 PASI-AMJP
EPA 350.1 Rev 2.0 1993 1 PASI-ANDS
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AMFO
92614358007 MW-8 EPA 200.7 Rev 4.4 1994 6 PASI-ADEC
SM 4500-H+B-2011 1 PASI-ASMS
TKN+NO3+NO2 Calculation 1 PASI-AMAB2
EPA 300.0 Rev 2.1 1993 1 PASI-AMJP
EPA 350.1 Rev 2.0 1993 1 PASI-ANDS
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AMFO
PASI-A = Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 4 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Sample:MW-1 Lab ID:92614358001 Collected:07/12/22 09:50 Received:07/12/22 14:12 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Arsenic ND ug/L 07/19/22 12:41 7440-38-207/18/22 18:4910.0 1
Barium 228 ug/L 07/19/22 12:41 7440-39-307/18/22 18:495.0 1
Chromium ND ug/L 07/19/22 12:41 7440-47-307/18/22 18:495.0 1
Iron 25800 ug/L 07/19/22 12:41 7439-89-607/18/22 18:4950.0 1
Lead ND ug/L 07/19/22 12:41 7439-92-107/18/22 18:495.0 1
Manganese 4490 ug/L 07/19/22 12:41 7439-96-507/18/22 18:495.0 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.5 Std. Units 07/13/22 14:52 H30.10 1
Analytical Method: TKN+NO3+NO2 Calculation
Pace Analytical Services - Asheville
Total Nitrogen Calculation
Total Nitrogen 0.46 mg/L 07/18/22 15:150.040 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate ND mg/L 07/15/22 00:43 14808-79-81.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia 0.50 mg/L 07/14/22 11:33 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total ND mg/L 07/15/22 04:42 7727-37-907/14/22 14:570.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 ND mg/L 07/13/22 00:530.040 1
Nitrogen, Nitrate ND mg/L 07/13/22 00:53 14797-55-80.040 1
Nitrogen, Nitrite 0.043 mg/L 07/13/22 00:53 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 5 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Sample:MW-2 Lab ID:92614358002 Collected:07/12/22 11:45 Received:07/12/22 14:12 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Arsenic 19.7 ug/L 07/19/22 12:44 7440-38-207/18/22 18:4910.0 1
Barium 1890 ug/L 07/19/22 12:44 7440-39-307/18/22 18:495.0 1
Chromium 69.9 ug/L 07/19/22 12:44 7440-47-307/18/22 18:495.0 1
Iron 77700 ug/L 07/19/22 12:44 7439-89-607/18/22 18:4950.0 1
Lead 15.0 ug/L 07/19/22 12:44 7439-92-107/18/22 18:495.0 1
Manganese 480 ug/L 07/19/22 12:44 7439-96-507/18/22 18:495.0 1
Analytical Method: SM 2540C-2015
Pace Analytical Services - Asheville
2540C Total Dissolved Solids
Total Dissolved Solids 366 mg/L 07/14/22 15:3550.0 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.5 Std. Units 07/13/22 15:12 H30.10 1
Analytical Method: TKN+NO3+NO2 Calculation
Pace Analytical Services - Asheville
Total Nitrogen Calculation
Total Nitrogen 16.9 mg/L 07/18/22 15:150.040 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 2.5 mg/L 07/15/22 01:28 14808-79-81.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia 18.0 mg/L 07/14/22 11:59 7664-41-70.30 3
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 16.9 mg/L 07/15/22 04:43 7727-37-907/14/22 14:570.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 0.055 mg/L 07/13/22 01:040.040 1
Nitrogen, Nitrate 0.055 mg/L 07/13/22 01:04 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 07/13/22 01:04 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 6 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Sample:MW-3 Lab ID:92614358003 Collected:07/12/22 10:35 Received:07/12/22 14:12 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Arsenic 56.9 ug/L 07/19/22 12:48 7440-38-207/18/22 18:4910.0 1
Barium 317 ug/L 07/19/22 12:48 7440-39-307/18/22 18:495.0 1
Chromium 5.2 ug/L 07/19/22 12:48 7440-47-307/18/22 18:495.0 1
Iron 125000 ug/L 07/19/22 20:23 7439-89-607/18/22 18:4950010
Lead 5.6 ug/L 07/19/22 12:48 7439-92-107/18/22 18:495.0 1
Manganese 4350 ug/L 07/19/22 12:48 7439-96-507/18/22 18:495.0 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.5 Std. Units 07/13/22 14:56 H30.10 1
Analytical Method: TKN+NO3+NO2 Calculation
Pace Analytical Services - Asheville
Total Nitrogen Calculation
Total Nitrogen 13.0 mg/L 07/18/22 15:150.040 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 29.3 mg/L 07/15/22 01:43 14808-79-81.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia 15.1 mg/L 07/14/22 12:00 7664-41-70.30 3
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 13.0 mg/L 07/15/22 04:44 7727-37-907/14/22 14:570.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 0.052 mg/L 07/13/22 01:000.040 1
Nitrogen, Nitrate ND mg/L 07/13/22 01:00 14797-55-80.040 1
Nitrogen, Nitrite 0.051 mg/L 07/13/22 01:00 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Sample:MW-4 Lab ID:92614358004 Collected:07/12/22 12:30 Received:07/12/22 14:12 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Arsenic ND ug/L 07/19/22 12:58 7440-38-207/18/22 18:4910.0 1
Barium 92.6 ug/L 07/19/22 12:58 7440-39-307/18/22 18:495.0 1
Chromium ND ug/L 07/19/22 12:58 7440-47-307/18/22 18:495.0 1
Iron 5700 ug/L 07/19/22 12:58 7439-89-607/18/22 18:4950.0 1
Lead ND ug/L 07/19/22 12:58 7439-92-107/18/22 18:495.0 1
Manganese 659 ug/L 07/19/22 12:58 7439-96-507/18/22 18:495.0 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.4 Std. Units 07/13/22 15:20 H30.10 1
Analytical Method: TKN+NO3+NO2 Calculation
Pace Analytical Services - Asheville
Total Nitrogen Calculation
Total Nitrogen 0.69 mg/L 07/18/22 15:150.040 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 7.0 mg/L 07/15/22 01:58 14808-79-81.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia 0.65 mg/L 07/14/22 11:47 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 0.65 mg/L 07/15/22 04:45 7727-37-907/14/22 14:570.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 ND mg/L 07/13/22 01:060.040 1
Nitrogen, Nitrate ND mg/L 07/13/22 01:06 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 07/13/22 01:06 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Sample:MW-6 Lab ID:92614358005 Collected:07/12/22 11:30 Received:07/12/22 14:12 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Arsenic ND ug/L 07/19/22 13:02 7440-38-207/18/22 18:4910.0 1
Barium 68.6 ug/L 07/19/22 13:02 7440-39-307/18/22 18:495.0 1
Chromium ND ug/L 07/19/22 13:02 7440-47-307/18/22 18:495.0 1
Iron 63.0 ug/L 07/19/22 13:02 7439-89-607/18/22 18:4950.0 1
Lead ND ug/L 07/19/22 13:02 7439-92-107/18/22 18:495.0 1
Manganese 15.1 ug/L 07/19/22 13:02 7439-96-507/18/22 18:495.0 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 5.4 Std. Units 07/13/22 15:08 H30.10 1
Analytical Method: TKN+NO3+NO2 Calculation
Pace Analytical Services - Asheville
Total Nitrogen Calculation
Total Nitrogen ND mg/L 07/18/22 15:150.040 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate ND mg/L 07/15/22 02:13 14808-79-81.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia ND mg/L 07/14/22 11:55 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total ND mg/L 07/15/22 04:46 7727-37-907/14/22 14:570.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 ND mg/L 07/13/22 01:030.040 1
Nitrogen, Nitrate ND mg/L 07/13/22 01:03 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 07/13/22 01:03 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 9 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Sample:MW-7 Lab ID:92614358006 Collected:07/12/22 12:00 Received:07/12/22 14:12 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Arsenic ND ug/L 07/19/22 13:05 7440-38-207/18/22 18:4910.0 1
Barium 47.0 ug/L 07/19/22 13:05 7440-39-307/18/22 18:495.0 1
Chromium ND ug/L 07/19/22 13:05 7440-47-307/18/22 18:495.0 1
Iron ND ug/L 07/19/22 13:05 7439-89-607/18/22 18:4950.0 1
Lead ND ug/L 07/19/22 13:05 7439-92-107/18/22 18:495.0 1
Manganese ND ug/L 07/19/22 13:05 7439-96-507/18/22 18:495.0 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.3 Std. Units 07/13/22 15:15 H30.10 1
Analytical Method: TKN+NO3+NO2 Calculation
Pace Analytical Services - Asheville
Total Nitrogen Calculation
Total Nitrogen 0.94 mg/L 07/18/22 15:200.040 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 1.5 mg/L 07/15/22 02:28 14808-79-81.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia ND mg/L 07/14/22 12:02 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total ND mg/L 07/15/22 04:47 7727-37-907/14/22 14:570.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 0.94 mg/L 07/13/22 01:050.040 1
Nitrogen, Nitrate 0.94 mg/L 07/13/22 01:05 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 07/13/22 01:05 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Sample:MW-8 Lab ID:92614358007 Collected:07/12/22 11:05 Received:07/12/22 14:12 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Arsenic ND ug/L 07/19/22 13:09 7440-38-207/18/22 18:4910.0 1
Barium 10.6 ug/L 07/19/22 13:09 7440-39-307/18/22 18:495.0 1
Chromium ND ug/L 07/19/22 13:09 7440-47-307/18/22 18:495.0 1
Iron ND ug/L 07/19/22 13:09 7439-89-607/18/22 18:4950.0 1
Lead ND ug/L 07/19/22 13:09 7439-92-107/18/22 18:495.0 1
Manganese ND ug/L 07/19/22 13:09 7439-96-507/18/22 18:495.0 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.0 Std. Units 07/13/22 15:02 H30.10 1
Analytical Method: TKN+NO3+NO2 Calculation
Pace Analytical Services - Asheville
Total Nitrogen Calculation
Total Nitrogen 2.2 mg/L 07/18/22 15:200.040 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 20.1 mg/L 07/15/22 03:13 14808-79-81.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia ND mg/L 07/14/22 12:03 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total ND mg/L 07/15/22 04:51 7727-37-907/14/22 14:570.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 2.2 mg/L 07/13/22 01:020.040 1
Nitrogen, Nitrate 2.2 mg/L 07/13/22 01:02 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 07/13/22 01:02 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 11 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
711205
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
200.7 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92614358001, 92614358002, 92614358003, 92614358004, 92614358005, 92614358006, 92614358007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3708652
Associated Lab Samples:92614358001, 92614358002, 92614358003, 92614358004, 92614358005, 92614358006, 92614358007
Matrix:Water
Analyzed
Arsenic ug/L ND 10.0 07/19/22 12:20
Barium ug/L ND 5.0 07/19/22 12:20
Chromium ug/L ND 5.0 07/19/22 12:20
Iron ug/L ND 50.0 07/19/22 12:20
Lead ug/L ND 5.0 07/19/22 12:20
Manganese ug/L ND 5.0 07/19/22 12:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3708653LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic ug/L 441500 88 85-115
Barium ug/L 454500 91 85-115
Chromium ug/L 463500 93 85-115
Iron ug/L 47405000 95 85-115
Lead ug/L 464500 93 85-115
Manganese ug/L 474500 95 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3708654MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92614315001
3708655
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Arsenic ug/L 500 96 70-13089 8500ND482444
Barium ug/L 500 98 70-13089 950010498457
Chromium ug/L 500 99 70-13091 9500ND498455
Iron ug/L 5000 102 70-13093 9500010252004770
Lead ug/L 500 100 70-13092 9500ND500458
Manganese ug/L 500 102 70-13093 850015.2 523 480
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3708656MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92614358007
3708657
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Arsenic ug/L 500 94 70-13093 2500ND472464
Barium ug/L 500 94 70-13093 150010.6 481 474
Chromium ug/L 500 96 70-13095 2500ND482474
Iron ug/L 5000 99 70-13097 15000ND49804920
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 12 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3708656MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92614358007
3708657
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Lead ug/L 500 96 70-13095 1500ND481474
Manganese ug/L 500 98 70-13097 1500ND493488
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 13 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
710643
SM 2540C-2015
SM 2540C-2015
2540C Total Dissolved Solids
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92614358002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3705721
Associated Lab Samples:92614358002
Matrix:Water
Analyzed
Total Dissolved Solids mg/L ND 25.0 07/14/22 15:34
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3705722LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids mg/L 250250 100 90-110
Parameter Units
Dup
Result QualifiersRPDResult
92614488005
3705723SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 68.0 370.0
Parameter Units
Dup
Result QualifiersRPDResult
92614250003
3705724SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 120 1119
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 14 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
710260
SM 4500-H+B-2011
SM 4500-H+B-2011
4500H+B pH
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92614358001, 92614358002, 92614358003, 92614358004, 92614358005, 92614358006, 92614358007
Parameter Units
Dup
Result QualifiersRPDResult
92613313001
3703698SAMPLE DUPLICATE:
pH at 25 Degrees C Std. Units 6.0 H306.0
Parameter Units
Dup
Result QualifiersRPDResult
92614358003
3703699SAMPLE DUPLICATE:
pH at 25 Degrees C Std. Units 6.5 H306.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 15 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
710433
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92614358001, 92614358002, 92614358003, 92614358004, 92614358005, 92614358006, 92614358007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3704644
Associated Lab Samples:92614358001, 92614358002, 92614358003, 92614358004, 92614358005, 92614358006, 92614358007
Matrix:Water
Analyzed
Sulfate mg/L ND 1.0 07/14/22 22:28
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3704645LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate mg/L 49.450 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3704646MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92614349001
3704647
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Sulfate mg/L 50 102 90-110102 050ND52.0 51.8
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3704648MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92614358006
3704649
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Sulfate mg/L 50 104 90-110103 1501.5 53.8 53.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 16 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
710372
EPA 350.1 Rev 2.0 1993
EPA 350.1 Rev 2.0 1993
350.1 Ammonia
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92614358001, 92614358002, 92614358003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3704352
Associated Lab Samples:92614358001, 92614358002, 92614358003
Matrix:Water
Analyzed
Nitrogen, Ammonia mg/L ND 0.10 07/14/22 10:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3704353LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Ammonia mg/L 5.05 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3704354MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92613746003
3704355
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Ammonia mg/L 5 106 90-110101 1519.9 25.2 25.0
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3704356MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92614067001
3704357
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Ammonia mg/L 5 104 90-110103 15ND5.2 5.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 17 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
710374
EPA 350.1 Rev 2.0 1993
EPA 350.1 Rev 2.0 1993
350.1 Ammonia
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92614358004, 92614358005, 92614358006, 92614358007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3704361
Associated Lab Samples:92614358004, 92614358005, 92614358006, 92614358007
Matrix:Water
Analyzed
Nitrogen, Ammonia mg/L ND 0.10 07/14/22 10:48
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3704362LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Ammonia mg/L 5.05 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3704363MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92614358004
3704364
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Ammonia mg/L 5 104 90-110103 050.65 5.8 5.8
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3704365MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92614358005
3704366
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Ammonia mg/L 5 101 90-110101 05ND5.1 5.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 18 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
710567
EPA 351.2 Rev 2.0 1993
EPA 351.2 Rev 2.0 1993
351.2 TKN
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92614358001, 92614358002, 92614358003, 92614358004, 92614358005, 92614358006, 92614358007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3705055
Associated Lab Samples:92614358001, 92614358002, 92614358003, 92614358004, 92614358005, 92614358006, 92614358007
Matrix:Water
Analyzed
Nitrogen, Kjeldahl, Total mg/L ND 0.50 07/15/22 04:24
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3705056LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Kjeldahl, Total mg/L 9.810 98 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3705057MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92613878002
3705058
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Kjeldahl, Total mg/L M1,R1107590-11093 19100.99 8.5 10.3
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3705059MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92613878003
3705060
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Kjeldahl, Total mg/L M1108290-11086 4100.35J 8.6 8.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 19 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
710123
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
353.2 Nitrate + Nitrite, Unpres.
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92614358001, 92614358002, 92614358003, 92614358004, 92614358005, 92614358006, 92614358007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3703258
Associated Lab Samples:92614358001, 92614358002, 92614358003, 92614358004, 92614358005, 92614358006, 92614358007
Matrix:Water
Analyzed
Nitrogen, Nitrate mg/L ND 0.040 07/13/22 00:36
Nitrogen, Nitrite mg/L ND 0.040 07/13/22 00:36
Nitrogen, NO2 plus NO3 mg/L ND 0.040 07/13/22 00:36
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3703259LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate mg/L 1.51.5 102 90-110
Nitrogen, Nitrite mg/L 1.01 102 90-110
Nitrogen, NO2 plus NO3 mg/L 2.62.5 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3703260MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92613980001
3703261
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Nitrate mg/L 1.5 99 90-11098 01.52.3 3.8 3.8
Nitrogen, Nitrite mg/L 1 90 90-11090 01ND0.90 0.90
Nitrogen, NO2 plus NO3 mg/L 2.5 95 90-11095 02.52.3 4.7 4.7
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3703314MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92614289002
3703315
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Nitrate mg/L 1.5 110 90-110108 21.5ND 1.7 1.6
Nitrogen, Nitrite mg/L 1 99 90-11099 11ND0.99 1.0
Nitrogen, NO2 plus NO3 mg/L 2.5 105 90-110104 12.5ND 2.6 2.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 20 of 26
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Sample was received or analysis requested beyond the recognized method holding time.H3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 21 of 26
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92614358001 711205 711305MW-1 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92614358002 711205 711305MW-2 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92614358003 711205 711305MW-3 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92614358004 711205 711305MW-4 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92614358005 711205 711305MW-6 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92614358006 711205 711305MW-7 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92614358007 711205 711305MW-8 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92614358002 710643MW-2 SM 2540C-2015
92614358001 710260MW-1 SM 4500-H+B-2011
92614358002 710260MW-2 SM 4500-H+B-2011
92614358003 710260MW-3 SM 4500-H+B-2011
92614358004 710260MW-4 SM 4500-H+B-2011
92614358005 710260MW-6 SM 4500-H+B-2011
92614358006 710260MW-7 SM 4500-H+B-2011
92614358007 710260MW-8 SM 4500-H+B-2011
92614358001 711256MW-1 TKN+NO3+NO2
Calculation
92614358002 711256MW-2 TKN+NO3+NO2
Calculation
92614358003 711256MW-3 TKN+NO3+NO2
Calculation
92614358004 711256MW-4 TKN+NO3+NO2
Calculation
92614358005 711256MW-6 TKN+NO3+NO2
Calculation
92614358006 711257MW-7 TKN+NO3+NO2
Calculation
92614358007 711257MW-8 TKN+NO3+NO2
Calculation
92614358001 710433MW-1 EPA 300.0 Rev 2.1 1993
92614358002 710433MW-2 EPA 300.0 Rev 2.1 1993
92614358003 710433MW-3 EPA 300.0 Rev 2.1 1993
92614358004 710433MW-4 EPA 300.0 Rev 2.1 1993
92614358005 710433MW-6 EPA 300.0 Rev 2.1 1993
92614358006 710433MW-7 EPA 300.0 Rev 2.1 1993
92614358007 710433MW-8 EPA 300.0 Rev 2.1 1993
92614358001 710372MW-1 EPA 350.1 Rev 2.0 1993
92614358002 710372MW-2 EPA 350.1 Rev 2.0 1993
92614358003 710372MW-3 EPA 350.1 Rev 2.0 1993
92614358004 710374MW-4 EPA 350.1 Rev 2.0 1993
92614358005 710374MW-6 EPA 350.1 Rev 2.0 1993
92614358006 710374MW-7 EPA 350.1 Rev 2.0 1993
92614358007 710374MW-8 EPA 350.1 Rev 2.0 1993
92614358001 710567 710763MW-1 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92614358002 710567 710763MW-2 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92614358003 710567 710763MW-3 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92614358004 710567 710763MW-4 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 22 of 26
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92614358
Blue Ridge Tissue Corp
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92614358005 710567 710763MW-6 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92614358006 710567 710763MW-7 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92614358007 710567 710763MW-8 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92614358001 710123MW-1 EPA 353.2 Rev 2.0 1993
92614358002 710123MW-2 EPA 353.2 Rev 2.0 1993
92614358003 710123MW-3 EPA 353.2 Rev 2.0 1993
92614358004 710123MW-4 EPA 353.2 Rev 2.0 1993
92614358005 710123MW-6 EPA 353.2 Rev 2.0 1993
92614358006 710123MW-7 EPA 353.2 Rev 2.0 1993
92614358007 710123MW-8 EPA 353.2 Rev 2.0 1993
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/20/2022 04:42 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 23 of 26
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